WORLDWIDE ENGINEERING STANDARDS Material Specification GMW3059 General Restricted and Reportable Substances for Parts GMW3034 1 Scope QU 000001 This specification lists substances whose use in materials and components, in the interests of personnel and environmental safety, are either prohibited or limited. QU 000002 These restrictions are based on existing legislation or self-imposed regulations. QU 000005 The aim of this specification is to restrict/stop the usage of the substances listed, to facilitate compliance with current and future regulations. VDA 232-101 1.1 Material Description. Not applicable. 1.1.1 Material Identification. Not applicable. 1.2 Cross-Reference of Replaced GMIO & NAO Specifications. Delta Motors GM do Brasil GM Holdens HN 1000, Clause J GM NAO GM1000M ISUZU ITDC QU 000000 SAAB STD 3977 1.2.1 Specifications Qualified to this Material Specification. Not applicable 1.3 Symbol. Not applicable 1.4 Typical Application. This specification applies to materials and components specified by the purchaser and for items where the design is held by the supplier (black box). 2 References Note: Only the latest approved standards are applicable unless otherwise specified. 2.1 Normative. ISO 11014 2.2 GM. QU 000003 QU 000004 2.3 Additional. 3 Requirements The list contained in this technical specification is based on legal requirements and VDA 232-101 “VDA List for Chemicals Subject to Declaration“ (from the Association of German Automobile Manufacturers)“. All substances that are listed in this standard in Table 1 and Table 2 that could exist in the product or could be emitted from the product, must be declared. Content limits are specified for all substances both forbidden and requiring declaration. Unless otherwise specified this limit amount is 0.1 % by mass for both declared and forbidden materials. For amounts below this limit a declaration is not required. This percentage is to be calculated for the single material/surface treatment level part, not the assembly. All substances in the list marked with an “F” are forbidden above the reporting limit specified in the table or 0.1% by mass if a limit is not listed. These substances may be forbidden for all uses or for specific applications due to legal or internal regulations. If technical requirements make the use of these substances absolutely necessary, a deviation from this regulation must be agreed upon between the supplier and the responsible department at the purchaser. All substances in the list marked with “D“ must be declared at levels above the limit noted in the table or © Copyright March 1999 General Motors Corporation All Rights Reserved Page 1 of 17 May 1998 GMW3059 GM WORLDWIDE ENGINEERING STANDARD 0.1% by mass if a limit is not given in the table. All influences of their use for the specific application shall be evaluated to achieve the highest possible level of safety and environmental compatibility. These substances must be replaced by other substances, not listed herein, as soon as the advance of technology, availability and economics permit. Periodic reviews of the “D” listed items shall be conducted, the frequency of which will be established by the purchaser. 3.1 Requirements on Delivery. Independent of this regulation, the supplier bears the responsibility for ensuring that the materials and components delivered meet the relevant legislations and regulations of the countries to which it is supplied. The requirements defined in this specification apply according to clause 3.1.1 for all new materials and components supplied, unless otherwise specified on the drawing. These requirements also apply to resourced or re-designed materials and components. 3.1.1 Chemical Requirements. See Table 1 and Table 2. The table is given in both alphabetical order and by group (ie. metals, CFC’s, etc.), respectively. Questions regarding the presence of these substances can be resolved by using the test method listed in the note column of Table 1 and Table 2 or by testing metals by atomic absorption, organics by gas chromatography, and fibers by polarized light microscopy if no test method is listed. 3.1.2 Mechanical Requirements. Not applicable 3.1.3 Physical Requirements. Not applicable 3.1.4 Additional Requirements. This specification requires the submission of data sheet 1 in Appendix A. The substances and the materials/components they are used in must be detailed. If the substance is marked with an “F”, the form must be signed by the department listed in the contact list for the Unit the part is being supplied to. If the material/component being supplied does not contain any of the substances listed in Table 1 and Table 2, check the appropriate box and submit the form as a declaration of compliance to the unit contact as listed in the address list. See also “Deviation”. 3.2 Processing Requirements. were not applicable Subparagraphs 3.3 Performance Requirements. were not applicable Subparagraphs 3.4 Requirements on other Stages during Life Cycle. Subparagraphs were not applicable 4 Manufacturing Process Not applicable 5 Rules and Regulations 5.1 Legal Regulations. For use of this material/specification the valid laws and other regulations and recommendations in the country of usage have to be followed. 5.2 Language. In the event of any conflict between the English and domestic language regarding this document, the English language will take precedence. 5.3 Restricted and Reportable Substances. Not applicable 5.4 Inspection and Rejection. All shipments of materials or parts under contract or purchase order manufactured to this specification shall be equivalent in every respect to the initial samples approved by engineering. There shall be no changes in formulation or manufacturing process permitted without prior notification and approval by engineering. Lack of notification by the supplier constitutes grounds for rejection of any shipment. While samples may be taken from incoming shipments and checked for conformance to this specification, the supplier shall accept the responsibility for incoming shipments meeting this specification without dependence upon purchaser’s inspection. 5.5 Initial Source Approval. No shipments shall be made by any supplier until representative initial production samples have been approved by Materials Engineering as meeting the requirements of this specification. 5.6 Safety Data Sheets. Completed copies of the Material Safety Data Sheets meeting GM information requirements, consistent with ISO 11014 standard must be submitted with any new material submissions or where a composition change has occurred. 6 Approved Sources Not applicable © Copyright March 1999 General Motors Corporation All Rights Reserved Page 2 of 17 May 1998 GM WORLDWIDE ENGINEERING STANDARD GMW3059 Restricted and Reportable Substances for Parts per GMW3059 7 Coding System This material specification shall be given in other documents, drawings, VTS, SSTS, CTS etc. as follows: 8.2 Revisions. 8 Release and Revisions 8.1 Release. The specification was first approved and released in May, 1998. © Copyright March 1999 General Motors Corporation All Rights Reserved May 1998 Page 3 of 17 GMW3059 GM WORLDWIDE ENGINEERING STANDARD Table 1 - Restricted (F) and Reportable (D) Substances- List in Alphabetical Order Substance Acetamide Acrylamide Acrylonitrile Actinolite o-Aminoazotoluene Salts Category Acetamide Acrylamide Acrylonitrile Fibers/Asbestos Azo dye CAS No. 000060-35-5 000079-06-1 000107-13-1 13768-00-8 Group 4-Aminobiphenyl Aminobiphenyl, 4- 000092-67-1 D 4-Aminobiphenyl Salts Azo dye Group F 2-Amino-4-nitrotoluene Salts Azo dye Group F Amosite Aniline Aniline Salts Fibers/Asbestos 12172-73-5 F Aniline Aniline Fibers/Asbestos 000062-53-3 Group 17068-78-9 D D F Metals Flame retardant Metals Metals 7440-36-0 001309-64-4 D D D D > 400 ppm Auramine 000492-80-8 D metal refinement, metal adhesive, leather and textile refinement, wood preservative, color and melting coating cotton Metals Metals Group D D pigments, additives in lubricants Azo dye 000092-87-5 Benzidine Salts Azo dye Group Benzo(a)anthracene Benzo(a)pyrene and other PAH Benzo(a)pyrene and other PAH Benzo(a)pyrene and other PAH Benzo(a)pyrene and other PAH Benzo(a)pyrene and other PAH Metals Metals Flame retardants CFC 000056-55-3 Group Group 000353-59-3 D > 10 ppm D > 10 ppm D > 10 ppm D > 10 ppm D>1 ppm D D D F CFC 000075-63-8 F Butadiene Phthalates Metals 000106-99-0 000085-68-7 007440-43-9 Cadmium compounds Metals Group Carbon Tetrachloride CFC Chloraniline 000056-23-5 Group D D F > 75 ppm, D 75 ppm F > 75 ppm, D 75 ppm F D Azo dye Group Anthophylite Antimony Antimonous trioxide Arsenic Arsenic compounds Auramine Barium Barium compounds except Barium sulfate Benzidine Benzo(b)fluoranthene Benzo(j)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Beryllium Beryllium compounds Brominated flame retardants Bromochlorodifluoromethane (Halon 1211) Bromotrifluoromethane (Halon 1301) 1,3-Butadiene Butyl benzyl phthalate (BBP) Cadmium Chloraniline p-Chloraniline Salts Group 000205-99-2 000205-82-3 000207-08-9 000050-32-8 Rating Note D D Will be F in the future. D QU 000004 F F Salt regulated with azo dye QU 000004 Example - occurrence solvent admixture, softener stabilizer residual monomer residual monomer friction lining, gaskets, insulation found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics friction lining, gaskets, insulation dye QU 000004 friction lining, gaskets, insulation flame retardant F > 100 Salt regulated with azo found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics ppm dye found in textile and leather dyes, antioxidants, F F Will be F in the future. lubricants, rubbers, plastics bituminous coal tar, mineral oil, bitumen, softener oil Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil electronic parts QU 000003 refrigerating or foaming agent, propellant QU 000003 refrigerating or foaming agent, propellant residual monomer QU 000001 Only if pigments, polymer stabilizer, surface intentionally added for D protection of metals QU 000001 Only if pigments, polymer stabilizer, surface intentionally added for D protection of metals hardener or cross linkage agent for polymers and epoxy resin found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics © Copyright March 1999 General Motors Corporation All Rights Reserved Page 4 of 17 May 1998 GM WORLDWIDE ENGINEERING STANDARD GMW3059 Chlorepoxypropane (Epichlorohydrin) Polychlorinated compounds Biocides 000106-89-8 D residual monomer Including 001336-36-3 1570-64-5 F softener, impregnating agent, insulation liquid D Biocides 59-50-7 D HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC Flame retardant 338-65-8 338-64-7 75-68-3 000075-45-6 134190-53-7 110587-14-9 000593-70-4 134190-54-8 28987-04-4 Group F F F F F F F F F D CFC HCFC HCFC 000076-15-3 108662-83-5 2837-89-0 F F F HCFC 354-25-6 F HCFC Azo dye 134190-50-4 Group F F HCFC HCFC HCFC CFC HCFC Metals Metals 431-07-2 75-88-7 421-04-5 000075-72-9 26588-23-8 007440-47-3 Group F F F F F D D > 0.01 g/cm2 Fibers/Asbestos 12001-29-5 F Metals Colophony 007440-48-4 8050-09-7 D D Colophony (Rosin) Copper Metals 007440-50-8 D Copper compounds Metals Group D Creosote 8001-58-9 D Azo dye Group F Fibers/Asbestos 1200-28-4 F Azo dye Group F Azo dye Group F Benzo(a)pyrene and other PAH CFC 000053-70-3 Phthalates Azo dye 000084-74-2 Group D F HCFC HCFC 431-06-1 471-43-2 F F Chlorepoxypropane (Epichlorohydrin) Chlorinated Biphenyl (PCB) Chlorocresol (ortho-) Chlorocresol (meta-) 2-Chloro-1,1-Difluoroethane 1-Chloro-1,2-Difluoroethane 1-Chloro-1,1-Difluoroethane Chlorodifluoromethane (R22) Chlorodifluoropropane Chlorofluoroethane Chlorofluoromethane (R31) Chlorofluoropropane Chlorohexafluoropropane Chloroparaffin, unbranched, (C10H22-nCln where n = 1 ... 8 to C30H62-nCLn where n = 1 ... 28) Chloropentafluoroethane (R115) Chloropentafluoropropane 2-Chloro-1,1,1,2Tetrafluoroethane 1-Chloro-1,1,2,2Tetrafluoroethane Chlorotetrafluoropropane 4-Chloro toluidine Salts 1-Chloro-1,2,2-Trifluoroethane 2-Chloro-1,1,1-Trifluoroethane 1-Chloro-1,1,2-Trifluoroethane Chlorotrifluoromethane (R13) Chlorotrifluoropropane Chromium Chromium(VI)-Salt Chrysotile Cobalt Creosote p-Cresidine Salts Crocidolite 2,4-Diaminoanisol Salts 4,4'-Diaminodiphenyl-methane Salts Dibenz(a,h)anthracene Dibromotetrafluoroethane (Halon 2402) Dibutylphthalate (DBP) 3,3'-Dichloro benzidine Salts 1,2-Dichloro-1,2-Difluoroethane 1,1-Dichloro-2,2-Difluoroethane 000124-73-2 QU 000003 refrigerating or foaming agent, propellant QU 000003 refrigerating or foaming agent, propellant flame retardant, plasticizer QU 000003 refrigerating or foaming agent, propellant found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics QU 000003 refrigerating or foaming agent, propellant Alloys exempt Will be F Jan. 1, 2003 Test method: GMW3034 QU 000004 alloying component chrome pigments, surfaces chromed friction lining, gaskets, insulation alloy metal Alloys, electronics, and wiring exempt Alloys, electronics, and stabilizer wiring exempt QU 000004 found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics friction lining, gaskets, insulation found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics D > 10 Will be F in the future. ppm QU 000003 F Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil refrigerating or foaming agent, propellant softener found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics © Copyright March 1999 General Motors Corporation All Rights Reserved May 1998 Page 5 of 17 GMW3059 GM WORLDWIDE ENGINEERING STANDARD 1,2-Dichloro-1,1-Difluoroethane Dichlorodifluoromethane (R12) Dichlorodifluoropropane 1,2-Dichloro-1-Fluoroethane 1,1-Dichloro-2-Fluoroethane 1,1-Dichloro-1-Fluoroethane Dichlorofluoromethane Dichlorofluoropropane Dichlorohexafluoropropane (R216) Dichloropentafluoropropane Dichlorotetrafluoroethane (R114) Dichlorotetrafluoroethane Dichlorotetrafluoropropane 1,1-Dichloro-1,2,2,2-Tetrafluoroethane 2,2-Dichloro-1,1,1Trifluoroethane Dichlorotrifluoropropane Di-(2-ethylhexyl)phthalate (DEHP) Diethyl phthlate 1,1,-Difluoroethene (R1132a) 3,3'-Dimethoxy benzidine Salts HCFC CFC HCFC HCFC HCFC HCFC HCFC HCFC CFC 1649-08-7 000075-71-8 134190-52-6 430-57-9 430-53-5 1717-00-6 00075-43-41 127404-11-9 000661-97-2 F F F F F F F F F HCFC CFC CFC HCFC CFC 127564-92-5 000076-14-2 001320-37-2 127564-83-4 000374-07-2 F F F F F HCFC 306-83-2 F HCFC Phthalates 116890-51-8 000117-81-7 F D Phthalates CFC Azo dye 000084-66-2 000075-38-7 Group D F F 3,3'-Dimethylbenzidine Salts Azo dye Group F 3,3'-Dimethyl-4,4'diaminodiphenylmethane Salts Dimethyl phthalate Di-n-octyl-phthalate (DOP) Formaldehyde Azo dye Group F Phthalates Phthalates Biocides 000131-11-3 000117-84-0 000050-00-0 D D F Glutaric aldehyde Heptachlorofluoropropane (R211) Hexachlorodifluoropropane (R212) Hexachlorofluoropropane Isothiazolinones Glutaric aldehyde CFC CFC 000113-30-8 D F F HCFC Biocide F D Lead Lead compounds, soluble in water Metals Metals 29470-94-8 Including 26822-20-4 26172-55-4 007439-92-1 Group Lead compounds, insoluble in water Mercury Metals Group D Metals 007439-97-6 076546-99-3 D F QU 000003 refrigerating or foaming agent, propellant QU 000003 refrigerating or foaming agent, propellant softener QU 000003 refrigerating or foaming agent, propellant found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics QU 000002 biocide, adhesives, residues and fragments on plastics found in adhesives, paints, binders, varnishes If uncertain about solubility use test..... soldering alloys Example soluble compounds include lead nitrate and lead acetate. cable covering, corrosion protection, pigments, additive for cathodic elpo process cable covering, corrosion protection, pigments, additive for cathodic elpo process F > 10 Decision regarding ppm exemption for lighting to be made by each GM Unit pigments Mercury compounds Metals Group 4,4'-Methylene-to (2-chloraniline) Salts Mineral fibres diameter <3µm, length >5µm, l:d > 3:1 and other respirable Monochloroheptafluoropropane (R217) Monomethyldibromodiphenylmethane Azo dye Group F > 10 ppm F Fibers/Asbestos Group D Flame retardants 099688-47-8 F residues and fragments during the manufacture of polymers Monomethyldichlorodiphenylmethane Flame retardants 076253-60-6 F residues and fragments during the manufacture of polymers CFC found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics friction lining, shielding, reinforcement, insulation, cable F © Copyright March 1999 General Motors Corporation All Rights Reserved Page 6 of 17 May 1998 GM WORLDWIDE ENGINEERING STANDARD GMW3059 residues and fragments during the manufacture of polymers Monomethyltetrachlorodiphenylmethane Naphthalene 2-Naphthylamine Flame retardants Naphthalene Naphthylamine 000091-20-3 000091-59-8 D F 2-Naphthylamine Salts Azo dye Group F Nickel Nickel compounds Metals Metals 007440-02-0 Group D D Alloys exempt N-Nitrosodi-n-butylamine N-Nitrosodiethanolamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodi-i-propylamine N-Nitrosodi-n-propylamine N-Nitrosoethylphenylamine N-Nitrosomethylphenylamine N-Nitrosomethylethylamine N-Nitrosomorpholin N-Nitrosopiperidine N-Nitrosopyrrolidine Nonylphenol (4-) NFO Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Phenol D D D D D D D D D D D D D Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Nonylphenolethoxylates NFE 4,4'-Oxydianiline Salts Phenol Azo dye 000924-16-3 001116-54-7 000055-18-5 000062-75-9 000601-77-4 000621-64-7 000612-64-6 000614-00-6 010595-95-6 000059-89-2 000100-75-4 000930-55-2 104-40-5 25154-52-3 9016-45-9 Group Pentachlorodifluoropropane Pentachlorofluoroethane (R111) Pentachlorofluoropropane Pentachlorophenol (PCP) Pentachlorophenol compounds Pentachlorotrifluoropropane (R213) Phenol HCFC CFC HCFC Phenol Phenol CFC 116867-32-4 000354-56-3 134190-48-0 000087-86-5 Group F F F F F F Phenol 000108-95-2 D Phenols as a group N-Phenyl-2-naphthylamine Phenol Phenyl-2naphthylamine Flame retardants Flame retardants Group 000135-88-6 D D antioxidant 059536-65-1 F F additive in plastics and textiles F F additive in plastics and textiles softener, impregnating agent, insulation liquid Polybromated Biphenyl (PBB) Polybromated Diphenylether (PBDE) Polybromated Terphenyl Flame retardants Polychlorinated Terphenyl (PCT) Polychlorinated compounds PVC Polyvinylchloride F Salt regulated with azo dye D F 009002-86-2 D Radioactive Compounds Radioactive Compounds Sodium azide Sodium azide 026628-22-8 D> background D Sodium nitrite Styrene Styrene oxide Tetrachlorodifluoroethane (R112) 1,1,1,2-Tetrachloro-2,2Difluoroethane Tetrachlorodifluoropropane 1,1,2,2-Tetrachloro-1Fluoroethane 1,1,1,2-Tetrachloro-2Fluoroethane Sodium nitrile Styrene Styrene CFC CFC 7623-00-0 000100-42-5 000096-09-3 000076-12-0 000076-11-9 D D D F F HCFC HCFC 127564-82-3 354-14-3 F F HCFC 354-11-0 F textile additive found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics nickel pigment, galvanic additive, bonderize additive rubber article rubber article rubber article rubber article rubber article rubber article rubber article rubber article rubber article rubber article rubber article rubber article found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics wood preservative wood preservative QU 000005 residual monomer in phenolic resins, fragments on polymer materials, wood materials and textiles PVC as a minority constituent in other polymers only gas generator airbag QU 000003 residual monomer, solvent residual monomer, softener refrigerating or foaming agent, propellant © Copyright March 1999 General Motors Corporation All Rights Reserved May 1998 Page 7 of 17 GMW3059 GM WORLDWIDE ENGINEERING STANDARD Tetrachlorofluoropropane Tetrachlorotetrafluoropropane (R214) Tetrachlorotrifluoropropane 4,4'-Thiodianiline Salts HCFC CFC 134190-49-1 002268-46-4 F F HCFC Azo dye 29470-95-9 Group F F Thallium Thallium compounds Thiram (TMTD) Tin organic compounds m-Toluidine o-Toluidine p-Toluidine o-Toluidine Salts Metals Metals Flame retardants Metals Azo dye Azo dye Azo dye Azo dye 007440-28-0 Group 137-26-8 Group 000108-44-1 000095-53-4 000106-49-0 Group D D D D D D D F 2,4-Toluylendiamine salts Azo dye Group F Fibers/Asbestos 14567-73-8 F HCFC 354-21-2 F HCFC 354-15-4 F HCFC CFC CFC HCFC HCFC HCFC CFC HCFC CFC 127564-90-3 000071-55-6 000079-00-5 359-28-4 811-95-0 2366-36-1 000075-69-4 134190-51-5 004259-43-2 F F F F F F F F F HCFC CFC CFC 127564-91-4 000076-13-1 026523-64-8 F F F HCFC CFC Azo dye 61623-04-9 000354-58-5 Group F F F Flame retardants Flame retardants Vinylchloride Vinylchloride 000512-56-1 115-86-6 000075-35-4 000075-01-4 D D F F Tremolite 1,2,2-Trichloro-1,1Difluoroethane 1,2,2-Trichloro-1,2Difluoroethane Trichlorodifluoropropane 1,1,1-Trichloroethane 1,1,2- or 1,2,2-Trichloroethane 1,1,2-Trichloro-2-Flouroethane 1,1,2-Trichloro-1-Flouroethane 1,1,1-Trichloro-2-Flouroethane Trichlorofluoromethane (R11) Trichlorofluoropropane Trichloropentafluoropropane (R215) Trichlorotetrafluoropropane Trichlorotrifluoroethane (R113) 1,1,1-Trichloro-2,2,2-Trifluoro ethane Trichlorotrifluoropropane 1,1,1-Trifluorotrichloroethane 2,4,5-Trimethylaniline Salts Trimethylphosphate Triphenylphosphate Vinylidene chloride Vinylchloride monomer found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics electronic parts, sensor, alloying components QU 000004 catalyst for PUR foams, stabilizer dye, textile auxiliary, curing agent dye, textile auxiliary, curing agent dye, textile auxiliary, curing agent found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics friction lining, gaskets, insulation QU 000003 refrigerating or foaming agent, propellant QU 000003 refrigerating or foaming agent, propellant found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics flame retardant residual monomer © Copyright March 1999 General Motors Corporation All Rights Reserved Page 8 of 17 May 1998 GM WORLDWIDE ENGINEERING STANDARD GMW3059 Table 2 - Restricted (F) and Reportable (D) Substances - List by Category Substance Acetamide Acrylamide Acrylonitrile 4-Aminobiphenyl Category Acetamide Acrylamide Acrylonitrile Aminobiphenyl, 4- CAS No. 000060-35-5 000079-06-1 000107-13-1 000092-67-1 Rating Note D D Will be F in the future. D Salt regulated with azo D Aniline Aniline Salts Aniline Aniline Auramine 000062-53-3 Group 000492-80-8 D D D Auramine 2,4,5-Trimethylaniline Salts Azo dye Group F 2,4-Diaminoanisol Salts Azo dye Group F 2,4-Toluylendiamine salts Azo dye Group F 2-Amino-4-nitrotoluene Salts Azo dye Group F 3,3'-Dichloro benzidine Salts Azo dye Group F 3,3'-Dimethoxy benzidine Salts Azo dye Group F 3,3'-Dimethyl-4,4'diaminodiphenylmethane Salts 3,3'-Dimethylbenzidine Salts Azo dye Group F Azo dye Group F 4,4'-Diaminodiphenyl-methane Azo dye Salts 4,4'-Methylene-to (2-chloraniline) Azo dye Salts 4,4'-Oxydianiline Salts Azo dye Group F Group F found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics Group F 4,4'-Thiodianiline Salts Azo dye Group F 4-Aminobiphenyl Salts Azo dye Group F 4-Chloro toluidine Salts Azo dye Group F Benzidine Azo dye 000092-87-5 found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics m-Toluidine o-Aminoazotoluene Salts Azo dye Azo dye 000108-44-1 Group o-Toluidine o-Toluidine Salts Azo dye Azo dye 000095-53-4 Group D F p-Chloraniline Salts Azo dye Group F p-Cresidine Salts Azo dye Group F p-Toluidine 2-Naphthylamine Salts Azo dye Azo dye 000106-49-0 Group D F Benzidine Salts Azo dye Group F Benzo(a)anthracene Benzo(a)pyrene and other PAH Benzo(a)pyrene and other PAH Benzo(a)pyrene and other PAH Benzo(a)pyrene and other PAH Benzo(a)pyrene and other PAH 000056-55-3 dye Benzo(a)pyrene Benzo(b)fluoranthene Benzo(j)fluoranthene Benzo(k)fluoranthene 000050-32-8 000205-99-2 000205-82-3 000207-08-9 Example - occurrence solvent admixture, softener stabilizer residual monomer residual monomer found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics dye cotton found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics F > 100 Salt regulated with azo ppm dye dye, textile auxiliary, curing agent D found in textile and leather dyes, antioxidants, F D > 10 ppm D>1 ppm D > 10 ppm D > 10 ppm D > 10 ppm Will be F in the future. lubricants, rubbers, plastics dye, textile auxiliary, curing agent found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics dye, textile auxiliary, curing agent found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics bituminous coal tar, mineral oil, bitumen, softener oil Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil Will be F in the future. bituminous coal tar, mineral oil, bitumen, softener oil © Copyright March 1999 General Motors Corporation All Rights Reserved May 1998 Page 9 of 17 GMW3059 Dibenz(a,h)anthracene Isothiazolinones GM WORLDWIDE ENGINEERING STANDARD Benzo(a)pyrene and other PAH Biocide 000053-70-3 D > 10 Will be F in the future. ppm D bituminous coal tar, mineral oil, bitumen, softener oil found in adhesives, paints, binders, varnishes Biocides Including 26822-20-4 26172-55-4 1570-64-5 Biocides 59-50-7 D Biocides 000050-00-0 F QU 000002 Butadiene CFC CFC 000106-99-0 000075-38-7 000076-11-9 D F F QU 000003 biocide, adhesives, residues and fragments on plastics residual monomer refrigerating or foaming agent, propellant CFC 026523-64-8 F CFC CFC CFC CFC 000071-55-6 000354-58-5 000079-00-5 000374-07-2 F F F F CFC 000353-59-3 F QU 000003 refrigerating or foaming agent, propellant CFC 000075-63-8 F QU 000003 refrigerating or foaming agent, propellant CFC CFC CFC CFC 000056-23-5 000076-15-3 000075-72-9 000124-73-2 F F F F QU 000003 QU 000003 QU 000003 refrigerating or foaming agent, propellant refrigerating or foaming agent, propellant refrigerating or foaming agent, propellant CFC CFC 000075-71-8 000661-97-2 F F QU 000003 refrigerating or foaming agent, propellant CFC CFC CFC CFC 001320-37-2 000076-14-2 F F F F QU 000003 refrigerating or foaming agent, propellant D Chlorocresol (ortho-) Chlorocresol (meta-) Formaldehyde 1,3-Butadiene 1,1,-Difluoroethene (R1132a) 1,1,1,2-Tetrachloro-2,2Difluoroethane 1,1,1-Trichloro-2,2,2-Trifluoroethane 1,1,1-Trichloroethane 1,1,1-Trifluorotrichloroethane 1,1,2- or 1,2,2-Trichloroethane 1,1-Dichloro-1,2,2,2-Tetrafluoro ethane Bromochlorodifluoromethane (Halon 1211) Bromotrifluoromethane (Halon 1301) Carbon Tetrachloride Chloropentafluoroethane (R115) Chlorotrifluoromethane (R13) Dibromotetrafluoroethane (Halon 2402) Dichlorodifluoromethane (R12) Dichlorohexafluoropropane (R216) Dichlorotetrafluoroethane Dichlorotetrafluoroethane (R114) Heptachlorofluoropropane (R211) Hexachlorodifluoropropane (R212) Monochloroheptafluoropropane (R217) Pentachlorofluoroethane (R111) Pentachlorotrifluoropropane (R213) Tetrachlorodifluoroethane (R112) Tetrachlorotetrafluoropropane (R214) Trichlorofluoromethane (R11) Trichloropentafluoropropane (R215) Trichlorotrifluoroethane (R113) 076546-99-3 CFC F CFC CFC 000354-56-3 F F CFC CFC 000076-12-0 002268-46-4 F F QU 000003 refrigerating or foaming agent, propellant CFC CFC 000075-69-4 004259-43-2 F F QU 000003 refrigerating or foaming agent, propellant CFC Chloraniline 000076-13-1 Group F D QU 000003 refrigerating or foaming agent, propellant hardener or cross linkage agent for polymers and epoxy resin Chlorepoxypropane 000106-89-8 (Epichlorohydrin) Colophony 8050-09-7 D Creosote 8001-58-9 D Amosite Fibers/Asbestos Fibers/Asbestos 13768-00-8 12172-73-5 F F QU 000004 QU 000004 friction lining, gaskets, insulation friction lining, gaskets, insulation Anthophylite Fibers/Asbestos 17068-78-9 F QU 000004 friction lining, gaskets, insulation Fibers/Asbestos 12001-29-5 F QU 000004 friction lining, gaskets, insulation Chloraniline Chlorepoxypropane (Epichlorohydrin) residual monomer D Colophony (Rosin) Creosote Actinolite Chrysotile © Copyright March 1999 General Motors Corporation All Rights Reserved Page 10 of 17 May 1998 GM WORLDWIDE ENGINEERING STANDARD Crocidolite Mineral fibres diameter <3µm, length >5µm, l:d > 3:1 and other respirable Tremolite Brominated flame retardants Monomethyldibromodiphenylmethane Monomethyldichlorodiphenylmethane Monomethyltetrachlorodiphenylmethane Polybromated Biphenyl (PBB) Polybromated Diphenylether (PBDE) Polybromated Terphenyl Thiram (TMTD) Trimethylphosphate Triphenylphosphate Antimonous trioxide Chloroparaffin, unbranched, (C10H22-nCln where n = 1 ... 8 to C30H62-nCLn where n = 1 ... 28) Glutaric aldehyde 1,1,1,2-Tetrachloro-2Fluoroethane 1,1,1-Trichloro-2-Flouroethane 1,1,2,2-Tetrachloro-1Fluoroethane 1,1,2-Trichloro-1-Flouroethane 1,1,2-Trichloro-2-Flouroethane 1,1-Dichloro-1-Fluoroethane 1,1-Dichloro-2,2-Difluoroethane 1,1-Dichloro-2-Fluoroethane 1,2,2-Trichloro-1,1Difluoroethane 1,2,2-Trichloro-1,2Difluoroethane 1,2-Dichloro-1,1-Difluoroethane 1,2-Dichloro-1,2-Difluoroethane 1,2-Dichloro-1-Fluoroethane 1-Chloro-1,1,2,2Tetrafluoroethane 1-Chloro-1,1,2-Trifluoroethane 1-Chloro-1,1-Difluoroethane 1-Chloro-1,2,2-Trifluoroethane 1-Chloro-1,2-Difluoroethane 2,2-Dichloro-1,1,1Trifluoroethane 2-Chloro-1,1,1,2Tetrafluoroethane 2-Chloro-1,1,1-Trifluoroethane 2-Chloro-1,1-Difluoroethane Chlorodifluoromethane (R22) Chlorodifluoropropane Chlorofluoroethane Chlorofluoromethane (R31) Chlorofluoropropane Chlorohexafluoropropane Chloropentafluoropropane Chlorotetrafluoropropane GMW3059 QU 000004 friction lining, gaskets, insulation Fibers/Asbestos 1200-28-4 F Fibers/Asbestos Group D Fibers/Asbestos 14567-73-8 F Flame retardants Flame retardants Group 099688-47-8 D F Flame retardants 076253-60-6 F residues and fragments during the manufacture of polymers F residues and fragments during the manufacture of polymers Flame retardants Flame retardants Flame retardants 059536-65-1 friction lining, shielding, reinforcement, insulation, cable QU 000004 residues and fragments during the manufacture of polymers F F Flame retardants Flame retardants Flame retardants Flame retardants Flame retardants Flame retardants 137-26-8 000512-56-1 115-86-6 001309-64-4 Group F D D D D D Glutaric aldehyde HCFC 000113-30-8 354-11-0 D F HCFC HCFC 2366-36-1 354-14-3 F F HCFC HCFC HCFC HCFC HCFC HCFC 811-95-0 359-28-4 1717-00-6 471-43-2 430-53-5 354-21-2 F F F F F F HCFC 354-15-4 F HCFC HCFC HCFC HCFC 1649-08-7 431-06-1 430-57-9 354-25-6 F F F F HCFC HCFC HCFC HCFC HCFC 421-04-5 75-68-3 431-07-2 338-64-7 306-83-2 F F F F F HCFC 2837-89-0 F HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC 75-88-7 338-65-8 000075-45-6 134190-53-7 110587-14-9 000593-70-4 134190-54-8 28987-04-4 108662-83-5 134190-50-4 F F F F F F F F F F friction lining, gaskets, insulation additive in plastics and textiles additive in plastics and textiles flame retardant flame retardant flame retardant, plasticizer QU 000003 refrigerating or foaming agent, propellant QU 000003 refrigerating or foaming agent, propellant © Copyright March 1999 General Motors Corporation All Rights Reserved May 1998 Page 11 of 17 GMW3059 GM WORLDWIDE ENGINEERING STANDARD Chlorotrifluoropropane Dichlorodifluoropropane Dichlorofluoromethane Dichlorofluoropropane Dichloropentafluoropropane Dichlorotetrafluoropropane Dichlorotrifluoropropane Hexachlorofluoropropane Pentachlorodifluoropropane Pentachlorofluoropropane Tetrachlorodifluoropropane Tetrachlorofluoropropane Tetrachlorotrifluoropropane Trichlorodifluoropropane Trichlorofluoropropane Trichlorotetrafluoropropane Trichlorotrifluoropropane Antimony Arsenic Arsenic compounds HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC HCFC Metals Metals Metals 26588-23-8 134190-52-6 00075-43-41 127404-11-9 127564-92-5 127564-83-4 116890-51-8 29470-94-8 116867-32-4 134190-48-0 127564-82-3 134190-49-1 29470-95-9 127564-90-3 134190-51-5 127564-91-4 61623-04-9 7440-36-0 Barium Barium compounds except Barium sulfate Beryllium Beryllium compounds Cadmium Metals Metals Group Metals Metals Metals Group 007440-43-9 Cadmium compounds Metals Group Chromium Chromium(VI)-Salt Metals Metals 007440-47-3 Group Cobalt Copper Metals Metals 007440-48-4 007440-50-8 D D Copper compounds Metals Group D Lead Lead compounds, insoluble in water Lead compounds, soluble in water Metals Metals 007439-92-1 Group D D Metals Group F Mercury Metals 007439-97-6 Group F F F F F F F F F F F F F F F F F D D D > 400 ppm metal refinement, metal adhesive, leather and textile refinement, wood preservative, color and melting coating D D D D F > 75 ppm, D 75 ppm F > 75 ppm, D 75 ppm D D > 0.01 g/cm2 pigments, additives in lubricants electronic parts QU 000001 Only if pigments, polymer stabilizer, surface intentionally added for D protection of metals QU 000001 Only if pigments, polymer stabilizer, surface intentionally added for D protection of metals Alloys exempt Will be F Jan. 1, 2003 Test method: GMW3034 alloying component chrome pigments, surfaces chromed alloy metal Alloys, electronics, and wiring exempt Alloys, electronics, and stabilizer wiring exempt soldering alloys cable covering, corrosion protection, pigments, additive for cathodic elpo process If uncertain about solubility use test..... Example soluble compounds include lead nitrate and lead acetate. cable covering, corrosion protection, pigments, additive for cathodic elpo process F > 10 Decision regarding ppm exemption for lighting to be made by each GM Unit Mercury compounds Metals Group F > 10 ppm Alloys exempt D D Nickel Nickel compounds Metals Metals 007440-02-0 Group Thallium Thallium compounds Tin organic compounds Naphthalene 2-Naphthylamine Metals Metals Metals Naphthalene Naphthylamine 007440-28-0 Group Group 000091-20-3 000091-59-8 D D D D F N-Nitrosodi-i-propylamine N-Nitrosodi-n-butylamine Nitrosamine Nitrosamine 000601-77-4 000924-16-3 D D Salt regulated with azo dye Will be F in the future. Will be F in the future. pigments nickel pigment, galvanic additive, bonderize additive electronic parts, sensor, alloying components catalyst for PUR foams, stabilizer textile additive found in textile and leather dyes, antioxidants, lubricants, rubbers, plastics rubber article rubber article © Copyright March 1999 General Motors Corporation All Rights Reserved Page 12 of 17 May 1998 GM WORLDWIDE ENGINEERING STANDARD N-Nitrosodi-n-propylamine N-Nitrosodiethanolamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosoethylphenylamine N-Nitrosomethylethylamine N-Nitrosomethylphenylamine N-Nitrosomorpholin N-Nitrosopiperidine N-Nitrosopyrrolidine Nonylphenol (4-) NFO Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Nitrosamine Phenol Nonylphenolethoxylates NFE Pentachlorophenol (PCP) Pentachlorophenol compounds Phenol Phenol Phenol Phenol Phenol Phenols as a group N-Phenyl-2-naphthylamine Phenol Phenyl-2naphthylamine Phthalates Phthalates Butyl benzyl phthalate (BBP) Di-(2-ethylhexyl)phthalate (DEHP) Di-n-octyl-phthalate (DOP) Dibutylphthalate (DBP) Diethyl phthlate Dimethyl phthalate Chlorinated Biphenyl (PCB) Phthalates Phthalates Phthalates Phthalates Polychlorinated compounds Polychlorinated Terphenyl (PCT) Polychlorinated compounds PVC Polyvinylchloride GMW3059 Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. Will be F in the future. rubber article rubber article rubber article rubber article rubber article rubber article rubber article rubber article rubber article rubber article QU 000005 wood preservative wood preservative residual monomer in phenolic resins, fragments on polymer materials, wood materials and textiles 000621-64-7 001116-54-7 000055-18-5 000062-75-9 000612-64-6 010595-95-6 000614-00-6 000059-89-2 000100-75-4 000930-55-2 104-40-5 25154-52-3 9016-45-9 000087-86-5 Group 000108-95-2 D D D D D D D D D D D Group 000135-88-6 D D antioxidant 000085-68-7 000117-81-7 D D softener 000117-84-0 000084-74-2 000084-66-2 000131-11-3 Including 001336-36-3 D D D D F D F F D Will be F in the future. softener, impregnating agent, insulation liquid softener, impregnating agent, insulation liquid F 009002-86-2 D Radioactive Compounds Radioactive Compounds Sodium azide Sodium azide 026628-22-8 D> background D Sodium nitrite Styrene Styrene oxide Vinylchloride monomer Vinylidene chloride Sodium nitrile Styrene Styrene Vinylchloride Vinylchloride 7623-00-0 000100-42-5 000096-09-3 000075-01-4 000075-35-4 D D D F F softener PVC as a minority constituent in other polymers only gas generator airbag residual monomer, solvent residual monomer, softener residual monomer © Copyright March 1999 General Motors Corporation All Rights Reserved May 1998 Page 13 of 17 GMW3059 GM WORLDWIDE ENGINEERING STANDARD Appendix A Data Sheet 1 © Copyright March 1999 General Motors Corporation All Rights Reserved Page 14 of 17 May 1998 GM WORLDWIDE ENGINEERING STANDARD Instructions for Data Sheet 1 Data Sheet 1 is to be filled out for all parts. The form should be mailed to each unit that the part is being supplied to. If the part is being supplied to more than one unit, for example NAO Car Group and Opel, the form must be mailed to each unit. A. Assembly (Asm)/Part Information: Title block Enter the information that identifies the part being supplied into sections B-H. B. Asm/Part Number: Enter the part identification number assigned by the unit the part is being supplied to. C. Asm/Part Name: Enter the name of the part as assigned by the unit the part is being supplied to. D. Model Yr/Vehicle Line: Enter the model year of the vehicle the part is being supplied for and the name of the vehicle. E. Asm/Part Revision Level and Rev. Date: Enter any information that would identify what the most current level of revision and what date that last revision occurred. F. Unit Supplied to: Enter the name of the organization you are supplying the part to. A list of units along with contact information for each is in the appendix. GMW3059 L. Department: Enter the department within the supplier company that the contact belongs to. M. Mail Code (if applicable): Enter internal mail code if required within supplier company to get mail to the contact person. N. Address: Enter address (including country), telephone number, and fax number for supplier. O. Declaration section: Mark the applicable box. If box 1 is marked proceed to section T sign and submit form. If box 2 is marked proceed to section P. P. Component in Assembly: If there is more than one component in the assembly/part being supplied enter the part number, name, and mass of the specific component that the reported substance is found in. If there is more than one component that contains the reported substance list all components that apply. If there is more than one reported substance, list all components that contain each substance. Q. Material/Surface treatment: Enter the standard number, name, and mass percentage of the material or surface treatment that contains the restricted or reported substance. R. Substance: Enter the CAS number, name, and mass percentage of the reported substance present in the material/surface treatment listed in Q. H. Comments: Enter any other information that would help identify the part. S. Purpose for Use and Plan to Eliminate Use Including Timing and Substitute Substances: State the reason this substance must be used. Also state what plans are in place to eliminate the use of this substance, by what date the use will be eliminated and what the substitute substance will be. I. Manufacturer/Supplier Information: Title block Supplier enters their information in sections J-N. T. Supplier Certification: Sign, print name and date to certify all listed information is true and correct. J. Name: Enter contact name at the supplier. U. Unit Approval if “F” Substances Present: If the substance listed is a “F” substance the unit the part is being supplied to must sign the form to approve the use. G. Asm/Part Mass: Enter the mass of the complete assembly being supplied. K. Company: Enter company name that is supplying the part. © Copyright March 1999 General Motors Corporation All Rights Reserved May 1998 Page 15 of 17 GMW3059 GM WORLDWIDE ENGINEERING STANDARD Address List Unit Contact: Unit: Dept.: Post-box/ mail code: Location: Mr./Mrs.: Phone: Fax: Adam Opel AG Holdens GM NAO Car Group ITDC, Central Laboratories Central Laboratory Materials Engineering PKZ: 85-70 Mail Point 350 480-205-161 65423 Rüsselsheim 241 Salmon St 30007 VanDyke Germany Port Melbourne 3207 Warren, MI 48090 Australia USA Christine Haber Phil Stirling Jack Relyea 06142 / 771745 61 3 9647 1714 (810)492-1291 06142 / 774484 61 3 9647 1286 (810)492-6354 Saab GM do Brasil Ltda GM NAO Truck Group Materials Technology Materials Eng. - Chemical Lab. CChemical Lab. Unit Contact: Unit: Dept.: Post-box/ mail code: Location: TVLEA 16-1 Cx. Postal 197 S-461 80 Trollhattan Sao Caetano do Sul - SP Sweden CEP 09501 - 907 Brasil Mr./Mrs.: Phone: Fax: Cristina Nordstrom Antonio Carlos Haddad 0520-84893 55 11 4234 7871 0520-78150 55 11 4234 7981 Unit Contact: Unit: Isuzu Dept.: Post-box/ mail code: Location: Mr./Mrs.: Phone: Fax: © Copyright March 1999 General Motors Corporation All Rights Reserved Page 16 of 17 May 1998 GM WORLDWIDE ENGINEERING STANDARD Deviations GMW3059 For parts being supplied to Saab, signatures are required for all substances, both D and F. © Copyright March 1999 General Motors Corporation All Rights Reserved Page 17 of 17 May 1998