2 Saturn upper atmospheric structure from Cassini EUV/FUV occultations 3 D. E. Shemansky 4 1 5 and X. Liu 6 1 7 Planetary and Space Science Div., Space Environment Technologies, Pasadena, CA, USA 8 dshemansky@spacenvironment.net 1 9 Received ; accepted –2– 10 11 ABSTRACT The Cassini UVIS experiment provides data on Saturn atmospheric physical properties through solar and stellar occultations. Transmission spectra in the EUV/FUV range allow extraction of vertical profiles of H2 and hydrocarbon abundances from the top of the atmosphere to about 300 km above the 1 bar pressure level. The stellar occultation (δOri egress, 2005 DOY 103) has allowed the most accurate data reduction from 300 km above the 1 bar level through the exobase for latitude -42.7◦ in the sunlit atmosphere. The hydrocarbon homopause is near the mesopause at 560 km ( 1. µb), based on measurements of CH4 , C2 H2 , C2 H4 . Other stellar occultations although not completely reduced, provide critical measurements of the latitudinal dependence of vertical atmospheric structure. Analysis of a stellar occultation at latitude 15.2◦ shows vertical abundance displacements of 100 – 200 km above the measurements at −42.7◦ , and a significantly different temperature profile. This work constrains the volumetric He/H2 ratio to 0.12, the low end of the range of values derived by Conrath & Gautier. The derived temperature profile below 700 km is sensitive to the He/H2 mixing ratio, moderately affecting the extracted hydrocarbon densities. The thermospheric temperatures derived from the H2 vertical profile are based on the assumption of a hydrostatic distribution. This assumption introduces inaccuracy in the high thermosphere because of a substantial rate of conversion of H2 to atomic hydrogen. Details of the atomic hydrogen vertical structure have not been extracted in the current work. The Voyager 2 stellar occultation at 3.8◦ latitude has been reanalyzed using a current H2 physical model in a photometric analysis, and shows vertical displacements similar to the UVIS results at 15.2◦ . Preliminary analysis of latitude dependence indicates the presence of significant differences in CH4 vertical structure. Model calculations indicate that the latitudinal depen- –3– dence of H2 vertical displacements is caused primarily by the combined effects of gravitation and temperature profile. 12 Subject headings: Outer planets: general — thermosphere: individual(vertical 13 structure –4– 14 15 1. Introduction Results from the Cassini UVIS experiment occultation probes of the vertical structure 16 of the Saturn atmosphere are described in this work. The analysis of stellar occultations 17 are targeted in this preliminary analysis. Solar occultations have also been obtained but 18 data reductions are not available at this time. The highest quality transmission data has 19 been obtained from the occultation of Delta Orionis (δOri) obtained on 2005 DOY 103 at 20 latitude −42.7◦ . The analysis of this occultation is described in detail in this paper. Figure 21 1 shows a plot of latitude location and statistical quality of 14 stellar occultations examined 22 in varying degrees of detail in the present work. The spectral resolution of the UVIS 23 spectrographs is high enough to allow the analysis of H2 discrete absorption in rotational 24 structure, and for the first time kinetic temperatures are constrained by measurement of 25 rotational temperature over a range of altitudes, as well as through modeling of the vertical 26 abundance profile. The vibrational populations of the H2 X state are also constrained by 27 a non-LTE approach to the data reduction, although the heavy spectral overlap of the 28 vibrational vectors does not allow a strong constraint. Figure 1 indicates that the δOri 29 occultation has a far higher quality than any of the other 13 events. The horizontal line in 30 Figure 1 partitions the occultations into spectrally analyzable events as opposed to those 31 limited to photometric analysis. The present work also benefits from the application of a 32 highly accurate H2 model structure that has been developed over several years in the recent 33 past (see Glass-Maujean et al. 2009, and references therein). 34 Simultaneously with the H2 spectral transmission spectra obtained with one of 35 the UVIS spectrographs, hydrocarbon absorption spectra are obtained with a second 36 spectrograph. The vertical structure of CH4 , C2 H2 , and C2 H4 has been extracted through 37 spectral analysis of the δOri occultation. Research on the temperature sensitivity of C2 H2 38 has been utilized here to constrain the kinetic temperature in the vicinity of the mesopause –5– 39 at −42.7◦ latitude. This temperature constraint then imposes a limit on the He/H2 mixing 40 ratio in the hydrostatic atmospheric modeling process. 41 2. 42 The Cassini UVIS experiment The Cassini UVIS (Ultraviolet Imaging Spectrograph) experiment is fully described by 43 Esposito et al. (2004). The observations utilized in the work referenced here are obtained 44 using the EUV and FUV spectrograph units identified as Channels (Esposito et al. 2004). 45 The EUV and FUV Channels in a single exposure produce 64 spectral vectors of maximum 46 length 1024 pixels (pxs). The sky projection of spatial pixel size is (pxs X pxw) = (0.25 47 X 1.0) mr, spectral pixel size is pxs = 0.6096524 Å (EUV) and pxs = 0.779589 Å (FUV). 48 The spectral range of the UVIS is 563. – 1182 Å (EUV) and 1115. - 1912. Å (FUV). The 49 airglow ports of these instruments are used in stellar occultation observations in addition to 50 spatially extended airglow measurements. Unlike the Voyager UVS experiment, the UVIS 51 contains a solar occultation port only in the EUV Channel. UVIS solar occultations cannot 52 provide information on the hydrocarbon structure because spectral signal in the EUV is in 53 complete H2 extinction before the altitude region where measurable hydrocarbon absorption 54 is reached. The FUV spectral region shows no measurable H2 discrete absorption, allowing 55 unobstructed measurement of hydrocarbon extinction. 56 57 3. Stellar Occultations The δOri occultation, which provides the most accurate available data, has been 58 analyzed spectrally in detail. The ζOri occultation on 2006 DOY 141 has been reduced 59 spectrally for H2 . The H2 vertical profile for both δOri and ζOri has been modeled to 60 obtain a first measure of latitude dependence of the vertical abundance and temperature –6– 61 profiles above 600 km. The remaining stellar occultations indicated in Figure 1 have been 62 reduced photometrically to provide preliminary data on latitudinal dependence of vertical 63 structure. The spectral analysis of the δOri event provides data on H2 , CH4 , C2 H2 , and 64 C2 H4 , but photometric analysis is restricted to H2 and CH4 . Instrument pointing for the 65 events shown in Figure 1 was stabilized by the spacecraft reaction wheels, and in each 66 case the star image motion was constrained to less than a spectral pixel width. The 67 latitude of the δOri egress occultation varied moderately on the sunlit side of the southern 68 hemisphere, but the critical region of the occultation was located at −42.7◦ . Measurements 69 of H2 atmospheric absorption were possible over the altitude range of 719 km to 1577 70 km above the nominal 1 bar level as determined by the Cassini navigation package. The 71 analysis of H2 absorption at altitudes greater than 1600 km is limited by signal noise. 72 Below 670 km, CH4 begins to contribute to the stellar absorption. The spectra are forward 73 synthesized using a rotational-level H2 absorption model (see Section 3.1) to produce the H2 74 line-of-sight abundance and temperature profiles. The data profiles constrain the derivation 75 of the density profile through application of a hydrostatic model. The hydrocarbon vertical 76 profiles obtained from the FUV channel measurements are spectrally analyzed using the 77 most recent temperature dependent cross sections. These reduction processes are necessarily 78 iterative. 79 The occultations in the EUV/FUV photon spectrum provide measurements of 80 atmospheric structure and composition from the exobase to 300 km altitude above the 1 bar 81 pressure level. The Cassini UVIS experiment provides the most accurate platform to date 82 in EUV/FUV transmission, for extracting atmospheric structure in outer planet research 83 primarily through higher spectral resolution, signal rates, and dynamic range. –7– 84 85 3.1. Vertical profile of H2 and hydrocarbons The H2 component is obtained in the EUV Channel. An example of the transmission 86 spectrum is shown in Figure 2. The analysis of the transmission spectra is carried out 87 through forward modeling, simulating the instrument response in detail. This process 88 is required in order to account for the finite point spread function (psf) of the UVIS 89 spectrographs. The transmission spectrum of a model atmosphere using a modeled stellar 90 source spectrum is applied iteratively in simulated instrument output to obtain an optimal 91 fit to the observations. The EUV spectral resolution in the core of the psf is δλ = 0.9 92 Å FWHM. The EUV transmission spectrum at Saturn is uncontaminated hydrogen over 93 the entire altitude range to the point of complete extinction (optical depths τ = 6 - 7). 94 The H2 model used in the analysis was developed over the past several years successively 95 at the University of Southern California (USC) and Space Environment Technologies 96 (SET)(Shemansky et al. 2009; Hallett et al. 2005a,b). The temperature dependent 97 absorption cross section spectra for the analysis are calculated at a resolution 98 to an accuracy of ∼ 5% for those transitions that contribute measurably to the absorption 99 spectrum. The transmission spectra are fitted using separate vibrational vectors of the λ δλ ∼ 500000 100 ground state H2 X(v:J) structure. Details of H2 physical properties are described by Hallett 101 et al. (2005a,b) for the non-LTE environment that develops in the excited atmosphere. 102 The fundamental physical quantities (coupled state structure, absorption probabilities, 103 predissociation probabilities) used in these calculations are referenced by Shemansky et al. 104 (2009); Hallett et al. (2005a,b); Glass-Maujean et al. (2009). The calculation methodology 105 assumes that rotational structure is in thermal equilibrium at the gas kinetic temperature, 106 but vibrational population is non-LTE (Hallett et al. 2005a). Detailed model calculations 107 (Shemansky et al. 2009; Hallett et al. 2005a) show that in actuality there is some deviation 108 from thermal populations in rotation, but evidently not enough to significantly affect the 109 absorption spectral properties. H2 X vibrational populations, however, deviate significantly –8– 110 from thermal and critically affect the state of the ionospheric plasma (Shemansky et 111 al. 2009; Hallett et al. 2005a,b). It has been found that the spectral fitting process is 112 more sensitive to rotational temperature than vibrational population distribution. In the 113 Cassini UVIS observations, therefore, the atmospheric temperature is derived through both 114 iterative determination of rotational temperature, and the shape of the vertical abundance 115 distribution in the hydrostatic model calculations (Shemansky et al. 2005). At lower 116 altitudes the kinetic temperature is also constrained by the measurements of the absorption 117 structure of the C2 H2 diffuse temperature sensitive (C̃ – X̃) bands (Wu et al. 2001). 118 Figure 2 shows the observed extinction spectrum at impact parameter 929 km against 119 the modeled non-LTE calculation. Derived rotational temperature and H2 abundance are 120 given in the figure. The 2005 DOY 103 occultation was a dayside observation at solar 121 phase ∼38◦ , with subsolar latitude −18.1◦ . Figure 3 shows the forward modeled hydrostatic 122 density distribution anchored at the 1 bar level to 400 km using the Lindal, et al. (1985) 123 results. The Voyager 2 (V2) UVS stellar occultation has been reanalyzed using the current 124 H2 model structure, and the resulting vertical H2 profile is also shown in Figure 3. The V2 125 occultation was on the darkside (Smith et al. 1983) at a latitude of 3.8◦ . The differences 126 in density at a given altitude (above the nominal 1 bar level) evident in the figure are 127 the combined consequence of the gravitation scale at the different latitudes of the two 128 occultations and different temperature profiles. Figure 3 also shows the modeled Helium 129 distribution anchored at a [He]/[H2 ] = 0.12 mixing ratio at 1 bar (Shemansky & Liu 2008). 130 The [He]/[H2 ] mixing ratio affects the modeled temperature structure in the vicinity of the 131 mesopause, and the applied ratio is limited by the temperature dependence of the C2 H2 (C̃ 132 – X̃) band cross section. In the upper thermosphere, density differences are extended by 133 the fact that the top of thermosphere temperatures at V2 and Cassini differ by more than 134 100K. The vertical partial pressure profiles from Voyager UVS and Cassini UVIS compared 135 to the total pressure derived from CIRS at latitude -20◦ (Fletcher et al. 2007) are shown in –9– 136 Figure 4. The vertical temperature profile is discussed in Section 3.4. 137 The analysis of the UVIS FUV spectrograph stellar occultation data yields the 138 hydrocarbon densities shown in Figure 3. Although there is an indication of the presence 139 of other species in the transmission spectra, the species for which vertical distributions are 140 obtained, CH4 , C2 H2 , and C2 H4 , are shown in Figure 3. The evidence for other species will 141 be discussed in later work. The only species profile that can be reliably extracted from the 142 V2 stellar occultation is CH4 (see Figure 3). The hydrocarbon homopause is just above 143 600 km in the UVIS occultation and at ∼ 900 km in the V2 occultation. A similar large 144 difference in homopause altitude is obtained in the UVIS ζOri occultation on 2006 DOY 145 141 at latitude 15.2◦ . The 1 bar radius in the Smith et al. (1983) work is consistent with 146 the Cassini results (Section 3.3). The vertical displacement of the hydrocarbon homopause 147 levels in the two cases is consistent with the vertical displacement of the H2 densities (see 148 Figure 3). The CH4 distributions are anchored at the 1 bar level with the value ([CH4 ]/[H2 ] 149 = 5.1 × 10−3 ) established by Flasar et al. (2005). Figure 5 shows the reduced abundance 150 data values for H2 and the hydrocarbons from the δOri occultation, compared to the model 151 calculations that allow the determination of the density profiles. 152 3.2. The impact of helium on the atmospheric model 153 Establishing an atmospheric model at Saturn starting at 1 bar requires the inclusion 154 of helium because of the significant impact on the mean mass of the fully mixed gas. At 155 this time the [He]/[H2 ] ratio is not definitively established. Lindal, et al. (1985) in the 156 analysis of Voyager radio experiment (RSS) occultations, used the mixing ratio established 157 by Conrath et al. (1984), [He]/[H2 ] = 0.034. Conrath et al. (1984) obtained [He]/[H2 ] 158 by analyzing the RSS occultation results and infrared thermal emission. Sixteen years 159 later, following the Galileo probe results at Jupiter, Conrath & Gautier (2000) found a – 10 – 160 systematic divergence from their approach and on reanalysis obtained [He]/[H2 ] = 0.11 161 – .16. The most direct determination would be obtained by utilizing a measured scale 162 height, and an independent measurement of temperature to establish the mean mass of the 163 gas. The UVIS occultation measurements provide the scale height structure in H2 with an 164 independent rotational temperature measurement, but the current data reduction reaches 165 only down to 700 km above 1 bar. The hydrocarbon data are analyzed down to 300 km, 166 and therefore overlap the RSS and CIRS experiment results (Figures 3, 6). The absorption 167 spectrum of C2 H2 contains the strong temperature dependent (C̃ – X̃) bands showing peaks 168 at 1477.91 Å (C̃ 1 Πu (0,1,0,0,0) – X̃ 1 Σg (0,0,0,0,0)) and 1519.43 Å (C̃ 1 Πu (0,0,0,0,0) – X̃ 169 1 Σg (0,0,0,0,0)) (see Figure 7). Figure 8 shows part of the C2 H2 absorption cross section 170 temperature dependence projected from the Wu et al. (2001) measurements. The upper 171 state is heavily coupled and the diffuse rotational structure is naturally blended in Figure 172 8. The width and magnitudes of the band heads change with temperature, and the blended 173 diffuse p-branch lines in the 1485 Å – 1510 Å region are also temperature dependent. Figure 174 7 shows the observed transmission spectrum at 583 km, compared to a simulation of the 175 instrument response to transmission through the modeled atmosphere at T = 120 K. The 176 model calculation shown in Figures 3 and 6 are based on [He]/[H2 ] = 0.12 at 1 bar. The 177 temperature profile shown in Figure 6 is forced by continuity with the H2 density and scale 178 height at 700 km with the RSS and CIRS profiles from 1 bar up to 300 km. The result 179 shows a distinct mesopause at 550 km. Fitting the reanalyzed Voyager results, also shown 180 in Figures 3 and 6, with the same [He]/[H2 ] constraint produces a different temperature 181 profile without a distinctly defined mesopause, very similar in shape to the Hubbard, et al. 182 (1997) profile between 300 km and 800 km, also shown in Figure 6. Other models with 183 lower values of [He]/[H2 ] can satisfy the observational constaints, but higher ratios force the 184 mesopause temperature too high for compatibility with the C2 H2 absorption spectrum and 185 continuity with the observed structure at 700 km for the profile in the δOri occultation. – 11 – 186 This analysis includes the basic assumption the vertical period in density and temperature 187 variance is limited to 1 or more atmospheric scale heights. At this time a lower limit on 188 the [He]/[H2 ] value has not been explored. A projection of the C2 H2 cross section has not 189 been obtained for temperatures below those shown in Figure 8, and a spectrum of C2 H2 190 dimer or the solid state is not available to establish a limit to the C̃ – X̃ low temperature 191 behavior. The modeled [He]/[H2 ] in Figure 3 remains fully mixed to the mesopause. The 192 calculation of diffusivity at that altitude using the Lennard-Jones potentials for He–He and 193 H2 –H2 , indicate a value of DHe,H2 (555km) = 1.6 × 104 cm2 s−1 . Diffusive separation for He 194 in the upper thermosphere is crudely estimated and will be refined in following work. 195 196 3.3. Latitudinal dependencies Figure 3 comparing derived densities for the UVIS δOri occultation at latitude −42.7◦ 197 and the Voyager UVS occultation at 3.8◦ shows vertical separations of equal densities of 198 ∼200 km, and ∼350 km for CH4 . The H2 vertical profile model calculations for these 199 two cases, starting with the same conditions at 1 bar, indicate that the difference is the 200 combined effect of latitude dependent temperature and gravitation. The assumption in 201 this case is that the 1 bar level is adequately determined by the ellipsoid installed in the 202 Cassini navigation package. The equatorial bulge is not included in these considerations. 203 Within the UVIS occultation events, a comparision of the optical depth spectrum of δOri 204 at −42.7◦ with the ζOri spectrum of nearly equal magnitude at 15.2◦ in Figure 9 shows a 205 vertical separation of ∼250 km. Figure 10 shows the abundance profiles of the δOri and 206 ζOri occultations compared to the current derivation from the Voyager δSco occultaion. 207 Data points with model calculations are shown in Figure 10, with error bars included on 208 the ζOri abundance values, which are less accurate than the δOri result (see Figure 1). 209 Both abundance profiles in Figure 10 show distinct changes in the log scale slope, at ∼900 – 12 – 210 km for δOri and at ∼1250 km for ζOri, signaling the impact of rising upper thermospheric 211 temperatures. There are also distinct differences in abundance distribution above the slope 212 transitions in the two occultations, with a curvature in the δOri data to smaller scale height 213 toward higher altitudes forcing a peak in temperature (Figure 6), and a significantly larger 214 scale height developing in the ζOri data above 1250 km. The ζOri abundance profile in 215 Figure 10 is close to linear on a log scale in the 700 km – 1200 km region, forcing the 216 temperature profile in this region to near constancy in the modeling process (Section 3.4). 217 As discussed in Section 4, the temperatures forced by the abundance profiles in the high 218 thermosphere are based on hydrostatic modeling, and the deviation caused by the loss of H2 219 through dissociation is not considered at this time. The Figure 11 shows vertical separations 220 of 200 – 300 km in CH4 abundance for the δOri and ζOri occultations. The latitudinal 221 effects internal to the UVIS occultations are therefore apparently similar to the comparison 222 with the Voyager UVS outcome. Figure 12 shows a plot of the impact parameter above 223 the assumed 1 bar oblate radius of transmission extinction for H2 and CH4 in the data 224 set examined here, as well as the Voyager UVS event, as a function of latitude. With the 225 exception of Voyager UVS, the CH4 extinction altitude falls below the H2 locations, but the 226 two species show a similar general trend. 227 228 3.4. Vertical kinetic temperature profiles The derived temperature profiles from UVIS 2005 DOY 103, V2 1981 DOY 238, the 229 Hubbard, et al. (1997) multiple Earth based stellar occultations, and the CIRS profile 230 at latitude −40◦ (Fletcher et al. 2007) are shown in Figure 6. The UVIS result at lat 231 −42.7◦ shows a distinct mesopause at 545 km at a temperature of 121 K. The mesopause 232 temperature is limited by the measured structure of the C2 H2 (C̃ – X̃) bands. The 233 uncertainty in temperature above 300 km is estimated to be ± 10 K for the UVIS result. – 13 – 234 The hydrostatic model calculation of the structure confined by the measured H2 profile at 235 higher altitudes, and the radio occultation results at altitudes below 400 km, is dependent 236 on the [He]/[H2 ] mixing ratio. In the region up to 1450 km in the δOri occultation the 237 temperature is also limited by the rotational temperature in the model analysis. The 238 two constraints, rotational structure and vertical profile are in good agreement, but a 239 more thorough analysis with a broader range of rotational temperature vectors needs to 240 be carried out to set definitive limits on the temperature uncertainty using the combined 241 methodologies. The UVIS δOri occultation analysis is the only existing derivation from 242 the sunlit atmosphere. The T∞ = 460 K thermosphere obtained from the 1981 occultation 243 in the present analysis is 40 K higher than the original analysis by Smith et al. (1983), 244 which is presumed to be caused mainly by the use of a much more accurate H2 model 245 in the present case. The temperature profiles derived from the spacecraft data using the 246 present H2 physical model are shown in Figure 13. It is evident that substantial differences 247 arise as an apparent function of latitude. The Voyager δSco profile (latitude 3.8◦ ) is much 248 more similar to the UVIS result for ζOri (latitude 15.2◦ ), than to the UVIS result at δOri 249 (latitude −42.7◦ ). The value of T∞ = 460 K from the Voyager δSco occultation is within 250 error estimates of the value, 407 K, from the derived result at UVIS ζOri, and both are 251 ∼100 K higher than from UVIS δOri at T∞ = 320 K. 252 253 4. Discussion and conclusions The Cassini UVIS occultation measurements reveal a significant dependence of 254 atmospheric vertical structure on latitude extending to the top of the thermosphere. 255 Although data analysis is not complete, selected occultations at latitudes −42.7◦ and 256 15.2◦ indicate significant differences in abundance and temperature vertical profiles. A 257 reanalysis in which the Voyager results were established on the same model basis as those – 14 – 258 of Cassini UVIS has verified the original work, and shows similarity to the low latitude 259 UVIS ζOri 15.2◦ occultation in derived H2 abundance and temperature (Figures 10 and 260 13). The Cassini UVIS temperature profile at latitude −42.7◦ shows two distinctive 261 properties: 1) A distinctive mesosphere with a temperature near 120 K (Figure 6), 2) An 262 apparent temperature peak near 1200 km at latitude −42.7◦ that may indicate localized 263 heat deposition in the sunlit atmosphere over a range of 1 to 2 scale heights. This feature, 264 however, does not have a clear explanation because of the fact that the model calculation is 265 hydrostatic. It is known that the upper thermosphere is subject to a substantial conversion 266 of H2 to the atomic state (Shemansky & Liu 2008). The temperature derived in the 267 hydrostatic calculation is therefore affected by the loss of H2 in the upper thermosphere and 268 on this basis may be too low by some uncertain factor. All of the hydrostatic models will 269 be affected by this process in the high thermosphere region. The reanalysis of the Voyager 270 results and the UVIS ζOri data at low latitude show a much less distinctive mesosphere 271 (Figures 6 and 13) similar to that derived by Hubbard, et al. (1997) (Figure 6). The 272 strong differences in the temperature vertical profiles at high and low latitudes indicate 273 that latitudinal mixing is a weak process at Saturn. The distributions shown in Figure 13 274 suggest that hydrocarbon radiative cooling at high latitude is vertically much more confined 275 than at low latitude. The profile at latitude −42.7◦ shows a distinct cold mesosphere at 545 276 km, while the low latitude profiles show broad vertical ranges extending over several scale 277 heights that are low temperature and nearly isothermal suggesting extensive vertical mixing 278 of the hydrocarbons. The vertical profiles of the higher order hydrocarbons at low latitude 279 have not been established. The UVIS ζOri occultation contains sufficient data quality to 280 allow determination of C2 H2 and C2 H4 vertical profiles, potentially allowing assessment of 281 the apparent vertical extent of the cooling process. The higher T∞ values at low latitude 282 may be related to the apparent concentration of heating by the dissociation of H2 at low 283 latitudes (Shemansky & Liu 2008). – 15 – 284 The vertical profiles of CH4 , C2 H2 , and C2 H4 have been obtained at latitude −42.7◦ . 285 Peak densities C2 H2 and C2 H4 are indicated at 400 km and 600 km, inferring that the main 286 region of production of higher order hydrocarbons is just above 600 km at −42.7◦ . The 287 equivalent region at low latitude is approximately 300 km higher, using the nominal 1 bar 288 oblate shape function. 289 Using the temperature dependence of the C2 H2 absorption cross section to limit the 290 temperature near the mesopause at latitude −42.7◦ , an upper limit of the He/H2 mixing 291 ratio has been determined at [He]/[H2 ] = 0.12 at 1 bar. This falls in the mid range of the 292 Conrath & Gautier (2000) estimate. – 16 – 293 REFERENCES 294 Conrath, B. J., D. Gautier, R. A. Hanel, & J. S. 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This manuscript was prepared with the AAS LATEX macros v5.2. – 18 – Data statistical quality Saturn UVIS star occultations to date 12 11 10 9 8 7 6 5 4 3 2 1 0 signal rate quality photometric cutoff -40 -20 -0 Latitude 20 40 Fig. 1.— UVIS star occultation statistical quality for reduced data presented in the current work, as a function of latitude. The main target of the present work is δOri at latitude −42.7◦ showing a quality value of 12 on the plot. The horizontal line marks the level below which data must be analyzed photometrically in order to obtain satisfactory signal levels. – 19 – 1.2 1.0 Alt: 929 km T = 240 K; C (H2) = 1.3x1020 cm-2 Vib. Distribution: F13 I/I0 0.8 0.6 0.4 0.2 0.0 900 950 1000 1050 1100 1150 λ (A) Fig. 2.— UVIS EUV stellar occultation transmission spectrum obtained 2005 DOY 103 at effective impact parameter 929 km. The rotational temperature is iteratively determined assuming LTE. The vibrational population distribution is non-LTE determined iteratively by fitting separate vibrational vectors into the model for optimal match to the spectrum. – 20 – 2000 H2 UVIS lat -40o He UVIS Lat -40o CH4 UVIS Lat -40o C2H2 UVIS Lat -40o C2H4 UVIS Lat -40o H2 V2 UVS Lat 3.8o He V2 UVS Lat 3.8o CH4 V2 UVS Lat 3.8o [N] CIRS Lat -40o 1800 1600 h (km) 1400 1200 1000 800 600 400 V2 UVS 1981 DOY 238 δδ-Sco Lat 3.8o 200 UVIS 2005 DOY 103 εε-Ori Lat -40o ε 0 0 2 4 6 8 10 12 14 16 18 20 -3 Log{[N] (cm )} Fig. 3.— Derived densities of H2 , He, CH4 , C2 H2 , and C2 H4 from UVIS 2005 DOY 103 (Lat −40◦ ) and H2 , He, CH4 from the V2 Voyager 1981 DOY 237 (Lat 3.8◦ ) events. The CIRS results giving total density at latitude −40◦ (Fletcher et al. 2007) are included. The Voyager results are green in the plot with superposed light green points indicating the range of the measured data. The UVIS results are blue with superposed cyan points showing the range of measured data. – 21 – CH4 UVIS Lat -40o H2 UVIS Lat -40o H2 V2 UVS Lat 3.4o CH4 V2 UVS Lat 3.8o C2H2 UVIS Lat -40o C2H4 UVIS Lat -40o He V2 UVS Lat 3.8o He UVIS Lat -40o CIRS_Fletcher 2007 2000 1800 1600 h (km) 1400 1200 1000 CIRS P total Lat -40o 800 600 400 200 0 V2 UVS 1981 DOY 238 δδ-Sco Lat 3.8o UVIS 2005 DOY 103 εε-Ori Lat -40o ε 10-11 10-10 10-9 10-8 10-7 10-6 10-5 10-4 10-3 10-2 10-1 100 101 102 103 P (mb) Fig. 4.— The equivalent of Figure 3 on a pressure scale. The CIRS results giving total pressure at latitude -40◦ (Fletcher et al. 2007) are included. – 22 – H2 08_13 model H2 Saturn rev6 data CH4 08_13 model CH4 Saturn rev6 data C2H2 08_13 model C2H2 Saturn rev6 data C2H4 08_13 model C2H4 Saturn rev6 data 2000 1800 1600 h (km) 1400 1200 1000 800 600 400 200 0 0 10 20 30 log([N] cm-2) Fig. 5.— Extracted abundances of H2 , CH4 , C2 H2 , and C2 H4 from the UVIS δOri occultation on 2005 DOY 103 with model fits plotted through the data. – 23 – V2_lat4_00_reanal Cassini UVIS_rev6 _08_13_1 Hubbard et al. 1997 CIRS Fletcher 2007 2000 1800 V2 UVS 1981 DOY 238 δδ-Sco Lat 3.8o 1600 UVIS 2005 DOY 103 εε-Ori Lat -40o ε Hubbard et al. (1997) Earth based stellar: equator model h (km) 1400 1200 1000 800 600 400 Fletcher et al.(2007) CIRS Lat -40o 200 0 0 100 200 T (K) 300 400 500 Fig. 6.— Saturn temperature profiles derived from the UVIS (δOri), V2, Hubbard, et al. (1997), occultations, and the Cassini CIRS result (Fletcher et al. 2007) at latitude -40◦ . – 24 – 0 -1 UVIS FUV 2005 DOY 103 583 km model _042e_02 -2 -ττ -3 -4 -5 -6 -7 1300 1400 1500 1600 1700 1800 1900 λ (A) Fig. 7.— Cassini UVIS FUV stellar occultation optical depth spectrum against a model fit containing CH4 , C2 H2 , C2 H4 , and upper limits to C2 H6 and several other species. The temperature of the diffuse C2 H2 (C̃ – X̃) band cross section in this calculation is empirically determined at 120 K. Weak contributions from dayside airglow appear in the short wavelength deep optical depth region of the spectrum, and in the 1500 - 1600 Å region. The effective impact parameter of this spectrum is 583 km. – 25 – 100 90 c2h2_295K_wu_Mb c2h2_150K_Wu_Mb xsec_T150_148_sim xsec_T295_148_sim xsec_T195_148_sim xsec_T120_148_sim xsec_T110_148_sim C Π Πu (0,1,0,0,0) -- X Σg (0,0,0,0,0) 80 1 1 λ00 = 1477.91 Å 70 σ (Mb) 60 50 40 30 20 10 0 1460 1470 1480 1490 1500 1510 λ (A) Fig. 8.— Projected photoabsorption cross section (Mb) of the C2 H2 C̃ 1 Πu (0,1,0,0,0) – X̃ 1 Σg (0,0,0,0,0) band for selected temperatures. The measured cross sections from Wu et al. (2001) are shown against the model fits. – 26 – 0 -1 -ττ -2 ζOri egr rec 073 δOri egr rec 045 -3 -4 ζOri = 997.77 km δOri= 722.1 km -5 -6 950 970 990 1010 1030 1050 1070 1090 1110 1130 1150 λ (A) Fig. 9.— Comparison of optical depth spectra from the UVIS EUV experiment at the δOri (lat −42.7◦ ) and ζOri (lat 15.2◦ ) occultations selected for equality in optical depth. The ζOri spectrum was obtained at impact parameter 997.8 km and the δOri spectrum was obtained at 722.1 km, above the nominal 1 bar pressure level. – 27 – 2000 H2 _06_141 lat 15.2o H2 _05_103 lat -42.7o model lat -42.7o model lat 15.2o H2 V2 81_237 model lat 3.8o 1800 h (km) 1600 1400 1200 1000 800 600 17 18 19 20 21 22 23 24 Log([H2] (cm-2)) Fig. 10.— Derived and modeled abundance of H2 from the stellar occultations using the Cassini UVIS experiment at δOri (lat −42.7◦ , 2005 DOY 103 ) and ζOri (lat 15.2◦ ,2006 DOY 141) and from the Voyager experiment at δSco (lat 3.8◦ , 1981 DOY 237). – 28 – 1000 CH4 ζOri _06_141 lat 15.2o CH4 δOri _05_103 lat -42.7o 900 h (km) 800 700 600 500 400 15 16 17 18 19 20 21 22 Log([CH4] (cm-2)) Fig. 11.— Extracted abundances from the UVIS FUV experiment at the δOri (lat −42.7◦ ) and ζOri (lat 15.2◦ ) occultations, as a function of altitude above the nominal 1 bar pressure level. kc_i_07-002 800 700 600 500 do_e_05-103 h (km) 900 -40 -20 -0 Lat 20 eo_i_06-079 UVIS H2 2005 -- 2007 V2 H2, CH4 1981 UVIS CH4 2005 --2007 zo_e_06-141 zo_e_07-202 eo_e_06-141 zo_e_06-079 eo_i_06-141 eo_e_07-202 do_i_07-202 eo_e_06-079 eo_e_06-118 do_e_07-202 1000 dsc_e_81-237 – 29 – 40 Fig. 12.— Extinction (τ = 6) impact parameters above the nominal 1 bar pressure level for H2 and CH4 for 12 UVIS stellar occultations as a function of latitude. – 30 – 500 T δOri 05_103 lat -42.7o T δSco 81_237 lat 3.8o T ζOri 06_141 lat 15.2o 400 Tg (K) 300 200 100 0 0 200 400 600 800 1000 1200 1400 1600 1800 2000 h (km) Fig. 13.— Derived vertical temperature profiles at Saturn from the Cassini UVIS occultations of δOri (lat −42.7◦ , 05 DOY 103 ) and ζOri (lat 15.2◦ , 06 DOY 141) and from the Voyager experiment at δSco (lat 3.8◦ , 81 DOY 237). These results are obtained using a common H2 physical model.