Assignment: Alka Seltzer Instructions: Read the article on Alka Seltzer (What would happen if you mixed sour salt with baking soda and added some water?) and answer the following questions. Some questions require a little extra research. Place answers on the answer sheet at the end of this document for submission. 1. Sour salt is the common name for: a) b) c) d) e) sodium bicarbonate sodium chloride acetylsalicylic acid (ASA) sodium citrate citric acid 2. Baking soda is the common name for: a) b) c) d) e) sodium bicarbonate sodium hydrogen carbonate acetylsalicylic acid (ASA) sodium citrate both a and b 3. What is the chemical formula of sour salt? a) b) c) d) e) C6H12O6 CH2O C2H6O C6H8O7 CH4O 4. How many “acidic” H atoms are there in one molecule of sour salt? a) b) c) d) e) 1 2 3 4 5 5. What is the chemical formula of baking soda? a) b) c) d) e) Na2CO3 NaCO3 NaH2CO3 NaHCO3 Na2HCO3 6. What type of reaction(s) would occur between an acid and baking soda? a) b) c) d) e) synthesis and combustion combustion and decomposition single displacement and synthesis decomposition and single displacement double displacement and decomposition 7. What are the products of the reaction between citric acid and baking soda? a) b) c) d) e) sodium citrate + water sodium + water + carbon dioxide sodium citrate + carbonic acid sodium chloride + carbon dioxide sodium citrate + water + carbon dioxide 8. What is the chemical formula for aspirin? a) b) c) d) e) C9H8O4 C12H22O11 CH2O C6H8O7 C7H6O3 9. How many “acidic” H atoms are there in one molecule of aspirin? a) b) c) d) e) 1 2 3 4 5 10. What are the products of the reaction between aspirin and baking soda? a) b) c) d) e) sodium bicarbonate + acetylsalicylic acid sodium acetylsalicylate + water + carbon dioxide sodium chloride + water sodium acetylsalicylate + carbon dioxide sodium + water + carbon dioxide 11. What are the ingredients in Alka Seltzer? a) b) c) d) e) aspirin baking soda citric acid both b and c a, b, and c 12. What is heartburn? a) b) c) d) e) the feeling you get when you see someone you’re attracted to a burning sensation felt in the stomach due to stomach ulcers a burning sensation felt in the mid esophagus region due to exposure to stomach acid a headache caused by doing too much homework none of the above 13. What is the purpose of taking Alka Seltzer? a) b) c) d) e) it is used as a sodium supplement it is used to neutralize excess stomach acid and treat an accompanying headache it is used to enhance your intelligence it is used to wash dishes it is used to satisfy your need to see a cool chemical reaction when you add it to water 14. What is the chemical formula for sodium citrate? a) b) c) d) e) Na2C4H4O6 NaCN Na2CO3 NaClO Na3C6H5O7 15. The article mentions that sodium citrate is an effective antacid. Why is this so? a) b) c) d) sodium ions can capture H+ ions from stomach acid which acts to neutralize the acid citrate ions can capture H+ ions from stomach acid which acts to neutralize the acid both a and b none of the above 16. Why is citric acid added as an ingredient for Alka Seltzer? a) to help get the “fizz fizz” to boost sales b) to form sodium citrate which acts as an effective antacid c) both a and b 17. What is the difference between the chemical makeup of a Ballistic Bomb and Alka Seltzer? a) the Ballistic Bomb contains premade, compressed CO2 gas which releases when it dissolves b) Alka Seltzer contains various scent chemicals c) the Ballistic Bomb does not contain any ASA 18. Why do they call it Alka Seltzer? a) it just sounds cool b) Alka Seltzer is the name of the person who invented it c) alka refers to alkaline (base) and seltzer refers to carbonated water (a plop plop fizz fizz antacid!) Answer Sheet: Alka Seltzer 1. ____ 2. ____ 3. ____ 4. ____ 5. ____ 6. ____ 7. ____ 8. ____ 9. ____ 10.____ 11.____ 12.____ 13.____ 14.____ 15.____ 16.____ 17.____ 18.____ Name: ______________________ /18 What would happen if you mixed sour salt with baking soda and added some water? You would get some pretty vigorous bubbling as the carbon dioxide generated escaped from the solution. Baking soda is sodium bicarbonate and will react with any acid to release carbon dioxide gas. Indeed it is called “baking” soda because it can react with acidic ingredients in recipes such as yogurt to make pastry dough rise by forming pockets of carbon dioxide. “Sour salt” is just the common name for citric acid, and combining it with baking soda will produce a fizz. And that has commercial applications. Alka Seltzer features both sodium bicarbonate and citric acid. Drop a tablet into a glass of water and it fizzes with impressive vigour. The fizzing sends a message to the consumer that something is happening. Indeed it is. Carbon dioxide is being released. What does that have to do with any medicinal effect? Not much. Alka Seltzer is meant to be taken if an upset stomach or “heartburn” is accompanied by a headache. Heartburn can be caused by excess acid in the stomach which can be readily neutralized by a base. Sodium bicarbonate itself could do a good job, but if you just dissolve bicarbonate in water there is no fizz. However, when citric acid is included as well, a reaction takes place producing sodium citrate with the release of carbon dioxide. Sodium citrate is an effective antacid. As far as the headache goes, Alka Seltzer treats it with aspirin. It contains acetyl salicylic acid which reacts with sodium bicarbonate to yield sodium acetyl salicylate. This is very soluble and leads to fast absorption. The same effect could be obtained just with a mixture of aspirin and baking soda, but then there would be no plop plop fizz fizz to boost sales. The same combo of sour salt and baking soda is used to put a fizz into the sales of the “Ballistic Bomb.” The advertising is clever. “Feel Good in the Southern Hemisphere! Try a Ballistic Bomb.” The marketers weren’t talking about hitching a ride aboard a missile to Australia. They were talking about the Southern Hemisphere of the body. The part that is immersed in the water in a bath. The Ballistic Bomb is a hardened cake of chemicals that is designed to be dropped into the bath water. It produces vigorous fizzing, supposedly the cause of pleasure in the “Southern Hemisphere,” while releasing a plethora of scents which claim to relax the bather and put a smile on his or her face. Different bombs have different scents. They range from “aphrodisiac jasmine” and “soothing rose” to “Sicilian orange” and “neroli” which costs “an absolute fortune” but is guaranteed to put anyone in a good mood. Essentially the Ballistic Bomb is a giant Alka-Seltzer tablet, without the medication. Baking soda is cheap, and citric acid is also an economical solid acid with “natural” overtones. In fact, the advertising for the Ballistic Bomb plays up the fact that citric acid is natural. This of course is irrelevant. Citric acid, or sour salt, is produced by the mycological fermentation of crude sugar solutions such as molasses with strains of Aspergillus niger. If it were chemically synthesized, it would still do the same thing. Citric acid is citric acid, no matter how it is made. What is clear is that when it is combined with sodium bicarbonate and dropped into the bath, a massive amount of carbon dioxide is released. A pretty interesting sensation but unfortunately the fizzing doesn’t last very long and the effect on the “southern hemisphere” is pretty limited. I think I’ll stick to the jacuzzi. Although I must admit that scent of “neroli” which is derived from the essential oils of the flowers of the orange tree, and named after the Italian princess who discovered it, is more appealing than the aroma of chlorine emanating from the jacuzzi. -1– Office for Science and Society