Far Ultraviolet Spectral Properties of Saturn's Rings from Cassini UVIS E. Todd Bradleya, Joshua E. Colwella, Larry W. Espositob, Jeffrey N. Cuzzic, Heather Tollerudd, Lindsey Chamberse a Department of Physics, University of Central Florida, Orlando, FL, 32816-2385, USA b LASP, University of Colorado, 392 UCB, Boulder, CO 80309-0392, USA c Space Science Division, NASA Ames Research Center, Mail Stop 24503, Moffett Field, CA, 94035, USA d Department of Geosciences, Pennsylvania State University, University Park, PA 16802, USA e Department of Earth and Planetary Sciences, University of California - Santa Cruz, 1156 High St, Santa Cruz, CA, 95064, USA This paper is dedicated to the memory of Michel Festou whose many contributions to the UVIS investigation included conceiving of the path length analysis presented here. Submitted to Icarus June 9, 2009 Suggested Running Head: Ultraviolet Spectrum of Saturn’s Rings Address Editorial Correspondence to: Todd Bradley, Department of Physics, University of Central Florida, Orlando, FL, 32816-2385, USA tbradley@physics.ucf.edu 2 Abstract Spectra taken by the Cassini Ultraviolet Imaging Spectrograph (UVIS) of Saturn’s C ring, B ring, Cassini Division, and A ring have been analyzed in order to characterize ring particle surface properties, and water ice abundance in the rings. UVIS spectra sense the outer few microns of the ring particles. Spectra of the normalized reflectance (I/F) in all four regions show a characteristic water ice absorption feature near 165 nm. Our analysis shows that the fractional abundance of surface water ice is largest in the outer B ring and decreases by over a factor of 2 across the inner C ring. We calculate the mean path length of UV photons through icy ring particle regolith and the scattering asymmetry parameter using a Hapke reflectance model and a Shkuratov reflectance model to match the location of the water ice absorption edge in the data. Both models give similar retrieved values of the photon mean, however the retrieved asymmetry (g values) are different. The photon mean path lengths are nearly uniform across the B and A rings. Shortward of 165 nm the rings exhibit a slope that turns up towards shorter wavelengths, while the UV slope of 180/150 nm (reflectance outside the water absorption ratioed to that inside the absorption band) tracks I/F with maxima in the outer B ring and in the central A ring. Retrieved values of the scattering asymmetry parameter show the regolith grains to be highly backscattering in the FUV spectral regime. 3 1. Introduction Saturn’s rings are known to be composed mostly of water ice (Cuzzi et al. 1984, Esposito et al. 1984). However, a decrease in reflectivity shortward of 600 nm, which gives the rings their characteristic color, implies the presence of a non-icy constituent (Lebofsky et al. 1970, Estrada and Cuzzi 1996, Cuzzi and Estrada 1998). Microwave observations of the rings have constrained estimates of the fractional abundance of water ice in the rings to be greater than 90% (Epstein et al. 1984). The remaining fraction is a contaminant that is primordial and/or due to meteoroid bombardment (Cuzzi and Estrada 1998). Water ice contains a distinctive absorption feature near 165 nm that was first observed in Saturn’s rings in 12 IUE observations from 1982 to 1985 (Wagener and Caldwell 1988). Near-infrared spectra taken with the Cassini Visual and Infrared Mapping Spectrometer (VIMS) have also shown the main rings to be composed mostly of water ice, with a decrease in reflectance at wavelengths below 600 nm suggesting an organic contaminant (Nicholson et al. 2008). While typical ring particle sizes have been shown to range in size from centimeters to several meters (e.g. Zebker et al. 1985), ultraviolet reflectance spectra contain information concerning the micro-structural surface properties of the particles themselves. The analysis in this paper assumes the rings to be composed of large (> 1 cm) particles, each of which is covered with a regolith of ice grains. Following the assumptions by Cuzzi and Estrada (1998), this analysis assumes that each regolith grain has its own single scattering albedo and that multiple scattering occurs from one regolith grain to another. The wavelength of the water ice absorption feature is governed by the distance photons travel through water ice and the absorption properties of the regolith ice grain. 4 The more ice that photons traverse, the more absorption there is in the water ice, and this causes greater absorption at longer wavelengths, increasing the wavelength of the absorption edge (Hendrix and Hansen 2008). Physical properties of ring particles that could affect the mean photon path length include the distance between cracks or scattering centers in the ring particles, mean spacing between contaminants in a water-ice matrix, and the size of individual ice grains on the surface of larger ring particles. We apply two photometric models to interpret spectra from the C ring, B ring, Cassini Division, and A ring and establish the mean photon path length, L, and the scattering asymmetry parameter, g, for a selected set of observations. The technique is based solely on the spectral shape of the absorption feature and not on the absolute magnitude of the normalized reflectance, I/F, where πF is the incident solar flux at Saturn. The two models we use are the Hapke model (Hapke, 1981, Hapke, 2002) and the Shkuratov model (Shkuratov et al, 1999, Poulet et al, 2002). We made the assumption that any contaminant present is gray and is spectrally flat in the FUV. This assumption is based on results from Khare et al (1984) where the imaginary component of the indices of refraction of Titan tholins vary by less than an order of magnitude over the spectral range of the FUV while the imaginary component of the index of refraction of water ice varies by over 8 orders of magnitude for the same spectral range (Warren and Brandt, 2008). The real part of the index of refraction for both water ice and carbon are relatively flat over the FUV spectral range, thus any spectral variations in the reflectance of a contaminant is assumed to be small and not treated in this investigation. We assess the relative water ice abundance across the rings by taking the UV slope, i.e., the ratio of the average I/F from 180-190 nm to the average I/F from 140-160 5 nm. Calculations made by (Hendrix and Hansen, 2008) show typical bidirectional reflectances of several contaminants to be on the order of 0.008 at a phase angle of 42°, which are more in the range of I/F averaged from 140-160 nm and considerably lower than I/F between 180-190 nm. Thus any contaminant present in an otherwise pure water ice regolith will serve to decrease the value of I/F for the long wavelengths. The presence of contaminant may increase or decrease I/F at the short wavelengths, depending on the relative magnitudes of the two. The result is that the UV slope will decrease for increasing contaminant levels providing a relative measure of the fractional abundance of the contaminant across the rings. In Section 2 we describe the observations and data reduction techniques used to determine I/F. In Section 3 we describe spectral modeling of the data using spectrally dependent terms from Hapke’s radiance factor model and from Shkuratov’s albedo model. Results are presented in Section 4 with estimates for the uncertainty in the photon path lengths and asymmetry parameters, and we discuss implications of our results for ring particle properties and composition in Section 5. 2. Observations and data reduction The Cassini UVIS is a spectrograph that contains two channels, an FUV channel (111.5 -191.2 nm) and an EUV channel (56.3-118.2 nm, see Esposito et al. 2004 for a complete description of UVIS). Here we analyze the water absorption edge in the FUV and thus only consider FUV observations. We have analyzed hundreds of observations in the FUV taken by the Cassini UVIS from 2005 to 2008. From these, we selected observations on the lit side of the rings with phase angles between 5° and 30°, with broad 6 spatial coverage of the rings and high signal-to-noise spectra with a projected smeared pixel size of no more than 4000 km in the radial direction (Table 1). The FUV channel has 3 selectable entrance slits of different widths (highresolution, low-resolution, and occultation). These result in different projected fields of view in the spectral direction as well as different spectral resolutions. For the FUV channel the high-resolution configuration results in a spectral resolution of 0.275 nm with a projected field of view of 0.75 mrad in the spectral direction. The low-resolution configuration results in a spectral resolution of 0.48 nm with a projected field of view of 1.5 mrad in the spectral direction. None of our selected observations used the occultation slit. The projected field of view in the spatial direction is 64 mrad for all 3 slit configurations. Since there are 64 pixels in the spatial direction, this results in an angular resolution of 1 mrad in the spatial direction. After light passes through the entrance slit and is dispersed by the grating, it is imaged onto a 1024 spectral × 64 spatial element CODACON detector, thus providing independent spectra of 64 different spatial locations. The ends of the detector in the spatial dimension are partially blocked by the detector mount resulting in 60 usable spectra for each measurement. Time series observations were made that built up a data cube with 2 spatial dimensions and 1 spectral dimension. One of the spatial dimensions results from moving the field of view from one location to another. Depending on the rate of the scan and the integration period, the spatial resolution in the direction perpendicular to the slit is generally different from the spatial resolution along the spatial axis of the slit. 7 1 2 3 4 Observation Name Maximum phase angle (degrees) Minimum phase angle (degrees) UVIS_008RI_SUBML20LP002_CIRS UVIS_014RI_SUBML15LP001_CIRS UVIS_036RI_SUBML17LP001_CIRS UVIS_054RI_SUBML08LP001_CIRS 20.0 16.8 18.9 36.6 0.950 4.38 4.60 19.4 Average projected field of view size (km) 250 X 2460 100 X 2660 365 X 2740 700 X 3375 Table 1. Summary of geometrical characteristics of observations used in this investigation. For the analysis of observations, only pixels with phase angles between 5° and 30° were used. We produced an image of the raw spectra for each ring observation to select data for this initial analysis. Spatial coverage and count rates are used as selection criteria to categorize the quality of the observations. We selected observations based on good spatial coverage and counting rates as well as consistent viewing geometry between observations (lit face, low phase angle). Data reduction consists of first subtracting a background from the raw counts. The background arises primarily from detector dark counts introduced by Cassini’s three radioisotope thermoelectric generators (RTGs). We then multiply the data by a calibration factor that converts the counts to a radiance in units of kilo-Rayleighs/Å, where 1 kilo-Rayleigh = 109 photons/sec/cm2 emitted over 4π steradians. We use a solar continuum flux (πF) measured by the Solar EUV Experiment (SEE) on board the TIMED spacecraft (Woods et al 2005). The solar spectra are available on the TIMED-SEE website (http://lasp.colorado.edu/see/l3_data_page.html). SEE has been making daily measurements of EUV and FUV solar irradiance since 2002. Solar continua that have been corrected for the rotation of the Sun in order to correspond to the face of the Sun 8 towards Saturn at the time of the observation were smoothed to the bandpass of the instrument and corrected for the Sun-Saturn distance. The solar flux was divided by π to get the radiance of a perfect Lambert surface and the observed radiance divided by that to produce I/F. During an observation the field of view of a pixel projected in the ring plane is affected by the spacecraft motion and the angle and orientation at which the line of sight intersects the ring plane. This results in pixels that are non-uniform both in size and distribution in the ring plane. Azimuthally binning pixels within relatively large radial bins may bias the result towards regions within bins where there is a higher concentration of pixels. In order to deal with this issue, we resample the data to generate an evenly distributed grid. In anticipation of data being azimuthally binned over some radial increment, we only consider the radial direction when resampling the data. We divide the rings into a 100 km radial grid and for each grid element, we select all pixels that intersect that element. The fraction, f, of each pixel within the element is multiplied by the value of I/F for that pixel and summed according to fi = 100 Ri n ∑ (I / F) I / F(resampled) = i * fi Eq 1 i= 1 n ∑f i i= 1 where Ri is the length of the ith smeared pixel in the radial direction and n is the total € for which some fraction falls within the grid element. All of the pixels number of pixels were larger than 100 km so that none of the pixels fit completely within an element. The result is an evenly weighted radial distribution of I/F values in 100 km increments. 9 After the data were evenly gridded, we then binned the results in larger radial increments in order to improve the signal-to-noise ratio. The sizes of the radial increments were determined by partitioning the rings into broad regions based on an optical depth profile from a UVIS stellar occultation profile. Figure 1 shows the optical depth profile along with the boundaries chosen for radial binning. The upper panel of Figure 2 shows I/F measured for four regions in the rings from 118-190 nm for observation 2. The spectra clearly show the water ice absorption feature present in all four regions. Lyman-α at 121.5 nm scatters out in the wings at longer wavelengths. However, the raw counts from Lyman-α scattered to pixels corresponding to wavelengths greater than 140 nm is almost a factor of 3 lower in magnitude than the Lyman-α counts at line center. For Lyman-α present in the ring observations this corresponds to count rates lower than the RTG background implying that scattered Lyman-α photons are negligible for wavelengths greater than 140 nm. Thus the spectral slope of the rings shortward of 160 nm is a real spectral characteristic of the rings and not an artifact of Lyman-α background. The lower panel of Figure 2 shows the averages of I/F from 140-160 nm and 175-190 nm as a function of ring plane radius. Error bars are shown that represent the 1-σ uncertainty due to photon counting and rtg background. The reason the uncertainty is so small is due to the large number of pixels that are used to generate each data point. At the low phase angles studied here, the long wavelength average of I/F shows that the outer B ring is significantly brighter than the rest of the rings. I/F changes with azimuth angle due to self-gravity wakes (Colwell et al, 2007), where the azimuth angle is defined as the angle between a vector from Saturn center to the intersection of the field of view with the ring plane and the line of sight vector 10 projected onto the ring plane. The azimuthal dependence is detectable in the data for observations with a large range of azimuth angles. For observation 3, the value of I/F in the A ring changed from 0.055 to 0.065 for a change in azimuth angle from 105° to 45°. 3. Spectral modeling 3.1 Radiative transfer for the rings We begin by expressing I/F for the rings according to Cuzzi et al (2002): I / F = APparticleO Eq 2 where A is the ring particle albedo, Pparticle is ring particle phase function, and O € incorporates geometry and optical depth as a scattering function. In the case where multiple scattering between ring particles may be ignored, O is separable from A and Pparticle and is thus a multiplicative constant for a given observational geometry. We used a numerical ray-tracing Monte-Carlo model (Chambers, 2008) based on Salo and Karjalainen (2003) to investigate the relative contributions of single and multiple scattering from ring particles for solar photons incident on the rings. The code models photon interactions with ring particles, includes Saturnshine, and a variable volume filling factor (D). The result of the code is a relation between albedo and I/F due to contributions from multiple orders of scattering; thus for measured I/F the contributions from both single and multiple scattering are determined. The code was benchmarked against results from Salo and Karjalainen (2003) as well as against Cassini data (see Chambers (2008) for details). We used the Callisto power-law phase function for the ring particles, and a modified Barkstrom’s law phase function was used for Saturn, which is based on that used by Dones et al. (1993). The Barkstrom phase function coefficients 11 were empirically changed from the coefficients used from Voyager data to match seasonal changes seen at Saturn at the time of Cassini. We performed tests at optical depths of 0.5, 1.5, 0.1 and 0.1 for the A-Ring, B-Ring, C-Ring and Cassini Division, respectively. Two suites of simulations were run with different values for the volume filling factor: D = 0.001 (classical thick ring) and D = 0.1 (thinner ring). For the FUV spectral regime and low phase angle observing geometry multiple scattering from ring particles was found to contribute from 2-15% to the reflected photon flux for the Cassini Division and B ring, respectively. Therefore in the following analysis we neglect multiple scattering between ring particles, which is further complicated by the presence of selfgravity wakes (Porco et al. 2008). Furthermore, if Pparticle is assumed to be spectrally independent over the wavelength range of the UVIS data, then P becomes a multiplicative constant for a given observational geometry. Without knowledge of the exact power law index for Pparticle or the dependence of the scattering function, O, on optical depth, the absolute magnitude of I/F is not modeled in the following analysis. However, based on the spectral location and shape of the water ice absorption feature, we are able to investigate the photon mean path length and the asymmetry parameter of the ice grains in the ring particle regolith. We use the spectrally dependent portions of two models, the Hapke model (1993, 2002) and the Shkuratov model (Shkuratov et al, 1999, Poulet et al, 2002) and scale them to the measured values of I/F in order to constrain the photon mean path length and the asymmetry parameter for the rings. Since both models are based on the indices of refraction for the constituents of the ring particle regolith and we are only using the indices of refraction for water ice in this 12 investigation, then scaling the model to the data requires consideration of the functional form of A that includes a term for non-ice contaminants that is not modeled. For an areal mixture of ice and one grey contaminant, A may be written as: A = f w Aw + (1 − f w ) * Ac Eq 3 where fw is the fractional abundance of water ice, Aw is the albedo of water ice, and Ac is € the albedo of the contaminant. Substituting Equation 3 into Equation 2 and rearranging terms gives I / F = f w Aw PparticleO + (1 − f w ) Ac PparticleO Eq 4 Using the average I/F at two wavelength intervals (180-190 nm and 153-160 nm) along with the average€Aw from either of the two models over the same two wavelength intervals results in two simultaneous equations that may be solved for factors that scales the model to the data on either side of the absorption feature as shown below. I / F( λ 2 ) = f w Aw( λ2 ) PparticleO + (1 − f w ) Ac PparticleO I / F( λ1 ) = f w Aw( λ1 ) PparticleO + (1 − f w ) Ac PparticleO Eq 5 € 1 refer to the averages of the two wavelength intervals. Solving these two where 2 and equations simultaneously gives f w PparticleO = ( I / F( λ 2 ) − I / F( λ 2 ) ) (A w( λ 2 ) − Aw( λ1 ) ) Eq 6 (1 − f w ) Ac PparticleO = I / F( λ 2 ) − f w Aw( λ2 ) PparticleO € Substituting Equation 6 back into Equation 4 gives 13 Mscaled = ( I / F( λ 2 ) − I / F( λ1 ) ) * A Aw( λ 2 ) − Aw( λ1 ) w Eq 7 ( I / F( λ 2 ) − I / F( λ1 ) ) * A + I / F( λ 2 ) − w( λ ) Aw( λ 2 ) − Aw( λ1 ) 2 € where Mscaled implies that the model is scaled in magnitude to I/F at wavelengths above and below the absorption edge. This technique incorporates the functional form of a two component areal mixed ring particle regolith. Therefore, although the contaminant albedo or fraction of water ice is not known, the water ice model scales to the same magnitude as it would if those quantities (along with Pphase and O) were known and put directly into Equation 4. 3.2 Hapke model The next step is to model the water ice albedo. I/F, which is referred to as the radiance factor by Hapke (1993), is given as follows: I / F = RADF = ϖ o µo {[ 1 + B(g) ] p( φ ,g) 4 µo + µ Eq 8 + H( ϖ o , µ o )H( ϖ o , µ ) − 1}R(Θ ) € I/F), is the ratio of the bidirectional reflectance of a surface to that of a where RADF (i.e., perfectly diffuse surface illuminated at an incidence angle = 0, ϖο is the regolith grain single scattering albedo, µο is the cosine of the solar incidence angle, µ is the cosine of the emission angle, B(g) is the opposition effect term, p(φ,g) is the regolith grain phase function for phase angle (φ) and asymmetry parameter (g), H(ϖο,µ) and H(ϖο,µο) are functions that arise from the contributions to the reflected light due to isotropic multiple 14 scattering between regolith grains (Chandrasekhar 1960), and is the large-scale surface roughness term. The opposition effect only becomes significant for phase angles smaller than the observations analyzed here so B(g) is neglected. The roughness term is used to deal with the roughness of the particulate surface on scales larger than the size of the regolith grains. This paper assumes that the ring particle surface is relatively smooth compared with the regolith grain size, and thus the roughness term is neglected. Furthermore, since we are not concerned with the absolute magnitude of I/F, scalar multipliers may be neglected as well. Comparison of the data with the spectrally dependent terms from the Hapke model, the water ice albedo, Aw, from Equations 4 and 7 is modeled according to: Aw = ϖ o [ p( φ ,g) + H( ϖ o , µ )H( ϖ o , µ o ) − 1] Eq 9 € where Hapke (2002) gives −1 1 − 2ro x 1 + x H( ϖ o ,x) = 1 − ϖ 0 x ro + ln 2 x Eq 10 € where x in Equation 10 refers to either µο or µ and ro = 1− 1− ϖ0 1+ 1− ϖ0 Eq 11 € 15 We use a single-lobed Henyey-Greenstein phase function (Henyey and Greenstein, 1941): p( φ ,g) = 1 − g2 (1 + g 2 + 2g cos φ ) 3 / 2 Eq 12 for the grain phase function, where φ is the phase angle and g is the single scattering € The asymmetry parameter, g, ranges from -1 (complete backward asymmetry parameter. scattering) to +1 (complete forward scattering). The Hapke model assumes that the regolith grain size is much larger than the wavelength in the FUV. Under this assumption the scattering efficiency, Qs = the regolith grain single scattering albedo. Qs is given by Hapke (1993) as Qs = Se + ( 1 − Se ) ( 1 − Si ) Θ 1 − Si Θ Eq 13 where the external scattering coefficient (Se) ad the internal scattering coefficient (Si) are given by € 2 (n − 1) + k 2 + 0.05 Se = 2 (n + 1) + k 2 4 Si = 1 − 2 n( n + 1) Eq 14 where and n and k are the real and imaginary components of the complex index of € refraction. The internal-transmission factor Θ is the total fraction of light entering the particle that reaches another surface after one transit and is given by Θ= ( 1 + r exp( − ) α (α + s) L ) ri + exp − α (α + s) L i Eq 15 where € 16 ri = 1 − α /(α + s) 1 + α /(α + s) Eq 16 € and Eq 17 α = 4πk / λ € L is the photon mean path length and s is the internal scattering coefficient inside the grain. We use a value of s = 1e-17 after Roush (1994). Figure 3 shows the complex index of refraction for water ice in the FUV. Equations 9 through 17 provide a model for the shape of the ring reflectivity spectrum that can be fit to the measured values of I/F with two free parameters: the mean photon path length L, and the grain phase function asymmetry parameter g. Equations 9-17 along with averages of I/F on either side of the absorption feature are used in Equation 4 to determine Mscaled for the Hapke case. 3.3 Shkuratov model Modeling Aw by the Shkuratov method uses the formulation from Shkuratov et al (1999) and Poulet et al (2002). For the albedo of a particulate surface the Shkuratov et al (1999) gives: Aw = 1 + ρ b2 − ρ 2f 2ρ b 2 1 + ρ b2 − ρ 2f − −1 2ρ b Eq 18 where ρ b = q ⋅ rb ρ f = q ⋅ rf + 1 − q € Eq 19 € 17 with q being the volume fraction filled by regolith grains and where rb and rf are the fractions of light scattered by a grain into the backwards and forwards hemispheres, respectively. rb and rf are given by 1 TeTi Ri exp(−2τ ) /(1 − Ri exp(−τ )) 2 1 r f = R f + TeTi exp(−τ ) + TeTi Ri exp(−2τ ) /(1 − Ri exp(−τ )) 2 rb = Rb + Eq 20 where the€transmission and reflection coefficients are given by Te = 1 − Re Ti = 1 − Ri R f = Re − Rb Rb ≈ (0.28 ⋅ n − 0.20)Re Re ≈ ro + 0.05 Eq 21 Ri ≈ 1.04 − 1/ n 2 € indices of refraction are denoted by n and k, respectively, and τ = The real and imaginary 4πkL/λ. Following the example of Poulet et al (2002), we define the asymmetry parameter, g = r f − rb and the single scattering albedo, ω = rb + r f . Then for initial r f + rb values of rf and rb, we fix g and solve for new values of rf and rb and then proceed to € € Ashk. In this manner g is a free variable and allows us to investigate both the calculate asymmetry and the photon mean path length as we did using the Hapke formulation. Equations 18-21 along with averages of I/F on either side of the absorption feature are used in Equation 4 to determine Mscaled for the Shkuratov case. 18 3.4 Determination of L and g Figure 2 (upper panel) clearly shows that the absorption edge near 165 nm. The wavelength and slope of the absorption edge depends on the values of L and g. We generated a family of model curves from Equation 9 (Hapke model) and Equation 18 (Shkuratov model) over a range of L from 0.3-100 microns in 0.1 micron increments and over a range of g from -1.0 to 1.0 in increments of 0.05 and scaled them in magnitude by the procedure described in Section 3.1. After scaling the model to the data, we quantify the agreement between model and data by the quantity Eq 22 where N is the number of data points used. After calculating D for each model curve over the range of L and g, the value of L and g corresponding to the minimum value of D gives the mean photon path length and single scattering asymmetry parameter. The difference between the normalized reflectance and the model fit from 150-190 nm is less than 10% at a spectral resolution of 1.5 nm. The values of L and g corresponding to the minimum value of D for observation 2 at r = 123,600 km were used to calculate Mscaled and plotted over I/F for that observation (Figure 4). For the Hapke model L = 3.8 microns and g = -0.5 and for the Shkuratov model L = 3.9 microns and g = -0.7. The fits from both models are similar to each other for other ring plane radii. The uncertainty in of L and g are difficult to show by means of error bars and may be irrelevant given that the uncertainty of how accurately the models describe the physical properties of the rings is unknown. The uncertainty in of L and g is best demonstrated by plotting additional model curves for values of L and g different from the optimum fit values. Figure 5 (upper left panel) shows the variation in the 19 Shkuratov model curves for 3 g values plotted over I/F from observation 2 at r = 123,600 km. L is kept fixed at the optimum value of 3.9 microns while g is given the values -0.5, 0.7, and -0.9, with g = -0.7 being the retrieved g value for this observation. The upper right panel shows the ratio of I/F to each of the model curves and demonstrates that in the spectral region from 160-170 nm that the curve with g = -0.7 is closest to one, while g values that are +/- 0.2 from the retrieved value are in error from 5-10%. The lower panels of Figure 5 shows a similar analysis for variation in L vales with errors in the fit compared to the model from 5-25% for L values that are +/- 2 microns from the retrieved value of 3.9 microns. 4. Results and analysis 4.1 UV slope The UV slope has been computed by taking the ratio of the average of I/F from 180-190 nm to the average of I/F from 150-160 nm and is shown in Figure 6. In order to make a comparison between multiple observations, the higher spatial resolution data had to be degraded to the resolution of the lowest spatial resolution data. For three of the observations, C ring data are not shown because there is off- axis light contamination from the dayside of the planet. The UV slope is an indicator of the fraction of contaminant in the rings as discussed in Section 1. As the fraction of contaminant increases, I/F for wavelengths greater than the absorption feature decreases in magnitude while I/F for wavelengths shorter than the absorption feature either increase or decrease, resulting in a lower value for the UV slope. Figure 6 shows that the outer B ring has the highest fractional abundance of water ice, while the C ring is the most contaminated. 20 4.2 Retrieved mean path length and asymmetry parameter Figure 7 shows the retrieved values of L and g for observation 2 for both the Hapke and Shkuratov models. The values of L (upper panel) vary by over a factor of 2 from the C ring to the inner B ring. The curve is relatively flat from the mid B ring through the outer A ring. For a radial bin, the retrieved L values from the Shkuratov and Hapke models agree to within a few percent, with the Shkuratov model producing the larger L values. The single scattering asymmetry parameter (lower panel) shows that the rings are strongly backscattering, with the C ring being the most backscattering. In order to test the g retrieval technique on other data sets, we performed a fit to I/F in the FUV taken by the UVIS of Enceladus at a low phase angle using the Hapke model approach and obtained a g value from -0.6 to -0.7 depending on assumed values of the backscattering parameters. The agreement between the two models is not as good for g as it was for L. The g values retuned from the Hapke model are consistently higher than for the Shkuratov model, with both displaying similar trends from the C ring through the Cassini division. However, the g values from the Hapke model show a slight increase from the inner to the outer A ring whereas the g values from the Shkuratov model show a decrease across the same region. Furthermore, there does not appear to be a correlation between L and g across the rings. Figure 8 shows a scatter plot of L and g to the UV slope. The linear Pearson correlation coefficient was computed to determine if there is a correlation between retrieved values of L and g with the UV slope. The correlation coefficients for L with the UV slope are 0.178 and 0.087 for the Hapke and Shkuratov models, respectively. The correlation coefficients for g and the UV slope are 0.276 and 0.437 for the Hapke and Shkuratov models, respectively, where the first four data points 21 were excluded since they all had the same value. This implies that the photon mean path length is not dependent on the UV slope; however, the asymmetry is strongly correlated with UV slope. 5. Disscusion Our analysis of low-phase FUV reflectance spectra of Saturn’s rings demonstrates that the reflectance of the rings in the FUV from 175-190 nm (longward of the water ice absorption feature near 165 nm) increases from the inner C ring through the outer edge of the B ring before dropping in the Cassini Division and then peaking again in the central A ring. Shortward of the absorption edge from 140-160 nm there is a similar trend of I/F with radius, but with much smaller amplitude variations. Although we cannot resolve much of the structure in the rings, I/F in the FUV does not generally track with ring optical depth except in the optically thin regions. Considering I/F averaged from 175-190 nm, we find, for example, a much larger value of I/F in the outer B ring (B4) than the central B ring (B2-B3) where the ring is nearly opaque, and we find the largest values of I/F in the central A ring where the optical depth for that ring is smallest. I/F across the B ring varies by more than a factor of two from the inner B ring to the outer B ring, whereas in the visible regime (Estrada and Cuzzi, 1996, Estrada et al. 2003, Cuzzi et al, 2002) the variation is less than 1.5. Furthermore the FUV I/F in the outer B ring is slightly less than a factor of two larger than I/F from the Cassini Division whereas in the visible regime the ratio of the outer B ring to Cassini Division I/F is greater than 3. Visible and infrared data presented in Cuzzi et at., 2002 show the same overall trend of I/F with radius but with much less variation. For instance, at a wavelength of 555 nm, Cuzzi et al. show I/F to go 22 from about 0.5 in the inner B ring to 0.65 in the outer B ring, whereas for the FUV I/F averaged from 175-190 goes from 0.06-0.12 over the same radial range. Thus the rings become less red from the inner to the outer B ring. The opposite is true from the inner A ring through the outer A ring where the rings become more red with increasing radius. We have ignored the effects of self-gravity wakes for this analysis, though the azimuthal brightness asymmetry is visible in the A ring and outer B ring in our data. However, we have azimuthally averaged our data, minimizing the effects of this azimuthal asymmetry since it has a smaller amplitude than the radial variations shown here. Results from the UV slope show that the Cassini division is more similar to the inner B ring and outer A ring than the outer B ring and Inner A ring. This differs from the slopes obtained by Estrada et al (2003) where the slopes in the inner B ring and outer A ring were larger than that in the outer B ring and inner A ring, respectively. However, Estrada et al studied a different spectral regime. Additionally the spatial resolution of the FUV data covered the entire Cassini Division, whereas the data presented by Estrada et al (2003) were able to resolve the Cassini Division and showed that the outer Cassini Division was comparable to the A ring and the inner Cassini Division was comparable to the C ring. The UV slope follows the same radial trend as I/F, which seems consistent with the idea that contaminants decrease I/F at wavelengths longer than the absorption edge and have only a small effect on I/F for wavelengths shorter than the absorption edge. The results presented here show the outer B ring to be the least contaminated and becoming more contaminated towards the inner B ring and outer A ring. The Cassini division shows the same level of contamination as the inner B ring and outer A ring. The C ring shows the highest degree of contamination; however the off axis light associated 23 with the C ring may actually be making the level of contaminant seem less than it really is under the assumption that off axis light scattered from Saturn may be more intense at the longer wavelengths than at the shorter wavelengths. The fits from the Hapke and Shkuratov models to I/F were almost identical. The upper left panel of Figure 5 shows that as g increases (that is, as the grains go from being highly backscattering at g = -0.9 to g = -0.5) the steepness of the water ice absorption edge decreases with only minimal affect on the spectral location of the absorption edge. The lower left panel of Figure 5 shows that adjusting the mean photon path length, L, does not affect the steepness of the absorption edge but and increase in L increases the wavelength of the absorption edge. The steepness of the absorption is an independent constraint on the particle scattering properties while the spectral location of the absorption edge constrains the photon mean path length. The Hapke and Shkuratov models gave similar results for retrieved L values, however the g values were somewhat different. One possible explanation for this is that for the Hapke model the g value manifests itself only in the single scattering term in the Hapke formulation, whereas it applies to all orders of scattering in the Shkuratov model. We have retrieved information concerning the directionality of scattering through the single scattering asymmetry parameter, g. Across all of the rings g was negative, implying that backscattering from regolith grains dominates at FUV wavelengths. The g values retrieved from the Hapke model showed a gradual increase towards less negative values (-0.85 to -0.45) from the C ring to the outer A ring. The g values retrieved from the Shkuratov model showed a similar overall trend from the C ring to the inner A ring (-1 to -0.75) but then dramatically decreased to ~ -0.9 for the outer A ring. These values 24 are more negative than results obtained for icy moons. For instance Verbiscer and Veverka (1994) obtained a g value = -0.399 +/- 0.005 for Enceladus using Hapke’s (1986) photometric equation. This result was based on data at much longer wavelengths than ours. The discrepancy between the g values of the rings and g values obtained by others for icy moons may be attributable to both wavelength dependencies and differences in ice-contaminant grain structure. If particles are “irregular” to the nm wavelength scale, as might be true for airless bodies at temperatures much less than the melting point of water (i.e., not terrestrial snows and frosts which are constantly annealed) then the more negative g’s might be physically understood. Longer wavelengths may not “sense” the fine structure of irregularly shaped un-annealed grains that are retrieved by the FUV analysis presented here. We have retrieved a measure of the amount of water ice that UV photons traverse before leaving the rings from the location of the absorption edge in the data. This mean photon path length, L, represents the total path through water ice on the surface of a ring particle. It is not a measure of the size of a ring particle or regolith grain, but is related to the distance between scattering centers within those regolith grains. These could be the far side of a small grain, cracks or other flaws in the ice, or non-ice contaminants within the grain. The retrieved value of L is relatively uniform from the mid B ring to outer A ring, while the minimum occurs in the inner C ring. One possible explanation is that the mean distance photons travel could be highly dependent on the level of contaminant, with more contaminant implying a shorter path length. A gray contaminant added to the water ice model would serve to reduce the albedo at wavelengths longer than the water ice absorption feature and slightly increase or decrease the albedo at wavelengths shorter 25 than the absorption feature; however, this would not change the spectral location of the absorption edge. A non-gray contaminant would cause a shift in the absorption edge and will be considered in future work. Four radial trends are characterized in this investigation: I/F, UV slope, g values and L values. The lack of correlation of L with the UV slope seems to imply that L depends on regolith grain characteristics other than contamination. One possibility is that photons scattered in the direction of the instrument did not encounter contaminants while photons that do encounter contaminants are absorbed. The same conclusion may be stated concerning the retrieved g values, which are only moderately correlated with the UV slope. If the photons reaching the instrument are indeed those photons that did not encounter contamination, then the retrieved g values are directly related to the structure of the ice grains on the ring particles. While pure water ice should be transparent to photons of wavelengths longer than the FUV absorption edge, the presence of internal facets or edges of grains in a complex structure of ice regolith would result in scattering incident photons. Other outer solar system ices have been shown to be backscattering (Verbiscer, 1994), although the values in this investigation show a larger degree of backscattering. This may be due to both wavelength differences and structure of the ring particle regolith ice grains. 26 References Chambers, L.S., 2008. Numerical modeling of Saturn’s satellites and ring system. Ph.D. thesis, University of California, Santa Cruz. 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Cuzzi, J.N., French, R.G., Dones, L., 2002. HST Multicolor (255-1042 nm) Photometry of Saturn’s Main Rings. Icarus 158, 199-223. Dones, L., Cuzzi, J.N., 1993. Voyager Photometry of Saturn’s A Ring. Icarus, 105, 184215. Doyle, L.R., Dones, L., Cuzzi, J.N., 1989. Radiative transfer modeling of Saturn's outer B ring. Icarus 80, 104-135. Epstein, E.E., Janssen, M.A., Cuzzi, J.N., 1984. Saturn’s rings – 3-mm low-inclination observations and derived properties. Icarus 58, 403-411. Esposito, L.W., Cuzzi, J.N., Holberg, J.B., Marouf, E.A., Tyler, G.L., Porco, C.C., 1984. Saturn’s rings: Structure, dynamics, and particle properties. In Saturn (T. Gehrels and M. Matthews, Eds.), University of Arizona Press, Tucson, 463-545. Esposito, L.W., Barth, C.A., Colwell, J.E., Lawrence, G.M., McClintock, W.E., Stewart, A.I.F., Keller, H.U., Korth, A., Lauche, H., Restou, M.C., Lane, A.L., Hansen, C.J., Maki, J.N., West, R.A., Jahn, H., Reulke, R., Warlich, K., Shemansky, D.E., Yung, Y.L., 2004. The CASSINI Ultraviolet Imaging Spectrograph Investigation, Space Science Reviews 115, 299-361. Estrada, P.R., Cuzzi, J.N., 1996. Voyager Observations of the Colar of Saturn’s Rings. Icarus 122, 251-272. Estrada, P.R., Cuzzi, J.N., Showalter, M.R., 2003. Voyager color photometry of Saturn’s main rings: a correction. Icarus 166, 212-222. Hapke, B., 1981. Bidirectional Reflectance Spectroscopy. 1. Theory. Journal of Geophysical Research 86, April 10, 3039-3054. Hapke, B., 1986. Bidirectional reflectance spectroscopy 4. The extinction coefficient and the opposition effect. Icarus 67, 264-280. Hapke, B., 1993. Theory of Reflectance and Emittance Spectroscopy. Cambridge University Press. Hapke, B. 2002. Bidirectional Reflectance Spectroscopy. 5. The coherent backscatter opposition effect and anisotropic scattering. Icarus 157, 523-534. 27 Hendrix, A.R., Hansen, C.J., 2008, Ultraviolet observations of Phoebe from the Cassini UVIS, Icarus, 193, 323-333. Henyey, C., Greenstein, J., 1941. Diffuse radiation in the galaxy. Astrophys. J. 93, 70-83. Khare, B.N., Sagan, S., Arakawa, E.T., Suits, F., Callcott, T.A., Williams, M.W., 1984. Optical Constants of Organic Tholins Produced in a Simulated Titanian Atmosphere: From Soft X-Ray to Microwave Frequencies. Icarus 60, 127-137. Lebofsky, L.A., Johnson, T.V., McCord, T.B., 1970. Saturn’s rings: Spectral reflectivity and compositional implications. Icarus 13, 226-230. Nicholson, P.D., Hedman, M.M., Clark, R.N., Showalter, M.R., Crikshank, D.P. Cuzzi, J.N., Filacchione, G., Capaccioni, F., Cerroni, P., Hansen, G.B., Sicardy, B., Drossart, P., Brown, R.H., Buratti, B.J., Baines, K.H., Coradini, A., 2008, A close look at Saturn’s rings with Cassini VIMS, Icarus 193, 182-212. Poulet, F., Cuzzi, J.N., Cruikshank, D.P., Roush, T., Dalle Ore, C.M., 2002. Comparison between the Shkuratov and Hapke Scattering Theories of Solid Planetary Surfaes: Application to the Surface Composition of Two Centaurs. Icarus 160, 313-324. Roush, T.L., 1994. Charon: More than water ice? Icarus 108, no. 2, pt. 1, p. 243-254. Salo, H., Karjalainen, R., 2003. Photometric modeling of Saturn’s rings I. Monte Carlo method and the effect of nonzero volume filling factor. Icarus, 164, 428-460. Shkuratov, Y., Starukhina, L., Hoffmann, H., Arnold, G., 1999. A Model of Spectral Albedo of Particulate Surfaces: Implications for Optical Properties of the Moon. Icarus 137, 235-246. Verbiscer, A. J., Veverka, J., 1994. A Photometric Study of Enceladus. Icarus 110, 155164. Wagener, R., Caldwell, J., 1986. On the abundance of micron-sized particles in Saturn’s A and B rings. In ESA, A Decade of UV Astronomy with the IUE Satellite 1, 8588. Warren, S.G., Brandt, R.E., 2008. Optical constants of ice from the ultraviolet to the microwave: A revised compilation. Journal of Geophysical Research, 113, D14220, doi:10.1029/2007JD009744. Woods, T.N., Eparvier, F.G., Bailey, S.M., Chamberlin, P.C., Lean, J., Rottman, G.J., Soloman, S.C., Tobiska, W.K., Woodraska, D.L., 2005. Solar EUV Experiment (SEE): Mission overview and first results. J. of Geophysical Research 110, A01312, doi: 10.1029/2004JA010765. Zebker, H.A., Marouf, E.A., Tyler, G.L., 1985. Saturn’s rings – Particle size distributions for a thin layer model. Icarus 64, 531-548. 28 Figure 1. Optical depth profile of the C through A rings measured with the Cassini UVIS High Speed Photometer (HSP) observing the β Centauri Rev 077 ingress occultation. Optical depths were calculated following the procedure in Colwell et al. (2007). The vertical arrows show the boundaries of the bins between which FUV spectra were averaged after the spectra had been re-sampled to an evenly distributed grid. Bin boundaries were chosen to match regional boundaries in the rings where possible (Colwell et al. 2009). The four main regions of the B ring are labeled. 29 Figure 2. I/F from observation 2 for 4 regions in the rings (upper panel). The center radial positions are 86000, 107250, 119965, and 127950 km for the C ring, B ring, Cassini Division, and A ring, respectively. The lower panel shows the average I/F from 1400160 nm and 175-190 nm plotted against ring plane radius. The small error bars represent the 1-σ uncertainty in the photon counting statistics and the rtg background that have been propagated through to I/F. 30 Figure 3. Complex index of refraction for hexagonal water ice taken from Warren and Brandt (2008). The real part (top panel) is shown on a linear plot while the imaginary part (lower panel) is shown as the log of the value. The absorption of water ice is determined by the imaginary part of the index of refraction. The strong decrease of k longward of 150 nm indicates that water ice becomes less absorbing for longer wavelengths and is thus the basis of the technique to determine the characteristics of water ice from the FUV reflectance. 31 Figure 4. Example of fit of Hapke model (blue curve) and Shkuratov model (red curve) to I/F from observation 2 for r = 123,600 km. For the Hapke model L = 3.8 microns and g = -0.5 and for the Shkuratov model L = 3.9 microns and g = -0.7, which were retrieved from the minimum value of D in Equation 22. The difference between the model and I/F was less than 10% at 1.5 nm resolution. Data below 153 nm were not modeled due to the additional structure in the spectrum that is not included in our Hapke model. 32 Figure 5. Shkuratov model curves compared to I/F for observation 2 at a ring plane radius = 123,600 km. The red curve in upper left and lower left panels is the optimum fit from Figure 4 with L = 3.9 microns and g = -0.7. For the upper left panel, additional model curves are plotted where L is kept fixed at 3.9 microns and g is given values of -0.9 and 0.5. Varying g values alter the slope of the model in the fall off region. The upper right panel is the ratio of I/f to each of the model curves from the upper left panel. The region from 160-170 nm shows a ~5-10% error for g that is 0.2 larger or smaller than the optimum value. For the lower left panel, additional model curves are plotted where g is fixed at -0.7 and L is given values of 1.9 and 5.9 microns and demonstrates the spectral variation of the absorption edge with L. The lower right panel shows a ~ 5-25% error for L that is 2 microns different from the optimum value. 33 Figure 6. UV slope for four different observations. The ratio is obtained by dividing the average I/F from 175-190 nm by the average I/F from 140-160 nm. Off-axis light contaminated the signal from the C ring, with observation 2 containing the least amount of contamination, thus being the only observation shown for the C ring. The field of view of each pixel projected in the ring plane for observations 3 and 4 was from 2-3 times larger than for observations 1 and 2. For the purpose of comparison between observations the spatial quality of observations 1,2, and 3 was degraded. 34 Figure 7. Retrieved value of L (upper panel) and g (lower panel) from observation 2. L is relatively flat from the mid B ring through the outer A ring within the uncertainties established in the analysis shown in Figure 5. The regolith grains in the ring particles are strongly backscattering in the FUV, but less so in the inner and central A ring and outer B ring where FUV reflectance and UV slope are largest. 35 Figure 8. Scatter plot of g (upper panel) and L (lower panel) to the UV slope from observation 2. The retrieved value of L is independent of the radiance. The linear Pearson correlation coefficient was computed to determine if there is a correlation between retrieved values of L and g with the UV slope. The correlation coefficients for g with the UV slope are 0.276 and 0.437 for the Hapke and Shkuratov models, respectively, where the first four data points are excluded since they are all the same value. The correlation coefficients for L with the UV slope are 0.178 and 0.087 for the Hapke and Shkuratov models, respectively. 36