International Conference on Global Trends in Engineering, Technology and Management (ICGTETM-2016) Physico-Chemical Characteristics of Velhale Percolation Tank Water in Jalgaon District Maharashtra Hemlata A.Wani#1 and G.P. Waghulade*2 #1 Department of Applied Science, SSBT’s College of Engineering and Technology, Bambhori,Jalgaon -425001(India) *2 D.D.N.Bhole college, Bhusawal-425201(India) Abstract -In the present investigation a rural tank was selected at Velhale village, Dist. Jalgaon to study the physico-chemical properties to assess the water quality status. The physico-chemical parameter such as temperature, pH, conductivity, chlorides, free CO2 , alkalinity, total hardness, calcium, magnesium, TDS, BOD, and COD were investigated. Water temperature fluctuated from 26.07oC to 30.66oC, pH 7.93 to 9.35, Electrical Conductivity 707.86 to 1056 µmhos/cm, TDS 260 to 480 mg/L, , alkalinity 174.30 to 254.27 mg/L, total hardness 189.33 to 226.05 mg/L, calcium 26.39 to 47.70 mg/L, magnesium 19.37 to 41.88 mg/L, Chloride 103.62 to 207.02 mg/L, Free CO2 13.09 to 28.04 mg/L, DO 5.95 to 7.35 mg/L, BOD 1.20 to 2.10 mg/L, and COD 26.85 to 33.12 mg/L.The higher values of TDS and hardness in the tank is an indication of water pollution. The estimated water quality parameters were compared with ISI and WHO standards. The tank water was found to be suitable for irrigation and fisheries. selected for water quality assessment and results obtained are compared with standards of ISI and WHO. Materials and methods For analysis six water samples were collected from six different places in the Velhale tank. The one sampling station was at the distance of 10m from the other sampling station. From each sampling station following types of water samples were studied for each month of every season. Water samples for analysis were collected in sterilized two liter capacity polyethylene can having double stopper. The temperature was recorded on the spot using 1x10 thermometer, DO was fixed at the time of sampling Keywords - Physico-chemical parameters, COD, BOD, TDS etc. and the other parameters like pH, con d u c t i v i t y Introduction Velhale tank is situated at 21o00’00" N latitude and calcium, magnesium, TDS, BOD, and COD were 75o 52’00" E longitude. Velhale tank is amongst the and conductivity, pH meter and conductometer were few The used. The standard procedure as given by APHA construction of this tank was started in 1952 and it (1995) [4] and Procedures followed using the was completed in 1955. The catchment area of literature given in Trivedi R.K. and Goel P.K. (1986) Velhale tank is 27.32 sq.km. Storage capacity of this [17] were followed for water analysis. The samples tank is 1.99 m3 Velhale tank is earthen type tank and were collected from April 2007 to February2008. larger tanks of Bhusawal district. c h l o r i d e s , f r e e C O 2 , Alkalinity, total hardness, estimated in laboratory. For the determination of pH spillway of tank is channel type ungated. Water of this tank is supplied to Varangaon town and Sakri, Fulgaon, Jatgaon, Manyarkheda Villages. Water of this tank is contaminated due to the percolation of fly ash from the pipes which passing over the tank. The tank water is mainly used for irrigation and fisheries. In present investigation the physico-chemical parameters of water at Velhale and storage point were ISSN: 2231-5381 http://www.ijettjournal.org Page 261 International Conference on Global Trends in Engineering, Technology and Management (ICGTETM-2016) The hydrogen ion concentration of the water is Results and discussion- Table no.1 Minimum and maximum values of the influenced by biological activities beside an addition of physico-chemical parameters of Velhale Tank chemical substances. Presence of organic matter in during April 2007-February 2008 large quantity may lower pH values due to the release of CO2. pH is an indication of type and intensity of Sr. Physico- Units No. chemical used Parameter 1 Temperature 2 pH 3 Electrical pollution. In the present investigation, higher pH values Minimum Maximum values values 26.070C 30.660C found in rainy season. The overall pH is high and water 7.93 9.35 is alkaline. The pH ranged between 7.93 to 9.35 µmhos/cm 707.86 1056 mg/L 260 480 0 C Conductivity 4 were found in winter season and lower pH values were Total dissolved indicating alkaline water reaction which was considered to be highly conductive for aquatic life. Similar pH values have been reported by Kiran et.al., solid 5 Total Alkalinity mg/L 174.30 254.27 (2005)[8]. Higher pH during the winter season was 6 Total Hardness mg/L 189.33 226.05 possibly due to exhaustion of the carbon dioxide from 7 Calcium mg/L 26.39 47.70 tank water for photosynthesis (Bandela 1998) [5]. 8 Magnesium mg/L 19.37 41.88 9 Chloride mg/L 103.62 207.02 10 Free CO2 mg/L 13.09 28.04 11 Dissolved mg/L 5.95 7.35 Electrical Conductivity During the period of present work, the maximum conductivity of tank water was found in rainy season and less in winter season in accordance with the Oxygen 12 BOD mg/L 1.20 2.10 13 COD mg/L 26.85 33.12 Temperature- water are given in Table no.1. The highest temperature of tank water was recorded in summer and lowest in winter season. As rise in temperature leads to the speeding up to the chemical reactions in water, reduces the solubility of gases and amplifies the taste and odour. The temperature influences different physiological process of algal blooms. It also enhances the metabolic processes in certain species which leads to high pollution load. Mane A.M. and Pawar S.K. (2007) [6] reported that as higher temperature recorded in May. Kamal Kishor, B. D. Joshi and Deepali (2005) [7] showed temperature fluctuation of pond water at Khanpur village in Bareilly district (U.P.) which ranges between 11.30C to 19.60C. Similar results have been observed by S. A. Manjare, S. A. Vhanalakar and D. V. Muley (2010) pH - ISSN: 2231-5381 their investigation of water from Khadkawasala reservoir, Pune. Electrical conductivity is measure of The physico-chemical parameters of Velhale tank [1]. observations made by Kamble et.al.,(2008) [16] during the total amount of dissolved ions in the water but rather the total amount of dissolved ions in the water. In present study least value recorded in winter season. The least value in conductance in winter season also recorded by Jadhav and Deshmukh (2006) [9] during the study of Rankala and Kalamba lakes water of Kolhapur district. During the present investigation the maximum conductivity was observed in rainy season, which was 1056 (µmhos/ cm) and minimum conductivity was recorded during winter season, which was 707.86 (µ mhos/cm). Total Alkalinity During the study period the minimum value of alkalinity was 254.27 mg/L and minimum value was 159.67 mg/L during rainy and winter season respectively. Noor Alam (2008) [3] recorded the same results in their investigation of Pachamba Pond water (Giridih). He reported that the total alkalinity was due http://www.ijettjournal.org Page 262 International Conference on Global Trends in Engineering, Technology and Management (ICGTETM-2016) to bicarbonates which varied from 76 to 135 mg/L. sample were found in summer season. Ravikumar Occurrence of high bicarbonates indicates the presence et.al.,(2006)[12]recorded the minimum concentration of of sewage rich alkaline substances and also high values magnesium was noticed in rainy season i.e. in July to of alkaline pH showing that the pond is highly September and maximum was recorded in May i.e in productive. Kanungo et.al., (2006) [10] also recorded summer season in their investigation on Kulahalli Tank the minimum value of alkalinity in the month of water near Hrappanahalli, Davanagere district, December while maximum during the month of June, it Karnataka. He has stated that when the rainfall is high, was due to higher amount of bound carbon dioxide it deplete magnesium quantity in water. The minimum during their investigation on Doodhadahri pond of and maximum magnesium values were 19.37 and 41.88 Raipur. mg/L respectively. According to the standards of ISI Total Hardness - and WHO, it can be said that magnesium content The hardness is mainly due to dissolved salts of values of Velhale tank water of most of sampling calcium and magnesium ions present in water. During stations selected in study area are around prescribed the present investigation, higher values of hardness limits. were observed in winter season, while lower values Chloride were observed in summer season. Higher values of In the present investigation Chloride contents range hardness can be attribution to low water level and high from 103.62 to 178.44 mg/L. The minimum and rate of evaporation. The minimum and maximum maximum values of chlorides content were found in values of hardness of tank water were 189.33 and winter and summer season respectively. In all the 226.05 mg/L respectively. But according to ISI and sampling point chloride contents were low in winter, WHO standards, the desirable and the maximum this may be due to the higher concentration of chlorides permissible values of total hardness for drinking water during summer may be due to reduced water level and are 200 mg/L, 600 mg/L (ISI) and 100 mg/L, 500 mg/L occasional run off loaded with contaminated water in to respectively. the water body from surrounding villages. In the Calcium - present study the maximum chloride content was In the present investigations, maximum values of observed in summer season. Similar results were calcium were found in winter season while minimum recorded by Ravikumar et.al, (2006) [12]. In their values of calcium were found in summer season. It investigation maximum chloride content was observed ranges from 26.39 to 47.7 mg/L. Similar trends were in June. The increase in chloride content may be due to observed by Ravikumar et.al. (2006) [12] during their increased temperature and evapotranspiration of water investigation of Neelgunda tank water near bodies.The same results were also recorded by Harapanahalli. According to them, when the rainfall is Basavaraja et.al, (2011) [2]. According to ISI and high, it depletes calcium quantity in water. Increase in WHO standards the desirable chloride content values calcium values in winter season could be attributed to are 250 and 250-1000 mg/L. In the present study the the rapid oxidation of organic matter in the substrate. values of chloride were well below the WHO and ISI Magnesium- limits and as such, the water appears suitable for During the period of present finding, mostly lower drinking, irrigation and fisheries. values of magnesium were obtained in rainy season, Free CO2 which might be due to its dilution by rainwater while During the present investigation the maximum value of higher values of magnesium in most of the water free CO2 found 28.04 mg/L in the winter season and ISSN: 2231-5381 http://www.ijettjournal.org Page 263 International Conference on Global Trends in Engineering, Technology and Management (ICGTETM-2016) minimum value of free CO2 was 13.09 mg/L recorded oxygen in water can kill the fish and other organisms during summer season. The free CO2 values variation present in water e.g. Game fish requires at least 5 mg/L was also studied by Kishor, Joshi and Deepali (2005) and coarse fish about 5 mg/L at minimum DO in [7]. Similar results also recorded by Mahajan water (C.L.Patil 2004) [14]. Similar maximum and S.R.(2001)[13] during their investigation on minimum values of DO recorded by Kanungo et.al, elocological studies of algae from certain lakes of (2006) [10]. The minimum value was recorded in the Jalgaon district of Maharashtra. He also recorded the months of August and maximum in the December, it similar results in his investigation, he found the higher was resulted due to greater consumption of oxygen by values of free CO in winter season this might be due to organisms during the rainy month. Similar values of 2 high abundance of phytoplankton in the tank. Water DO also recorded by Mahajan S.R.(2001) [13] during rich in CO was comparatively less alkaline where as their investigation on ecological studies of algae from 2 water deficient in the CO2 was more alkaline at all certain lakes of the progresses in winter, may be due to circulation by cooling and draw down of dissolved stations of the Velhale tank in the present study. oxygen in water. TDS During the present investigation the maximum BOD - concentration of TDS was recorded during winter In the present study period, the maximum value of season and minimum concentration of TDS was BOD was recorded in winter season and minimum recorded during rainy season. The lower TDS value value of BOD was recorded in summer season. The during rainy season in tank water is obviously due to variation BOD values ranged from 1.2 to 2.1 mg/L. dilution of water in this season. The similar results Kishor, Joshi and Deepali (2005)[7] recorded he BOD were also recorded by Ravikumar et.al.(2006) [11,12] variation between 1.20 to 4.42 mg/L. The minimum during their study on Neelgunda tank water near value of BOD was noted in the month of March and Harapanahalli, Davanagere. They recorded the lowest their investigation on pond water at Khanpur village in value of TDS in the month of August, and highest value Bareilly district (U.P). The biochemical oxygen of TDS in the month of February. They gave the TDS demand is said to be low and such a water course is value variation between 25.6-71.68 mg/L. In the rapidly restored. If the pollution load is massive large, present study, among all the stations of the tank water quantities of oxygen are consumed during self showed greater values of TDS. This was due to purification then the biochemical oxygen demand of contamination of water. The results of such type was water is said to be high. recorded by Mahajan S.R.(2001) [13] during their study COD period, on ecological studies of algae from certain lakes During the present study period, the maximum value of of Jalgaon district of north Maharashtra. COD was 33.12 mg/ L recorded in rainy season while Dissolved Oxygen - minimum value of COD was 26.85 mg/L recorded in During the present study work, maximum dissolved summer season. Similar values of COD were recorded oxygen was recorded in winter season and minimum by Jadhav and Deshmukh(2006) [9] in their dissolved oxygen was recorded in rainy season. The investigation of water of Rankala and Kalamba lakes of winter maxima can be attributed to the highest Kolhapur district of Maharashtra. In their study period solubility of oxygen gas due to low temperature. The the maximum value was recorded in rainy season and minimum quantity of dissolved oxygen required in minimum value was recorded in summer season. water depends upon the individual organism. Low ISSN: 2231-5381 http://www.ijettjournal.org Page 264 International Conference on Global Trends in Engineering, Technology and Management (ICGTETM-2016) [17] Conclusion Thus we conclude that the water parameters of the tank Trivedy R.K. and Goel P.K.(1986) : ‘Chemical and Biological Method for water pollution studies’ pp-8 [Environmental publications, Karad (India) 1986] are well within the limits of ISI and WHO standards. Hence the water would be used for drinking, irrigation and fisheries. However continuous monitoring of tank water is necessary to avoid any future drastic changes in the quality of the water. REFERENCES [1] S. A. Manjare, S. A. Vhanalakar and D. V. Muley (2010) : Analysis of water quality using physico-chemical Parameters Tamdalge tank in Kolhapur district, Maharashtra. 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