GENERAL CHEMISTRY CHM 120 Winter 2012 JohnStahl Office and Voice-Mail: 488-4299 E-Mail: jstahl@kvcc.edu Office Hours: T R 11:30 am -12:30 pm, Room 8540 Chemistry is all around us. Chemical reactions are constantly occurring in our everyday life. With each breath we take, a chemical reaction occurs. When we eat carbohydrates what reaction occurs? How does an antacid tablet work? What reaction occurs when an air bag inflates in a car accident? Did you ever wonder why fireworks are so colorful? Or why hot air balloons rise? Why are more homeruns hit in stadiums at high altitudes? What is the geometric shape of a water molecule or the carbon dioxide molecules that we exhale? Why is chemistry considered the central science? The answers to these questions and others can be found in Chemistry 120. I hope you will join me in discovering the chemistry that surrounds us. Course Description: Chemistry 120 at KVCC is an introductory college chemistry course. Topics include measurement, chemical terminology, stoichiometry, atomic theory, chemical bonding, geometry, the periodic table, gases, molarity, and thermochemistry. Mathematical relationships in chemistry are emphasized. Class Format: Topics will be presented in a lecture-discussion format with questions from the instructor and also from the students. Class participation by students is expected. Laboratory time will involve pre-experiment discussions and performance of experiments and/ or exercises. Lab work is designed to demonstrate concepts presented in class. To successfully complete this course, attendance is necessary in lecture and lab. Student Conduct: Treat others with respect. Be prepared for class and actively participate. Dress appropriately for lab. Turn cell phones off prior to class. Academic Honesty: KVCC’s policies regarding cheating, academic dishonesty, plagiarism, and fabrication will be upheld as stated in the Student Handbook under Student Rights and Responsibilities. https://www.kvcc.edu/services/students/pdf/KV_StudentHandbook.pdf Requisites: Textbook and OWL Access Code: Chemistry and Chemical Reactivity, 8 th Edition, Kotz, Treichel, and Townsend, 2012 Non-programmable scientific calculator with an exponent button Safety Glasses High school chemistry or CHM 099 and MATH 116 Prerequisites: Tutoring: Tutoring is available at the Learning Center (Room 2220) at KVCC. Call 488-4397 for an appointment. I also strongly encourage you to seek help from me as needed. Course material builds upon earlier principles. 1 Testing Policy: If an emergency situation occurs that prevents a student from taking a test, the instructor must be contacted preferably prior to the test (or within 24 hours of the scheduled test). Makeup exams are at the discretion of the instructor. Failure to contact the instructor will result in a zero for the test. Assessments: Assessment of your performance in this class will include quizzes, exams, and laboratory work. No make-ups are allowed for laboratory experiments/exercises or lecture quizzes. As a result, if you are absent, you are allowed to drop one laboratory score and one lecture quiz score from your total course points. Makeup exams are at the discretion of the instructor. (See Testing Policy above) Grading Criteria: Experiments 1 Ave. of 11 expts. = 1 Quizzes 4 quizzes x 25 pts. = Exams 4 exams x 100pts. = Total points 1 without using drop option 100 pts. 100 pts. 400 pts. 600 pts. Grades: Grades will be determined based on % points earned out of total points according to the following scale: % of total points Grade 90-100% 4.0 A 85-89 3.5 A-/B+ 80-84 3.0 B 75-79 2.5 B-/C+ 70-74 2.0 C (passing for transfer) 65-69 1.5 C-/D+ 60-64 1.0 D Below 60 0.0 OWL web site: Online required homework assignments will be accessed through OWL (Online Web-based Learning) at www.cengage.com/owl . In addition to required homework assignments, helpful tutorials and simulations are at this site. Please see the attached OWL Student Guide for more information. Laboratory Web Site: All experiments and lab procedures will be accessed through the web site http://classes.kvcc.edu/chm120. Prior to each lab session, the student must read the pre-lab and lab experiment at this website. The score for each lab experiment consists of 30 points for the OWL homework assignments and 70 points for the laboratory assignment. The scores from the 11 experiments are averaged to contribute 100 points to the total course points. You may miss one experiment without a penalty, however the second absence results in a zero for that experiment. The third absence from lab results in a zero for the missed experiment and an additional 10 % reduction of your course grade. Laboratory Safety Rules: Safety glasses must be worn while cleaning glassware, working with chemicals, and performing experiments (at all times in the lab). Sandals and open toe shoes are not allowed in the lab. Shoes must cover the entire foot. Dress appropriately for lab. Beverages and food may not be consumed in the lab. 2 Instructional Learning Objectives for CHM 120: Comprehends basic chemical concepts and principles Describes the properties of matter Translates word problems into chemical variables Applies concepts and principles to problem solving Comprehends chemical nomenclature and symbols Writes chemical names as chemical formulas Writes a chemical formula as a chemical name Writes a balanced chemical reaction for given chemical compounds Demonstrates knowledge of metric system Converts within the metric system Reports results in correct units and significant figures Comprehends mass and volume relationships Determines molar mass Converts grams to moles Converts moles to grams Calculates density Determines the percent composition of a compound Determines the empirical and molecular formula of a compound Calculates the molarity of a solution Describes the composition of atoms, molecules, and ions Determines the number of protons, neutrons, and electrons Represents an atom or ion with a nuclide symbol Interprets nuclide symbols Explains differences between isotopes of an element Interprets chemical reactions Classifies chemical reactions Predicts products of chemical reactions Comprehends quantitative relationships within chemical reactions Computes quantities of products produced in chemical reactions Determines limiting reagent in a reaction Calculates percent yield Computes volumes of reactants involved in titrations Demonstrates knowledge of gases Calculates the molar volume, molar mass, and density of a gas Applies the ideal gas law Interprets Charles’s Law, Boyle’s Law, Combined Gas Law Understands partial pressure Comprehends thermochemical relationships Interprets thermochemical equations 3 Calculates specific heat capacity and enthalpy Applies heat of fusion and heat of vaporization data Applies Hess’ Law Calculates enthalpy of reaction from standard enthalpies of formation Understands the electronic structure of atoms Computes the wavelength, frequency, or energy of a photon Comprehends the process of absorption and emission of light Determines the possible quantum numbers Describes atomic orbitals Writes the electronic configuration for an atom or ion Writes the orbital box diagram for an atom or ion Demonstrates knowledge of periodic table Classifies an element as a metal, nonmetal, or metalloid Identifies the group, period, or chemical family for an element Predicts and explains trends in atomic radii Predicts and explains trends in effective nuclear charge Predicts and explains trends in ionization energy Determines the geometry of molecules and ions Writes Lewis Dot Structures Writes resonance structures Determines formal charge Predicts most stable resonance structure Applies VSEPR model to molecules Predicts geometry and bond angles Determines polarity of a molecule Applies Valence Bond Theory to molecules Applies mathematical equations to solve for chemical variables Predicts the effect of varying a variable on other variables Manipulates mathematical equations Uses correct number of significant figures in results Applies basic chemical concepts to laboratory experiments Follows directions of experiment Collects chemical data Solves for desired variable using experimental data Completes laboratory assignment 4 The following is a brief description of the topics that will be discussed for each chapter of Chemistry and Chemical Reactivity, 8th Edition, Kotz, Treichel, and Townsend, 2012 Chapter 1 Basic Concepts of Chemistry: classification of matter, physical vs. chemical properties, elements and symbols Let’s Review Tools of Quantitative Chemistry: metric system, density, scientific notation, significant figures, dimensional analysis Chapter 2 Atoms, Molecules, and Ions: nuclide symbols, isotopes, periodic table, nomenclature, polyatomic ions, molar mass, moles, percent composition, empirical and molecular formulas Chapter 3 Chemical Reactions: balancing equations, predict products of reaction, complete and net ionic equations, solubility rules, electrolytes and nonelectrolytes, Arrhenius acids and bases, Bronsted-Lowry acids and bases Chapter 4 Stoichiometry: Quantitative Information about Chemical Reactions: stoichiometry, limiting reagents, percent yield, molarity, titrations, dilutions, pH Chapter 5 Principles of Chemical Reactivity: Energy and Chemical Reactions: energy, heats of reaction, enthalpy change, thermochemical equations, specific heat capacity, calorimetry, Hess’ Law, standard enthalpies of formation, heat of fusion, heat of vaporization Chapter 6 The Structure of Atoms: properties of light, electron transitions, quantum numbers, atomic orbitals, paramagnetism, diamagnetism Chapter 7 The Structure of Atoms and Periodic Trends: electron configurations, atomic radius, ionization energy, effective nuclear charge, periodic trends Chapter 11 Gases and Their Properties: pressure, gas laws, ideal gas law, stoichiometry involving gases, density, molar mass, partial pressure Chapter 8 Bonding and Molecular Structure: Lewis structures, resonance structures, formal charge, VSEPR model, molecular geometry, electronegativity, and polarity Chapter 9 Bonding and Molecular Structure: Orbital Hybridization and Molecular Orbitals: valence bond theory and hybrid orbitals Weather Info: To determine if KVCC is closed due to weather conditions, check KVCC’s web site, sign up for text messages, or call (269) 488-4750. 5 OWL Student Guide You will need an OWL access code to complete your online homework assignments. A special website has been established by Cengage for KVCC students to purchase textbooks and OWL access codes online at http://www.cengagebrain.com/micro/kvccchem Books and OWL access codes are also available at the KVCC bookstore. There are three ways to purchase your OWL access code: 1. Your access code may come bundled with the purchase of a new textbook. 2. You may purchase a stand-alone OWL (no textbook) in the bookstore. 3. You may purchase your OWL code online at http://www.cengagebrain.com/micro/kvccchem What You Need to Use OWL You’ll need an OWL access code, an internet connection and browser. Introductory assignments in OWL will specify browser requirements and test if your browser is configured correctly. Registration and Log In After you have your OWL access code you will need to register it. If you don’t have an OWL access code yet, you can use the 14-day free trial for temporary access. 1. Go to www.cengage.com/owl. 2. Click your course type in the Choose Your Course area: General Chemistry 3. Choose Register. 4. Click your textbook name. Chemistry & Chemical Reactivity, 8th Edition, Kotz, Treichel, Townsend; ISBN: 0-840-04828-9 (also for Hybrid) 5. Click your school name. 6. Click the blue arrow in the Student Registration column. 7. Click the blue arrow in the Section # column that matches your course and section. 8. Follow instructions to complete the Self-Registration Form. Enter your OWL Access Code or choose the 14-day free temporary access. 9. Press Continue to finish the registration process. The Successful Registration page will be displayed. 10. Click on the link at the top of the page to go to the Login Page. Bookmark this page in your browser as your login page for future visits. Log In to OWL 1. After you register, if you forget to bookmark your OWL login page, you can always log in from www.cengage.com/owl. 2. Choose your course and then choose Log In. 3. Choose your textbook and then choose your school. 4. Choose the arrow under User Login Page. On the next screen, enter the login name and password you chose during registration. If you forget your login information, use the "I forgot my login/password" link on the login page. 6 Getting Started with OWL For complete updated instructions, visit www.cengage.com/owl, find the For Students tab at top, click on Getting Started. View the registration and log-in video. To become more familiar with OWL, click on Student Quick Start and Access Code Guide. For Frequently Asked Questions, click on Student FAQs. Course Home Page and Left Navigation Menu After you log in to OWL, familiarize yourself with your Course Home page and the navigation menu on the left of the screen. Information Menu Bar At the top of each question page, you’ll find an information menu bar with the following resources: Chemical Formulas, Scientific Notation, Periodic Tables, and Tables. You can also access the Periodic Table and additional chemistry Tables by choosing Chemistry Tables from the left navigation menu on most OWL screens. Answer Formatting in OWL As with most online homework systems, when you answer questions in OWL, your responses must be correctly formatted in order to be graded. For some answers, you must enter superscripts and subscripts in your answer. Proper answer formatting is especially important when entering chemical formulas, mathematical equations, and units of measurement. Improper formatting will lead to otherwise correct answers being marked wrong. Be sure to complete the Intro to OWL assignments to learn the basics of answer formatting and setting up your browser correctly. Technical Support for OWL You can click Support at the top right of any page in OWL or go to www.cengage.com/chemistry/owlsupport. 7 Date 1/10 1/12 1/17 1/19 1/24 1/26 1/31 2/2 2/7 2/9 2/14 2/16 2/21 2/23 2/28 3/1 3/6, 3/8 3/13 3/15 3/20 3/22 3/27 3/29 4/3 4/5 4/10 4/12 4/17 4/19 4/24 4/26 Lecture Quiz/Exam Intro/Chap 1 Let's Review Chap 2 Chap 2 Chap 3 Quiz Chap 3 Chap 3 Chap 4 *************** *** Exam (Ch 1,2,3) Chap 4 Chap 4 Chap 4, 5 Chap 5 Quiz Chap 5 Chap 5 *********** *** Exam (Ch 4,5) Spring Break No Class Chap 6 Chap 6 Chap 7 Chap 7 Quiz Chap 11 Chap 11 *********** *** Exam (Ch 6, 7,11) Chap 8 Chap 8 Chap 8 Chap 8, 9 Quiz Chap 9, Review FINAL Exam (Ch 1-9,11) (If needed for Snow Day) Experiment Orientation Orientation Measurements Measurements Formula Hydrate / Nomenclature Formula Hydrate / Nomenclature Ionic Reactions Ionic Reactions No Lab Stoichiometry Stoichiometry Citric Acid Citric Acid Calorimetry Calorimetry No Lab Spectroscopy Spectroscopy Periodic Trends Periodic Trends Gases Gases No Lab Lewis Structures Lewis Structures Geometry Geometry Help Session 8