Research Journal of Environmental and Earth Sciences 4(4): 419-423, 2012 ISSN: 2041-0492 © Maxwell Scientific Organization, 2012 Submitted: December 16, 2011 Accepted: January 08, 2012 Published: April 15, 2012 Ambient Particulate Matter Monitoring - A Case Study at Tarkwa Kenneth J. Bansah and Newton Amegbey Mining Engineering Department, University of Mines and Technology, Tarkwa, Ghana Abstract: Air pollution from airborne particulates remains a major concern of the communities within the mining areas. In Ghana, little research has been done to ascertain the health implications of living around the mine sites. This study studied ambient particulate matter less than 10 :m (PM10) pollution at Gold Fields Ghana Limited (GFGL) mine residence in Tarkwa. A four-month PM10 monitoring was performed at GFGL mine residence. The Gaussian Dispersion Model was also used to predict the concentration of PM10 in the Tarkwa Township. The results show that 13% of the PM10 concentrations obtained exceeded the Ghana Environmental Protection Agency’s threshold limit of 70 :g/m3. The dispersion model indicated that PM10 generated from GFGL attains a concentration of 68 :g/m3 when it reaches the Tarkwa Township. Key words: Airborne particulates, air pollution, health implications, tarkwa, threshold limit INTRODUCTION selected as the study area. This study therefore, looks at PM10 levels and the possible impacts on residents at Gold Fields Ghana Limited mine site and the Tarkwa Township as a whole. Air pollution from airborne particulates is a major concern of the communities within the mining areas. Gold Fields Ghana Limited (GFGL), Tarkwa, Ghana operates an open pit mine. The mining activities involve overburden removal, drilling, blasting, loading, hauling and ore crushing. These activities together with increased vehicular movements on the untarred roads within and around the mine sites introduce particulates into the atmosphere. Particulates, when inhaled can evade the system’s natural defences and lodge deep in the lungs, leading to lung and heart diseases. Zinatunor (1998), researched into pollution of ambient air by particulate matter less than 10 :m (PM10) at the Tarkwa Township in Ghana. During the period, a six-month data was collected. The results show that 60% of the PM10 concentrations obtained exceeded the Environmental Protection Agency of Ghana (EPA) threshold of 70 :g/m3. A conclusion drawn was that “mining activities in Tarkwa pose a serious particulate pollution threat to the Tarkwa Township”. Amegbey and Ndur (2000) concluded that surface mining activities around the Tarkwa town have contributed to increased air borne particulate matter within the township. It also recommended that further studies into particle pollution in Tarkwa must be carried out. The studies must include dispersion modeling and particulate analysis in order to determine the sources contributing to the dust levels in the Tarkwa Township. In trying to solve particle pollution due to mining, in the Tarkwa Township, Gold Fields Ghana Limited (GFGL) residence which is most likely to be affected was Location, relief, topography and climate of GFGL: Gold Fields Ghana Limited, Tarkwa Mine, is located off the Tarkwa-Bogoso highway, about 1.5 km from Tarkwa in the Western Region of Ghana. Tarkwa Township has a population of about 41000. The topography of the mine comprises of ragged ridges with peaks reaching a height of 335 m above mean sea level in some areas, interspersed by undulating valley bottoms and a true reflection of the pitching fold structures of the Banket Series of the Tarkwaian System. Elevation in the area ranges from approximately 60 to 225 m. The central area of the mine is low lying and flatter and does not show the variations in elevation typical of the south and eastern areas near Tarkwa and Akontansi (Akurang, 2008). The mining area falls within the western equatorial climatic zone, with seasons primarily regulated by moist, south-west monsoon winds from the South Atlantic Ocean and dry dust-laden north-east trade winds, known as Harmattan, which blows over the Sahara Desert from the northern sub-tropical high pressure zone . The inter Tropical Convergence Zone crosses the mining area two times per year, causing hydrometeorological data including rainfall to peak during two periods; April to June and October to November. The mean annual rainfall is approximately 1933 mm; with a range of 1100 to 2600 mm. Average monthly temperatures range between 24 and 28°C, with the highest Corresponding Author: Kenneth J. Bansah, Mining Engineering Department University of Mines and Technology, Tarkwa, Ghana 419 Res. J. Environ. Earth. Sci., 4(4): 419-423, 2012 120.000 EPA Guideline 100.000 Concentration (g/m 3 ) Concentration (g/m 3 ) Concentration (g/m 3 ) Concentration (g/m 3 ) 120.000 80.000 60.000 40.000 20.000 EPA Guideline 100.000 80.000 60.000 40.000 20.000 f eb 2- M 4-M ay -08 a 6- M y - 08 a 8- M y - 08 a 10- y - 08 Ma 12- y - 08 Ma 14 y - 08 -M 16 ay -0 -M a 8 18 y - 08 -M 20 ay -0 -M 8 22 ay -08 -M 24- ay -08 M 26- ay -0 Ma 8 28 y - 08 -M 30 ay -08 -M ay 08 - 08 0.000 29 - 8 - 08 28 - b- 0 -f e 27 f eb 8 - 08 26 -f e b- 0 - 08 f eb f eb 25 - 24 - 8 - 08 f eb 23 - - 08 b- 0 f eb -f e 21 - 22 8 8 -f e b- 0 20 19 -f e b- 0 0.000 Days of the month Days of the month Fig. 1: PM10 concentration profile for February 2008 Concentration ( g/m 3 ) 100.000 Fig. 4: PM10 concentration profile for May 2008 Concentration ( g/m 3 ) EPA Guideline characterized by dry weather conditions, although there were few millimeters of rain. In all, 110 PM10 data were collected using the PQ100 Air Sampler. Five of the samples were discarded due to mishandling and moistening of the filter membranes. The procedure adopted for the particulate sampling with the PQ100 Air Sampler is as follows: 80.000 60.000 40.000 20.000 1-M a 3 - M r- 0 8 a 5 - M r- 0 8 a r7 - M 08 9 - M a r- 0 8 a 11 - r- 08 Ma 1 3 - r- 0 8 M 1 5 - a r- 0 8 M 1 7 - a r- 0 M 8 1 9 - a r- 0 8 Ma 2 1 - r- 0 Ma 8 2 3 - r- 0 8 Ma 2 5 - r- 0 8 M 2 7 - a r- 0 8 Ma 2 9 - r- 0 8 Ma r- 0 8 0.000 C Days of the month C Fig. 2: PM10 concentration profile for March 2008 Concentration (g/m ) 3 Concentration ( g/m 3 ) 120.000 C EPA Guideline C 100.000 80.000 60.000 C 40.000 20.000 C 1- A pr 3- A - 0 8 p 5 - A r- 0 8 p 7 - A r- 0 8 pr 9- A - 0 8 p 1 1 - r- 0 8 Ap 1 3 - r- 0 8 Ap 1 5 - r- 0 8 Ap 1 7 - r- 0 8 Ap 1 9 - r- 0 8 A 2 1 - p r- 0 8 Ap 2 3 - r- 0 8 A 2 5 - p r- 0 Ap 8 2 7 - r- 0 8 A 2 9 - p r- 0 Ap 8 r- 0 8 0.000 A 47 mm Whatman filter is weighed with a microbalance in a temperature and humidity controlled filter weighing room and inserted in the filter cassette. The weighed filter is placed in the PQ100 Air Sampler filtering unit. With a flow rate of 16.7 Lpm, the pump of the PQ100 is set to run for 24 h. The filter with the particulate sample is removed from the system and weighed after the 24 h sampling duration. The contaminant weight is determined by the difference between the post and pre-sampling filter weights. With the contaminant weight, the sampling duration and flow rate, the concentration of the particulate is determined according to Eq. (1): Concentration(:g/m3) = Contaminants Weight (1) (mg)×1000/ Total Sample Volume (m3) Days of the month Fig. 3: PM10 concentration profile for April 2008 Contaminant weight is the difference between initial filter weight and final filter weight in milligrams, and Total sample volume is the volume of air passed through the filter in cubic meters. The PM10 concentrations obtained during the period under review were plotted to determine whether these concentrations exceeded the EPA guideline value. Figure 1, 2, 3 and 4 illustrate the monthly variations in PM10 concentrations at GFGL. While the maximum PM10 concentration was 110 :g/m3, the minimum concentration temperatures recorded during February and March. Annual evaporation is much less than the annual precipitation, although evaporation losses from surface water bodies can be significant during the few dry months of the year (Akurang, 2008). PM10 monitoring and results: A 24 h PM10 monitoring was conducted for 110 days at GFGL residence. The monitoring activity started from the 19th of February and ended on the 7th of June 2008. This period was mainly 420 0.01 0.2 0.1 0.05 0.5 2 1 5 10 20 50 40 30 60 70 80 90 95 98 99 99.9 99.8 99.99 Res. J. Environ. Earth. Sci., 4(4): 419-423, 2012 1 9 8 7 6 5 4 3 EPA Guideline value Geometric mean 1 9 8 7 6 5 4 3 2 99.99 99.9 99.8 99 98 95 90 80 60 70 40 50 30 20 10 5.0 2.0 0.5 1.0 0.01 0.05 0.1 0.2 1 9 8 7 6 5 4 3 Concentration (g/m 3 ) 2 2 Probability Fig. 5: Probability versus mass concentration Concentration (g/m3) was 1.3 :g/m3. These concentrations were respectively recorded on 120 12 and 18th April, 2008. The average PM10 concentration 100 over the period of study was calculated to be 27 :g/m3. 80 The PM10 concentrations were further grouped into 68 60 concentration ranges. The probability that a given concentration will not be exceeded was calculated. A 40 graph of these probabilities versus the upper class limit 20 values of the concentration range was plotted on a log0 probability graph paper (Fig. 5). From the graph, the 6 0 1 3 8 2 5 4 7 Tarkwa Distance (km) probability that a given concentration will fall below the EPA guideline value is read to be 87%. Thus the Fig. 6: Distances versus PM10 concentrations probability of obtaining a concentration higher than the EPA guideline value is 13%. The geometric mean is also z = Vertical distance from ground level, m read to be 30 :g/m3. H = Effective stack height, m PM10 modeling and results: The Gaussian Dispersion Model was used to predict the concentration of PM10 in With a stack height of 30 m at the processing plant the Tarkwa Township. The Model is given by Eq. (2) and 1 m (assumed) for each of all other particulates (Cooper and Alley, 2002): emission sources, the effective stack height (H) was calculated to be 16.5 m. This is as a result of the 2 assumption that 50% of the emissions come from the Q H (2) C exp processing plant while 50% come from other sources. 2 y z 2 z Other parameters include a wind speed (:) of 0.65 m/s, emission rate (Q) of 306956 :g/s and a slightly stable atmosphere. Modeling was performed over a distance up where: C = steady-state concentration at a point (x, y, z), :g/m3 to about 7 km. The result of the modeling is illustrated in Fig. 6. Q = Emissions rate, µg/s Fy, Fz = Horizontal and vertical spread parameters DISCUSSION respectively, m µ = Average wind speed at stack height, m/s The minimum and maximum concentrations were 1.3 y = Horizontal distance from plume centerline, m and 110 :g/m3, respectively. While for 87% of the time 421 Res. J. Environ. Earth. Sci., 4(4): 419-423, 2012 Fig. 7: Relative positions of gold fields Ghana limited and tarkwa township Figure 7 shows the relative positions of GFGL and Tarkwa. A wind rose with predominant wind direction of North-East over the study period has also been superimposed on Fig. 7. Conventionally, a wind rose shows the various directions from which the wind blows. However, for easy interpretation of Fig. 7, the superimposed wind rose indicates the directions to which the wind blows. It could be seen from Fig. 7 that particulates emitted from GFGL can be transported by the wind towards the Tarkwa Township. concentrations fell below the threshold limit value (TLV) of 70 :g/m3 set by the Environmental Protection Agency of Ghana, for 13% of the period of measurement particulates concentration exceeded the EPA limit. Data available from February to May 1998 indicates an average PM10 concentration of 114 :g/m3 in the Tarkwa Township (Zinatunor, 1998). However, during the period under review, the average concentration was 30 :g/m3. This reduction in PM10 concentration may be due to increase dust suppression activities by GFGL. Moreover, most of the roads within and around the Tarkwa Township currently, have been tarred. It is interesting to note also that the highest PM10 concentration of 110 :g/m3 was recorded only once, during the period of study. This single highest concentration is lower compared to the average PM10 concentration in 1998. The results of particulates modeling show that PM10 concentration exceeded the 70 :g/m3 threshold set by EPA, within a distance of about 1.3 km from the mine. Also, PM10 generated from GFGL attains a concentration of 68 :g/m3 when it reaches the Tarkwa Township. As expected, the concentration of PM10 decreased as the distance of transportation increased (Fig. 6). This occurs due to the fact that, as particulates are transported, they come into contact with each other, coagulate and fall by gravity. Some particles may also react with other substances to form secondary particulates, which can get deposited by dry or wet deposition. Others may adhere themselves to water droplets, increasing their aerodynamic diameters as well as their settling velocity. An increase in wind speed will also cause dilution of PM10. CONCLUSION Analysis of data collected and subsequent study of the results obtained, revealed that PM10 levels at Gold Fields Ghana Limited mine residence exceeded the Environmental Protection Agency’s threshold limit of 70 :g/m3, 13% of the time. Particulates emitted from GFGL attain a concentration of about 68 :g/m3 on reaching the Tarkwa Township. ACKNOWLEDGMENT The authors wish to acknowledge the support of Mr. Steve Gyan and all the staff of the Environmental Department of GoldFields Ghana Limited who contributed to the success of this research. REFERENCES Akurang, J., 2008. A Study of the Drilling and Blasting Practices at Goldfields Ghana Ltd. BSc. Project Report, (Unpublished), University of Mines and Technology, Tarkwa, Ghana, pp: 8-15. 422 Res. J. Environ. Earth. Sci., 4(4): 419-423, 2012 Amegbey, N. and S. Ndur, 2000. Air Particulate Matter Monitoring in a Major Ghanaian Town. The Case Study of Tarkwa. Environmental Issues and Management of Waste in Energy and Mineral Production, Singhal and Mehrotra (Eds.), Balkema, Rotterdam, pp: 10. Cooper, C.D. and F.C. Alley, 2002. Air Pollution Control, a Design Approach. 3rd Edn., Waveland Press, Inc. Long Grove, Illinois, pp: 738. Zinatunor, K., 1998. Ambient air particulate matter monitoring in the tarkwa township. Ph.D. Thesis, Report, (Unpublished), Tarkwa School of Mines, Tarkwa, Ghana, pp: 66. 423