Geology of the northern part of the Cherry Creek metamorphics, Madison Co., Montana by Willard D Tompson A THESIS Submitted to the Graduate Faculty in partial fulfillment of the requirements for the degree of Master of Science in Applied Science at Montana State College Montana State University © Copyright by Willard D Tompson (1959) Abstract: Kyanite and sillimanite occur in the Precambrian schists, gneisses, and pegmatites of the Cherry Creek (Archean ?) metamorphics south of Ennis, Montana. The metamorphic rocks were formed as a result of the regional metamorphism of a thick sequence of sedimentary rocks—mostly limestones and shales. The stratigraphic section of metamorphic rocks is about 3,050 feet thick and consists of interlaminated dolomite-marble, dolomitic marble, kyanite-bearing schists and gneisses, amphibolites, and gneisses and schists, undivided. The rocks are tightly folded and a large isoclinal syncline, which plunges steeply to the east, repeats the section in the map area. Three types of pegmatites occur in the area and each type displays a preference for certain host rocks: kyanite pegmatites occur in kyanite schist or gneiss; feldspar-quartz-muscovite-tourmaline pegmatites occur in marble and in kyanite schist; and feldspar-quartz pegmatites are most prominent in quartz-feldspar gneiss. The kyanite pegmatites apparently formed by processes of metamorphic differentiation, in which aluminum ions were added to a quartz segregation and probably grew on kyanite nuclei already present in the quartz. The inversion, sillimanite replacing kyanite, occurs repeatedly in the kyanite pegmatites and is probably due to increased temperatures subsequent to the formation of the kyanite. According to equilibrium diagrams by Miyashiro (1949) and Hietanen (1956), pegmatitic kyanite forms at low temperatures and pressures and inverts to andalusite at higher temperatures and is stable,at higher pressures. The fact that in these pegmatites, sillimanite was produced with increased temperatures, suggests that kyanite possesses no low TP stability field. GEOLOGY OF THE NORTHERN PART OF THE CHERRY CREEK METAMORPHICS, MADISON CO., MONTANA by WILLARD D. TOMPSON A THESIS Submitted t o the Graduate F a c u l t y in p a r t i a l f u l f i l l m e n t of t h e require me nts f o r the degre e of Master of Science in Applied Science at Montana S t a t e College ' t I / Approved; Head, Major Department I. Bozeman, Montana May 1959 I I 2 CONTENTS Text Page A b s t r a c t .................................................................................................................................... 5 I n t r o d u c t i o n and g e n e r a l g e o lo g y ............................................................................... 6 P u r p o s e ...................................................................................................................................... 6 Acknowledgments.................................................................................................................... 6 F i e l d work............................................................................................................................... 6 Summary of p re v io u s work................................................................................................. 6 D e s c r i p t i o n of r o c k s .......................................................................................................... Dolomite-marble and d o l o m i t i c m a r b l e ........................................................... Kyanite s c h i s t , k y a n i t e g n e i s s and a s s o c i a t e d r o c k s ........................... G n e i s s ............................................................................................................................. S t r a t i g r a p h y of the metamorphic r o c k s ......................................................... 10 10 11 11 12 P e t r o l o g y of the p e g m a t i t e s .......................................................................................... B a s is f o r d i v i s i o n of p e g m a t i t e s .................................................................... Kyanite p e g m a t i t e s ................................................................................................... The si I l i m a n i t e group of m i n e r a l s ....................................................... S t a b i l i t y r e l a t i o n s of the s i l l i m a n i t e g r o u p ............................... Mineralogy of the k y a n i t e p e g m a t i t e s ................................................ D e s c r i p t i o n of k y a n i t e p e g m a t i t e s ....................................................... O p t i c a l p r o p e r t i e s o f k y a n i t e and p e t r o g e n e s i s ........................... I n v e r s i o n s and s t a b i l i t y r e l a t i o n s of the aluminum s i l i c a t e m i n e r a l s in the p e g m a t i t e s .............................................. O r ig in of k y a n i t e p e g m a t i t e s .................................................................. 13 13 14 16 17 20 20 21 31 32 Fe Id s p a r - q u a r t z - m u s c o v i t e - t o u r m a l i n e p e g m a t i t e s ................................... M in er al ogy ......................................................................................................... D e s c r i p t i o n ....................................................................................................... P e g m a ti te s in marble l a y e r s .................................................................... Rim Rock p e g m a t it e and V e t t e r P r o s p e c t ............................................ Control of l o c a l i z a t i o n of the Rim Rock p e g m a t i t e .................... 35 35 35 36 36 36 F e l d s p a r - q u a r t z p e g m a t i t e s ................................................................................. D e s c r i p t i o n of p e g m a t i t e s ........................................................................ Mineralogy of p e g m a t i t e s ........................................................................... P e g m a t i t e - h o s t rock c o n ta c t r e l a t i o n s h i p s and o r i g i n of p e g m a t i t e s ............................................................................... 37 37 38 39 133412 3 Text Page S t r u c t u r e .................................................................................................. Co ntact r e l a t i o n s between Precambrian rocks and P a l e o z o i c ro c ks . F o ld in g of th e metamorphic r o c k s ......................................... S t r u c t u r a l i n t e r p r e t a t i o n ........................................................................ Boudinage s t r u c t u r e s in th e marble l a y e r s ................................................ 40 40 41 41 44 P r i n c i p l e of th e metamorphic f a c i e s a p p l i e d to the rocks o f the n o r t h e r n p a r t of th e Cherry Creek metamorphics.......................................... 47 P o t e n t i a l f o r economic development of the Ennis k y a n i t e d e p o s i t ........... The volume of k y a n i t e - b e a r i n g rocks in thg map a r e a .......................... 49 49 I n d u s t r i a l uses of k y a n i t e ............................................................................................ 50 4 ILLUSTRATIONS F ig u r e 1. Page A real map showing l o c a t i o n of map a r e a in t h i s r e p o r t and type a r e a of Cherry Creek me tamorp hics............. .......................... 7 2. Map of k y a n i t e - b e a r i n g p e g m a t i t e .................................................................. 15 3. Diagram showing p o s s i b l e s t a b i l i t y r e l a t i o n s of th e aluminum s i l i c a t e m i n e r a l s ................................... ....................... 17 Diagram showing s t a b i l i t y r e l a t i o n s h i p s of k y a n i t e , s i l l i manite and a n d a l u s i t e under 15,000 p s i w a te r p r e s s u r e ............... 18 ^ E q u i li b r iu m diagram of the aluminum s i l i c a t e m i n e r a l s , i l l u s ­ t r a t i n g the pro p o s a l t h a t k y a n i t e may have no lo w -p r es su r e s t a b i l i t y f i e l d . ..................................................................................... 32 4. Map of Rim Rock' p e g m a t i t e ........ ....................................... 38 5. Geologic map of th e n o r t h e r n p a r t of th e Cherry Creek meta­ morphics, Madison C o . , Mont., w it h s t r u c t u r a l i n t e r p r e t a t i o n . 42 6. Map of f o l d s in d o l o m i t e - m a r b l e ........................................................... 43 7. Boudin in d o l o m i t e - m a r b l e . ............................................................................... 46 8. AKF diagram of am ph ib ol it e f a c i e s . . . . ; ......................i............................. 48 9. AKF diagram of e p i d o t e - a m p h i b o l i t e f a c i e s ..................................... 48 3A. SB. Plate -■ 1. Geologic map and c r o s s - s e c t i o n of the n o r t h e r n p a r t of the FrontisCherry Creek metamorphics, Madison C o . , Mont............................... .. pie ce 2. Ph o to m ic r o g ra p h s ..................................................................................................... 24 3. P h o to m ic r o g ra p h s ............................................................................................ ...... . 25 4. Ph o to m ic r o g ra p h s ..................................................................................................... 36 5. P h o to m ic r o g ra p h s........... .......................................................... 27 6. Ph ot o m ic r o g ra p h s ..................................................................................................... 28 7. Photomicrographs.................................... "................................................................ 29 8. Ph ot o m ic r o g ra p h s .......................... 30 5 ABSTRACT K yanite and s i l l i m a n i t e occur in th e Precambrian s c h i s t s , g n e i s s e s , and p e g m a t it e s of the Cherry Creek ,(Archean ?) metamorphics south of Ennis, Montana. The metamorphic rocks were formed as a r e s u l t of the r e g i o n a l metamorphism of a t h i c k sequence of sedimentary r o c k s —mostly li m e s to n e s and s h a l e s . The s t r a t i g r a p h i c s e c t i o n of metamorphic rocks i s about 3,050 f e e t t h i c k and c o n s i s t s of i n t e r l a m i n a t e d dolo m it e marble, d o l o m i t i c marble, k y a n i t e - b e a r i n g s c h i s t s and g n e i s s e s , amphi­ b o l i t e s , and g n e i s s e s and s c h i s t s , u n d iv id e d . The rocks a r e t i g h t l y fo l d e d and a l a r g e i s o c l i n a l s y n c l i n e , which plunges s t e e p l y to the e a s t , r e p e a t s th e s e c t i o n in the map a r e a . Three type s of p e g m a t it e s occur in th e a re a and each ty pe d i s p l a y s a p r e f e r e n c e f o r c e r t a i n ho s t r o c k s : k y a n i t e pe gm at ite s occur in k y a n i t e s c h i s t or g n e i s s ; f e l d s p a r - q u a r t z - m u s c o v i t e - t o u r m a l i n e pe gmatites occur in marble and in k y a n i t e s c h i s t ; and f e l d s p a r - q u a r t z peg mat ites a re most prominent in q u a r t z - f e l d s p a r g n e i s s . The k y a n i t e p e g m a t it e s a p p a r e n t l y formed by p r o c e s s e s of metamorphic d i f f e r e n t i a t i o n , in which aluminum ions were added t o a q u a r t z segreg a­ t i o n and p r oba bly grew on k y a n i t e n u c l e i a l r e a d y p r e s e n t in th e q u a r t z . The i n v e r s i o n , s i l l i m a n i t e r e p l a c i n g k y a n i t e , occurs r e p e a t e d l y in t h e k y a n i t e pe g m a t it e s and i s prob ab ly due to in c r e a s e d t e m p e ra t u re s subsequent t o the f or m at io n of the k y a n i t e . According to e q u i l i b r i u m diagrams by Miyas hiro (1949) and Hietanen (1956), p e g m a t i t i c ky a n it e forms a t low te m p e r a t u r e s and p r e s s u r e s and i n v e r t s to a n d a l u s i t e at h i g h e r t e m p e r a t u r e s and i s s t a b l e , a t h i g h e r p r e s s u r e s . The f a c t t h a t in t h e s e p e g m a t i t e s , s i l l i m a n i t e was produced w it h in c r e a s e d t e m p e r a t u r e s , s u g g e s ts t h a t k y a n i t e p o s s e s s e s no low TP s t a b i l i t y f i e l d . 6 INTRODUCTION AND GENERAL GEOLOGY The aluminum s i l i c a t e m i n e r a l s , k y a n i t e and s i l l i m a n i t e , occur in s c h i s t s , g n e i s s e s and pe g m at it es on th e n o r t h e a s t f l a n k of th e G rave ll y Range, Montana, about 12 m ile s south of Ennis, Montana, and 5 miles no rt h of and continuous w it h th e type a re a of th e Cherry Creek metamorphics ( P e a l e , 1896) ,(See F ig u r e I) . Precambrian rocks in th e a re a i n c l u d e : dolom ite -m arble and dolo m it i c marble, s c h i s t s , g n e i s s e s , a m p h i b o l i t e s , and p e g m a t i t e s . R e l i e f i s moderate and outc rops of Precambrian rocks a re l i m i t e d ; th e marble l a y e r s u s u a l l y form low r i d g e s , and the s c h i s t s commonly are covered by s o i l or a llu vi um . To th e west the Precambrian rocks d i s a p p e a r under P a l e o z o i c rocks and d i s p l a y a marked nonconformity with th e Middle Cambrian Fl a th e a d f o r m a ti o n , o l d e s t of th e P a le o z o i c rocks in th e r e g i o n . To th e e a s t t h e y are covered by l a r g e T e r t i a r y t r a v e r t i n e d e p o s i t s and by alluvium of the Madison R iv e r , Evidence of T e r t i a r y hot s pr in g a c t i v i t y is widesp read in t h e a r e a and t h e presence of p y r o l u s i t e in t h e hot spring d e p o s i t s has encouraged some p r o s p e c t i n g f o r t h a t m i n e r a l . PURPOSE The purpose of t h i s i n v e s t i g a t i o n i s twofold: (I ) to determine in some d e t a i l the l i t h o l o g i c ty p e s, t h e i r e x t e n t , and th e s t r u c t u r e of a p a r t of th e Cherry Creek metpmorphics, and (2) t o det ermi ne the o r i g i n of th e k y a n i t e p e g m a t i t e s . 7 \ '\ W O After U.S.G.S. I I 2 I I 3 4 S CALE S ' I i % IO MI LES -------------- i Areol Mop Showing Locotion of Mop Areo in This Report ond Type Area of Cherry Creek Metamorphics. Map Area in This Report W.OT.,1959 Type Area of Cherry Creek FIGURE I 8 ACKNOWLEDGMENTS The w r i t e r wishes t o acknowledge th e a s s i s t a n c e of s e v e r a l i n d i v i d u a l s as w e ll as a l l members of th e s t a f f of th e Department of Geography and Geology, Montana S t a t e C o ll e g e . Dr. Robert F o s t e r was c o n s u l t e d f r e ­ q u e n t l y d u ri n g a l l phases of th e i n v e s t i g a t i o n and c o n t r i b u t e d numerous v a l u a b l e s u g g e s t i o n s ; Dr. TVilliam McMannis v i s i t e d the a r e a and was h e l p f u l in the i n t e r p r e t a t i o n of s t r u c t u r e s ; Dr. N ic hola s Helburn made s c h o l a r s h i p funds a v a i l a b l e f o r c e r t a i n phases of the i n v e s t i g a t i o n ; Mr. Dan A n d r e tt a a s s i s t e d capably in the f i e l d work; the s t a f f of the L i b ra r y of Montana S t a t e College ob ta in e d many p u b l i c a t i o n s which were not immediately a v a i l a b l e ; Mr. Sumner Gerard provide d f i n a n c i a l su pport f o r t h i n s e c t i o n s ; and Mrs. I r e n e Kukkola and Mrs. N i t a Nickerson typed the manuscript. F i e l d equipment was s u p p li e d by th e Department of Geography and Geology, Montana S t a t e C o ll e g e. FIELD WORK F i e l d work was c a r r i e d out over a p e r i o d of about t h r e e months duri ng th e summer and f a l l of 1958. Mapping was done w it h pla ne t a b l e and a l i d a d e , and Brunton, d i r e c t l y on a to p o g r a p h ic base map with a s c a l e of I inch eq ual s 300 f e e t . The ba se map was developed by e n l a r g i n g a p o r t i o n of the U. S. Ge olog ical Survey, Varney and Cameron q u a d r a n g l e s . Air photos were used as an aid in i n t e r ­ p r e t a t i o n and in th e l o c a t i o n of s i g n i f i c a n t outc ro p s . SUMMARY OF PREVIOUS WORK Most w r i t e r s agree t h a t th e s e rocks had a sedimentary o r i g i n ; however, 9 views d i f f e r on the p r o c e s s e s involved in t h e i r metamorphism. P e a l e (1896, p.2) named t h e Cherry Creek rocks and a s s ig n e d them to Algonkian age. They were d e s c r i b e d as c o n s i s t i n g of "a s e r i e s of marbles or c r y s t a l l i n e li m e s to n e s and i n t e r l a m i n a t e d mica s c h i s t s , q u a r t z i t e s , and g n e i s s e s . . . They are a l l h i g h l y i n c l i n e d and are p e r f e c t l y conformable to one a n o th e r , occupying an a r e a of 30 to 40 square m ile s . . . They are fo ld e d , but th e f o l d s are somewhat obscure so t h a t i t i s im p o s si b le to e s t i m a t e a c c u r a t e l y the t o t a l t h i c k n e s s , but i t i s c e r t a i n l y not l e s s than s e v e r a l thousand f e e t . Between Cherry Creek and Wigwam Creek, on the west s id e of th e Madison Val ley , the unchanged beds of th e Cambrian r e s t upon the upturned edges of t h i s g r o u p . " Runner and Thomas (1928, p. 202-203) recog nize d a sedimentary o r i g i n f o r th e rocks of th e Cherry Creek and a t t r i b u t e d the a l t e r a t i o n s l a r g e l y to " t h e e f f e c t s of i n t r u s i v e g r a n i t e s and s i l e x i t e . " "Dynamic metamorphism i s regarded as having been of minor im p o r ta n c e ." " S e l e c t i v e metamorphism i s w e l l d i s p l a y e d . - Highly a l t e r e d sediments l i e in te rb e d d e d with c r y s t a l ­ l i n e l im e s to n e s , showing l i t t l e or no chemical ch an ges ." R a b b i t t (1946, p. 124) noted, "The t h i n banding, the concordancy w it h o t h e r rock u n i t s in th e s e c t i o n , and th e composition le ad me t o b e l i e v e t h a t t h e g n e i s s e s a re metamor­ phosed s h a l e s and s a n d s to n e s; th e metamorphism being e f f e c t e d by the soaking of th e sediments w it h hot s o l u t i o n s . I t i s pro b a b le t h a t th e re was not much movement of m a t e r i a l . " He l a t e r noted (p. 125), "The a m p h ib o li te s are concordant w it h th e g n e i s s e s , d o lo m ite s and p h y l l i t e s w it h which they are in c o n t a c t . No c r o s s c u t t i n g has been observed . . . . The a m p h ib o li te s of the a r e a seem to have been o r i g i n a l l y sediments which have been th oro u g h l y r e c r y s t a l l i z e d w i t h o u t the i n t r o d u c t i o n of much m a t e r i a l ." Reid (1957, p , 20) in propos ing a sedimentary o r i g i n f o r the Cherry Creek metamorphics s t a t e d , "The complex i n t e r g r a d a t i o n a l n a tu re of th e metamorphic r o c k s , the wide v a r i e t y of rock types p r e s e n t and t h e i r complex s t r u c t u r e seem, to the 10 p r e s e n t w r i t e r , to r e q u i r e the pro p o s a l of a sedimentary o r i g i n f o r both th e Pony and Cherry Creek metamorphic r o c k s . E a r l i e r works, of course, have p o s t u l a t e d t h a t th e Cherry Creek i s of sedimentary o r i g i n In h i s study of th e k y a n i t e pe g m a t it e s in the Cherry Creek area, H e i n r i c h (1948, p. 14) no te d, "The c o a r s e s t k y a n i t e and t h e r i c h e s t c o n c e n t r a t i o n s occur in the unmeta­ morphosed p e g m a t i t e s . " He concluded, "Most of the k y a n i t e in' th e g n e i s s i s g e n e t i c a l l y r e l a t e d to the i n t r u ­ s io n s of the p e g m a t i t e s . The for matio n of k y a n i t e does not appear t o r e ­ p r e s e n t mere r e c r y s t a l l i z a t i o n of m a t e r i a l s a l r e a d y p r e s e n t in th e gn e is s a t the time of p e g m a t i t i c i n t r u s i o n , bu t pro ba bly in volv e s t h e a d d i t i o n of aluminum to the w a ll rock by p e g m a t i t i c s o l u t i o n s . " Thus, most workers agree on the sedim enta ry o r i g i n of the Cherry Creek r o c k s ; in view of th e n a t u r e of t h e s e rocks i t could h a r d l y be o t h e r ­ wise. However, t h e r e i s no g e n e r a l agreement on p r o c e s s e s involved in t h e i r metamorphism. One th e o r y a s c r i b e s the metamorphism t o a r e c o n s t i t u ­ t i o n of m a t e r i a l s at hand w hi le th e o t h e r n e c e s s i t a t e s t h e i n t r o d u c t i o n of new m a t e r i a l s . F i e l d evidence does not su pport a t h e o r y f o r the i n t r o d u c t i o n of lar,ge amounts of m a t e r i a l and t h e rocks in th e a r e a could p r ob a bly have been formed by th e r e c r y s t a l l i z a t i o n of m a t e r i a l s p r e s e n t in t h e sedimentary rocks w it h the a d d i t i o n of l i t t l e or no new m a t e r i a l . DESCRIPTION OF ROCKS Dolomite-Marble and Dolomi tic Marble Dolomite-marble and d o l b m i t i c marble are the most abundant rocks in t h e map a r e a . They are very c o a r s e l y c r y s t a l l i n e and, on th e f r e s h s u r f a c e , are w h it e , grey, cream,, pink or v i o l e t in c o l o r . The weathe red outcrop ■ .11 i s u s u a l l y tan or brown. The marble i s r e s i s t a n t to w e a th e ri n g and forms th e r i d g e s of low hills. I t s t r i k e s e a s t e r l y and has a n e a r l y v e r t i c a l d i p . I t is l o c a l l y s i l i c e o u s and c o n t a i n s boudins of q u a r t z i t e and w o l l a s t o n i t e q u a r t z - d o l o m i t e ro c k . Amphibolite pods and pe g m a t it e s occur l o c a l l y in th e m a r b l e . At the Rim Rock p e g m at it e of S t o l l (1950, p . ' 5 9 ) ( P l a t e I) a l a r g e m i c r o c l i n e q u a r t z - t o u r m a l i n e - m u s c o v i t e p eg ma ti te i s a s s o c i a t e d with a small amphi­ b o l i t e pod and both a re conformable t o th e f o l i a t i o n of th e host ro^ek. A marble specimen taken from t h i s l o c a l i t y was found to c o n t a i n : 93 p e r c e n t d o l o m i t e , 6 p e r c e n t c a l c i t e , and I p e r c e n t o t h e r m i n e r a l s . Kvanite S c h i s t s , Kyanite Gneiss and A s s oc ia te d Rocks These rocks are l a r g e l y k y a n i t e - b i o t i t e - g a r n e t s c h i s t and k y a n it e b io tite-feld sp ar-q u art'z gneiss. They c o n ta i n va ri ou s amounts, of k y a n i t e . Mapped w it h t h e s e rocks a r e some g n e i s s e s , amphibolites, and pe gmatites which are not d i f f e r e n t i a t e d due to in a d eq u a te exposures or small s i z e . . In out crops of k y a n i t e g n e i s s , k y a n i t e bla des stand out in r e l i e f and generally exhibit l i t t l e , or no, l i n e a t i o n . Kyanite b l a d e s in the s c h i s t have a s t r o n g to weak l i n e a t i o n and t h e s c h i s t p o s se ss e s moderate f o l i ­ ation. Gneiss. Near th e s outhe rn l i m i t of the, map a r e a are a group of g n e i s s e s , s c h i s t s , p e g m a t i t e s , a m p h i b o l i t e s , and i r o n formation (a t h i n l a y e r , a ppr ox im a te ly 10 f e e t t h i c k , Pe rs ona l Communication, Dan Robertspri', 1958) 12 which a re no t d i f f e r e n t i a t e d by t h i s w r i t e r . The f o l i a t i o n of th e s e rocks i s p a r a l l e l to th e f o l i a t i o n of o t h e r rocks in the a r e a . L i t h o l o g i c a l l y , the rocks are q u a r t z - b i o t i t e - m u s c o v i t e - f e l d s p a r g n e i s s , q u a r t z - b i o t i t e s c h i s t s , a m p h i b o l i t e s , and a m ph ibo le -ga rnet g n e i s s . They c o n t a i n l a r g e t a b u l a r p e g m a t it e bodie s which a re composed of f e l d s p a r (mos tly mi c r o c l i n e ) and q u a r t z , and are concordant w it h th e f o l i a t i o n of th e h o s t rock, e xce pt f o r a few small p e g m a t it e s which cut the l a r g e peg­ m atites. S t r a t i g r a p h y of the Metamorphic Rocks The s t r a t i g r a p h y of t h e s e Precambrian rocks i s most c onv e n ie n tl y ex­ p r e s s e d in terms of broad u n i t s , co rre sp ond in g to the u n i t s as de fi n e d in t h e legend on the map ( P l a t e I ) . S t r u c t u r a l evidence must be employed in th e d e t e r m i n a t i o n of the r e l a ­ t i v e ages of the rock u n i t s si nce t h e r e i s no g e ner al agreement among g e o l o ­ g i s t s as t o which u n i t s are o l d e s t or y o u n g e s t , or to j u s t how many u n i t s e x i s t (complex f o l d i n g has caused r e p e t i t i o n of u n i t s ) . » The s t r u c t u r a l evidence (see S t r u c t u r e . p . 40 to 45) i n d i c a t e s t h a t th e g n e i s s e s and s c h i s t s a t the s outhe rn l i m i t of the map a r e a are the oJ.des t of th e Precambrian rocks in the a r e a . Furthermore, t h e r e i s evidence f o r the pr es enc e of an i s o c l i n a l f o l d (see Figure 5 ) . The c a l c u l a t e d s t r a t i g r a p h y i s measured along the l i n e Af-A (see P l a t p i I) from t h e southernmost c o n ta c t of the k y a n i t e - b e a r i n g ro c k s w ith the g n e i s s e s and s c h i s t s , t o the c e n t e r of th e u n i t in which th e mica p r o s p e c t (P r o s p e c t No. 2) occurs ( t h i s u n i t appea rs t o be the core of th e i s o c l i n a l 13 f o l d , see F ig ure 5 ) . The rock u n i t s are l i s t e d in o r d e r of t h e i r r e l a t i v e ages w it h th e o l d e s t rocks a t the bottom of the l i s t : Rock Type Thickness Kyanite-bearing s c h i s t , s c h is ts , g n e i s s e s , and a m p h ib o li te s ........................... 430 f e e t Dolomitp-marble and d o lo m it i c marble w it h some q u a r t z i t e , w o ll a s t o r i i t e rock and a m p h i b o l i t e . Contains many b o u d i n s .......................... ' ............................ 360 f e e t G ne iss es, s c h i s t s , and marble, un div id e d. ............................................................. Dolomite-marble and d o l o m i t i c marble . . K y a n i t e - b e a r i n g s c h i s t ....................................... Dolomite-marble and d o l o m i t i c marble . . Kyanite-bearing s c h is ts , s c h is ts , g n e i s s e s , and a m p h ib o li te s 210 f e e t . 100 f e e t 100 f e e t .1180 f e e t . ......... 670 f e e t T o t al Thickness of S e c ti o n 3050 f e e t Local t h i c k e n i n g and t h i n n i n g i s common in th e s e r o c k s , so the t h i c k ­ ne ss of any u n i t i s no t n e c e s s a r i l y c o r r e l a t i v e with th e t h i c k n e s s of the same u n i t in a n o th er l o c a l i t y . PETROLOGY OF THE PEGMATITES i The map a re a i s c h a r a c t e r i z e d by t h e occurrence of many pe gmatites which vary w id e ly in composition, s i z e , and shape. B a s i s f o r D iv is io n of Pegmatites The pe g m at it es p o s s e s s c e r t a i n c h a r a c t e r i s t i c s which are unique and which, when p r o p e r l y i n t e r p r e t e d , may p r o v id e a clue to th e pegmatite origin. These c h a r a c t e r i s t i c s a r e : (I ) th e mineralogy of the pe gm at ite , 14 (2) the type of p e g m at it e h o s t ro ck , (3) t h e c o n ta c t r e l a t i o n s h i p between t h e pe g m a t it e and i t s ho s t rock, and (4) th e shape of the p e gm at ite body. Although much u s e f u l i n fo r m a t io n may be gained from a study of the p e g m a t i t e , the d e t e r m i n a t i o n of the c o n t r o l s of pe gm at ite l o c a l i z a t i o n r e ­ quires fu r th e r inform ation. Bamberg (1956, p. 188) in h i s stu dy of the Greenland pe g m a t it e s no te d, nThe l o c a l i z a t i o n of p e g m a t it e s i s ( I ) r e l a t e d to the degre e of re g i o n a l metamorphism in the a r e a . . . (2) determine d by the mechanical p r o p e r t i e s of the h o s t r o c k s , and (3) c o n t r o l l e d by th e c h a r a c t e r of th e t e c t o n i c e v o l u t i o n of th e re g i o n s ( j o i n t s and f a u l t s g e n e r a l l y l o c a l i z e p e g m a t i t e s ) . The l o c a l i z a t i o n of s p e c i a l types of p e g m a t i t e s ( i . e . , c h a r a c t e r i z e d by a c e r t a i n m in e ra l composition; f o r example, g r a p h i t e - b e a r i n g p eg ma ti tes or p e g m a t i t e s w it h d i o p s i d e ) seems t o have been c o n t r o l l e d by a combination of the m in e r a l- c h e m ic a l composition of the ho s t rocks and th e temperature and p r e s s u r e a f f e c t i n g the complex a t th e time of emplacement of the peg­ m atite." Most p e g m a t it e s in th e a r e a can be pla c e d i n t o one of t h r e e groups, each group being somfewhat l i m i t e d in i t s oc currence t o a p a r t i c u l a r kind of ho s t ro c k . The three, groups may be b r o a d l y regarded a s ; (I) kyanite- q u a r t z p e g m at it e which commonly occur in k y a n i t e s c h i s t and k y a n i t e g n e i s s , (2) f e l d s p a r - q u a r t z - m u s c o v i t e - t o u r m a l i n e pe g m at it es which occur in both marble and in k y a n i t e s c h i s t and k y a n i t e g n e i s s , and (3) f e l d s p a r - q u a r t z p e g m a t i t e s which are most prominent in the gn e is s ne ar th e s outhe rn l i m i t of th e map a r e a . Kyanite P e g m a ti te s Kyanite pe g m a t it e s are r e s t r i c t e d in occurrence to h o s t rocks which c o n ta i n k y a n i t e . The p e g m at it e bodie s are g e n e r a l l y i r r e g u l a r in shape and have at l e a s t a p a r t of the p eg ma ti te body concordant w i t h th e f o l i a t i o n of the ho s t rock (F ig ure 2 ) . ■ 15 Sc a le I F o l i a t i o n of Kyanite S c h i s t Large Kyanite Blades Quartz Figu re 2 Kyanite b e a r i n g p eg ma ti te in Precambrian k y a n it e s c h i s t , lo c a t e d a t p r o s p e c t No. I (See P l a t e I ) . Pegma tite body is amoeba-I ike in shape and i s p a r t l y concordant and p a r t l y d i s c o r d a n t w it h host r o c k . C o n c e n tr a ti o n s of l a r g e k y a n i t e b la d e s occur l o c a l l y n e a r the margins of the pegmatite body. 16 The l a r g e s t c o n c e n t r a t i o n of the k y a n i t e pe gm at ite s occurs in the n o r t h c e n t r a l p a r t of the map a r e a . Local t h i c k e n i n g of the s c h i s t in t h i s l o ­ c a l i t y and th e l i n e a t i o n of minor f o l d axes sugg est s t h e p resen ce of an " a n t ic li n a l" fold. Thus, th e l o c a l i z a t i o n of th e s e k y a n i t e p eg ma ti tes may be p a r t l y r e l a t e d t o the f o l d . H e in r ic h (1948, p. 15) noted c o n c e n t r a t i o n s of k y a n i t e " i n a u re o le s around the q u a r t z - r i c h p e g m a t it e s " and s t a t e d , "Outward from th e pegmatite c o n t a c t s the grade d im in is h e s r a p i d l y . " This i s i n c o n s i s t e n t w ith ob s er - v a t i o n s made by t h i s w r i t e r because t h e q u a n t i t y of the k y a n i t e in any given l a y e r may i n c r e a s e , d e c r e a s e , or remain c o n s t a n t — independent of the p r o x i ­ mity of a p e g m a t i t e . Kyanite b l a d e s in t h e s c h i s t and. g n e i s s are g e n e r a l l y l e s s than one inch in l e n g t h , bu t many are over two inc hes in l e n g t h . The s i z e of k y a n i t e b l a d e s in t h e s c h i s t does not n e c e s s a r i l y i n c r e a s e in th e v i c i n i t y of a p e g m a t i t e ; b u t c e r t a i n l y th e l a r g e s t k y a n i t e b la d es occur in th e p e g m a t i t e s . The S i l l i m a n i t e Group of M i n e r a l s . - Kyanite, s i l l i m a n i t e , and an dal us i t e are polymorphs of th e compound AlgSiOg. A n d a lu s it e and s i l l i m a n i t e c r y s t a l l i z e in t h e orthorhombic system; k y a n i t e in t h e t r i c l i n i c system. They a l l belong to the c l a s s , n e s o s i l i c a t e s , (Winchell and Winchell, 1951, pp. 241, 250-258). The s i l i c o n - o x y g e n t e t r a h e d r a in n e s o s i l i c a t e s e x i s t s as s e p a r a t e e n t i t i e s , (Mason 1958, p. 77 ), i . e . , the oxygen atoms in the SiO^ t e t r a h e d r a are not shared w it h o t h e r t e t r a h e d r a . A ll t h r e e m i n e r a l s d i s s o c i a t e to form m u l l i t e (Al&SigOig), plu s l i q u i d or g l a s s , when h e a te d t o high te m p e r a t u r e s . Sillim an ite in v e rts t o 'm ullite 17 a t about 1545° C. and k y a n i t e and a n d a l u s i t e i n v e r t a t about 1300° C . , (Winchell and W i n c h e l l , 1951, pp. 520, 521 and 528). S t a b i l i t y R e l a t i o n s of the S i l l i m a n i t e Group. - The s t a b i l i t y r e l a t i o n s of the aluminum s i l i c a t e m in e r a ls are not w e ll known because the e n v i r o n ­ ment in which the m i n e r a l s are formed i s d i f f i c u l t to reproduce in the laboratory. Given the p ro p e r m a t e r i a l s w it h which to form the aluminum s i l i c a t e m i n e r a l s , t h r e e v a r i a b l e s i n f l u e n c e t h e i r c r y s t a l l i z a t i o n — temper­ a t u r e , p r e s s u r e ( p l u s s t r e s s ? ) , and the w a te r vapor p r e s s u r e in the system. I t i s the q u a n t i t a t i v e d e t e r m i n a t i o n of t h e s e th re e v a r i a b l e s which w i l l make p o s s i b l e the r e c o g n i t i o n of the s t a b i l i t y f i e l d s of th e th r e e alum­ inum s i l i c a t e m i n e r a l s . P e t r o g r a p h i c evidenc e and p e t r o l o g i c evidence are used to e s t i m a t e th e s t a b i l i t y r e l a t i o n s o f th e aluminum s i l i c a t e m in e ra ls and are summar­ iz ed in an e q u i l i b r i u m diagram (see F ig ur e 3 ) . Kyanite Sillim anite A n d a lu si t e Mullite Temperature Fig ur e 3. Diagram showing p o s s i b l e s t a b i l i t y r e l a t i o n s of the aluminum s i l i c a t e m in e r a ls ( a f t e r Miyashiro, 1949). Hietanen (1956) b e l i e v e s the t r i p l e p o i n t to be about 400°. 16 Raraberg (1952, p. 7 4 ) ( a f t e r Yoder, 1952) i n d i c a t e d ( i n e q u i l i b r i u m diagrams) t h a t a t 15,000 ps i w a te r vapor p r e s s u r e , the t r i p l e p o i n t is about 660°, as shown in Fig ur e 3A. Sillim anite Andalusite Kyanite _______________________ 430° 660° Temperature 990° Fi g u r e 3A. Diagram showing s t a b i l i t y r e l a t i o n s h i p s of k y a n i t e , s i l l i m a n i t e , and a n d a l u s i t e under 15,000 ps i w a te r p r e s s u r e . S i l l i m a n i t e i s u s u a l l y con sid ered t o be the h i g h e s t temperature form of the AlgSiO^ polymorphs. Mason (1956, p. 244) has suggested t h a t because s i l l i m a n i t e i s t h e commonest of the t h r e e m i n e r a l s , i t may possess the la rg e st s t a b i l i t y f i e l d . This p o i n t is perhaps c l a r i f i e d by Turner and Verhoogen (1951, p. 412): " I t i s h ig h l y pro bab le t h a t s i l l i m a n i t e , u s u a l l y assumed t o be s t a b l e only a t high te m p e r a t u r e s , i s a c t u a l l y th e s t a b l e form of AlgSiOg over a much b ro a d e r range, from normal s u r f a c e te m pe ra t ure s almost to the m e l t ­ ing p o i n t a t atmos phe ri c p r e s s u r e . " They a l s o su gge st t h a t some high te mp erat ure r e a c t i o n s , e . g . , the formation of s i l l i m a n i t e a t extreme t e m p e r a t u r e s , may be i r r e v e r s i b l e : " . . . s i l l i m a n i t e , formed only a t maximum metamorphic t e m p e r a t u r e s , at high p r e s s u r e s , or under c a t a l y t i c i n f l u e n c e of deformatio n or pore f l u i d s , would remain s t a b l e and show no tendency to i n v e r t to any oth e r form d u ri n g subsequent c o o l i n g . " A n d a l u s i t e a p p a r e n t l y i s s t a b l e a t high te m pe ratu res and low p r e s s u r e s (Ramberg, 1952, p. 45) and, in p a r t i c u l a r , i t does not form in rocks which 19 are S t r e s s e d ( B a r t h , 1951, p . 256) (Mason, 1958, p . 244) ( H i e t a n e n ,, 1956, p . 26) . B arth (1951, p. 256) n o te s " . ; . t h a t th e l a t t i c e of andalu- s i t e i s h i g h l y s u s c e p t i b l e t o , and e a s i l y d e s tr o y e d by s t r e s s f o r c e s . " "Writers g e n e r a l l y agree t h a t k y a n i t e develops in aluminous rocks which have undergone metamorphism a t high p r e s s u r e s and i n t e r m e d i a t e tem­ p e r a t u r e s (Mason, 1958, p. 244) (H ie ta nen , 1956, p. 26) (Griggs and Kennedy, 1956). Some w r i t e r s p r e f e r to i n c l u d e s t r e s s as a c o n t r i b u t i n g f a c t o r in the fo rm ati on of k y a n i t e , mostjly because k y a n i t e has a very high d e n s i t y (B a rt h , 1951, p. 256) (Hi e ta nen , 1956, p. 26). Barth (1951, p . 257) n o te s t h a t " a l t h o u g h s t r e s s may f a v o r the development of k y a n i t e , i t i s not n e c e s s a r y ; k y a n i t e can grow in a p e g m a t it e where n-o s t r e s s seems t o have been p r e s e n t . " M i y a s h i r o (1949a, a b s . ) c r i t i c i z e s t h e id e a t h a t s t r e s s i s n e c e s s a ry foy the fo rm ati on of c e r t a i n m i n e r a l s and c o n s id e rs te m p e r a t u r e , hydro­ s t a t i c p r e s s u r e , and c o n c e n t r a t i o n of the components as " t h e only e s s e n t i a l f a c t o r s c o n t r o l l i n g metamorphism." M u l l i t e i s no t common as a n a t u r a l I y - o c c u r r i n g m i n e r a l , bu t i t is produced a r t i f i c i a l l y . Kennedy (1955) has found t h a t a s o l i d s o l u t i o n e x i s t s between m u l l i t e and s i l l i m a n i t e a t t e m p e r a t u r e s of 550°-6000 and 400 b a r s t o 3000 bars (5000 p s i t o 43,500 p s i ) w a t e r p r e s s u r e . M u l l i t e i s formed a t the low p r e s s u r e s ; s i I limarrire a t the high p r e s s u r e s . ! The s i g n i f i c a n c e of the s t a b i l i t y r e l a t i o n s of the s i l l i m a n i t e group and t h e i r b e a r i n g on the k y a n i t e p e g m a t it e s in the map a r e a i s d i s c u s s e d below under "O ri g in of Kyanite P e g m a t i t e s . " , 20 Mineralogy of th e K yanite P e g m a t i t e s . - Quartz i s t h e most abundant m in e ra l in t h e kyani t e - b e a r i n g p e g m a t i t e s . The p eg ma ti te a t P r o s p e c t , No. I ( P l a t e I ) in th e n o r t h c e n t r a l p a r t of S e c ti o n 6 was mapped in some d e t a i l and c o n c e n t r a t i o n s of k y a n i t e are noted on the map of the peg mat ite (F ig u re 2 ) . C a l c u l a t i o n s based on s u r f a c e o b s e r v a t i o n s i n d i c a t e t h a t k y a n i t e and s i l l i m a n i t e comprise about o n e - h a l f p e r c e n t t o 1% p e r c e n t of th e volume of the p e g m a t i t e . is quartz. Approximately 98 p e r c e n t of th e pegmatite In th e a r e a s of k y a n i t e c o n c e n t r a t i o n q u a r t z makes up about 45 p e r c e n t of the t o t a l rock; k y a n i t e and s i l l i m a n i t e , 35 p e r c e n t ; s e r i c i t e , 15 p e r c e n t ; and t h e remaining 5 p e r c e n t may c o n s i s t of any of the fo ll ow ­ ing m i n e r a l s : p l a g i o c l a s e , m u s c o v i t e , g a r n e t , to u rm al in e , b i o t i t e , g r a p h i t e , and a p a t i t e . Other k y a n i t e p e g m a t i t e s in the a r e a c onta in about th e same m ine ral assemblage, but p r o p o r t i o n s vary in d i f f e r e n t p e g m a t i t e s . D e s c r i p t i o n of Kyanite P e g m a t i t e s . - Kyanite pe g m a t it e s d i s p l a y many k y a n i t e b la d e s up t o t h r e e inch es in l e n g t h and s e v e r a l are n e a r l y e i g h t inches. At th e southwest c orn e r of the p e gm at ite at P r o s p e c t No. I (F ig ur e 2) are a group of l a r g e i n t e r s e c t i n g bla des up t o te n inches long which are th e l a r g e s t seen in th e a r e a . I t i s i n t e r e s t i n g to note t h a t in t h i s p e g m at it e a l l c o n c e n t r a t i o n s of k y a n i t e occur n e a r th e margin of th e p e gm at ite body, and b la d e s of k y a n i t e are not o r i e n t e d and g e n e r a l l y i n te r s e c t other blades. The b la d es i n t h e pe gmatite are t r a n s p a r e n t , w h i t e or bl ue in c o l o r , and s i n g l e b l a d e s may e x h i b i t v a r i a t i o n s of a l l three colors. A b r i l l i a n t b lu e , which i s noted in some c r y s t a l s , i s g e n e r a l l y r e s t r i c t e d t o the c e n t r a l p a r t of the b l a d e . S i l l i m a n i t e occurs ( 21 as s m al l, w h it e , f e l t e d m a s s e s . At P r o s p e c t No. 5 ( P l a t e I) massive w h it e and brown s i l l i m a n i t e occurs in a smal l, i r r e g u l a r pod a s s o c i a t e d w it h a k y a n it e p e g m a t i t e . The c o n t a c t s are obs cur e, but the pod appears t o be about ten f e e t long and t h r e e f e e t wide and i s exposed in a small draw a t t h e s i t e . A b u l l d o z e r p i t has ex­ posed a s p e c t a c u l a r k y a n i t e - q u a r t z - s i I l i m a n i t e peg mat ite a t t h i s l o c a t i o n . Some of the q u a r t z in t h i s p e gm at ite b e a r s deep s t r i a t i o n s where i t has been in c o n t a c t w it h k y a n i t e b l a d e s . The s t r i a t i o n s a p p a r e n t l y were imposed upon th e q u a r t z by k y a n i t e . Small g a r n e t s , s p e c i e s p y r a l s p i t e , (a mixture of a lm a n d it e and s p e s s a r - t i t e as d e f i n e d by Winchell & W i n c h e l l , 1951, p . 483) occur in the s c h i s t and in th e pe g m at it es and commonly occur as i n c l u s i o n s in k y a n i t e b l a d e s . G r a p h it e i s a l s o an abundant (up t o one p e r c e n t ) mine ral i n th e s c h i s t and occurs commonly in the pe g m at it es and as i n c l u s i o n s in k y a n i t e and s i l l i ­ m a n it e . S i l v e r y - w h i t e s e r i c i t e occurs along the cleavage p l a n e s of kyan ite and appea rs to r e p l a c e k y a n i t e . Massive, yellow s e r i c i t e occurs in some of th e pe g m a t it e s and r e p l a c e s k y a n i t e , Quartz, p l a g i o c l a s e , and b i o t i t e . B i o t i t e , which i s a major c o n s t i t u e r i t of the k y a n i t e s c h i s t , i s not common in th e k y a n i t e p e g m a t i t e s . O p ti c a l P r o p e r t i e s of Kyanite and P e i t r o q e n e s i s . - A k y a n i t e bla de, which was ta ke n from th e p eg ma ti te at P r o s p e c t No. 5, was mounted on a s l i d e w it h th e 100 c le av ag e p a r a l l e l to th e pla ne of th e s l i d e . The ex­ t i n c t i o n a ng le , which was determined by t a k i n g the average of s ev e ra l ■22 measurements on t h i s b l a d e , was ZAc = 3 0 . 2 ° . Under t h e microscope s i l l i m a n i t e appea rs in small, f i b r o u s masses and as long, s t r a i g h t , or s l i g h t l y curving ne ed le s p r o j e c t i n g from the fibrous masses. Groups of n e ed le s are g e n e r a l l y p a r a l l e l t o s u b p a r a l l e l . I s o l a t e d s i l l i m a n i t e n e e d l e s occur, b u t are not as common as ne ed le s which p r o j e c t from f i b r o u s s i l l i m a n i t e . Almost w i t h o u t e x c e p t i o n , the s i l l i ­ ma nit e n e e d le s appear t o r e p l a c e q u a r t z or k y a n i t e . Some n e e d le s show an i n c l i n e d e x t i n c t i o n , and t h e s e , presumably, are n e e d le s of k y a n i t e — p o s s i b l y pseudomorphs a f t e r s i l l i m a n i t e . Hietanen (1956, p . 17-19), in h e r stu dy of the aluminum s i l i c a t e s in t h e Boehls B utte quadran gle, Idaho, noted "pseudomorphs of k y a n i t e and a n d a l u s i t e a f t e r s i l l i m a n i t e . " G ra p h it e i s found between the m in e ra l g r a i n s and as i n c l u s i o n s in some of th e m i n e r a l s . Kyanite commonly has g r a p h i t e i n c l u s i o n s and s i l l i ­ ma nit e may have g r a p h i t e w i t h i n the f i b r o u s masses. Graphite generally a pp ear s t o have been fo r c e d i n t o an " o r i e n t a t i o n " by th e c r y s t a l l i z a t i o n f o r c e s of the su rro und in g m i n e r a l s . P l a g i o c l a s e i s n o t abundant in the k y a n i t e pe gm at ite s and when p r e s e n t , i t i s commonly s e r i c i t i z e d . P l a g i o c l a s e from th e pe gmatite at P r o s p e c t No. I has been i d e n t i f i e d as a ndes in e (Ab^y, Angg), as determined by measurement of e x t i n c t i o n angles from the t r a c e of COIQ} in a l b i t e t w in s . S e v e ra l m in e ra l re pla cem en ts occur r e g u l a r l y in the p e gm at ite s and are worth n o t i n g : s i l l i m a n i t e — k y a n i t e ( s i l l i m a n i t e r e p l a c e s kya nit e) (s e e P l a t e ' l l , Fi g u r es I and 2, and P l a t e V I I I , Figu re I ) , sillim anite 23. q u a r t z (see P l a t e ¥■, Fi gu re I ) , s i l l i m a n i t e ->- kya nit e and p l a g i o c l a s e (s e e P l a t e VI, Fig ur e I ) , s i I l i m a n i t e —^-tourmaline (see P l a t e V, Figure I ) , s i l l i m a n i t e and k y a n i t e —^ g a r n e t (see P l a t e IV, Figure I ) , s e r i c i t e - ^ - k y a n i t e and q u a r t z (see P l a t e I I I , Fig ur e I and 2), m u s c o v i t e - ^ k y a n i t e (see P l a t e VII, Figure.,.2), s i l H m a n i t e — b i o t i t e ( i n minor amounts) , k y a n i t e — b i o t i t e ( i n mi nor amounts) and c a l c i t e may r e p l a c e any of the p e t m a t i t e / m i n e r a l s ( c a l c i t e i s a p p a r e n t l y a secondary m i n e r a l ) . '' The or d e r in which th e m in e ra ls formed,may be summarized as follows: q u a r t z and b i o t i t e , k y a n i t e , s i l l i m a n i t 4 , s e r i c i t e and c a l c i t e . I n or d e r to avoid ambiguity, i t should be noted t h a t a lt hough q u a r t z is r e p l a c e d by k y a n i t e and s i l l i m a n i t e , some q u a r t z a p p a r e n t l y formed l a t e r than the aluminum s i l i c a t e m in e ra ls and b e f o r e s e r i c i t e . Hence, th e re i s p ro b a b ly e a r ly - f o r m e d q u a r t z and l a t e - f o r m e d q u a r t z in t h e p e g m a t i t e s . 24 P la te F ig u r e I . Large k y a n i t e bla de being r e p l a c e d by s i l l i m a n i t e . Specimen taken from ky a n it e p e gm at ite a t p r o s p e c t No. I . Crossed n i c o l s , 67X. K = k y a n i t e ; Q = quartz; S = s illim a n ite . F ig ure 2. S i l l i m a n i t e r e p l a c i n g k y a n i t e and q u a r t z . Specimen from p eg ma ti te a t p r o s p e c t No. I . Crossed n i c o l s , 67X. K = k y a n i t e ; S = s i l l i m a n i t e ; Q = q u a r t z . PHOTOMICROGRAPHS II 25 P la te Fi gu re I . S e r i c i t e with g r a p h i t e i n c l u s i o n s . Some k y a n i t e being r e p l a c e d by s e r i c i t e . Crossed n i c o l s , 67X. K = k y a n i t e ; G = g r a p h i t e ; Q = q u a r t z ; S = s e r i c i t e . Specimen from p eg ma ti te a t p r o s p e c t No. I . F ig ure 2. Kyanite and s e r i c i t e with g r a p h i t e i n c l u ­ s i o n s . S e r i c i t e and k y a n it e being re p la c e d by s e r i c i t e . Crossed n i c o l s , 67X. K = k y a n i t e ; Q = q u a r t z ; G = g r a p h i t e ; S = s e r i c i t e . Specimen from p eg ma ti te at P r o s p e c t No. I PHOTOMICROGRAPHS III 26 P la te F ig u r e I . S i l l i m a n i t e and k y a n i t e r e p l a c i n g g a r n e t . Garnet has q u a r t z i n c l u s i o n s . Crossed n i c o l s 67X. K = kyanite; S = s illim a n ite ; G = garnet; Q = quartz. Specimen from p eg ma ti te a t p r o s p e c t No. I. F ig u r e 2. Quartz r e p l a c i n g p l a g i o c l a s e , k y a n i t e r e ­ p l a c i n g q u a r t z . Crossed n i c o l s , 67X. P = p l a g i o c l a s e ; Q = q u a r t z ; K = k y a n i t e . Specimen from k y a n i t e - q u a r t z g n e i s s n e a r p r o s p e c t No. 7. PHOTOMICROGRAPHS IV 27 P la te F ig u r e I . S i l l i m a n i t e n e e d le s p r o j e c t i n g from f i b r o u s s i l l i m a n i t e and r e p l a c i n g q u a r t z . Crossed n i c o l s , 67X. S = s i l l i m a n i t e ; Q = q u a r t z . Specimen from p e gm at ite n e a r p r o s p e c t No. I . F ig ure 2. S i l l i m a n i t e n e e d le s and f i b r e s r e p l a c i n g to u r m a l i n e . Plane l i g h t , 67X. Specimen from peg­ m a t i t e a t p r o s p e c t No. 5. S = s i l l i m a n i t e ; T = t o u r ­ m a lin e . PHOTOMICROGRAPHS V 2b P la te VI Fi g u r e I . S i l l i m a n i t e r e p l a c i n g k y a n it e and p l a g i o c l a s e . Specimen from p r o s p e c t No. 5. Crossed n i c o l s , 67X. P = p l a g i o c l a s e ; K = k y a n i t e ; S = s i l l i m a n i t e . Fi g u r e 2. Q ua rtz r e p l a c i n g p l a g i o c l a s e , k y a n i t e r e ­ p l a c i n g q u a r t z . Specimen from q u a r t z - k y a n i t e g n e i s s n e a r p r o s p e c t No. 7. P = p l a g i o c l a s e ; K = k y a n i t e ; Q = q u a r t z . Crossed n i c o l s , 67X. PHOTOMICROGRAPHS 136412 29 P la te Fi g u r e I . Large k y a n it e bla de w it h q u a r t z and g r a p h i t e i n c l u s i o n s . Specimen from k y a n it e g n e i s s n e a r p r o s p e c t No. 4 . Crossed n i c o l s , 67X. Q = q u a r t z ; K _ kyanite; G = g rap h ite. Fi g u r e 2. Kyanite blade be in g r e p la c e d by mu s co vi te . Specimen from V e t t e r Mica p r o s p e c t ( p r o s p e c t No. 2 ) . Crossed n i c o l s , 67X. Q = q u a r t z ; K = k y a n i t e ; M = mus cov ite. PHOTOMICROGRAPHS V II 30 Fi g u r e I . S i l l i m a n i t e r e p l a c i n g q u a r t z and k y a n i t e (along edge of b l a d e ) . Specimen from k y a n i t e peg­ m a t i t e a t p r o s p e c t No. I . Crossed n i c o l s , 67X. S = s i l l i m a n i t e ; Q = quartz; K = kyanite. Fig ur e 2. T ypi cal f i e l d of k y a n i t e - b i o t i t e s c h i s t . Specimen from p r o s p e c t No. 4 . Plane l i g h t , 67X. B = b i o t i t e ; K = kyanite; Q = quartz; G = grap h ite. PHOTOMICROGRAPHS P la te V III 31 I n v e r s i o n s and S t a b i l i t y R e l a t i o n s of th e Aluminum S i l i c a t e M inerals in t h e Kyanite P e g m a t i t e s . - Kyanite and s i l l i m a n i t e are t h e two aluminum s i l i c a t e m i n e r a l s which occur in the k y a n i t e pe g m a t it e s ; no a n d a l u s i t e was found in th e p e g m a t i t e s . The most common i n v e r s i o n of th e aluminum s i l i c a t e m i n e r a l s in the p e g m a t i t e s i s s i l l i m a n i t e —=^kyanite ( s i l l i m a n i t e r e p l a c i n g k y a n i t e ) , and t h i s i n v e r s i o n i s noted r e p e a t e d l y in t h i n s e c t i o n s (see P l a t e I I , Fi gure s I and 2 ) . The i n v e r s i o n , k y a n i t e - 5- s i l l i m a n i t e , may a l s o e x i s t because t h e r e are a few n e e d l e s which look l i k e s i l l i m a n i t e but have an i n c l i n e d e x t i n c t i o n , and hence, may be k y a n i t e —p o s s i b l y pseudomorphs a f t e r s i l l i ­ m a n it e . The c o n s i s t e n c y w i t h which the i n v e r s i o n , s i l l i m a n i t e —s-kyanite, occurs in th e k y a n i t e pe g m a t it e s may sug ges t t h a t a change i s in order f o r the e q u i l i b r i u m diagram, as shown in F ig u r e 3. The l o c a t i o n of the lower p a r t of th e k y a n i t e s t a b i l i t y f i e l d i s based on the f a c t t h a t ky a n it e may occur in a p e g m a t i t i c environment and presumably c r y s t a l l i z e s in a manner s i m i l a r to t h a t of most m i n e r a l s which are t y p i f i e d by p e g m a t i t i c occur­ rences, i . e . , c r y s t a l l i z a t i o n a t low t e m p e r a t u r e s and p r e s s u r e s . If this were t h e case, i . e . , i f the k y a n i t e in the peg ma ti tes ' c r y s t a l l i z e d at low t e m p e r a t u r e s and p r e s s u r e s , then i t s p o s i t i o n in the e q u i l i b r i u m diagram ( F ig u r e 3) should be a t th e lower end of t h e k y a nite s t a b i l i t y f i e l d . According to the diagram (Figure 3) t h e n , an i n c r e a s e in p r e s s u r e should no t a f f e c t th e k y a n i t e s in ce i t i s s t a b l e a t high p r e s s u r e s . An in c r e a s e in te m p e r a t u r e , however, should cause t h e k y a n i t e t o i n v e r t to a n d a l u s i t e , 32 an in v e r s i o n which did not occur in the pe gm at ite s d i s c u s s e d in t h i s paper. The i n v e r s i o n i s s i l l i m a n i t e —* -k ya nite , as noted above. Thus, the e q u i l i b r i u m diagram would pro bably be more a p p l i c a b l e to the k y a n i t e - s i l l i manite s t a b i l i t y r e l a t i o n s which were observed in the k y a n i t e pe gma ti te s, as d i s c u s s e d in t h i s pap er, i f the diagram were c o n s t r u c t e d as in Figure 3B. Kyanite Sillim anite A n d a lu si t e Temperature Figure 3B. E q u i li b ri u m diagram of the Aluminum s i l i c a t e m i n e r a l s , i l l u s t r a t i n g the p ro p o s a l t h a t k y a n i t e may have no lo w -p r es su r e s t a b i l i t y f i e l d . The p o s i t i o n of a n d a l u s i t e in t h i s e q u i l i b r i u m diagram i s taken from Miyashiro (1949) and s in ce no a n d a l u s i t e was i d e n t i f i e d in th e p e gm at ite s , i t s s t a b i l i t y f i e l d can be given no comment. The evidence o u t l i n e d above s t r o n g l y su gg est s t h a t the k y a n it e in t h e s e pe g m at it es did not form under low TP c o n d i t i o n s , but formed under c o n d i t i o n s of moderate p r e s s u r e s and i n c r e a s i n g t e m p e r a t u r e s . O rig in of the Kyanite P e g m a t i t e s . - Occurrence of rocks composed of q u a r t z and l a r g e k y a n i t e b la d e s ( g e n e r a l l y r e f e r r e d to as k y a n i t e pegma­ t i t e s ) have been d e s c r i b e d many times in t h e l i t e r a t u r e , and t h e i r o r i g i n 33 has been a t t r i b u t e d to v a r i o u s p r o c e s s e s which range from p r e c i p i t a t i o n from a hydrothermal s o l u t i o n to p r o c e s s e s i n v o l v i n g metamorphic d i f f e r e n ­ tiation. The f a c t t h a t k y a n i t e does occur in pe g m at it es has led many w r i t e r s to th e co nc lu si on t h a t k y a n i t e i s s t a b l e a t low PT c o n d i t i o n s as we ll as a t m o d e r a t e - t o - h j g h PT c o n d i t i o n s (see Fi gure 3 ) . S e v e r a l l i n e s of ev ide nc e le ad t o t h e co nclusion t h a t t h e p eg ma ti tes in th e map a r e a of t h i s i n v e s t i g a t i o n formed as a r e s u l t of metamorphic d i f f e r e n t i a t i o n ; p o s s i b l y a combination of p r o c e s s e s i n v o l v i n g re c r y s t a l ­ l i z a t i o n and c o n c r e t i o n ( see Ramberg, 1952, p . 220-226, 237-261). evidence may be summarized as fo l l o w s : The ( I ) k y a n i t e - q u a r t z p eg ma ti tes occur only in ho s t rocks which c on ta in k y a n i t e and q u a r t z ; ( 2 ) k y a n it e ( and s i l l i m a n i t e ) a re commonly shared between the p e gm at ite and host rock; (3) th e aluminum s i l i c a t e m in e r a ls commonly r e p l a c e o t h e r m in e r a ls in t h e p e g m a t i t e s ; (4) t h e r e has been no g r e a t enrichment of AlgOg ( s e e Figure 2 and p . 20), bu t r a t h e r a r e l a t i v e d e p l e t i o n of (Fe, Mg)D and g r e a t e n r i c h ­ ment of .SiO2 w i t h , p e rh a p s , s l i g h t l o c a l enrichment of AlgOg (replacement of, b i o t i t e by k y a n i t e a n d /o r s i l l i m a n i t e r e p r e s e n t s a r e l a t i v e l o c a l en­ richme nt of about 40 p e r c e n t AlgOg); and (5) th e p eg ma ti te bodie s pos se ss no r e g u l a r shape. Qu artz i s commonly r e p l a c e d in t h e p e g m a t it e s by k y a n i t e and s i l l i ­ m a n it e . Thus, i t may be re a s o n a b le t o b e l i e v e t h a t th e f i r s t s ta ge in th e for matio n of th e p e g m a t it e oc curred w it h the development of a q u a r t z segregation, i . e . , th e for matio n of a q u a r t z " v e i n " . The for mation of . / 34 t h e q u a r t z body could be i n i t i a t e d by d i l a t i o n or sh e a r, and. d uri ng i t s growth could pro ba bl y i s o l a t e some of th e m in e r a ls from th e ho s t rock as inclusions. The for matio n of a s e g r e g a t i o n in ro c ks which are in chemical e q u i ­ l i b r i u m w i l l r e s u l t in chemical d i s e q u i l i g r i u m , e . g . , a space which was occupied by rocks w i t h , pe rh a p s, 60 p e r c e n t SiOg, 20 p e r c e n t AlgOg, and 10 p e r c e n t KgO w i l l , a f t e r the s e g r e g a t i o n , be occupied by rocks with nearly 100 p e r c e n t SiOg. In o r d e r t o r e - e s t a b l i s h e q u i l i b r i u m , new mineral a s s o c i a t i o n s are formed in t h e ho s t r o c k s , and c e r t a i n ions ( t h e more mobile ions) may m i g r a t e t o the s i t e of d i s e q u i l i b r i u m and e s t a b l i s h a new assemblage of m i n e r a l s — in t h i s i n s t a n c e , k y a n i t e and q u a r t z , which are s t a b l e under the p r e v a i l i n g PT and chemical c o n d i t i o n s . The development of l a r g e c r y s t a l s in a metamorphic environment is w e l l e x p la i n e d by Ramberg (1952, p . 223): "The p r o b a b i l i t y of nuc le us formation a t given P and T and a given degree of s u p e r s a t u r a t i o n i s determined by th e c h a r a c t e r of the p r e - e x i s t i n g m i n e r a l s [kyanite in t h i s case] and t h e i r i n t e r f a c e s . The new n u c l e i w i l l , t h e r e f o r e , p r e f e r a b l y tend t o form in or on one of the p r e - e x i s t i n g m i n e r a l s or in an i n t e r f a c e between two p a r t i c u l a r s p e c i e s of old m i n e r a l s . . . . I f th e most f a v o r a b l e pla ce of n u c l e i formation i s an i n t e r f a c e between m i n e r a l s which are r a r e in the ho s t rock, then only a few n u c l e i w i l l form and th e growth of ' g l o m e r o b l a s t s ' ( p o l y c r y s t a l l i n e monomineralic c l u s t e r s ) around th e n u c l e i thu s c r e a t e s a c e r t a i n type of metamorphic d ifferentiation." Thus, i f the above t h e o r y i s a p p l i e d to the for mati on of the k y a n i t e q u a r t z p e g m a t it e s as d i s c u s s e d in t h i s p a p er , we may p o s t u l a t e t h a t a few k y a n i t e c r y s t a l s , i s o l a t e d in a q u a r t z - r i c h s e g r e g a t i o n , could a ct as n u c l e i f o r a d d i t i o n a l aluminum and s i l i c o n io ns , and when t h e aluminum and / 35 s i l i c o n ions became a v a i l a b l e , t h e i r growth on th e n u c l e i could promote th e development of l a r g e c r y s t a l s of k y a n i t e . The i n v e r s i o n , s i l l i - m a n i t e Jcyanite, which i s noted r e p e a t e d l y in t h i n s e c t i o n s , may be due t o an i n c r e a s e in te m p e ra t u re subsequent to the formation of k y a n it e (see Fi g u r e SB). S e r i c i t e r e p l a c e s k y a n i t e and s i l l i m a n i t e in most t h i n s e c t i o n s and appears t o have formed as a r e s u l t of r e t r o g r e s s i v e metamor­ phism, p o s s i b l y accompanied by the i n t r o d u c t i o n of HgO and KgO t o the pegmatite. I t has been shown t h a t the k y a n i t e pe g m at it es do n o t r e p r e s e n t a re a s of aluminum enric hme nt; and t h e r e f o r e , t h e r e i s no need t o suppose t h a t aluminum was in tr o d u c e d by hydrothermal s o l u t i o n s or p e g m a t i t i c s o l u t i o n s , as proposed by H e in ri c h (1945, p. 14 -1 5) . F u r t h e r , t h e r e i s no evidence of Precambrian i n t r u s i o n s in th e a r e a from which s o l u t i o n s might emanate. N e i t h e r i s t h e r e re aso n to b e l i e v e t h a t th e pe gm at ites are r e l a t e d to the T e r t i a r y e x t r u s i v e rocks in th e G r a v e l ly Range, since none of the peg­ m a t i t e s i n t r u d e rocks which are younger than Precambrian in a g e . r .-•Feldspar-Quartz-Muscovite-Tourmaline Pe gma tit e s M in er al og y. - These pe g m at it es occur in marble or s c h i s t and c ontai n m i c r o c l i n e , q u a r t z , p l a g i o c l a s e (Abgg, Ang), to urm al in e , b i o t i t e , g a r n e t , and" m u s c o v i t e . Kyariite and s i l l i m a n i t e may occur in minor amounts i f the ho s t rock c o n ta i n s k y a n i t e or s i l l i m a n i t e . M ic r ocl in e i s g e n e r a l l y the most abundant mi ne ral in t h e s e p e g m a t i t e s ; however, some pe gm at ite s which c o n ta i n q u a r t z , m us cov it e, and to u rm al in e c o nt ai n l i t t l e or no m i c r o c l i n e . D e s c r i p t i o n . - The p e gm at ite bodie s are len s- sh a pe d or i r r e g u l a r and 36 are conformable w it h th e f o l i a t i o n of th e ho s t r oc k. S e v e r a l of th e se p e g m a t i t e s c on ta in small c o n c e n t r a t i o n s of muscovite and some have been p r o s p e c t e d ; however, no s u c c e s s f u l mining program has d e v e l o p e d . .P e g m a ti te s in Marble L a v e r s . - S e v e r a l f e l d s p a r - q u a r t z - m u s c o v i t e - t o u r ­ maline p e g m a t it e s occur in marble l a y e r s in t h e n o r t h e r n o n e - f o u r t h of Section 6 ( P l a t e I ) , and a few are found in o t h e r p a r t s of th e map a re a , e . g . , th e p eg ma ti te which occurs in S e c t i o n of the southernmost marble u n i t . 6 along the -.southern boundary These pe g m a t it e s l i e w i t h i n the marble u n i t s and along th e margins of s c h i s t s and a m p h i b o l i t e s , which suggests t h a t t h e pe g m a t it e - fo rm in g m a t e r i a l s may have been d e r i v e d from the s c h i s t s and a m p h i b o l i t e s . Rim Rock Pegma tite and V e t t e r P r o s p e c t . - S t o l l (1950, p. 59) mapped t h e Rim Rock pe g m a t it e ( l o c a t e d in n o r t h c e n t r a l S e c ti o n t h e V e t t e r mica p r o s p e c t (P fo sp e c t No. 2, P l a t e I ) . 6 , P l a t e I) and He r e p o r t e d t h a t the southwest end of th e Rim Rock p e g m at it e i s in f a u l t c o n t a c t w it h a r e d d i s h brown, th in - b e d d e d q u a r t z i t e . No f a u l t i s e v i d e n t a t the l o c a t i o n of the p e g m a t i t e , and th e q u a r t z i t e which i s in c o n t a c t w ith the p eg ma ti te i s t a l u s from th e Middle-Cambrian F l a t h e a d for mation t h a t crops out about 350 f e e t t o the n o r th w e s t. Co ntrol of L o c a l i z a t i o n of the Rim Rock P e g m a t i t e . - The presence of a small am ph ib o li te boudin a d j a c e n t to th e Rim Rock p e g m a t it e suggests t h a t th e boudin may have in f l u e n c e d the l o c a l i z a t i o n of the p e g m a t i t e . During metamorphism t h e boudin could a ct as a r i g i d body c r e a t i n g a p r e s s u re shadow t o which th e peg m at it e- fo rm in g m a t e r i a l s could m i g r a t e . Ramberg (1956, p. 197) no te d, ; " P e g m a t i t i c m i n e r a l s w i l l grow in p r e s s u r e shadows in l e 6 .. of r i g i d i n ­ c l u s i o n s in much th e same f a s h io n t h a t q u a r t z grows in p r e s s u r e shadows of g a r n e t p o r p h y r o b l a s t s . " The s t r i k e of f o l i a t i o n of th e ho s t rock sugg est s t h a t d i l a t i o n , r e s u l t i n g from the f o l d i n g of the hos t ro ck , may a l s o have i n f l u e n c e d the l o c a l i z a t i o n of th e Rim Rock p e g m a t i t e , i . e . , a low p r e s s u r e a re a produced d u r in g f o l d i n g could c o nce iv a bly be an a r e a of accumulation f o r the peg­ m a t i t e - f o r m i n g m a t e r i a l s (F igu re 4 ) . F e l d s p a r - Q u a r t z Pe gma tit e s These pe g m a t it e s occur ne ar t h e so u th er n l i m i t of th e map area and are a s s o c i a t e d w it h t h r e e main host r o c k s : orthoclase-quartz-m icrocline- b i o t i t e g n e i s s , a m p h ib o le -q u a rt z g n e i s s , and a m p h ib o li te . The p e g m a t it e s were no t examined m i c r o s c o p i c a l l y and t h i s d i s c u s s i o n i s based on megascopic o b s e r v a t i o n s . D e s c r i p t i o n of P e g m a t i t e s . - The pe g m a t it e bodies are long and t a b u l a r and appear t o be m os tly concordant w it h th e f o l i a t i o n of t h e ho s t ro ck . They are th e l a r g e s t pe g m a t it e s in th e a r e a , but t h e i r e x a c t s i z e i s d i f f i c u l t to deter mine due t o in a d eq u a te e x p o su r e s . One of t h e s e peg­ m a t i t e s i s i n d i c a t e d on th e map (see P l a t e I ) ; however, i t s e x ac t s i z e i s no t shown because of i t s l i m i t e d ex posu re. be about 100 The p eg ma ti te body appears t o f e e t t h i c k , i n c l u d i n g some t h i n l a y e r s of g n e i s s , and may be n e a r l y a h a l f - m i l e long. Mineralogy of P e g m a t i t e s . - The p e g m a t i t e s are composed l a r g e l y of mi c r o c l i n e and m i c r o c l i n e - p e r t h i t e , and va ry in g amounts of q u a r t z . T a b u la r 3b 50 f t . Sc a le Fi g u r e 4 . Map of Rira Rock Pegmatite Map showing p o s i t i o n of pe gm at ite body (X) and a m phib olit e (black) and t h e i r r e l a t i o n to f o l i a t i o n of marble (wavy l i n e s ) . Dip of f o l i a t i o n is n e a r l y v e r t i c a l . Arrows i n d i c a t e d i r e c t i o n of fo r c e s t h a t may have pro ­ duced a s t r e s s couple, thus c r e a t i n g a d i l a t i o n which could a c t as a sink f o r pe g m a t it e - fo rm in g m a t e r i a l s . Modified a f t e r S t o l l (1950, p. 59). 39 q u a r t z ve in s occur p a r a l l e l to the f e l d s p a r p e g m a t i t e s . Pe gm at ite -H os t Rock Contact R e l a t i o n s h i p and O ri g in of P e g m a t i t e s . The c o n t a c t between t h e pe g m at it es and t h e i r host rocks i s d i f f u s e , and s h a r i n g of m i n e r a l s between hos t rocks and p e gm at ite s i s me ga sc op ic a lly v isible. Small g a r n e t s occur in the p e g m a t it e s and e x h i b i t no p a r t i ­ cular d is trib u tio n , i . e . , th e y are no t confined to the margins or the c e n t e r of the p e g m a t i t e s , but occur randomly throughout th e p e g m a t it e s . Such a random d i s t r i b u t i o n of the g a r n e t s would not be ex pec te d i f the p e g m a t i t e s were formed from aqueous s o l u t i o n s . In such c as e , the g a r n e t s would be p r e s e n t as i n c l u s i o n s which were picked up by the s o l u t i o n s from th e a d j a c e n t country ro c k . They would be ex pec te d to con­ c e n t r a t e , due t o t h e i r h i g h e r s p e c i f i c g r a v i t y , and t h e r e f o r e , would be found in c l u s t e r s r a t h e r than as i s o l a t e d i n d i v i d u a l s . A s l i g h t d e p l e t i o n of f e l d s p a r and q u a r t z a d j a c e n t to " a p l i t e ' 1 ( h e re used t o i n d i c a t e small s t r i n g e r s of f i n e - g r a i n e d f e l d s p a r - q u a r t z rock of ap pr ox im at el y th e same composition as t h e p e g m at it es ) s t r i n g e r s would seem to i n d i c a t e t h a t a t l e a s t p a r t of the f e l d s p a r and q u a r t z may have been d e r i v e d from th e host r o c k . The chemical composition of the q u a r t z - m i c r o c l i n e - b i o t i t e - o r t h o c l ase g n e i s s , as c a l c u l a t e d from the mode of one t h i n s e c t i o n was ap pro xim at el y: 70.1 p e rc e n t Siog; 11.2 p e rc en t AI 2 O3 ; 3 . 7 p e r c e n t ( a l , F e ) 2 O3 ; 3.1 p e r c e n t (Fe, Mg)0; 11.6 p e rc e n t (Na, K^O and .3 p e r c e n t HgO. The high p e r c e n ta g e (1 1.6 p e r c e n t ) of (Na, KjgO may i n d i c a t e t h a t some of t h i s m a t e r i a l was in t r o d u c e d duri ng metamorphism. •Ji The d i f f u s e c o n t a c t s between th e pe g m at it es and host rocks 40 would seem to i n d i c a t e t h a t th e (Na, K) 2 O was in tr o d u c e d by metasomatic processes. C o n c e n tr a ti o n of th e s e c o n s t i t u e n t s , which r e s u l t e d in the fo rm ati on of p e g m a t i t e s , may have oc cu rr ed a t the time of i n t r o d u c t i o n of t h e m a t e r i a l , or subsequent t o i n t r o d u c t i o n . The occurrence of l a r g e a m p h ib o li te l a y e r s ne ar t h e pe g m at it es may p r o v id e an e x p l a n a t i o n as t o the source of the p e gm at ite - fo rm in g m a t e r i a l s s in ce t h e more v o l a t i l e c o n s t i t u e n t s of the a m p h ib o li te s may have mi gr at e d from th e a m p h ib o li te s t o s i t e s f a v o r a b l e f o r p r e c i p i t a t i o n , th us e n r i c h i n g c e r t a i n rocks w it h f e l d s p a r and q u a r t z and d e p l e t i n g o t h e r ro c ks of th os e m a t e r i a l s . This type of metamorphic d i f f e r e n t i a t i o n was a l s o noted by Reid (1957, p. 20), " . . . the most a bund ant ly developed u l t r a b a s i c rocks l i e on the margins of the l a r g e s t metamorphic p e gm at ite b o d i e s . " STRUCTURE C o n ta ct R e l a t i o n s Between Precambrian Rocks and P a l e o z o i c Rocks The c o n t a c t between t h e Precambrian ro c ks and th e P a l e o z o i c rocks i s c l e a r l y v i s i b l e a t a few p l a c e s in t h e map a r e a and i s o th e r w is e covered by t a l u s from the P a l e o z o i c sedimentary r o c k s . The s t r i k e of the P a l e o z o i c rocks i s about N IO0 E and t h e dip i s about 5° 1W to IO0 Hf. The f o l i a t i o n of t h e Precambrian ro c ks s t r i k e s gen­ e r a l l y N 80° E, but has c o n s i d e r a b l e l o c a l v a r i a t i o n . The d ip v a r i e s from about 45° S t o 65° N, b u t, in g e n e r a l , i s n e a r l y v e r t i c a l . The f o l i ­ a t i o n of th e Precambrian rocks was t h e r e f o r e e s s e n t i a l l y v e r t i c a l at the time of d e p o s i t i o n of th e P a l e o z o i c r o c k s . Fol di ng of the Metamorphic Rocks The r e p e t i t i o n of d i s t i n c t l i t h o l o g i c types s ug ges ts t h a t the rocks may have been fo ld e d or f a u l t e d . There i s some ev ide nc e f o r r e p e t i t i o n by f o l d i n g , i . e . , minor f o l d s , m o d e r a t e - s i z e f o l d s , and r e p e t i t i o n of d i s t i n c t rock t y p e s ; but evidence f o r r e p e t i t i o n by f a u l t i n g was not o b s e r v e d . Minor f o l d s ( l e s s than 12 inches) occur in g n e i s s i c rocks in two l o c a l i t i e s , and a few minor f o l d s occur in marble l a y e r s . M oder at e -s iz e f o l d s ( l a r g e r than two f e e t ) a l s o occur in the marble, p a r t i c u l a r l y in the southernmost l a y e r (see F i g u r e s 5 and 6 and P l a t e I ) . S t r u c t u r a l I n t e r p r e t a t i o n . - The s t r u c t u r a l i n t e r p r e t a t i o n i s based upon th e a p p ar en t r e p e t i t i o n of c e r t a i n rock l a y e r s , th e l i n e a t i o n of f o l d a x e s , and the a t t i t u d e s of f o l i a t i o n of th e ro c k s . The g e n e r a l s t r u c t u r a l p a t t e r n a ppea rs t o be t h a t of an i s o c l i n a l s y n c l i n e (?) whose a x i s plunges about 60° to 70°, N 80° E (see Figure 5 ) . I f t h e s t r u c t u r e i s i n t e r p r e t e d t o be an ove rtu rne d a n t i c l i n e , i . e . , an a n t i c l i n e in which th e a x i s plunges HO 0 or 120°, N c r o s s - f o l d i n g should occu r. 8 0 ° E, then some No c r o s s - f o l d i n g i s observed in th e map a r e a . I f the s y n c l i n a l i n t e r p r e t a t i o n i s c o r r e c t , the o l d e s t of the Pr ecambrian rocks in t h e map a re a are the g n e i s s e s and s c h i s t s which occur a t the so uth er n l i m i t of the a re a, and th e youngest Precambrian rocks ( n o t n e c e s s a r i l y i n c l u d i n g pe gm at ite s) occur in the core of th e f o l d . 7 / ‘ Ii / / pCm Geologic Mop of the Northern Port of the Cherry C reek M etomorphics, Madison Co., M ontana with Structural Interpretation. EXPLANATION SCALE O 3 0 0 0 Feet I I WOiT., 1959 Ip € m | D o l o m i t e - M a r b l e a n d D o lo m itic M a r b l e Ip C k s I K y o n ite S c h i s t . S c h is ts , G n e is s e s |p € g s | G n e is s e s a n d S c h i s t s , U n d iv id e d ^ 5 ^ and F o lia tio n o f M e t a m o r p h i c R o c k s C o n ta c t o s M a p p e d FIGURE 5 ^ ,7 0 S tru c tu r a l In te r p re ta tio n P lu n g e o f F o ld A x e s of C o n ta c t . A m p h ib o lite s Map of Folds in Dolomite-Marble. See Location " F " , Plate I . W.D.T.,1959 SCALE O______________ 5 0 FEET I I FIG U R E 6 44 Boudinaqe S t r u c t u r e s in Marble Lavers Boudinage s t r u c t u r e s , which occur l o c a l l y in the ro c k s , are most f u l l y developed in s i l i c e o u s marble (see a re a d e s i g n a t e d "b oudin s" , P l a t e I , Section 6) and commonly have t h e i r X and Y axes p a r a l l e l and t h e i r Z a x i s p e r p e n d i c u l a r , or n e a r l y p e r p e n d i c u l a r , t o the f o l i a t i o n of th e e n c l o s i n g rock (see Ramberg, 1955, p. 522). The boudins are t y p i c a l l y b a r r e l - s h a p e d ( i n two dimensions) and are composed of q u a r t z , dolom ite , c a l c i t e , and w b l l a s t o n i t e (see F ig u r e 7 ) . Ramberg (1955, p. 512, 513, 517) has p o i n t e d out t h a t "Boudins are u s u a l l y oblong bodies wit h t h e s h o r t e s t dimension p e r p e n d i c u l a r t o th e s c h i s t o s i t y in th e e n c l o s i n g rocks and th e l o n g e s t dimension p a r a l l e l to the s c h i s t o s i t y . " ' As t o the o r i g i n of boudinage s t r u c t u r e s , he s t a t e s , " . . . th e b a s i c re aso n f o r boudinage s t r u c t u r e i s d i f f e r e n c e s in com­ p e te n c y between th e boudin l a y e r and t h e a d j a c e n t ro c k s , th e l a t t e r be ing r e l a t i v e l y incompetent or d u c t i l e , the former competent or b r i t t l e . "The b a r r e l - s h a p e of boudins i s . . . r e a d i l y e x p l a i n e d by compression p e r p e n d i c u l a r t o the l a y e r i n g and a consequent e l o n g a t i o n p a r a l l e l to the layering . . . " In r e g a r d t o the fo rm ati on of an e l o n g a t e body he s t a t e s (p . 517), " E lo n g a ti o n of a body of m a t t e r in one or more d i r e c t i o n s can be caused by, (I ) s t r e t c h i n g under t e n s i l e s t r e s s , ( 2 ) compression in a d i r e c t i o n p e r p e n d i c u l a r , t o the d i r e c t i o n ! s) of e l o n g a t i o n , or (3) a s t r e s s couple a t about a 45° angle t o the e l o n g a t i o n . " However, he concludes t h a t most boudins are produced by compression in a d i r e c t i o n p e r p e n d i c u l a r t o boudin e l o n g a t i o n : " . . . th e s t r u c t u r e of the incompetent rocks a d ja c e n t t o boudins . . . shows t h a t th e b a s i c re a so n f o r the e l o n g a t i o n of the incompetent roc ks , in by f a r th e most c a s e s, must have been a compressive s t r e s s p e r p e n d i c u l a r ( o r at an obtuse angle) t o the boudin l a y e r . " 45 The q u a r t z - d o l o m i t e - c a I c i t e - w o l l a s t o n i t e rock i s a p p a r e n t l y more b r i t t l e than th e marble, and thu s i t y i e l d e d t o s t r e s s by r u p t u r e ; whereas t h e marble y i e l d e d by f lowage. The l i n e a t i o n of th e boudins i s p a r a l l e l to the f o l i a t i o n of the e n c l o s i n g ro c k s , or about N 80° E, i n d i c a t i n g t h a t the compressive f o r c e s which formed t h e boudinage s t r u c t u r e s were p e r p e n d i c u l a r t o (or a t an obtuse angle to) t h e long a x i s of th e boudins. Such compressive f o r c e s could a l s o be employed t o e x p l a i n th e f o l d ­ ing of the ro c k s , as proposed in t h i s p a p e r . 46 Ol I Boudin in dolom ite-m arble. See Boudins ,P late I . Drawn a ft e r photograph. W.D.T., 1 95 9 i SCALE 6 I 12 Inches I Ruptures Foliation (vertical) Figure 7 Competent rocks 47 PRINCIPLE OF THE METAMORPHIC FACIES APPLIED TO THE ROCKS " OF THE NORTHERN PART OF THE CHERRY CREEK METAMORPHICS The rocks in th e map a r e a appear t o have been metamorphosed under c o n d i t i o n s ap proximating th o s e of the e p i d o t e - am phi bolit e f a c i e s or the a m p h ib o li te f a c i e s . This i n t e r p r e t a t i o n i s based upon th e o b s e r v a ti o n of s e v e r a l c r i t i c a l m in e ra l assemblages which occur in the a r e a : (1) Kyanite-sillim anite-m uscovite-plagioclase-quartz (2) Kyani t e - s i l l i m a n i t e - b i o t i t e - q u a r t z (3) K yanite-andalusite-pyralspite-biotite-quartz (4) C alcite-dolom ite-w ollastonite-quartz (5) Kyanit e - s i l l i m a n i t e - b i o t i t e - p y r a I s p i t e - m u s c o v i t e - q u a r t z (6) Mi c r o c l i n e - o r t h o c l a s e - b i o t i t e - q u a r t z (7) Amphibole (h o r n b le n d e ) - p l a g i o c l a s e F ig u r e 8 r e p r e s e n t s a s t a b l e m in e ra l assemblage^ of th e amp hibo lite f a c i e s ; F ig ure 9, a s t a b l e assemblage of th e e p i d o t e - a m p h ib o li te f a c i e s . I t i s noted t h a t specimens taken from w id e ly s ep a ra te d p o i n t s in the map a r e a may be c o n v e n i e n t l y p l o t t e d on t h e s e diagrams. 4b A Muscovite Staurolite \ — E-56-4-1 B iotite Almandine V-Vacant f i e l d M i c r o c li n e Figure b . Amphibolite f a c i e s : AKF diagram f o r rocks w it h excess Si&g and AlgO^. P o i n t E - 5 b - 4 - l r e p r e s e n t s p o s i t i o n of specimen of k y a n i t e - b i o t i t e s c h i s t taken from P r o s p e c t No. 4 ( a f t e r Tur ner and Verhoogen, 1951, p. 45 3) . Kyanite Staurolite Muscovite ,Garnet \ Chlorite E-Sb-GOrthdclase Biotite Figure 9. E p i d o t e - a m p h i b o l i t e f a c i e s : T a lc , k y a n i t e pota sh f e l d s p a r (AKF) diagram of the high e p id o te - a m p h i­ b o l i t e f a c i e s ( a f t e r Ramberg, 1952, p. 149). P o in t E-Sb-G-Gl i n d i c a t e s p o s i t i o n of b i o t i t e - p o t a s h f e l d s p a r q u a r t z g n e i s s . Specimen taken from gn e is s n e a r southern l i m i t of map a r e a . 49 POTENTIAL FOR ECONOMIC DEVELOPMENT OF THE ENNIS KYANITE DEPOSIT The economic p o t e n t i a l of t h i s d e p o s i t of k y a n it e and s i l l i m a n i t e i s dependent upon s e v e r a l f a c t o r s : (I) th e a c t u a l volume of k y a n i t e - b e a r i n g ro c ks in t h e a r e a and t h e p e r c e n t of k y a n i t e and s i l l i m a n i t e in the r o c k s , (2) the ea se w it h which t h e k y a n i t e - b e a r i n g rocks can be mined, (3) the e a s e w it h which th e k y a n i t e and s i l l i m a n i t e can be c o n c e n t r a t e d i n t o a mar­ k e t a b l e p r o d u c t, ( 4 ) t h e pro x im it y of a market f o r th e f i n i s h e d produ ct , ( 5 ) th e world market s i t u a t i o n f o r th e r e f r a c t o r y m a t e r i a l s , and ( 6 ) th e a b i l i t y of th e k y a n i t e and s i l l i m a n i t e t o convert t o m u l l i t e . The scope of t h i s pa per does not i n c l u d e a study of th e above f a c t o r s , w i t h th e p o s s i b l e e x c e p t i o n of the f i r s t , which w i l l be d i s c u s s e d b r i e f l y . The Volume of K va n it e- B e a ri n q Rocks in th e Map Area An a c c u r a t e e s t i m a t e of th e volume of k y a n i t e - b e a r i n g rock in the a r e a and t h e p e r c e n t of k y a n i t e in t h e rock can be made only a f t e r e x t e n s i v e t r e n c h i n g and sampling. The depth t o which t h e k y a n i t e - b e a r i n g rocks p e r s i s t can be de termined by s e l e c t i v e d r i l l i n g . is correct, i . e . , I f the s t r u c t u r a l i n t e r p r e t a t i o n i f th e s t r u c t u r e i s a s y n c l i n e (see p. 41 and Fig ur e 6 ) “'h th e k y a n i t e - b e a r i n g ro c ks may p e r s i s t t o c o n s i d e r a b l e d e p t h s . Ttiere jis no i re a s o n t o b e l i e v e t h a t t h e q u a n t i t y or q u a l i t y (massive k y a n i t e i s con- , , , , s i d e r e d t o be high q u a l i t y , and d i s s e m i n a t e d k y a n it e i s co n si d e re d t o be low q u a l i t y —both s u b j e c t t o t h e i r m u l l i t e - f o r m i n g a b i l i t i e s ) of the k y a n i t e , J in any l a y e r of th e k y a n i t e - b e a r i n g r o c k s , should i n c r e a s e or d e cr ea se w i t h depth. I 50 INDUSTRIAL USES OF KYANITE Kyanite has an i n d u s t r i a l a p p l i c a t i o n in the pro d u c ti o n of m u l l i t e - m u llite (plus free s i l i c a ) i s formed when k y a n i t e i s heat ed t o a tempera­ t u r e of about 1300° C. M u l l i t e i s used in th e manufacture of h i g h l y r e f r a c t o r y m a t e r i a l s which p o s s e s s a low c o e f f i c i e n t of ex pa ns io n, r e s i s t a n c e t o loads at high t e m p e r a t u r e s , and r e s i s t a n c e t o thermal shock and th e c o r r o s i v e a c t i o n of r e a c t i v e s l a g s (Haw, 1954). According t o Gunsallus and Tucker (1957, p.2) . . -about 90 p e r c e n t of a l l m u l l i t e r e f r a c t o r i e s have been employed t o l i n e fu r n a c e s o p e ra te d by th e m e t a l l u r g i c a l and g l a s s i n d u s t r i e s . . .; . . 1 0 p e r c e n t . . . consumed in m i s c e l l a n e o u s a p p l i c a t i o n s , c h i e f l y in t'he ceramics i n d u s t r y . " { 51 BIBLIOGRAPHY B a r t h , T. F. Ttf., 1952, T h e o r e t i c a l p e t r o l o g y : John Wiley 387 p . & Sons, I n c . , Bowen, N. L . , 1924, The system A^Og-SiOg (Abs.) : G e o l. Soc. America B u l l . , v. 35, no. I , p. 123. & Campbell, I . , Wright, L.A., 1950, Kyanite p a r a g e n e s i s a t Ogilby, C a l i f . ( A b s . ) : G e o l. Soc. America B u l l . , v . 61, no. 12, p. 1520-1521. Chadwick, R. A., 1958, Mechanisms of pe g m a t it e emplacement: G e o l . Soc. of America, v. 69, no.7 ,p. 803-836. Dunn, j . A . , 1929, The aluminous r e f r a c t o r y m a t e r i a l s ; k y a n i t e and s i l l i manite and corundum in n o r t h e r n I n d i a : I n d i a G eo l. Survey, Mem. 52, ( 2 ) , p. 145-274. F y f e , W. S . , Tu rn er, F. J . , and Verhoogen, J . , 1958, Metamorphic r e a c t i o n s and metamorphic f a c i e s : G e o l . Soc. America, Mem. 73, 259 p. G rig gs , D. T , , and Kennedy, G. C., 1956, A simple a p p a r a tu s f o r high p r e s s u r e s and t e m p e r a t u r e s : Am. J o u r . S c i . , p. 722-735. & G u n s a l l u s , B. L., Tucker, G. E., 1957, K yanite and r e l a t e d m i n e r a l s : U. S. Bureau of Mines Yearbook, 1957, 4 p. Haw, V. A., 1954, Kyanite in Canada: Canadian Min. M e t a l l . B u l l . , no. 501, p. 27-35. H e i n r i c h , E. W., 1948, D e p o si ts of the s i l l i m a n i t e group of m in e ra ls south of Ennis, Madison C o . , with no te s on o t h e r oc cur rence s in Montana: Mont. Bureau of Mines, Misc. C o n t r i b u t i o n no. 10, 22 p. ________________ , 1949, P e gm a tit e s of Montan'a: R e p r in t from Economic G e ol., v. 44, no. 4, 43 p. H ietanen, A., 1956, K ya ni te, a n d a l u s i t e and s i l l i m a n i t e in t h e s c h i s t in Boehls B u t t e q ua dra ng le , Idaho: R e p r i n t from Am. M i n e r a l o g i s t 41, p. 1-27, 27 p . J e f f e r y , J . A., 1944, The s i l l i m a n i t e group of m i n e r a l s : C a l i f . J o u r , of Mines and G e o l. , v. 39, no. 3, p. 383-390. Kennedy, G. C., 1955, P y r o p h y l I i t e - s i I l i m a n i t e - m u l I i t e e q u i l i b r i u m r e ­ l a t i o n s t o 20,000 b a r s and 800° C.: G e o l. Soc. America, V. 6 6 , no. 12, p . 1584. 52 Mason, B., 1 9 5 8 , , P r i n c i p l e s of g e och e m is tr y: John Wiley & Sons, 310 p. M iy a s h ir o , A., 1949a, A not e on s t r e s s m i n e r a l s CAbs. ) : G e o l. Soc. Japan J o u r . , 55, p . 216-217. ______________ , 1949b, The s t a b i l i t y r e l a t i o n s of k y a n i t e , s i l l i m a n i t e and a n d a l u s i t e , and t h e p h y s i c a l c o n d i t i o n s of the metamorphic p ro ce sse s (Abs. ) : G e o l. Soc. Japan, 55, p. 223. Nordstrom, C., 1947, Geology of a k y a n i t e d e p o s i t ne ar Ennis, Montana: T h e s is (B.S ) Montana School of Mines, B u tt e , Mont. P e a l e l A. C., 1896, Three Forks, Mont.: U. S. G e o l. Survey F o l i o #24, 7 p . , 4 maps. B a b b i t t , J . C., 1946, S t u d i e s of t h e Cherry Creek s e r i e s and anthop h y l l i t e in Montana; T h e s is (Ph.D.) Harvard U n i v e r s i t y . Ramberg, H., 1952, The o r i g i n of metamorphic Chicago P r e s s , 3T7 p. & metasomatic r o c k s : Univ. of ____________ , 1955, N a t u r a l and e x per im en ta l boudinage and pinc h and swell s t r u c t u r e s : J o u r . G e o l. , v . 63, no. 6, p. 512-526. ,________ , 1956, P e gm a tit e s in west Greenland: G e b l . Soc. America B u l l . , v. 67, p . 185-213. Read, H. H., 1933, Q u a r t z - k y a n i t e rocks in Unst, Sh et la nd I s l a n d s : Mineral Mag., v. 23, p. 319-328. Reid, R. R., 1957, Bedrock Geology of th e n o r t h end of th e Tobacco Root Mts. , Madison C o . , Montana: Mont. Bur. Mines G G e o l . , Mem. 36, 25 p. Runner, J . J . , and Thomas, L. C., 1928, S t r a t i g r a p h i c r e l a t i o n s of the Cherry Creek group i n th e Madison V a ll e y , Mont. ( A b s .) : G e o l . Soc. America B u l l . , v. 39, no. 2, p. 202-203. S t o l l , W. C., 1950, Mica & Heryl p e g m a t it e s in Idaho Survey P r o f . Paper 229-, 64 p . & Montana: U. S. G e o l. Stu ckey, J . L ., 1932, Cy an it e d e p o s i t s of North C a r o l i n a : Econ. G e ol., v. 27, no. 7, p . 661-674. Turner,' F. J . , and Verhoogen, J . , McGraw-Hill Book Co., I n c . 1951, Igneous and metamorphic p e t r o l o g y : W i n c h e l l , A. N., 1914, Mining d i s t r i c t s of t h e D il lo n quad rangle and , a d j a c e n t a r e a s : U. S . G e o l. Survey, B u l l . 574, 191 p ., 8 p i . 53 WinchelI, A. N., and Win che ll, H., 1951, jSlements of o p t i c a l mineralogy, p a r t 2: John Wiley and Sons, p. 483-^28. T PLATE I R l W. EXPLANATION Alluvium 18 l/2°i Quaternary Talus 72 66 T.7S. Travertine Tertiary Sedimentary Rocks, Undivided r Paleozoic p€Kp I \ ' / Middle Cambrian Flathead Formation Dolomite Marble and Dolomitic Marble Kyanite Bearing Schist Prominent. Includes Some Gneiss and Amphibolite Gneisses and Schists,Undivided Precambrian Amphibolite /' Pol Kyanite Bearing Pegmatite Pegmatites,Undivided. Generally Contain Quartz, Feldspar, Tourmaline and (or) Muscovite Mica Protpact X2 Contact Qt a Contact Approximately Located P tg i x IO Attitude of Bedding in S edim entary Rocks ^60 Attitude of Foliation in C rys ta llin e -V- Strike of Vertical Foliation in C rystalline ^rVo Attitude of Foliation Ar Strike of V ertical T.8S. I Il Carbonates 5840 ' I- / 6042 + 5 746 X 6000 Prospect in Kyonite Bearing /.5 0 Plunge o f Axes of M o d e r a t e - S iz e L in ea tio n H orizontal Anticlinal Folded A---- A' Cross S ection - •••___ Large Interm ittent Gneisses Joints Plunge of Trace of and Relative Movement Strike and Dip of I Gneisses Rock "eo \ / _o and Foliation in Schists Fault. Arrows Indicate y L\ in Schists Carbonates of Minor Folds Fold Axes Axis Foliation SCALE 9- T - - T - ^ IOOO___________________________ 2 0 0 0 I I 1 0 0 0 FEET Stream ) ----CONTOUR IN T E R V A L 40 GEOLOGIC MAP 6000 S m all Draw FEET AND CROSS SECTION A' of THE NORTHERN PART OF THE CHERRY CREEK METAMORPHICS MADISON COUNTY, MONTANA 5800 5600 pCm BASE MAP TOPOGRAPHY EY US. GEOL SURVEY, VARNEY 5400 GEOLOGY BY Cross Section WI L L A R D D. TOMPSON, JR. JANUARY, 1959 AND CAMERON QUADRANGLES MONTANA STATE UNIVERSITY LIBRARIES C S T ^ 136412