Sustainable Reuse of Treated Wastewater for Agriculture Ahmed Al-Busaidi, Mushtaque Ahmed and Baby Shaharoona College of Agricultural & Marine Sciences, Department of Soils, Water and Agricultural Engineering, Sultan Qaboos University, P.O. Box 34, Al-Khoud123, Muscat, Oman ahmed99@squ.edu.om Global Water Resources • World population food production limited fresh water resources Municipal Wastes Management 3R Approach Water Balance (Deficit- Excess) Water Balance in the Sultanate (MCM/Yr) 390 1267 Supply Demand 1657 Deficit Wastewater Treatment Plants > 402 Muscat STP water 5 PARAMETER Inorganics Standards for Wastewater Reuse (mg/l) Limitations: Contains some Heavy Metals Monitoring is Required Aluminum (as Al) Arsenic (as As) Barium (as Ba) Beryllium (as Be) Boron (as B) Cadmium (as Cd) Chloride (as Cl) Chromium (total as Cr) Cobalt (as Co) Copper (as Cu) Cyanide (total as CN) Fluoride (as F) Iron (total as Fe) Lead (as Pb) Lithium (as Li) Magnesium (as Mg) Manganese (as Mn) Mercury (as Hg) Molybdenum Nickel (as Ni) Ammonical (as N) Nitrate (as NO3) Phenol (total) Phosphorus (total P) Selenium (as Se) Silver (as Ag) Sodium (as Na) Sulphate (as SO4) Sulphide (total as S) Vanadium (as V) Zinc (as Zn) STANDARDS Class A 5 0.100 1 0.100 0.500 0.01 650 0.050 0.050 0.500 0.050 1 1 0.100 0.070 150 0.100 .001 0.010 0.100 5 50 0.001 30 0.020 0.010 200 400 0.100 0.100 5 Class B 5 0.100 2 0.300 1 0.010 650 0.050 0.050 1 0.100 2 5 0.200 0.070 150 0.500 0.001 0.050 0.100 10 50 0.002 30 0.020 0.010 300 400 0.100 0.100 5 Date palms in Oman واﻗﻊ زراﻋﺔ اﻟﻨﺨﻴﻞ ﻓﻲ اﻟﺴﻠﻄﻨﺔ الترتيب المحافظة/المنطقة Area عدد النخيل * No. of Date palms متوسط انتاج النخلة )كجم( )X (Kg كمية انتاج التمر )طن( )Pro. (Ton النسبة المئوية لالنتاج % 1 محافظة مسقط A 11573.92 34.17 338674 4.42 2 منطقة الباطنة B 111407.06 39.55 2817190 42.55 3 محافظة مسندمC 4521.00 31.31 144381 1.73 4 منطقة الظاھرة D 27136.37 49.29 550545 10.36 5 المنطقة الداخلية E 54497.28 57.22 952428 20.81 6 المنطقة الشرقيةF 43878.51 31.41 1397010 16.76 8 محافظة ظفارG 7 محافظة البريمي H 132.43 8704.10 6.19 21388 0.05 32.84 265012 3.32 6486628 40.37 261850 100.00 المجموع Total Result and discussion Heavy metals translocations in location 1 12 10 Mn GW Fe 12 10 4 Conc. (mg/l) Conc. (mg/l) 6 Cu Cr Cd Pb 8 6 Cu Cd Pb Ni 2 Zn Cr 4 2 B TWW Fe Zn 8 Mn Ni B 0 0 Soil Plant leaves Plant fruits Sample location Soil Plant leaves Plant fruits Sample location Result and discussion Heavy metals translocations in location 2 14 Conc. (mg/l) 10 8 6 GW Mn Fe Zn Cu Cr Cd Pb Ni B 45 40 35 Conc. (mg/l) 12 50 4 2 TWW Mn Fe Zn Cu 30 25 Cr Cd 20 Pb 15 Ni 10 B 5 0 0 Soil Plant leaves Sample location Plant fruits Soil Plant leaves Sample location Plant fruits Result and discussion Heavy metals translocations in location 3 12 Conc. (mg/l) 10 8 6 4 2 Mn Mn GW 8 Fe Zn 7 Zn Cu 6 Cu 5 Cr Fe Conc. (mg/l) 14 Cr Cd Pb Ni B Cd Pb 3 Ni 2 B 1 0 Soil 4 TWW Plant leaves Plant fruits Sample location 0 Soil Plant leaves Plant fruits Sample location Wheat Irrigated by Treated Wastewater Result and Discussion Plant parameters as affected by different irrigation methods and water qualities 40 35 FW Furrow FW Drip TW Furrow TW Drip 30 Value 25 20 15 10 5 0 Height (cm) Spike Length (cm) 1000 Grain Weight (g) Spike Yield (t/ha) Biological Yield Straw Yield (t/ha) (t/ha) Plant parameter Result and Discussion Nutrients (mg/L) present in wheat grains variables FW Furrow FW Drip TW Furrow TW Drip Na Ca Mg K Zn Cu Mn Fe Cd Ni Si 0.47 105.56 34.28 10.29 0.24 0.11 1.10 0.81 0.06 0.27 0.06 0.14 105.80 35.88 4.57 0.17 0.14 0.66 0.76 0.08 0.49 0.07 1.342 109.25 39.43 8.90 0.21 0.11 0.74 0.81 0.09 0.27 0.06 0.78 104.60 35.41 9.14 0.10 0.10 0.68 0.71 0.06 0.27 0.05 Conclusion: * Wheat can be irrigated by treated wastewater * More Studies are needed Mitigating Environmental Risks of Wastewater Reuse for Agriculture Vegetables irrigated by Treated Wastewater, Groundwater amd Mix of both Waters 1st Season Result and discussion Soil chemical properties 0.4 50% TWW 100% GW 75% TWW 100%TWW 0.35 Concentration 0.3 0.25 0.2 0.15 0.1 0.05 0 Fe B Ba Pb Micro element Co Cr 1st Season Result and discussion 1st Season Result and discussion Crop physical properties Maize Weight (g) Okra Weight (g) 1800 16 1600 14 1400 12 10 1000 Weight Weight 1200 800 8 6 600 4 400 2 200 0 0 50% TWW 100% GW 75% TWW Treatment 100%TWW 50% TWW 100% GW 75% TWW Treatment 100%TWW 1st Season Result and discussion Crop chemical properties maize 3 2 50% TWW 1.5 100% GW 1 75% TWW 100%TWW 0.5 0 Mn Cd Cu Fe Zn B Al Ba Cr Co Pb Ni Concentration Concentration 2.5 sweet corn 1.800 1.600 1.400 1.200 1.000 0.800 0.600 0.400 0.200 0.000 50% TWW 100% GW 75% TWW 100%TWW Mn Cd Cu Fe Zn Ti okra 3.5 50% TWW 100% GW 75% TWW 100%TWW 0.5 Concentration Concentration 2 1 Ba Cr Co Pb Ni Ti Sweet melon 3 1.5 Al Micro element Micro element 2.5 B 2.5 50% TWW 2 100% GW 1.5 75% TWW 1 100%TWW 0.5 0 0 Mn Cd Cu Fe Zn B Al Ba Cr Co Pb Ni Micro element Ti Mn Cd Cu Fe Zn B Al Ba Micro element Cr Co Pb Ni Ti Mitigating Environmental Risks of Wastewater Reuse for Agriculture 3rd Season In Progress Knowledge Gaps Studies on plant uptake of PPCPs are few and small in scale. Most studies were carried out under hydroponic or greenhouses conditions. Accumulation of PPCPs in vegetables irrigated with treated wastewater under field conditions is unknown. In Progress In Progress Usage of Treated Wastewater for Bio-fuel Production Definition of Biofuels fuels derived from biomass: plant material, crop energy, or agricultural and forestry wastes and byproducts used as energy source. Examples Sunflower oil Coconut oil Palm oil Rapeseed oil Why use Biofuels Fossil fuel: Limited Carbon dioxide Production Rural economy Bio-fuel: Renewable, Biodegradable Efficient Engine Friendly Healthier Carbon Neutral Job generation Global warming Converting food crops into biofuel “is a crime against humanity.” SO What to do?!!! What Is Jatropha (a biofuel crop)? Jatropha (Jatropha Curcas) is an excellent biofuel crop which has many other advantages over existing crops. The hardy Jatropha is resistant to drought and pests, and produces seeds containing up to 40% oil. When the seeds are crushed and processed, the resulting oil can be used in a standard diesel engine, while the residue can also be processed into biomass to power electricity plants. Growth of Jatropha after transplanting (Winter Time) Treated wastewater freshwater saline water (3 dS/m) Thank You