Discrimination of surface alteration based on digital processing of airborne multispectral data Kazuya Okada, Takeo Yokoyama Sumi tomo ~1etal Mining Co., Ltd. 5-11 3 Shimbashi Minato-ku Tokyo 105 JAPAN and Katsuo Arai Earth Resources Satellite Data Analysis Center 2 4-5 Azabudai Minato ku Tokyo 106 JAPAN Comission VII ABSTRACT This study concerns the analysis of spectra from a high-spectral resolution airborne spectroradiometer. Airborne data are severely affected by two factors, topographic effects and atmospheric effects. These effects must be removed to compare airborne data with laboratory measurements of reflectance spectra. Three techniques were applied in analyzing the Yerington and Virginia City (Nevada, U.S.A.) data; Logarithmic Residual, Flat Field Correction and Band Ratio. Interpretation based upon a combination of the Logarithmic Residual analysis and field measurements provided successful delineation of the alteration mineralogy. INTRODUCTION High spectral resolution airborne and field surveys were carried out over the Yerington and Virginia City mining areas in Nevada. The Yerington district was picked for research because it is a major, well exposed porphyry copper deposit, that is geologically (Dilles, 1984, Carten, 1986) and spectrally (Green and Lyon, 1984) well-studied. On the other hand, the Virginia City district is a typical example of vein-type silver and gold deposits, that is also geologically (Thompson, 1956) and spectrally (Elvidge and Lyon, 1984) ,~ell-studied . Recent studies with high spectral resolution remote sensing data have shown that the identification of individual alteration minerals is possible (Marsh and McKeon, 1983). However, researchers have been beset with many perplexing difficulties during the analysis of spectral curve-shape. Radiance spectra acquired in aircraft based spectrometers bear little resemblance to laboratory measurements of reflectance spectra. Though the cause or mechanism of these phenomena has yet to be sufficiently clarified, topographic and atmospheric effects can be considered as the main factors. In point of mineral exploration, airborne data must be converted into a form similar to reflectance spectra. Several practical methods for extracting mineral-related features have been developed (Green and Craig, 1985). In this study the authors appl ied three techniques ; Logarithmic Residual, Flat Field Correction and Band Ratio. 1. 2. INSTRUMENTATION AND DATA ACQUISITION The airborne survey was flown with the GER (Geophysical Environmental Reserch Corp.) visible and infrared spectroradiometer system. This system has 512 channels covering the visible to near infrared (VNIR; 400nm to 1000nm) region, where the iron minerals have characteristic spectral features. The short wave infrared (SWIR; 2000nm to 2500nm) region, where the clay and other alteration minerals have distinctive absorption features, is covered with 64 channels. Each channel has an individual detector and the measurements are m de simultaneously. The airc aft was flown at the barometric altitude of 8500 feet for the major part of the survey. Three traverses were flown at a hi er al tit ude of 20000 feet in order to study the effect of the pixel-size. The flying speed was about 110 miles per hour. The 8500 feet ASL is rou ly translated to 2000 feet above the average ground surface of 6500 feet elevation, so that an instantaneous field of view (IFOV) was 60 feet square. At a hi er altitude, the IFOV was 60 feet along the flight path and 400 feet perpendicular to it. The airborne survey was made between 9: 00 AM and 2: 00 PM fixing upon clear days; May 29 and 30, 1986. The field survey was carried out with the GER IRIS Mk-II and Mk-III system, which cover the 350nm to 3000nm region with the spectral bandwidth of 2nm (350nm to 1000nm) to 4nm (1000nm to 3000nm). IRIS is a dual beam system that looks at a target and a reference material (barium sulfate plate) simultaneously so that reflectance spectra can be measured with immunity to variations in the source illumination. This immunity has merits in the fields because a measurement takes not less than 10 minutes, which depends on the i lumination level, and variations in this period in the solar illumination cannot be disregarded. Field spectra were converted to percent reflectance by dividing the target radiance by the reference spectra. 3. GEOLOGY The Yerington district is composed of Cretaceous metamorphosed volcanics and marine sediments which were intruded during the Jurassic by Yerington batholith and Shamrock batholith, and of early Mesozoic pluton. Regional metamorphism converted these Mesozoic rocks into greenschist facies; chlorite, epidote, zoisite, albite, quartz and clay minerals. The Mesozoic system is unconformably overlain by Oligocene ignimbrite and Miocene andesite, basalt and sedimentary rocks. Figure 1 shows a geologic map of the Yerington disrict (Oilles, 1984). The Virginia City district is composed mainly of post-Cretaceous volcanics. The most extensively exposed formations are the Miocene Kate Peak formation and the Miocene Alta formation composed of andesitic lava and pyroclastic rocks. The Alta formation and the lower Kate Peak formation were subjected to hydrothermal alteration; propylitization, a gillization and al nitization. Major silver and gold deposits were mined from the Comstock Lode district. Figure 2 shows a geologic map of the Virginia City district (Thompson, 1956). 11930 15 EXPLAIIA TI ON ~KE -r'" F.ult ASIA Qu.tO AlluvllJlll TertE2] V~!~~~~l!ry LUDWIG Ij Rocks Cr.t~ Gronlte o PlutonIc Rocks t~::;:)Sh4..,.od 8athollth c=::J GranodIorite c::::::::::J Porphyry " ~ ~ v~~~:~~~~ ~!ring ~ f~TIP~;~:~:~\~:e ~ Verlngton 8othollth J-l1D Granodlori ta J-li Sed lmentary Rocks IT:rfl 1i ~\I'5Suk Olorite } ~ A~d~! ~~;F~! ~:~: o 10 t 15 KM , Figure 1 Geologic map of the Yerington district (after Dilles) 119..... 5· EXPlANATtON 39"30' ,-----~ ,ndlJ HOIOC<,.. } AlJuyjum a YOYAf;er 10clu lnclud_z Sfumb{)<llt Hllu Plelstocene QUATERNARY PI,iSlo" ... ) QUATERNARY and ANt> TERTIAKY('!J AAyoUl~ PI~ne{'~) (P1Jo«,,~? aM l'teuloC4~ J. 14"",· .. ItS A,.tlttsiu(P1,lsllX'itl&4?j.• Ad JrkOltlkut ~ok 0I1t4~ &u.olr (RriI'OC"nI~J lOTI:] fI.iu"",,,,, }QUATERNAR1f Ro_ ANU TERTIA RY loci lAUt.eIOWA FormaltoD PI",«", ~ "'"",sWN Df bU/1Jric lIII'UIu"~ .ru:t haulr CEJ E:J } Pho«nc WashinJ;lon Hill Rhyoblt } fI"'~.n' and MIOcene COAl Valley Fornu lion E] Kate ruk Formalion 'Rhyodoclu '0 .nd~,j't flows. b""CCIIU.IIMut'~siw,tXJt.r B o" ... io)()n vanodlOriu:. TERTIARY MK>crne ~ All" form,lIKln Chit!ly IJ'IO('UI.(' (JOWl IJfld flowbrtt"cil&J ~ H.n(o,d )hll RhyolHe Tuff I CRETACEOUS AND TRIASSIC(?) ~ ~ hkaoche:d IQCA.sof the J.:alt f'c,ik and Aha FQrm;Jl~n~ Comloct Normal r... ult IJ,ashf'd "",h~rr 'PP'OHI'I'IQllly Ivc.tI~;J &r Q,u;l b",U UII d()w'*'hTC ....1t ~idC! eDDH-4 o 1 2 MILES f~-'-,-----' - " - - - ' - - - - ' - - - - -_ _ _ _ _- ' l19~ GtolOICY mu·.Jdu,,J .. llu 1 tlf>lllpwn(l '1S6. pi 3gel~' 30 .. Sampk locality J) Figure 2 Geologic map of the Virginia City district Thompson) VII (after 4.FLAT FIELD CORRECTION Flat field correction is a method that uses a pixel or a number of pixels which are spectrally flat as references. Every pixel is devided by the reference spectra. Basalt Hill located in the southwestern part of the Virginia City area is underlain literally by basaltic rocks. Figure 3 shows a reflectance spectrum of a basalt sample which was collected at Basalt Hill. The reflectance curve is flat in the interesting region (500 to 2500nm). Radiance spectra acquired over Basalt Hill were employed as references. Figure 4 and 5 show an unprocessed radiance spectrum (SWIR) over an altered area and the result of Flat Field Correction. The resulting spectrum has a distinctive absorption feature of 2210nm clay mineral. R E F L E 80 C T A N C E 60 40 20 25=00 WAVE LENGTH Figure 3 3. R oq (* 10- 3 nm Reflectance spectrum Basalt ) 2.50 A D I 2. 00 A N 1. 50 C E 1. 00 R A T I 0 0.50 WAVE LENGTH nm Figure 4 WAVE LENGTH nm Unprocessed radiance spectrum 5.LOGARITHMIC RESIDUAL Logarithmic Residual following relationship. T (Log Figure 5 Residual) Flat field spectrum is corrected based upon the (1) j where X iA Ti PiA IA Radiance In channel A at point i Topographic factor at point i Reflectance of the terain in channel Solar illumination in channel A The Log Residual Y iA is defined by the Xi. X. A following +- X .. A at point i formula. (2) where X. A M- 1 Xi. N X .. 1 Li og X iA LA 1 og Xi,\. (MN) 2:. 1 LA log Xi,\. Figure 6 shows the result of Log Residual for the same The Log Residual spectrum shows a location as Figure 4 and 5. feature of 2210nm clay. The weak absorption distinctive 2350nm is cha acteristic of sericite. centered nea l 0 G R E S I D U O. 06 O. 04 O. 02 O. 00 -0. 02 L -0. 04 WAVE LENGTH nm Figure 6 Log Residual spectrum Figure 7 and 8 show another comparison of Flat Field Correction and Log Residual. Log Residual spectrum has a doublet near 2200nm which indicates the characteristic of kaolinite. This doublet can be hardly detected even in the labolatry measurement of rock samples. The Flat Field Correction could not extract the doublet. 1. 1 l 0 G 1.0 R A O. 04 O. 02 R E O.S O. 00 S I D U -0. 02 T I 0 A O. 7 L WAVE LENGTH nm Figure 7 Flat field c rrected spectrum -0.04 WAVE LENGTH nm Figure 8 Log Residual spectrum Comparing figure 7 to figure 8, so far as extracting the mineral-related feature, it is evident that Log Residual is superior to Flat Field Correctio Flat Field Corrected spectrum is formularized as follows on referring to equation (1). Z iA (3 ) The topographic effect can be considered as a constant with the wavelength, so that the ratio of topographic factors could not have influence on the curve-shape but shifts the average level. The assumption used in equation (1) holds valid when the solar illumination can be regarded as a function of wavelength. The fluctuations with time in the solar illumination would of Flat Field Correction. The reduce the efficiency difference of the data acquisition time between the target The fluctuations point and the reference is about 30 minutes. a fatal effect on the Flat Field in this period had Correction. 6. BAND RATIO Band Ratio is used widely because it is very convenient to extract spectral features from a large quantity of data such as satellite data. Figure 9 shows a ratio profile of channel 365 (BOOnm) over channel 220 (600nm). Chlorophyll pigments cause strong absorption in the visible region so that the vegetation has a reflectance plateau in the near infrared region. The high values shown in Figure 9 represent vegetated area. minerals, all the channels must be In order to identify the taken into consideration. However, Band Ratio is very useful as an expedient method to throw light on the remote sensing data at the first stage. 8 0 0 n m }''' 'I I I I I I I I I 6 - 4 - 2 - / 6 0 0 n m III 0 ~A 100 200 300 400 500 POINT Figure 9 7. Ratio profile channel 365 / channel 220 IDENTIFICATION OF ALTERATION MINERALS Of the three techniques investigated, the Log Residual was the best. The resul ting spectra could be directly compared wi th the ref lectance spectra. However, visual examinat ion of the spectral curve-shape takes much time. There were 94,928 spectra to investigate, so that the identification of individual minerals was done automatically by a computer to some degree. The algorithm was based upon the combination of the absorption detection by averaging differentiation and the correlation with the simulated standard reflectance spectra. The following are the selected typical samples of Log Residual spectra and the standard reflectance simulated from the field measurements by resampling the digital readings into the same wavelength centers as the airborne spectroradiometer in order to calculate correlation coefficients. (a) Alunite Alunite has and 2335nm. absorption bands centered L E C O. 00 T S A N C I D U A L 2210nm E F O. 02 R E 2165nm, R L 0 G near E Yo -0,04 WAVE LENGTH nm WAVE LENGTH nm Figure 10 Log Residual spectrum, Alunite Figure 11 Simulated standard reflectance, Alunite (b) Calcite Calcite has an absorption band centered near 2340nm. R L 0 O. 02 R O. 00 G E F L E C E T A N S I D C E U -0. 04 A L Yo -0. 06 WAVE LENGTH nm Figure 12 Log Residual spectrum, Calcite WAVE LENGTH nm Figure 13 Simulated standard reflectance, Calcite (c) Chlorite Chlorite has an absorption band centered near 2340nm. L 0 G O. 02 R E 0.01 E F L R E S O. 00 I 0 U A -0.0'1 Figure 14 C T A N C E WAVE LENGTH nm WAVE LENGTH nm Log Residual Figure 15 spectrum, Chlorite Simulated standard reflectance, Chlorite (d) Epidote Epidote has absorption bands curve-shape bears resemblance to 16 and 17. l 0 G near 2340nm. The as shown In Figure R E F O. 02 L E R E S I D U centered chlorite C T A O. 00 N C E A -0. 02 L Yo WAVE LENGTH nm WAVE LENGTH nm Figure 16 Log Residual spectrum, Epidote Figure 17 Simulated standard reflectance, Epidote (e) Gypsum Gypsum has a wide and shallow absorption band from near 2140nm to 2310nm which is formed by several absorption bands. L 0.04~mmmrnmmmrnm=~~n=~~~~ G 0.02 R E O. 00 o S I -0.02 D U -0. 04 A l -0.06 -0. R E F L E C T A , N C E I : : 1 : ~~t'I!!l!i!!lI~g!b!OI!!!I!j."!2~loo WAVE LENGTH nm WAVE LENGTH nm Figure 18 Log Residual spectrum, Gypsum Figure 19 Simulated standard reflectance, Gypsum (f) Montmorillonite Montmorillonite has an absorption band centered near 2200nm. Montmorillonite can be distinguished from sericite by lack of 2350nm absorption. L 0 G R E F l O. 02 E C R E S T O. 00 A N C I D U A L E Yo WAVE LENGTH nm Figure 20 Log Residual spectrum Montmorillonite WAVE LENGTH nm Figure 21 Simulated standard reflectance IVlontmori lloni te Figure 22 Alteration map of the Yerington district 1,19040'" Background II ALunite + * Gypsum 0 Montmori Honi tEl Ca1.cite Kao Li nite 39°20'N x Serici fa 6 Ch1.orite 0 Epidote Kao Linite or ALunite o 39°15'/1 Figure 23 Alteration map of the Virginia City district 5 10km (g) Sericite and Kaolinite The typical Log Residual spectra are shown in Figure 6 and 8. of sericite and kaolinite Figure 22 shows the result of the automatic identification of alteration minerals in the Yerington district. The notable alteration pattern composed mainly of epidote and chlorite was detected in the Yerington batholith that has undergone intrusion and mineralization several times. In the Tertiary facies, montmorillonite is common in Mickey Pass tuff and Singatse tuff. Typical gypsum spectra were detected in the southwestern part of Singatse Range where a sedimentary gypsum deposit was once mined. Figure 23 shows the spectral-alteration map of Virginia City district. This region is characterized by kaolinite, alunite, sericite and montmorillonite. These minerals were detected in an order that reflects the alteration intensity. e. g., transitional pattern from sericite to alunite. This result has proven that the high resolution spectral survey is an effective means for zoning of the alteration area. Problems of mixed layer minerals and of mixed pixel, i. e. , the ambiguity introduced by the heterogeneous composition of each pixel are left pending. However, the fact that the low and high altitude surveys have detected the same mineral zones leads to the conclusion that the IFOV was not critical as the spectral resolution in the investigated areas. 8. CONCLUSIONS The airborne high-resolution spectral surveys over the Yerington and Virginia City mining areas have proven to be an effective means of identifying alteration minerals which are important for mineral exploration. The Log Residual spectra have mapped the surface mineral pattern in fine detail along the traverses. In accord with the field spectral survey, the result provided successful delineation of the alteration mineralogy. The computerized mineral identification system that has still been under development will provide useful means for future research into remote sensing data of larger area with a large number of spectral channels. 9. REFERENCES Carten, R.B .. 1986, Sodium--Calcium Metasomatism: Chemical, Temporal. and Spatial Relationships at the Yerington, Nevada. POL'phyry Copper Deposit; Economic Geology. Vol.8l. pp.1495-I519 D ill e s , J . H ., 1 983 . The I' e t I' 010 g y and G e 0 c hem i s try 0 f the Ye r i n g ton bat hoI .i t h a n d the Ann ~1 a son Po r p h y r y Cop per De DOS it. We s t ern Ne v a d a ; Stanford Ph.D. Thesis Elvidge. C.D., Lyon, R.J .P., 1984, Mapping Clay Alteration in the Virginia Range - Comstock Lode, Nevada with Airborne Thematic Mapper Imagery; Int. Symp. on Rem. Sen. of Env., Third Thematic Conference, Hem. Sen. for Exploration Geology, p.16J 170 Green, A.A., Craig. M.D .. 1985. Analysis of Aircraft Spectrometer Data with Logarithmic Residuals; Proceedings of the /\irboene Imaging Spectrometer Data Analysis Workshop. pp.111-1I9 Green, I~.O., Lyon, H.J.P .. 1981. Mapping Mineral Alteration with Airborne Thematic Mapper Imagery in the Ann-Mason Region, Yerington [jistl'ict. Nevada; Int. Symp. on Rem. Sen. of Env.,· Third Thematic Conference, Rem. Sen. for Exploration Geology, pp.775-784 Mar s h , S . E., ~j eKe 0 Jl , J. B., 1983 . I n t e g rat c dAn a 1 y sis 0 f II i g h - He sol uti 0 n Field and Airborne Spectroradiometer Data for Alteration Mapping; Economic Geology, Vo1.78, DP.Gl8 632 Thompson, G.A .• 1956, Geology of the Virginia City (Juadrangle, Nevada; U.S.G.S. Bulletin 1042-C 1