Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Statistical Mechanics and Dynamics of Multicomponent Quantum Gases Austen Lamacraft October 26, 2011 6 2010 Fellows 9 Scialog 2010 19 Cottrell Schola 26 Additional Pro 28 Advisory Comm 30 Financials 32 Officers, Board Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Outline Statistical Mechanics of Boson Pairs Phase transitions and universality Boson pair condensates Interplay of strings and vortices Dynamics of Spinor Condensates Geometry of phase space Mechanics of the Mexican hat Connection to spinor condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Boson pairing and unusual criticality • Yifei Shi, Austen Lamacraft and Paul Fendley arXiv:1108.5744 • Also Andrew James and Austen Lamacraft Phys. Rev. Lett. 106, 140402 (2011) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Outline Statistical Mechanics of Boson Pairs Phase transitions and universality Boson pair condensates Interplay of strings and vortices Dynamics of Spinor Condensates Geometry of phase space Mechanics of the Mexican hat Connection to spinor condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Why study phase transitions? Magnetic Phase Diagram magnetic field first order= jump in magnetization at zero field temperature near critical point jump~ (Tc − T )β Concepts in Critical Phenomena: Amsterdam Nov. 27 2006 € critical point jump=0 slide 7 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Why study phase transitions? Magnetic Phase Diagram magnetic field first order= jump in magnetization at zero field temperature near critical point jump~ (Tc − T )β Concepts in Critical Phenomena: Amsterdam Nov. 27 2006 € critical point jump=0 slide 7 Amazingly, there is a sense in which the two problems are the same. Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Universality: pick your battles • Forget phase diagram and focus on phase transitions • Continuous transitions characterized by critical exponents • M ∝ (T − Tc )β , C ∝ (T − Tc )−α • At T = Tc correlation functions hM(x)M(y)i = • Behavior is characteristic of scale invariance C |x−y|2∆ Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates From scale invariance to simple models (Scale invariance) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates From scale invariance to simple models Studying simple models is a really good idea! Z= X e −βHIsing [σ] , {σ} βHIsing [σ] = −J σi = ±1 X <ij> σi σj Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Universality classes Characterized by broken symmetry of order parameter1 e.g. XY model βHXY [θ] = −J 1 Also spatial dimension X <ij> cos(θi − θj ) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Examples of 3D universality classes Ising class XY class • Liquid-gas, binary mixtures, • Easy plane magnets, • C ∝ (T − Tc )−0.11 • C ∝ (T − Tc )−0.01 uniaxial magnetic systems, micellization,. . . • ξ ∝ (T − Tc )−0.63 λ-transition in 4 He, superconductors, BEC,. . . • ξ ∝ (T − Tc )−0.67 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Examples of 3D universality classes Ising class XY class • Liquid-gas, binary mixtures, • Easy plane magnets, • C ∝ (T − Tc )−0.11 • C ∝ (T − Tc )−0.01 uniaxial magnetic systems, micellization,. . . • ξ ∝ (T − Tc )−0.63 Beautiful classification... λ-transition in 4 He, superconductors, BEC,. . . • ξ ∝ (T − Tc )−0.67 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Examples of 3D universality classes Ising class XY class • Liquid-gas, binary mixtures, • Easy plane magnets, • C ∝ (T − Tc )−0.11 • C ∝ (T − Tc )−0.01 uniaxial magnetic systems, micellization,. . . • ξ ∝ (T − Tc )−0.63 λ-transition in 4 He, superconductors, BEC,. . . • ξ ∝ (T − Tc )−0.67 Beautiful classification... Let’s try to break it! Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Bose condensates and superfluids are XY systems Bose condensation: macroscopic occupancy of single-particle state • Wavefunction Ψ(r) is condensate order parameter • Free to choose phase: XY symmetry breaking ~ • Superfluid velocity v = m ∇θ Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Vortices give a twist in 2D Quantized vortices: phase increases by 2π × q (Integer q) v= ~ ~ êθ ∇θ = m m r Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Vortices give a twist in 2D Logarithmic interaction between vortices of charge q1 , q2 Vq1 ,q2 (x − y) = −q1 q2 πn~2 ln |x − y| 2m 2D density n Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates The Kosterlitz–Thouless transition Consider contribution to the partition function from a q = ±1 pair Zpair = = Z Z dxdy exp [−βV1,−1 (x − y)] dxdy |x − y| βπn~2 2m Pair found at separation r with probability ∝ r 1− • Pair dissociates for kB T > kB TKT ≡ • Pair bound for T < TKT πn~2 2m βπn~2 2m Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Outline Statistical Mechanics of Boson Pairs Phase transitions and universality Boson pair condensates Interplay of strings and vortices Dynamics of Spinor Condensates Geometry of phase space Mechanics of the Mexican hat Connection to spinor condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Pair condensates: an Ising transition in an XY system Two Bose condensates with a definite phase |∆θi = N X n=0 Detect phase by interference e in∆θ |niL |N − niR Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Pair condensates: an Ising transition in an XY system Take a condensate of molecules and split it Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Pair condensates: an Ising transition in an XY system Dissociate pairs Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Pair condensates: an Ising transition in an XY system What is the resulting state? Superposition involves only even numbers of atoms N/2 X n=0 |2niL |N − 2niR = N N n=0 n=0 1X 1X |niL |N − niR + (−1)N |niL |N − niR 2 2 = |∆θ = 0i + |∆θ = πi Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Pair condensates: an Ising transition in an XY system Pair condensate −→ condensate breaks an Ising symmetry!2 2 Romans et al (2004), Radzihovsky et al. (2004) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates A simple model HGXY = − X hiji [(1 − ∆) cos(θi − θj ) + ∆ cos (2θi − 2θj )] Korshunov (1985), Lee & Grinstein (1985) • ∆ = 0 is usual XY; ∆ = 1 is π-periodic XY • ∆ < 1 has metastable minimum Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Schematic phase diagram What is the nature of phase transition along dotted line? action parameter !, which is defined below!. Second which have fourfold-rotational symmetry, they can form a Statistical Mechanics of Boson Pairssymmetric tetratic phase. of Spinor Condensates phase diagramDynamics is quite similar to that found by Mart fourfold Ratón et al. for particles with excluded-volume repu An interesting question is what happens if the symmetry of the particles is slightly broken. Will the symmetry of the This similarity indicates that the phase behavior is ge phase also be broken, or can the particles still form a higherfor particles with almost-fourfold symmetry, independe symmetry phase? For example, we can consider particles the specific interparticle interaction. with approximate fourfold-rotational symmetry that is The plan of this paper is as follows. In Sec. II, we pr slightly broken down to twofold, as in Fig. 1. Can these our model and calculate the mean-field free energy. We particles still form a tetratic phase, or will they only form a examine the phase behavior and calculate the phase dia less symmetric nematic phase? Recently, several experimental theoretical studiesP H Y S I C A L R E V I E W L E T T E R S VOLUME 92, and N UMBER 16 θ2 have addressed this problem. Narayan et al. #1$ performed with c ! 1 $ 2%d$2&=2 , a1 ! 2%d$4 experiments on a vibrated-rod monolayer and found that ν a2 ! 2)d a1 , b1 ! 1, b2 ! 2)%d twofold symmetric rods can form a fourfold symmetric tet%h2 =2'm1 kB &"n=c(%d=2&'2=d the tr ratic phase over some range of packing fraction and aspect at the tricritical point ! ! 0. ratio. Zhao et al. #2$ studied experimentally the ASF phase behavIn the neighborhood of Tc1 the ‘ ior of colloidal rectangles and found what they called an ^ 2 decouples at low energies Normal T field c0 almost tetratic phase. Donev et al. #3$ simulated the phase grated out of the partition function behavior of a hard-rectangle system withν an aspect ratio of 2, T Tc2 Tc1 c(n,T) tive quartic coupling g1 ! g! 1 ( g1 and showed they form a tetratic phase. Another simulation N-ASF transition is identical to tha by Triplett et al. #4$ showed similar results. In further theoθ1 as g! MSF nent system, continuous so long c(n,0) retical work, Martínez-Ratón etνal. #5,6$ developed a densityN-ASF functional theory to study the effectPRL of particle P H Y Stransition I C A LtakesRplace E V atI EvaW 106,geometry 015303on(2011) (the N phase is simply a vacuum of phase transitions. They found a range of the phase diagram nontrivial, is exactly soluble [7], 3 as in which the tetratic phase long shape is FIG.can 2. exist, Phase as diagram forthe a bosonic atom-molecule mixture FIG. 1. Schematic illustration of an interacting particle s An old problem with many guises Korshunov (1985) Lee & Grinstein (1985) Sluckin & Ziman (1988) Carpenter & Chalker (1989) buildup of atomic superfluid (with Romans et al (2004) pha in d ! 3, expressed in terms of detuning ! and T. in temperature the tetratic phase. shape particles indicates th nThe ! j" of j the , j#j , with meansym and a quantum It illustrates a finite-T tricritical point at T rotational symmetry offor thedinteraction is$broken down from fo > 2, and ! d=4 for d < 2) Radzihovsky et al.*jvs@lci.kent.edu (2004) critical point at ! %n; 0&. In the weakly interacting limit appropha to twofold. At T ! 0 the N-ASF transition priate to experiments the ratio T =T ! 2 . lec d-dimensional XY universality class Geng & Selinger 1539-3755/2009/80"1!/011707"6! (2009) 2 011707-1 ©2009 The American PhysicalofS Similarly, in the neighborhood wh or bound into molecules) to N, and detuning ! is related the resulting N-MSF transitions are James & AL (2011) spof to the energy of a molecule at rest, which can be experisality classes discussed above. The mentally controlled with a magnetic field. In the dilute illustrated in Fig. 2. In 3D itpro ex Ejima et al. (2011) gas limit g ; g ; g are proportional to the two-body singularity at the tricritical pointlon and c0 c 1 c2 10 2 2$ 5=3 1/U 1 c1 10 1 2 12 1 atom-molecule, and molecules-wave atom-atom, molecule scattering lengths, respectively, and " characterizes the coherent atom-molecule interconversion rate, encoding that molecules are composed of two atoms [5]. The mean-field phase diagram as a function of #1;2 and $ ! 1=kB0T can be worked out by minimiz-10 -8 -6 -4 action -2 ing Rthe imaginary-time (%) coherent-state R P S ! $h! d% dd x 2 " &# h@ ! % & $ H# % &# ; & &'. Simple totes to the single-component BEC pha To study the MSF phase, we sepa into classical condensate fields "&0O MSF) and fluctuations about it. With the to expand H^ # to second order in flu siti leads to H^ # ! E%0& %"20 & $ H^ %2& with 0 2# 4 Z g2 %0& d # ^ 4 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Outline Statistical Mechanics of Boson Pairs Phase transitions and universality Boson pair condensates Interplay of strings and vortices Dynamics of Spinor Condensates Geometry of phase space Mechanics of the Mexican hat Connection to spinor condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates How things change on the Ising critical line Redo KT argument accounting for string Domain wall terminates at disorder operator µ(x) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates How things change on the Ising critical line Disorder operators dual to σ(x) of Ising model hσ(x)σ(y)i = hµ(x)µ(y)i = Zpair = = Z Z 1 |x − y|1/4 dxdy hµ(x)µ(y)i exp −βV1/2,−1/2 (x − y) dxdy 1 |x − y| 4 + βπn~2 8m Dissociation at higher temperatures than for ‘free’ half vortices Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates How things change on the Ising critical line Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Numerical simulation using worm algorithm Z= YZ c π −π dθc Y w (θa − θb ), 2π habi w (θ) is written in terms of the Villain potential wV (θ) w (θ) ≡ wV (θ) + e −K wV (θ − π) ∞ ∞ X X J∗ 2 2 J e inθ e − 2 n wV (θ) ≡ e − 2 (θ+2πp) ∝ n=−∞ p=−∞ VHΘijL 0.5 1 -0.5 -1.0 2 3 4 5 6 Θij J∗ = J −1 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Numerical simulation using worm algorithm Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Boson pairing and unusual criticality: summary • We found an Ising transition where you’d expect an XY (KT) transition! • The same phenomenon in 3D would be truly remarkable (true long-range XY order developing at an Ising transition) Work underway Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Spin 1 microcondensates AL, Phys. Rev. A 83, 033605 (2011) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Manifesto • The order parameter of a BEC is a macroscopic variable • For a BEC with spin, it should be some kind of pendulum Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Outline Statistical Mechanics of Boson Pairs Phase transitions and universality Boson pair condensates Interplay of strings and vortices Dynamics of Spinor Condensates Geometry of phase space Mechanics of the Mexican hat Connection to spinor condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates A very simple system (Loading Asteroids) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Periodic boundary conditions = motion on a torus Quasiperiodicity: asteroid always hits spaceship! (Loading torus) Statistical Mechanics of Boson Pairs Description of phase space Phase space is a product T 2 × R2 Not as special as it seems! Dynamics of Spinor Condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Action angle variables Hamilton’s equations for H = E (p1 , p2 ) ∂H = v1 ∂p1 ∂H ẋ2 = = v2 ∂p2 ẋ1 = θi = 2πxi Li are angles on the torus obeying θi = 2πvi t + consti Li Simplest example of action (p1 L1 , p2 L2 ) angle (θ1 , θ2 ) variables Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Quantizing the system Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Other choices are possible a(p1 L1 ) + b(p2 L2 ) (1, 0) (0, 1) a, b ∈ Z (1, 1) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Different actions = different unit cells I1 2 1 p1 L1 = I2 1 1 p2 L2 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Outline Statistical Mechanics of Boson Pairs Phase transitions and universality Boson pair condensates Interplay of strings and vortices Dynamics of Spinor Condensates Geometry of phase space Mechanics of the Mexican hat Connection to spinor condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates The Mexican hat Consider the Hamiltonian for two dimensional motion H= p2 r2 − + r4 2 2 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates A natural approach – separate angular motion p2 r2 − + r4 2 2 2 p `2 r2 = r + 2− + r4 2 2r 2 px x + py y ` = xpy − ypx pr = r 2 `2 Defines potential for radial motion V (r ) = 2r 2 − r2 + r 4 H= VHrL 100 80 60 40 20 0.5 1.0 1.5 2.0 2.5 3.0 r Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Phase plane for reduced motion VHrL 100 80 60 40 20 0.5 1.0 1.5 2.0 2.5 3.0 r Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Phase space of integrable systems This is an integrable system: • 2 degrees of freedom and two integrals of motion (energy E, angular momentum `). Motion lies on two dimension submanifold of four dimensional phase space. • Closed trajectories for reduced motion in (r , pr ) plane, and angle θ in the (real) plane is cyclic coordinate ṗθ = 0 −→ pθ = `, const ∂H ` θ̇ = − =− 2 ∂` r (Note that θ motion is not trivial) • The motion at fixed (E , `) lies on a torus. Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Motion on the torus Hradial = pr2 `2 r2 + 2− + r4 2 2r 2 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Motion on the torus Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Quasiperiodic motion (Loading hat) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Action angle variables, and the Liouville–Arnold theorem Liouville–Arnold theorem • For a system integrable in the above sense, can find N conjugate pairs of action-angle variables (Ii , φi ), such that evolution of angles is trivial φi = ωt + φi,0 φ̇i = ∂H ∂Ii • Submanifold of phase space at fixed {Ii } is N-Torus T N Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates At a pinch... In the (`, E ) plane, there is a special point (0, 0) where torus pinches EFSTATHIOU, JOYEUX, AND SADOVSKIÍ Ma in co do Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates At a pinch... In the (`, E ) plane, there is a special point (0, 0) where torus pinches EFSTATHIOU, JOYEUX, AND SADOVSKIÍ Ma in co do Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Rotation angle in the Mexican hat Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Rotation angle φ 4π T −Φ 2π T Φ 2T t FIG. 13. (Color online) (Left) As we circle the origin in Sz , H space for q̃ < 0 the period lattice is deformed continuously, returning to its original form, but after shifting the lattice N ri co sc R th je F st ro th φ Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Hamiltonian monodromy in a nutshell Rotation angle increases by 2π as we circle the pinched torus Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Some history • 1673 Huygens finds period of spherical pendulum (20 years before Newton!) • Classical mechanics: Newton, Euler, .... Hamilton ... • 1980 Duistermaat discovers Hamiltonian monodromy, with the spherical pendulum a prominent example. • 1988 Cushman and Duistermaat discuss signatures in quantum mechanics (no time today...) • 1997 Molecular physicists become interested. Candidate systems are flexible triatomic molecules HAB, such as HCN, HCP, HClO. Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates From another cold atom lab... PRL 103, 034301 (2009) PHYSICAL REVIEW LETTERS week ending 17 JULY 2009 Experimental Demonstration of Classical Hamiltonian Monodromy in the 1:1:2 Resonant Elastic Pendulum N. J. Fitch,1 C. A. Weidner,1 L. P. Parazzoli,1 H. R. Dullin,2 and H. J. Lewandowski1 2 1 JILA and Department of Physics, University of Colorado, Boulder, Colorado 80309-0440 School of Mathematics and Statistics, The University of Sydney, Sydney, NSW 2006, Australia (Received 7 April 2009; published 15 July 2009) The 1:1:2 resonant elastic pendulum is a simple classical system that displays the phenomenon known as Hamiltonian monodromy. With suitable initial conditions, the system oscillates between nearly pure springing and nearly pure elliptical-swinging motions, with sequential major axes displaying a stepwise precession. The physical consequence of monodromy is that this stepwise precession is given by a smooth but multivalued function of the constants of motion. We experimentally explore this multivalued behavior. To our knowledge, this is the first experimental demonstration of classical monodromy. DOI: 10.1103/PhysRevLett.103.034301 PACS numbers: 45.05.+x, 02.30.Ik, 45.50.!j week e intriguing After more than 300 years since the formulation ofS I103, HE YR S ISC Athat L Rthe E Vsingular I E W L E T T17 E RJULY S PHY CThere A034301 L isRthus E(2009) V Ithe EW L E TPpossibility T PRL PRL 103, 034301 (2009) behavior of monodromy may be a common feature of Newton’s laws of motion, one would expect that a system ∼ 5 thresholds [17]. dynamics near chemical isomerization as simple as a mass on a spring would have been fully enclosing loop ($3) motion are A quantum analog of the resonant elastic pendulum understood for some time. In fact, an in-depth investigation former loop does not c under consideration here (Fig. 1) is the Fermi of even a subset of its possible dynamics produces a returning H% H2 resonance Lzto the initial #¼ ; $It¼ : in the CO2 molecule, whose monodromatic number of surprises. Chief among these is a phenomena features have is a simple distin 3=2 H2 "H[14,16]. 2 stepwise precession ad known as Hamiltonian monodromy, which was introduced been thoroughly investigated theoretically Despite behavior by Duistermaat in 1980 as a topological obstruction to the the large number of systems in which monodromy is along a loop With this scaling, the thread pierces the 2D lem the key to our first existence of global action-angle variables [1]. In the resotheoretically predicted, there have been no previousYet, clas∼3 ð$;and #Þ ¼ ð0;a0Þ, producing singularity [Fig. 2(a)]. monodromy is our abi nant elastic pendulum, monodromy has easily observable sical experiments only single quantumaexperiment is developing responsiblea more for the existence of monod resonant elastic pendu physical consequences. Specifically, the observed stepwise [18] of which wesingularity are aware. In heuristic be p The presence the monodromy-producing precession of the elliptical swinging major axis is given by understanding of monodromy in of quantum systems,sical it isexample cansingu Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Outline Statistical Mechanics of Boson Pairs Phase transitions and universality Boson pair condensates Interplay of strings and vortices Dynamics of Spinor Condensates Geometry of phase space Mechanics of the Mexican hat Connection to spinor condensates Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Spin 1 Bose condensates Bose condensation: macroscopic occupancy of single-particle state Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Spin 1 Bose condensates Bose condensation: macroscopic occupancy of single-particle state Q: But what if Bosons have spin? Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Spin 1 Bose condensates Bose condensation: macroscopic occupancy of single-particle state Q: But what if Bosons have spin? A: Macroscopic occupancy and interaction of different states Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Spin 1 Bose condensates Bose condensation: macroscopic occupancy of single-particle state Q: But what if Bosons have spin? A: Macroscopic occupancy and interaction of different states Bosons just oscillator quanta Macroscopic occupancy =⇒ Oscillators are (close to) classical Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Spin-1 gas in the single mode approximation HSMA = N = 1 X c0 c2 : N2 : + : S · S : +HZ . 2V 2V ∗ am am X ∗ am Smm0 am0 m,m0 m=−1 Smn spin-1 matrices, and HZ = h≡ S= P ∗ m am pm + qm2 am 1 2 ∗ ∗ Sz + 2 a1∗ a−1 (a0 )2 + (a0∗ )2 a1 a−1 + 2a0∗ a0 a1∗ a1 + a−1 a−1 2 2N q̃ ∗ ∗ + a1 a1 + a−1 a−1 . N q̃ = q/c2 n. h is energy per particle in units of c2 n Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Classical mechanics of the spin-1 gas h≡ 1 2 ∗ ∗ Sz + 2 a1∗ a−1 (a0 )2 + (a0∗ )2 a1 a−1 + 2a0∗ a0 a1∗ a1 + a−1 a−1 2 2N q̃ ∗ ∗ a1 a1 + a−1 a−1 . + N 2 | 0〉 → |+〉 + | –〉 a +1 0 |+〉 + | –〉 → 2 | 0〉 –1 Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Classical mechanics of the spin-1 gas There are three conserved quantities 1. The energy Nh 2. The angular momentum S z 3. The particle number N For a range of parameters this systems displays monodromy! Mechanics of Boson Pairs ns.Statistical In the case lable collision 140 ms ith total spin ttering lengths re, and, in the mF ergy including s 12,13, where 1.0 c een two atoms )/3m, where h̄ and a0,2 are the 0.8 nnels. For 87 Rb engths a0,2 are n-field energy 0.6 pical densities field, c0 n, and onetheless, the 0.4 -negligible and res depending 87 Rb (refs 18, 0.2 a (refs 15,34). ety of coherent pinor mixing, 0.0 0.0 formation and e with a large field treatment overned by the . For an F = 1 Dynamics of Spinor Condensates Single mode dynamics in experiment 1 0 –1 Period (s) 0.25 0.20 0.15 0.10 Spin populations 0.2 0.1 0.2 0.3 Time (s) 0.4 0.4 ρo 0.6 0.8 0.5 Chapman group (GA Tech) with 0.6 87 Rb Figure 1 Coherent spin mixing of spin-1 Bose condensate in an optical trap. 23 87 Lett group (NIST) The F = 1, m F = 1,0,−1 spinAlso states of Rb condensates confined in with an optical Na (2005) (2007) Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Rotation angle in spinor condensates Monitor evolution of perpendicular magnetization Can be measured by Faraday rotation spectroscopy Statistical Mechanics of Boson Pairs Dynamics of Spinor Condensates Summary In multicomponent quantum gases find unusual phase transitions Yifei Shi, AL & Paul Fendley arXiv:1108.5744 Andrew James & AL PRL 106, 140402 (2011) ...and unusual dynamics AL, Phys. Rev. A 83, 033605 (2011)