Wave or Particle ? Niels Bohr 1885-1962 Nobel Prize in Physics 1922 Werner Heisenberg 1901-1976 Nobel Prize in Physics 1932 Wave or Particle ? • A particle is a localized object, a wave is not • How does “it” go from waves to particles ? • Wave-particle duality ? Localization of a wave ? Consider a single wave: y(x,t) = A cos(kx-ωt) ħ MOMENTUM: The wave number k=2π/λ and the De Broglie wavelength λ = h/p k = 2πp/h = p/ In this case: k is well defined the momentum p = k is also very well defined x (arbitrary units) ħ POSITION: Where is the wave ? Everywhere (within the limit of the “definition” of the wave) Localization of two superposed Waves ? Consider 2 waves: y(x,t) = A cos(k1x-ω1t) + A cos(k2x-ω2t) with k1 close to k2 [BEATS!] = 2 A cos(½[(k 1-k2)x-(ω1-ω2)t]) cos(½[(k 1+k2)x-(ω1+ω2)t]) Posing ∆k=k1-k2 and ∆ω=ω1-ω2: y(x,t) = 2 A cos(½[∆kx-∆ωt]) cos(½[(k 1+k2)x-(ω1+ω2)t]) POSITION: Where is the “particle” ? Still not really localized, but now some “regions of space” seem more likely to contain the particle than others. λenvelope/2 The particle is between x1 and x2: x2-x1 = λenvelope/2 = π/(½∆k) Posing ∆x = x2-x1: ∆x∆k=2π ħ MOMENTUM: The momentum is now only known within ∆p= ∆k x1 x2 We gained a better knowledge of x, but we are losing our “perfect” knowledge of p More Waves ? 3 Waves Adding more waves: ∆x decreases ∆k increases 5 Waves ∆x.∆k~1 One can show similarly that: ∆ω.∆t~1 9 Waves ħ (Energy: E = hν = (2π)ν = ω) ħ 7 Waves Uncertainty relations between: Position and Momentum Energy and Time Particles can be represented by wave packets The double slits experiment with photons From: Quantum (J. Al-Khalili) • What about sending one photon at a time ? INTERFERENCE EFFECT ! The double slit experiment with electrons • 1961: C.Jonsson manages to produce very narrow slits to observe the interference effects due to the wave-like behavior of the electrons. Which slit ? (I) One slit blocked No interference Pictures from: Quantum (J. Al-Khalili) Which Slit ? (II) A apparatus is placed to detect when one photon goes through the top slit. Detector On NO INTERFERENCE ! Detector Off INTERFERENCE ! Pictures from: Quantum (J. Al-Khalili) Measurements and Quantum systems • To determine which slit the electron went through: We set up a light shining on the double slit and use a powerful microscope to look at the region. After the electron passes through one of the slits, light bounces off the electron; we observe the reflected light, so we know which slit the electron came through. • Use a subscript “ph” to denote variables for light (photon). Therefore the momentum of the photon is • The momentum of the electrons will be on the order of • The difficulty is that the momentum of the photons used to determine which slit the electron went through is sufficiently great to strongly modify the momentum of the electron itself, thus changing the direction of the electron! The attempt to identify which slit the electron is passing through will in itself change the interference pattern. Principle of Complementarity • Bohr’s principle of complementarity: it is not possible to describe physical observables simultaneously in terms of both particles and waves • Consequence: once you measure the wave- (particle-) like behavior of a phenomenon, you cannot measure a property linked to its particle- (wave-) like behavior. – e.g. once you determine that the photon/electron has made it through a given slit, you reveal its particle-like behavior, therefore you cannot observe the interference phenomenon anymore (linked to the wave behavior) ! Niels Bohr’s Coat of Arms (1947) “Opposites are Complementary” Heisenberg Uncertainty (I) • It is impossible to measure simultaneously, with no uncertainty, the precise values of k and x for the same particle. The wave number k may be rewritten as • For the case of a Gaussian wave packet we have Thus for a single particle we have Heisenberg’s uncertainty principle: Heisenberg Uncertainty (II) with ∆x~l/2 [we know the particle is located between 0 and l ] • If we are uncertain as to the exact position of a particle, for example an electron somewhere inside an atom, the particle can’t have zero kinetic energy. • The energy uncertainty of a Gaussian wave packet is combined with the angular frequency relation • Energy-Time Uncertainty Principle: The Copenhagen Interpretation From: Quantum (J. Al-Khalili) • “No one knows what happens behind the quantum curtain… but we should not care!” • Physics only depends on the outcomes of measurements (in other words: only the results count… ) Other interpretations… • De Broglie - Bohm • Many-Worlds • …