Ultra-thin flat lenses made of Graphene Sunan Deng, Kyle Jiang, Haider Butt School Mechanical Engineering University of Birmingham Birmingham B15 2TT, UK Abstract—Flat lenses can be made very thin and have the advantages of being aberration free when compared to curved surface lenses. They offer a compact design for a myriad of electro-optical applications, such as solar cell and fiber communication systems. This paper reports research into Fresnel zone plate, which is a flat lens constructed by graphene rings. Low number multilayer graphene was formed into Fresnel zone plates which utilize the reflection and transmission properties of graphene for their operation. The lenses and their performance in the visible regimes were analyzed computationally. Experimental measurements were also performed and good agreements were obtained with the modelling results. The work demonstrates the feasibility of atom thick graphene-based lenses, showing perspectives for ultra-compact integration. Keywords—graphene; flat lens; Fresnel zone plate I. INTRODUCTION A flat lens focuses light by changing the phase of light with surface structure in nano or micro scale, while traditional curved lens focuses light by propagating light in the lens for a distance. A flat lens provides the possibility to revolutionize the design of compact optical systems as it can be made very thin, even thinner than the wavelength of light. More importantly, flat lenses do not have imaging distortions, which is a big problem for traditional lenses. Previously aberration was corrected by techniques such as aspheric shapes or multilens designs, resulting in heavy weight and extra space. That problem can be avoided by using flat lenses, leading to ultrathin lenses, and Fresnel zone plate provides a suitable solution. A Fresnel Zone Plate (FZP) consists of a series of radially symmetric transparent and opaque rings. As it offers the possibility of designing high numerical aperture (NA) lens with low weight and small volume, FZP lenses are widely used in the optical industry and are key elements in systems like optical interconnects, beam focusing and integrated optics [1]. We explore the possibility of developing the thinnest lens by using graphene. Graphene has some excellent optical properties, especially the tunability under different Fermi levels. In the visible light regime, optical transmittance for single layer graphene is determined solely by the fine structure constant, α=e2/ħc, where c is the speed of light, and 𝑇 ≡ transmittance, the reflectance of mono-layer graphene under normal light incidence is relatively weak as defined by 𝑅 = 0.25𝜋 2 𝛼 2 𝑇 = 1.3 × 10−4 . However, the reflection will increase linearly with the number of layers, with 𝑁𝜋𝛼 for N layer graphene. Unlike single-layer graphene, according to Skulason et al.[3], few-layer graphene could have very high reflection contrast, indicating the possibility of making FZP lens of graphene on glasses. In this paper, the lensing effect of graphene FZP lens under light of wavelength 850 nm was studied through FDTD modelling. We choose 850 nm because it is one of the most important optical communication windows. Then graphene FZP lens array were fabricated by CVD and photolithography processes. Characterization using microscope shows that these lenses have the ability of focusing light with high contrast. The lenses were found to be thinner, more efficient, and easier to fabricate compared to the metasurface based flat lenses. This research confirms the possibility of making ultra-thin lens with graphene, which can play a key role in developing compact optical systems, such as laser focusing for optical storage and fire-optic system. II. DESIGN OF THE GRAPHENE FZP LENS The focal length f of an FZP lens is related to the radii r of successive zone edges. By means of an approximation for large focal lengths, the radius of different zones satisfies equation [4] : 𝑓 𝑟𝑛 𝑟 = 𝑛𝜆𝑛 ( where λ is the wavelength of light, n = 1, 2, 3…), and the radius of the nth zone (𝑟𝑛 ) in a FZP lens is given by 𝑟𝑛 = √𝑛𝑟1 . In this work, the lens was designed by setting the focal length to ~120 µm at an optical wavelength of 850 nm. The spacing and widths of the Fresnel zones were calculated with relation to n. Fig. 1 shows a three-dimensional schematic diagram of the FZP geometry and its operation. The radius of the central zones was 10 µm and the lens radius was about 49 µm. Light comes from the right side, then is reflected and diffracted by the FZP lens before being focused in the focal plane. 2𝜋𝐺 −2 (1 + ) ≈ 1 − 𝜋𝛼 ≈ 0.977, in which G = e2/4ħ is 𝑐 universal conductivity of graphene [2]. Compared with 978-1-4673-8156-7/15/$31.00 ©2015 Crown focusing effect of the graphene-based FZP lens. The red lines in Fig. 2(b) and (d) represent power flow extracted at x=0 and y at the focal plane in Fig. 2 (a) respectively. The focal length in the simulation is 114.5 nm, which is very close to the theoretical value. Fig. 1. A schematic showing the geometry and reflection mode operation of a graphene Fresnel zone plate. The incident light is from right. III. SIMULATION 2D simulation was performed owing to the radial symmetry of the Fresnel zone plates, with light coming from Y direction and graphene FZP lens with glass substrate on XZ plane. The computed electric field distribution of light reflected by 5-layer graphene FZP/glass structure are shown in Fig. 2[5] (a). High contrast focal point can be observed, which confirms the Fig. 2(b) compares the electric field distribution along the vertical lines (x=0) at the focal point of graphene FZP lens with (red line) and without (black line) glass substrate. Compared with results without glass substrate, the wave shapes in the red curves are interference effects produced by the glass substrate, which could tell from the green line generated from 5 µm thick glass substrate. When the interference influence was subtracted from the red curve, very clear focusing effect was obtained, shown as blue line B-A, which is very similar to the black line. Thus it can be concluded that the focal effect is leaded by graphene FZP lens while the interference is contributed by the glass substrate. The assumption were further confirmed by Fig.2 (c) and (d), in which 5-layer and 10-layer graphene FZP lenses on glass substrate have almost identical interference curves, but shows obvious difference at the focal point position. 10-layer graphene FZP lens contributes more to the focal lensing effect than 5-layer lens is because that the reflection of graphene will increase with the number of layers. Fig. 2. [5] Graphene FZP lens on glass substrate. (a) Power flow reflected from 5-layer graphene FZP lens on glass substrate with 850 nm incident light (Fermi level 0.1 eV) (b) Power flow extracted from x=0, across y-axis. The green line, red line and black line represent power flow when light is shined on glass substrate, graphene lens /glass substrate, and a graphene lens respectively. The blue line is get from subtracting the green line from the red line. The power flow distribution of the horizontal and vertical cross sectional via focal point for 5-layer (green lines) and 10-layer (red lines) graphene lenses are demonstrated in (c) and (d). Multi-layer graphene were synthesized by chemical vapour deposition method [6, 7]. Based on the modelling results, graphene FZP lenses were fabricated by photolithography processes. The lenses could work both in reflection and transmission mode of operation, as shown in Fig. 3, which are characterizations under Alicona microscope. middle. In this mode, the focal point was produced within the glass substrate. Then by adjusting the focal position of the microscopy, the focal point in reflection mode was obtained, as shown in Fig.3 (c). It is found that the intensity of the focal point in the reflection mode is lower than that in the transmission mode, which is corresponding with the optical properties of graphene. Fig. 3(a) shows a magnified single graphene FZP lenslet on glass substrate. The brighter areas are graphene while the darker areas are glass with graphene etched away, which shows good reflection optical contrast of few layer graphene on glass. Fig. 3(b) shows good performance of the lens work in transmission mode with high contrast focal point in the The experimental focal length of graphene FZP lens is 175um±10um, with visible incident light. According to the work principle of FZP lens, it can be derived that the incident light wavelength ranges from 540.5 nm to 606 nm, which are in the visible regime. Hence, the experimental data agree well with the theoretical value. IV. FABRICATION AND CHARACRIZAITON Fig. 3. [8] A single graphene FZP lenslet zoomed under optical microscope. (a) Magnified single graphene lenslet. (b) Graphene lens work as a transmission lens. (c) Graphene lens work as a reflection lens To study the surface profile of the multi-layered graphene lens, measurements were carried out using atomic force microscope (AFM), as shown in Fig. 4. The bright spots in Fig. 4(a) arise from the polymer residue post lithography and lead to artifacts in AFM images i.e. the black lines in Fig. 4(a). Fig. 4(b) shows the height distribution along the radial blue line in Fig. 4(a). The Fresnel zone is clearly shown in its surface profile and the average surface roughness measured 3.47 nm, which corresponds to approximately 10 layers of graphene. Fig. 4. [8] (a) An AFM image of a single graphene Fresnal zone plate. (b) Roughness distribution along the blue radial line in (a). V. CONLUSION In conclusion, we have developed ultrathin graphene-based FZP lenses on glass with nanoscale roughness. The lenses were designed to operate in the optical regime and fabricated by lithography technique. Their focusing properties were characterized. The lenses were found to be extremely thin, efficient, and easy to fabricate compared to the metasurface based flat lenses. Hence graphene FZP lens are highly promising as flat and ultrathin lenses. They have the potential to revolutionize the design of compact optical systems, such as laser focusing for optical storage and fiber-optic communications. ACKNOWLEDGMENT The authors would thank The Leverhulme Trust for the research funding. This research is partly funded by the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement No 644971. REFERENCES [1] [2] [3] [4] [5] [6] [7] [8] H. Butt, R. Rajesekharan, Q. Dai, S. Sarfraz, R. V. Kumar, G. A. Amaratunga, et al., "Cylindrical Fresnel lenses based on carbon nanotube forests," Applied Physics Letters, vol. 101, p. 243116, 2012. R. Nair, P. Blake, A. Grigorenko, K. Novoselov, T. Booth, T. Stauber, et al., "Fine structure constant defines visual transparency of graphene," Science, vol. 320, pp. 1308-1308, 2008. H. Skulason, P. Gaskell, and T. Szkopek, "Optical reflection and transmission properties of exfoliated graphite from a graphene monolayer to several hundred graphene layers," Nanotechnology, vol. 21, p. 295709, 2010. Y.-H. Fan, H. Ren, and S.-T. Wu, "Switchable Fresnel lens using polymer-stabilized liquid crystals," Optics Express, vol. 11, pp. 30803086, 2003/11/17 2003. S. Deng, A. K. Yetisen, K. Jiang, and H. Butt, "Computational modelling of a graphene Fresnel lens on different substrates," RSC Advances, vol. 4, pp. 30050-30058, 2014. P. R. Kidambi, B. C. Bayer, R. S. Weatherup, R. Ochs, C. Ducati, D. V. Szabó, et al., "Hafnia nanoparticles–a model system for graphene growth on a dielectric," physica status solidi (RRL)-Rapid Research Letters, vol. 5, pp. 341-343, 2011. K. Xi, P. R. Kidambi, R. Chen, C. Gao, X. Peng, C. Ducati, et al., "Binder free three-dimensional sulphur/few-layer graphene foam cathode with enhanced high-rate capability for rechargeable lithium sulphur batteries," Nanoscale, vol. 6, pp. 5746-5753, 2014. C.-F. Chen, C.-H. Park, B. W. Boudouris, J. Horng, B. Geng, C. Girit, et al., "Controlling inelastic light scattering quantum pathways in graphene," Nature, vol. 471, pp. 617-620, 03/31/print 2011.