4. Improvement of CRTM Surface TIR Emissivity: In Search of a Physically-Based Canopy Emissivity Model Author: Ming Chen and Fuzhong Weng Affiliation: IMSG at NOAA/NESDIS The interaction of electromagnetic radiation with plant leaves depends on a variety of canopy physical and chemical characteristics such as leaf area index, leaf biochemical compositions, leaf thickness, leaf water content, and so on. The radiative transfer modeling of canopy is therefore challenging in practice, yet desirable for accurate canopy radiation calculation and indispensible for the inference of vegetation properties from remote sensing data. Theoretically, a physically-based canopy model consists of two major radiative processes: the interactions of electromagnetic waves with individual leaf, and the multi-scattering among canopy leaves. As our initial effort, the PROSPECT leaf optical property model (Jacquemoud,1990), together with the SAIL (Scattering by Arbitrarily Inclined Leaves) canopy model (Verhoef, 1984, 1985), were adopted into the NOAA Community Radiative Transfer Model (CRTM) to simulate the two canopy radiative processes and to calculate the canopy directional-hemispherical emissivity. Although being widely used, the original combined PROSPECT and SAIL model, also referred to as PROSAIL, was mainly applied to the visual and near-infrared domain of 0.4um-2.5um. In our study, the PROSAIL model was expanded to thermal infrared range with the construction of the essential leaf absorption spectra and the leaf bulk refractive index over the range of 0.4um-15um. Various sensitivity tests and analyses were performed with the expanded CRTM-PORSAIL model. The model physical structures and the performance with respect to various canopy parameters are discussed in our presentation. In particular, the Kramers-Kronig-constrained variational function analysis (Kuzmenko, 2005) is introduced for the estimation of the leaf bulk refractive index (wavelength dependent) from leaf absorption spectra. A group of leaf \"trait\" parameters are used to characterize different canopy types. And the biophysical relationship between the original PROSAIL input parameters and the \"trait\" parameters is formed. Although our tentative leaf absorption spectra data were collected from literatures, it will be shown that the expanded CRTM-PORSAIL model could be used to successfully simulate the emissivity of the basic forest and grass types of the JPL emissivity library. In real applications, the expanded CRTM-PORSAIL model can be used for global emissivity mapping when combined with proper soil emissivity model or soil data library, and can be used for land surface property retrieval when coupled with CRTM.