AN ABSTRACT OF THE THESIS OF Jess Holcomb for the degree of Baccalaureate of Science in Bioresource Research, Environmental Chemistry Option, presented on May 30, 2008. Title: Effects of land management on carbon and nitrogen in soils from New Zealand Abstract approved: ________________________________________________________________________ Kate Lajtha, Primary Mentor The ability of soils to store large quantities of carbon (C) makes them an important factor in the global C cycle. Small changes within soil C can lead to large changes in atmospheric C. Land management practices can influence the amount of C that is stored within the soil and rates of C accumulation or loss. The Purukohukohu Experimental Basin in New Zealand provides a great opportunity to analyze C and nitrogen (N) differences in soils as it contains three catchments with different land use practices; native forest, pasture, plantation pine with Pinus radiata. By using Sequential Density Fractionation I could examine differences in pools of C and N in each land use type. Sequential Density Fractionation allows the soil organic matter to be analyzed based upon the stability of the C and N in each of the density fractions, with heavier density fractions generally corresponding to more stable C and N. The results showed a loss of C from converting native forest to pasture and a gain of C from converting pasture to plantation pine. The amount of C in the plantation pine was also larger than was the C in the native forest. There was an increase in N from the native forest to the pasture and the plantation pine had the highest N levels. The losses and gains of C in the plots are attributed to stable C inputs from the forested sites. More stable C inputs results in more C stored. The N increases were due to the planting of white clover in the pasture site, which resulted in high N in the plantation as it was planted on a pasture site. © Copyright by Jess Holcomb May 30, 2008 All Rights Reserved Effects of land management on carbon and nitrogen in soils from New Zealand by Jess Holcomb A THESIS submitted to Oregon State University Bioresource Research in partial fulfillment of the requirements for the degree of Baccalaureate of Science in Bioresource Research, Environmental Chemistry Presented May 30, 2008 Commencement June 2008 Baccalaureate of Science in Bioresource Research, Environmental Chemistry Thesis of Jess Holcomb Presented on May 30, 2008 APPROVED: Kate Lajtha, Mentor Markus Kleber, Secondary Mentor Cary Green, Committee Member I understand that my project will become part of the permanent collection of Oregon State University, Bioresource Research. My signature below authorizes release of my project to any reader upon request. Jess Holcomb, Author ACKNOWLEDGEMENTS We are grateful to Kim Townsend and Lea Wilson for assistance in conducting laboratory research. The authors would also like to thank Dr. Phil Sollins and Dr. Markus Kleber for the use of their laboratory space and helping analyze the data collected. Further analysis of data and helping collect field samples by Dr. Troy Baisden was greatly appreciated. TABLE OF CONTENTS Page 1. Introduction……………………………………………………………….. 1 2. Methods…………………………………………………………………… 2.1 Site Description of the Purukohukohu Experimental Basin…………. 2 2.2 Sequential Density Fractionation and C/N Analysis…………………. 2 3. Results…………………………………………………………………….. 5 4. Discussion…………………………………………………………………. 4.1 Density fractions dry mass…………………………………………… 4.2 Density fraction and total C………………………………………….. 4.3 Density fraction and total N………………………………………….. 4.4 Density fraction C:N ratios…………………………………………... 4.5 2.4 g/ml density fraction difference………………………………….. 9 9 11 12 13 5. Conclusion………………………………………………………………... 14 6. References…………………………………………………………………. 15 LIST OF FIGURES Figure Page Density Fraction Dry Mass…………………………………………………… 5 Density Fraction Carbon Mass………………………………………………... 6 Density Fraction Nitrogen Mass……………………………………………… 7 Total Soil Carbon Mass……………………………………………………….. 8 Total Soil Nitrogen Mass……………………………………………………... 8 Density Fraction C:N…………………………………………………………. 8 LIST OF TABLES Table Page Density Fraction Carbon Mass……………………………………………….. 6 Density Fraction Nitrogen Mass……………………………………………… 7 1 Effects of land management on carbon and nitrogen in soils from New Zealand 1. Introduction Small changes in the amount of carbon (C) stored in soils can result in a large change in global C cycling (Amundson, 2001). This is due to soils containing vast pools of C compared to other places in the environment on a global scale. Globally the amount of C stored in soils is nearly three times that of above ground biomass and approximately twice as much C as that found in the atmosphere (Dixon et al., 1991; Eswaran, 1993). The C in the soils can be lost but at the same time these soils have the ability to sequester C within the soil profile. Loss of soil C would result in large amounts of C being released into the atmosphere, while increases would result in sequestration of atmospheric C. Soil C may be highly resistant to decomposition; measurements of C in North American soils show C that had accumulated from before European colonization in 1500 A.D. (Stevenson and Cole, 1999). This ability to store C for a long period of time makes soils a great place for C to be sequestered to keep it out of the atmosphere. Conversion of forested areas to pasture lands and other agricultural areas are major influences on the modern landscape. Changes in land-use can affect the amount of C that can be stored in the soil as well as the amount of N (Neill et al., 1999). Upon conversion many pasturelands and agricultural lands are treated with N fertilizers to increase production (Parfitt et al., 2006). The addition of these fertilizers and their longterm effects on soil properties are not yet known (Sparling and Schipper, 2004). These changes could have an effect on how C and N are being stored within the soil 2 The Purukohukohu Experimental Basin near Taupo, New Zealand is a location that has several different land-use practices in the same watershed (Beets and Brownlie, 1987). Within the basin there are three different catchments that consist of a native podocarp/hardwood forest, improved pasture, and plantation pine (Pinus radiata) (MAF, 1999). It has been shown that the conversion from native forest to pasture can result in small losses of C in the soil after the conversion, but less is known how the long-term effects of the conversion have had on the amount of C in the soil (Lambert et al., 2000; Elmore and Asner, 2006). The conversion of pasture to Pinus radiata is a major sink for C in New Zealand, offsetting about half of the annual CO2 emissions from energy and industrial uses (MfE, 1997). These new plantation forests can store this C in vegetation, including live and dead forest C pools (Beets et al., 1999). It is uncertain however, how conversion to pine plantation has affected the soil C at these sites (Johnson, 1992). Our objectives are to: (i) determine how the land management practices affect the amount of C and N stored in the soil; (ii) determine in what density fraction the soils are either gaining/losing C and N based on the management practices. 2. Methods 2.1 Site Description of the Purukohukohu Experimental Basin The Purukohukohu Experimental Basin is located in the Paeroa Range in the Central North Island of New Zealand. A description of the vegetation, soil, climate, and pine stand management history is given in Beets and Brownlie (1987). The parent materials originated from Taupo volcanic center (1860 +/- 100 BP) and older ash showers from 3 Taupo and Okataina volcanic centers, which are classified as Pumice soils in the New Zealand Soil Classification System (Hewitt, 1998). Elevation ranges from 500 to 700 meters and topography ranges from gently rolling hills with slopes under 12 degrees to moderately steep slopes of 23 degrees to steep slopes of 30 degrees. Soils belong to the Oruanui series, which are highly permeable with loamy sand, silty sand and gravel. Rainfall averages 1500 millimeters per year, and temperature average 10oC. The basin includes three land-use catchments. Maps showing the boundaries between the main land-use catchments and the Puruki pine subcatchments have been published in Beets and Brownlie (1987). The three land-use treatments are: 1. Puruorakau (37.2 ha): Indigenous mesophyll forest classified as mixed podocarp/tawa (McKelvey, 1963). The indigenous forest catchment includes large podocarp trees including Dacrydium cupressium and Prumnopitys ferruginea, which can be 500-800 years old. No logging has occurred within the majority of this site. 2. Purutaka (22.5 ha): Originally cleared in the 1920s to seral scrub, then developed into improved pasture in 1957 for sheep and cattle grazing. Management of the pasture involves regular application of superphosphate fertilizer and the use of legumes (clover) to fix nitrogen ( Beets et al., 2002). 3 Puruki (35.4 ha): Initially was part of the Purutaka plot but switched land-use from pasture to Pinus radiata in 1973. The stand was initially stocked at a rate of 2200 trees per ha and fenced to exclude animal grazing. Puruki is subdivided into three subcatchments: Tahi, Rua, and Toru. Each different subcatchment has different thinning regimes applied. The understory is dominated by tall pasture species for the first three years until the canopy closed at six years. Bracken fern has been the dominant understory since the pine was thinned. 4 Soil samples were taken from each of the catchments from the depth of 0-15 centimeters below the litter layer. Three samples from each catchment were taken and mixed to create one homogeneous mixture. 2.2 Sequential Density Fractionation and C/N Analysis Samples from each plot were air dried and passed through a 2 millimeter sieve. Five grams of each soil were placed into tins and dried at 50oC and 100oC to determine moisture content. Fifty grams of each soil sample were placed into a 225-ml polycarbonate centrifuge tube with conical bottoms and 5-cm diameter mouths. These tubes allowed for physical separation of sediment and floating material while their transparency allowed easier aspiration of the supernatant without disturbing the sediment. A Sodium Polytungstate (SPT) solution with a density of 1.65 g cm-3 was added to the conical vial until there was 175 ml of solution in the vial. Samples were shaken for two hours. The soil suspensions were then centrifuged at 3500 rpm in a swinging-bucket rotor for ten minutes. After centrifugation, the floating material was aspirated and rinsed with deionized water on a glass fiber filter, Whatman GF/F, (0.7 μm) (Sollins et al., 2006). The density of the remaining SPT solution was increased by adding the next density SPT solution to the centrifuge tubes. Target densities for this fractionation were 1.65, 1.85, 2.00, 2.40, and 2.65 g cm-3. The 1.85 - 2.65 g cm-3 fractions were shaken for one hour. Fractions 2.00, 2.40, and 2.65 were “washed” in the centrifuge instead of being filtered. Deionized water was added to fractions and tubes were centrifuged until the 5 Fraction Mass (g soil) Native Pasture Plantation Pine 20 15 10 5 0 1.65 1.85 2 2.4 2.65 >2.65 Density Fraction (g/ml) Figure 1. Density Fraction dry mass of each density fraction for each of the treatments supernatant had a density of 1.00 g cm-3. Soil remaining after the 2.65 g cm-3 step was considered the >2.65 g cm-3. Fractions were dried at 50oC. All dried fractions were ground in a Spex mixer mill. Samples were sent to the Central Analytical Lab at Oregon State University for analysis of C and using a Leco CNS 2000. For the use of this experiment, only one trial of the samples were taken, this eliminates any statistics from being used in this paper. 3. Results The dry masses of the fractions from each land-use type were quite similar (Figure 1). There was some difference in mass at each fraction but it was usually under a gram. In most cases two of the treatments were almost similar at each density fraction and only 6 Table 1. Carbon mass for each of the density fractions Fraction (g/ml) 1.65 1.85 2 2.4 2.65 >2.65 Total (g) Native 1.508 g 0.320 g 0.635 g 1.127 g 0.175 g 0.004 g 3.771 g Pasture 0.825 g 0.166 g 0.978 g 1.090 g 0.206 g 0.016 g 3.284 g Plantation Pine 1.172 g 0.241 g 0.874 g 2.502 g 0.138 g 0.022 g 4.952 g Native Pasture Plantation Pine 3 2.5 Carbon (g) 2 1.5 1 0.5 0 1.65 1.85 2 2.4 2.65 >2.65 Density Fraction (g/ml) Figure 2. Carbon mass of each density fraction for each of the treatments one treatment showed a difference at that fraction. The greatest variation occurred at densities of 1.65, 2.4, 2.65, and >2.65. Each of these densities only had one fraction that was varied slightly from the others. The amount of carbon in each fraction were all similar among land-use types (Table 1). At the 2.4 g/cm3 density fraction the plantation pine was much larger than was that of the other two treatments (Figure 2). At the 2.4 g/cm3 density fraction the 7 T able 2. Nitrogen mass for each of the density fractions Fraction N (g/ml) 1.65 1.85 Native 0.062 g 0.0152 g Pasture 0.040 g Plantation Pine 0.053 g 2.4 2.65 >2.65 0.031 g 0.055 g 0.008 g 0.001 g 0.174 g 0.009 g 0.063 g 0.069 g 0.015 g 0.001 g 0.199 g 0.011 g 0.051 g 0.185 g 0.009 g 0.002 g 0.313 g Native 2 Pasture Total (g) Plantation Pine Nitrogen (g) 0.2 0.15 0.1 0.05 0 1.65 1.85 2 2.4 2.65 >2.65 Density Fraction (g/ml) Figure 3. Nitrogen mass of each density fraction for each of the treatments difference between the plantation pine and the other treatments was larger than at the other density fractions. This was the only fraction that showed a large difference between the treatments. The amount of nitrogen in the density fractions were all fairly similar amongst all of the treatments (Table 2). There was a large increase in nitrogen in the 2.4 g/cm3 fraction for plantation pine (Figure 3). The total C and N is calculated as the sum of all of the density fractions. Plantation pine contained the most C, followed by the native forest, and the pasture treatment having the least amount of total C (Figure 4). Plantation pine had the greatest 8 Pasture Plantation Pine Native 6 0.35 5 0.3 N mass (grams) C mass (grams) Native 4 3 2 1 Pasture Plantation Pine 0.25 0.2 0.15 0.1 0.05 0 0 Total Total Figure 4. Total soil carbon at each of the Figure 5. Total soil nitrogen at each of the treatments. Totals are a sum of all of the density treatments. Total is a sum of all of the density fractions. fractions. Native Pasture Plantation Pine C:N value (g C:g N) 30 25 20 15 10 5 0 1.65 1.85 2 2.4 2.65 >2.65 Fraction Density (g/ml) Figure 6. C: N ratio for each of the density fractions for each treatment mass of N, followed by the pasture, and the native forest had the lowest mass of N (Figure 5). The forest plot had the highest C: N ratio at all density fractions (Figure 6). The plantation pine plot had the next highest C: N ratio at all densities fractions except for the 9 2.4 g/cm3 and the >2.65 g/cm3. At these density fractions the plantation pine had the lowest C: N ratio. The pasture plot had the lowest C: N ratio at all of the density fractions except the 2.4 g/cm3 and the >2.65 g/cm3 were the plantation pine had the lowest C: N ratio. 4. Discussion 4.1 Density fractions dry mass The masses of the dry density fractions were all similar for each treatment at each corresponding density fraction (Figure 1). This result was expected as all of the treatments came from the same watershed. The parent material of all of the soil as well as the soil composition should be similar as all came from the same location. These soils were all in the Oruanui series, which are highly permeable with loamy sand, silty sand, and gravel (Beets et al., 2002). These fractions each have the same mass, but the amount of C and N in the organic matter that is sorbed to each fraction is what will set them apart. Each treatment will have different amounts of C and N in each of their fractions. 4.2 Density fraction and total C The differences in the amount of C in each of the treatments can be linked directly to the amount of C that is added through vegetation. The native forest had the second highest mass of total C (Figure 4). This mass was due to the forest’s input of longer decomposing forms of organic matter. This organic matter being woody materials with high C:N that decompose at a slower rate than that of grasses. The vegetation on the native site decreases decomposition time and allows C to build up in the soil due to its 10 long turn over time. The forested site is the only site in all of the treatments to have retained pre-bomb C (Manning and Melhuish, 2001). This shows that the C in the native forest has not been lost, showing a stable C form. The pasture treatment had the lowest total C of all of the treatments analyzed. This is due to the losses of the stable C that was on the site before the conversion to pasture. The pasture did have C inputs into the system through its own organic matter but it is not as recalcitrant as forest C. The pasture soils have the greatest rates of C mineralization in all of the treatments, showing that the pasture soils have labile inputs of C and not recalcitrant C pools (Parfitt et al., 2003). These labile pools of C lead to the carbon being easily lost from the system, unlike the stable forms of carbon from the native forest. The loss of C from the system is hard to account for as there seems to be no dominant form of C loss. The lack of erosion at the site makes it unlikely that the C is being lost through erosion (Schipper et al., 2007). The grazing intensity at these sites and changes in the type of livestock grazing has been suggested as a possible form of the C loss at this site but further work needs to be done to better prove this hypothesis (Elmore &Asner, 2006). The amount of C at this site since the conversion to pasture has been steadily declining (Figure 4) and it is not known if this site has reached an equilibrium or if it will continue to lose C in the future. Studies also show that there may be losses deeper in the pasture soil profile past one meter in depth (Veldkamp et al., 2003; Lettens et al., 2005b). Losses from deeper in the profile would only intensify the amount of total C lost at this site and increase the amount of CO2 being contributed to the atmosphere. 11 The amount of the total C at the plantation pine treatment was the highest of all of the treatments. These high C values can be attributed to the high levels of litter that does not decompose readily. The plantation pine had the most mass of C at the 2.4 g/ml density fraction (Figure 2). The 2.4 g/ml density fraction indicates more stable organic matter as it is not being broken down and more tightly sorbed to the soil surface (Sposito, 1984). This increase in the 2.4 g/ml density fraction shows that this treatment has an increase in the amount of stable C that has been introduced into the soil. This increase in C can be attributed to the amount of new growth in the pine plantation. The younger pine grow faster and are putting organic matter in the soil as a result of their growth compared to the native forest which is growing at a slower rate. The use of this area for logging is another source of the stable C entering the soil. During logging operations pine debris is directly added to the soil because it is unwanted timber. This results in woody debris being buried in the soil horizons (Oliver et al., 2004). The reintroduction of longer decomposing woody debris is a stable form of C as it decomposes. The amount of these lignified residues increase with the age of the stand (Paul et al., 2003b). This site is more than likely not reached equilibrium on its C pool as it is continually being harvested and replanted. 4.3 Density fraction and total nitrogen The native forest had the lowest amount of N in the soils due to the lack of N being added into the system. The N that was added to the native forest was mostly from wet and dry deposition, with wet deposition being the largest contributor to the N at the native forest with the addition of 3-6 kg N ha-1yr-1 (Dyck et al., 1987; Nichol et al., 1997). This is the 12 only source of N for the native forest which makes it have the lowest mass of N between all of the treatments. The increase of N in the pasture was due to legumes, white clover, planted at these sites upon conversion to pasture. Legumes are able to fix N so this site had more N added to the site compared to the native forest. The combination of P fertilizer and white clover in the pasture has shown to add 140-170 kg N ha-1yr-1 (O’Connor et al., 1979). The plantation pine had the highest mass of N out of all of the treatments because of its ability to produce stable organic matter. The plantation site was planted on previous pasture site that has had N fixation due to the white clover. The N in the soil was able to be used by the pine in the plantation and converted into organic matter. Since the pine has more stable organic matter the N is able to stay in the soil for a longer period of time. By looking at Figure 3 it can be seen that the largest difference between the treatments is at the 2.4 g/ml density fraction which is the stable organic fraction. The increase of N in this fraction shows that the pine’s ability to incorporate the N into its organic matter and then make them into a stable organic form is the reason that there is more N in the plantation pine soil. The N in the stable fraction is harder to use by microbial processes as it takes more energy to get at it so it stays in the soils. As a result the plantation pine soil is able to expand its N pool in the soil. 4.4 Density fraction C: N ratios The native forest had the highest C: N ratio at all density fractions. This is due to the litter quality in the native forest. The native forest had a high mass of C and a low mass of N due to the low N inputs at the site. This yielded vegetation that had a higher C: N 13 ratio. Forest sites also have higher C: N ratios as they are made up of woody material that naturally has higher C: N ratios. The pasture site had the lowest C: N ratio at all fractions except the 2.4 g/ml and the >2.65 g/ml. The pasture was expected to have a low C: N ratio because the quality of its organic material. Pasture grasses do not have a high C: N ratio so the organic matter that they put into the soil will also have a low C: N ratio. The presence of N from the legumes also increases the amount of N at the site allowing for more N to be in the vegetation. The plantation pine had the second highest C: N ratio at all fractions except the 2.4 g/ml and > 2.65 g/ml where it had the lowest C: N ratio. The high C: N ratio at all the other fractions is attributed to the woody organic matter that is being produced at this site. Similarly to the forest, the pine plantation produces vegetation that naturally has a high C: N ratio. The low C: N ratio at the 2.4 and >2.65 g/ml density fraction is attributed to the amount of N at these fractions. As seen in Figure 2 the pine plantation has the largest amount of N at the 2.4 g/ml density fraction. This N is in a stable form and is more resistant to decomposition. This increase in N at this fraction leads to the low C: N ratio. This low C: N ratio is not an indicator of the vegetation C: N ratio, rather it shows the ability of the plantation pine to create stable forms of soil organic matter that are able to sequester N with in the soil for long periods of time. 4.5 The 2.4 g/ml density fraction difference Each of the density fraction graphs (Figures 1, 2, 3) show a similar pattern in their appearance. Each one of the figures show a spike at the 2.4 g/ml density fraction for the 14 plantation pine. The dry fraction mass shows a difference of 2.2 grams between the plantation pine and the native forest. The C fraction mass shows a difference of 1.2 grams between the plantation pine and the native forest. The C difference is about half of the dry fraction difference. Organic matter is composed of about 50% C, so the increase of organic matter dry mass at the 2.4 g/ml density fraction directly yielded the increase of C at this same fraction density. Similarly the N difference between the plantation pine and the native forest at the 2.4 g/ml density fraction was 0.11 grams which gives a C: N ratio of 10. This C: N ratio is common in many forms of organic matter. This suggest that the increase in both the C and N at this fraction is due to the increase of organic matter at this fraction. This fraction is associated with stable organics, so the plantation pine treatment can easily be seen to be increasing in the amount of stable organic matter that is being put into the soil. As a result of this stable organic matter being re-introduced into the soil, the C and N levels in the plantation pine are able to rise. Another possibility for this spike in the plantation pine at the 2.4 g/ml density fraction could be an error in our experiment. Unfortunately we did not run multiple trials so we cannot be absolutely sure that this spike at the 2.4 g/ml density fraction at the plantation pine is due to stable organic matter or if it is an error. 5. Conclusion The conversion of native forest to pasture resulted in the loss of total soil C due to the loss of a stable organic C being put into the system. The conversion of pasture to the plantation pine resulted in an increase in total soil C due to the reintroduction of a stable 15 organic C source in the Puruki pine. The loss of C in the pasture and the gain of C in the plantation is all a result of stable organic C being put into the system. This stable organic C is the reason a soil is going to lose or gain C. The increase of N in both the pasture and the plantation pine was a direct result of the planting of legumes in the pasture. This addition gave these treatments N that was unavailable to the native forest. 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