Electronic Geosciences ISSN 1436-2511 Electronic Geosciences (1999) 4:1 Visualization and Analysis of Mixing Dynamical Properties in Convecting Systems with Different Rheologies A. A. Ten1, 2, D. A. Yuen1, and Yu. Yu. Podladchikov 3 1 Department of Geology and Geophysics, University of Minnesota Supercomputer Institute,1200 Washington Avenue S, Minneapolis, MN 55415-1227, USA. 2 Institute of Mineralogy and Petrography, Novosibirsk, 630090, Russia 3 Geologisches Institut, E.T.H., CH-8092, Zurich, Switzerland Correspondence to: A. A. Ten (email: arkady@msi.umn.edu) Received: 12 April 1999 / Revised: 24 August 1999/ Accepted: 30 August 1999 Abstract. We analyzed and compared the mixing properties of 2-D mantle convection models. Two rheologically different models, Newtonian and non-Newtonian (power-law), were considered with both the line and field methods. The line method is based on monitoring of passive particles joined into lines, while the field method relies on the advection of a passive scalar field. Both visual and quantitative estimates revealed that the efficiency of the Newtonian mixing is greater than the non-Newtonian. A heterogeneity placed in the non-Newtonian convection forms horizontal structures, which may persist for at least 1 Ga on the upper-mantle scale. In addition, the non-Newtonian medium reveals a lesser amount of stretching of the lines than the Newtonian material. The rate of the Newtonian stretching fits well with an exponential dependence with time, while the non-Newtonian rheology shows the stretching rate close to a power-law dependence with time. In the Newtonian medium the heterogeneity is reorganized into two unstable vertical columns, while the non-Newtonian mixing favors horizontal structures. In the latter case, these structures are sufficiently stable in both the temporal and spatial planes to explain the mantle geochemical and geophysical heterogeneities. Due to the non-linear character of power-law rheology, the non-Newtonian medium offers a "natural" scale-dependent resistance to deformation, which prevents efficient mixing at the intermediate length scales. Key words: Fractal – Heterogeneity – Mantle convection – Mixing – Non-Newtonian rheology · · · · · · Introduction Thermal Convection Model Monitoring Techniques Results and Discussion Conclusions References Introduction Mixing is an important component of many evolutionary processes in the universe. It can be scaled from unimaginably large galactic distances (Wu et al. 1999) to those of a coffee cup. The universality of this process extends its importance to both technology and the basic sciences. One area of application is mixing in the earth's mantle. The isotopic heterogeneities of the mantle xenoliths and their host basalts indicate that the mantle preserves huge reservoirs of unmixed material (Hart and Zindler 1989). Whether these heterogeneities have sources in the mantle (e.g. Wasserburg and De Paolo 1979) or they are relicts of unmixed protomaterial remains a debatable issue. Even though the modeling of mantle convection has exhibited great progress over the last decade, mixing remains poorly understood. Understanding of the mixing rate in the mantle and its ability to destroy heterogeneities on different scales plays a key role in the interpretation of the geochemical anomalies (e.g. Ten et al. 1997, Ferrachat and Ricard 1998). In this paper, we assess how different types of mantle rheologies influence mixing and investigate the efficiency of upper-mantle mixing as a mechanism of heterogeneity destruction. Generally, mixing may be considered as a superposition of three processes (Hoffman and McKenzie 1985, Ottino 1989): · · · Diffusional homogenization takes place by molecular diffusion. One may see that a drop of milk added to coffee quickly loses its sharp boundary . It is almost impossible to locate exact position of the boundary between milk and coffee even after a few seconds after the initial contact. Stretching and folding. Stirring of two immiscible materials will result in stretching and folding. The interface surface between them grows quickly, while retaining its original sharpness. Initially the isometric shapes become similar to convoluted threads. However, due to the negligibly small rate of diffusion the boundary remains distinct. Folding is important because it generates new scales in the system and increases its structural complexity. Breakups. The logical consequence of the stretching is breakup. There are two main reasons for breakup. First, strong stretching may bring surface tension into play. Surface tension induces topological instability of the threads and reconnection of interfaces. Second, the high stresses during the course of severe deformation can cause rupturing. In any case, breakup involves a topological transformation. For example, a sphere has one outer surface; if divided into two parts, it then forms two surfaces (e.g. Constantin et al. 1993). The diffusion and breakup are purely irreversible processes, while the stretching is kinematic and purely reversible. Another very important aspect in our understanding of mixing is the scale. One-centimeter heterogeneity may symbolize an unmixed system on the scale of a cup of coffee. The same-size feature in the Pacific Ocean would not be considered as a significant inhomogeneity looking down from a satellite. By geochemical means we would not be able to resolve a deep-sited heterogeneity less than 10 km in diameter, which is also below the resolution of seismic tomography of the upper mantle. All the above aspects of mixing are valid for the mantle. However, we may reasonably disregard the diffusional homogenization because of its extremely low rate, even at high temperatures. Diffusion in the mantle is not able to destroy even a 1-km heterogeneity over the span of the earth's age. In spite of deep-focused earthquakes indicating that the brittle behavior is present in the upper mantle, and that subducted oceanic crust can be broken into relatively small segments by the subduction process (Yasuda and Fujii 1998), the importance of breakup for mixing is small. The surface tension of mantle materials is extremely small, considering the high viscosity of the mantle rocks and scaling. It starts acting on a scale much smaller than that under consideration. Thus, stretching is the most important factor in mixing processes in the upper mantle. This kind of understanding of the mantle "mixing" is similar to the idea put forth in Hoffman and McKenzie (1985). In this context, the mixing properties of the system are entirely defined by the patterns of the velocity field and its dynamics. In other words, we are dealing with kinematic mixing. Hoffman and McKenzie (1985) analyzed a 2-D Newtonian mantle convection and established that lateral spreading of heterogeneity is proportional to the square root of the product of the eddy diffusivity and time. They estimated the time of doubling of material interfaces as Ra-0.51. Based on these findings the authors concluded that whole-mantle convection would probably homogenize the earth's mantle on a time-scale of 1 Ga, whereas upper-mantle convection requires only 200 to 300 Ma for homogenization. Not only the characteristic velocity but also the style of the convection was recognized as affecting efficiency of the mixing (Christensen 1989, Hansen et al. 1992). Three-dimensional stationary convection in a Newtonian fluid with the infinite Prandtl number was found to preserve particle heterogeneity on a time-scale of 200 Ma for the upper mantle (Schmalzl et al. 1996), consistent with the 2-D estimations. All these results rely on Newtonian rheology, whereas the rheology of the upper mantle is essentially non-linear (e.g. Karato 1997). It is unclear, however, whether rheology plays a significant role in the mixing. The visualization of mixing patterns in Newtonian and non-Newtonian convection (Ten et al. 1996) showed significant differences in the convection styles of the two rheologies. Such a difference results in different fractal behavior (Ten et al. 1997) and structural evolutionary behavior (Ten et al. 1997). In spite of a more chaotic character, non-Newtonian convection inhibits mixing to a greater degree than with Newtonian rheology. Although many properties affect the formation of the convective velocity field, we have concentrated our investigation on a rheological comparison. In other words, we have analyzed the difference in mixing due to differences in the two rheologies for a similar degree of convective vigor. We have used both line and field methods for the quantification and comparison of mixing properties. Thermal Convection Model To model upper-mantle convection we used a 2-D, basally heated, time-dependent model. The Prandtl number is taken to be infinity. The model combines the stream function formulation with a highly accurate fourth-order spline-based method (Naimark and Malevsky 1987, Malevsky and Yuen 1991 ) . Both non-Newtonian temperature-dependent and depth-dependent and Newtonian temperature-dependent and depth-dependent rheologies were considered. Rheology for the non-Newtonian model was close to olivine. This rheology establishes the power-law dependence between stress and strain rate: is a strain rate tensor, is a stress tensor, denotes the second invariant of the stress tensor, T is temperature, z is depth, A is a material constant, and B and C define temperature and depth dependencies. The power-law exponent n is equal to 3. The Newtonian rheology takes the same form of the rheological equation except that the power-law exponent n equals 1. Extensive references on mantle rheology can be found in Poirier (1985) and Karato (1997). To ensure the correctness of the comparison of the two mixing scenarios, approximately the same Nusselt number (Nu ~ 20) and all other parameters have been maintained except for the rheology. The constants B and C have been chosen in order to obtain a temperature-dependent viscosity contrast of about 300 and a depth-dependent viscosity increase of about 10 across the layer. The effective Rayleigh numbers are about 3x106 for both cases, thermal expansivity linearly decreasing by a factor of 1/3 across the layer. The aspect ratio of the box (width/depth) is 2. Free-slip boundary conditions have been imposed for the stream function. Dimensionless temperature has been kept at 0 and 1 on upper and lower boundaries respectively, while left and right sides of the box maintained symmetrical boundary conditions. These two models have been used to generate time-dependent velocity fields for mixing analysis. Since all the effective parameters for the models have been the same, we would expect that the observed differences in mixing are mainly due to the rheological influences. Monitoring Techniques We used two methods to monitor mass advection in the flow. The first is known as the field method. A passive, horizontally stratified color field (x) is initially placed in a 2D domain (Fig. 1). The horizontally-stratified field for the initial state of the models has some geophysical validity. However, a number of other initial states could have been chosen, probably with equal validity – blob markers from bottom to top (e.g. Hoffman and McKenzie, 1985), a small cube near the bottom (e.g. Schmalzl et al. 1996) or many other variations. Fig. 1 Initial horizontally stratified color field The field being advected by convection portrays the flow in the domain. An injection of dyes of different colors is a common technique used in flow visualization in laboratory experiments. The field method is a mathematical analogue of this technique. The evolution of the color field (x, t) is driven by the velocity and governed by a partial differential equation: (1) where x is a coordinate vector and t is time. This equation states that there are no mass sources/sinks and reactions in the system. In other words, the scalar field (x, t) can only be changed by advection, and the evolution of (x, t) is dictated by the velocity field V(x, t). However, the straightforward solving of Equation 1 has a distinct drawback. The finite difference approximation of the equation consists of spatial derivatives of V(x, t) and (x, t). While velocity derivatives could be estimated and are bounded, the evolution of (x, t) is not so easily predicted because of its hyperbolic character (Sethian 1996). In general, gradients in (x, t) should become greater with time. Material points, that were initially far apart, can approach close to each other, thus resulting in the very high gradients in (x, t) and consequently increasing the approximation error. The higher the gradient, the greater the error. An unfortunate outcome is that derivatives of (x, t), which are responsible for an approximation error, cannot be estimated in advance and do not have bounding values. Visually, this kind of error is manifested by mass flux between different colors. For instance, a close contact of blue and red parts results in the artificial changing of some points to green. Another type of error developing along the sharp gradients is the Gibbs instability, which involves sharp spatial oscillations of the field. This problem may be partially resolved with the Lagrangian formulation of the evolutionary equation (Eq. 1). In this case, the equation may be rewritten as: (2) where D/Dt is a substantive derivative. Mathematically, both equations are equivalent, but in practice there are some differences. Lagrangian formulation (Eq. 2) may drastically improve the accuracy of a numerical solution. However, solving Equation 2 requires much computer memory and high computational speed. Since many time-steps need to be integrated, the price for the accuracy becomes very high. The middle-ground could be the semi-Lagrangian method. The idea of the semi-Lagrangian method is to solve the equation using a Lagrangian formulation for only two (or any limited number) of sequential time-steps (e.g. Malevsky and Yuen 1991, Malevsky and Thomas 1997). Using the velocity field, we may backtrack the location of a material point at every node of an Eulerian grid. In other words, we may find the position of the material point from the previous time-step along with the value of the field in this point and assign that value to the current node. To perform this operation, we need a velocity field and scalar field at the previous time step (x, t– t) (see the animation in Fig. 2). Fig. 2 Characteristic-based method. A value of the field from previous time-step is advected to the current time-step. A ray is emitted backward from a grid node on the current time-step to locate coordinates and the value of the field for the previous time-step On each node of the Eulerian grid, the following algorithm is applied: · · 1. Take the coordinate (t) of the node (i, j) of the current time-step t. Find the coordinate (t–dt) of the material point currently located in the node (i, j) on · · the previous time-step (t– t). Find the value of the field in that coordinate [ ( (t– t), t– t)]. Assign the value found to the node (i, j) [ ( (t), t) = ( (t– t), t– t)]. The method is also referred to as the characteristics-based method (Malevsky and Yuen 1991), because finding the coordinate on the previous time-step is similar to launching the characteristics backward with time: (3) We used the fourth-order explicit Runge-Kutta method to integrate Equation 3 forward in time. This technique separates a temporal approximation error from a spatial approximation error. The third step is the spatial interpolation, which can be carried out using any convenient and reasonable method. Although any interpolation method has the approximation error, it is still much easier to implement a high accuracy interpolation than to solve a high-order approximation to a differential equation. To interpolate the field at a given point we employed a bi-cubic spline approximation (Ahlberg et al. 1967, Naimark et al. 1998). The great advantage of the field method is that it gives a uniform information density over the entire system (e.g. Zia et al. 1998). The whole computational domain is covered uniformly by a color field representing deformation in any part of the system. Such a global behavior is not manifested in particle-based methods. The Lagrangian tracer (particle)-based method represents another type of tracing method. It simulates, for example, aluminum particles, which are often used to visualize flows in laboratory experiments. This is a straightforward method, which requires solving one vector differential equation: (4) where x denotes the vector of particle positions. The method does not have the pitfalls of the field approach. It solves the same characteristic equation but does not require interpolation. The accuracy of the method is independent on how close the particles approach each other. The absence of interpolation and the related errors greatly improves the overall accuracy of the method. However, it is not a good all-round method. The particles, positioned initially as blobs, become very dispersed with time, thus making the estimate of the mixing very approximate. The information density is very uneven because particles cover only a small fraction of the area being investigated. Such a problem could be partially overcome with a line method. The line/contour modification is the logical extension of the particle method. Each line is represented by a set of up to one million particles (Ten et al. 1998). Larger numbers of particles on the line allow the resolution of smaller-scale flow features. Insufficient numbers of particles can cause degradation in the accuracy (Franjione and Ottino 1987). Although the original particle method does not require interpolation, the line method does. Due to the highly irregular deformation field, some parts of the lines are stretched much more extensively than others. Numerical accuracy, which is proportional to the linear density of the particles along the line, degrades much faster in the stretched areas. As a result, in order to maintain uniform accuracy, the particles need to be redistributed along the lines. Another reason for redistribution is that some parts of the line are straight, while others may be strongly bent. A straight line may be efficiently restored with two known points. The same length but a bent line requires more points for a proper representation. In general, the number of particles should be proportional to the local curvature of the line (e.g. Dritschel 1988). We used the fourth-order implicit Adams-Moulton method with variable time-step for integrating Equation 4. Particles are distributed over the line according to a density function that is proportional to the curvature. Although dynamic redistribution induces interpolation errors, it drastically increases the overall accuracy because the bent section of the line is represented by many particles. Line analysis technique. Dynamics of lines show how mass is being transported in a system. However, the dynamics give us no quantitative estimation for mixing. In order to retrieve mixing properties from the line dynamics, we employed a line analysis technique. Assume for now that heterogeneity is an uneven distribution of some marker (particles or field). If a marker layer or dense cluster of particles is set in a calculation domain, the heterogeneity of such a system will be the highest possible, since the layer or the cluster is compactly localized in space. As the system evolves, the marker (akin to the dye movement in laboratory experiments) is distributed over the entire domain. Therefore the strength of the heterogeneity degrades because the distribution function of the marker layer tends to the homogeneous distribution. We employed a unique line-based method to quantify the heterogeneity of a system. Our marker is represented by a horizontal layer, which is bounded by two lines and box sides. Its thickness is one-tenth depth of a calculation domain. If we subdivide the box on horizontal levels and find the fraction of the marker layer hosted by each level, we may draw a depth distribution function from this data (see right panel of Fig. 3). Peaks on the plot show the depths where the layer mass is concentrated. The marker layer is deforming, changing its position, which induces the dynamical behavior of the distribution. Thus, the distribution over the depth evolves also dynamically. In other words, a new depth distribution for the layer is generated at each time-step. These distributions assembled along the time-axis build a mixing surface (or map) on the depth--time plane. High terrains on this map indicate comparatively high concentration of the marker in corresponding time--depth points. A flat landscape on the map indicates a homogeneous distribution of the marker over the depth. Fig. 3 Mass distribution analysis. Mass of the marker layer is calculated at each monitoring level. Data represent distribution of the marker layer over depth (right panel) Results and Discussion Fig. 4 Newtonian mixing as monitored by the field method. The mixing is characterized by a smooth two-cell motion. Initial color field is shown in Fig. 1(click for animated GIF, 1.9 MB) Fig. 5 Non-Newtonian mixing as monitored by the field method. The mixing is erratic. Plume events essentially affect mixing. During these events, mixing occurs in narrow localized zones (click for animated GIF, 1.7 MB) Field. Figures 4 and 5 show the evolutions of the marker fields in the Newtonian and the non-Newtonian convection respectively, as they are portrayed by the field method. The field method is very suitable for visualization, but the presence of high gradient zones makes qualitative analysis inaccurate. In some places on the figures one may find numerical instabilities (the Gibbs oscillations) due to the high gradients. We used a grid with up to 3000×1500 nodes for monitoring the field. The actual calculations were performed in spline space on a 1000x1000 grid. The resolution of animations (Figs. 4 and 5) was reduced in order to fit with the requirement of this electronic publication. As can be seen from the animations, the Newtonian system evolves much more smoothly than the non-Newtonian. The non-Newtonian mixing evolution mainly takes place during occasional plume events. The smooth cellular-type motion of the Newtonian convection results in different mixing properties as compared to the chaotic, localized mixing of the non-Newtonian convection. Figure 6 shows the evolution of the local [in scale (S) and time (t) spaces] fractal dimensions (D) for the non-Newtonian (left panel) and the Newtonian (right panel) mixing. Fig. 6 Fractal dimension as a function of the scale and time. Scale is the size of the box used to calculate the fractal dimension by the box-counting method. Left panel presents an evolution of fractal dimension for the non-Newtonian convection. Right panel shows the fractal dimension for the Newtonian convection The scales represent a measure of the size of the box used in the determination of the fractal (Ten et al. 1997) and are related to the spatial resolution. Thus, the figure depicts fractal dimensions on different scales at different times. Both figures are characterized by the two blue regions. The lower-left blue area represents non-mixed scales, while the upper-right blue area represents a well-mixed area. The green-to-red transition zone reflects the state of mixing. A mixing process starts with the blue unmixed stage with a fractal dimension of 2. Then the convection starts destroying and building new scales which change the fractal dimension to the lower value of 1.6 to 1.8. After that, the medium becomes mixed and its fractal dimension reaches a value of 2 again (Ten et al. 1997). As can be seen from the figure, both the Newtonian and the non-Newtonian convection destroy large scales (top parts of the figures) very efficiently. It takes a relatively short time (the green–red band) to homogenize the large scales. However, at smaller scales the efficiency of the mixing is decaying in both cases. As a result, the smaller scales require more time for the homogenization and the green--red band becomes wider. Moreover, for the log(S) less than 4 the efficiency degrades to such a level that it seems not to be capable of homogenizing the smaller scales further. In spite of some resemblances, the Newtonian mixing differs markedly from the non-Newtonian mixing. While the Newtonian convection exhibits smooth propagation of transitions through the various scales with time, the non-Newtonian convection demonstrates sharp jumps and drops. Such behavior is characteristic of the non-Newtonian convection due to the highly chaotic nature of this kind of flow (Malevsky et al. 1992, Larsen et al. 1995, Larsen et al. 1996). Figure 6 indicates also that the green--red band is wider or, in other words, the non-Newtonian mixing requires more time to mix. This way of using fractals to characterize the degree of homogenization is also employed in astrophysics (e.g. Wu et al. 1999). Another method for quantifying the complexity of a fractal field is proposed by Rodriguez-Iturbe and co-authors (1998) in hydrology. It may be a viable alternative to the measuring of fractal dimension. Lines. The lines method delivers a much higher accuracy than the field method. We placed ten horizontal lines (each with 106 particles) at different depths (from red at the top to blue at the bottom; Fig. 7). Fig. 7 Initial positions of lines This high resolution is capable of resolving very sharp and hardly deformed shear zones (Figs. 8 and 9) without any line crossing, which would indicate inaccuracies in the calculation. We note that the one million particles per line means that the separation between any two particles initially is 1.3 m when scaled to the upper-mantle system. This number suggests that it would be very difficult to obtain a resolution of 1 to 10 km in 3-D mixing, but that resolution of O(102 km) should be feasible with 5 to 10 million particles distributed over the whole mantle. Fig. 8 Newtonian mixing as monitored by lines (click for animated GIF, 2.9 MB) Fig. 9 Non-Newtonian mixing as monitored by lines (click for animated GIF, 1.9 MB) The analysis (Fig. 3) applied to the lines reveals that the mass of the marker layer is dispersed within a very short time in the Newtonian convection. We analyzed one marker layer located at a depth of 0.5 (about 300 km for the upper mantle). A mixing map (Fig. 10) shows how the mass of the monitoring layer is distributed over the entire depth with time. From our previous results, the Newtonian convection in the upper mantle makes the marker layer statistically indistinguishable after less than 300 Ma (Fig. 10). Scaled for the upper mantle, a dimensionless time of 0.01 corresponds to around 1 Ga. Fig. 10 Mixing map depicts spatial-temporal evolution of Newtonian convection. Both surface (upper panel) and contours (lower panel) are shown. Data show evolution of marker layer distribution with time. Higher terrains represent higher concentration of the layer in depth--time space. Convection disperses the layer for a short time In contrast to common expectations but in accordance with the fractal dimension behavior (Fig. 6), the non-Newtonian medium is less efficient in mixing and preserves the unmixed material even on a scale of 1 Ga (Fig. 11). The mass of the marker layer is concentrated in the upper part of the convection box and remains stable. Even after 1 Ga the significant part (20 to 30% of the mass) of the marker layer is located at a depth of 0.2 (about 120 km) near the top. This type of analysis is structurally selective, i.e. it is mainly directed towards recognizing horizontal structures, whereas the vertical structures may be left undistinguished. Fig. 11 Mixing map of non-Newtonian convection. Both surface (upper panel) and contours (lower panel) are shown. Data show an evolution of depth distribution with time. Higher terrains represent higher concentration of marker layer in depth--time space. The marker layer resists mixing. It remains distinguishable for at least 1 Ga as scaled to the upper-mantle convection However, the same technique (Fig. 3) may be applied to the analysis of the vertical structures. We used the same horizontal marker layer, but the monitoring levels were positioned vertically. Thus, this modification shows the accumulation of the material of the marker layer in vertical columns. Analysis of the vertical structures reveals another type of behavior (Figs. 12 and 13). Now the non-Newtonian medium does not display any more significant vertical heterogeneity (Fig. 13), while the Newtonian convection still does (Fig. 12). Fig. 12 Mixing map of Newtonian convection. Analysis of vertical structures. Both surface (upper panel) and contours (lower panel) are shown. Data show an evolution of depth distribution with time. Higher terrains represent higher concentration of marker layer in depth--time space. Position of marker layer was the same as for horizontal analysis (Fig. 10). The Newtonian convection forms stable vertical structures Sporadically, the Newtonian convection forms vertical columns. They may last several hundred million years. These structures are less stable and are not so sharp and distinct compared to the non-Newtonian medium. Thus, the structural properties of the mixing differ as well. The Newtonian convection builds up vertically orientated structures, while the non-Newtonian flow tends to form horizontal heterogeneities. Mixing in the non-Newtonian medium is less efficient in comparison to the Newtonian medium. One can probably notice this difference in the mixing from the animations taken from the field approach (Figs. 4 and 5). Similar results were observed in the laboratory experiment for viscoelastic medium (Niederkorn and Ottino 1993). Fig. 13 Mixing map of non-Newtonian convection. Analysis of vertical structures. Both surface (upper panel) and contours (lower panel) are shown. Data show an evolution of depth distribution with time. Higher terrains represent higher concentration of marker layer in depth--time space. In contrast to Newtonian convection, non-Newtonian convection develops no stable vertical structures Length. Stretching is one of the most important aspects of the mantle mixing. One can easily monitor the stretching with the line method. The length of the line represents an integral characteristic of stretching along the Lagrangian interface. It yields more accurate information, since it represents the naturally averaged deformation, which can be strongly spatially dependent. The dynamics of the lengths are shown in Figure 14. The lengths evolve in a very similar way for all the lines (independently of the initial depth). This means that the mixing is more or less uniform along the depth. The Newtonian case (left panel of Fig. 14) exhibits more effective stretching than the non-Newtonian (right panel of Fig. 14). The exponential stretching in the Newtonian model fits with previous observations (Hoffman and McKenzie 1985, Christensen 1989). Similar mixing properties of the stretching statistics of the length were observed for granular media (Shinbrot et al. 1999). The non-Newtonian model exhibits a different rate of extension. It is less efficient and fits with a power-law with time on the later stages of the evolution. After 1 Ga, the line is stretched by as much as about 100 times longer for the non-Newtonian convection and 300 times longer for the Newtonian convection. The Newtonian medium is roughly three times more efficient in mixing than the non-Newtonian medium. We may expect that effective velocity no longer scales as Ra0.51 (McKenzie et al. 1974) for a non-linear medium. The smoothness of the Newtonian convection results also in a smooth stretching rate, whereas the non-Newtonian stretching is step-like (left panel of Fig. 14). This is further evidence of the strongly time-dependent plume-driven nature of the non-Newtonian mixing. The abrupt and powerful extension events occur during the plume bursts. As a result, the main mixing motion in the Newtonian convection is of cellular size, while for the non-Newtonian we may expect the redistribution of the kinetic energy between large-scale cell motion and smaller-scale plumes. Such a redistribution results in different scale-breaking properties, and, consequently, in different mixing properties. Fig. 14 Evolution of line lengths. Extension rates in Newtonian convection fit well with exponential law (left panel), while non-Newtonian convection exhibits power-law extension rates (right panel) Physical reasoning. It was commonly held (e.g. Hoffman and McKenzie 1985) that mixing in the Newtonian convection is much less efficient than in the non-Newtonian convection. It was suggested that the more chaotic behavior of the non-linear system would result in better mixing. Our results refute this common belief. The explanation of this contradiction comes from consideration of the velocity spectrum. In order to maintain a finite amount of energy in the system, it must decay with the horizontal wave number (Fig. 15) regardless of rheology. In other words, the variation of velocity becomes smaller over finer scales. On the other hand, the temporal variation of the velocity is the strain rate. Thus the spectrum reflects the behavior of the strain-rate. The strain-rate degrades on small scales, as does the stress. It is a key point for the non-Newtonian rheology whose effective viscosity is stress-dependent. Smaller stress for smaller scales means a higher effective viscosity (Fig. 13). Consequently, we may expect that the non-Newtonian rheology would probably resist mixing over smaller scales. However, plume-driven dynamics may affect mixing efficiency, enhancing it over the smaller scales. The combination of these two mechanisms would probably result in a scale partitioning of mixing and higher mixing resistance over the intermediate scales. This is an additional scale-dependent mechanism affecting only the non-Newtonian mixing. In contrast, the Newtonian viscosity, which does not depend on the stress, does not have this scale-dependent behavior. Fig. 15 Hypothetical spectra for non-Newtonian convecting medium. The velocity spectrum should decay. Consequently, effective viscosity rate should increase. However, the tendency of non-Newtonian media to localize a flow may affect the actual spectrum Figure 5 shows that the highest rate of the non-Newtonian convection development occurs during the plume event. In other words, the mixing in non-Newtonian media is driven by the plumes in its significant part. Thus, we may expect strong influences from these types of velocity field patterns on mixing. The cellular type mixing generates certain structural scales, which are different from those generated by the plume dynamics. The presence of multiple-scale generators for non-Newtonian convection may result in the multifractal style of mixing (Fig. 6). Fast-decaying velocity spectra (Malevsky and Yuen 1993) would imply that on a smaller scale deformation would become negligibly small. Thus, mixing degrades with the reduction of the scales (Metcalfe et al. 1995). This simply means that convection destroys the large-scale heterogeneities very fast, but it requires much more time to destroy the smaller scales. Three-dimensional convection shows a much stronger decay of kinetic energy spectra (Malevsky and Yuen 1993). Hence, the efficiency of 3-D mixing might be much lower than that of 2-D mixing, even with toroidal mixing. The question arises as to whether convection may efficiently destroy scales of less than 10 km and how much time is required to do so. Using the kitchen analogy, one cannot slice vegetables to get much smaller-sized pieces than the knife-edge, but how sharp then is the convective knife-edge? Conclusions In this study we have described the various numerical techniques used in the study of mixing and have displayed the visualizations derived from both the field and line-particle methods. The following principal conclusions can be drawn: · · · · The evolution of the fractal dimension shows that the non-Newtonian convection remains more fractal-like and lasts for a longer time than for the Newtonian convection. The Newtonian convection homogenizes the mass heterogeneities much faster and goes to a fractal dimension of 2, much more readily than for the non-Newtonian convection, whose fractal dimension lies around 1.6 for a long time. Stretching of the line indicates a greater amount of deformation for the Newtonian medium, whose line length grows exponentially with time. On the other hand, the length associated with the non-Newtonian mixing grows according to a power-law in time. The length of the line is three times longer for the Newtonian than for the non-Newtonian mixing, showing a greater amount of stretching. Horizontal layered structures are formed and are preserved by the non-Newtonian medium, while for the Newtonian medium there is a tendency for vertically polarized structures to develop. Because of the nature of the stress-dependent rheology, mixing at intermediate scales meets greater resistance in the non-Newtonian rheological medium. This scale-dependent threshold will limit the efficiency of mixing in non-Newtonian rheological medium. Toroidal motions in 3D will also meet this fate in non-Newtonian situations. Acknowledgement The fractal dimension surface (Fig. 6) was constructed by Leeza Pachepsky. We thank Julio Ottino for a stimulating conversation and Maarten A. Koenders and an anonymous reviewer for constructive reviews. We are grateful for the highly valuable assistance provided by John D. Clemens. This research has been supported by the EMSP program and the Geosciences program of the Department of Energy. 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