MIT OpenCourseWare http://ocw.mit.edu 8.21 The Physics of Energy Fall 2009 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms. Otto cycle Combustion and fuels Real engines Other engine cycles 8.21 Lecture 11 Internal Combustion Engines October 2, 2009 8.21 Lecture 11: Internal Combustion Engines 1 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Internal Combustion Engines Much energy used for transport–cars, trucks, planes, boats, . . . • U.S.: 25% Energy use, 33% CO2 • Globally 15%/20%, growing Presents unique challenge: need portable fuel, light engine Engine type Spark ignition Compression ignition Gas turbines Use Cycle cars, light trucks trucks, heavy vehicles airplanes Otto (Const. V) Diesel (Const. P) Brayton Most cars ∼ 20%-25% efficient. Increase 5%: save 15 EJ/year globally! (200M people’s total E use) 8.21 Lecture 11: Internal Combustion Engines 2 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles 4-stroke Spark Ignition (SI) engine: stages of operation 4-stroke SI engine image removed due to copyright restrictions. [Milton] (a) Air/fuel intake: piston goes down (b) Compression: piston goes up (c + d) Power: ignition, combustion, piston goes down (e) Exhaust: piston goes up 8.21 Lecture 11: Internal Combustion Engines 3 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Reciprocating SI engine Reciprocating SI engine image removed due to copyright restrictions. • First IC engines modeled on cannon! • Reciprocating engine: linear piston motion • Connecting rod → rotates crankshaft • Crankshaft → camshaft → valve control • Piston up: top dead center (TDC/TC) • Single cycle: crankshaft rotates twice • Max/min volume: V1 /V2 (Vt /Vc ) Displaced volume V1 − V2 (Vt − Vc = Vd ) • Compression Ratio r = V1 : V2 (typical 9.5:1) [Heywood] 8.21 Lecture 11: Internal Combustion Engines 4 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Idealize as thermodynamic Otto cycle (constant volume combustion) Otto cycle images removed due to copyright restrictions. [Milton] Otto + intake/exhaust [Milton] 1 → 2. Adiabatic compression: good approx. for compression (b) 2 → 3. Isometric heating: OK approximation for combustion (c) 3 → 4. Adiabatic expansion: OK approximation for power stroke (d) 4 → 1. Isometric cooling: OK approx. for exhaust + intake (e + a) Isometric cooling really just “blowdown”; Better: intake + exhaust as separate constant p (isobaric) processes 8.21 Lecture 11: Internal Combustion Engines 5 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles “Ideal gas” Otto cycle analysis • Approximate combustion at constant volume 3 p3 • Qin from combustion of fuel η= p - T4 −T1 T3 −T2 ⇒ T2 = T1 rγ−1 (r = V1 /V2 ) and similarly T3 = T4 rγ−1 2 Qout = CV (T4 − T1 ) 4 p4 1 p1 V2 = V3 =1− p1 V1γ = p2 V2γ ⇒ T1 V1γ−1 = T2 V2γ−1 Qin = CV (T3 − T2 ) p2 Qin −Qout Qin V - V1 = V4 So η =1− 1 T2 − T1 = rγ−1 T2 Critical feature: Compression ratio r 8.21 Lecture 11: Internal Combustion Engines 6 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Hydrocarbons: molecules composed of hydrogen + carbon atoms • Crude oil: mix of many hydrocarbons • Refineries: separate by properties • Gasoline: ∼ 500 molecules, 5-12 C’s Mixed for: High compression/efficiency, Minimize pollution Image removed due to copyright restrictions. iso-octane H H H C HH C H H H H C C C (2-2-4-trimethylpentane) H H H H C C H H H C H H [Heywood] 8.21 Lecture 11: Internal Combustion Engines 7 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Combustion SI: Spark Ignites fuel-air mixture, HC’s + O2 → H2 O + CO2 e.g. iso-octane: 2 C8 H18 + 25 O2 → 18 H2 O + 16 CO2 + 10.94 MJ where ∆H combustion ∼ = 5.47 MJ/mol ∼ = 47.9 MJ/kg (hhc) iso−octane Air/fuel ratio nomenclature: Stoichiometric: just enough O2 to burn all fuel (gasoline: ∼ = 14.7 : 1) Lean: excess oxygen (higher efficiency) Rich: excess fuel (lower efficiency, slightly rich → slight power increase) Exhaust: CO2 , H2 O + unburned HC’s, CO, NOx , . . . 8.21 Lecture 11: Internal Combustion Engines 8 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Combustion process + “knock” • Combustion process: ∼ 1/6 rotation centered into expansion phase Image removed removed due to copyright restrictions. [Milton] Image removed removed due to copyright restrictions. [Heywood] • Heat + pressure ⇒ premature combustion: Knock • Straight paraffins knock most easily Measured by “critical compression ratio”, CCRiso−octane ∼ 2 − 3× CCRn−heptane • “Octane rating” N: Knocks as N% iso-octane, 100 − N% n-heptane • 93 octane gasoline: knocks r ∼ 10.5 • Additives: aromatics, lead,. . . improve • Bottom line: rmax ≈ 10 with current gasoline mixtures 8.21 Lecture 11: Internal Combustion Engines 9 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Real SI engines Maximum compression ratio: 10:1 At 1500-2500 K, γhot air ≈ γair+spent fuel ≈ 1.3 ηOtto = 1 ∼ = 0.50 1 − rγ−1 Theoretical “Ideal gas” thermo analysis: 50% efficiency Real SI engines: max 35-40%. e.g. 4-cylinder Camry: ηmax ≈ 35% SI engine losses Image removed removed due to copyright restrictions. • Combustion not instantaneous • Heat loss during expansion • Blowdown: not constant volume • Exhaust/intake: “pumping losses” 8.21 Lecture 11: Internal Combustion Engines 10 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Throttle: reduces efficiency Image removed removed due to copyright restrictions. • Let up on gas: throttle reduces air/fuel flow (typical driving: intake 0.5 Atm) ⇒ reduced pressure on intake (increased pumping loss) Combining all these inefficiencies, power to systems: ∼ 25% delivered mechanical energy, as in transport example 8.21 Lecture 11: Internal Combustion Engines 11 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Atkinson cycle 3 p3 p • Keep valve open at start of compression ⇒ can have exp. ratio > comp. ratio p2 • Extract more energy w/ expansion 2 p4 p1 1b V2 = V3 V V1b 4 1 V1 = V4 • Reduces pumping losses [DOE report] 8.21 Lecture 11: Internal Combustion Engines 12 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Atkinson cycle in real engines Used in 2007 Toyota Camry hybrid • Expansion ratio 12.5:1 (compression ratio 9.5:1) • Maximum efficiency 35% → 38% [DOE report] • Reduces pumping losses • Maximum power 160hp → 147hp, made up by battery assist • Superior acceleration [DOE report] 8.21 Lecture 11: Internal Combustion Engines 13 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles Diesel (constant pressure combustion) cycle — Compression Ignition (CI) Image removed removed due to copyright restrictions. • Inject fuel after compression ⇒ can have r = V1 /V2 ∼ 15 − 20 : 1 • Efficiency → 70% theoretical, ∼ 45% realized (ideal cycle inaccurate) • Need heavy piston/cylinder head ⇒ trucks, buses, boats, . . . • More flexible fuel options (∼ biodiesel) 8.21 Lecture 11: Internal Combustion Engines 14 / 15 Otto cycle Combustion and fuels Real engines Other engine cycles SUMMARY • SI engines modeled by “ideal gas” Otto (constant V combustion) cycle • ηOtto = 1 1−rγ−1 • r = V1 /V2 limited to ∼ 10 by “knock” • Real engines: combustion process, heat loss, pumping reduce η →∼ 35% max, 25% average delivered. • Atkinson cycle: valve timing → more expansion, efficiency • Diesel (constant P combustion): CI → increased compression, efficiency 8.21 Lecture 11: Internal Combustion Engines 15 / 15