Gases Notes Name______________________________________ Period________Date__________________________ 12.1 A. Physical Properties: 1. Gases have _____________. The density is much smaller than ________________ or ________________, but they have mass. 2. Gases can be _________________________. Very easy to reduce the _____________ of a gas. Example: __________________________________________________________ 3. Gases completely _____________ their containers. 4. Gases can _______________ through each other rapidly. Example the _________________________ of food smells and perfume. 5. Gases exert ______________________. 6. The _____________________ of a gas depends upon _________________________. High Temp. = _____________ pressure, low temp. = ______________ pressure. B. Kinectic - Molecular Theory: 1. Gases are _______________ particles that have _____________. These particles are usually molecules, except for the ______________________________. 2. The particles in gases are separated by relatively __________________ distances. 3. The particles in gases are in constant rapid _________________ (random). 4. Gases exert pressure because their particles frequently ______________________ with the walls of their ________________________ and each other. 5. Collisions of gas particles are perfectly _______________________. 6. Temperature of a gas is simply a measure of the _____________________ energy of the gas particles. High temp. = ___________ K.E., Low temp. = ___________ K. E. 7. Gas particles exert no _________________ on one another. Attractive forces are so ________________ between particles they are assumed to be _______________. 1 C. Measuring Gases: 1. The following 4 variables will be used to do gas calculations: ______ - amount of a gas, it is measured in _____________ ______ - volume of a gas, it is measured in ______________________________ “STP” = Standard Temperature & Pressure: ______- Standard Temperature: _________ oC = _________K Taken in oC converted to Kelvin (K) Ex #1) 22°C = ________ K -27.3°C = ________ K T(K) = 100.°C = ________ K -273°C = _______ K ______- Standard Pressure: can be measured using the following units: (sea level pressure) ________________ atm (atmospheres) __________mm Hg ________________ Pa (Pascals) __________torr ________________ kPa (kilopascals) __________lb/in2 (psi) Ex #2) Convert 1.026 atm to kPa: Ex #3) Convert 98,500 Pa to mm Hg: 2. Atmospheric pressure is the pressure exerted by the ________________ in the atmosphere. This pressure varies with altitude and ______________ ______________ ________________ 3. Atmospheric pressure is measured with a _______________________. This is a glass tube sealed at one end and filled with Hg. 2 12.2 The Gas Laws A. Boyle’s Law: Pressure - Volume Relationship. The pressure & volume of a sample of gas at constant ______________________ are ____________________ proportional to each other. Ex #4) A gas has a volume of 300. mL under a pressure of 740. mm of mercury. If the temperature remains constant, calculate the volume when under a pressure of 750. mm. 3 B. Charles’ Law: Temperature - Volume Relationship. At constant _________________ the volume of a fixed amount of gas is ___________________ proportional to its absolute ________________________. * Temperatures must be in Kelvin!! K = oC + _______ Ex #5) What is the Celsius temperature of 68.20 mL of methane, if it occupies a volume of 0.02200 L at 50.0 oC? C. Avogadro’s Law: Amount - Volume Relationship. Equal ___________________ of gases at the same _______________________ and _________________________ contain an ________________ number of particles. 1 mole gas = _____________ = 6.02 x 1023 particles at STP (273 K & 1 atm) 4 He O2 Rn Therefore because of Avogadro’s Law if these three gases are at the same temperature and pressure, they must take up the same ______________________. D. Dalton’s Law of Partial Pressures: The sum of the partial ______________________ of all the components in a gas mixture is equal to the total ______________________ of the gas mixture. Ex #6) A flask contains a mixture of oxygen, argon, and carbon dioxide with partial pressures of 745 torr, 0.278 atm, and 391 torr respectively. What is the total pressure in the flask? Ex #7) The total pressure of a mixture of helium and neon is 498 mm Hg. If helium is 20.0 % of the mixture, what is the partial pressure of helium? 5 E. The Combined Gas Law: “Choyles” This law can be used to determine how changing two variables at a time affects a _________________ variable. Ex #8) A gas occupies 72.0 mL at 25 oC and 198 kPa. Convert these to standard conditions. What is the new volume? P1 = V1 = T1 = P2 = V2 = T2= 12.3 A.The Ideal Gas Law Although no “ideal gas” exists, this law can be used to explain the __________________ of _______________ gases under ordinary conditions. P = __________________________ V = __________________________ n = __________________________ R = __________________________ universal gas constant T = __________________________ 6 B. Ideal Gas Law & The Kinetic – Molecular Theory: 1. Under normal conditions (temperature & pressure) gases behave ____________________. PV = nRT n ____ P ____ (more gas, _________________________) T ____ P ____ (moves faster, ______________________) V ____ P ____ (smaller volume, ____________________) 2. Gases at ___________________________ and ____________________________ do NOT behave ideally. As you decrease the volume of a gas, the __________________ of the particles themselves __________________ ______________________. The Kinectic-Molecular Theory & Ideal Gas Law assume that gas particles have _____ _______________ of their own. 3. Second, the __________________ ________________ which are very ____________ when the particles are moving fast, become larger as they _____________ _____________. Ex #9) How many grams of carbon dioxide occupy a volume of 36.9 mL at 158 kPa and 72 °C? 7 C. Lifting Power of Gases: 1. Uses a gas “____________________________” than air (smaller ________________ mass.) Ex) The Hindenburg used ______________________________________ Ex) Today’s blimps use ______________________________________ 2. Hot Air balloons heat air to lower its ________________________. 3. Effusion is the movement of gas atoms or molecules through a hole so ______________ they move one particle at a time. Smaller particles effuse ____________________ than larger particles. Ex) → → 8