Journal of Geochemical Exploration 78 – 79 (2003) 293 – 296 www.elsevier.com/locate/jgeoexp Abstract Fluid escape from reservoirs: implications from cold seeps, fractures and injected sands Part I. The fluid flow system A. Mazzini *, R. Jonk, D. Duranti, J. Parnell, B. Cronin, A. Hurst Department of Geology and Petroleum Geology, University of Aberdeen, Meston Building, Aberdeen AB24 3UE, UK Abstract Fluid escape from reservoirs can take place through (hydraulic) fracturing, sand injection and seepage. Above several Tertiary hydrocarbon reservoirs in the North Sea, substantial amounts of fractures, sand injectites and seeps occur. Petrographic observations of these features show that all have carbonate cement associated with them that contains fluorescing hydrocarbon inclusions. The petroleum fluids escaping were partially trapped during the cementation and analysis of the cements allows understanding of the fluid flow system and the fluids involved. Cathodoluminescence indicates that sand injectites and fractures have one phase of cement associated with them. Seeps, however, show zoned carbonate cement, suggesting precipitation in a varying geochemical environment. This suggests that fractures and sand injectites were short-lived fluid-conduits, whereas seeps can act as fluid escape pathways over prolonged periods of time. D 2003 Elsevier Science B.V. All rights reserved. Keywords: Cold seeps; Injected sands; Hydrocarbons; Cathodoluminescence 1. Introduction Fluid escape from hydrocarbon reservoirs in the shallow crust is a common phenomenon, but the fluid flow pathways can be diverse and are presently not fully understood. Fluids follow different pathways and generate diverse geological structures and phenomena (Fig. 1). The occurrence of fluid seepage on the sea floor is manifested by the presence of hydrothermal vents (metal-rich deposits) and cold seeps (typically carbonate deposits). Cold seeps are associated with * Corresponding author. Tel.: +44-1224-273435; fax: +441224-272785. E-mail address: a.mazzini@abdn.ac.uk (A. Mazzini). carbonate mounds, coral reefs, pockmarks, mud volcanoes and seamounts. It is at these sites that seeping gases sustain chemosymbiotic communities inducing the precipitation of authigenic carbonates (Hovland et al., 1987; Ritger et al., 1987; Paull et al., 1992). Seep deposits can assume different scales and shapes, such as exposed and buried mineralised chimneys (Jorgensen, 1989), cemented fluid conduits and veins, micro and macro slabs, and cemented sedimentary layers (Hovland and Judd, 1988). In the subsurface, rapid fluid escape can take place through networks of fractures and injected sands. Often, fluid overpressures generate the pathways for fluid escape through (hydraulic) fracturing and sand injection (Cosgrove, 2001), but more importantly, once created they remain fluid escape pathways. Fluids may be trapped where 0375-6742/03/$ - see front matter D 2003 Elsevier Science B.V. All rights reserved. doi:10.1016/S0375-6742(03)00046-3 294 Abstract Fig. 1. Schematic submarine cross section showing a range of features through which fluids can escape from a reservoir: (1) diapiric structures eventually reaching the sea floor as mud volcanoes where chemosynthetic communities can occur; (2) dense networks of faults and fractures act as conduits for seepage (conventional cold seeps) or (3) can be used by sand injection and pockmarks. Injected sandstones can reach the sea floor or can terminate at various depths eventually allowing fluids to reach the sea floor through fractures and seepage. Grey boxes correspond to carbonate cemented features analysed. fractures or injected sandstones terminate or may continue to seep to the surface. It is important to know whether structures are truly trapping and sealing or whether fluid escape continues to take place, eventually manifesting itself as seeps on the sea floor. Carbonate is the most common cement associated with these features at shallow burial and the cements yield valuable information on the origin of the fluids and its various components. Our goal is to understand the linkage between reservoirs, fractures, injected sandstones and seeps via a study of carbonate cementation. 2. Methods of study Polished slabs and thin sections were studied using standard petrographic and cathodoluminescence techniques in order to analyse and distinguish the cementation phases. Cathodoluminescence was conducted with a Citl Cold Cathode Luminescence 8200 mk3 linked with a Nikon M32 microscope to evaluate the compositional variations during the crystal growth. 3. Study area The North Sea is a major producing hydrocarbon province. Some of the earliest descriptions of fluid escape features on the sea floor (Hovland and Judd, 1988) and descriptions of injected sandstones (Jenssen et al., 1993; Dixon et al., 1995; Lonergan and Cartwright, 1999) associated with hydrocarbon reservoirs are from this province. In the present study, samples were retrieved from the sea floor and from cores associated with several Tertiary hydrocarbon reservoirs showing substantial degrees of carbonate cement associated with seeps, fractures and sand injectites (Duranti et al., 2002). Abstract 4. Results Carbonate cements in seeps, fractures and sand injectites were analysed. Fluid inclusion and isotope 295 data indicate an intimate association with hydrocarbons. (Jonk et al., 2003, this issue), Seep deposits (Fig. 2A) are cemented with blocky and fibrous calcite, which is often recrystallised aragonite. Cath- Fig. 2. Plane light (left) and corresponding cathodoluminescence (right) pictures of the three carbonate cemented features analysed. Cold seeps at the sea floor consist of blocky calcite (A) that shows oscillatory zoning and no evidence of dissolution (B). Injected sandstones (C) show extreme minus cement porosities and one phase of carbonate cement (D). Fractures (E) contain unzoned carbonate cement (F). 296 Abstract odoluminescence shows zones of dull and bright luminescent calcite. It also shows a continuous precipitation history of carbonate with no evidence of dissolution events (Fig. 2B). Cement in injected sandstones is poikilotopic calcite. Minus cement porosities around 50% suggest that cementation took place early in the burial history (Fig. 2C). Cathodoluminescence shows one phase of cement (Fig. 2D). Fractures are around 1 mm thick and are cemented with calcite. The calcite exhibits either a beefy or a blocky texture (Fig. 2E). Again, the cathodoluminescence shows one phase of cement (Fig. 2F). 5. Discussion and conclusion Although all fluid escape features found above hydrocarbon reservoirs are characterised by carbonate cement, the cathodoluminescence shows a striking difference between seeps versus fractures and sand injectites. Seeps show zoned cement, suggesting varying geochemistry of the cementing fluid. The likely prolonged history of fluid seepage could be responsible for this. However, both sand injectites and cemented fractures show one phase of cement and thus one fluid phase responsible for cementation. This, together with the observed high minus cement porosities in sand injectites suggests rapid cementation following fracturing and sand injection. Crosscutting relations between cemented fractures and sand injectites are often contradictory, suggesting coeval fracturing and sand injection. Fluid overpressure in the reservoir causes rapid fluid escape through hydraulic fracturing and sand injection. The newly created fluid flow pathways are quickly cemented. Once cemented, fluid escape can continue to take place through seepage at the top of the structures (Fig. 1). Seepage takes place more slowly over a prolonged time, recording the longer-term geochemical changes in the cementation environment. This study suggests that fluid escape from reservoirs can occur catastrophically over short timespans through (hydraulic) fracturing and sand injection, but continued fluid escape can take place less catastrophically over a prolonged time through seepage. This conclusion is supported by fluid inclusion analysis. UV light observations on the described samples (Jonk et al., 2003, this issue) show that similar types of fluorescing hydrocarbon inclusions occur in injectites, fractures and cold seep features sampled from the same location. 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