l e n ~ u s 16, 253-280 (1972) Mariner 6 and 7 Ultraviolet Spectrometer Experiment: Photometry and Topography of Mars C H A R L E S W. H O R D Department of A stro-Geophysics and Laboratory for Atmospheric and ,~pace Physics, University of Colorado, Boulder, Colorado 80302 Received September 27, 1971 From data obtained by the ultraviolet spectrometers aboard the Mariner 6 and 7 Mars missions the reflectivity of the illuminated disk of Mars was found to have two distinct spectral types, associated with polar and nonpolar regions. In this work the characteristic spectrum of nonpolar regions on Mars is discussed. An interpretation of the variation of the intensity at 3050=3~due to surface pressure variations is given. A comparison of the ultraviolet observations with pressures inferred by the infrared spectrometer is used to test this interpretation and to determine physical parameters of Mars which lead to the observed reflectance. Earth based pressures obtained by broadening of the 1/~ band of CO2 and radar topography are compared with the ultraviolet results. INTRODUCTION p h o t o m e t r i c model a t w a v e l e n g t h s shorter I n 1969 the Mariner 6 a n d 7 s p a c e c r a f t t h a n 3500 A. Initial analysis has shown t h a t s w e p t p a s t Mars on the a f t e r n o o n side of w a v e l e n g t h s longer t h a n 3500 A h a v e dift h e p l a n e t o b t a i n i n g spectroscopic a n d ferent p h o t o m e t r i c properties which will not be discussed here. i m a g i n g d a t a of high spatial resolution. T h e u l t r a v i o l e t s p e c t r o m e t e r s a b o a r d the DATA Mariner s p a c e c r a f t o b t a i n e d i n f o r m a t i o n a b o u t the m a k e - u p of the Mars a t m o s p h e r e T h e long w a v e l e n g t h channel of the b a s e d u p o n emission s p e c t r a f r o m the Mariner ultraviolet s p e c t r o m e t e r s o b t a i n e d u p p e r m o s t p a r t of the a t m o s p h e r e (Barth one s p e c t r u m e v e r y three seconds in t h e et al., 1969, 1971). I n addition, o v e r 400 1900-4300A r a n g e at 2 0 A resolution s p e c t r a were o b t a i n e d of the illuminated (Pearce et al., 1971). An i n s t r u m e n t field of disk of Mars. Of these disk spectra, a b o u t view of 0?23 × 2?3 g a v e spatial resolution 40 were o b t a i n e d while viewing the which varied f r o m a b o u t 30 × 3 0 0 k m n e a r s o u t h e r n polar cap. Initial analysis of the the bright limb to 14 × 1 4 0 k m a t t h e polar cap s p e c t r a shows a distinctive closest a p p r o a c h of the spacecraft. T h e a b s o r p t i o n f e a t u r e at 2550 A which is m o s t long axis of t h e p r o j e c t e d field of view s i m p l y explained b y the presence of was oriented p e r p e n d i c u l a r to the solar 1 × l 0 3cm_atm of ozone which gives t h e direction. o b s e r v e d a b s o r p t i o n optical depth, r I n analyzing the s p e c t r o m e t e r d a t a it (2550A) = 0.3, ( B a r t h a n d H o r d , 1971). was f o u n d t h a t only small changes in N o n e of the n o n p o l a r s p e c t r a shows this spectral shape occur s h o r t w a r d of 3500A. a b s o r p t i o n feature, which is p r e s e n t in a l l This m e a n s t h a t the general p h o t o m e t r i c 40 polar spectra. T h e p h o t o m e t r i c proper- p r o p e r t i e s in this w a v e l e n g t h region are ties f o u n d f r o m the u l t r a v i o l e t polar d a t a r e l a t i v e l y w a v e l e n g t h i n d e p e n d e n t . I n h a v e been discussed b y P a n g a n d H o r d order to describe the p h o t o m e t r i c function, (1971). the i n t e n s i t y or reflectance m e a s u r e m e n t s I n this w o r k the p h o t o m e t r i c p r o p e r t i e s in a 100A w a v e l e n g t h b a n d centered at of t h e n o n p o l a r or desert regions of Mars 3050A are analyzed. T h e p h o t o m e t r i c are discussed. Specifically considered is t h e p r o p e r t i e s deduced are r e p r e s e n t a t i v e of 253 © 1972by AcademicPress,Inc. ~54 CHARLES W. HORD the wavelength region from 2 6 0 0 ~ to a b o u t 3500A. Second order changes in spectral shape, which do occur, are felt to be due to v a r y i n g atmospheric opacity at the shorter wavelengths and the increase in ground albedo contribution at longer wavelengths. Using the intensity sum over a 100A wavelength interval gives relative measurements to an accuracy b e t t e r t h a n 1%. Absolute intensities are limited by our knowledge of the solar flux and the i n s t r u m e n t calibration (Pearce et al., 197] ). PHOTOMETRIC MEASUREMENTS Reflectance properties of Mars at 3050 A measured b y Mariner 6 and 7 are shown in Figs. l, 2, and 3. Reflectance is defined as - ~B/F, (1) where B is the measured intensity, or surface brightness, and F is the solar flux at Mars. These figures show d a t a t a k e n at phase angles ranging from 46 ° to 91 ° as the i n s t r u m e n t field of view swept from the bright limb across the afternoon side of the planet t o w a r d the terminator. Also plotted are the cosine of the emission angle,/~, and cosine of the incidence angle, tL0, which have their usual radiative transfer meaning (Chandrasekhar, 1960) with emission angle defined as the angle between observed e m i t t e d radiation and the local normal, and the incidence angle defined as the angle between the Sun and local normal. The base maps used here show the ultraviolet observation swath across Mars in the combined c o n t e x t of Mariner television pictures (e.g., Leighton et al., 1969) and a classical map of Mars. Mariner 6 data, shown in Fig. 1, are ibr regions extending from n o r t h of' J u v e n t a e Fons to Aurorae Sinus and t~om Chryse to the west edge of Meridiani Sinus. Mariner 6 data, shown in Fig. 2, are for a region south of Margaritifer Sinus extending from P y r r h a e Regio to Deucalionis Regio. I n the Mariner 7 case, shown in Fig. 3, ultraviolet observations e x t e n d from south of N e c t a r across the Argyre 1 region t o w a r d the polar cap, and from the P a n d o r a e F r e t u m region across Noachis and Hellespontus into Hellas. A t a b u l a r listing of d a t a shown in Figs. 1, 2, and 3 is included in Table I along with latitude and longitude values. In order to compare these measurements with E a r t h - b a s e d measurements it is useful to find p a r a m e t e r s k and R 0 t h a t provide a best fit of the Minnaert fnnction R- R0/~0~'/~~ ~ (2) to the 3050 :~ reflectance (Minnaert, 1941). A recent discussion of the properties of this function and its application to Mariner 6 and 7 television data is given b y Young and Collins ( 1971 ). I t is i m p o r t a n t to note t h a t the ultraviolet location being observed on Mars is changing t h r o u g h o u t the measurements. E v e n t h o u g h Mars shows relatively small contrast in the ultraviolet, the albedo may be varying. [n order to make a more nearly valid application of Minnaert's law to these data, regions can be selected which have a nearly uniform albedo at visible wavelengths. Using the Mercator p h o t o m a p of" Mars prepared by Cutts et al. (1971) from Mariner 6 and 7 television d a t a and the 1969 Mars map prepared b y Lowell O b s e r v a t o r y (Inge el al., 1971 ), four regions having nearly uniform albedo were selected fbr analysis. Consider first Mariner 6 d a t a obtained at a phase angle of 91 °. In the Aurorae Sinus, Margaritifer Sinus region extending from a latitude and longitude o f - 1 2 7 7 , 42?7 to -15?9, 1878 the Minnaert parameters were k - 0.71 ± 0.(t2 and R 0 - 0.037. F o r the Deucalionis Regio region south of Meridiani Sinus in the latitude and longitude range from 1778, 357?7 to -1775, 34971 the Minnaert parameters were k 0.69 ± 0.06 and R 0 = 0.031. The Mariner 7 d a t a obtained at a phase angle of 91C' covered two regions of nearly uniform visual albedo. One of these regions extending from Deuealionis Regio across P a n d o r a e F r e t u m t o w a r d Hellespontus covering the latitude and longitude range from - I 9?8, 353?8 to 37?9, 33170 gives k = 0.31 ± 0.01 and R 0 = 0.022. This region appears uniibrm on the Lowell map; however, the Mercator p h o t o m a p based upon Mariner television pictures indicates a slight decrease ill albedo approaching Hellespontus. This decrease in albedo could account for the MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIMENT 255 ao io 0 I0 W ZO I-- I,.J 30 40 6C .O8 ! ........ ! ! ! 'I ....... I ! ..... I I i .... ~ s I I i I i .06 Z C) t~ -1 k~ Ist .04 ;o 92 0 1.0 ..... I I t , i ~ ! t . i i I I I I I l i ........ I I i v ~ i .... #' I I t I I I I I ..... i ! I a | ; ! .| . . . . ! | ! ! ! .8 / .6 / f .4 / / / / / 1 / / / 1 .2 if 0 80 ,, I a 60 I ! 40 I 20 340 320 500 280 LONGITUDE F r o . 1. M a r i n e r 6 reflectance m e a s u r e m e n t s a t 3050A. Tile t o p p a r t o f t h e figure s h o w s a p r o j e c t i o n of t h e u l t r a v i o l e t s p e c t r o m e t e r field o f view on a m a p p r e p a r e d b v tile A r m y T o p o g r a p h i c Service. This m a p d i s p l a y s an early version of t h e M a r i n e r 6 a n d 7 television p i c t u r e s ill t h e c o n t e x t of a classical m a p of Mars. R e f l e c t a n c e a n d t h e cosines o f t h e incidence a n d emission angles, F0 a n d / ~ , are g i v e n as a f u n c t i o n o f longitude. T h e s e d a t a were o b t a i n e d a t a p h a s e angle o f 62 °. ........ CHARLES ~ . HORD 256 20 I0 0 I0 0 20 I-V-- ,~ .J 30 40 5D 6o ! i ! ! i i t , , , j .06 LU "%, Z °,o°% .04 "~,~. .J LL LIJ .oz 0 l 1.0 ! t I , , , I , , i ~ .8 i I I I , , . I ¢ I . | . t . i i 1.,,/I 4j" .6 / .4 fl,/ J .2 I 0 ,I 80 I .... i 60 I I 40 ! I 20 ! I ! 0 340 J 320 i ........ | 300 LONGITUDE Fzo. 2. M a r i n e r 6 reflectance m e ~ s u r e m e n t s ~t 3050.3~ o b t a i n e d ,~t ~ p h a s e angle of 91 °. I ! 28O 257 M A R I ~ E R 6 AND 7 ULTRAVIOLET SPECTROMETER E X P E R I M E N T :2 1 .......... | I- ~ _1 3 6 _ , ,O8 I I I I ,,,,,i,~,, I ' :~I .06 I | I | | | .... I I I 1 | ! ! I~ I I ] | !,,,H ,° (J z W -t ~o ............. .04 . . . . . . . . . % W .02 I 1.0 .I 11 ! I I ! I .... ! '~ ~ I I I ~ I I ! ! I ! I ," '" i " I .8 w, .6 ! j f / ,i,/ ~ tt f t/I ,) .2 80 6o 4o 2o o 340 32o 300 28o LONGITUDE F](~'. 3. Ma,riner 7 refleeta~;ce m e a s u r ( m e n t s a t [ 0 5 0 A . P a t a in t h e l e f t - h a n d s w a t h w e r e o b t a i n e d a t a p h a s e a n g l e o f 46 ° a n d a t 91 ° in t h e t w o s w a t h s on t h e r i g h t . , 258 CHARLES W. HORD TABLE Mariner6, Lat. 1.2 0.5 -.2 -.8 -1.4 -1.9 -2.4 -2.9 -3.3 -5.7 -4.1 -4.5 -4.9 -5.3 -5.6 -5.9 -6.3 -8.6 -6.9 -7.2 -7.4 -7.7 -8.0 -8.3 -8.5 12.9 12.6 I2.1 11.7 11.3 10.8 10.4 10.1 9.7 9.3 9.0 8.6 8.3 8.0 7.6 7.3 7.0 6.5 6.2 5.9 5.7 5.1 4.9 4.7 4.4 4.2 4.0 3.8 3,3 3.1 Lon. 65.2 65.8 62.5 61.4 60.3 59.3 58.5 57.4 56.5 55.6 54.8 54.0 53.2 52.5 51.7 51.0 50.3 49.6 49.0 48.3 47.6 47.0 46.4 45.7 45.1 37.4 37.0 36.4 55.8 35.2 34.6 54.0 33.5 52.9 32.4 31.8 31.3 30.8 30.3 29.8 29.5 28.8 27.8 27.5 26.8 26.4 25.5 25.0 24.5 24.1 23.6 23.2 22.7 21.9 21.4 ~ 0.230 0.257 0.281 0.303 0.324 0.343 0.361 0.378 0.394 0.409 0.424 0.438 0.451 0.464 0.477 0.489 0.501 0.512 0.523 0.534 0.544 0.555 0.564 0.574 0.584 0.382 0.388 0.399 0.411 0.421 0.432 0.442 0.452 0.461 0.470 0.479 0.488 0.496 0.505 0.515 0.520 0.528 0.542 0.549 0.556 0.563 0.576 0.582 0.588 0.594 0.600 0.605 0.611 0.621 0.627 I Phase Angle=62.5 Uo 0.969 0.975 0.980 0.984 0.988 0.990 0.993 0.994 0.996 0.997 0.998 0.998 0.998 0.998 0.998 0.998 0.997 0.996 0.995 0.994 0.993 0.992 0.990 0.989 0.987 0.891 0.890 0.890 0.889 0.888 0.887 0.886 0.884 0.885 0.881 0.879 0.877 0.875 0.875 0.871 0.868 0.866 0.861 0.858 0.855 0.852 0.846 0.843 0.840 0.837 0.~34 0.850 0.827 0.820 0.816 R 0.0555 0.0557 0.0523 0.0525 0.0524 0.0461 0.0456 0.0451 0.0441 0.0448 0.0444 0.0436 0.0446 0.0437 0.0437 0.0454 0.0455 0.0473 0.0485 0.0481 0.0462 0.0451 0.0442 0.0442 0.0432 0.0483 0.0502 0.0473 0.0472 0.0450 0.0432 0.0433 0.0434 0.0425 0.0428 0.0422 0.0420 0.0420 0.0410 0.0411 0.0395 0.0386 0.0376 0.0367 0.0367 0.0361 0.0358 0.0354 0.0351 0.0355 0.0348 0.0339 0.0342 0.0543 0.0545 Pres. 4.56 4.64 4.89 5.32 5.67 4.89 5.06 5.21 5.24 5.61 5.73 5.75 6.18 6.14 6.34 6.95 7.16 7.84 8.31 8.44 8.06 7.90 7.79 7.93 7.77 6.19 6.70 6.30 6.48 6.16 5.93 5.11 6.27 6.18 6.42 6.41 6.49 6.61 6.50 6.64 6.51 6.20 6.12 5.97 6.05 5.97 6.07 6.02 6.01 6.21 6.08 5.90 6.06 6.23 6.36 Alt. 5.56 2.74 2.21 1.38 0.73 2.22 1.86 1.58 1.52 0.85 0.64 0.59 -.13 -.07 -.39 -1.30 -1.60 -2.50 -3.09 -3.25 -2.78 -2.59 -2.44 -2.62 -2.42 -.15 -.94 -.32 -.60 -.09 0.28 -.02 -.27 -.12 -.51 -.49 -.62 -.80 -.65 -.84 -.34 -.16 -.04 0.21 0.09 0.22 0.06 0.13 0.15 -.18 0.03 0.33 0.08 -.20 -.42 MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIMENT TABLE I continued Mariner 6, Phase Angle = 62.5 Lat. 2.7 2.5 2.4 2.2 2,0 1,8 1.6 1.5 1.5 I.I 1.0 0.8 0.7 0.5 0.4 0.2 O.l -.0 -.2 -.3 -.4 -.5 -.7 -.8 -.9 -I.0 -l.l -1.2 -1.3 -1.4 -1.5 -1,6 Lon. ~ 20.6 20.1 19.7 19.3 18,9 18.5 18,0 17,6 17.2 16.8 16.4 16.0 15.6 15.1 14.7 14,3 15,9 13.5 15.1 12.7 12.3 11.9 11.5 II,I I0.7 I0.3 9,9 9.6 9.2 8,8 8.4 8,0 0.637 0.641 0.646 0.651 0.655 0,660 0.664 0,668 0.672 0,676 0.680 0.684 0.688 0.691 0.695 0,698 0.702 0.705 0.708 0.711 0.714 0.717 0.720 0,723 0.726 0,729 0.731 0,734 0.756 0,739 0.741 0.743 Uo 0.809 0.805 0.802 0.798 0,794 0,790 0,786 0.782 0.778 0.774 0.770 0.766 0.761 0.757 0.755 0,749 0,744 0,740 0.755 0.731 0.726 0.722 0.717 0.712 0.708 0.703 0,698 0.694 0.689 0.684 0.679 0,674 R 0.0347 0.0349 0.0338 0.0325 0.0322 0.0310 0,0323 0.0311 0.0513 0.0315 0.0506 0.0505 0.0304 0.0296 0,0308 0,0297 0,0285 0.0300 0.0287 0.0299 0.0284 0.0295 0.0303 0.0289 0,0298 0.0286 0,0293 0,0300 0.0298 0,0309 0.0307 0,0302 Pres. 6.58 6.73 6.42 6.07 6,04 5,71 6,21 5.88 5.98 6.13 5.88 5.91 5.93 5.71 6.17 5,84 5,47 6,07 5.65 6.13 5.63 6.10 6.42 5.97 6.34 5,97 6,26 6,57 6.55 7,04 7.01 6,87 Alt. -.75 -.98 -,51 0.05 0,10 0,66 -,18 0.38 0.21 -.04 0.37 0.53 0.29 0,67 -,12 0,45 1,10 0,06 0.77 ".04 0.80 0.00 -.51 0.22 -,38 0,22 -,26 -,74 -.70 "I,43 -1.38 -I,18 Mariner 6, Phase Angle = 90.9 -12.7 -13.1 -13.5 -13.9 -14.3 -14.6 -15,0 -15.3 -15.5 -15.8 -16,1 -16.3 -16.5 -14.0 -14.2 -14-4 10 42.7 41.6 40.3 39.0 37,8 36,7 35.6 34,5 33,5 32.5 31,6 30.7 29.8 27,4 26,5 25,8 0.224 0.971 0.243 0.966 0,266 0,960 0.288 0.953 0,309 0,946 0.328 0,939 0.346 0,933 0.364 0.926 0.380 0,919 0.396 0.912 0,411 0.905 0.425 0,898 0.440 0,891 0.458 0.877 0.471 0,869 0,483 0,863 0.0559 0.0552 0.0514 0.0516 0.0505 0.0488 0.0464 0,0444 0,0446 0.0452 0.0437 0.0462 0.0451 0.0425 0,0408 0.0408 3.97 4.26 4.20 4.60 4.79 4,85 4,77 4,69 4.98 5.32 5,26 6.00 5,99 5.74 5.55 5.74 4.29 3.60 3.74 2.84 2,42 2,29 2.46 2,64 2,04 1.37 1.48 0.18 0.19 0.61 0,94 0.61 259 260 CHARLES W. HORD TABLE I continued Mariner 6, Phase Angle = 90.9 Lat. -14.6 -14.8 -14.9 -15.1 -15.2 -15.4 -15.5 -15.7 -15.8 -15.9 -16.0 -16.1 -16.3 -16.4 -16.5 -16.5 -16.6 -16.7 -16.8 -16.9 -17.0 -17,0 -17.1 -17.2 -17.2 -17.3 -17.3 -17.4 -17.4 -17.5 -17.5 -17.5 -17.6 -17.6 -17.6 -17.7 -17.7 -17.7 -17.7 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 -17.8 Lon. 25.0 24.3 23.5 22.8 22.1 21.4 20.8 20.1 19.4 18.8 18.4 17.5 16.9 16,3 15,6 15.0 14.4 13,8 13.3 12.7 12.1 11.5 11.0 10.4 9.9 9.3 8.8 8.2 7.7 7.1 6.6 6.1 5.6 5.1 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.1 359.6 359.1 358.6 357.7 357.2 356.7 356.3 355.8 355.3 354.9 354.4 354.0 ~ Uo 0.495 0.506 0,517 0.528 0.538 0,548 0.558 0.567 0.577 0.586 0.591 0,603 0,612 0,620 0.628 0.636 0.644 0.652 0.659 0.666 0.674 0,681 0.688 0.694 0.701 0.708 0.714 0.720 0.726 0.732 0.738 0.744 0.750 0.756 0.761 0.766 0.772 0.777 0.782 0.787 0.792 0.797 0.802 0.806 0.811 0.816 0.820 0.828 0.833 0.837 0.841 0.845 0.849 0.853 0.856 0.860 0.856 0.849 0,842 0.835 0,828 0.822 0,815 0.808 0,801 0.794 0.790 0,781 0.774 0.767 0.760 0.753 0.746 0.740 0.733 0,726 0.719 0.712 0,706 0.699 0.692 0.685 0.678 0.671 0.665 0.658 0.651 0.644 0.637 0.630 0.624 0.617 0.610 0.603 0.596 0.589 0.583 0.576 0.569 0.562 0.555 0.548 0.542 0.528 0.521 0.514 0.508 0.501 0.494 0.487 0.480 0.473 R 0.0415 0.0412 0,0408 0.0390 0,0381 0.0379 0.0369 0.0564 0.0364 0,0369 0.0369 0.0367 0.0362 0.0350 0.0338 0.0353 0.0325 0.0322 0.0317 0.0301 0.0301 0.0298 0.0292 0.0294 0.0287 0.0289 0.0285 0.0280 0.0283 0.0275 0.0273 0.0265 0.0257 0.0262 0.0259 0.0259 0.0261 0.0253 0.0252 0.0251 0.0240 0.0242 0.0241 0.0235 0.0238 0.0222 0.0224 0.0212 0.0215 0.0208 0.0205 0.0201 0.0194 0.0197 0.0193 0.0195 Pres. 6.08 6.18 6.24 5.94 5.87 5.95 5.83 5.85 5.97 6.24 6.33 6.45 6.42 6.19 5.97 5.95 5.81 5.82 5.77 5.37 5.48 5.48 5.37 5.53 5.41 5.55 5.50 5.41 5.62 5.43 5.45 5.25 5,07 5.32 5.28 5.36 5.52 5.31 5.34 5.38 5.05 5.22 5.24 5.10 5.26 4.76 4.89 4.58 4.76 4.57 4.51 4.41 4.20 4.38 4.29 4.44 Aft. 0.04 -.12 -.22 0.26 0.39 0.25 0.45 0.42 0.22 -.22 -.36 -.56 -.51 -.14 0.22 0.26 0.49 0.48 0.56 1.27 1.07 1.08 1.27 0.99 1.21 0.96 1.04 1.20 0.83 1.18 1.14 1.50 1.85 1.37 1.45 1.30 1.00 1.39 1.34 1.26 1.90 1.57 1.52 1.80 1.49 2.48 2.22 2.86 2.49 2.90 3.03 3.25 3.73 3.32 3.54 3.17 MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIMENT TABLE I continued Mariner 6, Phase Angle = 90.9 Lat. Lon. U ~o R 0.0194 0.0190 Pres. Alt. 4.44 4.37 3.17 3.33 -17.7 -17.7 353.5 353.1 0.864 0.867 0.467 0.460 -17.7 352.6 0,871 0.453 0.0187 4,31 3.48 -17.7 352.2 0.874 0.0186 4.34 3.41 -17.6 351.7 0,878 0.0180 4.14 3.88 -17.6 -17.6 -17.6 -17.5 -17.5 -17,5 351.3 350.8 350.4 350.0 349.5 349.1 0.881 0,884 0,887 0.890 0.893 0.896 0.446 0.439 0.432 0.426 0.419 0,412 0.405 0.398 0.0184 0.0180 0.0176 0.0175 0.0167 0.0174 4.36 4.28 4.17 4.18 3.92 4.27 3.37 3.54 3.80 3.79 4.42 3.57 Mariner 7, Phase Angle = 46.3 -35.6 -36.2 -36.8 -37.4 -37.9 -38.5 -39.0 -39.5 -40.0 -40.5 -41.0 -41.5 -42,0 -42.4 -42.9 =43.3 -43.8 -44.2 -44.6 -45.1 -45.5 -45.9 -46.3 -46.7 -47,1 -47,5 -47.9 -48.2 -48.6 -49.0 -49.4 -49.7 -50.I 50.4 49.7 49.0 48.3 47.7 47.1 46.5 45.9 45.3 44.7 44.2 43,6 43,1 42.6 42.1 41.6 41.0 40.5 40.1 39.6 39.1 38.6 38.1 37.6 37.2 36.7 36.2 35.8 35.3 34.9 34.4 33.9 33.5 0.317 0.330 0.343 0.355 0.367 0.578 0.389 0.400 0.410 0.420 0.429 0.438 0.447 0.456 0.464 0.472 0.480 0,488 0.495 0.503 0.510 0.517 0.524 0.530 0.537 0,543 0.549 0.556 0.562 0,567 0.573 0,579 0.584 0.615 0,620 0,624 0,628 0.632 0.655 0,639 0,641 0.644 0.646 0.648 0.650 0,652 0.654 0.655 0,656 0.658 0.658 0.659 0.660 0,661 0.661 0.661 0.662 0.662 0.662 0,662 0,661 0.661 0.661 0.660 0.660 0.659 0.0711 0.0678 0,0652 0.0623 0.0605 0.059~ 0.0577 0,0555 0.0528 0,0501 0.0480 0.0462 0.0451 0.0440 0.0430 0.0414 0.0389 0.0388 0.0389 0.0386 0.0387 0.0385 0.0385 0.0387 0.0392 0.0401 0.0397 0.0401 0.0405 0.0417 0.0425 0.0425 0.0421 7.49 7.31 7.21 7.01 6.96 6.98 6.92 6.73 6.44 6.13 5.90 5.70 5.62 5.54 5.45 5.25 4.88 4.95 5.04 5.06 5.16 5.19 5.27 5.37 5.55 5.83 5.80 5.98 6.13 6.46 6.72 6.81 6.77 -2.04 -1.81 -1.67 -1.39 -1.32 -1.34 -1.25 -.98 -.53 -.04 0.33 0.68 0.82 0.97 1.13 1.50 2.24 2.10 1.90 1.88 1.67 1.63 1.47 1.27 0.94 0.46 0.50 0.21 -.04 -.57 -.97 -1.09 -1.04 -50.5 33.0 0.589 0.658 0.0413 6.67 -.88 -50.8 32.6 0.595 0.658 0.0409 6.64 -.85 -51.2 -51.5 -51.9 -52.2 32.1 31.7 31.2 0.600 0.605 0.610 0~614 0.657 0.656 0.655 0.0405 0.0406 0.0403 0.0386 6.61 6.69 6.67 6.32 -.80 -.92 -.88 30.8 0-~54 -.35 261 262 CHARLES W. HORD T A B L E I continued Mariner 7, P h a s e Angle = 46.3 Lat. Lon. U ~ -52.6 -52.9 -53.3 -53.6 -53.9 -54.3 -54.6 -54,9 -55.3 -55.6 -55.9 -56.2 -56.6 -56.9 -57.2 -57,5 -57.8 30.3 29.9 29.4 29,0 28.5 28.0 0.619 0.624 0.628 0.633 0.637 0.641 0,645 0.649 0.653 0.657 0.661 0.665 0.668 0.672 0.676 0.679 0.682 0.653 0.651 0.650 0.649 0.647 0.646 0,645 0,643 0,641 0.640 0.638 0.636 0.634 0.632 0.630 0.628 0.626 27.6 27.1 26.7 26,2 25.8 25.3 24,8 24.4 23.9 25.4 22.9 R 0.0390 0.0400 0.0388 0.0385 0.0386 0.0389 0.0390 0.0375 0,0374 0.0370 0.0375 0.0375 0.0383 0.0576 0.0384 0.0395 0.0407 Pres. Alt. 6.47 6.80 6.53 6.53 6,60 6.73 6.81 6,48 6,49 6,44 6.62 6.67 6.94 6.80 7.08 7.42 7.80 -.59 -I.08 -.68 -.68 -.78 -.98 -I.10 -,59 -.61 -.53 -.81 -.89 -1.29 -I.08 -1.48 -1.95 -2.46 Mariner 7, Phase Angle = 90.7 -19.8 -20.4 -2|.4 -22.3 -23.3 -24.1 -24.9 -25.7 -26.4 -27.1 -28.4 -29.0 -29.6 -30.2 -30.7 -31,~ -3!.7 -32.2 -32.7 -33.1 -33,6 -34.0 -34.4 734.8 -35,2 -35.6 -35,9 -36,3 -36.6 -37.0 -37.3 -37.6 -37.9 353.8 353.2 352.3 351.5 350.6 349.8 349.0 348,2 347.4 346,7 345.2 344.5 343.9 343.2 342.5 341,8 341.2 340.5 339.8 339.2 338.6 337.9 337.3 336.6 336,0 335.4 334,8 334.1 333.5 352.9 332.3 331.6 331.0 0.225 0.238 0.260 0.281 0.301 0.320 0.338 0.355 0.371 0.387 0.416 0.429 0.443 0.455 0.467 0,479 0,491 0.502 0.512 0.523 0,533 0.543 0.553 0.562 0.571 0.580 0,589 0.597 0.606 0,6|4 0.622 0.630 0.637 0.971 0.968 0.962 0.956 0.949 0.943 0.936 0.929 0.923 0.916 0.903 0.896 0.890 0.883 0.876 0,870 0.863 0.856 0.850 0.843 0.836 0.830 0.823 0.816 0.810 0.803 0.797 0.790 0.783 0.777 0.770 0.763 0.757 0.0588 0.0574 0.0549 0.0523 0.0503 0.0481 0.0461 0,0445 0.0433 0.0420 0.0401 0.0387 0.0376 0.0369 0.0360 0,0351 0.0344 0.0336 0.0327 0.0324 0.0320 0.0312 0.0316 0.0304 0.0303 0.0298 0.0291 0.0294 0.0282 0.0280 0.0283 0.0276 0.0272 4.51 4.42 4.53 4.57 4.64 4.62 4.58 4,58 4.61 4.61 4.63 4.55 4.49 4.49 4,44 4.40 4.37 4.31 4.22 4.27 4,30 4.20 4.40 4.22 4.29 4.26 4.17 4.34 4.10 4,14 4.30 4.21 4.17 3.49 3.23 2.98 2.88 2.74 2.79 2.86 2,86 2.80 2.81 2.76 2.98 3.07 3.06 3.18 3.28 3.35 3.48 3.68 3.58 3.49 3.73 3,27 3.69 3,52 3.60 3,81 3.41 3.97 3.87 3.50 3.72 3.81 MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIMENT TABLE I continued Mariner 7, Phase Angle = 90.7 Lat. Lon. ~ ;~o R Pres. Alt. -38.2 -38.5 -38.8 -39.1 -39.3 -39.6 -39.8 -40,I -40.3 -40.6 -36.5 -36.7 -36.9 -37.1 -37.2 -37.4 -37.5 -37.7 -37.8 -38.0 -38.2 -38.4 0.645 0.652 0.659 0.666 0.673 0.680 0.686 0.693 0,699 0.705 0.695 0.700 0.706 0.711 0.716 0.721 0.725 0.730 0.735 0.739 0.748 0.752 0.750 0.744 0.737 0.730 0.724 0.717 0.710 0,704 0.697 0.691 0.651 0.644 0.637 0.631 0.624 0.618 0.611 0.604 0.598 0.591 0.578 0.571 3.90 4.01 3.73 3.93 3,85 3.58 0.756 0.760 0.764 0.768 0.772 0.565 0.558 0.551 0.545 0.538 0.0268 0.0264 0.0265 0.0260 0,0258 0.0260 0.0260 0.0266 0e0259 0.0264 0.0271 0.0266 0.0271 0.0273 0.0280 0.0285 0.0297 0.0506 0.0309 0.0312 0.0311 0.0316 0.0314 0.0316 0.0316 0.0322 0.0308 4.13 4.09 4.20 4.12 4.15 4.27 4.37 4.62 4.47 4,69 5.04 4.95 5.17 5.31 5.63 5.88 6.37 6.75 6.94 7.13 7.27 7.54 7.57 -38.8 -38.9 330.4 329.8 329.2 328.5 327.9 327.3 326.7 526.1 325.5 524.9 318.0 317.4 316.8 316.3 315.7 315.2 314.6 314.0 313.5 312.9 311.8 311.2 310.7 310.1 309.6 309.0 508.5 -39.0 •3 9 . 1 307.9 507.4 0.776 0.780 0.532 0.525 0.0307 0.0310 -39.1 306.8 0.783 0.518 0.0307 7.92 7.91 •3 9 . 2 •3 9 . 3 306.3 305.7 0.787 0.790 0.512 0.505 0.0310 0.0300 8.12 7.80 -2.85 -2.46 •39.4 •39.4 •39.5 39.5 ,39.6 39.6 39.7 39.7 39.7 39.8 39.8 39,8 39.8 39.8 39.8 305.2 304.6 304.1 303.5 303.0 302.4 301.9 301,3 300.8 300.3 299.7 299.2 298.7 298.1 297.6 0.794 0.797 0.800 0.803 0.806 0.809 0.812 0.815 0.818 0.821 7,28 7.21 7.27 7.21 -2.07 -2,27 -2.08 -2.20 -2,35 -2.22 -2.13 -1.78 -1.91 -1.83 -1,86 -1.77 -1.66 -1.75 -1.67 39.8 39.8 297.1 296.5 0.836 0.838 0.400 0.593 0.0291 0.0292 0.0287 0.0287 0.0288 0.0284 0.0280 0.0272 0.0272 0.0269 0.0268 0,0264 0.0260 0.0260 0,0257 0.0258 7.50 7.65 7.51 7.60 7.72 7.62 7.55 7.29 7.39 7.33 0,826 0.829 0.831 0.834 0.499 0.492 0.485 0,479 0.472 0.466 0.459 0.452 0.446 0.439 0.433 0,426 0.419 0.413 0,406 7.32 7.11 -1.81 -1.53 39.8 296.0 0.840 0.386 0.0245 295.5 0.843 0.380 0.0245 39.8 294.9 39.8 294.4 39.8 t 295.9 39.7 293,4 0.845 0.847 0,849 0.851 0.373 0.367 0,360 0.353 0.0244 0.0245 0.0254 0.0235 6.91 7.01 7.02 7.04 6.75 6.84 -1.24 39.8 -38.5 -38.6 -38.7 0.825 0.0251 3.35 2.78 3.11 2.64 1.92 2.09 1.66 1.38 0.81 0.37 -.42 -I.01 -1.29 -1.56 -1.74 -2.12 -2.15 7.75 -2.39 7.84 8.15 7.71 -2.51 7.72 -2.36 -2.61 7.35 -2.90 -2.33 -2.59 -1.38 -1.40 -1.43 -I.00 -1.15 263 264 C H A R L E S W . tt01~D TABLE I continued M a r i n e r 7, P h a s e A n g l e = 90.7 Lat. -39.7 -39.7 -59.6 -39.6 -59.5 -59.5 -59.4 -59.4 -59.5 -59.5 -59.2 -59.1 -59.0 -59.0 -58.9 -58.8 -58.7 -58.6 -58.5 -58.4 -58.5 -58.2 -38.1 Lon. 292.9 292.5 291.8 291.5 290.8 290.5 289.8 289.5 288.8 288.5 287.8 287.5 286.8 286.5 285.8 285.5 284.8 284.5 285.8 285.4 282,9 282.4 281o9 ~ 0.855 0.854 0.856 0.858 0.860 0.861 0.865 0.864 0.866 0.867 0.868 0.869 0.871 0.872 0.875 0.874 0.875 0.876 0.877 0.~77 0.878 0.879 0.879 ~o R 0.547 0.340 0.554 0.527 0.520 0.514 0.507 0.500 0.294 0.287 0.281 0.274 0.267 0.261 0.254 0.248 0.24I 0.254 0.228 0.221 0.215 0.208 0.202 small v a l u e of k for this region. I n the Hellas d a t a o b t a i n e d for the l a t i t u d e a n d longitude r a n g e from -39?6, 29173 to -3871, 28179 t h e Minnaert p a r a m e t e r s were k = 0.83 =~ 0.04 a n d R 0 = 0 . 0 5 5 . A s u m m a r y of ultraviolet Minnaert p a r a m e t e r s is given in T a b l e I I . D u e to t h e large phase angles of the Mariner o b s e r v a t i o n s c o m p a r e d w i t h g r o u n d - b a s e d observations, an e x a c t comparison of the 3050A reflectances is not possible. E x c l u d i n g unusual p h o t o m e t r i c properties, it is e x p e c t e d t h a t the E a r t h b a s e d m e a s u r e m e n t s of the geometric albedo should be of the s a m e order as the Minnaert constant, R0, for the range of k values found. E a r t h - b a s e d d a t a o b t a i n e d b y I r v i n e et al. (1968) indicate an a v e r a g e geometric albedo ~ 0 0 5 at 3050Jk E a r t h b a s e d r o c k e t d a t a o b t a i n e d in the 25503300_~ w a v e l e n g t h region b y B r o a d f o o t a n d Wallace (1970) give a geometric albedo ~0.09 at 3050A. I n this e x p e r i m e n t , the M a r t i a n polar caps were included in the i n s t r u m e n t field of view. A p a r t of the intensity measured by Broadfoot and 0.0226 0.0226 0.0222 0.0219 0.0218 0.0217 0.0217 0.02'14 0.0210 0.0206 0.0202 0.0195 0.0190 0.0182 0.0178 0.0174 0.0167 0.0167 0.0162 0.0165 0.0161 0.0157 0.0155 Pres. Alt. 6.55 6.60 6.52 6.42 6.46 6.49 6.54 6.52 6.59 6.29 6.19 5.84 5.79 5.47 5.56 5.27 5.05 5.09 4.95 5.05 5.00 4.92 4.76 -.71 -.78 -.66 -.51 -.57 -.61 -.70 -.67 -.46 -.50 -.14 0.45 0.55 1.10 1.50 1.47 1.95 1.82 2.15 1.94 1.99 2.15 2.48 Wallace m a y be a t t r i b u t e d to the considerably b r i g h t e r polar cap which has the effect of bringing their o b s e r v a t i o n s into closer a g r e e m e n t w i t h the Mariner ultraviolet s p e c t r o m e t e r results. T h e Mariner d a t a indicate t h a t t h e c o m b i n a t i o n of desert reflectance, showing a m o n o t o n i c increase in reflectance w i t h decreasing w a v e l e n g t h , c o m b i n e d w i t h a polar cap reflectance, with the b r o a d ozone absorption centered at 2550 ~ ( B a r t h a n d H o r d , TABLE I [ MINNAERT PARASIETERS UVS data Mariner 6 Aurorae Sinus, Margaritifer Sinus Mariner 6 Deuealionis P~egio Mariner 7 DeucMionis Regio, Pandorae Fretum Mariner 7 Hellas k Ro 0.71 ± 0.02 0.037 0.69 ± 0.06 0.031 0.31 ± 0.01 0.022 0.83 ± 0.04 0.055 MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIMENT ~65 .I0 0 0 ILl fJ Z l'-fO 0 0 0 .05 0 0 0 0 I I I I .--I ILl t'," 0 ! I 1 I I 2600 3100 I 3600 WAVELENGTH (A) F1G. 4. M a r i n e r 7 Mars reflectance as a f u n c t i o n of w a v e l e n g t h o b t a i n e d a t l a t i t u d e -1978 a n d l o n g i t u d e 353?8, w i t h /x0 ~ 0.971, /x = 0.225, a n d a p h a s e angle of 4-6?3. T h e d a t a p o i n t s o b t a i n e d e,~¢ery 4.3 A a t a resolution of 20 A h a v e been c a l i b r a t e d a n d d i v i d e d b y t h e solar flux, a n d are p r e s e n t e d here a t 100A resolution c o n s i s t e n t w i t h t h e 3050A reflectance d a t a . 1971), would tend to give the constant reflectance as a function of wavelength observed by Broadfoot and Wallace. An earlier rocket experiment performed by Evans (1965) seems to qualitatively match the spectral shape observed by the Mariner spectrometer for the nonpolar regions of Mars. Evans' experiment used photographic methods while Broadfoot and Wallace used photoelectric detection as did the Mariner ultraviolet spectrometer. Results from the Orbiting Astronomical Observatory (OAO) ultraviolet experiment o~ give geometric albedos of 0.0401 at 3215 A and 0.0428 at 2800 A (Caldwell, 1970) using photoelectric detection methods. SPECTRAL REFLECTANCE Analysis of the Mariner ultraviolet spectrometer (UVS) data has shown that the illuminated disk of Mars has two characteristic ultraviolet spectral reflectances. These two spectral types, associated with the polar and nonpolar regions of the planet, have been discussed (Barth and Hord, 1971). 2000 n~ >- Jo o o Z la.I I--.. z 0 2500 :3000 3500 4000 o WAVELENGTH ( A ) FIG. 5. Mariner 7 s p e c t r u m o b t a i n e d w i t h t h e s p e c t r o m e t e r field o f view including t h e b r i g h t limb o f Mars. This s p e c t r u m was o b t a i n e d a t l a t i t u d e - 2 9 ° a n d l o n g i t u d e 307 °, w i t h a p h a s e angle of 46?3 a n d a solar incidence angle equal to 55 °. 266 CHARLES W. HORD o4 2000 - ~r >bz tu bz I000- 0 I I I I I 2500 I I I 3000 1 ! 1 I I I 3500 o WAVELENGTH (A) I I I I I 4000 FIG. 6. Mariner 7 spectrum obtaincd alt latitude -39?0 and longitude 286?8, with #0 = 0.267, /z = 0.871, and a phase angle of 90?7. Figure 4 shows t h e n o n p o l a r Mars reflectance in t h e w a v e l e n g t h region f r o m 2600 to 3600A, o b t a i n e d b y dividing a c a l i b r a t e d s p e c t r u m of Mars b y t h e solar flux. I n this w a v e l e n g t h interval, each of the 400 n o n p o l a r spectra has the s a m e basic spectral s h a p e as shown in Fig. 4. D u e to the large v a r i a t i o n in the solar flux o v e r t h e long w a v e l e n g t h channel (1900- 4300/~), the i n s t r u m e n t s e n s i t i v i t y was set to cause a full-scale m e a s u r e m e n t a t a b o u t 3600/~ for m o s t of the s p e c t r a o b t a i n e d w h e n observing t h e i l l u m i n a t e d disk of Mars. This was done in order to o b t a i n necessary sensitivity at shorter w a v e lengths. H o w e v e r , several s p e c t r a were o b t a i n e d which were c o m p l e t e l y on scale t h r o u g h o u t the spectral r a n g e 2500 to 1.25 O 1.00 O O .75 0 0 0 0 0 I I I I I o o I I o 0 0 " .50 .25 0 3000 I 5500 I I |l I I 4000 o WAVELENGTH (A) FXG. 7. Ratio of terminator to limb intensities obtained by dividing the spectrum in Fig. 6 by that in Fig. 5. MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIMENT 267 4300J~. Figure 5 shows one of several the airmass along the instrument line of ultraviolet spectra measured with the sight. Near the bright limb of the planet, field of view of the instrument crossing the where the emission angle was large, the bright limb of Mars. In this particular airmass is better represented by the more geometry the long dimension of the UVS accurate Chapman function (see e.g., Hord slit made an angle of 55 ° with the tangent et al., 1970). In this discussion, the airmass to the limb and the field of view is only will be represented by the secant factor, partially filled with the bright disk of 1//t, as this assumption does not alter the Mars. This measurement at the bright limb conclusions reached here. Pressure is with the field of view underfilled allowed directly proportional to column density an on-scale (at all wavelengths) spectrum and therefore to optical thickness for a to be obtained at the bright limb. Figure 6 homogeneous atmosphere, independent of shows one of the spectra taken near the temperature structure, so that evening terminator which are also fully P = (Po/ro) r. (3) on-scale due to the decreased solar illumination. Figure 7 shows the reflectance near This assumption is made at the beginning the terminator relative to the bright limb and its accuracy will be evaluated at the reflectance and was obtained by dividing end of the analysis. In the absence of a the spectrum in Fig. 6 by the Fig. 5 turbid atmosphere, r 0 = 0.032 for Po = spectrum. A similar relative spectral 6.0rob if the major constituent is carbon reflectance is obtained by dividing any of dioxide. Ground reflectance is represented the spectra taken near the terminator by by the Minnaert function in Eq. (2). The any of the limb spectra. The spectral Minnaert parameters R o and k are taken to shapes are very nearly identical shortward be constant for this analysis, an assumption of about 3600A and show the character- which can be tested a posteriori. istie shape of the other nonpolar spectra. Atmospheric extinction is assumed to be Longward of 3500 A the terminator to limb due to scattering only so that pure intensity ratio increases monotonically, absorption is neglected. Taking into acwith wavelength, and illustrates the dif- count extinction and multiple scattering, ferent photometric properties in this the measured reflectance at 3050 A is wavelength region. The terminator spectrum was obtained in the visually bright Hellas region which accounts for the increase in ratio at longer wavelengths. + Ro/to~/t~-1 exp (-rM)} (4) PHOTOMETRIC MODEL In the following analysis, Mariner 6 and 7 infrared spectrometer pressure data (Herr et al., 1970) are combined with ultraviolet data in order to give a more realistic model of the 3050 A reflectance of Mars. The ultraviolet reflectivity is assumed to consist of two components; an atmospheric part, (p/4) (r//t), and a ground contribution, R0/t0k/t k-~. For the atmospheric part, p is the atmospheric scattering phase function, T is the vertical scattering optical depth, and r//t is the optical depth along the instrument line of sight. The phase function, p, depends upon the scattering angle, ~, which is the supplement of the phase angle. In the factor r//t, 1//t is where [1 - exp ( - r M ) ] / r M and exp ( - r M ) are attenuation factors associated with the atmospheric and surface parts of the reflectance. Total airmass, M, of the incident and outward optical paths is 1//to + 1//t. The multiple scattering factor, f, is a function of/t, t*0, ~, r as well as of the ground reflectance and the form of the phase function. Including the factor f makes Eq. (4) exact for the model selected. In practice, the magnitude of f can be estimated by comparison with exact solutions for simplified cases. For the small values of R 0 and r encountered on Mars, the strongest dependence o f f is on r. The f a c t o r f i s greater than unity by an amount of order 7. In this analysis f is taken to be 268 CHARLES W. HORD u n i t y which causes the optical thickness to be o v e r e s t i m a t e d b y a small amount. W h e n Eq. (4) is solved for optical thickness and substituted into Eq. (3), the pressure as a function of the 3 0 5 0 ~ reflectance, R, is p_Po 1 . [Ro/~0k/~k-I-RA] where R A is defined as pl(4[xM). E q u a t i o n (5), with values for the constants rolPo, R 0, k, and the phase function, p(~), constitute an algorithm for conversion of ultraviolet reflectance into pressure. MARINER INFRARED AND ULTRAVIOLET PRESSURES In the normalization of these d a t a to a single occultation m e a s u r e m e n t (Barth and Hord, 1971), only one p a r a m e t e r can be specified, n a m e l y rop(~)/Po, assuming no ground reflectance. Mariner infrared spectrometer pressure measurements (Herr et al., 1970) provide the o p p o r t u n i t y to u n d e r s t a n d more a b o u t the Mars physical p a r a m e t e r s used in Eq. (5) and provide a test of the assumptions involved. The p r i m a r y assumptions are a uniform ground reflectance and homogeneous scattering atmosphere. A total of 23 infrared measurements from Mariner 6 and 35 from Mariner 7 were c o m p a r e d with corresponding ultraviolet measurements. Due to an offset in the fields of view of the two instruments, m e a s u r e m e n t s of" similar areas were made at subsequent times. The set of 58 infrared measurements which lie along the ultraviolet viewing p a t h were selected for comparison. A corresponding set of 58 ultraviolet measurements, which correspond best in latitude and longitude with the infrared measurements, were also selected. Differences in spatial resolution a n d position observed on the planet have not been t a k e n into account in this analysis. The long dimension of the infrared s p e c t r o m e t e r slit, orientated perpendicular to the Sun, was 2?0 compared with 2?3 for the ultraviolet spectrometer. I n the narrow dimension, the effective infrared field of view was a b o u t half the size of the 0?23 ultraviolet dimension. Using these 58 measurements the parameters ro/Po, Ro, k, and p(~) for the scattering angles observed (~ = 89 °, 118 °, 134 °) were varied in order to minimize the root mean square (rms) error defined b y rms -'Y [ W (p(UVS)_ ~.~ ~ i /'=' L. . . . :v- p(IRS)~] --i / / 1/2 , J where p~uvs) and p~nts) are the ultraviolet, Eq. (5), and infrared pressure measurements. Using nonlinear least squares techniques, the sensitivity of the rms error to each of the p a r a m e t e r s of Eq. (5) could be tested. W i t h this procedure the phase function and optical d e p t h p a r a m e t e r s were not well separated and the Minnaert parameter, k, did not have a strong effect on the rms error. The p a r a m e t e r s obtained by this analysis were rop(89o)/Po = 0.0111, p(118°)/p(SW ') --0.qd, p(134°)/p(89 °) 1.18, R0 = 0.015, and k ~ 1. This choice of p a r a m e t e r s gave an rms error of 9% taking into account the degrees of freedom used in specif~'ing five parameters. The agreement is good considering t h a t pressure measurements used in this analysis varied b y more t h a n a factor of two. On a large scale, the agreement between the ultraviolet and infrared techniques is good, with the exception of the swath near Aurorae Sinus. I t is notable t h a t this is a region where chaotic terrain was observed b y the Mariner television e x p e r i m e n t (Sharp et al., 1971 ). This is also the region n o t e d b y N e u g e b a u e r et al. (1971), where the observed albedo did not give the predicted surface t e m p e r a t u r e , as measured b y the Mariner 6 infrared r a d i o m e t e r experiment. I t is suggested t h a t the assumption of h o m o g e n e i t y of' ultraviolet atmospheric scattering m a y be violated here and m a y be related to the different appearance of this region. On a finer scale, differences between the ultraviolet and infrared observations a~.'e evident.. Most notable is the Hellas region where the general trends of the ultraviolet and infrared d a t a agree b u t where infrared pressures show much larger fluctuations in the terrain t h a n is seen in MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIMENT the ultraviolet. Ultraviolet pressures determined from Eq. (5) are listed in Table I. A total of 337 pressure measurements were made. The inability to separate phase function and optical depth normalizations results from the small optical depth of the scattering atmosphere. A small optical depth causes the attenuation factors [1 - exp (-rM)]/-rM and exp (-TM) to show only small variation for the range of air masses, M, involved. Large values of air mass were encountered near the bright limb while the ultraviolet spectrometer was changing from high gain, used for observing the Mars upper atmosphere, to low gain, for observations of the disk reflectance. Some observations made immediately after changing gain have larger air mass values and are consistent with the interpretation given here. However, the large variation of M over the instrument field of view near the bright limb, coupled with the strong effect of viewing geometry uncertainties, limits the sensitivity of these measurements for separation of optical thickness and phase function normalizations. In the 1971 Mariner 9 ultraviolet spectrometer experiment, observations will be made continuously across the bright limb at 4km intervals with a resolution of the order of the lower atmosphere scale height. These limb data, coupled with observations nearer the terminator than were obtained by Mariner 6 and 7, can provide a basis for separating the 70 and p normalizations. Lack of separation of 70 and p factors means t h a t Eq. (5) can be expressed in a simpler way. Let the attenuation factors and multiple scattering factor, f, in Eq. (4) be replaced by average values (f>, <[1 - exp( 7M)]/7M>, and <exp(-TM)>. Results of this analysis indicate t h a t (f> ~ 1.1, <[1 - exp(-TM)]/TM> ~ 0.9, and <exp (-TM)> ~ 0.8. If these corrections, which are of order unity, are assimilated so that R/(f> --+ R, 7([1 - e x p ( - T M ) ] / T M > -+ 7, and Ro(exp (--~M)> -+ Ro, then Eq. (4) can be written R = (p14)(71t~) + R o t , o~t~~-~. (7) This form displays the essential dependence of 3050A reflectance on atmospheric 269 scattering and ground reflectance. Equation (7) may be combined with the pressure relation, Eq. (3), giving Po P = 70(p/4i J R , - Ro(~ot~)k]. (S) In this form, the coupling of the 70 and p normalizations is evident. I f the phase function is normalized so that p(89 °) = 1, then 70= 0.068 for Po = 6rob, which is about twice the scattering expected from a pure molecular atmosphere. Also note that the scattering phase function dependence, p(~), is more nearly isotropic than Rayleigh. This behavior is expected for particulate matter at the large scattering angles observed (see e.g. Deirmendjian, 1969). It is probable that the particulate scatterer has a forward peaked phase function so that p(89 °) is likely to be less than one in order to satisfy the phase function normalization relation 4~ p ( ; ) d ~ = ~0. (9) I f the single scattering albedo, &0, is less than unity, i.e. if pure absorption occurs, then p(89 °) may be even smaller. I f p(89 °) is less than one, then To > 0.068. Apparent agreement of the ultraviolet measurements with infrared measurements suggests the assumption of a homogeneously mixed particulate scatterer is good. This implies that the particulate scatterers may have fairly long lifetimes in the Martian atmosphere and therefore puts a restriction on particle size (see e.g. Pollack and Sagan, 1969). Turbulent support may allow somewhat larger particles to contribute to a uniformly mixed scatterer. The monotonic increase in ultraviolet refleetance with decreasing wavelength noted earlier (Barth and Hord, 1971) implies a small scatterer. I f these two restrictions are placed on the particle size, i.e. if the particles must be large enough to have the observed phase function dependence but small enough to be suspended uniformly in the atmosphere, then the scatterer size may be comparable to the scattering wavelength, or about 270 CHARLES W. HORD 0.3/~. A n o t h e r possibility t h a t admits to a n o n u n i f o r m l y mixed scatterer is t h a t larger particles account for the scattering and are preferentially stirred up for short times in the topographically low places on Mars. An atmospheric spectral feature observed b y the Mariner infrared spectrometer and identified as a silicate material (Herr and Pimentel, 1969) m a y be the nonmolecular scatterer observed in the ultraviolet. The limb haze observed b y the Mariner television e x p e r i m e n t does not appear homogeneous (Leovy et al., 1971) and is difficult to reconcile with the ultraviolet d a t a (Cutts, 1971 ). The concept of measuring surface pressure is based upon measured ultraviolet intensity being d o m i n a t e d b y scattering from an optically thin atmosphere against a small surface background. This possibility has been considered earlier b y E v a n s (1965), Pollack (1967), and Sagan and Pollack (1966, 1968). ALTITUDE ZERO Although pressure is the more fundamental measurement, relative altitudes can be inferred from the ultraviolet d a t a if some assumptions are made a b o u t atmospheric t e m p e r a t u r e structure. Belton and H u n t e n (1971) and H e r r et al. (1970) have discussed the use of simple isothermal models in making pressure-to-altitude conversions. H e r r et al. chose a single effective isothermal t e m p e r a t u r e , while Belton and H u n t e n a d o p t e d an isothermal model with variable effective t e m p e r a t u r e in order to b e t t e r represent latitudinal t e m p e r a t u r e variation. The simpler conversion has been used here with a single effective isothermal t e m p e r a t u r e of 190°K corresponding to a 10kin scale height. I f the true Martian atmosphere is more nearly adiabatic with a 5 ° K / k m lapse rate (Belton and H u n t e n , 1971) t h e n an isot h e r m a l average model gives relative altitudes which are in error b y ~<10% for the range of pressures encountered. These authors have selected a value near the m e a n Mars pressure for their altitude zero. H e r r et al. (1970) selected 6.0mb for their altitude zero while Belton and H u n t e n (1971) selected 5.5mb. I t is suggested t h a t the selection of a normalization p a r a m e t e r such as this be chosen to convey physically useful information. The physically useful normalization or choice of zero altitude on the E a r t h is sea level. B a r t h (197l) has suggested t h a t a meaningful normalization on Mars is to choose zero altitude to occur at the triple pointpressure of water, P 0 = 6.105rob. W i t h this selection, liquid water is i m m e d i a t e l y precluded at all altitudes greater t h a n zero. W a t e r m a y exist at altitudes less t h a n zero if the t e m p e r a t u r e is greater t h a n 0°C and equilibrium conditions are reached. I f Mars pressure is constant over geologic time, this would provide a unique pressurealtitude conversion reference point. SUMMARY AND COMPARISON WITH OTHER MEASUREMENTS Table I I I shows the subset of Mariner ultraviolet and infrared s p e c t r o m e t e r d a t a t h a t were compared. Figures 8, 9, and 10 show the infrared pressures from Table I I I and the complete set of ultraviolet pressures d e t e r m i n e d from the comparison in Table I. Table IV lists the Mariner infrared and ultraviolet pressure d a t a obtained n o r t h of Aurorae Sinus. As was the case in Table I I I , only the subset of d a t a points which correspond closely in latitude and longitude are given. The anomalous region where the ultraviolet and infrared intereomparison breaks down, is evident in the left-hand side of Fig. 10. The p r i m a r y effect of the solution for five parameters, which minimize the root mean square difference between nltraviolet and infrared measurements, is the gross shifting of the ultra.violet vertical scale in Figs. 8, 9, and 10. A residual rms error of 9% is quite small considering the n u m b e r of components. I f the sources of error are uneorrelated, it is correct to infer t h a t errors due to: (l) relative ultraviolet reflectance, (2) infrared spectrometer pressures, (3) field of view differences, (4) assumption of uniform ground reflectance, and (5) assumption of a homogeneous scattering atmosphere, all introduce an error less t h a n 9%. MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIMENT TABLE III MARINER 6, PRESSURE COMPARISON (in rob) P(UVS) Lat. 6.23 3.3 Lon. 21.9 P(IRS) 6.23 Lat. 2.7 Lon. 21.9 Difference 0 6.58 2.7 20.6 6.45 2.1 20.7 0.13 6.42 2.4 19.7 5.92 1.7 19.6 0.50 5.71 1.8 18.5 6.50 I.I 18.3 -0.79 5.91 .8 16.0 6.15 0.2 15.9 -0.24 6.17 .4 14.7 6.32 -0.3 14.7 -0.15 6.07 .0 13.5 6.16 -0.7 13.4 -0.09 5.63 -. 4 12.3 5.89 -I. 0 12.2 -0.26 5.97 -. 8 Ii. i 5.82 -i. 4 Ii. 0 O. 15 7.04 -1.4 8.8 5.82 -2.0 8.6 1.22 4.79 -14.3 37.8 4.63 -13.3 38.1 0.16 4.77 -15.0 35.6 4.54 -14.2 35.2 0.23 5.99 -16.5 29.8 5.27 -15.7 30.0 0~72 5.77 -16.8 13.3 5.67 -16.2 13.2 O. i0 5.48 -17.0 11.5 5.46 -16.5 11.4 0.02 5.41 -17.2 9.9 5.46 -16.7 9.7 -0.05 5.45 -17.5 6.6 5.51 -17.0 6.4 -0.06 5.28 -17.6 4.5 5.71 -17.1 4.7 -0.43 5.05 -17.8 1.5 4.96 -17.3 1.6 0.05 5.26 -17.8 359.6 4.95 -17.3 359.7 0.31 4.20 -17.8 355.3 4.66 -17.3 355.2 -0.46 4.44 -17.8 354.0 4.66 -17.3 353.7 -0.22 4.28 -17.6 350.8 4.70 -17.1 350.8 -0.42 4.88 -43.8 41.0 6.26 -47.2 41.4 -1.38 5.04 -44.6 40.1 5.01 -48.3 40.0 0.03 5.55 -47.1 37.2 5.59 -50.6 37.4 -0.04 5.80 -47.9 36.2 6.07 -51.6 " "36.1 -0.27 6.46 -49.0 34.9 6.43 -52.7 34.8 0.03 6.77 -50.1 33.5 5.50 -53.7 33.4 1.27 6.61 - 51.2 32.1 5.29 -54.7 32.1 i. 32 6,53 -53.3 29.4 5.48 -56.7 29.5 1.05 6.73 -54.3 28.0 5.49 -57.7 28.1 1.24 6.49 -55.3 26.7 6.74 -58.6 26.7 -0.25 6.67 -56.2 25.3 6.38 -59.6 25.3 0.29 7.08 -57.2 23.9 6.72 -60.5 23.9 0.36 4.62 -24.1 349.8 4.91 -26.4 349.7 -0.29 4.61 -26.4 347.4 4.75 -28.3 347.7 -0.14 4.63 -28.4 345.2 4.42 -30.0 345.7 0.21 4.53 -29.0 344.5 4.32 -31.6 343.8 0.21 4.22 -32.7 339.8 4.49 -34.3 340.0 -0.27 4.30 -33.6 338.6 4.16 -35.6 338.1 0.14 4.29 "-35.2 336.0 4.19 -36.7 336.2 0.I0 4.34 -36.3 334.1 4.34 -37.7 334.4 0 4.30 -37.3 332.3 4.05 -38.7 332.5 0.25 -0.I0 4.12 -39.1 328.5 4.22 -40.4 328.7 4.37 -39.8 326.7 4.26 -41.2 326.8 0.II 4.69 -40.6 324.9 4.83 -41.9 324.9 -0.14 7.71 -38.9 308.5 6.57 -40.3 308.6 1.14 7.91 -39.1 306.8 6.55 -40.6 306.8 1.36 7.72 -39.6 303.0 7.59 -41.0 302.8 0.13 7.29 -39.7 301.3 7.I0 -41.1 301.4 0.19 7.28 -39.8 299.2 8.16 -41.2 299.2 -O. 88 -0.39 7.21 -39.8 297.6 7.60 -41.2 297.5 6.91 -39.8 296.0 6.08 -4 i. 2 295.7 O. 83 6.60 -39.7 292.3 6.77 -41.0 292.2 -0.17 -0.28 6.49 -39.5 290.3 6.77 -40.9 290.5 6.39 -39.3 288.8 7. O0 -40.7 288.8 -0.61 5.84 -39.1 287.3 6.59 -40.5 287.1 -0.75 271 272 CHARLES ~V. HORD W (3 p..- C.J I I I I I I ! I I I I I I ! I I | 4 oO .•~; " ~ -. L.~ - • ~ 0 0 ~ tll @ • 2 5 n- o3 ~'" ~O 6J05 -%°" p- 0,. 7 ~ <[- 2 - -4 8 9 I0 - I 80 I ! 60 ~ | 40 I 1 1 P_O I I 0 I ~, 4 0 t I 320 | I 30 0 I I 280 LONGITUDE Fro. 8• M a r i n e r 6 u l t r a v i o l e t a n d i n f r a r e d s p e c t r o m e t e r pressures, Tile p a t h of t h e c e n t e r of t h e i n f r a r e d s p e c t r o m e t e r field of v i e w across Mars is i n d i c a t e d b y d a s h e d lines a n d circles d e s i g n a t e p r e s s u r e m e a s u r e m e n t s . Only t h a t p a r t of t h e i n f r a r e d d a t a w h i c h overlaps w i t h u l t r a v i o l e t m e a s u r e m e n t s is shown. T h e p a t h of t h e c e n t e r of t h e u l t r a v i o l e t s p e c t r o m e t e r fiold of view across Mars is i n d i c a t e d b y solid lines a n d p r e s s u r e m e a s u r e m e n t s are d e s i g n a t e d b y dots, Tho B a r t h p r e s s u r e n o r m M i z a t i o n has b e e n u s e d so t h a t zero a l t i t u d e occurs a t t h e triple p o i n t p r e s s u r e o f water. T a b l e V gives a c o m p a r i s o n of COz pressures d e t e r m i n e d b y Belton a n d H u n t e n (1971). T h e i r m e a s u r e m e n t s are b a s e d u p o n E a r t h - b a s e d m e a s u r e m e n t of the 1/, b a n d of C02 during t h e 1969 opposition. Figures 11 a n d 12 show the locations of t h e Belton a n d H u n t e n m e a s u r e m e n t s a n d the c o m p a r i s o n pressures listed in T a b l e V. The p r o j e c t e d field of view for these m e a s u r e m e n t s was 8 0 0 k m square or a b o u t 13 ° of l a t i t u d e or longitude at the equator• Points in T a b l e V were g e n e r a t e d b y s i m p l y a v e r a g i n g t h e CO2 pressures in a b o x of 20 ° longitude a n d 20 ° l a t i t u d e centered a t the locations where Mariner u l t r a v i o l e t m e a s u r e m e n t s were made. A subset of these averages were selected which showed the changes in C02 pressure along the u l t r a v i o l e t o b s e r v a t i o n swaths. More sophisticated weighting MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER m e t h o d s were tried and f o u n d not to materially improve or worsen the agreement. R e d u c t i o n of box size to l0 ° reduces the n u m b e r of comparison points significantly and does not show how well the general features of the two methods agree. The anomalous region n o r t h of Aurorae Sinus, n o t e d in comparing the Mariner infrared and ultraviolet measurements, is again obvious in the left-hand side of Fig. l l . General agreement exists in this region between E a r t h - b a s e d data. of Belton and H u n t e n and Mariner d a t a of H e r r et al. 273 EXPERIMENT Table VI compares altitudes obtained b y the H a y s t a c k r a d a r facility during the 1967 and 1969 oppositions (Pettengill et al., 1969; Rogers et al., 1970) with altitudes inferred from the Mariner ultraviolet pressure measurements. No scale adjustm e n t has been used so t h a t zero r a d a r altitude corresponds to the triple point pressure of water, P 0 = 6 . 1 0 5 m b . The assumption of an isothermal scale height of 10km, used to convert the ultraviolet pressures to altitude, is a d e q u a t e for this comparison as is seen in Fig. 13. A l0 ° latitude and longitude square centered at IF-J ' | J I I I J I I I 1 I 4 ~ I ~ I I 4, O* *'0b" "a 2 t~ "0 5 . % &o°co l.iJ a l 0 0 I-.. 5-z o~ ~O 0 0 o :.D •.-- ?\~>o ,~." • GO ", - 6.105 .~"0 O,,'-" 0 7 -.q."6 ",':" " o 8 9 -4 J. 80 I0 I 60 I I 40 ,I I 20 I I 0 I ,I 3 40 I I 320 l,,, I 300 LONGITUDE FIG. 9. Mariner 7 ultraviolet and infrared spectrometer pressures. n~ I I 280 ..... 274 CHARLES "W. HORD W I- | | I ! ! oo0% • ! I ! ' | I | | ' "l'' ! t ' | " o " " 0 W a | 5 0 "-" d.~ao . 0 6.,o5 2 I. 7 #." %" -4 IO " 'I 80 | '| I 60 I ! 40 : I 20 ' | I I 0 I I 5 40 I I 520 I 300 ! I 280 LONGLTUDE F r o . 10. M a r i n e r 6 u l t r a v i o l e t a n d i n f r a r e d s p e c t r o m e t e r p r e s s u r e s . T h e a n o m a l o u s c o m p a r i s o n o c c u r s n o r t h o f A u r o r a e S i n u s in t h e c h a o t i c region. TABLE IV MARINER 6, AURORAE SI-*;US REGION P(UVS) Lat. Long. P(IRS) Lat. Long. 4.36 4.89 5.21 5.73 6.18 6.95 8.06 7.93 1.2 --1,9 --2.9 --4.1 --4.9 --5.9 --7.4 --8.3 65.2 59.3 57.4 54.8 53.2 51.0 47.6 45.7 4.59 4.53 4.64 4,96 4.41 4.64 5.08 4.54 1.7 -1.3 --2.5 -3.6 --4.6 --5.6 --7.2 --8.0 65.2 59.6 57.3 55.0 53.0 51.0 47.3 45.6 Diflbrence --0.23 0.36 0.57 0.77 1.77 2.31 2.98 3,39 W m M A R I N E R 6 A N D 7 ULTRAVIOLET SPECTROMETER E X P E R I M E N T ~75 3~lnSS3~d it) o I I II J I I I t~ o o -o z o • .)..: o o - - (o M o .~: o •", 0 0 o o So °: - 0 0 ,; o o o o 0 0 SOfllllV7 0 0 0 LO • I ,¢ , I oJ ' ~ I 0 , I , I ,o~ I sGn1117 I v ! ~°Z 276 CHARLES W. HORD 3NI"IS S q a d o_ ~ ~d , ~ oo m Q ,, , , , '~ _o o - .% W F- °':$ -- --0 #° °*,p~ -- Z 0 U 3" 0 7 • .o 0 .o 4-. m 0 • • .. "F0 -- --~ , 0 04 0 -- 0 0 -- 0 oJ 0 ~') 3onzllv-1 0 0 I , I , I , I , I 0 I 3 a n J.lJ.-iv I , M A R I N E R 6 AND 7 ULTRAVIOLET SPECTROMETER EXPERIME~qT TABLE V is c a l c u l a t e d w i t h t h e m o d e l (Eq. 4) t o normalize the Mariner ultraviolet pressures to t h o s e o f t h e i n f r a r e d s p e c t r o m e t e r , t h e n EARTH-BASED CO2 PRESSURE Lat. Long. 1.2 -1.9 -3.7 -5.6 -7.4 -8.5 12.1 10.8 7.7 5.9 4.0 3.1 1.5 0.1 -0.5 -1.2 -13.5 -15.5 --15.1 --16.5 -17.5 --17.8 65.2 59.3 55.6 51.7 47.6 45.1 36.4 34.6 29.8 26.8 23.2 21.4 17.6 13.9 11.9 9.6 40.3 33.5 22.8 15.6 7.1 354.0 277 P(UVS) P(CO2) Difference 4.36 4.89 5.61 6.34 8.06 7.77 6.30 5.93 6.64 6.05 5.90 6.36 5.88 5.47 6.10 6.57 4.20 4.98 5.94 5.97 5.43 4.44 4.06 3.89 3.56 3.36 3.68 3.80 6.15 6.53 6.70 7.16 6.97 6.57 7.44 6.57 6.41 6.15 4.49 4.44 7.40 7.04 6.70 4.38 0.30 1.00 2.05 2.98 4.38 3.97 0.15 -0.60 0.08 -1.11 -1.07 -0.21 -1.56 1.10 0.31 0.42 -0.29 0.54 --1.46 --1.07 --1.27 0.06 the ultraviolet m e a s u r e m e n t locations was u s e d to g e n e r a t e r a d a r a l t i t u d e s , i n t h e s a m e m a n n e r u s e d for t h e c o m p a r i s o n w i t h E a r t h - b a s e d CO2 p r e s s u r e s . I t is n o t a b l e t h a t a s y s t e m a t i c difference i n t h e t w o sets of m e a s u r e m e n t s exists in the region e x t e n d i n g f r o m C h r y s e to t h e w e s t edge o f Meridiani Sinus. A systematic decrease in a l t i t u d e f r o m w e s t t o e a s t across t h i s r e g i o n is n o t a p p a r e n t i n t h e u l t r a v i o l e t m e a s u r e m e n t s , or i n e i t h e r of t h e COs pressure determinations. T h e m e a n p r e s s u r e b a s e d u p o n t h e 337 u l t r a v i o l e t m e a s u r e m e n t s is 5 . 8 m b . A m e a n v a l u e of 5 . 3 m b for t h e C02 p r e s s u r e w a s f o u n d b y H e r r et al., f r o m t h e M a r i n e r 6 and 7 infrared spectrometer data. A difference i n m e a n p r e s s u r e exists b e c a u s e o b s e r v a t i o n a l s w a t h s of t h e t w o M a r i n e r i n s t r u m e n t s were o n l y p a r t i a l l y o v e r l a p ping, even though the ultraviolet measurem e n t s were n o r m a l i z e d t o t h e i n f r a r e d spectrometer data. Belton and Hunten r e p o r t a m e a n p r e s s u r e o f 5.5 m b f r o m t h e i r E a r t h - b a s e d C02 m e a s u r e m e n t s . I f t h e M a r s g e o m e t r i c a l b e d o a t 3050 A A - p(180°) [1 - Es(27)] ÷ 2RoE2k+e(27), 8 (10) w h e r e p ( 1 8 0 °) is t h e p h a s e f u n c t i o n of 180 ° a n d E3 a n d E2k+2 are e x p o n e n t i a l i n t e g r a l s . The largest phase angle observed by M a r i n e r u l t r a v i o l e t s p e c t r o m e t e r was 134 ° so t h a t p ( 1 8 0 °) is u n k n o w n . I f p ( 1 8 0 °) ~ 1 a n d n o m i n a l v a l u e s of R 0 = 0.015, ]c ~ 1, a n d • = 0.066 ( c o r r e s p o n d i n g t o t h e a v e r a g e u l t r a v i o l e t p r e s s u r e of 5 . S m b ) are s u b s t i t u t e d i n t o E q . (10), t h e n A = 0.035. I n t h i s m o d e l , a t m o s p h e r i c s c a t t e r i n g , w h i c h is a c c o u n t e d for b y t h e first t e r m i n E q . (10), c o n t r i b u t e s 0.026 w i t h t h e r e m a i n d e r d u e t o g r o u n d r e f l e c t a n c e . T h e Caldwcll (1970) a n a l y s i s of t h e 0 A O u l t r a v i o l e t s p e c t r u m of Mars a t t r i b u t e s a sizeable p o r t i o n of t h e Mars a l b e d o t o a t m o s p h e r i c s c a t t e r i n g with the surface albedo c o n t r i b u t i o n equal to 0.7 a t 3 2 1 5 • a n d 0.5 a t 2 8 0 0 ~ . A n a l y s i s of E a r t h - b a s e d p o l a r i z a t i o n m e a s u r e m e n t s b y I n g e r s o l l (1971) also i n d i c a t e s a large atmospheric c o n t r i b u t i o n with surface TABLE VI EARTH-BASED RADAR Lat. Long. Alt. (UVS) 1.2 -0.2 -2.4 12.6 11.3 10.1 8.0 7.0 6.2 4.9 3.8 2.4 1.5 1.0 0.0 -0.7 -0.9 1.5 65.2 62.5 58.3 37.0 35.2 33.5 30.3 28.8 27.3 25.0 22.7 19.7 17.6 16.4 13.5 11.5 10.7 8.4 3.36 2.21 1.86 -0.94 -0.09 -0.27 -0.63 0.16 0.21 0.13 0.08 -0.51 0.38 0.37 0.06 -0.51 -0.38 -1.38 Alt. (Radar) Difference 2.43 2.20 1.98 3.31 2.07 1.68 1.92 1.46 1.02 0.85 0.59 -0.30 -0.68 --1.15 0.76 --0.61 --1.24 --1.2I 0.93 0.01 -0.12 -4.25 2.16 -I.95 -2.55 --1.62 -0.81 -0.72 -0.51 --0.21 1.06 1.52 0.82 0.10 0.86 0.17 27S CHARLES W. HORD 3anss3ad 0 I G If I I I I eJ ~. o ~ 0 :--" 0 ;--, w a ~ ~ Z o J • -.'.'.."(i~ .:%o ° 0 ":: e- O0 0 5 ":" :.". T # 2 .0 ~' .® ° 0 g .~ N I 0 0 0 0 0 0 3GnlllV7 0 0 ~,) o (4:) I ~ I oJ I I I o 3GAII±TV I ' I e~ ~- I 1 I MARINER 6 AND 7 ULTRAVIOLET SPECTROMETER E X P E R I M E N T a l b e d o c o n t r i b u t i n g o n l y 0.6 o f t h e t o t a l p l a n e t a r y a l b e d o a t 3 2 0 0 A . I t will b e i n t e r e s t i n g t o see i f t h i s m o d e l , w h i c h indicates that Mars has a very small g r o u n d r e f l e c t a n c e n e a r 3000 A as w e l l as a r e l a t i v e l y l a r g e a t m o s p h e r i c s i g n a l , is confirmed by the Mariner 9 Mars orbiter. ACKNOWLEDGMENTS I wish to thank Dr. C. A. Barth for his vahmble criticism of this work and, of course, his ultraviolet spectrometer data which makes this analysis possible. I wotfld also like to thank Drs. Herr, Pimentel, Horn, Bclton, and Htmten for the early availability of their data and valuable discussions. Karen Simmons and Lois ParmMec made valuable contributions in the preparation of the data. 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