Soil water and solute movement in Montana strip mine spoils by Franklin Brooks Arnold A thesis submitted in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE in Soils Montana State University © Copyright by Franklin Brooks Arnold (1976) Abstract: A study was initiated in November, 1974 at the Peabody Big Sky Mine near Colstrip, Montana to determine soil water and solute movement in strip mine spoils. Three spoils treatments, consisting of topsoiled nonvegetated, topsoiled revegetated and nontopsoiled revegetated spoils, and a native range site were studied. The testing and evaluation of an unsaturated soil water movement model showed the model to be applicable to soil water movement in both the mine spoils and native range. Calculation of in situ soil water budgets indicated drainage was occurring from the spoils and native range. Both the water movement model and the in situ water budgets indicated that the quantities of soil water movement in the native range was approximately 1.5 times greater than in the spoils. The lower amount of soil water movement in the spoils was attributed to bulk density, which was 54% higher than native range, and to higher contents of silt and clay than native range. Clay mineralogy analyses indicated that the dominant clay minerals in all treatments were non-expanding lattice clays, which would not greatly limit soil water movement due to expansion upon wetting. Infiltration rates of the native range were 60-86% higher than those of the spoils. These differences were attributed to the effects of soil structure, vegetation and topsoiling techniques. Saturated hydraulic conductivity of the native range was 3.5 times greater than that of the spoils treatments. The higher hydraulic conductivity of the native range was attributed to textural differences between the native range and spoils treatments. No definite trends in solute movement were shown due to the short time span of this study. With the exception of potassium and NCL-N, the solute concentrations of the spoils were not, in general, different from the native range. The spoils contained lower potassium and higher NO3-N concentrations than present in the native range. Exchangeable sodium percentages (ESP) and sodium adsorption ratio (SAR) indicated no sodium problems were present in the spoils and native range. The higher quantities of soil water movement in the native range compared to the spoils indicate that greater amounts of solute movement into the groundwater may occur from the native range than from the spoils. SOIL WATER AND SOLUTE MOVEMENT IN MONTANA STRIP MINE SPOILS by Franklin Brooks. Arnold A thesis submitted in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE in Soils CV-cHair^fson, G^adu^e Committee Co-chairperson, Gradiiafe Committee Head, Major Department Graduate MONTANA STATE UNIVERSITY Bozeman, Montana \ November, 1976 ■STATEMENT OF PERMISSION TO COPY In presenting this thesis in partial fulfillment of the requirements for an advanced degree at Montana State University, I' agree that the Library shall make it freely available, for inspection. I further agree that permission for extensive copying of this thesis for scholarly purpose may be granted by my major professor, or, in his absence, by the Director of Libraries. It. is understood that any copying or publication of this thesis for financial gain shall not be allowed without my written permission. Signature Date JfovemkezL £ 3 , iii ACKNOWLEDGEMENTS The author wishes to express his appreciation to the encourage­ ment and understanding in every phase of his project from his wife, Bellena. Special appreciation is due to Drs. Douglas Dollhopf and Hayden Ferguson for their guidance and valuable suggestions through­ out this investigation and manuscript preparation. The author also would like to thank Dr. Ervin Smith and Richard Kuntz for their time and effort in assisting with the reduction of the data on the computer. Lastly, the author thanks the Peabody Coal Company for funding of this investigation and for use of their Big Sky Mine property and. facilities. . TABLE OF CONTENTS Page . V I T A .................................. ............. ' .......... ii ACKNOWLEDGEMENTS................ .. . . ........................ iii LIST OF TABLES ................................................. LIST OF F I G U R E S ............... LIST OF APPENDICES . ........................................... ABSTRACT ........................................ yi vii x xiv INTRODUCTION .........................■........................... I LITERATURE R E V I E W ...................................... 3 METHODS AND MATERIALS 9 .......................................... Site Description and D e s i g n ......................... .. . . . Neutron Probe Calibration .......... .............. . . . . . Unsaturated Soil Water Flow .................... In Situ Unsaturated Soil Water Budget . . . . . .............. Soil Physical Measurements.............................. Clay M i n e r a l o g y ........... Infiltration R a t e s ............. Saturated Hydraulic Conductivity .............. Solute M o v e m e n t .................... RESULTS AND DISCUSSION Neutron Probe Calibration .......... Unsaturated Soil Water Flow ........ In Situ Unsaturated Soil Water Budget Soil Physical Measurements .......... Clay Mineralogy ..................... Infiltration Rates . . .............. Saturated Hydraulic Conductivity . . . Solute Movement .................... 9 16 17 22 24 25 26 26 29 32 32 34 42 52 63 66 69 72 V TABLE OF CONTENTS (CONTD) Page SUMMARY AND C O N C L U S I O N S .............. '......................... LITERATURE C I T E D ................ .. . ...................... . . 97 101 APPENDICES...................................................... 105 I LIST OF TABLES Table 1. 2. 3. 4. 5; 6. 7. 8. 9. 10. Page Depths of neutron probe access tubes for each treatment area at the Peabody Big Sky M i n e ................................... 15 Methods used for chemical analyses of the soil samples................................... 31 Actual soil water contents (W) compared to calculated water contents (Wc) using the unsaturated soil water flow model.............. ; . . . 36 Calculated annual soil water drainage from a 150 cm profile for the four treatment areas, Peabody Big ,Sky Mine............ 40 Annual soil water balance for the 150 cm profile of the four treatments, Peabody Big Sky Mine, for the 1975 hydrologic y e a r ................ 45 Annual soil water balance for deep profiles of the four treatments, Peabody Big Sky Mine, for the 1975 hydrologic y e a r .......................... 48 Bulk density, particle density and modulus of rupture analyses of surface soil samples, , Peabody Big Sky Mine, November, 1974 .................. 53 Bulk density through depth of the four treatment areas, Peabody Big Sky Mine, June, 1975.......... .. 57 Particle size distribution through depth for the four treatment areas, Peabody Big Sky Mine, November, 1974 .................................. 59 Particle size distribution and clay mineralogy of representative soil samples from the four treatments, Peabody Big Sky Mine, August, 1975 . . . . ; 65 LIST OF FIGURES Figure 1. Page Experimental plot design of the study area at the Peabody Big Sky M i n e ............................ 10 Topsoiled nonvegetated spoils site, Peabody Big Sky Mine .......................; ......... 11 Topsoiled revegetated spoils site, Peabody Big Sky M i n e .......................................... 11 Nontopsoiled revegetated spoils site, Peabody Big Sky M i n e .......... 12 5. Native range site, Peabody Big Sky Mine . . . . . . . . . . 13 6. Drill rig used for tube installation and taking of core samples, Peabody Big Sky M i n e .............................................. 14 Example of dike used for flooding of plots, Peabody Big Sky Mine ............. 18 8. Flooding of the plots, Peabody Big Sky M i n e .............. 19 9. Plot after the flooding period. Neutron probe is shown in operation, Peabody Big Sky Mine .......................................... 20 Infiltration apparatus in operation showing the collection of runoff, Peabody Big Sky M i n e .................................................. 27 Diagram of sample holder used for conductivity measurements, Peabody BigSky Mine ..................... 28 Neutron probe field calibration curve, Peabody Big Sky Mine ........................... 33 Soil desorption curves of 0-15 cm soil samples from the four treatment areas, Peabody Big Sky M i n e .................... 62 2. 3. 4. 7. 10. 11.. 12. 13. viii LIST OF FIGURES (CONTD) Figure 14. 15. 16. 17. 18. 19. 20. 21. 22 23. 24. Page Infiltration rates of the four treatment areas, Peabody Big Sky M i n e .......................... 67 Saturated hydraulic conductivity through depth for disturbed samples from the four treatment areas, Peabody Big Sky Mine ................ 71 Soil profile distribution of NO^-N from November, 1974 to October, 1975, Peabody Big Sky M i n e .......................................... 74 Soil profile distribution of NH.-N from June to October, 1975, Peabody Big Sky M i n e ................ 77 Soil profile distribution of PO.-P from November, 1974-October, 1975, Peabody Big Sky M i n e .............................................. 78 Soil profile distribution of NH.OAc extractable calcium from November, 1974 to October, 1975, Peabody Big Sky M i n e ................................. 80 Soil profile distribution of NH.OAc extractable magnesium from November, 1974 to October, 1975, Peabody Big Sky Mine ................................. 81 Soil profile distribution of NH^OAc extractable potassium from November, 1974 to October, 1975, Peabody Big Sky M i n e .................................. 83 Soil profile distribution of NH.OAc extractable sodium from November, 1974 to October, 1975, Peabody Big Sky Mine ................................... 84 Soil profile distribution of water soluble calcium from June to October, 1975, Peabody Big Sky M i n e .......................................... 87 Soil profile distribution of water soluble magnesium from June to October, 1975, Peabody Big Sky M i n e ..................................... 89 ix LIST OF FIGURES (CONTD) Figure 25. 26. 27. 28. Page Soil profile distribution of water soluble sodium from June to October, 1975, Peabody. Big Sky M i n e ............................ . . . 90 Soil profile SAR levels from June to October, 1975, Peabody Big Sky M i n e .......... .. .'91 Soil profile distribution of salt from November, 1974 to October, 1975, Peabody Big Sky M i n e .......................... .. . . . .93 Soil profile pH levels from November, 1974 to October, 1975, Peabody Big Sky Mine ................ 95 LIST OF APPENDICES Appendix Table I. 2. Page Soil Conservation Service classification and profile description of the Yaraac soil series.................. ........... .. .106 Results of linear regressions and cal­ culated values of water movement model parameters a and b for rep I, topsoiled nonvegetated treatment, Peabody Big Sky Mine, summer of 1975 . . . .......... . 109 3. Results of linear regressions and cal­ culated values of water movement model parameters a and b- for rep 2, topsoiled nonvegetated treatment, Peabody Big Sky Mine, summer of 1975 .......................... .110 4. Results of linear regressions and cal­ culated values of water movement model parameters a and b for rep 3, topsoiled nonvegetated treatment, Peabody Big Sky Mine, summer of 1975 ............ ............. ill 5. Results of linear regressions and cal­ culated values of water movement model parameters a and b for rep I, topsoiled revegetated treatment, Peabody Big Sky Mine, summer of 1975 ........................ . 112 Results of linear regressions and cal­ culated values of water movement model parameters a and b for rep 2, topsoiled revegetated treatment, Peabody Big Sky Mine, summer of 1975 .................. .. .113 Results of linear regressions and cal­ culated values of water movement model parameters a and b for rep 3, topsoiled revegetated treatment, Peabody Big Sky ' Mine, summer of 1975 .................. .. 114 6. 7. xi LIST OF APPENDICES (CONTD) Appendix Table 8. 9. .10. 11. 12. 13. 14. Page Results of linear regressions and cal­ culated values of water movement model parameters a and b for rep I, nontopsoiled revegetated treatment, Peabody Big Sky Mine, summer of 1975 .................... 115 Results of linear regressions and cal­ culated values of water movement.model parameters a and & for rep 2, nontopsoiled revegetated treatment, Peabody Big Sky Mine, summer of 1975 .................... 116 Results of linear regressions and cal­ culated values of water movement model parameters o. and & for rep 3, nontopsoiled revegetated treatment, Peabody Big Sky Mine, summer of 1975 .......... .. 117 Results of linear regressions and cal­ culated values of water movement model parameters # and & for rep I, native range treatment, Peabody Big Sky Mine, summer of 1975 . . ...................... 118 Results of linear regressions and cal­ culated values of water movement model parameters cl and b for rep 2, native range treatment, Peabody Big Sky Mine, summer of 1975 . . . .......... ■ ........ 119 Results of linear regressions and cal­ culated values of water movement model parameters a and b for rep 3, native range treatment, Peabody Big Sky Mine, summer of 1975,...................... .. . 120 Monthly soil profile water balance to the 150 and 480 cm depths for rep I, topsoiled nonvegetated treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 . . . . '121 xii LIST OF APPENDICES (CONTD) Appendix Table 15. 16. 17. 18. 19. 20. 21. 22. Page Monthly soil profile water balance to the 150 and 420 cm depths for rep 2, topsoiled nonvegetated treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 122 Monthly soil profile water balance to the 150 and 450 cm depths for rep 3, topsoiled 1 nonvegetated treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 . .......... 123 Monthly soil profile water balance to the 150 and 450 cm depths for rep I, topsoiled revegetated treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 . . . . . . . 124 Monthly soil profile water balance to the 150 and 480 cm depths for rep 2, topsoiled revegetated treatment, Peabody Big. Sky . Mine, January, 1975 to April, 1976 ............ 125 Monthly soil profile water balance to the 150 and 330 cm depths for rep 3, topsoiled revegetated treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 . . . . . . . .126 Monthly soil profile water balance to the 150 and 300 cm depths for rep I, nontopsoiled revegetated treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 . . . . ' . 127 Monthly soil profile water balance to the 150 and 480 cm depths for rep 2, nontbpsoiled revegetated treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 ........ - Monthly soil profile water balance to the 150 and 480 cm depths for rep 3, nontopsoiled revegetated treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 ........ .129 . 1-28 xiii LIST OF APPENDICES (CONTD) Appendix Table 23. 24. 25. Page Monthly soil profile water balance to the 150 cm depth for rep I, native range treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 . . . . . . . . . . 130 Monthly soil profile water balance to the 150 cm depth for rep 2, native range treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 ............ . ,131 Monthly soil profile water balance to the 150 cm depth for rep 3, native range treatment, Peabody Big Sky Mine, January, 1975 to April, 1976 .......... .. . . . 132 ABSTRACT A study was initiated in November, 1974 at the Peabody Big Sky Mine near Colstrip, Montana to determine soil water and solute movement in strip mine spoils. Three spoils treatments, consisting of topsoiled nonvegetated, topsoiled revegetated and nontopsoiled revegetated spoils, and a native range site were studied. The testing arid evaluation of an unsaturated soil water movement model showed the model to be applicable to soil water movement in both the mine spoils and native range. Calculation of in situ soil water budgets indicated drainage was occurring from the spoils and native range. Both the water movement model and the in situ water budgets indicated that the quantities of soil water movement in the native range was approximately 1.5 times greater than in the spoils. The lower amount of soil water movement in the spoils was attri­ buted to bulk density, which was 54% higher than native range, and to higher contents of silt and clay than native range. Clay mineralogy analyses indicated that the dominant clay minerals in all treatments were non-expanding lattice clays, which would not greatly limit soil water movement due to expansion upon wetting. Infiltration rates of the native range were 60-86% higher than those of the spoils. These differences were attributed to the effects of soil structure, vegetation and topsoiling techniques. Saturated hydraulic conductivity of the native range was 3.5 times greater than that of the spoils treatments. The higher hydraulic conductivity of the native range was attributed to textural differences between the native range and spoils treatments. No definite trends in solute movement were shown due to the short time span of this study. With the exception of potassium and NCL-N, the solute concentrations of the spoils were not, in general, different from the native range. The spoils contained lower potassium and higher NO3-N concentrations than present in the native range. Exchange­ able sodium percentages (ESP) and sodium adsorption ratio (SAR) indi­ cated no sodium problems were present in the spoils and native range. The higher quantities of soil water movement in the native range compared to the spoils indicate that greater amounts of solute movement into the groundwater may occur from the native range than from the spoils. INTRODUCTION An area of major concern with respect to surface strip mining of coal in the Western United States is the effect of mining on soil water and solute movement. This study was initiated in order to determine soil water and solute movement characteristics in strip mine spoils. Three different spoil treatments and a native range site were compared. The spoil treatments represented a range of geologic material and reclama­ tion techniques. Water and solute movement characteristics obtained from these spoils treatments should be representative of spoils mater­ ial present in the area surrounding Colstrip, Montana. A study of native range was necessary in order to obtain informa­ tion regarding soil water and solute movement characteristics in land undisturbed by mining activities. Results obtained from the native range site served as a basis of comparison for information obtained from the spoil areas. The native range site was chosen to be as representative as possible of mineable rangeland in the Colstrip area. The objectives of this study were to: 1) 2) 3) 4) test and evaluate an unsaturated soil water move­ ment model and apply the model to the mine spoils and native range; determine the in situ water budget in spoils and native range in order to determine quantities and rates of soil water movement on a hydrologic year basis.; measure'various physical characteristics in spoils and adjacent native range soils in order to explain differences in water movement which existed and to determine the effects of mining on these physical characteristics; and determine solute concentrations and translocation occuring in spoils and native range soils. . 2 This study was conducted at the Peabody Big Sky Mine near Colstrip, Montana. LITERATURE REVIEW Coalfields in 8 western states - Montana, Wyoming, North Dakota, South Dakota, Utah, Colorado, New Mexico and Arizona - . underlie in excess of 100 million acres and contain more than two trillion tons of coal. The coal deposits in Montana alone contain 13% of the total reserve in the United States (National Academy of Sciences, 1974). The area underlain by coal bearing rocks in Mon­ tana is 51,300 square miles which is 35% of the total area of the state. The projected area of land in Montana that will be disturbed by surface coal mining by the year 2000 is in excess of 42,000 acres (Copeland and Packer, 1972). It is important that sound re­ clamation techniques be established for these areas and that a thorough knowledge of the effects of mining on both the disturbed areas and surrounding areas is obtained. . Thus far, the major portion of reclamation research has been concerned with revegetation of strip mined areas. Emphasis has not been on the effects of mining on soil properties such as soil water and solute movement. Information on these factors is important since any changes in soil water and solute movement could result in ■changes in the overall hydrologic system and groundwater quality of the area. Verma and Thames (1975) have done some preliminary work on soil moisture in strip mine spoils in Arizona. Using a neutron probe, it was shown that partial recharge of the soil water occurred during.the 4 snowmelt period. However, soil moisture remained near the permanent wilting point to a depth of 200 cm during most of the period from September through May. No statements were made as to the occurrence or amount of drainage from the spoils. Sindelar, et al (1973) conducted a study which involved the effects of three different spoils surface manipulation treatments on soil moisture and revegetation at the Rosebud mine near Colstrip, Montana. Using soil moisture blocks, it was shown that the soil water potential at the surface remained near 15 atmospheres from May through November for all treatments. At 30 and 60 cm depths, soil water poten­ tial remained above 15 atmospheres for most of the period while the soil water potential remained significantly above 15 atmospheres for the entire period at a depth of 120 cm. The difference between these results and those of Verma and Thames was probably due to Montana's higher annual precipitation and lower mean annual temperature. Also, the surface manipulation treatments used tend to retain surface runoff allowing the water to enter the soil. . In stripping operations, the overburden is usually deposited in long, roughly parallel ridges or banks. These banks are then graded or leveled by moving the tops of the ridges into the valleys result­ ing in near level or rolling topography. Curtis (1973) measured moisture and density relations of graded strip mine spoils in Kentucky. The. study area was divided into four 5 blocks running parallel to former ridges which had been leveled. Two of the blocks were scarified by traversing the plots with a road grader equipped with ripper teeth. His results showed approx­ imately 20% higher bulk densities at the 30 to 270 cm depths in the leveled ridges as compared to the spoils material which had been moved into the valleys. The moisture contents (g/g) were sig­ nificantly higher in the valleys than in the leveled ridges. was assumed that the ridges became compacted in two ways. It First* the weight of the stacked spoils resulted in compaction and second, the heavy equipment, used in the grading operations resulted in com­ paction of the spoils. It was also found that scarification had little effect in reducing the surface density. Over the winter, however, all four plots showed a significant decrease in surface density which was attributed to frost action during the winter. Thus, in areas where frost action is encountered, such as Montana, sig­ nificant reductions in surface densities could occur. Limstrom (1960) did a study on strip mine spoils in Ohio. The infiltration rates on ungraded spoils banks and on adjacent graded banks were determined. The ungraded banks had infiltration rates of 10 cm/hr as compared to 1.5 cm/hr on the graded banks. Evidently __ the resurfacing of mine spoils can result in compaction and affect water movement in these spoils. Resistance to compaction is determined by particle size distribu­ 6 tion and composition of the particles in a soil. Compaction is most easily achieved with soils consisting of different particle sizes where smaller particles can be forced into voids between larger parti­ cles (Warkentin, 1971). This results in a decrease in pore volume and therefore a higher bulk density. The clay fraction of soils is generally considered as being the particle size class which is the major limiting factor to water move­ ment. However, the silt fraction can also have a great effect on soil water movement. and permeability. Diebold (1954) related silt content to bulk density He studied 215 medium textured soils in the south- western United States. It was found that soils with greater than 40% silt had higher.bulk densities than the soils with less than this amount of silt. For all soils, the permeability decreased with in­ creasing bulk density. For soils with the same bulk density, the per­ meabilities for soils with less than 40% silt were several times high­ er than those for the soils with higher silt contents. Also, for soils with low bulk densities (non-compacted), the infiltration rates were 1.5 times greater for soils with less than 40% silt. At bulk densities approaching 1.5 g/cm , the infiltration rates were twice as high for the lower silt content soils. Diebold speculated that the silt acts as a clogging material resulting in lower permeability and infiltration rates. Upon compaction, at least three changes in porosity will occur: 7 (I) the total porosity is reduced; volume of small pores increase; and (2) the total number and relative (3) the total number and relative volume of larger pores decreases (Hill and Sumner, 1967). Due to these changes in porosity, water transmission in compacted soils is greatly affected. The volume of water flowing through a tube or pore per unit of time is proportional to the fourth power of the. radius. Halving the size of the tube decreases volume of flow by a factor of 16. Therefore, decreasing the large voids through compaction has a large effect in decreasing water transmission in saturated soils. It has been found that the logarithm of the saturated hydraulic conductiv­ ity decreases linearly as void ratio increases (Warkentin, 1971). The relationship between porosity and unsaturated hydraulic con- ' ductivity is less straightforward. The large voids are filled with air and do not contribute to water flow, so there is less decrease in conductivity with decreasing porosity. Jackson (1963) studied the effects of soil texture and compaction on unsaturated hydraulic conductivity: He found that the hydraulic conductivity decreased with increasing compaction for a soil with high clay content but the hydraulic conductivity changed little with com­ paction for a coarse grained soil. Waldron, et al. (1970) examined the effect of compaction on the unsaturated hydraulic conductivity of a Yolo loam. The hydraulic conductivities were determined under isotropic confining pressures of 8 2 0.1 to 3.2 Kg/cm . For a decrease in porosity of 0.52 to 0.40 the hydraulic conductivity decreased from 2xl0-^ cm/sec to I .5x10~^ cm/ sec. This decrease in porosity is equivalent to an increase in bulk density of 1.33 to 1.60 g/crn^. Gumbs and Warkentin (1972) worked with a swelling clay soil packed into columns. It was found that small increases in bulk den- 3 sity over the range of 1.10 to 1.25 g/cm markedly decreased the rate of unsaturated water flow in the sample. The preceding discussion of the effects of compaction on water movement was limited to soils since no information could be located on water movement in mine spoils. However, the effects of compaction which were discussed would affect mine spoils in the same manner. More extensive research is needed in the area of soil water and solute movement in mine spoils. This information is needed not only to determine reclamation procedures and future use of the mine spoils but also to determine the effects of strip mining on surrounding areas Any changes in soil water and solute movement characteristics could conceivably affect the water supplies of nearby homesites and the qual ity of existing range and cropland near the mining areas. METHODS AND MATERIALS Site Description and Design The study area was located on the Peabody Big Sky Mine in south­ eastern Montana. The four treatments were topsoiled nonvegetated spoils, topsoiled revegetated spoils, nontopsoiled revegetated spoils and native range. The treatment plots all had approximately the same slope and aspect. Each treatment contained three replications measur­ ing 10x10 meters for a total size of 10x30 meters for each treatment. The field site and design is shown in Figure I. The topsoiled nonvegetated site was mined in February, 1974. site was reshaped and topsoiled during the spring of 1974. The The site is shown in Figure 2. The topsoiled revegetated site was mined in October, 1970 and re­ shaped and topsoiled in the winter of 1972. This site was seeded the following spring at 25 Ibs/acre to a mixture of crested wheatgrass, in­ termediate wheatgrass, western wheatgrass, smooth brome, alfalfa, yellow sweetclover, white sweetclover and green needlegrass. The top^ soiled revegetated spoils site is shown in Figure 3. Mining activity began on the nontopsoiled revegetated site in September, 1970. This site was recontoured several times, the last of which was in the winter of 1974. The site was seeded the following spring to the same mixture and rate as for the topsoiled revegetated spoils area. The resulting stand of vegetation for this site was poor. The nontopsoiled revegetated site is shown in Figure 4. 10 Figure I. Experimental plot design of the studyarea at the Peabody Big Sky Mine. 11 Figure 2. Topsoiled nonvegetated spoils site, Peabody Big Sky Mine Figure 3. Topsoiled revegetated spoils site, Peabody Big Sky Mine 12 Figure 4. Nontopsoiled revegetation spoils site, Peabody Big Sky Mine The soil of the native range site is in the Yamac soil series which consists of deep, well drained soils formed in an alluvium from sedimentary uplands. Camborthids. The soil family is fine-loamy, mixed Borollic The Soil Conservation Service classification and profile description of the Yamac series is given in Appendix Table I. The native range site is shown in Figure 5. Neutron probe access tubes were installed in the center of each rep in November of 1974. A trailer drawn Giddings^ drill rig was used to prepare holes to receive the tubing. The drill rig is shown in ■'‘Mention of trade names does not imply endorsement, but its purpose is to inform the reader. 13 In Figure 6. The tubes were installed as deep as possible before encountering resistance too great for the drill rig. The corresponding tube depths are listed by replication in Table I. Figure 5. Native range site, Peabody Big Sky Mine 14 Figure 6. Drill rig used for tube installation and and taking of core samples 15 Table I. Depths of neutron probe access tubes for each treatment • area at the Peabody Big Sky Mine, Treatment Replication Tube Depth (cm) Topsoiled nonvegetated spoils I 2 3 480 420 450 Topsoiled revegetated spoils I 2 3 450 480 330 Nontopsoiled revegetated spoils I 2 3 300 480 480 . Native range I 2 3 180 180 180 16 Neutron Probe Calibration Since a major portion of the study involved the use of neutron probe, it was necessary to determine whether or not the factory calibration was valid for the soils of the study area. Core samples were taken from each treatment area in 30 cm incre­ ments and weighed immediately. Neutron probe access tubes were installed following the taking of the core samples and moisture readings were taken using the neutron probe. The samples were oven- dried at IlO0C and the oven-dried weight of each core sample was determined. Using the moist weights from the field and the corre­ sponding oven-dried weights, the gravimetric water content of each sample was calculated. The volume of each sample was determined I from the inside diameter of the cutting tip and the core length of 30 cm. The bulk density of each sample was calculated using Equation I. oven dry weight of sample (g) Bulk density q volume of sample (cm) (I) The percent moisture by volume of each sample was then calcula­ ted using Equation 2. 17 Water content, L . . water content, % by weight by volume = — bulk density (2) Linear regression analysis was run on the neutron probe read­ ings, expressed as count ratio vs percent moisture by volume. A calibration curve was then calculated using the results of the lin­ ear regression. The field calibration was compared to the factory calibration to determine if any significant differences were present, Unsaturated Soil Water Flow In order to obtain knowledge of the unsaturated flow character­ istics of the treatment areas, a mathematical model developed by Sisson (1972) which describes the water flux through the soil was utilized during the summer of 1975. in order to apply the model. water movement can be present. Two requirements must be met First, no layers restricting soil Secondly, a uniform matric potential (Tm) must be present to the depth the calculations are made. The model has been tested on various agricultural soils in Montana but has not been applied to mine spoils. It was felt that spoils meet the first requirement since any layers restricting soil water move­ ment would have been destroyed by mining activity. The model utilizes Equation 3, (3) 18 where w = total water In cm above depth x x = depth in cm to which Ym is constant t = time in days from occurrence of soil water recharge a and b are constants In order to calculate the values for the constants the follow­ ing procedures were used. I. Dikes measuring 3x3 meters were constructed on each rep with the neutron probe access tube being located in the center of the dike. An example of this is shown in Fig­ ure 7. Figure 7. Example of dike used for flooding of plots 19 2. The plots were then flooded with the head being maintained by subsequent additions of water. Ponding was maintained for a period of approximately 36 hours. ation is shown in Figure 8, The flooding oper­ A sample of the ponding water was analyzed for pH, electrical conductivity, calcium, magnesium, sodium, sodium adsorption ratio (SAR), carbonates and bicarbonates in order to determine whether or not solutes were present which might affect water movement through the soil. Figure 8. Flooding of the plots 20 3, After completion of the ponding period, the remaining water was released and the plots covered with plastic to prevent moisture loss through evaporation. Moisture readings were then taken at 30 cm increments with the neutron probe. These readings were considered as being at time = 0. Figure 9 shows a plot after the flooding period. Figure 9. 4. Plot after the flooding period. shown in operation Neutron probe is Thereafter, moisture readings were taken onxan hourly basis the first day and with decreasing frequency the following days as the soil water flux decreased, The total time 21 period during which readings were taken covered 30 to 90 days. A series of water contents at various depths through time were thus obtained. Using Equation 3, and letting R = ax^"1"^ (4) the following equation is obtained. W = Rt"b (5) Taking the natural logarithms of both sides of Equation 5 yields In w = In R - b In t (6) Equation 6 is in the form of a linear equation where In w and In t are the y and x variables, respectively, and -b is the slope. Using the water contents (w) obtained at various times (t), lin­ ear regressions were performed in order to determine the slope. linear regression was run for each depth. The resulting r 2 A values for these regressions were then used to determine the maximum depth to which a uniform i(jm was obtained. Since the model should hold true o for the region of uniform (Jjii1, we used the r values as an indicator of the goodness of fit of the data to the model. Following this 22 ■reasoning, the r values should show an abrupt and continued decrease at depths below which a nearly uniform was obtained. In this manner, the value Of x in each plot was determined, Equation 7 is the equation of the regression line In w!* = s In t^ + I (7) where s = slope of regression line I = intercept of regression line . By comparing Equation 7 with Equation 6, it is seen that b is the negative of the slope of the regression line. By use of Equation 7 and any value of t^, the value of w. which lies on the regression line at that time can be calculated. The only unknown value is a which can now be solved for by substitution of the known values into Equation 3, In s i t u Unsaturated Soil Water Budget Using the neutron probe, soil moisture readings were taken on each rep on a monthly basis from January, 1975 to May, 1976. moisture readings were incorporated into a water budget model. tion 8 is the,water budget equation which was used. These Equa­ 23 + ASWC =’PPT - ET* + W F - R O (8) where ASWC = change in soil water content PPT = precipitation ET = evapotranspiration WF = water flow by unsaturated or saturated processes into or out of the zone RO = runoff The signs associated with Equation 8 indicate the direction of water movement from the system. A negative value signifies a loss of water from the system while a positive value indicates a gain in water. Of the five hydrologic components in Equation 8, ASWC., PPT, ET and RO are either measured or estimated. WF is found by rearranging Equation 8 to give WF = ASWC - PPT + ET + RO Once WF is estimated, all flow components are available for the water balance. ASWC was obtained from the monthly neutron probe read­ * Evapotranspiration (ET) results in a loss of water from the profile. For purposes of clarification, all ET values-presented in the results will be designated as negative values. However, in order to utilize Equation 8, the aboslute value of the negative'ET must be used, i.e ., + ASWC = PPT - {ET} - RO + W F , where ET is a negative value. 24 ings. PFT was estimated from rainfall gauge stations located at the Western Energy Rosebud Mine, 5 miles northeast of the field site, and at the Peabody Big Sky Mine. ET was obtained from lysimeters located on mine spoils at the Western Energy Rosebud Mine. RO was estimated as being zero since the slopes of all the treatment areas are nearly level. The RO component is subject to the most error by making this estimation but no means of measuring runoff were available, . Soil Physical Measurements Surface soil samples from each rep were analyzed for particle density, bulk density and modulus of rupture, were also constructed. Soil desorption curves The soil samples used for the particle den­ sity, modulus of rupture and soil desorption curve determinations were taken in November, 1974 while the samples for bulk density were taken in February, 1975, Procedures for particle density, modulus of rupture and soil desorption curves were as outlined by the United States Salinity Laboratory (1969). Bulk densities were measured using the ped method described by Blake (1965), In addition, bulk densities through depth were determined in June of 1975. rep. Soil cores were taken in 30 cm increments from each The samples were then ovendried at IlO0C and weighed. The volume of the cores were calculated from the inside diameters' of. the cutting tip and the core length of 30 cm. then calculated using Equation I, The bulk densities were 25 Since a layer of sandstone bedrock is present at a depth of 180 to 210 cm on the native range site, it was not possible to obtain core samples beyond this depth using our drill rig. Therefore, a core sample was obtained in June, 1975 from the native range site by a larger drilling rig operated by the Peabody Coal Company. The core extended to a depth of 6 meters, Where the cores were intact, the bulk density was determined using Equation I, In this case, the core volume was determined directly using calipers. Bulk den­ sity was obtained using.the ped method when the cores were not in­ tact. At some depths, no useable peds were obtained, No values of bulk density were determined at these depths. Particle size distribution was determined on core samples from each rep. The samples were taken in November, 1974, The 6 meter native range core sample taken in June? 1975 was also analyzed for particle size. The analyses were performed using the hydrometer method described by Day (1965). Particle size analyses were done by the Peabody Coal Company Central Laboratory in Freeburg, Illinois. Clay Mineralogy Clay mineralogy analyses were done on representative surface samples from each treatment. The analyses were performed using xray diffraction techniques under the supervision of Dr, Murray Klages, Professor of Clay Minerology, Montana State University. 26 Infiltration Rates Infiltration rate measurements were performed on each rep. The infiltration rates were determined using the method and appar­ atus described by Meeuwig (1971). shown in Figure 10. The infiltrometer apparatus is Basically, the device consists of a plexiglas water reservoir which delivers a raindrop effect onto the soil sur­ face through 517 capillary tubes. A flowmeter registers the water application rate while soil surface runoff is funneled into a collection cup. The infiltrometer encompasses a .31 m o sample area. Simulated rainfall was applied at a rate of 16.3 cm/hr. The volume of runoff was measured every 3 minutes for a 30 minute test period. The high rate of wa,ter application simulated a severe rainstorm in volume but not in raindrop collision force. Saturated Hydraulic Conductivity Saturated hydraulic conductivities with depth were determined on disturbed samples from each treatment. The constant head per- meameter used was similar to that described by Klute (1965) . The sample holders were constructed from 10 cm lengths of PVC pipe having an inside diameter of 7.62 cm. The bottoms of the holders were sealed with plexiglas through which a 0.64 cm drainage hole had been drilled. holder, A funnel was then attached to the bottom of each A diagram of the sample holder is shown in Figure 11, 27 Figure 10. Infiltration apparatus in operation showing the collection of runoff. A device was set up so as to maintain a constant head above each soil sample. A 0.005 CaClg solution was used in order to maintain the salt content of the samples. It was felt that the use of dis­ tilled water would result in the removal of soluble salts from the sample. If this occurred, flow could be decreased due to soil dis­ persion resulting in lower hydraulic conductivity values. 28 7.62 cm I.D. water level 10 cm soil sample Figure 11. Diagram of sample holder used for conductivity measure­ ments . The soil samples were air dried and ground to pass a 2 mm sieve. Filter paper was placed in the bottom of each sample holder to pre­ vent loss of the sample and the funnels were stoppered. Approximately 3 230 cm of soil were placed in each holder and packed with a vibrator. 29 The holders were then filled with the C a C ^ solution taking care not to disturb the samples. The constant head devices were then set up and the samples allowed to saturate for 16 hours, The stoppers were removed and the volume of flow measured until flow from the sample was constant. Once the equilibrium flow condi­ tions were obtained, which required 7 to 14 days, the saturated hydraulic conductivities were calculated using the following form of Darcy's Law. • K = (Q/At) (L/AH) (9) where K = conductivity of the soil to water in cm/day Q = volume of flow in cm 3 at equilibrium A = cross sectional area of sample in cm 2 t = time in days L = length of sample in cm AH = hydraulic head in cm Solute Movement In order to obtain measurements on solute movement,■core samples were taken on a twice yearly basis from each rep, in November, 1974 and June and October of 1975, Samples were taken These samples were taken to the maximum depth possible using our drilling rig. In addi­ tion, a 6 meter core sample from the native range site was taken in 30 June, 1975 by a larger drilling rig operated by Peabody Coal Com­ pany. All samples were analyzed for NO^-nitrogen, PO^-phosphorus, exchangeable calcium-magnesium-sodium-potassium, pH and electrical conductivity. In addition to these analyses, the samples taken in June and October of 1975 were analyzed for NH^-nitro'gen and water soluble calcium-magnesium-sodium for calculation of sodium adsorption ratio (SAR). for each analysis. Table 2 lists the methods and references All chemical analyses were done by the Peabody Coal Company Central Laboratory in Freeburg, Illinois. 31 Table 2. Methods used for chemical analysis of the soil samples. Method Analysis Reference NO3-N Phenoldisulfonic acid method Bremner (1965a) NH7-N 4 Steam distillation method Bremner (1965b) PO4-P NaHCO3 extractable P Olsen (1954) 1:20 soil:l N NH4OAC extract analyzed by atomic adsorption spectrophotometry Pratt (.1965) Saturated paste extracts analyzed by atomic adsorption spectrophotometry U 1S, Salinity Lab (1954) pH 1:2 soil:water Peech (1965) Electrical conductivity 1:2 soil:water extract U„S, Salinity Lab (1954) Exchangeable Ca-Mg—Na-K Water soluble Ca-Mg-Na tNa} SAR (({Ca} + {Mg})/2)1/2 • ... where all concentrations are in. meq/L U .S Salinity Lab (.1954) RESULTS AND DISCUSSION Neutron Probe Calibration The field calibration curve for the neutron probe and the factory calibration are shown in Figure 12. Data for the field calibration were obtained from observations of percent moisture by volume vs. count ratio comparisons from profiles in each treat­ ment. The data from the topsoiled nonvegetated site was consider­ ably different from the other three sites. This difference could possibly have been due to environmental factors affecting the neutron probe equipment, equipment malfunction or an insufficient length of time allowed for the scaler unit to warm up. Although the exact cause for the variation in data is not known, it was felt that the topsoiled nonvegetated data was in error. Calibration data from this site were therefore deleted. By deleting the topsoiled nonvegetated data, a high correlation of the data to the regression line was obtain'ed indicated by an r 2 of 0.81, giving the equation for the field calibration curve shown by Equation 10. moisture (% by volume) = 14,27 (count ratio) + 7.31 (10) Equation 11 is the factory calibration curve. moisture (% by volume) = 45.79 (count ratio) - 4.83 (11) The slope o f .14.27 for the field calibration was significantly Factory calibration Slope = 45.794 a Intercept = -4.83 P 30 Field calibration Slope= 14.27 h Intercept=7.309 r2 =0 .8 0 9 Count Ratio Figure 12. Neutron probe field calibration curve, Peabody Big Sky Mine, June, 1975. Slopes followed by the same letter indicates no significance at the 0.01 level. 34 different at the 0.01 level the factory calibration. 2 compared to the slope of 45.79 for Use of the factory calibration would re­ sult in moisture content estimates substantially different from the actual moisture contents. Due to this and to the high calibration correl­ ation between volumetric moisture content and field neutron probe counts, Equation 10 was used for the computation of all moisture contents presented in this thesis. At low count ratios, the field calibration would give erron­ eous moisture contents. Theoretically, a count ratio of ,zero indi­ cates no moisture present. However, the field calibration curve would indicate 7.31% moisture by volume at a count ratio of zero. Since very few of the count ratios obtained in the entire course of the study were below 0.5 and none below 0.2, the problem associated with count ratios near zero did not affect our calculations. Unsaturated Soil Water Flow Results of the linear regression of the natural logarithm of total water content (w) vs. natural logarithm of time (t) and the calculated values of the water movement model parameters a and b at each depth for each rep are given in-Appendix Tables 2 through 13. The depth (x) to which a uniform matric potential, 4y, was obtained O r Throughout the remainder of this thesis, any reference to sig­ nificance will be at the 0.05 level unless otherwise stated. r 35 is indicated in each table. In some cases, the choice of x was arbi­ trary since there wasn't always an abrupt drop in the r^ values nor did the r 9 values continue to decrease with depth in all cases. values of a and b decreased with depth for all reps. In general, This indicates that a and b are not true constants but are variable to a certain ex­ tent. Also, the b parameters for the native range reps were generally higher at any given depth than for the spoils treatments.. The greater the value of b, the greater is the negative slope of the regression of In w vs In t., Therefore, the larger b values for the native range reps indicate a higher rate of soil water movement through the native range soil as compared to. the spoils treatments. The chemical analysis' of the water used for the flooding of the plots were: pH (7.1), electrical conductivity (1300 ymhos/cm), calcium (7.07 mg/1), magnesium (14.53 meq/1), sodium adsorption ratio (1.17), carbonates (0 meq/1) and bicarbonates (7,08 meq/1). None of the concen­ trations are at levels which would result in decreased soil water move­ ment through their physio-chemical effect on the soil, was of particular importance. The SAR of 1.17 In general, use of irrigation water hav­ ing SAR values of 10 or greater results in dispersion of the clay frac­ tion of soils which could decrease soil water movement. The SAR of the flooding water was well below the critical value of 10. A comparison of calculated and actual soil water contents is given in Table 3. The r 2 value given in Table 3 is the r 2 of the linear re- . Table 3. Actual total soil water contents (IV) compared to calculated water contents (IV ) using the unsaturated soil water flow mo d e l . Topsoiled nonvegetated I Topsoiled revegetated Nontopsoiled revegetated Native range r Model Parameters 2 a b x (cm) t (days) IV^ (cm) iV(cm) Difference(cm)* 47.87 48.41 -0.54* 0.87 0.1969 0.0081 240 49.2 2 0.68 0.2094 0.0106 240 120.0 50.62 48.68 1.94* 3 0.71 0.2176 0.0047 210 63.1 45.96 44.71 1.25* I 0.43 0.2355 0.0091 120 78.2 28.37 26.67 1.70* 2 0.73 0.2406 0.0078 180 78.3 43.59 42.78 0.81* 3 0.11 0.2292 0.0021 60 79.2 13.74 13.46 0.28* I 0.58 0.2329 0.0058 60 49.1 13.99 13.03 0.96* 2 0.83 0.1968 0.0052 270 48.2 53.61 52.50 1.11* 3 0.53 0.2195 0.0230 60 102.2 13.01 13.03 -0.02* I 0.91 0.2321 0.0143 90 64.0 20.99 20.36 0.63* 2 0.81 0.2329 0.0170 90 64.0 21.08 20.46 0.62* 3 0.90 0.2009 0.0274 150 50.0 31.06 30.23 0.83* Mean ^ Difference(cm)' O rep Ig Treatment 0.93* 0.68b 0.69b * Difference within the same treatment followed by the same letter are not significant at the 0.05 level t Means followed by the same letter are not significant at the 0.05 level 37 gression for depth x indicated in Appendix Tables 2 through 13. value of x is the depth to which a uniform rep. \pm The was obtained in each The a and b values are those which correspond to x. Neutron probe readings were taken on October 7, 1975 which was after the water movement model testing period was terminated. The time t is the per- ' iod of time from t = 0 for each rep to the time of the October 7th readings. w c is the total water content above x calculated from the model parameters shown, w is the actual water content above x obtained from the on-site October 7 neutron probe readings. The differences ■ between w c and w are presented in the last column. In general, the calculated values were higher than the actual water contents. However, the differences are small when compared to the profile depth and time period from which w was calculated. For c• example, the largest difference of 1.94 cm is for a 240 cm profile over a period of 120 days. The water movement model is applicable to unsaturated soil water flow in the mine spoils since the differences between w and w c within each treatment were non-significant. Since the three mine spoil treatments represent a range of geological mater­ ial and reyegetation management at the Peabody Big Sky Mine, it can be assumed that the water movement model is applicable to all mine spoil types present at the mine. Further, it is felt this model should be applicable to mine spoil studies in the Western region, 2 It should be noted that the r- of the regression•is not necessarily 38 an indicator of the accuracy of the model since the differences between w^_ and w do not always increase with decreasing r values. The variation in the r^ values between reps could be due in part to environmental factors affecting the neutron probe measurements. It is possible that the r^ values could be improved by increasing the number of probe readings. It appears that data which show a low degree of correlation with the regression line still result in model parameters which give good predictions of water content of the soil. The annual drainage from a 150 cm. profile was calculated for each rep using the water movement model with t = 365 days. This time interval was used so that the drainage could be expressed on a hydrologic year basis. reasons. A profile depth of 150 cm was chosen for two First, the average depth for all reps to which a uniform was obtained was 150 cm. It was felt that use of the model for depths greater than 150 cm would not be valid for the reps which had uniform ipm at depths less than 150 cm. Second, 150 cm was assumed to be the maximum rooting depth of any vegetation present. Any water ■ draining past 150 cip would not be taken up by plants and it would not be a serious error to assume that the water would continue in its downward direction Of flow. First, the drainages were calculated using the a and b parameters calculated at the maximum depth of uni- . form ipm . However, since these parameters vary with depth and the depth of uniform ipm varied between the reps within the same treatment, 39 the calculated drainages showed a wide variation within treatments. The drainages were then calculated using the a and b parameters cal­ culated from the regression data for the 150 cm depth for each rep. These data are shown in Table 4 . PiZ^ is the initial water content in a 150 cm profile and was obtained from the neutron probe data at t = 0. This initial water content would approximate the soil water content after a recharge occurrence such as spring melt. PiZf is the final water content in the profile 365 days after the flooding or recharge event calculated using the water movement model. The difference between PiZ^ and PiZ^ represents the drainage from the profile for a one year period. The values of 0.05 and 7.25 cm for rep 3, ' topsoiled revegetated and rep 3, native range, respectively, were shown to be Outliersl at the 0.05 level. The term outlier refers to values which are significantly greater or less than the rest of the data. The values of 0.05 and 7.52 were not used in the calculation of the drainage means for the two treatments. No significant differences were present between the drainage means for each treatment in Table 4. However, these data indicate the drainage to be approximately equal for the spoils treatment while the native range drainage is approximately 1.5 times greater. Annual V v drainage from these spoils treatments ,on a hectare basis represents approximately 250 m^ha-^ whereas the annual drainage from the native range treatment would be 375 m^ha "K Therefore, when the,total area 40 Table 4. Calculated annual soil water drainage from a 150 cm profile for the four treatment areas, Peabody Big Sky Mine. ou. Average drainage (cm) Treatment rep Topsoiled nonvegetated I 2 3 34.71 36.81 35.39 31.09 33.53 33.84 3.62 3.28 1.45 2.78* Topsoiled revegetated I 2 3 36.56 37.18 33.54 34.59 35.04 33.49 1.97 ' 2.14 ■0.05* 2.05* Nontopsoiled revegetated I 2 3 31.26 32.31 34.21 30.85 30.28 29.48 0.41 2.03 4.73 2.39* Native range I 2 3 36.07 36.10 36.90 32.40 32.58 29.58 . 3.67 3.52 7.52* 3.59* * Wf drainage (cm) determined to be outliers at 0.05 level and not included in average drainage means with same letter indicate no significant difference at the •0.05 level 41 of the mine spoils present are taken into account, the drainage is substantial. It is also evident that the same area of native range would result in considerably greater amounts of drainage. These annual drainages were calculated on the assumption that no further precipitation or evapotranspiration occurred after the initial recharge. Soil water drainage is exponential which means that the rate of downward movement is greatest immediately after recharge of the profile with the rate of movement decreasing through time. Thus, a large portion of the water would drain from the pro­ file before any substantial amounts were lost through evapotranspir­ ation. The assumption that no evapotranspiration occurred during the year does not greatly affect the calculated drainage values. Any further precipitation occurring, minus losses through runoff and evapotranspiration, would tend to increase the drainage values. 42 In s i t u Unsaturated Soli Water Budget Soil water budgets on a yearly basis for each rep were deter­ mined in order to obtain information on the characteristics and quantities of soil water movement in the four treatments. The monthly soil water conditions were determined for the 150 cm pro­ file. depth and for the maximum profile depth of the neutron probe access tube. These monthly soil water data were used to determine the water budget on a hydrological year basis for each rep. These monthly soil water data for the two profile depths of each rep dur­ ing the period of January, 1975 through April, 1976, are given in Appendix Tables 14 through 25. The evapotranspiration values were obtained from weighing lysimeters installed in plots having a one year growth of vegetation. These plots are located on mine spoils at the Western Energy Rosebud Mine at Colstrip, Montana. No evapotranspiration values were available for the period of January to May of 1975. It was assumed that evapotranspiration for these months were equal to evapotranspiration values for the same months in 1976. It was believed that this approach would not introduce significant error into these calculations. Therefore, the measured i evapotranspiration values for January through May of 1976 were used for the unknown values in 1975. As discussed in a previous section, these plots were flooded in order to test and evaluate a soil water movement model. A two to three day flooding period was followed by a one to three month period during which time these plots 43 were covered with polyethylene (see methodology). The amount of water which entered the profile during flooding was calculated by difference using neutron probe readings taken prior to and follow­ ing the flooding operation. This increase in water content due to flooding was considered as being nearly equivalent to precipitation for the period when the plots were covered with plastic. Therefore, this quantity was entered under the PPT hydrologic factor for each rep during the month during which flooding occurred. are indicated in Appendix Tables 14 through 25. These values The quantity of water which entered the profile during flooding is normal for a monthly period and in some cases was less than would occur during a wet month. Therefore, flooding of these plots did not introduce an abnormal flux of water into the system. Changes in soil water content were not available for the first rep of the topsoiled nonvegetated and nontopsoiled revegetated treatments nor the third rep of the native range treatment from January to August, 1975. The neutron probe access tubes in these reps were damaged and the device for repairing the tubes was not available until early August. When evapotranspiration, runoff and soil water parameters were considered it was found that, in general, all reps showed a negative value for soil water flow (WF) for the year of 1975 and for the total period of January, 1975 to April, 19761 Since a negative value of WF indicated drainage loss from the profile, it is evident that drainage 44 is occurring. Most of the reps showed maximum drainage occurred during the months of April and May which corresponds to the spring melt period. Using the data presented in Appendix Tables 14 through 25, the annual water balance for a 150 cm profile for the 1975 hydrologic year was calculated for each treatment. A profile depth of 150 cm was chosen so that a comparison could be made between in_situ..measure­ ments with the neutron probe and annual drainage from a 150 cm profile calculated using the water movement model discussed in the previous section. The annual in situ soil water balance for the 150 cm profile of each treatment is given in Table 5. The amounts of water which entered the profile during flooding and the period of time which the plots were covered with plastic varied between treatments. This variation resulted in different values for precipitation and evapotranspiration between treatments shown in Table 5. The values of WF are all negative indicating drainage from the 150 cm profile occurred from each treatment. The native range showed the greatest drainage as indicated by a WF value of -12.28 cm. The topsoiled revegetated treat­ ment with a WF value of -11.07 cm had the greatest drainage for the spoils treatments followed by a drainage of 7.75 cm from the topsoiled nonvegetated treatment. The drainage of 4,60 cm from the nontopsoiled revegetated treatment was the lowest of the four treatments. These drainages from the 150 cm profile shown by the water balance 45 Table 5. Annual soil water balance for a 150 cm profile in the four treatments, Peabody Big Sky Mine for the 1975 hydrologic year. Negative values indicate loss of water from the profile while positive values indicate gain of water. All data are presented in centimeters.* Hydrologic Components PPT ET RO WF ASWC 38.01 . -23.51 0.0 Topsoiled revegetated 37.47 -21.20 0.0 -11.07 5.20 Nontopsoiled revegetated 41.24 -27.40 0.0 - 4.60 9.24 Native range 44.54 -25.82 0.0 -12.28 6.44 * Ln Topsoiled nonvegetated I Treatment 6.75 , PPT = precipitation ET = evapotranspiration RO' = runoff WF = waterflow by unsaturated or saturated processes into or out of the zone ASWC = change in soil water content (Table 5) are considerably greater and more variable between treatments than the calculated annual drainage using the water movement model shown in Table 4. One source of this variation was the use of the same evapo­ transpiration values for all treatments. Evapotranspiration would vary 46 considerably between treatments due to the presence of vegetation on two of the treatments. The greater amount of vegetation present on the topsoiled revegetated and native range treatments as compared to the sparse vegetation found on the weighing lysimeters would result in higher evapotranspiration losses than were shown. Once the surface of the bare soil on the nontopsoiled revegetated and topsoiled nonvegetated treatments dried, evapotranspiration would decrease due to the impedance of water movement through the dry layer (Yang and Delong, 1971) whereas the plants on the other two treatments would continue to transpire water. Thus, these greater evapotranspiration losses that would occur on the topsoiled revegetated and native range treatments would result in lower amounts of drainage than those values calculated in Table 5. These drainage values of the four treatments calculated using the water budget would probably still be higher than those drainages from the 150 cm profile calculated with the water movement model. The fact that no further precipitation was accounted for following the initial recharge of the profile in the use of the water movement model V calcualtions probably accounts for the lower drainage values obtained from the model. The values for ASWC in Table 5 are positive for all treatments indicating that the amount of water stored in the 150 cm profiles showed a net increase during the year. The nontopsoiled revegetated treatment showed “the largest change in soil water content with a gain of 47 9.24 cm during the 1975 hydrologic year. The topsoiled nonvegetated, topsoiled revegetated and native range treatments showed approximately the same increases in soil water content with values of 6.75, 5.20 and 6.44 cm, respectively. It is therefore evident that substantial in­ creases in soil water content occurred in the 150 cm profiles during 1975 and that drainage.from the profiles occurred. Using the data presented in Appendix Tables 14 through 22, the annual water balance for the maximum depths of the neutron probe access tubes on each of the three mine spoils treatments, which ranged from 390 to 435 cm, was calcualted, The access tubes used in these calcula­ tions were the same as those used for calculation of the water balance of the 150 cm profiles, A comparison of the in situ water balances for these deep profiles to those of the 150 cm profiles was made so that any changes in the water balance with depth could be determined. The data for the native range treatment was not included in these calculations since the maximum depth of the access tubes in the native range treat­ ment was only 180 cm. The water balance for the 1975 hydrologic year for the deep pro-' files of the three mine spoils treatments is presented in Table 6. The profile depths shown in the table are the average depth of the three replicated neutron probe access tubes located in each treatment. The amount of drainage from the deep profile showed a decrease for all treatments compared to the 150 cm profile drainage (Table 5). For 48 example, drainage from the topsoiled revegetated treatment for a 420 cm profile was 9.93 cm as compared to 11.07 cm for the same 150 cm profile, and drainage from the topsoiled nonvegetated treatment was Table 6. Annual soil water balance for deep profiles of the four treatments, Peabody Big Sky Mine for the 1975 hydrologic year. Negative values indicate a loss'of water from the profile while positive values indicate a gain in water. All data are presented in centimeters. Hydrologic Components Profile Depth (cm) PPT ET . 435 38.01 '-23,51 0.0 -1.92 12,58 Topsoiled revegetated 420 37.47 -21.20 0.0 -r9.93 6.34 Nontopsoiled revegetated 390 41.24 -27.40 0,0 .1,17 15.01 Treatment Topsoiled nonvegetated PPT ET RO WF RO WF ASWC = = = = precipitation evapotranspiration runoff waterflow by unsaturated or saturated processes into or out of the zone ASWC = change in soil water content Each component is an average of 2 reps with the exception of the topsoiled revegetated treatment components which are an average of 3 reps. 1.92 cm compared to 7.75 for the same 150 cm profile. As discussed previously, the vegetation on the topsoiled nonvegetated treatment would result in a lower amount of drainage than is shown in Table 6. In the 49 case of the nontopsoiled revegetated treatment, the positive WF value indicates that no drainage occurred but instead upward movement of 1.17 cm of water into the profile occurred. This upward movement could be due to the presence of higher quantities of water below the 390 cm depth. This higher amount of water at lower depths would result in upward movement of water due to the presence of a water move­ ment gradient towards the surface. The decreasing amount of drainage from the deep profile as com­ pared to the 150 cm profile indicated that a portion of the water which drained from the 150 cm profile was stored at.lower depths rather than all of it continuing its downward movement. This is shown by a com­ parison of the differences in ASWC in the 150 cm and deep profiles of each treatment with the amounts of drainage from the 150 cm profile. This comparison indicates that of the water draining out of the 150 cm profile, 10, 75 and 100% was stored at lower profile depths in the topsoiled, revegetated, topsoiled nonvegetated and nontopsoiled revegetated spoils treatments, respectively. The topsoiled revegetated treatment stored the least amount with 90% of the water draining from the 150 cm profile continuing its downward direction of flow. We are considering only one-dimensional unsaturated flow, that being in the vertical direction. Three possible situations can exist with respect to the verticle unsaturated soil water movement. These are: I) water can flow in a net upward direction towards the surface 50 with the rate of flow increasing or decreasing over time, ibrium conditions' can establish or 2) equil­ 3) net downward flow from the surface towards the groundwater table can occur with the rates of flow either decreasing or increasing over time. be Equilibrium conditions can taken as being either static where no net water movement is occur­ ring or the net upward or downward flow has reached an equilibrium val­ ue and is constant. A comparison of the WF and ASVJC values in Tables 5 and 6 for the three spoils treatments indicated that the spoils are presently in a situation where the net downward flow of water is increasing over time, which will reach some nearly constant rate at some later date. For example, the topsoiled revegetated treatment has had the greatest amount of time in which to stabilize and this treatment showed the greatest ■ amount of drainage from the deep profile. Also, this treatment had the least amount of change in drainage with depth and showed the least change in soil water content at the lower profile depths. The fact that the topsoiled revegetated treatment has had the greatest amount of time to stabilize and also showed the greatest amount of drainage from the deep profile indicates the drainage from the spoils are apparently increasing with time. .> In the same manner, the lesser amounts of change, in both the soil water content in the lower profile and the drainage with depth for the topsoiled revegetated treatment as compared to the two other spoils treatments, indicates the drainage, on an annual basis, is approaching an equilibrium value. As stated earlier, a portion of the water draining from the 150 cm profile of the spoils treatments is apparent­ ly being stored in the lower profile depths, rather than the entire flow continuing downward. Once the storage capacities of these lower depths are satisfied, greater drainage may then occur to greater depths. Assuming no large variations in annual precipitation and evapotranspiration, the change in soil water content on an annual basis should approach zero. As this process is taking place, drainage from the profile should increase to a nearly constant rate, The lesser amount of change in soil water content with depth from the topsoiled revegetated treatment indicates that the storage capacity of the lower profile depth is being met over time. The lesser difference between the 150 cm and deep profile drainage values indicated that the drainage from the spoils is moving towards an equilibrium value over time. Thus it is probable that given enough time, the mine spoils will reach a condition of equilibrium where both the change in soil water content in the lower profiles and the drainage rate from the spoils will be nearly constant. Once this equilibrium is attained, we can expect a constant amount of unsaturated flow into the saturated groundwater zone. It should be noted that flow into the groundwater zone will occur before equilibrium with the amount of flow increasing as equil- 52 lbrium is being reached, This flow of water into the groundwater system through the spoils is not to be considered an uncommon situation. Our data show that flow of water towards the groundwater is also occurring in the native range and is taking place at 1.5 times the rate as that of the spoils treatments (Table 4). Soil Physical Measurements Various soil physical measurements were made on soil samples from the four treatment areas. The objective here was to determine the cause of the lower rates of soil water movement in the spoils treatments as compared to the native range as discussed in previous sections. Results of the bulk density, particle density and modulus of rup­ ture analyses of the surface 0-15 cm soil samples from the four treat­ ments are shown in Table 7. Each datum presented in the table is a mean obtained from the three reps of each treatment. No significant differences in bulk density were present between treatments. However, small increases in bulk density can result in substantial decreases in water transmission rates in soils (Waldron, et al., 1970), Therefore, “3 the lower bulk density of 1.48 g cm for the native range treatment as compared to the bulk densities of 1,56, 1.58 and 1.54 g cm —3 for the topsoiled honvegetated, topsoiled* revegetated and nontopsoiled revege­ tated spoils treatments, respectively, could result in lower rates of water movement in the spoils in the surface 0-15 cm; 53 Table 7. Mean values of bulk density, particle density and modulus of rupture analyses of 0-15 cm soil samples, Peabody Big Sky Mine, November, 1974, Bulk density (g cm Treatment Particle density ) Modulus of rupture (bars) (g cm"3) Topsoiled nonvegetated 1.56a 2.42a Topsoiled revegetated I. 58a 2.39a Nontopsoiled revegetated 1 ,54a 2.47a 2.17a Native range 1.48a 2,38a 0.659a 1.360a .. 0.7 34a Each mean is an average of three replications. Means within the same column followed by the same letter indicate no significant difference at the 0.05 level. The differences in particle density between treatments were not significant. The generally accepted value of particle density for soils derived from quartz-like parent material is 2.65 g cm-^ . These parti­ cle densities of the four treatments (Table 7) are all less than this value. Particle density is a measure of the density of the particles alone, whereas bulk density takes into account the volume of the parti­ cles as well as the pore spaces between these particles. The closer the bulk density of a soil is to the particle density of that soil, the less is the pore volume of the soil. Assuming these lower values of particle density are not due to experimental error, less pore volume was present in these samples with these bulk densities than would occur 54 if these same samples had a particle density of 2.65 g cm bulk densities. with these Since water movement is dependent on the total pore volume of a soil, these lower particle densities indicate that slower rates of soil water movement are present in the treatments than would be expected in soils with a particle density of 2.65 g cm"^ and having bulk densities shown in Table 7. However, all four treatments would be affected to the same degree since no significant difference between particle density means were shown. Modulus of rupture is a measure of the degree of soil crusting which is a function of soil swelling and shrinking processes, Soil crusting is affected mainly by the presence of clay, organic matter and sodium. High clay contents enhance shrinking and swelling pro­ cesses in the soil and therefore can result in a greater degree of crusting. Organic matter tends to stabilize soil aggregates and thus decreases soil crusting since stable soil aggregates result in a lesser degree of crusting. Sodium enhances crusting of the soil by increasing the diffuse double layer of clays which results in dispersion of the clay particles. Soil crusting can affect water infiltration and per­ colation processes and ultimately emergence and growth of vegetation. i Although the effects of soil crusting on vegetation is dependent on the type of vegetation, the critical modulus of rupture is approximately I bar. For example, Hanks and Thorp (1957) showed that a modulus of rupture of this magnitude resulted in a decrease in emergence of grain 55 sorghum seedlings of 80%. Modulus of rupture values in Table 7 were not significantly dif­ ferent between treatments. Even though these differences were not significant, the modulus of rupture value of 2.107 bars for the nontopsoiled revegetated treatment was higher than the value of 1,36 bars for the topsoiled nonvegetated treatment and considerably higher than those values of 0.734 and 0.659 bars for the topsoiled revegetat­ ed and native range treatments, respectively. Since the topsoiled revegetated and native range treatments are well vegetated, the lower modulus of rupture for these treatments is probably due to the presence of organic matter in the 0-15 cm horizons which would decrease soil crusting. The topsoiled nonvegetated soil material would contain very little organic matter and therefore would have a greater tendency to develop soil crusts. This is substantiated by the higher modulus of rupture of this treatment as compared to the topsoiled revegetated and native range treatments. The high modulus of rupture for the non- topsoiled revegetated treatment is probably due not only to essentially little organic matter being present but also to a higher clay and/or sodium content in the surface as compared to the other treatments. The greater degree of soil crusting which would be present on the nontopsoiled treatment as indicated by the modulus of rupture could be a partial explanation for the poof stand of vegetation on this treatment. Crusting would tend to both decrease infiltration of water 56 through the surface and increase the difficulty of plants to emerge through the surface and develop roots. Therefore, establishment of vegetation would be impeded by both lack of water and mechanical resistance to seedling emergence and root growth. Bulk density measurements through depth were made for the four treatments using the core method described in the methodology. These measurements were made in order to determine any differences in the bulk densities of the profiles between treatments and to relate these differences to soil water movement characteristics and to effects of mining activity on compaction. A bulk density of 1.3 g cm-^ is the generally accepted value for a non-compacted soil with bulk densities of 1.5 g cm ^ or greater being considered as being high. Results of the bulk density through depth measurements are given in Table 8. Bulk densities for the native range profile from 120 to 600 cm were obtained from bulk density measurements of the single 6 meter native range core taken in June, 1975. All other bulk densities are averages of the three reps from each treatment. As shown in Table 8, there were no significant bulk density differences between treatments. Bowever, the high bulk densities of the native range treatment, starting at 120 cm and continuing to greater depths, were due to the sandstone bedrock material beginning at 120 cm. It was felt that it was not valid to compare the bulk density of consolidated sandstone to the unconsolidated spoils material. Therefore, the bulk 57 * Table 8. Bulk densities through depth in the four treatment areas, Peabody Big Sky Mine, June, 1975. Bulk density (g cm 3) Topsoiled nonvegetated Depth (cm) 0- 30 30- 60 60- 90 90-120 120-150 150-180 180-210 210-240 240-270 270-300 300-330 330-360 360-390 390-420 420-450 450-480 480-510 510-540 540-570 570-600 1.79 .1.87 1.68 1.79 1.73 1.69 1.77 1.76 1.74 1.81 1.81 1.77 1.84 1.85 1.93 1.97 1.99 Topsoiled revegetated 1.69 1.63 1.60 1.65 1.74 1.71 1.82 1.67 1.79 1.78 1.65 ‘ 1.68 1.68 1.76 1.72 1.66 1.59 1.60 1.71 1.87 Nontopsoiled revegetated Native range 1.64 1.58 1.73 1.88 1.72 1.60 1.89 1.74 1.79 1.75 1.75 1.86 1.91 1.73 1.74 1.79 1.66 1.64 1.76 1.40 1.38 1.51 1.57 1.96 1.87 1.90 1.90 1.94 1.94 1.98 2.00 2.05 2.05 1.86 1.98 1.94 1.77 1.76 1.81 Profile mean 1.81a 1.70* 1.75* 1.83* 120 cm Profile mean 1.78* 1.64* 1.71* 1.46b * With the exception of the 120-600 cm depth in the native range profile, each datum is a mean of three replications. Means followed by the same letter indicate no significance at the 0.05 level. 58 density means of the 120 cm profile, which would exclude the sand­ stone layer, for each treatment are also shown in Table 8, It was \ found that the 120 cm native range profile mean bulk density of 1.46 g cm"^ was significantly lower than the mean bulk density of 1,78, 1.64 and 1.71 g cm ^ for the topsoiled nonvegetated, topsoiled revegetated and nontopsoiled revegetated treatments, respectively. No significant differences were present between these bulk density ■ means of the three spoils treatments. It is apparent from these higher bulk densities in spoils near the surface that compaction of the spoils occurred during the replacement and contouring of the overburden. Since compaction results in decreased soil water move­ ment, the lower rate of soil water flow in the mine spoils as com­ pared to the native range site, shown by the water movement model, could be explained in part by the compaction of these spoil areas. Particle size analyses through depth were performed for the four treatments in order to determine any differences in particle size distribution between treatments. Results of these analyses are given in Table 9. Since we were not able to take samples past 120 cm in the native range treatment using our drilling equipment, the native range core taken in June 1975 was used for particle size analyses past the 120 cm depth. In general, the spoils treatments had higher amounts of clay and silt throughout the profile than did the native range treat­ ment. 59 Table 9. Particle size distribution through depth of the four treat­ ment areas, Peabody Big Sky Mine. Samples for the 120-600 cm depths for native range were taken in June, 1975. All other samples were taken in November, 1974. Treatment Depth (cm) Topsoiled nonvegetated 0- 15 15- 60 60- 90 90-120 120-150 150-180 180-240 240-300 300-360 360-480 Topsoiled ■ revegetated 0- 15 15- 60 60- 90 90-120 120-180 180-240 240-300 300-360 360-420 420-480 480-540 Nohtopsoiled revegetated 0- 15 15- 60 60-120 . 120-180 180-240 240-300 300-360 360-420 420-480 480-600 . % sand % silt 38.4 16.6 15.6 15.6 14.6 19.6 29.1 23.6 29.6 16.3 35.8 42,8 40.8 42.8 46.8 46,2 30.5 38.0 41.0 39,7 68,0 33.9 40.5 29.2 24.9 33.3 28.7 35.3 33.0 23.0 ■ 26.0 31.1 29.9 23.5 26.5 . 24.9 28,9 27.0 28.4 28.2 25,7 % clay Textural class 25,8 40.6 43.6 41.6 38,6 34.4 40.4 38.4 38.4 44.0 ' loam silty clay silty clay silty clay silty clay loam silty clay loam clay clay loam clay loam clay 13,3 36,8 33.5 ' 36.8 40.2 37.5 38.8 32.4 49.0 41,0 32.0 18.7 29.3 26.0 34.0 34.9 29.2 32.5 32,3 29.0 36.0 42.0 sandy loam clay loam clay loam clay loam clay loam clay loam clay loam clay loam clay loam clay loam clay 37,3 37.5 36.5 39,8 46.3 41,3 42.3 37.0 38.8 43,4 31.6 35.6 40.0 . 33.7 28,8 29.8 30.7 34,6 33.0 30,9 clay clay clay clay clay clay clay clay clay clay loam loam loam loam loam loam loam loam loam loam 60 Table 9 (cont'd) Treatment Depth (cm) 0- 30 30- 60 60- 90 90-120 120-150 150-180 180-210 210-240 240-270 270-300 300-330 330-360 360-390 390-420 420-450 450-480 480-510 510-540 540-570 570-600 ' % sand % silt % clay 39.7 33.5 27.6 31.6 28.8 38.8 40.8 46.8 44.4 46.4 56.4 54.4 53.6 53.6 59.6 61.6 57.6 69.6 67.6 65,6 33.6 38.2 34.4 38.4 47.6 39.6 43.6 39.6 41,6 39.6 31.6 33.6 33,6 33.6 25.6 25.6 27.6 17.6 19.6 21.6 26.7 29.3 38.0 30.0 23.6 21.6 15.6 13.6 14.0 14.0 12.0 12.0 12.8 12.8 14,8 12.8 14.8 12.8 12.8 12.8 Textural class loam ■ clay loam clay loam clay loam loam loam loam loam loam loam loam sandy loam sandy loam sandy loam sandy loam sandy loam sandy loam sandy loam sandy loam sandy loam With the exception pf the 120-600 cm depth of the native range profile, each datum is a mean of three replications. Since silt and clay can limit soil water movement (Diebold, 1954; Warkentin, 1971), this could partially explain the lower rate of water movement in the spoils indicated by the water movement model. The lower percentages of clay and silt in the topsoil of the two topsoiled spoils treatments compared to the nontopsoiled spoils treat­ ment resulted in higher infiltration rates as will be discussed in detail in a later section. Lower infiltration rates result in less 61 water entering the root zone and greater erosion due to runoff. Thus, the higher silt and clay content of the 0-15 cm depth in the nontopsoiled revegetated treatment could explain, in part, the poor stand of vegetation which was obtained on this site. The particle size distribution of the three spoils treatments shown in Table 9 indicates that the sand, silt and clay particles are present in approximately equal proportions. As pointed out by Warkentin (1971), compaction of a soil is most easily achieved when this situation exists. Due to this particle size distribution, the spoils are more susceptable to compaction during resurfacing opera­ tions which could explain the higher bulk density of the spoils shown in Table 8. Soil desorption curves show the water loss characteristics of soils with decreasing matric potential (^m) where a decrease in a greater negative number. denotes These curves are useful in showing the plant available water present at any given Soil desorption curves were constructed for the 0-15 cm soil samples from the four treatments. No moisture determinations were-, made at -3 atmospheres due to equip­ ment malfunction. These curves are shown in Figure 13, Little varia­ tion in soil desorption characteristics were shown between treatments. All treatments showed a rapid decrease in water content with decreasing matric potentials to -1.0 atm. The rate of water loss at matric poten­ tials from -1.0 to -15 atm was much less for all treatments than at 62 O A • * Topsoiled nonvegetated Topsoiled revegetated Nontopsoiled revegetated Native range C 20 O -3 -G -9 -12 -15 Matric Potential (atm) Figure 13. Soil desorption curves of 0-15 cm soil samples from the four treatment areas, Peabody Big Sky Mine, November, 1974. Each datum point is the average of three replications. 63 matric potentials from -0.1 to -I.atm. Desorption curves of this type indicate a sandy or loamy textured soil. Except at high matric potentials, little water would be available for uptake by plants. Clay Mineralogy Representative soil samples from the 0-15 cm depth of each treatment were taken in August, 1975 for clay mineralogy analysis. Knowledge of the clay minerals present in the treatments was desired in order to determine the possible effects of the clay fraction on water movement in the treatments. The clay mineralogy of these samples was determined using x-ray diffraction techniques. Particle size analyses were performed in conjunction with the clay mineralogy analyses. results of these analyses. Table 10 presents the Particle size distributions for the sur­ face samples from each treatment shown in this table coincide closely with those shown in Table 9 with the exception of the nontopsoiled revegetated treatment. Here, the silt content of 54% was considerably higher for the sample from this treatment taken in August, 1975 as compared to the silt content of 37.3% shown in Table 9 for the November, 1974 sample. This indicates a possible breakdown of the blue shale overburden present on the surface of the nontopsoiled revegetated treatment to silt size particles over time due to weathering. Coarse blue shale fragments were on the surface and in the root biosphere of this treatment. The fragments are very subject to weathering. When placed 64 in water, solid blue shale fragments will break down in a matter of hours. This increase in silt content could have a large effect on water movement since the work of Diebold (1954) showed that high silt con­ tents resulted in lower permeability and infiltration of water in the soil. The weathering of the blue shale into silt size particles could conceivably decrease water movement in the two topsoiled spoil treatments as well, since the overburden underlying the topsoil of these treatments contains considerable amounts of blue shale as was evident from core samples of these spoil treatments. The weathering of the blue shale in the topsoiled nonvegetated and topsoiled reveg­ etated treatments would be less rapid since the shale is not as direct­ ly exposed to fopceq of soil formation such as precipitation, temper­ ature, etc.. However, given enough time, it could be assumed that the silt content of the blue shale overburden in these spoils treatments would increase, possibly resulting in decreased soil water movement. Results of the clay mineralogy analyses in Table 10 indicate the dominant clay minerals in the surface soil of the four treatments are illite and kaolinite with small amounts of chlorite. The topsoiled nonvegetated treatment contained small amounts of smectite and vermiculite which were not present in the other treatments. The native range treatment showed a higher illite content than was present in the spoils treatments. Illite, kaolinite and chlorite are non-expanding lattice clays. % Table 10. Particle size distribution and clay mineralogy of representative surface depth soil samples from the four treatment areas , Peabody Big Sky Mine, August, 1975. k Particle size distributionL Textural Type and predominance of clay mineral % sand % silt % clay class Topsoiled nonvegetated 62 22 16 sandy clay loam low mod mod low trace Topsoiled revegetated 67 19 14 sandy clay loam O mod mod low O Nontopsoiled revegetated 25 54 21 silt loam O mod mod low O 52 34. 14 loam O high mod low .0 Treatment Native range . high = 50-75% moderate = 25-50% low = 5-25% trace = less than 5% Smectite Illite Kaolinite Chlorite Vermiculite Ln 66 Clay minerals of this type exhibit little change in structure upon wetting and therefore do not affect water movement to,any great ex­ tent. Smectite and vermiculite are expanding lattice clays. These types of clay mineral swell upon wetting which can result in decreased water movement. The presence of smectite and vermiculite in the topsoiled nonvegetated treatment indicates that water movement could be restricted to some extent due to expansion of' these clay minerals upon wetting. However, the predominant clay minerals in this treat­ ment are of a non-expanding nature which would tend to overshadow the detrimental effects of the small amounts of smectite and vermiculite. The clay mineralogy of the topsoiled revegetated, nontopsoiled reyegetated and native range treatments is completely dominated by illite, kaolinite and chlorite which indicates that water movement in the surface material of these treatments is not affected by any con­ siderable amounts,of expansion of clays in the soil. Thus, the lower rates of water movement in the spoil treatments compared to the native range site shown by the model cannot be explained by high contents of expanding lattice clays. Infiltration Rates■ Infiltration rates of the four treatments were measured and related to soil water drainage. Infiltration characteristics of the four treat­ ments are shown in Figure 14. Each line was determined by infiltration data obtained for a rep. within a treatment. Mean infiltratiqn rates of Infiltration (c m /h r ) O Topsoiled nonvegetated A Topsoiled revegetated • Nontopsoiled revegetated A Native range 15 20 Time (m inutes) Figure 14. 25 Infiltration rates of the four treatment areas, Peabody Big Sky Mine, August, 1975. Each line represents data for a rep within the treatment. Brackets followed by same letter indicate no significant difference between means at the 0.01 level. 68 of 11.90, 7.81, 4.46, and 1.87■cm/hr for the native range, topsoiled revegetated, topsoiled nonvegetated and nontopsoiled revegetated treatments, respectively, were all significantly different at the 0.01 level. These differences in infiltration rates between treat­ ments can be attributed to two major factors, the first of which is vegetation. Vegetation tends to decrease runoff allowing greater infiltration of rainfall and protects the soil ftorn, the beating action of the raindrops. The effect of vegetation was shown by the higher infiltration rates of the native range and topsoiled revege­ tated treatments compared to the infiltration rates of the topsoiled nonvegetated and nontopsoiled revegetated treatments of which both had essentially no vegetation. The higher rate of infiltration on the native range as compared to the topsoiled revegetated treatment could be due to the greater degree of soil structural development of the native range. The second factor affecting infiltration appears to be the pres­ ence of topsoil. Since both the topsoiled nonvegetated and nontop­ soiled revegetated treatments are essentially void of vegetation, the presence of topsoil is the probable remaining variable which affected infiltration rates. The significantly higher infiltration rate of the topsoiled nonvegetated treatment as compared to the nontopsoiled revegetated treatment indicates that the presence of topsoil can in- ' crease infiltration. 69 At least two factors could be responsible for the lower infil­ tration rates of the nontopsoiled revegetated treatment as compared to the other spoil treatments. First, the surface of the nontop­ soiled revegetated treatment had considerably higher silt and clay contents than the topsoil of the other two spoils treatments (Table 9). These higher.amounts of silt and clay would tend to decrease the infiltration rate of water. Second, the greater degree of soil crusting on the nontopsoiled treatment, as indicated by the modulus of rupture shown in Table 7, would tend to further decrease infiltra­ tion. These differences between the nontopsoiled and the topsoiled spoil treatments indicate the value of topsoiling as a management ■ tool. Soil water drainage from a profile would, in part, be dependent on the amount of infiltration into a profile. Thus, it appears these differences in infiltration rates could result in significantly dif­ ferent amounts of drainage between treatments. Saturated Hydraulic Conductivity The rate of water movement in a soil is dependent" On the hydraulic conductivity of that soil. Hydraulic conductivity is the effective flow velocity of water in soil, generally expressed as centimeters per unit of time. Slow rates of saturated hydraulic conductivity are gener ally considered as being in the range of 3.0 to 12.0 cm/day whereas 70 rapid rates are considered as being in the range of 300^600 cm/day (O'Neal, 1952). Saturated hydraulic conductivities through depth were determined to see if any differences between treatments existed. The saturated hydraulic conductivity through depth for the four treatments is shown in Figure 15. The mean saturated hydraulic con­ ductivity of 4.87 cm/day for the native range treatment was signifi­ cantly greater compared to the mean hydraulic conductivities of the spoil treatments. No significant differences were present between the spoils saturated hydraulic conductivities of 1.52, 1.31 and 1.30 cm/day for the topsoiled nonvegetated, topsoiled revegetated and nontopsoiled revegetated treatments, respectively. Saturated hydraulic conductivity was determined using disturbed samples which would result in the destruction of any structure present.. Since the presence of structure would probably result in greater rates of water movement, the hydraulic conductivity of the upper profile of the native range would be greater than that shown in Figure 15. The saturated hydraulic conductivity for the spoil treatments shown in Figure 15 compared to actual hydraulic conductivities under field con­ ditions, would probably not vary greatly since the spoils are in essence disturbed soils. The difference in the saturated hydraulic conductivity of the native rapge as compared to that of the spoils treatments was evident in the flooding portion of the water movement model procedure. Appli- 71 Hydraulic Conductivity Profile Mean Topsoiled nonvegetated Topsoiled revegetated Nontopsoiled revegetated Nativerange 480 1. 5 2 b 1.31 h /.3 0 b 4 .8 7 a 600 ) 2 4 6 8 IO Hydraulic Conductivity, K (cm /d ay) Figure 15. Saturated hydraulic conductivity through depth for disturbed samples from the four treatment areas, Peabody Big Sky Mine, September, 1975. Means followed by the same letter indicate no significant difference at the 0.05 level. 72 cation of approximately four to five times as. much water per unit time was necessary on the native range plots compared to the spoils treatments in order to maintain a constant ponding level. The consolidated layer of sandstone beginning at the 120 cm depth of the native range would possibly exhibit lower hydraulic conductivities than those shown for the 0-120 cm depths. However, cracks and fissures in the sandstone layer were apparently present and transmitted water readily. That these cracks and fissures were present was substantiated by the greater amount of water necessary during flooding. Also, neutron probe readings on the native range treatment through the entire course of the study did not indicate the presence of a perched water table at any time above the sand­ stone layer. If the sandstone layer was impermeable to water, a perched water table above this layer would have been evident. These differences in hydraulic conductivity between treatments correlate closely with differences in rate of water movement shown by the flow model. Both the saturated hydraulic conductivity and the model showed greater rates of water movement in the native range as compared to the spoils with little differences in movement rates between the spoils treatments. Solute Movement Chemical analyses of core samples from each treatment were per­ 73 formed on a twice yearly basis so that comparisons of the solute con­ centrations between treatments could be made and any trends in solute movement over time could be detected. However, at the writing of this thesis, the sampling, period covered only a one year interval. This time span was too short to detect any definite trends in solute movement. Therefore, the discussion in this section will be limit­ ed mainly to a comparison of solute concentrations between treatments in relation to plant, nutrition and any possible physiochemical effects on the soil. Chemical analyses of NO^-N and NH^-N were done since these, sol­ utes are the main sources of available nitrogen for plant uptake. Also, high concentrations of nitrates in water can be toxic to both livestock and humans. Drinking water having a nitrate concentration 3 of 10 ppm or greater is considered toxic to humans , with livestock having a somewhat higher tolerance. 3 If high concentrations of NO -N were present in the treatments, any drainage could result in the leaching of nitrate into the groundwater system, ultimately increasing the nitrate concentration of the groundwater. Results of N O y N analyses are given in Figure 16. The topsoiled nonvegetated treatment showed a decrease in profile mean concentrations over time indicating possible movement of nitrates out of the profile. ^U. S.'Public Health Service standards SOIL O 2 4 6 8 IO 12 O 2 NO3-N (ppm ) 4 6 8 IO 12 O 2 4 6 8 IO 12 200 S p rin g , 1975 N O -N P ro file Means 300 F a ll, /974 400 NOi N F a ll, 1975 N O -N P ro file Means 2 .5 3 ° a 3 86 2.4/ • » 6 IO 3 94 7.20 0 48 I .6 0 a I.11 P ro file Means ° Topsoiled no nvegetated 4.30-6 Topsoiled re v e g e ta te d 2.24 • N ontopsoiled re v e g e ta te d 4.57 , 500 * N ative range 0 .7 1 1 □ N ative ra nge (6 m core.) 600 Figure 16. Soil profile distribution of NO,-N from November, 1974 to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. CS 75 If vegetation were present on this treatment, the resulting plant uptake of NOg-N could result in a lesser amount of movement. No trends in NOg-N movement in the remaining treatments were evident. However, increasing concentrations of NOg-N over time were evident in the lower profile of the topsoiled revegetated and nontopsoiled revegetated treatments. These increases could be due to downward movement and accumulation at lower profile depth. highly, mobile in a soil system. Nitrates are The soil water which has been shown to be draining from the spoils and native range probably resulted in any translocation of nitrates shown in Figure 16. At profile depths below 50 cm, the spoils treatments showed substantially higher NOg-N concentrations than were present in the native range treatment. The Ft. Union blue shale present in the spoils generally has high amounts of fixed NH^-N (Power, et al, 1975). Upon exposure to weathering during mining activity, the NH^-N can be released and converted to NOg-N through microbial acti vity. These higher NOg-N levels in the spoils could be partially contributed to this mechanism. In addition, the higher levels of NO^-N in the topsoiled revegetated and nontopsoiled revegetated spoil treatments could be attributed to the addition of nitrogen fertilizer to these treatments at the time the seeding operations took place. 76 From the standpoint of plant nutrition, greater amounts of NOg-N would be available in the spoils for plant uptake. However, downward movement of this solute could result in a substantial in­ crease in the NOg-N level of the groundwater system in this area. Results of NH^-N analyses are given in Figure 17. The spoil treatments showed a decrease over time in the profile mean NH^-N concentration. It is felt that this decrease in NH^-N was due to conversion into NO^-N rather than loss due to movement to a deeper depth. In general, the NH^-N concentrations of the native range profile were not substantially different from those of the spoils treatments. Therefore, vegetation should do equally well from the standpoint of available NH^-H on all the treatments. Analyses of PO^-P were performed since this is the form of phosphorus most readily utilized by plants. ses are given in Figure 18. Results of these analy­ No trends in solute movement were < indicated with the mean concentrations of PO^-P in each profile showing little change over time. -PO^-P in soils is a non-mobile anion due to the interaction of phosphates and clay minerals. Thus, large differences in profile distribution of PO^-P over time would not be expected. In general, the levels of PO^-P in the surface 100 cm profile depth of the native range were higher than that of the spoils treat- SOIL NH-N (ppm) 0 Figure 17. 4 8 12 O 4 8 12 Soil profile distribution of NH^-N from June to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. SOIL 1 2 P O -P (ppm) 3 4 5 Oo Figure 18. Soil profile distribution of PO4-P from November, 1974-October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is the mean of three replications. 79 merits. This indicates that vegetation present on the spoils would have less PO^-P available for uptake than on native range until the roots were established past 100 cm. Ammonium acetate (NH^OAc) extractable calcium, magnesium, sodium and potassium were analyzed since these cations are major plant nuttients. Also, the relative concentration of these three elements to each other can be used to determine possible detrimental effects of sodium on soil physical properties. The quantity of a cation which can be extracted by NH^OAc is also an indication of the quantity of that cation which is held on the exchange complex of the clay frac­ tion. Cations which are held on the exchange complex are available for plant uptake. Values of NH^OAc extractable calcium are presented in Figure 19. No trends in the movement of calcium in the four treatments were evident. In general, profile concentrations of NH^OAc extract- able calcium in the spoil treatments were somewhat higher than those of the native range. The availability of calcium for plant uptake should be approximately the same in all treatments. The calcic hor­ izon which is commonly present at the 50 to 100 cm profile depths in the native range is evident in the spring and fall, 1975 analyses. Figure 20 shows the distribution of the NH^OAc extractable mag­ nesium in the four treatments. nesium was present. No evidence of movement of the mag­ Also, little difference in profile mean concen- s o i l e x t r a c t a b l e nh oac O 20 40 60 80 0 20 40 Ca (m e q /io o g ) 60 80 0 20 40 60 80 200 X 300 F a ll, 1974 Ca P ro file Means o Tbpsoiled no nve g e ta te d 30.3 a Topsoiled re v e g e ta te d 35. 1 • N ontopsoile d re v e g e ta te d 34.6. - 400 5 00 * N a tive range S p rin g , 1975 Ca P ro file Means F a ll, 1975 Ca P rofile Means 35.0 36 8 30.9 28.0 30.3 40.8 37.4 23 9 2 6 .2 a N ative range ( 6 m. core) 600 Figure 19. Soil profile distribution of NH^OAcextractable calcium from November, 1974 to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. Mg (m e q /io o g ) s o il e x t r a c t a b l e nh oac O 4 8 12 16 O 4 8 4 12 16 O 4 8 12 16 200 F a ll, 1975 6 . 12 P rofile Means 6 .7 5 • 4 91 6.68 6.60 7 .2 0 6/3 ° 7.30 P ro file Means F a ll, /974 400 P ro file Means Topsoiled nonvegefated 6 . 7 5 - a Topsoiled re v e g e ta te d 6 48 • N ontopsoiled re v e g e ta te d 4.97 500 a N ative ra nge 2 .8 9 a N ative range (6 m. co re ) 600 Figure 20. Soil profile distribution of NH4OAc extractable magnesium from November, 1974 to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. 82 trations of extractable magnesium was shown. This lack of difference indicates that the availability of magnesium for plant uptake is the same for both the spoils nad native range treatments. The NH^OAc extractable potassium analyses results are presented in Figure 21. For all sampling dates, levels of extractable potassium at 0-60 cm depths were higher in the native range than the spoils treat­ ments. Thus, less potassium'is available for uptake by plants in the spoil treatments which could result in a potassium deficiency for vegtation present on the spoils. A possible explanation for the higher potassium levels in the native range site is the high illite content in the native range as shown by the clay mineralogy analysis (see earlier section). Illite contains high levels of fixed potassium which can be extracted by plants over long periods of time. Upon the death and decay of the plant, the potassium is returned to the soil where it is either taken up by plants again or held on the exchange complex. Over long periods of time, the continued extraction of potassium from illite results in a substantial increase in potassium levels in the root zone. Since the native range site has been under constant vegeta­ tion for a long period of time, this mechanism would explain the higher concentrations of potassium present. Results of the NH^OAc extractable sodium analyses are given in Figure 22. In general, the profile means increased with time. This increase could be due to the infiltration and percolation of runoff SOIL EXTRACTABLE,NH OAc K (m eq/IO O g) 0.8 O 0.8 O 200 F a ll, 1975 I P ro file Means 300 ° a 0.28 0 .3 0 P ro file Means 0 16 0 .2 8 0.22 0 .3 7 0 .3 2 F a ll, /974 400 P ro file Means ° Topsoiled nonvegetated 0 . 1 2 -A Topsoiled re v e g e ta te d 0 .2 2 • N onfopsoiled re v e g e ta te d O. 17 500 a N ative range 0 .4 4 □ N ative range ( 6 m. core) 600 Figure 21. Soil profile distribution of NH4OAc extractable potassium from November, 1974 to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. SOIL EXTRACTABLE NH4 OAc N a(m eq/IO O g) CD Figure 22. Soil profile distribution of NH4OAc extractable sodium from November, 1974 to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. 85 water having a high sodium content. However, if this were clearly the case, the upper profile depths would show an initial increase in sodium, with the sodium levels of lower profile depths increasing over time as downward flow of soil water occurred. Since the entire profile, in general, showed an increase in extractable sodium, the increase is probably due to chemical variability between sample sites rather than to any infiltration and downward movement of high sodium runoff water. The exchangeable sodium percentage (ESP) is defined by Equation 10 . ' ESP= __________ exchangeable Na__________ _ x ]qq cation exchange capacity (CEC) where Na and CEC are in meq/100 g (10) ESP is used as an indicator of soil physical problems due to clay dispersion by the exchangeable sodium. An ESP of 15 or greater is used as the criterion for classification of a sodic soil. Serious soil physical problems can occur on a sodic soil. CEC is the sum of all exchangeable cations present in a system. Since calcium, magnesium, sodium and potassium represent the majority of the cations generally present on the exchange complex of clays and NH^OAc extractable cations approximate the exchangeable cations, CE C , can be approximated by the sum of the NH^OAc extractable cations which were determined. ■ , 86 Using cation exchange capacities approximated by this method and the. NH^OAc extractable sodium analyses in Figure 22, no ESP greater than 3.5 was obtained. Thus, the levels of ESP found in the four treat-: ment profiles are well below the critical ESP value of 15. No soil physical problems due to exchangeable sodium would be present in the spoils or the native range. Analyses of water soluble calcium, magnesium and sodium were nec­ essary in order to calculate the sodium adsorption ration (SAR), defined by Equation 11. SAR = (Na) / (((Ca) + (Mg))/2)% (11) where all concentrations are in meq/L In general, SAR values greater than 10 indicate that soil physical problems, such as clay dispersion, puddling, soil crusting and decreased percolation rates of water, will occur due to the sodium present. The profile distributions of water soluble calcium for the two sampling dates are given in Figure 23. The concentrations of water soluble calcium in the spoil treatments were substantially higher than ' ih the native range site. These higher calcium concentrations could result in lower values of SAR in the spoils by increasing the value of the denominator in Equation 11. Thus, the detrimental affects of sodium could be less in the spoils as compared to native range. SOIL SOLUBLE IO 20 30 O HO 2 Ca (rneqA) IO 20 30 IOO 200 Fall, 1975 Ca Profile Means o Topsoiled nonvegetaied 26.51 Topsoiled revegetated Nontopsoiled revegetated Native range -- a Native range (6 m. c o re ) S X 300 h~ CL UJ Q 400 500 6 0 0 Figure 23. Soil profile distribution of water soluble calcium from June to O c t o b e r , 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. 88 Results of the water soluble magnesium analyses are shown in Figure 24. Little differences in magnesium concentrations in the spoil treatments over time were shown. The native range showed higher initial concentrations of magnesium and lower concentrations in the fall than did the spoils treatments. The water soluble magnesium in the native range treatment showed a marked decrease over time. This decrease could possibly be due to translocation of magnesium during the flooding portion of the water model testing period. Figure 25 shows the results of the water soluble sodium analyses. No definite trends in sodium movement could be determined in the spoil treatments. As with the water soluble magnesium, the water soluble sodium in the native range also decreased considerably with time. This was possibly due to the large water volumes used in the flooding pro­ cedure on the native range treatment resulting in downward displacement of the sodium. Results of the SAR calculations are given in Figure 26. ues, over time showed little change in the spoil treatments. SAR val­ The de­ crease in SAR over time for thenative range resulted from the decreases in water soluble sodium and, to a lesser degree, magnesium which were discussed previously. All SAR values shown in Figure 26 were well below the critical value of 10. Thus, the levels of water sol­ uble sodium present in the treatments should not result in any detri­ mental affects to soil physical properties. These SAR and ESP values indicate that the lower rates of water movement in spoils, as compared SOIL SOLUBLE H O Mg (rneq/O 20 30 40 50 O IO 20 30 40 50 IOO - 200 - I \— CL 300 LU Q 400 - Spring, 1975 Mg Profile Means Fall, 1975 Mg Profile Means ~ ° Topsoiled nonvegetated 22.1A Topsoiled revegetated 25.8 • Nontopsoiled revegetated 24.4 + Nativerange 12.9 Native range (6 m.core) 500 - 6 0 0 Figure 24. Soil profile distribution of water soluble magnesium from June to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. SOIL SOLUBLE Na (meq/O H2° O 4 Figure 25. 8 12 O 4 8 12 Soil profile distribution of water soluble sodium from June to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range p r o f i l e , each datum is a mean of three replications. SODIUM ADSORPTION RATIO 2 3 4 0 1 2 3 4 T Fall, 1975 SAR Profile Means Topsoiled nonvegetated 0 .4 8 Topsoiled revegetated Nontopsoiled revegetated Native range Spring, 1975 SAR Profile Means 0 .9 5 1.18 0.81 Native range (6 m. core) 600 Figure 26. Soil profile SAR levels from June to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. 92 to the native range, shown by the water movement model, are not due to dispersion of the clay by high concentrations of sodium. Information on the salt content of the treatment profiles was desired since high contents of salt in the soil can affect plant growth. High salt concentrations in a soil result in an increased osmotic or solute potential of the soil. This increase in osmotic potential results in a decrease in the water movement gradient towards the plant causing water stress condition in the plant. Information on the salt content of the treatments was obtained from electrical conductivity measurements on saturated paste extracts. Since the electrical conductivity of a soil increases with increasing salt con­ tent, electrical conductivity is a measure of the salt level of a soil. The results of the electrical conductivity measurements are pre­ sented in Figure 27. Electrical conductivity varied little between treatments of over time. This indicates that salt levels of the four treatments were not substantially different, and that little overall I solute movement occurred over time. Soils having electrical conductivities greater than 4 mmhos/cm are classified as saline soils. Saline soils are generally non­ productive due to the detrimental effects of the high salt level to plant growth caused by the higher osmotic potential of the soil. The electrical conductivities shown in Figure 27 indicate that, in general, the 0-60 cm profile depths of the four treatments would be SOIL ELECTRICAL CONDUCTIVITY (mmhos/cm) p 300 S p rin g , 1975 EC - - P ro file Means * 400 500 600 52 F a ll, 1975 EC P ro file Means * 46 F a ll, 1974 EC P ro file Means Topsoiled n o n vege laled 5 . 4 0 _ * Topsoiled re v e g e ta te d • N ontopsoiled re v e g e ta te d 4 .5 0 3 .1 0 - * N a tiv e ra nge 0 . 6 5 o N a tive range ( 6 m c o re ) Figure 27. Soil profile distribution of salt from November, 1974 to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replications. VO W 94 classified as non-saline. Thus, vegetation with a 60 cm rooting depth would not be adversely affected by the salt levels present. The higher electrical conductivities found in the lower profile depths indicate that substantial amounts of salts were present. This arrangement indicates that salts could have been leached from the profile resulting in salt moving towards the groundwater. The pH of a soil affects plant growth by its indirect effect on governing the availability of plant nutrients and, when excessively high or low, by injuring the plant directly or by upsetting the meta­ bolism oi the roots. The pH of soils in the semi-arid West generally ranges from 7 to 8. Table 28 presents the results of the pH measurements. The top- soiled revegetated treatment was acidic (<pH 7) throughout most of its profile. Profiles of the other three treatments were generally above pH 7. However, none of the pH levels were excessively high or low. The pH of the surface 100 cm of each treatment was generally in the range of 7 to 8. No detrimental effects on plant growth due to pH should be expected. As stated earlier, the time span of the study was too short to detect any definite trends in movement of the various solutes. However, these data presented in this section will provide -good baseline information. Comparison of these data with solute data obtained at later dates at these same sites should provide informa- SOIL pH 6.0 6.5 7.0 75 8.0 8.5 9.0 6.0 6.5 70 75 8.0 8.5 9.0 6.0 6.5 70 8.5 9.0 VO Vl Figure 28. Soil profile pH levels from November, 1974 to October, 1975, Peabody Big Sky Mine. Except for the 6 m native range profile, each datum is a mean of three replicates. 96 tion on solute movement in strip mine spoils and native range. The fact that drainage from the spoils and native range is occurring (see earlier sections), downward movement of solutes towards the groundwater will likely occur over time. The solute concentrations presented in this section indicated that, in general, the concentrations of the solutes in the spoil treatments were not substantially differenet from those of the native range. This small difference in solute concentrations would result in approximately the same quantities of solutes available for translocation. The higher rates of water movement in the native range shown by the water move­ ment model as compared to the spoil treatments indicate that possibly greater amounts of solute movement into the groundwater would occur from the native range than from the spoils. fr SUMMARY AND CONCLUSIONS A study was initiated in November, 1974 at the Peabody Big Sky Mine near Colstrip, Montana to determine soil water and solute movement in strip mine spoils. Three spoils treatments, consisting of topsoiled nonvegetated, topsoiled revegetated and nontopsoiled revegetated spoils, and a native range site were studied. Each treatment consisted of three replications. An unsaturated soil water movement model was shown to be applic­ able to mine spoils and native range in the study area. Use of the model indicated that the quantity of unsaturated flow in the native range was approximately 1.5 times greater than in the spoils. Calculation of the lnt situ soil water budgets, with neutron scattering soil moisture equipment, indicated that drainage from the spoils and native range was occurring with drainage from the native range approximately 1.6 times greater than the average drainage from the spoils. Both the water movement model and the jLn situ soil water budgets showed the same trends in soil water flow between the spoils and native range, with the water budget indicating greater amounts of drainage for all treatments than did the water movement model. The in situ soil water budgets indicated that water flow in the spoils is evidently moving towards a state of equilibrium where the quantities of the downward flow of water will be nearly constant at some time in the future. Soil physical analyses indicated that the lower quantities of soil 98 water movement, shown by both the water movement model and the in situ measurements, in the spoils compared to native range were due to compaction and higher contents of clay and silt. Compaction in the spoils was indicated by the spoil bulk densities of 1.6 to 1.9 __g g cm which were approximately 54% higher than those of the native range. Clay mineralogy analyses of 0-15 cm surface samples indicated that the dominant clay minerals in both the spoils and native range were non-expanding lattice clays. Thus, the lower amounts of soil water movement in the spoils were probably not due to the presence of clay minerals which would expand to a great extent and limit soil water movement. Infiltration rates were shown to be significantly different be­ tween all treatments. Native range had the highest rate of infiltra­ tion followed in order by the topsoiled revegetated, topsoiled nonvegetated and nontopsoiled revegetated spoil treatments. Native range had 60-86% greater infiltration rates compared to the spoils. These differences in infiltration rates were attributed to the effects of soil structure, vegetation and topsoiling techniques. Saturated hydraulic conductivity of disturbed native range samples was 3.5 times greater than that of the spoil treatments. This higher hydraulic conductivity of the native range was attributed to textural differences between the native range and spoils. It was 99 conjectured that the saturated hydraulic conductivity of the native range under field conditions would be even greater due to the pres­ ence of soil structure and lower bulk density. The time span of this study was too short to show any definite trends in solute movement in spoils or native range. Comparison of chemical analyses data in this thesis with analyses at these same sites in future years should indicate the existence of solute movement, if any. With the exception of potassium and NO^-N, the solute concentra­ tions of the spoils, in general, were not substantially different from native range. The spoils contained lower amounts of extractable potas­ sium than native range which could result in potassium deficient vege­ tation on the spoils. NO^-N concentrations were considerably higher in spoils than in native range. The difference was probably due to the release of fixed NH^-N from the blue shale in the spoils and sub­ sequent conversion to NO^-N and to the application of fertilizer to the revegetated spoils treatments. Calculation of exchangeable sodium percentage (ESP) and sodium adsorption ratio (SAR) indicated the levels of sodium in both spoils and native range were not sufficiently high to result in adverse soil physical conditions. The higher quantities of water movement in the native range, shown by the water movement model and the in situ water budgets, compared to the spoil treatments indicate that possibly greater amounts of solute 100 movement into the groundwater would occur from the native range than from the spoils. LITERATURE CITED LITERATURE CITED 1. Blake, G. R. 1965. Methods of Soil Analysis. Part I. Physical and Minerological Properties. C. A. Black, ed. ASA Monograph No. 9. American Society of Agronomy, Inc, Madison, Wise. pp. 381-333. 2. Bremner, J . M. 1965a. Methods of Soil Analysis. Part 2. Chemical and Microbiological Properties. C. A. Black, ed. ASA Monograph No. 9. American Society of Agronomy, Inc. Madison, Wise, pp. 1216-1217. 3. Bremner, J . M. 1965b. Methods of Soil Analysis. Part 2. Chemical and Microbiological Properties. C. A. Black, ed. ASA Monograph No. 9. American Society of Agronomy, Inc. Madison, Wise. pp. 1191-1198. 4. Copeland, 0. L. and R. E . Packer. 1972. Land use aspects of the energy crisis and western mining. J. Forestry 70: 671-675. 5. Curtis, W. R. 1973. Moisture and density relations on graded strip mine spoils In Ecology and Reclamation of Devastated Land. Volume I. pp. 135-143. 6. Day, P . R. 1965. Methods of Soil Analysis. Part I. Physical and Minerological Properties. C . A. Black, ed. ASA Monograph No. 9. American Society of Agronomy, Inc. Madison, Wise. pp. 562-564. 7. Diebold, C. H. 1954. Permeability and intake rates of medium textured soils in relation to silt content and-degree of compaction Soil Sci. Soc. Am. Proc. 18:339-343. 8. Gumbs, F. A. and B. P. Warkenten. 1972. The effect of bulk density and initial water content on infiltration in clay soil samples. Soil Sci. Soc. Am. Proc. 36: 720-724. 9. Hanks, R. J. and F. C. Thorp. 1957. Seedling emergence of wheat, grain sorghum and soybeans as influenced by soil crust strength and moisture content. Soil Sci. Soc. Amer. Proc. 21: 357-359. 10. Hill, J. N . S . and M. E. Sumner. 1967. Effect of bulk density on moisture characteristics of soils. Soil Sci. 103: 234-238. 11. Jackson, R. D. 1963. Porosity and soil water diffusivity relations. Soil Sci. Soc. Am. Proc. 27: 123-126. 103 LITERATURE CITED (CONTrD) 12. Klute, A. 1965. ' Methods of Soil Analysis, Part I. Physical and Minerological Properties. C. A. Black, ed, ASA Monograph No. '9i American Society of Agronomy, Inc. Madison, Wise. pp. 214-215. 13. Limstrom,' G. A. Central States. 14. Meeuwig, R. 0. 1971. Infiltration and water repellency in granitic soils. USDA Forest Service Research Paper INT - 111. 15. National Academy of Sciences. 1974. Rehabilitation Potential of Western Coal Lands. Ballinger Pub. Co. Cambridge, Mass. 198 pp. 16. Olsen, S . R., C. V. Cole, F. S . Watanake and L. A. Dean. 1954. Estimation of available phosphorous in soils by extraction-with sodium bicarbonate. U. S . Dept. Agr. Circ., 939. 1960. Forestation of strip mined lands in the U. S . Dept. Agr. Handbook 166. I 17. O'Neal, A. M. 1952. A key for evaluating soil permeability by means of certain field clues. Soil Sci. Soc. Am. Proc. 16: 312-315. 18. Pratt, P . F. 1965. Methods of Soil Analysis, Part 7. Chemical and Microbiological Properties. C. A. Black, ed. ASA Monograph No. 9. American Society of Agronomy, Inc. Madison, Wise. pp. 1206„ 1033-1034. 19. Power, J. F. ,. J. J. Bond, W. 0. Willis and F. -M. Sandoval'. 1975 Forms and transformations of nitrogen in Fort Union shales. Agronomy Abstracts. Am. Soc. Agronomy 1975 Annual Meetings. p. 32. 20. Sindelar, B. W., R. L . Hodder and M. E . Majerus. 1973. Surface manipulation study In Surface Mined Land Reclamation Research in Montana. Mont. Agr. Exp. Sta. Report 40. 21. Sisson, J. 3. 1972. Hydraulic Properties of the Gerber Soil. M.S. Thesis. Montana State University, Bozeman, Montana. 22. United States Salinity Laboratory staff. 1969. Diagnosis and Improvement of Saline and Alkali Soils. L. A. Richards, ed. U. Si Dept. Agr. Handbook 60. 104 LITERATURE CITED (CONT'D) 23. Verma, T . R. and J. L. Thames. 1975. Rehabilitation of land disturbed by surface mining coal in Arizona. J. Soil Water Conser. 30: 129-13,1. 24. Waldron, L. J., J. L. McMurdie and J. A. Vomocil. 1970. Hydraulic conductivity of an isotropically compressed soil. Soil Sci. Soc. Am. Proc. 34: 393-396. 25. Warkentin, B. P. 1971. Effects of Compaction on Content and Transmission of Water in Soils In Compaction of Agricultural Soils. K. K. Barnes, ed. Amer. Soc. Agr. Engin. Michigan. 26. Yang, S . J. and E . Belong. 1971. Effect of soil water potential and bulk density on water uptake patterns and resistance to flow of water in wheat plants. Can. I. Soil Sc!.. 51: 211-220. APPENDICES 106 Appendix Table I. ■ Soil Conservation Serice classification and profile description of the Yamac soil series. The Yamac series consists of deep, well drained soils formed in alluvium from sedimentary uplands. These soils are nearly level to strongly sloping and are on fans, footslopes and terraces. The mean annual precipitation is about 12 inches, and the mean annual air temperature is about 42°F. Soil Family: Fine-loamy, mixed Borollic Camborthids. Typical Pedon: Yamac loam, grassland. unless otherwise noted.) (Colors are for dry soil Al— 0 to 4 inches, grayish brown (10YR 5/2) loam, very dark gray­ ish brown (10YR 3/2) moist; moderate fine and medium granular structure; soft, very friable, slightly sticky and slightly plas­ tic; many very fine roots; many fine pores; mildly alkaline (pH 7.4); clear boundary. (2 to 4 inches thick) B2— 4 to 11 inches, light olive brown (2.5Y 5/4) loam, olive brown (2.5Y 5/4) loam, olive brown (2.5Y 4/4) moist; moderate medium prismatic parting to weak fine and medium blocky structure; slight­ ly hard, very friable, slightly sticky and slightly plastic; many fine and very fine roots; common fine and very fine pores; mildly alkaline (pH 7.4); clear boundary. (6 to 12 inches thick) Clca— 11 to 26 inches, pale olive (5Y 6/3) loam, olive (5Y 5/3) moist; weak coarse prismatic structure; slightly hard, very fri­ able, slightly sticky and slightly plastic; common fine and very fine pores; common fine and very fine roots, violently efferves­ cent with common fine soft masses of lime, moderately alkaline (pH 8.0); gradual boundary. (20 to 30 inches thick) C2— 26 to 60 inches, pale olive (5Y 6/3) loam, olive (5Y 5/3) moist; massive; slightly hard, very friable, slightly sticky and slightly plastic; few very fine roots; violently efferves­ cent; strongly alkaline (pH 8.5). Range in Characteristics: The solum is 11 to 20 inches thick. The 10- to 40-inch control section is loam and has 18 to 27 percent clay, 40 to 55 percent silt plus very fine sand and 15 to 35 percent fine and coarser sand. In most pedons the upper 8 to 12 inches are noncalcareous, but some pedons are calcareous 107 Appendix Table I (con't) throughout. 46°F. The mean annual soil temperature ranges from 40° to The surface layer after mixing to depth of 7 inches has hue of 7.5Y through 2.5Y, value of 5 or 6 dry, and chroma of 2 or 3, An Al horizon as thick as 4 inches and with value of 5 dry and 3 moist is present in some pedons. Loam and clay loam are the most common texture phases. The B2 horizon has hue of 7.5YR through 5Y, value of 5 of 6 dry, and chroma of 2 through 4. It has moderate to strong prismatic structure with or without blocky structure. The upper 2 to 4 inches is usually noncalcareous but the lower part has weak to moderate effervescence in some pedons. Some pedons have B3ca horizons that have weak and moderate prismatic structure, have moderate to strong effervescence with few to common masses of segregated lime, and have hue of 7.5YR through 2.5Y, value of 5 or 6-dry, 4 or 5 moist, and chroma of 2 or 3. The Cca horizon has few to common masses of segregated lime and has hue of 5Y or IOYR and value of 6 or 7 dry. In some pedons, the C horizon below 25 inches has thin strata of sandy loam, silt loam, or gravelly loam. Below 40 inches in some pedons there are strata of loamy sand, sand, gravelly loam, or gravel­ ly clay loam. Geographic Setting: The Yamac soils are nearly level to strongly sloping and are on fans, footslopes and terraces.. The soils formed in loam textured alluvium derived locally from adjacent sedimentary uplands. The climate is cool, dry-semiarid, contin­ ental, with long, cold, dry winters and moist springs and sum­ mers. The mean annual precipitation is 10 to 14 inches, most of which falls in spring and early summer. Mean annual temper­ ature is 39° to 45°F., mean January temperature 10° to 25 F. and mean July temperature 60° to 72°F. The (32°F.) growing season is 105 to 135 days. Drainage and Permeability: Well drained; slow or medium runoff; moderate permeability. Use and Vegetation; These soils are used for both irrigated and nonirrigated cropland with major crops of small grain, and for rangeland. The principal vegetation is western wheatgrass, blue- Appendix Table I (con't) bunch wheatgrass, prairie junegrass, needle-and-thread grass, green, needlegrass, bluegrama and 'clubmoss. • Distribution and Extent: Yamac series is distributed throughout the eastern plains of Montana and possibly in adjacent states. It is of moderate extent. Series Established: Cascade County, Montana, 1975. Remarks: Yamac.soils were formerly classified as Brown soils. National Cooperative Soil Survey U.S.A., 109 A p p e n d i x Table 2, Results of linear r e g r e s s i o n s and c a l c u l a t e d v a lues of w a t e r m o v e m e n t m o d e l p a r a m e t e r s a an d b for r e p . I, top s o i l e d n o n v e g e t a t e d t r e a t m e n t , Peabody Big Sky Mine, summ e r of 1975. Regression Parameters Depth (cm) r * 2 Model Parameters slope intercept a b 15 0.883 ,-0.0165 1.594 0.3140 0.0165 30 0.945 -0.0154 2.108 0.2604 0.0154 45. 0.939 -0.0131 2.432 0.2406 0.0131 60 0.912 -0.0113 2.667 0.2291 0.0113 75 0.896 -0.0104 2.854 0.2213 0.0104 90 0.892 -0.0101 3.079 0.2308 0.0101 ■ 120 0.905 -0.0010 3.314 0.2184 ■0.0100 150 0.900 -0.0093 3.492 0.2089 0.0093 180 0.911 -0.0092 3.648 0.2038 0.0092 210 . 0.901 -0.0088 3.780 0.1991 0.0088 240* 0.870 -0.0081 3.900 0.1969 0.0081 270 0.710 -0.0098 4.001 0.1914 0.0098 300 , 0.482 -0.0112 4.088 0.1883 0.0112 330 0.351 -0.0124 4.170 0.1825 0.0124 360 ' 0.289 -0.0136 4.246 0.2790 0.0136 ■ 3.90 0.245 -0.0148 4.320 0.1765 0.0148 420 0.221 -0.0159 4.388 . 0.1741 0.0159 450 0.194 -0.0164 4.450 0.1721 0.0164 480 0.182 -0.0172 4.508 0.1700 0.0172 d e p t h to w h i c h u n i f o r m ij; was obtained HO A p p e n d i x Table 3. Results o f linear r e g r e s s i o n s and c a l c u l a t e d v a lues of w a t e r m o v e m e n t m o d e l p a r a m e t e r s 0. dn d b for rep 2, top s o i l e d n o n v e g e t a t e d t r e a t m e n t , Peabody Big Sky Mine, summer o f 1975. Regression Parameters Depth (cm) r * 2 slope intercept Model Parameters a b 15 0.653 -0.0172 1.605 0.3168 0.0172 30 0.603 -0.0125 2.119 0.2659 0.0125 45 0.576 -0.0106 2.450 . 0.2473 0.0106 60 0.554 -0.0098 2.698 0.2378 0.0098 75 0.533 -0.0089 2.897 0.2325 0.0089 90 0.532 -0.0084 3.134 0.2457 0.0084 120 0.568 -0.0082 3.374 0.2339 0.0082 150 0.604 -0.0086 3.564 0.2254 0.0086 180 0.663 -0.0097 3.727 0.2201 0.0097 210 . 0.683 -0.0103 3.865 0.2150 0.0103 :240* 0.683 -0.0106 3.975 0.2094 0.0106 270 0.658 -0.0099 .4.073 0.1910 0.0099 300 0.636 -0.0093 4.165 0.2036 0.0093 330 0.602 -0.0086 4.253 0.2027 ■ 0..0086 ;360 0.583 -0.0082 4.353 0.2057 0.0082 390 0.566 -0.0079 4.429 0.2051 0.0079 420 0.552 . -0.0076 4.501 0.2049 0.0076 depth to which uniform Ui m was obtained Ill A p p e n d i x Table 4. Results of linear r e g r e s s i o n s and c a l c u l a t e d v a l u e s of water m o v e m e n t m o d e l p a r a m e t e r s 0. and b for r e p 3, top s oiled n o n v e g e t a t e d treatment, Peabody Big Sky Mine, summer of 1975. Regression Parameters Depth (cm) r ' * 2 Model Parameters slope intercept a b 15 0.828 -0.0098 1.580 0.3152 0.0098 30 0.828 -0.0069 2.089 . 0.2605 0.0069 45 0.776 -0.0063 2.427 0.2457 0.0063 60 0.745 -0.0055 2.673 0.2360 0.0055 75 : 0.734 -0.0052 2.870 ■■ 0.2300 0.0052 90 0.722 -0.0048 3.106 0.2428 0.0048 120 0.710 t O.OOSO 3.351 0.2321 0.0050 150 0.726 -0.0048 3.550 0.2266 ' 0.0048 180 0. 722 -0.0048 3.711 0.2217 0.0048 210* 0.710 . -0.0047 3.847 0.2176 0.0047 240 0.686 -0.0044 . 3.964 0.2142 0.0044 270 0.692 -0.0044 4.067 0.2110 0.0044 300 0.692 -0.0042 4.160 0.2085 0.0042 330 0.692 -0.0040 4.244 0.2063 0.0040 360 0.678 -0.0038 4.320 0.2042 0.0038 390 0.664 -0.0037 4.391 0.2025 0.0037 420 '0.650 -0.0035 4.458 0.2012 0.0035 450 0.656 -0.0035 4.520 . 0.1998 0.0035 d e p t h to w h i c h u n i f o r m was o b t a i n e d 112 A p p e n d i x Table 5. Results of linear r e g r e s s i o n s a n d c a l c u l a t e d v a lues of w a t e r m o v e m e n t m o d e l p a r a m e t e r s CL a nd b for rep I, t o p s o i l e d r e v e g e t a t e d treatment, Peabody Big Sky Mine; summer of 1975. Regression Parameters * Model Parameters .2 r slope intercept 15 0.790 -0.0191 1.517 0.2886 0.0191 30 0.728 -0.0158 2.036 0.2420 0.0158 45 0.678 -0.0153 2.383 0.2272 0.0153 60 0.633 -0.0153 2.643 0.2199 0.0153 75 0.603 -0.0144 2.856 0.2179 0.0144 90 0.554 -0.0118 3.118 0.2382 0.0118 120* 0.426 -0.0091 3.385 0.2355 0.0091 150 0.248 -0.0058 3.578 0.2319 0.0058 180 0.105 -0.0032 3.732 0.2282 0.0032 210 0.014 -0.0010 3.861 0.2250 Q.0010 240 0.002 -0.0003 3.981 0.2228 0.0003 270 0.001 -0.0003 4.079 0.2185 0.0003 300 . 0.0001 -0.0001 4.162 0.2139 0.0001 330 0.003 -0.0004 4.255 0.2130 0.0004 360 0.005 -0.0005 4.328 0.2099 0.0005 390 0 .008 -0.0006 4.402 0.2085 0.0006 420 0.009 -0.0007 4.471 0.2073 0.0007 450 0.014 -0.0008 4.534 • 0.2059 0. 0008 depth to which uniform lb m was obtained a b n v3 A p p e n d i x Table 6. Depth (cm) * Results of linear regr e s s i o n s and calcul a t e d valu e s of w ater m o v e m e n t m o d e l p a r a m e t e r s <X a nd b for rep 2, top s o i l e d r e v e g e t a t e d treatment, Peabody Big Sky Mine, summer of 1975. Regression Parameters Model Parameters r2 ' slope •intercept a b 15 0.852 -0.0157 1.571 0.3074 0.0157 30 0.846 -0.0127 2.070 0.2530 0.0127 45 0.834 -0.0099 2.418 0.2402 0.0099 60 0.855 -0.0115 2,679 0.2318 0.0115 75 0.849 -0.0119 2.876 0.2248 0.0119 90 0.841 -0.0113 3.125 0.2403 0.0113 120 0.797 -0.0109 3.384 0.2333 0.0109 150 .0.754 -0.0084 3.606 0.2353 0.0084 180* 0.732 -0.0078 3.809 0.2406 0.0078 210 0.575 -0.0064 3.947 0.2383 0.0064 . 240 0.488 -0.0050 4.060 0.2350 0.0053 270 0.438 -0.0042 4.157 0.2311 0.0042 300 0.409 -0.0039 4.246 0.2276 0.0039 330 0.409 -0.0032 4.331 0.2261 0.0032 360 0.344 -0.0031 4.406 0.2235 0.0031 390 0.390 -0.0036 4.487 0.2230 0.0036 420 0.369 -0.0034 4.549 0.2205 0.0034 450 0.250 -0.0561 1.773. 0.0093 0,.0561 480 0.298 -0.0451 1.914 0.0107 0.0451 d e p t h to w h i c h u n i f o r m w as o b t a i n e d • I 114 A p p e n d i x Table 7. Results o f line a r r e g r e s s i o n s and c a l c u l a t e d v a l u e s of w a t e r m o v e m e n t m o d e l p a r a m e t e r s CL and 6 for rep 3, t o p s o i l e d r e v e g e t a t e d treatment, Peabody Big Sky Mine, summer of 1975 Regression Parameters. Depth (cm) r * 2 slope intercept Model Parameters a b 15 0.692 -0.0283 1.520 0.2821 0.0283 30 0.738 -0.-0187 2.065 0.2465 0.0187 . 45 0.468 -0.0080 2.385 0.2341 0.0080 60* 0.110 -0.0021 2.630. 0.2292 0.0021 75 0.0001 -0.00004 2.823 0.2243 0.00004 . 90 0.299 -0.0020 3.051 0.2327. 0.0020 120 0.372 -0.0018 3.299 0.2238 0.0018 150 0.185 -0.0011 3.518 0.2235 0.0011 180 0.003 -0.0001 3.693 0.2230 0.0001 210 0.049 -0.0006 3.836 0.2200 0.0006 240 0.068 -0.0006 3.970 0.2200 0.0006 270 0.311 -0.0016 4.101 0.2217 0.0016 300 0.327 -0.0018 4.217 0.2238 0.0018 330 0.394 -0.0022 4.311 0.2229 0.0022 depth to which uniform ij^ was obtained 115 A p p e n d i x Table 8. Results o f linear regre s s i o n s a n d c a l c u l a t e d v a l u e s of w a t e r m o v e m e n t m o d e l p a r a m e t e r s a. a nd b for rep I, n o n t o p s o i l e d r e v e g e t a t e d treatment, Pea b o d y B i g Sky Mine, summer of 1975 x Regression Parameters Depth (cm) r * 2 Model Parameters slope intercept a b 15 0.760 -0.0126 1.602 0.3199 0.0126 30 0.722 -0.0116 2.105 . 0.2629 0.0116 45 0.679 -0.0100 2.438 . 0.2449 0.0110 60* 0.576 -0.0058 2.661 0.2329 0.0058 75 0.492 -0.0034 . 2.834 0.2234 0.0034 90 ■ 0.118 -0.0011 3.045 . 0.2323 0.0011 120 0.164 -0.0013 3.279 0.2199 0.0013 150 0.244 -0.0018 3.441 0.2063 0.0018 180 0.180 -0.0014 3.590 0.1998 0.0014 210 0.200 -0.0015 3.721 0.1951 0.0015 240 0.147 -0.0013 3.829 0.1904 0.0013 270 0.039 -0.0006 3.934 . 0.1887 0.0006 300 0.031 -0.0005 4.037 0.1883 0.0005 depth to which uniform was obtained 116 Appendix Table 9. Results of linear regression and calculated values of water movement model parameters a and b for rep 2, nontopsoiled revegetated treatment, Peabody Big Sky Mine, summer of 1975 Regression Parameters Depth (cm) 2 V * slope intercept Model Parameters a b 15 0.868 -0.0145 1.517 0.2921 0.0145 30 0,848 -0.0163 1.989 0.2316 0.0163 45 0.827 -0.0137 2.269 0.2040 0.0137 60 0.790 -0.0106 2.475 0.1896 0.0106 75 0.705 -0.0091 2.660 0.1833 0.0091 90 0.551 -0.0092 2.921 0.1979 0.0092 120 0.404 -0.0094 3.227 0.2008 0.0094 150 0.545 -0.0078 3.457 0.2033 0.0078 180 0. 660 -0.0062 3.630 0.2029 0.0062 210 0.700 -0.0052 3.772 0.2013 0.0052 240 0.701 -0.0058 3.902 0.1998 0.0058 270* 0.834 -0.0052 4.002 0.1968 0.0052 300 0.835 -0.0056 4.094 0.1934 0.0056 330 0.819 -0.0058 4.182 0.1919 0.0058 360 0.856 -0.0054 4.257 0.1899 0.0054 390 0.846 -0.0059 4.331 0.1882 0.0059 ' 420 0.862 -0.0058 4.402 0.1876 0.0058 450 0.860 -0.0057 4.467 0.1869 0.0057. 480 0.861 -0.0054 4.528 0.1865 0.0054 d e p t h to. w h i c h u n i f o r m ij; was o b t a i n e d 117 A p p e n d i x Table 10. Results o f linear r e g r e s s i o n s and c a l c u l a t e d v a lues of w a t e r m o v e m e n t m o d e l p a r a m e t e r s a a nd b for rep 3, n o n t o p s o i l e d r e v e g e t a t e d treatment, P e a b o d y Big Sky Mine, summer of 1975. Regression Parameters Depth (cm) r * 2 Model Parameters slope intercept a b 15 0.761 -0.00280 1.594 0.3043 0.0280 30 0.712 -0.0272 2.109 0.2502 '0.0272 45 0.636 -0.0255 2.437 0.2307 0.0255 60* 0.533 -0.0230 2.672 0.2195 0.0230 75 0.407 -0.0197 2.853 0.2123 0.0197 90 .0.301 -0.0165 3.070 0.2222 0.0165 120 0.268 -0.0152 3.299 0.2099 0.0152 150 0.261 -0.0146 3.471 0.1992 0.0146 180 0.250 -0.0141 3.625 0.1938 0.0141 210 0.250 -0.0141 3.768 0.1912 0.0141 240 0.253 -0.142 3.894 0.1893 0.0142 270 0.259 -0.0142 3.998 0.1864 0.0142 300 0.257 -0.0142 4.099 0.1853 0.0142 330 0.257 -0.0142 4.191 0.1844 0.0142 360 0.261 -0.0143 4.273 0.1832 0.0143 390 0.260 -0.0143 4.348 0.1821 0.0143 420 0.260 -0.0143 4.420 0.1815 0.0143 450 ' 0.263 -0.0143 4.483 0.1802 0.0143 480 0.614 -0.1080 . 4.119 0.0658 0.0808 depth to which uniform ib m was obtained 118 A p p e n d i x Table 11. R e s u l t s of linear r e g r e s s i o n s a n d calcul a t e d v a l u e s of w a t e r m o v e m e n t m o d e l p a r a m e t e r s a and b for r e p I, n a t i v e range treatment, Peab o d y Big Sky Mine, summer o f 1975 Regression Parameters Depth (cm) r * 2 Model Parameters slope intercept a b 15 0.743 -0.0201 1.504 0.2841 0.0201 30 0.848 -0.0177 2.042 0.2419 0.0177 45 0.894 ' -0.0168 2.403 0.2305 0.0168 60 0.929 -0.0158 2.669 0.2254 0.0158 75 0.935 -0.0148 2.866 0.2198 0.0148 . 90* 0.912 -0.0143 3.104 0.2321 0.0143 120 0.361 -0.0102 3.347 0.2256 0.0102 150 0.304 -0.0105 3.540 0.2180 0.0105 180 0. 328 -0.0095 3.707 0.2154 0.0095 depth to which uniform lb was obtained ■ m ■ 119 A p p e n d i x Table 12. Results o f line a r r e g r e s s i o n s a n d c alculated v alues of w a t e r m o v e m e n t m o d e l p a r a m e t e r s a a nd b for rep 2, n a t i v e range treatment, Peab o d y Big Sky Mine, summer of 1975. Regression Parameters Depth (cm) r * 2 Model Parameters slope intercept a b 15 0.907 -0.0197 1.580 0.3068 0.0197 30 0.879 -0.0198 2.103 0.2560 0.0189 45 0.836 -0.0170 2.436 0.2380 0.0170 60 0.816 -0.0158 2.680 0.2279 0.0158 75 0.802 -0.0163 2.879 0.2212 0.0163 90* 0.805 -0.0170 ' 3.119 0.2329 0.0170 120 0.796 -0.0144 3.363 0.2246 0.0144 150 0.761 -0.0125 3.556 0.2194 0.0125 180' 0.753 -0.0106 3.704 0.2135 0.0106 depth to which uniform ijj was obtained 120 A p p e n d i x Table 13. R e sults of linear regressions a nd c a l c u l a t e d v a l u e s of w a t e r m o v e m e n t model p a r a m e t e r s CL and b v for rep 3, nati v e r a n g e treatment, P e a b o d y Big Sky M i n e , summer of 1975 Regression Parameters Depth (cm) r * 2 slope intercept Model Parameters a b 15 0. 968 -0.0384 1.506 0.2709 0.0384 30 0.968 -0.0354 2.054 0.2284 0.0354 45 0.965 -0.0291 2.401 0.2195 0.0291 60 0.950 -0.0270 2.658 0.2129 0.0270 75 0.942 -0.0270 2.856 0.2064 0.0270 90 0.938 -0.0281 3.091 0.2154 0.0281 120 0.920 -0.0289 3.340 0.2048 0.0289 150* 0.901 -0.0274 3.543 0.2009 0.0274 180 0.879 -0.0252 3.708 0.1987 0.0252 depth to which uniform ^ Tp m ■ was obtained Appendix Table 14. 460 Monthly soil profile water balance to the ISO and cm depths for rep I, topsoil nonvegetated spoils treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. AJl data are presented in centimeters. Jan Feb Mar Apr * y Period Total Jan. '75A p r . '76 0.00 1.96 2.00 4.98 6.50 62.06 -2.99 -3.13 -2.60 -3.76 -49.41 1976 1975 Mar Apr Nmy Jun Jul Al1 Sep Oct Precipitation, PPT 2.30 2.00 2.50 5.60 8.10 7.40 4.40 S-SOt 0.00 2.00 3.60 2.60 46.31 Eripo. transpiration, ET -0.81 0.00 0.00 -0.70 -3.20 -1.50 0.00 0.00 -0.01 2.29 Runoff, R O 2 . 0.00 -2.99* -3.13* -2.60* -3.76 0.00 0.00 0.00 0.00 -6.93 -10.10 0.00 0.00 0.00 0.00 0.00 Water flow, WF 460 cm Change soil water content ASWC — — Water flow, WF „ „ Change soil wat er content, ASWC — — — — — — — — — — 0 moisture reading for November not available. * evapotranspiration measured by weighing lysimeter method 2 runoff was not measured but assieed to be zero. ^ indicates amount of water which entered profile during flooding. covered with plastic. — — — -- 0.00 0.00 — 1.49 3.19 -1.57 -3.43 — — 0.00 0.00 0.00 0.00 3.07 0.39 0.40 3.39 -- 1.01 2.16 -2.70 -1.25 — — -6.76 0.45 1.35 3.58 — 5.89 6.10 -5.24 -8.27 -- — -6.76 1.75 1.75 4.68 — 5.41 -.07 -6.37 -6.09 — -- A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. (see m e t h o d o l o g y ) . Zero values for PPT and ET following this represents the period the plot was ET values for January to May, 1975, not measured but assumed to equal the measured ET values for January to May, 1976. data not available due to equipment malfunction. 0.00 121 ISO cm S Feb i Jan Nov0 Dec Yearly Total a S Profile Hydrologic Component Depth Appendix Table 15. Monthly soil profile water balance to the 150 and 420 cm depths for rep 2, topsoiled r.onvegetated spoils treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. I I Precipitation, PPT Evapoi t r a n s p i r a t i o n , ET Punoff, PO2 2.00 Mar Apr 2.50 5.60 -0.81* -2.99* -3.13* -2.8* May 8.10 Jun 5.40* Jul Aug Sep Oct 0.00 0.00 1.50 2.00 3.60 Nov0 -3.76* 0.00 0.00 0.00 -2.30 -0.70 -3.20 Dec I Total J*n Feb Mar Apr 2.60 35.60 0.33 1.96 2.00 4.98 May Apr. '76 6.50 44.87 -1.50 -21 .19 -0.81 -2.99 -3.11 -2. 80 -3.76 -30.92 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 - 8.47 0.00 -0.18 3.50 0.89 -2.52 -0.16 -7.45 -2.84 -0.10 0.50 -0.49 0.41 1.21 - 7 . 2 2 1.25 3.84 -1.80 -4.54 „ 1.31 2.51 0.26 0.28 4.18 -2.05 -2.84 -0.10 -0.30 0.81 0.81 2.31 7.19 0.77 2.81 -2.93 -2.36 - Wat er flew, WT 1.68 8.08 2.33 -1.94 2.49 -11.97 .13 -0.4C 0.00 0.80 1.80 1.35 - 2.41 2.43 8.31 -4. 16 -9. 44 - 5.27 C h a n g e soil w a t e r c o n t e n t , ASWC 3.17 7.09 1.70 0.86 -".13 -0.40 -0.80 2.10 2.20 2.95 1.95 7.28 -5.29 -7.26 8.68 6.83 -6.57 0 moisture reading for November not available. 1 eva potra nspir atio n mea sured b y wei ghing lysimeter me t h o d (see m e t h o d o l o g y ) . 12.00 A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. r u n o f f w a s not m e a s u r e d but a s s u m e d to b e zero. indicates amount of water which entered profile during flooding. covered with plastic. Zero val ues for PPT and ET following this rep resen ts the period the plot was E T v a l u e s f o r J a n u a r y to M ay , 197 5, n o t m e a s u r e d b u t a s s u m e d t o e q u a l t h e m e a s u r e d E T v a l u e s f o r J a n u a r y to May , 1976. d at a net a v a l Iao Ie due to e q u i p m e n t mal fun c t i o n . 5.48 122 4 20 ca 2.30 Feb Period Total 1976 Cha nge soil wat er content ASWC W a t e r flow, WF ISO cm I 1975 Proflie ,Hydrclogic Component ; Jan Depth Appendix Table 16. Monthly soil profile water balance to the 150 and 450 cm depths for rep 3, topsoiled nonvegetated spoils treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. 1975 Profile Hydrologic Component Depth Precipitation, PPT Evapoi transpiration, ET Runoff, RO^ Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2.30 2.00 2.50 5.60 8.10 7.40 4.32+ 0.00 0.00 2.00 3.60 2.60 0.00 0.00 0.00 -0.70 -3.20 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -0.81* -2.99* -3.13* -2.80* -3.76* -6.93 Yearly Total Feb Mar Apr 40.42 0.33 1.96 2.00 4.98 Ma y Apr. 6.50 49.69 -1. 50 -25.82 -0.81 -2.99 -3.13 -2. 80 -3.76 -35.55 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.37 - 8.29 1.14 3.99 -2.42 -4.35 -- - 9.93 0.00 -0.59 3.32 1.49 -2.27 0.25 -6.34 -3.35 -1.08 -0.17 -0.91 -0.01 0.90 2.33 0.86 0.53 4.59 -5.87 0.97 -1.08 -0.17 0.39 0.39 2.47 6.31 0.66 2.96 -3.55 -2.17 — Wa t e r flow, WF 1.31 7.46 1.53 -1.78 4.04 -14.24 -2.13 -2.07 -0.39 -0.02 0.88 3.98 - 1.43 2.46 8.71 -5.42- 10.51 -- Cha nge soil water content, ASWC 2.80 6.47 0.90 1.02 8.38 -13.77 2.19 -2.07 -0.39 1.28 1.28 5.08 15.17 1.98 7.68 -6.55 -8.33 — ° moisture reading for November not available. 1 eva potra nspir alio n mea s u r e d by wei g h i n g lysimeter met hod (see methodology). ^ runoff was not measured but assumed to be zero. A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. indicates amount of water which entered profile during flooding. covered with plastic. Zero values for PPT and ET following this represents the period the plot was Et values for January to May, 1975, not measured but assumed to equal the measured ET values for January to May, 1976. data not available due to equipment malfunction. '76 4.21 - 6.19 7.95 123 450 cm Feb Change soil water content, ASWC Wa t e r flow, WF 150 cm Jan Period Total 1976 I j Jan Appendix Table 17. Monthly soil profile water balance to the 150 and 450 ca depths for rep I, topsoiled revegetated spoils treatment, Peabody Big >line, January, 1975 to April, 1976. A negative value indicates a loss of water f-om the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. I i___ Profile Hyd rologic Component; Depth Precipitation, PPT Evapo, transpiration, E T 1 Runoff, RO^ 450 cm Jan Feb Mar Apr May Jun Jul Aug Sep Oct z.so 2.00 2.50 5.60 8.10 5.74* 0.00 0.00 0.00 2.00 5.60 Nov0 Dec Yearly Total Jan Feb Mar Apr 2.60 34.44 0.33 1.96 2.00 4.98 '76 6.50 43.71 -0.81 -2. 99 -3.13 -2. 80 -3. 76 -28.62 0.00 0.00 0.00 0.00 -0.70 -3.20 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -3.29 1.40 3:6 0.57 -- - 7.09 6.52 -3.77 0.37 2.13 2.75 -- 8.00 -0.60 - 3.56 -8.6" 2.4- ".'I 2.52 -- 0.47 11.99 9.15 1.44 6.58 4.70 -- 15.56 -0.81* -2.99* -3.13* -2.80* -3.76* -1.50 -18.89 N a y Apr. Water flow, WT -2.17 0.12 2.43 -1.90 -3.34 -4.88 -0.02 -0.82 -1.62 0.75 1.66 0.76 - 9.03 Cha nge soil water content, ASWC -C.68 -0.87 1.80 0.90 1.00 0.86 -0.02 -0.82 -1.62 2.05 2.06 1.86 W a t e r flow, WT -2.57 -2.28 1.92 -1.12 -5.87 -6.44 -0.13 0.30 -2.43 7.38 8.28 C ha nge soil wat er content, ASWC - 1 .08 -3.27 1.29 1.68 -1.53 -0.70 - 0.13 0.30 -2.43 8.68 8.68 0 moisture rea ding for Nov ember not available. * e v a p o t r a n s p i r a t i o n m e a s u r e d b y w e i g h i n g l y s i m e t e r m e t h o d (see m e t h o d o l o g y ) , 0.50 A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o Z e c e m b e r I b y 2. run off was not m e a s u r e d but a s s umed to be zero. indicates amount of water which entered profile during flooding. covered with plastic. Zer o v a l u e s for P PT and ET fol lowin g t h i s rep resen ts the per iod the plot was E T v a l u e s f o r J a n u a r y tc May , 197 5, n o t m e a s u r e d but a s s u m e d to e q u a l t h e m e a s u r e d E T v a l u e s f o r J a n u a r y t o M ay , 19'6. d a t a not a v a i l a b l e d u e t o e q u i p m e n t ma l f u n c t i o n . 124 150 cm Period Total 1976 1975 Appendix Table 18. Monthly soil profile water balance to the 150 and 480 cm depths for rep 2, topsoiled revegetated spoils treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters Precipitation, PPT Evapoj tra nspir ation , ET 480 cm Feb Mar Apr Msy Jun Jul Aug Sep Oct Nov0 2.30 2.00 2.50 5.60 8.10 8.34+ 0.00 0.00 0.00 2.00 3.60 0.00 0.00 0.00 0.00 -0.70 -3.20 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Wa t e r flow, WF -4.15 1.79 1.12 -0.91 -3.02 -5.10 -1.91 -0.16 -0.01 0.74 Change soil water content, ASWC -2.66 0.80 0.49 1.89 1.32 3.24 -1.91 -0.16 -0.01 Water flow, WF -7.98 6.08 1.12 -4.22 -7.99 -7.14 -1.26 -0.53 Cha nge soil water content, ASWC -6.49 5.09 0.49 -1.42 -3.65 1.20 -1.26 -0.53 -0.81* -2.99* -3.13* -2.80* -3.76* ° moisture reading for November not available. * evapotranspiratior. m e a s u r e d by w e i ghing lys imete r m et hod (see m e t h o d o l o g y ) . “ runoff was not measured but assumed to be zero. Dec I Total Jan Feb Mar Apr 37.04 0.33 1.96 2.00 4.98 2.60 6.50 46.31 -1. 50 -18 .89 -0.81 -2. 99 -3. 13 -2.80 -3. 76 -28.62 0.00 0.00 0.00 1.64 -1.79 -11.76 -3.48 1.56 3.07 2.04 2.04 -0.69 6.39 -3.96 0.53 1.94 3.46 -0.34 5.09 5.99 -2.44 -15.62- 0.93 3.03 8.27 4.46 -0.34 6.39 6.39 -1.34 4.53- 1.41 2.00 7.14 6.64 0.00 0.00 0.00 0.00 1.28 A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f c r O c t o b e r I t o D e c e m b e r I b y 2. indicates amount of water which entered profile during flooding. covered with plastic. Zero values for PPT and ET following this represents the period the plot was values for January to '-lay, 1975, not measured but assumed to equal the measured ET values for January to May, 1976. data not available due to equipment malfunction. 0.00 - 9.33 — 8.36 - 8.79 -- 8.90 125 150 cm Jan 0.00 Runoff, RO^ Period Total Jan . 1^SM a y A p r . '76 1976 1975 Profile Hydrologic Component Depth Appendix Table 19. Monthly soil profile water balance to the 150 and 330 cm depths for rep 3, topsoiled revegetated spoils treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. Profile Hydrologic Component Depth Precipitation, PPT Evapotra nspir ation , ET 350 cm 2.30 Feb 2.0 Mar Apr May Jun Jul Aug Sep Oct Nov0 2.50 5.60 8.10 7.40 4.84f 0.00 0.00 2.00 5.60 Dec 2.60 'Ieaxly Total 40.94 Jan Feb Mar Apr 0.33 1.96 2.00 4.98 H ay Apr. '76 6.50 50.21 - 1 . 5 0 -25 .82 -0.81 -2. 99 - 3 . 1 3 - 2 . 8 0 -3. 76 -35.55 0.00 0.00 0.00 -0.70 -3.20 Runoff, RO^ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Water 4.00 1.99 1.80 -3.65 -2.87 -4.50 -3.19 -0.16 -0.19 0.60 1.50 0.24 -12.34 -3.26 1.47 3.37 1.05 —— - 9.80 -2.51 1.00 1.17 -0.85 1.47 -4.03 1.65 -0.16 -0.19 1.90 1.90 1.34 2.69 -3.74 0.44 2.24 3.23 -- 4.86 Wat er flow, WF 3.24 3.82 1.78 -4.33 -6.58 -5.88 -3.51 -0.85 -1.04 3.01 3.91 0.28 -12.63 -6.86 2.34 6.73 3.24 -- - 7.18 Cha nge soil water content, ASWC 1.75 2.83 1.15 -1.53 -2.24 -5.41 1.33 -0.85 -1.04 4.31 4.31 1.38 2.49 ".34 1.31 5.60 5.42 — low, WF Change soil water content, ASWC -0.81* -2.99* -3.13* -2.80* -3.76* -6.93 0 moisture reading for November not available. * eva potra nspir atio n mea s u r e d by wei ghing lys imete r met hod (see methodology). ~ runoff was not measured but assumed to be zero. L S Y tC s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g I S K C f o r O c t o b e r I t o D e c e m b e r I b y 2. indicates amount of water which entered profile during flooding. covered with plastic. Zero values for PFT and ET following this represents the period the plot was values for January to May, 1975, not measured but assumed to equal the measured ET values for January to May, 1976. data not available due to equipment malfunction. ".48 126 150 cm Jan Period Total 1976 1975 Appendix Table 20. Monthly soil profile water balance to the 150 and 300 cm depths for rep I, nontopsoiled revegetated spoils treatment, Peabody Big Sky Mire, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. ProfiIe I Depth .Hydrologic Component Precipitation, PPT Evapci transpiration, ET R u n o f f , RO*" Cha nge soil wa t e r con tent, ASWC Wat er flow, WF 300 cm Cha nge soil water c o n t e n t , ASWC 2.30 2.00 5.60 2.50 8.10 7.40 4.40 -0.81* -2.99* -3.13* -2.80* -3.76* -6.93 -10.10 0.00 2.00 3.60 0.00 0.00 -0.70 -3.20 2.60 45.42 0.33 Apr 1.96 2.00 4.98 6 . SO 54.69 -1.50 -35.92 -0.81 -2.99 -3.13 -2.80 -3.76 -45.65 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -0.80 1.37 -0.17 -0.84 -7.80 -1.39 4.11 -0.82 -0.44 0.38 1.28 4.42 - 0.70 -5.29 0.69 0.38 -0.80 1.96 -3.46 -0.92 -1.59 4.10 -0.44 1.68 1.68 5.52 8.80 -5.77 1.82 -3.10 -1.24 1.37 -0.92 0.17 -9.70 -1.46 4.34 -0.31 -0.52 1.88 2."9 5.54 1.94 -8.97 4.29 -3.27 -1.87 6.64 11.44 -9.45 0.25 0.38 2.97 -1.55 -5.36 -0.99 -1.36 0 moi sture rea ding for Nov ember not available. 1 evapotra nspir atio n mea sured by wei ghing lys imete r me t h o d (see methodology). *■ 4.92* 4.61 -0.52 3.18 3.13 Period Total Jan . '75M a y A p r . '76 0.00 0.00 0.00 0.00 0.00 0.00 2.85 -1.97 -1.56 3.26 -4.40 A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g I S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. run off was not m e a sured but a ss umed to be zero. indicates amount of water which entered profile during flooding. covered wit h plastic. Zero val ues for PPT and ET following this rep resen ts the period the plot was v a l u e s f o r J a n u a r y to May , 1975, not m e a s u r e d b u t a s s u m e d to equ al t h e m e a s u r e d E T v a l u e s f o r J a n u a r y to May , 1976. data not available due to equipment malfunction. - 6.67 0.62 0.31 0.00 2.37 -** - T 88 1.16 127 Wat er flow, WF 150 cm --- 5- - - - - - Y e a r l y Sov Dec ! Total Appendix Table 21. Monthly soil profile water balance to the 150 and 480 an depths for rep 2, nontopsoiled revegetated spoils treatment, Peabody Big Sky Mire, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. T™" • Profile Hydrologic Component Depth 0.00 2.00 3.60 0.00 0.00 -0.70 -3.20 0.00 0.00 0.00 0.00 0.00 -1.17 0.49 1.39 2.59 --2 . 9 2 2.31 -2.69 -1.84 -1.17 1.79 1.79 3.69 --3 . 4 0 1.28 -3.82 Water flow, WF 4.24 5.14 7.12 — 10.8" 5.58 -5.39 -2.99 Change soil wat er content, ASWC 5.54 .5.54 8.22 — 11.35 4.55 -'.66 -0.81 Jan Feb Mar Apr Hsy Jun Jul Aug 2.30 2.00 2.50 5.60 8.10 7.40 4.40 -0.81* -2.99* -3.13* -2.80* -3.76* -6.93 -10.10 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Water flow, WF Change soil water content, ASWC -- -- — — — — — 0 moisture reading for November not available. 1 eva potra nspir atio n m e a s u r e d by wei ghing lysimeter met hod (see m e t h o d o l o g y ) . — 2.60 49.93 0.33 Feb Mar Apr 1.96 2.00 4.98 6.50 59.20 -1.50 -35.92 -0.81 -2.99 -3.13 -2.80 -3.76 -45.65 0.00 0.00 0.00 0.00 0.00 0.00 0.34 A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. *■ runoff was not measured but assumed to be zero. indicates amount of water which entered profile during flooding. covered with plastic. Zero values for PPT and ET following this represents the period the plot was values for January to May, 1975, not measured but assumed to equal the measured ET values for January to May, 1976. data not available due to equipment malfunction. 0.00 -- -- — -- 128 9.43* Runoff, RO^ 4 8 0 cm Dec Oct Evapo1 transpiration, ET 150 cm Nov0 Yearly Total Sep Precipitation, PPT Period Total Jan. '75H a y A p r . '76 1976 1975 Appendix Table 22. Monthly soil profile water balance to the 150 and 480 cm depths for rep 3, nontopsoiled revegetated spoils treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. 150 cm 4 8 0 cm Nov0 Dec Yearly Total Jan Feb Mar Apr 2.60 37.06 0.33 1.96 2.00 4.98 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Precipitation, PPT 2.30 2.00 2.50 5.60 8.10 a. S e t 0.00 0.00 0.00 2.00 3.60 Evapo, transpiration, ET 0.81* -2.99* -3.13* -2.80* -3.76* 0.00 0.00 0.00 0.00 -0.70 -3.20 0.00 0.00 0.00 0.00 0.00 0.00 0.00 46.33 -1.50 -18.89 -0.81 -2.99 -3.13 -2.80 -3.76 -26.82 0.00 0.00 0.00 0.00 0.00 0.00 Wat er flow, WF -2.76 3.30 1.46 -3.81 -6.38 -4.11 -1.26 -0.43 -0.21 0.52 1.43 3.76 8.49 5.02 3.52 -3.03 -1.92 Change soil water content, ASWC -1.27 2.31 0.83 -1.01 -2.04 4.25 -1.26 -0.43 -0.21 1.82 1.83 4.86 9.68 5.50 2.49 -4.16 Water flow, WF 3.87 5.38 -0.47 -1.59 -12.46 0.17 -3.75 -1.17 -0.56 4.46 5.36 8.90 Change soil water content, ASWC 2.38 4.59 -1.10 -8.12 8.53 -3.75 -1.17 -0.56 5.76 5.76 10.00 1.21 0.00 0.00 6.50 0.00 Runoff, R O 2 Period Total J an . '75M a y A p r . '76 1976 1975 Profile Hydrologic Component Depth 0 moisture reading for November not available. 1 ev a p o t r a n s p i r a t i o n m e a s u r e d b y w e i g h i n g lys imete r m e t h o d (see met hodol ogy). 0.00 0.00 — 2.77 0.40-1 5.96 9.69 -7.73 -2.87 — -16.47 18.57-1 6.44 8.66 -8.86 -0.69 — 1.24 2 r u n o f f w a s not m e a s u r e d b u t a s s u m e d t o be zero. values for Jan u a r y to May, Zero val ues for PPT and ET fol lowin g this rep resen ts the period the plot was 1975, n o t m e a s u r e d b u t a s s u m e d t o e q u a l the m e a s u r e d E T v a l u e s for J a n u a r y t o M a y , 1976. data not available due to equipment malfunction. -14.94 0.26 A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. indicates amount of water which entered profile during flooding. covered with plastic. 0.00 Appendix Table 23. Monthly soil profile water balance to the 150 cm depth for rep I, native range treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. Jar. Feb Mar Apr May Period Total J a n . '75 Apr . '76 0.33 1.96 2.00 4.98 6.50 53.36 -0.81 -2.99 -3.13 -2.80 -3.76 -35.55 1975 Hydrologic Component Precipitation, PPT Evapo, transpiration, ET Runoff, RO2 W a t e r flo w, WF Dec 3.60 2.60 44.09 -0.70 -3.20 -1.50 -25.82 Jan Feb Mar Apr May Jun Jul Aug Sep Oct 2.30 2.00 2.50 5.60 8.10 7.40 7.99* 0.00 0.00 2.00 0.00 0.00 0.00 -0.61* -2.99* -3.13* -2.80* -3.76* -6.93 Nov0 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -0.55 0.60 0.94 -0.71 -6.09 -2.53 -1.47 -2.63 -0.58 -0.14 0.77 0.14 -12.25 -1.23 1.33 0.95 -3.30 -- -14.50 0.94 -0.39 0.31 2.09 -1.75 -2.06 6.52 -2.63 -0.58 1.16 1.17 1.24 6.02 - i n C .30 - 0 . 1 8 - 1 . 1 2 0 moisture reading for November not available. A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. * e v a p o t r a n s p i r a t i o n m e a s u r e d b y w e i g h i n g l y s imete r m e t h o d (see met hodol ogy), r un off w a s not m e a s u r e d b u t a s s u m e d to be zero. indicates amount of water whi ch entered pro file during flooding. covered with plastic. Zer o va l u e s for PPT and ET following this rep resents the per iod the plot was v a l u e s f o r J a n u a r y t o M a y , 197 5, n o t m e a s u r e d b u t a s s u m e d t o e q u a l t h e m e a s u r e d E T v a l u e s f o r J a n u a r y to M ay , 1976. data not available due to equipment malfunction. 3.31 130 Change soil water content, ASWC 1976 ; Nearly Total Appendix Table 24. Monthly soil profile water balance to the 150 cm depth for rep 2, native range treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. 1976 1975 Hydrologic Component Precipitation, PPT Evapotranspiration, E T 1 Runoff, R O 2 Water flow, WF Feb Mar Apr M»y Jun 2.30 2.00 2.50 5.60 8.10 7.40 Jul Nov0 Dec Yearly Total Aug Sep Oct 0.00 0.00 2.00 3.60 2.60 44.99 Jan Feb Mar Apr Miy 0.33 1.96 2.00 4.98 6.50 54.26 -0.81 -2.99 -3.13 -2.80 -3.76 -35.55 0.00 0.00 0.00 -0.70 -3.20 -1.50 -25.82 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -1.00 1.48 0.60 -0.41 -5.66 -2.51 -2.52 -2.82 -0.59 0.16 1.06 -0.11 -12.32 -0.54 1.44 1.78 -3.62 — -13.26 0.49 0.49 -0.03 2.39 -1.32 -2.04 6.37 -2.82 -0.59 1.46 1.46 0.99 6.85 -1.02 0.41 0.65 -1.44 — 5.45 -0.61* -2.99* -3.13* -2.80* -3.76* -6.93 0 moisture reading for November not available. 1 e v a p o t r a n s p i r a t i o n m e a s u r e d b y w e i g h i n g l y s i m e t e r m e t h o d (see m e t h o d o l o g y ) . 2 r u n o f f w a s not m e a s u r e d but a s s u m e d t o b e zero. 0.00 0.00 A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. indicates amount of water which entered profile during flooding. Zero values for PPT and ET follwing this represents the period the plot was covered with plastic. v al ues for J a n u a r y to May, 1975, not m e a sured but a s s umed t o equal t h e m e a s u r e d ET v a l u e s for J a n u a r y to May, 1976. d a t a not ava ilabl e due to equ ipmen t malfunction. 0.00 131 Change soil wat er content, ASWC Jan Period Total Jan. '75A p r . '76 Appendix Table 25. Monthly soil profile water balance to the 150 cm depth for rep 3, native range treatment, Peabody Big Sky Mine, January, 1975 to April, 1976. A negative value indicates a loss of water from the profile and a positive value indicates a gain of water in the profile. All data are presented in centimeters. • 1975 1976 3.60 2.60 54.17 -0.70 -3.20 -1.50 -35.92 0.00 0.00 0.00 0.00 0.00 Wat er flow, WF -6.'7 -0.04 0.87 Change soil water content, ASWC -6.77 1.26 1.27 Hydrologic Component Precipitation, PPT Evapo1 transpiration, ET Runoff, RO^ Jan Feb Mar Apr n»y Jun Jul Aug Sep Oct 2.30 2.00 2.50 5.60 8.10 7.40 4.40 13.67+ 0.00 2.00 0.00 0.00 0.00 -0.81* -2.99* -3.13* -2.80* -3.76* -6.93 -10.10 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 moi sture rea d i n g f or N o v e m b e r not available. 1 eva potra nspir atio n m e a s u r e d b y wei ghing lysimeter rethxl (see m e t h o d o l o g y ) . runoff was not measured but Feb Mar Apr Msy 1.96 2.00 4.98 6.50 63.44 -0.81 -2. 99 -3. 13 -2. 80 -3. 76 -45.65 0.33 0.00 0.00 0.00 0.73 -1.32 1.40 1.09 -2.81 — -- 1.83 -1.80 0.37 -0.04 -0.63 — — 0.00 0.00 A S W C s h o w n f o r O c t o b e r a n d N o v e m b e r o b t a i n e d b y d i v i d i n g A S W C f o r O c t o b e r I t o D e c e m b e r I b y 2. a ss umed to b e zero. indicates amount of water which entered profil: during flo oding. covered with plastic. values for January to May Nov0 Zero val ues for PPT and ET fol lowin g this rep resen ts the period the plot was 1 9 7 5 , n o t m e a s u r e d b u t assiaeed t o e q u a l t h e m e a s u r e d E T v a l u e s f o r J a n u a r y t o M a y , 197 6. data not available due to equipment malfunction. Period Total Jan . '75A p r . '76 0.00 132 Dec Yearly Total 3 A762 N3?8 Ar66 cop.2 Arnold, Franklin B Soil water and solute* movement in Montana strip mine spoils DATg^s®* 3m , , o To O^jjdiLUdAAfiT 1 1H w jlM -). j . /(jL/c W Q 10. TWTRIIUBIURY y. u - JL u :#b KL /We/f ^AT 2 9 O ifF .«■/rtffi EiZU- A P a N /Z- I J) - 7 ^ V7- y /4h ^ - < U e^ ^