11/20/13 Atmos. Chem. Lecture 19, 11/20/13: Aerosol chemistry (inorganic) Chemical compositon of fne PM HN03 + NH3 + H20 mixtures H2S04 + NH3 + H20 mixtures H2S04 + HN03 + NH3 + H20 mixtures PSet 4 due Mon Nov 25 Fine partcles can travel deep into the lungs "Harvard Six Cites Study": fne partcle loading correlates with increased mortality; associated with lung cancer and cardiopulmonary disease !ncreased rate of mortality Health efects of partculate mater H T S L W © American Thoracic Society. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/help/faq-fair-use/. D. W. Dockery et al., New Engl. J. Med. 329 1753-1759 (1993) and F. Laden et al., Am. J. Resp. Crit. Care Med., 173, 667-672 (2006) 1 KK?LJ?KM !%"$'%('+"-'&'&(*-0$,%/* 0*&;9&,2'*#+ *0*$; &,2'*# !!!!"##! !%"$'%('+"-'&'&(*-0$,%/* '* &" +0$, &",*, %%'&"0% %(''+ L KK?LJ?KM &*$+'0*+'*'+'$ '*+%'CYL<Oμ%D;!&"$$4@ &*,*'+'$ @+@+(*4 @2"&@$'2&0+,C*0+,$%,*"$D "&%'CXL<Oμ%D;+@,'@(*-$'&1*+"'& @&",*,CM@D @+0$,CNL@D @ %%'&"0%CNWD @ !$'*"C$@D @'* &"+ &'* &" +@(*-$(*--'&"& ;1*4$'2"&1'$-$",4CKJ@O'**D9%'+,$4"&'&&+(!+ ;1('*(*++0*'FQPJJ'**A!" !$41'$-$ E'L<P3KJO?,%A1*4+'$0$ ;1('*(*++0*'FOJ'**A1'$-$ E'L<O3KJP?,%A1*4+'$0$ M 11/20/13 Interacton of liquid water with inorganic ions © John Wiley and Sons. All rights reserved. This content isexcluded from our Creative Commons license. For more information, see http://ocw.mit.edu/help/faq-fair-use/. S&P Ammonium nitrate (s): HN03 + NH3 Below the DRH (61.8% at 298K) NH4N03(s) � NH3(g) + HN03(g) © John Wiley and Sons. All rights reserved. This content isexcluded from our Creative Commons license. For more information, see http://ocw.mit.edu/help/faq-fair-use/. Stelson and Seinfeld 1982a (Atm. Env. 16:993) Mozurkewich 1993 (Atm. Env. 27A:261) S&P 4 KK?LJ?KM KJJ %%'&"0%&",*,C)D; MWMWL '1,!CPK<RV,LSRD KJ NWC)DWM@ C)D MC DWMC D K ,$+'&&"&$KSRL C% %KP;LOJQD +,!"+CG" KJ<LK7D'* NM)0"$"*"0%'&+,&,+ J<K Courtesy of Elsevier, Inc., http://www.sciencedirect.com. Used with permission. LNWMWL+4+,% MJV QOV +'0++("+; LNC D9MC D9LC D )0'0++("+; N@ C)D9N@LC)D9MC)D9 NWC)D9WC)D +'$"+("+; NNC+D9CNDLNC+D9 CNDMCNDLC+D E E $")0"+("+; LC$D © John Wiley and Sons. All rights reserved. This content is excluded from our CreativeCommons license. For more information, see http://ocw.mit.edu/help/faq-fair-use/. & O KK?LJ?KM MWLNWMWL+4+,% +'0++("+; LN9M9M9L )0'0++("+; N@9N@L9M9M@9NW9W +'$"+("+; NN9CNDLN9NM9 CNDMCNDL9CNDLNLNM9 CNDLNMNM $")0"+("+; LC$D & $ +'. $ %& ' !!!!"##! &$"&$0$,'*+ 3,&*'+'$ &'* &"'$C@ D# #" !/(;??222<"%<&1<0<<0#?"%?"%<(!(? !/(;??&&+<+< ,!<0? ? P KK?LJ?KM MWLNWMWL+4+,% M M M M H 2LSO 4 N M M H 2LSO 4 N M M M M M M [Note: Additional material is discussed here during lecture.] *+"& ;L99'*M8 & $QJV $ %& ' !!!!"##! Q 0,72SHQ&RXUVH:DUH KWWSRFZPLWHGX ---$WPRVSKHULF&KHPLVWU\ )DOO )RULQIRUPDWLRQDERXWFLWLQJWKHVHPDWHULDOVRURXU7HUPVRI8VHYLVLWKWWSRFZPLWHGXWHUPV