Self-ionization of Water & pH Name________________________________ 15.2 Review Period________Date____________________ Matching: On the line at left, write the letter of the best-matching definition. _____ 1. self-ionization a. has H3O+ concentration greater than 1 x 10−7 M _____ 2. pure water b. has H3O+ and OH− concentrations of 1 x 10−7 M _____ 3. Kw - ion product constant c. has a pH greater than 7 _____ 4. pH scale d. describes the reaction: H2O + H2O ↔ H3O+ + OH− _____ 5. acidic solution e. has a pH=7;may contain ions other than H3O+& OH− _____ 6. basic solution f. is equal to 1 x 10−14 at 25ºC _____ 7. neutral solution g. describes the acidity or basicity of a solution Short Answer: Answer the following questions in the space provided. 8. A chemist has a solution of unknown pH. Describe the most accurate way the pH can be determined. _____________________________________________________________________________________ 9. An indicator is a ____________ acid or base that is sensitive to ____________ concentration. Each separate indicator changes ________________ over a different range of __________ values. True or False: If the statement is true write “true.” If it is false, change the underlined word or words to make the statement true. Write your answer on the line provided. ___________________________ 10. In the reaction H2O + H2O ↔ H3O+ + OH-, water ionizes greatly. ___________________________ 11. The ion product constant (Kw) applies to every water solution at a given temperature. ___________________________ 12. An acidic solution contains only H3O+ ions. ___________________________ 13. A solution with a pH of 4 is acidic. ___________________________ 14. Indicators are made from neutral solutions. ___________________________ 15. When the pH of a solution decreases from 9 to 7, the [H3O+] increases by a factor of 2. Problems: Solve each of the problems as directed. Show all your work. 16. Based on the given information, classify the following as neutral, acidic, or basic. a. [H+] = 1 x 10−5 M _______________________________________ b. [OH−] = 1 x 10−5 M _______________________________________ c. [H+] = 1 x 10−7 M _______________________________________ 17. Calculate the pH of a solution where [OH−] = 1 x 10−4 M. 18. Given that a solution has a pH of 3, calculate the [H3O+] and [OH−]. 19. Calculate the [OH−] for an aqueous solution in which [H3O+] is 1 x 10−10 M. Is the solution acidic, basic, or neutral? What is the pOH of the solution? 20. Determine the [H3O+] for aqueous solutions that have the following pH values. a. 3 b. 6 c. 10 21. What is the [OH−] for solutions that have the following pH values? a. 5 b. 9 c. 13 22. The concentration of H3O+ ions in a solution is 3.8 x 10-9 M. What is the pH of the solution? Is the solution acidic, basic or neutral? What is the concentration of OH- ions? 23. The concentration of OH- ions in a solution is 1.6 x 10-6 M. What is the pH of the solution? Is the solution acidic, basic or neutral? What is the concentration of H3O+ ions? 22. [OH-] = 2.6 x 10-6M ; pH=8.42 Base 23. [H3O+]=6.0x10-9M; pH=8.22 Base