Theor. Appl. Climatol. 60, 63±76 (1998) General Department of Mathematics, Technological Education Institute of Piraeus, Greece Lower Tropospheric Structure and Synoptic Scale Circulation Patterns During Prolonged Temperature Inversions over Athens, Greece N. G. Prezerakos With 7 Figures Received March 11, 1997 Revised October 6, 1997 Summary In this paper an attempt is made to detect prolonged (of more than 24 hours duration) temperature inversions in the planetary boundary layer over Athens, to study their main characteristics and to ®nd out the synoptic situations with which the inversions are associated. Given the close relationship between the synoptic-scale atmospheric circulation and the occurrence, maintainance and decay of temperature inversions, a simultaneous three category classi®cation of presented inversions and their respective synoptic situations is presented. The classi®cation relies mainly on the similarities and differences in the formation and the maintenance of prolonged temperature inversions. To provide a record of the structure of the lower troposphere and the synoptic conditions favourable to the formation of inversions, mean ascents of temperature and dew-point temperature and mean wind pro®les for the years 1980±1994 were calculated for each category into which a total of 297 cases fell. The main element of this structure which strongly affects the pollution of the lower troposphere is the prolonged temperature inversion. Also, for each category, mean 500 and 850 hPa heights and temperature charts, 500 hPa height anomaly charts, mean sea level (MSL) pressure charts and MSL pressure anomaly charts were drawn. 1. Introduction Temperature inversion is a meteorological phenomenon which has been of great interest to Athenians during the last 22 years. This has been due to the close connection between the planetary boundary layer over Athens (henceforth APBL), temperature inversions (henceforth TI) and air pollution. This is a major problem since it reaches alarming levels many times not only in Athens but in the whole of Attica, which is the larger region to which Athens belongs. Many scientists (Zambakas, 1973; Lalas et al., 1982, 1983, 1987; Kambezidis et al., 1986, 1988; Katsoulis, 1988; Gusten et al., 1988; Melas et al., 1992, 1996; Kallos et al., 1993; Moussiopoulos et al., 1993; Varvagianni et al., 1993; Varotsos and Kondratyev, 1995) have dealt with the problem of atmospheric pollution in Athens but few of them have studied TI extensively (Dikaiakos, 1972, 1974; Tselepidaki et al., 1984; Prezerakos, 1984a). Almost all of the aforementioned papers showed a strong linkage of air pollution episodes to TI. The TI associated directly with these episodes were not the type which appear at night and early in the morning and are destroyed rapidly during the course of the morning heating, but the type of inversions which remain over the whole day and night and even longer. Therefore speci®c research is needed for these prolonged temperature inversions (henceforth PTI). 64 N. G. Prezerakos The occurrence of this sort of TI is favoured by certain synoptic-scale tropospheric circulation systems whose prediction by weather forecasters has improved enormously due to the rapid evolution of computers and numerical atmospheric models. These forecasts lead automatically to the accurate prediction of the PTI appearances one, two or even three days in advance. This last process plays an important role for the Athenians' health and prosperity because the accurate prediction of PTI in the APBL provides the Greek authorities with the possibility of taking suitable measures for pollutant emission restriction in advance-not just after the ground level concentrations have exceeded the maximum permitted values. An attempt is made here to determine and study the structure of the APBL associated with PTIs, that is, inversions which remain for more than 24 hours, appearing in the lower troposphere. We also study the synoptic-scale tropospheric circulation systems with which these PTIs are associated. The main aim of this and an earlier related paper (Prezerakos, 1984a) is to contribute to the accurate prediction of the occurrence of PTIs in the APBL without associating the PTI with air pollution. 2. Data and Method To study the structure of the APBL and the synoptic tropospheric circulation systems which are associated with the PTI the upper air observations at the Helliniko meteorological station (WMO No 16716) were used for selecting the cases to be considered. Helliniko is about 10 km south of the centre of Athens and about 300 m from the coastline, at an elavation of 10 m. The geography, climate and pollution sources in Attica are extensively described in other papers (Kambezidis et al., 1986; Prezerakos, 1986; Katsoulis, 1988) and so there is no need to reiterate them here. Upper air observations at Helliniko are made by Vaissala radiosondes twice daily at 0000 and 1200 UTC and have been detailed up to 700 hPa level with a resolution of 10 hPa during the last 22 years. Thus every TI which has occurred in from the surface up to 700 hPa would be certainly have been recorded. A total of 297 PTIs in the APBL were detected in the 15-year period, 1980-1994. The number of PTI events during a 15-year period is suf®cient to thoroughly study the APBL structure and the synoptic-scale tropospheric circulation patterns with which air pollution events are associated and is also suf®cient to obtain statistically signi®cant results. Although air pollution is closely associated with all kinds of stable layers in the lower troposphere, only the layers which showed a real TI, that is, a layer for which the top temperature was higher than the base temperature, were selected. For each layer beneath the 700 hPa level in which such a TI occurred (in cases where there were multiple inversion layers, the lowest one was considered) its date, duration and other characteristics were recorded. Such a TI is said to be of 12-hour duration when it is reported in two successive 0000 and 1200 UTC soundings at Helliniko. If the TI appears in the next 0000 UTC sounding than its duration is said to be 24 hours, if the same TI appears in the next 1200 UTC sounding then its duration is said to be 36 hours. Continuing in the same manner we de®ne 48, 60, 72, hour durations et cetera. The way the duration of the TI was de®ned does not guarantee that the inversion had not been destroyed temporarily in the time interval between two successive observations. Nevertheless, our experience from observing atmospheric conditions for many years in the APBL pollution watch supports the view that these TIs are not destroyed temporarily, especialy in the time interval between the 0000 and 1200 UTC observations. The TIs with a duration longer than 24 hours were identi®ed. Consequently the height, the top and base temperature, dew-point temperature and wind were registered for every inversion. Simultaneously it was realised that the group of inversions selected could be classi®ed into categories according to the manner of their formation. This led to three categories named A, B and C. Category A includes PTIs in the APBL forming by a combination of surface radiation cooling and synoptic-scale subsidence above. These inversions are features mainly of early-morning soundings, but under certain weather conditions they are not destroyed during the course of the day-time heating and thus are Lower Tropospheric Structure and Synoptic Scale Circulation Patterns During Prolonged Temperature Inversions maintained for 24 hours or more. Category B includes PTIs in the APBL forming by advection of warm air aloft and or cold air below, either alone or in combination. For this differential horizontal advection, to be more effective, large scale vertical wind shear and large scale horizontal temperature gradients are required (Saucier, 1955). The observed frontal inversions, when fronts were near Attica, are attributed to this cause but their durations are seldom 24 hours and so they are not included in this investigation. Category C, includes TIs forming by both surface radiation cooling and differential horizontal advection with synoptic-scale subsidence above. These latter inversions start as early-morning radiation inversions mostly combined with synoptic-scale subsidence and are retained during day-time because of a sea breeze at the lower half of the planetary boundary layer. This combination of early-morning radiation TI strengthened by synoptic-scale subsidence, followed by differential horizontal advection inversions caused by sea breeze create the APBL TI with longest duration. This category seems to be quite similar to category A and thus can be considered as a subcategory of category A. Table 1 shows a complete classi®cation of the 297 PTI events in the APBL that occurred in the 15-year period 1980±1994. Table 1 separates the A, B and C categories into months in order to separate the inversions of every category by season. Since the height, depth and intensity of PTIs in each category appeared to be very similar within each month it was not considered necessary to make a subclassi®cation of these inversion characteristics. Table 1 shows that category C only appears during summer, whereas category A appears in cold seasons. The appearance of category A is pronounced during spring and especially during May with 36 events. Category B appears only during spring and especially during March and category C appears during the 65 warm period of the year but mainly in June. Table 1 also shows that the number of events within each category and season is suf®cient for statistically signi®cant results in relation to mean meteorological ®elds and their anomalies. To study better the APBL structure and the synoptic scale circulation systems under consideration, mean soundings up to the 700 hPa level for Helliniko at 0000 and 1200 UTC have been calculated. These have been plotted on tephigrams for each category, for months with the largest number of PTI cases separately and for the ®rst day (F-day) of a group of successive days during which the PTIs occurred. Mean monthly charts of 500 and 850 hPa height and temperature, 500 hPa height anomaly and MSL pressure and its anomaly were made for all categories of the same months of F days at 1200 UTC. By anomalies we mean the difference from the long-term (1950±1975) average as published by Deutscher Wetterdienst (Barry and Perry, 1973). In addition, the student's t test (at the 0.01 statistical level) has been applied (Brooks and Carruthers, 1953) at each grid point of the anomaly ®elds in order to test whether the anomaly values have a probability of less than 1 per cent of being random. The geographical region considered in this investigation is large enough to include all synoptic patterns and possible centres of actions favouring the occurrence of PTIs in the APBL. This geographical region is covered by a grid point regime with a grid distance of 150 km. The calculations were performed by the computer facilities of the Greek Meteorological Service, using as input the European Centre of Medium range Weather Forecast (ECMWF) data as disseminated to the member states and the Deutscher Wetterdienst 500- hPa height and MSL pressure long-term monthly averages, gridded by Bessel's interpolation method in the same format as the ECMWF data. Table 1. Number of PTI per Month and Category within the 1980±1994 Period Month Categ. Jan Feb Mar Apr May A B C Total 7 12 18 15 26 12 7 12 33 38 36 5 15 56 Jun 60 60 Jul 15 15 Aug 15 15 Sep 30 30 Oct Nov Dec Total 23 5 3 23 5 3 130 32 135 297 66 N. G. Prezerakos 3. Analysis and Discussion 3.1 Category A As Table 1 shows, there were 130 events of PTI belonging to category A during the 15-year period under consideration. In this table we can see that spring and, in particular May, includes the maximum number of events. Winter is second in number of events, while in the warm period, from June to September, PTIs of this category do not occur. As the air pollution problem of Athens becomes severe, with cloudless, windless weather regimes and high solar angles which enhance photochemical pollution, we preferred to analyse and study the spring and in particular the May PTIs. There is no need for the analysis and study to be extended to the winter or even the autumn events since the APBL structure and tropospheric circulation during category A PTIs resemble the respective ones of spring. Also they are much fewer because the frequent appearance of synoptic-scale circulation systems with strong winds and greater cloudiness with precipitation destroys the inversions before they become prolonged. Figure 1 shows the mean structure of the lower troposphere (up to 700 hPa level) on F-days in May. At 0000 UTC (Fig. 1a) the inversion depth is about 760 m, the inversion base at ground level and the inversion intensity (temperature increase) is about 4.5 C. The average degree of stability, =z, is about 2 C/100 m which is somewhat greater than the values found by Katsoulis (1988) in cases of pollution episodes in Athens. This is resonable as this paper deals with inversions with exceptional intensity lasting longer than 36 hours, whereas Katsoulis (1988) deals with all nocturnal inversions when SO2 was more than 250 mg/m3 and/or smoke more than 200 mg/m3. The mean wind vector near the inversion layer is calm whereas it does not exceed 2.5 msÿ1 above up to 700 hPa. The variation of wind direction with height shows some warm advection above the inversion layer which cannot be strong due to the very low wind speed. Humidity at the surface decreases rapidly with height which is a well-known characteristic of stable air masses near the ground with synoptic-scale subsidence above a site near the sea, as at Helliniko meteorological station. These ascents also sug- Fig. 1. Mean May sounding for Hellinico upper air station during category A prolonged temperature inversions (PTI) at 0000 UTC (a) and 1200 UTC (b) of F days (®rst day of a group of successive days with a PTI over Athens) during 1980±1994 (36 cases). The continuous line is air temperature and the dashed line is dew point temperature. Direction (degrees) and speed (kn) (1 kn 0.5 msÿ1 ) of the vector mean wind are given for various levels gest that there are no clouds at all up to 700 hPa (3000 m). During the course of the morning, as the days are cloudless, the solar radiation heats the underlying surface which creates a convective lower planetary boundary layer capped by an inversion. This layer grows with time and reaches a maximum height at around midday (Tennekes, 1973; Yordanov and Kolarova, 1988). Although the diurnal solar heating is suf®cient to destroy nocturnal surface inversions in Athens in May, inversions of category A, forming mainly by subsidence and enhanced by surface cooling in early morning, retain their identity lifting only their base. Something similar occurs in Hemsby, U.K. (Milionis and Davies, 1992). As a consequence of the above process the 1200 UTC mean ascent (Fig. 1b) shows the temperature inversion base to be at about 320 m and its intensity is reduced to about 1.5 C. The wind speed at the surface and at inversion height is about 2.5 msÿ1 causing mixing near the surface which together Lower Tropospheric Structure and Synoptic Scale Circulation Patterns During Prolonged Temperature Inversions with diurnal heating (eddy convection), leads to a dry adiabatic lapse rate up to 350 m height, where the inversion base occurs. Also, the average mixing depth as de®ned by Katsoulis (1988) (extending from the surface to the height where the potential temperature exceeds its surface value by 2 C) is on average 450 m. Also the degree of stability, =z, of the inversion layer is on average 2 C/100 m which, compared with morning one, indicates that stability remains strong enough to retain the inversion longer, which indicates the existence of strong synopticscale subsidence. Figure 2 shows the mean tropospheric circulation of F days at 1200 UTC in May. This synoptic situation in the vicinity of Greece remains almost unchanged during the time period that a PTI occurs in the APBL. So the mean May circulation at 500 hPa isobaric surface is dominated by a synoptic-scale wave with the ridge over the central Mediterranean and central Europe (Fig. 2a). This ridge progresses slowly eastward and creates an advection of negative relative vorticity over Greece and in particular over Athens. This is also suggested by the 500 hPa height anomaly ®eld at ridge vicinity (for the similarity between 500 hPa height anomaly and the relative geostrophic vorticity and its advection see Prezerakos, 1990). The anomaly values over Italy surmount 180 gpm and are statistically signi®cant at the 0.01 level, a fact which indicates that similar ridges over the region are frequent. This kind of circulation must play an important role in the creation of the atmospheric conditions that favour the occurrence of PTIs in the APBL. This is highlighted by the close association of synoptic-scale subsidence and anticyclonic circulation or advection of negative relative vorticity over Greece. This veri®ed in Fig. 3 where the vertical velocity ®elds at Fig. 2. Mean monthly charts of (a) 500 hPa and (b) 850 hPa height and (c) Mean Sea Level Pressure (MSL) during category A prolonged temperature inversions over Athens at 1200UTC on F days in May during 1980 to 1994 (36 cases). Continuous thick lines height contours every 60 m in (a), (b) and Isobars every 4 hPa in (c). Continuous thin lines show isotherms every 5 C in (a) and 2 C in (b). Thin dotted lines show anomaly isopleths of the height ®eld in (a) and the pressure ®eld in (c). Shaded areas delineate height anomaly values (a) and pressure anomaly values (c), statistically signi®cant at the 0.01 level 67 68 N. G. Prezerakos 500 hPa(a), 700 hPa(b) and 850 hPa(c) are presented. These vertical velocities have been calculated by integration of the continuity equation (Wiin Nielsen, 1973): ÿ @! rp ~ V @p 1 (! dp=dt : a measure of vertical velocity, p: atmospheric pressure, ~ V: wind vector, rp : gradient on an isobaric surface). Utilizing the ECMWF's initialized data Fig. 3 shows clearly that the air in the troposphere at the 500 hPa level and below, subsides with mean vertical velocity of about 4 hPa/h and a bit less at the 850 hPa level. This differential vertical motion results in a subsidence type TI. The surface pressure map in Fig. 2c depicts an extended rather smooth ®eld of high atmospheric pressure with three large anticyclones covering most part of Europe (the Balkans included), central-north Africa and the central Mediterranean. Taking into account the recent synoptic evolution of the high barometric ®eld in association with the 500 hPa ¯ow (Fig. 2a) and the thermal and height ®elds at the 850 hPa isobaric surface (Fig. 2b) we can conclude that the northern anticyclone over the Balkans is a mobile cold type, which had moved in the rear of a cold front towards the Balkans. This large anticyclone is in the stage of changing into a deep warm anticyclone (except for a cold shallow surface layer which retains its identity longer). In so doing it slows down and becomes stationary over the Balkans and Greece. The large anticyclone to the south is a warm-core deep anticyclone of subtropical origin. Over time the two large anticyclones show a tendency to form a single continuously decaying anticyclone. The smooth high pressure ®eld over the Balkans guarantees the absence of a signi®cant synoptic scale pressure gradient. Positive pressure anomalies over the Balkans, including the Athens region, have values greater than 3 hPa and are signi®cant at the 0.01 level, a fact which underlines the dominant role of this stationary anticyclone with strong subsidence in the lower troposphere for the appearance of a prolonged inversion of category A. The 850 isobaric surface shows an anticyclonic circulation over Attica. This circulation Fig. 3. Mean monthly vertical velocities in hPa at 500 hPa (a), 700 hPa (b) and 850 hPa (c) during category A prolonged temperature inversions over Athens at 1200UTC of F days in May during 1980 to 1994 (36 cases). Isopleths every 2 h Pa/h, " upward, # downward is in vertical consistency with the surface anticyclone. A somewhat cold advection shown in the Athens region combined with anticyclone ¯ow favours synoptic-scale subsidence in the Lower Tropospheric Structure and Synoptic Scale Circulation Patterns During Prolonged Temperature Inversions lower troposphere. This appears on F day because a small displacement of the anticyclone eastwards on the next day results in Attica being under the central part of anticyclone where no advection occurs. Atmospheric subsidence maintains stability conditions although sometimes it is accompanied by cold advection which tends to destroy the TI. It is worth mentioning, however, that the differential downward motion (as Fig. 3 shows) in the lower part of the troposphere results mostly in an increase in stability. In other words the meteorological quantity @=@z > 0 increases. Examination of the ascents show that the stronger the inversion the greater the daily maximum temperature and the lower the height of the inversion base at 1200 UTC. The PTIs in the APBL are destroyed when the atmospheric circulation becomes cyclonic over Greece with a corresponding advection of cold air. This kind of circulation arises from the presence of cold fronts, which cross Greece coming from the west, northwest or even sometimes directly from the north. These latter fronts are the well-known ``Balkan fonts'' which are closely associated with cold air outbreaks towards Greece (Metaxas, 1978; Prezerakos and Angouridakis, 1984). The 500 hPa circulation associated with the ``Balkan fronts'' is due to the intensive strengthening and displacement northwards or northeastwards of the large scale ridge being in central Europe. This is a consequence of strong warm air advection occurring over the north-eastern Atlantic ahead of the low pressure system shown in Fig. 2a. The extension of the ridge north or northeastwards adopting mostly the shape of a meridional blocking, results in the establishment of an intense cyclonic circulation at the eastern ¯ank of this ridge (Bjerknes, 1951; Prezerakos and Flocas, 1996). A signi®cant maximum of relative vorticity then moves southwards, accompanied by cold air masses. In most of the events this maximum of vorticity results in cyclogenesis when it meets suitable conditions at the surface ahead of a cold front moving southwards pushed by an extension of a wedge of a cold anticyclone growing up at the northern part of the existing anticyclone (Fig. 2c). During this time the rest of the high pressure ®eld weakens signi®cantly until it loses its identity. 69 3.2 Category B Category B types, as Table 1 shows, appear only in spring and especially in March. Figure 4 depicts schematically the mean structure of the lower troposphere, when inversions of horizontal differential thermal advection appear over Attica in March of F days. Figure 4 shows clearly that this kind of inversion forms by the advection of warm air aloft. Early in the morning (Fig. 4a), the combined effect of surface cooling and distinct warm advection above the 900 hPa level results in a ground inversion with a mean depth of about 1600 m. The inversion intensity is, on average, 4 C. Also the average degree of stability, @=@z, is about 1.2 C/100 m which, despite the large vertical extent, is smaller than the corresponding average degree of stability (2 C/100 m) of category A inversions. Radiation and subsidence, responsible for the inversions in May (category A), create stronger stability in the lower troposphere. The origin of the category B type of TI can be better understood by inspecting the 1200 UTC ascents depicted in Fig. 4b. The distinct warm advection starts at about 900 hPa, where the wind reaches signi®cant speeds from the southwest. Above this level the wind direction veers and the Fig. 4. As Fig. 1 but for category B in March (15 cases) 70 N. G. Prezerakos speed increases rapidly with height, increasing the warm and relatively dry air advection as the dew-point depression suggests. Despite the warming from below due to solar radiation at this time that TI is not destroyed but its base is lifted by about 350 m, with a mixing layer depth (Katsoulis, 1988) of about 480 m. The average degree of stability of the inversion at this time (1200 UTC) is @=@z = 1 C/100 m, which is somewhat less than at night. The persistence of category B type PTIs even to midday is an occurrence which deserves to be emphasized. The advected warm air shows a tendency for large scale upward motion, which leads to a temperature drop. This process becomes very signi®cant when various small scale disturbances moving within the southwesterly tropospheric ¯ow approach Attica. On average this upwardmotion cooling is not suf®cient to compensate for the temperature rise due to warm air advection at the APBL's top. This is veri®ed by calculating the average thermal advection at the 850 hPa level over Athens; @T ~ ÿV rp T ÿV 2 4 10ÿ5 Csÿ1 @S (symbols as in Eq. (1), @T @S : temperature gradient along the ¯ow). This average warm air advection assisted by surface heating during day time should raise the 850 hPa temperature during a twelve-hour interval (0000 to 1200 UTC) by about 2 C. Instead, a drop of about 1 C occurred on average. This fact indicates the contribution by the upward motion at the 850 hPa level and below. This upward motion ! < 0 in a stable strati®ed atmosphere ÿ ÿ ÿ > 0 contributes to a temperature decrease according to the second term of the right hand side of the thermodynamic Eq. (3) (Wiin Nielsen, 1973) for temperature change in the atmosphere. But in the third term of the right hand, the diabatic effect must contribute positively to the temperature rise only in the second half of the time interval, close to 1200 UTC, when the surface is heated suf®ciently @T 1 q ~ ÿV rp T ! ÿa ÿ ÿ @t p cp dt 3 (symbols as in equation (1) and (2), ÿ @T=@p: adiabatic lapse rate moist or dry depending upon whether the air is saturated, ÿ @T=@p : actual lapse rate, cp : speci®c heat of moist air at constant pressure, q=dt heat energy change per unit mass caused by processes other than condensation). Although local temperature decreases slightly with time at the 850 hPa level over Helliniko the inversion is maintained. This inversion can be reinforced in cases when the tropospheric ¯ow over and near Attica is not perturbed but it is purely anticyclonic, favouring large scale subsidence. Also, the large vertical wind shear in the APBL (calm at surface and more than 12.5 msÿ1 at 850 hPa) (Fig. 4) associated with pronounced stability caused by TI could, in turn, increase the surface wind speed by downward convection of momentum occasionally (especially when the mobile relatively small atmospheric perturbations are approaching Attica) and decrease signi®cantly the stable structure of the APBL. In such time intervals a horizontal escape of pollutants usually occurs from Attica. Figure 5 shows the mean tropospheric circulation which favours the occurrence of the category B PTI in the APBL in March on F days. The mean 500 hPa (Fig. 5a) is dominated by an extended trough from northern France to south of the Atlas mountains in north Africa. This trough is associated, in perfect vertical consistency, with a developing depression at the surface in the region of the Atlas mountains, moving northeastwards and another one in central Europe (Fig. 5a). The mean 500 hPa ¯ow over Greece is southwesterly and mostly anticyclonic. Because the 500 hPa height ®eld is an average one, the aforementioned small scale pertubations moving in this ¯ow have been smoothed out. The anticyclonic ridge has just passed Greece, lying over Western Turkey and the eastern Mediterranean. Over this region the 500 hPa height anomaly values exceed 120 gpm and are significant at the 0.01 level. Also within the trough region height anomaly values are smaller than ÿ120 gpm in eastern Europe and ÿ60 gpm in the Atlas mountains region. The surface pressure ®eld is smooth over Balkans and relatively low as the pressure anomaly values suggest (less than ÿ6 hPa). This smooth relatively low pressure ®eld suggests that there is no considerable Lower Tropospheric Structure and Synoptic Scale Circulation Patterns During Prolonged Temperature Inversions Fig. 5. As Fig. 2 but for category B in March (15 cases) 71 synoptic-scale pressure gradient over Attica and in Balkans. This results in low surface wind speeds extending upwards, obstructing the warm air advection below the 950 hPa level. The warm air advection becomes signi®cant above the 950 hPa level, as the 850 hPa map shows (Fig. 5b), setting up the regime of differential warm air advection which, in turn, builds up and maintains the TI in the PBL. This regime is more pronounced over the Mediterranean and the coastal regions. This is a consequence of the southern ¯ow shown clearly in the 500 and 850 hPa maps (Fig. 5a,b) of dry and warm air advected directly from the Sahara desert. This air is usually much warmer than the sea surface during this season (spring) and so is cooled from below so that a surface TI builts up. This inversion opposes the vertical eddy ¯ux of water vapor and makes atmospheric air unable to be enriched with humidity, apart from a very shallow layer, as the APBL's structure shows (Fig. 4). This structure can be destroyed when the air ¯ow reaches physical obstacles (i.e. high land), where the air leaves its low tropospheric wet shallow layer at the windward side of the obstacle. The leeward air ¯ow has a low dewpoint and high dry-bulb temperature and is warmed additionally by vertical shrinking as it moves from the top of the obstacle to the surface, becoming very warm and dry with gusty winds. Such events have frequently been observed during spring in north Crete (a major island south of the Greek mainland) (Prezerakos, 1991; 1994). Occurrences of category B type PTIs in the APBL are usually precursors of severe weather phenomena coming into Greece. These are due to developing depressions which approach Greece from the southwest following the maximum of warm advection at the 850 hPa level and the maximum of advection of relative vorticity at 500 hPa. These sorts of depressions are some times rejuvenated in the region south of Sicily (Prezerakos and Michaelides, 1989) resulting in vigorous surface lows which pass through the Greek mainland or nearby Crete causing very strong surface winds and other severe weather phenomena with the simultaneous destruction of any temperature inversion in the Greek planetary boundary layer. 72 N. G. Prezerakos 3.3 Category C The category C PTIs (nocturnal inversions with subsidence in the lower troposphere elongated by the sea breeze) in the APBL occur during the warm period of the year (May to September) especially in June, (as Table 1 shows) when clear skies and calm winds favour nocturnal temperature inversions and the sea breeze competes with etesians (the prevailing northeasterlies in eastern Greece during summer). The major geographic axis of the Athens basin is along a NE-SW direction, with the sea in the west and south (Prezerakos, 1986; Katsoulis, 1988). The pure sea breeze on days with very weak synoptic-scale pressure gradient, and the sea breeze on days with a synoptic-scale pressure gradient favouring off-land winds, are identi®ed. The sea breeze on days with a synoptic-scale pressure gradient causing on shore winds is more dif®cult to identify. The latter cases are usually associated with cyclonic synoptic-scale tropospheric circulation (upward synoptic-scale vertical motion) with surface winds of suf®cient intensity (more than 7.5 msÿ1 ). These meteorological conditions appear very seldom during summer since the polar jet stream is far to the north of Greece (Reiter, 1975). Furthermore, when such synoptic conditions are associated with TIs in the APBL we can easily ®nd out that they are similar to the initial conditions of category B inversions. This kind of inversion rarely lasts more than 24 hours because the moderate surface wind, in combination with the rough land surface, result in turbulence which tends to destroy any inversions. As the Athens sea breeze penetrates as far as mount Parnitha, 30 km inland from the Saronicos gulf coast (Prezerakos, 1986), persistence of meteorological conditions associated with category C PTIs usually leads to an increase of air pollution near the southern foot of mount Parnitha during day-time, with a likely displacement of the polluted air back towards the city during night-time forced by land breeze or weak etesians (Lalas et al., 1983; Katsoulis, 1988). Category C PTIs are the most questionable ones concerning their likely interruption in the time interval between the end of the sea-breeze and the radiosonde release (0000 UTC). To ®ll Fig. 6. As Fig. 1 but for category C in June (60 cases) this gap boundary-layer observations are needed during this time interval. The 60 cases of category C PTIs in June, have a mean structure of the lowest troposphere of F days as shown schematically in Fig 6. The morning temperature ascent (Fig. 6a) is typical for a nocturnal surface temperature inversion with synoptic-scale subsidence above as the large dew-point departure shows. This ascent is quite similar to that category A which indicates that Category C could be considered as a subcategory of A. The wind pro®le shows a weak northeasterly ¯ow of about 1.5 msÿ1 force inside the inversion layer, while above the inversion the wind increases slightly with height, and its direction backs indicating some cold air advection, but not enough to destroy the inversion. The depth of the inversion is on average 450 m, connected with a stable layer of about 400 m depth above the inversion layer. The inversion intensity is about 3 C on average and the average degree of stability, =z, is 2 C/ 100m, strong enough to characterize the inversion as a nocturnal surface-radiation cooling one. Figure 6b illustrates the mean structure of the Athenean troposphere below 700 hPa level at 1200 UTC on F days for category C PTIs. Comparison of this midday structure with the Lower Tropospheric Structure and Synoptic Scale Circulation Patterns During Prolonged Temperature Inversions previous midnight one shows that the top and the base of the inversion were lifted and the whole layer was warmed. This is due to the midday surface heating which created a convective mixed layer, with a superadiabatic lapse rate between the surface and 160 m to where the base of the inversion was lifted. This surface heating, which is extraordinarily strong during summer, very often destroys the inversion except for the occasions on which sea-breeze conditions have been well established, as the Fig. 6b indicates, and when the tropospheric subsidence is strong enough. Although the mean monthly midday temperature ascent on pure sea-breeze cases is smoothed and it is not able to show the residual radiative inversion retained by the sea-breeze (Prezerakos, 1986), this inversion is clearly visible in Fig. 6b. This last fact leads to the conclusion that the basic characteristics of the inversions of category C are mostly similar, being retained thus at the average ascent. The dominant characteristic of an onshore ¯ow is the growth of an internal boundary layer with a temperature inversion at the vicinity of the interface. This inversion caps the internal boundary layer and its intensity is a function mainly of the boundary layer height and the atmospheric stability (Gryning and Batcharova, 1990; Varvagianni et al., 1993; Melas et al., 1996). As the ¯ow proceeds inland over the warmer ground, at midday the inversion is gradually destroyed from below. Unfortunately there are no data available to check the distance inland from Helliniko over which the inversion shown in Fig. 6b maintains its identity. However, observations made at Athens observatory (8 km distance from Helliniko) in May 1990, proved that the sea breeze temperature inversion appears at this site (personal communication with Dr. Kambezidis), which is close to Parthenon (2 km from the centre of Athens) and 300 m from the built up area. The distance inland over which the seabreeze inversion is maintained plays an important role in determining the extension of the area with high air pollution caused by the sea breeze. Figure 6 also clearly shows the midday wind pro®le, which is fairly typical for a sea-breeze regime during its period of maximum development at a coastal station (Prezerakos, 1986). The intensity of the temperature inversion has reduced to 1.5 C and the degree of stability, 73 =z, is on average 1 C/100m, justifying fairly well its role as a trap of air pollutants by obstructing their vertical escape. Figure 7 shows schematically the lower tropospheric mean circulation in the European and Mediterranean area at 1200 UTC on F days of category C PTIs in June. The main feature of the 500 hPa map (Fig. 7a) is a synoptic-scale wave with a ridge just west and northwest of Greece, a closed low off the west coast of France, and a vigorous high over the northeastern Atlantic. The axis of the ridge is almost identical with the 19 E meridian, whereas the Atlantic high shows a northeastward extension. This extension must have caused the occurrance of the low height ®eld over western Europe with its centre in western France (Bjerknes, 1951; Prezerakos and Flocas, 1996). Height anomaly values exceed 180 gpm over the Balkans, (signi®cant at the 0.01 level). The highest values of height anomalies, (signi®cant at the 0.01 level) appear in the Atlantic high, indicating the persistence of the system as would be expected since it is well known Azores anticyclone. The position of the ridge axis close to Greece is typical for the weakening of the etesian winds over the eastern Greek mainland and the Aegean Sea (Reiter, 1971; Prezerakos, 1984b). At the 850 hPa level, (Fig. 7b) most of the Balkans, southern italy, Libya and the Mediterranean in between are covered by an anticyclone, which is consistent with the 500 hPa ¯ow. In the eastern Balkans, the eastern Greek mainland and the Aegean Sea there is a northerly ¯ow maintaining a weak cold air advection, for which there is also evidence in the wind pro®le at Helliniko (Fig. 6). These northeasterlies also appear at the surface, as Fig. 7c shows. The isobars present a similar picture to that of the 850 hPa contours, at least, for southern Italy and the Balkans. The high pressure in the Balkans expressed by pressure anomalies with values around 6 hPa, (signi®cant at the 0.01 level) indicate that the persistence of the high over the Balkans is mainly due to anticyclones moving in the rear of the cold fronts, passing through north Greece towards northwestern Turkey. The combination of high pressure over the Balkans with the permanent (during summer) low pressure over the eastern Mediterranean still exists, resulting in maintainance of the etesians. 74 N. G. Prezerakos This synoptic-scale regime is stronger than the mesoscale sea breeze during the initial days of an etesian period (etesians last several days, see Reiter, 1971). During the initial two to three days of such etesian period (etesians episode) the gradient winds are very strong and any seperate mesoscale circulation (e.g. sea-breeze) is overshadowed (Varvagianni et al., 1993). But on the last days of the episode the synoptic-scale pressure gradient weakens signi®cantly allowing the sea-breeze to overcome the etesians. As Fig. 7 shows, the PTIs occur during such periods when the sea breeze dominates over the etesians, at least at Helliniko. The return ¯ow of the sea breeze coincides with the etesians in the layer from about 850 to 900 hPa (Prezerakos, 1986). 4. Conclusions Fig. 7. As Fig. 2 but for category C in June (60 cases) During the 15-year period from 1980 to 1994 297 events consisting of the lower troposphere prolonged temperature inversions (PTIs), persisting at least over 24 hours (as derived from 0000 and 1200 UTC radiosondes) occurred over the Helliniko upper air station. Based on the common characteristics which these inversions possessed, with respect to formation and maintenance, they were classi®ed into three categories: A, B and C, for each month of the year. Category A appears in almost all months of the year, except for summer and September. The month with the greatest number (36) of PTIs is May. From the mean monthly ascents for May and for the ®rst day of a group of successive days on which a PTI of the same category occurred it is found that category A types start as surface radiation cooling inversion, with strong atmospheric stability near the ground, and with no low and middle level clouds at all. Additionally, strong synoptic-scale subsidence contributes to the inversion layer. The wind is weak from the surface to the inversion layer but increases above it, up to 700 hPa level, although it still remains weak. Hence no signi®cant thermal advection occurs. Of course the base of the inversion is lifted and its depth and intensity decrease during the day, especially at midday, because of the warming from below, which is strong in May in the study region. At 1200 UTC in May with inversions of category A type, anticyclonic circulation over the Lower Tropospheric Structure and Synoptic Scale Circulation Patterns During Prolonged Temperature Inversions Balkans causes advection of negative relative vorticity at 500 hPa level resulting in large scale subsidence in the lower troposphere. These conditions, in turn, result in an even surface air pressure ®eld over the Balkans with cloudless skies. Strong and positive 500 hPa height and MSL pressure anomalies (signi®cant at the 0.01 level) over the Balkans region suggest that a persistent synoptic-scale atmospheric circulation over the Balkans causes the inversions in the planetary boundary layer over Athens. Inversions of category B only appear in spring and especially in March (15 cases). They form mainly by advection of warm air aloft. Warm air advection, in combination with the surface cooling early in the morning, results in a strong surface temperature inversion. However the degree of stability, =z, of category B types is smaller than for category A types where it reaches 2 C/100 m. This is due to the presence of large scale subsidence in category A types. Warm air advection in category B types usually results in large scale upward motion that tends to decrease stability and sometimes may even destroy the inversion. The main characteristics of atmospheric circulation associated with category B type inversions is the smooth low surface air pressure ®eld causing very weak winds and the strong vertical wind shear starting just above the 900 hPa level. Such conditions are associated with strong depressions with fronts approaching Greece. For that reason category B inversions are usually precursors of severe weather phenomena in Greece. Prolonged inversions of category C type appear mainly during the warm months of the year and especially in June (60 cases). They start usually as nocturnal surface radiation cooling inversions with synoptic-scale subsidence in the lower troposphere. During the course of the morning the developing sea breeze competes with the existing weak etesians and usually penetrates inland as far as mount Parnitha. The sea-breeze temperature inversion replaces the nocturnal inversion and so extends the duration of the temperature inversion. For inversions of this type it is not known how far inland the sea-breeze temperature inversion extends and whether the inversion is interrupted between 1200 and 0000 UTC. 75 The synoptic-scale tropospheric circulation, which is associated with category C types resembles most the circulation which occurs when a period of etesians is almost at its terminal stage, i.e., when the etesians have weakened enough to be overcome by the sea breeze. The main characteristics of this circulation are the occurrence of a 500 hPa ridge close to Greece and a rather smooth ®eld of high air pressure at the surface and at the 850 hPa level. This high pressure ®eld combined with permanent low of the eastern Mediterranean during summer, creates the synoptic-scale gradient for the etesians in eastern Greece. This paper has attempted to relate the occurrence of persistant temperature inversions that cause air pollution in the Athens area with certain types of tropospheric circulation. 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