AN ABSTRACT OF THE THESIS OF Robert Lance George for the dual degrees of Master of Science in Forest Science and Forest Engineering presented on June 12, 2006. Title: Baseline Stream Chemistry and Soil Resources for the Hinkle Creek Research and Demonstration Area Project Abstract approved: Kermit Cromack, Jr. Stephen H. Schoenholtz This research addressed the opportunity to obtain baseline data for both stream chemistry and soil resources for an intensively managed forest watershed, encompassed by the North and South Forks of Hinkle Creek Watershed Research and Demonstration Area Project near Sutherlin, Oregon. A solid representative database for both stream and soil nutrients in these forest watersheds will provide a model upon which to help gauge the effects of current and expected intensive forest management practices on industrial forest land. Eight original sampling points were described for water chemistry. In addition, samples were collected from three other locations directly below two clearcuts completed in 2001 that had subsequent intensive vegetation control measures in place. The total nutrient output in kg month-1 and kg ha-1 month-1 among the Hinkle Creek streams differed greatly due to discharge and watershed area, but their nutrient concentrations, with few exceptions, were closely related. All stream water N concentrations were low, except for some higher NO3-N concentrations for two partially treated watersheds, Clay and Beeby Creeks. DeMearsman Creek, a control, had an NO3-N + NO2-N concentration of 0.01mg L-1 in December, 2003. In contrast, a Beeby Creek tributary below a clearcut had a 1.75 mg L-1 concentration. The NO3-N concentrations increased substantially after urea fertilization of most of the Hinkle Creek basin in late October, 2004. Samples in January, 2005 showed a reversal of NO3-N + NO2-N concentrations between treatment vs. control watersheds (P < 0.02, T = 4.24). Partial clearcuts or completely forested basins both had similar nutrient concentration data, with the exception of N, especially NO3-N + NO2-N. Beeby Creek was significantly higher in NO3-N + NO2-N, with a two-sided inference (P < 0.0001, T = 6.26.5), than all of the other headwater streams. Clay Creek sampled above and below a clearcut showed no significant change (P = 0.272, T = 1.15). Hinkle Creek South Fork showed that the downstream effects of clearcutting, especially NO3-N + NO2-N output from smaller upstream tributaries, may transmit their effects to larger confluences downstream (P = 0.0001, T = 4.47). Newly published soil surveys from the National Resource Conservation Service and Douglas County SCS were used to set up a methodology for sampling the representative Hinkle Creek soil resources. Eight main soil types were mapped, 27 representative soil pits were dug in accordance with the location of the mapped soils, and standard soil survey descriptions were created. Soil cores were taken from different depths (0-15, 15-30 and 30-60 cm). These data were used to estimate total soil C, N, P, and S resources, soil cation exchange capacity, and available base cations (Ca, Mg, K, and Na). Soil N was low, with the most prevalent soil series, (Orford Gravelly Loam) having 1010 kg ha-1 (S.E. 143) in the top 15 cm. Low stream N concentration may be correlated with the low soil N content, which may limit Hinkle Creek tree production. ©Copyright by Robert Lance George June 12, 2006 All Rights Reserved Baseline Stream Chemistry and Soil Resources for the Hinkle Creek Research and Demonstration Area Project by Robert Lance George A THESIS submitted to Oregon State University in partial fulfillment of the requirements for the degree of Master of Science Presented June 12, 2006 Commencement June 2007 Master of Science thesis of Robert Lance George presented on June 12, 2006. APPROVED: _____________________________________________________________________ Co-Major Professor, representing Forest Science Co-Major Professor, representing Forest Engineering _____________________________________________________________________ Head of the Department of Forest Science Head of the Department of Forest Engineering Dean of the Graduate School I understand that my thesis will become part of the permanent collection of Oregon State University libraries. My signature below authorizes release of my thesis to any reader upon request. Robert Lance George, Author ACKNOWLEDGEMENTS I would like to express my sincerest appreciation to my major professor, Kermit Cromack, Jr., who awarded me the opportunity to study and live in this wonderful environment. His ability to challenge me while offering invaluable guidance and support provided me with a truly rewarding graduate experience. I would also like to thank my other major professor, Stephen Schoenholtz and my committee members, Jana Compton, Arne Skaugset, and Dominique Bachelet for taking time out of their busy schedules to provide timely advice and for being encouraging. I am especially grateful to Joel Norgren for all his help and knowledge with soil classification; this project is so much better as a result of his input. Nicholas Zegre provided all the hydrological data used in this study and I am extremely grateful. All of the members of the “Richardson Lab” also deserve recognition for their positive encouragement, advice, and support. I am also extremely appreciative of the financial support provided by Oregon State University, and of the State of Oregon funding for the Forest Research Laboratory located at OSU in the College of Forestry. Finally, I want to express my gratitude to my friends and family. My parents have always been excellent role models, teaching me the rewards of hard work and determination. Their unwavering support has helped me to see this process through. Lastly, a huge thank-you to my amazing friends who were there to challenge me as a student and as a friend, support me through all those good and not so good times, and to help me keep things in perspective by providing more than ample distractions. It is all of you who have made this experience so unforgettable. CONTRIBUTION OF AUTHORS I am grateful to Kermit Cromack, Jr. for the work he did on editing and supplying incredibly helpful advice in the completion of this thesis. TABLE OF CONTENTS Page Chapter 1: Introduction to the Study................................................................................... 1 Background and Site Description ................................................................................... 1 General Objectives.......................................................................................................... 5 Water Chemistry ............................................................................................................. 6 Soils................................................................................................................................. 7 Chapter 2: Soil Resources of the Hinkle Creek Watershed Research and Demonstration Area Project ...................................................................................................................... 10 Introduction................................................................................................................... 10 Methods......................................................................................................................... 12 Research design ........................................................................................................ 12 Sampling methods..................................................................................................... 12 Analysis methods ...................................................................................................... 17 Results and Discussion ................................................................................................. 18 Soil mapping accuracy.............................................................................................. 18 Soil bulk density ....................................................................................................... 22 Soil chemistry ........................................................................................................... 23 Chapter 3: Stream Chemistry of the Hinkle Creek Watershed Research and Demonstration Area Project.............................................................................................. 38 Introduction................................................................................................................... 38 Methods......................................................................................................................... 39 Research design ........................................................................................................ 39 Sampling methods..................................................................................................... 39 Analysis methods ...................................................................................................... 40 Results and Discussion ................................................................................................. 48 General water chemistry ........................................................................................... 48 Nitrogen .................................................................................................................... 52 Urea fertilization ....................................................................................................... 57 Chapter 4: Conclusion and Predictions............................................................................. 84 Bibliography ..................................................................................................................... 89 Appendices........................................................................................................................ 96 LIST OF FIGURES Figure Page 1.1 Hinkle Creek Watershed Research and Demonstration Area Project …... 3 2.1 Douglas County Soil Conservation Service soil map…………………… 15 2.2 Soil pit and water sampling locations…………………………………… 16 3.1 Hinkle Creek Watershed stream sampling locations………………...…... 46 3.2 Hinkle Creek Watershed Oct., 2004 urea fertilizer application area (green)........................................................................................................ 47 3.3 Clay Creek, showing NO3-N + NO2-N concentrations above and below a clearcut………………………………………………………….…..…. 77 Clay Creek, showing NO3-N + NO2-N concentrations above and below a clearcut. .………………………………………………………………. 77 Beeby Creek and its two main tributaries, showing NO3-N + NO2-N concentrations ………………………………………………….….…….. 78 Beeby Creek and its two main tributaries, showing NO3-N + NO2-N concentrations….…………………………………………………….….. 78 Hinkle Creek North and South Forks, showing NO3-N + NO2-N concentrations…………………………………………………………… 79 Hinkle Creek North and South Forks, showing NO3-N + NO2-N concentrations…………………………………………………………… 79 3.9 Hinkle Creek Watershed creek NO3-N + NO2-N concentrations…….…. 80 3.10 Hinkle Creek Watershed creek NO3-N + NO2-N concentrations.………. 80 3.4 3.5 3.6 3.7 3.8 LIST OF TABLES Table Page 1.1 Hinkle Creek Watershed description…………………………………..…. 6 1.2 Soil classification table for the main soil series located in the Hinkle Creek drainage……………………………………………………………. 9 Soil series comparisons at 0-15 cm depth for amounts of soil nutrients (< 4 mm size fraction)..…………………..……………………………….. 25 Soil series comparisons at 0-15 cm depth for nutrient element ratios, cation exchange capacity (CEC) and % base saturation….……………….. 26 Soil series comparisons at 15-30 cm depth for amounts of soil nutrients (< 4 mm size fraction)……………………..………………………………. 27 Soil series comparisons at 15-30 cm depth for nutrient element ratios, cation exchange capacity (CEC) and % base saturation………………….. 28 Soil series comparisons at 0-30 cm depth for all nutrients except C, S, and N, which are at 0-60 cm. (< 4 mm size fraction)………………………..... 29 Soil series comparisons at 0-30 cm depth for nutrient element ratios, cation exchange capacity (CEC) and % base saturation……...…………… 30 Soil series comparisons at 0-15 cm depth for concentrations of soil nutrients (< 4 mm size fraction)…………………….……………………... 31 Soil series comparisons at 15-30 cm depth for concentrations of soil nutrients (< 4 mm size fraction).……………...…………………………… 32 Soil series comparisons at 0-30 cm depth for concentrations of soil nutrients (< 4 mm size fraction)…………………………………………... 33 2.10 Soil series comparisons at 0-15 cm depth (< 4 mm size fraction).…….….. 34 2.11 Soil series comparisons at 15-30 cm depth (< 4 mm size fraction)..…….... 35 2.12 Soil series comparisons at 30-60 cm depth (< 4 mm size fraction)……….. 36 2.13 Soil series comparisons at 0-60 cm depth (< 4 mm size fraction)…...……. 37 3.1 Levels of detection and precision for CCAL analyses……………………. 43 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 LIST OF TABLES (Continued) Table Page 3.2 Analytical methodology for CCAL……………………………………….. 44 3.3 CCAL analytical instrumentation…………………………………………. 45 3.4 North Fork Hinkle Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1……………………………………………. 61 South Fork Hinkle Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1……………………………………………. 62 Myers Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. …………………………………………………… 64 DeMearsman Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. ……………………………………………..……. 65 Clay Creek A mean monthly flow rate and water chemistry nutrient amounts in kg month-1……………………………………………….……. 66 Clay Creek B mean monthly flow rate and water chemistry nutrient amounts in kg month-1. ……………………………………………..……. 67 Beeby Creek main channel mean monthly flow rate and water chemistry nutrient amounts in kg month-1……………………………………………. 68 3.11 Beeby Creek Tributary 1 nutrient concentrations in mg L-1………..…….. 69 3.12 Beeby Creek Tributary 2 nutrient concentrations in mg L-1………………. 70 3.13 Russell Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1…………………………………………………….. 71 Fenton Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1………………………………………………….…. 72 Hinkle Creek Watershed nitrogen and phosphorus concentrations for Oct. 2002 – Oct. 2003………………………………………………………..…. 73 Hinkle Creek Watershed silicon, base cation, sulfate, and chloride concentrations for Oct. 2002 – Oct. 2003……………….……………….... 74 3.5 3.6 3.7 3.8 3.9 3.10 3.14 3.15 3.16 LIST OF TABLES (Continued) Table 3.17 Page Hinkle Creek Watershed pH, alkalinity, and conductance values for Oct. 2002 – Oct. 2003………………….. ………….………………………..…. 75 Hinkle Creek Watershed pH, alkalinity, and conductance values for Dec. 2003 – May 2005…………..……….………………….…………………. 76 3.19 Stream chemistry data from H. J. Andrews WS #10 weir from 1973-75..... 81 3.20 Average inorganic and organic N concentrations for three Douglas-fir old-growth dominated streams at the H. J. Andrews Experimental Forest.. 81 Annual mean NO3-N (mg L-1) concentrations for three streams in the Alsea River basin both before (1965-1966) and after (1967-1968) treatments…………………….………………………………………….... 81 Yearly flow rated average nutrient concentrations of several streams in the Oregon Coast Range in 2000………………………………..………... 82 T-test results comparing Hinkle Creek Watershed creek NO3-N + NO2-N concentrations among streams with different clearcut percentages………. 82 T-test results comparing four Hinkle Creek Watershed headwater treatment creeks with two headwater control creeks for effects of urea N fertilization in fall, 2004……………………………….………………….. 83 Nitrogen exported from the North and South Forks of Hinkle Creek for the calendar year 2004…………….............................................................. 83 3.18 3.21 3.22 3.23 3.24 3.25 LIST OF APPENDIX TABLES Table Page A1.1 Soil horizon legend……….……………………………………….……….. 97 A1.2 Soil boundary legend…………...…………………………………..…..….. 97 A1.3 Soil texture legend……………..…….………………...……….…..…..….. 97 A1.4 Soil structure legend………………………………………..……..………. 98 A1.5 Soil consistency legend……………..……………………………..…...….. 98 A2.1 Soil pit # 1 description…………...…………………………...……..……... 99 A2.2 Soil pit # 2 description…………...……………………………...…..……... 99 A2.3 Soil pit # 3 description…………….…………………………….…..……... 100 A2.4 Soil pit # 4 description…………….……………………..…….…………... 100 A2.5 Soil pit # 5 description…………….………………………...……………... 101 A2.6 Soil pit # 6 description…………….……………………….…..…………... 101 A2.7 Soil pit # 7 description…………….………………….……………..……... 102 A2.8 Soil pit # 8 description…………….……………….………………...…….. 102 A2.9 Soil pit # 9 description…………….……………………..………………... 103 A2.10 Soil pit # 10 description……………………………………………..…….. 103 A2.11 Soil pit # 11 description……..……..…………………………….………... 104 A2.12 Soil pit # 12 description.………..…….……………………………….…... 104 A2.13 Soil pit # 13 description…………..………..……………………….……... 105 A2.14 Soil pit # 14 description…………..……………………………..….……... 105 A2.15 Soil pit # 15 description…………..…………………………..……….…... 106 A2.16 Soil pit # 16 description…………..…………………………………...…... 106 LIST OF APPENDIX TABLES (Continued) Table Page A2.17 Soil pit # 17 description.…………….……..…………………….………... 107 A2.18 Soil pit # 18 description……………..……………………………...……... 107 A2.19 Soil pit # 19 description.…………………………………………...…….... 108 A2.20 Soil pit # 20 description…………….……………………………………... 108 A2.21 Soil pit # 21 description…………..………………………………...…....... 109 A2.22 Soil pit # 22 description…………….……………………………………... 109 A2.23 Soil pit # 23 description.…………………………………………………... 110 A2.24 Soil pit # 24 description.…………………………………………………... 110 A2.25 Soil pit # 25 description…………………………………………………… 111 A2.26 Soil pit # 26 description.……………..……………………………..……... 111 A2.27 Soil pit # 27 description.…………………………………………………... 112 A2.28 Comments on soil pits1-27.…………………………………………..…… 112 Baseline Stream Chemistry and Soil Resources for the Hinkle Creek Watershed Research and Demonstration Area Project Chapter 1: Introduction to the Study Background and Site Description The Hinkle Creek Watershed Research and Demonstration Area Project is a paired-watershed study. The goal of this paired watershed study is to evaluate the efficacy of current forest practices on private industrial forestland upon water quality, aquatic habitat, and fish. Hinkle Creek is a 4th order stream flowing out of an ~2000 ha watershed located about 18 km east of Sutherlin, Oregon in the foothills of the Cascades (Figure 1.1). This watershed is almost wholly owned and managed by Roseburg Forest Products. All watersheds in the Hinkle Creek Area are primarily forested with 55-60 year old Douglas-fir [Pseudotsuga menziesii (Mirb.) Franco] with riparian zones covered in red alder [Alnus rubra Bong]. The key cooperators in the Hinkle Creek paired watershed study are Roseburg Forest Products, the College of Forestry and Department of Fisheries and Wildlife at Oregon State University, the Oregon Forest Industries Council, the Oregon Department of Forestry, Oregon Department of Fish and Wildlife, and the United States Geological Survey. The first goal for the paired watershed study is quantifying the impacts of modern forestry upon fish. Several species and stocks of salmonids have been listed as threatened or endangered throughout the Northwest. There is a mandate to develop forest practices that sustain and allow for the recovery of salmonid populations. This project is designed primarily to investigate the response of salmonids to current forest practices in a 2 forest intensively managed on a watershed scale. The effects of water quality, stream chemistry, soil resources, hydrology, and aquatic habitat are all being studied. All of these parameters are important in their own right, but all also are important as explanatory variables that affect fish populations. This project was designed to connect intensive forest management practices directly to fish through several environmental variables. The second goal of this project is to study the cumulative effects of modern forestry upon fish. The concerns regarding the impact of intensive forest management upon fisheries is increasingly about the effects of forest practices on multiple, non-fishbearing streams draining downstream to a single, small, fish-bearing stream. The goal of the Hinkle Creek project is to investigate how the direct effect of forest practices on water quality in non-fish-bearing stream reaches accumulates and to determine the indirect off-site effects on the fish-bearing stream. These cumulative effects have been addressed conceptually for many years; however, this project is one of the first to address the issue quantitatively. 3 Figure 1.1. Hinkle Creek Watershed Research and Demonstration Area Project. 4 Hinkle Creek is an important location for this study because the type of forest it represents covers vast areas of the Pacific Northwest, and little research has been focused upon modern forestry practices used on this landscape. Paired watershed studies are difficult to get established on private land because of the duration and acreage commitment required by the landowner. Roseburg Forest Products generously has made a long-term commitment to allow this study to take place. They have deferred harvest on the control watershed, the North Fork, until ~2011 and have changed harvest schedules on the South Fork to allow the research to occur. Paired watershed studies in the past have occurred primarily on land owned by the Forest Service or the state. These studies occurred in the late 1950’s, 1960’s, and early 1970’s (Brown et al., 1973; Sollins et al., 1980; Keppeler and Ziemer, 1990; Grant and Wolff, 1991; Thomas and Megahan, 1998; Ziemer, 1998; Beschta et al., 2000). They involved the conversion of large, mature or old-growth forests to managed forests. Road systems had to be constructed and the timber was harvested using logging systems and machinery from that era. These studies also occurred before modern forestry practices were developed. The type of forest ecosystem that is being managed on private industrial forestland and the methods that are used are different today than they were three decades ago. The forest stands are composed of naturally and artificially regenerated trees 1~70 years old. The road systems are built with a concern for minimizing erosion, and the harvesting systems are more benign to the environment. 5 Hinkle Creek represents all these changes. The intent of the landowner is to manage this forestland in perpetuity for the production of solid wood. The road system was in place and was improved as this harvest began. The logging equipment is contemporary and uses modern skyline yarding systems. Current forest practices that will be used include harvest unit size limits, adjacency restraints, riparian protection, and vegetation control. The research results from this study will be much more representative of current forest practices on private, industrial forestland than most of the previous studies which represented contemporary forest practices of their time. The geology, area, aspect, and size of the different watersheds are summarized in Table 1.1. The soil types are summarized in Table 1.2. General Objectives The research conducted during the present study represents only a small portion of this large project. The two main thesis objectives were: 1) to obtain monthly firstyear, and subsequent two-year seasonal water nutrient concentration data for a total of three consecutive years in six headwater streams, and in the North and South Forks of Hinkle Creek. Stream nutrients measured included: total N, P, and base cations (Ca, K, Mg, and Na), dissolved organic N (DON), and inorganic N (NO3-N, NH4-N ), stream pH, SO4, HCO3, Cl, and Si; 2) to obtain data for soil resources and geomorphology on these watersheds, including soil physical properties; soil texture; bulk density; pH; soil C, N, P, and S; soil cation exchange capacity (CEC); and exchangeable base cations (K, Ca, Mg and Na). This research was designed to integrate with the proposed Hinkle Creek Watershed Research and Demonstration Area Project on Hydrology and Water Quality. 6 Water Chemistry In September, 2002, two control and four treatment watersheds were selected for stream sampling, in addition to stream sampling sites just above the confluence of the North and South Forks of Hinkle Creek, for collection of water samples for chemical analyses. Since the eight original sampling points were described, we took additional samples from three other locations directly below two clearcuts completed in 2001. See Table 1.1 for general watershed characteristics. Table 1.1 Hinkle Creek Watershed description. Area (ha) Aspect Clearcut ~ % Hinkle Creek S.F. 1061 WNW 15 Tertiary andesitic and rhyolitic rock and landslide deposits Hinkle Creek N.F. 873 WSW 0 Tertiary andesitic and intrusive rock and landslide deposits Myers Creek 86 NNW 0 Tertiary intrusive rock DeMearsman Creek 156 WSW 0 Tertiary andesitic rock Fenton Creek 23 N 0 Holocene and Pleistocene landslide deposits Russell Creek 96 NNE 5 Holocene and Pleistocene landslide deposits Creek Geology * Clay Creek 65 N 40 Holocene and Pleistocene landslide deposits Beeby Creek 111 NNW 20 Tertiary rhyolitic rock All watersheds are primarily forested with 55-60 year old Douglas-fir (Pseudotsuga menziesii) with riparian zones partially covered with red alder (Alnus rubra). *(Sherrod, 2004) 7 Soils Newly published soil surveys from the National Resource Conservation Service (NRCS) were used to set up a method for sampling soils in the study watersheds. Eight main soil types were mapped, representative soil pits were dug in accordance with the location of the mapped soils, and standard soil survey descriptions were created. Twenty-seven soil pits were dug during summer, 2003, their descriptions recorded, and locations noted. These pits were revisited during late winter and spring, 2004, and soil cores were taken from different depths. This information has been used to create an estimate of total soil C, N P, and S resources, soil CEC, available base cations (Ca, Mg, K, and Na) and other soil physical and chemical properties noted in the research objectives. The classification of the eight soil types is shown in Table 1.2. Several soils are classified as Inceptisols but in the near future may be renamed Andisols once additional laboratory tests are run by the NRCS on a backlog of newer soil series (Dr. Joel A. Norgren, personal communication, 2006). Inceptisols previously included Andepts, which were to be placed in the new Andisol order (Buol et al., 1989). The Orford series (~45% of basin) is very deep, well-drained and usually found on footslopes, side slopes and ridges. The parent material is residuum and colluvium formed from sandstone, siltstone and volcanic rock (Johnson et al., 1994). The Klickitat (~20% of basin), Illahee (~5% of basin), Mellowmoon, Scaredman, Kinney, and Lempira (~1-4% each) series are very deep, well-drained and usually found on side slopes and ridges. The parent material is residuum and colluvium formed from volcanic rock (Johnson et al., 1994). 8 The Harrington series (~2%) is moderately deep, well-drained and usually found on side slopes and ridges. The parent material is colluvium formed from volcanic rock (Johnson et al., 1994). The Honeygrove series (~15% of basin) is very deep, well-drained and usually found on footslopes, side slopes and broad ridges. The parent material is residuum and colluvium formed from sandstone, siltstone and volcanic rock (Johnson et al., 1994). All series formed no earlier than the Tertiary period, and most colluvium and residuum was created during the Holocene and Pleistocene epochs (Sherrod, 2004). Table 1.2. Soil classification table for the main soil series located in the Hinkle Creek drainage. Soil Series Orford Klickitat Harrington Honeygrove Illahee Mellowmoon Scaredman Kinney Lempira Order Ultisols Inceptisols Inceptisols Ultisols Inceptisols Inceptisols Inceptisols Inceptisols Andisols Suborder Humults Udepts Udepts Humults Udepts Udepts Udepts Udepts Udands Great group Palehumults Dystrudepts Dystrudepts Palehumults Dystrudepts Dystrudepts Dystrudepts Dystrudepts Hapludands Subgroup modifier Typic Humic Humic Typic Humic Humic Humic Andic Typic Particle size Fine Loamyskeletal Loamyskeletal Fine Loamyskeletal Fine-loamy Loamyskeletal Fine-loamy Medial Mineralogy Isotic Isotic Isotic Mixed Isotic Isotic Isotic Isotic Amorphic (From Johnson et al., 1994) 9 10 Chapter 2: Soil Resources of the Hinkle Creek Watershed Research and Demonstration Area Project Introduction Studies focusing on the impacts of forestry upon natural resources often concentrate on water quality, including sediment, temperature, dissolved oxygen, water yield and nitrate-N (Grant and Wolff, 1991; Binkley, 1993). Soils are the foundation of an ecosystem, and most water quality parameters can be linked to the types of soils present on the watershed in addition to the logging systems used. Many studies seem to focus on either the water aspect or the soils alone, but don’t incorporate both of them (Johnson and Beschta, 1980; Homann et al., 2001). A representative soil database collected prior to forest manipulations creates a baseline for future comparisons. Watershed 10 at the H.J Andrews Experimental Forest in Blue River, Oregon shows how truly valuable this can be (Sollins et al., 1980). The range of soil C and N resources across the H.J. Andrews Forest varies by about 2.7 (Sollins et al., 1980; Means et al., 1992). The forest manipulations used at Hinkle Creek, including clearcutting, slash pile burning, complete vegetation suppression with herbicide for at least two years, and fertilization, will affect various soils differently. Landowners with knowledge of the soil’s characteristics, such as bulk density and various other physical properties, can better plan harvest schedules using existing soil maps to lessen impacts upon water quality. Using the newly published soils maps furnished by the NRCS, a soil sampling methodology was created to determine their accuracy. Having a representative sample 11 for the chemistry of the various soil series described gives valuable information to future researchers to forecast and analyze the possible effects upon stream chemistry. There are a myriad of possibilities as to why particular watersheds react differently to very similar treatment manipulations, but having at least a basic understanding of the soils present can only aid both researchers and landowners in planning future treatments. Nitrogen fertilization occurred on these watersheds in 1993 and in 2004 (Richard S. Beeby, Roseburg Resources Co., Roseburg, Oregon, personal communication, 2005), and knowledge of the soil properties could have important economic impacts. Soils will react differently to the same fertilizer input; however, by knowing which soils are fertile for tree growth and which are not, the landowner will benefit economically and ecologically from smaller nutrient inputs. Soils that are already nutrient-rich will not be needlessly fertilized, with possible runoff that may affect water quality (Tiedemann et al., 1978). An objective of this study was to determine the accuracy of existing soil maps by digging soil pits and comparing the descriptions to the ones already published. This was done to see if using the soil maps as a guide for research and forestry planning was a plausible idea in the Hinkle Creek basin. The main objective was to give a pre-treatment database of soil resources. Future researchers can revisit all of the pits dug and determine what changes the treatments have caused to soil physical and chemical properties. 12 Methods Research design This study used a paired watershed design that had previously been determined to be part of the overall larger study occurring at the Hinkle Creek Watershed Research and Demonstration Area Project (Figure 1.1). The treatment and control watersheds placement and treatment timetable was in place prior to the initiation of my research. Newly published soil surveys from the NRCS and Douglas County SCS were used to design a methodology for sampling the representative Hinkle Creek soil resources (Figure 2.1). Eight main soil types were mapped, representative soil pits were dug in accordance with the location of the mapped soils, and standard soil survey descriptions were created (see Appendices). Standard soil descriptions were produced using procedures and terminology outlined in the NRCS field book (Schoenberger et al., 2002). The pit locations were chosen to sample the different soil types to ascertain the accuracy of the published surveys and to cover as thoroughly as possible most of the basin (Figure 2.2). Dr. Joel A. Norgren, an experienced professional soil scientist with many years of mapping expertise, was hired to help select locations for the soil sampling, with assistance from William O. Russell, III, a Forest Science Ph.D. graduate student. In addition, a higher proportion of pits were located in clearcuts completed prior to the initiation of the study to aid in deciphering possible water chemistry treatment effects. Sampling methods Twenty-seven soil pits were dug during summer, 2003, their descriptions recorded, and locations noted using a Trimble GPS unit. The GPS was unable to connect 13 at one pit, so a description was still created without an exact location being noted. These soil pits were revisited during late winter and spring, 2004, and soil cores were taken from three different depths (0-15, 15-30, and 30-60 cm). A double-cylinder, slidinghammer core sampler was used (Blake and Hartge, 1986). The cores had a volume of 100 cm3 and were taken from the side of the pit horizontally entering the profile. The organic duff was not sampled. These data were used to create baseline data for soil resources and geomorphology on these watersheds, including soil physical and chemical properties: bulk density; pH; soil texture; soil C, N, P, and S; CEC; and exchangeable base cations (K, Ca, Mg and Na). This information was used to estimate total soil C, N, P, and S resources, soil CEC, available base cations (Ca, Mg, K, and Na) and other soil physical and chemical properties noted above. Soil cores from the three different depths in 23 pits were collected and dried for storage. They were sieved and the soil fraction < 4 mm was ground for analysis to avoid possible bias, using only the traditional < 2mm fraction (Corti et al., 1998; Harrison et al., 2003). Four other soil pits were mostly rock, and soils were described, but not analyzed chemically. The coarse fragment proportion from the soil cores was subtracted on a volumetric basis and only the bulk density of the fines was used to produce estimates of soil resources. For each soil pit sampled, the coarse fragment % for the different depths also was multiplied by (1 - % coarse fragments) to obtain the total nutrient pool of the fines to report the kg ha-1. The pools of soil resources were reported both as kg ha-1 and total percentage of sample. Element ratios and total amounts of exchangeable cations also were reported. 14 The sieved fine fraction (< 4 mm) of mineral soil samples was used for all soil chemical analyses. This size fraction includes a greater pool of soil nutrients, and encompasses a greater size range of soil aggregates (Homann et al., 2001). Soil samples were analyzed for total soil C, N and S after grinding to 80 mesh, drying at 60ºC in a drying oven, and then weighing into 200 mg sample aliquots prior to analysis using a LECO induction furnace (Bremner, 1996; Nelson and Sommers, 1996; Tabatabai, 1996). Soil pH was determined for mineral soil samples using a calibrated pH electrode and a 1:2 mass addition of distilled water (Thomas, 1996). The ammonium acetate method at pH 7 was employed for determining soil cation exchange capacity (Sumner and Miller, 1996). Exchangeable K, Ca, Mg and Na were determined on mineral soil samples with the ammonium acetate extraction method at pH 7 (Helmke and Sparks, 1996; Suarez, 1996). After extraction, K, Ca, Mg and Na concentrations were determined, using inductively coupled plasma mass spectroscopy (Soltanpour et al., 1996). The percentage base saturation was obtained by calculating the percentage of the total cation exchange capacity that was occupied, by the summation of the exchangeable base cations (K, Ca, Mg and Na). Mineral soil samples were digested in a micro-Kjeldahl unit, and then total soil P was subsequently determined using a Technicon autoanalyzer (Kuo, 1996; Cromack et al., 1999). 15 Legend 305E – Honeygrove Gravelly Clay Loam 466E – Kinney-Klickitat Complex 327E – Orford Gravelly Loam 900E – Lempira Gravelly Loam 463F – Klickitat-Kinney Complex 1460G - Klickitat-Harrington Complex 464G – Klickitat-Harrington Complex 1901F – Illahee-Mellowmoon-Scaredman Complex Figure 2.1. Douglas County Soil Conservation Service soil map. 16 Hinkle Creek Experimental Forest # # # # # # # Y # # # # Y # Y # # # # Y # # # # # # Y # # Y # # # ## Y # # Y # Y # Y ## Y # # # Y # Legend View1 Y # Grab Sample Points # Soil Pits Roads Streams Clear Cuts Figure 2.2 Soil pit and water sampling locations. 17 Analysis methods All statistical analyses were done using S-PLUS v. 7.0.2 statistical software (Insightful Corporation, 2005) and Microsoft Office Excel 2003 sp2 (Microsoft, 2003). All samples were analyzed by the Central Analytical Laboratory located at the Department of Crop and Soil Science, Oregon State University. Carbon, N and S values were reported as the percentage of sample. Phosphorus was reported in ppm, and K, Ca, Mg, Na and CEC were reported in meq 100g-1. Base saturation was reported in % (sum cations/CEC x 100). Carbon, N, S, and P were converted to kg ha-1 and K, Ca, Mg, and Na were converted to exchangeable kg ha-1. Cation exchange capacity was converted to cmolc kg-1. Bulk density of both the coarse and fines was reported in g cm-3 for all depths. Carbon, N and S were converted to kg ha-1 by first converting the % to g cm-3 using the bulk density of the fines and then multiplying by the number of cm3 in a hectare, including depth. Phosphorus was converted from ppm to % and then calculated on a kg ha-1 basis in the same way as for C, N and S. The equivalent weight of a cation is equal to its atomic weight in grams divided by the valence. A milliequivalent is 1/1000 of an equivalent, thus K, Ca, Mg, and Na were converted to exchangeable kg ha-1 by first converting meq 100g-1 to mg 100g-1 and following the same procedures as outlined above for the other nutrients. The soil pit description’s coarse fragment % of the different depths also was multiplied by the total nutrient pool of the fines to report the kg ha-1 (Hodges, 2003). 18 All calculations on the different soils were conducted separately for each pit and for each depth. The soil series of the same type were then placed together and the means and S.E. of the different depths for both bulk density and nutrients were calculated. Results and Discussion Soil mapping accuracy Soil mapping tends to be a qualitative endeavor. Accuracy is strived for, but to capture properly even a small watershed’s variability is an enormous undertaking. Soil maps are created by soil scientists by digging a few pits in a given region, describing those pits in detail: soil color, depth, boundary, texture, structure, consistency and coarse fragment percentage. They also keep records of slope, physiography, aspect, elevation, bedrock, vegetation and parent material (Johnson et al., 1994; Schoenberger et al., 2002). The researchers then can predict similar soils occurring on similar landscapes and map them as such. The soils series have built into their descriptions enormous variability to incorporate the heterogeneity of any landscape. Dr. Joel A. Norgren has been mapping soils all over the world for 40+ years and was enlisted to check on the existing soil maps’ accuracy. He was quoted as saying, “All soil maps are only as good as the researcher who did the field work and described the series.” Inaccuracies are commonplace in mapping and are well known to the soil science community. Over the course of summer, 2003, we concluded that the researchers who had mapped the Hinkle Creek Watershed basin did a very good job of describing the soils present. The boundaries they had used were very close to the ones we described, 19 and creating a new map was judged to be not worth the effort involved since an accurate one already existed. The twenty-seven soil pits covering the eight main soil series located in the drainage were very similar to the descriptions published in the Soil Survey of Douglas County (Johnson et al., 1994). Soil pit descriptions (Appendix Tables A1.1 – A1.5) for horizon, consistency, structure, texture, and boundary follow methodology and standards given by Schoenberger et al. (2002). Only moist values and chroma were recorded from the 27 pits. The detailed soil pit descriptions are given in Appendix Tables A2.1-A2.27. The Orford Series typically has a depth to bedrock of 150 cm or more and has a hue of 10YR or 7.5YR. The A horizon has a value of 2 to 4 moist and a chroma of 2 to 4 moist or dry. It is gravelly loam or gravelly silt loam. The B horizon has a value of 3 to 5 moist and a chroma of 4 to 6 moist or dry. It is clay, silty clay, silty clay loam, or clay loam. The BC and C horizons have values of 4 to 6 moist and 4 to 8 moist or dry. They are the same as for the B horizon, with the addition of gravelly silty clay or gravelly silty clay loam. Sixty percent of the pedon may be rock fragments (Appendix Tables A2.1, A2.4, A2.5, A2.6, A2.8, A2.9, A2.10, A2.13, and A2.21) (Johnson et al., 1994). The nine pits dug in areas mapped as Orford matched the description well, with some exceptions, but contrasting inclusions of different soils are always present, and as much as 15% of Orford may be inclusions and still qualify (Johnson et al., 1994). The Klickitat-Harrington is a complex of two series, and thus has different descriptions. The Klickitat Series is usually 50% and the Harrington around 40%, with 10% contrasting inclusions. Klickitat has a depth to bedrock of 150 cm or more and the profile has a hue of 10YR, 7.5YR, or 5YR. The A horizon has a value of 2 to moist and a 20 chroma of 2 to 3 moist. It is 60 to 75% rock fragments. The B horizon has a value of 3 to 4 moist and a chroma of 3 to 6 moist. It is very gravelly loam or very cobbly loam and is 35 to 60% rock fragments (Johnson et al., 1994). The Harrington Series has a depth to bedrock of 50-100 cm. The A horizon has a hue of 10YR, 7.5YR, or 5YR, a value of 2 to 3 moist and a chroma of 2 to 3 moist. It is 35 to 60% rock fragments. The B horizon has a hue of 7.5YR, 5YR, or 2.5YR and a value of 3 to 4 moist, and a chroma of 2 to 6 moist or dry. Both A and B horizons are very gravelly clay loam, extremely gravelly loam, or very cobbly loam, and the B horizon can approach 80% rock fragments (Appendix Tables A2.11, A2.19, A2.20, A2.22, A2.24, A2.25, and A2.26) (Johnson et al., 1994). The seven pits matched very well with the descriptions. The Honeygrove Gravelly Loam Series is made up of possibly 25% contrasting inclusions and a depth to bedrock of 150 cm or more. The A horizon has a hue of 5YR or 7.5YR, a value of 2 to 3 moist and a chroma of 2 to 4 moist or dry. The B horizon has a hue of 2.5YR or 5YR, a value of 3 to 4 moist and a chroma of 4 to 6 moist or dry. The horizon is silty clay, clay, or gravelly clay (Appendix Tables A2.14, A2.15, and A2.27) (Johnson et al., 1994). The three pits described matched the descriptions well. The Illahee-Mellowmoon-Scaredman Complex consists of 35% Illahee, 30% Mellowmoon, and 25% Scaredman with 10% contrasting inclusions. The Illahee Series has a depth to bedrock of 150 cm or more and a hue of 10YR or 7.5YR. The A horizon has a value of 2 to 3 moist and a chroma of 1 to 2 moist. It is 35 to 60% rock fragments. The B horizon has a value of 3 or 4 moist and a chroma of 2 to 6 moist. It is very gravelly loam, very cobbly loam, or extremely gravelly loam and is 35 to 70% rock fragments. The Mellowmoon Series has a depth to bedrock of 150 cm or more and a hue 21 of 10YR or 7.5YR. The A horizon has a value of 2 or 3 moist and a chroma of 2 or 3. The B and C horizons have a value of 3 to 6 moist and a chroma of 3 to 6 moist. They are clay loam, gravelly clay loam, gravelly loam, or loam. The Scaredman Series has a depth to bedrock of 50 to 100 cm and a hue of 10YR or 7.5YR. The A horizon has a value of 2 or 3 moist and a chroma of 2 or 3 moist or dry and is 60 to 75% rock fragments. The B horizon has a value of 3 or 4 moist and a chroma of 2 to 4 moist or dry. It is very gravelly loam or very cobbly loam and is 35 to 69% rock fragments (Appendix Tables A2.16 and A2.17) (Johnson et al., 1994). The two pits described fit the description well. The Illahee Rock Outcrop Series’ only difference is that it consists of 50% Illahee, 25% rock outcrop, and 25% contrasting inclusions (Appendix Tables A2.2 and A2.23) (Johnson et al., 1994). The two pits described fit the description well. The Kinney-Harrington Complex consists of 50% Kinney and 40% Harrington with 10% contrasting inclusions. The Kinney Series has a depth to bedrock of 100 to 150 cm. The A horizon has a hue of 10YR or 7.5YR, a value of 2 or 3 moist and a chroma of 2 to 4 moist or dry. The B horizon has a hue of 10YR, 7.5YR, or 5YR, a value of 3 to 5 moist, and a chroma of 3 to 6 moist or dry. It is loam, gravelly loam, gravelly clay loam, or clay loam. The Harrington series is described above. (Appendix Tables A2.3 and A2.7) (Johnson et al., 1994). The two pits described fit well within the description parameters. The Lempira Gravelly Loam Series can have up to 25% contrasting inclusions. The depth to bedrock is 150 cm or more and it has a hue of 10YR or 7.5YR. The A horizon has a value of 2 or 3 moist and a chroma of 2 moist. The B horizon has a value 22 of 3 or 4 moist and a chroma of 3 or 4 moist or dry. It is gravelly loam, cobbly loam, or clay loam (Appendix Table A2.12) (Johnson et al., 1994). The description is somewhat different and may be an inclusion. The Klickitat-Kinney Complex has its series described above and consists of 45% Klickitat, 35% Kinney and 20% contrasting inclusions (Appendix Table A2.18). The pit seems to fall somewhere in between Klickitat and Kinney and may be an inclusion. Soil bulk density The bulk density of forest soils in the Pacific Northwest is usually low (< 1.00 gm cm-3) and has a high infiltration capacity (McNabb et al., 1986; Heniger et al., 2002). Bulk density data reported for the majority of soil projects classifies fines as the < 2mm portion (McNabb et al., 1986; Heniger et al., 2002), to name just two examples. The Hinkle Creek samples are a little higher than the bulk density reported in other Pacific Northwest studies, but not significantly, and may be due to including the < 4mm fraction (Tables 2.10, 2.11, 2.12, and 2.13) (McNabb et al., 1986; Heniger et al., 2002). The sliding hammer method also has been shown to increase bulk density slightly (PageDumroese et al., 1999; Harrison et al., 2003). The bulk density of the 0 -15 cm cohort ranged from 0.81 – 1.08 gm cm-3 total and 0.30 – 0.77 gm cm-3 for the fines (Table 2.10). The 15 – 30 cm cohort ranged from 0.82 – 1.22 gm cm-3 total and 0.26 – 0.92 gm cm-3 fines (Table 2.11). The 30 – 60 cm cohort ranged from 0.94 – 1.23 gm cm-3 total and 0.33 – 0.98 gm cm-3 fines (Table 2.12). The mean bulk density of 0 – 60 cm is shown in Table 2.13. The bulk density tended to increase with depth as expected. 23 Soil chemistry Estimates of the total C, N, S and P pools in kg ha-1 have been completed and are shown in Tables 2.1, 2.3 and 2.5. Results for total amounts of exchangeable cations (K, Ca, Mg, and Na) also are given in Tables 2.1, 2.3 and 2.5. Element ratios (C/N, N/S, N/P), pH, CEC and base saturation are given in Tables 2.2, 2.4 and 2.6. The total percentage concentration of soil C, N and S, and the exchangeable cations in mg kg-1 data from the soil pits dug in the different soil series is shown in Tables 2.7, 2.8 and 2.9. Soil results for the Hinkle Creek watershed basin show that most of the watershed basin area has soils that are likely to be N limited for tree production, when compared to soils in the Oregon Coast Range (Cromack et al., 1999; Rothe et al., 2002; Perakis et al., 2006). The soils also are lower in N than those measured in watershed 10 at the H.J. Andrews Experimental Forest (Henderson et al., 1978). The K and Ca availability are lower than for soils in watershed 10 (Henderson et al., 1978). The C/N ratios are relatively high, but fall within the range of typical forest soils in the Northwest and may reinforce the possibility of N limitation for forest productivity at Hinkle Creek (Sollins et al., 1980). The total C was present in similar to slightly lower concentrations than in the six soil types studied by McNabb et al. (1986), while total N was present in much lower concentrations. The CEC and base saturation of the soils are typical for forests located in the Oregon and Washington Cascades. The very deep, weathered volcanic soils of the Hinkle Creek basin are high in base cations and the data reflect this. Soil concentrations for total N and total S for several of the Hinkle Creek soils were below the range of concentrations of these elements reported for many other soils (Stevenson and Cole, 1999). The total mean P concentration (0.109%) was substantially 24 higher than the upper range of P (0.05 – 0.08%) reported for many other soils (Stevenson and Cole, 1999). The mean N concentration in the 0-15 cm soil depth for all soil types represented in the Hinkle Creek Watershed was 0.167% N (SE = 0.02) (Table 2.7). This was near the low end of the range (0.02-1.06% N) reported for cool, temperate soils by Stevenson and Cole (1999). The average N content for the 0-15 cm soil depth in the Hinkle Creek basin was 919.2 kg ha-1 (SE = 212.2), which was 28% of the mean for the 0-15 cm depth for the 8 major soil types reported by Stevenson and Cole (1999). Total S concentrations averaged 0.0117% (S.E. = 0.0017), which was near the low end of the range of 0.01-0.05% total S reported by Stevenson and Cole (1999). The soil nutrient data reflect the effects of including the < 4 mm size fraction in the soil nutrient pool estimates. This approach is becoming more common in current forest soils research (Cromack et al., 1999; Homann et al., 2001, 2004). It is becoming more widely accepted that substantial amounts of forest soil nutrients, such as C, N, P, S, base cations, and micronutrients are contained within the coarse soil fraction (Cromack et al., 1999; Homann et al., 2004). These nutrient reserves are transferred gradually over time into the fine soil fraction by chemical and physical weathering processes, together with biological and biochemical processes occurring during soil structure permeation by tree roots, mycorrhizal fungi, bacteria and soil animals (Spycher et al., 1986; Cromack et al., 1988; Entry et al., 1992; Amaranthus and Perry, 1994; Coleman et al., 2004). Future management activities such as clearcutting, vegetation management, and forest fertilization will influence soil nutrient availability, soil nutrient capital, and soil organic matter reserves (Schoenholtz et al., 2000; Fisher and Binkley, 2000; Fox, 2000; Yildiz, 2000; Yildiz and Eşen, 2006). Table 2.1 Soil series comparisons at 0-15 cm depth for amounts of soil nutrients (< 4 mm size fraction). Soil Series (0-15 cm depth) a No. of Soil Pits C S N P K Ca Mg Na ‹---------------------Total----------------------› ‹------------------Exchangeable--------------› ‹--------------------------------------------------kg ha-1------------------------------------------------› 23990 82 1010 964 179 968 461 21 3466a 9 143 250 26 262 324 3 Orford Gravelly Loam 9 Klickitat – Harrington 4 19266 5355 46 11 827 152 416 120 167 72 905 407 118 56 13 2 Honeygrove Gravelly Loam 3 24880 7722 72 39 1079 270 462 79 181 41 627 201 135 58 18 3 Illahee-MellowmoonScaredman Complex 2 29326 10241 77 31 1062 337 634 192 182 59 577 224 115 62 11 3 Illahee Rock Outcrop 2 10236 6723 45 25 475 351 317 173 75 2 520 60 92 8 19 4 Kinney-Harrington Complex 1 12573 22 341 252 25 172 17 3 Lempira Gravelly Loam 1 46043 162 2194 1515 304 839 117 20 Klickitat-Kinney Complex Italics denote S.E. 1 8676 17 366 174 172 670 102 9 25 Table 2.2 Soil series comparisons at 0-15 cm depth for nutrient element ratios, cation exchange capacity (CEC) and % base saturation. Soil Series (0-15 cm depth) Orford Gravelly Loam a No. of Soil Pits 9 C/N 23.8 1.1a N/S 12.9 1.8 N/P 1.3 0.2 pH 5.0 0.1 CEC (cmolc kg-1) 33.8 2.5 % Base Saturation 23.0 5.0 Klickitat - Harrington 4 23.7 4.7 20.3 4.6 2.3 0.5 5.7 0.1 28.3 5.7 32.8 4.5 Honeygrove Gravelly Loam 3 22.8 1.4 15.9 6.5 2.3 0.2 5.4 0.0 26.6 5.5 21.9 4.8 Illahee-Mellowmoon-Scaredman Complex 2 27.3 1.0 14.3 1.4 1.7 0.0 5.5 0.3 36.4 4.2 25.0 0.3 Illahee Rock Outcrop 2 24.4 3.9 9.1 2.8 1.3 0.4 5.2 0.2 33.2 3.2 26.4 7.3 Kinney-Harrington Complex 1 36.9 15.4 1.4 5.7 37.2 22.7 Lempira Gravelly Loam 1 21.0 13.6 1.4 5.1 36.6 16.9 Klickitat-Kinney Complex Italics denote S.E. 1 23.7 21.6 2.1 5.5 40.9 33.7 26 Table 2.3 Soil series comparisons at 15-30 cm depth for amounts of soil nutrients (< 4 mm size fraction). Soil Series (15-30 cm depth) No. of Soil Pits C S N P K Ca Mg Na ‹---------------------Total-----------------------› ‹-----------------Exchangeable-----------------› ‹-------------------------------------------------kg ha-1---------------------------------------------------› 21448 97 924 763 172 1085 564 33 6182a 14 205 184 20 312 376 3 Orford Gravelly Loam 9 Klickitat-Harrington 4 15538 2071 59 16 799 128 484 117 222 104 1404 669 231 122 37 9 Honeygrove Gravelly Loam 3 14105 3456 62 5 690 183 513 19 125 7 487 206 148 36 47 11 Illahee-MellowmoonScaredman Complex 2 28162 2294 66 18 1127 129 699 38 181 4 662 232 147 93 31 11 Illahee Rock Outcrop 2 6350 3766 25 1 302 240 219 22 88 6 1141 88 226 58 31 5 Kinney-Harrington Complex 1 5601 15 207 189 30 104 12 3 Lempira Gravelly Loam 1 50987 175 2193 1561 271 834 107 27 1 18819 35 824 387 217 1348 208 29 Klickitat-Kinney Complex a Italics denote S.E. 27 Table 2.4 Soil series comparisons at 15-30 cm depth for nutrient element ratios, cation exchange capacity (CEC) and % base saturation. Soil Series (15-30 cm depth) Orford Gravelly Loam a No. of Soil Pits 9 C/N 22.2 1.8a N/S 11.8 3.3 N/P 1.4 0.2 pH 5.0 0.1 CEC (cmolc kg-1) 34.2 2.6 % Base Saturation 22.6 5.6 Klickitat-Harrington 4 21.1 4.5 15.3 2.4 1.8 0.3 5.5 0.1 26.2 4.2 33.2 7.6 Honeygrove Gravelly Loam 3 20.6 1.4 11.0 2.3 1.3 0.3 4.9 0.2 26.1 6.5 13.9 3.3 Illahee-Mellowmoon-Scaredman Complex 2 25.1 0.8 19.1 7.3 1.6 0.3 5.2 0.3 35.3 4.9 18.4 0.4 Illahee Rock Outcrop 2 30.0 11.4 12.4 10.0 1.3 1.0 5.3 0.1 37.0 1.8 42.7 5.4 Kinney-Harrington Complex 1 27.1 13.5 1.1 5.6 35.0 18.3 Lempira Gravelly Loam 1 23.3 12.5 1.4 5.2 37.3 15.7 Klickitat-Kinney Complex Italics denote S.E. 1 22.8 23.7 2.1 5.4 43.5 30.3 28 Table 2.5 Soil series comparisons at 0-30 cm depth for all nutrients except C, S, and N, which are at 0–60 cm (< 4 mm size fraction). Soil Series No. of Soil Pits C S N P K Ca Mg Na ‹----------------------Total----------------------› ‹-------------------Exchangeable---------------› ‹--------------------------------------------------kg ha-1-------------------------------------------------› 72629 348 3171 1727 351 2053 1024 55 10858a 22 440 423 42 534 699 5 Orford Gravelly Loam 9 Klickitat – Harrington 4 51168 14179 155 28 2341 539 900 473 389 175 2308 1074 350 177 50 11 Honeygrove Gravelly Loam 3 64152 20110 457 96 2813 692 975 80 306 44 1114 340 283 75 65 8 Illahee-MellowmoonScaredman Complex 2 90013 17772 220 39 3400 602 1332 154 363 63 1240 455 262 155 42 14 Illahee Rock Outcrop 2 27135 12865 140 26 1286 841 536 195 163 4 1661 148 318 66 50 1 Kinney-Harrington Complex 1 29420 72 1025 441 55 276 29 7 Lempira Gravelly Loam 1 157282 617 7472 3076 576 1673 224 48 Klickitat-Kinney Complex Italics denote S.E. 1 52964 112 2108 561 388 2018 310 38 a 29 Table 2.6 Soil series comparisons at 0-30 cm depth for nutrient element ratios, cation exchange capacity (CEC) and % base saturation. Soil Series (0-30 cm depth) Orford Gravelly Loam a No. of Soil Pits 9 C/N 22.4 1.0a N/S 10.8 1.8 N/P 2.3 0.4 pH 5.0 0.1 CEC (cmolc kg-1) 34.0 2.5 % Base Saturation 22.8 5.1 Klickitat - Harrington 4 22.2 4.5 16.3 2.4 2.6 0.2 5.6 0.1 27.3 4.9 33.0 6.0 Honeygrove Gravelly Loam 3 22.2 1.9 15.9 6.5 2.8 0.5 5.0 0.2 26.4 5.8 17.9 3.6 Illahee-Mellowmoon-Scaredman Complex 2 26.4 0.5 16.9 0.6 2.5 0.2 5.3 0.3 35.9 4.5 21.7 0.1 Illahee Rock Outcrop 2 26.2 7.5 9.5 5.4 2.1 0.8 5.3 0.1 35.1 2.5 34.6 6.4 Kinney-Harrington Complex 1 29.2 14.3 2.3 5.7 36.1 20.5 Lempira Gravelly Loam 1 21.3 12.4 2.4 5.1 37.0 16.3 Klickitat-Kinney Complex Italics denote S.E. 1 24.8 20.2 3.8 5.4 42.2 32.0 30 Table 2.7 Soil series comparisons at 0-15 cm depth for concentrations of soil nutrients (< 4 mm size fraction). Soil Series (0-15 cm depth) a No. of Soil Pits C S N P ‹---------------------Total---------------------------› ‹-----------------------%-----------------------------› 2.66 0.009 0.11 0.11 0.5a 0.001 0.02 0.03 K Ca Mg Na ‹-------------------Exchangeable--------------› ‹-----------------------mg kg-1------------------› 183 920 360 20.7 26 180 216 2.3 Orford Gravelly Loam 9 Klickitat - Harrington 4 3.91 0.8 0.011 0.004 0.17 0.02 0.08 0.01 288 86 1500 400 192 72 27.6 4.6 Honeygrove Gravelly Loam 3 2.92 0.4 0.008 0.003 0.13 0.01 0.06 0.00 225 21 780 260 136 60 2.3 4.6 Illahee-MellowmoonScaredman Complex 2 6.22 0.2 0.016 0.001 0.23 0.00 0.14 0.00 399 9 1220 100 228 60 25.3 2.3 Illahee Rock Outcrop 2 2.25 1.4 0.010 0.005 0.10 0.07 0.08 0.04 174 33 1220 240 216 36 43.7 6.9 Kinney-Harrington Complex 1 9.96 0.018 0.27 0.200 177 1360 132 27.6 Lempira Gravelly Loam 1 4.72 0.017 0.22 0.155 293 860 120 20.7 Klickitat-Kinney Complex Italics denote S.E. 1 2.56 0.005 0.11 0.051 523 1980 300 27.6 31 Table 2.8 Soil series comparisons at 15-30 cm depth for concentrations of soil nutrients (< 4 mm size fraction). Soil Series (15-30 cm depth) No. of Soil Pits C S N P ‹---------------------Total----------------------› ‹------------------------%-----------------------› 1.96 0.009 0.08 0.07 0.001 0.02 0.02 0.56a K Ca Mg Na ‹----------------------Exchangeable-------------------› ‹--------------------------mg kg-1-----------------------› 158 900 408 27.6 29 220 252 2.3 Orford Gravelly Loam 9 Klickitat - Harrington 4 2.23 0.39 0.010 0.005 0.12 0.03 0.06 0.01 219 74 1420 460 216 84 48.3 2.3 Honeygrove Gravelly Loam 3 1.13 0.24 0.005 0.000 0.05 0.01 0.04 0.00 106 19 400 180 120 36 36.8 6.9 Illahee-MellowmoonScaredman Complex 2 3.99 0.79 0.010 0.005 0.16 0.02 0.10 0.03 255 49 860 100 180 84 39.1 4.6 Illahee Rock Outcrop 2 1.29 0.80 0.005 0.000 0.06 0.05 0.05 0.01 178 33 2260 80 444 96 62.1 6.9 Kinney-Harrington Complex 1 6.26 0.014 0.21 0.171 268 940 108 27.6 Lempira Gravelly Loam 1 5.13 0.018 0.22 0.157 259 840 108 27.6 Klickitat-Kinney Complex Italics denote S.E. 1 2.71 0.005 0.12 0.056 329 1940 300 41.4 a 32 Table 2.9 Soil series comparisons at 0-30 cm depth for concentrations of soil nutrients (< 4 mm size fraction). Soil Series (0-30 cm depth) a No. of Soil Pits C S N P ‹--------------------Total---------------------› ‹----------------------%-----------------------› 1.92 0.008 0.08 0.09 0.001 0.01 0.03 0.32a K Ca Mg Na ‹----------------Exchangeable--------------› ‹--------------------mg kg-1------------------› 171 912 386 25.3 26 180 228 2.3 Orford Gravelly Loam 9 Klickitat - Harrington 4 2.73 0.44 0.010 0.004 0.13 0.03 0.07 0.01 253 79 1456 420 204 84 39.1 4.6 Honeygrove Gravelly Loam 3 1.67 0.29 0.009 0.002 0.08 0.01 0.05 0.00 166 10 588 220 140 48 29.9 4.6 Illahee-MellowmoonScaredman Complex 2 4.2 0.4 0.010 0.001 0.2 0.0 0.1 0.0 327 20 1040 80 240 72 23 2.3 Illahee Rock Outcrop 2 1.43 0.77 0.007 0.002 0.07 0.05 0.06 0.03 176 0 1440 160 330 72 52.9 2.3 Kinney-Harrington Complex 1 6.7 0.015 0.22 0.185 223 1160 120 27.6 Lempira Gravelly Loam 1 4.2 0.015 0.19 0.156 276 860 120 27.6 Klickitat-Kinney Complex Italics denote S.E. 1 2.5 0.005 0.10 0.054 426 1960 300 34.5 33 34 Table 2.10 Soil series comparisons at 0-15 cm depth (< 4 mm size fraction). Bulk Density of Fine Soil Total Bulk CoarseSoil Densitya Fractiona Fractiona Soil Series -3 (0-15 cm depth) ‹-------------g cm --------------› % 0.92 0.76 14 Orford Gravelly Loam 0.04 0.06 3 a Klickitat - Harrington 1.10 0.11 0.62 0.07 45 8 Honeygrove Gravelly Loam 0.70 0.08 0.61 0.09 13 6 Illahee-MellowmoonScaredman Complex 0.97 0.07 0.42 0.07 29 16 Illahee Rock Outcrop 0.94 0.13 0.52 0.01 35 5 Kinney-Harrington Complex 1.08 * 0.30 * 73 7 Lempira Gravelly Loam 0.81 0.77 15 Klickitat-Kinney Complex 0.94 0.41 45 Values shown are means, with S.E. in italics. 35 Table 2.11 Soil series comparisons at 15-30 cm depth (< 4 mm size fraction). Bulk Density Total Bulk Coarse Soil of Fine Soil Fractiona Soil Series Densitya Fractiona -3 (15-30 cm depth) ‹-------------g cm ------------› % 1.00 0.92 11 Orford Gravelly Loam 0.06 0.08 3 a Klickitat - Harrington 1.22 0.07 0.92 0.08 46 7 Honeygrove Gravelly Loam 1.04 0.17 0.94 0.13 12 7 Illahee-MellowmoonScaredman Complex 1.01 0.05 0.69 0.06 29 16 Illahee Rock Outcrop 1.09 0.16 0.61 0.09 39 2 Kinney-Harrington Complex 1.04 * 0.26 * 76 3 Lempira Gravelly Loam 0.82 0.78 15 Klickitat-Kinney Complex 0.98 0.84 45 Values shown are means, with S.E. in italics. 36 Table 2.12 Soil series comparisons at 30-60 cm depth (< 4 mm size fraction). Bulk Density Total Bulk Coarse Soil of Fine Soil Soil Series Densitya Fractiona Fractiona -3 (30-60 cm depth) ‹-----------g cm ------------› % 1.03 0.92 10 Orford Gravelly Loam 0.04 0.05 4 a Klickitat - Harrington 1.17 0.03 0.66 0.11 49 8 Honeygrove Gravelly Loam 1.03 0.21 0.98 0.22 4 3 Illahee-MellowmoonScaredman Complex 1.00 0.04 0.68 0.13 23 23 Illahee Rock Outcrop 1.23 0.05 0.84 0.06 49 12 Kinney-Harrington Complex 1.35 * 0.33 * 76 3 Lempira Gravelly Loam 0.94 0.90 15 Klickitat-Kinney Complex 1.00 0.73 45 Values shown are means, with S.E. in italics. 37 Table 2.13 Soil series comparisons at 0-60 cm depth (< 4 mm size fraction). Bulk Density of Fine Soil Total Bulk Coarse Soil Densitya Fractiona Fractiona Soil Series -3 (0-60 cm depth) ‹------------g cm ------------› % 0.98 0.87 12 Orford Gravelly Loam 0.03 0.04 2 Klickitat - Harrington 1.16 0.05 0.74 0.06 47 4 Honeygrove Gravelly Loam 0.92 0.10 0.84 0.10 10 3 Illahee-MellowmoonScaredman Complex 0.99 0.03 0.60 0.07 27 7 Illahee Rock Outcrop 1.08 0.08 0.66 0.07 41 10 Kinney-Harrington Complex 1.16 0.07 0.30 0.03 76 2 Lempira Gravelly Loam 0.90 0.06 0.86 0.06 15 0 0.76 0.14 45 0 0.96 0.06 a Values shown are means, with S.E. in italics. Klickitat-Kinney Complex 38 Chapter 3: Stream Chemistry of the Hinkle Creek Watershed Research and Demonstration Area Project Introduction The importance of studying stream chemistry as a tool for understanding forest management impacts upon watersheds is well documented in the literature (Brown et al., 1973; Martin and Harr, 1989; Binkley and Brown, 1993; Vanderbilt et al., 2002; Dahlgren, 1998). The role of streams in nutrient cycling and export is functionally linked to the forest through which they flow. A disturbance to the forest will change the nutrient export in some fashion; some nutrients may increase, while others decrease, until a state of dynamic equilibrium is reached at some time in the future. Modern industrial forestry practices disturb the forest-stream interaction. The temporal patterns and magnitude of these disturbances to stream chemistry are not well known in managed stands located on private land. There has been much research done on the effects of converting old-growth forests to managed stands (Brown et al., 1973; Sollins et al., 1980; Keppeler and Ziemer, 1990; Binkley and Brown, 1993; Grant and Wolff, 1991; Ziemer, 1998; Thomas and Megahan, 1998; Beschta et al., 2000). There has been little research focused on the effects of modern industrial forestry with faster rotation cycles on stream nutrient budgets in the Pacific Northwest. The goal of this study was to construct baseline stream chemistry data for eight watersheds in the Hinkle Creek basin prior to the initiation of intensive forest management treatments. Hydrologic data provided by Nicholas P. Zegre were compiled, and monthly export budgets were created for the different nutrients. 39 Methods Research design This study used a paired watershed design that previously had been determined to be part of the overall larger study occurring at the Hinkle Creek Watershed Research and Demonstration Area Project (Figure 1.1). The treatment and control watersheds placement and treatment timetables were in place prior to the initiation of my research. Water chemistry samples were taken from the same location every time to ensure no co-founding variables were introduced from slight location changes. The sample sites corresponded with locations where gauging stations were constructed. The gauging stations measured stream discharge and temperature, and provided invaluable data to incorporate with the present study’s stream chemistry concentrations that permitted construction of a monthly nutrient outflow. They were convenient, stable locations to ensure that no heterogeneity was introduced into the sampling procedures. In addition to the eight gauging station locations, three other stream sampling points were chosen below clearcuts at road crossings to ascertain if any changes in stream chemistry could be forecast for future treatments. Sampling methods The water samples were obtained for this study using a grab sample methodology employed by the Environmental Protection Agency and the sample always was collected upstream from the researcher. The one-liter bottles were rinsed three times prior to filling the bottle on the 4th grab. The sample was collected from the center of the current or thalwag and care was taken to minimize sediment disruption. 40 Samples were transported on ice in coolers within the same day to the Oregon State University Co-operative Chemical Analytical Laboratory. Portable coolers were then placed in a walk-in refrigerator overnight. Total N and P were analyzed within 24 hr of the sample collection. The other nutrients generally were analyzed within the same week. These protocols were followed for the duration of the study. The samples were collected monthly for the first year of the study and seasonally thereafter. Stream nutrients measured included: total N, P, and base cations (Ca, K, Mg, and Na), dissolved organic N (DON), and inorganic N (NO3-N, NH4-N), stream pH, SO4, HCO3, Cl, and Si. Table 3.1 shows the detection levels, Table 3.2 the methodology, and Table 3.3 the instrumentation used by the Co-operative Chemical Analytical Laboratory (CCAL). Analysis methods All statistical analyses were done using S-PLUS v. 7.0.2 statistical software (Insightful Corporation, 2005) and Microsoft Office Excel 2003 sp2 (Microsoft, 2003). For most of the first year of the study, only stream concentration data were collected, due to the unexpected delay in gauging station construction. Precipitation data and downstream tributary discharge data were searched for, but no viable records were found to produce an estimate through regression of the 1st year’s hydrological data. The hydrological data used to construct monthly budgets collected from the gauging stations were provided and vetted for quality control by Nicolas Zegre, the head research assistant at Hinkle Creek for the duration of this study. Hydrological monitoring was conducted at eight locations throughout the Hinkle Creek Watershed. Six headwater locations were gauged (2 control watersheds, 4 treatment watersheds) (Figure 3.1) while 41 both the North and South Forks of Hinkle Creek were gauged directly upstream from their confluence. The turbidity threshold sampling system (TTS) was used to orchestrate hydrology sampling. Monitoring stations were equipped with Campbell Scientific, Inc. CR10x data loggers that controlled the entire sampling regime. Hydrologic data were collected at 10-minute intervals at the headwater locations and 30-minute intervals at the two confluence locations. This was reported as daily means by the USGS at the confluence locations. Water level heights and discharge measurements at all locations were measured using the combination of Druck PDCR 1830 pressure transducers with Montana flumes at headwater locations, while discharge was calculated at the North and South Forks by stage discharge relationships developed by the USGS. Stream turbidity was measured by D&A OBS-3 Turbimeters and suspended sediment concentrations were sampled by ISCO 3700-c portable water sampling systems. The data were used to construct mean monthly flow estimates and the nutrient concentrations were multiplied by this to produce kg month-1 and kg ha-1 month-1 outflow. All nutrients measured were reported in mg L-1 and hydrological data were reported in L sec-1. The hydrological data were collected and the 10 minute and daily mean flows were used to create monthly means and S.E. This produced a mean L sec-1 month-1 estimate from which total L month-1 was calculated. This value was multiplied by the concentration data in mg L-1 and converted to kg month-1 outflow. This rate was converted to kg ha-1 month-1 outflow by dividing kg month-1 by the size of the watershed. Statistical T-tests and F-tests were done to compare Beeby Creek with the other streams to determine if having a portion of the watershed clearcut may produce changes in N export (Steel et al., 1997). These tests only were used on data collected prior to the 42 basin-wide N fertilization which occurred in late October, 2004. Clay Creek also had a T-test applied to samples collected above and directly below a clearcut prior to urea N fertilization. Pre-fertilization data were compared to post-fertilization data for N, using an F-test for all streams. These statistical comparisons were preliminary, and need further testing, using statistical methods involving time series (Ramsey and Schafer, 2002). Fertilization results were compared for stream N concentrations for individual sampling dates after urea N fertilization in the fall of 2004. The post-fertilization stream samples were collected on January 25, 2005 and on May 25, 2005. Results for total dissolved N, dissolved organic N, NO3-N + NO2-N, and NH4-N were compared using two sample T-tests (Ramsey and Schafer, 2002). 43 Table 3.1. Levels of detection and precision for CCAL analyses. Analysis Level of detection Precision@ 0.2 mg/1 +/- 0.02 mg/l1 0.010 mg/l2 +/- 0.002 mg/l 0.06 mg/1 +/- 0.065 mg/l3 0.1 mg/l +/- 0.1 mg/l 0.02 mg/1 +/- 0.085 mg/l 0.001 mg/1 +/- 0.0006 mg/l3 0.001 mg/12 +/- 0.001 mg/l 4 0.01 mg/1 +/- 0.006 mg/1 Nitrogen, total Kjeldahl 3 0.001 mg/1 +/- 0.001 mg/l Phosphate, ortho 3 0.001 mg/1 +/- 0.002 mg/l Phosphorus, total 0 – 14 pH units +/- 0.1 pH unit5 pH 0.03 mg/1 +/- 0.015 mg/l3 Potassium 0.20 mg/12 +/- 0.05 mg/l Silica 0.01 mg/1 +/- 0.005 mg/l3 Sodium 0.4 us/cm +/- 2%5 Specific conductance 0.01 mg/1 +/- 0.025 mg/l Sulfate @ • Precision evaluated by repeated analysis of near detection level standard solutions. 1 • Titration precision and accuracy evaluated by comparison with Gran titration results. 2 • Method specified detection level as yet unconfirmed, but evaluated as reasonable by monitoring sample response at this concentration level. 3 • Evaluated by low concentration detection level analysis. • 4Estimate based on low concentration standards analyzed on a continuing basis. • 5Limitation of instrument scale on instrument currently in use. • *Note that for ammonia-nitrogen, the laboratory has been able to produce data with the same precision as stated above at a detection level of 0.005 mg/l. Alkalinity Ammonia-nitrogen* Calcium Carbon, dissolved organic Chloride Magnesium Nitrate-nitrogen 44 Table 3.2. Analytical methodology for CCAL. Analysis * Alkalinity 403, procedure 4c, titrate to pH 4.5. Modifications: Use 0.02N Na2CO3 and 0.02N H2SO4. 417F. 303A; flame atomic absorption spectroscopy. Modifications: nitrous oxide/acetylene flame. Addition of 1 ml 50,000 mg/1 lanthanum oxide to 10 ml sample to control ionization. 5310B. Ammonia Calcium Carbon, dissolved organic Chloride Specific conductance Magnesium Nitrate Nitrogen, total Kjeldahl pH Phosphate, ortho Phosphorus, total Potassium Silica Sodium Sulfate * Method # with specifications and modifications 4110B. 205; Wheatstone bridge. 303A; flame atomic absorption spectroscopy. 418F. Technicon industrial method 100-70W; different formulations for color and ammonium chloride reagents. Kjeldahl digestion: H2SO4, CuSO4/KCl, Nessler finish. 423; Calomel reference electrode, glass pH electrode, temperature compensator. 424F. Modifications: Ascorbic acid reagent 2g/100 ml. 424C, 424F. Modifications: microwave digestion 60 minutes, 50 ml analysis volume, ascorbic acid reagent 2g/100 ml. 303A; flame atomic absorption spectroscopy. Technicon industrial method 105-71W/B. 303A; flame atomic absorption spectroscopy. 4110B. Method numbers refer to Standard Methods for the Examination of Water and Wastewater 15th Edition, 1980; except sulfate, chloride and dissolved organic carbon Standard Methods for the Examination of Water and Wastewater 17th Edition, 1989. 45 Table 3.3. CCAL analytical instrumentation. Analysis Instrumentation Alkalinity Radiometer type TTT 1c auto-titrator with glass pH electrode, calomel reference electrode and temperature compensator electrode. Technicon Auto-Analyzer II. Varian SpectrAA 220 atomic absorption spectrophotometer. Shimadzu TOC-5000A Ammonia Calcium Carbon, dissolved organic Chloride Specific conductance Magnesium Nitrate Nitrogen, total Kjeldahl pH Phosphate, ortho Phosphorus, total Potassium Silica Sodium Sulfate Dionex 4000i Ion Chromatograph. YSI model 31 conductivity bridge. Varian SpectrAA 220 atomic absorption spectrophotometer. Technicon Auto-Analyzer II. Milton-Roy 601 spectrophotometer with 2.54 cm pathlength cell. Analyze at 425 nm. Radiometer type TTT 1c auto-titrator with glass pH electrode, calomel reference electrode and temperature compensator electrode. Milton-Roy 601 spectrophotometer with 10 cm pathlength. Milton-Roy 601 spectrophotometer with 10 cm pathlength. Varian SpectrAA 220 atomic absorption spectrophotometer. Technicon Auto-Analyzer II. Varian SpectrAA 220 atomic absorption spectrophotometer. Dionex 4000i Ion Chromatograph. 46 Stream Legend and Sampling Locations C-O2 = Myers Creek T-10 = Russell Creek C-O9 = DeMearsman Creek T-12 = Clay Creek T-03 = Fenton Creek T-14 = Beeby Creek T-14B = Beeby Tributary 1 T-14C = Beeby Tributary 2 Figure 3.1. Hinkle Creek Watershed stream sampling locations. 47 Figure 3.2. Hinkle Creek Watershed Oct., 2004 urea fertilizer application area (green). 48 Results and Discussion General water chemistry Tables 3.4 – 3.14 include mean monthly flow rate and water chemistry nutrient output amounts in kg month-1 and kg ha-1 month-1 from October, 2003 – May, 2005 for all the streams located in the Hinkle Creek basin. Concentration data also are given in mg L-1. The mean concentration of all nutrients for streams located in the Hinkle Creek watershed for the water year October, 2002 – October, 2003 is given in Tables 3.15 – 3.16. Tables 3.17 and 3.18 show pH, alkalinity and specific conductance values over the same time period. Table 3.4 has several footnotes that explain headers for this table and subsequent stream chemistry tables. Phosphorus concentrations were lower than those observed for Watershed #10 on the H.J. Andrews LTER for an old-growth Douglas-fir forest that was growing on volcanic derived soils (Table 3.19) (Sollins et al., 1980). The three mid-elevation watersheds studied by Martin and Harr (1989) at the H.J. Andrews LTER have similar total dissolved P concentrations. Phosphorus concentrations were higher at Hinkle Creek than those cited for several Environmental Protection Agency (EPA) ecoregions in the USA (NCASI, 2001; Ice and Binkley, 2003; Binkley et al., 2004). The geologically younger parent material formed from the volcanic rock probably accounts for the higher P levels compared to other ecoregions in the United States which have soils formed from much older, more highly-leached geologic substrates. Phosphate was present in concentrations similar to those in three mid-elevation watersheds on the H.J. Andrews LTER (Martin and Harr, 1989) and in three streams studied in the Alsea River basin in western Oregon (Brown et al., 1973). Total P concentration varied little between all the 49 streams studied, and basins with clearcuts in place prior to the initiation of the study (Table 1.1) showed no significant differences in this nutrient. Anthropogenic inputs of P are significant in many regions of the country, but are probably of minor influence in the Hinkle Creek Watershed. In P deficient regions, geologic input of P by dust can be important (Schlesinger, 1997). Among base cations, Ca was present in higher concentrations than K, Mg or Na, except in Fenton Creek. This differs from streams found in the Salmon River basin in the Oregon Coast Range where Na and Ca share dominance (Compton et al., 2003). Calcium concentrations in the Hinkle Creek streams were higher than in watershed #10 (Sollins et al., 1980) and in the three mid-elevation watersheds studied by Martin and Harr (1989) in the H.J. Andrews LTER. However, Ca concentrations in the present study were similar to those in the Salmon River basin (Compton et al., 2003) (Table 3.22). Sodium concentrations were higher than in the three mid-elevation watersheds at the H.J. Andrews LTER (Martin and Harr, 1989), in watershed #10 (Sollins et al., 1980), and were lower than in most streams in the Salmon River basin (Compton et al., 2003) (Table 3.22). The proximity to the ocean of the Salmon River watersheds may account for the difference. Magnesium concentrations were similar to those in the Salmon River basin (Compton et al., 2003) (Table 3.22) and higher than in the streams studied at the H.J. Andrews LTER (Sollins et al., 1980; Martin and Harr, 1989). Potassium was present in lower concentrations than in the streams studied in the Alsea River basin (Brown et al, 1973) and in concentrations very similar to the three mid-elevation watersheds at the H.J. Andrews LTER (Martin and Harr, 1989), to watershed #10 (Sollins et al., 1980) and to the Salmon River basin (Compton et al., 2003) (Table 3.22). Base cation concentrations 50 are correlated directly with the weathering of parent material located in a watershed, and differences in the geographic locales of the watersheds cited and geologic substrate differences are the most likely sources of variation. Anthropogenic inputs of base cations are of minor importance in all the studies cited. The total output of base cations in kg ha-1 when compared to other experimental watersheds, such as Coweeta Hydrological Laboratory in North Carolina, Walker Branch watershed at the Oak Ridge National Laboratory in eastern Tennessee, and the H.J. Andrews LTER near Blue River, Oregon, as shown in Henderson et al. (1978), would follow the same ratios. Hinkle Creek more closely resembled the H.J. Andrews LTER base cation output. Silica was present in high concentrations in all streams, but lower than in the three mid-elevation watersheds at the H.J. Andrews LTER (Martin and Harr, 1989). Silica is derived almost exclusively from the weathering of silicate rocks, and the soils derived from the weathering of volcanic parent material located at Hinkle Creek are rich in silicate compounds (Table 1.1). Chloride concentration was lower than in the Salmon River basin streams (Compton et al., 2003). This most likely is a result of the Salmon River basin’s proximity to the ocean. The Cl concentrations are very low, overall. High Cl concentrations usually are associated with anthropogenic inputs from road salts and sewage. These are not a factor at Hinkle Creek. Sodium chloride tracer tests have been used in the Hinkle Creek basin, but Cl is a conservative tracer and no tests were ever performed within the same week of sampling. Sulfate concentrations were low compared to values in streams studied by Vitousek (1977) in the northeastern United States. This was to be expected, due to the 51 lack of anthropogenic atmospheric pollution from fossil fuel burning. The SO4-S concentrations also were lower than in many Oregon and Washington coastal streams (Herger and Hayslip, 2000). Alkaline HCO3-C concentrations were average, which is to be expected because of the basin’s volcanic geology. Bicarbonate derives almost entirely from the weathering of carbonate minerals such as limestone. Volcanic geology has little sedimentary rock associated with it. Anthropogenic inputs of lime also were absent. The pH of the streams in the Hinkle Creek basin ranged from 7.3 – 7.7 and stayed well below the Oregon maximum pH standard of 8.5 set by the Oregon Department of Environmental Quality. Samples were taken during extremely low flows in summer months when the highest pH would be expected and the maximum standard never was approached. The pH was much higher than in streams found in the northeastern United States where acid deposition from precipitation is a serious problem (Vitousek, 1977). The pH values were very similar to those for three mid-elevation streams studied by Martin and Harr (1989) and also to values for the watershed #10 stream at the H.J. Andrews LTER (Sollins et al., 1980). Conductivity is a measure of the electrical conductance of water and usually is directly correlated with total dissolved ions. The Hinkle Creek stream data follow this pattern. Hinkle Creek streams had higher specific conductance than the three streams studied by Martin and Harr (1989) in the H.J. Andrews LTER. DeMearsman Creek had the highest concentration of dissolved ions as well as the highest specific conductance. Sediment was low during the dry season and higher during winter flows, as would be expected. There is a broad undertaking of research on sediment yield associated with 52 the Hinkle Creek hydrological studies, and that research will thoroughly cover this subject. Nitrogen The stream chemistry values for the majority of nutrients studied at Hinkle Creek were very similar to one another. The total nutrient output in kg month-1 and kg ha-1 month-1 (Tables 3.4 – 3.14) among the streams differed greatly due to discharge and watershed area, but their nutrient concentrations, with few exceptions, were closely related. Hinkle Creek South Fork and Myers Creek both had concentrations of ~4 mg L-1 of Ca in December 2003, but the South Fork exported 10,338 kg (~967.4 L sec-1mean monthly flow) and Myers only 572 kg (~54 L sec-1mean monthly flow) during the month. On a unit area basis, Meyer exported 6.64 kg ha-1 of Ca, while the Hinkle Creek South Fork exported 9.74 kg ha-1 of Ca for December, 2003. There were no apparent order of magnitude differences for any of the streams for any nutrients. Discharge seemed to have little effect on concentration for most of the nutrients. Partial clearcuts or completely forested basins both had similar nutrient concentration data, with the apparent exception of N, especially NO3-N + NO2-N (Tables 3.4 - 3.15), occurring in all except the forested portion of Beeby Creek, partially in Clay Creek, and in the South Fork of Hinkle Creek. All stream water N concentrations were low, except for some higher NO3-N concentrations for two partially treated watersheds, Clay and Beeby Creeks. These streams flow into Hinkle Creek South Fork, which seems to have raised NO3-N + NO2-N concentrations in the South Fork as well. Results for NH4-N show that this inorganic form of N was present in low concentrations in all of these watersheds. The NH4-N concentration levels were similar to those in many other streams found in the west, but 53 were lower than in most streams located in the northeast and southeast (Binkley et al., 2004). The NH4-N results were very similar to streams found at the H.J. Andrews LTER (Table 3.20). Organic N, as both particulate, unfiltered total N, and as dissolved total N, also occurred in low concentrations. Dissolved organic N (DON) had concentrations similar to those in streams at the H.J. Andrews LTER (Martin and Harr, 1989; Vanderbilt et al., 2003) (Table 3.20) and in the Salmon River basin in Oregon’s Coast Range (Compton et al., 2003) (Table 3.22). It was lower than the mean concentration of DON in forests measured in the northeastern and southeastern United States (Binkley et al., 2004). Table 3.25 shows the difference in N export for the North and South Fork of Hinkle Creek for the calendar year of 2004. The South Fork is higher in all categories, but especially in inorganic N, which may be a result of the partial clearcuts occurring on the basin. A yearly mean of the four seasonal sample points was created to produce the estimates. Basin-wide urea fertilization occurred in October of 2004 and the next section will deal with those effects. This section discusses pre-fertilization data. The first complete set of samples was collected in October of 2002. Samples given to CCAL usually had a 2-3 month lag time before results were mailed. In January of 2003 the first data set was received. It was immediately noticed that the NO3-N value from one stream, Beeby Creek, was one to two orders of magnitude higher than NO3-N values from all the other streams (Figures 3.3 – 3.10). The decision was made to sample the two Beeby Creek tributaries that originated at the basin’s headwaters to discover possible causes. Tributary 1 is forested except for ~ 5% of its edge, while Tributary 2 has ~ 50% clearcut at its headwaters. The rest of the Beeby Creek basin is forested (Figures 54 3.5 and 3.6). Tributary 2 accounted for most of the NO3-N + NO2-N that entered the Beeby Creek main stream channel. The general hypothesis was that the clearcut portion of the Beeby Creek watershed was responsible for the increase in NO3-N + NO2-N. The aggressive vegetation suppression with herbicide employed by Roseburg Forest Products for the first two years probably was lowering N uptake and allowing the mobile NO3-N + NO2-N to move through the soil solution and into the streams. These results were similar to the initial N chemistry results for Hubbard Brook experimental treatment watershed following clearcutting and 3 yr of herbicide treatment to suppress vegetation recovery (Likens and Bormann, 1995). We decided to test this theory further by utilizing an opportunity afforded by Clay Creek. The gauging station on Clay Creek was directly above a clearcut that had been done prior to the study. The clearcut ended downslope, next to a road crossing and offered an ideal sampling location. The decision was made to sample the water directly above (A) and directly below (B) the clearcut to look for changes between the two points (Figures 3.3 and 3.4). Results presented in Table 3.23 show the statistical significance values for T-tests comparing Beeby Creek to the other headwater streams; a comparison between Clay Creek above (A) and below (B) the clearcut; and a comparison between Hinkle Creek South Fork and North Fork, which was completely untreated. The Beeby Creek main tributary was significantly higher in NO3-N + NO2-N, with a two-sided inference (P < 0.0001 and T = 6.16 - 6.51), than all of the other headwater streams. Clay Creek A vs. B showed no significant change (P = 0.272 and T = 1.15). Samples taken from the 55 sampling point below the clearcut did seem slightly higher in NO3-N + NO2-N concentration until the summer of 2003, when one sample from the Clay Creek A section above the clearcut showed a spike in NO3-N + NO2-N concentration (Figures 3.3 and 3.4). This spike may have skewed the T-test, and without it, there may have been significant differences. The rest of the data suggest that the section below the clearcut had slightly higher NO3-N + NO2-N concentrations. No reason for the spike could be ascertained. Hinkle Creek South Fork showed that downstream effects of clearcutting, especially NO3-N + NO2-N output from smaller upstream tributaries, may transmit their effects to larger confluences downstream (P = 0.0001 and T = 4.47) (Figures 3.7 and 3.8). There was no pre-treatment data available, so the discrepancies between Beeby Creek’s clearcuts having possible treatment effects on the stream, and Clay Creek’s clearcuts having little to no effect can only be postulated. The difference in soils and slope between the Beeby Creek and Clay Creek watersheds may account for the observed stream concentration differences. Four soil pits were dug on the clearcut at the headwaters of Beeby Creek Tributary 2. The slope of the headwaters in this part of Beeby Creek #2 ranged from 65-90% and the soils were shallow and extremely rocky (Appendix Tables A2.2, A2.3, A2.23 and A2.24). They seemed to have low water-holding capacity and, in addition, they were overlain on fractured bedrock, which transmitted the water downslope very quickly. The seedlings that had been planted had a high mortality rate and there was basically no vegetation on most of the hillslope. Conditions seemed ideal for leaching of highly mobile NO3-N + NO2-N. In contrast, the three soil pits dug on the clearcut section of the Clay Creek 56 watershed below the stream gauging point had very deep soils with low rock content and colluvium as the parent material (Appendix Tables A2.1, A2.4, and A2.5). The slope ranged from 17-30% and the deep soils overlay massive clay. The seedlings had little mortality and the riparian zone was covered with hardwoods and shrubs. The large water-holding capacity, low slope and nutrient uptake by vegetation may explain the discrepancies between the two watersheds’ differing responses to clearcutting and to NO3-N + NO2-N output. Hinkle Creek streams, with the exceptions of Beeby Creek and the South Fork, were lower in NO3-N + NO2-N concentrations (Figures 3.9 and 3.10) than streams in the Alsea River basin (Table 3.21) and in the Salmon River basin (Table 3.22). In contrast, they were very similar in NO3-N + NO2-N concentration to watershed streams located on the H.J. Andrews LTER (Tables 3.19 and 3.20). The highest NO3-N + NO2-N concentration measured in Tributary 2 was 1.75 mg L-1 in December, 2004 (Table 3.12). This value still was substantially lower than in many forest streams in the northeast, southeast and other regions affected by anthropogenic inputs from fertilizers, and air pollution from fossil fuel burning (Vitousek, 1977; Likens and Bormann, 1995; Hong et al., 2005; Binkley et al., 2004). It also was well below the Environmental Protection Agency’s limit for safe drinking water of 10 mg L-1. However, it was four orders of magnitude higher than in most of the other headwater streams at Hinkle Creek and the long-term effects of changes of this magnitude on forest productivity and ecological sustainability may be an issue for forest managers. 57 Urea fertilization During October, 2004 the basin was fertilized with urea (46% N) CO(NH2)2, which is an organic form of N (Tisdale et al., 1993). It was applied at the rate of 440 lbs urea acre-1 or 202 kg N acre-1 (Figure 3.2). The application area is green, and the untreated area is grey on the map. Wide buffers were maintained along major waterways. The urea application was performed aerially with helicopters. A double-fly swath pattern using GPS “shape files” was used to ensure accurate application. Tables 3.4 – 3.14 and Figures 3.3 - 3.10 show that the concentration of NO3-N + NO2-N and DON in Hinkle Creek streams increased substantially after the October, 2004 urea N fertilization. The control streams, Myers, DeMearsman and Hinkle Creek North Fork, became the new temporary leaders in NO3-N + NO2-N and DON export. Myers Creek in October, 2004 went from 0.01 mg L-1 NO3-N + NO2-N and 0.02 mg L-1 DON, to 0.64 and 0.69 mg L-1, respectively, in the January, 2005 sampling. DeMearsman Creek went from 0.009 mg L-1 NO3-N + NO2-N and 0.03 mg L-1 DON, to 0.75 and 0.80 mg L-1, respectively, in the January, 2005 sampling. Hinkle Creek North Fork surpassed the South Fork in both forms of N for the first time in this study. All of the streams showed an increase in N concentrations after the October, 2004 sampling, which, considering the extensive application area, would seem likely. The fertilization effect persisted for different lengths of time for the various N components. By the May, 2005 sampling, the concentrations of NO3-N + NO2-N were already well on their way back to pre-fertilization levels. The two control headwater streams had significantly higher NO3N + NO2-N concentrations in both January and May, 2005 (P < 0.02 and P < 0.05, respectively) than the four experimental treatment streams (Table 3.24). Total dissolved 58 N also was significantly higher for both sampling dates, while DON showed significance only for May, 2005 (P < 0.05). Stream NH4-N concentrations were not affected by urea application for these two sampling dates. This pattern of rapid increases in nitrate following fertilization and then returning to background levels has been observed in many other fertilization studies (Moore, 1975; Tiedemann et al., 1978; Binkley and Brown, 1993; Binkley et al., 1998; Anderson, 2002). Higher concentrations of urea (DON) in stream water from accidental application over waterways would probably have been noticed had the sampling occurred during the fertilization application. Moore (1975) found that after three weeks, all N entering the stream had been transformed from urea to nitrate. The Hinkle Creek data seem to contradict this, as the higher DON concentration was still elevated five months later in the treatment watersheds. General statistical comparisons among the headwater streams are presented using F-tests. Results for Hinkle Creek stream N chemistry using these tests showed that there were highly significant differences among the six headwater streams for TDN (F5, 96 = 38.49; P < 0.001) and for NO3-N + NO2-N (F5, 96 = 39.53; P < 0.001). In contrast, our findings for both DON (F5, 93 = 2.26; P < 0.1) and for NH4-N (F5, 96 = 1.23; P = NS) were not significant for these streams. Results for NO3-N + NO2-N, which included Beeby Creek Tributary 1 (the forested portion of Beeby Creek watershed) and the other five headwater streams, exhibited no significant difference (F5, 87 = 1.80; P = NS). On the other hand, our findings for NO3-N + NO2-N that included the clearcut portion of Beeby Creek Tributary 2 and the five other headwater creeks showed a highly significant difference (F5, 90 = 46.62; P < 0.001). Total dissolved N also exhibited a significant 59 effect from Beeby Creek Tributary 2 and the other five headwater streams (F5, 90 = 49.04; P < 0.001). However, Beeby Creek Trbutary 1 unexpectedly showed a significant effect for TDN (F5, 86 = 3.04; P < 0.01). This latter result suggests that there was significant variation in TDN within the six watersheds, including the forested portion of Beeby Creek drained by Tributary 1. Beeby Creek presented an excellent opportunity to compare the stream chemistry N responses within the Beeby Creek watershed. Samples taken at the gauging station located at the watershed base were compared with two Beeby Creek tributaries, 1 and 2. Tributary 1 drains from a 95% forested location, while Tributary 2 flows from a 50% clearcut area of the watershed. Results for these comparisons show that there was a significant difference among the mean values for TDN (F2, 33 = 14.23; P < 0.001), for NO3-N + NO2-N (F2, 33 = 13.94; P < 0.001) and also for DON (F2, 32 = 5.29; P < 0.025). In contrast, no difference was detected among mean values for NH4-N within the Beeby Creek watershed (F2, 32 = 1.58; P = NS). The annual amount of N exported in 2004 by the South Fork of Hinkle Creek was substantially greater than that for the North Fork of Hinkle Creek (Table 3.25). On a unit area basis (kg ha-1yr-1), the quantity of NO3-N + NO2N exported was 11.6 times greater for the South Fork than for the North Fork. Total dissolved N was 2.6 times greater (kg ha-1yr-1) for the South Fork than for the North Fork. The export of NH4-N (kg ha-1yr-1) was 2.9 times greater for the South Fork. In contrast, the amount of DON (kg ha-1yr-1) exported was very similar for both the North and South Forks of Hinkle Creek in 2004 (Table 3.25). Although previous studies have focused on the short-term effects of urea fertilization on stream N chemistry (Moore, 1975; Tiedemann et al., 60 1978), this research may be among the first to document a significant, long-term increase in stream DON concentration (Table 3.24), as observed in May, 2005, seven months after the urea application in late October, 2004. In contrast, the January, 2005, stream DON concentrations were not significantly affected by urea fertilization (Table 3.24). Major storm events can significantly affect stream nutrient transport, as observed in this study and also in previous work (Vanderbilt et al., 2003). For example, the December, 2003, total monthly losses of TDN from the Hinkle Creek Watershed (Tables 3.4 and 3.5) were 95.4% (for the South Fork) and 53.7%(for the North Fork) of the total annual N losses estimated for these two streams, respectively, in 2004 (Table 3.25). The predominant N loss from the South Fork in December, 2003, was in the form of NO3-N + NO2-N (79.0%), while the predominant N loss from the North Fork in December, 2003, was in the form of TDON (78.8%) as shown in Tables 3.4 and 3.5. Table 3.4. North Fork Hinkle Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S. E. % for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 Oct. 2003 18.5 8.6 Dec. 2003 614.7 10.0 Feb. 2004 432.1 5.8 Apr. 2004 134.6 0.4 July 2004 27.8 6.6 Oct. 2004 83.6 25.7 Jan. 2005 143.9 8.0 May 2005 396.7 12.1 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹-----------------------------------------------------------------------------------kg month-1----------------------------------------------------------------------------› 1.9 2.9 0.9 0.1 0.9 0.8 0.5 431 273 28.8 355 99.5 6.9 96.3 0.002 0.003 0.001 0.0001 0.001 0.001 0.001 0.49 0.31 0.03 0.41 0.11 0.01 0.11 0.038 0.059 0.019 0.002 0.019 0.017 0.01 8.68 5.5 0.58 7.16 2.006 0.14 1.94 103.6 131.5 16.4 11.5 37.8 32.9 14.8 12153 5565 593 57458 1760 280 3518 0.119 0.151 0.019 0.013 0.043 0.038 0.017 13.92 6.37 0.68 8.54 2.02 0.32 4.03 0.063 0.08 0.01 0.007 0.023 0.02 0.009 7.38 3.38 0.36 4.53 1.069 0.17 2.14 27.1 37.9 5.4 5.4 24.9 17.3 8.7 8889 3205 347 4937 1288 173 1646 0.031 0.043 0.006 0.006 0.029 0.020 0.010 10.18 3.67 0.40 5.66 1.48 0.20 1.89 0.025 0.035 0.005 0.005 0.023 0.016 0.008 8.21 2.96 0.32 4.56 1.19 0.16 1.52 10.1 11.9 1.4 0.3 7.0 5.6 2.4 2673 1155 136 1752 549 55.8 485 0.012 0.014 0.002 0.0001 0.008 0.006 0.003 3.06 1.32 0.16 2.01 0.63 0.06 0.56 0.029 0.034 0.004 0.001 0.02 0.016 0.007 7.66 3.31 0.39 5.02 1.573 0.16 1.39 2.2 2.8 0.6 0.1 1.9 2.2 0.8 649 294 32.8 474 131 11.9 107 0.002 0.003 0.001 0.0001 0.002 0.002 0.001 0.74 0.34 0.04 0.54 0.15 0.01 0.12 0.029 0.038 0.008 0.001 0.026 0.029 0.011 8.7 3.94 0.44 6.36 1.76 0.16 1.44 8.3 9.6 0.7 0.7 4.0 4.3 2.0 1913 1074 121 1665 454 31.3 385 0.009 0.011 0.001 0.001 0.005 0.005 0.002 2.19 1.23 0.14 1.91 0.52 0.04 0.44 0.037 0.043 0.003 0.003 0.018 0.019 0.009 8.55 4.8 0.54 7.44 2.027 0.14 1.72 17.0 206 187 2.3 7.7 5.8 3.1 3098 1183 127 2154 571 53.9 528 0.019 0.236 0.214 0.003 0.009 0.007 0.004 3.55 1.36 0.15 2.47 0.65 0.06 0.60 0.044 0.535 0.485 0.006 0.02 0.015 0.008 8.04 3.07 0.33 5.59 1.483 0.14 1.37 180 328 148 0.0 26.6 24.4 9.6 NA 3453 393 6014 1185 128 1551 0.207 0.376 0.169 0.000 0.030 0.028 0.011 NA 3.96 0.45 6.89 1.36 0.15 1.78 0.17 0.309 0.139 0.000 0.025 0.023 0.009 NA 3.25 0.37 5.66 1.115 0.12 1.46 TDON = total dissolved organic N. TDN = total dissolved N. TUnP = total unfiltered P. eD PO4-P = dissolved PO4-P. TDP = total dissolved P. NA = not analyzed. a c b d 61 Table 3.5. South Fork Hinkle Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S. E. % for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 July 2003 35.2 3.8 Aug. 2003 24.1 2.2 Oct. 2003 26.2 4.0 Dec. 2003 967.4 6.4 Feb. 2004 501.3 7.3 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹-----------------------------------------------------------------------------------kg month-1---------------------------------------------------------------------------› 4.3 15.8 11.1 0.4 2.8 2.5 1.4 919 373 43.4 539 156 15.1 123 0.004 0.015 0.010 0.0003 0.003 0.002 0.001 0.87 0.35 0.04 0.51 0.15 0.01 0.12 0.046 0.168 0.118 0.004 0.030 0.027 0.015 9.74 3.95 0.46 5.72 1.658 0.16 1.30 2.6 7.2 4.6 0.0 1.6 1.2 0.9 621 268 29.7 394 114 9.1 83.4 0.002 0.007 0.004 0.000 0.001 0.001 0.001 0.59 0.25 0.03 0.37 0.11 0.01 0.08 0.040 0.111 0.071 0.000 0.024 0.018 0.014 9.61 4.15 0.46 6.10 1.757 0.14 1.29 2.7 5.9 3.1 0.1 1.6 1.4 0.8 668 289 31.6 427 115 11.2 89.9 0.003 0.006 0.003 0.0001 0.002 0.001 0.001 0.63 0.27 0.03 0.40 0.11 0.01 0.08 0.038 0.084 0.044 0.002 0.023 0.020 0.012 9.51 4.12 0.45 6.08 1.636 0.16 1.28 134.7 744 588 20.8 59.6 51.8 20.8 18034 7047 725 10338 2254 414 3991 0.126 0.701 0.554 0.019 0.056 0.049 0.019 16.99 6.64 0.68 9.74 2.12 0.39 3.76 0.052 0.287 0.227 0.008 0.023 0.020 0.008 6.96 2.72 0.28 3.99 0.870 0.16 1.54 28.9 129 91.7 8.8 27.6 18.8 10.0 9746 3240 264 5689 1270 201 1645 0.027 0.122 0.086 0.008 0.026 0.018 0.009 9.19 3.05 0.25 5.36 1.20 0.19 1.55 0.023 0.103 0.073 0.007 0.022 0.015 0.008 7.76 2.58 0.21 4.53 1.011 0.16 1.31 62 Table 3.5 South Fork Hinkle Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S.E.% for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1(cont.). Month Flow rate L sec-1 Apr. 2004 231.2 15.2 July 2004 67.3 5.0 Oct. 2004 108.7 15.5 Jan. 2005 189.5 10.0 May 2005 512.8 10.2 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹-----------------------------------------------------------------------------------kg month-1--------------------------------------------------------------------------› 16.2 58.1 40.1 1.8 12.0 9.6 4.2 4458 1654 180 2571 919 89.9 743 0.015 0.055 0.038 0.002 0.011 0.009 0.004 4.20 1.56 0.17 2.42 0.87 0.08 0.70 0.027 0.097 0.067 0.003 0.020 0.016 0.007 7.44 2.76 0.30 4.29 1.533 0.15 1.24 3.6 11.0 5.6 1.8 4.9 4.9 2.0 1542 579 66.7 961 234 28.9 290 0.003 0.010 0.005 0.002 0.005 0.005 0.002 1.45 0.55 0.06 0.91 0.22 0.03 0.27 0.02 0.061 0.031 0.010 0.027 0.027 0.011 8.55 3.21 0.37 5.33 1.296 0.16 1.61 10.8 18.9 7.3 0.9 4.1 5.2 2.3 2597 1069 119 1796 449 37.8 373 0.010 0.018 0.007 0.001 0.004 0.005 0.002 2.45 1.01 0.11 1.69 0.42 0.04 0.35 0.037 0.065 0.025 0.003 0.014 0.018 0.008 8.92 3.67 0.41 6.17 1.543 0.13 1.28 20.3 227 202 5.1 10.2 7.6 4.6 3767 1254 122 2361 654 76.1 609 0.019 0.214 0.190 0.005 0.010 0.007 0.004 3.55 1.18 0.11 2.22 0.62 0.07 0.57 0.04 0.448 0.398 0.010 0.020 0.015 0.009 7.42 2.47 0.24 4.65 1.289 0.15 1.20 192 330 137 0.0 34.3 30.2 12.4 NA 3695 385 6538 1136 165 1566 NA 0.181 0.311 0.129 0.000 0.032 0.028 0.012 3.48 0.36 6.16 1.07 0.16 1.48 0.140 0.240 0.100 0.000 0.025 0.022 0.009 NA 2.69 0.28 4.76 0.827 0.12 1.14 63 Table 3.6. Myers Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S.E.% for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 Dec. 2003 53.9 1.3 Feb. 2004 48.9 0.5 Apr. 2004 16.2 0.7 July 2004 6.8 0.3 Oct. 2004 6.6 1.0 Jan. 2005 15.3 0.7 May 2005 45.6 1.1 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹-----------------------------------------------------------------------------------kg month-1---------------------------------------------------------------------------› 8.1 10.5 0.4 2.0 5.3 4.5 2.0 1137 557 59.2 572 130 30.3 276 0.094 0.122 0.005 0.023 0.062 0.052 0.023 13.19 6.47 0.69 6.64 1.51 0.35 3.20 0.056 0.073 0.003 0.014 0.037 0.031 0.014 7.87 3.86 0.41 3.96 0.904 0.21 1.91 1.7 4.2 0.5 2.0 2.9 2.1 1.2 945 380 41.7 473 111 22.1 186 0.020 0.048 0.006 0.023 0.034 0.024 0.014 10.97 4.41 0.48 5.49 1.28 0.26 2.16 0.014 0.034 0.004 0.016 0.024 0.017 0.010 7.71 3.10 0.34 3.86 0.902 0.18 1.52 1.6 1.8 0.2 0.1 1.0 1.0 0.7 335 151 16.8 170 61.9 8.0 59.6 0.018 0.021 0.002 0.001 0.012 0.011 0.008 3.89 1.75 0.19 1.97 0.72 0.09 0.69 0.037 0.044 0.004 0.003 0.024 0.023 0.016 7.98 3.59 0.40 4.04 1.474 0.19 1.42 0.1 0.5 0.2 0.2 0.6 0.5 0.3 163 74.4 9.3 87.4 24.3 2.4 25.0 0.001 0.006 0.002 0.003 0.007 0.006 0.003 1.89 0.86 0.11 1.01 0.28 0.03 0.29 0.007 0.03 0.010 0.013 0.032 0.028 0.016 8.90 4.07 0.51 4.78 1.327 0.13 1.37 0.4 0.7 0.2 0.1 0.7 0.5 0.4 168 87.9 10.7 96.6 28.6 3.6 29.5 0.005 0.008 0.002 0.001 0.008 0.006 0.004 1.95 1.02 0.12 1.12 0.33 0.04 0.34 0.023 0.041 0.011 0.007 0.037 0.030 0.021 9.47 4.95 0.60 5.44 1.609 0.20 1.66 1.6 28.2 26.2 0.5 0.9 0.8 0.5 340 152 16.8 207 62.9 8.2 65.0 0.018 0.327 0.304 0.006 0.010 0.009 0.006 3.94 1.76 0.19 2.40 0.73 0.09 0.75 0.038 0.69 0.640 0.012 0.021 0.020 0.012 8.31 3.71 0.41 5.07 1.540 0.20 1.59 NA 15.7 26.5 10.6 0.2 3.4 1.1 1.1 410 26.9 858 182 9.8 159 NA 0.182 0.308 0.123 0.003 0.040 0.013 0.013 4.75 0.31 9.96 2.12 0.11 1.84 0.128 0.217 0.087 0.002 0.028 0.009 0.009 NA 3.35 0.22 7.02 1.492 0.08 1.30 64 Table 3.7. DeMearsman Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S E.% for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 Dec. 2003 123.7 1.1 Feb. 2004 99.9 0.6 Apr. 2004 43.5 0.5 July 2004 29.0 0.4 Oct. 2004 20.6 1.2 Jan. 2005 40.6 0.7 May 2005 133.6 1.1 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹----------------------------------------------------------------------------------kg month-1----------------------------------------------------------------------------› 18.9 21.5 1.7 1.0 7.6 6.3 3.3 2717 1070 76.2 1896 481 49.7 772 0.121 0.138 0.011 0.006 0.049 0.040 0.021 17.38 6.85 0.49 12.13 3.07 0.32 4.94 0.057 0.065 0.005 0.003 0.023 0.019 0.010 8.20 3.23 0.23 5.72 1.450 0.15 2.33 5.8 9.5 2.0 1.8 5.5 4.0 2.3 2171 766 52.6 1455 433 35.1 378 0.037 0.061 0.013 0.011 0.035 0.026 0.014 13.89 4.90 0.34 9.31 2.77 0.22 2.42 0.023 0.038 0.008 0.007 0.022 0.016 0.009 8.67 3.06 0.21 5.81 1.729 0.14 1.51 2.1 3.8 0.5 1.2 2.0 1.7 1.0 970 388 27.1 730 239 15.8 155 0.014 0.025 0.003 0.008 0.013 0.011 0.006 6.21 2.48 0.17 4.67 1.53 0.10 0.99 0.019 0.034 0.004 0.011 0.018 0.015 0.009 8.60 3.44 0.24 6.47 2.116 0.14 1.37 0.6 2.3 0.7 0.9 1.8 1.6 0.9 745 312 24.1 623 180 10.9 122 0.004 0.014 0.004 0.006 0.011 0.010 0.005 4.76 1.99 0.15 3.99 1.15 0.07 0.78 0.008 0.029 0.009 0.012 0.023 0.021 0.011 9.58 4.01 0.31 8.02 2.315 0.14 1.57 1.8 2.7 0.5 0.4 1.3 1.2 0.7 509 259 19.3 553 155 6.1 87.8 0.012 0.017 0.003 0.002 0.008 0.007 0.004 3.25 1.66 0.12 3.54 0.99 0.04 0.56 0.033 0.049 0.009 0.007 0.023 0.021 0.012 9.21 4.69 0.35 10.01 2.814 0.11 1.59 4.8 87.1 81.7 0.7 2.2 1.6 0.9 945 340 23.9 721 200 10.9 150 0.031 0.557 0.523 0.004 0.014 0.010 0.006 6.05 2.18 0.15 4.61 1.28 0.07 0.96 0.044 0.802 0.752 0.006 0.020 0.015 0.008 8.70 3.13 0.22 6.64 1.841 0.10 1.38 NA 81.9 150 67.3 0.4 10.7 9.3 3.9 1220 139 1610 290 46.5 490 NA 0.524 0.957 0.430 0.002 0.069 0.060 0.025 7.80 0.89 10.30 1.86 0.30 3.14 0.229 0.418 0.188 0.001 0.030 0.026 0.011 NA 3.41 0.39 4.50 0.811 0.13 1.37 65 Table 3.8. Clay Creek A mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S.E. % for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 Dec. 2003 57.9 1.0 Feb. 2004 52.5 0.4 Apr. 2004 21.9 0.9 July 2004 11.1 0.2 Oct. 2004 9.4 0.3 Jan. 2005 21.2 0.6 May 2005 35.2 0.6 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹---------------------------------------------------------------------------------kg month-1------------------------------------------------------------------------------› 7.0 8.4 0.6 0.8 4.8 3.1 1.7 965 382 52.7 583 116 24.8 257 0.107 0.129 0.010 0.012 0.074 0.048 0.026 14.81 5.86 0.81 8.95 1.77 0.38 3.95 0.045 0.054 0.004 0.005 0.031 0.020 0.011 6.22 2.46 0.34 3.76 0.745 0.16 1.66 2.1 9.1 5.1 1.8 2.2 2.1 1.2 870 330 42.1 508 108 21.1 187 0.032 0.139 0.079 0.028 0.034 0.032 0.018 13.35 5.07 0.65 7.79 1.65 0.32 2.87 0.016 0.069 0.039 0.014 0.017 0.016 0.009 6.61 2.51 0.32 3.86 0.819 0.16 1.42 1.6 2.2 0.5 0.1 1.4 1.1 0.6 404 156 18.8 254 81.8 8.5 80.2 0.025 0.034 0.008 0.001 0.021 0.017 0.009 6.20 2.40 0.29 3.89 1.25 0.13 1.23 0.029 0.039 0.009 0.001 0.024 0.020 0.010 7.11 2.75 0.33 4.46 1.438 0.15 1.41 1.1 1.6 0.4 0.1 0.9 0.8 0.4 240 94.9 12.8 161 33.3 4.8 53.6 0.017 0.024 0.006 0.001 0.014 0.012 0.006 3.68 1.46 0.20 2.47 0.51 0.07 0.82 0.037 0.053 0.013 0.003 0.031 0.026 0.013 8.05 3.19 0.43 5.40 1.120 0.16 1.80 0.8 1.6 0.6 0.2 0.8 0.7 0.5 214 95.3 12.5 170 35.7 3.3 35.6 0.013 0.024 0.009 0.003 0.012 0.011 0.007 3.29 1.46 0.19 2.61 0.55 0.05 0.55 0.033 0.063 0.023 0.007 0.030 0.028 0.019 8.55 3.80 0.50 6.78 1.424 0.13 1.42 2.9 25.8 22.4 0.5 1.5 1.0 0.6 390 139 18.8 263 62.7 8.5 78.5 0.044 0.396 0.344 0.008 0.024 0.015 0.010 5.98 2.13 0.29 4.03 0.96 0.13 1.20 0.051 0.454 0.394 0.009 0.027 0.017 0.011 6.85 2.44 0.33 4.62 1.103 0.15 1.38 5.6 8.5 2.8 0.1 2.6 2.3 0.9 NA 248 32.1 403 63.6 13.2 123 0.085 0.130 0.043 0.001 0.040 0.035 0.014 NA 3.80 0.49 6.18 0.98 0.20 1.88 0.059 0.09 0.030 0.001 0.028 0.024 0.010 NA 2.63 0.34 4.27 0.675 0.14 1.30 66 Table 3.9. Clay Creek B mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S.E. % for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 Dec. 2003 57.9 1.0 Feb. 2004 52.5 0.4 Apr. 2004 21.9 0.9 July 2004 11.1 0.2 Oct. 2004 9.4 0.3 Jan. 2005 21.2 0.6 May 2005 35.2 0.6 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹------------------------------------------------------------------------------------kg month-1--------------------------------------------------------------------------› 6.5 31.0 21.7 2.8 4.7 2.8 1.7 949 365 59.0 527 115 23.3 227 0.100 0.476 0.333 0.043 0.071 0.043 0.026 14.57 5.59 0.90 8.09 1.77 0.36 3.48 0.042 0.2 0.140 0.018 0.030 0.018 0.011 6.12 2.35 0.38 3.40 0.743 0.15 1.46 3.0 11.7 7.8 0.9 2.4 1.8 1.1 870 312 44.7 454 103 19.7 175 0.046 0.180 0.119 0.014 0.036 0.028 0.016 13.35 4.78 0.69 6.97 1.58 0.30 2.69 0.023 0.089 0.059 0.007 0.018 0.014 0.008 6.61 2.37 0.34 3.45 0.783 0.15 1.33 1.7 6.2 4.5 0.0 1.4 1.1 0.5 386 148 21.6 223 75.8 8.0 71.1 0.026 0.095 0.069 0.000 0.021 0.017 0.008 5.92 2.27 0.33 3.42 1.16 0.12 1.09 0.03 0.109 0.079 0.000 0.024 0.019 0.009 6.79 2.60 0.38 3.92 1.334 0.14 1.25 1.2 1.6 0.4 0.0 1.0 0.9 0.3 235 87.8 12.8 139 30.4 4.2 36.6 0.018 0.024 0.006 0.000 0.016 0.013 0.005 3.60 1.35 0.20 2.13 0.47 0.06 0.56 0.039 0.053 0.013 0.001 0.035 0.029 0.011 7.88 2.95 0.43 4.66 1.021 0.14 1.23 0.8 1.8 0.8 0.2 0.6 0.5 0.3 200 84.0 11.8 131 32.0 3.3 36.9 0.013 0.027 0.012 0.003 0.009 0.007 0.005 3.07 1.29 0.18 2.02 0.49 0.05 0.57 0.033 0.071 0.031 0.007 0.024 0.019 0.013 7.98 3.35 0.47 5.24 1.278 0.13 1.47 2.4 25.2 22.3 0.4 1.3 1.0 0.5 137 20.5 233 61.9 245 6.8 71.1 0.038 0.387 0.343 0.006 0.020 0.016 0.008 2.09 0.31 3.58 0.95 3.75 0.10 1.09 0.043 0.443 0.393 0.007 0.023 0.018 0.009 2.40 0.36 4.10 1.09 4.300 0.12 1.25 6.4 10.6 4.0 0.2 2.5 2.2 0.8 NA 241 31.1 370 59.8 10.4 126 0.098 0.162 0.061 0.003 0.038 0.033 0.012 NA 3.70 0.48 5.68 0.92 0.16 1.94 0.068 0.112 0.042 0.002 0.026 0.023 0.008 NA 2.56 0.33 3.93 0.634 0.11 1.34 67 Table 3.10. Beeby Creek main channel mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S.E. % for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 Dec. 2003 126.9 1.2 Feb. 2004 71.3 0.6 Apr. 2004 35.5 1.4 July 2004 11.7 0.3 Oct. 2004 23.8 1.4 Jan. 2005 37.3 1.3 May 2005 78.7 1.1 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹---------------------------------------------------------------------------------kg month-1----------------------------------------------------------------------------› 12.9 317 296 7.5 6.5 5.1 2.7 2343 901 68.0 1554 309 64.6 673 0.117 2.857 2.673 0.068 0.058 0.046 0.025 21.15 8.13 0.61 14.03 2.79 0.58 6.08 0.038 0.931 0.871 0.022 0.019 0.015 0.008 6.89 2.65 0.20 4.57 0.908 0.19 1.98 5.0 76.9 71.6 0.4 3.0 2.9 1.8 1323 479 37.5 891 194 32.1 257 0.045 0.695 0.646 0.003 0.027 0.026 0.016 11.94 4.32 0.34 8.04 1.75 0.29 2.32 0.028 0.431 0.401 0.002 0.017 0.016 0.010 7.41 2.68 0.21 4.99 1.087 0.18 1.44 2.7 39.8 37.1 0.1 1.7 1.2 0.8 660 258 18.4 474 122 17.5 109 0.024 0.360 0.335 0.001 0.015 0.011 0.007 5.96 2.33 0.17 4.28 1.10 0.16 0.99 0.029 0.433 0.403 0.001 0.018 0.013 0.009 7.17 2.80 0.20 5.15 1.323 0.19 1.19 1.3 5.3 4.0 0.0 1.0 0.8 0.4 273 113 9.1 237 54.2 5.0 41.1 0.011 0.048 0.036 0.000 0.009 0.007 0.004 2.46 1.02 0.08 2.14 0.49 0.05 0.37 0.04 0.168 0.128 0.000 0.031 0.025 0.014 8.68 3.59 0.29 7.55 1.725 0.16 1.31 1.4 14.9 13.0 0.5 1.4 1.2 0.8 531 222 17.2 450 113 8.9 74.1 0.013 0.134 0.117 0.005 0.013 0.011 0.007 4.80 2.01 0.16 4.06 1.02 0.08 0.67 0.022 0.233 0.203 0.008 0.022 0.019 0.012 8.32 3.48 0.27 7.04 1.774 0.14 1.16 4.5 54.6 49.6 0.5 1.7 1.5 0.9 696 23 17.0 437 103 20.0 114 0.041 0.493 0.448 0.005 0.015 0.014 0.008 6.28 2.14 0.15 3.94 0.93 0.18 1.03 0.045 0.547 0.497 0.005 0.017 0.015 0.009 6.97 2.37 0.17 4.37 1.032 0.20 1.14 NA 48.3 90.9 42.4 0.2 4.8 6.1 2.1 626 46.4 1172 223 29.5 255 NA 0.436 0.820 0.382 0.002 0.044 0.055 0.019 5.65 0.42 10.58 2.01 0.27 2.30 0.229 0.431 0.201 0.001 0.023 0.029 0.010 NA 2.97 0.22 5.56 1.056 0.14 1.21 68 Table 3.11. Beeby Creek Tributary 1 nutrient concentrations in mg L-1. Month TDONa TDNb NO3-N + NO2-N NA NH4-N Dec. NA NA NA 2003 Feb. -0.072a 0.063 0.033 0.102a 2004 Apr. 0.030 0.071 0.031 0.010 2004 July NA NA NA NA 2004 Oct. NA NA NA NA 2004 Jan. 0.034 0.161 0.121 0.006 2005 May 0.088 0.146 0.056 0.002 2005 a These values may be due to possible laboratory error. TUnPc TDPd D PO4-Pe Si NA NA NA NA 0.008 0.010 0.003 0.009 0.009 NA Na K Ca Mg SO4-S Cl NA NA NA NA NA NA 6.19 2.13 0.11 3.35 0.595 0.36 0.17 0.003 6.21 2.22 0.10 3.46 0.782 0.82 0.16 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 0.006 0.007 0.003 6.34 2.04 0.09 3.30 0.617 0.00 0.17 0.013 0.014 0.003 NA 2.40 0.08 4.18 0.573 0.30 0.12 69 Table 3.12. Beeby Creek Tributary 2 nutrient concentrations in mg L-1. Month Dec. 2003 Feb. 2004 Apr. 2004 July 2004 Oct. 2004 Jan. 2005 May 2005 TDONa TDNb NH4-N TUnPc TDPd D PO4-Pe Si Na K 0.029 1.786 0.011 0.019 0.011 0.008 6.65 2.58 0.17 0.045 1.110 1.060 0.005 0.015 0.013 0.008 6.55 2.31 0.050 1.023 0.973 0.000 0.013 0.014 0.008 6.30 0.049 0.148 0.098 0.001 0.034 0.024 0.010 0.033 0.373 0.323 0.017 0.037 0.016 0.033 0.935 0.895 0.007 0.013 0.419 0.834 0.414 0.001 0.018 NO3-N + NO2-N 1.746 Ca Mg SO4-S 4.61 0.816 0.49 0.15 4.00 0.734 0.59 2.38 0.15 4.09 1.079 0.46 7.48 2.96 0.20 5.46 1.022 5.78 0.011 7.05 2.90 0.20 5.18 0.945 1.38 0.012 0.007 2.08 0.13 0.77 3.74 1.150 0.59 0.018 0.008 NA 2.42 0.12 4.18 0.587 0.56 70 Table 3.13. Russell Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S. E. % for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 Dec. 2003 60.1 1.6 Feb. 2004 45.7 0.6 Apr. 2004 16.7 1.1 July 2004 5.2 0.5 Oct. 2004 12.0 1.0 Jan. 2005 27.7 0.8 May 2005 60.2 0.9 TDONa TDNb NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S TUnPc Cl NO2-N ‹-----------------------------------------------------------------------------------kg month-1---------------------------------------------------------------------------› 4.0 12.6 7.7 0.8 3.4 3.2 1.6 1200 429 33.8 723 157 25.8 242 0.042 0.131 0.080 0.008 0.035 0.034 0.017 12.48 4.46 0.35 7.52 1.63 0.27 2.51 0.025 0.078 0.048 0.005 0.021 0.020 0.010 7.45 2.66 0.21 4.49 0.973 0.16 1.50 1.5 4.5 2.2 0.8 1.9 2.2 1.1 888 295 24.0 519 116 18.3 155 0.015 0.046 0.023 0.008 0.020 0.023 0.012 9.24 3.07 0.25 5.39 1.20 0.19 1.61 0.013 0.039 0.019 0.007 0.017 0.019 0.010 7.76 2.58 0.21 4.53 1.011 0.16 1.35 1.3 1.5 0.2 0.0 0.7 0.9 0.5 342 122 9.1 225 57.2 6.9 54.9 0.013 0.016 0.002 0.000 0.008 0.009 0.005 3.56 1.27 0.09 2.34 0.59 0.07 0.57 0.03 0.035 0.005 0.000 0.017 0.020 0.012 7.91 2.82 0.21 5.20 1.323 0.16 1.27 0.2 0.4 0.1 0.1 0.4 0.4 0.2 127 48.5 4.4 85.8 18.5 2.5 19.2 0.002 0.004 0.001 0.001 0.004 0.005 0.002 1.32 0.50 0.05 0.89 0.19 0.03 0.20 0.016 0.029 0.009 0.004 0.031 0.032 0.016 9.16 3.51 0.32 6.21 1.342 0.18 1.39 0.1 0.1 0.0 0.0 0.1 0.1 0.0 23.9 9.4 0.8 19.3 4.1 0.4 3.6 0.001 0.001 0.000 0.000 0.001 0.001 0.000 0.25 0.10 0.01 0.20 0.04 0.00 0.04 0.027 0.038 0.008 0.003 0.024 0.024 0.017 9.20 3.63 0.31 7.43 1.588 0.15 1.38 2.4 15.8 12.8 0.6 1.5 1.0 0.8 578 188 14.1 368 92.8 12.6 90.5 0.025 0.164 0.133 0.006 0.015 0.010 0.008 6.01 1.96 0.15 3.83 0.96 0.13 0.94 0.032 0.213 0.173 0.008 0.020 0.013 0.011 7.79 2.54 0.19 4.96 1.251 0.17 1.22 12.9 21.9 9.0 0.0 3.7 3.9 1.8 NA 455 33.8 914 153 19.3 193 0.134 0.228 0.094 0.000 0.039 0.040 0.018 NA 4.73 0.35 9.50 1.59 0.20 2.01 0.08 0.136 0.056 0.000 0.023 0.024 0.011 NA 2.82 0.21 5.67 0.951 0.12 1.20 71 Table 3.14. Fenton Creek mean monthly flow rate and water chemistry nutrient amounts in kg month-1. Italics denote S. E. % for stream flow rate. Bolded numbers are nutrient amounts in kg ha-1 month-1. Underlined numbers are nutrient concentrations in mg L-1. Month Flow rate L sec-1 Dec. 2003 9.5 1.7 Feb. 2004 8.0 0.6 Apr. 2004 4.0 0.9 July 2004 1.9 0.2 Oct. 2004 2.0 0.5 Jan. 2005 4.2 0.5 May 2005 10.4 0.8 TDONa TDNb TUnPc Cl NO3-N + NH4-N TDPd D PO4-Pe Si Na K Ca Mg SO4-S NO2-N ‹-----------------------------------------------------------------------------------kg month-1---------------------------------------------------------------------------› 0.8 1.6 0.33 0.48 1.5 0.9 0.6 180 87.9 13.2 70.7 15.7 5.1 43.6 0.035 0.070 0.015 0.021 0.067 0.039 0.025 7.96 3.88 0.58 3.12 0.69 0.22 1.92 0.031 0.063 0.013 0.019 0.060 0.035 0.022 7.12 3.47 0.52 2.79 0.618 0.20 1.72 0.5 0.8 0.16 0.08 0.7 0.5 0.4 165 69.6 9.6 64.8 16.6 3.6 30.1 0.023 0.034 0.007 0.004 0.030 0.022 0.018 7.27 3.07 0.42 2.86 0.73 0.16 1.33 0.026 0.038 0.008 0.004 0.034 0.025 0.020 8.21 3.47 0.48 3.23 0.828 0.18 1.50 0.2 0.3 0.07 0.02 0.4 0.4 0.3 93.9 41.2 5.2 37.6 12.5 2.0 15.1 0.008 0.012 0.003 0.001 0.017 0.017 0.012 4.14 1.82 0.23 1.66 0.55 0.09 0.67 0.018 0.027 0.007 0.002 0.038 0.037 0.026 9.13 4.01 0.51 3.66 1.219 0.19 1.47 0.1 0.2 0.07 0.04 0.3 0.2 0.2 51.6 23.1 3.0 23.1 5.8 1.0 8.1 0.005 0.010 0.003 0.002 0.012 0.011 0.007 2.28 1.02 0.13 1.02 0.25 0.04 0.36 0.023 0.043 0.013 0.007 0.052 0.048 0.032 10.25 4.60 0.59 4.59 1.144 0.20 1.62 0.1 0.2 0.04 0.05 0.3 0.3 0.2 61.7 31.6 3.6 29.8 8.3 1.1 8.5 0.005 0.009 0.002 0.002 0.012 0.012 0.011 2.72 1.40 0.16 1.32 0.37 0.05 0.38 0.02 0.038 0.008 0.010 0.053 0.051 0.045 11.60 5.95 0.67 5.61 1.568 0.21 1.60 0.4 0.7 0.28 0.09 0.4 0.3 0.2 90.4 39.2 5.7 38.9 11.3 2.0 17.7 0.016 0.033 0.013 0.004 0.018 0.014 0.011 3.99 1.73 0.25 1.72 0.50 0.09 0.78 0.032 0.065 0.025 0.008 0.036 0.027 0.021 7.96 3.45 0.50 3.42 0.997 0.18 1.56 1.4 1.7 0.31 0.03 1.1 1.1 0.6 NA 105 14.3 106 17.6 4.2 39.2 0.061 0.075 0.014 0.001 0.047 0.048 0.028 NA 4.63 0.63 4.67 0.78 0.19 1.73 0.049 0.061 0.011 0.001 0.038 0.039 0.023 NA 3.75 0.51 3.78 0.628 0.15 1.40 72 73 Table 3.15. Hinkle Creek Watershed nitrogen and phosphorus concentrations for Oct. 2002 – Oct. 2003. Creek TDON TDN NO3 - N + NO2 - N NH4 - N TUnP TDP D PO4 -P ‹------------------------------------mg L-1--------------------------------› Hinkle Creek S. Fork 0.039 0.004a 0.139 0.021 0.095 0.019 0.005 0.001 0.020 0.002 0.018 0.002 0.009 0.001 Hinkle Creek N. Fork 0.040 0.003 0.062 0.009 0.017 0.008 0.004 0.001 0.019 0.002 0.017 0.001 0.009 0.001 Myers Creek 0.032 0.004 0.055 0.004 0.014 0.004 0.009 0.001 0.028 0.001 0.024 0.001 0.015 0.001 DeMearsman Creek 0.026 0.003 0.041 0.003 0.010 0.002 0.005 0.001 0.023 0.004 0.017 0.001 0.010 0.001 Fenton Creek 0.025 0.005 0.051 0.002 0.018 0.002 0.009 0.004 0.047 0.005 0.041 0.004 0.033 0.004 Russell Creek 0.019 0.002 0.043 0.005 0.021 0.004 0.004 0.001 0.024 0.002 0.019 0.001 0.013 0.001 Clay Creek A 0.028 0.007 0.070 0.019 0.030 0.017 0.012 0.005 0.030 0.003 0.021 0.002 0.014 0.001 Clay Creek B 0.040 0.010 0.099 0.019 0.049 0.015 0.010 0.002 0.027 0.002 0.020 0.001 0.012 0.001 Beeby Creek Main Channel 0.031 0.004 0.510 0.084 0.470 0.082 0.009 0.003 0.021 0.002 0.019 0.001 0.012 0.001 Beeby Creek Trib. 1 0.032 0.004 0.079 0.010 0.034 0.011 0.014 0.004 0.014 0.004 0.008 0.001 0.003 0.000 Beeby Creek Trib. 2 a Italics denote S.E. 0.048 0.004 0.981 0.188 0.928 0.190 0.006 0.001 0.017 0.002 0.014 0.001 0.009 0.000 74 Table 3.16 Hinkle Creek Watershed silicon, base cation, sulfate and chloride concentrations for Oct. 2002 – Oct. 2003. Creek Si Na K Ca Mg SO4 -S Cl ‹---------------------------------------------mg L-1----------------------------------------› Hinkle Creek S. Fork 8.26 0.32a 3.28 0.20 0.37 0.02 5.20 0.24 1.401 0.073 0.14 0.00 1.30 0.04 Hinkle Creek N. Fork 8.14 0.20 4.23 0.30 0.50 0.03 6.03 0.33 1.753 0.103 0.15 0.01 1.67 0.08 Myers Creek 8.85 0.29 4.16 0.20 0.52 0.03 4.91 0.19 1.394 0.063 0.18 0.00 1.43 0.05 DeMearsman Creek 8.99 0.15 4.33 0.32 0.31 0.02 8.82 0.75 2.742 0.241 0.13 0.00 1.48 0.06 Fenton Creek 9.85 0.60 4.82 0.39 0.59 0.02 4.47 0.27 1.230 0.088 0.20 0.01 1.52 0.04 Russell Creek 8.63 0.28 3.25 0.17 0.27 0.01 6.30 0.33 1.517 0.085 0.15 0.00 1.47 0.09 Clay Creek A 7.76 0.31 3.29 0.22 0.42 0.02 5.34 0.30 1.251 0.080 0.15 0.01 1.44 0.07 Clay Creek B 7.45 0.37 2.98 0.19 0.46 0.03 4.49 0.25 1.251 0.077 0.16 0.01 1.28 0.03 Beeby Creek Main Channel 8.11 0.30 3.46 0.23 0.26 0.01 7.08 0.53 1.896 0.284 0.16 0.00 1.44 0.05 Beeby Creek Trib. 1 6.36 0.11 2.31 0.07 0.12 0.00 3.80 0.18 0.684 0.037 0.18 0.02 1.30 0.16 Beeby Creek Trib. 2 a Italics denote S.E. 6.91 0.22 2.82 0.19 0.19 0.01 5.24 0.31 1.030 0.073 0.21 0.01 1.21 0.04 75 Table 3.17 Hinkle Creek Watershed pH, alkalinity and conductance values for Oct. 2002 – Oct. 2003. pH Alkaline HCO3 – C mg L-1 Conductance μs cm-1 Hinkle Creek S. Fork 7.52 0.03a 5.76 0.33 50.3 2.6 Hinkle Creek N. Fork 7.58 0.03 7.04 0.45 60.4 3.7 Myers Creek 7.48 0.03 6.12 0.26 53.0 2.1 DeMearsman Creek 7.68 0.03 9.07 0.75 75.6 6.1 Fenton Creek 7.49 0.05 6.03 0.46 52.7 3.8 Russell Creek 7.52 0.02 6.60 0.39 56.4 3.1 Clay Creek A 7.53 0.04 5.78 0.38 50.7 3.3 Clay Creek B 7.44 0.05 5.11 0.33 44.9 2.53 Beeby Creek Main Channel 7.60 0.04 6.90 0.65 62.8 4.6 Beeby Creek Trib. 1 7.33 0.02 3.88 0.21 34.9 1.4 7.33 0.06 4.44 0.57 47.7 2.7 Creek Beeby Creek Trib. 2 a Italics donote S.E. 76 Table 3.18 Hinkle Creek Watershed pH, alkalinity, and conductance values for Dec. 2003 – May 2005. pH Alkaline HCO3 – C mg L-1 Conductance μs cm-1 Hinkle Creek S. Fork 7.49 0.03a 5.19 0.38 46.2 2.7 Hinkle Creek N. Fork 7.57 0.04 6.33 0.49 55.6 3.7 Myers Creek 7.47 0.05 5.91 0.44 52.4 3.2 DeMearsman Creek 7.63 0.04 7.38 0.78 63.3 5.7 Fenton Creek 7.46 0.05 5.28 0.50 47.0 3.9 Russell Creek 7.54 0.02 5.78 0.41 50.3 3.1 Clay Creek A 7.47 0.04 5.00 0.42 44.9 3.2 Clay Creek B 7.47 0.04 4.51 0.29 40.9 2.0 Beeby Creek Main Channel 7.56 0.05 5.62 0.59 51.5 3.7 Beeby Creek Trib. 1 7.37 0.03 3.44 0.22 31.3 1.5 7.31 0.03 3.91 0.41 42.0 1.8 Creek Beeby Creek Trib. 2 a Italics denote S.E. 77 Above clearcut Clay Creek 2002 - 2003 Below clearcut 0.200 0.150 0.100 03 .‘ 03 O ct ‘0 3 Au g. ‘ Ju ly ‘0 3 ‘0 3 Ju ne ay M ‘0 2 Ja n. ‘0 3 Fe b. ‘0 3 M ar .‘ 03 Ap r. ‘0 3 ec . 02 D ov .‘ O ct .‘ 0.000 02 0.050 N NO3-N + NO2-N (mg L-1) 0.250 Month Figure 3.3. Clay Creek, showing NO3-N + NO2-N concentrations above and below a clearcut. Above clearcut Clay Creek 2003 - 2005 Below clearcut 0.450 NO3-N + NO2-N (mg L-1) 0.400 0.350 0.300 0.250 0.200 0.150 0.100 0.050 0.000 Dec. ‘03 Feb. ‘04 Apr. ‘04 July ‘04 Oct. ‘04 Jan. ‘05 May ‘05 Month Figure 3.4. Clay Creek, showing NO3-N + NO2-N concentrations above and below a clearcut. Basin-wide fertilization occurred after the October, 2004 sampling. 78 BB Main Beeby Creek 2002 - 2003 BB Trib. 1 BB Trib. 2 1.400 1.200 1.000 0.800 0.600 0.400 O ct .‘ 03 03 ‘0 3 .‘ Au g Ju e ly ‘0 3 3 ‘0 Ju n 03 .‘ M ay ‘0 3 ar . M Ap r 3 ‘0 Fe b. Ja n. 0.000 ‘0 3 0.200 O ct .‘ 02 N ov .‘ 02 D ec .‘ 02 NO3-N + NO2-N (mg L-1) 1.600 Month Figure 3.5. Beeby Creek and its two main tributaries, showing NO3-N + NO2-N concentrations. Trib. 1 is forested except for ~ 5% of its edge. Trib. 2 has~ 50% clearcut at its headwaters. The rest of the Beeby Creek basin is forested. BB Main Beeby Creek 2003- 2005 BB Trib. 1 2.000 BB Trib. 2 NO3-N + NO2 -N (mg L-1) 1.800 1.600 1.400 1.200 1.000 0.800 0.600 0.400 5 M ay ‘0 05 Ja n. ‘ 04 .‘ O ct ‘0 4 Ju ly 04 Ap r. ‘ 04 Fe b. ‘ De c. 0.000 ‘0 3 0.200 Month Figure 3.6. Beeby Creek and its two main tributaries, showing NO3-N + NO2-N concentrations. Trib. 1 is forested except for ~ 5% of its edge. Trib. 2 has ~ 50% clearcut at its headwaters. The rest of the Beeby Creek basin is forested. 79 North Fork Hinkle Creek 2002 - 2003 South Fork 0.200 0.150 0.100 M ar .‘ 03 Ap r. ‘0 3 M ay ‘0 3 Ju ne ‘0 3 Ju ly ‘0 3 Au g. ‘0 3 O ct .‘ 03 No v. O 0.000 ‘0 2 De c. ‘0 2 Ja n. ‘0 3 Fe b. ‘0 3 0.050 ct .‘ 02 NO3-N + NO2-N (mg L-1) 0.250 Month Figure 3.7. Hinkle Creek North and South Forks, showing NO3-N + NO2-N concentrations. North Fork Hinkle Creek 2003 - 2005 South Fork 0.600 NO3-N + NO2-N (mg L-1) 0.500 0.400 0.300 0.200 0.100 0.000 Dec. ‘03 Feb. ‘04 Apr. ‘04 July ‘04 Month Oct. ‘04 Jan. ‘05 May ‘05 Figure 3.8. Hinkle Creek North and South Forks, showing NO3-N + NO2-N concentrations. Basin-wide fertilization occurred after the October, 2004 sampling. 80 Myers Hinkle Streams 2002 - 2003 DeMearsman Russell 0.060 Fenton NO3-N + NO2-N (mg L-1) 0.050 0.040 0.030 0.020 ‘0 3 Au g. ‘0 3 O ct .‘ 03 Ju ly ‘0 3 Ju ne M ay ‘0 3 Ap r. Ja n. ‘0 3 Fe b. ‘0 3 M ar .‘ 03 ‘0 2 D ec . ov .‘ 02 N O ct .‘ 02 0.000 ‘0 3 0.010 Month Figure 3.9. Hinkle Creek Watershed creek NO3-N + NO2-N concentrations. Fenton and Russell Creeks are treatment basins and Myers and DeMearsman Creeks are controls. All basins are completely forested. Myers Hinkle Streams 2003 - 2005 DeMearsman Russell 0.800 Fenton NO3-N + NO2-N (mg L-1) 0.700 0.600 0.500 0.400 0.300 0.200 0.100 0.000 Dec. ‘03 Feb. ‘04 Apr. ‘04 July ‘04 Month Oct. ‘04 Jan. ‘05 May ‘05 Figure 3.10. Hinkle Creek Watershed creek NO3-N + NO2-N concentrations. Fenton and Russell Creeks are treatment basins and Myers and DeMearsman Creeks are controls. All basins are completely forested. Basin-wide fertilization occurred after the October 2004 sampling. 81 Table 3.19. Stream chemistry data from H.J. Andrews WS#10 weir from 1973-75 . Stream nutrients Conc. (mg L-1) 0.019 NO3-N + NO2-N 0.035 Kjeldahl N 0.054 Total P 1.96 Na 0.339 K 3.20 Ca 0.834 Mg 4.17 Alkalinity HCO3–C Data from Sollins et al. (1980). Table 3.20. Average inorganic and organic N concentrations for three Douglas-fir old-growth dominated streams at the H.J. Andrews Experimental Forest. Concentration mg L-1 NO3-N NH4-N DONa PONb a WS #2 (1982-2001) 0.001 0.007 0.020 0.020 WS #9 (1969-2001) 0.003 0.008 0.040 0.020 WS #8 (1972-2001) 0.004 0.009 0.020 0.010 DON denotes dissolved organic N. PON denotes particulate organic N. Data from Vanderbilt et al. (2003). b Table 3.21. Annual mean NO3-N (mg L-1) concentrations for three streams in the Alsea River basin both before (1965-1966) and after (1967-1968) treatments. Year 1965 1966 1967 1968 Flynn Creek (uncut control) 1.21 1.16 1.18 1.18 Needle Branch (clear-cut) 0.12 0.19 0.44 0.43 Data from Brown et al. (1973). Deer Creek (patch-cut) 1.12 0.98 1.21 1.12 82 Table 3.22. Yearly flow rated average nutrient concentrations of several streams in the Oregon Coast Range in 2000. Concentration NO3-N (mg L-1) DON (mg L-1) Ca (µeq L-1) Mg (µeq L-1) Na (µeq L-1) K (µeq L-1) Teal Creek 1.352 0.052 363 207 638 18 µeq L-1 = microequivalents per liter Data from Compton et al. (2003). Baxter Creek 1.203 0.063 71 85 162 12 Curl Creek 0.875 0.048 356 200 291 6 Bear Creek 0.652 0.047 274 192 243 11 Slick Rock 0.074 0.020 133 65 110 4 Table 3.23. T-test results comparing Hinkle Creek Watershed creek NO3-N + NO2-N concentrations among streams with different clear-cut percentages. Creek T df P-value Hinkle N.F. vs. Hinkle S.F. 4.47 32 P = 0.0001 Beeby vs. Myers 6.46 32 P < 0.0001 Beeby vs. DeMearsman 6.51 32 P < 0.0001 Beeby vs. Fenton 6.42 32 P < 0.0001 Beeby vs. Russell 6.34 32 P < 0.0001 Beeby vs. Clay 6.16 32 P < 0.0001 Clay A vs. Clay B 1.15 13 P = 0.272 Salmon River 0.167 0.033 151 92 140 4 83 Table 3.24. T-test results comparing four Hinkle Creek headwater treatment creeks with two headwater control creeks for effects of urea N fertilization in fall, 2004. Nitrogen type T-test value df P value Sampled 1-25-05 4.95 4 P < 0.01 Total N 0.52 4 NS* Dissolved organic N 4.24 4 P < 0.02 NO3 – N + NO2 – N 1.85 4 NS NH4 – N Sampled 5-25-05 Total N Dissolved organic N NO3 – N + NO2 – N NH4 – N * Not significant 3.06 3.24 4 4 P < 0.05 P < 0.05 2.83 1.04 4 4 P < 0.05 NS Table 3.25. Nitrogen exported from the North and South Forks of Hinkle Creek for the calendar year 2004. NH4 - N Total dissolved Total dissolved NO3 - N + Creek NO2 - N organic N N ‹--------------------------------------kg yr-1---------------------------------› 196* 245 33 16 North Fork 256 780 469 55 South Fork ‹----------------------------------- kg ha-1 yr-1------------------------------› 0.224 0.281 0.038 0.018 North Fork 0.241 0.735 0.442 0.052 South Fork *Mean values. Standard errors (S.E.) are approximately 25% of mean values. 84 Chapter 4: Conclusion and Predictions This study focused primarily on cataloguing baseline stream chemistry and soil resources for a new experimental forest located on private industrial forest land owned by Roseburg Forest Products. This information will be valuable for future researchers to use to catalogue any changes that occur. The stream chemistry data are all pre-treatment except for some additional research added by sampling water and soils from pre-existing clearcuts. A limitation of this study is that there were no pre-treatment data for these clearcut sample sites, so a statistically robust conclusion cannot be drawn. However, qualitative inferences gleaned from information collected from the pre-existing treatments can be discussed. The statistical comparisons for the increased stream N concentrations observed after urea N fertilization permitted use of two sample T-tests (Ramsey and Schafer, 2002). The treatments occurring at Hinkle Creek Research and Demonstration Area Project are in line with current modern forest industrial practices which include clearcutting, slash pile burning, fertilization and robust vegetation control using herbicide for two years after harvest. It seems likely that the stream chemistry patterns observed for Beeby and Clay Creeks will be repeated in the rest of the basin. Most of the nutrient concentrations measured in the water coming from the clearcuts will change little, as many other studies have found (Brown et al., 1973; Martin and Harr, 1989; Binkley and Brown, 1993). Nitrogen, especially NO3-N + NO2-N, will increase dramatically in areas of steep slope and shallow, rocky soils overlaying bedrock. The increase in NO3-N + NO2-N may be less in areas with deep soils and lower slope gradients, but still will occur. 85 The duration of these changes also will depend upon the decomposition rates of slash and organic debris left on the clearcuts, and upon vegetation re-establishment and the increased uptake of inorganic N. Martin and Harr (1989) and Dahlgren (1998) both found that nitrate levels returned to normal within three years of clearcutting. The treatments for these studies were clearcutting and broadcast burning of slash. Needle Branch Watershed, in the Alsea basin study, increased from 0.70 to and 2.10 mg L-1 NO3 –N and took six years to return to pre-treatment levels (Brown et al., 1973). This research area also was clearcut and broadcast burned. The difference between these studies and Hinkle Creek is the complete suppression of vegetation for two years. Broadcast burning sets the stage for vigorous vegetation growth following the burn, and vegetative uptake of inorganic N compounds. The forester usually hopes that seedlings, during the two years after treatment, are the only vegetation getting nutrients from the soil. Due to the large percentage of bare ground around the seedlings after broadcast burning and herbicide application, increased leaching of inorganic N can occur (Kimmins, 1997; Yildiz, 2000). As organic debris left on the watershed undergoes decomposition and N mineralization, this nutrient leaches out through the soil solution and into the stream water. For example, the clearcut portion of Beeby Creek still showed high levels of NO3-N + NO2-N five years after clearcutting and herbicide treatment. An unfortunate planting failure occurred on the 2001 Beeby Creek Tributary 2 clearcut, apparently due to defective nursery seedlings, thus delaying reforestation (Richard S. Beeby, Roseburg Resources, Co., personal communication, 2004). The highest levels of NO3-N + NO2-N recorded in this study were 1.75 mg L-1 in December of 2003 in Beeby Creek Tributary 2. This is well below the EPA guidelines 86 -1 for safe drinking water of 10 mg L . However, it was three to four orders of magnitude higher than NO3-N + NO2-N concentrations observed in other headwater streams located in the Hinkle Creek drainage. The effects of an increase of this magnitude upon the functional ecology of a stream system which evolved under conditions of N limitation are hard to gauge, but should not be ignored. If stream discharge followed a similar trajectory, the scientific community and landowners would take notice. Forest recovery from tree replanting and from natural succession processes are important in protecting the soil surface. Moreover, the water samples collected also only measure inorganic N that has not been taken up by stream biota. Bernhardt et al. (2003) found that in-stream N uptake dampens export of this nutrient. The magnitude of NO3-N entering the stream may be much higher than recorded and may impact the stream biota in an unanticipated manner, possibly by increasing stream primary production. Aerial fertilization with urea, even with the inclusion of wide buffer strips around riparian zones, still increases stream N export substantially, even though the total amounts of N lost were a small fraction of the 202 kg ha-1 N applied to Hinkle Creek forests. Hinkle Creek North Fork continued to show an increase of three orders of magnitude for NO3-N + NO2-N three months after urea application. If samples had been taken after the first precipitation event following fertilization, these levels may have been much higher, especially for DON (Moore, 1975). The long-term implications of repeated N-fertilizer use throughout future stand rotations in intensive forest management will have to be considered (Johnson, 2006). 87 Future impacts on soil resources are hard to predict until after various management treatments occur. Soils will react very differently, depending on the locations of the soil pits in relation to skid trails, roads, slash piles, etc. Soil pits which were dug where a skid road or landing later is placed will most likely see an increase in bulk density and a lowering of C content (Heninger et al., 2002). Soils surrounding pits which are located in the middle of the treatment area may undergo little change, while those under a slash pile burn would have substantial changes in soil chemistry. A more comprehensive sampling of soils could be undertaken to follow long-term changes in soil nutrient pools, especially soil C and N (Homann et al., 2001, 2004). The stand that was clearcut along the headwaters of Beeby Creek was a remnant of old-growth Douglas-fir (Pseudotsuga menziesii) and western redcedar (Thuja plicata Donn). Judging from the small diameter, tight growth rings and wide spacing of the stumps in the clearcut, the original stand had difficulty becoming established here. Forest managers may want to take more into account the type of soils present in an area that is to be clearcut and the previous stand characteristics. Five years after treatment, the 2001 clearcut along the headwaters of Beeby Creek still has little to no regeneration of conifer seedlings. It is still exporting relatively large amounts of NO3-N + NO2-N compared to the other watersheds. Long-term stand productivity may be affected, and better uses for the land or different management objectives may be ecologically and economically more feasible for landscapes such as the headwaters of Beeby Creek. As these forests recover from clearcutting, it will be worthwhile to consider adding work on riparian ecosystem functions (Triska et al., 1989, 1993; Wondzell and Swanson, 1996; Jones and Mulholland, 2000; Naiman et al., 2005), especially along stream reaches of the 88 major tributary creeks of the North and South Forks of Hinkle Creek. The headwater streams present additional opportunities for riparian research. Future research opportunities will exist for studying forest productivity and succession processes in the intensively managed young stands that will develop in the Hinkle Creek Basin (Busse et al., 1996; Kimmins 1997; Fisher and Binkley, 2000; Fox, 2000). 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USDA Forest Service General Technical Report No. PSW-GTR-168, pp. 15-24. 96 APPENDICES 97 Appendix Tables A1.1 through A1.5 provide explanations for the column headers and abbreviations used in Appendix Tables A2.1 through A2.27. Nomenclature used is from Schoenberger et al. (2002). Table A1.1 Soil horizon legend. HOR Horizon In cm Depth Munsell charts Color Coarse fragments > 4mm Coarse Stoniness % stones and boulders Table A1.2 Soil boundary legend. BDRY Boundary Clear C Wavy W Gradual G Smooth S Diffuse D Abrupt A Irregular I Table A1.3 Soil texture legend. TEXT Texture Silt Loam SIL Gravelly Loam GRL Silty Clay Loam SICL Silty Clay SIC Very Gravelly VGR Clay Loam CL Loam L Sandy Loam SL Clay C 98 Table A1.4 Soil structure legend. STRUCT Structure Strong 3 Fine F Granular GR Coarse CO SBK Sub angular Blocky Moderate 2 Medium M Weak 1 Massive MA Table A1.5 Soil consistency legend. CONSIST Consistency Strong S Hard H Friable FR Very V Sticky S Plastic P Non Plastic PO Non Sticky SO Slightly Plastic SP Slightly Sticky SS 99 Table A2.1 Soil pit # 1 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 43 24' 13.699308"N 123 02' 02.69954"W SLOPE ASPECT PIT NUMBER N 1 17% STONINESS 10-15% ELEVATION 627 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Old landflow COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 0-2.5 CW 10yr 2/1 SIL 3FGR Sh/FR/PO/SO 15% A 2.5 - 23 GW 10yr 3/2 GRL 3COGR Sh/FR/PO/SS 10% AB 23 - 41 DS 10yr 3/3 SIL 2MSBK SFI/P/SO 5% BA 41 - 76 DS 10yr 3/5 SICL 1MSBK FR/VP/SS 0% B 76 - 125+ 10yr 4.5/4 SIC MA VF/VP/S 0% Table A2.2 Soil pit # 2 description. SOIL SERIES Illahee Rock Outcrop LATITUDE & LONGITUDE o o 43 24' 16.98851"N 123 00' 27.84114"W SLOPE ASPECT PIT NUMBER NNW 2 65% STONINESS 10-15% ELEVATION 871 m PARENT MATERIAL Colluvium volcanic tuff breccia HOR DEPTH BDRY PHYSIOGRAPHY Colluvial toeslope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 0 -1.5 AS 10yr 2/1 SIL 3FGR Sh/FR/PO/SO 40% A 1.5 - 18 GW 10yr 3/2 VGRSIL 3COGR Sh/FR/PO/SO 37% BA 18 - 38 DW 10yr 3/3 CL 1MSBK FR/PO/SO 37% B 38 - 75+ 10yr 3/4 CL 1MSBK FR/PO/SO 37% 100 Table A2.3 Soil pit # 3 description. SOIL SERIES Kinney Harrington LATITUDE & LONGITUDE o o 43 24' 16.98851"N 123 00' 27.84114"W SLOPE ASPECT PIT NUMBER 3 W 75% STONINESS 20% ELEVATION 871 m PARENT MATERIAL Colluvium volcanic scree HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 0-2.5 CW 10yr 2/1 VGRSIL 3FGR VFR/PO/SO 65% A 2.5 - 30 GW 10yr 3/2 VGRL 1MGR VFR/PO/SO 75% C 30 - 80+ 10yr 3/3 VGRSIL 1MGR VFR/PO/SO 75% Table A2.4 Soil pit # 4 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 123 01' 52.37869"W 43 24' 27.15759"N SLOPE ASPECT PIT NUMBER N 4 25% STONINESS 15% ELEVATION 558 m PARENT MATERIAL Colluvium volcanic tuff breccia HOR DEPTH BDRY PHYSIOGRAPHY Old landflow COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O Missing A 0 - 15 CW 10yr 4/4 SIC 1MGR P/S 15% BE 15 - 51 DI 10yr 4/5 C 2MSBK P/S 0% B 51 - 70 CI 10yr 5/4 SIC 1MSBK P/S 0% BC 70+ 10yr 5/1 C MA VP/S 0% 101 Table A2.5 Soil pit # 5 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 43 24' 27.07729"N 123 01' 48.91094"W SLOPE ASPECT PIT NUMBER N 5 30% STONINESS 25% ELEVATION 556 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Old landflow COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O Missing A 0 - 10 GS 10yr 3/2 L 3MGR PO/SO 30% E 10 - 25.1 CS 10yr 3/3 SIL 3COGR SP/SO 30% B 25 - 76 CW 7.5yr 4/4 SIC 3MSBK P/S 20% BC 76 - 127+ 10yr 4/6 C 1COSBK VP/S 16% Table A2.6 Soil pit # 6 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 123 01' 11.48780"W 43 24' 34.69350"N SLOPE ASPECT PIT NUMBER E 6 85% STONINESS 0% ELEVATION 591 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O Missing A 0 - 2.5 GW 10yr 3/2 SIL 3MGR PO/SO 0% E 2.5 - 13 DW 10yr 3/3 SIL 1FSBK SP/SO 0% BE 13 - 46 D 10yr 3/4 SICL 1MSBK P/SO 0% B 46 - 89 CS 7yr 3/4 SICL 1COSBK P/S 0% 102 Table A2.7 Soil pit # 7 description. SOIL SERIES Kinney Harrington LATITUDE & LONGITUDE o o 43 24' 34.69350"N 123 01' 11.48780"W SLOPE ASPECT PIT NUMBER W 7 80% STONINESS 90+% ELEVATION 591m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O Missing A 0 - 23 GW 10yr 2/2 SIL 3MGR PO/SO 80% BE 23 - 61 D 7.5yr 3/3 SIL 3COGR SP/SO 80% B 61 - 102+ 7.5yr 3/4 SIL 1FSBK FR/SP/SO 70% TEXT STRUCT CONSIST COARSE Table A2.8 Soil pit # 8 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 43 24' 19.04637"N 123 02' 31.62661"W SLOPE ASPECT PIT NUMBER N 8 15% STONINESS 0% ELEVATION 577 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Convex slope COLOR DRY MOIST O Missing A 0 - 2.5 CW 10yr 3/3 SICL 3FGR P/SS 10% E 2.5 - 15 CW 10yr 4/3 SICL 2COGR P/SS 10% BE 15 - 25 CW 10yr 4/6 SIC 2FSBK P/SS 10% B 25 - 64 G 10yr 5/3 SIC 1COSBK VP/S 0% BC 64 - 102+ 10yr 5/1 C 1MSBK P/S 103 Table A2.9 Soil pit # 9 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 43 24' 09.00433"N 123 01' 28.56712"W SLOPE ASPECT PIT NUMBER 9 30% NNE STONINESS 15% ELEVATION 675 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O Missing A 0 - 20 GW 10yr 3/3 SICL 2MGR P/S 15% BE 20 - 36 CW 7.5yr 3/3 SICL 2COGR P/SS 20% B 36 - 91 GS 7.5yr 4/6 SIC 2MSBK P/SS 30% BC 91 -127+ 10yr 4/6 C 2COSBK P/S 30% STRUCT CONSIST COARSE Table A2.10 Soil pit # 10 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 123 01' 33.84571"W 43 25' 14.49470"N SLOPE ASPECT PIT NUMBER N 10 20% STONINESS 5% ELEVATION 517 m PARENT MATERIAL Colluvium volcanic tuff BDRY PHYSIOGRAPHY Old land flow DRY O 2.5 - 0 CS Litter and Organic Matter A 0 - 13 G 10yr 3/2 SIL 2MGR SP/SO 5% E 13 - 31 G 10yr 3/4 SICL 2COGR P/SO 3% BE 31 - 51 G 10yr 4/4 SIC 2MSBK P/SS 0% B 51 - 102 G 10yr 4/6 SIC 1COSBK P/S 0% BC 102 - 127+ 10yr 4/6 CL MA P/S 0% HOR DEPTH COLOR TEXT MOIST 104 Table A2.11 Soil pit # 11 description. SOIL SERIES Klickitat Harrington LATITUDE & LONGITUDE o o 43 26' 04.46722"N 123 00' 44.05280"W SLOPE ASPECT PIT NUMBER 11 100% NW STONINESS 35% ELEVATION 625 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 2.5 - 0 CS Duff, non incorporated A 0 - 10 GS 10yr 3/2 SIL 2COGR SP/SO 25% E 10.1 - 31 GS 7.5yr 3/3 SICL 2COGR P/S 40% BE 31 - 64 CW 7.5yr 3/4 CL 3COGR P/SS 65% TEXT STRUCT CONSIST COARSE Table A2.12 Soil pit # 12 description. SOIL SERIES Lempira Gravelly Loam LATITUDE & LONGITUDE o o 123 00' 40.90326"W 43 26' 36.48751"N SLOPE ASPECT PIT NUMBER 12 7% NW STONINESS 10% ELEVATION 948 m PARENT MATERIAL Colluvium + Residuum HOR DEPTH BDRY PHYSIOGRAPHY Bench COLOR DRY MOIST O Missing A 0 - 36 CW 10yr 2/2 SIL 2FGR SP/SO 15% BE 36 - 56 GS 10yr 3/3 SICL 1MSBK P/SS 0% B 56 - 92 GS 7.5yr 4/4 C 3MSBK VP/S 0% BC 92 - 112 GS 10yr 4/5 C 1COSBK VP/S 0% BCg 112 - 127+ 10yr 4/2 C MA VP/S 0% 105 Table A2.13 Soil pit # 13 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 43 25' 20.93428"N 123 02' 12.59405"W SLOPE ASPECT PIT NUMBER W 13 4% STONINESS 10% ELEVATION 426 m PARENT MATERIAL Colluvium / Alluvium HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 5.2 - 0 CS Duff, non incorporated A 0 - 2.5 CS 10yr 2/1 GRL 1FGR PO/SO 18% E 2.5 - 13 CW 10yr 2/2 CL 2COGR P/SS 12% BE 13 - 31 G 10yr 4.5/3 SIC 2MSBK VP/S 10% B 31 - 107 DG 10yr 4/4 C 2MSBK VP/S 25% BC 107 - 127+ 10yr 4/4 C MA VP/S 30% STRUCT CONSIST COARSE Table A2.14 Soil pit # 14 description. SOIL SERIES Honeygrove Gravelly Loam LATITUDE & LONGITUDE o o 123 02' 16.33969"W 43 25' 13.68649"N SLOPE ASPECT PIT NUMBER E 14 27% STONINESS 15% ELEVATION 450 m PARENT MATERIAL Colluvium old landflow HOR DEPTH BDRY PHYSIOGRAPHY Uneven slope COLOR DRY TEXT MOIST O 1.5 - 0 CS Duff, non incorporated A 0 - 31 CW 5yr 3/3 L 3FGR PO/SO 25% BE 31 - 69 GS 5yr 5/5 SIC 2FSBK P/SS 10% B 69 - 122 GS 2.5yr 3/6 C 3MSBK VP/S 5% BC 122 - 183+ 2.5yr 2.5/6 C 3MSBK VP/S 5% 106 Table A2.15 Soil pit # 15 description. SOIL SERIES Honeygrove Gravelly Loam LATITUDE & LONGITUDE o o 43 25' 00.89508"N 123 02' 37.84452"W SLOPE ASPECT PIT NUMBER N 15 5% STONINESS 5% ELEVATION 487 m PARENT MATERIAL Colluvium Brome Creek Flow HOR DEPTH BDRY PHYSIOGRAPHY Bench overland flow COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 2.5 - 0 CS Duff, non incorporated A 0 - 23 CW 5yr 3/3 SICL 3COGR P/SS 5% BE 23 - 51 GS 7.5yr 4/4 SIC 3FSBK VP/SS 0% B 51 - 99 GS 5yr 4/6 C 2MSBK VP/SS 0% BC 99- 127+ 5yr 4/6 C 3COSBK VP/S 0% Table A2.16 Soil pit # 16 description. SOIL SERIES Illahee-Mellowmoon-Scaredman Complex LATITUDE & LONGITUDE o o 123 00' 07.46654"W 43 26' 41.95404"N SLOPE ASPECT PIT NUMBER 16 22% NW STONINESS 5% ELEVATION 1090 m PARENT MATERIAL Residuum strongly weathered tuff HOR DEPTH BDRY PHYSIOGRAPHY Convex ridge top COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O Missing A 0 - 28 GS 10yr 2/2 L 2MGR FR/PO/SO 13% E 28 - 43 GW 10yr 3/2 SIL 2MGR FR/PO/SO 0% BE 43 - 69 GD 10yr 4/3 SICL 1FSBK SP/SO 0% B 69 - 122 GD 10yr 4/6 SICL 2MSBK P/SO 0% Bt 122 - 152+ 10yr 5/4 SICL 1COSBK P/SO 0% 107 Table A2.17 Soil pit # 17 description. SOIL SERIES Illahee-Mellowmoon-Scaredman Complex LATITUDE & LONGITUDE o o 43 26' 47.96423"N 123 00' 24.32634"W SLOPE ASPECT PIT NUMBER 17 50% WSW STONINESS 45% ELEVATION 1018 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 2.5 - 0 CS Duff, non incorporated A 0-5 CS 10yr 2/1 VGRL 3FGR PO/SO 45% E 5.0 - 36 G 10yr 3/2 VGRL 2FGR PO/SO 45% EB 36 - 51 GD 10yr 3/3 VGRL 1MGR PO/SO 45% BE 51 - 114 GD 10yr 4/3 VGRL 1MGR PO/SO 45% Bt 114 - 153 10yr 4/4 VGRL 1MGR PO/SO 45% STRUCT CONSIST COARSE Table A2.18 Soil pit # 18 description. SOIL SERIES Klickitat Kinney LATITUDE & LONGITUDE o o 122 59' 54.91424"W 43 25' 58.91110"N SLOPE ASPECT PIT NUMBER 18 55% SSW STONINESS 30% ELEVATION 1009 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT MOIST O 1.5 - 0 CS Duff, non incorporated A 0 - 20 GW 7.5yr 3/2 GRCL 1MGR PO/SO 45% BA 20 - 41 G 7.5yr 3/3 GRCL 2MSBK P/SS 45% B 41 - 66 G 7.5yr 3/4 SICL 2MSBK P/S 45% 108 Table A2.19 Soil pit # 19 description. SOIL SERIES Klickitat Harrington LATITUDE & LONGITUDE o o 43 26' 33.50883"N 123 01' 14.26269"W SLOPE ASPECT PIT NUMBER 19 S 55% STONINESS 50% ELEVATION 876 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 0.5 - 0 CS Duff, non-incorporated A 0 - 25 GS 10yr 2/2 VGRL 3MGR PO/SO 75% E 25 - 48 CS 10yr 3/2 VGRL 2MGR SP/SO 65% B 48 - 61 CW 10yr 3/2 VGRL 1COGR SP/SO 60% STRUCT CONSIST COARSE Bedrock Table A2.20 Soil pit # 20 description. SOIL SERIES Klickitat Harrington LATITUDE & LONGITUDE o o 123 00' 47.80426"W 43 25' 28.40341"N SLOPE ASPECT PIT NUMBER 20 60% NW STONINESS 10% ELEVATION 767 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT MOIST O 1.5 - 0 CW Duff, non-incorporated A 0 - 2.5 CS 10yr 2/1 GRL 1MGR PO/SO 20% E 2.5 - 36 CW 5yr 3/3 CL 2MGR SP/SO 12% BE 36 - 76 GW 2.5yr 3/3 SIC 1MSBK SP/SO 12% B 76 - 127 5yr 4/4 C 2MSBK P/S 10% 109 Table A2.21 Soil pit # 21 description. SOIL SERIES Orford Gravelly Loam LATITUDE & LONGITUDE o o 43 25' 10.67336"N 122 59' 59.26102"W SLOPE ASPECT PIT NUMBER 21 S 10% STONINESS 20% ELEVATION 894 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Undulating bench COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 2.5 - 0 CS Duff, non-incorporated A 0-8 CS 7.5yr 2/2 GRL 2FGR PO/SO 20% E 8.1 - 38 CW 7.5yr 3/3 GRL 3COGR SP/SO 25% BE 38 - 97 G 5yr 3/4 SICL 2MSBK P/SS 12% B 97 - 127 G 7.5yr 3/4 SIC 2MSBK P/S 13% Bct 127+ 7.5yr 3/4 SIC MA P/S 20% STRUCT CONSIST COARSE Table A2.22 Soil pit # 22 description. SOIL SERIES Klickitat Harrington LATITUDE & LONGITUDE o o 123 00' 28.49329"W 43 24' 54.13763"N SLOPE ASPECT PIT NUMBER 22 S 80% STONINESS 15% ELEVATION 730 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT MOIST O 1.5 - 0 CW Duff, non-incorporated A 0-8 CS 7.5yr 2/2 VGRL 2FGR PO/SO 40% E 8.1 - 25 CW 7.5yr 3/3 VGRL 2COGR SP/SO 40% BE 25 - 48 GS 7.5yr 3/4 SICL 2MSBK P/SS 35% B 48 - 61 AI 5yr 3/4 SIC 2FSBK P/S 45% Bedrock 110 Table A2.23 Soil pit # 23 description. SOIL SERIES Illahee Rock Outcrop Complex LATITUDE & LONGITUDE PIT NUMBER 23 PHYSIOGRAPHY Planar slope STONINESS 20% ELEVATION 901 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY No reading, thick brush SLOPE ASPECT 90% NNE COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O Missing A 0-8 CS 10yr 3/3 GRSIL 1FGR PO/SO 25% E 8.1 - 28 GW 10yr 4/3 VGRSIL 2COGR PO/SO 40% C 76+ 10yr 4/5 VGRSIL 1FSBK PO/SO 70% TEXT STRUCT CONSIST COARSE VGRL 2MGR PO/SO 70% Table A2.24 Soil pit # 24 description. SOIL SERIES Klickitat Harrington LATITUDE & LONGITUDE o o 123 00' 13.41586"W 43 24' 22.14790"N SLOPE ASPECT PIT NUMBER W 24 65% STONINESS 50% ELEVATION 1071 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH O Missing AC 0 - 38 Bedrock BDRY PHYSIOGRAPHY Planar slope AS COLOR DRY MOIST 10yr 2/2 111 Table A2.25 Soil pit # 25 description. SOIL SERIES Klickitat Harrington LATITUDE & LONGITUDE o o 43 26' 14.39903"N 122 59' 57.68543"W SLOPE ASPECT PIT NUMBER N 25 95% STONINESS 40% ELEVATION 928 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT STRUCT CONSIST COARSE MOIST O 2.5 - 0 CW Duff, non-incorporated A 2.5 - 31 CW 10yr 2/2 GRL 3FGR PO/SO 50% E 31 - 66 CW 7.5yr 3/2 GRL 2MGR PO/SO 50% AC 66 - 89 GW 10yr 3/3 GRL 2MGR PO/SO 40% C 89+ AI 7.5yr 3/3 GRL 1COGR PO/SO 45% STRUCT CONSIST COARSE Table A2.26 Soil pit # 26 description. SOIL SERIES Klickitat Harrington LATITUDE & LONGITUDE o o 123 00' 24.13669"W 43 26' 24.10439"N SLOPE ASPECT PIT NUMBER 26 W 60% STONINESS 50% ELEVATION 911 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope COLOR DRY TEXT MOIST O 2.5 - 0 CS Duff, non-incorporated A 0 - 10 CS 7.5yr 2/2 VGRL 2FGR PO/SO 40% E 10.1 - 36 CW 7.5yr 3/2 CL 1MGR SP/SO 70% BE 36 - 76 GS 7.5yr 3/4 SICL 1MSBK P/SO 60% BC 76 - 122 G 10yr 4/4 SIC 1COSBK P/SS 55% C 122 - 140+ 10yr 3/4 SIL MA P/SS 15% 112 Table A2.27 Soil pit # 27 description. SOIL SERIES Honeygrove Gravelly Loam LATITUDE & LONGITUDE o o 43 26' 00.19443"N 123 01' 08.94762"W SLOPE ASPECT PIT NUMBER 27 20% NW STONINESS 40% ELEVATION 618 m PARENT MATERIAL Colluvium volcanic tuff HOR DEPTH BDRY PHYSIOGRAPHY Planar slope O 2.5 - 0 CS Duff, non-incorporated A 0 - 10 CS 5y r2/2 SIL 2MGR PO/SO 10% 10.0 - 41 GW 5yr 3/3 SIC 2COGR P/SS 5% E COLOR DRY MOIST TEXT STRUCT CONSIST COARSE BE 41 - 97 GW 7.5yr 4/6 C 2FSBK VP/S 0% Bt 97 - 127 CS 7.5yr 5/6 C 3MSBK VP/S 0% C 127+ 10yr 4/6 SIC MA P/SS 0% Table A2.28. Comments for Soil Pits 1 - 27: Pit No. Comments 1. Occasional coarse 10yr 5/2.5 mottles below 90 cm. 2. Possibly a Harrington inclusion. Moderately deep and well-drained. Many fine and medium roots throughout profile. 3. Abundant roots throughout profile. 4. Constructional topography once land flow became immobile. 5yr 5/6 irregular inclusions, clay skins and mottles below BE. 5. Deep and well-drained. 6. Deep and well-drained. 7. Very deep skeletal soils. 8. Abundant mottles 7.5yr 5/1, 5yr 5/8 below BE horizon. Roots very abundant in A horizon and almost nonexistent in B. Probably poorly drained due to mottles. 9. Well-drained deep soil. Rock fragments heavily weathered and roots common throughout. 10. Few coarse prominent 10yr 5/2, 7.5yr 5/8 mottles in BC horizon. Deep and welldrained. 11. Abundant fine, medium and coarse roots throughout profile. 113 12. Deep and well-drained. BCg has common coarse prominent 5yr 4/6, 10yr 4/2 mottles. 13. Deep and well-drained. 14. Deep and well-drained. Common abundant medium/fine roots throughout. 15. Common and continuous clay skins below 100 cm. 16. Many fine/medium roots through BE horizon, common in B and few in Bt. 17. Abundant fine–coarse roots throughout profile. 18. Well-drained. Fractured basalt bedrock. 19. Abundant fine–coarse roots throughout profile. 20. Deep and well-drained. 21. Deep clay soil with rotten paragravel in BCt. 22. Shallow, steep well-drained soil. 23. Abundant fine and medium roots until C horizon, then few. 24. Shallow, well-drained skeletal soil on top of bedrock. Becomes saturated very quickly and is a possible explanation for high nitrate leaching associated with watershed. 25. Very steep, rock mulch soil. 26. Skeletal soil with large boulders. C horizon has abrupt soil change that appears to be colluvium associated with a terminal moraine covering an older pre-existing soil. 27. Deep, heavily weathered profile. Abundant fine–medium roots throughout.