Chapter 3 Part II: The Electron Name_______________________________ 3.3 1. Waves: Period______Date_____________________ A. Amplitude: _________________ of the wave. The higher the wave the _______________ intensity. B. Wavelength: (λ , lambda) in nanometers (1 x 10-9m) Measured from ______________ to _____________ or from ________________ to _________________. C. Frequency: (ν , nu) The ____________________ of times a wave passes a fixed point. Measured in ____________/___________ (1/s) 1 cycle/second = __________________(Hz) ex) Radio FM 93.3 megahertz (MHz) is ________________________ cycles/sec. D. Speed of Light: (c) = __________________________ or 186,000 miles/sec. The relationship between wavelength and frequency can be shown with the following equations: λ= c or ν = c ν λ This is an ____________________ relationship. If λ ↑ then ν _______ 2. Quantum Theory: A. Planck’s Hypothesis: (Max Planck 1900) 1. An object absorbs or emits ___________________ in a little packet or bundle called a ________________________ (quanta - plural). 2. Energies are __________________________. 3. Equation relating energy (E) to frequency (, nu) h = _________________________________ (6.6262 x 10-34J*sec) E = h This is a __________________ relationship, as ν , E _____ B. Light (Electromagnetic Radiation): 1. A quantum of light is called a _______________________. 2. Light travels through space in ____________________. 3. Light acts like a ____________________ when it interacts with matter. 4. This shows the __________________________________________________________ 1 3. The Atom: A. Atomic Emission Line Spectra: contains only certain colors or _________________________ ( ) of light. 1. Every _______________ has its own ___________ ______________________ (fingerprint). B. Bohr Model of Hydrogen: (1911) 1. Bohr said the energy of an electron was _______________________ (only certain __________________ that represented different amounts of energy.) 2. Bohr labeled each __________________ ____________________ with a __________________________ _________________________ (n). 3. n=1 lowest level or ______________________ _____________________. 4. When electrons _____________________ energy they jump to a higher (__________________________) state. n=2 n=3 n=4 n=5 n=6 n=7 5. Radiation (_________________) is emitted when an _______________________ falls back from a _____________________ level to a _____________________level. C. Werner Heisenberg: (1927) 1. Heisenberg’s Uncertainty Principle: states the ___________________ and _______________________ (speed, direction & mass) of a moving object cannot simultaneously be measured and known exactly. 2. You cannot predict _______________________ locations of particles. 3. He found a problem with the __________________________ - no way to observe or measure the orbit of an ______________________. 4. Quantum Mechanics A. Quantum Mechanical Model of the atom combines previous ideas and treats the electron like a ________________ that has ____________________ _____________________. Impossible to state the exact _______________________ or _________________________ of an electron, but you can state a _______________________ of where the electron is located. 2 B. Electron Density – Where the density of an electron cloud is high – there is a ___________ probability that is where the electron is located. If the electron density is __________ then there is a ___________ probability. C. Atomic Orbitals – region around the ____________ where an ______________ with a given _______________ is likely to be found (not the same as Bohr’s orbits!) 1. Orbitals have characteristic ______________, ______________, & _________________. 2. Orbitals do _______ describe how the ________________ _______________. 3. The drawing of an orbital represents the ______________________________ within which the electron is found _____________ of the time. 4. Sublevels can have 4 different __________________. s-orbital p-orbital d-orbital f-orbital D. Quantum Numbers – Finding an address for the electrons from general to specific. 1. state: Principal Quantum Number (n) or the _________________ ranges from _______ 2. city: Sublevel _____________________ either ______, ______, ______ or _______. 3. street: Orbital The __________________________ in space ex) __________________ 4. house: Spin The ___________ or __________ motion of the electrons. 3 5. The number of Sublevels in an energy level _______________ the Principal Quantum Number. 6. Orbital: There are always an ___________ number of orbitals. s-sublevel has _____ orbital. p-sublevel has _____ orbitals. d-sublevel has _____ orbitals. f-sublevel has _____ orbitals. Orbitals in higher principal levels get ___________________. A max of ________ electrons fit in each orbital. 7. Electron Spin a. Two electrons in each orbital have _______________________ spins. (_______________________ and ____________________________________) b. The opposite spin is written: ______ or ______ c. Pauli Exclusion Principle: 1. Each orbital can only hold _______ electrons. 2. The electrons must have ________________________ spins. s-sublevel = max ________ electrons p-sublevel = max ________ electrons d-sublevel = max ________ electrons f-sublevel = max ________ electrons 3. Incorrect: _____ Incorrect: _____ Correct: _____ d. Hund’s Rule: Electrons will ________________ __________ among the orbitals before they ____________ ______. Incorrect: ____ ____ ____ Correct: ____ ____ ____ 4 E. Electron Configurations: 1. Shows the distribution of electrons among the _________________________. Describes where the electrons are found and what _____________________ they possess. 2. The Aufbau Principle: electrons are added one at a time to the __________________ energy orbital. 5 Ex) electron configuration for Na: _________________________________________ Ex) orbital filling diagram for Na: _________________________________________ 3. Electron Dot Diagrams: Write _________________ for the element. Place dots around the symbol to represent________________ _____ & _____ electrons only. Do NOT include ______ + ______ orbitals in the diagram. Electron Configuration 16 8 O 35 17 Cl Orbital Box Diagram Electron-dot Diagram 127 52 Te 6