16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10: Ablative Cooling, Film Cooling Transient Heating of a Slab Typical problem: Uncooled throat of a solid propellant rocket Inner layer retards heat flux to the heat sink. Heat sink’s T gradually rises during firing (60-200 sec). Peak T of heat sink to remain below matl. limit. Back T of heat sink to remain below weakening point for structure. Prototype 1-D problem: Can be solved exactly, or can do transient 1-D numerical computation. But it is useful to look at basic issues first. Thermal conductance of B.L.=hg Thermal conductance of front layer = Thermal conductance of layer i = 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez ki δi k1 δ1 ( δi = thickness, ki = thermal conductivity) Lecture 10 Page 1 of 12 Want layer 1 to have k1 δ1 hg to protect the rest. ⎛ k1 1 W / m / K ⎞ k1 W = 330 2 compared to (Say, porous, Oriented graphyte, ⎜⎜ ⎟⎟ → δ1 mK ⎝ δ1 = 3 mm ⎠ W hg ∼ 50, 000 2 , so OK here). mK Also, from governing equation ρc ∂T ∂2 T ∂T ∂2 T =k 2 → =α 2 ∂t ∂t ∂x ∂x (α = k , thermal diffusivity, m 2 / s ) ρc we see that x2 ∼ αt , or x ∼ x2 . α αt , or t ∼ So the layer 1 will “adapt” to its boundary conditions in a time t ∼ Say, c so α = 710 J and ρ KgK 1100 Kg ( 3 m δ12 . α1 1 solid graphyte), 2 1 = 1.3 × 10−6 m2 / s . 710 × 1100 (3 × 10 ) The layer “adapts” in t ∼ −3 1.3 × 10 2 −6 = 7.0 sec (more like δ2 = 1.8 sec ). 4α ⇒ Treat front layer quasi-statically, i.e., responding instantly to changes in heat flux: k1 T (t) wh1 −T (t) wc1 δ1 q (t) This also means we can lump the thermal resistances of BL and 1st layer in series: 1 (hg ) eff δ 1 + 1 hg k1 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 2 of 12 and since k1 δ1 (hg )eff hg , ∼ k1 δ1 hg ( )eff For layer 2 (the heat sink), k2 is high (metal) and hg is now small (thanks to 1st layer) so, very likely, k2 δ2 (hg )eff (For instance, say Copper, k2 (hg )eff 360 W , with δ2 = 2 cm. We now have mK k2 k k W W = 350 2 , but 2 = 36, 000 2 , so indeed, 2 δ2 δ2 δ2 mK mK (hg )eff ). Under these conditions, the heat sink is being “trickle charged” through the high thermal resistance of layer 1. Most likely, heat has time to redistribute internally, so that T2 is nearly uniform across the layer. We can then write a lumped equation. ρ2c2 δ2 Define τ = dT2 = q = hg dt ( )eff ( Taw − T2 ) ρ2c2 δ1δ2 k1 τ T2 = Taw − ( Taw − T0 ) e k1 ( Taw − T2 ) δ1 dT2 + T2 = Taw dt − ( T2 (0 ) = T0 ) t τ For our example, say ρ2 = 8900 Kg / m3 (Copper), c2 = 430 τ= J , δ2 = 2 cm KgK 8900 × 430 × 3 × 10−3 × 2 × 10−2 = 230 sec 1 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 3 of 12 This is comfortable. Suppose Taw = 3300 K , T0 = 300 K , and we fire for 120 sec: (60) (60) T2 (120 ) = 3300 − 3000 e − 120 230 (989) = 1520 K May need 4 cm which is still (OK) for Copper (melts at 1360K, but no stress bearing, so can go to ~900. Also OK for steel on Carbon str member). NOTE: (0.02) δ22 = = 1.1 sec , so, indeed, layer 2 “adapts” quickly to B.C.’s 4α2 4 × 9.4 × 10−5 2 → uniform k2 360 = = 9.4 × 10−5 m2 / s . ρ2c2 8900 × 430 A More Exact Solution Consider Taw “turned on” at t=0. The B.L. has a film coefficient hg , and the first ( )eff layer has δ1 , k1 , so that hg = hg δ 1 + hg 1 k1 ∼ k1 . Layer 2 has thickness δ2 , and has δ1 k2 , ρ2 , σ2 , α2 . The back is insulated. Then one can prove that layer 2 has a temperature distribution 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 4 of 12 Taw − T2 ( x, t ) Taw − T0 where an = ∞ = ∑a e −λn2 n α2t δ22 n =1 ⎛δ −x ⎞ cos ⎜ 2 λn ⎟ ⎝ δ2 ⎠ 2 sin λn λn + sin λn cos λn and λn (n=1,2,…) are the roots of λn tan λn = (hg )eff δ2 k1 δ2 k2 δ1 k2 Graphically, For small ∆ ≡ λ12 and also a1 k1 δ2 , small λ1 , so tan λ1 k 2 δ1 ∆ λ1 ∆ = 1 λ12 λ1 , so k1 δ2 k2 δ1 α2 δ22 k1 δ2 k δ1 2 k /ρ c k1 2 2 2 = ≡τ 2 ρ2c2 δ1δ2 δ2 from before So, leading term is then Taw − T2 ( x, t ) Taw − T0 e − t τ ⎛δ −x ⎞ λ1 ⎟ cos ⎜ 2 ⎝ δ2 ⎠ 1 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 5 of 12 which is what we found before. The other terms are much smaller, except at very small time. For thermal protection of solid rocket nozzles read sec. 14.2 (pp. 550-563) of Sutton-Biblarz, 7th ed., especially, pp. 556-563. A key concept is ablative materials. They contain a C-based homogeneous matl. embedded in reinforcing fibres of strong (anisotropic) C. Best is C/C, strong expensive fibre since nozzle can get to 3600 K, can be 2D or 3D. Also good is C or Kelvin (Aramid) fibres +phenolic plastic resins (for large nozzles) For the shuttle RSRM, the throat insert (C cloth phenolic) regresses ~ 1 inch/120 sec, and the char depth is ~ 0.5° inch/120 s. 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 6 of 12 Film Cooling of Rockets For application of data on slot-injected films, we need to define the initial film thickness s, velocity uF , density ρF , or at least mass flux uF ρF . i i i i Assume we know the flow rates mc and mF , where mc is the “core” flow and mF the “film” flow. We also know the fully-burnt temperatures and molecular weights ( Tc , TF ; Mc , MF ). The areas occupied at the “fully burnt” section are not known; let them be Ac , AF . From continuity, i uc A c = mc ρc i mc R = Tc P Mc (1) P = Pc is common to both 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 7 of 12 i i mF uF AF = mF R = TF P MF ρF (2) and the total cross-section is known: Ac + AF = A (3) We need some additional information to find uF . The two momentum equations are (neglecting friction): duc dP ⎫ + = 0⎪ dx dx ⎪⎪ duc duF = ρFuF ⎬ ρcuc dx dx ⎪ duF dP + = 0⎪ ρFuF ⎪⎭ dx dx ρcuc ρ uF duF = c ρF uc duc (4) Both, ρF and ρc , have been evolving as drops evaporate and burn. We make now the approximation of assuming their ratio to remain constant (equal to the fullyburnt value). Then (4) integrates to uF2 u2c = ρc ρF uF = uc ρc ρF (5) Substitute into the ratio (2)/(1) i ρFuF AF mF ρ = i → F ρcuc Ac ρc mc i or i ρc AF mF = i ρF Ac mc AF mF = i Ac mc ρc ρF (6) ρFuF = ρcuc ρF ρc (7) and also ⎛ρu This last ratio ⎜⎜ F F ⎝ ρcuc ⎞ ⎟⎟ is called the “film cooling parameter”, MF : ⎠ 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 8 of 12 MF = ρF = ρc MF Tc Mc TF (8) The film thickness s (at complete burn up) follows from 2 AF = π ⎡D2 − (D − 2s ) ⎤ ⎫ ⎢⎣ ⎥⎦ ⎪ 2 ⎪ AF ⎛ D ⎞ = ⎬ ⎜ ⎟ −1 ⎪ A c ⎝ D − 2s ⎠ 2 A c = π (D − 2s ) ⎪ ⎭ i s 4s D (if s D) ρc ρF D AF D mF = 4 Ac 4 i mc (9) From Rosenhow & Hartnett, Chapter 17-B, we characterize film cooling by the change it induces to the driving temperature ( Taw ) for heat flow. In the absence of a ( ) γ −1 2⎞ ⎛ 0 0 − Tw . The film = Tc ⎜1 + r film, Taw Mc ⎟ , and we calculate ( qw )No Film = hg Taw 2 ⎝ ⎠ 0 F F to Taw (lower, presumably). The lowest we could Taw to get is TF , so changes Taw we define a film cooling efficiency η= 0 F Taw − Taw Taw − TF ⎧⎪η = 0 Limits: ⎨ ⎪⎩η = 1 (10) F 0 if Taw = Taw if F Taw = TF (no effect) (max imum effect) If we can predict η , then ( F 0 0 Taw = Taw − η Taw − TF ) (11) and then ( F qw = hg Taw − Tw ) (12) where hg is computed as if there were no film. To predict η , we first computes the parameter 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 9 of 12 µF ⎞ x ⎛ ζ= ⎜⎜ ReF ⎟ µc ⎟⎠ MF s ⎝ − 1 4 (13) where x is the distance downstream of the film injection (here we assume this is from the burn-out section), and ρFuF s ReF = (14) µF and ρFuF = MF ( ρcuc ) , from before From ζ , there are several semi-empirical correlations for η . A recommendation from R & H is 2 η= 1.9 Pr 3 ⎛ cp 1 + 0.329 ⎜ c ⎜ cp ⎝ F ⎞ 0.8 ⎟ζ ⎟ ⎠ (15) (or η = 1 if this gives >1) which is supported by air data of Seban. Example Say TF ρ 1 M 0.8 = ; F = 0.8 → F = = 1.6 → MF = 1.6 = 1.265 ρc 0.5 Tc 2 Mc i mF i mF 1 = 0.1 → i = 9 m (0.01) mc (0.0101) i Say D=0.5m x t − x com pl. com b = 0.5 m P=70 atm=7.09 × 106 N / m2 ⎫ ⎪ 7.09 × 106 × 0.020 = 5.33Kg / m3 ; ρF = 8.53Kg / m3 Tc = 3200 K ⎬ ρc = 8.314 3200 × ⎪ Mc = 20 g / mol; γ c = 1.2 ⎭ Mc = 0.2 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 10 of 12 uc = 0.2 1.2 × 8.314 × 3200 = 253 m / s 0.02 1 = 200 m / s 1.6 uF = 253 Say µF = 2 × 10−5 Kg / m / s → ReF = 8.53 × 200 × s 2 × 10 −5 = 8.53 × 107 s ReF = 9.37 × 105 i ρc 0.5 = × ρF 4 D mF s= 4 i mc 1 9 OR 0.0101 1 = 0.0110 m 1.6 0.000998 (8.51 × 10 ) 4 0.6 µF ⎛ TF ⎞ =⎜ ⎟ µc ⎜⎝ Tc ⎟⎠ ζ= = 0.50.6 = 0.660 ( 0.5 9.37 × 105 × 0.660 1.265 × 0.0110 8.51 × 104 0.000998 epc µF = 0.8 µc c pF ) (say, rF 2 η= ( 1.9 × 0.8 3 1 + 0.329 × 0.8 × 1.2820.8 (25.74 )0.8 ) − 1 4 = 1.282 (25.74) rc ), Pr = 0.8 = 1.24 → η = 1 0.368 0.361 So, this offers perfect film cooling, meaning Tc = 1600 K 2 (3200-0.361(3200-700)=2296 K) F Taw = TF = If the wall is made of Cu, and is at Tw = 700K , the reduction in heat flow is qFw q0w = 1600 − 700 = 0.360 3200 − 700 ⎛ 2296 − 700 ⎞ ⎜ 3200 − 700 = 0.638 ⎟ ⎝ ⎠ which can be decisive. 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 11 of 12 (This example shows one could get good film cooling with much less than 10% flow in the film, maybe with only 2%). 16.512, Rocket Propulsion Prof. Manuel Martinez-Sanchez Lecture 10 Page 12 of 12