SCH Assignment: Hydrogen Peroxide - The Genie In The Bottle Read the article “The Genie In The Bottle” by Dr. Joe Schwarcz and answer the following questions. Bring in your answers to class and you will transfer them to a scantron card. 1. The smoke effect in the show I Dream of Jeannie was accomplished by decomposing hydrogen peroxide. Which of the following correctly shows the decomposition of hydrogen peroxide? a. b. c. d. e. H2O2 H2 + O2 H2O H2 + O2 H2O2 H2O + H2 H2O2 H2O + O2 none of the above 2. Why is hydrogen peroxide sold in brown bottles? a. brown colouring agents are inexpensive to produce b. hydrogen peroxide is photosensitive and the brown colour protects the H2O2 from dangerously decomposing in a closed bottle c. brown colouring agents are less massive and help to lighten the weight for transport d. the brown colour goes well with the white shelving in the stores e. all of the above 3. What is a catalyst? a. a substance that decreases the rate of a chemical reaction without being permanently consumed b. a substance that increases the rate of a chemical reaction while being permanently consumed c. a substance that decreases the rate of a chemical reaction while being permanently consumed d. a substance that increases the rate of a chemical reaction without being permanently consumed e. none of the above 4. Which catalyst was most likely used to decompose the H2O2 to produce the “smoke” effect? a. b. c. d. e. hemoglobin catalase glutathione peroxidase manganese(IV) oxide none of the above 5. To differentiate between a reactant and a catalyst, the name or the formula of the catalyst used is written: a. b. c. d. e. in brackets before the reactants in brackets after the products above the “reacts to form” arrow “” any of the above are used none of above 6. What is the “smoke” in the “smoke” effect? a. b. c. d. e. carbon soot oxygen gas water vapour condensed water none of the above 7. What is an enzyme? a. b. c. d. e. one of the fat-soluble vitamins one of the water-soluble vitamins a biological catalyst a general term for a product of a decomposition reaction none of the above 8. Which of the following are enzymes that can decompose H2O2? a. b. c. d. e. catalase glutathione peroxidase hemoglobin all of the above none of the above 9. What is meant by “has peroxidase activity”? a. b. c. d. e. able to decompose water into hydrogen and oxygen able to synthesize hydrogen peroxide from water and oxygen able to decompose hydrogen peroxide into water and oxygen able to synthesize water from hydrogen and oxygen none of the above 10.Why do our bodies have enzymes that have peroxidase activity? a. we need to be able to digest hydrogen peroxide if we drink some b. hydrogen peroxide is a natural by-product of metabolism which can release free radicals linked to cancer if it is not dealt with c. our body needs to use them to convert water and oxygen into hydrogen peroxide in case our bodies have too much water d. all of the above e. none of the above 11.What is a free radical? a. b. c. d. e. an entity that has an unpaired e- making it highly reactive any positive or negative ion a neutral, inert entity a compound of Xe and F none of the above The decomposition of hydrogen peroxide is involved in the diagnostic medical test for occult (hidden) blood in feces. The process involves a series of chemical reactions. Questions 12 – 14 relate to this. 12.Reaction 1 A colourless form of tetramethylbenzidine is mixed with __________ to produce hydrogen peroxide. a. b. c. d. e. water acetic acid sodium hydroxide strontium peroxide none of the above 13.Reaction 2: The hydrogen peroxide produced will then decompose to release __________ if __________ is present in the feces. a. b. c. d. e. water, blood oxygen, water blood, water hydrogen, oxygen oxygen, blood 14.Reaction 3: Any oxygen that may have been produced in reaction 2 will react with the tetramethylbenzidine to convert the tetramethylbenzidine to its oxidized form which appears __________. This signals the presence of occult blood. a. b. c. d. e. red orange yellow green blue Hydrogen peroxide is also used to detect the presence of blood at a crime scene. Even if the perpetrator tries to clean up the blood, remnants will remain which can be detected. Questions 15 – 16 relate to this. 15.A chemical reaction that produces light is called: a. b. c. d. e. combustion phosphorescence chemiluminescence fluorescence none of the above 16.If blood is present, then hemoglobin will catalyze the breakdown of hydrogen peroxide to release oxygen. The oxygen will react with __________ releasing characteristic light as evidence. a. b. c. d. e. ethanol acetone methane ethylene glycol luminol 17.Peroxide is a metabolic by-product produced by living things including humans and bacteria. The green iridescence seen on various types of cold cuts is a telltale sign of the presence of bacteria. The green iridescence is the result of: a. b. c. d. e. the reaction between myoglobin and the packaging material the reaction between hemoglobin and myoglobin the reaction between water and hemoglobin the reaction of myoglobin and bacteria-produced peroxide none of the above 18.What did the Germans use the “genie” for during WWII? a. b. c. d. to power the Komet to send out S.O.S. signals to put on chemistry demonstration shows for their soldiers to power the pumps that delivered fuel and oxygen to the combustion chamber of the V2 rocket e. both a. and d. 19.What did Bell Aerosystems in the United States use the “genie” for after WWII? a. b. c. d. e. to make a hit T.V. sitcom to make a personal jet pack to develop a top secret spy plane to power a hot-air balloon none of the above