2012-2013 ANNUAL REPORT Facts at a Glance Tenure-Track Faculty FTE Teaching Faculty FTE Undergraduate Students 2012-2013 Highlights 12 2 156 Drexel Materials Researchers Develop Materials to Improve Battery Technology Distinguished University & Trustee Chair Professor Yury Gogotsi, A. W. Grosvenor Professor Michel Barsoum and colleagues are the first to report successful intercalation of MXenes with several organic molecules, creating a flexible and electrically conductive “paper” showing a lithium ion capacity of four times that of typical MXene material. M.S. & B.S./M.S. Students 42 Ph.D. Students 68 Li Elected Fellow of the American Physical Society Ph.D. Awarded (12-13) 10 M.S. Awarded (12-13) 18 Professor Christopher Li was recommended for Fellow by the Division of Polymer Physics. The election to Fellowship in the American Physical Society is limited to no more than one half of one percent of the membership and is recognition of a scholar’s outstanding contributions to the field of physics. B.S. Awarded (12-13) 19 Research Expenditures $5.5M Refereed Journal Publications 110 Five National Fellowship Awardees Five Materials students have received prominent national fellowship awards this year, including a Barry Goldwater Scholarship, the Department of Defense Science, Mathematics, and Research for Transformation (SMART) Scholarship, a Fulbright Scholarship, and two National Science Foundation Graduate Research Fellowships (NSF GRFP). Alumni Appointed to Faculty Positions Two recent Ph.D. alumni have been appointed to faculty positions at Ohio State University and University of Massachusetts Amherst. Barsoum, Gogotsi, with Students and Colleagues Win ACerS 2013 Ross Coffin Purdy Award This award is given to the author(s) “judged to have made the most valuable contribution to ceramic technical literature during the calendar year prior to the selection.” The ACerS Board unanimously approved the award subcommittee’s selection of Barsoum and Gogotsi et al. 11 15 15 20 24 Letter from the Department Head 2012 -2013 has been marked by growth, particularly in our faculty and student ranks. Not only have we grown in numbers, but we have also continued to increase the quality of our people and, with that, the level of our accomplishments. The result is an enthusiasm that punctuates all aspects of our department. This September we welcomed two new assistant professors. Dr. Garritt Tucker (Ph.D. Georgia Tech, Postdoc Sandia National Lab) is an expert in structure/ property relationships and the behavior of materials in extreme environments with atomistic simulations. Dr. Ekaterina Pomerantseva (Ph.D. Moscow State University, Postdoc University of Maryland) will enhance our strength in solid state chemistry and energy storage solutions. Leslie Anastasio has also joined our staff as Operations Manager in a new job share position with Dorilona Rose, a first for Drexel. 4 Our established faculty have set a good example for the newcomers. Dr. Christopher Li has been elected Fellow of the American Physical Society. This brings the number of Fellow elections in the department to 12. Drs. Michel Barsoum and Yury Gogotsi and colleagues received the 2013 Ross Coffin Purdy Award for their article “Two-Dimensional Transition Metal Carbides” published in ACS Nano. This award is given to the author(s) “judged to have made the most valuable contribution to ceramic technical literature during the calendar year prior to the selection.” The work of Dr. James Rondinelli has appeared in the Journal of the American Chemical Society and Advanced Materials, and an article on the Materials Genome Initiative (MGI) is set to appear in The Bulletin of the American Ceramic Society. Drs. Steven May and Jason Baxter, affiliated faculty member in the Department of Chemical and Biological Engineering, have been awarded a $380,000 grant from the National Science Foundation (NSF) for “Photoexcited Carrier Dynamics in Oxide Semiconductors for Photovoltaics.” The department has received another Department of Education Graduate Assistance in Areas of National Need (GAANN) award, led by Dr. Michele Marcolongo, myself, and Dr. Caroline Schauer. GAANN BIOMSE: Innovative Biomaterials is an award that provides funding to doctoral students majoring in materials science and engineering with a focus on biomaterials. The research from our faculty and their groups have also appeared on several journal covers including Macromolecules (Professor Christopher Li and Ph.D. student Eric Laird), Advanced Healthcare Materials (Dr. Yury Gogotsi, former research professor Volker Presser, and former postdoc Sun-Hwa Yeon), and Journal of Applied Physics (Dr. Mitra Taheri, Ph.D. candidates Christopher R. Winkler and Michael L. Jablonski, and colleagues from the University of Illinois, Urbana-Champaign). We announce that two of our recent Ph.D. alumni have received academic positions. Dr. Stephen Nonnenmann (Ph.D. 2010; advisor: Jonathan Spanier) joins the Department of Mechanical and Industrial Engineering at the University of Massachusetts—Amherst and Dr. Stephen Niezgoda (Ph.D. 2010; advisor: Surya Kalidindi) joins Ohio State University with a joint position in the Departments of Materials Science & Engineering and Mechanical and Aerospace Engineering. With the addition of these alumni academic positions, 27% of our Ph.D. graduates from 2006-2010 are now faculty members in academia. Our undergraduate class in September 2013 is expected to reach 156 students, an all time high, and the quality of our students continues to be the highest in the College of Engineering. Our incoming class had the highest GPA, SAT, and ACT averages among the incoming classes compared to all other departments within the College of Engineering. Our students successfully compete for the most coveted national scholarships. This year we had five students receive prestigious national awards. Amanda Pentecost (advisor: Yury Gogotsi) and Derrick Smith (advisor: Christopher Li) have received NSF Graduate Research Fellowships and are both continuing their Ph.D. studies at Drexel. Matthew Hartshorne (advisor: Mitra Taheri) has received the DoD SMART scholarship. Sarah Lightfoot Vidal (advisor: Michele Marcolongo) is a recipient of a Fulbright Scholarship. Emily Buck (advisor: Caroline Schauer) is the first Drexel Materials student to receive a Barry Goldwater Scholarship. We continue to bring the joys of materials science and engineering to a larger community. This year marked our third offering of Philly Materials Science and Engineering Day. Presented in conjunction with the University of Pennsylvania and in partnership with the Franklin Institute, among other organizations, an unprecedented 2,000 visitors of all ages and backgrounds came to experience talks, demos, and interactive activities. I invite you to join us on Saturday, February 1, 2014 for more materials science fun. It should be noted that this past year marks Professor Surya Kalidindi’s departure to join Georgia Tech. Surya served as the materials department head from 2001 to 2007 and subsequently became department head in Mechanical Engineering and Mechanics. I would like to thank Surya for his service to both our department and Drexel and wish him all the best in his new position. Finally, I will be stepping down as Department Head on December 31 and will pass the baton to Professor Michele Marcolongo. These past 6.5 years of my tenure have been tremendously rewarding. My sincere thanks to this truly special group of faculty, staff, students, and alumni. You have made this post an enjoyable one! I am extremely proud to have served this extraordinary group of people and look forward to what is to come. Antonios Zavaliangos, Ph.D. Department Head and Professor 5 Materials Science & Engineering Faculty Michel W. Barsoum Steven May Ph.D., Massachusetts Institute of Technology A.W. Grosvenor Professor Hao Cheng Ph.D., Northwestern Univ. Assistant Professor Ekaterina Pomerantseva* Ph.D., Northwestern University Assistant Professor Ph.D., Moscow State University Assistant Professor Yury G. Gogotsi James Rondinelli Ph.D., Kiev Polytechnic, UA Distinguished Univ. & Trustee Chair Prof. Richard Knight Ph.D., University of California, Santa Barbara Assistant Professor Caroline L. Schauer Ph.D., Loughborough, UK Assoc. Dept. Head, Teaching Prof. Christopher Y. Li Ph.D., SUNY Stony Brook Associate Professor Wei-Heng Shih Ph.D., University of Akron Professor Ph.D., Carnegie Mellon University Hoeganaes Assistant Professor of Metallurgy Garritt Tucker* Ph.D., Georgia Institute of Technology Assistant Professor Christopher Weyant Ph.D., Northwestern University Associate Teaching Professor Antonios Zavaliangos Ph.D., Massachusetts Institute of Technology Department Head and Professor * Arrived in FY 2013—2014 Mohammad A. Islam Ph.D., Columbia University Research Assistant Professor Vadym Mochalin Ph.D., National Academy of Sciences of Ukraine Research Associate Professor Alessia Polemi Ph.D., University of Siena Research Assistant Professor Katsiaryna Prudnikova Ph.D., University of Virginia Research Assistant Professor Assoc. Prof., Chemical & Biological Engineering Yossef Elabd Professor, Chemical & Biological Engineering Adam Fontecchio Professor, Electrical & Computer Engineering Alexander Fridman J. S. Nyheim Chair Prof., Mech. Engr. & Mech. Haviva Goldman Assoc. Professor, Neurobiology and Anatomy Kenneth K. S. Lau Ph.D., Columbia University Associate Professor RESEARCH FACULTY Jason Baxter Asst. Prof., Mechanical Engr. and Mechanics Jonathan E. Spanier Ph.D., Univ. of Pennsylvania Professor AFFILIATED FACULTY E. Caglan Kumbur Ph.D., Ohio State University Professor Michele Marcolongo 6 Mitra Taheri Assoc. Prof., Chemical & Biological Engineering Bahram Nabet EMERITUS FACULTY Roger Corneliussen Roger D. Doherty Ihab Kamel Jack Keverian Alan Lawley Fellow of the National Academy of Engineering Professor, Electrical and Computer Engineering Giuseppe Palmese Department Head, Chemical & Bio. Engr. Wan Young Shih Associate Professor, Biomed. Engr. & Health Sys. Karl Sohlberg Associate Professor, Chemistry Margaret Wheatley John M. Reid Prof., Biomed. Engr. & Health Sys. Dr. Ekaterina Pomerantseva Joins Department in September 2013 Dr. Ekaterina Pomerantseva joins the Department in September 2013 as Assistant Professor. Prior to coming to Drexel, Dr. Pomerantseva was a postdoctoral research associate in the MEMS Sensors and Actuators Laboratory (MSAL), led by Professor Reza Ghodssi, at the University of Maryland, College Park. She worked in the area of micro-/nanoelectromechanical systems (MEMS/NEMS) with a focus on microdevices for energy storage, including the development of three-dimensional hierarchical electrodes for lithium-ion microbatteries and a platform for in situ measurement of electrochemical reaction induced mechanical changes in lithium-ion battery electrodes. She received a Ph.D. degree in 2007 from Moscow State University (Moscow, Russia) where she also did her undergraduate studies at the Department of Materials Science. She explored the world of functional materials through research conducted under the supervision of Professor Eugene Goodilin. Her research interests involved high temperature superconductors, materials with colossal magnetoresistance, catalysts, ionic conductors, and cathodes for lithium batteries. The latter became her major interest during the year and half that she stayed at Moscow State University as a junior researcher. In 2009-2010 she worked as a postdoctoral fellow with Professor Linda Nazar at the University of Waterloo (Waterloo, Canada), where she fabricated and studied the electrochemical behavior of electrodes for lithium-oxygen batteries. At Drexel, Dr. Pomerantseva’s Materials Electrochemistry Group will develop novel nanostructured materials and architectures for high performance electrochemical energy storage, with particular interest in exploring emerging directions such as hybrid supercapacitors, metal-air batteries and multivalent intercalation systems. Dr. Pomerantseva strives to develop long lasting, yet compact and safe, next generation power sources. With a focus on fundamental science, her work will contribute to developing new energy storage technologies with improved efficiency and better stability. 7 Materials In Action Materials Science & Engineering Staff Department Staff Leslie Anastasio Operations Manager Sarit Kunz Academic Program Coordinator Yenneeka Long Business Manager Andrew Marx Keiko Nakazawa Materials Program Manager Dorilona Rose Operations Manager Adam Weiss Technology Support Coordinator Systems Administrator Drexel Nanotechnology Institute (DNI) Jill Buckley Business Coordinator Michelle Sipics Education and Outreach Coordinator Core Facilities Dmitri Barbash Research Scientist, XPS & XRD Manager Ed Basgall Manager, Scanning Electron Microscopy Sahar Javedani Associate Director, Core Facilities and Special Projects Craig Johnson Manager, Transmission Electron Microscopy 8 Materials Becomes First Drexel Department to Implement Job Sharing Arrangement Drexel Materials welcomes Leslie Anastasio, who joined the staff in November 2012 as Co-Operations Manager with Dorilona Rose in Drexel University’s first ever job sharing arrangement. Leslie and Dorilona, who has been with the department since 2002, both work half time, splitting the work week and sharing responsibility for communications, outreach, development, and special projects for the department. “We were pleased to be able to put into place the first official Job Share Work Arrangement within the Department of Materials Science and Engineering,” shares Nadia McCrimmon, Executive Director in Human Resources. “The Flexible Work Arrangement policy was created to assist employees with maintaining a work-life balance. Job share is one of four options that employees may request as a flexible work arrangement.” “With the success of the job share within Materials Science and Engineering, we hope that other departments will use this experience as an example of how successful the Flexible Work Arrangements can be with their employees.” Leslie graduated Magna Cum Laude from Macalester College in 1993 and came to Drexel Materials with close to 20 years of experience in nonprofit managem e n t , communications, planning, and fundraising. Her past roles have included Project Manager, Administrative Manager, Public Affairs Director, and Executive Director for organizations providing youth services, protecting women’s rights, and creating affordable housing. When not at work, Leslie enjoys spending time with her husband, Vern, and children Jake (10 yrs.) and Elizabeth (8 yrs.), drawing, playing the piano, and running. Professor Hao Cheng’s Nanobiomaterials and Cell Engineering Laboratory Develops Biomaterials for Unmet Medical Needs Materials that interact with biological systems have changed the landscape of medicine. From blood Dr. Hao Cheng in the dialysis tubing Nanobiomaterials to implantable and Cell Engineering medical devices Laboratory (NCEL). to tissue regeneration scaffolds to drug delivery nanoparticles, biomaterials find their applications in a broad range of diseases. Thanks to a growing understanding of the structure-property relationship of biomaterials and cell-materials interactions, the development of biomaterial products to improve human health care is increasing at a rapid pace. Assistant Professor Hao Cheng and his students in the Nanobiomaterials and Cell Engineering Laboratory (NCEL) work at the interface of materials science and medicine, spanning fundamental studies to translational research. The NCEL group aims to understand nanomaterial-cell interactions at a molecular level and apply this knowledge in creating new biomaterials for disease therapy. One major research thrust of the NCEL group is the development of cell membrane-derived nanoparticles as drug carriers for the treatment of inflammation-related diseases including cancer and cardiovascular disease. Nanoparticles less than 200nm in size can alter the pharmacokinetics and toxicity of encapsulated drugs in ways that improve efficacy and reduce side-effects. So far there are about a dozen FDA-approved nanomedicines, used mostly for cancer therapy because leaky tumor vasculature and impaired lymphatic drainage allow nanoparticles to passively accumulate in tumors. The low efficiency of targeting, however, represents a bottleneck to advance nanomedicines into clinical applications. Currently, nanoparticles are mostly made of polymers or lipids which are quickly cleared by phagocytes in the liver and spleen of patients after systematic administration since these nanoparticles are recognized by phagocytes as “foreign” bodies. The NCEL group utilizes the membranes of circulating cells, such as red blood cells (RBCs) and white blood cells (WBCs), as the materials to fabricate nanoparticles. Particles derived from patient RBC or WBC membranes are expected to be recognized as “self” by immune systems. Reduced clearance will extend particle circulation time and increase the chance that nanoparticles accumulate in diseased tissues. Nature has its own mechanism to deliver cells to targeted locations, for example leukocytes homing to inflammatory tissues. The NCEL group is developing intelligent nanoparticles which harness the cell homing process to target inflammatory tissues. This strategy requires the proper control of nanoparticle-cell RBC membrane-derived nanoparticles (MNP). A) Schematic illustration of MNP fabrication using chemically modified cell membranes. B) Phase contrast image of RBCs. C) Representative confocal image of RBCs which were engineered on membranes with fluorescently labeled peptide. D) Representative transmission electron microscopy image of negatively stained MNP. 9 Materials In Action interactions. To this end, the NCEL group uses a cell membrane engineering technique, initially developed by Prof. Hao Cheng, to modify the membranes of RBCs with peptides targeting inflamed blood vessels and circulating cells at the same time, enabling the conjugation of peptides/ proteins onto stem cell membranes without affecting cell viability, proliferation or multipotency. The modified RBC membranes are then isolated and fabricated into nanoparticles to deliver drugs into tumors and atherosclerotic plaques. The NCEL group also investigates the effect of binding kinetics on nanoparticle cell interactions, which are subject to change under fluid shear force. In spite of the extensive study of nanobiomaterials, Transmission electron image of a-MEGO. Image taken by Dr. Eric Stach of Brookhaven National Lab. 10 investigation of the kinetics of nanoparticle-cell interactions has been rare and may lead to significant findings to modulate cellular functions. Stem cells can self-renew and differentiate into specialized cell types under proper stimulation, and have become the cornerstone of regenerative medicine, promising to address many unmet medical needs. One of the major hurdles to using stem cells for tissue regeneration is the low efficiency of homing and engraftment of stem cells in diseased tissues. The second research area of the NCEL group is to engineer stem cells with non-genetic methods to enhance cell homing to inflammatory tissues where regeneration is needed. Non-genetic engineering methods circumvent the safety issues associated with genetic modification of cells. The NCEL group is optimizing a chemical modification method, which showed promising results in vivo, and developing new methods using nanotechnology to further increase the availability of stem cells to diseased tissues. In addition to the potential for increased targeting, the engineered cells are expected to reside in a microenvironment more suitable for regeneration than unmodified cells, as the engineered cells recognize the diseased tissues at a molecular level. The NCEL group strives to integrate materials science with biology to develop novel biomaterials. Their research is poised to benefit human life. Nanomaterials Group Collaboration Breaks Low Temperature Energy Storage Record Distinguished University and Trustee Chair Professor Yury Gogotsi, members of the Nanomaterials Research Group, and collaborators at University of Texas at Austin and the Paul Sabatier University in Toulouse, France have engineered an electrolyte supercapacitor system that can store a large amount of energy at extremely low temperatures. Recently featured in the journal Nano Energy, this research suggests a vastly improved alternative to current systems that power technology at very low temperatures, which require oversized batteries that have a very low efficiency and short lifetime. Anyone who has tried to start a vehicle on a very cold day understands that low temperatures adversely affect engine performance. This is in part because cold temperatures thicken motor oil, requiring extra energy to get engine parts moving, and because the battery’s ions are slowed by the cold, causing the battery to operate at very low efficiency. In the supercapacitor system developed by Nanomaterials Group researchers and their collaborators, a unique carbon nanomaterial, activated microwave exfoliated graphite oxide (a-MEGO), was combined with a eutectic mixture of ionic liquids. The a-MEGO has a high surface area and allows for a large amount of charge to be stored capacitively on its surface, while the mixture of ionic liquids has a very low melting point and a wide voltage stability window. This supercapacitor system delivers the most energy at a low temperature of -50 °C (-58 °F). Commercial supercapacitors, by comparison, use an electrolyte that will fail at temperatures below -25 °C (-13 °F). Additionally, supercapacitors will last for more than 10 years and up to 1 million charge/ discharge cycles, compared to batteries that will last a couple years for about 1 thousand cycles. This study reinforces the potential of graphene in energy storage applications, but also demonstrates that only the right combination of an electrode material and an electrolyte leads to truly outstanding performance. This opens the door to development of even better supercapacitors using safe and non-flammable ionic liquid electrolytes. Drexel Materials Researchers Develop Materials to Improve Battery Technology Members of Drexel Materials’ Nanomaterials and MAX Phase Research Groups recently reported on the discovery of a new family of two-dimensional materials called “MXenes.” The materials’ structures are similar to graphene, with which they share many properties, including good electrical conductivity and potential applications in energy storage. Now, in a Nature Communications article titled “Intercalation and Delamination of Layered Carbides and Carbonitrides,” Professors Yury Gogotsi, Michel Barsoum, and colleagues have demonstrated several new possible avenues for practical applications of MXenes. MXenes are transition metal carbides and nitrides, created by selectively removing aluminum from layered ternary carbides known as MAX phases. Through this exfoliation process, the carbide layers are separated into two MXene sheets just a few atoms thick. MXenes can accommodate various ions and molecules between their layers by a process known as intercalation, which is sometimes a necessary step in order to exploit the materials’ unique properties. For example, placing lithium ions between MXene sheets has been shown to render them promising materials for both lithium-ion batteries and electrochemical capacitors. Computational studies have suggested that fully exfoliating, or delaminating, certain MXenes would yield layers with exceptional charge capacities for use in battery anodes. To date, however, large-scale delamination had not been achieved. In “Intercalation and Delamination of Layered Carbides and Cabonitrides,” the Drexel Materials team reports on successful intercalation of MXenes with several organic molecules, including dimethyl sulfoxide (DMSO), which allowed them to fully exfoliate stacked layers into MXene sheets and ultimately create MXene “paper” by filtering flakes from solution. This flexible and electrically conductive “paper” showed a lithium ion capacity of four times that of typical MXene material, with extremely high charging rates and a cyclability superior to graphite, which is used in commercial lithium-ion batteries. Critically, this work demonstrates that such material can be synthesized on a large scale. Hydroxyl terminated MXene Ti3C2 with monolayers of hydrazine molecules between the MXene layers. Intercalation reactions, like the one shown, establish MXenes as full-fledged members of the growing family of 2D materials. Image credit: Vadym Mochalin 11 Excellence in Scholarship Master of Science in Materials Science and Engineering Doctor of Philosophy in Materials Science and Engineering Lucas Amspacher Matthew Hartshorne Denis Madende Brian Beatty Nasreen Khan Ian McDonald Pietro Bonato Andrew Lang Amanda Pentecost Guannan Chen Hang Kuen Lau Thomas Richards Robert Coward Sarah Lightfoot Vidal Nathan Wald Robert Devlin Travis Longenbach Hanqi Wu Bachelor of Science in Materials Science and Engineering Ioannis Neitzel “Development and Characterization of a Chemically Crosslinked Polyvinyl Alcohol/Polyethylene Glycol Hydrogel for Injectable Nucleus Pulposus Replacement” “Magnetoelectricity in Individual Multi-component Nanowires” “Nanodiamond-Polymer Composites” Supervising Professor: Jonathan Spanier Current position: Development Engineer; Hella; Lippstadt, Germany Supervising Professors: Michele Marcolongo and Anthony Lowman Current position: Postdoctoral Researcher; Rowan University; Glassboro, NJ Xi Chen “Design, Synthesize and Characterize Hierarchically Ordered Nanofibers (NFSKs) for Biomimetic Mineralization” Yen-Ming Lu Lucas Amspacher (Summa Cum Laude) Ian McDonald Brian Beatty (Cum Laude) Amanda Pentecost (Magna Cum Laude) Alicia Busenius-Kriete Elizabeth Poyss Robert Coward Amalie Elizabeth Donius Brittany Preston Utku Guclu Bryant Richardson Nasreen Khan (Cum Laude) Ebony Thompson “Structure-Property-Processing Correlations in Chitosan-based Porous Hybrid Materials” Sarah Lightfoot Vidal Travis Longenbach (Cum Laude) 12 Stephanie Howell Johnson Jonathan Andrus Andrew Lang Congratulations to the Class of 2013! Valerie Regina Binetti Ashley Moretti Supervising Professor: Christopher Y. Li Current position: Postdoctoral Researcher; Johnson & Johnson; Skillman, NJ Elizabeth Toby Supervising Professors: Antonios Zavaliangos and Ulrike G.K. Wegst Nathan Wald (Summa Cum Laude) Current position: Postdoctoral Researcher; Oral Biology, School of Dental Medicine, University of Pittsburgh; Pittsburgh, PA Current position: Applications ScientistGeotech; Croda (Specialty Chemicals); DE Marjorie Austero Kiechel “Post-processing of Electrospun Chitosan Fibers” Supervising Professor: Caroline L. Schauer Current position: Visiting Researcher; Natural Polymers and Photonics Laboratory, Drexel University; Philadelphia, PA Nina Jeong Lane “Lattice Dynamical Studies of Select MAX Phases” Supervising Professors: Michel Barsoum and James Rondinelli Current position: Rotation Engineer; Intel Corporation; Mountain View, CA Supervising Professor: Yury Gogotsi Carlos Perez “High Power Electric DoubleLayer Capacitors based on RoomTemperature Ionic Liquids and Nanostructured Carbons” Supervising Professor: Yury Gogotsi Current position: Postdoctoral Fellow; Bonnell Group, University of Pennsylvania; Philadelphia, PA Riju Mohan Singhal “Carbon Nanotube Based Devices for Intracellular Analysis” Supervising Professor: Yury Gogotsi Current position: Applications Engineer; CVD Equipment Corporation; Central Islip, NY Oren David Leaffer “Photoluminescence and Resonance Raman Spectroscopy of MOCVD Grown GaAs/AlGaAs Core-Shell Nanowires” Supervising Professor: Jonathan Spanier 13 Excellence in Scholarship Drexel Material Advantage Students Visit Washington D.C. to Advocate for STEM Education Every April, materials students from around the country converge in Washington, On April 11th, Gregory, Boris, Ziyin, and Drexel Mechanical Engineering D.C. for Congressional Visits Day. Organized by Material Advantage, the student & Mechanics undergraduate Daniel Diazdelcastillo teamed up with Carnegie professional organization, Congressional Visits Day is designed to raise visibility Mellon undergraduate Lauren Jellison to visit the offices of legislators from across and support for science, technology, engineering, and mathematics (STEM). Pennsylvania and their home districts. They shared their stories about how federal This year, three students from Drexel Materials participated in the event: Ph.D. candidates Gregory Vetterick (Advisor: Mitra Taheri) and Boris Dyatkin (Advisor: Yury Gogotsi) and undergraduate student Ziyin Huang. Prior to the event, the students spent several weeks contacting the offices of members of Congress, arranging meetings with representatives, senators, and their staff. On April 10th, they traveled to D.C. and spent the evening learning about life on the hill from Congressional Fellows and networking with their peers. funding for STEM education and basic research have directly impacted their lives and asked for the senators’ and representatives’ continued support. The group Awards & Achievements Li Elected Fellow of the American Physical Society Professor Christopher Li has been elected Fellow of the American Physical Society. one half of one percent of the membership and is recognition of a scholar’s outstanding contributions to the field of physics. Li was recommended for Fellow by the Division of Polymer Physics. The election to Fellowship in the American Physical Society is limited to no more than Li has been elected “For his outstanding contributions to the understanding of structure/property relationships of complex polymer-based, heterogeneous architectures.” He will be recognized for this honor at the annual meeting of the Division of Polymer Physics. was able to visit the offices of nine members of Congress, including Pennsylvania Senator Robert Casey, Jr., Representative Allyson Schwartz (PA-13, Montgomery and Philadelphia Counties), and Representative Chaka Fattah (PA-02, Philadelphia County), whose district includes Drexel University. This marks the third consecutive year that Drexel Materials students have participated in the event. Knight Receives 2013 William Hunt Eisenman Award Professor Richard Knight received the 2013 William Hunt Eisenman Award from the Philadelphia Liberty Bell Chapter of ASM International. Established in 1957, the William Hunt Eisenman Award recognizes dedicated service to the society, foresight, dynamic management, leadership, and promotion of the metals industry and metallurgical education. At the award presentation, Professor Knight delivered a lecture entitled “Recycling of Polymeric Materials Using Induction Coupled Plasma Technology.” Currently, polymeric materials make up a significant percentage of the municipal solid waste stream. Few economically viable recycling techniques are available to deal with this polymeric material, and it is either dumped in landfills, incinerated, or inefficiently recycled through downgraded use. Thermal plasma treatment has the potential to effectively recycle polymeric material by converting it back into monomers or other useful materials. Richard Knight (center) with MSE alum Ron Smith (left), and Trevor Jones of Solar Atmospheres (right) Kristy Jost Selected to Attend Lindau Nobel Laureate Meeting 14 Back Row (L to R): Greg Vetterick, Representative Chaka Fattah, Boris Dyatkin; Front Row: Daniel Diazdelcastillo (Drexel MEM), Lauren Jellison (Carnegie Mellon), Ziyin Huang Left to Right: Ziyin Huang, Greg Vetterick, Lauren Jellison, Senator Robert Casey, Jr., Daniel Diazdelcastillo, Boris Dyatkin Materials Ph.D. candidate and DoD NDSEG Fellow Kristy Jost (advisor: Yury Gogotsi, co-advisor: Genevieve Dion) was selected to participate in the 63rd Lindau Nobel Laureate Meeting, held from June 30 to July 5, 2013 in Lindau, Germany. Lindau Award recipients are nominated and selected by the sponsoring agencies and organizations (ORAU, ORISE, DOE, NIH, NSF, Mars, Inc.). Kristy, who was sponsored by Mars, Inc., was selected as one of 550 young researchers from among thousands of applications from around the world to attend this prestigious annual meeting. 15 Kristy conducts research on smart textiles and, more specifically, wearable energy storage. The goal of her research is to provide non-toxic, flexible power to various electronic components embedded in clothing. She completed her Bachelor of Science in Fashion Design at Drexel’s Westphal College of Media Arts and Design and transitioned to the Department of Materials Science and Engineering after completing research on smart textiles as an undergraduate. awarding scholarships to college students who intend to pursue careers in these fields.” This year’s Lindau meeting focused on Chemistry and Chemistry-related fields. At the meeting, there are opportunities for both formal and informal interaction between the Laureates and the young researchers. Five Materials Students Receive National Fellowship Awards Emily has chosen a research path, getting involved in the lab very early in her undergraduate career. She is currently working with Professor Caroline Schauer’s Natural Polymers and Photonics Group to develop an economic filter from crab shells that is able to remove select contaminants from polluted water sources, such as arsenic and mercury. The filter is composed of electrospun nanofibers from the crab shells which are post-processed through chemical functionalization. In the coming years, Emily plans to continue to pursue the ways in which electrospun polymer nanofibers can be used for water filtration applications. After completing the B.S./M.S. program, she plans to obtain a Ph.D. in Materials Science and Engineering to prepare for a career in research. Emily Buck Receives Goldwater Scholarship Matthew Hartshorne Receives SMART Scholarship B.S./M.S. student Emily Buck (advisor: Caroline Schauer) has been awarded a 2013 Barry Goldwater Scholarship. The Barry Goldwater Scholarship and Excellence in Education Program seeks to “provide a continuing source of highly qualified scientists, mathematicians, and engineers by Ph.D. student Matthew Hartshorne (advisor: Mitra Taheri) has received the 2013 Department of Defense Science, Mathematics, and Research for Transformation (SMART) Scholarship. This award provides a full scholarship and stipend along with post-graduation employment in the Department of Defense. Previous Drexel Materials Lindau nominees include Jessica Schiffman (2008, awarded) and Nina Lane (2011). (Left to right) MSE students Emily Buck, Matthew Hartshorne, Sarah Lightfoot Vidal, Amanda Pentecost, and Derrick Smith received national fellowship awards. 16 Awards & Achievements The Goldwater scholarship is given to 300 students nationally, and each University is allowed to nominate four candidates. This year all four Drexel nominees were awarded scholarships. Emily is the first Drexel Materials student to receive the scholarship. Matt will be studying the effects of strain on the sensitization of grain boundary engineered austenitic stainless steels and will take a position in the Air Force Research Laboratory upon graduating. Sarah Lightfoot Vidal Receives Fulbright Scholarship B.S./M.S. student Sarah Lightfoot Vidal (advisor: Michele Marcolongo) has been selected as a Fulbright student grantee to work in Concepción, Chile at the Centro de Investigación de Polímeros Avanzados (CIPA) in collaboration with the Functional Polymers department at the Universidad de Concepción. Her project focuses on the development of a polymer blend of Polyhydroxyalkanoates (PHA) for wound healing applications. Sarah has been an undergraduate researcher with Dr. Marcolongo’s Biomaterials Research Group for three years and plans to pursue a Ph.D. in Biomedical Engineering at Tufts University. With this award, Sarah joins the largest group of Drexel students to receive the award in a single year. She is also the second Drexel Materials student to receive a Fulbright scholarship while enrolled as a student in the department, joining Dr. Aaron Sakulich (advisor: Dr. Michel Barsoum) who received the award in 2007. Amanda Pentecost and Derrick Smith Receive NSF Graduate Research Fellowships B.S./Ph.D. student Amanda Pentecost (advisor: Yury Gogotsi) and Ph.D. student Derrick Smith (advisor: Christopher Li) are both recipients of the 2013 National Science Foundation Graduate Research Fellowship (NSF GRFP). The fellowship provides funding for three years of graduate stipend and tuition support, as well as opportunities to conduct research internationally. Amanda’s current research is a collaborative project with the Shanghai Advanced Research Institute’s Nanomedicine and Translational Medicine Center, located in Shanghai, China. She is working to create a drug delivery system with a carbon nanoparticle platform in order to deliver chemotherapeutic drugs to brain tumors. Derrick’s current research involves investigating nano-confinement behaviors of ion transport in polymer systems for polymer battery membrane applications using holographic lithography. The strength of his research in this area has led to his first publication, “Tuning Ion Conducting Pathways Using Holographic Polymerization,” in Nano Letters 2012 12;1. Nationwide, 36 fellowships were awarded to students in Materials Science and Engineering departments. Of these, only seven departments, including Drexel Materials, received two or more NSF GRFP awards this year. With these two awards, a total of ten students from Drexel’s Department of Materials Science and Engineering have received the fellowship. Past recipients include Ph.D. student Kristy Jost (advisor: Yury Gogotsi), B.S. student Prineha Narang (advisor: Yury Gogotsi), B.S./M.S. student Holly McIlwee (advisor, Caroline Schauer), M.S. student Alex Moseson (advisor: Michel Barsoum), and Ph.D. students Stephen Niezgoda (advisor: Surya Kalidindi), Kris Behler (advisor: Yury Gogotsi), María Pía Rossi (advisor: Yury Gogotsi), and John Chmiola (advisor: Yury Gogotsi). Ph.D. Students Babak Anasori and Michael Naguib Awarded High Praise at MS&T At the 2012 Material Science & Technology (MS&T) Conference in Pittsburgh, PA, Ph.D. student Babak Anasori (advisor: Dr. Michel Barsoum) received the Diamond Award from the Basic Science Division of 17 the American Ceramic Society for Graduate Excellence in Materials Science (GEMS) and, along with Ph.D. student Michael Naguib (advisors: Barsoum & Gogotsi), earned a Roland B. Snow Best of Show Award for their image “Green MXene Turtle.” Awards & Achievements The GEMS Awards recognize the outstanding scientific and academic achievements of graduate students in materials science and engineering. Each year, the selection committee identifies ten students to receive the GEMS award and, based on the quality of their oral presentations at MS&T, selects the top three from that group to receive Diamond Awards. Drexel Materials Students Shine at 2012 MRS Fall Meeting Drexel Materials Science and Engineering students racked up an impressive number of awards at the Fall 2012 meeting of the Materials Research Society (MRS), which was held November 25 - 30 in Boston, MA. Ph.D. students Kristy Jost (advisor: Yury Gogotsi) and Riju Singhal (advisor: Yury Gogotsi) were among 24 students from 16 institutions, including Harvard, MIT, and Stanford, invited to present research as finalists for the Graduate Students Awards. Only Cornell University had more finalists for these awards than Drexel. MRS Graduate Student Awards honor and encourage graduate students whose academic achievements and current materials research display a high level of excellence and distinction. Jost and Singhal 2012 MRS Graduate Student Award winners Riju Singhal (far left) and Kristy Jost (far right) with Professor Yury Gogotsi (center left) and MRS President Bruce Clemens (center right). 18 each received silver awards, which include a certificate and $200 prize. Jost’s presentation, “All-textile EDLCs for Applications in Wearable Electronics,” described her work on fabrics capable of energy storage. Singhal discussed carbon nanotube endoscopes for single cell studies in his presentation “Carbon Nanotube Based Multifunctional Probes for Intercellular Analysis and Microfluid Separation.” According to MRS President Bruce Clements, this is the first time two students of the same advisor won competitive and very prestigious Graduate Student Awards. Moreover, each of them won additional awards at this MRS meeting. Kristy Jost received the Arthur Nowick Graduate Student Award for showing Professor Yury Gogotsi with MRS Best Poster Award winners Yang Gao and Riju Singhal. Ph.D. student Babak Anasori’s image “The Happy 2-D World,” 2nd place winner in the MRS Science as Art Contest. particular promise as a future teacher and mentor. Jost received a presentation plaque and $500 prize with this award. Riju Singhal and Electrical and Computer Engineering Ph.D. student Yang Gao (advisor: Adam Fontecchio) were selected for a Best Poster Award, which also includes a $500 prize. Their entry “Carbon Based Multifunctional Nano-probes for Cellular Injection, Potential Measurement, and Electrophysiology” was one of a handful to receive this award out of over 800+ poster entries. The winning team also includes Professors Zuly Orynbaeva and Gary Friedman. Additional awards were given to Ph.D. student Babak Anasori (advisor: Michel Barsoum), who’s piece “The Happy 2-D World,” won a second place award in the Science as Art Competition, and to the Drexel MRS student chapter (president: Jake McDonough), which took third place in the MRS T-shirt design contest. “It’s wonderful to see our students receiving this much-deserved recognition,” says Yury Gogotsi, Distinguished University and Trustee Chair Professor. “We are delighted to see this acknowledgement of Drexel’s outstanding materials science and engineering programs from MRS. This clearly places Drexel among the leading institutions in the world in the materials field.” Ph.D. Student Joshua Young Places in Sigma Xi Student Research Showcase Ph.D. student Joshua Young (advisor: James Rondinelli) won third place in the Graduate Chemistry/Biochemistry Division of the Sigma Xi Student Research Showcase for his work “Atomic Scale Structural Design Strategies for Artificial Polar Oxides.” Sigma Xi is a scientific research society founded in 1886 to honor excellence in scientific investigation and foster research cooperation among all fields of science and engineering. The Sigma Xi Student Research Showcase is a virtual research presentation competition open to graduate, undergraduate, and advanced high school students. Joshua’s presentation is available for viewing online at http://joshuayoungresearch.tumblr.com. The following graduate students have been awarded fellowships from the College of Engineering (from left to right): Shan Cheng (advisor: Christopher Li) – Harry Brown Fellowship Fund; Gregory Vetterick (advisor: Mitra Taheri) – Koerner Family Award; Babak Anasori (advisor: Michel Barsoum) – George Hill, Jr. Endowed Fellowship Fund; Mark Scafetta (advisor: Steven May) – Koerner Family Award; John (Jake) McDonough (advisor: Yury Gogotsi) – Leroy Resser Endowed Fellowship Fund; and Joshua Young (advisor: James Rondinelli) – Joseph and Shirley Carleone Endowed Fellowship Fund. 19 ALUMN IMPACT Ph.D. Alumnus Stephen Niezgoda Appointed Assistant Professor at OSU Alumnus Stephen Niezgoda (Ph.D. 2010, advisor: Surya Kalidindi) has accepted a joint appointment as assistant professor in both the Department of Materials Science and Engineering and the Department of Mechanical and Aerospace Engineering at Ohio State University (OSU) beginning August 2013. At OSU, Stephen’s research will focus on developing programs in crystal plasticity and other micromechanics modeling, stochastic approaches to multiscale modeling, computational material design tools, and materials data sciences. Most recently, Stephen was a post-doctoral researcher with the Materials in Dynamic and Radiation Extremes group within the Materials Science and Technology Division at Los Alamos National Laboratory. He worked with Don Brown at the Los Alamos Neutron Science Center (LANSCE), where he focused on the computational and experimental challenges of 3D High Energy X-ray Diffraction Microscopy (HEDM) (evolution of nuclear fuel assemblies during simulated reactor conditions). Stephen previously worked with Carlos Tome on developing the new technique of cross-correlation EBSD, as well as crystal plasticity models for hexagonal and low symmetry materials. Prior to joining Los Alamos, Stephen completed his dissertation work in the Mechanics of Microstructures Group on the statistical analysis of microstructure data and microscopy image processing techniques. Upon graduation, Stephen was selected as the graduating doctoral student deemed to have the “Most Promise to Enhance Drexel’s Reputation” in the Mathematical Sciences and Engineering category. He was the recipient of NSF GRFP, DoD NDSEG (declined), and NSF IGERT fellowships. probe approach enables the first direct imaging of bulk-mediated and surface-mediated charge transfer processes within SOFC membrane electrode assemblies. During his doctoral studies at Drexel, Stephen worked in the Mesoscale Materials Laboratory At UMass Amherst, Stephen will form the Nanomaterials for Interface-Controlled Energy 20 Laboratory (NICE), which focuses on the design, synthesis, and in-situ characterization of nanostructured materials for use in energy transduction technologies such as solid oxide fuel cell electrode assemblies and organic photovoltaics. Stephen most recently served as a Nano/ Bio Interface Center postdoctoral research fellow in the Department of Materials Science and Engineering at the University of Pennsylvania under the guidance of Professor Dawn A. Bonnell. His research focused on clarifying the roles of interfacial phenomena and transfer mechanisms within energy-related materials via direct, localized scanning probe microscopy imaging methodologies under extreme operating conditions. This high-temperature scan Engineering. He also received the NSF-IGERT and NSF GK-12 fellowships during his tenure in the department. Materials Alumna Dr. Svetlana Dimovski Quoted in Article on Open Innovation Alumna Dr. Svetlana Dimovski (Ph.D. 2006; advisor: Yury Gogotsi) was interviewed for an article about “open innovation” (OI) that was featured in the October 2012 issue of Specialty Chemicals Magazine. The article discusses how many major chemical manufacturers are creating or enhancing Ph.D. Alumnus Stephen Nonnenmann Appointed Assistant Professor at UMass Amherst Alumnus Stephen Nonnenmann (Ph.D. 2010, advisor: Jonathan Spanier) has accepted an appointment as assistant professor in the Department of Mechanical and Industrial Engineering at the University of MassachusettsAmherst in the area of Materials Engineering, effective September 1, 2013. on the synthesis and characterization of nextgeneration non-volatile memory elements, which exploited nanoscale curvature to preserve functionality at finite length scales. For this, Stephen earned the “Best Doctoral Dissertation” award in the category of Mathematical Sciences and formalized infrastructures that encourage OI between private industry, academia, government agencies, and professional groups in order to speed the development and utilization of specialty chemicals. Dimovski, who serves as Manager of Open Innovation and Science Relations for BASF North America, is quoted describing how process transparency and agility are critical components of their efforts to build outside collaborative efforts. Ph.D. Alumnus Dr. Ranjan Dash Featured in Inaugural Issue of Drexel Magazine 40 Under 40 Ph.D. alumnus Dr. Ranjan Dash (MBA/Ph.D. ’06, advisor: Yury Gogotsi) has been featured in the inaugural issue of Drexel Magazine’s 40 Under 40. The Drexel 40 Under 40 features young alumni/ae who exhibit innovative, entrepreneurial, and cutting-edge qualities in their careers and leadership. Ranjan has been noted as a cofounder of a start-up nanotechnology company. Ranjan is previously the recipient of the 2011 Alumni Entrepreneur Award from the Drexel University Alumni Association and the Drexel University Young Alumni Entrepreneur Award, as well as an MIT Technology Review TR35 as one of 35 innovators under the age of 35 representing the cutting-edge in science and technology. Upon graduation, he received the graduate student “Most Likely to Enhance Drexel’s Reputation” Award (Engineering and Physical Sciences). Ranjan was the first Drexel student to complete a Ph.D. and M.B.A. simultaneously. 21 ALUMN IMPACT Alumnus Dr. William Frazier Selected 2013 NAVAIR Esteemed Fellow Materials alumnus Dr. William E. Frazier (B.S 1981, M.S. 1984, Ph.D. 1987) was selected as a 2013 Naval Air Systems Command (NAVAIR) Esteemed Fellow. Esteemed Fellow is the highest honor awarded through NAVAIR’s peer selection Fellows Program, which recognizes highly skilled individuals from NAVAIR’s engineering and scientific community deemed to be experts within their fields. Esteemed Fellows represent peer designation of the top .25 percent of the NAVAIR research and engineering workforce. Dr. Frazier is the Chief Scientist of Air Vehicle Engineering at NAVAIR. Alumnus Dr. Neville Vakharia Appointed Assistant Professor and Research Director in Drexel’s Westphal College Alumnus Dr. Neville Vakharia (B.S., 1990) has been appointed assistant professor and research director in Drexel’s Westphal College of Media Arts & Design. After earning his bachelor’s degree in materials, Vakharia worked in new product development, marketing, and global product management for W.L. Gore & Associates, Inc., manufacturer of GORE-TEX products. He holds two international patents and has developed several new products and technologies. With over 10 years of experience as an arts administration professional, Vakharia most recently 22 held the position of Director of the Cultural Data Project (CDP) at The Pew Charitable Trusts, where he oversaw the operations, expansion, and strategic direction of CDP, a growing national initiative created to improve the management and financial capacity of arts organizations, inform grant making strategies, and serve as a powerful tool for cultural policy research and analysis. Prior to joining Pew, Vakharia served as Director of Technology Services and Programs for the Arts & Business Council of Greater Philadelphia, where he created and launched the Technology Connectors, a program designed to support the technological capabilities of the region’s arts and cultural organizations through education, strategic planning, and consulting. As Director of Marketing for the Prince Music Theater, Vakharia oversaw all audience development strategies, and for 12 years was the co-producer of the ArtsFest Film Festival, central Pennsylvania’s largest film festival. Vakharia has worked as an adjunct faculty member in the Arts Administration program and earned his Master of Science in Arts Administration from Drexel University. Dr. George Dieter Selected for Alpha Sigma Mu Distinguished Life Member Award Dr. George E. Dieter was chosen as a recipient of the Alpha Sigma Mu Distinguished Life Member Award, presented as part of the Materials Science and Technology 2012 Conference and Exhibition in Pittsburgh, PA in October 2012. Engineering Education (ASEE), and was national president of ASEE in 1994. He was elected a member of the National Academy of Engineering in 1993. Dieter received his B.S. in Metallurgical Engineering from Drexel University in 1950 and later returned to head the department and subsequently serve as Dean of Engineering. He also holds a Sc.D. from Carnegie Mellon University and served as the Director of the Processing Research Institute there from 1973 to 1977. He subsequently went on to hold the position of Dean of Engineering at the University of Maryland from 1977 to 1994. Alpha Sigma Mu is the international professional honor society for materials science and engineering. According to their website, “Distinguished Life Member is Alpha Sigma Mu’s highest honor...This award is to be conferred upon those select few whose technical attainment and contributions to society through leadership in the field of materials science and engineering have resulted in significant benefits to humankind.” In particular, Dieter is known for his pioneering texts in two areas at the interface between materials and mechanical engineering, Mechanical Metallurgy, first published in 1961, and Engineering Design: A Materials and Processing Approach, the first published text in this field. He was chair of the Engineering Deans Council of the American Society for Dieter was honored, along with alumna Dr. Elizabeth Hoffman (MSE B.S. 2002, Ph.D. 2007; advisors: Michel Barsoum and Yury Gogotsi), 2012 ASM International Silver Medal Distinguished Life Member Award winner Dr. George Dieter (center) with Alpha Sigma Mu Fellows Dr. Fred Schmidt (left) and George Vander Voort (right). Awardee, and Dr. Antonios Zavaliangos, Alpha Sigma Mu Fellow, at an event sponsored by the department and Howard Kuhn on Sunday, October 7, 2012. 23 MAJOR RESEARCH INITIATIVES & ACTIVITIES Barsoum, Gogotsi, with Students and Colleagues Win ACerS 2013 Ross Coffin Purdy Award A. W. Grosvenor Professor Michel W. Barsoum (top left) , Distinguished University and Trustee Chair Professor Yury Gogotsi,(top right), Ph.D. candidate Michael Naguib (bottom left, advisor: Michel Barsoum), Ph.D. candidate Olha Mashtalir (bottom right, advisor: Yury Gogotsi), B.S. student Joshua Carle, former research professor Volker Presser, and Dr. Jun Lu and Professor Lars Hultman from Linköping University, are recipients of the 2013 American Ceramic Society’s (ACerS) Ross Coffin Purdy Award. This award is given to the author(s) “judged to have made the most valuable contribution to ceramic technical literature during the calendar year prior to the selection.” The ACerS Board unanimously approved the award subcommittee’s selection of Barsoum and Gogotsi et al. for their article “TwoDimensional Transition Metal Carbides” published in ACS Nano, Vol. 6, No. 2, 1322-1331, 2012. This achievement was recognized Monday, October 28, 2013 at the ACerS Honors and Awards Banquet during the Materials Science and Technology Conference which took place October 27-31, 2013 in Montréal, Quebec, Canada. May and Baxter Receive Funding to Develop Complex Oxides for Solar Energy Conversion Assistant professor Steven May (pictured) of the Department of Materials Science and Engineering and Jason Baxter, affiliated faculty member of materials and assistant professor in the Department of Chemical and Biological Engineering, have been awarded a grant from the National Science Foundation for “Photoexcited Carrier Dynamics in Oxide Semiconductors for Photovoltaics.” 24 The budget for the three-year project is $380,000 (ECCS-1201957). Semiconductors made from transition metal oxides are earth-abundant, consist largely of nontoxic elements, and have electronic and optical properties that can be engineered. While this combination of properties makes complex oxides promising candidates for applications in photovoltaics and photocatalysis, a detailed fundamental understanding of how to optimize complex oxides for solar energy application is lacking. Using a combined approach of advanced materials synthesis and ultrafast optical spectroscopy, May and Baxter will identify promising routes to improve the material properties that are most critical for solar-based applications. In doing so, this project will contribute critical insights needed for the development of a new generation of oxide-based solar energy conversion devices. Materials Receives Department of Education GAANN Grant for Innovative Biomaterials The Department of Materials Science and Engineering has been awarded a three-year $533,000 Department of Education Graduate Assistance in Areas of National Need (GAANN) grant, led by PI Professor Michele Marcolongo, professor Antonios Zavaliangos, and associate professor Caroline Schauer (co-PIs). Operations Manager Dorilona Rose also contributed to this proposal and will help to oversee the administration of the grant. GAANN BIOMSE: Innovative Biomaterials is targeted at providing education for doctoral students majoring in materials science and engineering with a focus on synthetic biomaterials for medical devices, drug delivery for controlled release of pharmaceuticals, molecular engineering for tissue restoration, and tissue scaffolds for 3-D cellular engineering. GAANN Fellowships provide need-based financial support to Ph.D. students pursuing a degree in a field of study identified as an area of national need. Barsoum’s and Gogotsi’s Discovery of MXenes Featured in Chemical & Engineering News The work of A. W. Grosvenor Professor Michel Barsoum and Distinguished University and Trustee Chair Professor Yury Gogotsi and their team of researchers was featured in the October 8, 2012 issue of Chemical & Engineering News (C&EN). Their discovery of a new class of 2-D materials last year, which they dubbed MXenes, was part of a cover story in C&EN on the recent discovery of several different types of 2-D materials. The article describes the process by which the researchers discovered MXenes and the potential these materials have for new technologies. SEM image of the exfoliated layers of two-dimensional Ti3C2 layers called MXene. Exfoliation of Ti3AlC2 is accomplished by etching the aluminum out from the structure, which results in 2-D layers of Ti3C2. The gold fish on the image is 12μm long. Winner of Nano Today front cover competition 2012, Nano Today, Vol 7, No. 1, February 2012. Image credit: Babak Anasori, Michael Naguib, Yury Gogotsi and Michel W. Barsoum (MAX phase group and Drexel Nanotechnology Institute), Zeiss Supra 50VP SEM in Drexel University’s Core Facilities. 25 MAJOR RESEARCH INITIATIVES & ACTIVITIES NSF Features Gogotsi’s Sepsis Treatment Research on LiveScience Sepsis treatment advances by Distinguished University and Trustee Chair Professor Yury Gogotsi, former research professor Volker Presser, and former postdoc Sun-Hwa Yeon were selected by the National Science Foundation for feature on the science news website livescience.com. Sepsis, also known as blood poisoning, occurs when an infection triggers the body to react with severe inflammation. In 40-60% of cases, the condition is fatal. Gogotsi, Presser, and Yeon developed a filtration system of mesoporous carbons derived from silicon carbide-based ceramics that are highly effective at removing excess cytokines which build up in the blood as sepsis progresses, which in turn allows more time for antibiotics and other drugs to take effect, improving survival rates. This NSF sponsored work was also featured in a cover article in the November 2012 issue of Advanced Healthcare Materials. 26 electro-optical response to the “amount” of polar displacements at the unit cell level in the crystal. The new structure-based approach to tailoring the optical properties of materials provides a novel platform to design materials at the atomic scale with targeted macroscopic responses. The generation of intense coherent deep-UV light from nonlinear optical materials is crucial to applications ranging from semiconductor photolithography and laser micromachining to photochemical synthesis. Additionally, Rondinelli collaborated with researchers at the Oak Ridge National Laboratory to publish synthesis and characterization studies A new deep-UV NLO material, Ba4B11O20F is obtained by introduction of fluorine atoms in a barium borate system to generate large polar atomic displacements that Rondinelli and collaborators identify to be responsible for the SHG response—it is approximately 10X that of KH2PO4 and is the largest of borates containing neither lone pair active ions nor second-order Jahn-Teller active transition metals. which describe how to stabilize new phases in ferroelectric materials by heteroepitaxial engineering in Advanced Materials. The article, “Interplay of Octahedral Tilts and Polar Order in BiFeO3 Films,” Remarkably, the phase is metastable and can be switched into a polar ferroelectric state under an applied electric bias. The work offers new insight for the rational design of ferroic phases in materials for use in low-power electronics. Study of New Two-Dimensional Carbide Published in Europhysics Letters Ph.D. student Nina Lane (advisors: Michel Barsoum and James Rondinelli), A. W. Grosvenor Professor Michel Barsoum, and assistant professor James Rondinelli reported a firstprinciples study of a new 5d two-dimensional carbide with a graphene-like lattice and semi-metallic behavior in Europhysics Letters. Rondinelli Work Featured in the Journal of the American Chemical Society and Advanced Materials Professor James Rondinelli and colleagues at Northwestern University and Xinjiang Technical Institute of Physics & Chemistry reported a structure-based design strategy for second harmonic generating crystals with large responses in the Journal of the American Chemical Society. The article, titled “Designing a Deep Ultraviolet Nonlinear Optical Material with Large SHG Response,” describes a new atomic structure acentricity descriptor and links the macroscopic demonstrates that a distinct nonpolar BiFeO3 phase emerges simultaneously with changes in octahedral tilts at an oxide–oxide interface. Their article, “Correlation effects and spin-orbit interactions in two-dimensional hexagonal 5d transition metal carbides, Tan+1Cn (n=1, 2, 3),” describes how the dimensionality of the pristine sheets due to changes in polyhedral stacking alters the electron–electron interactions and the stability of long-range magnetic order. These low-dimensional carbide materials with heavy transition metal cations offer a new route to incorporate magnetism for novel spin-based electronics without the need for post-processing surface functionalization. The two-dimensional Tan+1Cn (n = 1,2,3) (left), and their corresponding electronic band structures. Journal Covers Feature Drexel Materials Research Professor Christopher Li and Ph.D. student Eric Laird published an invited perspective cover piece on “Structure and Morphology Control in Crystalline Polymer-Carbon Nanotube Nanocomposites” in the April 2013 issue of Reprinted with permission from Macromolecules 2013, 46, 2877-2891. Copyright 2013 American Chemical Society. Macromolecules, the leading journal in polymer science. The perspective presents the recent progresses on the structure, morphology, and related applications of semicrystalline polymer-CNT nanocomposites, work of particular significance from the Soft Materials Lab over the past eight years. 27 MAJOR RESEARCH INITIATIVES & ACTIVITIES Sepsis treatment advances by Distinguished University and Trustee Chair Professor Yury Gogotsi, former research professor Volker Presser, and former postdoc Sun-Hwa Yeon were featured in the cover article “Cytokine Removal: Hierarchical Porous Carbide-Derived Carbons for the Removal of Cytokines from Blood Plasma” in the November 2012 issue of Advanced Healthcare Materials. Hoeganaes Assistant Professor of Metallurgy Mitra Taheri, Ph.D. candidates Christopher R. Winkler and Michael L. Jablonski, and colleagues from the University of Illinois, Urbana-Champaign published a cover piece on “Accessing Intermediate Ferroelectric Switching Regimes with Time-Resolved Transmission Electron Microscopy” in the September 2012 issue of the Journal of Applied Physics. The piece reports the authors’ use of in situ transmission electron microscopy to study the dynamics of ferroelectric domains in BiFeO3 and other ferroelectric materials. These biasing experiments provide a real-time view of the complex dynamics of domain switching and complement scanningprobe techniques, allowing a better understanding of the dynamics of ferroelectric switching, particularly in the vicinity of extended defects, that is needed to incorporate BiFeO3 into novel spintronics devices and sensors. Breast Cancer Detection Sensor Developed at Drexel Receives Grant from Pennsylvania Department of Health Professor Wei-Heng Shih, in conjunction with affiliated faculty member Dr. Wan Shih in the School of Biomedical Engineering, Science and Health Systems, and Dr. Ari Brooks, chief of surgical oncology at Drexel’s College of Medicine, has received a $878,422 grant from the Pennsylvania Department of Health’s Commonwealth Universal Research Enhancement (CURE) program to further commercialize and Volker Presser, Sun-Hwa Yeon, Cekdar Vakifahmetoglu, Carol A. Howell, Susan R. Sandeman, Paolo Colombo, Sergey Mikhalovsky, Yury Gogotsi: Cytokine Removal: Hierarchical Porous Carbide-Derived Carbons for the Removal of Cytokines from Blood Plasma. Advanced Healthcare Materials. 2012. 1. 682. Copyright Wiley-VCH Verlag GmbH & Co. KGaA. Reproduced with permission. Inset, bottom left: In-situ probing of domain switching in BiFeO3 by transmission electron microscopy (image by M. Taheri & C. Winkler, sample by A.R. Damodaran, J. Karthik, & L.W. Martin, UIUC). Reprinted with permission from J. Appl. Phys. 112, 051901. Copyright 2012, AIP Publishing LLC. Li Receives NSF Grant for Polymer Crystallization at Curved Liquid/Liquid Interface Professor Christopher Li has been awarded a four-year $488,000 National Science Foundation Division of Materials Research grant for his project “Polymer Crystallization at Curved Liquid/Liquid Interface.” 28 Curved space is incommensurate with typical ordered structures with three-dimensional (3D) translational symmetry. In this project, Li proposes to investigate packing crystalline polymer chains in a curved incommensurate space using an emulsion-solution crystallization method. If successful, the well-controlled single- or multiple-component ensembles will not only shed light on using polymeric capsules for drug delivery and gene therapeutics, they can also be extremely useful for applications such as catalysis, surface enhanced Raman spectroscopy, and artificial nanomotors. clinically validate a sensor to aid in the early detection of breast cancer. “Intelligent Breast Exam” (iBE™) uses piezoelectric finger technology to glean more accurate information from routine breast examinations. After a series of clinical tests, it could become a valuable tool for physicians in the early detection of breast cancer. UE LifeSciences Inc., a Philadelphiabased startup, licensed the technology in 2010. Spanier, May, and Baxter Receive DURIP Professor Jonathan Spanier (PI), with co-PIs assistant professor Steven May and assistant professor Jason Baxter (Chemical & Biological Engineering) received funding for “Laser sources for characterization of functional oxide materials” from the US Army Research Piezoelectric finger sensor technology developed at Drexel is being integrated into the Intelligent Breast Exam (iBE™) technology at UE LifeSciences. Office and the Department of Defense under the DURIP program. The new instrumentation, which includes a diode-pumped solid state and tunable Ti:S laser with frequency doubling, is being used to investigate the optical and optoelectronic properties of oxides, including luminescence and resonant Raman scattering. In particular, it is being used to study the photovoltaic properties of new ecologically-friendly earth-abundant element oxides for high-efficiency solar energy conversion. The award received is approximately $198,000. Computational Materials Science: Building Multidisciplinary Efforts to Advance Materials Discovery The Materials Genome Initiative (MGI) is a national program aimed at accelerating the discovery of advanced materials and reducing by half the time to integrate and deploy them into energy, medical, security, and communication technologies. Within this framework, the early stages of materials development rely on harnessing available computational science tools to (i) formulate materials structure–property–functionality 29 Special Highlights Page Title databases from a plethora of diverse data, and (ii) establish protocols to search through that data to (iii) efficiently guide the selection of materials for synthesis and subsequent integration. The ultimate aim is to render serendipitous discoveries obsolete and, in turn, make rational or predictive materials discovery-by-design the gold standard, reducing both costs and time to discovery. In the December 2013 issue of The Bulletin of the American Ceramic Society, assistant professor James Rondinelli and colleagues from across the United States articulate in their article, “Accelerating Functional Materials Discovery: Insights from Geological Sciences, Data-driven Approaches, and Computational Advances,” that advances in materials discovery will greatly benefit from unconventional multidisciplinary efforts (J.M. Rondinelli, N.A. Benedek, D.E. Freedman, A. Kavner, E.E. Rodriguez, E.S. Toberer, and L.W. Martin, Accelerating Functional Materials Discovery: Insights from Geological Sciences, Data-driven Approaches, and Computational Advances, American Ceramic Society Bulletin, 93 x-y (2013)). Rondinelli and co-authors, joined by colleagues in the physical sciences, in particular petrologists, geochemists, mineral physicists, and information scientists were motivated to write this article after participating in an NSFsponsored workshop in February 2012 on the MGI in Ceramics, Geosciences, and Solid-State Chemistry. Growing Philly Materials Day Highlighted in Print and Web Articles The October 2012 issue of MRS Bulletin featured the article “Drexel hosts Philly Materials Day” by Ph.D. student Steven Spurgeon (advisor: Mitra Taheri). Schematic of the Earth as a synthetic vessel with minerals forming in different regions highlighted. Each mineral phase selected for this figure is also synthesized in laboratories for their unusual properties and applications under controlled environments that mimic geological conditions. Drexel Materials Expands Social Media Presence 30 Follow us on Twitter @DrexelMaterials and like us on Facebook (www.facebook.com/drexelmaterials) to receive timely departmental news and fascinating materials related links. Additionally, joining our LinkedIn group is a great way to get materials networking and job opportunities and stay in touch with other alumni and friends of Drexel Materials. You can link to all of our social media sites from the homepage of our website @ www.materials.drexel.edu. Hands-on demonstrations such as making slime and liquid nitrogen ice cream are two of the many ways the wonder of materials science is explored at Philly Materials Day. Spurgeon’s article describes the planning and execution of the day-long festivities, which seek to educate and excite people of all ages about the intriguing world of materials science. The article includes a quote from associate department head Richard Knight, the event’s emcee, saying, “The age-old problem we find is that people have no concept of what materials science and engineering is, but once you explain and show people, they have a better idea. They begin to realize then that everything is made of materials and there’s a reason why we choose the materials we do.” Philly Materials Day was also featured in an article posted to the Materials Research Society’s (MRS) Science Enthusiasts website and Materials360 Online in March 2013. The article details the success of Philly Materials Day 2013 and the history of this three-year collaboration between Drexel University, the University of Pennsylvania, and the Franklin Institute. The 2013 Philly Materials Day brought over 2000 people to Drexel University’s Bossone Research Enterprise Center for a day of hands-on materials science and engineering fun. Planning for the 2014 Philly Materials Day, scheduled for February 1, 2014, is now underway. More information can be found at www.phillymaterials.org. For a Second Year, Summer Institute Offers High School Students Materials Research Opportunities The Drexel Material Science and Engineering Summer Institute, run by teaching associate professor Christopher Weyant, provides hands-on research experience for high school students through week-long sessions focused on biotechnology, electronics, and energy with the integration of nanoscience and sustainability throughout. This year, the program expanded from one session to two, and increased enrollment from 16 to 28 students from Pennsylvania and New Jersey. Students accepted into the program demonstrate their aptitude for science and engineering through excellent performance in math and science courses, quality recommendations, and an essay related to their viewpoint on materials science and engineering. Each week culminates in group presentations focused on two primary experiments in electrospinning of nanofibers and fabrication and evaluation of dye-sensitized solar cells. To learn more about the Summer Institute, visit www.materials.drexel.edu/ programs/summerinstitute. High school students acquire hands-on materials research experience during the Summer Institute. 31 40 Years of MATE 100: The Materials Two-Day Course For most Drexel Materials majors, their earliest memories of the department coincide with MATE 100 or one of its earlier incarnations: a two-day freshman materials introductory course held the week before the official start of the term. Besides the perk of getting to move into the dorms early, students get the opportunity to become familiar with their new major, or potential major, as well as faculty, staff, and fellow students, all while earning two credits to add to their transcripts. This year marks the 40th year of the course, now called “Materials for Emerging Technologies,” so we checked in with alumni, former department head Dr. Alan Lawley, and former staff member Judy Trachtman for reminiscences about the course and its beginnings. A 2013 MATE 100 participant shows off her foam creation. 32 Dr. Lawley recalls that the need for the course stemmed from dwindling enrollment in the then Department of Metallurgical Engineering and a lack of information given to high school students about materials and their importance in today’s society (the latter still a challenge today). The course was conceived of by popular Professor George Smiernow, whom Dr. Lawley describes as speaking with “a mix of English and American, spiced with a strong Russian accent.” The course began as a three-day intro, later reduced to two. The first few years put a heavy emphasis on metals; ceramics, polymers, and other evolving areas of materials science and engineering began to appear in the course in subsequent years. The course originally was limited to 30-40 students; today we have limited the course to 125 participants and frequently have a wait list. Judy speaks of the logistical challenges—figuring out what, and how, to charge and organize housing with residential living, order food, notify potential students, and find out how to give the two credits to the participants. Students checked into the dorms the day before the start of the course and at the conclusion of the first day, the movie “The Man in the White Suit” was shown—a satirical comedy starring Alec Guinness and featuring the allure and hazards of materials science and engineering at the heart of the movie. While we’ve replaced Dr. Lawley’s Birmingham, UK banter with Dr. Rick Knight’s English patter, today’s course has much the same structure as it did in its infancy. It features lectures from our faculty about the emerging areas of materials as well as hands-on labs run by our graduate students to give bright eyed new freshmen a chance to immerse themselves in the lab and get a taste of research. Lunches are an opportunity for students to mingle among themselves and talk one-on-one with faculty. Current and former students frequently identify the two-day course as their reason for majoring in materials science and engineering. Whatever the reason for taking the course, it has become an integral part of the beginning of the fall here in Drexel Materials. “I took the MATE 100 two-day materials course in the fall of 1975 before the term started. [Editor’s note: this was the year the department became the Department of Materials Engineering.] I was an incoming freshman with no idea what type of engineering I would study. I still had a very foggy understanding of engineering as I started my university experience. The course led by Professor Alan Lawley really excited me and opened my eyes to the field of materials. The projects were quite fun and there was camaraderie. I recall sitting with the faculty and other students over the bag lunches. It was all so new to me, but I liked the atmosphere of the department. We were required to take the intro courses for several types of engineering the first year. But by the end of the year, I knew I wanted to be a Materials Engineer. During my time at Drexel, I became quite interested in polymers. Polymers were dwarfed at the time by the metallurgy focus of the department. Professor Roger Corneliussen helped me extensively, and enabled me to get into graduate school at Northwestern University, again studying polymer physics within materials science. (Top to bottom) Ph.D. students Michael Ghidiu and Darin Tallman assist a MATE 100 student to prepare a Prince Rupert’s drop by dripping molten glass from a stir rod into water. An annual MATE 100 favorite—making foam. Ph.D. alumnus (2008) Kishore Tenneti leads this group in the slime and foam demos in 2003. A 2013 two-day course participant pours liquid nitrogen at the liquid nitrogen ice cream demo. The two-day materials engineering course started my path into materials science. Having the course before I saw any of the other types of engineering (mechanical, chemical, civil…) certainly was an advantage for materials!” –– Dr. Paul Howard, B.S. 1980 Research Director for Chemistry, Schlumberger, Cambridge, UK “35 years ago I was a naïve 17-yearold, who liked math and science but didn’t know what he wanted to do with his life. After the MATE 100 course, I was certain that I wanted to be a Materials Engineer. I have spent the last 30 years putting into practice the concepts that were introduced in that course, and I have loved every minute of it. My favorite memory of the course was Dr. Alan Lawley’s Joke of the Day. I still use some of the jokes that he told at the beginning of each class.” –– Don Byrnes, B.S. 1983 “I had never heard of materials science as a field of its own before MATE 100, but the course gave me an idea of the huge variety of materials research Another 2003 photo of a foam demo. techniques, approaches, and fields of application. Actually seeing all the labs, equipment, and enthusiastic researchers really impressed on me that, in this department, smart people were actively chasing down answers to interesting and important questions in fields as diverse as medicine, aerospace, and nanotechnology. This broad range of materials impact became the reason I joined the Materials department and made materials science and engineering my major freshman year. Even now, as a pre-junior, I keep realizing it was MATE 100 that first introduced me to graduate students and professors in the department with whom I have found myself researching. In a way, seeing materials science shown off at the two-day course was a first step on my path to becoming a materials scientist myself, and someday adding to the materials knowledge and inventions to be displayed to entice the next generation of potential materials science students.” –– Laura Allan B.S./M.S. Student Class of 2016 “I took the course in 1976 (I do believe the Periodic Chart was pretty well filled out then). To this day, I can remember first learning why aluminum foil is shiny on one side and dull on the other!!!” –– Frank Zimone, B.S. 1980; M.S. 1983 “So many memories! I remember a student who hadn’t had breakfast passed out during one of the labs. I once had to pull Alan [Lawley] out of his lecture because the roof of his house was on fire!” –– Judy Trachtman, Former Staff Member “For my part, I flirted with fame as a late night TV comedian by relating the story of the ‘spherical chicken’ and the annual spring festival on ‘shin-kicking’ in the United Kingdom!” –– Dr. Alan Lawley, Professor Emeritus and Former Department Head 33 Thank You To Our Donors Supporting Materials page text The Department of Materials Science and Engineering gratefully acknowledges its donors. Your generosity benefits both current and future materials students and faculty, reaching well beyond the classroom and lab. If you are interested in making a financial or non-financial contribution to the department, please visit: www.materials.drexel.edu/support Individual Donors Mrs. Aileen M. Ather Steven May, Ph.D. Dr. Jonathan Ayutsede Mr. Michael J. McDermott Mr. Dmitri Alexander Bohn Mr. Michael J. Micklus Dr. Hao Cheng Mr. Michael J. Pechulis Dr. John F. Copeland Frederick E. Schmidt, Jr., Ph.D. Mr. Joseph R. Cauvin Mr. Edwin P. Stankiewicz Dr. George E. Dieter, Jr. Robert A. Swift, Ph.D. Ms. Keiko Nakazawa Glover Dr. Mitra Taheri Dr. Richard Knight Mr. James R. Whetstone, Jr. Ms. Sarit Kunz Mr. Walter T. Young Hoa Lam, Ph.D. Dr. Antonios Zavaliangos Ms. Yenneeka Long 34 The Materials Endowment Fund The Anne L. Stevens Endowed Scholarship Fund The Department of Materials Science and Engineering Endowment Fund supports undergraduate and graduate student fellowships and faculty development. This past year, $1,500 in funds were awarded to Emily Buck (advisor: Caroline Schauer), Tianjiao Cai, and Nasreen Khan (advisor: Christopher Li). Another scholarship available to our students is the Anne L. Stevens Endowed Scholarship Fund, which provides financial support to female students in the Department of Materials Science and Engineering who demonstrate academic merit and financial need. The scholarship was established in 2007 with a generous gift from Stevens (’80) and the Lockheed Martin Corporation Directors Charitable Award Fund. The Anne L. Stevens Endowed Scholarship Fund has given $154,575 in awards since its inception in 2007. This year, awards were given to Laura Allan (advisor: Yury Gogotsi), Madeline Bouchard, Emma Foley, Brittany Gallagher, Emily Holcombe (advisor: Mitra Taheri), Gabrielle Housel (advisor: Yury Gogotsi), Jessica Kennelly, Sarah Lightfoot Vidal (advisor: Michele Marcolongo), Brittany Pattinson (advisor: Jonathan Spanier), Amanda Pentecost (advisor: Yury Gogotsi), Elaine Ruiz (advisor: Antonios Zavaliangos), and Amanda Toth (advisor: Caroline Schauer). The A. W. Grosvenor Scholarship Fund The A. W. Grosvenor Scholarship Fund supports tuition for undergraduate students. $7,538 from the A. W. Grosvenor Scholarship Fund was awarded to Eric Angell, Jacob Horejs, Travis Longenbach (advisor: Yury Gogotsi), and Elaine Ruiz (advisor: Antonios Zavaliangos). The Koczak Scholarship Fund Corporate Donors Boeing, Inc. When you send a financial contribution to Drexel, please be sure to designate your contribution to “Materials Science and Engineering.” Possible avenues for contribution include: Thermal Spray Depot, LLC If you have donated to MSE in FY 2013 and are not listed or are listed erroneously, we apologize for the oversight. Please contact us if you have any corrections to your listing or wish to be recognized in future publications. The Koczak Scholarship Fund provides tuition support for undergraduate students. Matthew Nelson (advisor: Yury Gogotsi) received $1,817 in funding. 35 Drexel University Department of Materials Science and Engineering 2012-2013 Annual Report News Editors Leslie Anastasio Dorilona Rose Layout & Design Andrew Marx Cover Image Credits 1. B.S./M.S. student Pelin Kansu adds substrate for an Elisa like assay with a multi-channel pipette. Photo credit: Victoria Edwards. 2. SEM of layered MXene along with added illustration of intercalated ions between layers. Original image credit: M. Lukatskaya, Y. Dall’Agnese, E.Ren, Y. Gogotsi. 3. What looks like red astroturf is actually how tiny carbon nanotubes template macromolecular chains upon crystallization of the latter, forming nano-hybrid shish kebabs, a new class of hybrid materials. Credit: Professor Christopher Li and Ph.D. candidate Eric Laird of the Soft Materials Lab. 1 2 4 3 5 7 6 9 8 4. Participants at our annual ASM International Materials Camp test their composite bridges with Dr. Rick Knight (in yellow shirt). 10 11 5. This image of dancing rubber balls is actually the electron localization function (ELF) for the rationally designed benign polar material Ba4B11O20F, which exhibits a large second harmonic generation that may soon find application in non-linear optical technologies, such as in lasers, optical signal processing, and biological imaging. Credit: Professor James Rondinelli and the Materials Theory and Design Group. 6. A young participant gets a hand from Ph.D. student Jake McDonough on mixing up liquid nitrogen prepared ice cream at Philly Materials Day 2013. 7. NSF Graduate Research Fellow Kelsey Hatzell uses a coprecipitation method to make manganese oxide to use as the flowable electrode material in the Electrochemical Flow Capacitor, a technology for grid energy storage. Photo credit: Victoria Edwards. 8. Ph.D. student James Nathaniel prepares a thin film sample. Photo credit: Victoria Edwards. 3141 Chestnut Street LeBow 344 Philadelphia, PA 19104 9. Two-dimensional Ti3C2 layers called MXene. This image is a combination of three separate Scanning Electron Microscope (SEM) images on MXene particles (Turtle, Butterfly, and the cave). The width of the cave is about 3µm. Award: Second Place in “Science as Art” competition in MRS Fall 2012. Credit: Babak Anasori, Michael Naguib, Yury Gogotsi and Michel W. Barsoum (MAX phase group and Drexel Nanotechnology Institute), Zeiss Supra 50VP SEM in Drexel University’s Centralized Research Facilities (CRF). Phone 215.895.2323 Fax 215.895.6760 Web www.materials.drexel.edu Email materials@coe.drexel.edu 10. Fluorescently-stained biomimetic aggrecan (developed in the Marcolongo Lab) has been injected into intervertebral tissue and shows uniform distribution within the tissue resulting in molecularly engineering the intervertebral disc. This strategy is being explored as an injection to alleviate early disc degeneration leading to back pain. (Image taken by Sarah Lightfoot Vidal, B.S./M.S. 2013) 11. Getting suited up for the popular slime demo at Philly Materials Day 2013.