Miami-Dade Limestone Products Association 13292 N.W. 118th Avenue Miami, FL 33178 L-31N Seepage Management Field Test The Performance of a Partially Penetrating Seepage Barrier along the L-31N Canal July 2011 Prepared on behalf of the Miami-Dade Limestone Products Association by MacVicar, Federico & Lamb, Inc. West Palm Beach, Florida L-31N Seepage Management Field Test Lake Belt Seepage Management Demonstration Project Background Recent investigations by the U.S. Geological Survey and the South Florida Water Management District have documented distinct layering within the Biscayne Aquifer and identified preferential flow zones within specific layers in the area of the L-31N Canal, which defines the northern portion of the eastern boundary of Everglades National Park (ENP). One of the high flow layers is the Miami limestone, which makes up the top 5 to 10 feet of the aquifer in the vicinity of the canal. It is this top layer of porous rock that appears to serve as a conduit allowing water from the wetlands within ENP to flow into the L-31N Canal. The proposed field test of a partially penetrating seepage barrier was described in an earlier report produced in February 2009. The proposal was presented to the Lake Belt Mitigation Committee, as well as technical staff at Everglades National Park and the South Florida Water Management District. The SFWMD issued a right of way permit for the construction of the test project, including monitoring wells, on the berm between the L-31N Levee and Canal at a location one mile south of Tamiami Trail. The goal of the test was to document the performance a of partially penetrating flow barrier in reducing groundwater interception by the canal. The test consisted of constructing a cement-bentonite flow barrier in a narrow trench extending through the Miami limestone layer of the aquifer just west of the L-31N Canal. The test barrier was located with its midpoint adjacent to the northern cluster of monitoring wells installed as part of the L-31N Seepage Management Pilot Project. (Figure 1) Site Layout Figure 2 shows the geologic cross section at the monitoring well cluster from USGS Scientific Investigations Report 2005-5235 (Cunningham, et al). The Biscayne Aquifer in this area is generally considered to consist of the Miami oolite in the upper section and the Ft. Thompson formation below. Below the Ft. Thompson is the lower permeability Tamiami Formation, which is not considered to be part of the Biscayne Aquifer. At this location, the Miami oolite, shown as the uppermost light blue layer in Figure 2, is 6 to 8 feet thick and is classified as a conduit flow zone with very high permeability. The salmon colored layer below the Miami oolite is classified as a leaky, low permeability layer in the USGS report. A two foot thick layer of fine sediment has accumulated on the bottom of the canal impeding hydraulic interaction between the canal and the aquifer directly below the canal. It is likely that the Miami oolite layer is a significant source of groundwater flow from ENP to the L-31N Canal. This test was designed to help determine the extent to which a seepage barrier through the top layer of the aquifer would reduce the unwanted diversion of water from ENP to the adjacent canal. A one thousand linear feet long cementbentonite seepage barrier, 28 inches wide and 18 feet deep, was constructed in the canal right-of- way between the L-31N Canal and Levee. July 2011 2 L-31N Seepage Management Field Test Figure 1. Project location. July 2011 3 L-31N Seepage Management Field Test Figure 2. Schematic diagram of test area cross-section. Well core and layer coloring are taken from USGS Scientific Investigations Report 2005-5235 (Cunningham, et al, 2006). The Miami oolite (top blue layer) is categorized as a conduit flow zone in that report. Monitoring Well Instrumentation The wells shown in Figure 3 were equipped with instruments to allow the continuous recording of water level, flow direction, flow velocity and water temperature. It was expected that by constructing the barrier with the midpoint adjacent to the monitoring wells, the impact of the barrier on groundwater flow would be detected. Changes in both the velocity and direction on flow in the shallow groundwater well were predicted to occur. However, the data produced by the instrumentation to detect velocity and direction proved difficult to interpret in the heterogeneous, complex flow paths through the rock in that location. The most informative data seemed to be the simple water level readings collected in each well, with the flow direction in the wells near the end of the test wall also proving useful. Figure 3. Location of seepage barrier within the L-31N Canal right-of-way and sketch of monitoring well placement. July 2011 4 L-31N Seepage Management Field Test Monitoring Results For the purpose of providing an initial look at the impacts of installing the barrier, the data set was divided into pre-and post-construction periods of 30 days each. With the high transmissivity of the aquifer, any changes to the groundwater flow as a result of the test barrier were expected to be subtle, and difficult to detect. The plot of the stage data in Figure 4 shows a greater stage difference between the canal and the recording wells on the west side of the barrier after the slurry wall was constructed. However it is impossible to tell whether the difference is caused by the barrier or simply by changing conditions in the area. The L-31N Canal is actively managed during the wet season to keep the stage within a narrow range, while the wet season rainfall tends to increase the stage in the Park. Both of these conditions are noticeable from the data collected after the wall was installed. Water Level Data Before and After Barrier Installation 8.0 Center Well D Center Well C Well 425 Well 475 L-31N Stage ENP Stage 7.5 Stage 7.0 6.5 6.0 Barrier Installed 5.5 7/4 7/18 8/1 8/15 8/29 9/12 9/26 10/10 Figure 4. Water level data from monitoring wells, L-31N Canal and adjacent wetland in ENP. To try to isolate the effect of the test barrier, plots were developed of the stage difference between the wells just west of the barrier and the canal for 30-day periods just prior to and after the construction of the barrier. Figure 5 is the plot of the stage difference between the shallow groundwater well about 25 feet west of the barrier and the canal stage about 30 feet to the east. The plot shows an increase in the stage difference after construction and also a decrease in the r-squared value of the relationship between the groundwater and the canal. Both of these would indicate that the wall had the desired effect of separating the canal from the shallow groundwater. However, a similar plot, Figure 6, for a station about a mile to the south exhibits similar characteristics, and this location could not be affected by the test barrier. With the extremely high transmissivity July 2011 5 L-31N Seepage Management Field Test of the aquifer in this location, a significant impact on the stage either in the surface water or the shallow groundwater was not expected. The changes seen in these data from before and after the construction are more likely a response to the changing conditions than to the impact of the barrier itself. That is not to say that the barrier would not be effective at reducing groundwater flow to the canal, only that the stage data alone do not provide definitive evidence of the success or failure of the concept. Figure 5. Well D is the shallow groundwater stage just west of the midpoint of the slurry wall. The L-31N Canal is just east of the wall. The difference in the relationship between the two data groups is a function of the changing hydrologic conditions as well as the construction of the wall. 6.60 Pre and Post Slurry Wall Construction: NESS20-29 Site R² = 0.3303 Enp Stage (NESS20-29) 6.50 6.40 6.30 R² = 0.5827 6.20 6.10 prior to construction after construction 6.00 5.85 5.90 5.95 6.00 6.05 L-31N Canal Stage 6.10 6.15 6.20 Figure 6. Site NESS20-29 is a groundwater stage about 500 feet west of the L-31N Canal and about a mile south of the test wall. The presence of the test wall has no effect on this site. July 2011 6 L-31N Seepage Management Field Test In addition to the ground and surface water stage data, information on groundwater flow velocity and direction was also collected. The flow velocity and direction data is difficult to interpret and no definitive conclusions regarding the performance of the barrier could be derived from the data set. Barrier installed Figure 7. Data collected from the velocity sensor before and after wall construction. July 2011 7 L-31N Seepage Management Field Test Additional Testing Due to the uncertainties in determining the effectiveness of the seepage barrier, the following additional testing/evaluations were performed during 2010 and 2011: • Groundwater stage analysis • Groundwater temperature changes • Groundwater tracer test • Canal flow measurement analysis • Barrier physical integrity testing Groundwater stage measurements In preparation for the tracer test, a total of 40 shallow and deep monitoring wells were installed in the vicinity of the seepage barrier and at a control site (without the seepage barrier) approximately 500 feet to the south (Figure 8). The well locations and depths (with the exception of four shallow wells at the ends of the barrier) were identical. Figure 8. Tracer test monitoring locations. The top of the low permeability freshwater limestone layer (Q4 marker bed) between the Miami oolite and the Ft. Thompson formation was identified at a depth of approximately 14 feet below land surface at the site. The shallow monitoring wells were installed both east and west of the barrier and completed in the Miami oolite above the Q4 layer (with a total depth of 11 feet and well screen between 7 and 11 feet). The deep monitoring wells were installed only west of the barrier and completed in the Ft. Thompson formation below the Q4 layer (with a total depth of 40 feet and well screen between 20 and 40 feet). July 2011 8 L-31N Seepage Management Field Test Groundwater stage data were collected periodically in the 6 shallow upgradient tracer test dye introduction wells and the associated downgradient shallow and deep monitoring wells (Appendix 1). In addition, stage data in the USGS monitoring well (G-3576) located one mile west of the barrier and in the L-31N Canal (AVM-1) were obtained from the USGS website. At the southern monitoring site (with no barrier), the flow at the project site was from the west (from ENP to the L-31N Canal) during the west season and from both the west (ENP) and east (canal) during the dry season (Figure 9). Figure 9. Average water levels at the southern control site without the barrier. The groundwater stage in the vicinity of the barrier also varied seasonally (Figure 10). The top graph shows that the average groundwater stages in the deep and shallow monitoring wells at the control site were essentially identical, suggesting minimal flow between the Miami oolite and the Ft. Thompson formation. However during the wet season, the deep water levels at the barrier site are higher, suggesting some upward flow due to the installation of the barrier. Similarly, the bottom graph shows that the average water level in the shallow west and east wells at the control site are similar (with a slight positive gradient towards the canal during the wet season). The wells are approximately 20 feet apart and the slight gradient reflects the overall westerly flow from ENP to the L31N Canal. During the wet season, the water levels in the west wells at the barrier site are noticeably higher than the east wells, suggesting that the barrier is interrupting the shallow flow resulting in higher upgradient water levels. July 2011 9 L-31N Seepage Management Field Test Figure 10. Comparison of water level differences in the tracer test monitoring wells. Prior to these measurements, it was unclear whether the 1000-foot barrier would influence groundwater stages because of the high permeability of the Biscayne aquifer and groundwater flow around the barrier. However, the seasonal changes observed indicate that the barrier does affect both lateral and vertical groundwater flow. Groundwater temperature measurements Temperature data were collected periodically in the 6 shallow upgradient tracer test dye introduction wells and the associated downgradient shallow monitoring wells, as well as in the marsh and L-31N canal immediately west and east of the middle of the barrier wall (Appendix 1). As would be expected, the temperatures in the marsh and canal varied seasonally, while the temperature changes in the shallow monitoring wells were less significant (Figure 11). During the wet season, the average temperatures in the wells near the barrier wall were lower than the temperatures at the control site suggesting that the groundwater adjacent to the barrier was perhaps more stagnant (with the lower temperatures reflecting temperatures from the cooler dry season). July 2011 10 L-31N Seepage Management Field Test Figure 11. Seasonal changes in average temperatures. This is also suggested from the changes in temperature between the monitoring events (for example between August and October 2010 - Figure 12). The temperatures decreased in the marsh and canal during this period. The temperatures at the control site monitoring wells show similar (but smaller) decreases. However, the monitoring wells adjacent to the barrier did not show a temperature change. Figure 12. Temperature changes between monitoring events. July 2011 11 L-31N Seepage Management Field Test Tracer Test The tracer test was designed by Tom Aley of the Ozark Underground Laboratory (OUL) in Missouri, which has extensive experience in conducting tracer tests in karst environments. All of the laboratory dye analyses were also performed by OUL. Mr. Aley’s analysis of the preliminary results and all of the test results are included in Appendix 2. As shown in Figure 8, a total of 40 shallow and deep monitoring wells were installed in the vicinity of the seepage barrier and at a control site (without the seepage barrier) approximately 500 feet to the south. Six of the shallow upgradient wells were used to introduce the dye into the Miami oolite above the Q4 layer. In addition, a total of 40 canal monitoring stations with the sampler suspended at approximately the same depth as the shallow monitoring wells were established at both sites. The canal stations were installed in groups of four (50 feet upstream of the dye introduction well and 0, 50, and 100 feet downstream). The relative locations and depths of the wells and canal stations relative to the barrier wall and the site geology are shown in Figure 12. Figure 12. Geologic cross-section showing monitoring locations. The dye concentrations were analyzed using activated carbon samplers, which provide an integrated concentration for the period during which they are suspended in water. The activated carbon continually adsorbs and accumulates the dye, which is eluted and quantified in OUL’s lab after collection. Two sets of carbon packs were placed in the wells and canal prior to dye introduction on October 13, 2010 to check for potential dye interferences (there were none). Carbon packs were collected from the wells and canal on day 1, 2, 4, 7, 14, 21, 28, 35, 49, 63, and 77 after introduction of the tracer. Three dye introductions were performed at both the control and barrier sites, with Rhodamine WT July 2011 12 L-31N Seepage Management Field Test in the north and south wells and Fluorescein in the center wells. The different dyes were utilized to be able to potentially identify flow paths. Results 1. Dye was detected in both the canal and shallow downgradient well samples at both the barrier and control sites in the first set of samples collected approximately 24 hours after dye introduction. The dye could initially be identified as entering the canal at several discrete locations, but over time due to canal flow and wind, the dye spread over a much larger area. Figure 13 shows the Fluorescein distribution two days after dye introduction at the center location at the barrier and control sites. Figure 13. Fluorescein detections after two days – barrier (left) and control (right) sites. 2. Four months after dye introduction, water samples were obtained from the dye introduction wells. Dye could still be visually identified at the introduction wells at the barrier site, while no dye was visible at the control site (Figure 14). These results suggested that the groundwater flow was influenced in the vicinity of the barrier. Figure 14. Dye introduction wells at completion of tracer test (four months after introduction). 3. The influence of the barrier was also suggested by the cumulative dye concentrations in the shallow downgradient monitoring wells (Figure 15). The wells at the barrier site had higher cumulative concentrations than the wells at the control site, suggesting more stagnant flow conditions in the vicinity of the barrier. The low concentrations in the northern well at the control site can be explained by the observation that the July 2011 13 L-31N Seepage Management Field Test dye, rather than moving directly east to the canal, moved to the southeast and missed both the shallow monitoring well and canal station east of the introduction well. Cumulative Dye Concentration 30000 Wall N40 No-Wall S40 25000 20000 15000 10000 5000 0 Day 1 Day 2 Day 4 Day 7 Day 14 Day 21 Day 28 Day 35 Day 49 Cumulative Dye Concentration 6000 Wall N41 No-Wall S41 5000 4000 3000 2000 1000 0 Day 1 Day 2 Day 4 Day 7 Day 14 Day 21 Day 28 Day 35 Day 49 Cumulative Dye Concentration 50000 Wall N42 No-Wall S42 40000 30000 20000 10000 0 Day 1 Day 2 Day 4 Day 7 Day 14 Day 21 Day 28 Day 35 Day 49 Figure 15. Cumulative tracer concentrations measured in downgradient shallow wells. 4. The cumulative canal results were more variable than those for the wells. The cumulative concentrations for each dye introduction location were calculated by adding the concentrations in the 4 canal stations associated with the dye introduction, minus four times the concentration of the dye detected at the nearest upstream canal station. The dye moved downstream in the canal during the testing period and the purpose of subtracting the concentration at the upstream station was to eliminate any dye that originated from an upstream dye introduction. There was not a consistent relationship between the cumulative concentrations at the barrier and control sites (Figure 16). Higher concentrations were detected in the southern canal station group at the control site (relative to the barrier site), which is what would be expected as a result of greater groundwater flow at the control site. The same relationship might have been detected at the northern canal station group, but at the control site it was observed that the dye was entering the canal south of the canal station directly east of the introduction well and therefore the overall control “group” concentration was lower. However, the center canal station group showed the opposite relationship with a higher cumulative concentration at the barrier site. This result raised the question of whether there was potentially a wall construction issue (perhaps due to a bad seam) in the center of the barrier. July 2011 14 L-31N Seepage Management Field Test Cumulative Dye Concentration 5000 Wall 250 4000 No-Wall 250 3000 2000 1000 0 Day 1 Day 2 Day 4 Day 7 Day 14 Day 21 Day 28 Day 35 Day 49 Cumulative Dye Concentration 25000 No-Wall 500 Wall 500 20000 15000 10000 5000 0 Day 1 Day 2 Day 4 Day 7 Day 14 Day 21 Day 28 Day 35 Day 49 Cumulative Dye Concentration 50000 40000 Wall 750 No-Wall 750 Day 2 Day 7 Day 14 Day 21 Day 28 Day 35 Day 49 30000 20000 10000 0 Day 1 Day 4 Figure 16. Cumulative tracer concentrations measured in canal samples. 5. With one exception (the northern well at the control site), dye was not detected in the deep downgradient wells at either the barrier or control sites during the wet season. This confirms the water level data which suggested slight upward flow at the barrier site during the wet season. Once the deep and shallow water levels became similar during the dry season, dye was detected in all of the deep downgradient wells. 6. A series of shallow monitoring wells were constructed upgradient of the barrier wall to potentially be able to identify flow around the barrier. Dye was detected in only one upgradient well (N7), which is located 50 feet north of the southern dye introduction well at the barrier site. Dye was first detected at low levels on Day 28, with much higher concentrations in all of five samples through Day 119. The potential flow to the north is considered anomalous, because it was anticipated that flow would be to the south in response to the regional southeasterly gradient. The shallow upgradient wells were constructed only 5 feet to the west of the barrier wall (because of the location of the levee) and it is thought that perhaps there were not additional upgradient detections because of low flow conditions immediately behind the barrier. Canal Flow Measurements The USGS monitors a group of acoustic velocity meters (AVM) in the L-31N Canal. These meters are located at distances 1, 3, 4, 5, and 7 miles south of Tamiami Trail. At AVM-1 and AVM-4, monitoring wells were installed immediately and one mile west of the L-31N Levee in order to define the water level gradient from the marsh to the canal. AVM-1 and the associated monitoring wells are located in the middle of the barrier wall. July 2011 15 L-31N Seepage Management Field Test The daily seepage flows into the L-31N Canal between Tamiami Trail and AVM-3 (which includes the barrier) and between AVM-3 and AVM-5 (2-4 miles south [downstream] of the barrier) were calculated using data before and after construction of the barrier in August 2009. The seepage flows were plotted vs. the stage differences between the marsh and canal at AVM-1 and AVM-4, respectively (Figures 17 and 18). The data suggest lower seepage rates in the northern section of the canal (which includes the barrier) after the barrier was constructed. By comparison, the seepage flows in the southern section of the canal are similar for the same time periods before and after construction of the barrier. These data suggest that the barrier may be influencing the seepage rate into the northern section of the L-31N Canal. Stage Difference vs. Seepage Flow, Pre and Post-Wall L-31N Canal AVM3-Upstream Flow vs. G3576-AVM1 Water level 700 Seepage Rate (cfs) Seepage calculated from S-335 to AVM3 Before 8/15/2009 After 8/30/2009 500 300 100 -100 -300 G-3574 -0.5 0.0 0.5 1.0 Stage Difference (ft) 1.5 AVM-1 2.0 G-3576 AVM3-Upstream Flow vs. G3574-AVM1 Water level 700 Before 8/15/2009 After 8/30/2009 Seepage Rate (cfs) 500 300 100 -100 -300 -0.6 -0.4 -0.2 0.0 0.2 0.4 0.6 0.8 1.0 Stage Difference (ft) 28 Figure 17. Pre and post-barrier stage difference vs. seepage flow at AVM-1. Stage Difference vs. Seepage Flow, Pre and Post-Wall at AVM-4 L-31N Canal AVM5-AVM3 Flow vs. G3578-AVM4 Water level 300 Seepage rate (cfs) Seepage calculated from AVM3 to AVM 5 Before 8/15/2009 After 8/30/2009 200 100 No Wall 0 -100 -200 G-3577 -300 AVM-4 -1.0 -0.5 0.0 0.5 Stage diffeence (ft) 1.0 1.5 2.0 1.5 2.0 G-3578 AVM5-AVM3 Flow vs. G3577-AVM4 Water level 300 Before 8/15/2009 After 8/30/2009 Seepage rate (cfs) 200 100 0 -100 -200 -300 -1.0 -0.5 0.0 0.5 Stage difference (ft) 1.0 29 Figure 18. Pre and post-barrier stage difference vs. seepage flow at AVM-4. July 2011 16 L-31N Seepage Management Field Test Barrier integrity testing As a result of the tracer test results (rapid detection of dye in the L-31N Canal and the variability in the cumulative dye concentrations at the different canal station groups), it was decided to investigate the integrity of the barrier wall. The initial investigation was performed using a cone penetrometer (CPT) at 13 different locations along the barrier. The cone penetrometer uses a steel probe, which includes sensors to measure tip resistance, sleeve friction, and pore pressure with depth as the probe was pushed into the barrier. These measurements were used to estimate the soil type. The Ardaman & Associates report, which includes the profiles for the 13 locations, is included in Appendix 3. The tip resistance was low and uniform (suggesting a clay material) to an average depth of approximately 13.4 feet for the 13 locations. The sleeve friction and pore pressure measurements were also uniform to a similar depth. At deeper depths, the tip resistance increased until the operator stopped advancing the probe at a tip resistance of approximately 100 tons/square foot. This “refusal” depth was reached at an average depth of approximately 16.7 feet for the 13 locations. The deeper high tip resistance measurements suggest “sandier” material. Figure 19 shows representative cone penetrometer depth profiles for CPT-3 (350 feet from the south end of the barrier), CPT13 (150 feet from the north end) and CPT-12B (250 feet from the north end). The cone penetrometer measurements suggested uniform clay material to depths ranging from approximately 10 feet in CPT-13 to 17 feet in CPT-12B and refusal depths ranging from approximately 12.5 feet in CPT-13 to 18 feet in CPT-3. The barrier wall was proposed to a depth of 18 feet, so it would be deeper than the low permeability hard layer at approximately 14-16 feet. Measurements taken during barrier construction indicated that the trencher cut the trench to a depth of greater than 18 feet and that the excavator removed the cuttings in the trench to a depth of at least 18 feet during emplacement of the cement-bentonite slurry. The CPT results suggest that the cement-bentonite barrier does not extend down to the design depth of 18 feet. As a result of the cone penetrometer tests, borings were drilled through the barrier wall at the locations of CPT-3 and CPT-13 (Figure 20). In both borings, the barrier showed consistent cement-bentonite slurry properties to depths of approximately 8 feet, with good to poor properties between approximately 8 and 14.5 feet, and a non-functional seepage barrier at depths below 14.5 feet. Several of the CPT holes remained open to the depth where the tip resistance began to increase (and presumably collapsed at deeper depths). Water levels were measured in the CPT holes and the depth-to-water was found to be at the same depth as the surrounding aquifer. These measurements suggest that the bottom of the barrier is acting as a porous connection to the aquifer. The depth measurement summary for each CPT location and the borings descriptions are included in Appendix 3. July 2011 17 L-31N Seepage Management Field Test Figure 19. Cone penetrometer measurements within the barrier. July 2011 18 L-31N Seepage Management Field Test CPT 3 0-8 8-10 10-12 12-15 15-19 CPT 13 0 - 10 10 – 13 13 - 15 15-17 17-19 19-20 Figure 20. Borings within the barrier adjacent to the CPT locations. July 2011 19 L-31N Seepage Management Field Test Conclusions The primary objective of the seepage barrier test was to document the potential effectiveness of a partially penetrating barrier along the eastern boundary of Everglades National Park. The barrier was shown to be effective in affecting groundwater flow based on the following: • Water level differences upgradient and downgradient of the barrier • Presence of dye remaining upgradient of the barrier at the end of the test • Changes in stage vs. AVM flow data before and after construction of the barrier • Tracer test cumulative mass balance differences in the canal and well samples at the barrier site vs. the control site. • Changes in temperature at the barrier site vs. the control site The following tracer test and barrier integrity results indicate that the cement-bentonite barrier does not extend to the design depth of 18 feet. At the two borings locations, the barrier was shown to not have been reliably installed at depths below 14 feet. • Early dye detections in the canal during the tracer test • Non-uniform cone penetrometer measurements at depth • Borings within the barrier. July 2011 20 Appendix 1 Groundwater stage and temperature measurements L-31N Water Level Data Depth to Water Station number Name Survey elevation 8/31/2010 10/5/2010 10/12/2010 11/10/2010 12/29/2010 2/9/2011 NORTH N11 NIN1 NIN2 NIN3 N40 N14/15 N41 N16/17 N42 N18/19 N13 North end Injection well - 250' Injection well - 500' Injection well - 750' Shallow downgradient -250' Deep downgradient -250' Shallow downgradient -500' Deep downgradient -500' Shallow downgradient -750' Deep downgradient -750' South end 9.27 8.30 8.79 9.67 7.73 7.72 7.68 7.63 7.66 7.72 8.64 3.06 2.06 2.54 3.41 1.59 1.49 1.49 1.38 1.59 1.51 2.47 3.07 2.08 2.56 3.38 1.61 1.51 1.51 1.38 1.61 1.50 2.49 3.21 2.19 2.68 3.53 1.71 1.66 1.63 1.50 1.71 1.66 2.61 3.23 2.28 2.76 3.61 1.76 1.71 1.67 1.55 1.75 1.72 2.67 3.57 2.56 3.04 3.94 2.03 2.02 1.96 1.92 1.98 2.04 3.00 3.98 2.99 3.49 4.38 2.43 2.44 2.35 2.33 2.38 2.44 3.41 Injection well - 250' Injection well - 500' Injection well - 750' Shallow downgradient -250' Deep downgradient -250' Shallow downgradient -500' Deep downgradient -500' Shallow downgradient -750' Deep downgradient -750' 9.50 8.75 9.25 7.95 8.07 7.77 7.82 8.00 7.96 3.30 2.55 3.03 1.78 1.90 1.59 1.63 1.82 1.77 3.32 2.56 3.01 1.81 1.91 1.59 1.64 1.79 1.75 3.46 2.71 3.16 1.93 2.04 1.73 1.80 1.95 1.90 3.53 2.79 3.28 2.02 2.13 1.81 1.86 2.02 1.98 3.87 3.12 3.59 2.33 2.44 2.10 2.19 2.36 2.32 4.34 3.57 4.04 2.77 2.91 2.55 2.61 2.79 2.75 SOUTH SIN1 SIN2 SIN3 S40 S14/15 S41 S16/17 S42 S18/19 Water level (NGVD29) Station St ti number Name SSurvey elevation 8/31/2010 10/5/2010 10/12/2010 11/10/2010 12/29/2010 2/9/2011 NORTH N11 NIN1 NIN2 NIN3 N40 N14/15 N41 N16/17 N42 N18/19 N13 North end Injection well - 250' Injection well - 500' Injection well - 750' Shallow downgradient -250' Deep downgradient -250' Shallow downgradient -500' Deep downgradient -500' Shallow downgradient -750' Deep downgradient -750' South end 9.27 8.30 8.79 9.67 7.73 7.72 7.68 7.63 7.66 7.72 8.64 6.21 6.24 6.25 6.26 6.14 6.23 6.19 6.25 6.07 6.21 6.17 6.20 6.22 6.23 6.29 6.12 6.21 6.17 6.25 6.05 6.22 6.15 6.06 6.11 6.11 6.14 6.02 6.06 6.05 6.13 5.95 6.06 6.03 6.04 6.02 6.03 6.06 5.97 6.01 6.01 6.08 5.91 6.00 5.97 5.70 5.74 5.75 5.73 5.70 5.70 5.72 5.71 5.68 5.68 5.64 5.29 5.31 5.30 5.29 5.30 5.28 5.33 5.30 5.28 5.28 5.23 Injection well - 250' Injection well - 500' Injection well - 750' Shallow downgradient -250' Deep downgradient -250' Shallow downgradient -500' Deep downgradient -500' Shallow downgradient -750' Deep downgradient -750' 9.50 8.75 9.25 7.95 8.07 7.77 7.82 8.00 7.96 6.20 6.20 6.22 6.17 6.17 6.18 6.19 6.18 6.19 6.18 6.19 6.24 6.14 6.16 6.18 6.18 6.21 6.21 6.04 6.04 6.09 6.02 6.03 6.04 6.02 6.05 6.06 5.97 5.96 5.97 5.93 5.94 5.96 5.96 5.98 5.98 5.63 5.63 5.66 5.62 5.63 5.67 5.63 5.64 5.64 5.16 5.18 5.21 5.18 5.16 5.22 5.21 5.21 5.21 7.21 6.48 5.93 7.11 6.47 5.95 6.95 6.30 5.84 6.92 6.24 5.82 6.40 5.85 5.71 5.98 5.50 5.35 SOUTH SIN1 SIN2 SIN3 S40 S14/15 S41 S16/17 S42 S18/19 G-3576 G-3574 L-31N canal USGS AVM-1 website L-31N Temperature Data Station number Name 7/30/2010 8/31/2010 10/5/2010 2/9/2011 27.1 27.2 27.3 28.4 27.7 26.9 26.0 29.7 28.1 28.4 28.7 29.1 28.5 27.8 27.8 30.2 28.6 28.6 28.9 28.7 28.5 28.2 28.3 29.7 23.6 23.3 23.6 23.2 23.0 23.6 24.1 23.2 Injection well - 250' Injection well - 500' Injection well - 750' Shallow downgradient -250' Shallow downgradient -500' Shallow downgradient -750' 30.2 30.8 30.2 28.5 29.8 27.9 30.3 30.1 30.4 29.7 30.2 29.0 28.6 28.3 28.7 29.0 29.1 29.1 21.6 24.1 22.4 23.0 24.2 24.1 staff gauge USGS AVM-1 walkway 31.0 29.1 29.6 28.1 27.5 26.7 17.1 22.5 NORTH (barrier) N11 NIN1 NIN2 NIN3 N40 N41 N42 N13 North end Injection well - 250' Injection well - 500' Injection well - 750' Shallow downgradient -250' Shallow downgradient -500' Shallow downgradient -750' South end SOUTH (no wall) SIN1 SIN2 SIN3 S40 S41 S42 ENP L-31N canal Appendix 2 Tom Aley (2011) Preliminary Results Analysis of Dye Tracing Results from a Slurry Wall Test, Miami, Florida Tracer Test results summary Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # U1131 N1 Station Name Shallow well-200' Date/Time Date/Time Date Placed Recovered Recovered 8/24/10 1335 Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm 8/31/10 1210 8/31/2010 ND ND U1124 N9 Shallow well-850' 8/24/10 1235 8/31/10 1130 8/31/2010 ND ND U1129 N14 Deep well-250'-22' 8/24/10 1325 8/31/10 1200 8/31/2010 ND ND U1130 N15 Deep well-250'-39' 8/24/10 1325 8/31/10 1200 8/31/2010 ND ND U1126 N18 Deep well-750'-22' 8/24/10 1255 8/31/10 1140 8/31/2010 ND ND U1127 N19 Deep well-750'-39' 8/24/10 1255 8/31/10 1140 8/31/2010 ND ND U1132 N21 Canal-0' 8/24/10 1350 8/31/10 1215 8/31/2010 ND ND U1125 N37 Canal-1000' 8/24/10 1245 8/31/10 1120 8/31/2010 ND ND U1128 N41 Shallow well -500' 8/24/10 1310 8/31/10 1150 8/31/2010 ND ND U1122 S1 Shallow well-200' 8/24/10 1215 8/31/10 1110 8/31/2010 ND ND U1114 S9 Shallow well-850' 8/24/10 1110 8/31/10 1015 8/31/2010 ND ND U1119 S14 Deep well-250'-22' 8/24/10 1205 8/31/10 1105 8/31/2010 ND ND U1121 S15 Deep well-250'-39' 8/24/10 1205 8/31/10 1105 8/31/2010 ND ND U1116 S18 Deep Well-750'-22' 8/24/10 1140 8/31/10 1035 8/31/2010 ND ND U1117 S19 Deep well-750'-39' 8/24/10 1140 8/31/10 1035 8/31/2010 ND ND U1123 S21 Canal-0' 8/24/10 1225 8/31/10 1115 8/31/2010 ND ND U1115 S37 Canal-1000' 8/24/10 1120 8/31/10 1025 8/31/2010 ND ND U1118 S41 Shallow well-500' 8/24/10 1155 8/31/10 1050 8/31/2010 ND ND U1772 N1 Shallow well-200' 10/5/10 1345 10/12/10 1035 10/12/2010 ND ND U1765 N9 Shallow well-850' 10/5/10 1330 10/12/10 1125 10/12/2010 ND ND U1770 N14 Deep well-250'-22' 10/5/10 1350 10/12/10 1045 10/12/2010 ND ND U1771 N15 Deep well-250'-39' 10/5/10 1350 10/12/10 1046 10/12/2010 ND ND U1767 N18 Deep well-750'-22' 10/5/10 1335 10/12/10 1110 10/12/2010 ND ND U1768 N19 Deep well-750'-39' 10/5/10 1335 10/12/10 1110 10/12/2010 ND ND U1773 N21 Canal-0' 10/5/10 1348 10/12/10 1019 10/12/2010 ND ND U1766 N37 Canal-1000' 10/5/10 1332 10/12/10 1120 10/12/2010 ND ND U1769 N41 Shallow well -500' 10/5/10 1340 10/12/10 1055 10/12/2010 ND ND U1782 S1 Shallow well-200' 10/5/10 1322 10/12/10 1140 10/12/2010 ND ND U1774 S9 Shallow well-850' 10/5/10 1310 10/12/10 1215 10/12/2010 ND ND U1779 S14 Deep well-250'-22' 10/5/10 1320 10/12/10 1145 10/12/2010 ND ND U1781 S15 Deep well-250'-39' 10/5/10 1320 10/12/10 1145 10/12/2010 ND ND U1776 S18 Deep Well-750'-22' 10/5/10 1300 10/12/10 1210 10/12/2010 ND ND U1777 S19 Deep well-750'-39' 10/5/10 1300 10/12/10 1210 10/12/2010 ND ND U1783 S21 Canal-0' 10/5/10 1325 10/12/10 1135 10/12/2010 ND ND U1775 S37 Canal-1000' 10/5/10 1305 10/12/10 1220 10/12/2010 ND ND U1778 S41 Shallow well-500' 10/5/10 1315 10/12/10 1200 10/12/2010 ND ND U1922 N1 Shallow well-200' 10/12/10 1040 10/14/10 1349 10/14/2010 ND ND U1917 N2 Shallow Well-300' 10/12/10 1100 10/14/10 1345 10/14/2010 ND ND U1916 N3 Shallow Well-350' 10/12/10 1100 10/14/10 1343 10/14/2010 ND ND U1915 N4 Shallow Well-450' 10/12/10 1100 10/14/10 1332 10/14/2010 ND ND U1911 N5 Shallow Well-550' 10/12/10 1145 10/14/10 1330 10/14/2010 ND ND U1910 N6 Shallow Well-600' 10/12/10 1145 10/14/10 1327 10/14/2010 ND ND U1909 N7 Shallow Well-700' 10/12/10 1145 10/14/10 1317 10/14/2010 ND ND U1905 N8 Shallow Well-800' 10/12/10 1145 10/14/10 1314 10/14/2010 ND ND U1904 N9 Shallow well-850' 10/12/10 1145 10/14/10 1312 10/14/2010 ND ND U1923 N10 Shallow well-(-5) 10/12/10 1027 10/14/10 1405 10/14/2010 ND ND U1924 N11 Shallow well-(-15') 10/12/10 1030 10/14/10 1406 10/14/2010 ND ND U1903 N12 Shallow Well-1005' 10/12/10 1145 10/14/10 1300 10/14/2010 ND ND U1902 N13 Shallow Well-1015' 10/12/10 1145 10/14/10 1300 10/14/2010 ND ND U1919 N14 Deep well-250'-22' downgradient 10/12/10 1042 10/14/10 1352 10/14/2010 ND ND U1921 N15 Deep well-250'-39' downgradient 10/12/10 1042 10/14/10 1352 10/14/2010 ND ND U1913 N16 Deep Well-500'-22' downgradient 10/12/10 1100 10/14/10 1335 10/14/2010 ND ND U1914 N17 Deep Well-500'-39' downgradient 10/12/10 1100 10/14/10 1335 10/14/2010 ND ND U1907 N18 Deep well-750'-22' downgradient 10/12/10 1145 10/14/10 1320 10/14/2010 ND ND Page 1 of 19 Conc. ppb Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered 10/14/2010 Fluorescein Results Peak nm Conc. ppb ND RWT Results Peak nm Conc. ppb U1908 N19 Deep well-750'-39' downgradient 10/12/10 1145 10/14/10 1320 ND U1966 N20 Canal-(-50') 10/12/10 1015 10/14/10 1105 10/14/2010 ND ND U1965 N21 Canal-0' 10/12/10 1005 10/14/10 1107 10/14/2010 ND ND U1964 N22 Canal-50' 10/12/10 1005 10/14/10 1109 10/14/2010 ND ND U1963 N23 Canal-100' 10/12/10 1005 10/14/10 1111 10/14/2010 ND ND U1962 N24 Canal-200' 10/12/10 1005 10/14/10 1113 10/14/2010 ND ND U1961 N25 Canal-250' 10/12/10 1005 10/14/10 1115 10/14/2010 ND 569.0 70.9 U1961D N25 Canal-250' 10/12/10 1005 10/14/10 1115 10/14/2010 ND 569.2 70.3 U1959 N26 Canal-300' 10/12/10 1005 10/14/10 1117 10/14/2010 ND 568.6 20.5 U1958 N27 Canal-350' 10/12/10 1005 10/14/10 1119 10/14/2010 ND 570.2 17.3 U1957 N28 Canal-450' 10/12/10 1005 10/14/10 1121 10/14/2010 515.4 205 568.7 19.7 U1956 N29 Canal-500' 10/12/10 1005 10/14/10 1123 10/14/2010 515.9 1,460 ND U1956D N29 Canal-500' 10/12/10 1005 10/14/10 1123 10/14/2010 516.3 1,650 ND U1955 N30 Canal-550' 10/12/10 1005 10/14/10 1125 10/14/2010 515.2 135 570.2 3.58 U1954 N31 Canal-600' 10/12/10 1005 10/14/10 1127 10/14/2010 515.3 158 570.0 5.52 U1953 N32 Canal-700' 10/12/10 0955 10/14/10 1129 10/14/2010 515.3 77.9 571.2 5.60 U1952 N33 Canal-750' 10/12/10 0955 10/14/10 1131 10/14/2010 515.2 41.5 569.3 35.2 U1952D N33 Canal-750' 10/12/10 0955 10/14/10 1131 10/14/2010 515.4 57.5 568.9 51.6 U1951 N34 Canal-800' 10/12/10 0955 10/14/10 1133 10/14/2010 515.4 24.2 569.3 12.9 U1950 N35 Canal-850' 10/12/10 0955 10/14/10 1135 10/14/2010 515.2 49.0 569.6 19.5 U1949 N36 Canal-950' 10/12/10 0955 10/14/10 1137 10/14/2010 515.3 41.0 570.3 14.7 U1948 N37 Canal-1000' 10/12/10 0955 10/14/10 1139 10/14/2010 515.0 22.6 570.2 5.66 U1947 N38 Canal-1050' 10/12/10 0955 10/14/10 1141 10/14/2010 515.2 33.5 569.6 9.42 U1946 N39 Canal-1100' 10/12/10 0955 10/14/10 1145 10/14/2010 515.3 34.4 569.7 14.3 U1918 N40 Shallow Well-250' downgradient 10/12/10 1042 10/14/10 1355 10/14/2010 ND 568.6 220 U1912 N41 Shallow well 500' downgradient 10/12/10 1100 10/14/10 1337 10/14/2010 516.0 U1906 N42 Shallow Well-750' downgradient 10/12/10 1145 10/14/10 1322 10/14/2010 ND 569.0 U1901 S1 Shallow well-200' 10/12/10 1145 10/14/10 1247 10/14/2010 ND ND 1,280 ND U1896 S2 Shallow Well-300' 10/12/10 1230 10/14/10 1245 10/14/2010 ND ND U1895 S3 Shallow Well-350' 10/12/10 1230 10/14/10 1242 10/14/2010 ND ND U1894 S4 Shallow Well-450' 10/12/10 1230 10/14/10 1233 10/14/2010 ND ND U1890 S5 Shallow Well-550' 10/12/10 1230 10/14/10 1230 10/14/2010 ND ND U1889 S6 Shallow Well-600' 10/12/10 1230 10/14/10 1226 10/14/2010 ND ND U1888 S7 Shallow Well-700' 10/12/10 1230 10/14/10 1209 10/14/2010 ND ND 426 U1884 S8 Shallow Well-800' 10/12/10 1230 10/14/10 1205 10/14/2010 ND ND U1883 S9 Shallow well-850' 10/12/10 1230 10/14/10 1202 10/14/2010 ND ND U1898 S14 Deep well-250'-22' downgradient 10/12/10 1145 10/14/10 1250 10/14/2010 ND ND U1899 S15 Deep well-250'-39' downgradient 10/12/10 1145 10/14/10 1250 10/14/2010 ND ND U1892 S16 Deep Well-500'-22' downgradient 10/12/10 1230 10/14/10 1235 10/14/2010 ND ND U1893 S17 Deep well-500'-39' downgradient 10/12/10 1230 10/14/10 1235 10/14/2010 ND ND U1886 S18 Deep Well-750'-22' downgradient 10/12/10 1230 10/14/10 1210 10/14/2010 ND ND U1887 S19 Deep well-750'-39' downgradient 10/12/10 1230 10/14/10 1210 10/14/2010 ND U1945 S20 Canal-(-50') 10/12/10 0955 10/14/10 1105 10/14/2010 515.4 15.9 ND U1944 S21 Canal-0' 10/12/10 0955 10/14/10 1107 10/14/2010 515.3 16.7 ND U1943 S22 Canal-50' 10/12/10 0955 10/14/10 1109 10/14/2010 515.2 12.1 ND U1942 S23 Canal-100' 10/12/10 0955 10/14/10 1111 10/14/2010 515.0 17.2 569.4 U1941 S24 Canal-200' 10/12/10 0955 10/14/10 1113 10/14/2010 515.2 15.4 ND U1939 S25 Canal-250' 10/12/10 0955 10/14/10 1115 10/14/2010 515.1 25.4 569.5 21.1 U1939D S25 Canal-250' 10/12/10 0955 10/14/10 1115 10/14/2010 515.1 19.2 569.5 15.3 U1938 S26 Canal-300' 10/12/10 0945 10/14/10 1117 10/14/2010 515.5 13.4 569.1 142 U1937 S27 Canal-350' 10/12/10 0945 10/14/10 1119 10/14/2010 515.4 20.2 568.9 101 U1936 S28 Canal-450' 10/12/10 0945 10/14/10 1121 10/14/2010 515.4 18.2 569.1 54.5 U1935 S29 Canal-500' 10/12/10 0945 10/14/10 1123 10/14/2010 516.0 1,100 570.0 47.1 U1935D S29 Canal-500' 10/12/10 0945 10/14/10 1123 10/14/2010 516.0 1,240 569.0 65.3 Page 2 of 19 ND 4.01 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm Conc. ppb U1934 S30 Canal-550' 10/12/10 0945 10/14/10 1125 10/14/2010 515.4 213 569.2 23.6 U1933 S31 Canal-600' 10/12/10 0945 10/14/10 1127 10/14/2010 515.6 222 568.8 28.6 U1932 S32 Canal-700' 10/12/10 0945 10/14/10 1129 10/14/2010 515.4 180 569.5 36.6 U1931 S33 Canal-750' 10/12/10 0945 10/14/10 1131 10/14/2010 515.1 122 569.3 504 U1931D S33 Canal-750' 10/12/10 0945 10/14/10 1131 10/14/2010 515.2 124 569.1 583 U1930 S34 Canal-800' 10/12/10 0945 10/14/10 1133 10/14/2010 515.4 130 569.0 226 U1929 S35 Canal-850' 10/12/10 0945 10/14/10 1135 10/14/2010 515.2 120 569.3 173 U1928 S36 Canal-950' 10/12/10 0945 10/14/10 1137 10/14/2010 515.2 107 569.3 107 U1927 S37 Canal-1000' 10/12/10 0945 10/14/10 1139 10/14/2010 515.3 77.4 569.1 70.9 U1926 S38 Canal-1050' 10/12/10 0945 10/14/10 1141 10/14/2010 515.3 63.7 569.1 46.1 U1925 S39 Canal-1100' 10/12/10 0945 10/14/10 1145 10/14/2010 515.4 63.7 568.8 42.8 U1897 S40 Shallow Well-250' downgradient 10/12/10 1145 10/14/10 1255 10/14/2010 ND U1891 S41 Shallow well-500' downgradient 10/12/10 1230 10/14/10 1238 10/14/2010 515.1 U1885 S42 Shallow Well-750' downgradient 10/12/10 1230 10/14/10 1212 10/14/2010 ND 569.0 U2170 N1 Shallow well-200' 10/14/10 1335 10/15/10 1133 10/15/2010 ND ND U2166 N2 Shallow Well-300' 10/14/10 1335 10/15/10 1122 10/15/2010 ND ND U2165 N3 Shallow Well-350' 10/14/10 1335 10/15/10 1118 10/15/2010 ND ND U2164 N4 Shallow Well-450' 10/14/10 1335 10/15/10 1116 10/15/2010 ND ND U2159 N5 Shallow Well-550' 10/14/10 1250 10/15/10 1107 10/15/2010 ND ND U2158 N6 Shallow Well-600' 10/14/10 1250 10/15/10 1103 10/15/2010 ND ND U2157 N7 Shallow Well-700' 10/14/10 1250 10/15/10 1100 10/15/2010 ND ND U2153 N8 Shallow Well-800' 10/14/10 1250 10/15/10 1048 10/15/2010 ND ND U2152 N9 Shallow well-850' 10/14/10 1250 10/15/10 1045 10/15/2010 ND ND U2171 N10 Shallow well-(-5) 10/14/10 1335 10/15/10 1138 10/15/2010 ND ND U2172 N11 Shallow well-(-15') 10/14/10 1405 10/15/10 1141 10/15/2010 ND ND U2151 N12 Shallow Well-1005' 10/14/10 1250 10/15/10 1041 10/15/2010 ND ND U2150 N13 Shallow Well-1015' 10/14/10 1250 10/15/10 1037 10/15/2010 ND ND U2168 N14 Deep well-250'-22' downgradient 10/14/10 1335 10/15/10 1126 10/15/2010 ND ND U2169 N15 Deep well-250'-39' downgradient 10/14/10 1335 10/15/10 1126 10/15/2010 ND ND U2162 N16 Deep Well-500'-22' downgradient 10/14/10 1335 10/15/10 1109 10/15/2010 ND ND U2163 N17 Deep Well-500'-39' downgradient 10/14/10 1335 10/15/10 1109 10/15/2010 ND ND U2155 N18 Deep well-750'-22' downgradient 10/14/10 1250 10/15/10 1050 10/15/2010 ND ND U2156 N19 Deep well-750'-39' downgradient 10/14/10 1250 10/15/10 1050 10/15/2010 ND ND U2214 N20 Canal-(-50') 10/14/10 1105 10/15/10 0953 10/15/2010 ND ND U2213 N21 Canal-0' 10/14/10 1125 10/15/10 0955 10/15/2010 ND ND U2212 N22 Canal-50' 10/14/10 1125 10/15/10 0957 10/15/2010 ND ND U2211 N23 Canal-100' 10/14/10 1125 10/15/10 0959 10/15/2010 ND ND U2210 N24 Canal-200' 10/14/10 1125 10/15/10 1001 10/15/2010 ND ND U2209 N25 Canal-250' 10/14/10 1125 10/15/10 1003 10/15/2010 ND 569.3 800 U2209D N25 Canal-250' 10/14/10 1125 10/15/10 1003 10/15/2010 ND 569.3 568 U2208 N26 Canal-300' 10/14/10 1125 10/15/10 1005 10/15/2010 ND 569.3 217 U2207 N27 Canal-350' 10/14/10 1125 10/15/10 1007 10/15/2010 ND 569.0 102 U2206 N28 Canal-450' 10/14/10 1125 10/15/10 1009 10/15/2010 515.3 258 569.1 144 U2205 N29 Canal-500' 10/14/10 1125 10/15/10 1010 10/15/2010 516.1 3,210 568.0 55.8 U2205D N29 Canal-500' 10/14/10 1125 10/15/10 1010 10/15/2010 516.0 2,410 568.2 44.4 U2204 N30 Canal-550' 10/14/10 1125 10/15/10 1012 10/15/2010 516.1 705 568.8 59.2 U2203 N31 Canal-600' 10/14/10 1125 10/15/10 1015 10/15/2010 515.1 201 568.9 35.3 U2202 N32 Canal-700' 10/14/10 1145 10/15/10 1017 10/15/2010 515.1 208 569.3 45.9 U2201 N33 Canal-750' 10/14/10 1145 10/15/10 1019 10/15/2010 515.3 160 568.9 364 U2199 N34 Canal-800' 10/14/10 1145 10/15/10 1022 10/15/2010 515.1 106 569.2 130 U2198 N35 Canal-850' 10/14/10 1145 10/15/10 1025 10/15/2010 515.2 204 569.3 223 U2197 N36 Canal-950' 10/14/10 1145 10/15/10 1027 10/15/2010 515.1 98.5 569.4 84.8 U2196 N37 Canal-1000' 10/14/10 1145 10/15/10 1029 10/15/2010 515.0 179 569.5 154 U2195 N38 Canal-1050' 10/14/10 1145 10/15/10 1031 10/15/2010 515.0 73.5 569.4 61.5 Page 3 of 19 ND 8.68 ND 243 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results 10/14/10 1145 10/15/10 1034 10/15/2010 515.0 Peak nm Conc. ppb Conc. ppb U2194 N39 Canal-1100' U2167 N40 Shallow Well-250' downgradient 10/14/10 1335 10/15/10 1130 10/15/2010 ND U2161 N41 Shallow well -500' downgradient 10/14/10 1340 10/15/10 1115 10/15/2010 516.1 U2154 N42 Shallow Well-750' downgradient 10/14/10 1250 10/15/10 1054 10/15/2010 ND 567.5 U2149 S1 Shallow well-200' 10/14/10 1250 10/15/10 1157 10/15/2010 ND ND U2145 S2 Shallow Well-300' 10/14/10 1200 10/15/10 1208 10/15/2010 ND ND U2144 S3 Shallow Well-350' 10/14/10 1200 10/15/10 1211 10/15/2010 ND ND U2143 S4 Shallow Well-450' 10/14/10 1200 10/15/10 1214 10/15/2010 ND ND U2138 S5 Shallow Well-550' 10/14/10 1200 10/15/10 1223 10/15/2010 ND ND U2137 S6 Shallow Well-600' 10/14/10 1200 10/15/10 1228 10/15/2010 ND ND U2136 S7 Shallow Well-700' 10/14/10 1200 10/15/10 1230 10/15/2010 ND ND U2132 S8 Shallow Well-800' 10/14/10 1200 10/15/10 1240 10/15/2010 ND ND U2131 S9 Shallow well-850' 10/14/10 1200 10/15/10 1243 10/15/2010 ND ND U2147 S14 Deep well-250'-22' downgradient 10/14/10 1250 10/15/10 1203 10/15/2010 ND 569.2 274 U2148 S15 Deep well-250'-39' downgradient 10/14/10 1250 10/15/10 1203 10/15/2010 ND 569.6 68.6 U2141 S16 Deep Well-500'-22' downgradient 10/14/10 1200 10/15/10 1217 10/15/2010 ND ND U2142 S17 Deep well-500'-39' downgradient 10/14/10 1200 10/15/10 1217 10/15/2010 ND ND U2134 S18 Deep Well-750'-22' downgradient 10/14/10 1200 10/15/10 1234 10/15/2010 ND ND U2135 S19 Deep well-750'-39' downgradient 10/14/10 1200 10/15/10 1234 10/15/2010 ND U2193 S20 Canal-(-50') 10/14/10 1105 10/15/10 1323 10/15/2010 515.0 53.4 569.3 31.0 U2192 S21 Canal-0' 10/14/10 1115 10/15/10 1322 10/15/2010 515.0 57.0 569.2 37.2 U2191 S22 Canal-50' 10/14/10 1115 10/15/10 1320 10/15/2010 515.1 60.2 569.1 39.6 U2190 S23 Canal-100' 10/14/10 1115 10/15/10 1318 10/15/2010 515.3 60.8 568.9 42.3 U2189 S24 Canal-200' 10/14/10 1115 10/15/10 1316 10/15/2010 515.3 69.5 569.2 46.3 U2188 S25 Canal-250' 10/14/10 1115 10/15/10 1314 10/15/2010 515.2 64.4 569.0 120 U2188D S25 Canal-250' 10/14/10 1115 10/15/10 1314 10/15/2010 515.1 78.3 569.2 129 U2187 S26 Canal-300' 10/14/10 1145 10/15/10 1312 10/15/2010 515.1 30.4 569.2 610 U2186 S27 Canal-350' 10/14/10 1145 10/15/10 1310 10/15/2010 515.2 42.1 569.2 468 U2185 S28 Canal-450' 10/14/10 1145 10/15/10 1308 10/15/2010 515.2 58.2 569.2 375 U2184 S29 Canal-500' 10/14/10 1145 10/15/10 1305 10/15/2010 516.3 1,420 569.1 399 U2184D S29 Canal-500' 10/14/10 1145 10/15/10 1305 10/15/2010 516.3 1,310 569.0 368 U2183 S30 Canal-550' 10/14/10 1145 10/15/10 1304 10/15/2010 516.3 518 568.2 242 U2182 S31 Canal-600' 10/14/10 1145 10/15/10 1302 10/15/2010 516.2 745 569.3 411 U2181 S32 Canal-700' 10/14/10 1145 10/15/10 1300 10/15/2010 515.5 219 568.9 198 U2179 S33 Canal-750' 10/14/10 1145 10/15/10 1258 10/15/2010 516.3 206 567.9 7,830 U2179D S33 Canal-750' 10/14/10 1145 10/15/10 1258 10/15/2010 516.2 249 568.0 8,470 U2178 S34 Canal-800' 10/14/10 1145 10/15/10 1257 10/15/2010 515.1 102 569.3 611 U2177 S35 Canal-850' 10/14/10 1145 10/15/10 1254 10/15/2010 515.2 99.8 569.3 538 U2176 S36 Canal-950' 10/14/10 1145 10/15/10 1252 10/15/2010 515.1 115 569.3 398 U2175 S37 Canal-1000' 10/14/10 1145 10/15/10 1250 10/15/2010 515.1 94.4 569.4 325 U2174 S38 Canal-1050' 10/14/10 1145 10/15/10 1249 10/15/2010 515.1 87.2 569.3 278 U2173 S39 Canal-1100' 10/14/10 1145 10/15/10 1247 10/15/2010 515.2 85.2 569.2 245 U2146 S40 Shallow Well-250' downgradient 10/14/10 1255 10/15/10 1205 10/15/2010 ND U2139 S41 Shallow well-500' downgradient 10/14/10 1200 10/15/10 1220 10/15/2010 515.0 U2133 S42 Shallow Well-750' downgradient 10/14/10 1200 10/15/10 1237 10/15/2010 ND 567.7 U2086 N1 Shallow well-200' 10/15/10 1109 10/17/10 1125 10/17/2010 ND ND U2082 N2 Shallow Well-300' 10/15/10 1109 10/17/10 1112 10/17/2010 ND ND U2081 N3 Shallow Well-350' 10/15/10 1109 10/17/10 1108 10/17/2010 ND ND U2079 N4 Shallow Well-450' 10/15/10 1109 10/17/10 1105 10/17/2010 ND ND U2075 N5 Shallow Well-550' 10/15/10 1037 10/17/10 1053 10/17/2010 ND ND U2074 N6 Shallow Well-600' 10/15/10 1037 10/17/10 1050 10/17/2010 ND ND U2073 N7 Shallow Well-700' 10/15/10 1037 10/17/10 1047 10/17/2010 ND ND U2069 N8 Shallow Well-800' 10/15/10 1037 10/17/10 1035 10/17/2010 ND ND U2068 N9 Shallow well-850' 10/15/10 1037 10/17/10 1031 10/17/2010 ND ND Page 4 of 19 63.4 RWT Results Peak nm 888 569.5 45.9 568.9 1,490 ND 3,920 ND ND 39.5 ND 2,930 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered 10/17/10 1130 10/17/2010 10/15/10 1109 Fluorescein Results Peak nm Conc. ppb Conc. ppb U2087 N10 Shallow well-(-5) U2088 N11 Shallow well-(-15') 10/15/10 1141 10/17/10 1134 10/17/2010 ND ND U2067 N12 Shallow Well-1005' 10/15/10 1037 10/17/10 1027 10/17/2010 ND ND U2066 N13 Shallow Well-1015' 10/15/10 1037 10/17/10 1023 10/17/2010 ND ND U2084 N14 Deep well-250'-22' downgradient 10/15/10 1109 10/17/10 1116 10/17/2010 ND ND U2085 N15 Deep well-250'-39' downgradient 10/15/10 1109 10/17/10 1116 10/17/2010 ND ND U2077 N16 Deep Well-500'-22' downgradient 10/15/10 1109 10/17/10 1056 10/17/2010 ND ND U2078 N17 Deep Well-500'-39' downgradient 10/15/10 1109 10/17/10 1056 10/17/2010 ND ND U2071 N18 Deep well-750'-22' downgradient 10/15/10 1037 10/17/10 1038 10/17/2010 ND ND U2072 N19 Deep well-750'-39' downgradient 10/15/10 1037 10/17/10 1038 10/17/2010 ND ND U2130 N20 Canal-(-50') 10/15/10 0953 10/17/10 0926 10/17/2010 ND ND U2129 N21 Canal-0' 10/15/10 1012 10/17/10 0928 10/17/2010 ND ND U2128 N22 Canal-50' 10/15/10 1012 10/17/10 0930 10/17/2010 ND ND U2127 N23 Canal-100' 10/15/10 1012 10/17/10 0932 10/17/2010 ND ND U2126 N24 Canal-200' 10/15/10 1012 10/17/10 0935 10/17/2010 ND ND U2125 N25 Canal-250' 10/15/10 1012 10/17/10 0938 10/17/2010 ND 569.0 419 U2125D N25 Canal-250' 10/15/10 1012 10/17/10 0938 10/17/2010 ND 569.1 603 U2124 N26 Canal-300' 10/15/10 1012 10/17/10 0942 10/17/2010 ND 569.0 221 U2123 N27 Canal-350' 10/15/10 1012 10/17/10 0943 10/17/2010 ND 569.6 169 U2122 N28 Canal-450' 10/15/10 1012 10/17/10 0947 10/17/2010 515.2 260 568.9 72.5 U2121 N29 Canal-500' 10/15/10 1012 10/17/10 0950 10/17/2010 516.3 2,850 568.4 59.9 U2121D N29 Canal-500' 10/15/10 1012 10/17/10 0950 10/17/2010 516.4 3,090 568.9 91.3 U2119 N30 Canal-550' 10/15/10 1012 10/17/10 0952 10/17/2010 516.3 555 569.1 64.2 U2118 N31 Canal-600' 10/15/10 1015 10/17/10 0955 10/17/2010 515.2 234 569.4 54.9 U2117 N32 Canal-700' 10/15/10 1034 10/17/10 0958 10/17/2010 515.4 192 569.3 96.1 U2116 N33 Canal-750' 10/15/10 1034 10/17/10 1001 10/17/2010 515.3 135 569.3 644 U2116D N33 Canal-750' 10/15/10 1034 10/17/10 1001 10/17/2010 515.3 115 569.3 631 U2115 N34 Canal-800' 10/15/10 1034 10/17/10 1005 10/17/2010 515.3 65.3 569.1 122 U2114 N35 Canal-850' 10/15/10 1034 10/17/10 1007 10/17/2010 515.4 126 569.1 186 U2113 N36 Canal-950' 10/15/10 1034 10/17/10 1010 10/17/2010 515.4 111 569.1 164 U2112 N37 Canal-1000' 10/15/10 1034 10/17/10 1012 10/17/2010 515.3 97.4 569.3 130 U2111 N38 Canal-1050' 10/15/10 1034 10/17/10 1014 10/17/2010 515.4 66.1 569.3 95.8 U2110 N39 Canal-1100' 10/15/10 1034 10/17/10 1017 10/17/2010 515.3 70.7 569.2 107 U2083 N40 Shallow Well-250' downgradient 10/15/10 1109 10/17/10 1120 10/17/2010 ND 567.7 5,820 U2076 N41 Shallow well -500' downgradient 10/15/10 1113 10/17/10 1101 10/17/2010 516.1 U2070 N42 Shallow Well-750' downgradient 10/15/10 1037 10/17/10 1042 10/17/2010 ND 567.8 U2065 S1 Shallow well-200' 10/15/10 1157 10/17/10 1156 10/17/2010 ND ND U2061 S2 Shallow Well-300' 10/15/10 1243 10/17/10 1207 10/17/2010 ND ND U2059 S3 Shallow Well-350' 10/15/10 1243 10/17/10 1210 10/17/2010 ND ND U2058 S4 Shallow Well-450' 10/15/10 1243 10/17/10 1214 10/17/2010 ND ND U2054 S5 Shallow Well-550' 10/15/10 1243 10/17/10 1227 10/17/2010 ND ND U2053 S6 Shallow Well-600' 10/15/10 1243 10/17/10 1232 10/17/2010 ND ND U2052 S7 Shallow Well-700' 10/15/10 1243 10/17/10 1235 10/17/2010 ND ND U2048 S8 Shallow Well-800' 10/15/10 1243 10/17/10 1250 10/17/2010 ND ND U2047 S9 Shallow well-850' 10/15/10 1243 10/17/10 1255 10/17/2010 ND ND U2063 S14 Deep well-250'-22' downgradient 10/15/10 1203 10/17/10 1200 10/17/2010 ND 570.0 320 U2064 S15 Deep well-250'-39' downgradient 10/15/10 1203 10/17/10 1200 10/17/2010 ND 569.8 58.3 U2056 S16 Deep Well-500'-22' downgradient 10/15/10 1243 10/17/10 1218 10/17/2010 ND ND U2057 S17 Deep well-500'-39' downgradient 10/15/10 1243 10/17/10 1218 10/17/2010 ND ND U2050 S18 Deep Well-750'-22' downgradient 10/15/10 1243 10/17/10 1241 10/17/2010 ND ND U2051 S19 Deep well-750'-39' downgradient 10/15/10 1243 10/17/10 1241 10/17/2010 ND U2109 S20 Canal-(-50') 10/15/10 1323 10/17/10 1350 10/17/2010 515.4 57.8 569.3 79.0 U2108 S21 Canal-0' 10/15/10 1316 10/17/10 1347 10/17/2010 515.2 49.4 569.2 70.5 U2107 S22 Canal-50' 10/15/10 1316 10/17/10 1344 10/17/2010 515.2 30.9 569.4 48.3 Page 5 of 19 ND RWT Results Peak nm ND 1,470 ND 6,890 ND Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm Conc. ppb U2106 S23 Canal-100' 10/15/10 1316 10/17/10 1342 10/17/2010 515.3 45.2 569.4 76.7 U2105 S24 Canal-200' 10/15/10 1316 10/17/10 1340 10/17/2010 515.4 39.6 568.9 54.1 U2104 S25 Canal-250' 10/15/10 1314 10/17/10 1336 10/17/2010 515.1 37.5 569.5 110 U2104D S25 Canal-250' 10/15/10 1314 10/17/10 1336 10/17/2010 515.3 37.4 569.3 101 U2103 S26 Canal-300' 10/15/10 1247 10/17/10 1333 10/17/2010 515.4 36.2 569.5 915 U2102 S27 Canal-350' 10/15/10 1247 10/17/10 1337 10/17/2010 515.3 27.3 569.3 428 U2101 S28 Canal-450' 10/15/10 1247 10/17/10 1330 10/17/2010 515.3 48.5 569.6 396 U2099 S29 Canal-500' 10/15/10 1247 10/17/10 1325 10/17/2010 516.1 1,610 569.7 327 U2099D S29 Canal-500' 10/15/10 1247 10/17/10 1325 10/17/2010 516.2 1,750 569.5 375 U2098 S30 Canal-550' 10/15/10 1247 10/17/10 1321 10/17/2010 515.9 418 569.4 232 U2097 S31 Canal-600' 10/15/10 1247 10/17/10 1318 10/17/2010 516.0 413 569.4 313 U2096 S32 Canal-700' 10/15/10 1247 10/17/10 1315 10/17/2010 515.3 157 569.4 205 U2095 S33 Canal-750' 10/15/10 1247 10/17/10 1313 10/17/2010 516.3 147 568.1 8,520 U2095D S33 Canal-750' 10/15/10 1247 10/17/10 1313 10/17/2010 516.4 105 568.0 8,320 U2094 S34 Canal-800' 10/15/10 1247 10/17/10 1310 10/17/2010 515.1 143 570.0 988 U2093 S35 Canal-850' 10/15/10 1247 10/17/10 1308 10/17/2010 515.1 72.2 569.9 414 U2092 S36 Canal-950' 10/15/10 1247 10/17/10 1306 10/17/2010 515.1 97.9 569.9 379 U2091 S37 Canal-1000' 10/15/10 1247 10/17/10 1304 10/17/2010 515.1 99.3 570.0 349 U2090 S38 Canal-1050' 10/15/10 1247 10/17/10 1302 10/17/2010 515.1 85.9 569.8 306 U2089 S39 Canal-1100' 10/15/10 1247 10/17/10 1300 10/17/2010 515.2 76.9 569.6 239 U2062 S40 Shallow Well-250' downgradient 10/15/10 1205 10/17/10 1203 10/17/2010 ND U2055 S41 Shallow well-500' downgradient 10/15/10 1243 10/17/10 1222 10/17/2010 515.2 U2049 S42 Shallow Well-750' downgradient 10/15/10 1243 10/17/10 1245 10/17/2010 ND 567.8 U2267 N1 Shallow Well-200' 10/17/10 1056 10/20/10 1320 10/20/2010 ND ND U2263 N2 Shallow Well-300' 10/17/10 1056 10/20/10 1317 10/20/2010 ND ND U2262 N3 Shallow Well-350' 10/17/10 1056 10/20/10 1315 10/20/2010 ND ND U2261 N4 Shallow Well-450' 10/17/10 1056 10/20/10 1306 10/20/2010 ND ND U2256 N5 Shallow Well-550' 10/17/10 1023 10/20/10 1304 10/20/2010 ND ND U2255 N6 Shallow Well-600' 10/17/10 1023 10/20/10 1302 10/20/2010 ND ND U2254 N7 Shallow Well-700' 10/17/10 1023 10/20/10 1253 10/20/2010 ND ND U2250 N8 Shallow Well-800' 10/17/10 1023 10/20/10 1248 10/20/2010 ND ND U2249 N9 Shallow well-850' 10/17/10 1023 10/20/10 1250 10/20/2010 ND ND U2268 N10 Shallow Well-(-5) 10/17/10 1056 10/20/10 1327 10/20/2010 ND ND U2269 N11 Shallow Well-(-15') 10/17/10 1134 10/20/10 1330 10/20/2010 ND ND U2248 N12 Shallow Well-1005' 10/17/10 1023 10/20/10 1244 10/20/2010 ND ND U2247 N13 Shallow Well-1015' 10/17/10 1023 10/20/10 1243 10/20/2010 ND ND U2265 N14 Deep well-250'-22' downgradient 10/17/10 1056 10/20/10 1322 10/20/2010 ND ND U2266 N15 Deep well-250'-39' downgradient 10/17/10 1056 10/20/10 1323 10/20/2010 ND ND U2258 N16 Deep Well-500'-22' downgradient 10/17/10 1056 10/20/10 1308 10/20/2010 ND ND U2259 N17 Deep Well-500'-39' downgradient 10/17/10 1056 10/20/10 1309 10/20/2010 ND ND U2252 N18 Deep well-750'-22' downgradient 10/17/10 1023 10/20/10 1255 10/20/2010 ND ND U2253 N19 Deep well-750'-39' downgradient 10/17/10 1023 10/20/10 1256 10/20/2010 ND ND U2310 N20 Canal-(-50') 10/17/10 0926 10/20/10 1040 10/20/2010 ND ND U2309 N21 Canal-0' 10/17/10 0952 10/20/10 1042 10/20/2010 ND ND U2308 N22 Canal-50' 10/17/10 0952 10/20/10 1044 10/20/2010 ND ND U2307 N23 Canal-100' 10/17/10 0952 10/20/10 1046 10/20/2010 ND ND U2306 N24 Canal-200' 10/17/10 0952 10/20/10 1048 10/20/2010 ND ND U2305 N26 Canal-300' 10/17/10 0952 10/20/10 1052 10/20/2010 ND 569.6 146 U2304 N27 Canal-350' 10/17/10 0952 10/20/10 1054 10/20/2010 ND 569.0 165 U2303 N28 Canal-450' 10/17/10 0952 10/20/10 1056 10/20/2010 516.2 619 568.9 77.6 U2302 N29 Canal-500' 10/17/10 0952 10/20/10 1058 10/20/2010 516.3 950 568.5 34.8 U2302D N29 Canal-500' 10/17/10 0952 10/20/10 1058 10/20/2010 516.3 1,690 569.2 73.0 U2301 N30 Canal-550' 10/17/10 0952 10/20/10 1100 10/20/2010 515.8 218 568.7 49.8 U2299 N31 Canal-600' 10/17/10 0955 10/20/10 1102 10/20/2010 515.5 139 569.1 57.3 Page 6 of 19 ND 96.3 ND 3,130 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm 73.4 RWT Results Peak nm N32 Canal-700' 10/17/10 1017 10/20/10 1104 10/20/2010 U2297 N33 Canal-750' 10/17/10 1017 10/20/10 1106 10/20/2010 515.5 61.9 569.0 474 U2297D N33 Canal-750' 10/17/10 1017 10/20/10 1106 10/20/2010 515.4 57.2 569.1 474 U2296 N34 Canal-800' 10/17/10 1017 10/20/10 1108 10/20/2010 515.5 37.3 568.9 167 U2295 N35 Canal-850' 10/17/10 1017 10/20/10 1110 10/20/2010 515.3 29.7 568.9 90.6 U2294 N36 Canal-950' 10/17/10 1017 10/20/10 1112 10/20/2010 515.3 21.8 569.2 58.3 U2293 N37 Canal-1000' 10/17/10 1017 10/20/10 1114 10/20/2010 515.5 35.6 568.9 79.7 U2292 N38 Canal-1050' 10/17/10 1017 10/20/10 1116 10/20/2010 515.5 32.8 568.9 83.3 U2291 N39 Canal-1100' 10/17/10 1017 10/20/10 1117 10/20/2010 515.4 20.8 568.9 47.3 U2264 N40 Shallow Well-250' downgradient 10/17/10 1056 10/20/10 1324 10/20/2010 ND 567.8 3,530 U2257 N41 Shallow well -500' downgradient 10/17/10 1101 10/20/10 1312 10/20/2010 516.2 U2251 N42 Shallow Well-750' downgradient 10/17/10 1023 10/20/10 1259 10/20/2010 ND 568.0 U2246 S1 Shallow Well-200' 10/17/10 1156 10/20/10 1218 10/20/2010 ND ND U2242 S2 Shallow Well-300' 10/17/10 1255 10/20/10 1216 10/20/2010 ND ND U2241 S3 Shallow Well-350' 10/17/10 1255 10/20/10 1215 10/20/2010 ND ND U2239 S4 Shallow Well-450' 10/17/10 1255 10/20/10 1204 10/20/2010 ND ND U2235 S5 Shallow Well-550' 10/17/10 1255 10/20/10 1201 10/20/2010 ND ND U2234 S6 Shallow Well-600' 10/17/10 1255 10/20/10 1200 10/20/2010 ND ND U2233 S7 Shallow Well-700' 10/17/10 1255 10/20/10 1150 10/20/2010 ND ND U2229 S8 Shallow Well-800' 10/17/10 1255 10/20/10 1147 10/20/2010 ND ND U2228 S9 Shallow well-850' 10/17/10 1255 10/20/10 1145 10/20/2010 ND ND U2244 S14 Deep well-250'-22' downgradient 10/17/10 1200 10/20/10 1220 10/20/2010 ND 569.2 113 U2245 S15 Deep well-250'-39' downgradient 10/17/10 1200 10/20/10 1221 10/20/2010 ND 569.6 40.7 U2237 S16 Deep Well-500'-22' downgradient 10/17/10 1255 10/20/10 1206 10/20/2010 ND ND U2238 S17 Deep well-500'-39' downgradient 10/17/10 1255 10/20/10 1207 10/20/2010 ND ND U2231 S18 Deep Well-750'-22' downgradient 10/17/10 1255 10/20/10 1154 10/20/2010 ND ND U2232 S19 Deep well-750'-39' downgradient 10/17/10 1255 10/20/10 1155 10/20/2010 ND U2290 S20 Canal-(-50') 10/17/10 1350 10/20/10 1050 10/20/2010 515.4 15.6 568.7 35.4 U2289 S21 Canal-0' 10/17/10 1340 10/20/10 1052 10/20/2010 515.3 24.3 569.0 52.1 U2288 S22 Canal-50' 10/17/10 1340 10/20/10 1054 10/20/2010 515.3 10.1 569.0 20.8 U2287 S23 Canal-100' 10/17/10 1340 10/20/10 1056 10/20/2010 515.4 17.5 568.9 41.6 U2286 S24 Canal-200' 10/17/10 1340 10/20/10 1058 10/20/2010 515.5 13.1 569.0 32.9 U2285 S25 Canal-250' 10/17/10 1336 10/20/10 1100 10/20/2010 515.6 15.5 569.1 600 U2285D S25 Canal-250' 10/17/10 1336 10/20/10 1100 10/20/2010 515.3 13.4 569.1 224 U2284 S26 Canal-300' 10/17/10 1300 10/20/10 1102 10/20/2010 515.5 16.5 569.3 624 U2283 S27 Canal-350' 10/17/10 1300 10/20/10 1107 10/20/2010 515.6 7.62 568.9 130 U2282 S28 Canal-450' 10/17/10 1300 10/20/10 1106 10/20/2010 515.9 16.9 568.8 142 U2281 S29 Canal-500' 10/17/10 1300 10/20/10 1108 10/20/2010 516.1 635 568.5 141 U2281D S29 Canal-500' 10/17/10 1300 10/20/10 1108 10/20/2010 516.4 762 570.0 157 U2279 S30 Canal-550' 10/17/10 1300 10/20/10 1110 10/20/2010 515.4 144 569.3 83.8 U2278 S31 Canal-600' 10/17/10 1300 10/20/10 1112 10/20/2010 515.5 103 569.0 84.5 U2277 S32 Canal-700' 10/17/10 1300 10/20/10 1114 10/20/2010 515.5 69.2 569.2 79.0 U2276 S33 Canal-750' 10/17/10 1300 10/20/10 1116 10/20/2010 516.0 62.7 568.0 8,460 U2276D S33 Canal-750' 10/17/10 1300 10/20/10 1116 10/20/2010 516.2 76.3 568.4 9,380 U2275 S34 Canal-800' 10/17/10 1300 10/20/10 1118 10/20/2010 515.5 69.1 569.3 458 U2274 S35 Canal-850' 10/17/10 1300 10/20/10 1120 10/20/2010 515.6 50.9 569.0 269 U2273 S36 Canal-950' 10/17/10 1300 10/20/10 1122 10/20/2010 515.6 44.4 568.9 173 U2272 S37 Canal-1000' 10/17/10 1300 10/20/10 1124 10/20/2010 515.5 33.1 568.9 114 U2271 S38 Canal-1050' 10/17/10 1300 10/20/10 1126 10/20/2010 515.5 27.9 568.8 90.5 U2270 S39 Canal-1100' 10/17/10 1300 10/20/10 1128 10/20/2010 515.8 27.1 569.2 85.4 U2243 S40 Shallow Well-250' downgradient 10/17/10 1203 10/20/10 1223 10/20/2010 ND 570.6 6.60 U2236 S41 Shallow well-500' downgradient 10/17/10 1255 10/20/10 1209 10/20/2010 515.5 U2230 S42 Shallow Well-750' downgradient 10/17/10 1255 10/20/10 1158 10/20/2010 ND 568.0 U2494 N1 Shallow Well-200' 10/20/10 1308 10/27/10 1310 10/27/2010 ND ND 574 569.1 Conc. ppb U2298 Page 7 of 19 515.3 Conc. ppb 103 ND 8,640 ND 77.7 ND 4,090 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm Conc. ppb U2490 N2 Shallow Well-300' 10/20/10 1308 10/27/10 1309 10/27/2010 ND ND U2489 N3 Shallow Well-350' 10/20/10 1308 10/27/10 1308 10/27/2010 ND ND U2488 N4 Shallow Well-450' 10/20/10 1308 10/27/10 1257 10/27/2010 ND ND U2484 N5 Shallow Well-550' 10/20/10 1243 10/27/10 1256 10/27/2010 ND ND U2483 N6 Shallow Well-600' 10/20/10 1243 10/27/10 1255 10/27/2010 ND ND U2482 N7 Shallow Well-700' 10/20/10 1243 10/27/10 1245 10/27/2010 ND ND U2477 N8 Shallow Well-800' 10/20/10 1243 10/27/10 1244 10/27/2010 ND ND U2476 N9 Shallow well-850' 10/20/10 1243 10/27/10 1243 10/27/2010 ND ND U2495 N10 Shallow Well-(-5) 10/20/10 1308 10/27/10 1321 10/27/2010 ND ND U2496 N11 Shallow Well-(-15') 10/20/10 1330 10/27/10 1322 10/27/2010 ND ND U2475 N12 Shallow Well-1005' 10/20/10 1243 10/27/10 1236 10/27/2010 ND ND U2474 N13 Shallow Well-1015' 10/20/10 1243 10/27/10 1235 10/27/2010 ND ND U2492 N14 Deep well-250'-22' downgradient 10/20/10 1308 10/27/10 1316 10/27/2010 ND ND U2493 N15 Deep well-250'-39' downgradient 10/20/10 1308 10/27/10 1317 10/27/2010 ND ND U2486 N16 Deep Well-500'-22' downgradient 10/20/10 1308 10/27/10 1300 10/27/2010 ND ND U2487 N17 Deep Well-500'-39' downgradient 10/20/10 1308 10/27/10 1301 10/27/2010 ND ND U2479 N18 Deep well-750'-22' downgradient 10/20/10 1243 10/27/10 1249 10/27/2010 ND ND U2481 N19 Deep well-750'-39' downgradient 10/20/10 1243 10/27/10 1250 10/27/2010 ND ND U2537 N20 Canal-(-50') 10/20/10 1040 10/27/10 1040 10/27/2010 ND ND U2536 N21 Canal-0' 10/20/10 1100 10/27/10 1042 10/27/2010 ND ND U2535 N23 Canal-100' 10/20/10 1100 10/27/10 1046 10/27/2010 ND U2534 N24 Canal-200' 10/20/10 1100 10/27/10 1048 10/27/2010 516.4 1.22 569.2 U2533 N25 Canal-250' 10/20/10 1100 10/27/10 1050 10/27/2010 516.3 1.87 569.2 293 U2533D N25 Canal-250' 10/20/10 1100 10/27/10 1050 10/27/2010 516.7 2.39 568.8 339 U2532 N26 Canal-300' 10/20/10 1100 10/27/10 1052 10/27/2010 515.9 1.66 569.6 194 U2531 N27 Canal-350' 10/20/10 1100 10/27/10 1054 10/27/2010 515.5 5.39 569.3 106 U2530 N28 Canal-450' 10/20/10 1100 10/27/10 1056 10/27/2010 515.6 190 569.0 57.1 U2529 N29 Canal-500' 10/20/10 1100 10/27/10 1058 10/27/2010 516.4 2,570 568.2 33.9 U2529D N29 Canal-500' 10/20/10 1100 10/27/10 1058 10/27/2010 516.1 2,650 567.7 43.2 U2528 N30 Canal-550' 10/20/10 1100 10/27/10 1059 10/27/2010 515.2 164 569.0 46.3 U2527 N31 Canal-600' 10/20/10 1102 10/27/10 1100 10/27/2010 515.5 57.7 568.7 38.0 U2526 N32 Canal-700' 10/20/10 1117 10/27/10 1102 10/27/2010 515.3 30.9 569.1 78.8 U2525 N33 Canal-750' 10/20/10 1117 10/27/10 1104 10/27/2010 515.3 37.5 569.3 749 U2525D N33 Canal-750' 10/20/10 1117 10/27/10 1104 10/27/2010 515.3 42.5 569.7 771 U2524 N34 Canal-800' 10/20/10 1117 10/27/10 1106 10/27/2010 515.3 30.3 569.2 200 U2523 N35 Canal-850' 10/20/10 1117 10/27/10 1108 10/27/2010 515.3 28.0 569.1 157 U2522 N36 Canal-950' 10/20/10 1117 10/27/10 1110 10/27/2010 515.5 17.1 568.9 83.4 U2521 N37 Canal-1000' 10/20/10 1117 10/27/10 1112 10/27/2010 515.4 22.7 569.1 102 U2519 N38 Canal-1050' 10/20/10 1117 10/27/10 1114 10/27/2010 515.5 16.1 569.0 60.6 U2518 N39 Canal-1100' 10/20/10 1117 10/27/10 1116 10/27/2010 515.2 11.2 569.1 48.6 U2491 N40 Shallow Well-250' downgradient 10/20/10 1308 10/27/10 1318 10/27/2010 ND 567.6 3,560 U2485 N41 Shallow well -500' downgradient 10/20/10 1312 10/27/10 1303 10/27/2010 515.9 U2478 N42 Shallow Well-750' downgradient 10/20/10 1243 10/27/10 1251 10/27/2010 ND 568.1 U2473 S1 Shallow Well-200' 10/20/10 1218 10/27/10 1208 10/27/2010 ND ND U2469 S2 Shallow Well-300' 10/20/10 1145 10/27/10 1207 10/27/2010 ND ND U2468 S3 Shallow Well-350' 10/20/10 1145 10/27/10 1206 10/27/2010 ND ND U2467 S4 Shallow Well-450' 10/20/10 1145 10/27/10 1155 10/27/2010 ND ND U2463 S5 Shallow Well-550' 10/20/10 1145 10/27/10 1154 10/27/2010 ND ND U2462 S6 Shallow Well-600' 10/20/10 1145 10/27/10 1153 10/27/2010 ND ND U2461 S7 Shallow Well-700' 10/20/10 1145 10/27/10 1140 10/27/2010 ND ND U2456 S8 Shallow Well-800' 10/20/10 1145 10/27/10 1139 10/27/2010 ND ND U2455 S9 Shallow well-850' 10/20/10 1145 10/27/10 1138 10/27/2010 ND ND U2471 S14 Deep well-250'-22' downgradient 10/20/10 1220 10/27/10 1212 10/27/2010 ND 569.6 186 U2472 S15 Deep well-250'-39' downgradient 10/20/10 1220 10/27/10 1213 10/27/2010 ND 569.8 57.7 Page 8 of 19 ND 710 5.24 ND 10,700 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results 10/20/10 1145 10/27/10 1201 10/27/2010 ND ND Peak nm Conc. ppb RWT Results Peak nm Conc. ppb U2465 S16 Deep Well-500'-22' downgradient U2466 S17 Deep well-500'-39' downgradient 10/20/10 1145 10/27/10 1202 10/27/2010 ND ND U2458 S18 Deep Well-750'-22' downgradient 10/20/10 1145 10/27/10 1145 10/27/2010 ND ND U2459 S19 Deep well-750'-39' downgradient 10/20/10 1145 10/27/10 1146 10/27/2010 ND U2517 S20 Canal-(-50') 10/20/10 1050 10/27/10 1045 10/27/2010 515.4 13.4 568.9 48.7 U2516 S21 Canal-0' 10/20/10 1058 10/27/10 1047 10/27/2010 514.8 7.46 568.6 21.8 U2515 S22 Canal-50' 10/20/10 1058 10/27/10 1049 10/27/2010 515.5 12.9 569.1 54.8 U2514 S23 Canal-100' 10/20/10 1058 10/27/10 1051 10/27/2010 515.5 10.3 568.9 38.8 U2513 S24 Canal-200' 10/20/10 1058 10/27/10 1052 10/27/2010 515.6 12.1 569.4 43.7 U2512 S25 Canal-250' 10/20/10 1100 10/27/10 1055 10/27/2010 515.7 11.1 569.1 149 U2512D S25 Canal-250' 10/20/10 1100 10/27/10 1055 10/27/2010 515.7 7.60 569.1 110 U2511 S26 Canal-300' 10/20/10 1128 10/27/10 1057 10/27/2010 515.8 13.2 569.5 408 U2510 S27 Canal-350' 10/20/10 1128 10/27/10 1059 10/27/2010 515.7 7.18 569.0 129 U2509 S28 Canal-450' 10/20/10 1128 10/27/10 1101 10/27/2010 515.6 11.1 569.1 112 U2508 S29 Canal-500' 10/20/10 1128 10/27/10 1103 10/27/2010 516.1 518 569.1 66.2 U2508D S29 Canal-500' 10/20/10 1128 10/27/10 1103 10/27/2010 516.3 556 569.4 96.9 U2507 S30 Canal-550' 10/20/10 1128 10/27/10 1105 10/27/2010 515.5 92.9 569.4 48.8 U2506 S31 Canal-600' 10/20/10 1128 10/27/10 1107 10/27/2010 515.5 95.7 569.3 87.8 U2505 S32 Canal-700' 10/20/10 1128 10/27/10 1109 10/27/2010 515.2 61.4 569.6 80.8 U2504 S33 Canal-750' 10/20/10 1128 10/27/10 1111 10/27/2010 516.7 47.6 568.0 7,900 U2504D S33 Canal-750' 10/20/10 1128 10/27/10 1111 10/27/2010 516.8 60.5 568.0 9,510 U2503 S34 Canal-800' 10/20/10 1128 10/27/10 1113 10/27/2010 515.5 36.8 569.3 263 U2502 S35 Canal-850' 10/20/10 1128 10/27/10 1115 10/27/2010 515.5 37.1 569.3 197 U2501 S36 Canal-950' 10/20/10 1128 10/27/10 1117 10/27/2010 515.5 28.3 569.6 125 U2499 S37 Canal-1000' 10/20/10 1128 10/27/10 1119 10/27/2010 515.4 22.8 569.2 92.4 U2498 S38 Canal-1050' 10/20/10 1128 10/27/10 1121 10/27/2010 515.7 15.6 568.8 58.2 U2497 S39 Canal-1100' 10/20/10 1128 10/27/10 1123 10/27/2010 515.7 15.0 569.2 62.4 U2470 S40 Shallow Well-250' downgradient 10/20/10 1223 10/27/10 1214 10/27/2010 ND 568.0 13.3 U2464 S41 Shallow well-500' downgradient 10/20/10 1145 10/27/10 1203 10/27/2010 515.5 U2457 S42 Shallow Well-750' downgradient 10/20/10 1145 10/27/10 1147 10/27/2010 ND 567.9 U2828 N1 Shallow Well-200' 10/27/10 1300 11/3/10 1342 11/3/2010 ND ND U2824 N2 Shallow Well-300' 10/27/10 1300 11/3/10 1341 11/3/2010 ND ND U2823 N3 Shallow Well-350' 10/27/10 1300 11/3/10 1340 11/3/2010 ND ND U2822 N4 Shallow Well-450' 10/27/10 1300 11/3/10 1312 11/3/2010 ND ND U2817 N5 Shallow Well-550' 10/27/10 1235 11/3/10 1311 11/3/2010 ND ND U2816 N6 Shallow Well-600' 10/27/10 1235 11/3/10 1310 11/3/2010 ND ND U2815 N7 Shallow Well-700' 10/27/10 1235 11/3/10 1302 11/3/2010 ND ND U2811 N8 Shallow Well-800' 10/27/10 1235 11/3/10 1301 11/3/2010 ND ND U2810 N9 Shallow well-850' 10/27/10 1235 11/3/10 1300 11/3/2010 ND ND U2829 N10 Shallow Well-(-5) 10/27/10 1300 11/3/10 1357 11/3/2010 ND ND U2830 N11 Shallow Well-(-15') 10/27/10 1322 11/3/10 1358 11/3/2010 ND ND U2809 N12 Shallow Well-1005' 10/27/10 1235 11/3/10 1241 11/3/2010 ND ND U2808 N13 Shallow Well-1015' 10/27/10 1235 11/3/10 1240 11/3/2010 ND ND U2826 N14 Deep well-250'-22' downgradient 10/27/10 1300 11/3/10 1346 11/3/2010 ND ND U2827 N15 Deep well-250'-39' downgradient 10/27/10 1300 11/3/10 1347 11/3/2010 ND ND U2819 N16 Deep Well-500'-22' downgradient 10/27/10 1300 11/3/10 1330 11/3/2010 ND ND U2821 N17 Deep Well-500'-39' downgradient 10/27/10 1300 11/3/10 1331 11/3/2010 ND ND U2813 N18 Deep well-750'-22' downgradient 10/27/10 1235 11/3/10 1309 11/3/2010 ND ND U2814 N19 Deep well-750'-39' downgradient 10/27/10 1235 11/3/10 1306 11/3/2010 ND ND U2871 N20 Canal-(-50') 10/27/10 1040 11/3/10 1040 11/3/2010 ND ND U2870 N21 Canal-0' 10/27/10 1059 11/3/10 1042 11/3/2010 ND ND U2869 N22 Canal-50' 10/27/10 1059 11/3/10 1044 11/3/2010 ND ND U2868 N23 Canal-100' 10/27/10 1059 11/3/10 1046 11/3/2010 ND ND U2867 N24 Canal-200' 10/27/10 1059 11/3/10 1048 11/3/2010 ND ND Page 9 of 19 ND 102 ND 4,980 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # U2866 N25 Station Name Canal-250' Date/Time Date/Time Date Placed Recovered Recovered 10/27/10 1059 11/3/10 1050 Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm Conc. ppb 11/3/2010 ND 569.4 151 U2866D N25 Canal-250' 10/27/10 1059 11/3/10 1050 11/3/2010 ND 569.9 131 U2865 N26 Canal-300' 10/27/10 1059 11/3/10 1052 11/3/2010 ND 569.3 97.1 U2864 N27 Canal-350' 10/27/10 1059 11/3/10 1054 11/3/2010 517.2 2.65 570.0 58.3 U2863 N28 Canal-450' 10/27/10 1059 11/3/10 1056 11/3/2010 515.4 119 569.3 30.0 U2862 N29 Canal-500' 10/27/10 1059 11/3/10 1058 11/3/2010 515.9 3,660 567.4** 14.9 15.0 U2862D N29 Canal-500' 10/27/10 1059 11/3/10 1058 11/3/2010 515.9 3,440 567.6** U2861 N30 Canal-550' 10/27/10 1059 11/3/10 1100 11/3/2010 515.2 107 569.5 26.2 U2859 N31 Canal-600' 10/27/10 1100 11/3/10 1102 11/3/2010 515.4 28.6 569.8 35.8 U2858 N32 Canal-700' 10/27/10 1116 11/3/10 1104 11/3/2010 515.5 18.3 569.5 184 U2857 N33 Canal-750' 10/27/10 1116 11/3/10 1106 11/3/2010 515.3 13.6 569.4 462 U2857D N33 Canal-750' 10/27/10 1116 11/3/10 1106 11/3/2010 515.3 10.1 569.1 300 U2856 N34 Canal-800' 10/27/10 1116 11/3/10 1108 11/3/2010 515.3 12.9 569.3 141 U2855 N35 Canal-850' 10/27/10 1116 11/3/10 1110 11/3/2010 515.5 12.0 568.4 99.9 U2854 N36 Canal-950' 10/27/10 1116 11/3/10 1112 11/3/2010 515.3 9.02 569.5 71.1 U2853 N37 Canal-1000' 10/27/10 1116 11/3/10 1114 11/3/2010 515.4 10.2 569.5 61.6 U2852 N38 Canal-1050' 10/27/10 1116 11/3/10 1116 11/3/2010 515.4 5.21 568.9 31.1 U2851 N39 Canal-1100' 10/27/10 1116 11/3/10 1118 11/3/2010 515.0 6.76 569.7 36.2 U2825 N40 Shallow Well-250' downgradient 10/27/10 1300 11/3/10 1348 11/3/2010 ND 567.9 5,290 U2818 N41 Shallow well -500' downgradient 10/27/10 1303 11/3/10 1332 11/3/2010 515.4 U2812 N42 Shallow Well-750' downgradient 10/27/10 1235 11/3/10 1307 11/3/2010 ND 568.1 U2807 S1 Shallow Well-200' 10/27/10 1208 11/3/10 1218 11/3/2010 ND ND U2803 S2 Shallow Well-300' 10/27/10 1138 11/3/10 1217 11/3/2010 ND ND U2802 S3 Shallow Well-350' 10/27/10 1138 11/3/10 1216 11/3/2010 ND ND U2801 S4 Shallow Well-450' 10/27/10 1138 11/3/10 1207 11/3/2010 ND ND U2796 S5 Shallow Well-550' 10/27/10 1138 11/3/10 1206 11/3/2010 ND ND U2795 S6 Shallow Well-600' 10/27/10 1138 11/3/10 1205 11/3/2010 ND ND U2794 S7 Shallow Well-700' 10/27/10 1138 11/3/10 1152 11/3/2010 ND ND U2790 S8 Shallow Well-800' 10/27/10 1138 11/3/10 1151 11/3/2010 ND ND U2789 S9 Shallow well-850' 10/27/10 1138 11/3/10 1150 11/3/2010 ND ND U2805 S14 Deep well-250'-22' downgradient 10/27/10 1212 11/3/10 1222 11/3/2010 ND 569.7 136 U2806 S15 Deep well-250'-39' downgradient 10/27/10 1212 11/3/10 1223 11/3/2010 ND 569.6 66.8 U2798 S16 Deep Well-500'-22' downgradient 10/27/10 1138 11/3/10 1210 11/3/2010 ND ND U2799 S17 Deep well-500'-39' downgradient 10/27/10 1138 11/3/10 1211 11/3/2010 ND ND U2792 S18 Deep Well-750'-22' downgradient 10/27/10 1138 11/3/10 1155 11/3/2010 ND ND U2793 S19 Deep well-750'-39' downgradient 10/27/10 1138 11/3/10 1156 11/3/2010 ND U2850 S20 Canal-(-50') 10/27/10 1045 11/3/10 1045 11/3/2010 515.5 5.95 569.8 U2849 S21 Canal-0' 10/27/10 1052 11/3/10 1047 11/3/2010 515.2 6.31 569.6 30.9 U2848 S22 Canal-50' 10/27/10 1052 11/3/10 1049 11/3/2010 515.2 5.12 569.6 27.5 U2847 S23 Canal-100' 10/27/10 1052 11/3/10 1051 11/3/2010 515.4 1.05 568.2 5.22 U2846 S24 Canal-200' 10/27/10 1052 11/3/10 1053 11/3/2010 514.8 4.25 569.0 20.4 U2845 S25 Canal-250' 10/27/10 1055 11/3/10 1055 11/3/2010 515.7 6.22 569.5 223 U2845D S25 Canal-250' 10/27/10 1055 11/3/10 1055 11/3/2010 515.7 5.61 569.3 188 U2844 S26 Canal-300' 10/27/10 1123 11/3/10 1057 11/3/2010 515.6 4.09 569.5 92.3 U2843 S27 Canal-350' 10/27/10 1123 11/3/10 1059 11/3/2010 515.7 4.54 569.7 73.7 U2842 S29 Canal-500' 10/27/10 1123 11/3/10 1103 11/3/2010 515.9 465 569.5 41.7 U2842D S29 Canal-500' 10/27/10 1123 11/3/10 1103 11/3/2010 515.2 268 569.3 43.5 U2841 S30 Canal-550' 10/27/10 1123 11/3/10 1105 11/3/2010 515.2 58.4 569.2 26.9 U2839 S31 Canal-600' 10/27/10 1123 11/3/10 1107 11/3/2010 515.3 58.0 569.5 54.1 U2838 S32 Canal-700' 10/27/10 1123 11/3/10 1109 11/3/2010 515.2 22.6 569.5 34.5 U2837 S33 Canal-750' 10/27/10 1123 11/3/10 1111 11/3/2010 515.5 12.8 569.7 1,510 U2837D S33 Canal-750' 10/27/10 1123 11/3/10 1111 11/3/2010 515.8 17.4 568.2 2,530 U2836 S34 Canal-800' 10/27/10 1123 11/3/10 1113 11/3/2010 515.1 15.7 569.7 93.6 U2835 S35 Canal-850' 10/27/10 1123 11/3/10 1115 11/3/2010 515.3 16.8 569.7 92.1 Page 10 of 19 189 ND 10,500 ND 34.5 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm Conc. ppb U2834 S36 Canal-950' 10/27/10 1123 11/3/10 1117 11/3/2010 515.2 16.7 569.5 68.9 U2833 S37 Canal-1000' 10/27/10 1123 11/3/10 1119 11/3/2010 515.3 12.5 569.8 52.3 U2832 S38 Canal-1050' 10/27/10 1123 11/3/10 1121 11/3/2010 515.2 11.0 570.0 36.2 U2831 S39 Canal-1100' 10/27/10 1123 11/3/10 1123 11/3/2010 515.3 12.2 569.5 50.3 U2804 S40 Shallow Well-250' downgradient 10/27/10 1214 11/3/10 1224 11/3/2010 ND 569.2 8.97 U2797 S41 Shallow well-500' downgradient 10/27/10 1138 11/3/10 1212 11/3/2010 515.1 U2791 S42 Shallow Well-750' downgradient 10/27/10 1138 11/3/10 1157 11/3/2010 ND 567.6 U3072 N1 Shallow Well-200' 11/3/10 1330 11/10/10 1434 11/10/2010 ND ND U3068 N2 Shallow Well-300' 11/3/10 1330 11/10/10 1422 11/10/2010 ND ND U3067 N3 Shallow Well-350' 11/3/10 1330 11/10/10 1418 11/10/2010 ND ND U3066 N4 Shallow Well-450' 11/3/10 1330 11/10/10 1414 11/10/2010 ND ND U3062 N5 Shallow Well-550' 11/3/10 1240 11/10/10 1402 11/10/2010 ND ND U3061 N6 Shallow Well-600' 11/3/10 1240 11/10/10 1358 11/10/2010 ND ND U3059 N7 Shallow Well-700' 11/3/10 1240 11/10/10 1354 11/10/2010 ND 569.6 U3055 N8 Shallow Well-800' 11/3/10 1240 11/10/10 1342 11/10/2010 ND ND 61.3 ND 2,140 6.41 U3054 N9 Shallow well-850' 11/3/10 1240 11/10/10 1338 11/10/2010 ND ND U3073 N10 Shallow Well-(-5) 11/3/10 1330 11/10/10 1438 11/10/2010 ND ND U3074 N11 Shallow Well-(-15') 11/3/10 1358 11/10/10 1442 11/10/2010 ND ND U3053 N12 Shallow Well-1005' 11/3/10 1240 11/10/10 1334 11/10/2010 ND ND U3052 N13 Shallow Well-1015' 11/3/10 1240 11/10/10 1330 11/10/2010 ND ND U3070 N14 Deep well-250'-22' downgradient 11/3/10 1330 11/10/10 1430 11/10/2010 ND ND U3071 N15 Deep well-250'-39' downgradient 11/3/10 1330 11/10/10 1430 11/10/2010 ND ND U3064 N16 Deep Well-500'-22' downgradient 11/3/10 1330 11/10/10 1410 11/10/2010 ND ND U3065 N17 Deep Well-500'-39' downgradient 11/3/10 1330 11/10/10 1410 11/10/2010 ND ND U3057 N18 Deep well-750'-22' downgradient 11/3/10 1240 11/10/10 1350 11/10/2010 ND ND U3058 N19 Deep well-750'-39' downgradient 11/3/10 1240 11/10/10 1350 11/10/2010 ND ND U3116 N20 Canal-(-50') 11/3/10 1040 11/10/10 NT #VALUE! ND ND U3115 N21 Canal-0' 11/3/10 1040 11/10/10 0930 11/10/2010 ND ND U3114 N22 Canal-50' 11/3/10 1100 11/10/10 0932 11/10/2010 ND ND U3113 N23 Canal-100' 11/3/10 1100 11/10/10 0934 11/10/2010 ND ND U3112 N24 Canal-200' 11/3/10 1100 11/10/10 0936 11/10/2010 ND ND U3111 N25 Canal-250' 11/3/10 1100 11/10/10 0938 11/10/2010 ND 568.6 U3111D N25 Canal-250' 11/3/10 1100 11/10/10 0938 11/10/2010 ND 568.6 82.9 U3110 N26 Canal-300' 11/3/10 1100 11/10/10 0940 11/10/2010 ND 568.6 35.6 U3109 N27 Canal-350' 11/3/10 1100 11/10/10 0942 11/10/2010 515.8 0.941 570.0 20.5 U3108 N28 Canal-450' 11/3/10 1100 11/10/10 0944 11/10/2010 515.6 67.7 569.0 16.3 U3107 N29 Canal-500' 11/3/10 1100 11/10/10 0946 11/10/2010 516.1 1,250 569.6** 13.3 U3107D N29 Canal-500' 11/3/10 1100 11/10/10 0946 11/10/2010 516.0 821 570.0** 12.5 U3106 N30 Canal-550' 11/3/10 1100 11/10/10 0948 11/10/2010 515.6 20.1 567.5 10.4 U3105 N31 Canal-600' 11/3/10 1102 11/10/10 0950 11/10/2010 515.8 6.90 570.6 6.29 U3104 N32 Canal-700' 11/3/10 1118 11/10/10 0952 11/10/2010 515.8 3.03 569.6 32.6 U3103 N33 Canal-750' 11/3/10 1118 11/10/10 0954 11/10/2010 515.8 4.08 569.2 192 U3103D N33 Canal-750' 11/3/10 1118 11/10/10 0954 11/10/2010 515.6 4.66 569.3 232 U3102 N34 Canal-800' 11/3/10 1118 11/10/10 0956 11/10/2010 516.0 2.92 569.5 62.9 U3101 N35 Canal-850' 11/3/10 1118 11/10/10 0958 11/10/2010 515.2 3.13 569.4 42.6 U3099 N36 Canal-950' 11/3/10 1118 11/10/10 1000 11/10/2010 516.2 2.11 569.0 19.7 U3098 N37 Canal-1000' 11/3/10 1118 11/10/10 1002 11/10/2010 515.2 3.10 569.0 26.2 U3097 N38 Canal-1050' 11/3/10 1118 11/10/10 1004 11/10/2010 516.0 1.97 570.6 14.6 U3096 N39 Canal-1100' 11/3/10 1118 11/10/10 1006 11/10/2010 515.8 1.29 570.0 9.26 U3069 N40 Shallow Well-250' downgradient 11/3/10 1330 11/10/10 1426 11/10/2010 ND 567.8 2,620 U3063 N41 Shallow well -500' downgradient 11/3/10 1332 11/10/10 1406 11/10/2010 515.2 U3056 N42 Shallow Well-750' downgradient 11/3/10 1240 11/10/10 1346 11/10/2010 ND 568.2 U3051 S1 Shallow Well-200' 11/3/10 1218 11/10/10 1215 11/10/2010 ND ND U3047 S2 Shallow Well-300' 11/3/10 1150 11/10/10 1227 11/10/2010 ND ND Page 11 of 19 59.5 73.3 ND 2,920 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm Conc. ppb U3046 S3 Shallow Well-350' 11/3/10 1150 11/10/10 1231 11/10/2010 ND ND U3045 S4 Shallow Well-450' 11/3/10 1150 11/10/10 1235 11/10/2010 ND ND U3041 S5 Shallow Well-550' 11/3/10 1150 11/10/10 1251 11/10/2010 ND ND U3039 S6 Shallow Well-600' 11/3/10 1150 11/10/10 1255 11/10/2010 ND ND U3038 S7 Shallow Well-700' 11/3/10 1150 11/10/10 1259 11/10/2010 ND ND U3034 S8 Shallow Well-800' 11/3/10 1150 11/10/10 1311 11/10/2010 ND ND U3033 S9 Shallow well-850' 11/3/10 1150 11/10/10 1314 11/10/2010 ND ND U3049 S14 Deep well-250'-22' downgradient 11/3/10 1222 11/10/10 1219 11/10/2010 ND 568.6 48.4 U3050 S15 Deep well-250'-39' downgradient 11/3/10 1222 11/10/10 1219 11/10/2010 ND 569.4 26.6 U3043 S16 Deep Well-500'-22' downgradient 11/3/10 1150 11/10/10 1239 11/10/2010 ND ND U3044 S17 Deep well-500'-39' downgradient 11/3/10 1150 11/10/10 1239 11/10/2010 ND ND U3036 S18 Deep Well-750'-22' downgradient 11/3/10 1150 11/10/10 1303 11/10/2010 ND ND U3037 S19 Deep well-750'-39' downgradient 11/3/10 1150 11/10/10 1303 11/10/2010 ND U3095 S20 Canal-(-50') 11/3/10 1045 11/10/10 1015 11/10/2010 516.6 1.43 569.8 U3094 S21 Canal-0' 11/3/10 1053 11/10/10 1017 11/10/2010 515.8 0.972 570.2 5.24 U3093 S22 Canal-50' 11/3/10 1053 11/10/10 1019 11/10/2010 515.6 1.23 569.4 9.47 U3092 S23 Canal-100' 11/3/10 1053 11/10/10 1021 11/10/2010 516.4 1.23 570.2 10.7 U3091 S24 Canal-200' 11/3/10 1053 11/10/10 1023 11/10/2010 516.0 1.36 569.4 8.21 U3090 S25 Canal-250' 11/3/10 1055 11/10/10 1025 11/10/2010 515.6 1.88 569.4 69.5 U3090D S25 Canal-250' 11/3/10 1055 11/10/10 1025 11/10/2010 516.0 2.25 570.2 65.2 U3089 S26 Canal-300' 11/3/10 1123 11/10/10 1027 11/10/2010 516.4 3.21 570.4 53.5 U3088 S27 Canal-350' 11/3/10 1123 11/10/10 1029 11/10/2010 515.8 1.94 568.8 14.1 U3087 S28 Canal-450' 11/3/10 1123 11/10/10 1031 11/10/2010 515.8 2.02 569.2 11.3 U3086 S29 Canal-500' 11/3/10 1123 11/10/10 1033 11/10/2010 515.4 75.7 570.4 14.7 U3086D S29 Canal-500' 11/3/10 1123 11/10/10 1033 11/10/2010 515.0 67.7 567.8 12.8 U3085 S30 Canal-550' 11/3/10 1123 11/10/10 1035 11/10/2010 515.2 26.6 569.0 17.5 U3084 S31 Canal-600' 11/3/10 1123 11/10/10 1037 11/10/2010 515.0 17.8 569.2 15.4 U3083 S32 Canal-700' 11/3/10 1123 11/10/10 1039 11/10/2010 515.4 10.9 569.8 16.1 U3082 S33 Canal-750' 11/3/10 1123 11/10/10 1041 11/10/2010 516.2 7.54 569.6 766 U3082D S33 Canal-750' 11/3/10 1123 11/10/10 1041 11/10/2010 515.2 6.43 569.6 665 U3081 S34 Canal-800' 11/3/10 1123 11/10/10 1043 11/10/2010 515.2 4.59 570.4 26.6 U3079 S35 Canal-850' 11/3/10 1123 11/10/10 1045 11/10/2010 515.2 4.73 569.0 19.8 U3078 S36 Canal-950' 11/3/10 1123 11/10/10 1047 11/10/2010 515.6 3.25 569.4 11.2 U3077 S37 Canal-1000' 11/3/10 1123 11/10/10 1049 11/10/2010 514.8 2.60 570.0 7.64 U3076 S38 Canal-1050' 11/3/10 1123 11/10/10 1051 11/10/2010 515.6 2.36 570.0 9.47 U3075 S39 Canal-1100' 11/3/10 1123 11/10/10 1053 11/10/2010 516.0 3.42 570.2 11.0 U3048 S40 Shallow Well-250' downgradient 11/3/10 1224 11/10/10 1223 11/10/2010 ND U3042 S41 Shallow well-500' downgradient 11/3/10 1150 11/10/10 1247 11/10/2010 515.0 U3035 S42 Shallow Well-750' downgradient 11/3/10 1150 11/10/10 1307 11/10/2010 ND 569.3 U3442 N1 Shallow Well-200' 11/10/10 1434 11/17/10 1257 11/17/2010 ND ND U3437 N2 Shallow Well-300' 11/10/10 1422 11/17/10 1255 11/17/2010 ND ND U3436 N3 Shallow Well-350' 11/10/10 1418 11/17/10 1253 11/17/2010 ND ND U3435 N4 Shallow Well-450' 11/10/10 1414 11/17/10 1248 11/17/2010 ND ND U3431 N5 Shallow Well-550' 11/10/10 1402 11/17/10 1246 11/17/2010 ND ND U3430 N6 Shallow Well-600' 11/10/10 1358 11/17/10 1244 11/17/2010 ND ND U3429 N7 Shallow Well-700' 11/10/10 1354 11/17/10 1235 11/17/2010 ND 568.6 U3425 N8 Shallow Well-800' 11/10/10 1342 11/17/10 1233 11/17/2010 ND ND ND ND ND 58.7 ND U3424 N9 Shallow well-850' 11/10/10 1338 11/17/10 1231 11/17/2010 ND U3443 N10 Shallow Well-(-5) 11/10/10 1438 11/17/10 1307 11/17/2010 ND ND U3444 N11 Shallow Well-(-15') 11/10/10 1442 11/17/10 1309 11/17/2010 ND ND U3423 N12 Shallow Well-1005' 11/10/10 1334 11/17/10 1227 11/17/2010 ND ND U3422 N13 Shallow Well-1015' 11/10/10 1330 11/17/10 1225 11/17/2010 ND ND U3439 N14 Deep well-250'-22' downgradient 11/10/10 1430 11/17/10 1259 11/17/2010 ND ND U3441 N15 Deep well-250'-39' downgradient 11/10/10 1430 11/17/10 1301 11/17/2010 ND ND Page 12 of 19 9.06 798 108 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm Conc. ppb U3433 N16 Deep Well-500'-22' downgradient 11/10/10 1410 11/17/10 1250 11/17/2010 ND ND U3434 N17 Deep Well-500'-39' downgradient 11/10/10 1410 11/17/10 1252 11/17/2010 ND ND U3427 N18 Deep well-750'-22' downgradient 11/10/10 1350 11/17/10 1237 11/17/2010 ND ND U3428 N19 Deep well-750'-39' downgradient 11/10/10 1350 11/17/10 1234 11/17/2010 ND ND U3486 N20 Canal-(-50') 11/10/10 0928 11/17/10 1040 11/17/2010 ND ND U3485 N21 Canal-0' 11/10/10 0930 11/17/10 1042 11/17/2010 ND ND U3484 N22 Canal-50' 11/10/10 0932 11/17/10 1044 11/17/2010 ND ND U3483 N23 Canal-100' 11/10/10 0934 11/17/10 1046 11/17/2010 ND ND U3482 N24 Canal-200' 11/10/10 0936 11/17/10 1048 11/17/2010 ND ND U3481 N25 Canal-250' 11/10/10 0938 11/17/10 1050 11/17/2010 ND 569.1 108 U3481D N25 Canal-250' 11/10/10 0938 11/17/10 1050 11/17/2010 ND 569.4 118 U3479 N26 Canal-300' 11/10/10 0940 11/17/10 1052 11/17/2010 ND 568.2 50.2 U3478 N27 Canal-350' 11/10/10 0942 11/17/10 1054 11/17/2010 ND 569 20.8 U3477 N28 Canal-450' 11/10/10 0944 11/17/10 1056 11/17/2010 515.6 85.2 569.1 16.4 U3476 N29 Canal-500' 11/10/10 0946 11/17/10 1058 11/17/2010 515.6 81.8 568.0 10.9 U3476D N29 Canal-500' 11/10/10 0946 11/17/10 1058 11/17/2010 515.4 58.1 570.7 9.00 U3475 N30 Canal-550' 11/10/10 0948 11/17/10 1100 11/17/2010 515.2 15.6 569.6 6.46 U3474 N31 Canal-600' 11/10/10 0950 11/17/10 1102 11/17/2010 515.4 4.87 570.8 5.65 U3473 N32 Canal-700' 11/10/10 0952 11/17/10 1104 11/17/2010 515.9 3.82 569.1 65.0 U3472 N33 Canal-750' 11/10/10 0954 11/17/10 1106 11/17/2010 516.2 3.85 569.4 286 U3472D N33 Canal-750' 11/10/10 0954 11/17/10 1106 11/17/2010 516.3 2.18 568.8 174 U3471 N34 Canal-800' 11/10/10 0956 11/17/10 1108 11/17/2010 516.6 1.66 568.2 44.0 U3470 N35 Canal-850' 11/10/10 0958 11/17/10 1110 11/17/2010 516.8 1.31 568.6 25.0 U3469 N36 Canal-950' 11/10/10 1000 11/17/10 1112 11/17/2010 514.8 1.20 569.6 16.9 U3468 N37 Canal-1000' 11/10/10 1002 11/17/10 1114 11/17/2010 515.8 1.60 570.0 13.6 U3467 N38 Canal-1050' 11/10/10 1004 11/17/10 1116 11/17/2010 515.8 1.31 569.2 10.1 U3466 N39 Canal-1100' 11/10/10 1006 11/17/10 1118 11/17/2010 516.2 1.03 569.6 9.08 U3438 N40 Shallow Well-250' downgradient 11/10/10 1426 11/17/10 1303 11/17/2010 ND 567.5 2,650 U3432 N41 Shallow well -500' downgradient 11/10/10 1406 11/17/10 1254 11/17/2010 515.5 U3426 N42 Shallow Well-750' downgradient 11/10/10 1346 11/17/10 1241 11/17/2010 ND 569.3 U3421 S1 Shallow Well-200' 11/10/10 1215 11/17/10 1204 11/17/2010 ND ND U3416 S2 Shallow Well-300' 11/10/10 1227 11/17/10 1202 11/17/2010 ND ND U3415 S3 Shallow Well-350' 11/10/10 1231 11/17/10 1200 11/17/2010 ND ND U3414 S4 Shallow Well-450' 11/10/10 1235 11/17/10 1149 11/17/2010 ND ND U3410 S5 Shallow Well-550' 11/10/10 1251 11/17/10 1147 11/17/2010 ND ND U3409 S6 Shallow Well-600' 11/10/10 1255 11/17/10 1145 11/17/2010 ND ND U3408 S7 Shallow Well-700' 11/10/10 1259 11/17/10 1134 11/17/2010 ND ND U3404 S8 Shallow Well-800' 11/10/10 1311 11/17/10 1132 11/17/2010 ND ND U3403 S9 Shallow well-850' 11/10/10 1314 11/17/10 1130 11/17/2010 ND ND U3418 S14 Deep well-250'-22' downgradient 11/10/10 1219 11/17/10 1206 11/17/2010 ND 569.6 44.7 U3419 S15 Deep well-250'-39' downgradient 11/10/10 1219 11/17/10 1208 11/17/2010 ND 569.0 22.8 U3412 S16 Deep Well-500'-22' downgradient 11/10/10 1239 11/17/10 1151 11/17/2010 ND ND U3413 S17 Deep well-500'-39' downgradient 11/10/10 1239 11/17/10 1153 11/17/2010 ND ND U3406 S18 Deep Well-750'-22' downgradient 11/10/10 1303 11/17/10 1136 11/17/2010 ND ND U3407 S19 Deep well-750'-39' downgradient 11/10/10 1303 11/17/10 1138 11/17/2010 ND U3465 S20 Canal-(-50') 11/10/10 1015 11/17/10 1045 11/17/2010 516.6 0.857 570.0 6.24 U3464 S21 Canal-0' 11/10/10 1017 11/17/10 1047 11/17/2010 515.8 0.917 569.2 5.89 U3463 S22 Canal-50' 11/10/10 1019 11/17/10 1049 11/17/2010 516.2 0.808 570.6 5.50 U3462 S23 Canal-100' 11/10/10 1021 11/17/10 1051 11/17/2010 516.2 0.783 569.4 5.6 U3461 S24 Canal-200' 11/10/10 1023 11/17/10 1053 11/17/2010 516.8 0.648 569.2 6.84 U3459 S25 Canal-250' 11/10/10 1025 11/17/10 1055 11/17/2010 515.8 0.625 569.6 18.9 U3459D S25 Canal-250' 11/10/10 1025 11/17/10 1055 11/17/2010 517.2 0.683 569.2 16.2 U3458 S26 Canal-300' 11/10/10 1027 11/17/10 1057 11/17/2010 514.8 0.898 570.2 21.7 U3457 S27 Canal-350' 11/10/10 1029 11/17/10 1059 11/17/2010 517.8 0.540 570.2 8.49 Page 13 of 19 48.7 ND 1,190 ND Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm 516.4 Conc. ppb 0.937 RWT Results Peak nm 570.8 Conc. ppb U3456 S28 Canal-450' 11/10/10 1031 11/17/10 1101 11/17/2010 8.26 U3455 S29 Canal-500' 11/10/10 1033 11/17/10 1103 11/17/2010 515.0 47.6 569.4 20.1 U3455D S29 Canal-500' 11/10/10 1033 11/17/10 1103 11/17/2010 515.2 45.2 569.2 20.3 U3454 S30 Canal-550' 11/10/10 1035 11/17/10 1105 11/17/2010 515.2 12.0 569.6 4.13 U3453 S31 Canal-600' 11/10/10 1037 11/17/10 1107 11/17/2010 515.2 13.8 570.0 7.58 U3452 S32 Canal-700' 11/10/10 1039 11/17/10 1109 11/17/2010 515.4 5.26 ND U3451 S33 Canal-750' 11/10/10 1041 11/17/10 1111 11/17/2010 515.5 5.02 569.8 373 U3451D S33 Canal-750' 11/10/10 1041 11/17/10 1111 11/17/2010 516.8 3.68 569.7 1,240 U3450 S34 Canal-800' 11/10/10 1043 11/17/10 1113 11/17/2010 515.6 2.86 569.0 13.7 U3449 S35 Canal-850' 11/10/10 1045 11/17/10 1115 11/17/2010 515.6 2.67 569.0 11.3 U3448 S36 Canal-950' 11/10/10 1047 11/17/10 1117 11/17/2010 515.2 1.95 568.0 7.85 U3447 S37 Canal-1000' 11/10/10 1049 11/17/10 1119 11/17/2010 515.4 2.62 568.2 8.73 U3446 S38 Canal-1050' 11/10/10 1051 11/17/10 1121 11/17/2010 514.6 1.97 569.0 5.68 U3445 S39 Canal-1100' 11/10/10 1053 11/17/10 1123 11/17/2010 515.6 1.17 570.4 5.38 U3417 S40 Shallow Well-250' downgradient 11/10/10 1223 11/17/10 1210 11/17/2010 ND U3411 S41 Shallow well-500' downgradient 11/10/10 1247 11/17/10 1155 11/17/2010 515.3 U3405 S42 Shallow Well-750' downgradient 11/10/10 1307 11/17/10 1140 11/17/2010 ND 569.0 U3914 N1 Shallow Well-200' 11/17/10 1257 12/1/10 1257 12/1/2010 ND ND U3910 N2 Shallow Well-300' 11/17/10 1255 12/1/10 1255 12/1/2010 ND ND U3909 N3 Shallow Well-350' 11/17/10 1253 12/1/10 1253 12/1/2010 ND ND U3908 N4 Shallow Well-450' 11/17/10 1248 12/1/10 1248 12/1/2010 ND ND U3904 N5 Shallow Well-550' 11/17/10 1246 12/1/10 1246 12/1/2010 ND ND U3903 N6 Shallow Well-600' 11/17/10 1244 12/1/10 1244 12/1/2010 ND ND U3902 N7 Shallow Well-700' 11/17/10 1235 12/1/10 1235 12/1/2010 ND 568.7 U3897 N8 Shallow Well-800' 11/17/10 1233 12/1/10 1233 12/1/2010 ND ND ND ND 40.3 ND 751 362 U3896 N9 Shallow well-850' 11/17/10 1231 12/1/10 1231 12/1/2010 ND U3915 N10 Shallow Well-(-5) 11/17/10 1307 12/1/10 1307 12/1/2010 ND ND U3916 N11 Shallow Well-(-15') 11/17/10 1309 12/1/10 1309 12/1/2010 ND ND U3895 N12 Shallow Well-1005' 11/17/10 1227 12/1/10 1227 12/1/2010 ND ND U3894 N13 Shallow Well-1015' 11/17/10 1225 12/1/10 1225 12/1/2010 ND ND U3912 N14 Deep well-250'-22' downgradient 11/17/10 1259 12/1/10 1259 12/1/2010 ND ND U3913 N15 Deep well-250'-39' downgradient 11/17/10 1301 12/1/10 1301 12/1/2010 ND ND U3906 N16 Deep Well-500'-22' downgradient 11/17/10 1250 12/1/10 1250 12/1/2010 ND ND U3907 N17 Deep Well-500'-39' downgradient 11/17/10 1252 12/1/10 1252 12/1/2010 ND ND U3899 N18 Deep well-750'-22' downgradient 11/17/10 1237 12/1/10 1237 12/1/2010 ND ND U3901 N19 Deep well-750'-39' downgradient 11/17/10 1239 12/1/10 1239 12/1/2010 ND ND U4197 N20 Canal-(-50') 11/17/10 1040 12/1/10 1040 12/1/2010 ND ND U3957 N21 Canal-0' 11/17/10 1042 12/1/10 1042 12/1/2010 ND ND U3956 N22 Canal-50' 11/17/10 1044 12/1/10 1044 12/1/2010 ND ND U3955 N23 Canal-100' 11/17/10 1046 12/1/10 1046 12/1/2010 ND ND U3954 N24 Canal-200' 11/17/10 1048 12/1/10 1048 12/1/2010 ND ND U3953 N25 Canal-250' 11/17/10 1050 12/1/10 1050 12/1/2010 ND 569.0 81.5 U3953D N25 Canal-250' 11/17/10 1050 12/1/10 1050 12/1/2010 ND 568.2 74.9 U3952 N26 Canal-300' 11/17/10 1052 12/1/10 1052 12/1/2010 ND 569.0 34.2 U3951 N27 Canal-350' 11/17/10 1054 12/1/10 1054 12/1/2010 ND 569.0 16.6 U3950 N28 Canal-450' 11/17/10 1056 12/1/10 1056 12/1/2010 515.6 10.4 568.4 7.29 U3949 N29 Canal-500' 11/17/10 1058 12/1/10 1058 12/1/2010 515.4 40.6 568.8 12.6 U3949D N29 Canal-500' 11/17/10 1058 12/1/10 1058 12/1/2010 515.4 84.1 568.7 18.2 U3948 N30 Canal-550' 11/17/10 1100 12/1/10 1100 12/1/2010 515.8 8.13 569.2 6.73 U3947 N31 Canal-600' 11/17/10 1102 12/1/10 1102 12/1/2010 516.2 3.01 ND U3946 N32 Canal-700' 11/17/10 1104 12/1/10 1104 12/1/2010 516.1 2.95 569.3 U3945 N33 Canal-750' 11/17/10 1106 12/1/10 1106 12/1/2010 515.0 2.07 569.0 202 U3945D N33 Canal-750' 11/17/10 1106 12/1/10 1106 12/1/2010 516.5 1.61 568.8 160 U3944 N34 Canal-800' 11/17/10 1108 12/1/10 1108 12/1/2010 516.6 1.63 569.5 38.0 Page 14 of 19 54.5 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered 11/17/10 1110 12/1/10 1110 517.2 Conc. ppb 0.944 RWT Results Peak nm N35 Canal-850' U3942 N36 Canal-950' 11/17/10 1112 12/1/10 1112 12/1/2010 516.8 0.700 569.0 11.4 U3941 N37 Canal-1000' 11/17/10 1114 12/1/10 1114 12/1/2010 516.6 0.673 569.0 9.77 U3939 N38 Canal-1050' 11/17/10 1116 12/1/10 1116 12/1/2010 516.8 1.32 569.0 14.6 U3938 N39 Canal-1100' 11/17/10 1118 12/1/10 1118 12/1/2010 515.8 0.990 569.6 10.5 U3911 N40 Shallow Well-250' downgradient 11/17/10 1303 12/1/10 1303 12/1/2010 ND 567.6 2,780 U3905 N41 Shallow well -500' downgradient 11/17/10 1254 12/1/10 1254 12/1/2010 515.5 U3898 N42 Shallow Well-750' downgradient 11/17/10 1241 12/1/10 1241 12/1/2010 ND 569.2 U3893 S1 Shallow Well-200' 11/17/10 1204 12/1/10 1204 12/1/2010 ND ND U3889 S2 Shallow Well-300' 11/17/10 1202 12/1/10 1202 12/1/2010 ND ND U3888 S3 Shallow Well-350' 11/17/10 1200 12/1/10 1200 12/1/2010 ND ND U3887 S4 Shallow Well-450' 11/17/10 1149 12/1/10 1149 12/1/2010 ND ND U3883 S5 Shallow Well-550' 11/17/10 1147 12/1/10 1147 12/1/2010 ND ND U3882 S6 Shallow Well-600' 11/17/10 1145 12/1/10 1145 12/1/2010 ND ND U3881 S7 Shallow Well-700' 11/17/10 1134 12/1/10 1134 12/1/2010 ND ND U3876 S8 Shallow Well-800' 11/17/10 1132 12/1/10 1132 12/1/2010 ND ND U3875 S9 Shallow well-850' 11/17/10 1130 12/1/10 1130 12/1/2010 ND ND U3891 S14 Deep well-250'-22' downgradient 11/17/10 1206 12/1/10 1206 12/1/2010 ND 569.2 75.7 U3892 S15 Deep well-250'-39' downgradient 11/17/10 1208 12/1/10 1208 12/1/2010 ND 568.6 23.9 U3885 S16 Deep Well-500'-22' downgradient 11/17/10 1151 12/1/10 1151 12/1/2010 ND ND U3886 S17 Deep well-500'-39' downgradient 11/17/10 1153 12/1/10 1153 12/1/2010 ND ND U3878 S18 Deep Well-750'-22' downgradient 11/17/10 1136 12/1/10 1136 12/1/2010 ND 568.6 U3879 S19 Deep well-750'-39' downgradient 11/17/10 1138 12/1/10 1138 12/1/2010 ND ND U3937 S20 Canal-(-50') 11/17/10 1045 12/1/10 1045 12/1/2010 517.8 0.612 569.6 U3936 S21 Canal-0' 11/17/10 1047 12/1/10 1047 12/1/2010 516.2 0.610 569.4 6.92 U3935 S22 Canal-50' 11/17/10 1049 12/1/10 1049 12/1/2010 516.4 0.660 568.8 5.67 U3934 S23 Canal-100' 11/17/10 1051 12/1/10 1051 12/1/2010 516.2 0.768 569.4 6.37 U3933 S24 Canal-200' 11/17/10 1053 12/1/10 1053 12/1/2010 516.6 1.02 568.0 9.53 U3932 S25 Canal-250' 11/17/10 1055 12/1/10 1055 12/1/2010 517.6 1.58 569.3 98.4 U3932D S25 Canal-250' 11/17/10 1055 12/1/10 1055 12/1/2010 516.6 1.36 569.2 51.8 U3931 S26 Canal-300' 11/17/10 1057 12/1/10 1057 12/1/2010 517.2 0.831 569.4 15.8 U3930 S27 Canal-350' 11/17/10 1059 12/1/10 1059 12/1/2010 516.6 0.913 568.8 9.36 U3929 S28 Canal-450' 11/17/10 1101 12/1/10 1101 12/1/2010 515.2 1.29 569.6 8.80 U3928 S29 Canal-500' 11/17/10 1103 12/1/10 1103 12/1/2010 515.4 57.9 570.0 8.33 U3928D S29 Canal-500' 11/17/10 1103 12/1/10 1103 12/1/2010 515.3 181 ND U3927 S30 Canal-550' 11/17/10 1105 12/1/10 1105 12/1/2010 515.2 9.34 570.0 5.90 U3926 S31 Canal-600' 11/17/10 1107 12/1/10 1107 12/1/2010 515.4 6.08 567.6 9.14 U3925 S32 Canal-700' 11/17/10 1109 12/1/10 1109 12/1/2010 515.6 2.84 ND U3924 S33 Canal-750' 11/17/10 1111 12/1/10 1111 12/1/2010 516.5 1.52 569.2 209 U3924D S33 Canal-750' 11/17/10 1111 12/1/10 1111 12/1/2010 516.5 1.75 568.8 284 U3923 S34 Canal-800' 11/17/10 1113 12/1/10 1113 12/1/2010 515.6 2.36 568.8 13.5 U3922 S35 Canal-850' 11/17/10 1115 12/1/10 1115 12/1/2010 515.6 1.65 569.4 8.60 U3921 S36 Canal-950' 11/17/10 1117 12/1/10 1117 12/1/2010 516.8 1.10 570.6 6.09 U3919 S37 Canal-1000' 11/17/10 1119 12/1/10 1119 12/1/2010 516.2 1.32 570.0 6.55 U3918 S38 Canal-1050' 11/17/10 1121 12/1/10 1121 12/1/2010 515.6 1.26 569.0 8.28 U3917 S39 Canal-1100' 11/17/10 1123 12/1/10 1123 12/1/2010 515.6 1.41 568.8 8.69 U3890 S40 Shallow Well-250' downgradient 11/17/10 1210 12/1/10 1210 12/1/2010 ND U3884 S41 Shallow well-500' downgradient 11/17/10 1155 12/1/10 1155 12/1/2010 515.2 U3877 S42 Shallow Well-750' downgradient 11/17/10 1140 12/1/10 1140 12/1/2010 ND 568.9 U4642 N1 Shallow Well-200' 12/1/10 1257 12/15/10 1257 12/15/2010 ND ND U4637 N2 Shallow Well-300' 12/1/10 1255 12/15/10 1255 12/15/2010 ND ND U4636 N3 Shallow Well-350' 12/1/10 1253 12/15/10 1253 12/15/2010 ND ND U4635 N4 Shallow Well-450' 12/1/10 1248 12/15/10 1248 12/15/2010 ND ND U4631 N5 Shallow Well-550' 12/1/10 1246 12/15/10 1246 12/15/2010 ND ND 32.7 569.6 Conc. ppb U3943 Page 15 of 19 12/1/2010 Fluorescein Results Peak nm 20.5 ND 1,420 12.5 4.73 ND 29.9 ND 959 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm U4630 N6 Shallow Well-600' 12/1/10 1244 12/15/10 1244 12/15/2010 ND ND U4629 N7 Shallow Well-700' 12/1/10 1235 12/15/10 1235 12/15/2010 ND 567.2 U4625 N8 Shallow Well-800' 12/1/10 1233 12/15/10 1233 12/15/2010 ND ND ND Conc. ppb 3,330 U4624 N9 Shallow well-850' 12/1/10 1231 12/15/10 1231 12/15/2010 ND U4643 N10 Shallow Well-(-5') 12/1/10 1307 12/15/10 1307 12/15/2010 ND ND U4644 N11 Shallow Well-(-15') 12/1/10 1309 12/15/10 1309 12/15/2010 ND ND U4623 N12 Shallow Well-1005' 12/1/10 1227 12/15/10 1227 12/15/2010 ND ND U4622 N13 Shallow Well-1015' 12/1/10 1225 12/15/10 1225 12/15/2010 ND ND U4639 N14 Deep well-250'-22' downgradient 12/1/10 1259 12/15/10 1259 12/15/2010 ND ND U4641 N15 Deep well-250'-39' downgradient 12/1/10 1301 12/15/10 1301 12/15/2010 ND ND U4633 N16 Deep Well-500'-22' downgradient 12/1/10 1250 12/15/10 1250 12/15/2010 ND ND U4634 N17 Deep Well-500'-39' downgradient 12/1/10 1252 12/15/10 1252 12/15/2010 ND ND U4627 N18 Deep well-750'-22' downgradient 12/1/10 1237 12/15/10 1237 12/15/2010 ND ND U4628 N19 Deep well-750'-39' downgradient 12/1/10 1239 12/15/10 1239 12/15/2010 ND ND U4686 N20 Canal-(-50') 12/1/10 1040 12/15/10 1040 12/15/2010 ND ND U4685 N21 Canal-0' 12/1/10 1042 12/15/10 1042 12/15/2010 ND ND U4684 N22 Canal-50' 12/1/10 1044 12/15/10 1044 12/15/2010 ND ND U4683 N23 Canal-100' 12/1/10 1046 12/15/10 1046 12/15/2010 ND ND U4682 N24 Canal-200' 12/1/10 1048 12/15/10 1048 12/15/2010 ND ND U4681 N25 Canal-250' 12/1/10 1050 12/15/10 1050 12/15/2010 ND 569.2 U4681D N25 Canal-250' 12/1/10 1050 12/15/10 1050 12/15/2010 ND 569.0 46.3 U4679 N26 Canal-300' 12/1/10 1052 12/15/10 1052 12/15/2010 ND 569.6 8.27 U4678 N27 Canal-350' 12/1/10 1054 12/15/10 1054 12/15/2010 ND 567.0 6.14 U4677 N28 Canal-450' 12/1/10 1056 12/15/10 1056 12/15/2010 515.2 14.9 569.6 7.09 U4676 N29 Canal-500' 12/1/10 1058 12/15/10 1058 12/15/2010 515.5 180 ND 33.3 U4676D N29 Canal-500' 12/1/10 1058 12/15/10 1058 12/15/2010 515.5 160 ND U4675 N30 Canal-550' 12/1/10 1100 12/15/10 1100 12/15/2010 514.8 3.01 570.6 3.74 U4674 N31 Canal-600' 12/1/10 1102 12/15/10 1102 12/15/2010 515.8 1.29 569.2 4.31 U4673 N32 Canal-700' 12/1/10 1104 12/15/10 1104 12/15/2010 515.6 0.705 569.0 16.3 U4672 N33 Canal-750' 12/1/10 1106 12/15/10 1106 12/15/2010 516.1 1.50 569.2 60.0 U4672D N33 Canal-750' 12/1/10 1106 12/15/10 1106 12/15/2010 517.0 1.40 569.0 62.2 U4671 N34 Canal-800' 12/1/10 1108 12/15/10 1108 12/15/2010 516.2 0.509 570.6 15.1 U4670 N35 Canal-850' 12/1/10 1110 12/15/10 1110 12/15/2010 514.6 0.646 569.4 11.0 U4669 N36 Canal-950' 12/1/10 1112 12/15/10 1112 12/15/2010 515.8 0.592 568.2 7.46 U4668 N37 Canal-1000' 12/1/10 1114 12/15/10 1114 12/15/2010 ND 568.4 4.92 U4667 N38 Canal-1050' 12/1/10 1116 12/15/10 1116 12/15/2010 ND 568.6 7.83 U4666 N39 Canal-1100' 12/1/10 1118 12/15/10 1118 12/15/2010 ND 568.8 3.52 U4638 N40 Shallow Well-250' downgradient 12/1/10 1303 12/15/10 1303 12/15/2010 ND 567.7 5,510 U4632 N41 Shallow well -500' downgradient 12/1/10 1254 12/15/10 1254 12/15/2010 515.8 U4626 N42 Shallow Well-750' downgradient 12/1/10 1241 12/15/10 1241 12/15/2010 ND 569.2 U4621 S1 Shallow Well-200' 12/1/10 1204 12/15/10 1204 12/15/2010 ND ND U4616 S2 Shallow Well-300' 12/1/10 1202 12/15/10 1202 12/15/2010 ND ND U4615 S3 Shallow Well-350' 12/1/10 1200 12/15/10 1200 12/15/2010 ND ND U4614 S4 Shallow Well-450' 12/1/10 1149 12/15/10 1149 12/15/2010 ND ND U4610 S5 Shallow Well-550' 12/1/10 1147 12/15/10 1147 12/15/2010 ND ND U4609 S6 Shallow Well-600' 12/1/10 1145 12/15/10 1145 12/15/2010 ND ND U4608 S7 Shallow Well-700' 12/1/10 1134 12/15/10 1134 12/15/2010 ND ND U4604 S8 Shallow Well-800' 12/1/10 1132 12/15/10 1132 12/15/2010 ND ND U4603 S9 Shallow well-850' 12/1/10 1130 12/15/10 1130 12/15/2010 ND ND U4618 S14 Deep well-250'-22' downgradient 12/1/10 1206 12/15/10 1206 12/15/2010 ND 569.2 33.7 U4619 S15 Deep well-250'-39' downgradient 12/1/10 1208 12/15/10 1208 12/15/2010 ND 569.8 19.8 U4612 S16 Deep Well-500'-22' downgradient 12/1/10 1151 12/15/10 1151 12/15/2010 ND ND U4613 S17 Deep well-500'-39' downgradient 12/1/10 1153 12/15/10 1153 12/15/2010 ND ND U4606 S18 Deep Well-750'-22' downgradient 12/1/10 1136 12/15/10 1136 12/15/2010 ND 568.2 Page 16 of 19 16.9 ND 682 21.0 Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered 12/15/10 1138 12/15/2010 ND 570.0 ND 12/1/10 1138 Fluorescein Results Peak nm Conc. ppb RWT Results Peak nm Conc. ppb U4607 S19 Deep well-750'-39' downgradient 3.28 U4665 S20 Canal-(-50') 12/1/10 1045 12/15/10 1045 12/15/2010 ND U4664 S21 Canal-0' 12/1/10 1047 12/15/10 1047 12/15/2010 ND ND U4663 S22 Canal-50' 12/1/10 1049 12/15/10 1049 12/15/2010 ND ND U4662 S23 Canal-100' 12/1/10 1051 12/15/10 1051 12/15/2010 ND ND U4661 S24 Canal-200' 12/1/10 1053 12/15/10 1053 12/15/2010 ND ND U4659 S25 Canal-250' 12/1/10 1055 12/15/10 1055 12/15/2010 ND 568.6 U4659D S25 Canal-250' 12/1/10 1055 12/15/10 1055 12/15/2010 ND 571.0 8.32 U4658 S26 Canal-300' 12/1/10 1057 12/15/10 1057 12/15/2010 ND 570.6 10.2 U4657 S27 Canal-350' 12/1/10 1059 12/15/10 1059 12/15/2010 ND ND U4656 S28 Canal-450' 12/1/10 1101 12/15/10 1101 12/15/2010 ND U4655 S29 Canal-500' 12/1/10 1103 12/15/10 1103 12/15/2010 515.8 54.8 U4655D S29 Canal-500' 12/1/10 1103 12/15/10 1103 12/15/2010 515.2 40.4 ND U4654 S30 Canal-550' 12/1/10 1105 12/15/10 1105 12/15/2010 515.6 3.66 ND U4653 S31 Canal-600' 12/1/10 1107 12/15/10 1107 12/15/2010 515.8 3.54 ND U4652 S32 Canal-700' 12/1/10 1109 12/15/10 1109 12/15/2010 516.2 1.10 ND U4651 S33 Canal-750' 12/1/10 1111 12/15/10 1111 12/15/2010 516.2 1.19 568.8 219 U4651D S33 Canal-750' 12/1/10 1111 12/15/10 1111 12/15/2010 517.0 0.746 568.6 149 U4650 S34 Canal-800' 12/1/10 1113 12/15/10 1113 12/15/2010 517.2 0.611 ND U4649 S35 Canal-850' 12/1/10 1115 12/15/10 1115 12/15/2010 517.8 0.624 ND U4648 S36 Canal-950' 12/1/10 1117 12/15/10 1117 12/15/2010 515.2 0.525 ND U4647 S37 Canal-1000' 12/1/10 1119 12/15/10 1119 12/15/2010 516.2 0.498 ND U4646 S38 Canal-1050' 12/1/10 1121 12/15/10 1121 12/15/2010 517.6 0.607 ND U4645 S39 Canal-1100' 12/1/10 1123 12/15/10 1123 12/15/2010 516.2 0.482 U4617 S40 Shallow Well-250' downgradient 12/1/10 1210 12/15/10 1210 12/15/2010 ND U4611 S41 Shallow well-500' downgradient 12/1/10 1155 12/15/10 1155 12/15/2010 515.2 U4605 S42 Shallow Well-750' downgradient 12/1/10 1140 12/15/10 1140 12/15/2010 ND 569.4 U5003 N1 Shallow Well-200' 12/15/10 1257 12/29/10 1257 12/29/2010 ND ND U4998 N2 Shallow Well-300' 12/15/10 1255 12/29/10 1255 12/29/2010 ND ND U4997 N3 Shallow Well-350' 12/15/10 1253 12/29/10 1253 12/29/2010 ND ND U4996 N4 Shallow Well-450' 12/15/10 1248 12/29/10 1248 12/29/2010 ND ND U4992 N5 Shallow Well-550' 12/15/10 1246 12/29/10 1246 12/29/2010 ND ND U4991 N6 Shallow Well-600' 12/15/10 1244 12/29/10 1244 12/29/2010 ND ND U4990 N7 Shallow Well-700' 12/15/10 1235 12/29/10 1231 12/29/2010 ND 568.0 U4986 N8 Shallow Well-800' 12/15/10 1233 12/29/10 1233 12/29/2010 ND ND 8.68 ND ND ND ND 29.5 ND 792 8,770 U4985 N9 Shallow well-850' 12/15/10 1231 12/29/10 1235 12/29/2010 ND ND U5004 N10 Shallow Well-(-5') 12/15/10 1307 12/29/10 1307 12/29/2010 ND ND U5005 N11 Shallow Well-(-15') 12/15/10 1309 12/29/10 1309 12/29/2010 ND ND U4984 N12 Shallow Well-1005' 12/15/10 1227 12/29/10 1227 12/29/2010 ND ND U4983 N13 Shallow Well-1015' 12/15/10 1225 12/29/10 1225 12/29/2010 ND ND U5001 N14 Deep well-250'-22' downgradient 12/15/10 1259 12/29/10 1259 12/29/2010 ND 569.8 1,230 U5002 N15 Deep well-250'-39' downgradient 12/15/10 1301 12/29/10 1301 12/29/2010 ND 570.0 1,470 U4994 N16 Deep Well-500'-22' downgradient 12/15/10 1250 12/29/10 1250 12/29/2010 515.0 51.4 U4995 N17 Deep Well-500'-39' downgradient 12/15/10 1252 12/29/10 1252 12/29/2010 515.0 5.67 U4988 N18 Deep well-750'-22' downgradient 12/15/10 1237 12/29/10 1237 12/29/2010 ND 569.6 205 U4989 N19 Deep well-750'-39' downgradient 12/15/10 1239 12/29/10 1239 12/29/2010 ND 569.5 143 U5047 N20 Canal-(-50') 12/15/10 1040 12/29/10 1040 12/29/2010 ND ND U5046 N21 Canal-0' 12/15/10 1042 12/29/10 1042 12/29/2010 ND ND U5045 N22 Canal-50' 12/15/10 1044 12/29/10 1044 12/29/2010 ND ND U5044 N23 Canal-100' 12/15/10 1046 12/29/10 1046 12/29/2010 ND ND U5043 N24 Canal-200' 12/15/10 1048 12/29/10 1048 12/29/2010 ND ND U5042 N25 Canal-250' 12/15/10 1050 12/29/10 1050 12/29/2010 ND 570.0 15.6 U5042D N25 Canal-250' 12/15/10 1050 12/29/10 1050 12/29/2010 ND 569.6 16.3 U5041 N26 Canal-300' 12/15/10 1052 12/29/10 1052 12/29/2010 ND 569.2 12.6 Page 17 of 19 ND ND Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered Fluorescein Results Peak nm U5039 N27 Canal-350' 12/15/10 1054 12/29/10 1054 12/29/2010 ND U5038 N28 Canal-450' 12/15/10 1056 12/29/10 1056 12/29/2010 516.2 U5037 N29 Canal-500' 12/15/10 1058 12/29/10 1058 12/29/2010 515.2 Conc. ppb RWT Results Peak nm Conc. ppb 569.6 7.52 2.08 569.4 7.32 25.5 ND ND U5037D N29 Canal-500' 12/15/10 1058 12/29/10 1058 12/29/2010 515.5 35.5 U5036 N30 Canal-550' 12/15/10 1100 12/29/10 1100 12/29/2010 515.8 1.85 U5035 N31 Canal-600' 12/15/10 1102 12/29/10 1102 12/29/2010 ND U5034 N32 Canal-700' 12/15/10 1104 12/29/10 1104 12/29/2010 516.8 569.2 11.0 U5033 N33 Canal-750' 12/15/10 1106 12/29/10 1106 12/29/2010 ND 569.2 38.7 ND ND 0.544 U5033D N33 Canal-750' 12/15/10 1106 12/29/10 1106 12/29/2010 ND 569.6 40.7 U5032 N34 Canal-800' 12/15/10 1108 12/29/10 1108 12/29/2010 ND 569.6 21.4 U5031 N35 Canal-850' 12/15/10 1110 12/29/10 1110 12/29/2010 ND 569.6 15.1 U5030 N36 Canal-950' 12/15/10 1112 12/29/10 1112 12/29/2010 ND 568.6 11.1 U5029 N37 Canal-1000' 12/15/10 1114 12/29/10 1114 12/29/2010 ND 569.4 7.09 U5028 N38 Canal-1050' 12/15/10 1116 12/29/10 1116 12/29/2010 ND 569.2 10.2 U5027 N39 Canal-1100' 12/15/10 1118 12/29/10 1118 12/29/2010 ND ND U4999 N40 Shallow Well-250' downgradient 12/15/10 1303 12/29/10 1303 12/29/2010 ND U4993 N41 Shallow well -500' downgradient 12/15/10 1254 12/29/10 1254 12/29/2010 515.3 U4987 N42 Shallow Well-750' downgradient 12/15/10 1241 12/29/10 1241 12/29/2010 ND 569.6 U4982 S1 Shallow Well-200' 12/15/10 1204 12/29/10 1204 12/29/2010 ND ND U4977 S2 Shallow Well-300' 12/15/10 1202 12/29/10 1202 12/29/2010 ND ND U4976 S3 Shallow Well-350' 12/15/10 1200 12/29/10 1200 12/29/2010 ND ND U4975 S4 Shallow Well-450' 12/15/10 1149 12/29/10 1149 12/29/2010 ND ND U4971 S5 Shallow Well-550' 12/15/10 1147 12/29/10 1147 12/29/2010 ND ND U4970 S6 Shallow Well-600' 12/15/10 1145 12/29/10 1145 12/29/2010 ND ND U4969 S7 Shallow Well-700' 12/15/10 1134 12/29/10 1134 12/29/2010 ND ND U4965 S8 Shallow Well-800' 12/15/10 1132 12/29/10 1132 12/29/2010 ND ND U4964 S9 Shallow well-850' 12/15/10 1130 12/29/10 1130 12/29/2010 ND ND U4979 S14 Deep well-250'-22' downgradient 12/15/10 1206 12/29/10 1206 12/29/2010 ND 570.2 7.89 U4981 S15 Deep well-250'-39' downgradient 12/15/10 1208 12/29/10 1208 12/29/2010 ND 567.6 3.93 U4973 S16 Deep Well-500'-22' downgradient 12/15/10 1151 12/29/10 1151 12/29/2010 515.4 14.4 U4974 S17 Deep well-500'-39' downgradient 12/15/10 1153 12/29/10 1153 12/29/2010 515.8 1.24 U4967 S18 Deep Well-750'-22' downgradient 12/15/10 1136 12/29/10 1136 12/29/2010 ND 570.6 279 U4968 S19 Deep well-750'-39' downgradient 12/15/10 1138 12/29/10 1138 12/29/2010 ND 569.8 60.3 U5026 S20 Canal-(-50') 12/15/10 1045 12/29/10 1045 12/29/2010 ND ND U5025 S21 Canal-0' 12/15/10 1047 12/29/10 1047 12/29/2010 ND ND U5024 S22 Canal-50' 12/15/10 1049 12/29/10 1049 12/29/2010 ND ND U5023 S23 Canal-100' 12/15/10 1051 12/29/10 1051 12/29/2010 ND ND U5022 S24 Canal-200' 12/15/10 1053 12/29/10 1053 12/29/2010 ND ND U5021 S25 Canal-250' 12/15/10 1055 12/29/10 1055 12/29/2010 ND 570.0 10.7 U5021D S25 Canal-250' 12/15/10 1055 12/29/10 1055 12/29/2010 ND 568.2 13.5 U5019 S26 Canal-300' 12/15/10 1057 12/29/10 1057 12/29/2010 ND 570.0 8.02 U5018 S27 Canal-350' 12/15/10 1059 12/29/10 1059 12/29/2010 ND ND U5017 S28 Canal-450' 12/15/10 1101 12/29/10 1101 12/29/2010 ND U5016 S29 Canal-500' 12/15/10 1103 12/29/10 1103 12/29/2010 515.4 7.31 ND U5016D S29 Canal-500' 12/15/10 1103 12/29/10 1103 12/29/2010 514.8 8.01 ND U5015 S30 Canal-550' 12/15/10 1105 12/29/10 1105 12/29/2010 515.6 3.34 ND U5014 S31 Canal-600' 12/15/10 1107 12/29/10 1107 12/29/2010 514.8 2.50 ND U5013 S32 Canal-700' 12/15/10 1109 12/29/10 1109 12/29/2010 515.6 1.16 ND U5012 S33 Canal-750' 12/15/10 1111 12/29/10 1111 12/29/2010 517.6 0.822 569.8 22.3 U5012D S33 Canal-750' 12/15/10 1111 12/29/10 1111 12/29/2010 516.2 0.796 569.0 23.2 U5011 S34 Canal-800' 12/15/10 1113 12/29/10 1113 12/29/2010 516.8 0.855 569.6 5.29 U5010 S35 Canal-850' 12/15/10 1115 12/29/10 1115 12/29/2010 ND U5009 S36 Canal-950' 12/15/10 1117 12/29/10 1117 12/29/2010 ND ND U5008 S37 Canal-1000' 12/15/10 1119 12/29/10 1119 12/29/2010 ND ND Page 18 of 19 567.7 41.3 7,090 ND 1,600 ND ND ND ND Ozark Underground Laboratory L-31N Seepage Project MacVicar, Federico and Lamb Table 1. Results for charcoal samplers analyzed for the presence of fluorescein and rhodamine WT (RWT) dyes. Peak wavelengths are reported in nanometers (nm); dye concentrations are reported in parts per billion (ppb). OUL Station # # Station Name Date/Time Date/Time Date Placed Recovered Recovered 12/29/10 1121 12/29/2010 Fluorescein Results Peak nm Conc. ppb ND RWT Results Peak nm U5007 S38 Canal-1050' 12/15/10 1121 U5006 S39 Canal-1100' 12/15/10 1123 12/29/10 1123 12/29/2010 ND ND U4978 S40 Shallow Well-250' downgradient 12/15/10 1210 12/29/10 1210 12/29/2010 ND ND U4972 S41 Shallow well-500' downgradient 12/15/10 1155 12/29/10 1155 12/29/2010 515.4 U4966 S42 Shallow Well-750' downgradient 12/15/10 1140 12/29/10 1140 12/29/2010 ND 569.8 U6128 N1 Shallow Well-200' 12/29/10 1257 2/9/11 1257 2/9/2011 ND ND U6124 N2 Shallow Well-300' 12/29/10 1255 2/9/11 1255 2/9/2011 ND ND U6123 N3 Shallow Well-350' 12/29/10 1253 2/9/11 1253 2/9/2011 ND ND U6122 N4 Shallow Well-450' 12/29/10 1248 2/9/11 1248 2/9/2011 ND ND U6117 N5 Shallow Well-550' 12/29/10 1246 2/9/11 1246 2/9/2011 ND ND U6116 N6 Shallow Well-600' 12/29/10 1244 2/9/11 1244 2/9/2011 ND ND U6115 N7 Shallow Well-700' 12/29/10 1235 2/9/11 1235 2/9/2011 ND 568.0 U6111 N8 Shallow Well-800' 12/29/10 1233 2/9/11 1233 2/9/2011 ND ND Conc. ppb ND 73.3 ND 1,080 6,670 U6110 N9 Shallow well-850' 12/29/10 1231 2/9/11 1231 2/9/2011 ND ND U6129 N10 Shallow Well-(-5') 12/29/10 1307 2/9/11 1307 2/9/2011 ND ND U6130 N11 Shallow Well-(-15') 12/29/10 1309 2/9/11 1309 2/9/2011 ND ND U6109 N12 Shallow Well-1005' 12/29/10 1227 2/9/11 1227 2/9/2011 ND ND U6108 N13 Shallow Well-1015' 12/29/10 1225 2/9/11 1225 2/9/2011 ND ND U6126 N14 Deep well-250'-22' downgradient 12/29/10 1259 2/9/11 1259 2/9/2011 ND 568.4 10,700 U6127 N15 Deep well-250'-39' downgradient 12/29/10 1301 2/9/11 1301 2/9/2011 ND 568.1 4,200 U6119 N16 Deep Well-500'-22' downgradient 12/29/10 1250 2/9/11 1250 2/9/2011 515.5 194 U6121 N17 Deep Well-500'-39' downgradient 12/29/10 1252 2/9/11 1252 2/9/2011 515.3 23.7 U6113 N18 Deep well-750'-22' downgradient 12/29/10 1237 2/9/11 1237 2/9/2011 ND 568.3 U6114 N19 Deep well-750'-39' downgradient 12/29/10 1239 2/9/11 1239 2/9/2011 ND 569.6 993 U6125 N40 Shallow Well-250' downgradient 12/29/10 1303 2/9/11 1303 2/9/2011 ND 567.4 6,170 U6118 N41 Shallow well -500' downgradient 12/29/10 1254 2/9/11 1254 2/9/2011 515.6 U6112 N42 Shallow Well-750' downgradient 12/29/10 1241 2/9/11 1241 2/9/2011 ND 567.9 U6107 S1 Shallow Well-200' 12/29/10 1204 2/9/11 1204 2/9/2011 ND ND U6103 S2 Shallow Well-300' 12/29/10 1202 2/9/11 1202 2/9/2011 ND ND U6102 S3 Shallow Well-350' 12/29/10 1200 2/9/11 1200 2/9/2011 ND ND U6101 S4 Shallow Well-450' 12/29/10 1149 2/9/11 1149 2/9/2011 ND ND U6096 S5 Shallow Well-550' 12/29/10 1147 2/9/11 1147 2/9/2011 ND ND U6095 S6 Shallow Well-600' 12/29/10 1145 2/9/11 1145 2/9/2011 ND ND U6094 S7 Shallow Well-700' 12/29/10 1134 2/9/11 1134 2/9/2011 ND ND U6090 S8 Shallow Well-800' 12/29/10 1132 2/9/11 1132 2/9/2011 ND ND U6089 S9 Shallow well-850' 12/29/10 1130 2/9/11 1130 2/9/2011 ND ND U6105 S14 Deep well-250'-22' downgradient 12/29/10 1206 2/9/11 1206 2/9/2011 ND ND U6106 S15 Deep well-250'-39' downgradient 12/29/10 1208 2/9/11 1208 2/9/2011 ND U6098 S16 Deep Well-500'-22' downgradient 12/29/10 1151 2/9/11 1151 2/9/2011 515.3 43.3 U6099 S17 Deep well-500'-39' downgradient 12/29/10 1153 2/9/11 1153 2/9/2011 515.8 6.25 U6092 S18 Deep Well-750'-22' downgradient 12/29/10 1136 2/9/11 1136 2/9/2011 ND 570.0 1,450 U6093 S19 Deep well-750'-39' downgradient 12/29/10 1138 2/9/11 1138 2/9/2011 ND 569.6 236 U6104 S40 Shallow Well-250' downgradient 12/29/10 1210 2/9/11 1210 2/9/2011 ND ND U6097 S41 Shallow well-500' downgradient 12/29/10 1155 2/9/11 1155 2/9/2011 515.6 U6091 S42 Shallow Well-750' downgradient 12/29/10 1140 2/9/11 1140 2/9/2011 ND Page 19 of 19 189 ND ND 6,000 ND 12,600 ND 76.7 ND ND ND 569.8 1,510 Appendix 3 Ardaman & Associates (2011) L-31N Seepage Barrier Investigation, Miami-Dade County, Florida Cone penetrometer testing results Barrier wall borings notes L-31N Barrier Testing CPT 1 2 3 4 5 6 7 8 9 10 11 12 13 Location 150 250 350 450 490 495 500 505 510 550 650 750 850 Average Refusal Depth 16.9 18.2 18.0 13.7 17.2 17.4 18.0 17.1 16.8 16.9 16.9 17.6 12.5 16.7 Distances from south end of barrier Disturbed: q>30 3/9/2011 Disturbed Depth 14.8 13.5 12.2 13.0 13.0 13.0 15.0 13.0 14.0 12.5 12.8 17.0 10.5 13.4 Disturbed Thickness 2.1 4.7 5.8 0.7 4.2 4.4 3.0 4.1 2.8 4.4 4.1 0.6 2.0 3.3 4/7/2011 Open Hole Depth to Depth Water 7.5 4.3 13.5 4.3 10 3.6 2 no 2 no 13.5 3.5 13.5 3.5 12.5 3.5 14.5 3.5 collapsed no 13.5 3.2 2.5 no not found no 4/4/2011 L-31 Seepage Wall Borings Ardaman & Associates – Miami Office Manager - Evelio Horta / Driller - George Jeff Rosenfeld – MFL and Les Bromwell – BCI Two borings – sampled using split spoons and manual-operated hammer until 15’ deep (when limestone pebbles/ sand size material encountered) and then switched to automated hammer and recorded blow counts Borings drilled adjacent to Ardaman CPT holes: CPT3 - 350’ from south end of wall (still open to depth of 11’) CPT showed elevated resistance starting at 12.5’ and refusal at 18’) CPT13 - 850’ from south end of wall (still open to depth of 12’) CPT showed elevated resistance starting at 10.5’ and refusal at 12.5’) Bottom of trench at approximately 18-20’ and Q4 hard layer at approximately 14-16’ Trench approximately 28” wide and both CPT and borings within wall material CPT-3 0-8’ full recovery – full bentonite material cores – broken material on photo due to removal from split spoon – depth to water at approximately 3’ – light grey to 3’ darker brown from 3’ to 8’ 8-10’ approximate 50% recovery - upper section full formed core as above / lower section material was more wet not as formed. 10-12’ 0% recovery – not sure why – split spoon had catcher so it would seem that material was fluid and drained from spoon. Lower probability that material was fine sand that was not retained in spoon. 12-15’ Driller recommended 3’ penetration in 2’ spoon to try to compact material so it would be retained in spoon. Full spoon recovery. 12-14.5 (?) – formed bentonite material core but wetter than above – also noticed fine grained material within core. From 14.5-15’ (?) – limestone pebbles 15-17’ “fill material” from milling trench? – some formed core in spoon (due to wet condition vs. presence of slurry?). Seemed to be more related to being wet – some but not a lot of slurry material present (Blow counts – 3,3,3,3) 17-18.5 “fill material” as above (Blow counts – 5,5,6) 18.5 – 19’ “fill material” as above (Blow counts – 46) - refusal at 19’ Material consolidated within portion of core box Row 3 0-8’ Row 4 8-15’ Row 5 15-19’ Samples also collected in glass jars Les took jars contained sandy material from 15-17 and 17-18.5 for possible permeability testing by forming material within test vessel. CPT-13 0-10’ full recovery – full bentonite material cores – broken material on photo due to removal from split spoon – depth to water at approximately 3’ – light grey to 3’ darker brown from 3’ to 10’. Could see fill material within bentonite from 7-10’ and feel sand within the bentonite. 10-13 missing zone in CPT-3. Did 3’ penetration in 2’ spoon to try to compact material so it would be retained in spoon. Full spoon recovery – wetter material from 1011’(?) – more cohesive 11-13’(?). 13-15 13-14’ wet material (not as formed) 14-14.5’ formed core but limestone pebbles within bentonite “shell” 14.5-15’ limestone pebbles (0.5 – 1”) 15-17 25% recovery – limestone pebbles as above –some wet slurry material (Blow counts – 3,3,3,4) so there was material - just not recovered 17-19 full recovery – 17-18 limestone pebbles as above with some slurry material 18-19 clean limestone pebbles and fine material – no slurry (Blow counts – 5,7,8,8) 19-20 limestone pebbles – no slurry (Blow counts – 8,16) Material kept in core box – no fine grained material (as in CPT-3) to test