June, 2008 This month we will consider “what was new” at the SID conference in LA. Well, for one thing, our conference center was next to the theater where the final “American Idol” was taped. Walking to the conference on that day there were lots of cameras and lines of very well dressed people that looked considerably less nerdy than us in the SID crowd. A more technical note, three things stood out as somewhat new to me. These are not the result of careful reflection however, but are just what I happened to notice. One thing was the emphasis on 3D. 3D is not new at all, but the interest and emphasis on it was. There is particular interest in the 3D for movie theaters. I suppose that as 3D material is generated for movies, we might expect home equipment that could also show them, and this could drive a larger 3D display businesses. From a user viewpoint, 3D technology still has a long way to go before it achieves its goal of a generating a virtual space, so this could be an interesting area in the coming years. Another new thing was the interest in liquid crystal devices called pico projectors. These are available, for example, from Displaytech (http://www.aboutprojectors.com/news/2008/01/04/displaytech-displaysiview-pico-projector-at-ces-08/; http://www.displaytech.com/projection.html ; ) and 3M (http://www.3m.com/mpro/technology.html ) The 3M unit is shown in the picture: The main application for these is for PDA’s and cell phones where a larger image is desired. The other new thing was the liquid crystal blue phase display shown by Samsung. The pictures below are of the display and the sign below it. Samsung did not say anything about this technology demonstration, beyond what is in the picture above. The Blue phase is a liquid crystalline phase of highly chiral molecules that exists between the chiralnematic ( cholesteric ) and isotropic phases. While the cholesteric phase as a single helical axis, the blue phase has a three dimensional array of helical axes. Why this could exist can be sort-of seen by considering first a single chiral molecule represented by the vertical solid line in the two pictures below: It can be seen that if neighboring molecules would like to twist relative to that center molecule, they could do that (for example ) with the helical axis coming out of the paper (as on the left), or along a horizontal axis (as on the right). If the 3D collection of molecules picks one axis, the twisting along the other axis will be frustrated. So, what about a 3D collection of molecules where both of the twist axis shown above exist at the same time? This is what happens in the blue phase. But there is no way to have multiple axes and fill the space in a continuous manner. Peter Collings’ book “Liquid Crystals, Natures Delicate Phase of Matter” (Princeton) gives an clear description of this phase, but without going into the details there are two things that are characteristic of this phase. One is that it has a array of defects that results from locations where the helical twisting is discontinuous. The spacing of these defects can be on the order of the wavelength of visible light and can create a 3D Bragg reflector (or photonic crystal). Related to this, the phase can have a blue color, (and therefore the name). The other characteristic, is that while the phase is locally anisotropic, because of the tight multi-dimensional helix, it is macroscopically isotropic. The interesting part for electo-optical applications is that if an electric field is applied to the blue phase, the director field can be distorted and the material exhibits macroscopic birefringence. This basic idea then is to have in-plane electrodes to create an in-plane field to induce the birefringence. A display using this could be considered to have at least two nice attributes. One is that the low field state is truly isotropic, so if this is the black state it will be have an excellent viewing angle. Another is that due to the large amount of internal distortion of the 3D structure of the phase, it will relax very quickly after a field is applied, and that relaxation will be independent of the cell thickness. But there are issues. One is that the naturally occurring blue phase only exists over a very narrow temperature range, and another is that the voltage and cell thickness required to get a half wave retardation can be large. The first problem has been solved by polymer stabilization of the phase. This method is made clear in a paper “Large Electrooptic Kerr Effect in Polymer Stabilized Liquid Crystalline Blue phases” by Y. Hisakado, H. Hikuchi, T. Nagamura, and T. Kajiyama in Advanced Materials,17, No.1, January 6, 2005 page 96. But the other problem is not solved here. In this paper they give data on a 25 micron thick device that has inter-digital electrodes with 50 micron gaps between them. If I have done the math correctly…I come up with a requirement of over 300 volts needed to be applied to the electrodes to achieve a half wave retardation from the cell. So, it looks to me (if any of the above relates to the Samsung display) that Samsung has made some major advances in solving the high voltage problem. I could be on completely track about this device, but if so…this work could lead to new display modes that are very fast and have excellent viewing angle. STAFFING Bentley Wall has accepted a position with Dynamic Eye, and has already begun full time employment there. However, he will continue to provide limited consulting services to the IPP in the future. This means that ACF bonding and GCMS analysis will still be available through the LCDRF at the same high level as in the past. Also, Doug Bryant is at a training seminar (June 16 -20) related to our optical ellipsometer, so he will be better able to answer any question you have about this powerful technique. And, he will be on vacation July 7 -11. NEWS New on the IPP Web Site Videos of recent seminars can be found in the members-only section of the web site (click the yellow button at the bottom of the IPP home page). In the last issue of the IPP newsletter you were given a user id and password. We’ve recently posted the LCI Annual Report 2006-2007, which can be found at: http://www.lci.kent.edu/ipp/07/lciconnection.htm LCI News Kent State Awarded More than $14 Million to Study Liquid Crystals and Soft Matter On May 21, Kent State University announced that it will lead a partnership of eight northeast Ohio entities in a $14.5 million Ohio Research Scholars Program project to establish a Research Cluster on Surfaces in Advanced Materials. The new research center will be located at Kent State's Liquid Crystal Institute. Lieutenant Governor Lee Fisher, chair of the Ohio Third Frontier Commission, and Ohio Board of Regents Chancellor Eric Fingerhut, announced the award this afternoon as a reaffirmation of Ohio’s commitment to attracting world-class talent and better aligning Ohio’s research investments with economic development. The funding for the Kent State partnership was selected through a competitive proposal process on the basis of how effectively it related to Ohio's targeted technology/research focus areas of advanced materials; biosciences; instruments, controls, and electronics; information technology; and power and propulsion. The research venture will combine the scientific excellence in fundamental and applied research at Kent State and Case Western Reserve University with innovative approaches to environmental technologies at the Cleveland Botanical Garden and highly successful commercialization of new technologies at Ohiobased AlphaMicron, Inc., CoAdna Photonics, Inc., Kent Displays, Inc., Kent Optronics, Inc., and LXD, Inc. The significant state investment is being made to ensure that Ohio retains its top international ranking for liquid crystal technology, research, technology transfer and commercialization. Kent State will receive two endowed Research Scholar positions and Case Western Reserve will receive one. The Ohio Research Scholars Program provides grants to strengthen and increase the number of clusters of research excellence that are led by Ohio's academic institutions that support regional economic priorities. The Ohio Research Scholars Program aims to achieve this through aggressive investment in the attraction of senior research talent and related facilities and equipment, and promotion of unique collaborations needed to build and sustain scientifically and commercially promising lines of research. LCI Seminars: June 11, 2008: Prof. Yuriy Reznikov, Institute of Physics, Kiev, Ukraine, "Ferroelectric colloids in nematic liquid crystals". LCI Hosts Three REU Undergraduates this Summer Three CPIP Faculty members will be advising Summer REU (Research Experience for Undergraduates) students from June 2 through August 8. Professor Antal Jakli is advising Saba Hamidi from South Carolina State University; Professor Oleg Lavrentovich is advising Nara Lee from George Washington University; and Professor Qi-Huo Wei is advising Hannah Ainsworth from Salem College (North Carolina). The students receive a summer salary and free dorm room. They will attend weekly seminars and cleanroom training. At the end of the term each student will give a research presentation. The International Liquid Crystal Conference is June 29 – July 4 in Korea. The LCI will be well represented at this conference giving a number of papers. If you think you might be interested in anything presented at the conference, please go to : http://www.ilcc2008.org and have a look at what will be presented. If you see a paper you are interested in, please let me know and I will try to get additional information about it. Please also let us know if you would like more detailed information about the SID Conference or any activities at the LCI. Phil Bos pbos@lci.kent.edu 330-672-2511