FOREST PRODUCTS LIBRARY FOREST RESEARCH LABORATOR Y OREGON STATE UNIVERSIT Y RATE OF TEMPERATURE CHANGE IN LAMINATE D !MUMS HEATED IN AIR UNDER CONTROLLE D RELATIVE HUMIDITY CONDITION S Reviewed and Reaffirmed July 1954 No. 11434 UNITED STATES DEPARTMENT OE AGRICULTUR E FOREST SERVIC E FOREST PRODUCTS LABORATOR Y Madison 5, Wisconsi n in Cooperation with the University o! Wisconsin PA C ' :1W OF PET ERA.TIIRE . ,,• 4 'nArI' r7 LAl' I?A'Y t 7t tBERS HEATED? 1 .p IN AIR UNDER CONTROLLED RELLTIVE IRIDIIDITY CONDITIONSz. 1 r ri Iv- _..^ ../ } . ! ~., w t-I By J . D . MaoLEAN, SENIOR ENGINEER In gluing laminated timber with resin glues that must be heated t o obtain the required setting temperatures, it is desirable to have a mea~a s of estinet?ng the time needed to reach a given temperature in the inner ' d,lue line, where temperature changes take place most slowly . Informatitn on she rate of temperature change in laminated timbers is of interest in the fabrication of boat keels, ribs, and similar construction . A large amount of experimental work has been done at the Fores t Products Laboratory in studies of both heat conductivity and the rate o f temperature change in mood heated in different mediums . Results of thes e investigations have been discussed in a number of publications (1 to o),L . The purpose of this paper is to discuss the rate of temperatur e change in laminated timbers heated in air under controlled humidity con . ditors . In p revious studies of the rate of temperature change in wood , it has been found that the heating medium, as well as the temperature conditions employed, affects the rate at which the temperature increases (6) . To obtain. data, therefore, on the rate of heating under dry-kil n conditions when the humidity is controlled to maintain a definite moistur e equilibrium, a series of experiments were made on laminated blocks of whit e oak, red . oak, maple, hickory, southern pine, and coast Douglas-fir . 'Thes e blocs were constructed by gluing 6 to 14 laminations 3/4-inch thick, 4 an d inches wide, and 4 feet long .& This length was sufficient to avoid th e ei ect of end heating at the 3T id length, where the temperature reading s were taken . Dry-bulb temperatures employed were approximately 110°, 160° , and 200° to 205° F . The humidity was regulated to obtain an equilibriu m ucisture content of about 12 percent . Resin glues of the low-temperatur e pbe : colic ty p e were used in gluing the laminations . Results of these experiments showed that when the dry-bulb temper a ., tare was 110° F . and 160 0 F . and the relative humidity about 70 and 80 per cent, res p ectively, the diffusivity was about the same as when panels o f -This mimeograph is one of a series of progress reports prepared by th e sorest Products .Laboratory to further the Nation's war effort . Result s here reported are preliminary and may be revised as additional dat a b ecome available . ==nnerels in parentheses refer to publicatl ens named in the list of refer ences at the end of this paper . . .imeo . Nee L_1 434 fri the same species were heated in a hot press . The rate of heating as indi cated by the diffusivity, which is discussed later, was between 10 and 1 5 percent faster, however, when the wood was heated at a temperature o f approximately 200° F . and the relative humidity was about 85 percent . This might be expected considering the greater amount of water vapor in-the air . For example, at 200° F . and 85 percent relative humidity, the air would hav e nearly 2-1/2 times as much water as at 160° F . and 80 percent relative humidity. Three laminated test blocks, two of white oak and one of Douglas-fir , were heated at 160° F . without humidity control, to compare the results wit h those obtained under controlled conditions . It was found that the rate o f heating was somewhat slower under these conditions and some checking of th e glue joints occurred . All blocks heated in a dry kiln with the humidity controlled to give a moisture equilibrium of about 12 percent were in good condition after heating . Factors Affecting the Rate of Temperatur e Change in Woo d Important factors affecting the rate of temperature change in wood are ; the heating medium, the direction of heat travel, the density of th e wood and the moisture content of the wood . Heating Medium Experiments show, when wood is heated, that steam heats faster than liquids, liquids heat faster than hot plates, and hot plates heat faste r than dry air (6) . Direction of Heat Trave l The rate of temperature change in wood heated in the direction o f the fibers is two to three times that of wood heated across the fibers (2) . While there may be a small difference in the rate of temperature chang e across the annual rings (radial direction) in comparison with the rate o f change parallel with the annual rings (tangential direction) experiment s indicate that whatever difference exists is too small to justify consider ing these two directions separately (2) . Except in short lengths wit h large cross-sectional areas, the effect of end heating does not need to b e taken into consideration as a factor in the temperature rise at the cente r of the block . For this reason, the present discussion will be confined t o heating in the transverse direction . Mimeo . No . 81434 -2- Density or Specific Gravity In ge rer-al, heavier 'w o 's, heat metee slo'Wly than lighter woods . Although , t: e heat Cohductivi .t of wood increases with an' ine ,rease i n density, the rate of temperature- change, on the c .oitrary ., deeireases wi'th ' an increase in density . That is, the ligh'ter ' woods ; although more resistant to heat flow, will change temperature mere rapidly,, un'de'r any given heatig conditions, than the heavier woods . that are 'better hea t conductors . , For a given temperature more heat units are absorbed pe r unit volume by the heavier woods because of their greater amount of woo d substance ; this will naturally.'tend'to decrease the rate of-heating as th e density increases . The effect of density on the rate of temperature change depends t o a considerable extent on the heating 'medium, For example, its effect i s more cons-pi-eTTus with' steam as the heating medium than when 7 :1a ds ar e employed . Likewise, wood'density has less effect on the rate of heatin g when hot plates are used than when .wood is heated in liquids . This variation appearb'to be the result' of'differences, in surface resietaiO. e t o heat transmission from the, hea ++ing medium to the 'Wood in' contact''wra .th it . When liquids or gases are used ; the specific heat, rate of circulation , and similar variables 'probably have an important bearing on the result s obtained . 1 1 ' 1. Tloisture Content Previous experiments . on green timbers heated in steam and in liquid s slimed that green material hes .ted. faster than seasoned wood (6) . Above th e fiber-saturation pei :nt (about 30 percent voistuta eonten~t)• the spate of heating under any given temperature conditions was not appreciably affected b y further increases in moisture content (2, 6),, For practical purposes it is sufficiently accurate to assume tha t the rate of heating under equilibrium moisture content conditions does no t vary to an important extent' as a result .ofmoisture content variation, ove r the range of about 10 ' to 20 percent . The difference in the rate of heatin g Within these moisture content limits is .therefore not important in makin g temperature determinations . Determination of Temperature Change s Lt. Tlie rem of he :t tranend ssidn ap y spec'ifieal .y 4-6 isotropic sv,b,stances, that is, substances having the same physical characteristics an d the same properties in all di regtions : Although wood does not cio.me under ' this class ' .fication, . it does hesre- sufficient uniformity in at•u,c. x°e s o that .mathemaetical calculations ear, be applied to ddetermi the rate. o f temperature charge after experimental data have been obtained . uncles 'variou s heating conditions . 'chile certain variations from the average ' will occu r in individua l timbers, because of differences in growth conditions and othe r r: 'himeo . No . P1434 -3 - variable factors, the computed data will be withie,e' nits o f c w t needed for practical purposes . Formulas employed in d .ltulating the #rate of temperature change in rectangular seeti=s of solid . wood, will als o apply i computing temperature changes in laminated timibe`rs . of the salhtcposs-s:eetion dimensions . In the-heating of any solid, the rate of +emp,era .tre t am.ge' at a given point-depends on the diffusivityL of thee . subs znce, ,a factor that . _ nay be considered a constant over normal ranges of temperatu•re . .Diffii~t y h2 repr oentme / may be expressed by the following equation in which . the specific heat, and iZ the conduc.kileey fusivity, P the density,- e , h o In Since the diffusivity required in making computations rs dependent , on the heating medium used, it is necessary to dete-rmin .e the diffusivity _ for the particular heating conditions employed . The value determined fro m such experimental tests may, for this reason, be considered an . appa.Fent diffusivity rather than the true diffusivity of the wood . Any important influence of the glue on the rate of heating als o affects the diffusivity, Tests made on some laminated sections heated i n the kiln without glue indicated that the difference in re,suits obtaine d with and without glue was negligible for the thickness of laminations used . Diffusivity was computed for each laminated block used in the series . of experiments made in the dry kiln and the results weiaveraged for eac h species . The average diffusivity for woods heated in the dry kiln wit h dry bulb temperatures of 110° F . and 160° F, are included in table 1- .. While all the species -listed in this table were not used in thes e experiments, extensive tests made with various heating mediums (6) hav e shown that woods of similar density heat at about the same rate under th s • same conditions . It is, therefore, possible to determine the approximat e - effect of density wi_th . any particular heating medium, when experiment s have been made on woods of several different densities . This relation wa s taken into consideration . in preparing table 1 from the experimental dat a obtained . Since the rate of temperature change is approximately the same fo r both the radial and tangential directions, the average diffusivity value s given in table 1 for the respective species a pply generally to heating i n either the radial or tangential direction . The diffusivity factor fo r heating in the longitudinal d`iretti- on: is higher since the rate of heatin g 'Diffusivity measures the change of temperature that would be produced i n a unit volume of the substance by the amount of heat that flows in uni t time through unit area of a layer of unit thickness and having uni t difference of temperature between the faces . h'iimeo . 1 o . R1434 -4- n th%rats th across tO -1110espse is considera4 .Y faster along the fibers the length of ,the tim1wgrv isoo-sstuncidt .6k0twesCi4ft4 tefttomr4mOr4he effett of end heat jiOg ew,tendifteo talae.jib, agettreon whe_0poMb *nimum ratt of temperature char tp- . occur*- longkAba.nal Oefusivitmewbinvolved ' i the '• 0 temperat4rt 0QUriPeAkans tor this MEW* . . 2 It 1 P AV 'NspettelApan increrseiin theArtOte .INt.heat"Ete amount 4f water 1 o The amount oftAetitpr . Mapor required t vapor is itiAmMi4ei obtain a Mien rektive hogidity increases rapidjrloel the higher tempeaPs. tares and4ppargifty for is reasonl 41p 4AgIftsOnOWtvdetermined in itt@el , exlNiArivea4sigiisralkst tn- the higher tempwstttgr.,e (:;T.OgSt. Th.m-4ke" . period rreelde*AboRa Omen tsaperaturv At'otfzarr Pra'ssigtof:4 to . the diffutsivitIN liteviodiv when .6heo,lelVitsivity as_ .increasedi :k taAreggettP -1 age ' it r@dmotwi grgt r hooting, pe'iod 'bp take sale. L. . . 'UsisleW a Equatio (anndiNI)t :m$ used . to-AIPWridWItile tt .iZigiftitpl _ for the timbers used in the experiments . *d Cqputatiqp f. Temperature 's!-- : tr . .1 If computations of temperature are 2NIAt ,VeNT-JeUrkssurdfailfl,itMeArtkYlo :, heating temperature, initial wood temperature, and parti e a timber of given dimensions, simple proportional timoviter,oeratAum r-ela£ tions can be used that make it possible to apply the data for finding the temperature at atm. (9q ilaftt-‘P-t 't varegaes mentioned ,-*rM given IstUr! are different . - This 7:73.11 be MTr-ated -15TZ b The following factors are involved in reputing the -terdie'raturt s attained .in heating . roct'angl:ar timbers in a: dry kilzi under controlle d relative) humidity . 4 . Initial 'weed temperature . 2, Temperature of the heating medium, in this case ; the dr. ibla b temperature of the_ :-iln,. . 6 3. Diffusivity-of the wNio , L . Hedtg period . 5 . Cross-sectional dimensions (w4eteAhe eff,eet of .en1d, hettixg is be -eona4deped .).,,, neglected the length do,Q. n® t 6. Positi:dn df the paint with reapegt to the-four -ice surfaces . All of these Ddctors ore included in equakton 4 .lp,the appendix . A largo amount of tedious computations d* .ngegssaryt to .use; eqa_aat.:,On 4 for . temperature calculations . For this reason, the time-tgmpwrature curves i n figures 1 to 9 have been prepared to-make it . pQs4iblp to compute the temperature easily'-ithout using the basic equation , Mimeo . No . R1! 34 -5 - These computations are based on the assumption that the temperatur e of the mood surface is constant throughout the heating period and tha t goad, circulation of the air is maintained . It is not usually possible to maintain a constant temperature from the time heat is first applied, since some of the early part of the heating period may be required to bring th e kiln to the desired maximum temperature . Under such conditions, the heat 'period should be extended to compensate for the gradual increase i n surface temperature or, in other words, for the lower average temperatur e before the maximum is reached . When the rate of increase in the kiln tem perature is reasonably uniform it would probably be satisfactory to increas e the heating period about one-half the time needed to reach the maximum tem perature . This is assuming tha t) during the period the temperature is bein g raised, the temperature change in the wood is about the same as would b e attained in one-half the time if the maximum temperature had been applie d at the start . For example, if 1 hour is taken in bringing the temperatur e up to the max t, the heating period should be increased about 1/2 hour ove r that determined from the charts . If the temperature conditions are not fairly uniform on all su•face s and at all parts of the timbers being heated, the length of the heatin g period should be increased a sufficient amount to compensate for the tem perature difference . The kiln operator must depend on his judgment in estimating how meeh di e s=hould be taken to compere : .te fa ng the variable conditions . Charts and Formulas for Temperature-Computation s Definitions of the symbols used and a list of the auxiliary formula s derived from equation 4 en in the appendix . Auxiliary formulas are indicated by letters for purpose of reference . Figures 1 to 8 sham com puted temperature curves based on an assumed initial wood temperature o f 60 ° F ., a heating temperature of 200 ° F . aRdr ll di fti.s ty of 0 .00025 . These curves are shown for timbers having actual thicknesses of 1, 2, 3 , L, 6, 8, 10, 12, and 14 inches and actual widths varying from the squar e dimensions to 16 inches . Temperatures are plotted for the eenter of al l sizes given and are also shown for 1-1/2 inches from the surface for a thickness of 6 inches (fig . 4) and for each inc h aitnterval from the surfac e to a depth of 4 inches in timbers 8, 10, and 12 inches thick with width s up to 15 inches (figs . 5, 6, and 7) . Figure 9 shows . the computed tempera ture at the center of square timber dimensions ranging from 2 by 2 inche s to 18 by-18 inches in cross section . Examples illu t•atT g the use of the figures show how temperature computations can be made fow :intermediat e thicknesses . In determining the timber dimensions it is necessary to ad d the thickness of the wood cauls as both the width and thiehAess 1ff%,,a+t th e rate of heating . While the cauls may not always be of the same specie s and hence may 'not have quite the same diffusivity as the matewi]y Wf, .g glued usually the effect on the rate-of heating :does net require . arz special consideration . If the cauls are thick In proportion to the, electio n being glued the lamer diffusivity of the two woods should be used iz com puting the required heating period to insure an ample time allowance . •, Mimeo . No . R10I -6- When the width and thickness of a timber are not the same, the temperature will always change more slowly along the transverse axis perpendicula r to the wide faces than along the axis connecting the narrow faces . For example, in a timber 6 by 12 inches in cross-section, the temperature chang e takes place more slowly at the mid section along the 6-inch axis connectin g the faces 12 inches wide, than it does along the 12-inch axis connecting th e faces 6 inches wide . The temperatures given in the figures for points betwee n the center and surface are therefore temperatures at distances measured alon g the shorter transverse axis and apply for the portion of the timber wher e end heating does not affect the results . Under commercial conditions, desired information relating to tempera ture changes in rectangular timbers will be either : t (1) The time Tb required to obtain a given temperature Ux at some particular point or , (2) The temperature U x when the heating period Tb is given . Only a very simple computation is necessary to use the data plotte d in figures 1 to 8 for any particular heating conditioA and for any species having a diffusivity different from 0 .00025, that assumed for making the temperature computations . To avoid the arithmetical calcula tions for finding values of Ux or U (as indicated in equations U1 and Cl appendix) figure 10 was prepared to make it possible to determine thes e temperatures directly after connecting the initial wood temperatures U a , and the heating medium temperature Ub , with a straight edge . Method of Using Figure 10 In this figure the initial wood temperature Ua and temperature Ux ar e read on the vertical left-hand scale . Values of Ub are read on the vertica l right-hand scale, and values of U are given on the bottom scale . To use the chart, place a straight edge connecting the given initial wood temperature U a on left-hand scale, with the given heating temperature Ub on the right-han d scale . This is illustrated in figure 10 by the full line connecting th e initial wood temperature 60° F . and the heating medium temperature 220° F . and also by the dotted line connecting the initial wood temperature 75° F. and the heating medium temperature 200° F . -.assume, for example, that the initial wood temperature and heating temperature are those connected by th e dotted line and that Ux = 180° F . To find the corresponding temperature U , (any temperature obtained from the figure for the timber in question) pas s horizontally from Ux = 180° F . on the left-hand scale to the intersectio n with the dotted line . Directly below this point, the temperature U is found on the bottom scale to be about 177° F . If U is known and it is desired t o find Ux read upward to the line connecting the two temperatures and find Ux on the left-hand scale opposite the point of intersection . For example, again using the dotted line assume U = 155° F . Opposite the point of intersectio n directly above 155° F., Ux is found to be about 160° F . Mimeo . No . RJ L alt -~7 - .1 desired at a part .c l r poet , a timb p.-r- err-h n theg is Ua and the hating ~nedYt- temperature is . .Ub, the f ow' be used . Determine temper .ti e U by• 'm &ns . oaf equatim-(C 1) ie using figure 10 . From the prig er fie- (f 1 tea ) ttrlktl gtestion ; find the hating pgp'' :r°'1r'ta-ch~ hemp rn tie T, fcl' } . required poet. Determiner bit 41figure, by the factor P' taker Mee tabs. 1, $g.y, .the s considerat0, To find w per twh kvsl.tirajg% Tb by the factor F, taken from table 1 for the _ _ . iod !I _ de _is g si., l orc T ( find the corresponding heating period T . In this case T Tb . ' F s . c)~~~~,~' . Find, from the proper figure, (figs .. 1 to 9) the temperature U after heat u. for T ho w, ..peterm e the t er-at'gx g (C1) appendix, or figure 10 . v. -ll Exanip1-t Data give n Dry-bulb temperature - - 175° = Ub Initial wood temperature r• 70° Cr tt al . nensi 8 by .11 .5 it hw,s _ 'Sprc ies ' -- . white Ua r cl•tIcl , ino ,udg . .eki't . .~ . . oak -t_ Y Require d Find heating period needed to, obta 17:0,° F . at .the _cente-- , n -a tLemy.O±Ett ure - Solutio n U., . From equation (C) or figure lcL f old the c, using equation (C 1) r U 9BO T r 170) (l40) , _ 200 - L 7 ,or about . 113 a r Ji L1 Zf figure 10 is used place the straight edge on%VO° .,' 1-eft-hay ~ on 175° F . right-hand scale . From 170°, the requi0od roper u Mimeo . No . Rl434 , , , 1. ' left-hand scale pass horizontally to the line connecting the tempertb.le s of 70° and 175° F. and read the temperature U on the bottom scal e found to be but 193° F ., the r. ate+ obtained rasing equa :t a tem ratur•e", , _ FirIA from figure 5',4 d to red -Vbilroe.i ;'of a t. fiber ~ 193° , F'os'flit 4 nter `lf' ' die's ' i om the surface " a' $ X «' usivity ,inehes'f• 't sound to be about 19 .5 hours when t1d " • ("OM is 0 .00025 .0' . -,= : r:+=+-:_ w 1 -1 ' 1 Sine.E'"table 1 shows that F = 1 .25 for oak, the time T found from th e chart-must be multiplied by 1 .25 . 19,5 x 1,25 z T b 24 .4 or about 24 . 5 hours, Tip Yieat~i p4rio'd• nee l,ed'' to obtain a temperature of 170° F . at th e center cf a timbe 8-by 14 .5 inc'hes'. Example 1 b Assuming the . same timber and same, heating colditi~ rs as gen in. cl- from one , of the . example l a , find t`fie -temperature . at a distance of 1 surfaces 8 inches apart after the timber has been heated for' 14 hours . Since 14 hours = Tb , the corresponding time T, to be used in finding th e temperature U from the chap' ). 14 +I .25. 11 .g .zhours ' .t• .-Tige,te pegeatur e ' J obtained,At, .1 my from thrf_e he, from f gure t to te ' aoou;'' ~.d V. ~ e, .• equation {B1) or from figu?e 10 . Using '{ e uation (Bl ~ Ux l7~ = 16 6 This can 'be' fo.pIrITI - bm f't'gu tk* ' by placin ►klt 188° F. oi' in exa i l-e a Te din u r -tr 70° and 175° F . ' i'e-gM` !r y''i b tip across from the point of .i €,01oni.;. . the temperatures PC. by using' equation TB") . • and Exa mpie. 2 ~, D-ter gi ve•'x . ~~ :` •.~ . ©m scale t i -hand scale_i ocnetig it 16'60'. T 1:1' tit* -aft I 'mt . ' , q ;' • - '; k t, . i ~ti I T . 11 . : ,:r .11. u" •- + - :''t" -T Dry-Ibul'b+ tempe'ratu .ne a' PM " F. `l ilI-i ,. i •• + n F . =' Ua .,r ) .:` -auk e: '} ~7 e . .. . . t ,,o p diiYhes includin g CI no .vifi p!6 7 to. al dim thickness of cauls . • 't • l r1 r.fmi -. . ~~ • .•• In+ati~l wood temis,~ ' r .sll , Speel,rs fShoast UQ r .~ ter, -1 . I - , .! imeo . Trio . 'R143 4 I C L -9 :,. Require d Find ho g period necessary to c tAtn 190° F . = (Ux ) at the center. to .erat a of . As previously explained, whew, the dxxyw u.lb temperature is betwee n 180° and 200° F . the .dif iv`ii - g n• ix-table should be Increased eimat 10 percent, since the rate of heating as indicated by the diffusi v=ity, .i a somewhat faster in this higher temperature rage, apparently because of the greater-amount of water vapor in the air . From table 1 the diffusivit y for Douglas-fir, for temperatures below 180° F . is given as 0 .00022 . Tao creasying. this by 10 percent gives 0 .000242 . The factor F (last colum n table 1) would then be 0 .00025 + 0,000242 = 1 .03 ap proximately . This faqi r is the same as would be obtained by dividing F = 1 .14, taken from table 1 , by 1 .1, In this example it is necessary to interpolate for the thickness o f 6-1/2 inches which is between two thicknesses for which temperature compu tations have been made (figures 4 and 5) . This can be done by first find ing the heating periods required for timbers 6 by 8-1/2 and 8 by 8-1/ 2 inches . As in example la , the first step is to determine U by using eithe r equation (C1) or figure 10 ap illustrated in the preceding examples, I n this caste U is found to be about 191 0 F . The second step is to find from figures 4 and 5 the time T require d to obtain a temperature of 1WJ° F . at the center of a 6- by 8-1/2- and o f an 8- by 3-1/2-inch timber . From figure 4 the time T2 required to reach a temperature of 191° F . . at the center (5 inch from the surface) of a 6- by 8-1/2-inch timber- is fend to be about 8 .75 hours and from figure 5 the time T1 required to reach this te:rterature'at the center of an 3- b y 8-1/2-inch timber is found to be about 12 .5 hours . The difference in thickness of these two timbers is 8 - 6 = 2 inches and the difference in the heating period required to obtain the same timperature at the cente r is 12 .5 - 8 .75 = 3 .75 hours, The timber 6-1/2 by 8-1/2 inches in cross section is 6-1/2 - 6 or 1/2 inch thicker than the one 6 by 8-1/2 inche s for which the required heating period was found to be 8 .75 hours . Dividing 1/2 by 2 gives 1/4 . The heating period required for the timber 6-1/2 b y 8-1/2 inches in cross-section would then be computed as 8 .75 plus 1/4 (12 .5 - 8 .75) = 9 .69 or about 9 .7 hours when the diffusivity is 0 .00025 . Since the time 9 .7 must be multiplied by 0 .00025 + 0,000242 s 1.03 the computed--heating period Tm needed to obtain a temperature of 190° a t the center of the 6 .1/2 by 8-1/2 inch timber is, for the conditions given , (9 .7) (1 .03) = 10 hours, approximately , If in the foregoing example the dimensions were 7-1/2 by 8-1/2 inche s instead of 6-1/2 by 8-1/2 inches the required heating period would b e Mimeo . No . 81434 -10 . computed as 8 :75 plus (?~ _ (12 .5 - 8030 * 11 .5f. Sours. MultipT ing this by 1 .03 gives 11 .9 hours required te reach - . #ernperatKTe of• 190°F . i n the 7-1/2 by 8-1/2 inch coast Douglas-fir ;ri .bens I44ermarple 2•-it is - • assumed that the difference in heating wefiod required f'or•the•intermedia E :_ . in th i• thickness p prop_ortioKj.1,~to the diffe r ence in hmerng periods reed for't . i Expressed in terms o ness of a timberlint.ermedi another havin { a ste: lie r • W a have the t. sam- wv .` iWI r temperature at a given .r . of the timber with a thickness rm'wou i.e~l f'i ' Dm - D2 T2 + ( DDm D ) (T1 - T2) v litre T1 is the . time fegnz1'e 4 1 2 temperature Ux al :-+e sane-'proportional 4,0xeVAOrlknes s DI and T 2 Is the tome required to obtain IMILiAirnIgIVAMSTilOtel'Milme Proportional distance in the timber of I ti''t? g oZ ~► ~:~, 0 ` This is illustrated in example 2 where Dm = 6-1/q ; 40 . "°1t„ ' D 2 ^ 6", T= 12 .5 hrs . and T 2 = 8.75 hrs . The width of all three timbers is the sayte, 8-1/2" . Similarly for the timber 7-1/2 x 8-1/2 inches i n cross-section Dm = 7-1/2 inches while Dl, D 2 , T1 and T2 are the same as in the first computation . Humidity Curves iT ,s R they el tive .Figures 11 and, .12 are added fat mtveni ppice , in,i;i-acl humidity required to obtain any give r 1 .equiflibriu4a moist ;e •F ontel.: ori t o find the required wet bulb temperature for a given relative humi1 7 aridr dry-bulb temperature . Figuur sho is the i*elati'dn sof' :' 'qu-i~lib S i i Sri®e~~4tu' ® content, dry bulb tem p erature and relat4T'• hui irdi j4•ari figur di jsbiowff ., . aa1btt-, eratu sJ4 ., ' ' the relative humidity for different wet ! aVaddl APPENDIX _a ,4 - ~ , iiFormula Used For Computing the Rath of Te-3 ayture Ch i . tl r Rectangular Timbers Surrounded by a Heating Medium at'C tenstant 'Te 'n erature • . If h2 repre 'tints the diffusivit,y i, the ,rajSal direction .'.o the diffusivity in the' tangential direction and q', . time diffusil- ty in the a<'ime o . No . R1434 -11- longitudinal direction, the change of temperature in a timber woeId t e expressed by a partial differential equation in the general form , 5U 6t - 52U 2 5x2 + k h 2 62 U 5y2 + q 2 5 2U (1, z r In this expression U represents the temperature at any point thin th e timber and t represents the time heat is applied . If the length,of the timber is assumed to be sufficient to pre Ven t end heating affecting the tefl1 tature at ' the mid length, where temperatur e changes take place most slowly, and when for practical purposes the tan ^-ential dif fusivity = 2 may be assumed to be the same as the radia l diffusivity h2 , equation (1) can be written , U 5U = h 2 I52 ` rb' 5x2 62 U 77d (2 ) In order to compute the diffusivity or the temperature changes i n timbers of various cross-sectional dimensions equation (2) must be solve d subject to the follauing boundary conditions : LetZ=(U--U I ) U=U0 whent = 0 Z = (Uo - Ul ) when t = 0 Z = 0 when x = 0, y =0 and t 0 x=a, y=b,i In this case U is the temperature at any point (x, y) in a trans verse section of the timber ; Uo is the temperature of the wood before hea t is applied ; U1 is the temperature of the heating medium ; x and y are dis tances from the coordinate axes at x = 0 and y = 0 ; a and b are the cross-sectional dimensions of the timber and t is the time in seconds . Substituting Z in equation (2 ) FZ 6t h2 2Z -6 : x 2 &2Z 8 y2 (3 ) A solution of this equation to meet the boundary condition$ gives, cc Z = Z 2 n 1 n=1 Am, n .Mimeo . No . 81434 sin m sin .. b e -12 - TI2 h2 t (a2 + ~2) . where Am,n is the definite integra l ab a .fb f( 00 X ,fL) sin k ma sin b µ• d~ d u when f(k,p.) is a constant and equal to (U 0 - U1 ) a.s in the heating c tions assumed, 4(Uo - .U l ) iri ab 4 (U o - m: sin nb N• dk dp. .n TJ '-&a cos riTfr [1 - cos m Tr mn7r2 16(U o - U TI 2 MI when .rrj Apt", yie,•ztefg i1 e h odd, ant 0 w. we 7. + 1 sin a sin sin 3bY e sin 5a + 1 sin 7T sin be by e + 1 sin l x s in be a in 7rxa + 71 sin ±' imeo . ho . 81434 sin 77rv e b 7T 'o r rhrs est .Th~. ! st few te'nv the„ , ternpe-,a-tuxe.•II at any Pgr{,x,Y)E Ptn r be written, - J ., , . tiny; flat , .` . . . ape? - t may th . 7T 9 ) 2 h2 t 2h2 7f•t b 2 25 2_ + 'b (a b2 - -T2 h2 t (a2+' 25 b 7T2 h2 t (ag + 7r h2 t (12+ a -13 - 2 1 ) ) 49 ) b +• • • (4 ) geimaddion ( covert b ze that 'we mom verg r- secttea l c r' J -t i esw A1* valves tee , a and s> se' sand okly a ns as n led heating periods . It may be noted t is large amd also $I the cro gsr since t le e1 eI ( * _. a dr tions are Different frtse Data for Time-tem I ~; r : 1 ting G -- . I .qua .® The equations (A) to (C) are relations derived)* - + show the relation of time and diffusivity and methods ofg thwltmg the These weed b e tove wee . t tke lieat; r s• t orPesPoaA*ng *' from tVtWe wetted ice' dORPWM the data for IOW temp in the fig es . ' Syg*p Used ' vO strat3 LqEdggrCalfirotAwt - @Np at' I la '~ 91ying to comput9 data (figures 1 to 9, inclusive ) -e . U0 = Initial wood temperature assumed as 60° F . Ul = Heating medium temperature as,su ed . h2 = Diffusivity ab U ed a ZOO' F . Q0 O9025 (s quire inch per second) . t at acmes :o . toter distance from the su&faee . Values of U are temperature s Temperature obtained in a givcm ti within the wood at ttld, ; astance from the surface shows by the figure . . " T = Time of heating (im, hours) nece ary to obtain the .tern ate * U . This period of heating is determine d , frem the fiiguie Se the timber under consideration* Mimeo . No t R143)4 -14, S, bo1s Appiring to 'T'ece!'-)e'rathiee CVnIputatibi-isl''.1hen Diffusivit , . , . Feating end', or'anth" '' are Different from Those Used n. Computing Data Plotted in Figures 1 to 9, Inclusive a-a- - - w6od 't-enperatu p i ; ,r Ub = Any heating medium tem.perature i. - r. l*#I , ado, .voiOlie' .of . .. , di ffafS. ivity'astaumerl fioe'a 41ee wood , ,( sepla,r-piitt a per second) . Temperature obtained at. a clefiNe .te point in the timber whe n . the WO..Qd temr2taturd .ta, the heating temperature Ub , or both are different , from U o .= 60 0 and. U l 200° .F ., th e Ux initial wood and' iaelItt'Lug .meditlm temperatures used in eemputin g the- curve - ehO Wff -iri. - the figure's& ' Tb .7; Time of heating (in hours) required to obtain the temperatur e Uwhet: either thedi.ffusivItT. h , the initial woods femp .epa e tare Ua , the heating medium. ter,7)erature Fboner all til.'ree variables are different frc 60 0 , U l 200° F ., and 0 .00025, the valuer used in computing data for the curves . The relation of the heating period T and the heating period T b i s readily determined from the actuation, T, (h2 ) = T ( 0 . : 0 0 2 5. ) . ' --- ---- -1,1,, (A ) In -LI-Le expression T is the computed heating period found from the . figur e for the timber in question, and 0 .00025 is the diffusivity ces,sume .d in ma'-inc the cDoputa.tions .. Tb - is the heating period. to be determiaerf,eo r -vhich, is assumed when the wood has a diffusivity Values of h2x for different species are given in , ' ean be readily shown that the relation of the tempe,ratures U and ; U j assumed in compalting the- values ;. of U pl .otted in . the figures, anti =an y other wood' arLd heating med.im temperature U a and . U b is expresse d by the equation , -1 . U = Ux b I I (U b e U 9. ) ( TT ' - ' o ) -where Ux is the temperatu r e obtained at a particular distance fronii th e sua . 'ace when either ;U.o: i Ub , or -both are differerA -far and U I ‘ Yi1neo . -Ko . R14-34 7hen Ux is assumed, it is necessary to salve for U to dete .rmin e the heating period T from the-proper f-igure . . -Solving for U tn equation ( B) gives, (Ub - Ux) (Ul "( U'b ' - Us ) (C ) - - . Since in computing the time-temperature curves shown'in figure s I to 9, inclusive, U0 was assumed as 6 00 ar'd U1 'al.-20 00 '. ;` subs:titlittin• these numerical values in equations (B) and (C) gives , Ux U U,~ 20 .- (Ub - Ua ) (200 - U) I f , 140 -T(Ub .- .- ux) .:,(140).l . T .. •-- (B 1 ) - (Ub - Ua) Values •e' U and U can also be determined by means of figure 10 a s x explained in the text . 1 ! a Reference s (1) MaeLEMI, J . D . 1930 . "Studies of heat conduction in wood -- results of ; steamin g ' green round southern pine timbers , " Proc . A ."T .1i. , pp . 197-217 . (2) (3 ) 19'32 . "Studies of heat conduction in wood -- Par 'II ---Result s of steaming green sawed southern pine timbers," Pzoc . pp . 303-329 . 1934 . "Temperatures in green southern pine timbers after variou s steaming periods," Proc .. A .W.P .A., pp . 355-373 . ( 4) 1935 . (5) Mimeo . " Temperature and moisture changes in coast Douglas-fir, " Proc . laseST .P .A ., pp . 77-103 . - ' 1936 . "Average temperature and moisture .reduction- calculations for steamed round southern pine timbers , " Proc . A .W.P .A . , pp . 256-279 . . R1434 . ;i (6 ) ( 7) Mac LEAN? , J . D . 1940 . "Rela t. ion of wood density to rate of temperature change i n wood in different heating mediums,'4 Proc . A .W .P,A . , pp . 220-248 . 1941 . "Thermal conductivity of wood," Heating, Piping and Ai r Conditioning 13(6) :380-391 . - (8 ) 7 - :_ --, .,- - 1942, "The rate of temperature change in wood panels heate d between hot plates, " Mimeograph No . R1299 of the Forest Products Laboratory . (9) 1943 . "Method of computing the rate of temperature change i n wood and plywood panels when the two opposite face s are maintained at different temperatures," Mimeograp h r No . 81406 of the Forest Pro4.uats Laboratory . w ,r . -*-. -- + 1• ~.. . w - -~.. - .I nA Mimeo, No . R1434 _17_ r Table 1 .--Average diffusivity factors determined from experiments in th e dry-kiln with the humidity controlled to dive equilibrium moisture content conditions of about 12 percent, and fromother data . (For moisture content range of about 10 to 20 percent and dry-bul b temperatures up to about 180° F . ) Specific gravity range (air dry wood) 0 .4 0 to .5 0 Woods tested t Other woods of Average ?t similar specific : di.ffu s; gravrity sivity facto r • hx Facto r F ?. 0 .0002 5 :Port Orford `white- : 0 .000220 : cedar, eastern : redceciar, _hemlock, : :mahogan y :Douglas-fir hx 1 .1 4 .50 to .60 :Southern yellow :pine Blackgum, black walnu t .000210 : 1 .1 9 .60 to .70 :Red oak, white :oak, suga r :maple, hickory :Ash, yellow birch .000200 : 1 .2 5 . -The factor F will be found convenient in finding T b where T b (hx) = T(0 .00025) . This is shown as equation (A) in the appendix . From this equation T b - C .0002 5 25 (T) =FT or solving for T, give s T = Tb The diffusivity values. hX should be increased about 10 percent fo r dry-bulb temperatures between 180 0 and 200° F . and about 15 percent for dry-bulb temperatures over 200° F . The factor F should be divide d by 1 .1 when the diffusivity is increased 10 percent and should b e divided by 1 .15 when it is increased 15 percent . Pimeo . 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N/ 3b'nl d8.d/N.71 0 N t- at N TEMPERATURE /2 /NCHES FROM SURFACE 200 TEMPERATURE 3 INCHES FROM SURFAC E ■ W.-MM alai 01■■■■■ =I =I /2 HRS. = sum 1/ /90 /o 9 k /80 8 EMS= 'M 1■\■■► SIN ►I■■\■■■CI N 6 ■\■■■■■■■ ■ ■■~■■■■NI•• ■ k /7 0 to /6 0 /50 Lk, /40 ■■■■S SA■■ N■ ■■■■■■■ LIMEM11■■■■■ ■ SI= MI5 UN I= ■►~■■■■■■rt e4 ■■■■■■■■■■■ =► .■■■■■■■ ■■■I-=BEM-© ■■■■■■■■■■■EMIRS W.■ 11 •1••••11••• M =MI 9■ ■ ■ ■ _i■ ■ ■ ■ •••■■■■■■■~■\ .■■■■■■■■ ■■■■■■r■rE0■■■■SLIE . ■■■■■■■■■■■~■■■■■■■■■ ■ ■■ ■■ ■■■■■■ ■■■■■■ ■ ■■■ ■W ■■■■■■■■■■■~i■■■■■■■■■ ■ E RIN1 ■■■■■■■■■■■___• 60 ■■■■■■■■■■■~■■■■■■■■ ■ 6 /2 /4 8 /0 W/DTH (/NCHES /6 6 8 /0 /2 /4 /6 . WIDTH (NCHE$) Pignre 4 .--Temperatures at center and halfway between the center and surfaces of timbers 6 inches thick, after various heating periods . Temperature of heating medium, 200° r . ; initial wood temperature, 60° 7 . ; diffusivity, 0 .00025 . 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N N N AMPr~ AMMIOM ,■,I■K.■II■EEM E O °a h * ■Ca■ ■■ r r„I,I,IE .FNN■.,,■!..■>•I■■II■■■■ ■ MEE= EEO ■1/1NI NBUIPIRVAOMMIW/■M■■IM■■■■ ■ rllMAIE■AW■■%I IN%■►I■r1■■ IENIMI ■ 1WANNWRi glINVAM/ rAIMMIOW11WAIMEME11 ■■■■■■■■■■■■■■■■■■■■■■■■■■■ ■ ~e!~©tiIUI!II■■■■■ n■IIiii MIAM MINIKIDI■!■■i■■■II■■■■■■■ ■~~,ir~~~~rMBWA11 ■MEMEI ■MI■■■■■■ ■ ■ltIM ■MI►IWIV1■ IWINL■■l,■■N■■■■■■ ■ E1NI/►III ANA NI/■II ■r1■NI NI •M■■■■■■■ r► ■.MEWA■■.A■■■■■■■■ lIIIIIIIuIIIIIIIu'IIIIIIu I ■l I'r IMNIO"M■11■■■■■■■■■■■■■■■ ■ ■rr!'iiv .~i►ZIMMI■nn■■■■■■■■■■■■■■■ ■ N O O n U • O O O -'n N (do) .Va/H1 SgH2N/ O/ S8JPW/1 aim O O O O 41 °O A/I 38/7162Y3dW31 O N O 200 TEMPERATURE //NCH ' FROM SURFACE TEMPERATURE 2 /NCHES FROM SURFACE TEMPERATURE 3 /NCHE S FROM SURFACE TEMPERATUR E 4 /NCHES FROM SURFAC E P-1111UI24H,7 MIIIIM• dPl .■■■■■ .■■■■■ HRS -saN`5 30HR /9 0 -~`~ o.Almim!ml 16 RSStgi EB C ■ ■,~~~ 2 ,~'M 2 /80 EMIR ■■MSC ■■\\N E 6 ■■LIU M .11■■ e■■~•~■ ■■,■ER ■■MO ■■r■■■~■~\ /o ■■■\U■ '4 ■-■\■■D ■ __:::i■ ■■■■MN ■ E011■©■■~S■■■■■■■S9 ■■■■■■■■■■■■■■ ■ .•■e■■■\S■■■ ■■■■■■ ■■ 5rn ■■■■■~■■■■■► ■ ■~-• ■ 1b 8 26 22 a,:'--►►~►r+ 20 ~~~ ~ 20 i°■_ - /B l4 ■■■■■■__■:::o■~ :::m: ■■i■■■■■■rr0■■►`■■■'° ■■\■■■ ■ ■ ■■■■■■■■■rru■■■■■■■■■\\■■■ ■ ■■■■ ■ ■■■■■■■ ■ ■ERIE■■■■■••■■ ■■■■■■■■■■■■■■■■■r ■■■■■►n ■ ■■■■■■■ \■■■■■ l0 ■■■■■U■■■■■■■ i■::■■©■ WNWo■■ ■■■■■■ ■■■■■■■ ■ ■■■■■■■■ ■■■■■■ ■■■_o■ ■■■■■■ ■■ ■■■■■■ ■■■■■■■■ ■■■■■■■ ■■■■■ ■ ■■■■■■ ■ ■■■■■■■ ■■■■■■■ t■■■■■ ■■■■■■■■■■■■■■■■■■■■■■OM111 . ■ ■■■■■■ ■■■■■■■■■•■U■ ■■■■ ■ 70 ■■■■■■■ ■■■■■■■ r~■■ ■■■■■■■■ ■■■■■■■■■■■■■■■■■■■■■U■■■ 2 ■ 60 /2 /4 /6 •W/DTH (INCHES) Z M /2 /4 /6 QNCHES, /2 ./4 . /6 WIDTH QNCHES) /2 /4 /6 WIDTH INCHES) Figure 7 .--Temperatures at distances of 1, 2, 3, and 1 inches from the surface s of timbers 12 inches thick aftbr various heating periods . Temperatures of heating medium, 20 00 F. ; initial wood temperature, 60° 7 . ; 48975 F diffusivity, 0 .00025 . \ r. S h MAIME1111211111111111111 V (7) J/7/H1 S3H)N/ */ S y Jg '/1 02M v.c N/ 2b'n1Va'2d1-V21 c( q~ ^1NNN N N IIIIUWIWIUMIIUHVAI!1iIi ~^1 rniuriururnuri ( .)w7/H1 SJNON/ Z/ S 7GGV/1 02A/I'S N/ 28/)1 b'6JJdG3J1 sO 0 N zoo /90 /80 s -o /70 /6 0 i MIM MM. MMOLI IB =KIM /6 OO .IOMW I~~ zd =1=11WIMIMMOOLVIMMMIO N ■nu__nr■MIM►INNIN EMI 1111M==IZIM M „-I-I■.L-=■11== ►UL kk 6 8 22 Zp /2 9 -w\\IMM.` M InINIMOMM /00 90 80 70 " 60 ~~►~~~ ~ __LW 2 MI M11MVIII.WMMM■MI . 1•11 . MI10IMUSIMMMi'l 9 /0 // /2 /3 /4 /5 7 8 SQUARE CROSS-SECT/WV D/MENS/ONS (/NC/-/E5 ) 3 4 5 6 /6 /7 /8 Figure 9 . -Tempevatur;Qs-ait_the center of square-dimension lumber and timbers ranging from 2 by 2 inohes'to 18 by 18 inches in cross section, after various heating periods . Temperature z M 46977 .E of heating medium, 200° F . ; initial wood temperature, 60° F . ; diffusivity, 0 .00025 . 264 ■■■■■■■.■■■.■■■ .■■■■■■■■■■■■ 270 ■■■■■■■■=M■■■■■■■■■■■■■■■ ■ 270 ■■■■■■.■■■■■ ..■■■■■■■■■■■■■■ ■■ ■■■. ■ ■ ■■■■■ ■■■ ■ ■ ■■ ■ ■..■ ■■■ 260 280 260 250 240 ?30 22 0 2/0 j 200 ■•.■■■■. .■■.■■■■..■.■..■■■.■ 250 ■■.■■. .■■■■■■■■■.■.■■■.■■■■■ ■■■■■■■.■■■.■■■■■ ....■■■■.■ ■■■ ■ ■■ ■~ ■■■~ ■ ■■■■■■■.■ ■. ■■. 240 ■■■ ■. .■ ■■■ ■■. ■■■■■■ ■■■■■■■■■ 230 ■■■■■.■■■■■■■■N■■■■■■■I . .■■■ ■■■...■ .■■■■.■■■.■■■■■■■■.■ 220 .■■■ ■■■■■.. ■■■■ ■ ■. ■■■■■■■■■ r ■■■■..■■■■■■■■■■■.■ .■... .■, . 2/0 ■■■■.■■■■■■■■■.■■■■.■■■.■ru■ ■■■■■■■■■.■■.■■■■.■■.■■.■■.■■ ■■.■■ ■■■ ■■ ■■■■ ■ ■ ■ ■■ .. ■■■ii■■ zoo ■■■■■■■■■.■. .■■■■■■.■■wI■■0. /so ' .■.■■■■■■C■■.~ .omoral ■■ .E■■■■■ ■. .■.■■.■ ■■■■■■■■I..a■■■ K /7 0 .■.■■■ ..■■■■■■■■:■. .iIS..■■.■■ /60 MMUS E.= A /5 0 R ■■■■■■■■■ ■■■■■Ila■■■Y■■■■■ ■ j /40 ■■ .■■■■■■■■■■■ i u.■■N■..■.. ■■.■■■■■■ .■■.IGi■■■■■■■■■■•■■ o ■■ ■■u■■.■■■rM .■■■■■■■.■■■ /3 j ■■ ■■■.■..■r..■■■■■■■■■■■■■■ ■ • /20 ■■ ■■■■■.D'■■■■■ ■■■■■■■■■■ ■ E ,zz' /9 0 ttl /8 0 ■ii■■■:::■:■i■■i ■:i:Eii■iii _::::::::::s..= ■■~~::iQI•••••• ■•u••••u•• ■■■■■■■I■■■■■■■■■■■.■■■■■■■■ ■■■■NM■■■■■f .~■■■■.■■■■■■■ nnn.■r...■■■ n nnnnnnnnnnnnn 3 ■WEN=■■■■■■■■■■■■■■■■■■■■■■ W 1, // 0 /00 90 ■Ei.■■.■■■■..■■■■■■■.■■■■■.■ ■'r■■■. ■■■■■ ■. ■■■■ ■■ ■■ ■ ■.■■ ■.■ ■ ■■MNI ■■ ■■ ■I.■■■■■ ■■■■ ■■■ M■■■U■•■■■.■■■■■■■■■■■■■■ .■■ ■■■■■■■■.■■■■■.■■■■■■■■■■■■ ■■■■■■■■.■■■■ .■■■■■.■■■■■■■ ■■■■■■■■..■■■..■.■■.■■■■■■.. ■ ■■.■■■■■■■■■■■■■■■■■■■■■■■■ ■■■■■.■■■■■■■■■■■■■ .■.■■...■ ■■■.■. .■■■■■■■■■■.■■■■■■■■■■ ■■■■■■■■■■■■■■■■■■■■■■■ .■■■■ EKE= EN• p••■■■■M•■■■■■■■■■■■■■■■■■ ■ 60 70 80 90 /00 //O /20 /30 /40 /50 /60 /70 /80 /90 200 U TEMPERATURE (•4) ng tteemperat uurere UUa, whenthe Uheatis ingigvenmediorum tetmperat uurere U8bwhen )Sgurs 1O.--Ohart forgiven,findiwhen ng thethecorrespondi initial wood mperat e mperat 0. i s Z M 48978 F or both are different from those assumed in computing the plotted temperature'. J 8o 70 60 50 4o 30 20 /0 32 3/ 30 29 28 27 26 25 X24 oZ C~h e 3 22 Wz/ 20 1111 1 1==l EMI= ~=MINI_= _11EMI1■.11=1MI~-- I =NM= ``MMUEEN /00 /9 °QC/8 44I W /7 /6 Ko/5 4, 14 iz) /3 MN=-=■l _ =M I 11M-M11MIRI~EM-=-■•_`M=1 ■111='.Mu~•11`_ 70 5 4 3 2 1=1 =~~`=EPm.`M`MMI P. rf) 40 30 20 60 70 80 90 /00 //0 /20 /30 /40 /50 /60 /70 /80 /90 200 2/0 2/ 2 DRY BULB TEMPERATURE 4 Figure 11 .--8elation of dry-bulb temperature, relative humidity, and equilibrium moistur e content of wood . Z M 48979 F IIIIIMMMMEEMM E 1111IMMOMMAIRIMM E IIIIIIMRIIIIMMMMME 111111MEOMAIRIMAI M 1 II'IiI'-i'tiI MEMAIMAIMISil IIif IMMMMIMEMMEM IMMIWMLIMMLIMW IMMWMMMMMM M IIMMMMMWME M IINKIMMEME M IIMMINMWMM E BIENMEEMEME MEMOMEREM E EEWEMMMMM n ns •EIMMEMEME • MilINEMBIN N •11MMEII.M .M. 0 •11EIEWEEMI E N IMEMIMMMIMMIMMEM • 11 II a1 N- h o a-) N (1 NJJ~1.Jd') .(1/O/G3/JH _7/1 /IV 7-7bV