LITHOS-02063; No of Pages 14 ARTICLE IN PRESS Lithos xxx (2009) xxx–xxx Contents lists available at ScienceDirect Lithos j o u r n a l h o m e p a g e : w w w. e l s e v i e r. c o m / l o c a t e / l i t h o s Hot and deep: Rock record of subduction initiation and exhumation of high-temperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California Christopher M. Smart, John Wakabayashi ⁎ California State University, Fresno, Department of Earth and Environmental Sciences, 2576 E. San Ramon Avenue, Mail Stop ST-24, Fresno, CA 93740, USA a r t i c l e i n f o Article history: Received 23 July 2008 Accepted 6 June 2009 Available online xxxx Keywords: Subduction initiation Metamorphic soles Ophiolites High-pressure rock exhumation a b s t r a c t Studies of a 10 to 300-m-thick unit of high-grade metamorphic rock (“external schists”) that crops out along the western border of the Feather River ultramafic belt (FRB), northern California, yield new insights into subduction initiation and ophiolite emplacement processes. The high-temperature (T) foliation of the external schists dip moderately to steeply eastward beneath the ultramafic rocks of the FRB, a 150-km-long slab of suboceanic upper mantle and the high-T fabric shows a tops-to-the-west (FRB-side-up) sense of shear. The structurally highest external schists record peak metamorphic conditions of 650–760 °C at 1.3– 2.2 GPa. In contrast, sheeted dikes of the Devil's Gate ophiolite that overlie the ultramafic rocks yield metamorphic conditions of 710–730 °C at about 0.3–0.7 GPa. A km-scale lens of amphibolite within ultramafic rocks yields somewhat lower pressures than the structurally highest external schist, as do the structurally lower rocks within the external schists. Significant exhumation of the external schists relative to the structurally overlying ophiolitic rocks occurred along at least two major zones and the most significant exhumation was accommodated at least 1.5 km structurally above the ultramafic-external schist contact. Based on available geochronology, intraoceanic subduction may have initiated at approximately 240 Ma, and exposure of the external schist occurred prior to the deposition of rocks in the structurally highest part of the Calaveras Complex (minimum 177 Ma), a subduction complex that structurally underlies the external schists. High-T metamorphism of the Devil's Gate ophiolite may have resulted from partial (failed) ridge subduction. © 2009 Published by Elsevier B.V. 1. Introduction Mechanisms of subduction initiation are the subject of considerable debate, but most authors agree subduction initiation exploits preexisting weaknesses and material contrasts in the oceanic lithosphere (Casey and Dewey, 1984; Mueller and Phillips, 1991; Stern and Bloomer, 1992; Wakabayashi and Dilek, 2003). Ophiolites are on-land remnants of oceanic crust and many of these ophiolites structurally overlie the position of former subduction zones (e.g., Moores, 1970). Structurally beneath many ophiolites are thin (b500 m) units of highgrade metamorphic rocks called metamorphic or dynamothermal soles. These soles are thought to have formed during subduction initiation beneath young oceanic lithosphere (hot subduction initiation), based primarily on the high temperature of metamorphism recorded in them (peak temperatures in the 700–900 °C range), their lithologies (primarily metabasite with meta-pelagic sediments), and their structural and chronologic relationships with the ophiolite that directly overlies them (Williams and Smyth, 1973; Spray, 1984; Jamieson, 1986; Hacker, 1990). Metamorphic soles commonly have ⁎ Corresponding author. E-mail address: jwakabayashi@csufresno.edu (J. Wakabayashi). inverted metamorphic gradients due to tectonic underplating during subduction of progressively older (and colder) oceanic lithosphere (Peacock, 1987; 1988; Hacker, 1990; 1994; Gnos, 1998), and show anticlockwise pressure–temperature–time (P–T–t) paths (P on positive y-axis) (Wakabayashi, 1990; Dilek and Whitney, 1997; Önen and Hall, 2000; Guilmette et al., 2008). Because metamorphic soles apparently formed during inception of subduction, their geology, and the geology of adjacent rocks, provide insight into the setting and mechanisms associated with hot subduction initiation (i.e. Jamieson, 1986; Hacker, 1990; Guilmette et al., 2008). Although many studies have been conducted on metamorphic soles, some critical aspects of metamorphic sole development have received little attention. For example, metamorphic soles were once assumed to have been “welded” to the base of ophiolites after they were underplated (scraped off the downgoing plate) as subduction began beneath the ophiolite (Williams and Smyth, 1973; Malpas, 1979; Searle and Malpas, 1980). Such a model assumed that no exhumation of the sole relative to the ophiolite occurred after metamorphism. As new geobarometric methods became available, studies showed metamorphic pressures for soles that vastly exceeded that which could be explained by the structural thickness of the ophiolite above the sole, indicating significant exhumation of the sole 0024-4937/$ – see front matter © 2009 Published by Elsevier B.V. doi:10.1016/j.lithos.2009.06.012 Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS 2 C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx amphibolite beneath ophiolites that are too thick (kilometers) to have been generated by conductive heating beneath a hot mantle hanging wall (Harper et al., 1996; Barrow and Metcalf, 2006), highgrade rocks that may have been derived from the base of a magmatic arc instead of from the top of the downgoing plate (Grove et al., 2008), and high-grade metamorphic rocks that structurally overlie, rather than underlie an ophiolite (Dilek et al., 2008). This paper presents structural, lithologic, and metamorphic P–T estimates for an amphibolite unit bordering the Feather River ultramafic belt in northern California. We will review the regional framework of these rocks, then present new field, petrographic, and metamorphic petrologic data that bear on the origin and evolution of these rocks. We will show that structural, lithologic, and petrologic evidence supports a metamorphic sole model for these rocks and the specific field and petrologic relationships give new insight into the exhumation of such rocks and the importance of such exhumation in models of subduction initiation and ophiolite emplacement. 2. Regional setting Fig. 1. Location map. Modified from Edelman and Sharp (1989). Abbreviations are CC: Calaveras Complex, DGO: Devil's Gate ophiolite, RAS: Red Ant schist, SFU: Shoo Fly Complex and other rocks bordering the east side of the Feather River ultramafic belt, WU: Undifferentiated Mesozoic (primarily) and Paleozoic metamorphic and plutonic rocks. relative to the ophiolite (summarized in Wakabayashi and Dilek (2000, 2003). For example, metamorphic pressures estimates range from about 0.95 GPa to 1.8 GPa for different parts of the sole beneath the Semail ophiolite of Oman (Gnos, 1998; Searle and Cox, 2002; Gray and Gregory, 2003), probably the world's most thoroughly studied metamorphic sole. The thickness of the overlying ophiolite can only account for burial pressures of about 0.5 to 0.6 GPa (e.g., Searle and Malpas, 1980). Many ophiolites are much thinner than the Semail ophiolite, and the disparity between pressure estimates associated with metamorphic sole pressures (of about 0.5 to 1.5 GPa) and the potential burial pressure associated with the ophiolite thickness (about 0.1 to 0.4 GPa) may be much greater (e.g., Jamieson, 1986; Guilmette et al., 2008). In addition, studies have identified inverted P gradients (structurally high parts with pressure estimates of about 1.0 to 1.8 GPa to structurally low parts of about 0.3 to 0.4 GPa) within metamorphic soles, indicating major internal imbrication within the sole (Jamieson, 1980; Jamieson, 1986; Gnos, 1998). These metamorphic pressure contrasts have not been addressed in detail in models of subduction initiation (and metamorphic sole development) and ophiolite emplacement (Wakabayashi and Dilek, 2003). Another problem that has introduced complexity into the study of metamorphic soles and subduction initiation processes has been the identification of high-grade metamorphic rocks that are spatially associated with ophiolite belts but do not appear to be classic metamorphic soles as defined above. These include units of The 150-km-long by 1–8 km wide Feather River ultramafic belt (FRB) of the northern Sierran Nevada, California (Fig. 1), comprises variably serpentinized ultramafic rocks, with lesser amounts of metagabbro, metadiabase, and metabasalt; collectively these rocks have been considered an ophiolite (Ehrenberg, 1975; Sharp, 1988; Edelman et al., 1989, Saleeby et al., 1989; Edelman and Sharp, 1989). All rocks of the FRB appear to have undergone peak metamorphism at amphibolite grade, with locally variable retrogression, although there are significant internal differences in peak metamorphic conditions as we will show. The FRB has yielded a rather large range in igneous (two dates of 385 ± 10 and 314 + 10/−8 Ma, U/Pb zircon; Saleeby et al., 1989) and metamorphic ages (about 234 to 387 Ma, Ar/Ar and K/Ar hornblende; Weisenberg and Avé Lallemant, 1977; Standlee, 1978; Hietanen, 1981; Böhlke and McKee, 1984) and it has been called a polygenetic ophiolite (Saleeby et al., 1989) (geochronology summarized in Table 1). In the headwaters of the South Fork Feather River, and Slate Creek, pillow basalts, sheeted dikes, and gabbros crop out structurally above ultramafic rocks of the FRB. These mafic igneous rocks and the subjacent ultramafic rocks have been called the Devil's Gate ophiolite (Edelman et al., 1989), so the Devil's Gate ophiolite may be considered a subunit of the FRB (Fig. 1). Metamorphic age dates obtained from the Devil's Gate ophiolite are 276 ± 6 Ma (Ar/Ar hornblende; Standlee, 1978) and 248 Ma (K/Ar hornblende, Hietanen, 1981). The FRB is faulted along both eastern and western boundaries against rocks of dramatically different age and lithology (Sharp, 1988; Saleeby et al., 1989). East of the FRB is the Shoo Fly complex which consists of Ordivician to Devonian continentally-derived metasandstone and chert deposited that are structurally overlain by a tectonic mélange (Varga and Moores, 1981; Hannah and Moores, 1986). A Devonian to Permian volcanic sequence overlies the Shoo Fly complex at an angular unconformity (Durrell and d'Allura, 1977; Harwood, 1983; Hannah and Moores, 1986). The Shoo Fly Complex has Table 1 Feather River ultramafic belt geochronology. Location Age (Ma) Method Reference Alleghany schist Oriental Mine granite (intrudes Alleghany schist) Metagabbro intruding FRB in Yuba River area Devil's Gate ophiolite Gabbro dike intruding FRB north of Devil's Gate Red Ant schist Metaplagiogranite interlayered with “internal schist” “External schist” 322 ± 27, 345 ± 9; 343.7 ± .6 388 ± 22/−12 285 ± 8 248; 272 ± 6; 387 ± 7 N174 306–324 236 ± 4 K/Ar, hornblende; Ar/Ar, hornblende U/Pb, zircon K/Ar, hornblende K/Ar, hornblende; Ar/Ar, hornblende Ar/Ar hornblende K/Ar, muscovite U/Pb, zircon Ar/Ar hornblende Böhlke and McKee (1984); Hacker (1993) Saleeby et al. (1989) Hietanen (1981) Hietanen (1981); Standlee (1978) Standlee (1978) Schweickert et al. (1980) Saleeby et al. (1989) Weisenberg and Avé Lallemant (1977) Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx undergone pumpellyite–actinolite grade metamorphism in the regions flanking the FRB, (Day et al., 1988; Hacker, 1993). The FRB is faulted against the Calaveras Complex on its west and, locally, the Red Ant schist. The Calaveras Complex is considered a subduction complex composed mainly of phyllite and metachert with blocks of volcanic rocks (Hietanen, 1981; Sharp, 1988; Edelman et al., 1989). In-situ conodonts and fusulinids found in the metasediments indicate that they were deposited at least as late as the Permian and that the unit youngs westward (Hietanen, 1981; Bateman et al., 1985). The subduction–accretion or assembly of the Calaveras Complex was underway by 177 Ma, based on the U/Pb zircon age of a pluton that cross cuts some of the earlier structures within the Calaveras Complex (Sharp, 1988). In the Calaveras Complex is mainly of pumpellyite– actinolite grade in regions adjacent to the FRB (Day et al., 1988; Hacker, 1993). 3 The Red Ant schist consists of quartz-rich schists (metachert and metaclastic rocks) and metavolcanic rocks that underwent blueschist facies metamorphism (Schweickert et al., 1980; Hietanen, 1981; Edelman et al., 1989). The Red Ant schist crops out structurally beneath and west of the Devil's Gate ophiolite, whereas 10 km to the south it occurs east of and structurally beneath the FRB in the North Yuba River area (Edelman et al., 1989). In the North Yuba River area an amphibolite-grade unit, known as the Alleghany schist, is found structurally beneath FRB ultramafic rocks and structurally above Red Ant schist. Radiometric dates on the Alleghany schist are 322 ± 27 and 345 ± 9 Ma (K/Ar, hornblende; Böhlke and McKee, 1984) and 343.7 ± 0.5 Ma (Ar/Ar, hornblende; Hacker, 1993). A K/Ar age on a white mica taken from the Red Ant schist indicates that the metamorphic age of the Red Ant schist is at least 174 Ma (Schweickert et al., 1980). The actual metamorphic age of the Red Ant schist is difficult to interpret Fig. 2. Geologic map of the western border of the Feather River ultramafic belt. Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS 4 C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx because the closure temperature for the white mica may be close to (or have been exceeded by) the temperature of the ubiquitous pumpellyite–actinolite overprint of all of the metamorphic terranes in this part of the northern Sierra Nevada, and because excess argon cannot be directly interpreted in conventional K/Ar results (Hacker, 1993). A thin unit (10 to 300 m thick) of amphibolite, locally garnetbearing, crops out along the west border of the FRB in the North Fork Feather River area (Fig. 2). Williams and Smyth (1973) and Ehrenberg (1975) proposed that these high-grade metamorphic rocks may be a metamorphic sole. Our study focuses on this unit and its structural and metamorphic relationships to adjacent units. 3. Field relationships and structural geology 3.1. Geologic units and lithologies The study area covers ~15 km2 of area near the confluence of the North Fork Feather River and the East Branch North Fork Feather River (Fig. 2) and spans the western border of the FRB, where it is faulted against the eastern Calaveras Complex. The Calaveras Complex and FRB units in this area generally strike northwesterly and dip steeply to the east and are intruded by gabbroic and dioritic bodies that cross cut the major foliation in both the FRB and Calaveras Complex (one of the latter is shown on the northwestern part of Fig. 2). The variably serpentinized ultramafic rocks of the Feather River ultramafic body make up the easternmost and structurally highest unit in the area. In this region, the ultramafic belt is 3–5 km wide. These ultramafic rocks are metamorphosed in amphibolite facies conditions with characteristic minerals such as tremolite, talc, and locally anthophyllite, with antigorite (Ehrenberg, 1975, this study). The tremolite reaches a centimeter in length and is commonly several mm long. These rocks have a metamorphic foliation defined by planar layering of amphibole long-axes. Although foliated, many of these rocks form massive outcrops with relatively sparse fractures. In contrast some outcrops exhibit closely spaced (cm scale or less) fractures or a brittle foliation, and some of these fractured rocks tend to have been retrograded to lower grade serpentinite mineralogy (lizardite-dominated). In this area, crustal rocks are rare within the ultramafic body and this is generally representative of the FRB as a whole (Ehrenberg, 1975). Crustal rocks within the ultramafic body consist of small (less than a hundred meters in long dimension) postmetamorphic dioritic or gabbroic intrusions, and lenses up to 3 km in the long dimension of amphibolite that have been called the internal schists (Ehrenberg, 1975). Saleeby et al. (1989) obtained a U/Pb date of 306–324 Ma for a plagiogranite (tonalite) that intrudes internal schist and Weisenberg and Avé Lallemant (1977) report an Ar/Ar hornblende age of 236 ± 4 Ma from the same unit. The western contact of the ultramafic body, the Rich Bar fault, dips moderately to steeply eastward and appears to steepen in dip or become overturned in the southernmost part of the field area (Fig. 2). This contact is offset by late brittle faults (Fig. 2). Directly west of the contact is a b300 meter thick unit of amphibolite facies metamorphic rocks, the external schist of Ehrenberg (1975), the rocks that have been proposed as a possible metamorphic sole (Williams and Smyth, 1973; Ehrenberg, 1975). The external schist consist primarily of amphibolite, with lesser amounts of metachert (nearly pure quartz with very small amounts of garnet, white mica, and other phases), and somewhat intermediate rock, that we call “quartz-bearing amphibolite” that may have been mafic rock with cm-scale (or less) chert interlayers or lenses. The structurally highest part of the external schist includes garnet amphibolites (Fig. 2). Plagioclase amphibolite or epidote amphibolite make up most of the structurally lower parts of the external schist. The metamorphic grain sizes of most minerals range from tenths of a mm, to about 2 mm for most these rocks. The external schist shows abundant partial melting textures (Fig. 3), indicative of peak metamorphic temperatures above the wet basalt solidus. Some of the external schist in the Rich Bar area (southern part of Fig. 2 along East Branch Feather River) appears bluish in outcrop, but microprobe analyses (see below) show that these rocks lack sodic amphibole or other blueschist facies minerals. West of, and structurally beneath, the external schist crop out slates/phyllites, cherts, and minor metavolcanic rocks of the Calaveras Complex. This unit has the aspect of a melange with a slate/phyllite matrix and chert blocks up to tens of meters or so in long dimension. The structurally highest part of Calaveras Complex rocks exposed near the Beldon Siphon (Fig. 2) appear to have a coarser metamorphic grain size (metamorphic white mica and actinolite to several tenths of a mm) than the very fine grained (hundredths of mm metamorphic grain sizes) rocks that characterize the remainder of the Calaveras Complex in this area. The Beldon Siphon exposures also include what appear to be metamorphosed breccias with clasts of amphibolite and mafic volcanic rocks set in a phyllite or fine white mica quartz schist matrix. A hornblende gabbro dike or small pluton intrudes the Calaveras Complex and cuts the northern section of the external schist in Yellow Creek canyon (“gb” in the northwestern part of Fig. 2). This dike lacks the foliation seen in the Calaveras Complex and external schist and lacks high-grade metamorphism. Additional samples were collected from the Devil's Gate ophiolite, about 40 km southeast of the study area (Fig. 1), for comparison with samples from the field area. Here sheeted dikes and pillow basalts are recognizable despite having been metamorphosed at amphibolite grade (Edelman et al., 1989). 3.2. Structural geology Fig. 3. Photo of melt segregations in external schist. The black arrows point to areas where zones that appear to have been melt rich (felsic material between small pieces of amphibolite restite) restite) feed leucosomes. This location about 15 m north of sample location FR6. The ultramafic rocks, internal schist and external schist exhibit a foliation defined by the planar alignment high-temperature metamorphic minerals that strikes northwest and dips northeast (Fig. 2). Foliations in the southeast portion of the area tend to dip vertically or to the west. The steepening is apparent in the map patterns exhibited by the external and internal schist contacts. Throughout the area the foliations are subparallel to the contact between the external schist and the ultramafic unit. The external schist has a stretching lineation, most easily recognized by the alignment of the long axes of amphiboles. This lineation orientation shows much scatter. Lineations Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx 5 Fig. 4. Photomicrograph of garnet amphibolite sample 92-2. Plane polarized light. Abbreviations: grt: garnet, hbl: hornblende; rt: rutile. Fig. 5. Photomicrograph of sample FR6, a quartz-rich garnet–clinopyroxene amphibolite. Plane polarized light. Abbreviations as for Fig. 4 and: cpx: clinopyroxene, qtz: quartz, ttn: titanite, phen: phengite. plunge direction is tied to the foliation dip, so east-plunging lineations are associated with east-dipping foliation. C and s surfaces, shear bands, and asymmetric porphryclast tails, and asymmetric small-scale (generally centimeter to meter scale) folds in the foliation, consistently ultramafic-side-up sense-of-shear, which is tops-to-the-west for east-dipping foliation. Isoclinal folds are common in the external schist, although these are most easily observed only in outcrops that show pronounced compositional layering. Amplitudes of these folds vary from centimeter scale to at least tens of meters. Axes of these folds appear to be subparallel to the foliation strike. The consistent shear sense orientation in the external shear sense indicates that this sense of shear predates the folds, rather than being associated with high-temperature passive flow or flexural slip folding which would result in opposite senses of shear on opposing limbs of folds. The early isoclinal folds are themselves folded by at least one generation of more open folds at the scale of meters or larger, and these later generations of folds are responsible for the scatter in the foliation and lineation orientations. Foliation within the Calaveras Complex is subparallel to the foliation in the external schist and ultramafic rocks. Calaveras complex folding, and shear sense within the Calaveras Complex were not evaluated in this study. been heavily retrogressed or altered, with a fine-grained growth of white mica, and Ca-silicate minerals. Epidote tends to show a higher pistachite content (higher birefringence and deeper yellow pleochroism) in epidote amphibolite than the garnet-amphibolite. Rutile is commonly rimmed and in some cases nearly entirely replaced by titanit. Garnet is rare in the metabasite and most are badly retrograde and fractured, and consist of fragments generally less than 0.1 mm, but some reach 4 mm. The grain size of most minerals in amphibolite range from 0.1 to 5 mm with the tendency for somewhat finer grain sizes in epidote amphibolite. Hornblendes ranges in size from 1 to 5 mm. Hornblendes exhibit variable retrogression and commonly have patchy brownish regions with surrounding areas of brownish green, green and bluish green amphibole. Epidote found in the garnet amphibolite is usually 1–2 mm while those found in the epidote amphibolite ~ 0.1 mm in size. Pale green clinopyroxene up to 0.5 mm in size occurs in some plagioclase amphibolite. We did not find clinopyroxene in mafic garnet amphibolite (Fig. 4), whereas clinopyroxene does occur in the quartz-bearing garnet amphibolite. Hornblende shows a strong preferred orientation with the long axes lying in the foliation planes. Quartz shows evidence of plastic 4. Petrography Mineral abbreviations in the following sections are from Kretz (1983). 4.1. External schist We have divided the external schist into three main rock types, metabasites, rocks that appear to reflect fine interlayering of metacherts and metabasite in varying proportions, and metacherts. The metabasites of the external schist can be divided into garnet amphibolite (Hbl + Grt ± Ep ± Ab ± Qtz + Rt), plagioclase amphibolite (Hbl + Pl (entirely or nearly entirely replaced by Ab) ± Cpx ± Qtz + Rt or Ttn) or epidote amphibolite (Hbl + Ab + Ep ± Qtz ± Chl with either Rt or Ttn). Some amphibolite from the Rich Bar area also have rare bluish rims on green or green-brown hornblende. Apparent blue amphibole rims on hornblende from amphibolite associated with the FRB have been previously identified by Ferguson and Gannett (1932) from the Alleghany district in the Yuba River region, about 60 km southeast of the field area. We did not find fresh plagioclase (excluding albitic plagioclase) in the external schist. The (inferred) plagioclase has Fig. 6. Back scattered electron (BSE) image of FR6. garnet (grt), phengite (phen), clinopyroxene (cpx) with albite (ab), and quartz (qtz). The rims of the phengites are very slightly brighter than the cores, probably reflecting higher Fe concentration and correspondingly higher Si substitution; this subtle difference is best viewed on the upper of the two phengites in the view. Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS 6 C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx schist (Fig. 2). Rutile is widely distributed at all structural levels of the external schists in both the amphibolites and quartz-rich amphibolites. Titanite commonly rims rutile (Fig. 7) and in some samples nearly completely replaces it. Some of the amphibolites do not contain rutile, but contain titanite only; ilmenite appears to rim titanite in some samples. The metachert consists mainly of quartz (generally 90% or more) with layers of phengite and sparse garnets. The quartz grains are 0.1– 0.5 mm in size. Their textures show significant plastic strain with subgrain development, ribbon grains, and c and s surface development. Garnets in the metachert are small (0.5 mm) and broken up. Bluish (hand specimen) rocks that resemble blueschist from Rich Bar area are quartz rich (possibly metacherts) with pale green amphiboles with dark blue rims, stilpnomelane, and rare garnet. 4.2. The internal schist Fig. 7. Photomicrograph showing titanite (ttn) rimming relics of rutile (ru) in sample FR6. Plane polarized light. Other abbreviations same as Figs. 4 and 5. strain with ribbon grains and subgrain development. Asymmetric shear fabrics with shear bands and c and s surfaces are common. Quartz-bearing amphibolite, which may have been derived from variable proportions of finely interleaved metachert and metabasite, contains 10–50% quartz. Those rocks with the highest quartz contents may be impure (perhaps tuffaceous) metacherts or siliceous metatuffs, whereas those with the lowest quartz contents may represent metabasites with limited intercalated metachert. The primary (highgrade) assemblage is Hbl + Qtz + Cpx + Grt + Phen ± Pl ± Chl ± Rt ± Zo. Biotite has been reported from these rocks (Ehrenberg, 1975; Hacker and Peacock, 1990) and we observed grains in some samples that may have been biotite, but have been altered to chlorite and clay minerals. Most garnet is 0.5 mm in size, but some reach 2 mm. Garnet is commonly rather heavily altered or retrogressed with ragged rims and common replacement by chlorite. The garnet tends to be heavily fractured with considerable alteration along the fractures, both of garnets and the abundant inclusions (Fig. 5). Very pale green clinopyroxene is typically 0.5–1 mm forms heavily fractured grains with ragged margins (Fig. 6). The pyroxene appears to be intergrown with albite, the textural affinity of which is not clear, and fine-grained alteration minerals are present along fractures and margins of grains. Hornblende is brownish with occasional green rims and locally pale green actinolitic outermost rims. The hornblende commonly is less than 1 mm, but some reach 3 mm in size. Hornblendes appear to reflect variable retrogression with irregular brownish patches in the interior of the grains surrounded by greenish or brownish green amphibole, with actinolite representing the texturally latest amphibole forming the rims or along fractures. Phengite forms grains of 0.5 mm or smaller (average about 0.1 mm). It appears to have grown in multiple textural generations with an earliest generation in apparent textural equilibrium with the garnet, clinopyroxene and brown amphibole (Fig. 6) defining an early foliation. The texturally early phengite grains tend to be the larger ones, and many of them are bent with undulatory extinction. Later strain-free phengites are found in the matrix, and also cross cutting the early, larger grains. Zoisite occurs as elongate grains up to 2 mm in length and is colorless with low birefringence, and anomalous colors on parallel extinction; it appears in textural equilibrium with garnet, clinopyroxene, and brown hornblende. Secondary pumpellyite is present, as limited overgrowths and as comparatively rare vein filling. Foliation and fabric in the quartz-bearing amphibolite resembles that of the mafic amphibolite. Garnet in both quartz-bearing amphibolites and the metabasites appears to be restricted to the upper structural levels of the external The internal schist consists mainly of plagioclase amphibolite (Hbl + Pl (replaced by Ab)± Qtz± Rt± Ttn) that is interleaved with hornblendite (Hbl ± Rt ± Ttn). No garnets were found by us or Ehrenberg (1975) in the internal schist. In some samples the hornblende is optically homogeneous and olive green whereas in others the amphibole is zoned from a pale, apparently actinolitic core to an olive green rim (Fig. 8). Plagioclase locally appears to be fresh, although we were unable to obtain to find plagioclase during our electron microprobe analysis (see below), whereas in many other samples, it is riddled with later alteration products that include fine-grained white mica and other minerals. Kfeldspar occurs in felsic segregations in the amphibolites. Euhedral titanite is common in the plagioclase amphibolites. Late veins of prehnite are common. Grain sizes are 1–3 mm for the plagioclase amphibolite and 3–5 mm for the hornblendite. The planar orientation of amphiboles and amphibole-rich and feldspar-rich layers define the high-temperature foliation in these rocks. A preferred elongation direction in amphiboles defines a mineral lineation that appears to be present in some samples of the internal schist. Ehrenberg (1975) interpreted these rocks as metagabbros, but we did not find any samples that exhibited textures that suggest a gabbroic, rather than basaltic protolith. The lack of associated metasediments (such as metacherts or the quartz-bearing amphibolites) in the internal schists may suggest gabbroic, rather than basaltic protolith, however. Fig. 8. Photomicrograph of internal schist sample FR16. Plane polarized light. Most of this view shows amphiboles that are zoned from pale actinolitic cores to darker hornblende rims. Rutile grain is shown. Most of the rutile in this sample has been replaced by titanite. Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx 7 rocks found at Belden Siphon (Fig. 2) are somewhat coarser grained with metamorphic grain sizes up to 0.3 mm. A breccia, noted above contains a matrix of quartz-phengite schist with some actinolite, and clasts up to several cm in size of amphibolite. These amphibolite clasts appear similar to the plagioclase amphibolites of the external schist. Many of the amphibolite clasts contain rutile and some have bluish rims on the hornblendes. 5. Electron microprobe analysis of selected phases Fig. 9. Photomicrograph of sample from sheeted dike unit of the Devil's Gate ophiolite. Plane polarized light. Abbreviations: act: actinolite, alt-px: probable altered pyroxene (completely replaced by fine-grained intergrowth of minerals), hbl: hornblende, ilm: ilmenite. 4.3. Devil's gate ophiolite In order to assess metamorphic contrasts within the FRB, we examined samples from the Devil's Gate ophiolite, 40 km southeast of the study area. In contrast to the external schists, the Devil's Gate ophiolite appears to represent the remnants of the upper plate of subduction system in contrast to the apparent metamorphic sole rocks, the external schists. The Devil's Gate ophiolite samples appeared to have had upper oceanic crustal protoliths: dikes and pillow basalts. We examined them in order to assess the contrast between the metamorphism of the upper plate of a subduction system and the apparent metamorphic sole. The upper crustal lithologies were chosen because they were reported in the literature (e.g. Edelman et al., 1989; Hacker, 1990) to have been metamorphosed at amphibolite grade, and because amphibolite grade metamorphism in the dikes and/or basalt levels of an ophiolite is higher than expected for sea floor metamorphism (e.g., Alt and Teagle, 2000; Schiffman and Smith, 1988). A sample from a sheeted dike outcrop has hornblende to 2 mm in size that is zoned from a pale green actinolitic core to a greenishbrown rim (Fig. 9). Plagioclase appears to have once been part of the metamorphic assemblage, but it is largely replaced by albite and dense mats of fine-grained white mica and other minerals. Brownish clots of minerals appear to replace former blocky mineral forms; these may have been igneous or metamorphic pyroxene. Some clinopyroxene to 0.5 mm remains in this rock but there is no direct textural connection between this clinopyroxene and the brownish mineral clots. Because this clinopyroxene is locally concentrically rimmed by actinolite and hornblende outward, it is likely igneous clinopyroxene. Ilmenite occurs as irregular opaque grains to 0.7 mm in size. Texturally late prehnite is common. Although most of the hornblende exhibits a somewhat static fabric without notable preferred orientation, shear zones cut the rock and these shear zones have plastically-deformed quartz and albite, and green to brown green amphibole. 4.4. Calaveras complex Calaveras Complex rocks in this area are commonly extremely fine grained and many of them exhibit few metamorphic minerals that are readily identifiable in thin section. Most metamorphic minerals have grain sizes of 0.1 mm or less. The slate samples have little visible mineralogy other than quartz, albite, and fine white mica. Cherts tend to be nearly all quartz with some white mica. Metavolcanic rocks contain quartz, albite, white mica, chlorite, epidote, and actinolite. The In order to evaluate the P–T conditions of metamorphism as well as identify certain minerals, mineral compositions were determined for minerals from six samples, four from the external schist, one from the internal schist, and one from the sheeted dike unit of the Devil's Gate ophiolite. The mineral chemistry was determined using a CAMECA SX100 Electron Microprobe at the University of California, Davis. The accelerating potential was 15 kV and the beam current was10 nA, with counting times of 10 s for peaks, and 5 s for background. Amphiboles, pyroxenes, garnets, and epidote minerals were analyzed with a beam diameter of 1 micron, whereas feldspars and phengites were analyzed with a beam diameter of 10 μm. Mineral formulae were calculated from data on the following basis: Amphiboles: For some site assignments discussed in the text: 13 total cations excluding Ca, Na, and K, although for Table 4 amphiboles formulae are simply charge balanced to 23 oxygens. Clinopyroxene: 6 oxygens and 4 cations. Garnet: 12 oxygens. Phengite: 22 oxygens. Representative results for garnet, clinopyroxene, phengite, and amphibole are shown in Tables 2 to 5, respectively. 5.1. Garnets Garnets from a quartz-rich external schist (sample FR6) were pyrope poor and rich in almadine and grossular. The compositional range of the garnets is Py8–10Alm42–47Sp4–5Gr35–43And2–9Uva0–2, and they have an average composition of Py9Alm43Sp5Gr38And6Uva1. Because of the heavy alteration and fragmentation of the garnets in this rock, we were unable to identify zoning. The garnet analyses we obtained show relatively small compositional variation and no systematic spatial variation. Whereas our analysis did not identify, neither could we demonstrate that the original garnet was unzoned, owing to its poor preservation. In addition, our analyses may be biased toward the core regions of the garnet relics owing to greater degree of alteration and fracturing of the rim regions. Garnet was analyzed from a metachert Table 2 Garnet compositions (weight percent). Sample analysis MgO CaO MnO FeO Al2O3 Cr2O3 SiO2 TiO2 Total Formula based on 24 O Mg Ca Mn Fe2+ Fe3+ Al Cr Si Ti Total FR6 FR6 FR6 FR6 YR32 grt-1 grt-2 grt-3 grt-4 grt-1 2.27 15.00 2.24 20.38 22.88 0.00 37.19 0.16 100.12 2.17 15.22 2.12 20.37 22.16 0.04 38.60 0.10 100.79 2.26 15.31 1.96 20.35 22.02 0.02 37.26 0.17 99.36 2.26 15.04 2.02 21.19 21.96 0.01 37.88 0.11 100.46 0.82 4.96 25.71 9.92 21.45 0.01 36.97 0.42 100.26 0.53 2.50 0.30 2.45 0.21 4.20 0.00 5.80 0.02 16.01 0.50 2.53 0.28 2.66 0.00 4.05 0.01 5.98 0.01 16.02 0.53 2.58 0.26 2.46 0.21 4.08 0.00 5.85 0.02 15.99 0.52 2.51 0.27 2.59 0.17 4.03 0.00 5.90 0.01 16.00 0.20 0.86 3.51 1.35 0.00 4.08 0.00 5.96 0.05 15.96 Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS 8 C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx Table 3 Clinopyroxene compositions (weight percent). Sample analysis Na2O MgO Al2O3 SiO2 K2O CaO TiO2 FeO MnO Cr2O3 Total Formula based on 6 O Na Mg Al Si K Ca Ti Fe2+ Fe3+ Mn Cr Total Table 5 Amphibole compositions. FR6 FR6 FR6 cpx-1 cpx-2 cpx-3 0.28 12.00 0.75 52.96 0.01 22.75 0.00 10.46 0.14 0.02 99.37 0.33 12.08 0.94 52.83 0.01 23.75 0.02 9.90 0.18 0.03 100.08 0.35 12.51 1.11 52.72 − 0.01 23.57 0.05 9.29 0.18 0.01 99.80 0.02 0.68 0.03 2.01 0.00 0.92 0.00 0.36 0.00 0.00 0.00 4.02 0.02 0.68 0.04 1.98 0.00 0.96 0.00 0.30 0.01 0.01 0.00 3.98 0.03 0.70 0.05 1.98 0.00 0.95 0.00 0.27 0.02 0.01 0.00 4.01 (YR32) that showed zoning in backscatter electron (BSE) imaging, but only two usable analyses were obtained. This garnet was spessartine rich with a composition of Py4–8Alm19–30 Sp42–62Gr8–14And6–7Uva0. 5.2. Amphibole Amphiboles were analyzed from the quartz-bearing external schist (FR6), plagioclase (former) amphibolite from the external schist (YR45), a quartz-bearing schist or metachert from the external schist that appeared to have blue amphibole rims on green amphibole (RB52), and Table 4 Phengite compositions (weight percent). Sample analysis FR6 FR6 FR6 FR6 FR6 wm-1 wm-2 wm-2 (rim) wm-3 wm-3 (rim) 4.40 0.18 10.43 2.88 0.04 0.01 3.40 NA 28.28 0.01 48.60 0.04 98.25 4.44 0.11 10.13 2.82 0.15 0.06 4.12 0.49 28.27 0.02 49.04 0.15 99.80 4.49 0.22 10.21 3.57 0.01 0.03 4.70 0.09 25.18 0.00 52.13 0.02 100.66 4.49 0.22 10.38 2.59 0.00 0.06 3.85 0.77 31.10 0.05 47.56 0.21 101.29 4.44 0.02 9.97 4.33 0.03 0.05 6.01 0.01 21.85 0.00 53.11 0.00 99.81 Formula based on 22 O Na 0.04 K 1.78 Mg 0.55 Ca 0.00 Mn 0.00 Fe 0.37 Ba NA Aliv 3.25 Alvi 1.48 Cr 0.00 Si 6.52 Ti 0.01 Total 18.00 0.03 1.75 0.57 0.02 0.01 0.47 0.03 3.12 1.38 0.00 6.62 0.02 18.00 0.06 1.74 0.71 0.00 0.00 0.52 0.01 2.94 1.03 0.00 6.96 0.00 17.96 0.06 1.77 0.52 0.00 0.01 0.43 0.04 3.19 1.68 0.01 6.35 0.02 18.09 0.00 1.72 0.87 0.00 0.01 0.68 0.00 2.69 0.80 0.00 7.18 0.00 17.94 H2O Na2O K2O MgO CaO MnO FeO BaO Al2O3 Cr2O3 SiO2 TiO2 Total Sample analysis H2O Na2O K2O CaO MgO MnO FeO Al2O3 Cr2O3 SiO2 TiO2 Total FR6 FR6 YR45 RB52 FR16 FR16 DGO1 am-2 am-4 am-3 am-3 am-4 am-5 am-2 2.01 1.37 1.60 11.71 9.08 0.27 16.48 15.32 0.01 41.55 0.86 100.26 2.03 1.29 1.63 11.65 9.86 0.17 15.55 15.37 0.04 42.35 0.88 100.83 2.00 2.22 0.36 10.51 9.45 0.30 19.67 13.13 0.01 42.53 0.64 100.82 2.07 0.43 0.03 11.64 15.16 0.38 13.15 1.75 0.01 54.44 0.06 99.14 2.00 1.89 0.49 10.96 9.75 0.39 18.52 12.84 0.03 42.60 0.82 100.29 2.00 1.54 0.43 11.06 10.38 0.37 17.62 10.82 0.02 44.27 0.81 99.30 2.07 0.93 0.33 11.43 14.93 0.21 12.69 8.13 0.08 47.90 1.20 99.90 0.63 0.07 1.64 2.05 0.04 1.15 1.25 1.74 0.52 0.00 6.19 0.07 15.33 0.12 0.02 1.82 3.22 0.05 1.36 0.28 0.15 0.08 0.00 7.85 0.00 14.96 0.54 0.09 1.72 2.13 0.05 1.22 1.05 1.67 0.55 0.00 6.24 0.09 15.35 0.44 0.08 1.75 2.28 0.05 1.30 0.87 1.38 0.50 0.00 6.53 0.09 15.27 0.26 0.06 3.16 1.74 0.03 0.54 0.97 1.07 0.30 0.01 6.81 0.13 15.06 Formula proportion based on 23 oxygens Na 0.39 0.37 K 0.30 0.30 Ca 1.86 1.82 Mg 2.00 2.15 Mn 0.03 0.02 1.62 1.43 Fe2+ 0.42 0.47 Fe3+ Aliv 1.75 1.72 Alvi 0.92 0.93 Cr 0.00 0.00 Si 6.15 6.18 Ti 0.10 0.10 Total 15.55 15.49 plagioclase amphibolite from the internal schist (FR16). We also analyzed amphibole from a sheeted dike sample from the Devil's Gate ophiolite. The amphiboles are edenites and pargasites (Yavuz, 2007) (Fig. 10). Toward more aluminous amphiboles in Fig. 10 is a bit deceiving in that actinolite was intentionally avoided (not entirely with success) with the exception of RB52 where it is the primary calcic amphibole; actinolite appears as a late overprint in most of the external schist. In Fig. 11, aluminum and titanium contents of amphibole are shown, as these concentrations are pressure and temperature dependent, respectively in high-temperature calcic amphiboles (Ernst and Liu, 1998). Note that Fig. 11 excludes the more actinolite-rich analyses, but is comprised of variably retrogressed amphiboles. The variable retrogression appears to be reflected by the positive correlation between Al and Ti contents of amphibole in each sample. The spread of data shows the greatest scatter or spread for FR6 consistent with the greater degree of retrogression of amphiboles seen in thin sections that sample. In RB52 the blue amphibole rims do not appear to be sodic amphibole. Although most of these rims are small enough so that they are difficult to analyze, a few patches were large enough so that we believe the microprobe analysis consists entirely of one of these patches instead of a combination between the patch and the main core amphibole. These analyses show the bluish rims and patches to be richer in magnesioriebeckite component than the core amphibole, but the NaB occupancy is no higher than about 0.4. These results are similar to microprobe results obtained by the second author on apparent blue amphibole rims on garnet amphibolite of the external schist from the Rich Bar area in 1987. 5.3. Clinopyroxene Clinopyroxene from quartz-bearing amphibolite (FR6) span a compositional range is Wo47–49En34–36Fs15–17 Jd1–2. Clinopyroxene exhibits inclusions or intergrowths of albite (Fig. 6). Although the clinopyroxene is heavily fractured and has fine-grained alteration products growing along these fractures, the remaining pyroxene does not appear to have suffered much retrogression or alteration, based on the narrow range of compositions. It is possible that the albite within Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx 9 Fig. 10. Amphibole compositions and classification. the clinopyroxene represents (1) growth in equilibrium with clinopyroxene, (2) exsolution of a Na-poor clinopyroxene and albite from an earlier Na-rich clinopyroxene, because there are no other obvious minerals that replace the clinopyroxene or (3) a later retrograde product that may have formed in conjunction with other retrograde minerals along the fractures. 5.4. Phengite Phengite in FR6 varies in Si content from 3.23 to 3.72 formula units, based on an 11 oxygen formula. Fe content ranged from .14 to .43, and Mg content ranged from .22 to .46. We did not analyze all of the phengites for barium, but those we did showed low Ba concentrations (Table 4). Phengite analyses can be divided into two groups, those with low Si contents of about ~3.3 (3.18–3.37) and those with high Si contents (3.45–3.72). Owing to the small size of the grains (most grains had a width of no more than four microprobe beam diameters) we could not quantitatively evaluate zoning in the phengites. The higher Si phengite is texturally late. This can be seen in BSE imagery, where lighter rims (higher average atomic number with higher phengite substitution) are seen on some of the larger phengite grains (Fig. 6). 5.5. Feldspars We tried to find plagioclase relics in the various amphibolite samples but could not. Many grains that appeared to be plagioclase in Fig. 11. Aluminum and titanium contents in amphiboles. Note that this plot includes some partly retrogressed amphiboles, but excludes some of the more actinolitic (clearly late) amphiboles. It is likely that only the highest aluminum and titanium concentrations reflect the true high-grade amphibole compositions. Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS 10 C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx thin section, proved to be albite and various intergrown alteration minerals. In FR16 our analyses showed potassium feldspar was present in the felsic layers in that sample. The other feldspar identified was nearly pure albite in samples YR45. 6. Thermobarometry Peak P–T conditions were estimated for several samples from the external schists, one from the internal schists and one from the sheeted dike unit of the Devil's Gate ophiolite (results summarized on Fig. 12). For all samples, we used Ernst and Liu (1998) amphibole thermometry and barometry. We also noted the presence of partial melting textures in many rocks that indicated that temperatures exceeded the wet basalt solidus. The presence or absence of garnet in mafic rocks and the occurrence of rutile were also employed to estimate minimum or maximum pressure. One sample, quartz-rich amphibolite/schist FR-6 contained garnet, clinopyroxene, hornblende, phengite and rutile, so we were able to apply all of the above constraints in addition to estimated temperature from the garnet– clinopyroxene Fe–Mg exchange reaction of Ravna (2001), and pressure by garnet–clinopyroxene–phengite barometry of Ravna and Terry (2004). An older calibrations of the grt–cpx Fe–Mg exchange reaction (Ellis and Green, 1979) was included for comparison. Similarly the older grt–cpx–phen calibration of Waters and Martin (1993); with empirical correction published in Wain et al. (2001) was used for comparison to results obtained from the Ravna and Terry (2004) calibration. We shall present the thermobarometric estimates for sample FR-6 first, then review those of the other samples. Apparent partial melting textures were found on the outcrop where sample FR6 was collected constrain the minimum temperature to 650 °C based on wet basalt solidus (Poli, 1993; Peacock et al., 1994) (Fig. 12). Garnet–clinopyroxene thermometry (Ravna, 2001) gives a temperature range of garnet–clinopyroxene pairs of about 550– 760 °C. Owing to the degraded nature of garnets, that may have influenced the range in their composition, we prefer the higher part of the temperature range. Rutile found in FR6 constrains the minimum pressure to be about 1.3 GPa at 650 °C (Ernst and Liu, 1998). The maximum pressure of 2.2 GPa at 660 °C is from the stability of hornblende in wet basalt or amphibolite (Peacock et al., 1994; Liu et al., 1996). Application of garnet–clinopyroxene–phengite barometry (Ravna and Terry, 2004) yielded pressures of about 1.4–1.9 GPa at 650–760 °C for phengite cores (of about Si 3.3). Because of the somewhat ambiguous textural relationships of the phengite we also did the P–T calculations using what we believed to be texturally late phengites (high Si) as the phengite in equilibrium with garnet and clinopyroxene. This produced ultrahigh pressure (UHP) results (N3 GPa) which we consider unrealistic owing to the lack of UHP mineral assemblages and presence of hornblende. This supports our interpretation of the high Si phengites as being late and not in equilbrium with the high T assemblage. The updated version of the Waters and Martin (1993) calibration (Wain et al., 2001) applied to phengite cores yielded pressures of 2.2–2.4 GPa at 650–760 °C; most of this range is above estimated hornblende stability. The amphibole thermobarometer of Ernst and Liu (1998) applied to the calcic amphiboles gave a temperature of about 670–710 °C at 1.7–2.0 GPa. Owing to the retrograded nature of the amphiboles in all of our rocks, we selected amphiboles with reasonable stoichiometry and good totals that had the highest Al and Ti contents. Our selection of the compositional clusters with the highest Al and Ti contents for each sample may artificially restrict the natural compositional variation and uncertainty in the P–T estimate, or it is possible that we are overestimating the compositional variability (and resultant P–T estimate range) by including some variably retrogressed amphiboles in our analysis. It is difficult to assess the true variability of the highgrade amphibole compositions with such widespread retrogression. For the samples other than FR6, we cannot directly compare the same methods, except for the presence or absence or rutile, but we can compare amphibole compositions. P–T conditions for YR45, which is structurally low in the external schist, based on amphibole thermobarometry are 630–670 °C and 1.55–1.75 GPa. The presence of rutile places a lower limit of 1.3 Gpa for peak metamorphic conditions. Amphibole thermobarometry applied to the internal schist yielded temperatures of 640–680 °C and pressures of 1.4–1.6 GPa (Fig. 12). Partial melting textures are found in the internal schists suggest that peak metamorphic temperature exceeded 650 °C. The presence of rutile in the internal schist appears to suggest a minimum pressure of about 1.3 GPa at 650 °C. Amphibole thermobarometry applied to the Devil's Gate ophiolite sheeted dike sample results in estimated P–T conditions of about 710–730 °C and 0.3–0.4 GPa. The presence of ilmenite and lack of titanite, along with the lack of garnet, indicates a maximum pressure of 0.7–0.8 GPa. 7. Discussion 7.1. Discussion of thermobarometric results Fig. 12. Summary diagram of P–T estimates of metamorphism for various samples. Spots and polygon are P–T estimates from amphibole thermobarometry of Ernst and Liu (1998) for sample DGO (Devil's Gate ophiolite, sheeted dike sample), IS (internal schist), and samples YR45 and FR6 of the external schist. Other thermometers and barometers applied specifically to sample FR6 are as follows: R2000: Ravna (2001) garnet–clinopyroxene thermometer (the lower limit for R2000 is well below the wet basalt solidus, so it is not plotted), RT04: Ravna and Terry (2004) garnet– clinopyroxene–phengite barometer, EG79: Ellis and Green (1979) garnet–clinopyroxene thermometer, shown for comparison, as well as WM: Waters and Martin (1993) garnet–clinopyroxene–phengite barometer revised as in (Wain et al., 2001). The preferred limits on the P–T conditions of metamorphism for sample FR6 are shown in gray. Other curves shown: hbl out: hornblende breakdown (Liu et al., 1996), garnet-in (Liu et al., 1996), ilmenite, rutile and titanite stability (Liu et al., 1996), and the wet basalt solidus from Poli (1993). In order to compare our P–T estimates to those published from similar tectonic settings and for us to compare P–T conditions between different samples we will further discuss the thermobarometry. Although the Waters and Martin (1993); with correction in Wain et al. (2001) calibration of the grt–cpx–phen barometer commonly gives lower P estimates in eclogites (Page et al., 2007), we found it to give higher pressures for FR6. Whether or not the grt– cpx–phen barometry is applicable to sample FR6 is unclear, owing to the somewhat unclear textural association of the earliest formed white mica, and the question as to whether the clinopyroxene retained the composition it had at peak pressure. Accordingly, our grt–cpx–phen results should be viewed with some caution. The compositional dependence of mineral compositions and stability may also impact the P and T estimates. To better evaluate Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx the applicability of the equilibria used in our PT estimates we obtained major element chemical data by X-Ray fluorescence analysis (PANalytical MagiX Pro). With the exception of sample FR6, the external and internal schists, and the Devil's Gate ophiolite samples appear to have major and minor element compositions similar to MORB used in the experiments that the Ernst and Liu (1998) amphibole thermobarometer was calibrated with (Table 6). FR6 is derived from a protolith that is more felsic than MORB, perhaps MORB with interlayered chert, so amphibole compositions in that sample may not be directly comparable to those in the other samples we investigated. The minimum pressure represented by rutile is also compositionally dependent. Rutile is widely distributed throughout the external and internal schists in rocks of a wide range in compositions, from quartz-rich rocks more felsic than FR6 to those of true MORB composition. Thus, we believe it is reasonable to apply minimum pressure of rutile occurrence summarized in Ernst and Liu (1998) that was based on MORB. Similarly garnet stability is strongly compositionally dependent, but garnet is present in true MORB-derived metabasites (sample 92-3 in Table 6, for example) as well as the quartz-bearing FR6. The highest temperatures obtained were the grt–cpx temperatures estimated from sample FR6. It is possible that this thermometer did not capture the peak temperature of metamorphism because: (1) our analyses of garnet in FR6 may have avoided the more degraded rim areas where prograde zoning may have been reflected; and (2) the clinopyroxene may not necessarily reflect its composition at the peak of metamorphism because of subsequent retrograde metamorphism or exsolution. In view of the above we believe the external and internal schists formed at about 650–760 °C (possibly higher) at pressures greater than 1.3 GPa (rutile stability MORB composition), but less than 2.2 GPa (hornblende stability in MORB composition), and the grt– cpx–phen pressure estimate for sample FR6 falls within that broader pressure range. Comparison of amphibole compositions between the external and internal schists suggests that the external schists may have formed at slightly to moderately higher pressures (say 0.1 to 0.7 GPa) than the internal schists and significantly higher pressures (ca. 1 GPa) than the Devil's Gate ophiolite. The latter conclusion is also consistent with the occurrence of ilmenite instead of rutile in the Devil's Gate ophiolite. Although FR6 is not of MORB composition, its amphibole compositions may indicate an inverted pressure gradient, or imbrication, within the external schist, but the difference in bulk composition between the non-MORB FR6 and MORB YR45 renders this assessment uncertain. Garnet within metabasites (of approximate MORB composition) is restricted to the structurally higher part of the Table 6 Whole rock compositional data. Sample oxide SiO2 Al2O3 FeO Fe2O3 Fe2O3b MgO MnO TiO2 CaO Na2O K2O P2O5 Total FR6 92-3 YR45 FR16 DGO 68.23 10.00 51.33 13.96 51.98 15.11 51.46 13.33 47.60 18.47 6.02 4.20 0.09 0.93 10.43 0.2 0.92 0.224 101.187 15.27 10.17 0.09 1.23 7.55 1.04 0.22 0.091 100.9337 14.31 6.74 0.17 0.97 8.73 2.65 0.08 0.061 100.812 13.41 6.83 0.22 2.17 9.61 2.63 0.23 0.164 100.0643 9.56 10.25 0.17 0.67 13.59 0.59 0.12 0.008 101.0569 MORB Experimentsa 49.11–52.38 12.74–16.93 7.55–10.72 1.89–3.23 6.58–10.31 0.17–0.22 1.24–2.51 10.05–11.10 1.93–3.76 0.06–0.49 0.15–0.27 99.28–100.75 a MORB material compositions for amphibole experiments compiled by Ernst and Liu (1998), including that study, Liou et al. (1974), Apted and Liou (1983), Spear (1981), Poli (1993), and Helz (1979). b All iron as Fe2O3. 11 external schist (where sample FR6 was collected), and this qualitatively supports an inverted pressure gradient within the external schists, as well as higher pressures of the structurally higher part of the external schist compared to the internal schist. The presence of pumpellyite, actinolite, and chlorite, as late mineral growth in many of the samples is consistent with the pumpellyite–actinolite overprint that is characteristic of many rocks of the northern Sierra Nevada and crystallized at conditions of about 150–350 °C and 0.2–0.4 GPa (Hacker, 1993). The high Si content (3.45–3.72 formula units, 11 oxygen formula) of the late phengites in FR6 is not compatible with phengites associated with the pumpellyite–actinolite overprint (Hacker, 1993; Wakabayashi, unpub. data). In contrast, such high-Si phengites in FR6 are similar in composition to those observed in blueschist facies terranes (e.g. Sorenson, 1986; Wakabayashi, 1990; El-Shazly et al., 1997; Smith et al., 1999; Tsujimori and Liou, 2004). The late phengite growth may be evidence of a blueschist facies overprint on this rock. Other evidence for a blueschist facies overprint in the external schists is lacking, however. Thus, external schists may have experienced retrograde blueschist facies conditions, whereas all of the FRB and associated rocks (internal and external schists, Devil's Gate ophiolite) underwent late pumpellyite– actinolite metamorphism. The PT estimates we obtained from the external schists (650– 760 °C, 1.3–2.2 GPa) are comparable to those obtained for other metamorphic soles such as beneath the Semail ophiolite of Oman (700–900 °C, 0.95 to 1.77 GPa (Gnos, 1998; Searle and Cox, 2002)), beneath the Palawan ophiolite of the Philippines (700–760 °C, N0.9 GPa (Encarnacion et al., 1995)), and beneath the Yarlung-Tsangpo ophiolite of Tibet (750–875 °C, 1.3–1.5 GPa (Guilmette et al., 2008)). 7.2. Are the external schists a metamorphic sole? As noted in the Introduction, high-grade metamorphic rocks have been found in association with ophiolite belts that are not metamorphic soles, so it is useful to evaluate the field and petrologic data from the external schists in light of the metamorphic sole hypothesis. Williams and Smyth (1973) and Ehrenberg (1975) suggested that the external schists may be a metamorphic sole on the basis of the highgrade metamorphism and contact with the ultramafic rocks. Our field and structural data indicates that the external schists are a thin (10 to 300 m thick) unit that dips eastward beneath the ultramafic rocks and that the high-temperature shear fabric in the external schist exhibits a tops-to-the-west (ultramafic-side-up) sense-of-shear. Such a hightemperature fabric should be expected in metamorphic soles. The external schists appear to be composed entirely of metabasite with metachert, similar to most metamorphic soles (e.g., Spray, 1984; Jamieson, 1986). Inverted temperature and pressure gradients found within some soles (e.g., Jamieson, 1986; Gnos, 1998) may be present in the external schists, but the limitations of our thermobarometry do not allow us to define inverted metamorphic gradients as definitively as the two studies cited above. In summary we believe the external schists that field, lithologic, structural, and metamorphic characteristics of the external schists are typical of a metamorphic sole. We suggest these rocks formed at the initiation of intra-oceanic subduction as previously proposed for many metamorphic soles. 7.3. Tectonic synthesis: subduction initiation and exhumation of a metamorphic sole Our structural and petrologic data indicate that the external schists formed as a metamorphic sole during the inception of eastward subduction beneath the Feather River ultramafic belt. In addition, the metamorphic data provides additional insight into the tectonic evolution of the external schists and related rocks. The pressure of metamorphism of the external schist (N1.3 Gpa) is well in excess of Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS 12 C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx what can be explained by the structural thickness of rocks intervening between these rocks and the crustal rocks within or at the higher structural levels of the FRB. The position of the internal schist is equivalent to 1 to 1.5 km kilometers of cross-strike map distance from the FR6 internal schist, corresponding to a maximum thickness of 1 to 1.5 km for a vertical average foliation dip. Owing to the uncertainties in the barometric estimates it is difficult to estimate the absolute P difference between the internal schist and FR6, but it is likely in the range of 0.1 to 0.7 GPa, corresponding to a burial difference of 3.3 to 23.0 km, for an average overburden specific gravity of 3.1 (allowing for some serpentinization of the overlying mantle as well as the possibility of some eroded oceanic crust). This requires that faults of an apparent normal sense accommodated exhumation of the external schists relative to the internal schists. This exhumation is required even if the peak metamorphism of the internal and external schists occurred at significantly different times. The internal schists do not appear to have been deeper than recorded by their peak metamorphic assemblage. Amphiboles in some of the samples of internal schist show prograde zoning with actinolite cores and there is no evidence of high P retrograde metamorphism. The Devil's Gate ophiolite dike sample, although collected about 40 km to the southeast of the main field area, appears to be representative of the upper oceanic crust that may have overlain much of the ultramafic rocks of the FRB. A comparison of the Devil's Gate ophiolite with the internal and external schists is appropriate because there is no evidence of an along-strike metamorphic gradient in either internal or external schist metamorphism between the study area and the Devil's Gate ophiolite (e.g. Hacker and Peacock, 1990; Hacker, 1993). The Devil's Gate ophiolite sheeted dike sample records a much lower metamorphic pressure than the internal schists (about 0.6 to 1 GPa lower, corresponding to a burial depth difference of 20 to 33 km), and the intervening ultramafic rock mass (at most 6 km across strike) is much too thin to account for the pressure difference. The metamorphic pressure contrast indicates that the internal schist was exhumed relative to the Devil's Gate ophiolite by lithospheric-scale normal faults located east of (structurally above) the internal schists within the ultramafic rocks. Such faults would have to be located structurally beneath the Devil's Gate ophiolite (Fig. 13). Relative exhumation is demanded for the internal schist relative to the Devil's Gate ophiolite regardless of the comparative ages of metamorphism because neither rock has prograde or retrograde assemblages that record a higher P than the peak assemblages. The exhumation of the external schist (metamorphic sole) relative to the overlying ophiolite crustal section was accommodated by at least two major zones of exhumation, one of which was at least 1 km structurally above the ultramafic-external schist interface, east of the internal schist body, and the other permissibly located anywhere between the ultramafic-external schist interface and the western boundary of the internal schist body. More accurate locating of metamorphic pressure contrasts within the ultramafic rocks themselves is not feasible owing to the insensitivity of various reactions in metaultramafic rocks to pressure (e.g., Evans, 1977). If in fact an inverted pressure gradient is preserved in the external schist, then internal thrust faults are required to have juxtaposed the rocks of the external schist (Fig. 13). The structurally lowest unit of the external schist is much higher P than the Calaveras Complex that structurally underlies it, and this exhumation (apparent thrust fault sense) may have taken place prior to the deposition of the structurally highest parts of the Calaveras Complex as noted below. Fig. 13. Tectonic cartoons showing the evolution of the northern Feather River ultramafic belt with emphasis on the metamorphism and exhumation of the external schists. Note that the thickness of the external schists is exaggerated so that they are visible on these diagrams. I.S. (internal schist) schematically shows the relative position of the internal schist sample, whereas YR45 and FR6 track two samples of the external schist. Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012 ARTICLE IN PRESS C.M. Smart, J. Wakabayashi / Lithos xxx (2009) xxx–xxx Timing of subduction initiation, sole development and sole exhumation is difficult to ascertain owing to the scarcity of geochronologic data, but the hornblende Ar/Ar age of 236 ± 4 Ma (Weisenberg and Avé Lallemant, 1977) reflects cooling of the internal schist through hornblende closure (~525 ± 50 °C; Harrison, 1981). The high-pressure, high-temperatures in the external and internal schists may have been approximately coeval owing to their proximity and similar PT conditions of metamorphism, so the internal schist age may have formed in the same subduction initiation event as the external schist and cooled through hornblende closure for Ar at approximately the same time. Cooling of the sole is expected to rapid with continued subduction, so the hornblende age is probably less than 5 m.y. older than the actual metamorphic age (e.g., Hacker, 1991). Exhumation of soles relative to the upper crustal parts of overlying ophiolites appears to be rapid for examples where ophiolites were emplaced over continental margins. In such cases many ophiolites were emplaced over continental margins within 10 m.y. after formation (Dewey, 1976; Dilek et al., 1999), and structural relationships indicate that exhumation of the sole relative to the ophiolite must have occurred prior to final emplacement (reviewed in Wakabayashi and Dilek, 2003). For ophiolites structurally above subduction complexes, as appears to be the case with the FRB, geochronologic data is much scarcer worldwide. Subaerial exposure of the external schist appears to have occurred prior to the accretion of the structurally highest unit of the Calaveras Complex that has breccia clasts of external schist. The accretion age of the oldest Calaveras Complex is uncertain, however, except that it exceeds 177 Ma (Sharp, 1988). Collectively the existing structural, metamorphic, and geochronologic framework suggests initiation of subduction sometime slightly before 236 Ma, subduction of the sole to depths exceeding 43 km (N1.3 GPa) and exhumation and subaerial exposure of some of these rocks by 177 Ma. The eastern contact of the FRB against the Shoo Fly Complex and other rocks is more difficult to evaluate. The pressure of hightemperature metamorphism estimated for the Devil's Gate ophiolite is not significantly different (within uncertainty) than that of estimates for the low-grade metamorphism of the Shoo Fly Complex and related rocks (Day et al., 1988; Hacker, 1993). On this basis the eastern FRB contact does not record large amounts of differential vertical movement. In contrast the temperature of metamorphism (~ 700 °C) for the upper crustal parts of the FRB reflected by the temperature of metamorphism of the sheeted dike sample of the Devil's Gate ophiolite is vastly higher than any of the rocks adjacent to the FRB to the east. This metamorphic relationship (no P contrast but large T contrast) suggests that the eastern boundary of the FRB may have accommodated significant strike-slip displacement. The origin of the metamorphism of the Devil's Gate ophiolite poses some difficult problems. In many of the classic ophiolites of the world, the ophiolite structurally overlying the sole exhibits negligible burial metamorphism (most exhibit sea floor metamorphism) (e.g., Wakabayashi and Dilek, 2000; 2003). The crustal ophiolitic rocks of the FRB, such as the Devil's Gate ophiolite, and possibly the internal schist, are clearly different. The high T, low P metamorphism of the Devil's Gate ophiolite clearly reflects a much higher geothermal gradient than that recorded in the high T, high P external schist. The metamorphism is not compatible with sea floor metamorphism because the prograde amphibole zoning indicates cooling after crystallization, followed by heating, in contrast to sea floor metamorphism where temperatures should generally reflect a progressive cooling. In addition, sea floor amphibolite metamorphism is restricted to the gabbro layer and beneath, and has not been found associated with sheeted dikes (e.g. Liou and Ernst, 1979; Evarts and Schiffman, 1983; Schiffman and Smith, 1988, Alt and Teagle, 2000). Ridge subduction has been suggested to be associated with very high geothermal gradients (e.g., Sisson and Pavlis, 1993; Brown, 1998) and such an event may explain the high-T 13 metamorphism of the crustal ophiolitic parts of the FRB such as the Devil's Gate ophiolite. One speculative scenario that would explain the metamorphism of the Devil's Gate ophiolite would be failed subduction of the ridge crest during the same event that led to the inception of subduction and creation of the external schist (Fig. 13). Many of the details of the tectonometamorphic evolution of the FRB require more geochronologic data and related metamorphic data tied to a specific structural-tectonic setting, for better understanding. We are currently engaged in a geochronologic campaign in this region and we hope that the results will help refine models for ophiolite genesis, subduction initiation, and early subduction zone exhumation. Acknowledgments This research was supported by the National Science Foundation Grant EAR-0635767 to J.W., and awards from the California State University, Fresno, College of Science and Mathematics to C.M.S. We thank S. Roeske and S. Mulcahy for their assistance with microprobe analyses, G. Torrez for XRF analyses, and R. Jamieson, W. 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Please cite this article as: Smart, C.M., Wakabayashi, J., Hot and deep: Rock record of subduction initiation and exhumation of hightemperature, high-pressure metamorphic rocks, Feather River ultramafic belt, California, Lithos (2009), doi:10.1016/j.lithos.2009.06.012