• DEPARTMENT OF CHEMISTRY ChemNews www.chem.umn.edu Spring 2005 GREETINGS FROM THE CHAIR Wayne L. Gladfelter Faculty . . . . . . . . 2-3 Alumni . . . . . . . . 4-6 RSEC . . . . . . . . . . . 7 Teaching . . . . . . . . 8 Research . . . . . . . . 9 Centennial Celebration Photo Essay . . . 10-11 Awards . . . . . . .12-15 Degrees . . . . . . 16-17 Donors . . . . . . 17-19 Dear Alumni and Friends: As always I hope this letter finds you well. Our letter is arriving later than it has in the past four years, and our plan is to continue sending it out at the end of the spring semester. This allows us to undertake the task of creating the letter at a time of the year that is a little less hectic. The big event during 2004 was the centennial celebration held on October 9. Although students were taking chemistry courses and graduating as majors before 1904, it was in this year that the School of Chemistry was established and George B. Frankforter was appointed as its first Dean. The presentation, which highlighted selected parts of our history, can be downloaded from our departmental website at www.chem.umn.edu/alumni/HistoryWeb/History. html. Following the presentation about 250 participants joined us for dinner and a party at the Campus Club in Coffman Memorial Union. We include a few pictures of the event elsewhere in this newsletter. Over the past two years we have focused a great deal on the Kolthoff Hall renovation. The state bonding bill, which includes two-thirds of the funds for the 26.1 million dollar project, was signed into law by Governor Pawlenty on April 11, 2005. One of the major components of the project will involve installing new fume hoods throughout the building and redoing the entire heating, ventilation, and air conditioning system. We will also redress many of the fire and safety code issues that have changed since its construction in the late 1960s. Perhaps the most exciting component of the project is the renovation of the space (approx. 10,000 sq. ft.) that was “temporarily” (since 1970) used to teach the general biology labs. This provides us with an important opportunity to reorganize space and relieve some of the congestion around the department. Planning the entire project will require another nine to twelve months, so construction will begin in mid-2006 and be completed in 2008. We thank Professor Ron Gentry, who is retiring after 35 years, for his outstanding scholar- UNIVERSITY OF MINNESOTA CHEMISTRY Wayne L. Gladfelter ship and service to the department. This included serving as Chair from 1989 to 1999. At the same time we are excited to welcome Christy L. Haynes as the newest faculty member. She is planning to arrive this summer and initiate a research program in bioanalytical chemistry. Christy received the 2005 Nobel Laureate Signature Award from the ACS at the San Diego meeting. This was an exciting event because in addition to Christyʼs award, Jeannette Brown (MS ʼ58) received the American Chemical Society Award for Encouraging Disadvantaged Students into Careers in the Chemical Sciences. Jeannette was also awarded an Outstanding Achievement Award from the University of Minnesota in 2005. Also on stage at San Diego were Harvard Professor Eric Heller (BS ʼ68) who received the ACS Award in Theoretical Chemistry and Dr. Joe Porwoll (PhD ʼ82), President of Sigma Aldrich, who presented the Sigma Aldrich Award in Synthetic Organic Chemistry. This was also a great year for our faculty, who received many awards summarized elsewhere in this letter. After nine years of service, Dean H. Ted Davis returned to full time teaching and research in the Department of Chemical Engineering and Materials Science. Our new Dean is Steven L. Crouch, who has been a member of the Department of Civil Engineering for 35 years and who has served as the Associate Dean of Finance and Planning since 1997. One of Dean Crouchʼs early tasks was to appoint the new Chair of Chemistry. We are very fortunate that Jeff Roberts has agreed to accept this assignment. This means, of course, that I am completing my term as Chair. It has been an honor to serve in this office for these past six years, and I am grateful to many staff, faculty, and students for making this time productive. One of the joys of the job has been developing a closer relationship with many of you. It has helped me to recognize that our impact on the field of chemistry and, more broadly, on society is amplified many times over by our students. I look forward to continue meeting you at ACS or other meetings in the future. ALUMNI & FRIENDS BREAKFAST American Chemical Society Meeting & Exposition August 28 - September 1, 2005, Washington, DC USA The Alumni & Friends Breakfast Meeting is scheduled for 7:30 on Tuesday August 30 at the 228th ACS Meeting in Washington, D.C. Please be sure to register for event #46 when you fill out the ACS registration form. Page 1 Faculty Chemistry Promotions Dr. Christy Haynes Joins Department 2005 Darrin York: from tenure-track Assistant Professor to Associate Professor with tenure. Christy L. Haynes will be joining the Chemistry Department faculty this fall as an Assistant Professor. While she was actually hired more than two years ago, she has spent the interim time doing postdoctoral research with Professor R. Mark Wightman at the University of North Carolina, Chapel Hill. Christy grew up in Arizona and moved to Minnesota in 1995 to attend Macalester College in St. Paul. 2003-2004 While at Macalester, she performed research in ProEdgar Arriaga: from fessor Rebecca Hoyeʼs laboratory, working toward the total synthesis of elenic tenure-track Assistant acid. She also worked in the polymer formulation laboratory at Imation CorporaProfessor to Associate tion throughout her undergraduate years under the direction of Dr. Sharon Simpson. Professor with tenure. Upon finishing her B.A. in Chemistry (with minors in mathematics and Spanish) in 1998, Christy decided to attend graduate school at Northwestern University, where she 2003-2004 thought she would study inorganic synthesis and x-ray crystallography. Instead, she joined Craig Forsyth: from the research group of Professor Richard P. Van Duyne, a physical/analytical chemist, and Associate Professor starting working on projects relating to nanostructure fabrication and laser spectroscopy. to full Professor with Christy had a very successful doctoral career, publishing 28 peer-reviewed manutenure. scripts, writing several funded research grants, and winning numerous awards. In fact, she just accepted the Nobel Laureate Signature Award for Graduate Education at the spring 2005 ACS meeting (see Faculty Awards, p. 12) in San Diego. awards the Horace T. Morse/UniverThis award recognizes the outstanding sity of Minnesota Alumni Award for achievements of one graduate student/ Outstanding Contributions to Underpreceptor pair in Chemistry each year. graduate Education to Professor Ken Leopold at the 2005 graduation celebraChristy will be teaching Gention (see page 12). eral Chemistry II for the department Dr. Crouch was named dean of this fall. Although she has never been the Institute of Technology in January in a class with more than 40 students, 2005. He grew up in Sleepy Eye, Minshe is excited to interact with the nesota, graduating from its public high 350 University of Minnesota underschool in 1961. He received bachelor’s, graduates in her course. She plans master’s, and doctoral degrees in mineral to bring nanoscience, green chemisengineering from the University of Minnetry, and some biological chemistry sota and began his career with the Mining Research Laboratory of the Chamber of into her lectures and class activities. Mines of South Africa in 1968. In 1970 he In addition she will be setjoined the University of Minnesota faculty as an assistant professor in what is now the Department of Civil ting up a research laboratory, with Engineering. From 1987 to 1997 he served as head of that department and in 1997 became the college’s the help of her postdoc, Dr. Adam D. associate dean for finance and planning. As dean, Crouch hopes to strengthen the college’s interdisciplinMcFarland, to perform state-of-the-art ary initiatives in digital technology and nanotechnology and to expand its involvement in the University’s laser spectroscopy and electrochemisInitiative for Renewable Energy and the Environment. try measurements. Christy is highly collaborative and enjoys working at the interfaces of physical, analytical, biological, and Spring 2005 materials chemistry. She plans to apply surface-enhanced Raman scattering to study sediment pollution and remediation. She also intends to correlate Raman scattering measured Newsletter Committee inside living neuronal cells with electrochemically measured neurotransmitter release to Wayne Gladfelter, David Hoffman, Kathy Ross Production: Deborah Schoenholz understand brain-based disorders. Her diverse research plans also include a new route to Photos: Vinothini Ambrose, Chris Lundby, synthesis size and shape tunable noble metal nanoparticles for plasmonics applications. Wayne Gladfelter, Eric Schulz Christy will arrive in Minnesota during the summer of 2005 with her spouse, Charles, and their two dachshunds. Charles has just completed his M.B.A. and hopes This publication is available in alternative formats upon request. Please call 612-626-9405. The to find a job in real estate development focusing on sustainable building and commuUniversity of Minnesota is an equal opportunity nity enhancement. When not in the laboratory or classroom, they are likely to be at the educator and employer. theater or the symphony or visiting Charlesʼs large extended family in the Twin Cities. Newly Appointed Institute of Technology Dean Steven L. Crouch ChemNews Printed on recycled paper. Page 2 Faculty Jeff Roberts To Be New Chair of Chemistry Department Distinguished McNight University Professor Jeffrey Roberts has accepted a five-year appointment as Chair of the University of Minnesota Chemistry Department effective September 1, 2005. He will be replacing Wayne Gladfelter. Professor Roberts has been with the University since 1990, fresh from postdoctoral studies at Stanford. He is looking forward to his tenure as Chair and believes that the University of Minnesota's new Strategic Positioning Initiative will offer many opportunities for the Chemistry Department to prosper. Jeff's interest in teaching has led him to work diligently toward creating a quality educational experience for graduate students and undergraduate students alike. He thinks that "the most satisfying part of the job is watching the light come on when they (students) begin to understand . . . it is what makes the job worthwhile." He served as Director of Graduate Studies for the Chemistry Department from 2000 to 2003 and since then has become Graduate Faculty for the Department of Mechanical Engineering. In addition, he is the Director of The University of Minnesota Twin Cities Research Site for Educators in Chemistry (see page 7), a National Science Foundation– W. Ronald Gentry funded initiative designed to foster new and meaningful scientific interactions Ron Gentry was born on July 7, 1942 in Texarkana, Texas. He received his Bachelor between a large, Ph.D.–granting chemistry of Science in chemistry, summa cum laude, in 1964 from the University of Redlands in department and the departments of 30 to California. He did his graduate work in physical chemistry at the University of California, 35 primarily undergraduate institutions (www.chem.umn.edu/rsec/). Berkeley, and was granted the Ph.D. in 1967. After postdoctoral studies at Massachusetts Jeff is married to Deborah Jaffey, Institute of Technology, he joined the faculty of the Department of Chemistry, University Ph.D. and chemist for the Imation of Minnesota, in 1970, and served his entire academic career at Minnesota. He was procompany in Oakdale, Minnesota. He moted to Associate Professor in 1975, to full Professor in 1979, and served as Chair of the and Deborah have two children, Anna (9) Department of Chemistry from 1989 to 1999. His professional awards include an Alfred P. and Eleanor (4). Among his many awards Sloan Research Fellowship, 1975-77, and a Yamada Science Foundation Fellowship at Keio and honors, he received the Camille and University and University of Tokyo, 1984. He was elected Fellow of the American PhysiHenry Dreyfus New Faculty Award for cal Society in 1987. His numerous professional activities include service on the editorial 1990-1991 and has been a Fellow of the board of the Journal of Chemical Physics, service as a Journal of the American Chemical Alfred P. Sloan Foundation (1996-1998). Society associate editor, and chairing or co-organizing national and international conferences He received his B.S. in Chemistry in including the Conference on the Dynamics of Molecular Collisions at Gull Lake, Minnesota. 1982 from UC Berkeley and his Ph.D. in Gentryʼs research interests are in physical chemistry and chemical physics: molecular Chemistry from Harvard University in 1988. energy transfer, state-to-state reaction dynamics, laser chemistry and spectroscopy, and dynamics of atomic and molecular collisions at ultralow kinetic energies. In addition to mentoring many undergraduates, he supervised the studies of twelve Ph.D. students and one Master Masterʼs student. Professor Gentry is generally considered, along with Nobel Laureate Yuan T. Lee, one of the two most outstanding molecular beam experimentalists in the world. His merged beam and pulsed beam apparati were widely influential, and his currentloop pulsed value design and electroformed skimmer revolutionalized the whole field. His discovery of the extremely weakly bound helium dimer with an average internuclear distance greater than 50 Å is considered one of the most dramatic tour de force measurements ever accomplished. Most of his experimental work was the result of a fruitful thirty-year thirtycollaboration with Professor Clayton F. Giese of the Physics Department. Gentry has moved to Port Townsend, Washington, and will spend his retirement years on his photography hobby, on his love of boating, and continuing to work on his latest research interest, which involves the use of ultraminiature mass spectrometers for environmental monitoring of volcanic behavior in Hawaii and Costa Rica. We wish Ron and his wife Sharron many happy and productive years. Retirement Page 3 Alumni Alumni in the Press 2 2005 Founders Survey Finds IT Alumni Are Sparkplugs of Minnesota Business We are proud of the accomplishments of our alumni and want to share their news. PDFs of these articles may be accessed at www. chem@umn.edu:Alumni Pat Gruber (Ph.D. ‘88, Gray): MINNESOTA June 2003 The creation of new companies is a vital component of Minnesota Minnesota's economic growth and future prosperity. During the early 1990s the Institute of Technology (IT) set out to determine how many active companies had been founded by our alumni. The goal of this project was to show that investment in IT, whether through state funding or private contributions, yields a tremendous return. contributions The findings were impressive: more than 1,000 companies in business at the time (in some cases under a different name or ownership) could trace their roots to IT. Published in 1993 as IT 1000, the survey found that these companies collectively employed more than 150,000 people and generated annual sales in excess of $20.3 billion. John Talley (Ph.D. ‘79, Gassman): FORBES June 23, 2003 Matt Wehling (BChem ‘87): St. Paul PIONEER PRESS August 4, 2003 Dan Getman (Ph.D. ‘82, Gassman): STL TODAY.com St. Louis Post Dispatch August 6, 2003 Albert Matlack (Ph.D. ‘50, Koelsch): The News Journal, Wilmington, Delaware John Dolan (BChem ‘97) - The Business Journal, Minneapolis/St. Paul Create a Graduate Fellowship in Chemistry and Double the Impact of your Gift 2005 IT Alumni Survey The Institute of Technology again surveyed its alumni in 2004 in an attempt to clearly define the economic impact that IT alumni have had on the state of Minnesota, to build bridges between industry and IT, and to allow us to learn from Imagine that with a phone our alumni how we can improve the career development of our students. call, an email, or the stroke Since the first report was published, the corporate landscape has of a pen you had the power changed dramatically. The rise of the Internet and rapid advancements in to double all the good that a information technology fueled an explosion of entrepreneurial activity in fellowship does: change a the late 1990s. And the dawn of the 21st century heralded a wave of new life, spark new ideas, generventures at the intersection of biology, information technology, and engineerate breakthrough technoloing. Clearly the time was ripe to take another look at our alumni and their gies, or underwrite creative work in a discipline you love. accomplishments. The 21st Century Graduate Last fall, with generous support from the Mr. and Mrs. George W. Fellowship Endowment Taylor Foundation, IT surveyed nearly 48,000 alumni and received more Amber Runge, IT Graduate gives you the power to create than 15,000 responses. Broader in scope and more detailed in its analysis than a meaningful legacy during your lifetime, and is the 1990s poll, the 2004 survey confirmed that the entrepreneurial spirit is thriving the perfect opportunity to help nurture promising among IT alumni: graduate students in Chemistry. Established in 2000, this endowment is •3,024 respondents–a fifth of the total–reported founding one or more compaa result of the University licensing agreement nies. for the AIDS drug Ziagen with Glaxo Wellcome •Approximately 4,150 of the companies created by IT graduates remain acPLC, a pharmaceutical company. The fund was tive today. Many of these companies are mature: forty percent have been in created with royalties generated by worldwide sales of Ziagen, which was developed at business more than ten years; another 25 •Approximately 1,000 Chemistry the University by a research team led by percent have been in business between five alumni completed the 2004 survey, pharmacy professor Robert Vince. Gifts of and ten years; a third have been in business with 57 percent responding that they $25,000 or more that are designated to enless than five years. had attended the Institute of Techdow graduate fellowships may be eligible •Nearly two-thirds of the active companies nology for graduate school. for matching through the fund. founded by IT alumni are located in Minne•Over 100 Chemistry alumni identiMaybe youʼve been thinking about maksota: 53.1 percent in the Twin Cities metro fied themselves as company founding a gift to Chemistry for a while now, but area and 8.6 percent in Greater Minnesota. youʼve been waiting for the right moment ers, representing graduating classes •These Minnesota companies (roughly to come along. I hope you will conclude ranging from 1935 to 2001. 2,600) employ more than 175,000 people that now is the perfect time to create a •Chemistry Founders have estaband generate approximately $46 billion in legacy by investing in human potential-the lished more than 140 companies, best bargain youʼll ever find. For more annual revenue. with 67 percent of the companies information, contact David Hoffman, de•The active companies located outside being founded in the last ten years. velopment officer for the Chemistry DepartMinnesota (about 1,500) employ nearly •The companies represent a variment at 612-625-6035 or 800-587-3884, or 376,000 people and generate approximately ety of economic sectors, with the dhoffman@it.umn.edu. $44 billion in annual revenue. majority in consulting services and manufacturing. Page 4 Alumni Where Are You and What Are You Doing? Dr. Conrad Bergo (Ph.D. 1972) is a professor of Chemistry, recently returned from a lecture tour in Kentucky and North Carolina. Bergo was the invited speaker to the chemistry departments of Eastern Kentucky University and University of North Carolina-Asheville. He was also the speaker at a dinner meeting of the Sigma Xi Chapter in Asheville. Bergo reported on results of research carried out at East Stroudsburg University and on trips to gather information in Thailand. He spoke about the chemistry of processes used in manufacturing crafts and the chemistry of foods and spices that give the foods in Thailand its distinct character. Jeffrey J. Cernohous (Ph.D. 1997–Hoye) spent five years in 3Mʼs Adhesive Technologies Center working on applications for materials that have a controlled polymer architecture. He then moved to 3Mʼs Dyneon organization in late 2002 as their Development Group Leader. After being six-sigmatized to death, Cernohous left 3M in October 2003 to start his own specialty materials (polymers) company, Interfacial Solutions. He is currently in the process Alumni Jeanette Brown Receives ACS Award for Encouraging Disadvantaged Students into Careers in the Chemical Sciences Sponsored ponsored by the Camille and Henry Dreyfus Foundation Chemistry’s 2005 Outstanding Achievement Award recipient is Jeannette E. Brown (MS 1958) from Hillsborough, NJ. Ms. Brown earned the B.A. degree in chemistry from Hunter College in 1956 and the M.S. degree from the University of Minnesota in 1958. She was the first African American woman to receive a degree from our graduate program. continued on page 7 of joining a new business incubator at the University of Wisconsin-Stout and has been named an adjunct professor there. Cernohaus is enjoying the life of an entrepreneur and says he will continue to do so as long as he can. Lt. Col. Mark W. Dahl (B.S. 1985) has not had much contact with U of MN over the last 19 years. He became a Marine officer five days after receiving confirmation of his 1985 graduation and was quickly swept off to Quantico, VA, with his new bride of three days, to become a 2nd Lieutenant. Dahl went on to flight school and has spent 18 years flying F/A-18 Hornet fighter aircraft. He now works as a Legislative Affairs Officer as a Lieutenant Colonel at the Peter Keim Trumper, Pentagon. Dahl has taken 30+ credits toward an M.S. age 48, died of cancer at his home in Brunswick, Maine, on July 7, 2004, following a valiant struggle in Biology at the Institute to overcome the disease. for Creation Research in He was born in Philadelphia and grew up in Vermont. He attended the Grammar School and Santee, CA, and he has the Putney School and spent some of his childhood in the Dominican Republic, Bogota, Columbia, completed multiple military and on a Navaho Reservation in Shiprock, New Mexico. He worked at Rescue, Inc., and completed schools over the years. His his undergraduate education at St. Olafʼs College in Minnesota. He earned his doctoral degree in goal is to become a teacher Chemistry at the University of Minnesota and held a postdoctoral fellowship at the University of after military retirement, Pennsylvania. Peter taught organic chemistry at Bowdoin College and the University of Southern probably junior or senior Maine, co-authored several editions of the textbooks Microscale Organic Laboratory and Microscale high school in math or sciTechniques for the Organic Laboratory, served as editor of Chemical Educator and edited numerous ence. Dahl's father still lives medical textbooks. He was a student at the University of Maine School of Law and at the time of his in Minnetonka, and his sister death was one paper short of his law degree. is finishing her fourth year at He was predeceased by his mother, Nance Peiper Trumper and is survived by his wife, Susan U of MN, going into medeA. Kaplan of Brunswick, Maine, brother Jonathan Trumper of Maplewood, New Jersey, sister Rachel Debasitis of Woodstock, Vermont, father John Trumper of Brattleboro, Vermont, aunt and uncle Elcine. The Dahl's have four lin and Donald Spitzer of Haverford, Pennsylvania, and nephews Max and Willy Trumper and Jesse children: Devin 13, Connor Snyder. 11, Tyler 9, and Lauren 7. Peter enjoyed reading a broad range of literature, listening to music, autocross and Formula They have been happily One racing, and cooking extraordinary dinners for his friends and family. He was passionate about married for 19 years this education and proud of his students, particularly those who pursued careers in research, education, June. Semper Fidelis. or medicine. A man with a keen intellect and a lovely dry wit, Peter will be sorely missed by those who loved him and whose lives he touched. The family requests that contributions in Peterʼs name continued on page 6 be made to the Palliative and Supportive Care Program at MidCoast Hospital in Brunswick, Maine, where an educational fund will be established to recognize and further the education of nurses and certified nursing assistants. Memorial Page 5 Alumni continued from page 5 Andrew DeMaster (B.S. 1997) enrolled in a biotechnology doctoral program at the University of Wisconsin after graduation from the University of Minnesota. He exited early with an M.S. and went on to law school. For the past year, he has been working as an attorney for a Minneapolis law firm (Kinney & Lange) specializing in patent, trademark, and copyright law. Jeff Bankers (Ph.D 2004–Miller) is currently Senior Scientist in Home Care Division at Dial Corporation in Scottsdale, AZ. David Flannigan (B.S. 2001) is currently in his fourth year of graduate school at the University of Illinois at Urbana/Champaign conducting spectroscopic studies of sonoluminescence in Prof. Ken Suslickʼs lab. James P. Schlichting (B.S. 1975) is a Quality Project Manager with Abbott Labs. Since finishing his BS in Chemistry at Minnesota in 1975 he has completed an MS in Chemical Engineering (U of Wisconsin) and a MBA at Northern Illinois University. He has held manufacturing and development engineering positions at IBM (semiconductor processing and magnetic media) and positions in process development and pilot plant management at Valspar and the Dexter Corporation. Michael J. Collins (Ph.D. 1971– Henneike/Britton) received his degree in Inorganic Chemistry working with Dr. H. Fred Henneike, who left for Georgia State University in Atlanta before he finished. Doyle Britton became his official mentor after Henneike left, and Collins attests to the great job Britton did in keeping his student on track to finish. He also organized and ran very engaging informal brown bag seminars on the current literature and current work in the labs. Collins has been Professor of Chemistry at Viterbo University in La Crosse WI since 1976 and is currently completing a term as Chair of the Natural Science Division and Chemistry Department chair. He will be spending the next academic year on sabbatical at Minnesota in the RSEC program, working with Dr. Larry Que, tentatively to explore the thermodynamics of ligand bindPage 6 Promise of Tomorrow – The Wayland E. Noland Scholarships Professor Wayland Noland has established two new undergraduate scholarships that will benefit chemistry students. “I established the funds, because I think the students at Minnesota are first rate and deserve the support, support,” said Noland. The first two Noland Scholars will be selected in the coming year. The scholarships will be matched under a new program aimed at increasing by 50 percent the number of students who receive scholarships. ““I want to make sure that all students with the desire and ability to succeed at the U have the opportunity to do so, so,” said University President Robert Bruininks, who announced the drive last fall. Approximately 4,500 U of MN students currently receive privately funded scholarships. But Minnesota trails other Big Ten institutions in the number and size of scholarships it can offer to new students. Professor Noland has been a member of the University of Minnesota Chemistry faculty since 1952. During his long career he has built his reputation as an accomplished researcher, a dedicated teacher, and a generous supporter of the University. These new scholarships, in addition to his many other contributions, are a significant statement about his commitment to our students, the University, the Institute of Technology, and the Chemistry department. For more information about the University of Minnesota Scholarship Matching program, call 612-625-6035 or 800-587-3884, or visit www.giving.umn. ing and the redox properties of catecholase model complexes. operator/laboratory technician at Midwest Finishing Inc. in Brooklyn Park. Successes over the years have included his first sabbatical with Alan Hooper, Professor of Biochemistry, Molecular Biology, and Biophysics in CBS. Subsequent work with him and his group resulted in several publications on the electrochemistry of hydroxylamineoxidoreductase and other heme proteins. Kari Hendlin (BChem 1996) now also has a degree in Biomedical Engineering, and she is working at the VA Medical Center and the University of Minnesota doing clinical research and device testing in urology. Her daughter, Kenzie, is 10 years old and keeping her very busy. Collins was named the CASE Wisconsin Professor of the Year in 1988 and was awarded the bronze medal in the CASE National Professor of the Year Program that year. Bob Buntrock (BChem 1962–Noland) and wife Gloria have moved to Orono, Maine, primarily to be near their daughterʼs family, including two small grandsons. He is getting well acquainted with the staff and faculty at the University of Maine Chemistry Deptartment and Library. He has made a presentation on chemistry careers to a freshman chem class (with more planned). Buntrock will be assisting in the Chemistry Olympiad exam for the Maine Section ACS. Buntrock Associates is still in business, with a few remaining information service customers. Viterbo has sent several of its chemistry graduates to the U of M for graduate study in chemistry over the years, most recently Adam Schellinger. We also presently have a chemistry grad in St. Paul studying plant biochemistry. Karl Ochs II is currently living in St. Paul with his wife, Diane. He works as a waste treatment RSEC Chemistry Research at Undergraduate Institutions: RSEC HELPS MAKE IT POSSIBLE The Research Site for Educators in Chemistry (RSEC) is in its fourth year of operation. RSEC, which is supported by a generous grant from the National Science Foundation, is directed by Jeff Roberts with the expert assistance of Vickie Woodcock. Professors and their students from undergraduate institutions all over the Midwest (and beyond) are able to forge new collaborations with Minnesota faculty members and to build their own sustainable research programs. The last year saw a significant increase in the number of women participating in the program. Rita Majerle (Hamline University) used RSEC funding to start a collaboration with George Barany, in which she learned the state of the art in solidphase peptide synthesis. Shoshanna Coon (University of Northern Iowa) launched a new research project on the production and characterization of organic monolayers on silicon. Dr. Coon, a colleague of Xiaoyang Zhu, writes, “The RSEC program has been incredibly valuable to me already. Just being able to see and copy existing experimental techniques, rather than having to reinvent the wheel, has made it feasible for me to start this new research project and write a proposal to obtain funding for it.” Thirty-one students, over half of them women, have participated in RSECsponsored research projects. A number of them have graduated and gone on to graduate or professional programs or into industry; some are still undergraduates. Most have presented posters at national meetings, with their travel underwritten by RSEC travel grants. Jeanette Brown continued from page 5 She carried out her graduate thesis research in the area of synthetic organic chemistry in the laboratory of Professor Frederic Koelsch. Ms. Brown’s independent research career began at CIBA Pharmaceutical Company (now Novartis) where she worked as a Chemist for eleven years. She then moved to Merck and Co. where she was a Research Chemist for 26 years until her retirement in 1995. From 1995 until 2002 Ms. Brown was affiliated with the New Jersey Insitute of Technology, Newark, N.J. She is presently an Educational Consultant and was the 2004 Société Fellow of the Chemical Heritage Foundation. Throughout her research career Ms. Brown has been an advocate for science education and a mentor and role model for underrepresented students. She has participated in countless scientific outreach programs and career days for students at all educational levels from elementary levels through college. Ms Brown has served the American Chemical Society in many capacities. Her leadership as Project SEED Committee Chairperson from 1986 - 1988 was critical for the program’s growth and current success. Project SEED continues today, and in Make Your Dona2001 the program received the Presidential Award for Excellence in tion to the Chemistry Science, Mathematics and Engineering Mentoring. Department's Ms. Brown began her association with the New Jersey InstiSpecial Projects tute of Technology prior to her retirement from Merck. While “on loan” from Merck (1993 - 1995), she was a Visiting Professor of Chemistry Fund by enclosing your gift in and helped craft the New Jersey Institute of Technology Alliance for the envelope provided in Minority Participation in Science Grant that was successfully funded the back of this newsletter. by NSF. She was also a Science Advisor to the New Jersey Institute Help support our faculty of Technology Urban Elementary Outreach Program and to the New and students. continued on page 20 Teaching Assistants Meet Amanda Nienow RSEC Teaching Intern During the fall of 2004, Viterbo University (La Crosse, Wisconsin) and RSEC co-sponsored Amanda Nienow as a teaching intern with Kyle Backstrand, a Viterbo professor. Amanda, a U of MN chemistry doctoral student since 2001, had the opportunity to teach an undergraduate chemistry course in Viterboʼs Division of Natural Sciences. Amanda wrote the syllabus and exams, set the daily agenda, held office hours and had to pass muster with no fewer than six faculty observers. She also had the opportunity to attend the Midwest Area Chemistry Teachers at Liberal Arts Colleges annual meeting in October. Amanda, a native Minnesotan and alum of St. Maryʼs University in Winona, plans to graduate in the spring of 2006. Sheʼs looking for a post-doctoral position in enviromental physical chemistry. Amanda hopes to secure a faculty position at a small liberal arts college in the Midwest. Look out for her in the future! Page Johnson Welcomes Students to Chemistry Department Labs Chemistry graduate student Page Johnson (Advisor Professor Mark Distefano) has been a Teaching Assistant for Dr. Wissinger in the organic laboratory course 2311 for the past three years and has decided to pursue a career in teaching. She has a B.S. in Chemistry and B.Ch.E. from the U of M in 2001. Send us your update to either She will be completing the initial www.chem.umn.edu/alumni/contact.html or alumni@chem.umn.edu licensure program in secondary Let us know what you think. science education and her masters We want this publication to reflect your interests. Send comments to: in chemistry this summer. After ChemNews Department of Chemistry that, Page has been hired to teach 207 Pleasant Street S.E. high school Chemistry in Edina Minneapolis, MN 55455 in the fall. or chemnews@chem.umn.edu Attention Alumni Page 7 Teaching & Research Organic Laboratory Course a Little Greener The general organic laboratory course, 2311, is required for nearly a thousand students each year at the University of Minnesota. The two-semester-in-one course meets for lecture once a week and then for two four-hour experimental sections where students learn the techniques required for isolation, purification, separation, and identification of organic compounds. Approximately twenty experiments are performed during the semester and include the synthesis of banana oil, recycling of a plastic beverage bottle, and hydrogenation of the essential oil isolated from cloves. In an effort to keep the curriculum of the laboratory course current, Dr. Jane Wissinger, Director of the Organic Laboratories, has been investigating the use of “greener” experiments. That is, experiments that consider the impact on the environment of Figure 1: Solvent-Free Syntheses of Chalcones starting materials used, energy consumed, by-products formed, and waste produced. Many challenges exist en route to accomplishing this goal including maintaining a connection between the reactions and theory taught in the lecture portions of the organic course and considering the cost and equipment involved in running a large institutionʼs laboratory. Chemistry graduate student Page Johnson has been a Teaching Assistant for Dr. Wissinger in the organic laboratory course 2311 for the past three years and has decided to pursue a career in teaching. As part of her masterʼs thesis, Page decided to investigate recently published green organic chemistry experiments and their suitability for use in the 2311 curriculum. She successfully tested the most promising experiment with her own section of 2311 students spring semester 2005. The experiment titled, “Solvent-Free Synthesis of Chalcones”1 involves the aldol condensation reaction; an important carbon-carbon bond forming reaction in organic synthesis. An aldol condensation reaction traditionally is performed in an aqueous and/or organic solvent and requires external heating, extraction workup, and purifications. In contrast, the chalcone experiment (illustrated generically in Figure 1) involves solvent-less solid to solid grinding of Figure 2: the two reactants Mortar an d pestle g plus solid NaOH rinding of the reacta nts. (Figure 2) with a mortar and pestle. No solvent is necessary and energy duct is applied through crude pro e th f o n o grinding versus elecFiltrati Figure 3: trical heating source and reflux. The resulting product is then simply rinsed with water and vacuum filtered (Figure 3). In a few cases, this synthesized chalcone is of sufficient quality that further purification is not necessary. More commonly a recrystallization yields a pure white solid, as illustrated in Figure 4. Most of Pageʼs students obtained excellent experimental results and enjoyed “learning about green chemistry.” In addition, the chalcone class of compounds is of interest because many of these molecules are natural products isolated from plants sources and have been shown Figure 4: Student product after crystallization to have interesting biological activity including anti-cancer properties.2 Overall, the chalcone experiment was a pedagogical success and will be fully implemented in the 2311 organic laboratories this summer. Palleros, D.R. J. Chem. Educ. 2004, 81, 1345-1347. Dimmock, J.R.; Elias, D.W.; Beazely, M.A.; Kandepu, N.M. Current Med. Chem. 1999, 6, 1125-1149. 1 2 Page 8 Research Highlights These are just a few of the highlights of the research conducted in the department within the last year. For more on the research developments see the departmental website: http://www.chem.umn.edu/netstep/ Analytical techniques to investigate the sequestration of anticancer drugs in individual acidic organelles Figure 1. Scientists have speculated that acidic organelles (lysosomes and endosomes) sequester drugs that are weak bases (e.g. doxorubicin, pKa ~8.4) because they become protonated when they enter the lumen of an acidic organelle (e.g. pH < 6). If this process occurs in a cancer cell, the acidic organelle contributes to eliminate the drug from this cell, which ultimately leads to the cellʼs survival and cancer drug resistance. (A) Composite confocal image of CEM/C2 cells. Red and green indicate doxorubicin in the nucleus and nanospheres in acidic organelles, respectively. In a recent accelerated article published by Analytical Chemistry (77, 2281–2287, 2005), Yun Chen, Richard Walsh and Edgar (B) Electropherogram Arriaga report on the detection and quantification of the region showing acidic anticancer drug doxorubicin in individual acidic organelles. organelles with and The investigators used as models human leukemia cell lines without doxorubicin isolated that engulf (endocytose) fluorescently-labeled nanospheres into from CEM/C2 cells. Acidic acidic organelles and then treated these cells with doxorubicin. organelle (i.e. nanosphere) Using confocal fluorescence microscopy, the investigators were detection, at 510 ± 20nm. Doxorubicin detection at able to identify the position of acidic organelles (Green domains 635nm ± 27.5nm. Separation in Figure 1A), but doxorubicin (red domain in Figure 1A) did not was performed at –300V/cm colocalize in acidic organelles and was mainly localized in the in sucrose-HEPES buffer. nucleus. Cells were incubated In contrast, when these researchers used capillary with 50-nm diameter electrophoresis with laser-induced fluorescence detection (CE- nanospheres for 48 h and 25 LIF) they were successful at separating and detecting individual µM DOX for 15 min. events associated with acidic organelles containing doxorubicin (e.g. event detected simultaneously in the two channels of the LIF detector, Figure 1B) and other acidic organelles that did not contain doxorubicin (e.g. event detected only in acidic organelle channel). After calibration of this detector, they discovered that on average acidic organelles contained ~ 10-20 molecules of doxorubicin per organelle. This was the lowest measured amount of a fluorescent drug associated with acidic organelle sequestration. The contribution of phosphate-phosphate repulsions to the free energy of DNA bending The packaging of nucleic acids, especially DNA, is of vital importance to all life-forms from viruses to multicellular organisms. Human cells, for example, contain approximately 2 meters Figure 1. of DNA packed into a nucleus with a radius of 3 µm. This The structure of a 71 represents a million-fold reduction in the effective packing base pair bent DNA volume of DNA in the nucleus relative to that in solution. model illustrating In addition to its role in the packaging of genetic material, average counter-ion DNA bending is also important for the regulation of gene occupations at the expression and protein-DNA binding. It is of fundamental phosphates calculated importance therefore to understand the nature of the forces by Monte Carlo that govern the bending of charged DNA molecules into simulation using non-linear structures and quantify the magnitudes of their a linear-scaling associated energetic factors. Green’s function solvation approach. Red indicates higher occupancy. The bent DNA model was based on the crystallographic structure of approximately one full turn of histone-bound DNA in a nucleosome core particle (PDB entry 1AOI). The calculations predict that phosphate-phosphate repulsions account for approximately 30 percent of the total free energy required to bend DNA from canonical linear B-form into the conformation found in the nucleosome core particle. Recently, the research group of Prof. Darrin York of the Department of Chemistry along with graduate students Kevin Range and Evelyn Mayaan, and in collaboration with Prof. L. James Maher III of the Department of Biochemistry and Molecular Biology, Mayo Clinic College of Medicine, have studied the energetics of DNA bending with theoretical models. continued on page 20 Page 9 Page 10 Page 11 Faculty Awards 2004-2005 Christy Haynes: 2005 American Chemical Society’s Nobel Laureate Signature Award for Graduate Education in Chemistry the award contributes to the improvement of undergraduate education at the University by publicizing their work to serve as a resource for the whole faculty. Two other chemistry professors have received this award: Gary Gray and Kent Mann. This prestigious national Jeff Roberts: Distinguished award was established to McKnight Professorship recognize an outstanding graduate student and her or The purpose of the program is to honhis preceptor(s), in the field of or and reward our most distinguished chemistry, as broadly defined. and highest-achieving mid-career Christyʼs award winning disfaculty who have recently attained sertation was entitled, “Funfull professor status - especially those who have made damentals and Applications significant advances in their careers at the Univerof Nanoparticle Optics and Rich van Duyne, Christy L. Haynes, and Chemistry Department sity, whose work and reputation are identified with Surface Enhanced Raman the University of Minnesota, and whose work has Chair Wayne Gladfelter at 2005 ACS Award Presentation Scattering,” with Rich van brought great renown and prestige to Minnesota. Duyne at Northwestern University. She is currently an NIH PostIn the broadest terms, Jeffʼs scientific interests lie in the study doctoral Fellow in R. Mark Wightmanʼs laboratory at the University of chemical reactions at complex interfaces, especially those relevant of North Carolina at Chapel Hill and will begin her independent to atmospheric and materials science. Guided by this general theme, academic career as an Assistant Professor of Chemistry at the Jeff has made seminal contributions in three important areas: (i) University of Minnesota in the fall of 2005. surface chemistry on ice and liquid sulfuric acid, (ii) mechanisms for Christy joins Wayne Gladfelter in receipt of this national chemical vapor deposition, and (iii) the chemistry of size-selected award. aerosol particles. Michael Bowser: American Chemical Society Division of Analytical Chemistry’s Award for Young Investigators in Separation Science This award is intended to recognize and encourage outstanding contributions to the field of separation science by a young chemist or chemical engineer. The award is presented annually at the Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy. Mike is the second recipient of this new national award. Tim Lodge: Institute of Technology Distinguished Professorship This professorship is the highest honor granted by the college to its professors. Tim was recognized for excellence in service to the Institute, teaching, and research, which have made him one of the most respected faculty members in the college. The highly interdisciplinary and collaborative research program that he leads has earned him a glowing international reputation. His unusually effective teaching has earned accolades and generated widespread enthusiasm from his students. Tim joins three other IT Distinguished Professors in the department: Wayne Gladfelter, Louis Pignolet, and Don Truhlar. Ken Leopold: Horace T. Morse/University of Minnesota Alumni Award for Outstanding Contributions to Undergraduate Education (see page 2 for picture) Each year since 1965, the U of MN has recognized a select group of faculty members for their outstanding contributions to undergraduate education. In addition to honoring individual faculty members, Page 12 Jeff joins George Barany, Bill Tolman, Tim Lodge, and Chris Cramer in receipt of this award. Andy Taton: McKnight Land-Grant Professorship The major purpose of the McKnight Land-Grant Professorship program is to strengthen our faculty for the future. The program is designed to advance the careers of our most promising junior faculty members who are at the beginning stages of their professional careers, and who have the potential to make significant contributions to their scholarly fields and to their departments. Andy is frequently consulted as an expert in the burgeoning field of “bionanotechnology,” and has participated in the organization of a new “Center for Translational Nanotherapy,” a collaborative effort among researchers in science and engineering, biology, and the medical school. He has extended this multidisciplinary approach to his teaching, which has included overhauling our graduate-level course in organic spectroscopy and our junior level polymer laboratory course to reflect current technologies and research. Andy joins the ranks of these fellow chemistry professors to receive this accolade: Doreen Leopold, Steven Kass, Ken Leopold, Jeff Roberts, Bill Tolman, Karin Musier-Forsyth, Chris Cramer, Craig Forsyth, Ilja Siepmann, Andreas Stein, Marc Hillmyer, Richard Hsung, and Kris McNeill. Andy Taton: Alfred P. Sloan Research Fellowship Selection procedures for the Sloan Research Fellowships are designed to identify those who show the most outstanding promise of making fundamental contributions to new knowledge. Sloan Research Fellows, once chosen, are free to pursue whatever lines of inquiry are of the most compelling interest to them. Their Sloan funds can be applied to a wide variety of uses for which other, more restricted funds such as research project grants cannot usually be employed. Staff Awards Professor Taton has begun an ambitious, creative research program combining inorganic nanopatricles with nanostructured polymers, with an eye towards applications in materials science and biotechnology. Andy joins the following faculty who have received this national recognition: Chris Cramer, Ron Gentry, Wayne Gladfelter, Tom Hoye, Steve Kass, Larry Que, Jeff Roberts, Ilja Siepmann, Bill Tolman, and Don Truhlar. Don Truhlar: Lise Meitner Lectureship Award 2006/2007 The “Lise Meitner Lectureship” is the distinction given by The Lise Meitner-Minerva Center each year to a prominent quantum chemist whose work has had an important impact on the chemical community. The Lise Meitner Lectureship award for the year 2006/07 is given to Professor Truhlar as one of the major contributors to the enormous potential of computational quantum chemistry as a research tool in chemistry, through his numerous contributions to the generation of practical methods for electronic structure, potential energy surfaces, solvent models, reaction rates, and dynamics. The Civil Service Outstanding Service Award program recognizes civil service personnel who have provided significant contributions to the departmentʼs mission of teaching, research, and service. Outstanding Civil Service Awards for 2004 were given to: Rita M. Hoerth (Principal Accounts Specialist) Christine M. Lundby (Principal Administrative Specialist) Marc Hillmyer: Elmore H. Northey Professor of Chemistry Marc Hillmyer has been chosen as the first recipient of the Elmore Northey Professorship. This five-year award is intended to recognize an outstanding member of the department who does not currently hold another revenue-bearing Chair or Professorship. The resources for this departmental award come from the bequest of Elmore Northey. Marc joins three other distinguished faculty as holders of Departmental Professorships: Don Truhlar (Lloyd H. Reyerson Professorship), Karin MusierForsyth (Merck Professorship), and Tom Hoye (Merck Professorship). Chris Cramer: Award for Outstanding Contributions to Postbaccalaureate, Graduate, and Professional Education Dale Randall, Commencing in 1998-99, Manager, Research the University of Minnesota recognized a select group of Stockroom, faculty members for their is the official photographer outstanding contributions to for the National Association of postbaccalaureate, graduate, Scientific Materials Managers and/or professional education. (NAOSMM). She was awarded This honor is awarded annually to exceptional a travel grant of $1,124 to attend candidates nominated by their colleges in their NAOSMMʼs 31st Annual Conferquest to identify excellence in postbaccalaureence and Trade Show - August ate, graduate, and/or professional education. In 2-5, 2004, in Philadelphia, PA. addition to honoring individual faculty members, the award will contribute to the improvement During 2004, the following staff of postbaccalaureate, graduate, received longevity awards for their and/or professional education service to the department: at the University by publicizing their work to serve as resource •Anne Mockovak, Chief Financial Officer, 5 years to the whole faculty. •Nancy Hagberg, Executive Secretary, 10 years •Chuck Tomlinson, Assistant to Vice-Chair, 10 years continued on page 14 •Flurnia Hadley-Davis, Executive Secretary, 20 years These awards were presented at a reception held in their honor on January 6, 2005. CAPA Awards Each year the Council of Academic Professionals and Administrators (CAPA) recognizes units of the University of Minnesota that are exemplary in their support of professional and administrative (P&A) staff. The winner of the Outstanding P&A Unit Award for 2004 was the Department of Chemistry. Representatives of the department received the award at a U-wide event on April 28, 2004. P&A staff in the Department of Chemistry are: Janis Bates, Mingjen Chen, Barb Edgar, Joe Franek, Dan MacEwan, Anne Mockovak, Susan Page, Dana Reed, Debbie Schoenholz, Stephanie Stathopoulos, Ted Tolaas, Chuck Tomlinson, Jane Wissinger, Letitia Yao, Victor Young In his acceptance speech on behalf of the P&A staff, Chemistry Administrator Stan Bonnema stated, “Outstanding departments do not create outstanding employees. They may, and should, foster and encourage personal and professional growth. I believe it is outstanding employees who create a functional, goal- and service-oriented unit and department. The Department of Chemistry may be a good place to work, but, in reality, it is the hard work, smart thinking, and dedication of our faculty, staff, and students that make it so.” Page 13 Undergraduate Fellowships and Prizes Senior Awards •Peteris Auzins Memorial Scholarships awarded to advanced undergraduates who have demonstrated outstanding achievement in undergraduate research in addition to overall scholastic excellence: Benji Mathews. •David A. and Merece H. Johnson Scholarship awarded to an advanced undergraduate who has demonstrated outstanding achievement in undergraduate research in addition to overall scholastic excellence: Anthony Vosberg. •The Kenneth E. and Marion S. Owens Scholarship In Chemistry awarded to an advanced undergraduate who has demonstrated outstanding achievement in undergraduate research in addition to overall scholastic excellence: Emily Que. Junior Awards •The Robert C. Brasted Memorial Fellowship a fellowship as well as a parttime apprenticeship in the Departmentʼs General Chemistry Program awarded to an outstanding chemistry major who has expressed an interest in a teaching career in chemistry: Prateek Verma. •The Lloyd W. Goerke Scholarship awarded to a chemistry major who has shown outstanding academic achievement and who has financial need: Kevin Tung. •M. Cannon Sneed Scholarship awarded to a chemistry major who has demonstrated great promise for future achievement: Jenny Werness. •George T. Walker Scholarship awarded to a chemistry major who has shown outstanding academic achievement and who has financial need: Jacob Kilian and Shawn Olson. Sophomore Awards •Thomas DuBruil Memorial Awards awarded to sophomores who have demonstrated outstanding achievement in undergraduate research in chemistry: Loren Greenman and Quincy Long. Other Awards •J. Lewis Maynard Memorial Prize in Advanced Inorganic Chemistry. This award is given for outstanding scholastic achievement in advanced inorganic chemistry: Brandon Johnson. •CRC Freshman Chemistry Achievement Award sponsored by the CRC Press, Inc. This award consists of the latest CRC Handbook of Chemistry and Physics and is given to a freshman chemistry major for outstanding scholastic achievement in Page 14 Faculty Awards continued from page 13 Through the entirety of his career at the U of MN, Chris has made enormous contributions to the Graduate Program of the Chemistry Department, and these efforts are particularly deserving of the recognition for which this award has been designed. He has also made substantial contributions to graduate education in chemistry outside the University, both through service and in his role as the author of the leading textbook in his research field. Chris joins Tom Hoye, Larry Que, and Pete Carr in this recognition. Mark Distefano: George W. Taylor/IT Alumni Society Award for Distinguished Teaching The Taylor Award for Distinguished Teaching recognizes faculty who have made outstanding contributions to undergraduate and/or graduate teaching in the Institute of Technology. A citation from one of the supporting letterʼs states, “He taught the students with a sort of dynamic enthusiasm that is rarely witnessed in professors, particularly ones who teach in the sciences. Difficult subject matter was made accessible by his concrete examples and direct links to his own research. These characteristics transformed organic chemistry from a potentially boring subject to one filled with excitement and fascination.” Other Taylor Distinguished Teachers include Gary Gray, Kent Mann, Ken Leopold, and Lou Pignolet. Bill Tolman: L. I. Smith Professor of Chemistry Bill Tolman has been chosen to receive the title of L.I. Smith Professor of Chemistry. Bill joins four other distinguished faculty as holders of Professorship: Don Truhlar (Lloyd H. Reyerson Professorship), Tom Hoye (Merck Professorship), Kevin Musier-Forsyth (Merck Professorship), and Marc Hillmyer (Elmore H. Northey Professorship). Larry Que: The Max Planck Institute for Bioinorganic Chemistry Frontiers of Biological Chemistry Award In 1995 the Directors of the Institute established an annual guest lectureship on “Frontiers in Biological Chemistry,” combined with an award. freshman chemistry: Sheri Imsdahl. •Merck Index Award sponsored by Merck & Co., Inc. This award consists of the latest edition of the Merck Index and is given to sophomore chemistry majors for outstanding scholastic achievement in organic chemistry: Richard Osness and Nicole Thome. •Undergraduate Award in Analytical Chemistry sponsored by the Division of Analytical Chemistry of the American Chemical Society. This award consists of a yearʼs subscription to the journal, Analytical Chemistry and is given for outstanding scholastic achievement in analytical chemistry: Casey Lantz. •Robert C. Brasted Outstanding Undergraduate TA Awards. This award was established in 2001 in honor of Robert C. Brasted, Professor at the University of Minnesota from 1947 to 1986 and former Director of General Chemistry for more than 25 years. Dr. Brastedʼs strong commitment to teaching and education earned him fifteen teaching awards including: the American Chemical Society Award in Education, The Chemical Manufacturers Award, The James Flack Norris Award of the Boston ACS Section, the John Kuebler Award of Alpha Chi Sigma and the Mosher Award of the California Section. He was the only person to receive all five of these awards. The Brasted Outstanding Undergraduate TA Awards recognize outstanding contributions to teaching by undergraduate assistants: Per Lee. •Hardy Scholarships. Owing to a generous gift from Edgar Hardy we were able to award this grant to four promising students in our program: Kari Anderson, Brandon Johnson, Yousi Ma, Jiangwei Yao. Postdoc and Graduate Fellowships and Awards Postdoc Awards First Year Fellowships •NIH Postdoctoral Fellowship Robert Kennedy (Musier-Forsyth) •Graduate School First Year Fellowship Erik Farquar (Que) Dorian Nelson (Hoye) Jake Rafferty (Siepmann) •NIH-NRSA Postdoctoral Fellowship 2004 Kristen Stewart (Musier-Forsyth) •First Year IT Fellowship Julia Rossini (Gladfelter) Jaye Warner (Buhlmann) •NIH National Research Service Award Post-doctoral Fellowship (Modeling Oxygen Activation by Monocopper Enzyme Sites) 2003-2006 Ben Gherman (Cramer) •Minnesota Supercomputing Institute Research Scholar 2004-2005 Divesh Bhatt (Siepmann) •Four Year 3M Graduate School Fellowship Kelly E. Anderson (Siepmann) My-Nuong Vo (Musier-Forsyth) Ben Duckworth (Distefano) Jen Grzybowski (Veglia) Brandie Kovaleski (Musier-Forsyth) •Louise T. Dosdall Endowed Fellowship 2004-2005 Nermeen Aboelella (Tolman) •DOE Computational Science Graduate Fellowship 2004-2008 Matthew J. McGrath (Siepmann) •Carl Storm Fellowship to attend the •First Year Departmental Block-Grant Metals in Biology Gordon Conference Fellowship (January 2004) Lynn Weyer (Forsyth) Anne Reynolds (Tolman) Established in 1999, the Academy of Distinguished Teachers is a forum through which its members provide important leadership to the University community, serving as mentors, advisers, and spokespersons for the University’s teaching mission. Academy members come from all four of the University’s campuses – Crookston, Duluth, Morris, and the Twin Cities. Former University of Minnesota President Mark Yudof established the Academy of Distinguished Teachers in 1999 in recognition of the importance of outstanding teaching to the University. Winners of both the Horace T. Morse-University of Minnesota Alumni Association Award and the Award for Contributions to Postbaccalaureate, Graduate, and Professional Education comprise the membership of the Academy. Chemistry inductees are: Pete Carr Chris Cramer Gary Gray Tom Hoye Ken Leopold Kent Mann Larry Miller (retired) Lou Pignolet Larry Que http://www.adt.umn.edu/index.html The mission of the Academy of Distinguished Teachers is to recognize and celebrate teaching excellence, to foster the continued improvement of teaching and learning at the University of Minnesota, and to strengthen the resources necessary to do so. •First Year Departmental Kolthoff Fellowships Amanda Bialke (Hoye) Jeff Buth (McNeill/Arnold, CivEng) Melanie Fearing (Arriaga) Rachel Gabor (Penn) Carolyn Gamble (Hillmyer/ Tolman) Brendan Gordon (Mann) Ramona Johnson (Penn/ Swackhamer) Joe Katzenmeyer (Arriaga) Matthew Meyer (Kass) Travis Mills (Zhu) Ayako Hosokawa (Distefano) Changhong Ko (Hsung) Stepan Lenevitch (Distefano) Elena Sizova (Hoye) Yan Zhou (Gao) Graduate School Dissertation Fellowships Jia Liu (Hsung) Amanda Nienow (Roberts) Chad Lindstrom (Zhu) Other Awards •American Chemical Society COMP Division Chemical Computing Group Excellence Award and Overend Award in Physical Chemistry Fall 2003 Jason Thompson (Cramer) •NIH Chemistry and Biology Interface Predoctoral Training Grant 2004-2005 •3rd Annual Graduate Student Research Symposium Travel Awards (May 2004) Dwight Stoll (Carr) Angela [DeGreef] Follett (McNeil) Amanda Nienow (Roberts) •Best Dissertation Award from the Graduate School (June 2004) Sherri Hunt (Leopold) •Overend Award in Physical Chemistry Fall 2004 Matt Craddock (Leopold) •Louise T. Dosdall Endowed Fellowship 2005-2006 Anne Boreen (McNeill) •4th Annual Graduate Student Research Symposium Travel Awards (May 2005) Ce Wang (Forsyth) Nathaniel Lynd (Hillmyer) Aleksey Kurdyumov (Hsung) Eric Klinker (Que) •Department of Chemistry Travel Grant Laurie Breyfogle (Hillmyer/Tolman) •2005 Distinguished Masterʼs Thesis Award of the Midwestern Association of Graduate Schools (MAGS) Nominee: Christopher Jeffrey (Hoye) •Robert L. Ferm Outstanding Graduate Teaching Assistant Award for 2004-2005 Erin Dahlke (Truhlar) Junha Jeon (Hoye) Larry Masterson (Veglia) Jaye Warner (Buhlmann) Page 15 Master's Degrees Advisor Esther Frick Hillmyer David Gingery Jason Jadin Evan Kaneski Jamie Klappa Buhlmann Que Forsyth McNeill Kim Kroncke McNeill Junseok Lee John Lewin Zhibo Li Priscilla Lugo-Mas Siepmann, Weisberg Cramer Hillmyer, Lodge Forsyth Melissa Ostroski Forsyth, Musier-Forsyth Jana Scott O’Doherty Ilya Tsukerman Carr Nikolay Zhuravlev Siepmann Ph.D. Degrees Advisor Mohammed AlDaous Adrian Anderson Stein Jeffrey Bankers Miller Michael Danielson Mary Engler Hoye Forsyth Kathryn Fuller Arriaga Nilhan Gunasekera Arriaga, Musier-Forsyth Min Hu Thomas Hunter Hoye O’Doherty John Jalas Distefano, Hecht Ahren Jasper Truhlar Joseph Kappel Barany Lakshmi Kesavan Gao Yang Khandogin York Bethany Kormos Cramer Ryan Major Zhu Alessandro Mascioni Veglia Mark Mehn Que Jason Mulder Hsung, Zhu Amy Saenger Stankovich Arriaga Thesis Title Synthesis and Characterization of Polylactide Containing Block Copolymers and Their Potential as Thermoplastic Elastomers and Toughening Agents. Functionalized Carbon Nanotubes for Chemically Selective Scanning Tunneling Microscopy Inorganic Chemistry Methods of Spiroketal Formation in Nutural Product Synthesis The Synthesis, Characterization, and Properties of Pyridylpyrrole Derivatives and their Zinc and Boron Complexes. Synthesis and Development of Chemiluminescent Probes for the Detection of Singlet Oxygen. Simulating the Vapor-Liquid Equilibria of Large Cyclic Alkanes Current Location Eli Lilly and Company U of MN, PhD Rochester MN: Teacher River Falls, WI Woodruff, WI INX International, Appleton, WI: Research Chemist General Electric, San Diego, CA A Rapid Method for Determining C-H Bond Dissociation Energies U of MN, PhD as a Means of Assessing Metabolic Stability of Drug Molecules Fluorinated Amphiphilic Miktoarm Star Triblock Copolymers. U of MN, PhD Synthetic Efforts Towards the C3-C14 Spiroketal Domains of University of Washington 7-Deoxy Okadaic Acid Analogs. Synthetic Studies Towards the C31-C46 Side Chain Fragment of the Phorboxazoles. 1. Studies on a Palladium-Catalyzed Glycosidation Reaction and a Diastereoselective Allylation Reaction. II. Studies Towards the Synthesis of Unnatural Monosaccharides and an alpha, beta-Unsaturated delta-Lactone Natural Product Analog. The Effect of Phosphate on Retention of Anti-Depressant Drugs on Polybutadiene-Coated Zirconia (PBD-ZRO2). Monte Carlo Simulations for Phase Equilibria and Chromatographic Systems. Thesis Title Synthesis, Physiocochemical Characterization, and Catalytic Evaluation of Three-Dimensionally Ordered Macroporous Metal Oxide Catalysts and Photocatalysts. Strategies for the Elucidation of Doxorubicin Metabolism by Capillary Electrophoresis with Laser-induced Fluorescence Detection. Vapoconductive Materials: Mechanism and Sensor Applications. A Total Synthesis of Callipeltoside A. Phorboxazole A: Enhanced Synthesis of Biologically Active Analogs of the Phorboxazoles. Analysis of Individual Mitochondria and Acidic Organelles by Capillary Electrophoresis with Laser-Induced Fluorescence Detection. Investigations Into the Use of Capillary Electrophoresis for the Analysis of Nuclear Preparations and the Nuclear Localization of Fusion Proteins at the Single Cell Level. A Total Synthesis of (-)-Zampanolide and (-)-Dactylolide. Investigation Into the Syntheses of alpha, beta-Unsaturated delta- Lactone and Macrolide Natural Products. Stereo- and Regioselectivity in the Cytochrome P450-Mediated Metabolism of the Tobacco-Specific Nitrosamine 4-(Methylnitrosamino)-1 -(3-Pyridyl)-1-Butanone (NNK). Non-Born-Oppenheimer Chemistry: Coupled Potential Energy Surfaces and Semiclassical Trajectories. Synthetic Strategies for Solid-Phase Synthesis: I. Design, Synthesis, and Applications of Handles. II. Combinatorial Synthesis of Small Molecules. Understanding the Catalytic Mechanism of Haloalkane Dehalogenase: A Combined QM/ MM Study. Development and Application of Linear-scaling Quantum Methods for the Study of Biological Macromolecules. The Study of Liquid Solution and Solid Phase Systems: I. Reactions and Thermodynamics of Alkyl Halides II. Structures and Energetics of Group 13-15 Compounds. Physical and Chemical Properties of Organic Monolayers on Silicon Oxide and Gold Surfaces. Solution and Solid-State NMR of Membrane-Bound Proteins and Peptides. Modeling Oxygen Activation at Mononuclear Nonheme Iron(II) alpha-Keto Acid-Dependent Dioxygenases. I. Synthesis of Chiral Ynamides II. Reactions Involving Chiral Ynamides. Thermodynamic Investigation of Substrate Activation and Regulation in Human Short-Chain ACYL-CoA Dehydrogenases. U of MN Duluth U of MN Cancer Center Northbrook, IL Moscow, Russia Current Location SABIC, Saudi Arabia: Researcher Amgen, Thousand Oaks, CA (after Eco Labs, St. Paul, MN) Dial, Scottsdale, AZ: Senior Scientist, Home Care Division 3M Pharmaceuticals Madison, Wisconsin Minnesota Bureau of Criminal Apprehension, St. Paul, MN (after postdoct, Mass Spectrometry Consortium for the Life Sciences, U of MN) University of Wisconsin Marathon County: Assistant Professor Albany Molecular Research Postdoc, Stanford University (with Prof. Barry Trost) U of MN, Medical School (starting a pathology residency at UCSF soon) Postdoc Montpelier, France (with Prof. J. Martinez) NIH postdoc with Anne Baranger at Wesleyan University Hysitron, Inc. Postdoc U of MN (with Prof. G. Veglia) NIH postdoctoral fellow under Prof. Jonas Peters at Caltech NIH postdoctoral fellow at Harvard University (Professor David Evans) Clinical Chemistry Postdoctoral Training Program, University of Washington, Seattle, WA continued on page 20 Page 16 Chemistry Degrees Granted from July 1, 2002 to June 30, 2003 Bachelor's Degrees and Home Town Bryan Paul Berry Douglas Brinkman Beth Brockshus Robin Caperton Anna Chalin Andrew Lee Fraser Kate Gemmell Vikisha Goberdhan Helia Hatefi Derek Heidbrink Carla Marie Hemmila Joshua Hewuse Jacob Hodge Kristopher Hodgson Cori Ann Huffman Medora Huseby Andy Janisch Amy Jenk Uti Stan Kar William Knopke Timothy Kohnke Paul Kralovec II Casey A Lantz Christian Lavarreda Angela Mandy Matthew Mann Benji Mathews Jason Merkel Kristen Mills James Nathan Andrea Nelson Duluth MN Plymouth MN Burnsville MN Minneapolis MN St. James MN Lino Lakes MN Minneapolis MN Minnetonka MN Roseville MN Burnsville MN Blaine WI Spencer WI Rochester MN Sioux Falls SD Appleton WI Moorhead MN Thief River Falls MN Wauwatosa WI Fridley MN St. Louis Park MN Eagan MN Wayzata MN Brooklyn Park MN Minneapolis MN Long Lake MN Kamloops, BC, Canada White Bear Lake MN Fort Atkinson WI Arden Hills MN Robbindale MN Minneapolis MN The Following Companies Have Generously Donated to the Department of Chemistry Educational Grants 3M Company Abbott Laboratories Cambridge Isotope Laboratories, Inc. The Dow Chemical Company Foundation Interfacial Solutions, LLC Omicron Nano Technology USA Positive Light, Inc. Procter & Gamble Company RHK Technology Schlumberger Technology Corporation Left to right, new graduates Alison Wagner, Jaressa Tucker, and Jason Merkel Vikesh Patel Mandy Peacock Gregory Perrault Viet Quoc Pham Brian Philippy Jennifer A Plautz Emily Que Jenny Lynn Reynolds Daniel Sagstetter Justin Mark Schmidt Jonathan Schrupp Samuel Shirley Sarah Sorlie Bryan Gary Sowieja Christina Thomas Deborah Tobias Jareesa Tucker Darrick Unger Eymi Vera Anthony Vosberg Alison Wagner Nathan Wilhelm Brian Wong Peter Wynia John Chan Yick Nor Isnaini Yusoff Mumbai, India St. Paul MN North Branch MN Little Canada MN Calloway MN Minnetonka MN Roseville MN Apple Valley MN Apple Valley MN Mukwonago WI Fridley MN Minneapolis MN Roberts WI Inver Grove Hts MN Mahtomedi MN Prior Lake MN Lansing MI St. Louis Park MN Bloomington MN Lake Elmo MN Fort Atkinson WI Burnsville MN Jakarta Pusat, Indonisia Roseville MN New Hope MN Kuala Lumpur, Malaysia Matching Funds 3M Company Abbott Laboratories Fund Agilent Technologies, Inc. Air Products & Chemicals, Inc. Alliant Techsystems, Inc. AstraZeneca Pharmaceuticals LP BP Foundation, Inc. Bristol-Myers Squibb Foundation, Inc. Cargill, Inc. ChevronTexaco Corp. Cognis Corp. Crompton Corp. Deloitte Foundation Dow Corning Corp. The Dow Chemical Company Foundation Ecolab Foundation Eli Lilly & Company Foundation ExxonMobil Foundation GE Foundation General Mills Foundation GlaxoSmithKline Foundation Guidant Foundation, Inc. H B Fuller Company Foundation Honeywell Hometown Solutions IBM International Foundation The Medtronic Foundation The Merck Company Foundation Motorola Foundation Novartis U S Foundation The Pfizer Foundation The Pharmacia Foundation, Inc. The PQ Corp. The Procter & Gamble Fund Seagate Technology LLC Shell Oil Company Foundation The Sherwin-Williams Foundation Tennant Foundation Waters Corp. Page 17 Many Thanks to our Individual Donors in 2003 and 2004 Individual support from our alumni and friends is crucial to the myriad activities of our department. Thanks to your generosity, we have been able to offer fellowships and scholarships to our outstanding students, retain our best faculty, and implement projects which will improve our facilities. The Chemistry Special Projects Fund is the department’s main discretionary fund, which supports student fellowships and awards as well as the bulk of the other activities mentioned in this newsletter. With gratitude, we acknowledge our 2003-2004 donors. Chemistry Special Projects Fund Timothy W. Abraham Harmon B. Abrahamson Irving M. Abrams Charles D. Adams Steven J. Albrechtsen Bruce D. Alexander Thomas C. Allison Carl J. Almer Roger W. Amidon Marie P. Anderson Mark L. Anderson Carl K. & Eroica K. Atonovsky Mary C. Anttila Mark W. Arriola Laura M. Babcock & James A. Jensen Jerold O. & Donna M. Bahls John J. Baldwin William E. Barber Paul T. Barger Jonathan L. Bass Bruce N. Bastian Robert L. Batdorf Wadim Batorewicz Donavan F. Beaver Mary T. Benson John T. Bergman Leonard & Marlyce Bjeldanes William & Sandra Blackley Christine A. Blaine Margaret R. Blake Frank D. Blum G. Bohnert Bodem Michael Boehlke Angela J. Boettcher Leo F. Bohanon Newman M. Bortnick David C. & Felicia J. Boyd Mark E. Branum Brian M. Breczinski Larry J. Bresina Dona L. Brock Murray W. Brockman Beth L. Brockshus Dow E. Brophy Christopher W. Brown Dean G. Brown Gary W. Brudvig Page 18 Andrew D. Bruskiewicz Jay S. Buckley Jr. Paul W. Busse Clyde W. Cady Paul J. Cahill John D. Cahoy Gordon B. Carlton Andrew J. Caruso S. Chakrabarti & P.J. Bell Chi Chang Daniel Y. Chang Yu Sen Chen Phyllis R. Chiarelli Brian H. Chollar Clayton G. Christensen Lief Christensen Henry B. Clark Robert E. Coffman Martha E. Copeland Nancy G. Cordonier Arthur J. Coury Frank A. Cutler Jr. Wesley J. Dale James C. Darling Dorothy D. & Darwin D. Davis George E. Davis Charles A. Daws Saliya A. De Silva Jonathan & Sharon De Vries Jonathan W. De Vries Paul A. Deck Jonathan P. Dick Christopher J. Dinsmore Diane R. Dittenhafer Mark L. Dittenhafer Qi Dongfeng Karen D. Donnelly Kenneth J. Dornfeld Charles H. Douglass Jr. Gregg M. Downing Jonathan W. Draxten Douglas S. Dunn Alison A. Eckhoff David W. Edelstein John A. & Barbara L. Edgar Gilbert L. Eian James A. Elberling Christopher K. Enstrom Christopher D. Erickson Thomas J. Evensen Jurgen H. Exner Raymond J. Farm James B. Federline Christopher Felix Eileen M. Ferguson Daniel W. & Patricia D. Firth Douglas E. & Kristi A. Fjare Steven R. Flom Marvin W. Formo Nile N. Frawley Daniel A. Freedman Robert W. Freerksen Irong Fu Mark A. Fung Fook Frederic R. & Ellen M. Furuya Alan J. Gengenbach Daniel P. Getman James H. Gibson Terry J. Gilbertson A. C. Gilby Norman W. & Joan Gill David C. Gilmer George R. Glaros Sabiha A. Gokcen David J.W. Goon John E. Gozum Robert W. Grady Robert L. Graham George W. Griesgraber Gloria Grode-Lauria Eston M. Gross Gregory S. Gross Todd E. Gross Karen A. Gruetzmacher Richard T. Haasch Mark D. Hadler Kenneth E. Hafften Joyce B. Hall Claude D. Hall Sr. Tina M. Hallis David A. Halsrud Philip D. Hammen Charles & Lois Hammer Robert P. Hammer Joseph B. Hanson Paul R. Hanson Curtis D. Hargadine Mark H. Hartmann Sean D. Harvatine Henry A. Havel Todd R. Hayes Jerome R. Heiman Walden L. Heino Kari A. Hendlin Stacy K. Henle Henry E. Hennis Steven G. Hentges Kim L. Henze Jerry A. & Deborah Herby Martin V. Herschberger Robert E. Hileman Kevin K. Hobbie Keri L. Hobbs Milton L. Hoefle David J. Hoffman Heidi J. Hoglund Troy V. Holland Theodore R. Holman Howard E. Holmquist Paul A. Holte Nicholas J. Horvath William Horwitz Greg A. Howell Peter A. & Gladys L. Howell Rebecca C. & Thomas R. Hoye Craig A. Hoyme Yue Hu He Huang Allan M. Huffman John W. Hull Jr. Michelle J. Hunt Steven E. Husebye Jonathan E. Hutchins David Hyun Gary G. Irish Henry V. Isaacson Robert J. Iverson Charles F. Jackels Jr. Richard A. Jackson Anthony C. Jeannotte II Melody Jewell Eugene & Marjorie Johnsen Brian J. Johnson Bruce D. & Janine Johnson Curtis E. Johnson Russell D. Johnson Susan A. Johnson Kenneth E. Johnson & Sally J. Starz Richard W. Joos Thomas H.R. Jozefiak Michael A. Kahlow Julie A. Kaiser-Braden Gregory J. Kampa Theresa M. & Dennis H. Kelly III Richard T. Kilby Bill B. Knopke James K. Knudsen John G. Koland John H. Konnert Kenneth E. Kosel Maria J. Koutsoukos Kenneth Kustin Richard J. Kvitek Gary Y. W. Kwong Clayton L. Lance Ronald F. Lange Eric C. Larson Leo J. Laux Claire and Margot LeClaire Melida J. C. & Steven H. C. Lee Richard J. Legare Nan Wang & Jianjun Li Yuan Li Tai-Ming Liang Arnold A. Liebman Grant M. Lillevold Steven E. Lindberg Kyle J. Lindstrom Yu-Ying Liu Robert G. Lockwood Timothy P. Lodge John K. Lofdahl Franco Lombardo Karen D. & Donald H. Lucast Bing Luo Gerold Luss Lin Ma Zhiliu Ma Andrew S. Magee Mary P. & Helmut K. Maier Khurram J. Malik Joel G. Malmberg Ming Man Steven C. & Beth March Susan & Curtis Marcott James J. Markham M. John Markuson Julie & Christopher G. Marquardt Brian J. Martin Deanna Carlson Martin Mark W. Martinson Montgomery J. Mason Albert S. Matlack Bruce M. Mattson James H. Maysilles Donald S. McClure John McCool Blaine C. McKusick Terri L. McLernon Crawford Lectureship Fund: Joyce B. & Timothy J. Hall, Henry A. Havel, I. C. & Kimi Hisatune, Thomas A. Kestner, Robert G. Parr, and Laychoo Tan Gassman Lectureship Fund: Jonathan & Janice Chasman, Philip J. Chenier, Paul A. Deck, John H. Dygos, Gerda Ann Gassman, Kentaro Okuma, and D. James Schreck Bert Meier and Gerda Gassman Goerke UG Scholarship Fund: John T. Bergman, Charles A. Daws, Daniel W. Firth, Lloyd W. Goerke, Greta A. Gosewisch, Derk J. Hogenkamp, James K. Knudsen, Ronald F. Lange, Patty L. McNally, Dale G. Swan, Lynn Swanson, Steven J. Tinker, and Kristen M. Zeller-Hack Izaak M. Kolthoff Fund: Madolyn Y. Babcock, Miran K. Chantooni Jr., Grace Po-Yuen Chiu, Johannes F. Coetzee, Charles M. Hall, Albert C. Holler, Ralph A. Johnson, Douglas P. Root, and Yutaka Okinaka Barany Research Account: Michael Barany Graham N. Gleysteen Fellowship: Agnes Gleysteen Fraser Wayland E. Noland Research Fellowship: Rodney D. Dekruif, Roy A. Johnson, Lee E. Klade, and Wayland E. Noland Owens Endowed Fellowship: Kenneth E. & Marion S. Owens Owens Scholarship: Kenneth E. & Marion S. Owens Krogh Endowed Fellowship: Janna P. DeLue, Lester C. & Joan M. Krogh Brasted Memorial Fund: Ieva O. Hartwell Overend Memorial Fund: Madolyn Y. Babcock, Kathleen A. Davis, Thomas G. Goplen, and Curtis A. Marcott Moscowitz Memorial Fund: Mary E. Learmont & Steven C. Riemer Sally Herz Memorial Scholarship Fund: Edgar E. Hardy Margaret C. Etter Memorial Lectureship in Materials Chemistry: Elise A.Sudbeck Thomas P. Du Bruil Memorial Fund: Ann C. and Paul Brey, Paul D. Brey, Justine & Thomas W. Du Bruil, and Francis J. & Theresa B. Haddy John Wertz Fellowship Fund: Florence C. Wertz Patty L. McNally Mark T. Meeks Curtiss J. Meredyk Joseph F. Merklin Gregory E. & Colleen G. Meyer John G. Meyer Vaughn P. Miller Bahram Moasser Erich J. Molitor Edwin F. Morello Gerald H. Morine John J. Muellner Ann M. Mueting Mary H. Murai Pamela W. & Craig B. Murchison Mark D. Nachbor Brian E. Nelson Richard G. Newell John G. Newman Joseph Nichols Brent A. Nielsen Lawrence A. Nielsen Karl C. Ochs II Martha J. Ohlson Jody M. Olsen Kurt D. Olson Peter C. Olson H. James Osborn Thomas G. Ostertag Dean A. Ostlie Chuanbin Pan C. S. Papageorgiou Rudolph Pariser Helen M. Parker George W. Parshall Sadanand V. Pathre Kim Paulsen David R. Peck James R. Persoon & Barbara L. Schmidt Barbara J. Peterson Marvin L. Peterson Sheri L. Peterson Wayne A. Peterson Richard M. & Patricia A. Pieper Ronald L. Plante Joseph P. Porwoll Lawrence W. Potts James H. & Elberta L. Prestegard William W. Prichard William F. Prigge Michael J. Prokosch R. James Puhl Stanton F. Rak Floyd L. Ramp Anthony J. Razel Benjamin R. Reed Gretchen Mary Rehberg Lucinda Reichley-Yinger Michael D. Rein Edgar E. Renfrew Malcolm M. & Carol C. Renfrew Matthew K. Renner Veronica A. Reynolds Rebecca L. Rezac Aloyce J. Rholl Daniel H. Rich Timothy I. Richardson Martin P. Rigney Donald N. Robinson Thomas S. & Debra J. M. Robison Daniel S. Rocque Kevin J. Roesselet Edgar R. & June M. Rogier Anthony R. Rossini Wayne J. Rothschild Emily S. & Nestor A. Rotstein Leonid I. Rubinstein Alan H. Runck David P. Ruschke Paul S. Russo Mark A. Rustad Victor & Catherine Ryan Lowell E. Salyards Gary L. Santee Scott S. Sardeson Richard F. Sauers Mark S. Schaberg Joseph D. Schroeder Jay F. Schulz Kirby J. Scott Richard M. Scribner John K. Seaburg Lynne T. Sergi Edward J. Seus William J. Shugard Richard J. Sinn Steven R. Skorich Richard S. Smith Samuel Smith Quentin F. Soper Richard F. Sprecher Thomas G. Stavros Mark & Kathleen Steine Vernon A. Stenger Robert E. & Debra R. Stevens Mary P. Stickelmeyer Joseph F. Stieber Roger W. Strassburg Dorothy B. & Melvin P. Stulberg Elise A. Sudbeck Joseph C. Suhadolnik Richard J. Sundberg Todd A. Swanson Laychoo Tan Kenneth J. Tauer Paul E. Tavernier Paul R. Thatcher James R. Throckmorton Charles R. Thueson Steven J. Tinker Wade J. Tornquist Charles A. Triplett Edward T. Ulrich Rebecca A. Urbanek John R. VanPilsum Jr. Richard E. Volkmann James R. Vyvyan James J. Wade Terence C. Wagenknecht Mary J. Wahlstrom Joseph T. Warden Jr. Bridget K. Warmka Mark W. Watson Edward O. Welke Valerie Ann Weller Edward L. Wheeler Larry R. Wilson Larry D. Winter Dawn M. Witherill James T. Wolter Charles D. Wright Ellen L. Wu Frank Z. Yang Lee R. Zehner Hongyu Zhao Patrick G. Zimmerman John J. Zingsheim Michelle M. Zirngible Page 19 continued from page 16 Ph.D. Degrees Advisor Simon Shannon Barany Development of New Tools for Solid-Phase Organic Library Synthesis: Backbone Amide Linker (BAL) Anchoring Approaches and Monitoring Methods. Thesis Title Sergey Sokolov Stein Cheng-Min Tann Jonathan Thomson Distefano,Brezonik, Sobelman Carr Judit Tulla Puche Barany Jiashi Wang Hsung Fai Chu Wong Musier-Forsyth, Distefano Xiqin Yang Carr Andrew Zalusky Hillmyer Macroporous Metal Oxides: Synthesis, Characterization and Application in Catalysis and Electrochemical Power Sources. Design of Artifical Enzymes by Site Directed Mutagenesis and Chemical Engineering of a Protein Cavity. High Temperature Ultra-Fast Liquid Chromatography: Theory and Practice. I. Palladium-Mediated Strategies for the Synthesis of Small Molecules. II. Synthetic Studies Towards Partially Folded Peptides. I. Synthetic Application of Formal [3+3] Cycloaddition II. Synthetic Studies toward Fusidilactone C. Class II Proline-tRNA Synthetase: Amino Acid Editing and Incorporation of Unnatural Amino Acids. Mixed-Mode Separations of Cationic Analytes on Polybutadiene Coated Zirconia and Octadecyl Silane Bonded Silica Phases. Nanoporous Materials from Ordered Polylactide-Containing Block Copolymer Templates. Current Location 3M Corporate Research Lab, St. Paul, MN: Senior Research Chemist; Founding President (U of MN chapter) National Organization of Black Chemists and Chemical Engineers (NOBCChE)] Schlumberger Pace Analytical Systec, New Brighton, MN Barcelona Science Park, Barcelona, Spain: Senior Scientist Postdoc, Harvard University (with Prof. Yoshito Kishi) Postdoc,University of Utah (with Prof. Peter Beal) GlaxoSmithKline, King of Prussia, PA Dow Jeanette Brown continued from page 7 Jersey Statewide Systemic Initiative Professional Development Site. In 1995 Ms. Brown officially joined the New Jersey Institute of Technology as a Faculty Associate in the Department of Pre-College Programs. She assumed the position of New Jersey Statewide Systemic Initiative Coordinator with responsibility as the chief professional developer of K-8 teachers where she designed, developed and coordinated the NJIT Thrust K-8 Professional Development Program. Ms. Brown was also a New Jersey Institute of Technology curriculum trainer for middle school teachers and served as a Regional Director of the New Jersey Systemic Statewide Initiative between 1998 and 2002. Ms. Brown has been recognized for her exemplary career. She was named an “Outstanding Woman in Science” in 1990 by the Metropolitan New York Chapter of the Association of Women in Science (AWIS). In 1991 she was named to the Hunter College Hall of Fame for her mentorship of minority students and her work with Project SEED. Ms. Brown received the ACS Women Chemists Committee Regional Award for Contributions for Diversity in 2002. Her mentorship and advocacy continue with her current writing project, a history of African American women chemists for Harvard University’s “African American Lives Series.” Finally, in 2005 she received the national American Chemical Society Award for Encouraging Disadvantaged Students into Careers in the Chemical Sciences. Department of Chemistry Institute of Technology Kolthoff and Smith Halls 207 Pleasant St. S.E. Minneapolis, MN 55455 Research Highlights continued from page 9 In this work, a linear-scaling Greenʼs function solvation method was employed, along with Monte Carlo simulation of counterion occupations at the phosphate residues, in order to quantify the preferential ion and solvation stabilization of bent versus linear DNA. From these calculations, they were able to predict that the electrostatic phosphate-phosphate contribution to DNA bending is on the order of 30 percent - a substantial, but not fully dominating effect. This work is featured on the cover of a recent issue of Nucleic Acids Research 33(4) 1257 (2005). A movie showing how the counterion distribution changes with ion load is also available. Nonprofit Org. U.S. Postage PAID Minneapolis, MN Permit No. 155