Name:______________________________ Chemistry Final Review L2 Into Unit 1. Why is Chemistry often called the central science? 2. What are the different branches of Chemistry? 3. State the Law of Conservation of Matter. Scientific Method A. Experiment E. Hypothesis B. Variable F. Theory C. Control G. Observation D. Conclusion H. Law 4. ______ In an experiment, one ____________ is tested at a time to determine how it affects result. 5. ______When you don’t do anything different than normal in an experiment, it serves as a __________ group. 6. ______ Is a possible answer to a question Math in Chemistry 7. List the SI base units for the following: Volume __________ Mass _____________ Amount/count _______________ Temperature __________ 8. For the following, list the number of significant figures in each: A. 0.0000095________________ B. 745672345 _________________ C. 0.0346001________________ D. 29480000___________________ 9. How many liters in 445 mL? Name:______________________________ 10. How many meters is 651 nm? 11. Sally has to make some temperature measurements. She reads a thermometer to be 52.2oC, 51.5oC, 52.3oC, and 52.2oC. The actual temperature is 49.2oC 12. Do his measurements exhibit high precision? ______________ 13. Do his measurements exhibit high accuracy?______________________ Explain! 14. Measurements are always uncertain because A. Instruments aren’t designed for measurements B. All measurements involve some estimation C. People don’t know how to use instruments D. None of the above E. All of the above 15. 614.0 cm – 2.134 cm = a. 612 cm c. 611.87 cm b. 611.9 cm d. 611.866 cm 16. 428 / 41 a. 10 c. 10.4 b. 10. d. 10.44 17. Convert the following to scientific notation: a. 2000 b. 0.0947 c. 23998 d. 6097000.0 18. Convert the following to standard notation: a. 2.6 x 106 b. 1.2 x 10-4 c. 5.11 x 100 d. 2.300 x 1012 19. How many significant figures do the following numbers have? a. 2.30 b. 1000 c. 0.20100 d. 3.2 x 103 Name:______________________________ 20. A piece of pie has a mass of 200.0g and a volume of 140mL. What is its density? a. 1.4286 g/mL b. 1.428 g/mL c. 1.43 g/mL d. 1.4 g/mL 21. A toy rocket flew 23.0m when launched. How many yards did it fly? (2.3cm = 1.0 in) 22. Convert 123oC to Kelvins? Matter 23. An element a. can be broken down into simpler substances b. are used to make other elements c. are used to make compounds d. are never found in the periodic table of elements 24. Chemical reactions can be used to separate a. elements b. pure substances b. mixtures d. compounds 25. A change in the force of Earth’s gravity on an object will affect its a. mass b. density c. weight d. kinetic energy 26. An property that depends on the amount of material that is present. a. intrinsic b. extrinsic 27. Classify each of the following as either a physical or chemical change. _______________________ A. folding paper _______________________ B. burning paper _______________________ C. dissolving MIO in water _______________________ D. cutting your hair _______________________ E. bleaching your hair Name:______________________________ 28. Identify each as an element, compound, or mixture. For mixtures, identify it as homogeneous or heterogeneous. _______________________ A. grape Kool Aid _______________________ B. Jello with fruit in it _______________________ C. air _______________________ D. a piece of glass (SiO2) _______________________ E. carbon dioxide _______________________ F. silicon _______________________ G. water _______________________ H. copper wire 29. The four states of matter are: __________________________________________ _________________________________________________________________. The Atom _____30. Group 1 _____31. Group 2 _____32. Group 9 _____33. Group 18 A. B. C. D. E. F. Transition metals Alkali metals Alkaline Earth metals Noble gases Inner transition metals Halogens 34. Write the complete chemical symbol for an atom with 31 protons, 38 neutrons, and 28 electrons. 35. Element X has two natural isotopes. The isotope with mass 62.9265 amu has a relative abundance of 69.17%. The isotope with mass 64.9278 amu has a relative abundance of 30.83%. What is the average atomic mass of element X? What is the identity of element X? Name:______________________________ 36. Fill in the sections of the table that are empty. Element # of protons # of neutrons # of electrons 10 10 Mass # Charge (+, −, 0) -1 226 +1 88 Rn 0 Nomenclature 37. What are the 3 types of bonds? 38. Which type of bond occurs with a transfer of electrons? 39. Which type of bond occurs with a sharing of electrons? 40. Potassium chloride has which type of bond? 41. When are Roman numerals used in naming compounds? 42. Name the following compounds. Both ionic and covalent molecules are here, and they are mixed! A. KOH ___________________________ B. LiF _____________________________ C. SO2 _____________________________ D. N2O3 ____________________________ 43. Give the correct formula for the following: A. Zirconium (II) nitratate __________________________ C. Nitrogen gas _______________________ D. Sulfuric Acid ______________________________ G. Phosphorus pentachloride ________________________ H. Barium hydroxide _________________________ Name:______________________________ Reactions and Equations A. Coefficient B. Reactant C. Product D. Balanced E. Endothermic F. Exothermic G. Subscript H. Precipitate I. Diatomic J. Aqueous _____ 44. A reaction that releases heat. _____ 45. A reaction that absorbs heat. _____ 46. A starting substance in a chemical reaction. _____ 47. A new substance formed in a chemical reaction. _____ 48. A solid product. _____ 49. A solid compound dissolved in water. Write out a word equation for the following equations. 50. Ag2O 51. Sb ---------------> Ag + O2 + Cl2 -----------> SbCl2 52. Why do we balance equations? Substitute symbols and formulas for names, and then write a balanced equation for each of the following reactions. 53. Ethane (C2H6) gas burns in air to make carbon dioxide and water. 54. Magnesium reacts with carbon dioxide to form to make magnesium oxide and carbon. Name:______________________________ Balance the following reactions. 55. ___ Na + ___ O2→ ___ Na2O 56. __ BaCl2 + ___ NaOH → ____ Ba(OH)2 + ___ NaCl 57. ___ Fe+ ___ CuSO4 → ____ Cu + ___ FeSO4 58. ___ NbI3 + ___ I2 → ___ NbI5 Identify the type of chemical reaction shown below as synthesis (S), decomposition (D), single replacement (SR), double replacement (DR), or combustion (C). 59. S + Cl2 → SCl2 60. Al + H2O → Al2O3 + H2 61. NaF → Na + F2 62. C7H14 + O2 → CO2 + H2O 63. KBr + AgNO3 → AgBr + KNO3 Given the following reactants predict the products. 64. CuO (s) à 65. AgNO3 (aq) + HCl (aq) à 66. H2SO4(aq) + Ca(OH) 2(aq) à 67. Mg(s) + TiCl4(aq) à 68. SF4(s) à 69. What is the activity series, and why is it important when working with single replacement reactions? Name:______________________________ For #64-68 (above), give the complete and net ionic equations for 3 of them. 70. complete: net: 71. complete: net: 72. complete: net: The Mole 73. What is the value of Avogadro’s number? 74. What does it tell you? 75. How many moles are in the following? a. 2.8 x 1024 atoms of carbon b. 23 grams of oxygen 76. How many grams are in the following? a. 31.2 liters of nitrogen at STP b. 2.61 x 1022 atoms of boron 77. Calculate the molecular formula of the compound whose molar mass is 147g and empirical formula is C3H2Cl. 78. What is the concentration of Hydrochloric acid (HCl) if 0.90 grams of the HCl are dissolved in 250.0 mL? Is this a strong acid? Name:______________________________ Stoichiometry 79. Calculate the mass of ammonia (NH3) formed when 5.40g of hydrogen gas reacts with an excess of nitrogen. Be certain to balance the equation. 80. If 80.0g of Cu reacts with S, how much product is made? 2 Cu + S à Cu2S Energy and Thermodynamics 81.Label all parts of the heating curve Name:______________________________ 82.Label all parts of the phase diagram _____ 83. The First Law of Thermodynamics states: a. Matter is neither created nor destroyed b. Energy is constant within a system c. The amount of energy in a reaction depends on the size of the molecules in the reaction d. The energy of the universe is constant _____ 84. An Exothermic reaction is when: a. Energy flows out of a system b. Energy flows into a system c. The system is at equilibrium d. A reaction that doesn’t occur _____ 85. The amount of energy needed to raise the temperature of a substance by one degree: a. Heat capacity b. Specific het capacity c. Thermal energy d. Entropy _____ 86. The amount of disorder in an object or system: a. Heat capacity b. Specific heat capacity c. Thermal energy d. Entropy Name:______________________________ _____ 87. Temperature is defined as: a. the measure of how hot or cold something is b. the measure of the flow of energy c. the measure of heat d. All the above 88. Iron with a mass of 35 g is heated. The temperature of the iron mass increased from 33˚C to 1350˚C. The iron absorbed 20083 J of heat. What is the specific heat of iron? 89. How much energy does it take to turn 360.0 grams of water (the amount of liquid in a 12 oz. can) into steam? Is this an endo- or exothermic process? Gas Laws ____ 90. According to kinetic molecular theory, gas particles a. are spaced far apart. b. are constantly moving. c. have mass. d. all of the above. ____ 91. Kinetic energy a. is energy associated with movement. b. increases with increasing temperature. c. is given by ½mv2 d. all of the above. ____ 92. The diffusion of a gas is its tendency to a. move through other gases b. move away from other gases c. decompose d. do nothing ____ 93. According to kinetic molecular theory, a. the gas molecules themselves have a volume of zero. b. the gas molecules exert no attractive and repulsive forces on one another c. when gas molecules collide with one another, energy is conserved. d. all of the above. 94. A 3.0L tank of O2 gas is a pressure of 2.5 atm. What will the volume of oxygen be if it is reduced to a pressure of 0.75 atm? Assume constant temperature. Name:______________________________ 95. A gas in a hot air balloon at 38.0oC has a volume of 2.97L and a pressure of 3.14atm. The air is heated to 118.0oC and the volume drops to 1.04L. What is the new pressure (in atm)? 96. What is the volume of 20 moles of a gas under 4 atm of pressure at 14 oC? R= .0824atm-L/mol-K R= 8.314 Pa-L/mol-K EMR 97. Label the properties of the wave depicted below. B C A D E _______ Which letter represents the wavelength of the wave? _______ Which letter represents the amplitude of the wave? _______ Which letter shows a crest? _______ Which letter shows a trough? _______ Can frequency be drawn in? (Yes or No) 98. If energy decreases, frequency ______________, and wavelength ________________. 99. List all of the sections of the electromagnetic spectrum from the shortest to the longest wavelengths in order. 100. Suppose your favorite FM radio station broadcasts at 102.1MHz (1.021 X 108Hz). What is the wavelength of the station? Name:______________________________ 101. X rays have a wavelength of 1.10 X 10-9m. What is the energy associated with this wave? Nuclear 102. What is the minimum amount of uranium called? 103. What is the spontaneous emission of nuclear radiation? 104. Where are protons located? 105. What is the charge of a beta particle? 106. What is a positively charged electron? 107. The measure of which a radioactive substance loses half of its radioactivity. 108. Where are the heaviest elements (greater than lead) created? 109. What is the type of decay that releases an electron and turns a neutron into a proton? 110. This equation states that the energy released by the reaction is equal to the mass multiplied by the speed of light squared. 111. What is the mass of an alpha particle? 112. What is the mass associated with a gamma ray? 113. What type of radiation is most easily blocked? 114. If you start with 8.0 g of C-14, how much is left after 2 half lives? Complete the following nuclear equations. 115. ______ + 3781Rb → 3681Kr Name:______________________________ 15 116. 8 O → 157 N + ______ 58 117. 28 Ni + −10 e → _______ 238 118. 92 U → _______ + 24 He 21 119. 10 Ne → 178 O + _____ Electron Configurations Use the diagrams to answer the questions or complete the statements Figure 6-3 _____ 120. What is the charge on the ion that would most readily be formed by magnesium in Figure 6-3? a. 1+ c. 1– b. 2+ d. 2– _____ 121. In Figure 6-3, what is the charge on the ion that would most readily be formed by sulfur? a. 1+ c. 1– b. 2+ d. 2– Name:______________________________ _____ 122. In Figure 6-3, which of the elements shown would be unlikely to form any compounds? a. Al c. P b. Si d. Ar _____ 123. Which of the four orbital diagrams in the figure above is correct for phosphorus? a. a c. c b. b d. d _____ 124. In in the figure above, what is the total number of electrons that can occupy the n = 3 level? a. 3 c. 9 b. 6 d. 18 Write the electron configuration of the following elements: 125. Na 126. Cu 127. F 128. I Name:______________________________ The Periodic Table Match the person with their contribution to the Periodic Table. _____129. Mendeleev _____130. Moseley _____131. Dobereiner _____132. Newlands A. arranged elements by atomic number B. grouped elements in to sets of three C. predicted the existence and properties of three undiscovered elements D. organized elements into repeating groups of eight, which he termed octaves For each of the following pairs, circle the atom or ion that has the larger atomic radius. 133. Na or Ca 134. N or N3135. Ca or Ca2+ 136. O or F For each of the following pairs, circle the atom that has the higher ionization energy. 137. Cl or Br 138. Rb or K 139. Mg+ or Mg2+ 140. Te or I For each of the following pairs, circle the atom that has the lower electronegativity. 141. Be or B 142. P or Sb Acids and Bases 143. For the following reactions, identify the acid, the conjugate acid, the base, and the conjugate base: HNO3 + H2O à H3O+ + NO3CO32- + H2O à HCO3- + OH- Name:______________________________ 144. What is the pH of an HCl solution that has a concentration of 2.34 x 10-5 M? 145. What is the pOH of the solution? 146. If the pH of a solution of HNO3 is 2.60, what is the concentration of H+ ions?