Diurnal cycle of air pollution in the Kathmandu Valley, Nepal: 2. Modeling results The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Citation Panday, Arnico K., Ronald G. Prinn, and Christoph Schär. “Diurnal Cycle of Air Pollution in the Kathmandu Valley, Nepal: 2. Modeling Results.” Journal of Geophysical Research 114, no. D21 (2009). As Published http://dx.doi.org/10.1029/2008jd009808 Publisher American Geophysical Union Version Final published version Accessed Thu May 26 20:40:21 EDT 2016 Citable Link http://hdl.handle.net/1721.1/85645 Terms of Use Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. Detailed Terms Click Here JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 114, D21308, doi:10.1029/2008JD009808, 2009 for Full Article Diurnal cycle of air pollution in the Kathmandu Valley, Nepal: 2. Modeling results Arnico K. Panday,1,2,3 Ronald G. Prinn,4 and Christoph Schär5 Received 10 January 2008; revised 27 May 2009; accepted 10 June 2009; published 6 November 2009. [1] After completing a 9-month field experiment studying air pollution and meteorology in the Kathmandu Valley, Nepal, we set up the mesoscale meteorological model MM5 to simulate the Kathmandu Valley’s meteorology with a horizontal resolution of up to 1 km. After testing the model against available data, we used it to address specific questions to understand the factors that control the observed diurnal cycle of air pollution in this urban basin in the Himalayas. We studied the dynamics of the basin’s nocturnal cold air pool, its dissipation in the morning, and the subsequent growth and decay of the mixed layer over the valley. During mornings, we found behavior common to large basins, with upslope flows and basin-center subsidence removing the nocturnal cold air pool. During afternoons the circulation in the Kathmandu Valley exhibited patterns common to plateaus, with cooler denser air originating over lower regions west of Kathmandu arriving through mountain passes and spreading across the basin floor, thereby reducing the mixed layer depth. We also examined the pathways of pollutant ventilation out of the valley. The bulk of the pollution ventilation takes place during the afternoon, when strong westerly winds blow in through the western passes of the valley, and the pollutants are rapidly carried out through passes on the east and south sides of the valley. In the evening, pollutants first accumulate near the surface, but then are lifted slightly when katabatic flows converge underneath. The elevated polluted layers are mixed back down in the morning, contributing to the morning pollution peak. Later in the morning a fraction of the valley’s pollutants travels up the slopes of the valley rim mountains before the westerly winds begin. Citation: Panday, A. K., R. G. Prinn, and C. Schär (2009), Diurnal cycle of air pollution in the Kathmandu Valley, Nepal: 2. Modeling results, J. Geophys. Res., 114, D21308, doi:10.1029/2008JD009808. 1. Introduction [2] In this paper we present results of theoretical investigations using a numerical model aimed at addressing questions about processes that control air quality in the Kathmandu Valley, Nepal. These questions arose from the analysis of data from a field experiment that we conducted in 2004 – 2005 [Panday and Prinn, 2009]. The Kathmandu Valley is a bowl shaped basin in central Nepal, halfway between the Ganges Plains and the Tibetan plateau. It has a flat floor area of 340 km2, and it is located 1300 m above sea level (masl), surrounding by mountains reaching 2000 – 1 Program in Atmospheric and Oceanic Sciences, Princeton University, Princeton, New Jersey, USA. 2 Formerly at Center for Global Change Science, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA. 3 Now at Department of Environmental Sciences, University of Virginia, Charlottesville, Virginia, USA. 4 Center for Global Change Science, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA. 5 Institute for Atmospheric and Climate Science, Swiss Federal Institute of Technology, Zurich, Switzerland. Copyright 2009 by the American Geophysical Union. 0148-0227/09/2008JD009808$09.00 2800 masl. There are five passes of 1500– 1500 masl on the west and east sides, and one winding river outlet (the Bagmati River) to the south. The valley is inhabited by close to 3 million people. Its vehicle fleet exceeds 300,000 motorcycles and a hundred thousand other vehicles. In recent years its growing air pollution problem has caught increasing attention, especially during winters. [3] In urban mountain basins, an important effect of the surrounding topography is to reduce the exchange of valley air with the free troposphere and thereby to concentrate pollutants near the basin bottom. Ventilation of basins is often dominated by complex valley wind systems that are driven by differential heating and cooling of surrounding mountain slopes and characterized by a strong diurnal cycle. At night, basins often fill with pools of cold air. In addition to local radiative cooling, basin bottoms experience an additional cooling component due to the arrival of drainage flows from colder surrounding mountain slopes [Whiteman et al., 2004a]. Such cold air pools have been studied extensively in the Columbia Basin [Whiteman et al., 2001; Zhong et al., 2001] Danube Basin [Zängl, 2005], Virginia [Allwine and Lamb, 1992], Colorado [Whiteman, 1982; Kelly, 1988; Neff and King, 1989; Whiteman et al., 1999], Bulgaria [Savov et al., 2002], Slovenia [Rakovec et D21308 1 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 1. Kathmandu Valley, viewed from the south in Google Earth (printed with permission). The high Himalayas and Tibetan Plateau are visible at the top edge of the image. Kathmandu city is labeled in red. Yellow labels show important measurement sites. al., 2002] and Japan [Kondo et al., 1989]. Cold pools in small basins and sinkholes in the Rockies and in Austria have been chosen for the extensive field observations designed to understand their processes [Clements et al., 2003; Whiteman et al., 2004a, 2004b]. Often the top of a cold air pool is marked by a strong temperature jump [Whiteman et al., 2001]. Within and immediately above the cold pools, there is a strong temperature inversion, which suppresses buoyant vertical transport of pollutants. The daytime growth of a mixed layer over a basin thus requires the dissipation of the basin’s cold air pool and its associated temperature inversion. [4] In the Kathmandu Valley, we conducted a field experiment between September 2004 and October 2005. A companion paper [Panday and Prinn, 2009], and a dissertation [Panday, 2006], describe the results in detail. Here we summarize some salient aspects of the observational campaign and formulate the objectives of the current paper. The observational set up included a laboratory in Bouddha, east of Kathmandu city, where we continuously measured carbon monoxide (CO), ozone, fine particulates (PM10) and weather variables. In addition, during part of the time we had a mini sodar operating nearby, and we had four temperature loggers on a TV tower, as well as additional temperature loggers on a valley rim peak, at the base of the valley rim, and on a small peak overlooking the lab site. These sites are shown on Figure 1. [5] One of the key results discussed in the companion paper is the observation of two daily CO peaks in the Kathmandu Valley. Figure 2 shows the diurnal cycle of carbon monoxide measurements at the laboratory in Bouddha in October 2004 and January 2005. We have chosen to show the maximum and minimum values for each 10-min time interval, in order to show the values below which CO never dropped, and the values that were never exceeded. In addition, Figure 2 shows the median for each 10-min time interval as a measure of where 50% of the data may be located in a possibly not normal distribution. The diurnal cycle shows a distinct peak in the morning, and one in the evening. In part 1 [Panday and Prinn, 2009] we have shown that the two peaks are not merely driven by the emissions but strongly affected by the diurnal circulation and mixing in the Kathmandu Valley. In particular, CO bag sampling on small neighboring peaks indicated the nighttime lifting of pollutant layers, while ozone measurements on a tall peak showed the isolation of these sites from Kathmandu Valley air at night. In the current paper (part 2) we will use a high-resolution numerical model to clarify the underlying dynamical mechanisms. [6] To set the scene for the simulations, Figures 3 and 4 show meteorological observations on six representative, consecutive days in February 2005. Most days were sunny, with low wind speeds at night, and strong westerly winds during the afternoons. Figures 4a and 4b indicate that saturation occurred on most mornings, and that on several afternoons the dew point dropped, indicating the arrival of a different air mass. Figure 4c shows the temperature recorded on Nagarkot peak (1972 masl), and at Kharipati (1373 masl), at the base of Nagarkot. While Kharipati was warmer than Nagarkot during the daytimes, it was colder during most nights, indicating a temperature inversion. Figure 4d compares the temperature at Kharipati with a valley-center location. We see that in the evening, the temperature dropped more rapidly in Kharipati. This is consistent with the formation of a nocturnal cold air pool in the valley 2 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 2. Diurnal cycle of CO at the main laboratory in Bouddha during the months of (a) October 2004 and (b) January 2005, averaged over 10-min intervals. The centerline represents the monthly median value for each 10-min interval. Vertical bars show the highest and lowest 10-min averages recorded that month for each time interval. The x axis is in Nepal Standard Time, which is UTC + 5 h 45 min. through the arrival of katabatic winds from the valley rim slopes. Figure 5a shows the lapse rate computed from the temperature difference between Nagarkot and Kharipati. We see stable conditions at night, and a midday lapse rate near the 9.8 K/km dry adiabatic lapse rate, indicating a well- mixed layer between the valley bottom and the altitude of Nagarkot. Figures 5b and 5c show the lapse rate calculated using temperatures at different levels on the TV tower. We see stable conditions down to the lowest levels at night (consistent with a cold air pool in the valley), and strong Figure 3. (a) Solar radiation, (b) wind speed, and (c) wind direction measured by the weather station on the Hyatt roof in Bouddha during a typical 6-day period in spring 2005. The period considered contains a weekend (26 – 27 February). 3 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS Figure 4. (a) Relative humidity at the Hyatt roof in Bouddha during the same 6 days as in Figure 2, (b) temperature (black) and dew point (green) on the Hyatt roof during the same time, (c) temperature on Nagarkot Peak (red) and Kharipati at the base of Nagarkot (blue), and (d) temperature at Kharipati (blue) and at 5 m on the TV tower (black). Figure 5. Lapse rates (K/km) estimate between different measurement sites: (a) between Kharipati and Nagarkot, (b) between the bottom two loggers on the TV tower, and (c) between the 5-m and the 48-m logger on the TV tower. 4 of 20 D21308 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS thermals at midday that shrink with height. Sodar data were not available in February, but sodar-derived mixed layer heights in May showed that the mixed layer peaked at midday at a depth of 400 to 800 m (see part 1). These values are surprisingly low. It is possible that the sodar’s range prevented us from seeing the full height of the mixed layer. However, the fact that sodar data showed a shrinking mixed layer height over the course of the afternoon suggests that perhaps other processes were at play. [7] The observational results are discussed in more detail in part 1 [Panday and Prinn, 2009]. It explained the observed daily twin peak pattern of CO in terms of diurnal variations in emissions and ventilation. The morning peak decreased at the same time that the nocturnal cold air pool had dissipated, and strong westerly winds removed pollutants that had accumulated in the city over the course of the morning. The evening peak began when evening rush hour took place after rapid ventilation ceased. Parts of the evening emissions were found to be lifted and recirculated the next morning, adding to the morning pollution peak. Our observations left some important questions unanswered, however. They did not give us a complete picture of the dynamics of the nocturnal cold air pool and the daytime mixed layer, nor did they indicate the pathways of pollutant ventilation out of the valley. In this paper we use numerical modeling to address these questions, using Pennsylvania State University (PSU)/National Center for Atmospheric Research (NCAR) mesoscale meteorological model (also known as MM5). We will use observations to validate the numerical model results, and then turn attention to two specific scientific issues. These concern the dissipation of the nocturnal cold-air pool and its replacement by a mixed layer in the Kathmandu valley, and the analysis of air-parcel trajectories to elucidate the fate of polluted valley air. [8] Section 2 describes the model set up. Section 3 compares model results with observations. Section 4 discusses possible mechanisms for the dissipation of nocturnal cold air pools and mixed layer growth in mountain basins, and shows modeling results for Kathmandu. Section 5 examines pathways of pollutant ventilation out of the valley during different times of day. The study is concluded in section 6. 2. Numerical Modeling [9] We set up version 3.6.1 of the mesoscale meteorological model MM5 for use around the Kathmandu Valley. Initial and boundary conditions were taken from global final analyses (FNL), prepared every 6 h at 1° resolution by the National Center for Environmental Prediction (NCEP), and available online through the National Center for Atmospheric Research (NCAR) Data Support Section webpage (http:// dss.ucar.edu/datasets/ds083.2/). The modeling domain was set up using a Lambert conformal projection, with four levels of two-way nesting, stepping down in resolution from one degree NCEP FNL data at the side boundaries while maintaining a 1:3 grid resolution ratio. The four nested domains had horizontal grid resolutions of 27, 9, 3, and 1 km and were all centered at 27.7°N, 85.3°E, corresponding to a point in central Kathmandu City, close to the Dharahara tower (Figure 6). The outer two domains had 50 by 50 horizontal grid squares, while the inner two domains had 75 D21308 by 75 grid squares. The outermost domain spanned much of the Ganges Basin and a big part of the Tibetan Plateau, while the innermost domain spanned approximately three times the horizontal extent of the Kathmandu Valley, reaching into neighboring valleys. [10] Land use and vegetation for the simulations were taken from the public USGS 25-category 30 arc-second database downloadable via the MM5 homepage (ftp://ftp. ucar.edu/mesouser/MM5V3/TERRAIN_DATA/), while underlying topography was taken from the USGS GTOPO-30 (global 30 arc-second) database and smoothed appropriately for each nest level. At the 1-km grid resolution of the innermost domain, the model topography was able to capture essential features of the Kathmandu Valley, including the surrounding mountains, passes, and relatively flat basin bottom. It did not capture small-scale features within the valley bottom, such as Chobhar hill, Chobhar Gorge, Swayambhu hill, the Pullahari-Kapan ridge, Changu Narayan hill or any of the river channels. MM5 is not designed for use at resolutions less than 1 km without modifications to the code [Gohm et al., 2004]. [11] Our model runs were initialized with NCEP analyses at 0600 UTC, corresponding to 1145 Nepal Standard Time. Initialization at midday rather than midnight was chosen because mountain valleys often contain stably stratified air masses at night, which are disconnected from overlying regional flows and poorly represented in the synoptic-scale analysis that initialize and drive the model. The model runs were allowed to spin up for 36 h before the results were used. Experimental runs with various vertical sigma coordinate configurations led to a final choice of 40 vertical layers extending from the surface to 100 mbar. The five bottommost layers were each 15 m thick (corresponding to 0.006s), while above them the layer thickness was gradually increased. At the top of the model domain, boundary conditions were chosen to allow radiation of internal gravity waves [Klemp and Durran, 1983]. Simulation time steps were 60 s in the outermost domain with 27 km resolution, necessitating a 1 s time step in the innermost domain. The lateral boundaries of the outermost domain used linear interpolation between the 6-hourly time steps of the NCEP analysis, with a relaxation extending four grid cells into the domain. [12] Cloud microphysics was parameterized using the Simple Ice Scheme [Dudhia, 1989]. This uses explicit microphysics calculations to simulate cloud and rainwater as well as cloud ice. MM5 was allowed to calculate cumulus clouds explicitly in the inner two domains (3 km and 1 km resolution), while in the coarser resolution outer domains cumulus clouds were parameterized using the updated KainFritsch scheme [Kain, 2004]. The boundary layer was parameterized using the MRF scheme [Hong and Pan, 1996], which is suitable for fine resolution runs while maintaining computational efficiency. Solar and terrestrial radiation were calculated every 30 min, using a parameterization that included long- and short-wave radiation interacting with clear air, clouds, precipitation and the ground [Dudhia, 1989]. For the surface energy budget, a five-layer soil model was used [Dudhia, 1993], with soil moisture initialized by the driving analysis. [13] We carried out simulations for February and May 2005, and used the MM5-customized interpolation and 5 of 20 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 D21308 Figure 6. The four nested domains used in our MM5 simulations. Domain 4 (labeled) is centered on the Kathmandu Valley. plotting package RIP4 (ftp://ftp.ucar.edu/mesouser/MM5V3/ RIP4.TAR.gz) to generate plots and to calculate forward and backward trajectories. The trajectories were calculated at 1-min intervals using horizontal and vertical vectors output by MM5 every half hour. 3. Model Validation [14] Next we look at MM5’s ability to reproduce the Kathmandu Valley’s meteorology. To this end we use a simulation initialized on 8 February 2005, 0600 UTC (1145 NST), and analyze a representative 2-day period. Figure 7 shows that MM5 accurately captured the nighttime temperature, but underestimated the daytime temperature at our Bouddha station. It also shows that MM5 accurately captured the daytime relative humidity minimum, but that it overestimated relative humidity for most of the simulation, including an overestimate of the duration of saturation. The underestimate of the diurnal temperature cycle, in combination with the overestimate of the diurnal humidity cycle, suggests that this bias is at least partly due to an incorrect representation of the Bowen ratio (overestimated evapotranspiration at the expense of underestimated sensible heat flux). Such an error could derive from too high a soil moisture content in the initial conditions. In addition, part of the bias seen here might have explanations other than model error. First, it is plausible that during the daytime the temperature at the rooftop weather station was slightly contaminated by local infrared radiation from the tile roof underneath it, while the MM5 results represent an average over a grid cell of 1 km by 1 km. Second, the weather station was located 22 m above ground, while MM5’s bottom layer center was 7.5 m above ground. Fog tends to develop from the ground up, so it is indeed possible that there was fog near the ground earlier in the morning than the time when 100% relative humidity was reached at the weather station. [15] Figures 8a and 8b show that MM5 captured the diurnal temperature cycle at the TV tower and at Nagarkot Peak remarkably well. At Kharipati MM5 slightly underestimated the temperature during the day and overestimated it at night. Part of that may be due to topographic smoothing by MM5, which lifted the location of Kharipati to a higher elevation. Figure 9 shows the temperature in the lowest model layer (between s = 1 and s = 0.994) over the Kathmandu Valley at dawn (Figure 9a) and in the afternoon (Figure 9b). At dawn the entire basin bottom was filled with 6 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 7. Intercomparison of measurements by the weather station on the Hyatt roof (blue) on 9 and 10 February 2005 with MM5 simulations for the same time period at the grid cell containing the Hyatt roof and main laboratory (red). (a) Air temperature and (b) relative humidity. a pool of cold air whose temperature was similar to that of the highest peaks on the valley rim. We also see that surrounding river valleys (for example, in the upper left quadrant of the plots) did not contain cold pools. In contrast to the Kathmandu Valley’s confined basin shape, these river valleys allows drainage flows to travel unimpeded. In the afternoon the Kathmandu Valley’s center was warmer than its edges, and the cold pool was gone. Figure 8. Intercomparison of air temperature measurements by Hobo loggers (blue) at three locations on 9 and 10 February 2005 with MM5 simulations (red) for the same time period at grid cells containing the logger sites. (a) TV tower bottom (5 m above ground), (b) Nagarkot, and (c) Kharipati. 7 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 9. (a) Air temperature in the lowest MM5 layer (color shading) at 0545 NST on 10 February 2005. The underlying topography is indicated by contour lines with a contour interval of 100 m. (b) Same as in Figure 9a but for air temperature in the lowest MM5 layer at 1445 on 10 February 2005. The black line indicates the location of the cross section in Figures 12, 14, 15, 16, and 17. [16] Figure 10 shows the relative humidity in the surface layer at dawn and shortly before noon on 10 February 2005 and compares it to photographs from Hattiban taken at the same times. At dawn a large part of the valley center had 100% relative humidity, while the rest of the valley floor had relative humidity exceeding 90%. In fact, during the early morning hours the simulation showed frequent fluc- tuations in the locations of the area reaching the 100% threshold, indicating that many of the areas shown in dark blue actually had relative humidity close to 100% as well. Indeed at dawn that morning we photographed a thin fog layer covering much of the valley. Time-lapse photography showed that over the course of the morning the fog layer thickened, and then disappeared from the surface by late 8 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 10. (left) Photographs of the valley from Hattiban Ridge and (right) MM5 output of relative humidity in the bottommost layer on 10 February 2005. The color scale goes from white to blue to indicate increasing relative humidity; red indicates where the threshold value of 100% is achieved. The glow in the early morning photograph results from a thin sheet of fog. morning. Consistent with this, the MM5 simulation shows that by 1145 NST the relative humidity near the surface was below 40% in the entire valley. [17] Figure 11 shows wind vectors computed by MM5 in the lowest model layer before dawn and in the afternoon of 10 February 2005. The modeled patterns fit with what we observed. At dawn the valley center had almost zero surface winds. At the edges of the valley, katabatic winds descended from mountain ridges, while drainage flows traveled down both the Bagmati river valley (coordinates 20 km NS, 32 km EW) and the river valleys outside of the Kathmandu Valley. We also see easterly winds crossing the passes on the western edge of the Kathmandu Valley, such as at Bhimdhunga Pass (42 km NS, 31 km EW). During the afternoon, strong winds traveled up the river valleys, while the entire Kathmandu Valley bottom was swept by westerly/northwesterly winds entering through the western passes. Afternoon wind speeds on the order of 5 – 6 m/s over the valley were close to the average afternoon wind speeds measured at the Bouddha station. We also see that the up-valley winds from the Bagmati River valley were able to enter the southern parts of the valley, but were pushed eastward by the stronger westerlies entering from the western passes. [18] Figure 12 shows west– east cross sections through the innermost domain of the MM5 simulation, with contours of potential temperature as well as wind vectors. At night there was a strongly stratified cold air pool in the valley (indeed its top corresponded to the height of the valley’s passes). By 1145 NST the cold air pool was gone, and the mixed layer extended up beyond the height of the valley rim peaks while westerly winds travel through the valley. This is consistent with our observation of winds in Figure 3, observations of the lapse rate between Kharipati and Nagarkot in Figure 5, and observations of mixed layer height by the sodar shown in part 1. 4. Dynamics of the Nocturnal Cold Air Pool and the Daytime Mixed Layer [19] Having verified MM5’s ability to reproduce observed meteorology in the Kathmandu Valley, we now proceed to address the first of our two questions: What mechanisms are responsible for the dissipation of the nocturnal cold air pool in the Kathmandu Valley, and how does the mixed layer behave during the day? We discuss four possible mechanisms for cold-pool dissipation before examining model results. [20] The first mechanism is often observed over flat plains, where inversion breakups are driven by surface heating [Stull, 1988; Young et al., 2000; Angevine et al., 2001; Garcia et al., 2002]. A convective mixed layer grows upward as the surface warms up after sunrise. Thermals generated by the heated bottom rise to increasingly greater heights, chipping away at the inversion above. As the mixed layer grows, it entrains air that was previously isolated from the surface by the inversion. Entrainment of ozone-rich air can cause a rapid rise in ozone observed at the surface in the morning. The mixed layer above a flat plain often grows until the late afternoon, breaking through the uppermost remnants of the inversion, and then entraining air from the less stable residual layer that had spent the night above the inversion. The mixed layer has been observed to grow faster over cities owing to enhanced convection driven by urban heat islands [Kallistratova and Coulter, 2004] and to be 9 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 11. Surface wind vectors (yellow) from MM5 superimposed upon gray scale shaded topography (meters above sea level) at (a) 0545 NST and (b) 1615 NST on 10 February 2005. The Kathmandu Valley is the flat area at the center of the frame. For visual clarity, wind vectors have only been plotted for every second grid cell. Their length is proportional to the wind speed; a vector length of two grid cells corresponds to a speed of 10 m/s. affected by reduced soil moisture content [Santanello et al., 2005]. The Kathmandu Valley has a ratio of vertical relief (altitude difference from the bottom to the rim) to horizontal expanse on the order of 1:30. The basin bottom thus expe- riences very little shading by surrounding mountains, making this mechanism plausible. [21] The second mechanism usually dominates in narrow mountain valleys. Higher slopes receive morning sunlight 10 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 12. West to east vertical cross-section A through the Kathmandu Valley on 10 February 2005, showing the Trisuli River (TR) low tributary valleys west of Kathmandu (WV), the western valley rim peaks (Nagarjun, NJ), the elevated flat basin of the Kathmandu Valley (KV), the eastern valley rim peaks (Nagarkot, NK), and the lower valleys to the east. Color shading and contours in the atmosphere indicate potential temperature; vectors are proportional to wind velocity in the plane of the plot. Vectors displayed in the bottom right of each plot correspond to maximum wind velocity (horizontal, vertical) in each plot: 20 m/s, 23.4dPa/s at 0245 NST; 15.2 m/s, 22.4 dPa/s at 0945 NST, 15.6 m/s, 29.1 dPa/s at 1045 NST, and 16.8 m/s, 37 dPa/s at 1145 NST. first. As the slopes warm up, upslope flows are generated which carry air up from the valley bottom. The air departing from the valley bottom is replenished by the generation of a wind blowing up the river valley. In many places strong winds are found blowing up river valleys during the daytime, while a shallow layer of air blows up sidewalls perpendicular to the valley axes [Atkinson, 1981; Whiteman, 1990; Prévôt, 1994; Li and Atkinson, 1999; Prévôt et al., 2000; Whiteman, 2000]. Up-valley winds driven by the warming of the Mustang Basin have been studied in detail in the Kali Gandaki Valley in northern Nepal [Egger et al., 2000, 2002]. [22] A third mechanism is found in basins and wide valleys [Whiteman, 1982]. Here warming sidewalls generate upslope flows as in the second mechanism. But, rather than generating a replacement flow up the river valley, the air mass leaving the basin bottom is replenished by subsidence overhead. Subsidence heating over the basin center provides additional erosion of the inversion from the top. This mechanism has been observed in basins ranging in size from 1 km [Whiteman et al., 2004b] to several hundred kilometers across [Banta and Cotton, 1981; Kondo et al., 1989; Whiteman et al., 1999; Zhong et al., 2001]. If a basin is wide enough, then the upslope flows and inversion erosion might begin first on the east-facing west side of the basin [Kelly, 1988]. There have also been observations of a hybrid mechanism that combines aspects of the first and the third, whereby the breakdown of the cold air pool 11 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS happens through a combination of thermals rising from a warming surface, as well as subsidence descent over the cold air pool to compensate for the fraction of the air mass traveling up the slopes [Whiteman, 1982]. In complex valleys (and probably also valleys of intermediate size), a combination of the second and third mechanism are also possible [Rotach and Zardi, 2007]. [23] In the fourth mechanism the cold pool is dissipated by turbulent erosion caused by vertical wind shear at the top of the basin, leading to shear-generated turbulence and the penetration of the upper-level wind downward through the cold air pool [Whiteman and Doran, 1993]. This mechanism has been studied in Ljubljana, Slovenia, using MM5 mesoscale model simulations [Rakovec et al., 2002]. The study found that wind speeds aloft must exceed a certain threshold to begin eroding the cold air pool, and must increase over time to be able to completely remove the pool. In some basins, deep persistent temperature inversions can be removed rapidly when cold air advects overhead, reducing the inversion strength [Whiteman et al., 2001; Zängl, 2005]. The authors of a field study in the South Park Basin in Colorado [Banta and Cotton, 1981] describe three wind regimes in the basin: downslope, upslope (both of which take place in narrow valleys as well), and afternoon winds in the same the direction as the wind above the basin (something usually not found in narrow valleys). In the Kathmandu Valley, during the dry season, the prevailing upper-level winds are westerlies. During afternoons the surface winds within the valley are westerlies as well. [24] Figure 12 shows the time evolution of potential temperature and wind vectors over the Kathmandu Valley on a west-to-east cross section during the morning of 10 February 2005. We see evidence for the dominance of the third mechanism described above in the episodes that we modeled: namely, that the inversion breaks up through the combined effect of upslope flows along the valley edge, and subsidence over the valley center. The potential temperature contours in Figure 12 show that on the morning of 10 February 2005, a mixed layer characterized by constant potential temperatures first grew at the valley edge, while the valley center remained stably stratified. A zoomed-in view of the high-resolution model output confirms that the winds near the surface were indeed blowing upslope. The downward dip in potential contours over the valley center seen at 0945 and 1045 NST suggests that wind vectors over the valley center had a downward component. However, to confirm that subsidence took place, we carry out a back-ofthe-envelope calculation. If there were no subsidence, then the air leaving the valley would need to be balanced by inflows through the Bagmati Valley. Assuming a valley circumference of 90 km, an average upslope flow of 3 m/s, and an upslope flow depth of 200 m, we get an outflow of 5.4 107 m3/s. For that to be balanced by inflows through the roughly 2 km2 cross-sectional area of the Bagmati Valley, we would need wind speeds of 27 m/s or 97 km/h! Such winds speeds were not found in our simulations, nor did local residents of the Bagmati Valley ever mention such high wind speeds. A more realistic upper bound on the inflow through the Bagmati Valley of 10 m/s would only provide 2 107 m3/s, leaving 3.4 107 m3/s for subsidence. Over a valley-bottom area of 340 km3 that would give a subsidence rate of 0.1 m/s or about 360 m/h. D21308 [25] By 1145 NST, there was a uniform mixed layer over the valley (the valley-center stratification was gone), but there continued to be higher potential temperatures over the peaks, driving upslope flows, which allowed air parcels reaching the peaks to mix to higher elevations than ones rising straight up from the basin floor. [26] We can conclude that in February in the Kathmandu Valley, the cold pool dissipation is more strongly influenced by the third mechanism described above than by the second mechanism; it appears that during the time studied, winds up the Bagmati Valley played a smaller role in basin air replenishment during morning upslope flows compared to the role played by subsidence over the basin center. [27] Further evidence for upslope flow driven mechanisms was found during time-lapse photography from Hattiban ridge (Figure 13). We found that the fog along the edges of the basin dissipated rapidly, hours before the fog over the center of the basin dissipated. At the time that the fog along the edges was dissipating, strong upslope winds were felt at the camera location. [28] For comparison to our winter findings, Figure 14 shows a cross section at 0945 NST on 11 May 2005. We again see evidence of stronger vertical mixing over the peaks in comparison to the basin center as well as upslope flows; these were found, that day, to initiate the mixed layer growth around the basin perimeter as early as 0700 NST, with a deep mixed layer already existing by 0945 NST. In addition, though, we see in Figure 14 that the land surface over the basin bottom was heating as well, with an unstable near-surface region of higher potential temperature than in the air above. However, this was only seen briefly; by 1015 NST the air over the entire valley was well mixed. The MM5 simulations suggest that in May a hybrid of the first and the third mechanisms controls the growth of the mixed layer. Shortly after dawn, upslope flows begin, at least on sunlit slopes, eroding the nocturnal stable stratification as described in the third mechanism. However, as the Sun rises higher, the basin bottom generates thermals that let the mixed layer grow from below (first mechanism). A likely reason that this mechanism was seen in the May simulation but not in the February simulation is the fact that in February the basin bottom was covered by fog, which reduced the surface heating. A delay in the breakup of a valley inversion in winter was also found in a lidar study in Bulgaria [Savov et al., 2002]. Note that the surface thermals seen in the TV tower data in February (Figure 5) only appear after the morning fog has dissipated. [29] In the episodes modeled, no evidence was found in support of the fourth mechanism (turbulent erosion by winds flowing across the top of the cold air pool) playing a dominant role in the removal of the Kathmandu Valley’s nocturnal inversion. The mechanism would have required us to find the cold pool remaining intact in the basin bottom, while its top was slowly eroded away by winds. [30] The dissipation of the nocturnal cold air pool is not the only factor that affects the growth of the Kathmandu Valley’s daytime mixed layer. If a basin sits at a higher elevation compared to regions outside the surrounding mountains, it can generate thermal circulations similar to what is found on raised plateaus. Plateaus often serve as elevated heat sources [Egger, 1987; Molnar and Emanuel, 1999]. The daytime heating expansion of air columns above 12 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 13. Kathmandu Valley from Hattiban on the morning of 8 December 2005 at (a) 0752 NST and (b) 0830 NST. a plateau and above nearby lowlands results in higher pressure and lower temperature above the lowlands than above the plateau [Gaertner and Fernandés, 1993]. Plateau circulations have been studied in theory by several researchers, including the effects of valleys leading to the plateau [Egger, 1987; Zängl et al., 2001], and the effect of plateau height and the existence of a mountain rim around the plateau [Zängl and Gonzales Chico, 2006]. If there are mountain passes connecting a basin to the low-lying outside regions, as is the case in the Kathmandu Valley, these passes are found to play crucial roles in the circulation. Detailed field and modeling studies of the gap flows taking places at the edges of plateaus and elevated basins have been carried out for the Tibetan Plateau [Egger et al., 2000; Zängl et al., 2001; Egger et al., 2002], the Bolivian Altiplano [Egger et al., 2005; Zängl and Egger, 2005; Reuder and Egger, 2006], and the Mexico City Basin [Doran and Zhong, 2000; de Foy et al., 2006]. 13 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 14. Potential temperature and wind vectors on the same cross section as Figure 17, but at 0945 NST on 11 May 2005. Vectors displayed in the bottom right of the plot correspond to maximum wind velocity: 14.2 m/s horizontal, 99.3 dPa/s vertical. [31] Figure 15 shows a continuation of the time series of MM5 cross sections from Figure 12. We see the arrival into the Kathmandu Valley through the western passes of lower potential temperature air originating above the lower neighboring valleys to the west. Starting from the valley’s western rim, this air spreads across the entire bottom of the Kathmandu Valley in less than an hour. This creates a new stratification that confines the mixing to much lower heights than was possible moments earlier. We thus have an explanation of sodar observations (see part 1), which show that the depth of the mixed layer decreased over the course of the afternoon. [32] A modeling study of diurnal flows through passes leading from the Pacific lowlands to the Bolivian Altiplano also found a density current of cooler air spreading from the pass across the Altiplano as a cold front [Zängl and Egger, 2005]. The winds arriving into the Kathmandu Valley from the west during the afternoon appear to be part of a larger plateau circulation. Earlier researchers calculated a temperature difference of 2.5 K at noon time between air at the valley bottom, and the cooler air at the same elevation above lowlands 60 km to the southwest of Kathmandu [Regmi et al., 2003]. The Iberian Peninsula also experiences a plateau circulation, with an afternoon heat low, and here too a front of cooler air travels in from the plateau edge, pushing underneath the existing boundary layer [Gaertner and Fernandés, 1993]. Similar gravity driven flows have been found in idealized simulations [de Wekker et al., 1998] and in the lee of the Sierra Nevada [Zhong et al., 2008]. Researchers of the plateau circulation at Zugspitzplatt, Germany [Gantner et al., 2003], found air arriving on the plateau from higher elevations, marked by a drop in the dew point. Indeed, our data showed an afternoon drop in dew point in Kathmandu (Figure 4b). Following the isentropes from left to right on Figure 15, we see that the air sweeping through the Kathmandu Valley bottom during the afternoon originated at a higher elevation than the valley. 5. Ventilation Pathways [33] The timing and evolution of the mixed layer in the Kathmandu Valley has an effect on when and how pollutants can be ventilated from the valley. Our second question thus concerns the pathways of the pollutants when they leave the valley. Before looking at model simulations, let us consider some hypotheses of possible pollutant ventilation pathways. [34] The first hypothesis is that the pollutants are ventilated from the Kathmandu Valley because the daytime mixed layer rises above the height of the surrounding mountains, to altitudes where polluted air can flow over the rim mountains. Such behavior has been observed and modeled in Mexico City [Bossert, 1997; Fast and Zhong, 1998]. During the TRACT experiment over the Black Forest in southern Germany, it was found that the altitude of the top of the mixed layer is higher over mountains than over surrounding flat land, and that the mixed layer top rises and falls with the underlying topography [Kalthoff et al., 1998; Kossmann et al., 1998]. In other words, the top of the fully formed mixed layer may be flat over the Kathmandu Valley center, and then rise as one approaches the valley rim mountains, reaching levels higher than the mountain tops. The sodar data indicated a mixed layer height approaching the height of the surrounding mountains even at the valley center, while the temperature logger data indicated well mixed conditions at least up to the height of Nagarkot near the valley’s edge. Once mixed to heights above the surrounding mountains, pollutants can easily be carried eastward by the strong westerly winds that blow parallel to the Himalayas during the dry season [Moore, 2004]. 14 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 15. Continuation of Figure 12, showing potential temperature and wind vectors during the afternoon of 10 February 2005. Vectors displayed in the bottom right of each plot correspond to maximum wind velocity (horizontal, vertical) in each plot: 17.7 m/s, 71.0 dPa/s at 1515 NST; 16.8 m/s, 56. dPa/s at 1545 NST; 15.7 m/s, 73.0 dPa/s at 1615 NST; 14.5 m/s, 90.5 dPa/s at 1645 NST. [35] The second hypothesis is that the pollutants are removed from the valley by flows through mountain passes, with relatively clean air blowing in through the western valley rim passes and polluted air spilling out through the eastern passes. A field study in the South Park basin of Colorado [Banta and Cotton, 1981], found that an inversion in the morning prevented upper-level westerly winds from penetrating to the surface. However, once the inversion was gone the westerlies could reach down to the surface. An idealized modeling study of flows through valleys that terminated at the edge of a plateau [Egger, 1987] (similar to the valleys to the west of Kathmandu Valley that terminate at its western passes) shows that the existence of such valleys enhances the wind intensity above the plateau. Egger [1987] also shows that the up-valley wind intensity in these valleys is determined by the difference in elevation of the plateau heat source (1300 m in the Kathmandu Valley’s case), and the lowland heat source (500– 600 m in the valleys west of Kathmandu). Tracers passing from a lowland area over a mountain ridge into a basin have been studied before [Kimura and Kuwagata, 1993], as have flows through passes and mountain gaps in Athens [Asimakopoulos et al., 1992], Mexico City [de Foy et al., 2006] and the Brenner Pass in the Austrian Alps [Mayr et al., 2002]. In winter, Mexico City regularly experiences a low-level jet exceeding 10 m/s entering the basin through a pass to the southeast [Doran and Zhong, 2000]. Tracer transport modeling has shown that the flow through this pass plays an important role in flushing pollutants out of Mexico City [Bossert, 1997]. A 2003 field campaign studying the diurnal variations in circulation over the Bolivian Altiplano (an elevated plateau surrounded by mountains) carried out vertical soundings at the in-flow passes that found inflow to start a few hours after sunrise, at the time when the stable nighttime layer over the Altiplano had heated sufficiently to become neutrally buoyant [Egger et al., 2005]. [36] The third hypothesis is that pollutants are vented out of the Kathmandu Valley by upslope flows at the valley rim 15 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 16. Lagrangian trajectories released at 0745 NST on 10 February 2005 on a line between 38 km EW 26 km NS and 38 km EW, 46 km NS, (top) shown on a contour map (masl) and (bottom) projected onto a west to east cross section. Green denotes times from 0745 to 1145 NST, red is from 1145 to 1545 NST, orange is from 1545 to 1945 NST, and brown is from 1945 to 2345 NST. mountains, which transport the pollutants into more rapid flows aloft. Thermally driven upslope and up-valley winds have been studied in many places and have been found to be efficient ways of transporting air pollutants from lower altitudes and venting them into fast-flowing upper-level winds. At the Jungfraujoch mountain observatory in Switzerland, pollutants are seen arriving from the valleys during warm summer afternoons [Baltensperger et al., 1997]. Winds blowing up the valleys of the Black Forest mountains have been found to transport tracers out of Freiburg [Kalthoff et al., 2000]. Polluted air has been observed traveling up the Yahagi River valley in Japan [Kitada et al., 1986]. A modeling study of Santiago de Chile found pollutant export above mountain peaks through the convergence of upslope flows [Schmitz, 2005]. Mountains near Phoenix, Arizona, provide sufficient ventilation to the city that there is no multiple-day buildup of ozone from local emission sources [Fast et al., 2000]. Up-valley flows in the Ticino area of 16 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 Figure 17. Same as Figure 16, but for a release time of 1545 NST on 10 February 2005. southern Switzerland have been found to carry pollutants upward from industrial northern Italy to the crest of the Alps [Prévôt et al., 2000]. These flows can transport several times the valley volume over the course of a day [Henne et al., 2004]. [37] We examined ventilation pathways from the Kathmandu Valley using the results of Lagrangian model trajectories for 10 February 2005. The trajectories in Figures 16 –18 were released in the surface layer, along a 20-km north-south line running through the center of the innermost domain (26 km NS, 38 km EW, to 46 km NS, 38 km EW). For visual clarity, release points are only shown at 2-km intervals; these are a small selection of hundreds of trajectories that were examined to draw conclusions. [38] Figure 16 shows trajectories with a release time of 0745 NST. We see that, over the course of the morning, most of the trajectories traveled toward the nearest valley rim slope, before traveling up the slopes to a height of 500– 1000 m above the basin bottom. Then, before 1145 NST they started to travel eastward, crossing the Kathmandu 17 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS D21308 passes during the night, consistent with the strong easterly winds observed at Bhimdhunga Pass during the night [Panday and Prinn, 2009]. It is likely that the drainage winds in the neighboring valleys were also responsible for driving the light easterly winds that were found along the top of the Kathmandu Valley’s cold pool at night and that also were observed in the nighttime sodar soundings. 6. Conclusion Figure 18. Trajectories released at 2345 NST on the same line as in Figures 11 and 12, shown on a contour map (masl). Black denotes time from 2345 to 0345 NST, blue is from 0345 to 0745 NST, green is from 0745 to 1145 NST, red is from 1145 to 1545 NST, orange is from 1545 NST to 1945 NST, and brown is from 1945 to 2345 NST. Valley at high elevation. A closer look at individual tracers shows that upon arriving at the eastern valley rim, trajectories which passed over passes or low ridge regions maintained their altitude, whereas trajectories passing over the eastern mountain peaks experienced a step-like gain in altitude that was driven by the convergence of upslope flows over the mountain tops east of the Kathmandu Valley. [39] Figure 17 shows the trajectories that were released along the north – south line on the valley floor at 1545 NST on 9 February 2005. Most trajectories converged to flow through the Sanga and Nala passes on the eastern valley rim, and a higher pass on the southern valley rim, above the town of Tika Bhairav. Most of the trajectories reached outside of the valley within less than 2 h of their release. They no longer rose to the height of the valley rim peaks. They could not rise as high during the afternoon because the mixed layer had shrunk as a result of the arrival of cooler air from neighboring valleys that formed a lowaltitude afternoon inversion over the Kathmandu Valley, as we saw in section 4. [40] Finally, Figure 18 shows trajectories released at 2345 NST along the same 20 km north – south line. The trajectories originating at the southern end of the Kathmandu Valley traveled down the Bagmati river valley. Most of the trajectories released within the central Kathmandu Valley lingered close to their points of origin. Trajectories released near the western valley-rim passes rose and crossed over the passes, and traveled down the western valleys until the morning, when upslope and up-valley winds carried them back up. In Figure 11a we saw strong nocturnal drainage winds in these western valleys before dawn. The strong drainage winds indicate a sufficient pressure gradient to force some Kathmandu Valley air up and over the western [41] In our field observations of air pollution in the Kathmandu Valley during the dry season of 2004 – 2005, we noted that carbon monoxide, as a tracer of anthropogenic emissions, had a distinct diurnal pattern of morning and evening peaks. In this paper we have described simulations using the MM5 mesoscale meteorological model nested up to 1-km resolution, and verified its ability to capture the local meteorology in the valley as measured during our campaigns. We studied the dynamics of the dissipation of the nighttime cold-air pool and temperature inversion, and the subsequent evolution of the daytime mixed layer. We concluded that the cold pool dissipation was dominated by the mechanism of upslope flows along the valley rim mountains, accompanied by subsidence over the basin center. In addition, during fogfree days there was erosion of the inversion from below by the growth of thermals forming over a warming surface. The Kathmandu Valley’s mixed layer height peaked around noon, and then decreased again over the course of the afternoon. This pattern was explained using MM5 simulations that showed gravity-driven flows penetrating into the basin bottom through the western mountain passes. These brought air that originated above lower-lying terrain to the west of the valley that was cooler and denser than the air found over the Kathmandu Valley in the late morning. The Kathmandu Valley thus exhibited an afternoon circulation pattern similar to what had been found on plateaus elsewhere in the world. [42] Using forward trajectories released in the MM5 flow fields, we found that the dominant pathway of pollutant ventilation depends upon the time of day. On the February day investigated, we found that during the morning, tracers were advected out of the valley by transport up the slopes of the valley rim mountains, and from there they were carried east by the upper-level westerly winds. During the afternoons, tracers were found to be removed from the valley at a faster rate through the mountain passes, both to the east and to the south. During the night, some tracers near the Bagmati River were advected out down the river valley, and near the western passes some tracers were able to escape from the Kathmandu Valley through drainage flows. [43] Our extensive new observations and numerical modeling add significantly to the current understanding of the valley’s atmospheric dynamics and air pollution meteorology. The Kathmandu Valley’s air quality is strongly affected by the wind systems generated by the surrounding topography. Our study has several implications for air quality policy in the Kathmandu Valley. It points to the fact that the timing of emissions is key. If the evening rush hour takes place before sunset, as it does in summer, its emissions are ventilated out of the valley before the cold pool sets in. If the rush hour takes place after sunset (as it does in winter), it is responsible for much higher pollution levels 18 of 20 D21308 PANDAY ET AL.: KATHMANDU VALLEY MODELING RESULTS in the evening. As discussed in detail in part 1 [Panday and Prinn, 2009], these pollutants are lifted up, but recirculated in the morning, adding to the morning pollution. The Kathmandu Valley also appears to be a rather unsuitable place for combustions sources that operate 24 h a day, such as the brick kilns on the outskirts of the city. Emissions that take place outside of the well ventilated midday and afternoon hours contribute much more to air pollution in Kathmandu than would emissions that are restricted to wellventilated time periods. Designing an effective air pollution control strategy for the Kathmandu Valley thus requires careful consideration of the pollution diurnal cycle, and time-dependent restrictions on polluting activities. [44] Acknowledgments. 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