Design of an indirect-fired falling-particle air preheater for MHD power generation by Chris Dewey Jensen A thesis submitted in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE in Chemical Engineering Montana State University © Copyright by Chris Dewey Jensen (1976) Abstract: A preliminary design for an indirect-fired falling-particle air preheater for a 400 MW (thermal) MHD power generation plant was made. The project was broken down into three major parts: material properties prediction, development of a theoretical model, and capital and annual cost estimation of the overall design. A theoretical model was developed for an indirect-fired cored-brick air preheater. Capital and annual costs were estimated and compared to those of the falling-particle air preheater. It was found that overall air preheat systems involving these two designs would have approximately the same capital costs of ~ $44 x 10^6, and annual costs of ~$6 x 10^6. An economic comparison was then made between overall indirect-fired air preheat designs, and overall direct-fired designs. In both the falling-particle and cored-brick cases, the capital cost of the indirect-fired design was approximately 50% greater than the capital cost of the direct-fired design. STATEMENT OF PERMISSION TO COPY In p re s e n tin g t h is th e s is in p a r t i a l f u l f i l l m e n t o f th e req u irem en ts f o r an advanced degree a t Montana S ta te U n iv e r s it y , I a g ree t h a t th e L ib r a r y s h a ll make i t f r e e l y a v a ila b le f o r in s p e c tio n . I f u r t h e r agree t h a t p e rm is s io n f o r e x te n s iv e copying o f t h i s th e s is f o r s c h o la r ly purposes may be g ra n te d by my m ajor p r o fe s s o r , o r , in h is absence, by th e D ir e c t o r o f L i b r a r i e s . o f th is It is understood t h a t any copying o r p u b lic a tio n th e s is f o r f i n a n c ia l g a in s h a ll not be a llo w e d w ith o u t my w r it t e n p e rm is s io n . S ig n a tu re Date DESIGN OF AN INDIRECT-FIRED FALLING-PARTICLE AIR PREHEATER FOR MHD POWER GENERATION by CHRIS DEWEY JENSEN . A th e s is s u b m itted in p a r t i a l f u l f i l l m e n t o f th e re q u ire m e n ts f o r th e degree of , MASTER OF SCIENCE in Chemical E n g in e e rin g Approved: C h a irp e rs o n , G raduate Committee Head, M a jo r Depactmght Graduate?Dean MONTANA STATE UNIVERSITY Bozeman, Montana A ugust, 1976 iii ACKNOWLEDGMENT The a u th o r w ishes to g iv e s p e c ia l thanks to D r. W illia m G e n e tti f o r h is in v a lu a b le s u p p o rt in th e developm ent o f t h i s p r o je c t . S p e c ia l thanks a ls o goes to D r. R. L . Mussulman o f th e M echanical E n g in e e rin g D epartm ent o f . h i s many h e lp fu l s u g g e s tio n s . The a u th o r g r a t e f u l l y acknowledges f i n a n c ia l s u p p o rt from ERDA/MHD D iv is io n . F i n a l l y , thanks goes to S h e rry G reene, s e c r e ta ry f o r th e Chemical E n g in e e rin g D ep artm en t, f o r her ty p in g o f t h i s th e s is . iv TABLE OF CONTENTS Page V IT A ............................ ........................ .............................................................................. . ACKNOLWEDGMENTS ................................ ii iii L IS T OF TABLES........................... v iii L IS T OF FIGURES ............................................... .... .......................................... .... ix NOMENCLATURE.............. .......................................................... . ABSTRACT..................................... x x ii INTRODUCTION............................................ I CONVENTIONAL TURBINE AND MHD POWER GENERATION. ............................ I COMPARISON OF E F F IC IE N C IE S ............................... 4 THE NEED FOR PREHEATED A IR ................................................................... 5 DIRECT AND INDIRECT-FIRED AIR PREHEATERS . . . i . . . . . . 6 . 8 MODEL DEVELOPMENT AND DESIGN OF. FALLING-PARTICLE AIR PREHEATER. . 14 -GENERAL AIR PREHEATER D E S IG N ........................... INTRODUCTION................... ^ . PREDICTION OF MATERIAL PROPERTIES. . . . . . . . . . . . . . . . . 14 14 GENERAL DESIGN CONSIDERATIONS............................................................................ 15 PARTICLE SIZE DISTRIBUTION .............................................. 16 PARTICLE TERMINAL VELOCITIES AND CHAMBER DIAMETER................... . 17 DETERMINATION OF INSULATIONTHICKNESS............................................................ 17 OVERALL HEAT LOSS TO SURROUNDINGS..................................... DEVELOPMENT OF MODEL DESIGN COMPUTER PROGRAM ........................ • ■ _ - - : v . -• ' , - . ; 18 . . 20 TABLE OF CONTENTS (C o n t ) . Page MODEL DEVELOPMENT AND DESIGN OF CORED-BRICK AIR PREHEATER. COST SUMMARYFOR INDIRECT-FIRED AIR PREHEATERS . . . . 21 . . . .................................... 23 FALLING-PARTICLE AIR PREHEATERS....................... 23 CORED-BRICK AIR PREHEATERS. ........................................................................... 24 FUEL SOURCES FOR INDIRECT-FIRED AIR PREHEATERS . . . ................................... 25 INTRODUCTION . ................................................................. 25 COAL CARBONIZATION......................................................................................... .... . 25 COAL G A S IF IC A T IO N ................................................................. 26 OVERALL INDIRECT-FIRED AIR PREHEAT SYSTEMS COST COMPARISON . . . . 30 CAPITAL COST COMPARISON........................................ 30 ANNUAL COST ESTIMATION. 30 .................................................................................... COMMENTS. ...........................................................................................................................33 CAPITAL COST COMPARISON OF DIRECT AND INDIRECT-FIRED AIR PREHEAT SYSTEMS. ................... ... ................... . . . . .......................................... .... 33 COMMENTS........................... 33 ;APPENDICES ...................................................................... APPENDIX ' A: 35 PREDICTION OF MATERIAL PROPERTIES. . . . . . 1. CONSTITUENTS OF.COAL GAS, MOLE %. 2. PRODUCTS OF COAL GAS COMBUSTION ........................................................ 3. HOT 4. EXHAUST"GAS PROPERTIES..., HOT AIR PROPERTIES. .-. 36 . . . . . . . . . . . . .. . . .. . . . 36 36 . ............................................................ -V ................., ' - ' i . •. ____ ................ 37 38 • . ‘. A r - ;-v •' V - . _• v ; • * vV.- f/ ‘ • ‘ Vl TABLE OF CONTENTS(Cont). Page 5. ALUMINA PARTICLE PROPERTIES.............................................. .... 6. INSULATION DATA. 7. MHD COAL EXHAUST GAS PROPERTIES. .3 8 ......................................................................................... . . ................................. 39 GENERAL DESIGN BALANCES................................. ................................ 41 1. COMPOSITION OF MONTANA SUB-BITUMINOUS COAL ............................ 41 2. AIR INPUT TO 400 MW(T) MHD COMBUSTOR.......................................... 41 3. HEAT TRANSFER RATE TO AIR IN PREHEATER ...................................... 42 APPENDIX B: APPENDIX C: . . 38 MODEL DEVELOPMENT OF FALLING-PARTICLE AIR PREHEATER. 43 1. PARTICLE SIZE DISTRIBUTIONS. ............................................................. 2. TERMINAL VELOCITY AND CHAMBER DIAMETER CALCULATION. . . 43 3. DETERMINATION OF INSULATION THICKNESS. ■. . . 45 4. WALL HEAT LOSS DETERMINATION................... ...• . . .. ....................... 5. OVERALL HEAT LOSS DETERMINATION.................................................. 6. DEVELOPMENT OF DESIGN EQUATIONS. 7. DEFINITIONS OF PROGRAM VARIABLES AND PROGRAMLISTING . . . . . . . 43 . ■. . 47 47 ............................ . . 49 53 APPENDIX D: MODEL DEVELOPMENT.OF CORED-BRICK AIR PREHEATER . . . 65 APPENDIX E: COST PREDICTION FOR FALLING-PARTICLE AIR.PREHEATER . 72 . I. INSULATION COSTS,. . . .. .........................'....................................... 2. STEEL COLUMN COST. 3. ALUMINA PARTICLE COST...........................................................74 4. MISCELLANEOUS CAPITAL COSTS . 72 72 74 v ii TABLE OF CONTENTS (C o n t ) . Page 5. ESTIMATION OF ANNUAL MAINTENANCE COSTS APPENDIX F: . COST PREDICTION FOR CORED-BRICK AIR PREHEATER. . . . INSULATION COSTS ............................................................. .......................... 76 2. STEEL COLUMN C O S TS ................... \........................................ .. 76 3. CORED-BRICK COST. 77 4. MISCELLANEOUS CAPITAL C O S T S ..................................... ...................... 77 5. ESTIMATION OF ANNUAL MAINTENANCE COSTS..................................... 78 I. DESIGN DATA ............................................... .... FOR.COAL CARBONIZATION SYSTEM . . . . . MASS AND ENERGY. APPENDIX H: 79 BALANCES.............................. DESIGN DATA 79 FOR COAL GASIFICATION SYSTEM. . . . . . 1. MASS AND ENERGY 2. CAPITAL AND ANNUAL COST PREDICTION.............................................. 81 BALANCES............................................... ...... BIBLIOGRAPHY . . . . . . . . . • 76 1. APPENDIX G: • 75 81 82 ..................... .............................................................. . ■ 83 . ■ ) .. . y - ■■ ; ........... X : ' . . : . f . y - '! - : . . V- ' , ■ " ' . v iii L IS T OF TABLES TABLE PAGE I FALLING-PARTICLE CHAMBER DIMENSIONS............................ ............................21 II CORED-BRICK CHAMBER DIMENSIONS . III ESTIMATED CAPITAL COST OF AN INDIRECT-FIRED FALLING- . . . . . . . . . ................... 22 PARTICLE AIR PREHEATER .................................................................................23 IV ESTIMATED CAPITAL COST OF AN INDI RECT-FI RED COREDBRICK.AIR PREHEATER........................... V COST COMPARISON OF OVERALL INDIRECT-FIRED COREDBRICK AND FALLING-PARTICLE AIR VI 24 PREHEAT SYSTEMS...................31 CAPITAL COST COMPARISON OF DIRECT AND INDIRECT-FIRED AIR PREHEAT SYSTEMS. .................................................................. . . . c. • - •• V ,* . ,. 33 - 'J . v ; . • '. L s A , •» „ • ’ ‘ • -T zk- *- \ f i ' I* V. - . r . • .‘ ' 1 ^ /} .• ^ » - ■ ' • \ ■' ix LIS T OF FIGURES FIGURE 1 PAGE CONVENTIONAL TURBINE AND MHD POWER GENERATION SYSTEMS COMPARISONS.................................................... 2 2 COMPARISON OF DIRECT AND INDIRECT-FIRED AIR PREHEAT SYSTEMS........................... 7 3 CROSS-SECTION OF A CORED-BRICK AIR PREHEATER ................................. IO 4 SIM PLIFIED SCHEMATIC OF FALLING-PARTICLE AIR PREHEATER 12 5 COLUMN INSULATION CROSS-SECTION. 6 AIR PREHEAT SYSTEM WITH COAL CARBONIZER AS FUEL SOURCE . . . 27 7 AIR PREHEAT SYSTEM WITH COAL GASIFIER AS FUEL SOURCE . . . . 28 8 ENTHALPY OF MHD COAL EXHAUST GAS v s . TEMPERATURE.................... 40 . . . . . . . . . .......................................19 X ■ NOMENCLATURE (E xclu d es te rm in o lo g y used e x c lu s iv e ly in computer program . See Appendix C -7 f o r d e f i n i t i o n s o f program v a r i a b l e s ) . EXPLANATION SYMBOL A AC cD cP 0C Fd nT UNITS p a r t i c l e s u rfa c e a re a ft2 p a r t i c l e c r o s s -s e c tio n a l a re a ft2 drag c o e f f i c i e n t dim en sionless s p e c if ic h e a t (c o n s ta n t p re s s u re ) BTUZlbm0F in s id e column d ia m e te r ft drag fo rc e Ib f to ta l number o f ho les in c o r e d -b r ic k col umn dim en sionless Nu N u s s e lt number, hD/k Pr P ra n d tl number, C m/k P " . dim en sionless R h e a t t r a n s f e r r e s is ta n c e °F hr/BTU Re Reynolds number, Du^p/y dim en sionless St S ta n to n number, Nu/RePr dim ensionless TW o u ts id e w a ll te m p e ratu re . °R p a r t i c l e te m p e ra tu re °R V gas te m p e ra tu re °R T= am bient te m p e ra tu re °R TS uO do o v e r a ll h e a t t r a n s f e r c o e f f i c i e n t h o le d ia m e te r in c o r e d -b r ic k B T U Z h rft2oF ft Xl NOMENCLATURE (C o n t) EXPLANATION SYMBOL p a r tic le d ia m e te r f fr ic tio n fa c to r g a c c e le r a tio n o f g r a v it y dP g r a v ita tio n a l 9c c o n s ta n t, 3 2 .1 7 UNITS ft d im en sio n less ft /s e c 2 5' f t l b m/ l b f sec h c o n v e c tiv e h e a t t r a n s f e r c o e f f i c i e n t B T U Z h rft2oF k therm al c o n d u c tiv ity B T U Z h rft0F q h e a t t r a n s f e r r a te uA uT V . BTUZhr gas v e lo c it y ftZ s e c p a r t i c l e te rm in a l v e lo c it y ftZ s e c p a r t i c l e v e lo c it y ftZ s e c gas mass flo w r a te Ib mZhr p a r t i c l e mass flo w r a te I b mZbr ’ “g wS X v e r t ic a l 5 in s u la t io n th ic k n e s s U v is c o s it y pg ps 0 . TW d is ta n c e from to p o f column ft ft lb Z fts e c gas d e n s ity 1V p a r t i c l e d e n s ity Ib mZ f t 3 tim e shear s tre s s a t w a ll AX in c re m e n ta l change in X ZIP p re ss u re drop ft3 sec Ib f Z ft2 ft Ib p Z in 2 ABSTRACT ( A p r e lim in a r y design f o r an i n d i r e c t - f i r e d f a l l i n g - p a r t i c l e a i r p re h e a te r f o r a 400 MW (t h e r m a l) MHD power g e n e ra tio n p la n t was made. The p r o je c t was broken down in t o th re e m ajo r p a r ts : m a te r ia l p ro p e rtie s p r e d ic t io n , developm ent o f a t h e o r e t ic a l m odel, and c a p it a l and annual c o s t e s tim a tio n o f th e o v e r a ll d e s ig n . A t h e o r e t ic a l model was developed f o r an i n d i r e c t - f i r e d c o re d -b ric k a i r p r e h e a te r . C a p ita l and annual costs were e s tim a te d and compared to those o f th e f a l l i n g - p a r t i c l e a i r p r e h e a te r . It.w a s found t h a t o v e r a ll a i r p re h e a t systems in v o lv in g these two designs would have a p p ro x im a te ly th e same c a p it a l costs o f ~ $44 x 1 0 6 , and annual costs o f ^$6 x IO ^. An economic comparison was then made between o v e r a ll i n d i r e c t - f i r e d a i r p re h e a t d e s ig n s , and o v e r a ll d i r e c t - f i r e d d e s ig n s . In both th e ... f a l l i n g - p a r t i c l e and c o r e d -b r ic k c ases, th e c a p it a l c o s t o f th e i n d i r e c t f i r e d design was a p p ro x im a te ly 50% .g r e a t e r than the c a p it a l c o s t o f the d i r e c t - f i r e d d e s ig n . INTRODUCTION CONVENTIONAL TURBINE AND MHD POWER GENERATION Magnetohydrodynamic (MHD) power c o n versio n is a method o f g e n e ra tin g e l e c t r i c i t y w ith fe a tu r e s s im i l a r to those o f a c o n v e n tio n a l steam t u b r in e d riv e n g e n e ra to r. These s i m i l a r i t i e s w i l l be d is c u s s e d , and then fe a tu r e s p e c u lia r to MHD power con versio n w i l l F ig u re I illu s tr a te s be d is c u s s e d . a v e ry s im p l i f i e d steam tu r b in e d riv e n g e n e ra to r and a MHD g e n e ra to r. In th e case o f the steam tu rb in e g e n e ra to r, th e th erm al energy o f h o t combustion products (form ed by th e b u rn in g o f some f o s s il to steam . fu e l) is tra n s fo rm e d in t o l a t e n t energy by v a p o riz in g w a te r The tra n s fo rm a tio n to m echanical energy is accom plished by expanding th e steam a g a in s t tu r b in e b la d e s . r o ta te s a co n ductor (t h e a rm a tu re ) s ta to r). F i n a l l y , th e tu r b in e s h a f t in a s t a t io n a r y m agnetic f i e l d (th e As the lin e s o f m agnetic f l u x a re b ro k en , a n e t e le c tro m o tiv e fo rc e and r e s u lt in g c u r r e n t flo w is c re a te d in accordance w ith F a rad a y 's laws o f in d u c tio n . I t should be p o in te d o u t t h a t th e w o rkin g gas in the t u r b in e c o u ld be any h o t , high p re s s u re g a s, as w e ll as steam . • The MHD power co n ve rs io n system has a number o f s i m i l a r i t i e s -tu rb in e g e n e r a to r. In th e MHD c a s e , th e conductor which breaks the lin e s o f m agnetic fo rc e o f th e s t a t io n a r y m agnetic f i e l d c o n d u c tin g f l u i d , co n d u c tin g f l u i d to th e u s u a lly a gas. is a h o t , e l e c t r i c a l l y Thus th e therm al energy o f th e is tra n s fo rm e d d i r e c t l y to e l e c t r i c a l e n e rg y . The system c o n s is ts o f an expanding d u ct through which th e h o t gas flo w s , which is lin e d on two o p p o s ite s id e s w ith e le c tr o d e s . The e le c tro d e s ■ 2 - E le c tr ic a l Thermal K in e tic Mechanical Brushes Arm ature T u rb in e S ta to r Steam Hot Combustion Products E le c tr ic a l Thermal H ot Cond. Exhaust E le c tro d e s E lec tro m a g n e t FIGURE I . CONVENTIONAL TURBINE AND MHD POWER GENERATION SYSTEMS COMPARISONS - 3 c a r r y th e c u r r e n t to th e e x te r n a l lo a d c i r c u i t in the same fashion* as th e brushes in th e c o n v e n tio n a l g e n e ra to r. . I t should be noted here t h a t th e r o t a t io n a l m otion o f th e arm ature in a c o n v e n tio n a l g e n e ra to r c re a te s a a lt e r n a t i n g c u r r e n t , whereas th e co n tin u o u s m otion o f th e gas p a s t th e e le c tro d e s in an MHD g e n e ra to r c r e a te s d i r e c t c u r r e n t . The two types o f MHD systems p o s s ib le a re open c y c le and clo sed c y c le . In th e c lo sed c y c le case, th e conducting f l u i d re g e n e ra te d through the use o f h e a t e xch an g ers. o f system a re c y c le s in v o lv in g is re c y c le d and Examples o f t h i s ty p e noble g a se s , and l i q u i d m e ta ls . In the open c y c le c a s e , th e co n d u ctin g f l u i d passes through th e MHD d u c t o n ly once. S in ce t h i s paper is d ir e c te d tow ard th e design o f h e a t exchange components f o r open c y c le d f o s s i l - f u e l e d MHD systems th e c lo s e d c y c le system w i l l n o t be discussed f u r t h e r . In an open c y c le MHD system , th e h o t gas (com bustion products o f some f o s s i l fu e l) is made an e l e c t r i c a l s ee d , such as KgO o r KgCOg. conductor by th e a d d itio n o f a The low io n iz a t io n p o te n tia l o f th e seed en ab les a f r e e flo w o f e le c tr o n s w it h in th e gas. th is typ e is c a lle d a plasm a. The e l e c t r i c a l ^ c o n d u c tin g gas o f c o n d u c tiv ity o f th e gas is a r e l a t i v e measure o f th e ease in which th e gas w i l l conduct e l e c t r i c i t y . The optimum seed c o n c e n tra tio n is about 1-5% b y .w e ig h t ( 1 , 2 ) . -J-:; • .. ■■ : ■: : V - ' ' v. . ■■ .v; i V-.-v - v :■V.'. v,-. ~ ... :.. {. / • - 4 - COMPARISON OF EFFICIENCIES In th e ty p e o f power co n ve rs io n systems discussed so f a r , therm o­ dynamic e f f i c ie n c y is o p tim iz e d by m axim izing th e te m p e ra tu re o f th e w o rkin g gas. The presence o f h ig h ly s tre s s e d moving p a rts in a tu r b in e g e n e ra to r becomes th e l i m i t i n g f a c t o r in th e w orking gas te m p e ra tu re , and thus in th e g e n e ra to r e f f i c i e n c y . tr ic a l As a r e s u l t o f t h i s , th e e le c ­ e f f i c i e n c i e s o b ta in e d in c o n v e n tio n a l steam tu r b in e power p la n ts is between 30-45% . In th e case o f MHD system s, no moving o r h ig h ly s tre s s e d p a rts a re p re s e n t, and a l l e x te r n a l c o o lin g . p a rts a re r e a d ily a c c e s s ib le to Thus th e l i m i t i n g f a c t o r in MHD e f f i c i e n c y is th e te m p e ra tu re o f th e w orking gas i t s e l f , which can be much h ig h e r than th e maximum te m p e ra tu re in a t u r b in e . It is fo re s e e n t h a t w orking gas . te m p e ratu re s as h ig h as 5 0 0 0 -6 0 0 0 °F a re p o s s ib le f o r MHD a p p lic a t io n s . E f f i c i e n c i e s o f systems em ploying p re s e n t te c h n o lo g y are p re d ic te d to be about 50%. as 60%. Advanced systems a re fo re s e e n to have e f f i c i e n c i e s as high As a f u r t h e r comparison th e average e f f i c ie n c y o f a n u c le a r f i s s i o n power g e n e ra tin g f a c i l i t y is 32%. Thus an advanced MHD p la n t would have 1 .5 tim es the. e f f i c i e n c y o f a c o n v e n tio n a l steam tu r b in e p la n t, and 1 ,9 tim e s th e e f f i c ie n c y o f a c o n v e n tio n a l n u c le a r p la n t . I t should be noted here t h a t th e advantage o f an MHD system is n o t is high e f f i ­ c ie n c y a lo n e , b u t i t s a b ility to c o n v e rt therm al to e l e c t r i c a l in much h ig h e r te m p e ra tu re ranges th a n tu r b in e g e n e ra to rs . energy As a r e s u l t , th e exhaust gases from th e MHD d u c t would be tr a n s f e r r e d t o . a conven- - 5 .t io n a l gas o r steam tu r b in e g e n e ra tin g f a c i l i t y , The t o t a l o r "bottom ing" p la n t . power o u tp u t o f t h e . f a c i l i t y . w o u l d be about e v e n ly d iv id e d between th e MHD -p la n t and the b ottom in g p la n t ( 1 , 3 ) . THE NEED FOR PREHEATED AIR The w o rking gas te m p e ratu re s necessary f o r e f f i c i e n t MHD power g e n e ra tio n a re w e ll above gas te m p e ratu re s a c c e s s ib le .b y c o n v e n tio n a l com bustion methods. The combustion o f coal W ith am bient a i r g ives a maximum te m p e ra tu re o f about 3 00 0 °F . However, e f f i c i e n t MHD power g e n e ra tio n re q u ire s a te m p e ra tu re o f about SOOO0F. a v a ila b le in a c h ie v in g t h i s te m p e ra tu re . oxygen. Two methods a re The f i r s t is th e use o f excess In view o f th e high c o s t o f a f a c i l i t y capable o f producing th e amounts o f oxygen which would be necessary f o r a commercial s c a le MHD i n s t a l l a t i o n , t h i s method is looked upon as uneconom ical w ith p re s e n t te c h n o lo g y . The second method in v o lv e s p re h e a tin g th e combustion a i r b e fo re i t used to burn th e c o a l. is e x t e n s iv e ly in th e s te e l in d u s tr y . T h is method has been used C o n ven tio n al tube and s h e ll h e a t exchangers can be used to p re h e a t a i r to about 1 70 0 °F . To reach th e te m p e ra tu re necessary f o r MHD power g e n e r a tio n , an a i r p re h e a t tem per­ a tu r e o f ab o u t SlOO0F is r e q u ir e d . needed which w i l l Thus a h e a t exchange system is r a is e th e te m p e ra tu re o f a i r from 1 7 0 0 °F to 310 0 °F . A number o f systems a re p r e s e n tly b e in g looked a t . V- .w _- , . ' .A .* ‘ -S'/..? • I' V.... ■ • -... V/ . . .-v - .■ .. w . v -V . ! ...... . ■■■• ■■■ - 6 - DIRECT AND INDIRECT-FIRED AIR PREHEATERS ' A i r p re h e a te rs a re o f two b a s ic ty p e s a cc o rd in g to how th e y f i t i n t o th e o v e r a ll MHD process - d i r e c t - f i r e d and i n d i r e c t - f i r e d , as shown in F ig u re 2 . The d i r e c t - f i r e d a i r p re h e a te r u t i l i z e s th e therm al energy o f th e MHD exh au st gas, which le a v e s th e MHD d u c t a t about 3 3 0 0 °F , to d i r e c t l y p re h e a t a i r . The i n d i r e c t - f i r e d a i r p re h e a te r u t i l i z e s the th e rm a l energy o f exhaust from a s e p a r a te ly f i r e d c le a n fu e l combustor to p re h e a t th e combustion a i r . d is a d v a n ta g e s . The d i r e c t - f i r e d design has th re e b a s ic F i r s t , th e MHD exh au st is s la g , both o f which a re h ig h ly c o r r o s iv e . laden w ith v a p o riz e d seed and Second, as th e exh a u s t gas t r a n s fe r s h e a t in t h e . a i r p r e h e a te r , both th e seed and s la g condense, c o a tin g th e in t e r n a l works o f th e p r e h e a te r . This s o lid re s id u e would have to be c o n tin u o u s ly removed, not o n ly from an o p e ra tio n s s ta n d p o in t, b u t a ls o because th e c o s t o f th e seed makes re c y c le im p e r a tiv e . T h ir d , th e i n l e t p ressu re to th e MHD d u c t must be ~8 atm in o rd e r t h a t th e gas can push i t s e l f through the d u c t. As a r e s u l t o f t h i s , th e p reheated com bustion a i r must be p re s s u riz e d to 8 atm . p re s s u re from th e MHD d u c t is d iffe r e n tia l atm. However, th e o u t l e t Thus, th e re w i l l be a pressure o f ^6 % atm . between th e exh a u s t gas s id e and th e a i r s id e o f th e p r e h e a te r . d is a d v a n ta g e s . a re e n c o u n te re d . The i n d i r e c t - f i r e d a i r p re h e a te r has none o f these S in c e .th e fu e l is c le a n , no problems w ith seed and s la g A ls o , s in c e th e i n l e t p ressu re o f th e combustion products o f th e fu e l can be a r b i t r a r i l y :• .... V -:, .-V; v .. ■:-> V:. s e t , the h o t gas s id e and th e - . - v . v ; - v V v v v - ':V.; Vv - 7 Power Out DIRECT-FIRED AIR PREHEATER A ir In v e r te r Power Out Steam Supply Heat A ir P reh e a t MHD Duct Feed A ir ^ lO O 0F INDIRECT-FIRED AIR PREHEATER FIGURE 2 . Clean w F u e l-Z - P reheater COMPARISON OF DIRECT AND INDIRECT-FIRED AIR PREHEAT SYSTEMS - 8 - a i r s id e o f th e p re h e a te r can be run a t a 1 :1 pressure r a t i o . The main d is ad v a n ta g e o f th e i n d i r e c t - f . i r e d a i r p re h e a te r is t h a t , s in c e a s e p a ra te c le a n fu e l must be employed, ~ 2 p o in ts in o v e r a ll c y c le e ffic ie n c y w ill be l o s t ( 5 , 8 ) . A lso th e need f o r a c le a n fu e l is a d is a d v a n ta g e . GENERAL AIR PREHEATER DESIGN S ince c o n v e n tio n a l lo w -te m p e ra tu re h e a t exchange m a te r ia ls and design a re in a d eq u a te f o r h ig h -te m p e ra tu re a i r p re h e a te r a p p lic a t io n s , new m a te r ia ls and designs must be c o n s id e re d . M a te r ia ls most l i k e l y to be a b le to w ith s ta n d h ig h -te m p e ra tu re c o rro s io n and therm al s tre s s a re o f th e r e f r a c t o r y ty p e . The m a te r ia l used f o r th e h e a t - t r a n s f e r medium should have a high therm al c o n d u c tiv ity and h e a t c a p a c ity fo r e f f ic ie n t heat tra n s fe r. The th re e most p o p u la r c a n d id a te s , in o rd e r o f in c re a s in g c o s t, a re alum ina ( A ^ O g ) , magnesia (M gO ), and z ir c o n ia (Z r O g ). M a te r ia ls o f t h i s ty p e a re employed in th e design o f both th e h e a t t r a n s f e r medium and th e e x te r n a l in s u la t io n o f th e a i r p re h e a te r. O f th e many a i r p re h e a te r designs p r e s e n tly being re s e a rc h e d , two w i l l be focused upon. th e f a l l i n g - p a r t i c l e These are the c o r e d -b r ic k a i r p r e h e a te r , and a i r p r e h e a te r. The c o r e d -b r ic k a i r p re h e a te r is b a s i c a ll y an in s u la te d column packed w ith l o n g i t u d i n a ll y cored r e f r a c t o r y b ric k s o f high h e a t c a p a c ity . A c r o s s -s e c tio n o f a t y p ic a l c o r e d -b r ic k a i r p re h e a te r is shown in - 9 F ig u re 3 . The s e p a ra te b ric k s a re o f hexagonal c ro s s -s e c tio n and th e core d ia m e te r ranges from 0 .2 5 inches to 0 .7 5 inches ( 4 , 1 1 ) . method o f o p e ra tio n is as fo llo w s : The th e a i r p re h e a te r column is s u it a b ly v alv ed a t each end so t h a t h o t gas o r a i r can a l t e r n a t i v e l y be run through th e column, in c o u n te rc u rre n t d ir e c t io n s . In itia lly , b r ic k s a re heated f o r a s p e c ifie d p e rio d o f tim e by h o t.g a s . is heated by ru n n in g i t o f tim e . th e cored Then a i r through .the colum n, a ls o f o r a s p e c ifie d amount A problem is t h a t th e a i r o u tp u t is o f a c y c lic n a tu r e , w h ile th e MHD process re q u ire s a c o n s ta n t flo w r a te o f combustion a i r . T h is problem is s o lv e d .b y th e use o f a number o f c o r e d -b r ic k a i r p re h e a te rs o p e ra tin g in a c o ntinuous c y c le to o u tp u t a c o n s ta n t a i r flo w r a t e and te m p e ra tu re . The g r e a t e s t amount o f h e a t t r a n s f e r p e r u n it volume (and th e r e f o r e th e h ig h e s t a i r p re h e a t te m p e ra tu re ) is o b ta in e d w ith th e s m a lle s t flo w passage d ia m e te r, 0 .2 5 in c h e s . problem in th e i n d i r e c t - f i r e d c as e . T h is p re s e n ts no However, in the d i r e c t - f i r e d case, c lo g g in g o f th e flo w passages by condensing seed and s la g re q u ire s t h a t th e passage d ia m e te r be on th e o rd e r o f 0 .7 5 inches f o r e f f e c t i v e o p e r a tio n . Thus, f o r a g iv en a i r p re h e a t te m p e ra tu re , th e d i r e c t - f i r e d a i r p re h e a te r w i l l be o f c o n s id e ra b ly l a r g e r . s i z e th a n th e i n d i r e c t - f i r e d a i r p r e h e a te r . An im p o rta n t p o in t is t h a t therm al expansion o f r e f r a c t o r y m a te r ia ls in th e s e te m p e ra tu re ranges is c o n s id e ra b le , and must be accounted f o r in th e o v e r a ll column design ( 4 , 5 ) . The f a l l i n g - p a r t i c l e a i r p re h e a te r is shown by s im p l i f i e d schem atic - 10 CORED ERICK MATRIX CONFIGURATION 1/4 INCH DIAMETER HOLE O _ O O _ O O FIGURE 3. -o CROSS-SECTION OF A CORED-BRICK AIR PREHEATER - 11 in F ig u re 4 . th e o th e r . The design c o n s is ts o f two v e r t i c a l colum ns, one above Small 0 .0 5 inch d ia m e te r) r e f r a c t o r y p a r t i c l e s fa ll through th e upper chamber, a re h e ld up a t th e in t e r f a c e between the cham bers, and then f a l l through th e lower, chamber. The p a r t i c l e s are th en r e tu rn e d to th e to p o f th e upper chamber by a pneum atic b lo w e r, co m p letin g th e c y c le . A t th e to p o f each chamber is a d i s t r i b u t o r p la t e which spreads th e p a r t i c l e s e v e n ly across th e chamber d ia m e te r. Hot gas (th e h e a tin g f l u i d ) e n te rs th e bottom o f th e upper chamber, flo w s up th e chamber c o u n te rc u rre n t to th e flo w o f p a r t i c l e s , and e x it s a t th e to p o f th e chamber through an exh au st m a n ifo ld .. As th e gas flo w s p a s t th e p a r t i c l e s , therm al energy is t r a n s fe r r e d to th e p a r t i c l e s . In s im i l a r fa s h io n , a i r e n te rs the bottom o f th e lo w er chamber, flow s upward c o u n te rc u rre n t to th e p a r t i c l e f lo w , and e x it s m a n ifo ld . through an exhaust As th e a i r flo w s p a s t th e heated p a r t i c l e s , therm al energy is t r a n s fe r r e d to th e a i r . It should be noted here t h a t th e design shown in F ig u re 4 is s p e c if ic f o r th e i n d i r e c t - f i r e d c as e . S ince both the upper and lo w e r chambers a re a t n e a r ly th e same p re ss u re (~ 8 a tm ), th e w e ig h t o f a number o f f e e t o f p a r t i c l e s a t th e i n t e r f a c e between th e chambers should o f f s e t any lea k ag e o f a i r o r hot gas. However, s in c e such a la r g e p re s s u re d i f f e r e n t i a l e x is ts between th e upper and lo w er chambers in th e d i r e c t - f i r e d c a s e , a complex v a lv in g mechanism o f some s o r t must be d evised to p e rm it continuous flo w o f p a r t i c l e s th e upper to lo w e r chamber, and m in im ize a i r ,le a k a g e . from U n lik e th e c o re d - - 12 Exhaust Gas P ~ 8 atm . C lean Comb. Gas T ~ 3500°F A i r to MHD M i-T e m p e ratu re Pneumatic Blow er A ir In le t FIGURE 4 . SIM PLIFIED SCHEMATIC OF FALLING-PARTICLE AIR PREHEATER - 13 b r ic k a i r p r e h e a te r , th e f a l l i n g p a r t i c l e a i r p re h e a te r is a continuous p ro c e s s , o u tp u ttin g a c o n s ta n t flo w r a t e and te m p e ratu re o f combustion a ir . Thus, c y c lic o p e ra tio n and i t s complex v a lv in g a re unnecessary. MODEL DEVELOPMENT AND DESIGN OF FALLING-PARTICLE AIR .'PREHEATER INTRODUCTION A t h e o r e t ic a l model o f th e f a l l i n g assembled on computer by W. E. G e n e t t i. p a r t i c l e a i r p r e h e a te r was A p r e lim in a r y design was then made based on th e r e s u lt s o f th e model d a ta . c a l l y w ith th e design o f an i n d i r e c t - f i r e d h e a te r. fa llin g A ls o , a design f o r an i n d i r e c t - f i r e d was made. v ie w p o in t. T h is th e s is d e a ls s p e c i f i ­ p a r t i c l e a i r p re ­ c o r e d -b r ic k a i r p re h e a te r The two designs a re compared from both a s t r u c t u r a l and c o s t In a d d it io n , a co st t r a d e o f f a n a ly s is is made f o r both th e f a l l i n g - p a r t i c l e and c o r e d -b r ic k designs between th e i n d i r e c t - f i r e d and th e d i r e c t - f i r e d c ases. Design and c o s t d a ta f o r d i r e c t - f i r e d a ir p re h e a te rs were p ro v id ed by W. E. G e n e tti and R. L . Mussulman. PREDICTION OF MATERIAL PROPERTIES As a p re lu d e to model developm ent o f th e a i r p r e h e a te r , e q u atio n s were developed to p r e d ic t th e g e n era l p r o p e r tie s o f th e m a te r ia ls in v o lv e d in th e d esig n f o r th e necessary te m p e ra tu re and p re ss u re ra n g e s . m a te r ia ls in c lu d e th e h o t exh au st gases (h e a tin g f l u i d ) , a i r f l u i d ) , fa llin g (h e a te d r e f r a c t o r y p a r t i c l e s , and i n s u la t io n . As m entioned e a r l i e r , a s e p a ra te c le a n fu e l a i r . p r e h e a te r . The This fu e l could be f u e l o i l , produced from th e d e v o l a t i l i z a t i o n . o f c o a l. a v a i l a b i l i t y o f fu e l o i l and n a tu ra l is n e e d e d .to f i r e n a tu ra l th e g as, o r a fu e l In view o f th e c o s t and g a s, a fu e l produced from coal - 15 d e v o l a t i l i z a t i o n was c a lle d f o r in th e o r ig in a l d e s ig n . T h is fu e l is produced by th e h e a tin g o f coal to around 2 0 0 0 °F in th e absence o f a i r , d r iv in g o f f th e v o l a t i l e , m a tte r as a gas w ith a h e a tin g v a lu e o f O ab o u t 575 B T U /ft . T h is process is a ls o c a lle d c a r b o n iz a tio n . C a rb o n iz a tio n o f 2000 lb o f coal y ie ld s about 1 1 ,0 0 0 f t ^ p lu s about 1400 lb o f coke. o f coal g a s, The c o n s t itu te n ts o f th e coal gas and i t s products o f combustion a re presen ted in Appendix A. E q u atio ns f o r th e fo llo w in g g e n e ra l p r o p e r tie s f o r a i r and th e h o t exh au st gases were developed: and h e a t c a p a c it y , a l l v is c o s it y , therm al c o n d u c tiv ity , as a fu n c tio n o f te m p e ra tu re , and d e n s ity as a fu n c tio n o f te m p e ra tu re , and p re s s u re . These e q u a tio n s , along w ith o th e r p e r t in e n t m a te r ia l p r o p e r tie s a re presented in Appendix A. GENERAL DESIGN CONSIDERATIONS A l l p re h e a te r desig n w o rk , both f o r t h i s r e p o r t and f o r th e G e n e t t iMussulman d e s ig n , was done on th e b a sis o f a 400 megawatt (th e rm a l) MHD power g e n e ra tio n f a c i l i t y . power in p u t to th e MHD .d u c t. r e a c tio n and i t s The th erm al power r a t in g is d e fin e d as th e The s to ic h io m e try o f the. MHD combustion r e la t e d mass b a lan c e s a re presen ted in Appendix B - I . As is evidenced by th e a i r re q u ire m e n t f o r th e combustion r e a c t i o n , th e a i r p re h e a te r must supply 1 .2 7 9 .x IO 6 I b r a i r / h r to th e com bustor. As p r e v i ­ o u s ly m e n tio n e d , th e te m p e ra tu re o f th e preh eated a i r m ust-be about SlOO0 F - 16 - S in ce c o n v e n tio n a l s h e ll-a n d -t u b e h e a t exchangers a re cap a b le o f producing a i r te m p e ratu re s o f 1700 F , t h is is assumed to be th e a i r i n l e t te m p e ra tu re o f th e a i r p r e h e a te r . W ith these p aram eters s e t , th e h e a t t r a n s f e r r a t e to th e a i r in th e p re h e a te r can be c a lc u la te d (Appendix B - 3 ) . found to be 5 .1 5 5 x IO^ B T U /h r. This was I t should be noted a t t h i s p o in t t h a t t h i s design f o r a 400 MW h eat.e x ch an g e f a c i l i t y c a lls f o r th re e a i r p re h e a te r colum ns, two running s im u lta n e o u s ly in p a r a l l e l , and one s p a re . 5 Thus, f o r one column, th e a i r flo w r a te would be 6 .3 9 5 x 10 I b / h r and th e h e a t t r a n s f e r r a t e to th e a i r would be 2 .5 7 8 x 10^ B T U /h r. PARTICLE SIZE DISTRIBUTION The n e x t s te p in model development was to o b ta in a r e a l i s t i c d i s t r i b u t i o n o f th e alum ina p a r t i c l e s . s iz e I t was found t h a t th e ta b u la r alu m in a s to c k s u p p lie d by the Aluminum Company o f America would have to be c l a s s i f i e d , narrow ing th e p a r t i c l e s iz e d i s t r i b u t i o n down to usable ra n g e s . Two p a r t i c l e s iz e ranges were in v e s tig a te d . . I n th e la r g e s t p a r t i c l e d ia m e te r is 0 .0 5 i n . The wide d i s t r i b u t i o n 0 .0 3 8 - 0 .0 5 i n . d ia m e te r, and the narrow d i s t r i b u t i o n d ia m e te r. e i t h e r case, is is 0 .0 4 2 - 0 .0 5 i n . These d is t r ib u t io n s w i l l be r e f e r r e d to as "b lo w o u ts ", s in c e any p a r t i c l e s m a lle r th an th e in c lu d e d range would blow o u t th e to p o f th e chamber. Appendix C -I . These two p a r t i c l e s iz e d is t r ib u t io n s a re l i s t e d in - 17 PARTICLE TERMINAL VELOCITIES AND CHAMBER DIAMETER The in s id e d ia m e te r o f th e chamber is a fu n c tio n o f th e te rm in a l v e l o c i t y o f th e p a r t i c l e s . The te rm in a l v e l o c i t y o f a p a r t i c l e d e fin e d as t h a t v e lo c it y a t which th e f a l l i n g is p a r t i c l e stops a c c e le r a t in g . In o th e r w o r d s ,s in c e drag in c re a s e s as v e lo c it y in c re a s e s , i t is th e maximum a t t a i n a b l e v e lo c it y o f th e p a r t i c l e The in a given f l u i d . te rm in a l v e l o c i t i e s o f th e s m a lle s t p a r t i c l e s were c a lc u la t e d , sin ce th e y would be th e f i r s t to “blow o u t" . The maximum g a s .v e lo c it y ( a t maximum te m p e ra tu re ) was then taken to be 100% o f t h i s te rm in a l v e l o c i t y . Thus, s in c e th e a i r mass flo w r a t e is known, th e a i r chamber d ia m e te r can be c a lc u la t e d . These c a lc u la t io n s a re p resen ted in Appendix C -2 . A t t h is p o in t , i t was i n i t i a l l y were z e r o ; thus = qga s - assumed t h a t chamber h e a t losses In t h is m anner, a gas mass flo w r a te was found and gas chamber d ia m e te r c a lc u la t e d in analogous .fa s h io n to th e a i r chamber d ia m e te r, as p re se n te d in Appendix C -2 . r a te is 6 .5 2 x IO^ I b / h r . The gas mass flo w The in s id e dia m e te rs o f th e gas and a i r chambers a r e , r e s p e c t iv e ly , 1 4 .2 f e e t and 1 1 .1 f e e t ( f o r th e 0 .0 4 2 inch blow out c a s e ). DETERMINATION OF INSULATION THICKNESS The th ic k n e s s o f in s u la t io n needed to e f f e c t i v e l y in s u la t e th e column was now d e te rm in e d . P ro p e rtie s o f th e in s u la tio n used are p re se n te d in Appendix A -6 . A t r i a l - a n d - e r r o r s o lu tio n to th e in s u la tio n 18 th ic k n e s s was made fo llo w in g th e procedure presen ted in Appendix C -3 , w ith th e l i m i t i n g c o n d itio n t h a t th e maximum o u te r w a ll te m p e ra tu re should n o t be above % 2 5 0 °F . an o v e r a ll The r e s u lt in g w a ll c r o s s -s e c t io n , having th ic k n e s s o f 3 .5 f e e t , is shown in F ig u re 5 . OVERALL HEAT LOSS TO SURROUNDINGS W ith th e w a ll c ro s s -s e c tio n known, th e r a t e o f h e a t lo s s through th e w a ll can now be d e te rm in e d . The h e a t t r a n s f e r e q u a tio n developed in Appendix C -3 is used to f in d th e o u te r w a ll v alu e s o f gas te m p e ra tu re . Then (q /A ) loss is found a t each o f these te m p e ra tu re s , and a curve is f i t is (q /A )i te m p e ra tu re a t v a rio u s as a fu n c tio n o f Tg. to th e d a ta . The r e s u lt in g eq u atio n These c a lc u la t io n s a re r e la t e d in Appendix C -4 . O v e ra ll a i r p re h e a te r h e a t lo s se s can now be c a lc u la t e d . o v e r a ll The lo sses are assumed to be the sum o f th e h e at losses in the a i r and gas cham bers, p lu s th e h e a t lo s s from th e p a r t i c l e r e c y c le system . The fo llo w in g two assum ptions must be made: 1. The h e ig h ts o f th e gas and a i r chambers are 20 f e e t and 30 f e e t , 2. r e s p e c t iv e ly . The h e a t lo s s from th e p a r t i c l e re c y c le system is approxim ated by th e a r it h m e t ic average o f th e h e a t losses from th e gas and a i r chambers. T h is p ro ced u re is o u tlin e d in Appendix C -5 . W ith th e o v e r a ll h e a t - ro (4 ) (3 ) r2 (2 ) ^ (I) r. I O u ter Wall In n e r Wall I r3 19 - 3 ................ -V T ^— 1 .1 2 5 f t A r4 1 .1 2 5 ir 3 (I) Norton AH-199B (2 ) Norton AN-599 (3 ) J o h n s -M a n v ille JM -3000 (4 ) J o h n s -M a n v ille JM-23 FIGURE 5 . -------------- t+ d ----------------- H 0 .7 5 f t 0 .5 0 f t A r2 A r1 COLUMN INSULATION CROSS-SECTION — 20 - lo s s known, th e amount o f h e a t tr a n s fe r r e d from th e h o t gas to the p a r tic le s can be d e te rm in e d , and a r e f in e d v a lu e f o r th e gas e x i t te m p e ra tu re is found to be 2 3 3 0 °F . The average p a r t i c l e te m p e ra tu re between th e chambers is assumed to be th e average o f th e bottom gas te m p e ra tu re and th e to p a i r te m p e ra tu re , o r 3 30 0 °F . te m p e ra tu re in th e p a r t i c l e re c y c le system is The average p a r t i c l e s p e c ifie d to be th e average o f th e to p gas te m p e ra tu re and th e bottom a i r te m p e ra tu re , o r 2 0 1 5 °F. T h is method o f e s tim a tin g th e chamber h e ig h ts to a r r iv e a t th e o v e r a ll h e a t lo sses is assumed to be r ig o r o u s , s in c e h e a t losses amount to o n ly ~ 0.2% o f th e t o t a l h e a t t r a n s f e r r a t e . Now t h a t a l l h e a t t r a n s f e r r a te s a re known, the p a r t i c l e mass flo w r a t e is c a lc u la t e d to be 6 .5 4 x IO^ I b / h r . DEVELOPMENT OF MODEL. DESIGN COMPUTER PROGRAM A computer program was developed to a s s is t in th e p r e lim in a r y design o f th e a i r p r e h e a te r . The o p e ra tio n o f th e program in v o lv e s th e s o lu tio n o f th re e sim ultaneous d i f f e r e n t i a l b alan ce between p a r t i c l e s e q u a tio n s : and a i r across a d i f f e r e n t i a l a momentum b a lan c e on a f a l l i n g an energy elem ent o f tim e , p a r t i c l e , and an o v e r a ll energy b a la n c e , in c lu d in g h e a t lo s s e s , across a d i f f e r e n t i a l balan ces a r e developed in Appendix C -6 . column e le m e n t. D e f in it io n s o f a l l These program v a r ia b le s , a program l i s t i n g , and a program o u tp u t are p re se n te d in Appendix C -7 . As can be s ee n , th e program o u tp u t g iv es a l i s t i n g o f im p o r ta n t chamber parameters in .in c r e m e n t s o f h e i g h t , s t a r t i n g a t th e to p o f th e gas o r a i r column and.moving down. Based on t h i s data and data a lr e a d y p re s e n te d , o v e r a l l chamber dimensions can be c a l c u l a t e d . are l i s t e d These in T a b le I . TABLE I . FALLING PARTICLE CHAMBER DIMENSIONS Gas Chamber A i r Chamber Blowout ( i n . ) .0 3 8 .042 .03 8 .042 In s id e D ia m eter ( f t ) 1 5 .1 1 4 .2 1 1 .8 4 1 1.1 O utside D ia m eter ( f t ) 2 2 .1 2 1 .2 1 8 .8 4 1 8.1 Chamber H e ig h t ( f t ) 2 0 .5 1 4 .2 3 9 .8 3 0 .0 Gas Mass Flow Rate ( I b / h r ) 6 .5 2 x l0 5 Max. Gas V e l o c i t y ( f t / s e c ) 1 8 .9 6 .5 2 x l0 5 6 .3 9 5 x l0 5 2 1 .5 Gas I n l e t Temperature ( 0F) 3500 3500 Gas E x i t Temperature ( 0F) 2330 2330 1 8 .3 4 . 6 .3 9 5 x l0 5 2 0 .8 8 1700 1700 3100 3100 MODEL DEVELOPMENT AND DESIGN .OF CORED-BRICK. AIR PREHEATER A model was developed to s i z e an i n d i r e c t - f i r e d cored b r i c k a i r p r e h e a tin g system. It i s assumed t h a t a 400 megawatt (th e rm a l) power g e n e r a tio n f a c i l i t y would r e q u i r e an a i r p r e h e a te r system c o n s is t in g o f seven s e p a r a te cored b r i c k chambers, s i x on l i n e w i t h one s p a r e . At any given ti m e , two columns would be h e a t in g a i r o r be being heated by - h o t gas. 22 - The model c o n s is ts o f an energy b a lance across a d i f f e r e n t i a l elem ent o f chamber a r e a , assuming th e b r ic k s to be i s o t h e r m a l . For the i n d i r e c t - f i r e d c a s e , b r ic k s w i t h . 0 .2 5 inch d ia m e te r holes a re used. T h is h o le s i z e giv es th e b r i c k s a c r o s s - s e c t io n a l 25%. g e om etric p o r o s i t y o f C o n v e ctiv e h e at t r a n s f e r data ( 1 7 ) f o r h e a t t r a n s f e r c o e f f i c i e n t s i n c i r c u l a r tubes is used. Pressure d ro p , as w e ll as volume, must be o p tim iz e d t o g iv e th e b e s t d e s ig n . Appendix D. Model development i s p resented in An i n s u l a t i o n th ic k n e s s o f 3 .5 ' f t is assumed. The chamber dimensions r e s u l t i n g from t h i s model a re presented in T a b le I I . TABLE I I . CORED BRICK CHAMBER DIMENSIONS Hole D iam eter ( i n . ) 0 .2 5 O v e r a ll H e ig h t ( f t ) 2 3 .3 In s id e D iam eter ( f t ) 8 .9 O utside D iam eter ( f t ) 15.9 AT - A i r Flow ( 0F) aV 155 AT - Gas Flow ( 0F) dv 100 Pressure Drop, psi 4 .4 3 . COST SUMMARY FOR IN D IR E C T-F IRED • AIR PREHEATERS FALLING-PARTICLE AIR PREHEATERS C a p it a l c o s t p r e d i c t i o n f o r th e i n d i r e c t - f i r e d f a l l i n g - p a r t i c l e a i r p r e h e a te r is developed i n Appendix E.. o n ly . T a b le I I I These costs are f o r one u n i t gives c o s t data f o r both, one u n i t and f o r an o v e r a l l t h r e e - u n i t system. TABLE I I I . ESTIMATED CAPITAL COST OF INDIRECT-FIRED FALLING-PARTICLE AIR PREHEATER 0 .0 3 8 i n . Blowout U n i t Cost T o ta l C o s t* 0 .0 4 2 in . Blowout U n it Cost T o ta l C ost* $ 2 .2 7 x l0 6 $ 6 . S lx l O 6 $ 1 .7 2 x l0 6 $ 5 .2 x l0 6 1 .7 3 x l0 6 5 . ID x lO 6 1 .3 3 x l0 6 5 . OxlO6 Alumina P a r t i c l e s .1 2 x l0 6 .3 6 x l0 6 .IB x lO 6 .4 5 x l0 6 P ip in g .3 x l0 6 .D xlO 6 .S x lO 6 .DxlO 6 Valves 1 .3 6 x l0 5 .4 1 x l0 6 .IS B x lO 6 .4 1 x l0 6 S te e l In s u la tio n I n s tr u m e n t a t io n S tru c tu re TOTAL * T o ta l Cost o f 3 u n it s .S x lO 6 .S x lO 6 ■ 6 .2 x l0 6 4 .7 x l0 6 2 0 .2 x l0 6 1 7 . OxlO6 . / - 24 CORED-BRICK AIR PREHEATERS C a p ita l costs f o r the c o r e d - b r ic k a i r p r e h e a te r system are developed in Appendix F. A g a in , th e s e f i g u r e s a re f o r one u n i t o n ly . The o v e r a l l c o r e d - b r ic k a i r p r e h e a t e r system c o n s is ts o f seven u n i t s . These costs a re summarized i n T able IV . TABLE I V . ESTIMATED CAPITAL COST OF INDIRECT-FIRED CORED-BRICK AIR PREHEATER U n i t Cost T o ta l Cost (7 u n i t s ) $ .21 6 X IO 6 $ 1 .5 1 x IO6 In s u la tio n .662 X IO 6 4 . 6 3 x IO 6 Cored B r ic k .552 X IO6 3 .8 6 x IO6 S te e l P ip in g Valves I n s tr u m e n t a t io n S tru c tu re TOTAL 1 .1 x IO 6 .136 X IO 6 .9 5 x IO 6 . 3 x IO6 3 . 0 x IO6 $ 1 5 .4 x IO6 FUEL SOURCES F O R IN DIRECT-FIRED AIR PREHEATERS INTRODUCTION A complete i n d i r e c t - f i r e d a i r p r e h e a t e r system w i l l in c lu d e a f u e l source o f some s o r t . n e c e s s a rily Since the purpose o f i n d i r e c t - f i r e d a i r p r e h e a t e r design i s t o g e t away from th e disadvantages o f using th e seed and s la g - l a d e n MHD e xhaust gas as an energy s o u rc e , th e fu e l should be c le a n and burn e f f i c i e n t l y . under c o n s i d e r a t i o n a r e f u e l The th r e e m ajor f u e l s p r e s e n t l y o i l , n a tu r a l gas, and s y n t h e t i c gas made from p a r t i a l I y o r c o m p le te ly g a s i f i e d c o a l . c o s t and s c a r c i t y o f f u e l o i l and n a t u r a l However, in l i g h t o f the gas, the c o s t o f running a commercial s c a le i n d i r e c t - f i r e d a i r p r e h e a te r w i t h these m a t e r i a l s would be p r o h i b i t i v e . been c o n c e n tra te d upon. Thus, th e p o s s i b i l i t y o f coal g a s i f i c a t i o n has Two b a s ic g a s i f i c a t i o n designs a r e c o n s id e re d , co al c a r b o n i z a t i o n and coal g a s i f i c a t i o n . COAL CARBONIZATION Coal c a r b o n i z a t i o n in v o lv e s th e h e a t in g o f coal in th e absence o f a ir. A t a te m p e ra tu re o f 1800 - 2 0 0 0 °F , the v o l a t i l e m a t t e r in the coal i s d r iv e n o f f as an i n t e r m e d i ate-BTU f u e l v a lu e o f a p p r o x im a te ly 550 B T U /ft^ ( 1 0 ) . fu e l gas, having a h e a tin g I f t h i s gas co u ld be used to th e a i r p r e h e a t e r , then coal would be th e s o le f u e l source o f the o v e ra ll power g e n e r a tio n complex. The c a r b o n iz a t io n o f a ton o f coal y i e l d s a p p r o x im a te ly 1 1,0 00 f t 3 o f t h i s f u e l gas plus about 1400 Ib ^ o f coke. The coke b y -p ro d u c t would be mixed w i t h th e coal fe e d to - th e MHD combustor. Mass and energy balances f o r t h i s system a re pre se n te d i n Appendix G. MHD exh a u s t gases. F ig u re 6 . 26 - The c a r b o n iz e r would b e .h e a te d by d i f f u s e d A s i m p l i f i e d design o f th e system is shown in The balances pre se n te d in Appendix G re v e a l t h a t , even i f pure coke were used as th e s o le f u e l source in th e MHD combustor, the coke flo w r a t e from th e coal c a r b o n iz e r would be n e a r l y tw ic e the necessary coke flo w r a t e t o th e MHD combustor. a lo n e , th e use o f coal c a r b o n i z a t i o n t o f u e l p r e h e a te r appears h i g h l y i n f e a s i b l e . Thus, on t h i s ba sis the i n d i r e c t - f i r e d a i r Because o f t h i s , an economic study o f coal c a r b o n i z a t i o n was n o t pursued. COAL GASIFICATION The p o s s i b i l i t y o f using g a s i f i e d coal as th e f u e l i n d i r e c t - f i r e d a i r p r e h e a t system was i n v e s t i g a t e d . g a s i f i c a t i o n o f coal t o s y n t h e t i c f u e l source f o r th e The complete gas o f high BTU c o n te n t ( ~ 950 B T U /f t^ STD) in v o lv e s h e a t in g th e coal to g a s i f y th e v o l a t i l e m a t t e r , s h i f t r e a c t i n g the carbon monoxide w i t h w a t e r to form hydrogen and carbon d i o x i d e , removal o f HgS and COg, and f i n a l l y m ethanation o f th e r e s u l t i n g gaseous m i x t u r e . However, m ethanation o f th e CO-Hg gas m ix tu r e has y e t to be c o m m erc ially dem onstrated. g a s f i c i a t i o n system w i l l Thus the be p resented h e r e , b u t i t should be noted t h a t progress is necessary b e fo r e the system i s t e c h n o l o g i c a l l y f e a s i b l e . Data on th e system is pre se n te d i n Appendix H. F ig u re 7 d e p ic t s a - 27 - Fuel Gas P reheate # _ T=1700 MHD Duct Combustio Chamber FIGURE 6 . AIR PREHEAT SYSTEM WITH COAL CARBONIZATION AS FUEL SOURCE To Bottoming P la n t - 28 a ' 1700°F G a s ifie r Preheater L. I . MHD Duct FIGURE 7. AIR PREHEAT SYSTEM WITH COAL GASIFIER AS FUEL SYSTEM A ir - 29 - s i m p l i f i e d coal g a s i f i e r as th e f u e l p re h ea te r. source f o r an i n d i r e c t - f i r e d a i r Data on th e p o s s i b i l i t y o f p a r t i a l char r e c y c le or o th e r uses f o r c h ar was not a v a i l a b l e . The p a r t i c u l a r g a s i f i c a t i o n process i n v e s t i g a t e d i s th e CC^-acceptor p r o c e s s , as i t c a p ita l cost o f a l l processes looked a t . has th e lo w e s t o v e r a l l However, i t i s o n ly capable o f g a s i f y i n g l i g n i t e and no n -c a kin g sub-bitum inous c o a l s . Data was n o t a v a i l a b l e on t h e f e a s i b i l i t y o f u t i H i z i n g Montana sub-bitum inous coal in t h e CC^-acceptor process. coal As i s shown in Appendix H - l , the flo w r a t e to th e g a s i f i e r would be about 47% o f th e t o t a l f l o w r a t e t o th e power g e n e r a tin g complex. The c a p i t a l coal c o s t f o r the g a s i f i c a t i o n system i s e s tim a te d a t $ 2 7 .5 x 10^, w i t h an e s tim a te d annual o p e r a t in g c o s t o f $ 4 . 3 x 106 ( 7 ) . OVERALL INDIRECT-FIRED AIR PREHEAT SYSTEMS COST COMPARISON CAPITAL COST COMPARISON As can be seen in comparing Tables I I I and I V , the f a l l i n g - p a r t i c l e p r e h e a te r ( 0 . 0 4 2 i n blow out) and th e c o r e d - b r ic k p r e h e a te r have n e a r l y th e same c a p i t a l co st, v a r y in g b y . o n ly $ 1 .6 x 10®. T h is i s w i t h i n th e l i m i t s o f e s tim a te d accuracy f o r a .l o n g - r a n g e economic a n a l y s is o f t h i s ty p e . w ill Assuming t h a t th e c a p i t a l c o s t o f th e f u e l be th e same f o r both a i r p r e h e a t systems, o v e r a l l source system system c a p i t a l costs can now be e s t im a te d . -ANNUAL COST ESTIMATION An e s t im a te o f annual maintenance costs f o r th e a i r p r e h e a te r was made. The development o f th e s e costs is presented in Appendix E-5 f o r th e f a l l i n g - p a r t i c l e a i r p r e h e a t e r , and in Appendix F-5 f o r the c o r e d - b r ic k a i r p r e h e a t e r . I t should be noted t h a t th e s e f i g u r e s are q u i t e rough e s t im a t e s , and should be weighed w ith a p p r o p r ia t e s k e p t ic is m . T a b le V pre se n ts an o v e r a l l c a p i t a l and annual cost comparison f o r th e two i n d i r e c t - f i r e d a i r p re h e a t systems. - 31 TABLE V. ■ COST COMPARISON OF OVERALL INDIRECT-FIRED CORED-BRICK AND FALLING-PARTICLE AIR PRE­ HEAT SYSTEMS C o r e d -B r ic k A i r P r e h e a te r P r e h e a te r C a p i t a l Cost $ 1 5 .4 x IO6 F a llin g -P a rtic le A i r P re h e a te r ( 0 . 0 4 2 i n . Blowout) $ 1 7 .0 x IO6 Fuel Source C a p i t a l Cost 2 7 . 5 x IO6 2 7 . 5 x IO 6 TOTAL C a p i t a l 4 2 . 9 x IO 6 4 4 . 5 x IO 6 Cost TOTAL Annual Cost (in c lu d e s f u e l source) $ 5 . 8 x IO6 $ 6 . 4 x IO 6 COMMENTS A number o f im p o rta n t p o in ts should be made in c o n s id e r in g these two o v e r a l l 1) designs: The l e v e l o f te c h n o lo g y o f th e c o r e d - b r ic k a i r p r e h e a te r design i s much h ig h e r than t h a t o f th e f a l l i n g - p a r t i c l e d e s ig n . a i r p re h e a te r The u t i l i t y o f th e c o r e d - b r ic k design has been demonstrated i n a number o f a p p l i c a t i o n s , and an abundance o f design d a ta i s a v a i l a b l e . The f a l l i n g p a r t i c l e d e s ig n , however, has not y e t been dem onstrated. 2) Since th e f a l l i n g - p a r t i c l e d e s ig n .o u tp u ts a s te a d y a i r flo w r a t e a t a u n iform te m p e r a tu r e , o p e r a t io n o f th e MHD combustor and duct would p ro b a b ly be smoother than w ith th e c y c l i c - 32 - o p e r a tio n s o f th e c o r e d - b r ic k d e s ig n . 3) The need f o r c o n s t a n t - o p e r a t in g w ill v a lv e s in th e c o r e d - b r ic k in c re a s e annual m aintenance costs as a r e s u l t o f v a lv e breakdown and a t t r i t i o n . v a lv e s w i l l W ith th e f a l l i n g - p a r t i c l e d e s ig n , be used o n ly f o r s t a r t u p , shutdown, and flo w r a t e c o n tro l. 4) P a r t i c l e replacem ent through a p p r o p r ia t e access p o r ts (p ro b a b ly i n th e p a r t i c l e r e c y c le system) i n th e f a l l i n g - p a r t i c l e design w i l l be a r e l a t i v e l y e f f o r t l e s s p ro c e d u re , r e q u i r i n g no equipment shutdown and d i s m a n t l i n g . C o r e d -b r ic k replacem ent i n th e c o r e d - b r ic k d e s ig n , however, w i l l shutdown and complete d is m a n t l i n g . r e q u i r e column CAPITAL COST COMPARISON OF DIRECT AND INDIRECT-FIRED AIR PREHEAT SYSTEMS C a p ita l c o s t data f o r d i r e c t - f i r e d c o r e d - b r ic k and f a l l i n g - p a r t i c l e a i r . p re h e a t systems was s u p p lie d by W. E. G e n e tti and R. L. Mussulman ( 1 2 ) . These d a ta a re compared w i t h i n d i r e c t - f i r e d design d a ta i n T a b le V I . Only th e 0 .0 4 2 i n . blowout design o f t h e f a l l i n g - p a r t i c l e a i r p r e h e a te r i s c o n s id e re d . Annual c o s t d a ta f o r d i r e c t - f i r e d a i r p r e h e a t systems was not a v a i l a b l e . TABLE V I . CAPITAL COST COMPARISON OF DIRECT AND • ■ INDIRECT-FIRED AIR PREHEAT SYSTEMS DIRECT-FIRED O v e r a ll C a p i t a l Cost INDIRECT-FIRED F a llin g -P a rt. C o r e d -B ric k F a llin g -P a rt.- C o re d -B ric k $ 3 0 .4 x IO6 $ 3 1 .3 x IO 6 $ 4 4 .5 x IO6 $ 4 2 .9 x IO 6 As can be seen, i n each design case th e c a p i t a l f i r e d a i r p r e h e a t system i s about 75% o f t h e c a p i t a l c o s t o f the d i r e c t c o s t o f th e i n d i r e c t - f i r e d system. COMMENTS In comparing th e o v e r a l l designs o f d i r e c t and i n d i r e c t - f i r e d a i r p r e h e a t systems, the f o l l o w i n g comments can be made: I) T o t a l coal f u e l costs f o r th e o v e r a l l . power g e n e r a tin g complex w i t h th e i n d i r e c t - f i r e d a i r p re h e a t system w i l l be - 34 n e a r l y double those o f th e o v e r a l l a i r p r e h e a t. complex w i t h d i r e c t - f i r e d However, s in c e the therm al energy o f th e MHD exhaust gas w i t h i n d i r e c t - f i r e d a i r p r e h e a tin g i s not used t o preheat a i r , a g r e a t e r percentage o f the t o t a l t h e complex w i l l power o u tp u t o f be produced by th e bottom ing p l a n t . In a d d i t i o n , a l a r g e r bottom ing p l a n t would be a b le t o u t i l i z e th e therm al energy o f th e exhaust gas l e a v in g th e i n d i r e c t f i r e d a i r p r e h e a t system. 2) S ince th e environm ent w i t h i n th e d i r e c t - f i r e d system design i s much more c o r r o s i v e than t h a t o f th e i n d i r e c t - f i r e d system d e s ig n , annual maintenance costs can be expected to be s u b s t a n t i a l l y h ig h e r w ith the d i r e c t - f i r e d system. 3) A few p o in ts i n o v e r a l l thermodynamic e f f i c i e n c y a r e l o s t in th e power g e n e r a tin g complex using an i n d i r e c t - f i r e d p r e h e a t s y s te m .( 5 , 8 ) . a ir APPENDICES - APPENDIX A: I. 2. 36 - PREDICTION OF MATERIAL PROPERTIES C o n s titu e n ts o f Coal Gas, Mole % CO CO2 H2 N2 O2 CH^ 8 .6 1 .5 5 2 .5 3 .5 0 .3 3 1 .4 H e a tin g V a lu e , B T U /ft^ 575 Products o f Coal Gas Combustion CO2 H2O N2 Mole % 8 .7 7 2 1 .2 3 7 0 .0 0 W eight % 1 4 .1 5 14.01 7 1 .8 5 (A v e . M ol. W t. = 2 7 . 2 8 ) Flame Temp. = 3665°F Notes on p r e d i c t i o n o f exhaust gas and a i r p r o p e r t i e s : a) V i s c o s i t y and therm al c o n d u c t i v i t y o f gaseous m ix tu re s were found a t given te m p e ratu re s assuming t h a t : pmix ~ I ^ i y i - ' *Snix ~ |^i*S' where y .. = mole f r a c t i o n o f component i . V i s c o s i t i e s and thermal c o n d u c t i v i t i e s were c a l c u l a t e d a t a number o f te m p e r a tu r e s . d a ta were then f i t t o th e f o l l o w i n g general e q u a tio n s : B - m i x * AT b) mix The h e a t c a p a c i t y o f th e exhaust gas was assumed to"obey the f o l l o w i n g e x p re s s io n : m + X twH2O cPH2O + Wr 'PC0, The - 37 - w a t e r v a p o r, and carbon d i o x i d e , r e s p e c t i v e l y . The X is a f a c t o r in tro d u c e d t o account f o r d i s s o c i a t i o n o f HgO and COg in the gas a t high te m p e r a tu r e s . X i s e s tim a te d from h e a t c a p a c i t y data c a l c u l a t e d f o r coal combustion gases and the com position o f such gases. S ince th e w e ig h t f r a c t i o n s and h e a t c a p a c i t i e s o f a l l gas c o n s t i t u e n t s a re known, th e f a c t o r X can be c a l c u l a t e d a t a number o f te m p eratu res (1 5 ). Cp^ was c a l c u l a t e d f o r a number o f te m p e ra tu re s , and a curve was fit t o th e r e s u l t i n g data ( 1 4 , 1 5 ) . fo llo w e d by W. E. G e n e tti A s i m i l a r procedure was in d e ve lo p in g the h e a t c a p a c ity e q u atio n fo r hot a i r . c) The Id e a l Gas Law is assumed a c c u r a te in th e d e n s it y e q u a tio n . 3. Hot Exhaust Gas P r o p e r t ie s • Temperature Range: P = 3 7 . 4 P /T T = °R , k = 1 .2 3 4 x 10 ii = 1 .5 2 x 10 2000 - 4000°F - 4 r 778 - 7 -J-.684 P = ATM, p = l b m / f t 3 T=°R, k= B T U /h rft°F T = °R , y = Ib m /fts e c Cp = - . 0 2 6 0 + 5 .1 0 0 x IO "6 T + 2 .9 6 7 x IO- 8 T "2 T = °R - 4. 38 - Hot A i r P r o p e r t ie s Temperature Range: P = 3 9 .1 2 P /T 1500 - 3500°F T = °R , Q -4 t .5 8 3 k = 4 .7 3 6 x TO y = 6 .0 7 x 10 - 7 -J-.513 P = ATM, p = l b m/ f t T = °R , k = B T U Z h rft0F T = °R , y = I b mZ f t s e c 3 C = .2261 + 2 .8 2 9 5 x IO - 5 T - 2 .2 8 6 x IO - 9 T2 P T = °R , 5. Alumina ( P a r t i c l e ) Note: Cp = BTUZlbm0F P r o p e r t ie s The alumina p a r t i c l e used i n t h i s design i s a t a b u l a r alumina pro d u c t o f th e Aluminum Company o f Am erica. pure fused a lu m in a . It is 99.5% The p a r t i c l e d ia m e te r range i s 0 .0 3 6 in - 0 .0 5 in . P = 232 I b mZ f t 3 k = 2 .9 1 + 2 .9 1 8 x 10- 6 ( T - 2 7 6 0 ) 2 - 1 . 5 6 1 1 x 10- 1 2 ( T - 2 7 6 0 ) 4 T = °R , k = B T U Z h rft0F Cp = .25667 + 1 .6 3 3 9 x IO - 5 T 6. T = °R , Cp = BTUZlbm0F I n s u l a t i o n Data The i n s u l a t i o n i s o f f o u r b a s ic ty p e s . A v c o -E v e r e tt Research L a b o r a t o r i e s , This d a ta was s u p p lie d by I n c . , E v e r e t t , Mass ( 5 ) . - 39 M fg . (I) Norton Type Thickness in . AH-199B 3 k, B T U /h rft°F ■ C o s t, $ Z f t 3 1 .7 9 140 ( 2 ) Norton AN-599 4 .5 .894 120 ( 3 ) J o h n s -M a n v ille JM -3000 4 .5 .292 100 ( 4 ) J o h n s -M a n v ille JM-23 4 .5 .119 80 7. MHD Coal Exhaust Gas P r o p e r t ie s These p r o p e r t i e s o f th e exhaust gas from an MHD duct were developed by W., E. G e n e t t i . p = 4 0 .9 4 6 P/T T = °R , P = ATM, k = .000872 T= k = B T U Z h rft0F p = 6 .0 8 4 x 10 Cp = .848446 - -7 jk °R , T ' = °R, I b mZ f t 3 p = I b mZ f t s e c .0004834T + 1 .0 1 1 0 6 x IO - 7 T2 T = ° R, 8. p = F o llo w in g is a graph ■; Cp == BTUZlbm0F F ig u re 8,, o f e n th a lp y o f MHD coal exhaust gas v s . te m p e r a tu re , e s tim a te d by Avco E v e r e t t Research L a b o r a to r ie s In c . 40 - 1300 1200 1100 1000 900 800 700 600 500 400 300 200 100 0 500 1000 1500 Gas Temp -° K 8. ENTHALPY OF MHD COAL EXHAUST GAS vs. TEMPERATURE - 41 APPENDIX B: I. GENERAL DESIGN BALANCES Composition o f Montana S ub-bitum inous Coal P roxim ate A n a ly s is (6 ) Weight P e rc e n t (as r e c e i v e d ) M o is tu re 2 4 .3 V o l a t il e M a tte r 2 8 .6 F ixed Carbon 3 9 .6 Ash 7 .5 100.0 U lt im a t e A n a ly s is (as r e c e iv e d ) Ash 7 .5 S u lfu r 0.8 Hydrogen • Carbon . 6.1 5 2 .2 0.8 N itr o g e n 3 2 .6 Oxygen 100.0 H ig h e r H e a tin g Value 2. 8944 B TU /lb^ A i r I n p u t t o 400 MW (T h e rm a l) MHD Combustor Heat In p u t = 400 x IO 6 W att I x 3 .4 1 4 BTU h r w att = 1 .3 6 5 6 x IO9 BTU/hr ■ lb Coal Rate = 1 .3 6 5 6 x IO 9 BTU/hr x - g g ^ 'BTU = 1 ^527 x 1()5 _ 42 - Formula f o r M o is tu re and Ash-Free C o a l : CH. 8 ° . 0 8 N. 0 2 S .00 8 Combustion R e a ctio n : CH. 8 ° . 0 8 N.0 2 S .00 8 + 1 .1 7 8 0 2 -> CO2 + .4 H2O + .02N0 + .OOSSO2 Assume m o le c u la r w e ig h t o f coal = 1 4 .6 2 (m o is tu re and a s h - f r e e ) A i r re q u ire m e n t f o r coal combustion: 1 .1 7 8 mole O2 mole coal x mole coal 1 4 .6 2 lb Coal x 32 l b O9 _______ _ £ mole O2 100 lb A i r 21 lb O2 = 1 2 .2 8 lb A i r l b coal (m o is tu r e -a s h f r e e ) The m oistu re and a s h - f r e e coal r a t e i s : ( 1 . 5 2 7 x IO5 ) ( . 6 8 2 ) = 1 .0 4 1 x IO 5 I b / h r Thus, th e combustion a i r r a t e i s : A i r Rate = 1.0 4 1 x IO5 l b coal hr = 1 .2 7 9 x IO5 lb x 1 2 .2 8 lb a i r l b coal a ir/h r H eat T r a n s f e r Rate to A i r i n P r e h e a te r 3100°F qa i r Wa i r z ITOO0F Cpa i r 1 .2 7 9 x IO u l b a i r dT x 4 0 3 .0 4 BTU 5 .1 5 5 x IO8 BTU/hr - 43 - APPENDIX C: I. MODEL DEVELOPMENT OF FALLING-PARTICLE AIR P a r t i c l e S iz e D i s t r i b u t i o n Blowout No. F r a c t io n 0 .0 4 2 i n . . D ia m e te r, i n . 0 .0 5 0 .0 1 1 0 .0 5 0 .0 1 8 2 0 .0 4 6 0 .1 2 8 0 .0 4 6 0 .1 0 3 3 0 .0 4 4 0 .2 5 6 0 .0 4 5 0 .2 0 6 7 0 .0 4 2 0 :2 5 6 0 .0 4 4 0 .1 5 5 0 0 .0 4 0 0 .1 9 3 0 .0 4 3 5 0 .1 0 3 4 0 .0 3 9 .0 .1 0 5 0 .0 4 3 0 .1 5 5 0 0 .0 3 7 5 0 .0 5 1 0 .0 4 2 0 .2 5 8 4 0 .0 3 8 i n . D ia m e te r, i n . 2. PREHEATER Blowout No. F r a c t io n Term inal V e l o c i t y and Chamber D iam eter C a l c u l a t i o n Term inal v e l o c i t y is c a l c u l a t e d using th e general e q u a tio n f o r s p h e r ic a l p a rtic le s developed i n McCabe and S m ith , U n i t O perations o f Chemical E n g in e e r in g , Second E d i t i o n , pp. 1 64 -1 6 9: U uT I 9 ps } 5 / 7 1 8 .5 } 3 Now, assuming t h a t d8 / 7 2 /7 P u 3 /7 m u ; = U j f o r th e s m a l l e s t p a r t i c l e a t the h ig h e s t te m p e ra tu re : (2) Wa - UApA A , WA/U Ap = , 0 . 2 / 4 D. ir (3 ) Ub . p 44 W ith a l l gas p r o p e r t i e s e v a lu a te d a t th e h ig h e s t chamber te m p e r a tu re . A i r Chamber: ( p r o p e r t i e s e v a lu a te d a t T = 3560°R) 0 .0 3 8 i n . Blowout Uy, f t / s e c 1 8 .3 4 As an i n i t i a l - 0 .0 4 2 i n . Blowout UA , f t / s e c D i, f t 1 8 .3 4 1 1 .8 4 U y ,f t / s e c ‘ . 2 0 .8 8 U ^ ,f t / s e c 2 0 .8 8 D i, f t 1 1 .1 e s t i m a t e , no h e a t losses were assumed; thus qa i r = qgas = 2 .5 7 8 x IO 8 BTU/hr Gas Chamber: To o b ta in th e gas mass f lo w r a t e (w g ), the f o l l o w i n g e xpre s sion was used: 3500°F qgas = Wg -f ZSOO0F CpG dT The 2 3 0 0 °F e x i t te m p e ra tu re o f th e gas is a ls o an e s t i m a t e , which w i l l s ubse que ntly be r e f i n e d . From t h i s c a l c u l a t i o n , Wri = 6 .5 2 x IO 5 I b / h r 9 Now, i n analogous fa s h io n t o th e a i r chamber d ia m e te r c a l c u l a t i o n s th e gas chamber d ia m e te r i s c a l c u l a t e d . a t T = 3 5 0 0 °F .= 3 9 6 0 °R ). (Gas p r o p e r t i e s a r e developed 45 - 0 .0 3 8 i n . Blowout 0 .0 4 2 i n . Blowout Uy = Ug, f t / s e c D ij f t . 1 3 .3 0 1 5 .1 Note: • Uy = Ugj f t / s e c D ij f t . 1 5 .1 4 1 4 .2 Since th e maximum te m p e ra tu re o f t h e . gas chamber occurs a t th e bottom o f the chamber, t h i s i s where th e te r m in a l c a l c u l a t i o n s were made. v e lo c ity However, s in c e v e l o c i t i e s a t t h e to p o f the column a r e d e s ir e d ( t o be analogous to th e a i r column d a t a ) , th e above v e l o c i t i e s a re a r e s u l t o f m u l t i p l y i n g th e bottom te r m in a l by th e f a c t o r 2760oR /3 9 6 0 oR, assuming th e I d e a l v e lo c itie s Gas Law to ho ld i n t h i s te m p e ratu re range. 3. D e te r m in a tio n o f I n s u l a t i o n Thickness The general e q u a tio n f o r h e a t t r a n s f e r between th e gas i n the column and am bient a i r is : " ' V - Uo <Tg - U (5 ) where Tg = gas te m p e ratu re Too = am bient a i r te m p e ratu re Uq = o v e r a l l h e a t t r a n s f e r c o e f f i c i e n t based on o u ts id e column area q /A 0 = h e a t f l u x D R,w a ll ( 6) - 46 - h. = in n e r w a ll c o n v e c tiv e h e at t r a n s f e r c o e f f i c i e n t h„ = o u te r w a ll c o n v e c tiv e h eat t r a n s f e r c o e f f i c i e n t o (7 ) '4 N a tu r a l c o n v e c tio n is assumed between th e o u te r w a ll r e s i s t a n c e to heat t r a n s f e r o f th e s t e e l and a i r . The s t r u c t u r e on th e o u ts id e o f th e i n s u l a t i o n i s assumed small r e l a t i v e to the i n s u l a t i o n r e s i s t a n c e , and i s n e g le c te d . ( 1 0 ) , th e c o r r e l a t i o n f o r th e o u te r From P e r r y 's c o n v e c tiv e h e at t r a n s f e r c o e f f i c i e n t i s : 1 /3 ( 8) H0 - 0 . 1 8 (Tw - T J f o r GrPr > IO^ S ince Tw i s unknown, Tw is .n e e d e d as a fu n c t i o n o f T , the gas te m p e ra tu re : From e q u a tio n 6: (9 ) Now, s in c e q/A Q = h0 (T w - Too) , (Tg - U = —Sr— <T„ t h i s can be equated t o e q u atio n 5: -U do) - 47 - S u b s t i t u t i n g e q u a tio n 9 i n t o e q u a tio n 10 g iv e s : <Tg - T J = ( I + h0(£ V x^ M ( H) T w -TJ S u b s t i t u t i o n o f e q u a tio n 8 i n t o e q u a tio n 11 g i v e s : 4 /3 ■ (Tg " U - <TW - T J + -18 (Tw - T j An ( =Rwa11 + ^ - ) ( 12) - or 4 /3 <Tg - T J = (Tw - T J 'I ln (— ) where + - 18 ( T w - T J ln (% -) rI w a ll NOTE: 4. In t h i s design h. l n ( - % r — ). + (13) ( £Rwall + - n A - + i i ln (— z r~ ) - r ] is assumed t o be 10 B T U / h r f t ° F . Wall Heat Loss D e te rm in a tio n In itia lly , Tw i s found f o r v a r io u s values o f Tg using e q u atio n 12 in Appendix C -3 . 5 in Appendix C -3 . Then ( cIZA)-Joss is found f o r these values using e q u a tio n A curve i s then f i t t o th e d a t a , r e s u l t i n g in t h e f o l l o w i n g e q u a tio n : ( q / A ) i oss = - 4 4 . 9 + .0612 Tg , Tg = °R (14) ( q / A ) i oss = B T U / h r f t 2 5. O v e r a ll Heat Loss D e te rm in a tio n Using e q u a tio n 14, an average h e a t lo s s i s found f o r each chamber: - 48 - (q /A ), = 1 1 6 .3 La i r h rft (q /A ), = 1 4 6 .3 — Lgas h rft^ Now, assuming t h a t L „ =c = 20 f t and L . = 30 f t and D gaS a lr °gas (1 4 .2 + 7 .0 ) = 2 1 .2 f t = (QZA)1 1T(D0 ) ( L ) % q. , D = ( 1 1 . 1 + 7 . 0 ) = 1 8 .1 f t °a ir (15) = ( 1 4 6 . 3 ) (m )( 2 1 . 2 ) ( 2 0 ) = 1 .9 5 x IO5 BTU/hr gas q, = ( 1 1 6 . 3 ) ( it) ( 1 8 . 1) (3 0 ) = 1 .9 8 x IO 5 BTU/hr La i r q, = % ( 3 . 9 3 3 x IO 5 ) = 1 .9 7 x IO 5 BTU/hr re c y c le The o v e r a l l h e a t l o s s , then i s : q, ^ o v e ra ll = ( 1 . 9 5 + 1 .9 8 + 1 .9 7 ) x IO 5 = 5 . 9 x IO5 BTU/hr An o v e r a l l energy balance g iv e s : 3960°R ga i r + gIoss ~ ggas ^g ^T q ^Dgc*^ Tq i s the o n ly unknown i n t h i s e q u a tio n : T = O 2790°R = 2330°F which agrees c l o s e l y w i t h th e o r i g i n a l e s t im a te f o r th e gas e x i t te m p e ra tu re o f 2 30 0 °F . An energy balance between th e s o l id s and th e a i r i n th e a i r chamber g iv e s : 49 - cIsoIids (1 7 ) cIa ir + a ir 3760°R Cn dT = ( 2 . 5 7 8 x IO 8 + 1 .9 8 x IO 5 ) BTU/hr Ps Ws ^2475°R which g iv e s Wg = 6 .5 4 x 10 6. Ib /h r Development o f Design Equations Equations w i l l be developed f o r th e a i r column; thus Tg > Tg a t any p o i n t in th e column. A ls o , i t i s assumed t h a t X ( v e r t i c a l p o s itio n ) equals 0 a t th e to p o f each column. I) Energy Balance Between P a r t i c l e s and A i r across D i f f e r e n t i a l Time Element: wSc Pst S l e + i6 - wS=P5t where Ag = t o t a l S I9 - (1 8 ) - " V tS - V s u r fa c e area o f p a r t i c l e s f a l l i n g i n tim e elem ent Ae (Particle Vol. in ae) ( -s^ l flrea Volume ) p a rtic le 6W_ ie )(- (1 9 ) d PpS 6 wScP5 - 6 <T, - Ts> - 50 - ?Ts C P TS rTS Note: In a l l x -v e rtic a l Ps rlv ( 20) (T 9 - V design e q u a t i o n s , the independent v a r i a b l e is to be d is ta n c e . Thus, to tr a n s fo r m th e above e q u a t io n . _ / dTs \ / ' dT_ ^ jQ / de \ ' H v 6h d Pps cPsv dx ( 21 ) de * " Ts^ ( T h i s i s program s ta te m e n t 9 3 . 0 0 ) 2) X - D i r e c t i o n Momentum Balance on One P a r t i c l e : ma. 2T ( x - d i r e c t i on fo r c e s ) mg ma X = S - de where - F. Fd gc TTdP3 TrdD pS S - Fd9c is th e drag fo r c e on th e p a r t i c l e c ro s s -s e c tio n a l From ( 9 ) , area. ( 22) 9 C d Pg ( V W ) 2 Ac Fd = ------- - | g (2 3 ) ( 9 ) and Ac is th e p a r t i c l e - A3 a; de Pg(V+U)' ps 9 ■ cC 3CPpg g - de 51 - d 2g A fi- (2 4 ) (v+u)‘ 4 dPpS A g a in , s in ce th e independent v a r i a b l e x i s d e s i r e d . de de _dV_ (2 5 ) de __ g___________ 3CD °q (V+U) dx ^ AdppgV (26) (program s ta te m e n t 9 5 .0 0 ) This e q u a t io n , when i n t e g r a t e d , giv es V as a fu n c t i o n o f x . can be i n t e g r a t e d again t o g iv e e as a f u n c t i o n o f x: de = dx 3) I V O v e r a ll (27) (program s ta te m e n t 9 6 .0 0 ) Energy Balance Across D i f f e r e n t i a l Column Element AX: T In s u l. In s u l. X+AX I 52 [WgCpg( T g " J r e f ^ x + A x - (q/A)[_ Ir (Dc + 26) Ax - " Wg gCpg g " ^ e f j l X3 r g'( T g = - h s ( P a r t i c l e S u rfa c e Area i n Ax) (T 5 - T g) (28) where p a r t i c l e s u r fa c e area i n Ax d- 2 V o l. p a rtic le de GWsAx 6 de P s dp Thus, e q u a tio n 28 becomes (q / A ) , ir(D + 26) 6 W5 - h, -------------Now, s o l v i n g e q u a tio n 20 f o r -W - ( Ts - Tg) (2 9 ) (T 5- T g ) and s u b s t i t u t i n g t h i s v a lu e i n t o e q u a tio n 29: dT_ ( q / A ) , ir(D +26 ) WsCps (3 0 ) WgCpg % % The f i r s t term on th e r i g h t i n t h e above e q u a tio n i s la b e l e d XX i n program s ta te m e n t 1 0 4 .0 0 . program s ta te m e n t 9 9 . 0 0 . The second term is la b e l e d YY ( 7 ) in T h e i r sum and the r e s u l t i n g d i f f e r e n t i a l e q u a tio n are program s ta te m e n t 105.00. - 7. D e f i n i t i o n s o f Program V a r ia b le s and Program L i s t i n g (lis te d in o r d e r o f appearance in program w i t h s ta te m e n t number) Statem ent No. M: TEMPO: 4 .0 0 5 .0 0 53 - - ' , s iz e it e r a t io n ' f o r p a r tic le s (M = 1 - 7 ) gas te m p e ratu re a t to p o f chamber,°R TP: . p a r t i c l e te m p e ra tu re a t to p o f chamber,°R 6 .0 0 ,7 .0 0 A , B : . c o n stan ts in gas v i s c o s i t y e q u a tio n 8 .0 0 ,9 .0 0 C,D: c o n stan ts i n gas therm al c o n d u c t i v i t y e q u a tio n 1 0 .0 0 F: c o n s ta n t i n gas d e n s i t y e q u a tio n 1 1 .0 0 P: chamber p r e s s u r e , atm 1 2 .0 0 UG: gas v e l c o i t y a t top o f chamber, f t / s e c 1 3 .0 0 ,1 4 .0 0 1 5 .0 0 AB ,BB5BC: ' constants in gas h e a t c a p a c ity e q u a tio n 1 6 .0 0 OS: . o v e r a l l 1 7 .0 0 WO: 1 8 .0 0 W: chamber d ia m e te r , gas mass flo w r a t e , Ib /h r p a r t i c l e mass flo w r a t e , 2 0 . 0 0 - 2 6 . 0 0 DP(M): d ia m e te r o f p a r t i c l e 3 1 . 0 0 - 3 7 . 0 0 FR(M): number f r a c t i o n o f t o t a l 4 3 .0 0 . 10: in te g r a t io n order 4 4 .0 0 . VP: in itia l 45. DO4 6 . 00 AA5AG: in c lu d in g i n s u la t i o n , f t Ib /h r 1M1, f t p a r tic le s o f s iz e p a r tic le v e lo c ity constants in h e a t loss e q u a tio n 4 8 .0 0 V(M): v e lo c ity o f p a r t i c l e o f s iz e 4 9 .0 0 T (M ): t i m e , seconds •j 1M1, f t / s e c 1M1 - 54 - 5 0 .0 0 TS(M): te m p e ratu re o f p a r t i c l e s o f s i z e 5 5 .0 0 WS(M): W * FR(M) - - 7rD^M)3 p_ 1M1 90R W FR (M )D (M )' 7 WBlTl Zc' FR(M) M=I = mass flo w r a t e o f p a r t i c l e s o f s i z e 1M1, I b / h r 7 9 .0 0 TG: 8 0 .0 0 DENG: gas d e n s i t y , l b / f t ^ 8 1 .0 0 DENS: p a r t i c l e d e n s i t y , 232 l b / f t ^ 8 2 .0 0 V IS: 8 3 .0 0 KG: 8 4 .0 0 U: gas v e l o c i t y a t te m p e ra tu re TG, f t / s e c 8 5 .0 0 Gr (V is c o s ity /d e n s ity )(3 6 0 0 ), f t ^ /h r 86.00 PR: 88.00 TH: 9 0 .0 0 R(M): gas. te m p e r a tu re ,° R gas v i s c o s i t y , I b ^ / f t s e c gas therm al c o n d u c tiv ity , B T U /h rft°F (gas h e a t c a p a c i t y ) ( v i s o c i t y ) / ( c o n d u c t i v i t y ) , dimen­ s io n le s s p a r t i c l e thermal c o n d u c t i v i t y , B T U / h r f t ° F p a r t i c l e Reynolds number "of p a r t i c l e s i z e , 1M ', • dim ensionless 9 1 .0 0 H: p a r t i c l e s u r fa c e c o n v e c tiv e h e a t t r a n s f e r c o e f f i c i e n t B T U / h r f t ^ ° F , from: 9 2 .0 0 9 4 .0 0 9 4 .2 1 Z: CD: Nu = 0 . 2 R e ' ^ P r ^ ^ (R e fe re nce 13) p a r t i c l e h e a t c a p a c i t y , BTUZlbm0F drag c o e f f i c i e n t , dim ensionless (th ree d iffe r e n t . ■ e xpressions f o r drag c o e f f i c i e n t are g iven f o r th r e e d i f f e r e n t ranges o f Reynolds number) 9 7 .0 0 YZ: 9 8 .0 0 S (M ): gas h e a t c a p a c i t y , B T U /lb m°F s t r e s s on p a r t i c l e o f s i z e 1M1, psi - 9 9 .0 0 YY(M): 55 - h e a t t r a n s f e r r a t e between p a r t i c l e s o f s iz e 1M and gas, BTU/hr 1 01.00 TEMPP( 7 ) : w eig h ted average p a r t i c l e te m p e ra tu re f o r a l l p a rtic le s 1 03 .00 Q: q /A ( h e a t lo s s t o w a l l s per u n i t o u ts id e a r e a ) , B T U /h rft2 1 04.00 NOTE: . XX: t o t a l h e a t loss from chamber w a l l , BTU/hr For i n f o r m a t i o n on general F o r tr a n fo rm a t and s u b r o u tin e s , see r e f e r e n c e ( 1 8 ) . I* OOO 2. 000 3.000 4.000 4. 500 5.000 6.000 7.000 8. 000 9. 000 10.000 11.000 12.000 i3;ooo 14.000 15.000 16.000 17.000 18.000 19.000 20.000 21.000 22.000 23.000 24.000 25.000 26.000 31.000 32:000 33. 000 34:000 35:000 36:000 37:000 42.000 NAME LIST DIMENSION. TSC7), V(7), WS(7), R(7), DTS(7), TEMPP(0:7) 1DV(7),T(7),DT(7),DP(7),S(7),FR(7),YY(0:7),UBC0:7) TEMPO= 3560« YY(O)=O. T P = 3760. A = . 000000607 B = . 513 C = :0004736 D = . 583 F= 39. 12 P= 8. U G = 2 0 . 88 A B = . 2261 BB= . 000028295 B C = - . 000000002286 .DS= 18. I UG= 6. 395E5 U = 6 . 54E5 REAL KG DPC I) = .05/12 DPC 2 ) = . 046/12 DP C3)= . 0 4 5 / I2 DPC4)=.044/12 DP CS)=.0435/12 DP C6) = .043/12 . DPyC 7) = . 042/12 FRC I)=.0182 FR C2) = . 1033 FR C3) = :20 67 F R C4) = . I550 FR C5) = « 1034 FR(6) = « I550 FR C7) = .2584 INPUT DX,X,PI,PF 43V000 44.000 45« OOO 46. OOO 47. OOO 48.OOO 49.000 50-000 51.000 52.OOO 53.000 54.000 55." 000 56 V OOO 57.000 58» 000 59.000 60.000 6 1."000 62.000 63.000 64.000 65.OOO 66.000 67.000 68.000 69.000 70.000 10=2 ' VP=» I 149 12 I 900 901 902 903 A A = - 4 4 o9 A G = - 0612 D0 149 M= I* 7 V(M) = VP T(M) = O. TS(M)=TP VB(O) = Oo V B ( M ) = W B (M-I)+FR(M)*(DP(M)**3) CONTINUE " D0 12 M= I/ 7 WS(M)=FR(M)*(DP(M)**3)*V/VB(7) CONTINUE INPUT WRITE ( 108, 900) FO RMAT ( 'POSITION', 4X> *TS( I ) ', 7X, fTS (2) *, 7X, I *TS(3) ', 7X, ^ 5 ( 4 ) r, 7X, rTS(S) r) "WRITE” (108/901) F O R M A T < *TS (6) ", 7X, 'TS(7)',7X, 'TS( S ) ',7X, 'TS(9) ’, 7X, l'TS(10)'/6X,'TS(ll)') "WRITE (108, 902) FORMAT ( 'GAS TEMP', 4X, 'V(I)', 8X# 'V(2) ', 8X, 'V(3) 8X, I *V (4 ) ', 8X, 'V (5 ) ' ) ~ "WRITE (108,9035 _ FORMAT ( 'V(6) ', 8X, 'V(7) ', 8X, 'V(S) ', 8X, 'V(9) ', 8X, I 'V ( I O ) ',7X,'V ( I l ) '5 "WR I T E " (108/904) " I \ 9 06 FORfcAT C' STRESS ( I ) ' , 3 X STRESS ( 2 ) ' , 3 X , ' STRESS ( 3 ) ' , 3 X , I ' STRESS C4 )* , 3 X V STRES'S ( 5 5* > 3 X * * STRESS ( 6 ) ' ) ^R I TE ( 1 0 8 , 9 0 5 ) F ORfcAT ( ' S TRESS (7 ) ' , 3 X , ' S T R E S S ( 8 ) ' , 3 X , ' STRESS ( 9 ) ’ , 3 X , I * STRESS ( 1 0 ) ' , 2 X , ' S T R E S S ( 1 1 ) ' , 2 X , ' PRANDL NUf c ' ) WRI TE ( 1 0 8 , 9 0 6 ) FORf cATCf cAX REY NUfc' , I X , ' fcIN REY KU fc ' , I X , ' PART T E f c P ' , 3 X , 7 8 .000 79 .000 80 . 0 0 0 2 0 81 . 0 0 0 82 . 0 0 0 83.000 84 . 0 0 0 85 . 0 0 0 86 . 0 0 0 87 . 0 0 0 88.000 89 . 0 0 0 90 . 0 0 0 91 . 0 0 0 92 . 0 0 0 93 . 0 0 0 93.100 93 . 2 0 0 94 . 0 0 0 94.100 94 . 2 0 0 9 9 94 . 2 0 5 94 . 2 1 0 8 0 0 9 4 . 3 0 0 98 95 . 0 0 0 I ' GAS V E L ' , 5 X , ' f c A X T I f c E ' , 4 X , ' f c I N T I f c E ' ) TG=TEfcPG ' ' DENG = F * ( P / T G ) DENS = 2 3 2 . ' U IS = A * ( T G * * B ) HG =C * ( TG * * D ) U=UG * ( i’G /TEfcPG ) G = (A/C ) * ( T G * * ( B - D ) ) *3 600 • PR=G*(AB+BB*TG+tiC*(TG**2 ) ) z DO 13 fc = l , 7 ' T H = 2 . 91 + ( 2 . 9 1 8 E - 6 ) * ( TS ( fc ) - 2 7 6 0 . ) * * 2 I - ( I .56 I I E -12 ) * ( T S (fc)-27 60 . ) * * 4 R ( M ) = D E NG * ( U +U (fc) ) * DP (fc ) / U IS H = KG * ( . 2 * ( R ( f c ) * * . 7 ) * ( P R * * . 3 3 4 ) ) / D P ( M ) £ = • 2 5 6 6 7 + . 0 0 0 0 1 6 3 3 9 * r S (fc) D T S (f c) = . 0 0 1 6 7 * h * ( T G - T S ( f c ) ) / ( D E N S * D P ( fc ) * Z * V ( M ) ) ' I F ( R ( M ) . LE .1 . ) , G 0 TO 9 9 I F ( R ( f c ) .GE . 5 0 0 . ) , G O TO. 8 0 0 CD = I 8 . 5 / ( H ( f c ) * * . 6 ) ' ! GO TO 98 CD= 2 4 . / R ( M ) ' GO TC 98 C D = . 44 I i XXX —:0 • DV ( f c ) = 3 2 .-17 / V ( f c ) - . 7 5 * C D * ( ( V( f c) +( J ) * * 2 ) *DE NG / (DENS * ( DP (fc ) ) 7 I .000 7 2 .000 7 3. . 0 0 0 7 4 .000 75 . 0 0 0 7 6 .000 77 . 0 0 0 90^ 905 * U CK ) ) 96 . 0 0 0 97 . 0 0 0 98.000 99-000 100 . 0 0 0 101 . 0 0 0 102 . 0 0 0 103 . 0 0 0 I 04«000 I 05 . 0 0 0 I 06 . 0 0 0 107 . 0 0 0 108.000 109.000 I 10 . 0 0 0 I I I .000 I I 2 .000 I 13 . 0 0 0 I 14.000 I 15 - 0 0 0 I 16 . 0 0 0 I 17 . 0 0 0 I I 8.000 I I 9-000 120*000 121 . 0 0 0 1 22 . 0 0 0 DT ( M ) = I • /.V CM ) YZ=AB+BB *TG +BC* CTG * * 2 ) S ( M) =34 . 6 * H * D P < M ) * ( T S ( M ) - T G ) / T H Y Y ( K ) = Y Y ( K - 1 ) +DTS ( M ) W S ( M ) * Z / (WG * Y Z ) PEMPP ( 0 ) = 0 • TEMPP (M ) =TEt-PP ( M- V ) +WS ( M ) *TS ( M ) /W 13 COMP I MJE Q = A A +AG =KTG+TEt - PP (7 ) ) / 2 • XX = 3 . 1 4 * Q * D 5 / ( . v G * Y Z ) DTG = X X + Y Y (7 ) C AL L PHNPE (P I , P E , N E , X , TS ( I ) , TS ( 2 ) , TS ( 3 ) CALL PHN PR ( 0 , PS ( 6 ) , T S (7 ) , 0 . , 0 . , 0 . , 0 • ) C AL L P H N P H ( 0 , PG , V ( I ) , V ( 2 ) , V (3 ) , V ( 4 ) , V (5 C AL L P R^iT R ( 0 , U ( 6 ) , V (7 ) , 0 . , 0 • , 0 • , 0 • ) CALL PHNTR ( 0 , S ( I ) , S ( 2 ) , S ( 3 ) , S ( 4 ) , S ( 5 ) , S CAL L P H N T H ( 0 , S (7 ) , 0 . , 0 . , D S , 0 • , 0 • ) CAL L PRNTR ( I , R ( I ) , R ( 7 ) , TEMPP (7 ) , J , T (7 ) , T GO TC ( 1 0 0 , 1 ) , NE 100 , CAL L I NT I ( X , D X , I O ) ' DO 2 0 0 M= I , 7 C AL L I N T d S ( M ) , DPS ( M ) ) C AL L I N T ( V ( M ) , D V ( M ) ) CALL I N T C P ( M ) , D P ( M ) ) 200 . CONTI NUE CAL L I NT (TG ,DPG ) G O TO 2 0 END , TS ( 4 ) , TS ( 5 ) ) ) ) (6)) (I )) , / \ ! F ORT 4 CD J EXT . FORTRAN OPTI ONS >NS I U » VERSION F00 ! RUN S J l L I B . 2 3 4 LINKING $ LINKING : LIB ' P I * ASSOCIATED. L I N K I N G ‘ SYSTEN L I B ? . 0 1 ^ 0 . j2 « ^ 4 0 . ?* POS I T I ON TS (I) TS (7 ) TS ( 6 ) V (I) GAS TENP V (7 ) U (6 ) STRESS(2 ) STRESS( I ) STRESS(S) STRESS (7 ) KAX REY NJN N I N R E Y - NUN 3 7 6 0 .0 .00000 376 0 .0 37 6 0 . 0 •10000 . 35 6 0 . 0 • I 0000 • I 0000 618.10 . 655 .25 •00000 57 9 . 9 6 160 . 26 190.79 I .9999 3529.0 3329.9 I .9146 1169.7 47 9 *0 9 240 .38 ■ 3 6 4 4 .0 3 4 8 0 .3 4.3615 I . 4 5 14 9 30 . 4 6 .00000 177 . 3 3 i TS ( 2 ) TS(S) V(2) V(S) STRESS( 3 ) STRESS( 9 ) PART TE NP 37 6 0 . 0 .00000 . 10000 .00000 6 0 8 .66 . .00000 3 76 0 .0 - 3 60 2 .0 .00000 /3.1250 .00000 85 2 . 0 6 .00000 3549-0 TS ( 3 ) TS ( 9 ) U (3 ) U (9 ) STRESS( 4 ) S TRESS ( 1 0 ) GAS UEL 376 0 .0 •00000 •I0000 •00000 TS ( 4 ) TS(10) V (4) ^ V (10) STRESS ( 5 ) STRESS( 1 1 ) NAX T I KE 376 0 .0 •00000 .10000 .00000 5 99*16 I 8-100 20.880 ■ 35 84 . 6 .00000 2 .7 5 25 •00000 7 5 8 .7 4 18.100 I 9*530 594.38 •00000 •10000 .00000 589.59 •00000 ‘ 35 61 . 4 .00000 2 . 3 4 94 ■ .00000 703.78 • , •00000 .00000 •00000 *00000 2 . 4 8 10 TS ( 5 ) TS ( 11 ) V (5) V(Il) STRESS (6 ) PRANDL NUN N I N T IKE 3 7 6 0 *0 . 3 5 4 6 .7 •00000 2.1359 .00000 640.93 .00000 .7 881 9 3 .9998 3406.9 3204.8 2 .5 887 1402 .5 535 .00 259-62 . 9.9993 3 1 3 6 .3 2 9 1 4 -7 4 .0916 1935 . 0 768*61 3 0 2 . 81 . 3 4 8 3 «6 3264.0 6 . 3 4 94 ' 2 .6406 1180.1 . .00000 196.14 ' 5.9996 3306-8 3 0 9 9 . 0 •' 3.1411 1592.1 608.64 275.10 7 .9995 3218.0 3 00 3 .5 3 .6348 1766 .3 6 87 . 9 2 289.21 3 5 6 1 .7 3360.2 5 .5544 2 .0975 I 064 • 6 •0 0000 I 87 . 1 2 ■ ' / • 3 4 0 7 .7 3178.6 6.. 9 7 5 0 ■ 3 .1298 I 2 91 .7 I .00000 204.95 3333.5 -3099.7 . 7 .5 0 95 3 . 5 8 40 ' 1 4 0 2 .7 .00000 ^ 2 1 3 .7 8 3498.2 .00000 3.9784 .00000 959.38 •00000 343 4 .2 3474.1 .00000 3 .5330 3404.9 .00000 4 . 5 9 80 .00000 I 057 .0 .00000 3 3 3 7 .1 3 3 7 7 .1 .00000 4.1227 •00000 921 «82 3318.0 .00000 5 .123 I .00000 1 15 4 .5 •00000 3249.5 . , 3 23 6 .0 .00000 5.5966 .00000 1252.9 •00000 3168.0 3 4 4 4 .2 •00000 ; 3 . 0 6 87 .00000 •00000 83 9 - 7 8 I 8.100 ' 18.797 772.96 ' 3426 .6 .00000 2 .8304 •00000 700 .3 8 .00000 »00000 3 .6124 1.1891 3 3 4 4 .6 «00000 3 «6361 .00000 84 8 • 92 3 3 2 6 .3 *00000 3 . 3 895 .00000 772.27 I 8.100 .00000 •00000 .1 8 . 1 7 6 . \ 3288-3 .00000 4 .6334 .00000 I 007 .6 4 . 4 5 81 I .5244 3254.9 •00 0 00 4.1366 .00000 93 0 -3 9 3236 .9 ' .00000 3 .8862 - •00000 I 8.100 .00000 17.616 5.1519 85 0 • 96 •00000 I *8242 3 2 0 5 .3 .00000 5 .0991 317 1 .9 .00000 4.5970 .00000 1014.8 3 1 5 4 .3 •00000 4 .3446 •00000 932 -7 9 •00000 1095.8 I I 8.10017 . 0 95 .00000 •00000 5 -7480 2.1000 I I .999 3059.4 2830.7 4 .5223 2102.0 847.99 - 316.34 13.999 . 2986.1 27 5 0 . 2 4.9332 . 2267 .4 923 .7 6 3 30 .05 15.999 2915 .4 2672.4 5 . 3 2 87 2429.3 993 - 8 4 344.12 17.998 2 846.8 2596.8 5.7119 25 84 . 5 105 6 . 4 358*69 3 2 6 0 .7 3 0 2 5 *1 7 .9885 4.0131 1512.9 •00000 2 22 .77 3157 .6 «00000 6 .036 9 .00000 135 1 .1 •00000 3090.9 3126.6 •00000 5 .5349 .00000 1184.1 18*100 16 . 6 0 2 3 0 93 . 6 ■ .00000 5 . 0 2 97 ' 3189.2 2953 .6 ■ 8.4303 4 .4232 1620.4 .00000 2 3 2 . 01 3 0 8 2 .3 .00000 6 .4536 •00000 1 4 4 6 .5 .00000 ' 3017 .0 3 05 I .3 .00000 5.9489 .00000 1270.0 I 8.100 16.130 301 9 . 0 •00000 5 .441 9 *00000 1181.6 3118.9 3009.4 .00000 6 .8525 .00000 2978.6 2947.1 .00000 5 .8381 2 884 .5 8*845 9 4.8183 17 2 2 • I .00000 2 41 . 5 8 'I 1536.4 .00000 2 945 .7 3049.6 . 2817 . 2 9.2419" 5.2014 1815.2' •00000 , 25 I . 5 6 ' . ' 2 93 8 . 5 •00000 7 .237 5 .00000 1617.9 .00000 . 2 87 6 *5 ■ 307 6 .6 .00000 4 .7762 ' •00000 •00000 1 0 9 9 .5 •00000 6 .2747 1014.7 •00000 2 .357 8 3 0 0 2 .6 *00000 5.1877 •00000 1094.0 •00000 2.6011 •00000 6 . 74 89 •00000 6 .3462 .00000 1350.5 18.100 15 . 6 7 4 125 8 . 5 •00000 7.1817 2 90 8 . 1 .00000 •6 .7302 .00000 1423 .0 • ' I 8.100 15.231 2 877 . 4 .00000 6 .2216 •00000 1327.7 *00000 7.5808 / 2931 .2 *00000 .00000 - ■ 5 .5 836 .00000 1167.9 »00000 2.8324 2862 .0 .00000 5 .966 9 •00000 1234 .4 *00000 x3 . 0 5 3 3 2669.3 •00000 7.6113 ' .00000 1688.4 ..00000 2808.8 2 83 9 . 4 .00000 7.1035 .00000 1485.5 I 8.100 14 . 7 97 2 80 9 . 4 *00000 6 .5 947 •00000 13 87 .1 •00000 7.9519 2913.8 2686*5 9.9921 5 • 93 96 I 9 63 . 5 •00000 27 3 . 0 2 2801.5 .00000 7 .975 9 .00000 1746 .0 .00000 27 4 2 . 5 2772.1 .00000 7 .4679 •00000 1536.4 I 8.100 14 . 3 7 2 2742.8 •00000 6.9591 .00000 1435.6 .00000 8 . 2 991 2728.3 .00000 6 .7045 „ ,-« 0 0 0 0 0 1338.1 •00000 , 3 . 4 6 87 2846.8 2 6 2 2 .3 10.353 6 .2996 2 0 1 5 *1 , .00000 284.72 2734.5 .00000 8 . 3 34 6 .00000 1789.9 .00000 267 6 . 9 27 05 . 6 .00000 7 .826 8 • 00000 157 5 . 2 I 8.100 13.951 2677 .0 .00000 7.3182 •00000 1472.8 •00000 8.6274 2662.9 .00000 7 .063 8 «00000 1374 • I •00000 ■ 3 «666 1 2668.7 •00000 8 . 6 852 .00000 I 81 9 . 7 .00000 2612.4 2 6 4 0 .4 .00000 8.1777 •00000 1602 .0 18.100 13.537 ,2612.4 .00000 7 «66 96 .00000 1498.7 .00000 8.9361 I 9*997 277 9 . 8 2522*9 6 .0849 27 2 8 - 5 1110.2 373.90 2 981 . 3 2751 .2 9*6230 5 .57 46 I 896 .4 •00000 2 6 2 . 01 21«996 2714.1 2450.4 6 . 4 4 96 2856.9 1154.4 389.87 24.005 2649.1 2 3 7 8 .7 6 . 8091 2 965 .7 1189.1 4 0 6 . 81 26 . 0 0 3 25 85 . 2 2308.1 7.1611 305 0 . 8 1214 .5 424 .68 , 27 80 . 6 2559.1 10 .7 05 6 .6522 2 0 5 0 .5 .00000 2 97 . 0 9 - ' 2794.5 •00000 6 .33 99 .00000 1291 . 4 .00000 3 .265 I ' . '1 25 9 8 . 7 -00000 7 .4154 •00000 1399.6 .00000 3.8557 28 .002 2521 . 9 2 2 3 8 .2 7 . 5 0 82 3110.8 123 1 . 9 4 4 3 .7 2 , 30 .001 2459.1 216 8 .7 7.8514 3145.9 1242.8 464.10 • 27 15 *0 2 4 96 .5 I I .050 7 .0001 2 07 0 .6 •00000 310.29 2 6 0 3 .7 .00000 9 .0306 .00000 I 83 6 .7 .00000 2548.6 2575.9 .00000 8 .5236 •00000 '1617.8 18.100 13.127 2548*5 .00000 8.0161 .00000 1514.6 .00000 9.2289 2 5 3 5 .1 •00000 7 .7622 •00000 1415.8 »00000 4 . 0 3 93 2649.9 243 4 .2 11 . 3 9 0 7 . 3441 207 7 .2 .00000 324 .42 2539.3 •00000 9 . 3 7 16 .00000 1 8 4 2 .5 , .00000 2 4 85 . 3 2511.9 .00000 8.8652 .00000 1624 .4 I 8.100 12.720 2 4 85 • I .00000 8 . 3 5 84 .00000 1522.1 •00000 9.5075 2472.0 .00000 8.1049 •00000 1424 .4 .00000 • 4.2173 - 244 8 .4 .00000 9 .2033 ' .00000 1624 .0 I 8.100 12.314 2422.1 *00000 8 »6 97 4 •00000 1523.2 •00000 9 .7735 2409.2 •00000 8 .4444 .00000 x 1 4 2 7 .1 .00000 4 .3901 25 85 . 0 237 2 .2 I I .7 26 ■, 7 . 6 8 5 0 '2 0 72 .8 .00000 33 9 . 63 32 .000 2396.6 2099.6 8 . 1 913 3157 .6 1248.8 4 8 6 . 01 ! , 2 47 5 .3 .00000 9.7089 .00000 1 83 9 . 5 •00000 2 4 2 2 .4 - 65 - APPENDIX D: MODEL DEVELOPMENT OF CORED-BRICK AIR PREHEATER B r ic k s a r e assumed i s o t h e r m a l . w ith The geom etric p o r o s i t y o f b r ic k s . 2 5 - i n c h d ia m e te r holes is 25%. AIR PREHEATER WITH DIFFERENTIAL ELEMENT: Energy Balance o v e r D i f f e r e n t i a l Element Ax: h e a t i n p u t - heat o u tp u t = h e a t t r a n s f e r r e d to / f r o m b r ic k s W 3 Ux - “gPgTglx " where Px = Trd0 N1 , N j = number o f holes i n c r o s s -s e c t io n PT = ( T b r 1 Ck - Tg) Note: The f a c t o r 2 accounts f o r the f a c t t h a t , a t any g iv en tim e , gas w i l l be flo w in g through two chambers. <!> - 66 - wgCpg 5 i -IK (2 ) - 2hV T l (3 ) WgGPgdTg = ZhPxdXAT D e fin in g Nu = hd^/k and i n t e g r a t i n g across the o v e r a l l chamber le n g th g iv e s : W - V \ M ' - 2 (J v > Cpr . % px U T (4 ) - V 2ATP„ Nu E quation 4 can be w r i t t e n in terms o f known dim enionless v a r i a b l e s : UbPd0 W. where U. p Ak Wg = gas mass flo w r a t e Ab = t o t a l c r o s s - s e c t io n a l area o f holes Ab = 2(%)AC f o r a ge o m etric p o r o s i t y o f . 2 5 , f o r two chambers. 2W_ UbP Ac = c r o s s - s e c t io n a l area o f one chamber % CPq W S u b s t i t u t i n g e q u a tio n s 5 and 6 i n t o e q u a tio n 4 g iv e s : - 67 - RePrAc (Tg^ - T ^ ) (7) Nu 4PX AT C r o s s - s e c t io n a l Area o f holes _______ P o r o s it y __________________ ■ P e r im e te r o f holes (N t 1 TTdQ2 ) 4 tV rd0 And, S t = S ta n to n Number = Nu do ' Tg2 - Tg1 ) \ L (8 ) S t 4 AT The o v e r a l l chamber le n g th is c a l c u l a t e d from e q u a tio n 8 . The chamber d ia m e te r is c a l c u l a t e d from e q u a tio n 5: Re 2V o v A, 2V o y Re C . 8W d h 4 ' D= w The le n g th and d ia m e te r o f the chamber a re a r r i v e d a t through a t r i a l a n d - e r r o r pro c ed u re . Reference ( 7 ) giv es a graph o f Re vs = S t Pr2 /3 where ( 10) T h is in c lu d e s Reynolds numbers i n both th e la m in a r and t u r b u l e n t - f l o w r e g io n s . fo u n d . Thus, f o r a given Reynolds number, the Stanton number can be Then L and D can be c a l c u l a t e d , re s p e c tiv e ly . It is assumed t h a t a i r is flo w in g through th e chamber: Tn 9Z = SlOO0F Tn 9I = 1700°F Vf m = 3 . 3 x 10~5 I b fflZ f t s e c Pr = .72 Wg = 1 .2 7 9 x IO6 I b / h r ■ pa v d o using e q uations 8 and 9 , = -13 l b / f t 3 =0.25 inches According to th e d a ta o f r e fe r e n c e ( 1 7 ) , a high Stanton number can be reached in the la m in a r f lo w re g io n (Re < 2 0 0 0 ) . is in v e r s e ly p ro p o rtio n a l to Re, the r e s u l t i n g design has a very l a r g e c r o s s - s e c t io n a l a r e a , and a small column h e i g h t . param eters i n th e t u r b u l e n t re g io n a re used. maximum However, s in c e d ia m e te r Thus, design In t h i s r e g i o n , a o f 0 .0 0 3 8 occurs a t Re = 7000. An average AT o f 155°F is taken from e s t a b l i s h e d d a ta f o r c o n v e c tiv e h e a t t r a n s f e r from cored b r ic k s to a i r (5). I n c o r p o r a t in g t h i s data i n t o e q u a tio n s 8 and 9 g iv e s : A t Re = 7000, S t = .00 4 7 from e q u a tio n 10. ■- 69 - . L = 2 3 .3 f t D = 8 .9 f t As a check, the chamber is s iz e d assuming t h a t h o t gas i s flo w in g through th e chamber. A g a in , e s t a b l i s h e d data ( 5 ) gives an average AT between th e ho t gas and the cored b r i c k s o f IOO0 F. The f o l l o w i n g param eters are used: T = 3500°F g2 Tn = 2300°F 9I y AV = 3 . 5 x IO- 5 I b ^ / f t s e c Pr P = .72 = .089 l b / f t 3 W g = 1 .3 0 4 x IO 6 l b / h r m d = 0 .2 5 inches o F o llo w in g th e procedure o u t l i n e d above, the f o l l o w i n g d a ta are developed: L = 2 0 .0 f t D = 8 .7 f t Since th e chamber dimensions c a l c u l a t e d from a i r flo w d a ta a re l a r g e r , th e y a re c o nsidered c o n s e r v a t iv e and a re used in a l l c a lc u la tio n s . subsequent - 70 CHAMBER PRESSURE DROP Pressure drop is c a l c u l a t e d across th e chamber, h e i g h t . The momentum e q u a tio n f o r flo w in a c i r c u l a r pipe gives ( 1 6 ) : where - AR _ 4 w 4L ' dO (H ) , the w a ll shear s t r e s s , can be d e fin e d in terms o f the t Fanning f r i c t i o n f a c t o r ( 9 ) as: Ub^Pf "w - ( 29; 12) S u b s t i t u t i n g e q u a tio n 12 i n t o e q u a tio n 11: - AP AL Now, s in c e Re 2db2 pf d O9 C V dO we can w r i t e Z f y 2 Re2 -AP AL (1 3 ) O r, o v e r th e o v e r a l l chamber h e i g h t L, -AP == (1 4 ) do V The B la s iu s e q u a tio n ( 9 ) i s used to d e fin e th e Fanning f r i c t i o n f a c t o r i n th e t u r b u l e n t flo w re g io n : f .= 0 .0 7 9 Re"^ (15) -7 1 - Thus, using e quations 15 and 14 and employing the a i r f l o w data used p r e v i o u s l y , th e chamber pressure drop i s : -AP = 4 .4 3 psi APPENDIX E: I. 72 - COST PREDICTION FOR FALLING-PARTICLE AIRE PREHEATER Costs In s u la tio n U n it p r ic e s f o r r e f r a c t o r y i n s u l a t i o n m a t e r i a l Appendix A - 6 . In itia lly , a re p resented in chamber volumes f o r each i n s u l a t i o n ty p e a r e c a l c u l a t e d using V = — J— (D * - D* )L . (I) See F ig u re 5 f o r column i n s u l a t i o n c r o s s - s e c t io n and d e s ig n a tio n o f s p e c ific in s u la tio n ty p e s . Note: assumed a t each end o f the column. a re doubled. Hem ispherical caps a re I n s u l a t i o n costs f o r ends T h e . f o l l o w i n g data r e s u l t : (One U n i t ) 0 .0 3 8 i n . Blowout 0 .0 4 2 i n . Blowout In s u la tio n Body 1 .0 8 x IO4 7500 Volume ( F t ^ ) Ends 3200 2900 T o ta l 1 . 4 x IO4 1 .0 4 x IO4 TOTAL COST 2. $ 1 .7 3 x IO6 $ 1 .3 3 x IO6 S te e l Column Cost To c a l c u l a t e the necessary s t e e l th ic k n e s s f o r th e column, the f o l l o w i n g r e l a t i o n between p re ss u re and t e n s i l e s t r e n g t h is used: 2 TrdtL = 2 ttL pr (2 ) - 73 - where r = column in s id e ra d iu s t = s te el th ic k n e s s p = column i n t e r n a l a = s te e l pressure t e n s i l e s tr e n g th L = column h e i g h t Thus, i t f o llo w s t h a t (3 ) where D is th e column o f a = 1 .x I p s i d ia m e te r ( i n c l u d i n g i n s u l a t i o n ) . is used f o r s t e e l . Note: caps a re assumed a t each end o f th e column. a re doubled. A value A g a in , hem is p h e rica l S te e l costs f o r ends Using e q u a tio n 3 t o c a l c u l a t e the s t e e l th ic kn es s giv es th e f o l l o w i n g data (a s t e e l d e n s it y o f 490 lb / f t ^ is assumed): . (One U n i t ) 0 . 0 3 8 i n . Blowout 0 .0 4 2 i n . Blowout S te e l Body 4 . 3 7 x IO 5 Weight ( I b ffl) Ends 1 .6 x IO 5 . 1 .4 x IO 5 T o ta l 5 .9 7 x IO 5 4 .3 3 x IO 5 $ 2 .2 7 x IO 6 $ 1 .7 2 x IO 6 TOTAL COST 2 .9 3 x IO 5 - 3. 74 - Alumina P a r t i c l e Cost In p r e d i c t i n g th e mass o f p a r t i c l e s a i r p re h ea te r, it needed to i n i t i a l l y charge the i s assumed t h a t a p a r t i c l e bed a p p ro x im a te ly 4 f e e t deep w i l l . l i e above the top and m iddle d i s t r i b u t o r p la te s eac h, and a t th e chamber bottom. In a d d i t i o n , it is assumed t h a t the p a r t i c l e mass in th e pneumatic r e c y c le system w i l l equal about the mass o f p a r t i c l e s above one d i s t r i b u t o r p l a t e . In p r e d i c t i n g how much o f the f a c t o r y - s u p p l i e d p a r t i c l e stock can be used i n each b lo w o u t, i t is assumed t h a t 81% o f the s to c k can be used to a ch ie v e a 0..038. i n : b lo w o u t, and 54% o f th e s to c k can be used to a c h ie v e a 0 .0 4 2 i n . b low out. Using these f i g u r e s and O assuming a bed d e n s it y o f 135 l b ^ / f t , the f o l l o w i n g p a r t i c l e masses are p r e d i c t e d . ( . a p a r t i c l e c o s t o f $ . 2 5 / l b m is assumed): 0 .0 3 8 i n . Blowout: M = 4 . 7 x IO^ lb m Cost = $ 1 .2 x IO 5 0 .0 4 2 i n . Blowout: M = 6 . 1 x IO5 I b m m Cost = $ 1 . 5 x IO5 These masses a re o f f a c t o r y - d e l i v e r e d p a r t i c l e s to c k . 4. M is c e lla n e o u s C a p i t a l Costs (a ) P ip in g - a p ip in g c o s t o f $ 1 0 0 0 / f t i s assumed. In a d d i t i o n , i t assumed t h a t 300 f t o f p ip in g i s necessary f o r each u n i t . This is - 75 gives a p ip in g c o s t o f $3 x 1 0 ^ / u n i t . (b ) Valves - f o u r v a lv e s a r e p r e d i c t e d pe r u n i t , a t a c o s t o f $ 3 4 ,0 0 0 /v a lv e . (c ) T h is gives a v a lv e c o s t o f $ 1 .3 6 x 1 0 ^ / u n i t . In s tr u m e n t a t io n - i t is assumed t h a t in s tr u m e n t a t io n costs w i l l a p p r o x im a te ly $3 x IO^ f o r th e o v e r a l l a i r p r e h e a t system. be This f i g u r e is used f o r both blow out c ases, and f o r th e c o r e d - b r ic k system. (d ) Foundations and S t r u c t u r e - th e o v e r a l l c a p i t a l c o s t f o r the fo u n d a tio n s and s t r u c t u r e o f th e u n i t i s assumed t o be 90% o f the column s t e e l 5. , cost. E s tim a tio n o f Annual Maintenance Costs ~ ■ The m ajor annual c o s t f o r the a i r p r e h e a t e r is p a r t i c l e replacem ent due t o p a r t i c l e breakup and b lo w o u t. A ccording to a n a l y s is done by W. E. G e n e t t i , the tu r n o v e r tim e d u rin g which th e t o t a l p a r t i c l e bed must be re p la c e d can be ro u g h ly e s tim a te d a t . 100 days. A t a p a r t i c l e c o s t o f $ .1 5 x 1 0 ^ / u n i t , the annual p a r t i c l e replacem ent c o s t f o r t w o . u n i t s is a p p r o x im a te ly $ 2 .1 x 1 0 * \ ■: /• • . APPENDIX F : I. 76 - COST PREDICTION FOR CORED-BRICK A IR PREHEATER I n s u l a t i o n Costs An i n s u l a t i o n th ic k n e s s o f 3 . 5 f e e t is used f o r the c o r e d - b r ic k columns, th e same as w i t h th e f a l l i n g - p a r t i c l e F ig u r e 5 f o r i n s u l a t i o n c r o s s - s e c t i o n . column. See A g a in , e q u a tio n I in Appendix E - I i s used to c a l c u l a t e volumes f o r each i n s u l a t i o n ty p e . Note: Hem ispherical caps a r e assumed a t each end of. the column, and i n s u l a t i o n costs f o r the ends a re doubled. (One U n i t ) I n s u l a t i o n . Volume, f t d Cost Body 3168 $ 3 . 1 8 x IO5 Ends 1763 3 .4 4 x IO 5 • 8098 $ 6 . 6 2 x IO 5 TOTAL 2. S te e l Column Cost The r e l a t i o n s h i p used to c a l c u l a t e the thic k n e s s o f the s te e l column f o r th e c o r e d - b r ic k a i r p r e h e a te r is the same as t h a t used in Appendix E - 2 . f o r th e f a l l i n g - p a r t i c l e a i r p r e h e a t e r . Knowing th e column t h i c k n e s s , t h e t o t a l mass o f s t e e l necessary f o r the column can then be p r e d i c t e d . Note: A g a in , h e m is p h e ric a l s t e e l caps a re assumed a t each end o f th e column. S te e l costs f o r th e ends a re doubled. A s te el cost - 77 o f $3/1 t>m is assumed. (One U n i t ) Ps^e e -] = 490 I b mZ f t 3 S te e l Weight ( I b m) Cost Body 3 X IO4 Ends 2 . 1 x IO4 1 .2 6 x IO 5 TOTAL 5 .1 x IO4 2 . 1 6 x IO5 3. 9 x IO4 Cored B r ic k Costs The cored b r i c k h e a t t r a n s f e r m a t e r i a l Norton AH299. The m a t e r i a l has 0 . 2 5 inch cored holes g i v in g i t a 25% geom etric c r o s s - s e c t io n a l p o ro s ity . p o r o s i t y and a p u r i t y o f 99.5% a lu m in a . $ 3 8 1 /b u lk ft . It used in t h i s a n a ly s is is I t has an 18% m a t e r ia l The m a t e r i a l c o s t is . is assumed t h a t th e column is c o m p le te ly f i l l e d w ith cored b r i c k . Volume = — f — . D2L = 1450 f t 3 Cost o f Cored B r ic k = $ 5 .5 2 x IO 3 4. (a ) , M is ce llan e o u s C a p i t a l Costs P ip in g - a p ip in g c o s t o f $ 1 0 0 0 / f t is assumed. A p i p i n g len g th o f 1100 f e e t f o r the o v e r a l l s e v e n - u n i t a i r p r e h e a t complex is assumed. . (b ) This giv es a t o t a l Valves - i t p ip in g c o s t o f $ 1 .1 x 10®'. i s assumed t h a t f o u r h ig h -t m p e r a tu r e v alv es a re needed f o r each column. '' V alve c o s t is $ 3 4 , 0 0 0 / v a l v e . x- , • : x-- A . T h is gives a : -x/ :- A . - / , - - ; - 78 - v a lv e c o s t o f $ 1 .3 6 x 1 0 ^ / u n i t . (c ) In s tr u m e n t a t io n - as w it h th e f a l l i n g - p a r t i c l e system, it is assumed t h a t o v e r a l l th e c o r e d - b r ic k system w i l l (d ) a i r p r e h e a te r in s tr u m e n t a t io n c osts f o r be a p p ro x im a te ly $3 x 10^. Foundations and S t r u c t u r e - the o v e r a l l c a p ita l c o st f o r fo u n d a tio n and s t r u c t u r e f o r th e c o r e d - b r ic k system i s e x t r a ­ p o la te d from c o s t data s u p p lie d by W. E. G e n e tti f i r e d c o r e d - b r ic k a i r p r e h e a t system. fo r a d ire c t- This c o s t f o r th e o v e r a l l i n d i r e c t - f i r e d system i s a p p r o x im a te ly $3 x 10®. 5 5. E s t im a tio n o f Annual Maintenance Costs Annual costs f o r th e c o r e d - b r ic k a i r p r e h e a te r a re m o s tly due t o c o r e d - b r ic k re p la c em e n t due to therm al shock and h i g h r te m p e ratu re c o rro s io n . E stim ated annual costs f o r a system o f t h i s c a p a c ity a r e found to be $ 1 . 4 x .10®. a t % 1 .7 y e a r s . The m a t r i x l i f e t i m e is e s tim a te d T h is data is p re se n te d i n r e f e r e n c e ( 1 0 ) . APPENDIX G: I. DESIGN DATA FOR COAL CARBONIZATION SYSTEM Mass and Energy Balances A ll flo w r a t e s a re l a b e l e d on F ig u re d 6. From r e f e r e n c e ( 1 0 ) , th e combustion a i r r a t e A 1 f o r the i n t e r m e d i a t e BTU fu e l gas is -A' = 1 2 .4 7 G Also from r e fe r e n c e ( 1 0 ) , fo llo w in g : (I) coal c a r b o n i z a t i o n y i e l d s th e . 2000 I b ffl Coal -> 1400 I b m coke + ~ 600 lb f u e l gas Thus, using th e nom enclature o f F ig u re 6, A b = 600 1400 * K (2 ) Now, to r e l a t e A and G, an energy ba lanc e is ta k e n .a c r o s s the a i r . p r e h e a te r ( n e g l e c t i n g energy lo s s e s ) : 3500°F (G + A 1) / Cp dT exhaust 2330°F 3100°F dT A / Cp a ir 1700°F (3 ) Using th e h e a t c a p a c i t y data from Appendix A i n e q u a tio n 3 , and s u b s t i t u t i n g i n e q u a tio n s I and 2 , g iv e s : K =; .1773 A As an i n i t i a l te s t, it (4 ) is.assum ed t h a t th e f u e l MHD combustor is pure coke, d e l i v e r e d a t T c a rb o n ize r. f lo w t o the 1800°F from th e coal From th e re q u ire m e n t t h a t th e therm al in p u t t o th e MHD du c t be 400 MW, and n o tin g t h a t ^ c o m b u s tio n ~ 14»000 B TU/lbm - 80 - ■and Cp - = .36 3 B T U /lb ^ °F f o r coke, KAHcomb + KC (1 8 0 0 °F - 7 7 °F ) = 1 .3 6 6 x IO9 m which y i e l d s ’’ K = 9 . 3 4 x 10 (5 ) A l b m/ h r . Now, from r e f e r e n c e ( 1 0 ) , th e a i r re q u ire m e n t f o r combustion o f coke is A = 1 1 . 2K. an a i r f l o w r a t e o f A = 1 .0 4 6 x 10® I b fflZ h r . This gives S u b s titu tin g th is v a lu e i n t o e q u a tio n 4 giv es th e coke pro d u c tio n r a t e necessary to produce enough f u e l gas to h e a t t h i s a i r flo w r a t e : K = ( . 1 7 7 3 ) ( 1 . 0 4 6 x IO 6 ) = 1 .8 5 5 x IO 5 l b ffl/ h r (6 ) As can be seen, th e coke f lo w r a t e from th e c a r b o n i z e r is n e a r ly tw ic e th e coke f l o w r a t e to th e MHD combustor. - 81 APPENDIX H : I,- DESIGN DATA FOR COAL. GASIFICATION SYSTEM Mass and Energy Balances Flow r a t e s a re l a b e l e d .o n F ig u re I . From r e fe r e n c e ( 7 ) , the c o n ve rs io n r a t e f o r th e .C O g -a c c e p to r g a s i f i c a t i o n process is ~ 60%. Then, - , G = .6 0 D (I) For th e combustion o f a high BTU g a s , t h e a i r r a t e necessary i s : A' = 17.24G . Now, an energy balance across t h e a i r p r e h e a te r y i e l d s (2 ) (n e g le c tin g energy l o s s e s ) : 3400°F 3100°F (G + A 1) / CRexhaust 2330' Note: I 1700' a ir a fla m e te m p e ra tu re o f 3 4 0 0 °F is assumed f o r combustion o f th e gas (1 0 ).. A ls o , th e h e at c a p a c it y o f th e combustion products i s assumed to be c lo s e to t h a t o f th e i n t e r m e d i a t e - BTU gas p re s e n te d in Appendix A - 3 . Since ambient coal i s being used in th e MHD combustor, A = 1 .2 7 9 x IO^ l b ^ / h r (see Appendix B - 2 ) . S u b s t i t u t i n g e q u a tio n 2 i n t o e q u a tio n 3 and s o l v i n g f o r G g iv es : G = Using t h i s 8 .0 5 3 x IO 4 l b m/ h r value i n e q u a tio n I giv es th e coal (4 ) i n p u t r a t e to th e - 82 g a s ifie r: D = 1 .3 4 x IO 5 l b m/ h r (5 ) S ince the coal f l o w r a t e to th e MHD duct i s 1 .5 2 7 x IO^ I b fflZhr (see Appendix B - 2 ) , th e coal f lo w r a t e to th e g a s i f i e r is *4 7 % o f the t o t a l 2. coal r a t e to t h e power g e n e r a tin g complex. ■ C a p i t a l and Annual Cost P r e d i c t i o n Reference ( 7 ) gives a c a p i t a l c o s t o f $103 x IO^ f o r a COg - a c c e p to r g a s i f i c a t i o n system w it h an o u tp u t o f 250 x 10° s c f 3 gasZday. Assuming a, gas d e n s i t y o f . O S l l b fflZ f t th e c a p i t a l , an e s t im a te o f c o s t o f t h e g a s i f i c a t i o n system f o r t h e a i r p re h ea te r is : C = (103 x IO 6 ) [■- 8 ---° -5- - y 1" — 1 x -------- ^ ------------ ] 2 5 0 x l0 b( . 0 5 1 ) = $ 2 7 .5 x IO 6 The annual o p e r a t in g c o s t o f the 250 x 10 as $16 x IO6 . 6 scfZday p l a n t is given Thus, f o l l o w i n g th e same procedure as above, th e annual o p e r a t in g c o s t o f t h e g a s i f i c a t i o n system f o r th e a i r . p r e h e a te r can be e s tim a te d as: Annual o p e r a t in g c o s t = $ 4 . 3 x I O6 •Vi. ' BIBLIOGRAPHY I. Rosa, R ic h ard J . , N o te s , " E E .580 - MHD Power C o n v e rs io n ", Autumn 1975. . 2. Rosa, R. J . , Magnetohydrodynaniic Energy C o n v e rs io n , M c G r a w -H ill, I n c . , 1968. 3. I S h i e n d l i n , A. E . , and Jackson, W. 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