THE INFLUENCE OF MINERALOGY, CHEMISTRY AND PHYSICAL ENGINEERING PROPERTIES ON SHEAR STRENGTH PARAMETERS OF THE GOATHILL ROCK PILE MATERIAL, QUESTA MOLYBDENUM MINE, NEW MEXICO by Luiza Aline Fernandes Gutierrez Submitted in partial fulfillment of the requirements for the Degree of Master of Science in Mineral Engineering with Specialization in Geotechnical Engineering New Mexico Institute of Mining and Technology Department of Mineral Engineering Socorro, New Mexico March, 2006 ABSTRACT This thesis develops information regarding the engineering characteristics (direct shear, Atterburg Limits, particle size) of the Goathill North (GHN) rock pile material at the Questa molybdenum mine in New Mexico and examines correlations with chemistry, mineralogy, particle size distribution and weathering indexes (SWI – simple weathering index, WPI – weathering potential index, MI – Muira index). Results of peak internal friction angle () ranged from 40º to 47º and residual friction angle varied between 37º and 41º. These high values of peak internal and residual friction angle are attributed to grain shape (subangular to very angular) and relative density of the test specimens. Correlations of from GHN samples with chemistry and mineralogy are shown to be weak or absent. Correlation of with lithology was not observed. Negative correlations were observed for %Fines, liquid limit, plasticity index, LOI (lost of ignition), SWI, WPI, and MI. The decreased as these parameters increased. Direct shear tests were performed using a 2-inch square shear box and air-dried samples with a maximum particle size of 3.36 mm (U.S standard sieve No. 6). A displacement rate of 0.5 mm/min (0.02 in/min), and normal stress varying from 159 to 800 kPa (23 to 116 psi) were adopted for all the tests. These tests were conducted on disturbed samples. The values determined from these tests should not be used for slope stability considerations. GHN rock pile samples were classified according to the United Soil Classification System (USCS as poorly- to well-graded gravel with fines and sand). The percent of fines (silt + clay size) and percent of clay varied from 3 to 19 and 0.3 to 6, respectively. Most of the fines were identified as CL-group (inorganic clay with low swell potential). ACKNOWLEDGEMENTS Support for this research was provided by the Molycorp Corporation. in the form of a Research Assistantship, by the WAAIME (The Woman’s Auxiliary to the American Institute of Mining, Metallurgical, and Petroleum Engineers), and by the New Mexico Bureau of Geology and Mineral Resources. I gratefully acknowledge this support. I would like to express my sincere appreciation to Dr. McLemore and Dr. Aimone-Martin for providing guidance, insight, and support throughout the course of this research. Appreciation is also extended to Dr. Mojtabai who is on the thesis advisory committee and who encouraged me to do my thesis research at New Mexico Tech. I would like to thank many people who provided insight and suggestions on this research: Dr. Virgil Lueth, Kelly Donahue, Erin Phillips, Fernando Junqueira, Dr. Fakhimi, Dr. Gundiler, Prof. Ward Wilson, Mike Smith, and other members of the Molycorp project weathering study. I especially want to thank Rick Lynn, Lynne Kurilovitch, Farid Sariosseri, Pedro Martin Moreno, Erico Tabosa, Vanessa Viterbo, Heather Shannon, Claudia Duarte, Alexandre, Igor, Armando and Jario for assistance with the laboratory testing program. Last but not least, I would like to thank Remke van Dam for all his support by reviewing my thesis thousand times, and literally going through this experience with me. This thesis is dedicated to my parents Marta Gutierrez and Zenon Gutierrez, my sisters Norma Gutierrez Ventura, Kelly Gutierrez Alves, Adela Gutierrez Branco, and to my lovely husband. TABLE OF CONTENT List of Tables………………………………………………………………...…………...iv List of Figures…………………………………………………………………...………...v 1. 2. 3. INTRODUCTION ...................................................................................................... 1 1.1. Background ......................................................................................................... 1 1.2. Thesis Objective.................................................................................................. 2 1.3. Site Description................................................................................................... 3 1.4. Thesis Outline ..................................................................................................... 8 REVIEW OF STUDIES AT GOATHILL NORTH ROCK PILE.............................. 9 2.1. Past Geotechnical Studies (Before Regrading) ................................................... 9 2.2. Present Work and Preliminary Results ............................................................. 14 LITERATURE REVIEW OF CONCEPTS RELATED TO THIS RESEARCH .... 20 3.1. Strength of Granular Materials ......................................................................... 20 3.2. Weathering Process ........................................................................................... 27 3.3. Effect of Weathering on Geotechnical Properties of Mine Rock ..................... 30 3.4. Published Grain Size distribution and Shear Strength Parameters for Mine Rock ........................................................................................................................... 34 4. METHODOLOGY ................................................................................................... 38 4.1. Sampling ........................................................................................................... 38 4.2. Particle Size Analysis ....................................................................................... 39 4.3. Direct Shear Test Under Consolidated Drained Conditions ............................. 44 4.3.1. 4.4. 5. Initial Test ................................................................................................. 47 Index Properties and Mineralogy ...................................................................... 54 RESULTS AND DISCUSSIONS ............................................................................. 55 i 5.1. Indices Testing .................................................................................................. 55 5.2. Direct Shear Test Results .................................................................................. 59 5.3. Verification of Direct Shear Test Results ......................................................... 61 5.4. Correlations of Direct Shear Results with Geological and Geotechnical Parameters ..................................................................................................................... 64 5.5. 6. Correlations of Direct Shear Test Results with Weathering Indices ................ 73 CONCLUSIONS AND RECOMENDATIONS ................................................... 7978 REFERENCES ............................................................................................................. 8180 APPENDIX A – SAMPLE LOCATION...................................................................... 8685 APPENDIX B – GRAIN SIZE DISTRIBUTION CURVES AND SUMMARY TABLE .. ............................................................................................................................... 8887 APPENDIX C – DIRECT SHEAR STRESS-STRAIN DIAGRAMS ..................... 118117 APPENDIX D – MOHR COULOMB DIAGRAMS................................................ 156154 APPENDIX E – DESCRIPTION OF GEOLOGIC UNITS, SUMMARY OF GEOLOGICAL AND GEOTECHNICAL DATA USED FOR CORRELATIONS 176174 APPENDIX F – STANDARD OPERATING PROCEDURES ............................... 186184 LIST OF TABLES ii Table 2.1. Summary of geotechnical properties at GHN rock pile ................................... 10 Table 2.2. Summary of friction angle of Molycorp mine rock piles and “weak zone” at GHN and their gradation results. ...................................................................................... 10 Table 3.1. Weathering field survey used to characterize the weathering sequence in the gneiss................................................................................................................................. 32 Table 3.2. Main engineering-geological features of weathered horizons near Acri (after Calcaterra et al., 1998). ..................................................................................................... 32 Table 3.3. Shear strength parameters of sedimentary residual soil with weathering grades varying from III to V......................................................................................................... 34 Table 3.4. Grain size distribution of rock piles around the world. ................................... 35 Table 3.5. Summary of mine rock values of friction angle and cohesion. ....................... 37 Table 4.1. The minimum specimen size required for particle size analysis according to the diameter of the largest particle (U.S. Army Corps of Engineers, 1970). .................... 41 Table 4.2. Summary of results of the 3 methods for particle size analyses. ..................... 43 Table 4.3. Summary of the results from direct shear tests using different maximum particle size and shear box size. ........................................................................................ 50 Table 4.4. Summary of the results from direct shear test using different maximum particle size. ................................................................................................................................... 52 Table 4.5. Summary of direct shear test results for samples at dry and moist state. ........ 52 Table 5.1. Summary of particle size analysis of samples from GHN by geologic unit. ... 56 Table 5.2. Summary of Atterberg limits results of samples from GHN by geologic unit. 57 Table 5.3. Summary of moisture content and paste pH results of samples from GHN by geologic units. ................................................................................................................... 57 Table 5.4. Summary of direct shear test results of samples from GHN by geologic units. ........................................................................................................................................... 60 iii LIST OF FIGURES Figure 1.1. Location of Molycorp Questa mine, northern Taos County, New Mexico. ..... 4 Figure 1.2. Aerial photo of Questa mine showing the nine rock piles adjacent to the open pit. ....................................................................................................................................... 4 Figure 1.3. Goathill North rock pile before regrading. ....................................................... 6 Figure 1.4. One of the trenches (LFG-004) excavated on stable portion of Goathill North rock pile during the regrading. ............................................................................................ 6 Figure 2.1. Friction angle of GHN mine rock based on triaxial test results ..................... 12 Figure 2.2. Grain size distributions from triaxial samples from Sugar Shack rock piles and typical Goathill North mine rock. .............................................................................. 13 Figure 2.3. Friction angle versus confining stress. ........................................................... 14 Figure 2.4. Example of a geologic map. ........................................................................... 15 Figure 2.5. Geologic cross section of bench 9, trench LFG-006. ..................................... 15 Figure 2.6. Plot of QSP hydrothermal alteration intensity................................................ 17 Figure 2.7. Plot of authigenic gypsum across bench 9, trench LFG-006.......................... 18 Figure 2.8. Results of paste pH and NAG pH across bench 9, trench LFG-006. ............. 18 Figure 3.1. Examples of sphericity and roundness charts. ................................................ 23 Figure 3.2. The effect of particle shape on internal friction angle for sand. ..................... 24 Figure 3.3. Correlations between the effective friction angle and relative density for different soil type. ............................................................................................................. 25 Figure 3.4. Variation of peak internal friction angle with effective normal stress for direct shear tests on standard Ottawa sand.................................................................................. 26 Figure 3.5. Physical break up of a boulder by transformation of anhydrite to gypsum minerals at Questa mine site. ............................................................................................ 29 Figure 3.6. Evidence of chemical weathering process (oxidation) at Questa mine site. .. 30 iv Figure 3.7. Correlation of weathering grade with dry density and porosity. .................... 33 Figure 4.1. Generalized geologic cross section of GHN showing the location of the samples analyzed in this thesis. ........................................................................................ 39 Figure 4.2. Comparison of three different approaches for estimation of particle size distribution using sample GHN-LFG-0003. ..................................................................... 43 Figure 4.3. Manually direct shear equipment. .................................................................. 46 Figure 4.4. Example of a shear stress versus shear strain plot.. ........................................ 47 Figure 4.5. Example of a shear diagram showing the best fit line for the peak internal friction angle and the residual internal friction angle. ...................................................... 47 Figure 4.6. Shear box size effects on direct shear test. ..................................................... 49 Figure 4.7. Results of effect of particle size on direct shear test using a 2-inch shear box. ........................................................................................................................................... 51 Figure 4.8. Results of influence of moisture on direct shear test. ..................................... 53 Figure 5.1. Range of grain size distribution for samples from GHN rock pile................. 58 Figure 5.2. Distribution of the samples from GHN rock pile on the plasticity chart........ 58 Figure 5.3. Direct shear test results for a dry sample versus a sample with gravimetric moisture content of 12.4%. ............................................................................................... 61 Figure 5.4. Mohr-Coulomb diagram for sample GHN-KMD-0014 using two direct shear test equipments.................................................................................................................. 62 Figure 5.5. Mohr-Coulomb diagram for sample GHN-KMD-0017 using two direct shear test equipments.................................................................................................................. 63 Figure 5.6. Mohr-Coulomb diagram for sample GHN-KMD-0027 using two direct shear test equipments.................................................................................................................. 64 Figure 5.7. Stratigraphic position of the geologic units for bench 9 (Trench LFG-006). . 65 Figure 5.8. Cross plots of internal friction angle versus paste pH.. .................................. 65 Figure 5.9. Cross plots of internal friction angle versus NAGpH .................................... 65 Figure 5.10. Cross plots of internal friction angle versus percent of fines.. ..................... 66 Figure 5.11. Cross plots of internal friction angle versus plasticity index.. ..................... 66 Figure 5.12. Cross plots of internal friction angle versus liquid limit.. ............................ 67 v Figure 5.13. Cross plots of internal friction angle versus percent Amalia Tuff.. ............. 67 Figure 5.14. Cross plots of internal friction angle versus percent Andesite.. ................... 68 Figure 5.15. Cross plots of internal friction angle versus quartz-sericite-pyrite (QSP) alteration.. ......................................................................................................................... 69 Figure 5.16. Cross plots of internal friction angle versus propylitic alteration. ............... 69 Figure 5.17. Cross plots of internal friction angle versus LOI (lost of ignition). ............. 70 Figure 5.18. Cross plots of internal friction angle versus percent epidote. ...................... 70 Figure 5.19. Cross plots of internal friction angle versus percent illite...... ...................... 71 Figure 5.20. Cross plots of internal friction angle versus percent MgO.. ......................... 71 Figure 5.21. Cross plots of internal friction angle versus percent CaO. ........................... 72 Figure 5.22. Cross plots of internal friction angle versus percent Al2O3.......................... 72 Figure 5.23. Plot of WPI and MI with distance across bench 9, trench LFG-006. ........... 75 Figure 5.24. Plot of WPI and MI for all GHN samples. ............................................... 7675 Figure 5.25. Cross plot of Friction angle versus simple weathering index (SWI) for bench 9 samples, trench LFG-006. .............................................................................................. 76 Figure 5.26. Cross plot of Friction angle versus weathering potential index (WPI) for samples from bench 9, trench LFG-006. .......................................................................... 77 Figure 5.27. Cross plots of Friction angle versus Miura Index (MI) for samples from bench 9, trench LFG-006. ................................................................................................. 77 vi This thesis is accepted on behalf of the Faculty of the Institute by the following committee: _________________________________________________________ Research Advisor __________________________________________________________ Academic Advisor __________________________________________________________ Committee Member ___________________________________________________________ Date I release this document to the New Mexico Institute of Mining and Technology. _____________________________________________________________ Student's Signature Date 1. INTRODUCTION 1.1. Background This thesis develops information regarding the engineering characteristics of Goathill North rock pile material at the Questa molybdenum mine in New Mexico and examines correlations of internal friction angle with mineralogy, chemistry and weathering indexes. Molycorp Inc. is funding a multidisciplinary study to investigate the potential effects of chemical and physical weathering on the slope stability of Goathill North rock pile, one of the nine rock piles at the mine. The project is a unique opportunity to sample and study the internal material of this rock pile. The ultimate goal of the study is to assess the risk of mass failure of the mine rock pile over at least 100 years. Another way to state this goal simply is to ask: Will the mine rock piles become gravitationally unstable with time due to weathering? The weathering aspects of the rock pile and stability analyses are being studied by other members of the team to the same end. This thesis research will complement the weathering studies by examining the shear strength using a direct shear apparatus with a 2-inch shear box. Rock piles are disposal facilities for overburden (also termed “mine rock”). Overburden or mine rock is the barren or uneconomic mineralized rock that must be removed in order to mine the mineral resource. Surface mine operations create rock piles that by weight, volume, or height represent some of the largest structures built by man. Compared with other engineered structures, little or no characterization of the material has been performed before, during, or especially after construction of the rock piles (Robertson, 1982). Since the 1980s, environmental regulations forced mine operators to 1 consider the design of rock piles and in some cases enforced requirements for maximum slope angles, factors of safety for slope stability, and site reclamation. These considerations have led to the need for information on the strength characteristics of the materials that comprise rock piles. Unfortunately, little detailed information has been published on this topic. Thus, a secondary goal of this thesis is to add to the base of knowledge in this area. 1.2. Thesis Objective The purpose of this work is to interpret data on the engineering characteristics of the Goathill North (GHN) rock pile at the Molycorp Questa Molybdenum mine, and to examine correlations of internal friction angle with mineralogy, chemistry and weathering indexes. The key elements of this research are to: Investigate the variation of shear strength within the GHN rock pile by performing a series of direct shear tests. Investigate the variation of Geotechnical index properties within the GHN rock pile by performing particle size analyses and by measuring Atterberg limits, specific gravity, and moisture content. Investigate the effect of gradation, chemistry, and mineralogy on shear strength by correlating mineralogy, chemistry, and the data from particle size analyses with friction angle. 2 1.3. Site Description The Questa molybdenum mine (Figure 1.1), owned and operated by Molycorp, Inc., is located 5.6 km (3.5 mi) east of the Village of Questa, in Taos County, northern New Mexico, in the western portion of the Taos Range of the Sangre de Cristo Mountains. The mine site is located in an area of high relief with elevations varying from 2,310 to 3,295 m (7,580 to 10,812 ft) in an area of about 15.54 km2 (6 mi2). The main headframe of the mine is located on the south-facing slopes of the Red River Valley at approximately 2,438 m (8000 ft) above sea level. The Questa molybdenum mine has been in operation, though not continuously, since 1918, during which time several mining methods have been used to extract molybdenite (“moly” - MoS2) from this “Climax-type” porphyry molybdenum deposit. Initially, the mine was a small underground working, with donkey-hauled ore cars delivering ore to the surface that was broken up by workers. Later, from 1965 to 1982, large-scale open pit mining methods were used to extract the ore. Currently the mine operates underground using block caving mining methods. During the open-pit period of mining, approximately 320 million tons of overburden rock overlying and surrounding the ore body were excavated and deposited in steep valleys adjacent to the open pit (URS Corporation, 2000). The resulting nine rock piles are shown in Figure 1.2. In general, the mine rock piles are at the angle of repose (35º to 40º) and have long slope lengths (up to 600.5 m or 1970 ft) and comparatively shallow depths (~30-60 m or ~98-196 ft) (Shaw et al., 2002). 3 Figure 1.1. This image shows the location map of Molycorp’s Questa molybdenum mine, which is in northern Taos County, New Mexico. Goathill North & Goathill South Rock Piles Sulphur Gulch Rock Pile Figure 1.2. This image shows an aerial photo of Questa mine showing the nine rock piles adjacent to the open pit. 4 The GHN rock pile is one of the nine rock piles created during open-pit mining. Before reclamation GHN contained approximately 4.2 million m3 (5.5 million yds3) of overburden material with slopes similar to the original topography (Norwest Corporation, 2004). Studies by Norwest Corporation (2003) revealed that the GHN rock pile was constructed in an area characterized by hydrothermal alteration scars. These hydrothermal alteration scars are natural, colorful (red to yellow to orange to brown), relatively unstable landforms that are characterized by steep slopes (greater than 25 degrees), moderate to high pyrite content (typically greater than 1 percent), little or no vegetation, and extensively fractured bedrock (McLemore et al., 2004; Meyer and Leonardson, 1990). The toe of the GHN rock pile is founded on a colluvium bench underlain by pre-sheared material. Foundation movements associated with the initial development of the slide occurred between 1969 and 1973 (Norwest Corporation, 2003; Norwest Corporation, 2004), and continued to occur for more than 30 years untilthe initial reclamation of that pile was completed in 2005. GHN rock pile can be divided into two areas - a stable area and an unstable area, as shown in Figure 1.3. In 2004-2005, Molycorp stabilized this rock pile by removing material off the top portion of both areas to the bottom of the pile (Norwest Corporation, 2003). This regrading decreased the slope, reduced the load, and created a buttress. During the progressive down-cutting (regrading) of the top of GHN, trenches were constructed to examine, map, and sample the undisturbed internal geology of the rock pile as shown in Figure 1.4. Samples collected from these trenches form the basis for this thesis. 5 Figure 1.3. This image shows Goathill North rock pile before re-grading, looking east. Solid line indicates approximate location of trenches completed in summer-fall 2004; dashed line indicates the boundary between the stable and unstable portions of the rock pile (after McLemore et al., 2006). Figure 1.4. This image shows one of the trenches (LFG-003) excavated on the stable portion of the Goathill North rock pile during the re-grading. 6 The geology at the Questa mine includes four main lithologies, all of which are hydorthermally altered to varying degrees: andesite porphyry, aplite porphyry, andesite to quartz latite porphyry flows, and rhyolite tuff (Amalia Tuff). Most of the mined rockpile material consists of andesite, rhyolite tuff and porphyritic aplite. Several studies of the Questa mine have used the term ‘mixed volcanics’ to describe the lithology of the rock piles. These ‘mixed volcanics’ consist of andesite, latite, quartz latite, and volcaniclastic rocks all of which have been subjected to varying amounts of hydrothermal alteration (Shaw et al., 2002). The climate at the mine is semi-arid with mild summers and cold winters(Wels et al., 2002). The long-term average annual precipitation at the mill site (located at the base of the mine site) is approximately 401 millimeters (15.8 in). Temperatures vary greatly both annually and diurnally. The average daily maximum temperatures range from 2.7º to 25º C (37º to 77º F) with average daily minimum temperatures ranging from -14.4º to 5º C (6º to 41º F). During five months of the year (November through March) the average monthly temperature is below freezing (Robertson GeoConsultants Inc., 2000). Hot days and cool nights characterize summer. The rainy season is during July and August. Heavy localized rainfalls during July and August often cause flash floods and mudflows, which sometimes block the highway between the Village of Questa and the Town of Red River (Molycorp Inc., 2002). 7 1.4. Thesis Outline Chapter 2 contains a critical literature review of past and present studies on the Goathill North rock pile. Chapter 3 discusses the factors that influence strength of a granular soil, such as those found in the GHN rock pile. Chapter 4 presents the methodology used in this thesis. Chapter 5 presents both the results of the physical measurements and a discussion of those results. Chapter 6 contains conclusions and recommendations. Appendices and references are located at the end of this thesis. 8 2. REVIEW OF STUDIES AT GOATHILL NORTH ROCK PILE Past Geotechnical Studies (Before Re-grading)Past evaluations of the geotechnical properties of the GHN rock pile were completed by several consulting companies hired by Molycorp, Inc. These projects included stability evaluations and the development of closeout and mitigation plans. The characterization of geotechnical properties included laboratory tests of particle size distribution, Atterberg limits, dry unit weight, specific gravity, moisture content, and shear strength. Samples were collected from the surface in test pits or from deeper in the pile from drill holes. Drill hole depths range from 9 to 70.4 m (30 to 231 ft). Drill hole logs indicated four different units, listed in descending order as follows (Norwest Corporation, 2004): Mine rock Colluvium (and “weak zone”) Weathered bedrock Bedrock Laboratory results from different projects are summarized in Table 2.1 and Table 2.2. Although the laboratory results included all four units, this thesis research examined only the mine rock (first unit). Therefore, this document will be focused on describing the mine rock. The previous studies’ particle size analyses indicate that the GHN rock pile has a wide variation in gradation ranging from cobble-sized material to silty sands and clayey sands. The mine rock is mostly sandy gravel with less than 20% fines, clay contents less 9 than 12%, and plasticity indexes (PI) less than 10%. Dry unit weights of 21 mine rock samples indicate an average of 1.82 g/cm3 (113.3 pcf) with standard deviation of 0.13 g/cm3 (8 pcf) (Norwest Corporation, 2004). The specific gravity of the mine rock based on 15 samples ranges from 2.66 to 2.80 g/cm3 (166 to 175 pcf) (Norwest Corporation, 2004; URS Corporation, 2003). Table 2.1. Summary of geotechnical properties at GHN rock pile Particle size distribution Reference Sampling method Sample description % Gravel Norwest Corporation, 2004 Atterberg limits mine rock %Sand %Fines 55.1 33.9 (Ave.) (Ave.) 19.2 13.9 (STDEV) (SDTEV) 42 42 (#samples) (#samples) % Clay colluvium - - Norwest Corporation, 2004 "weak zone" of the colluvium - - 36-65 11-34 (range) (range) 7 7 (#samples) (#samples) URS Corporation, 2003 mine rock Norwest Corporation, 2004 35-54 36-49 (range) (range) 28 28 (#samples) (#samples) Plasticity index Comments 11.1 5.6 27.7 9.5 6.7 (Ave.) (Ave.) (Ave.) (Ave.) (Ave.) 6.6 2.5 3.6 3.4 3.9 sandy gravel (SDTEV) (SDTEV) (SDTEV) (SDTEV) (SDTEV) with cobbles 42 17 36 36 42 (#samples) (#samples) (#samples) (#samples) (#samples) 24.1 8.5 (Ave.) (Ave.) 10.7 4.8 (SDTEV) (SDTEV) 91 50 (#samples) (#samples) split tube drill Liquid limit (%) Natural Moisture Content, w (%) 11.2 (Ave.) 3.6 (SDTEV) 84 (#samples) - - 14-25.3 (range) 7 (#samples) - - 6-28 2.1 -12.8 24-37 4-18 2.6-13.1 sandy and (range) (range) (range) (range) (range) clayey gravel 28 28 28 28 28 with cobbles (#samples) (#samples) (#samples) (#samples) (#samples) test pits URS Corporation, 2003 Robertson GeoConsultants Inc., 2000 drill hole bedrock (highly altered/weathered andesite) - - 30-49 (range) 4 (#samples) mine rock 59 ( 1 sample) 19 (1 sample) 5 (1 sample) 30-36 12-21 11.4-12 (range) (range) (range) 4 4 4 (#samples) (#samples) (#samples) 2 28 (1 sample) (1 sample) 12 (1 sample) 2.7 (1 sample) - sample (GT-18) Table 2.2. Summary of friction angles of Molycorp mine rock piles and the “weak zone” at GHN and their gradation results. 10 Reference Mine rock / Norwest Inc., 2004 and URS Corporation Inc., 2003 Mine rock/ Robertson GeoConsultant s Inc., 2000 Sample location % Fines (-0.75mm) %Clay (-0.002mm) Plasticity index SSW-3 Sugar Shack West rock pile 18.8 6.6 8 Friction angle (degrees) Cohesion 36 average Test Comments Norwest suggested friction angle of Consolidated undrained triaxial test GHN rock pile is the same as the average friction angle of this two samples from Sugar Shack rock piles at Questa. The tests were Consolidated performed by URS Corporation Inc., undrained triaxial test 2003. SSM-6 Sugar Shack Middle rock pile 29.1 7.7 11 GT-18 GHN rock pile 5 2 12 31 561psf direct shear test Shear box size= 2.4" diameter Test conditions=saturated # of tests considered = 3 different normal load TH-GH-04S 60.0-61.0' 36 11 16.6 39.8 0.0 direct shear test Sample size= 2.41" diameter Test conditions= saturated # of tests considered = 3 different normal load TH-GH-04S 69.0-71.0' 65 34 25.3 22.3 0.0 direct shear test Sample size= 2.41" diameter Test conditions= saturated # of tests considered = 3 different normal load TH-GH-02S 137.5-138.5' 49 21 18.5 19.7 - direct shear test # of tests considered = 3 different normal load 44 18 15.6 30.0 - direct shear test # of tests considered = 1 normal load TH-GH-10S 44.7-45.5' 39 20 24.8 27.0 - direct shear test # of tests considered = 1 normal load TH-GH-14S 90.5-91.0' 39 15 18.2 25.0 - direct shear test # of tests considered = 2 different normal load TH-GH-14S 94.2-95.0' 40 14 14 29.5 - direct shear test # of tests considered = 2 different normal load Weak Zone/ Norwest Inc., TH-GH-02S 2004 141.0-141.8' - Robertson GeoConsultants (RGC) Inc. (2000) performed a series of fourteen 12inch saturated direct shear tests on Questa rock pile material including one mine rock sample from the GHN rock pile. Their results showed a range of friction angles and cohesion from 41º to 47º and 9.6 to 96 kPa (200 to 2000 psf). Results from a 2.4-inch saturated direct shear test on a mine rock sample from the GHN rock pile showed an average friction angle of 31º and cohesion of 26.9 kPa (561 psf) (Robertson GeoConsultants Inc., 2000). Robertson GeoConsultants Inc. (2000) reported that all direct shear tests exhibited evidence of strain hardening. The effect of strain hardening is that shear strength 11 continues to increase at very large strains under the conditions of the test and no sudden reduction in shear strength as strain occurs (Robertson GeoConsultants Inc., 2000). A study performed by Norwest Corporation in 2004 on GHN concluded that the friction angle of the mine rock is an average of two triaxial test results performed on samples from the Sugar Shack rock piles at Questa mine (Norwest Corporation, 2004). The Mohr Coulomb diagram combined for the two samples gives a friction angle of 36º as is shown in Figure 2.1. The assumption was justified by the similarity in particle size distribution of these samples with the particle size distribution of the mine rock from GHN as can be seen in Figure 2.2. The testing was conducted over a confining stress range up to about 2,750 kPa (57,435 psf). The results show that the friction angle decreases somewhat with confining stress from about 40º at low stresses to 35º at 2,750 kPa or 57,435 psf as shown in Figure 2.3. Figure 2.1. This graph shows the friction angle of GHN mine rock based on triaxial test results for samples from Sugar Shack rock piles that have gradations lying towards the finer range of materials sampled at GHN rock pile (from Norwest Corporation, 2004). 12 Figure 2.2. This graph shows the grain size distributions from triaxial samples from Sugar Shack rock piles and typical Goathill North mine rock (from Norwest Corporation, 2004). 13 Figure 2.3. This graph shows friction angle versus confining stress showing a decrease in friction angle as confining stress increases (from Norwest Corporation, 2004). 2.1. Present Work and Preliminary Results The present work on the GHN rock pile is being performed by a multidisciplinary group of engineers and scientists with the following main objectives: 1. Understanding weathering processes, both at the surface and within the mine rock pile which could affect the geotechnical properties of the pile. 2. Measuring the rate at which such weathering processes occur over time. 3. Determining the effect of these processes on the geotechnical properties of the pile (e.g., grain size, grain shape and textures, cementation, shear strength, moisture content) for further long-term stability analyses. (This thesis research is complementing this work by providing initial geotechnical data). During the regrading of the GHN rock pile, several trenches were excavated into the interior of the pile. For every trench, geologic maps and logs of each bench were created to describe the different subsurface mine rock units. Subsurface units were defined based on grain size, color, texture, stratigraphic position, and other physical properties that could be determined in the field. Examples of a geologic map and the subsurface units for trench LFG-009 are shown in Figures 2.4 and 2.5, respectively. Units were correlated between benches and on each side of a trench, and several units were correlated downward through the series of five successively excavated trenches. A detailed description of each unit for all the trenches is presented in McLemore et al. (2006) and in Appendix E. 14 Figure 2.4. This figure shows an example of a geologic map like those created for each trench at GHN rock pile. Geologic map of trench LFG-009 (from McLemore et al., 2005). Figure 2.5. This figure shows a geologic cross section of bench 9, trench LFG-006 showing the identified subsurface units. See Appendix E for description of the subsurface units. Field and laboratory analyses reveal that the GHN rock pile consists primarily of hydrothermally altered andesite and Amalia Tuff (McLemore et al., 2005). The andesite and Amalia Tuff rock fragments are comprised primarily of quartz and feldspar. However, andesite contains less quartz and more plagioclase than the rhyolitic Amalia 15 Tuff. In addition, Amalia Tuff commonly contains quartz phenocrysts, which are usually absent in the andesite. The andesite and Amalia Tuff have been subjected to variable intensities of hydrothermal alteration as well as weathering. Hydrothermal alteration is the change in original composition of the rock in place by hydrothermal (warm to hot aqueous) solutions associated with mineralization and associated ore-forming events such as granitic intrusions. Hydrothermal alteration is a pre-mining condition and includes both hypogene (primary) and supergene (secondary) processes. Hypogene alteration occurred during ore-formation. Supergene alteration, a type of weathering, occurred at low temperatures near Earth’s surface after the formation of the ore deposit, but before mining commenced. The major hypogene alteration types at GHN include quartz-sericitepyrite (QSP), propyllitic, argillic, and potassic alteration (Carpenter, 1968). Weathering can be defined as the process of rock and mineral alteration to more stable forms under the variable conditions of moisture, temperature, and biological activity that prevail at the surface (Birkeland, 1999). Most rocks and minerals exposed at and immediately beneath the earth’s surface are in an environment quite unlike that under which they are formed (Birkeland, 1999). Preliminary results of petrographic analysis of samples from bench 9, trench LFG-006, show that both hydrothermal alteration of fragments within the pile varies according to the predominant lithology (rhyolite typically shows more QSP alteration than andesite) and that weathering increases from the interior of the pile to the edge of the pile, as shown in the Figures 2.6 and 2.7. The QSP alteration intensity was defined by the percentage of hydrothermal alteration minerals (quartz, sericite, pyrite))that have replaced primary minerals and ground mass. A major indicator of weathering is the 16 abundance of authigenic gypsum crystals, which indicates that some weathering of sulfide minerals (essentially all pyrite) and calcite occurred after emplacement of the rock pile (Campbell et al., 2005). Results from paste pH and net acid generation (NAG pH) show a range from 2.1 to 10. Paste pH and NAG pH typically increase with distance from the outer, oxidized zone (west) towards the interior, unoxidized zone (east) of the GHN rock pile as shown in Figure 2.8 (Tachie-Menson, 2006). These results can be attributed to a number of factors, including (1) the different lithologies of the stratigraphic units that comprise the rock pile, (2) the amount of weathering and leaching that had occurred before the material was mined and dumped (deposited) onto the pile, and (3) the differences among variables, such as oxygen concentration, moisture content, and presence of bacteria, that influence weathering of the rock pile both at the surface and within the pile (Tachie-Menson, 2006). Figure 2.6. This graph shows a plot of QSP hydrothermal alteration intensity (defined by the percentage of hydrothermal alteration minerals that have replaced primary minerals) across bench 9, trench LFG-006 (from McLemore et al., 2005). Refer to Figure 2.5. for geologic units. 17 Figure 2.7. This graph shows a plot of authigenic gypsum across bench 9, trench LFG-006 (from McLemore et al., 2005). Refer to Figure 2.5. for geologic units. Bench 9, LFG-006 12 10 pH 8 6 4 Paste pH NAG pH 2 0 0 20 40 60 Distance from 9NW (ft) 80 100 Figure 2.8. This graph shows the results of paste pH and NAG pH across bench 9, trench LFG-006 (after Tachie-Menson, 2005). 18 A post-mining weathering index for the rock pile is currently being developed. A weathering index is a measure of how much the sample has weathered. McLemore (2005) described a simple, descriptive weathering index (SWI) that is based upon field observations (color, grain size, mineral texture, and the presence or absence of certain minerals indicative of weathering) for the purpose of identifying the relative intensity of weathering of samples collected for the project. Other weathering indexes found in the literature are being evaluated as well. Most weathering indexes are based on geochemical parameters that restrict their applications to the type of environment that they were developed for. 19 3. LITERATURE REVIEW OF CONCEPTS RELATED TO THIS RESEARCH 3.1. Strength of Granular Materials A granular soil is composed of particles larger than approximately 0.075 mm or No. 200 standard U.S. sieve size. Typically it is assumed that these soils do not exhibit significant effective cohesion (resulting from electrostatic particle attractions) and are free-draining (water not bound inside particle structure), with low retention of water between particles. Coarse granular soil is composed of at least 50 percent by weight of gravel (1/4-inch diameter) or larger particles (Holtz and Kovacs, 2003; Quine, 1993). The shear strength of a granular soil can be defined by equation 3.1, c tan (3.1) where c is cohesion (in kPa, MPa or psf), is total stress ( in kPa, MPa or psf), and is the internal angle of friction of the soil (in degrees) (Das, 1983). This equation is generally referred to as the Mohr-Coulomb failure criteria. For saturated soils, the stress carried by the soil solids is the effective stress and equation 3.1 is modified to equation 3.2: c ( u ) tan c' ' tan 20 (3.2) where u is the pore water pressure, c’ is the effective cohesion, and ’ is the effective stress on the failure plane at the failure. Since it is assumed that granular material does not present any effective cohesion, equation 3.2 is generally simplified to equation 3.3 in many references (Das, 1983; Holtz and Kovacs, 2003; Terzaghi et al., 1996). ' tan (3.3) Therefore, the shear strength of granular soil is frequently characterized by its internal friction angle (). The internal friction angle is a function of the following characteristics (Hawley, 2001; Holtz and Kovacs, 2003): Particle size (friction angle increases with increase in particle size) Grain quality (weak rock such as shale verses strong rock such as granite) Particle shape and roughness of grain surface (friction angle increases with increasing angularity and surface roughness) Grain size distribution (well graded soil has a higher friction angle than a poorly graded soil) State of compaction or packing (friction angle increases with increasing density or decreasing void ratio) Applied stress level (decreasing with increasing stress, resulting in a curved strength envelope passing through the origin) Various studies have successfully evaluated how the parameters listed above affect internal friction angle. Findings from these studies are presented in the following paragraphs. 21 It has been recognized (Holtz, 1960; Holtz and Gibbs, 1956) that an increase in the proportion of coarse material in an otherwise fine-grained granular soil can result in an increase in friction angle. Typical values for medium-dense sand can range from 32º to 38º, while typical values for medium-dense sandy gravel can range from 34º to 48º (Das, 1983). Triaxial strength testing of large-size (up to 200 mm or 7.87 in) rockfill particles suggested that rock piles are expected to have internal friction angles in the range of 40º to 50º, the lower end of the range corresponding to fine-grained material, and the upper end of the range corresponding to coarse-grained material (Leps, 1970). Particle size and shape reflects material composition, grain formation and release from the mineral matrix, transportation, and depositional environments. Chemical action and physical abrasion increase with weathering and more weathered sands tend to be rounder regardless of particle size (Cho et al., 2004). Particle shape is characterized by three dimensionless ratios (Barrett, 1980; Krumbein, 1941): sphericity (eccentricity or platiness), roundness (angularity), and smoothness (roughness). Sphericity and roundness can be estimated visually using the comparison charts shown in Figure 3.1. The use of these charts makes it easier to examine the influence of particle shape on geotechnical properties (Cho et al., 2004). The relationship between particle shape and friction angle is presented in Figure 3.2. Open circles are for sand with sphericity > 0.7, and closed circles are for sand with sphericity < 0.7. The plot shows a negative correlation between internal friction angle and roundness. As roundness varied from 0.1 (very angular) to 1 (well rounded), the internal friction angle decreased from 40º to approximately 28º. Particles with a higher sphericity generally had lower friction angles. Surface roughness will also have an effect on internal friction angle, although surface roughness is very difficult to 22 measure. Generally, the greater the surface roughness, the greater will be the internal friction angle (Holtz and Kovacs, 2003). (a) (b) Figure 3.1. This figure shows examples of sphericity and roundness charts (a) from (Cho et al., 2004) and (b) from AGI (American Geological Institute) data sheet 18.1 comparison chart for estimating roundness and sphericity, by Maurice C. Powers, copyright 1982. These charts were used for this project. 23 Figure 3.2. This graph shows the effect of particle shape on internal friction angle for sand ( from Cho et al., 2004). Open circles and closed circles are for sand with sphericity higher than 0.7 and sphericity lower than 0.7, respectively. The effects of grain size distribution on internal friction angle can be observed on samples with the same relative density. Figure 3.3 shows the correlation between the effective friction angle from triaxial compression tests and both relative density and soil classification. When two sands have the same relative density, the soil that is better graded (for example, an SW soil as opposed to an SP soil) has a larger (Holtz and Kovacs, 2003). 24 Figure 3.3. This graph shows the correlations between the effective friction angle and the relative density for different soil types (from Holtz and Kovacs, 2003). ML: Silt, SM: Silty sand, SP: Poorly graded sand, SW: Well-graded sand, GP: Poorly graded gravel, GW: Well-graded gravel. The influence of void ratio (state of compaction or packing) and of applied stress level are illustrated in Figure 3.4 (Das, 1983). Figure 3.4 is a plot of the results of direct shear tests on standard Ottawa Sand. For loose sand (initial void ratio approximately 0.66), the value of decreases from about 30º to less than 27º when the normal stress is increased from 45 to 766 kPa (0.5 to 8 ton/ft2). Similarly, for dense sand, decreases from approximately 34.5º to about 30.5º due to an increase in normal stress from 45 to 766 kPa (0.5 to 8 ton/ft2). 25 Figure 3.4. This graph shows the variation of peak internal friction angle with effective normal stress for direct shear tests on standard Ottawa sand (from Das, 1983). The determination of the internal friction angle () and the effective cohesion (c) is commonly accomplished by the direct shear test or the triaxial test. The direct shear test is preferred because of its simplicity and lower cost. The advantages and disadvantages of direct shear tests are given below. Advantages of direct shear testing are as follows: The test is relatively inexpensive and quick to perform. It requires less sophisticated equipment than other methods and it is easier to reduce the data and interpret the results. 26 It has been found that soil parameters and c obtained by direct shear testing are nearly as reliable as triaxial values. Typical values obtained with the direct shear test are 1 to 2 degrees larger than values obtained with the triaxial test (Bowles, 1979). It is good for measuring residual strength values (Quine, 1993). Disadvantages or limitations of the direct shear test (Holtz and Kovacs, 2003) are as follows: Shearing stress is not uniformly distributed across the sample. Initial failure occurs at the corners and ends of the box, and propagates towards the center. The test forces failure to occur along a fixed zone or plane. There is an uncontrolled rotation of principal planes and stresses that occurs between the start of the test and failure. Pore water pressures for fine-grained soils are neither controlled nor monitored. 3.2. Weathering Process Weathering is the process of rock and mineral alteration to more stable forms under the variable conditions of moisture, temperature, and biological activity that prevail at or near the surface (Birkeland, 1999). Two main types of weathering are recogonized: physical weathering, in which the original rock disintegrates to smaller-sized material with no appreciable change in chemical or mineralogical composition, and chemical 27 weathering, in which chemical and/or mineralogical composition of the original rock and minerals are changed (Clark and Samall, 1982). The mechanism common to all processes of physical weathering is the establishment of sufficient stress within the rock so that the rock breaks (Clark and Samall, 1982). The most common processes associated with physical weathering are unloading by erosion of overlying material; by expansion of cracks or along grain boundaries by crystallizing open-space-filling minerals or freezing water; and by thermal expansion (associated with fire, for example) and contraction of the constituent mineral (Birkeland, 1999). Physical weathering results in a decrease in grain size, which increases surface area that in turn leads to greater chemical reactivity and the exposure of fresh mineral surfaces. As shown in Figure 3.5, the fragments of andesite within the rock piles at the Questa mine are affected by a physical break up of the rock caused by the volume change produced by the transformation of anhydrite to gypsum or other crystal growth along fractures. 28 Figure 3.5. This image shows the progressive physical break up boulders by the transformation of anhydrite to gypsum common at the Questa mine site. Chemical weathering processes include dissolution, carbonation, hydration, hydrolysis, oxidation and reduction (Birkeland, 1999; Clark and Samall, 1982; Gerrard, 1988). Evidences of chemical weathering are shown by several field and laboratory criteria including: (1) change in color due to oxidation of iron-bearing minerals as shown in Figure 3.6, (2) depletion of original minerals (non-clay and clay), (3) alteration of original clay minerals or neo-formation of clay minerals, (4) neo-formation of iron or aluminum oxides and oxyhydroxides, (5) changes in major-element chemistry versus that of the assumed parent material, (6) the chemistry both of the waters that move through the soil and that of the streams draining a particular basin (Birkeland, 1999). 29 Figure 3.6. This image shows evidence of chemical weathering process (oxidation of iron ) at Questa mine site. The rate of weathering is complex; it involves not only particle size, but also types of material, climate, moisture, exposure conditions, and plant, animal, and microbial activities. Generally, in an acidic environment, both the rate and the amount of weathering increases with time due to the reduction of grain size, which allows more surface area of the material to be exposed to the process (Bowles, 1979). 3.3. Effect of Weathering on Geotechnical Properties of Mine Rock Few studies exist on the effect of weathering on the geotechnical properties of material found in mine rock piles. However, natural hillslopes and rockfill dams have general similarities to rock pile material (Leps, 1970; Quine, 1993; Robertson, 1985; 30 URS Corporation, 2003). Therefore, in this literature review of the effect of weathering on the geotechnical properties of mine rock, studies on natural hillslope and rockfill material will be included as well. Seedsman and Emerson (1985) studied the role of clay-rich rocks in spoil pile failures at the Goonyella Mine in Australia. They observed a reduction of the friction angle by 6º to 12º due to chemical weathering and by 2º to 3º caused by the presence of fines generated by physical weathering. According to Seedsman and Emerson, the reduction of the friction angle caused by physical weathering does not occur gradually as the fines fraction (silt + clay) increases but, insteadrelatively suddenly at a fines content of about 10%. At this fines content, the larger particles in the spoil are no longer in direct contact with each other but instead tend to be supported in a matrix of silt- and clay-sized particles. Calcaterra et al. (1998) studied the weathering processes in crystalline rocks of the Sila Massif, Calabria, Southern Italy. Weathering grades were identified using a weathering field survey classification scheme proposed by the Hong-Kong Geotechnical Control Office. Descriptions of completely to moderately weathered gneissic rocks are presented in Table 3.1. Laboratory results of geotechnical properties in Table 3.2 showed that strength, density, specific gravity, and porosity decreased as weathering grade increased. Specific gravity did not significantly decrease with an increase in weathering grade. Thuro and Scholz (2003) presented density and porosity results in agreement with the findings from Calcaterra et al. (1988) shown in Figure 3.7. 31 Table 3.1. This table shows the weathering field survey used to characterize the weathering sequence in the gneiss (after Calcaterra et al., 1998). Weathering grades I, II, and VI were unavailable to survey. Weathering grade V Field survey Parent rock Gneiss (corestones) brownish to reddish-orange coarse-grained soils, retaining original mass structure and material fabric (less than 30% rocks, as "corestones"); slake in water, easily crumbled by hand and finger pressure into grains, indented by geologic hammer. Relict discontinuities are recognizable. IV Gneiss III Gneiss completely discolored (brownish-red) weak rocks. Do not slake in water, can be broken by hand into smaller fragments. Discontinuities are clearly visible, original fabric is present. greenish-grey rocks stained and discolored along discontinuities and original fabric are wholly preserved. Table 3.2. This table shows the main engineering-geological features of weathered horizons near Acri (after Calcaterra et al., 1998). Weathering grade V V Parent rock Granitoids (soil) Gneiss (corestones) IV Gneiss III Gneiss Specific gravity (kN/m3) Bulk density (kN/m3) Dry density (kN/m3) 26.3-27.6 (7) 26.0-26.5 (5) 26.1-26.7 (6) 26.3-29.9 (5) 19.3-20.0 (7) 22.1-25.2 (5) 23.1-25.4 (6) 25.3-28.6 (5) 18.3-19.4 (7) 21.2-24.4 (5) 22.7-25.2 (6) 25.2-28.6 (5) Saturated density (kN/m3) Porosity (%) 21.4-22.2 28.7-32.2 (7) (7) 23.0-25.5 8.2-15.5 (5) (5) 24.0-25.7 5.0-13.1 (6) (6) 25.6-29.0 2.2-4.7 (5) (5) Point load strength (MPa) n.d. 0.7-1.1 (4) 0.4-2.9 (6) 0.5-4.1 (4) The numbers in brackets refer to the number of samples tested, and n.d. = not determined 32 Figure 3.7. This graph shows the correlation of weathering grade with dry density and porosity. High/mean/low values are plotted for each grade (from Thuro and Scholz, 2003). Huat et al. (2005) studied the strength parameters in a profile of sedimentary residual soils of various weathering grades. The weathering grades varied from III to V, where the lower end is for less weathered material and the higher end is for more weathered material. The site comprised residual soil of weathered sandstone, overlying schist and quartzite. The soils were generally yellowish brown and consisted mainly of fine sands, silt and clay. Results of triaxial tests are shown in Table 3.3. The results show an increase in cohesion but a decrease in angle of friction as the soil/rock becomes more weathered. An increase in fines content with weathering grade was also observed, which according to the authors was the reason for a decrease in friction angle. Lumb (1962; 1965) conducted extensive work on residual soils in Hong Kong. They successfully used particle size parameters to indicate the degree of weathering based on field observations that most soil profiles exhibit trends of decreasing particle size and increasing clay content towards the surface. 33 Even though most literature presents similar results and indicates a reduction of strength with increasing weathering, it cannot be generalized that weathering will always decrease mine rock/soil strength. Most of these studies are based upon soil profiles that ranged from unweathered rock to weathered soil that formed over a long period of time. Cementation was not a factor in these studies. Chemical weathering can produce cements, such as hematite, that will join grains together and that are not easily dissolved in water. According to (Pernichele and Kahle, 1971) field studies of rock piles indicate that the cementing action of iron precipitates formed within the piles as a result of natural or production leaching tends to improve the strength of the piles over time. Generally, the cementation is so complete that vertical cuts are capable of standing for years without signs of failure. Table 3.3. This table shows the shear strength parameters of sedimentary residual soil with weathering grades varying from III to V. The lower end is for less weathered material and the higher end is for more weathered material Weathering grade V IV IV-III III Cohesion, c (kPa) 10 8 4 0 Angle of friction, (degrees) 26 28 31 33 3.4. Published Grain Size distribution and Shear Strength Parameters for Mine Rock 34 Table 3.4 summarizes values of grain size distribution for different rock piles from around the world. Percentages of gravel, sand and fines in the mine rock piles range from 45 to 70, 20 to 43, and 3 to 29, respectively. These distributions support the generalized classification “sandy gravel with cobbles” attributed to rock piles in the literature (Hawley, 2001; Leps, 1970; Quine, 1993; Robertson, 1985). Table 3.5 summarizes values of internal friction angle and cohesion from different rock piles. Typical values of cohesion vary between 0 to 239 kPa (0 and 5000 psf) and friction angles vary between 21º and 55º, with most values reported between 38º and 45º. Table 3.4. This table shows the grain size distribution of rock piles from around the world. 35 Mine and Location Cobbles (%) Gravels (%) Sand (%) Fines (%) Silt (%) Clay (%) reference Ajo mine, Arizona Copper mine 5 67 20 8 7 1 Savci and Williamson (2002) Aitik Mine, Sweden Copper mine 6 45 34 15 n.d. n.d. URS Corporation (2003) Midnite Mine, Washington Uranium Mine n.d. 50-65 (range) 21-43 (range) 11-29 (range) n.d. n.d. URS Corporation (2003) Bonner Mine San Juan County, Colorado n.d. 70 20 10 8 2 Stormont and Farfan (2005) Kidston gold mines, Australia 30 37 30 3 n.d. n.d. URS Corporation (2003) Morenci mine, Arizona Copper mine n.d. 50-56 (range) 30-34 (range) 10-20 (range) n.d. n.d. URS Corporation (2003) n.d.= not determined 36 Table 3.5. This table shows a summary of mine rock friction angle and cohesion data from around the world. Mine and location Lubelskie, Poland Mine rock material/ rock type or Deposit type n.d. Internal friction angle (degrees) Fresh 32-55 5 years old 34-35 7 years old 27-37 Fresh 36-41 8 years old 21-29 Apparent cohesion (kPa) Comments References Friction angle decreases, cohesion increases with age Filipowicz and Borys (2005) Friction angle decreases, cohesion increases with age Filipowicz and Borys (2005) 0 Triaxial test 6-inch diameter dmax=3/4" samples comprised of moderately to slightly weathered rock with 20% fines URS Corporation (2003) British Columbia Mine Waste Rock Pile Research Committee (1991), URS (2003) 20-32 21-35 25-40 18-23 Upper Silesian, Poland n.d. Bouganville Copper Ltd., Papua New Guinea Fractured rock (Panguna andesite) Endako British Columbia, Canada Molybdenum mine 100% Quartz monzonite 36 24 Material properties 30% > 300mm and 2% < No.200 sieve Bald Mountain gold, Nevada Dundrberg Shale 39 172 Direct shear test shear box size 15in x 15in dmax = 3 inch Quine (1993) Barrick gold, Nevada Argillized granodiorite 38-40.3 83-139 Direct shear test shear box size 15in x 15in dmax = 3 inch Quine (1993) Big Spings gold, Nevada Argillaceous siltstone 47-50 206-239 Direct shear test shear box size 15in x 15in dmax = 3 inch Quine (1993) Candelaria gold, Nevada Siltstone and shale 43-47 90-239 Direct shear test shear box size 15in x 15in dmax = 3 inch Quine (1993) Newmont gold, Nevada Siltstone/sandstone Siltstone/ argillized sandstone 35-51 69-205 Direct shear test shear box size 15in x 15in dmax = 3 inch Quine (1993) Round Mountain gold, Nevada Rhyolitic tuff 40-41.5 77-96 Direct shear test shear box size 15in x 15in dmax = 3 inch Quine (1993) PT Freeport Indonesia’s Gasberg Open –Pit Mine 37.6-42.2 34-64 Direct shear test n.d. 39.6-40.4 0-11 Triax compression consolidated, undrained Bonner Mine San Juan County, Colorado n.d. 37 5 direct shear test shear box size 30in x 30in x 16in tall Midnite Mine, Washington Uranium Mine Porphyritic quartz monzonite, and calcsilicate rock and marble 32.6-43.7 0-29 trixial test 4-inch diameter dmax =3/4" 37 31 trixial test 6-inch diameter dmax =1 1/2" 29-45 27-37 n.d. = not determined 37 Walker, W.K. and J. M.J (2001) Stormont and Farfan (2005) URS Corporation (2003) 4. METHODOLOGY 4.1. Sampling A multifaceted sampling program was carried out by the principal investigators of the Molycorp Project Weathering Study. The sampling program was conducted from Spring 2004 through April 2005. A total of 36 samples from the GHN rock pile were analyzed during this thesis project. Samples were comprised mainly of a combination of Amelia Tuff and andesite mine rock. The sampling occurred during the re-grading period of the GHN rock pile when the trenches were excavated. Approximately 5 gallons of solid material was collected for geotechnical analyses for each sample. Samples for gravimetric moisture content, mineralogy, and chemical analyses were also collected at the same locations. All samples were collected as disturbed material Samples examined for this thesis project were used to determine the effects of physical and chemical properties on the direct shear test and were not used to calculate slope stability. Because all samples are a subset of the original material, the resulting shear tests are not representative of the entire rock pile and cannot be used to calculate friction angle for the pile. Figure 4.1 shows a cross section of the GHN rock pile before re-grading including locations of the samples that were analyzed in this thesis. A list of all the samples and their respective coordinates (UTM easting, UTM northing, and elevation) is given in Appendix A. 38 3000 Elevation (m) 2950 2900 2850 2800 2750 0 50 100 150 200 250 300 350 400 450 Easting (m) Original Topographic 2003 profile 1967 profileprofile 1967 Sample location Figure 4.1. This figure shows a generalized cross section of GHN with the location of the samples analyzed for this thesis project. 4.2. Particle Size Analysis Particle Size Analysis was performed to evaluate the sieving procedure most appropriate to the samples from the GHN rock pile. Generally, the distribution of particle sizes larger than 75 m (retained on the No. 200 U.S. standard sieve) is determined by sieving, while the distribution of particle sizes smaller than 75 m is determined by a sedimentation process with a hydrometer. This combined particle size analysis can be performed using different approaches, such as dry sieve and wet sieve (or wash sieve). Wet sieving is used instead of dry sieving when the material is not soluble in water and is difficult to screen due to the presence of extremely fine particles that either agglomerate or cause binding on the coarser sieves (U.S. Army Corps of Engineers, 1970). To 39 determine the most appropriate procedure for the samples from the GHN rock pile, initial tests of wet and dry sieving were performed, with separations made on the No. 10 (2 mm) and No. 200 (75 m) U.S. standard sieves using sample GHN-LFG-0003. The results were compared and the influence of aggregate fines on particle size distribution for this kind of material was studied. All sieves used in this thesis research were U.S. standard sieves. Method 1, “Dry sieving with separation made on No. 200 sieve,” consisted of mechanical dry sieving for particles larger than 75 m, and applying a sedimentation process using a hydrometer for particles smaller than 75 m. These combined particle size analyses (mechanical sieving and hydrometer) were performed in accordance with U.S. Army Corps of Engineers (1970) methods. Method 2, “Dry sieving with separation made on No. 10 sieve,” consisted of dry sieving for particles larger than No. 10 sieve (2 mm). The material smaller than 2 mm was analyzed using a sedimentation process (hydrometer) followed by the dry sieving for the part larger than 75 m. First, hydrometer analysis was performed on all material passing the No. 10 sieve (2 mm). The weight used was approximately 115 g for sandy soils and approximately 65 g for silt and clay soils. The dry sieving of oven-dried material between 75 m and 2 mm was performed after the fines (passing No. 200 sieve) were washed out using wet sieving. The method No. 2 combined particle size analysis was performed in accordance with the American Society for Testing and Material standard procedures (ASTM, 2002a). Method 3, “Wet sieving,” consisted of washing particles larger than 75 m through a series of sieves, and performing a sedimentation process using a hydrometer for 40 particles smaller than the No. 200 sieve. This combined particle size analysis for method 3 was performed in accordance with the U.S. Army Corps of Engineers (1970) method. All three methods were applied to the same sample in order to compare the procedures. First, the sample was air dried and two representative splits were taken by the method of cone and quartering (ASTM, 1987). The minimum mass of the sample used for particle size analysis was related to the maximum particle size present in the bucket. Table 4.1 shows different size particles and the corresponding minimum mass of sample necessary to perform the test (U.S. Army Corps of Engineers, 1970). One sample split was used for dry sieving (method 1, followed by method 2); the second split was used for wet sieving. The sample preparation for dry sieving consisted of breaking up the aggregates thoroughly with a mortar and pestle. The sample preparation for wet sieving consisted of soaking the specimen in water for 24 hrs. Table 4.1. This table shows the minimum specimen size required for particle size analysis according with the diameter of the largest particle (U.S. Army Corps of Engineers, 1970). Nominal diameter of the Approximate minimum largest particle mass of the sample inches (mm) (g) 3 (76.2) 6000 2 (50.8) 4000 1 (25.4) 2000 1/2 (12.7) 1000 0.18 (4.75) 200 0.079 (2mm) 100 41 Results of the three methods are summarized in Table 4.2. The coefficient of curvature (Cc) is defined as the ratio (D30)2/(D10 x D60), where D60, D30, and D10 are the particle diameters corresponding to 60, 30, and 10% fines on the cumulative particle size distribution curve. The coefficient of uniformity (Cu) is defined as the ratio D60/D10. Figure 4.2 is a plot showing a comparison of the particle size distributions for the three methods. A comparison of methods 1, 2 and 3 shows that wet sieving analysis provided more fines than the other two methods. The fines are removed from the surface of coarse grains by water. These results indicate that wet sieving is the best method for particle size analysis. However, the duration of method 3 was a concern because it required more time (about 6 hours) than either method 2 (about 2 to 3 hours) or method 1 (about 2 hours). Method 2 is preferred over method 1 because method 2 produced results that were considerably closer to method 3 (e.g., % of fines: method 1 = 2.53, method 2 = 11.59, and method 3 = 17.78). Furthermore, no problems were encountered during the testing using method 2. Using method 1, it was observed that aggregates of fines were plugging the sieve openings, and this condition was even worse for sieves smaller than No.10 sieve (2 mm). Based on the results of these tests, method 2, “dry sieving with separation on No. 10 sieve” (ASTM, 2002a), was selected for particle size analysis of all the samples described in this thesis. 42 Table 4.2. This table is a summary of results of the 3 methods for particle size analyses. GHN-LFG-0003 Dry sieve w/ Dry sieve w/ separation on separation on No200 sieve No10 sieve Fines (%) Sand (%) Gravel (%) D10 (mm) D30 (mm) D60 (mm) Cu Cc 2.53 67.05 30.42 0.27 1 3.1 11.48 1.19 11.59 42.59 31.00 0.019 0.59 3.1 163.16 5.91 SP-SC Poorly graded sand with clay and gravel SW well graded sand with gravel USCS classification Wet sieve 17.80 65.51 16.69 0.004 0.35 1.5 375.00 20.42 SC Clayey sand with gravel U.S. STANDARD SIEVE SIZE 100 4 6 3 2 1-1/2 1 3/4 1/2 3/8 1/4 4 8 10 16 20 30 40 50 60 100 140 200 90 PER CENT FINER BY WEIGHT 80 70 Wash sieve, Fines= 17.41% 60 50 Separation No10, Fines = 11.59% 40 30 Separation No200, Fines = 2.53% 20 10 0 1000.0000 100.0000 10.0000 1.0000 0.1000 0.0100 0.0010 GRAIN SIZE MILLIMETERS BOULDERS COBBLES SAND GRAVEL Coarse Fine Coarse Medium SILT OR CLAY Fine Figure 4.2. This graph shows a comparison of the grain size distribution for the three different approaches tried for the estimation of particle size distribution using sample GHN-LFG-0003. 43 4.3. Direct Shear Test Under Consolidated Drained Conditions All direct shear tests were conducted at the Soils Mechanics Laboratory in New Mexico Institute of Mining and Technology following Standard Industrial Practice (ASTM, 1998) and using standard manual equipment as shown in Figure 4.3. Prior to testing, all samples were air-dried and a mortar and pestle was used to break up the aggregates. Samples at field moisture contents were created by adding water and then allowed to cure for 24 hrs. Strain rates of 1% and 0.5% were used to perform direct shear tests on dry samples and samples at field moisture contents, respectively. The sample density for the direct shear tests was based on measurements from a nuclear gauge. The dry density ranged from 1.06 to 2.31 g/cm3 (66.5 to 144.8 pcf) with an average of 1.69 g/cm3 (106 pcf) and standard deviation of 0.15 g/cm3 (9.6 pcf). The wet density ranged from 1.16 to 2.43 g/cm3 (72.4. to 151.9 pcf) with an average of 1.8 g/cm3 (112.5 pcf) and standard deviation of 0.18 g/cm3 (11 pcf). Therefore, a dry density of 1.7 ± 0.2g/cm3 (106 ± 10pcf) or a wet density of 1.8 ± 0.2 g/cm3 (112.5 ± 11 pcf) was selected for the shear box tests. The purpose of using only one value of dry density or wet density for all samples was to reduce the number of variables that could affect the friction angle. The specimens were prepared by lightly compacting the soil in three lifts so that each lift had the same relative compression. Normal stresses required for testing were estimated by dividing the applied load by the area of the shear box. Loads represented the weight of the rock pile overburden 44 consistent with the depth of the sample in the rock pile. Using a 2-inch shear box, the normal stress varied between 50 kPa (1044.27 psf) and 800 kPa (16708 psf). These values duplicate depths in the rock pile between 3 m and 48 m (9.8 ft to 157.6 ft) considering sample density of 1.7 g/cm3 (106 pcf). For a 4-inch shear box the maximum normal stress that could be applied (due to equipment limitations) was less than half of the value ( 350 kPa or 7310 psf) obtained for a 2-inch shear box. This value duplicates a maximum depth in the rock pile of 21 m (69 ft) considering sample density of 1.7 g/cm3 (106 pcf). Peak shear strength and residual shear strength were determined from plots of shear stress versus shear strain. One example is shown in Figure 4.4. Internal friction angle was obtained using a linear best-fit line from the plot of peak shear strength versus normal stress. An example plot is given in Figure 4.5. The residual friction angle was obtained using a similar best-fit line. 45 Figure 4.3. This image shows the manual direct shear equipment used, with views showing the 2-inch square shear box, displacement dials and load frame. 800 Peak shear strength Residual shear strength 700 Shear stress (kPa) 600 500 400 300 200 Normal stress = 754kPa Normal stress = 562kPa 100 Normal stress = 356kPa Normal stress = 159kPa 0 0 2 4 6 8 10 12 Shear strain (%) 46 14 16 18 20 Figure 4.4. This graph shows an example of a shear stress versus shear strain plot. The test was conducted at four different normal stresses 159, 356, 562, and 754 kPa. The arrows indicate the peak shear strength and the residual shear strength. Peak internal friction angle Residuall friction angle 800 700 peak Shear strength (kP 600 500 400 residual 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) Figure 4.5. This image show an example of a shear diagram showing the best fit line for the peak internal friction angle and the residual internal friction angle. 4.3.1. Initial Test A series of trial direct shear tests were performed to define the best conditions for testing. Results of the effect of shear box size, maximum particle size, and moisture content were studied to define the appropriate test conditions. The effects of particle size and shear box size on friction angle were investigated using dry samples and three maximum particle sizes: material passing the No. 3/8 (9.5 mm)sieve, material passing the No. 4 (4.75 mm) sieve, and material passing the No. 6 (3.35 mm) sieve. The investigation on the effect of shear box size was performed on dry samples passing the No. 4 and the No. 6 sieves. Each sample was tested in 2- and 4-inch square shear boxes. The direct 47 shear tests for samples at field moisture content were performed using a 2-inch shear box on material passing a No. 6 sieve. The effects of shear box size, maximum particle size, and moisture are presented in plots of shear stress versus normal stress shown in Figures 4.6 through 4.8 and in summary Tables 4.3 through 4.5. Figure 4.6 shows the results of initial direct shear tests for two samples from GHN, using 2- and 4-inch shear boxes. Table 4.3 summarizes the results for both samples. The difference in internal peak friction angle with shear box size was statistically insignificant as shown by the high correlation (R2) values. Therefore, the selection of the shear box size was based on the surface area of shearing that provided the range of normal stresses that encompassed the field normal stresses. The 2-inch shear box provided a range of normal stress between 50 kPa (1044.27 psf) to 800 kPa (16708 psf). The 4-inch shear box provided a range of normal stress between 50 kPa (1044.27 psf) to 350 kPa (7310 psf). Therefore, the 2-inch shear box size was selected for this study rather than the 4-inch shear box. 48 600 Sample ID: GHN-KMD-0056 dmax = 4.76mm 500 = 1.03 n Shear stress(kPa) 400 R2 = 0.99 peak = 45.8o 300 200 4inch shear box 100 2inch shear box 0 0 100 200 300 400 500 600 Normal stress (kPa) (a) 600 Sample ID: GHN-LFG-0003 dmax = 4.76mm Shear stress(kPa) 500 400 = 0.95 n R2 = 0.98 peak = 43.2o 300 200 4inch shear box 100 2inch shear box 0 0 100 200 300 400 500 600 Normal stress (kPa) (b ) Figure 4.6. Shear box size effects on direct shear test (a) for sample GHN-KMD0056 with dmax = 4.76 mm, (b) GHN-LFG-0003 with dmax = 4.76 mm. 49 Table 4.3. Summary of the results from direct shear tests using different maximum particle size and shear box size. Sample ID Maximum particle size mm GHN-KMD-0056 4.76 GHN-LFG-0003 Shear box Size (in) Peak internal friction angle (degrees) R2 2 46.12º 0.9955 4 45.57º 0.9978 2 43.5º 0.9858 4 43.5º 0.9913 4.76 Figure 4.7 shows the effects of maximum particle size for samples GHN-KMD0056 and GHN-LFG-0003. There was little difference in internal peak friction angle with variations in maximum particle size (dmax). Both samples showed correlation (R2) values of 0.98 for the best fit lines. When each series of direct shear tests are considered separately, the results show an increase in correlation (decrease of data scatter) with a decrease in dmax as shown in Table 4.4. Based on these results, a conservative maximum particle size of 3.36 mm was selected for testing the remainder of the samples to minimize possibility of data scatter. 50 600 Sample ID: GHN-KMD-0056 2-inch shear box size Shear stress(kPa) 500 R2 = 0.98 peak = 47.4o 400 300 200 dmax = 9.52 mm dmax = 4.76 mm 100 dmax = 3.36 mm 0 0 100 200 300 400 500 600 Normal stress (kPa) (a) 600 Sample ID: GHN-LFG-0003 2-inch shear box size Shear stress(kPa) 500 R2 = 0.98 peak = 45o 400 300 200 dmax = 4.76 mm dmax = 3.36 mm 100 0 0 100 200 300 400 500 600 Normal stress (kPa) (b ) Figure 4.7. This figure shows the results of the effect of particle size on direct shear tests using a 2-inch shear box for (a) sample GHN-KMD-0056 with maximum particle sizes (dmax) of 9.52, 4.76, and 3.36 mm and (b) sample GHN-LFG-0003 with dmax of 4.76 and 3.36 mm. 51 Table 4.4. This table summarizes the results from direct shear test using different maximum particle sizes. Shear Maximum particle size box Size (mm) (in) Sample ID GHN-KMD-0056 GHN-LFG-0003 2 2 Peak internal friction angle (degrees) R2 9.52 48.8º 0.9654 4.76 47º 0.9901 3.36 46.05º 0.9963 4.76 43.5º 0.9840 3.36 45.5º 0.9891 Direct shear results for different moisture contents are given in Table 4.5 and Figure 4.8. Adding water decreased the peak internal friction angle and increased the apparent cohesion component, as shown in Table 4.5. The cohesion component is estimated from the plot of shear stress versus normal stress by the interception of the trendline with the y-axis. Measurements of pore water pressure were not done because of limitations of the testing equipment. The remaining tests were conducted on dry samples. Table 4.5. This table is a summary of direct shear test results for samples at dry and moist states. samples air-dried Sample ID Peak internal friction angle (degrees) Apparent cohesion (kPa) GHN-KMD-0017 42.15º 0 GHN-KMD-0018 44.43º 0 Trying to achieve field moisture content Moisture Peak internal friction angle (degrees) Apparent cohesion (kPa) 14.97 12.40 34.27º 34.09 13.45 11.00 33.9º 41.33 Field moisture content content (%) achieved (%) 52 GHN-KMD-0017 700 600 Shear stress (kPa) dry note: shear box size: 2 inches max. part. Size: 3.36mm moisture 12.4% 500 2 R = 0.96 peak = 42o 400 300 200 2 R = 1.00 peak = 34o 100 0 0 100 200 300 400 500 600 700 Normal stress (kPa) (a) GHN-KMD-0018 600 note: shear box size: 2 inches max. part. Size: 3.36mm Shear stress (kPa) 500 dry moisture 11% 400 2 R = 0.99 peak = 44.4o 300 2 R = 0.96 peak = 33.9o 200 100 0 0 (b ) 100 200 300 400 500 600 Normal stress (kPa) Figure 4.8. This figure compares the results of the influence of moisture on the direct shear test for samples (a) GHN-KMD-0017 and (b) GHN-KMD-0018. 53 The remaining direct shear tests were performed in a 2-inch shear box using dry samples. Samples were first sieved on a No. 6 sieve (3.35 mm), then a minimum of four fractionsof approximately 120 g (~ 4 oz) ofeach specimen were used for the tests. A dry density of 1.7 ± 0.2g/cm3 (106 ± 10pcf) was achieved for all samples. A small density range was desired to reduce the number of variables affecting the friction angle. All the specimens were prepared by lightly compacting three lifts to attain the same relative compression. A strain rate of 1% and normal stress varying from 159 to 800 kPa (23 to 116 psi) were adopted for all the tests. 4.4. Index Properties and Mineralogy Other physical properties characterized in this study include moisture content, liquid limit (LL), plastic limit (PL), plasticity index (PI), and specific gravity. Definitions of theses terms as used in this document are given in appendix G. Tests were conducted according to ASTM standard procedures (ASTM, 2001a; ASTM, 2001b; ASTM, 2002b). Mineralogy of the samples was determined using a modal mineralogy analysis provided by geoscientists at the New Mexico Bureau of Geology and Mineral Resources. The modal mineralogy combines results from various chemical and mineralogical analyses, including petrography, electron microprobe, clay mineralogy, pyrite concentrations using the Reitveld method, and whole rock chemistry from X-ray fluorescence (XRF) spectrometry. More information regarding the methodologies used to determine the modal mineralogies can be found in project reports (McLemore et al., 2006) and project standard operating procedures (Appendix F). 54 5. RESULTS AND DISCUSSIONS Results of the measurements performed for this study are found in Appendices B through E. Particle size analyses are located in Appendix B. Appendix C contains direct shear stress-strain plots. Mohr Coulomb diagrams are given in Appendix D. In Appendix E, sample mineralogy, measurements of Atterberg limits, direct shear test results, specific gravity, particle size distribution, and moisture content are summarized. 5.1. Indices Testing Tables 5.1 through 5.3 present results of particle size analysis, measurements of Atterberg limits, moisture content, paste pH, and direct shear test results for samples from the GHN rock pile arranged according to geologic units. Geologic units were defined based on grain size, color, texture, stratigraphic position, and other physical properties that could be determined in the field. Their characteristics are described in Appendix E and in McLemore et al. (2005, 2006). Based on gradation and Atterberg limits, the majority of samples from the GHN rock pile are classified as poorly- to well-graded gravels with fines and sand according to the United Soil Classification System (USCS). The table given in Appendix B shows the USCS symbols for all soils that were classified. Soil ranged from GW, GW-GC, GWGM, GP, GP-GC, GP-GM, SC, SM, SW-SC, and SP-SC. Figure 5.1 shows the range of particle size distributions for all the samples listed in Appendix B. Most of the fines were 55 identified as CL-group using the plasticity chart shown in Figure 5.2. The CL-group is an inorganic clay with low swell potential. The remaining samples fall in the ML category, which is an inorganic silt. Table 5.1. This table is a summary of particle size analyses for samples from GHN indexed by geologic unit. Number of Samples Geologic unit Gravel (%) Sand (%) Fines (%) Silt (%) Clay (%) Ave Max Min Ave Max Min Ave Max Min Ave Max Min Ave Max Min C 41.83 - - 46.95 - - 11.22 - - 5.51 - - 5.57 - - 1 I 46.45 55.69 37.21 37.99 43.66 32.32 15.56 19.13 11.99 12.72 14.57 10.87 2.84 4.56 1.12 2 J 56.77 63.40 49.84 35.29 41.01 29.36 7.94 10.70 4.70 6.25 8.34 4.42 1.69 3.97 0.28 5 54.55 57.57 51.53 35.88 38.95 32.80 9.45 9.99 9.36 8.13 8.18 8.07 1.46 1.46 1.45 2 K 54.90 69.62 45.06 35.24 44.20 24.97 9.86 12.54 5.41 6.16 7.97 3.12 3.69 5.71 2.28 4 O 55.25 70.45 41.56 35.45 47.93 24.21 9.31 12.64 5.34 6.26 8.20 3.23 3.04 4.89 2.10 10 M 61.18 - - 28.83 - - 9.99 - - 5.58 - - 4.41 - - 1 R 54.51 63.12 45.90 35.09 41.12 29.07 10.40 12.98 7.82 7.41 8.78 6.05 2.89 4.20 1.77 2 Oxidized, outter zone Intermediate zone N Unoxidized, internal zone S 64.90 74.83 54.98 26.64 33.68 19.59 8.46 11.34 5.58 5.87 7.04 4.70 2.59 4.31 0.88 2 U 69.49 87.39 60.06 24.10 32.33 9.66 6.41 8.66 2.95 3.77 5.05 1.70 2.63 3.61 1.25 3 V 61.44 65.12 58.75 30.69 33.31 28.11 7.87 8.90 6.77 4.97 5.31 4.57 2.90 3.58 2.20 3 56 Table 5.2. This table is a summary of Atterberg limit results for samples from GHN indexed by geologic unit. Plastic limit, PL Geologic unit Liquid limit, LL Plasticity index, PI Number of Samples Average Maximum Minimum Average Maximum Minimum Average Maximum Minimum I 23.28 24.67 21.88 32.62 35.28 29.95 11.60 17.91 5.28 2 J 19.84 22.08 17.96 34.12 38.44 28.73 14.29 17.24 9.26 3 22.66 24.88 20.44 34.73 35.58 33.88 14.72 15.14 14.29 2 Oxidized, outter zone Intermediate zone N Unoxidized, internal zone K 19.30 19.56 19.04 30.60 34.68 26.51 11.80 15.13 8.47 3 O 20.09 23.50 16.55 33.21 37.81 29.55 13.34 17.82 9.15 7 M 19.02 - - 30.03 - - 11.01 - - 1 R 16.80 - - 35.51 - - 18.76 - - 1 S 20.94 - - 28.11 - - 11.01 - - 1 U 22.39 26.45 18.33 33.62 34.52 32.71 11.23 14.38 8.07 2 V 22.00 25.64 18.36 32.44 35.34 29.54 10.44 16.98 3.90 2 Table 5.3. This table is a summary of moisture content and paste pH results for samples from GHN indexed by geologic unit. Geologic Unit Number of samples Moisture Content (%) Average Maximum Minimum Number of samples Paste pH (s.u.) Average Maximum Minimum Oxidized, outer zone C 6.97 9.33 5.48 3 2.85 3.43 2.33 12 I 15.47 23.89 10.72 5 3.07 4.77 2.19 28 J 10.39 17.13 6.61 16 3.37 5.75 2.14 52 13.13 17.25 9.6 17 3.39 4.71 2.15 58 K 10.16 11.77 8.34 9 4.83 7.2 2.36 36 L 8.62 1 6.46 8.74 2.25 9 O 11.2 18.01 6.15 50 5.49 8.98 2.43 163 M 10.45 15.09 5.54 13 4.45 9.56 2.41 57 R 10.51 11.46 9.91 3 6.05 9.6 3.17 16 S 10.43 13.36 7.43 6 6.25 9.47 2.61 20 U 10.61 13.23 7.99 2 3.86 5.52 2.45 15 V 9.23 9.6 8.59 3 4.39 5.77 3.37 11 W 9 9.58 8.41 2 6.65 6.68 6.62 2 Intermediate zone N Unoxidized, internal zone 57 U.S. STANDARD SIEVE SIZE 4 6 100 3 2 1-1/2 1 3/4 1/2 3/8 1/4 4 8 10 16 20 30 40 50 60 100 140 200 90 PER CENT FINER BY WEIGHT 80 70 60 50 40 range of grain size distribution 30 20 10 0 1000.0000 100.0000 10.0000 1.0000 0.1000 0.0100 0.0010 GRAIN SIZE MILLIMETERS BOULDERS COBBLES SAND GRAVEL Coarse Fine Coarse SILT OR CLAY Medium Fine Figure 5.1. This graph shows the range of grain size distribution for samples from the GHN rock pile. 60 U IN E -L IN CH or OH 40 A Plasticity index (PI) E 50 -L CL 30 ML CL or OL 20 MH or OH CL-ML 10 ML or OL 0 0 10 20 30 40 50 60 70 80 90 100 Liquid limit (LL) Figure 5.2. This graph shows the distribution of samples from the GHN rock pile on the plasticity chart. 58 5.2. Direct Shear Test Results The peak internal friction angle () and the residual friction angle (residual) were measured by direct shear tests using dry samples with maximum particle sizes of 3.36 mm (0.13 in). The test results are given in Table 5.4. The peak internal friction angle ranged from 40º to 47º and the residual friction angle varied between 37º and 41º. Correlation coefficients (R2) for tests on peak angles ranged from 0.95 to 1.00 and averaged 0.99 for a minimum of four tests. High correlations demonstrated that individual test conditions were reproducible, therefore high confidence can be placed on the results. Dry densities obtained during the tests ranged from 1.48 to 1.82 g/cm3 (92.4 to 113.6 pcf). The maximum dry density obtained for the relative density test was 1.82g/cm3 (113.6 pcf). Therefore, the maximum and minimum relative test densities were 100% and 81%, respectively. The average test relative density was 95%. Typical values of internal friction angle and residual friction angle for sand-sized material are 28º to 60º (Holtz and Kovacs, 2003) and 26º to 35º (Das, 1983), respectively. The lower range applies to round, loose sand and the higher range is for angular, dense sand. The values for internal friction angle are higher than the values reported for saturated conditions ( average = 31º and 36º) in past geotechnical studies conducted on the GHN rock pile (Norwest Corporation, 2004; Robertson GeoConsultants Inc., 2000). The difference in between dry and saturated conditions is to be expected. Figure 5.3 shows normal stress versus shear stress for one sample tested both dry and at 12.4% moisture content. It is clear that the addition of water to soil with an appreciable amount of non- 59 clay fines (19.3% in this case) produced an apparent cohesion. As such, was reduced from its value in the dry soil case. Table 5.4. This summary table shows direct shear test results of samples from GHN indexed by geologic unit. In te rn a l fric tio n a n g le (d e g re e s ) R e s id u a l fric tio n a n g le (d e g re e s ) A v e ra g e M a x im u m M in im u m A v e ra g e M a x im u m M in im u m I 43 43 42 38 38 38 2 J 44 43 45 39 39 38 3 44 44 44 38 39 37 2 K 44 47 42 38 39 37 3 O 44 47 42 38 41 37 13 M 44 - - 41 - - 1 R 44 45 43 40 40 39 2 S 45 - - 37 - - 1 P 46 - - 37 - - 1 U 44 46 43 38 39 37 4 V 46 47 44 40 40 39 2 G e o lo g ic u n it Num ber of S a m p le s O x id iz e d , o u tte r z o n e In te rm e d ia te z o n e N U n o x id iz e d , in te rn a l z o n e 60 GHN-KMD-0017 700 600 Shear stress (kPa) dry note: shear box size: 2 inches max. part. Size: 3.36mm moisture 12.4% 500 2 R = 0.96 peak = 42o 400 300 200 2 R = 1.00 o peak = 34 100 0 0 100 200 300 400 500 600 700 Normal stress (kPa) Figure 5.3. This graph shows direct shear test results for a dry sample versus a sample with gravimetric moisture content of 12.4%. In the case of saturated soils, is often further reduced if small amounts of clay are present in the fines. Internal friction angles were correlated with weathering, chemistry, and mineralogical effects. As such, the reader is reminded that these tests were conducted on disturbed samples. The values determined from these tests should not be used for slope stability considerations. 5.3. Verification of Direct Shear Test Results Additional direct shear tests were conducted using a calibrated Ele direct shear testing apparatus borrowed from Kleinfelder Laboratory in Albuquerque. The proving ring for this motorized machine is annually calibrated. A 2.5-inch round shear box was used to test three samples from the GHN rock pile: GHN-KMD-0014, GHN-KMD-0017, 61 and GHN-KMD-0027. The purpose of these tests was to provide validation of the tests conducted with the manual Soiltest shear box machine in the Mineral Engineering Department at New Mexico Tech. The Mohr-Coulomb diagrams for these tests using both machines are shown in Figures 5.4 through 5.6. The shear test results using the Ele machine fell along the trend lines defined by data generated with the machine at New Mexico Tech (NMT). The addition of the corroborating data did not change the values. Therefore, all test results obtained at New Mexico Tech are considered to be representative and reproducible. Friction angle-NMT Residual Friciton angle- NMT Kleinfelder Lab. Kleinfelder Lab. 800 Sample ID. GHN-KMD-0014 Shear strength (kPa) 700 2 600 R = 1.00 500 400 300 2 R = 0.92 200 100 0 0 100 200 300 400 500 Norma stress (kPa) 600 700 800 Figure 5.4. This graph shows the Mohr-Coulomb diagram for sample GHN-KMD0014. Data points generated by both the automatic Ele and the manual NMT shear box machines are included. 62 Friction angle- NMT Residual friction angle - NMT Kleinfelder Lab Kleinfelder Lab 600 Sample ID. GHN-KMD-0017 Shear Strength (kPa) 500 2 R = 0.96 400 300 200 2 R = 0.97 100 0 0 100 200 300 400 500 600 Normal load (kPa) Figure 5.5. This graph shows the Mohr-Coulomb diagram for sample GHN-KMD-0017. Data points generated by both the automatic Ele and the manual NMT shear box machines are included. Friction angle - NMT Kleinfelder Lab 600 Sample ID. GHN-KMD-0027 Shear strength (kPa) 500 400 2 R = 0.97 300 200 100 0 0 100 200 300 400 Normal Load (kPa) 63 500 600 Figure 5.6. This graph shows the Mohr-Coulomb diagram for sample GHN-KMD0027. Data points generated by both the automatic Ele and the manual NMT shear box machines are included. 5.4.Correlations of Direct Shear Results with Geological and Geotechnical Parameters The influence of geological and geotechnical parameters on internal friction angle () were evaluated and correlated. Correlations were made with respect to geologic units. An example of these units is given in Figure 5.7 for bench 9 from Trench LFG-006. Similar stratigraphic positions of the units were evident at other elevations where samples were collected. The geological and geotechnical parameters examined included texture (lithology and alteration), modal mineralogy, chemistry, % fines, and Atterberg limit (liquid limit and plasticity index). The geological and geotechnical data used in this section are summarized in tables in Appendix E. Correlations are presented in Figures 5.8 through 5.22. In these plots, the samples are presented according to geologic unit. For all the plots in this section, the outer zone (oxidized zone) of the pile included unit I, the intermediate zone included units N and J, and the internal zone (unoxidized zone) included units O, K, M, S, P, R, U, and V. Graphs on the left represent correlations for bench 9 and graphs to the right represent all samples tested in this study, including bench 9. 64 Figure 5.7. This diagram shows the stratigraphic positions of the geologic units for bench 9 (Trench LFG-006). J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 0 1 2 3 4 5 6 7 8 9 10 0 1 2 3 4 Paste pH 5 6 7 8 9 10 Paste pH Figure 5.8. These graphs show cross plots of internal friction angle versus paste pH. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 0 1 2 3 4 5 6 7 8 9 10 0 NAGpH 1 2 3 4 5 6 7 8 9 10 NAGpH Figure 5.9. These graphs show cross plots of internal friction angle versus NAGpH. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. 65 J-N O K M-S-P I R-U-V 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 J-N O K M-S-P R-U-V 45 44 43 42 41 41 40 40 0 2 4 6 8 10 12 14 16 18 20 22 0 2 4 6 8 10 %Fines 12 14 16 18 20 22 %Fines Figure 5.10. These graphs show cross plots of internal friction angle versus percentage of fines. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P I R-U-V 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 J-N O K M-S-P R-U-V 45 44 43 42 41 41 40 40 0 2 4 6 8 10 12 14 16 18 0 20 2 4 6 8 10 12 14 16 18 20 Plasticity index Plasticity index Figure 5.11. These graphs show cross plots of internal friction angle versus plasticity index. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. 66 J-N O K M-S-P I R-U-V 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 J-N O K M-S-P R-U-V 45 44 43 42 41 41 40 40 20 22 24 26 28 30 32 34 36 38 40 20 42 22 24 26 28 30 32 34 36 38 40 42 Liquid limit Liquid limit Figure 5.12. These graphs show cross plots of internal friction angle versus liquid limit. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 0 20 40 60 80 100 0 %Amalia Tuff 20 40 60 80 100 %Amalia Tuff Figure 5.13. These graphs show cross plots of internal friction angle versus percentage of Amalia Tuff. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. 67 J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 0 20 40 60 80 100 0 20 40 %Andesite 60 80 100 %Andesite Figure 5.14. These graphs show cross plots of internal friction angle versus percentage of Andesite. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 0 10 20 30 40 50 60 70 80 90 100 0 %QSP alteration 10 20 30 40 50 60 %QSP alteration 68 70 80 90 100 Figure 5.15. These graphs show cross plots of internal friction angle versus quartzsericite-pyrite (QSP) alteration. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 0 10 20 30 40 50 60 70 80 90 100 0 10 20 30 %Propylitic alteration 40 50 60 70 80 90 100 %Propylitic alteration Figure 5.16. These graphs show cross plots of internal friction angle versus propyllitic alteration. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 0 1 2 3 4 5 6 7 0 8 1 2 3 4 LOI LOI 69 5 6 7 8 Figure 5.17. These graphs show cross plots of internal friction angle versus LOI (lost of ignition). Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P I R-U-V 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 J-N O K M-S-P R-U-V 45 44 43 42 41 41 40 40 0 2 4 6 8 10 12 14 16 18 0 20 2 4 6 8 10 12 14 16 18 20 %Epidote %Epidote Figure 5.18. These graphs show cross plots of internal friction angle versus percentage of epidote. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P I R-U-V 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 J-N O K M-S-P R-U-V 45 44 43 42 41 41 40 40 0 2 4 6 8 10 12 14 16 18 0 20 2 4 6 8 10 %Illite %Illite 70 12 14 16 18 20 Figure 5.19. These graphs show cross plots of internal friction angle versus percentage of illite. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P I R-U-V 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 J-N O K M-S-P R-U-V 45 44 43 42 41 41 40 40 0 0.5 1 1.5 2 2.5 3 0 3.5 1 2 3 4 %MgO %MgO Figure 5.20. These graphs show cross plots of internal friction angle versus percentage of MgO. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 0 0.5 1 1.5 2 2.5 3 3.5 0 %CaO 1 2 3 %CaO 71 4 5 Figure 5.21. These graphs show cross plots of internal friction angle versus percentage of CaO. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. J-N O K M-S-P R-U-V I 48 47 47 46 46 Internal friction angle (degrees) Internal friction angle (degrees) I 48 45 44 43 42 41 J-N O K M-S-P R-U-V 45 44 43 42 41 40 40 12 12.5 13 13.5 14 14.5 15 15.5 16 12 %Al2O3 12.5 13 13.5 14 14.5 15 15.5 16 %Al2O3 Figure 5.22. These graphs show cross plots of internal friction angle versus percentage of Al2O3. Plot on the left side includes samples only from bench 9. Plot on the right side includes all GHN samples tested in this study. Variations in values with paste pH and NAGpH are shown in Figures 5.8 and 5.9. A positive correlation of paste pH and NAGpH with is apparent only for bench 9 data. In Figures 5.10 through 5.12 correlations with geotechnical properties show a decrease in as PI, LL, and percent fines increase. These correlations are expected and documented in the literature (Das, 1983; Holtz and Kovacs, 2003). The increase of fines reduces the contacts between coarse grains, thereby reducing the interlocking contacts that results in a decrease in . Although test results are for dry samples, the effects of 72 fines with atmospheric moisture (1-3% in the laboratory) are apparent. If tests had been conducted at field moisture contents, these correlations would be far stronger. Correlations of with lithology (andesite and Amalia Tuff), shown in Figure 5.13 and 5.14, are not apparent. Alteration of these rock types is given in Figures 5.15 and 5.16. QSP alteration shows a weak negative trend with . The negative trend is probably caused by the presence of the clay mineral sericite. The negative correlation of with LOI (Figure 5.17) may be explained by the presence of clay minerals. An increasing in LOI can be translated in an increasing in clay minerals. Figures 5.18 and 5.19 show that there are weak trends to no correlations of with mineralogy. The same is true with MgO, CaO, and Al2O3 chemistry data (Figures 5.20 through 5.22). When each of these elements is plot separately correlations are week to absent. In summary, correlations of with geological parameters are weak or nonexistent. The weak correlations might be due to the small range in values obtained. Results from direct shear tests showed that varies from 42 to 47 degrees, with an average of 44 degrees, as summarized in Table 5.4. Considering a maximum error of ±2 degrees in friction angle (W. Wilson, personal communication, 2005), there is only a small statistical variation in friction angle within the rock pile. 5.5. Correlations of Direct Shear Test Results with Weathering Indexes A weathering index is a measure of how much the sample has weathered. Numerous weathering indexes have been proposed and used over the years, but most of 73 them are based only on geochemical parameters, which restricts their application to the type of environment for which they were developed. Therefore, there is a need to develop a weathering index for the rock piles at the Questa mine. For the purpose of identifying relative intensity of weathering of samples collected in the project, McLemore (2005) described a simple, descriptive weathering index (SWI) that is based upon field observations (color, grain size, mineral texture, and presence or absence of certain minerals indicative of weathering). Together with SWI, other published chemical weathering indexes are being evaluated as well. WPI – Weathering Potential Index (Reiche, 1943, Infran, 1996, 1999) WPI = 100*(K2O+Na2O+CaO+MgO-H2O) / (SiO2 +Al2O3 +Fe2O3+ FeO + TiO2+CaO+MgO +Na2O+K2O) MI – Miura Index (Miura, 1973) MI = (MnO +FeO+CaO +MgO+Na2O+K2O) / (Fe2O3+Al2O3+3H2O) The Weathering Potential Index, WPI (Reiche, 1943, Infran, 1996, 1999) and the Miura index, MI (Miura, 1973) had shown to be applicable in this study. These weathering indexes show a trend similar to paste pH (Figures 5.23 and 5.24). The paste pH and the weathering indexes show a trend of increasing weathering from the inner portion (less oxidized) to the outer portion (oxidixed egde). These weathering indexes are calculated based on chemical data reflecting changes in mineralogy (i.e. feldspar to clay, calcite-pyrite to gypsum-jarosite). The data and graphs in Figure 5.23 and 5.24 were generated by geoscientists at the New Mexico Bureau of Geology and Mineral Resources. 74 11121314151617181920- 20 bedrock rubble zone shear zone R,U,V and W M,S,P K O N J C and I 0.7 0.5 MI WPI 0.6 10 0.4 0.3 0 0.2 0 100 200 0 100 Hfrom 200 Hfrom Figure 5.23. This figure shows plots of the WPI and MI weathering indexes with distance across bench 9, trench LFG-006. The outer oxidized edge is at Hfrom=0 and the inner zone of the bench is at Hfrom=105. Weathering increases towards the left. 0.7 20 0.6 10 MI WPI 0.5 0 0.4 0.3 -10 0.2 0.1 -20 2 3 4 5 6 7 8 9 2 10 3 4 5 6 7 pastepH pastepH 75 8 9 10 Figure 5.24. This figure shows plots of WPI and MI vs. paste pH for all GHN samples. WPI and MI are explained in Figure 5.23. Figure 5.25 through 5.27 are plots of weathering indexes (SWI, WPI and MI) versus internal friction angle for samples from bench 9, trench LFG-006. A general trend of decreasing friction angle with increasing degree of weathering is apparent for all of these weathering indexes. A similar trend was observed in friction angle and weathering by Ifran (1996, 1999). The effects of weathering are not linear because weathering is so complex and dependent upon, lithology, composition of original rock, composition of fluids interacting with the rock pile material. I J-N O K M-S-P R-U-V Internal friction angle (degrees) 48 47 46 45 44 43 42 41 40 5 4 3 2 1 0 SWI Figure 5.25. This figure shows a cross plot of Friction angle versus simple weathering index (SWI) for bench 9 samples, trench LFG-006. Weathering intensity increases towards the left. 76 I J-N O K M-S-P R-U-V 48 Internal friction angle (degrees) 47 46 45 44 43 42 41 40 0 2 4 6 8 10 12 14 WPI Figure 5.26. This figure shows a cross plot of Friction angle versus weathering potential index (WPI) for samples from bench 9, trench LFG-006. The weathering intensity increases towards the left. I J-N O K M-S-P R-U-V 48 Internal friction angle (degrees) 47 46 45 44 43 42 41 40 0 0.2 0.4 0.6 0.8 MI Figure 5.27. This figure shows a cross plot of Friction angle versus Miura Index (MI) for samples from bench 9, trench LFG-006. The weathering intensity increases towards the left. 77 78 6. CONCLUSIONS AND RECOMENDATIONS This study presents an investigation of the influence of physical, geological, mineralogical, and chemical properties on shear strength properties of the GHN rock pile at Questa molybdenum mine, New Mexico. Representative samples were collected based upon visible changes in the weathering characteristics and were not collected for the purpose of slope stability analysis. Shear strength was analyzed using dry samples to eliminate the effects of cohesion. The influences of the physical, geological, mineralogical, and chemical properties of rock pile samples on friction angle were studied. The synthesis of these analyses leads to the following conclusions: The majority of samples from the GHN rock pile are classified as poorly to well graded gravels with fines and sand. Most of the fines (silt &clay) are classified as inorganic clay with low swell potential. The peak internal friction angle ranged from 40º to 47º and residual friction angle varied between 37º and 41º. These high values of peak internal and residual friction angle are attributed to grain shape (subangular to very angular) and relative density of the test specimens. The lowest were for materials near the face of the pile. Correlations of from GHN samples with chemistry, and mineralogy are shown to be weak or absent. 79 Negative correlations were observed for %Fines, LL, PI, LOI. The decreased as these parameters increased. Correlation of with lithology was not observed. The internal friction angle for samples from bench 9, trench LFG-006 showed some trends with three different weathering indexes. Friction angle decreased as degree of weathering increased. Recommendations for future work include: Determine the effects of cementation on friction angle. (Based on laboratory observations it may be possible to test the cementation by allowing the sample to air dry in the shear box. After the test is performed the sample would be broken down and tested again. The difference between the two friction angles is an estimation of the effect of cementation on friction angle.) Determine the effects of cohesion on the strength of the mine rock. Examine the mineralogy and chemistry on the same size fraction that is used in the direct shear test (i.e. test the assumption that the analyses on the entire sample reflect the particle size fraction used in the shear tests). 80 REFERENCES ASTM, 1987. Standard Preparation of Soil Samples for Particle Size Analysis and Determination of Soil Constants (D421), Annual Book of ASTM Standards. American Society for testing and Materials (ASTM), West Conshohocken, PA. ASTM, 1998. Standard Test Method for Direct Shear Test of Soils Under Consolidated Drained Conditions (D3080), Annual Book of ASTM Standards. American Society for Testing and Materials (ASTM), West Conshohocken, PA. ASTM, 2001a. Standard Laboratory Determination of Water (moisture) Content of Soil, Rock, and Soil-Aggregate Mixtures (D2216). Annual Book of ASTM Standards. American Society for Testing and Materials (ASTM), West Conshohocken, PA. ASTM, 2001b. Standard Test Method for Liquid Limit, Plastic Limit, and Plasticity Index of Soils (D4318). Annual Book of ASTM Standards. American Society for Testing and Materials (ASTM), West Conshohocken, PA. ASTM, 2002a. Standard Test Method for Particle-Size Analysis of Soils (D422), Annual Book of ASTM Standards. American Society for Testing and Materials (ASTM), West Conshohocken, PA. ASTM, 2002b. Standard Test Methods for Specific Gravity of Soil Solids by Water Pycnometer (D854), Annual Book of ASTM Standards. American Society for Testing and Materials (ASTM), West Conshohocken, PA. Barrett, P.J., 1980. The Shape of Rock Particles, A Critical Review. Sedimentology, 27: 291-303. Birkeland, P.W., 1999. Soils and Geomorphology. Oxford University Press, Inc., New York, 430 pp. Bowles, J.E., 1979. Physical and Geotechnical properties of soils, 1. McGraw-Hill, Inc., 478 pp. 81 Calcaterra, D., Parise, M. and Dattola, L., 1998. Weathering Processes in Crystalline Rocks of the Sila Massif, Calabria, Southern Italy, as Predisposing Factor for the Development of Debris Flows. In: A. Evangelista and L. Picarelli (Editors), The Second International Symposium on Hard Soils-Soft Rocks. A. Balkema, Naples, Italy, pp. 73-84. Campbell, A.R., Lueth, V.W. and Pandey, S., 2005. Stable Isotope Discrimination of Hypogene and Supergene Sulfate Minerals in Rock Piles at the Questa Molybdenum Mine, New Mexico. Geological Society of America Abstracts with Programs. Carpenter, R.H., 1968, Geology and Ore Deposits of the Questa Molybdenum Mine Area, Taos County, New Mexico: Ore Deposits of the United States, 1933-1967,vol. 2, AIME Graten-Sales, p.1328-1350. Cho, G.C., Dodds, J. and Santamarina, C.J., 2004. Particle Shape Effects on Packing Density, Stiffness and Strength of Natural and Crushed Sands - Internal Report, Georgia Institute of Technology, 33pp. Clark, M.J. and Samall, R.J., 1982. Slopes and Weathering. London, Cambridge University Press, 112pp. Das, B.M., 1983. Advanced Soil Mechanics. New York, McGraw-Hill Book Company, 511 pp. Gerrard, A.J., 1988. Rocks and Landforms. London, Academic Division of Unwin Hyman, 319 pp. Hawley, P.M., 2001. Site Selection, Characterization, and Assessment. In: W.A. Hustrulid, M.K. McCarter and D.J.A. Van Zyl (Editors), Slope Stability in Surface Mining. Society for Mining, Metallurgy, and Exploration, Inc (SME). Littleton, pp. 267-274. Holtz, R.D. and Kovacs, W.D., 2003. An Introduction to Geotechnical Engineering. Civil Engineering and Engineering Mechanics Series. Pearson Education Taiwan Ldt., 733 pp. Holtz, W.G., 1960. The Effect of Gravel Particles on Friction Angle, ASCE Research Conference on Shear Strength, pp. 1000-1001. 82 Holtz, W.G. and Gibbs, H.G., 1956. Triaxial Shear Tests on Previous Gravelly Soils. Journal of Soil Mechanics and Foundation Engineering Division, 82: 1-22. Huat, B.B.K., Ali, F.H. and Affendi, A., 2005. Shear Strength Parameters of Unsaturated Tropical Residual Soils of Various Weathering Grades. EJGE. Irfan, T. Y., 1996, Mineralogy, fabric properties and classification of weathered granites in Hong Kong: Quaternary Journal of Engineering Geology, v. 29, p. 5-35. Irfan, T. Y., 1999, Characterization of weathered volcanic rocks in Hong Kong: Quaternary Journal of Engineering Geology, v. 32, p. 317-348. Krumbein, W.C., 1941. Measurement and Geological significance of Shape and Roundness of Sedimentary Particles. Journal of Sedimentary Petrology, 11(2): 6472. Leps, T.M., 1970. Review of Shearing Strength of rockfill. Journal of Soil Mechanics and Foundation Engineering Division, 96(SM4): 1159-1170. Lewis, H. S., Susteyo, W., Miller, S. D., and Jeffery, J. J., 1997, Waste Rock Management Planning and Implementation at P.T. Freeport Indonesia Company s Mining Operations in Irian Jaya., Fourth International Conference on Acid Rock Drainage: Vancouver, p. 1361-1376. Liu, C. and Evett, J.B., 2003. Soil Properties Testing, Measurements, and Evaluation, Prentice Hall, Upper Saddle River, New Jersey, 5th Edition, 423p. Lumb, P., 1962. The Properties of Decomposed Granite. Geotechnique, 12: 226-43. Lumb, P., 1965. The Residual Soils of Hong Kong. Geotechnique, 15: 180-194. McLemore, V.T., Lueth, V. and Walker, B.M., 2004. Alteration Scars in the Red River Vallley, Taos County, New Mexico. New Mexico Geological Society Guidebook, 55: 19-24. McLemore, V.T. et al., 2005. Preliminary Status Report On Molycorp Goathill North Trenches, Questa, New Mexico, 2005 National Meeting of the American Society 83 of Mining and Reclamation. American Society of Mining and Reclamation, Breckenridge, Colorado, pp. 26. McLemore, V.T. et al., 2006. Characterization of Goathill North Mine Rock Pile, Questa Molybdenum Mine, Questa, New Mexico, International Conference of Acid Rock Drainage (ICARD). ASMR, St. Louis. Meyer, J.W. and Leonardson, R.W., 1990. Tectonic, Hydrothermal and Geomorphic controls on alteration scar formation near Questa, New Mexico, New Mexico Geological Society Guidebook, pp. 417-422. Miura, K., 1973, Weathering in plutonic rocks. Part I weathering during the late-Pliocene of Gotsu plutonic rock: Journal Society Engineering Geology Japan, v. 14, no. 3 Molycorp Inc., 2002. Request for Letters of Intent. In: B. Walker (Editor), Questa, NM. Norwest Corporation, 2003. Goathill North Mine Rock Pile Evaluation and Conceptual Mitigation Plan. Unpublished Report to Molycorp Inc. Norwest Corporation, 2004. Goathill North Slide Investigation, Evaluation and Mitigation Report, Unpublished Report to Molycorp Inc. Pernichele, A.D. and Kahle, M.B., 1971. Stability of Waste Dumps at Kennecott's Bingham Canyon Mine. Tansactions, Society of Mining Engineers, AIME, 250: 363-367. Quine, R.L., 1993. Stability and deformation of mine waste dumps in north-central Nevada. M. S. Thesis, University of Nevada, Reno, 402 pp. Reiche, P., 1943, Graphic representation of chemical weathering: Journal of Sedimentary Petrology, v. 13, p. 58–68. Robertson, A.M., 1982. Deformation and Monitoring of Waste Dump Slopes, pp. 16. Robertson, A.M., 1985. Mine Waste Disposal: An Update on Geotechnical and Geohydrological Aspects. 84 Robertson GeoConsultants Inc., 2000. Interim Mine Site Characterization Study, Questa Mine, New Mexico. 052008/10, Robertson Geoconsultants Inc. Unpublished Report toMolycorp Inc. Seedsman, S.A. and Emerson, W.W., 1985. The Role of Clay-rich Rocks in Spoil Pile Failures at Goonyella Mine, Queensland, Australia. International Journal of Rock Mechanicas and Mining Science, 22: 113-118. Shaw, S.C., Wels, C., Roberston, A. and Lorinczi, G., 2002. Physical and Geochemical Characterization of Mine Rock Piles at the Questa Mine, New Mexico: An Overview, 9th International Conference on Tailings and Mine Waste ’02. Balkema., Rotterdam. Tachie-Menson, S., 2005. Characterization of Acid Drainage Potential from the Goathill North Rock Pile of the Questa Molybdenum Mine, Questa, New Mexico - Initial Results. Geological Society of America Abstracts with Programs, 37(7): 349. Terzaghi, k., Peck, R.B. and Mesri, G.M., 1996. Soil Mechanics in Engineering Practice. John Wiley and Sons, Inc., New York, 549 pp. Thuro, K. and Scholz, M., 2003. Deep Weathering and Alteration in Granites - A Product of Coupled Processes, International Conference on Coupled T-H-M-C Processes in Geosystems: Fundamentals, Modeling, Experiments and Applications, Sweden. U.S. Army Corps of Engineers, 1970. Grain Size Analysis, Engineering Design: Laboratory Soil Testing. Department of the Army Headquaters, Washington, DC, pp. V1-V28. URS Corporation, 2000. Interim Mine Rock Pile Erosion and Stability Evaluations, Questa Mine. Unpublished Report to Molycorp Inc. URS Corporation, 2003. Mine Rock Pile Erosion and Stability Evaluations Questa Mine, Unpublished Report to Molycorp, Inc. Wels, C.; Loudon, S.; Fortin, S., 2002. Factors influencing net infiltration into mine rock piles at Questa Mine, New Mexico; in Tailings and Mine Waste '02: proceedings of the Ninth International Conference on Tailings and Mine Waste: Fort Collins, Colorado, USA, p. 469-477 85 APPENDIX A – SAMPLE LOCATION 86 Sample GHN-KMD-0013 GHN-KMD-0014 GHN-KMD-0015 GHN-KMD-0016 GHN-KMD-0017 GHN-KMD-0018 GHN-KMD-0019 GHN-KMD-0026 GHN-KMD-0027 GHN-KMD-0051 GHN-KMD-0052 GHN-KMD-0053 GHN-KMD-0055 GHN-KMD-0056 GHN-KMD-0057 GHN-KMD-0062 GHN-KMD-0063 GHN-KMD-0065 GHN-KMD-0071 GHN-KMD-0072 GHN-KMD-0073 GHN-KMD-0074 GHN-KMD-0078 GHN-KMD-0079 GHN-KMD-0081 GHN-KMD-0082 GHN-KMD-0088 GHN-KMD-0092 GHN-LFG-0085 GHN-LFG-0088 GHN-LFG-0090 GHN-VTM-0450 GHN-VTM-0453 GHN-VTM-0454 UTM east UTM north (meters) (meters) Units O K R S I J O M N O K contact between Unit N I V O N J V Unit U, V contact coarse zone in Unit O O (coarse sand) U U U R O O O1 K O P O (coarse layer) O (clay rich) O 87 453696 453677 453723 453698 453772 453685 453708 453682 453708 453711 453727 453695 453696 453705 453657 453734 453647 453643 453648 453667 453667 453671 453672 453718 453676 453731 453657 453729 453740 453734 453740 453723 453676 453680 4062143 4062146 4062142 4062143 4062140 4062146 4062147 4062140 4062148 4062142 4062144 4062145 4062139 4062140 4062127 4062140 4062115 4062115 4062115 4062137 4062137 4062137 4062134 4062144 4062138 4062143 4062127 4062141 4062141 4062141 4062142 4062141 4062137 4062137 Elevation (ft) 9731 9691 9736 9731 9688 9694 9738 9689 9739 9734 9739 9698 9694 9697 9635 9755 9600 9599 9601 9644 9644 9646 9644 9737 9650 9760 9635 9736 9758 9736 9758 9736 9650 9650 APPENDIX B – GRAIN SIZE DISTRIBUTION CURVES AND SUMMARY TABLE 88 89 C H I I J J J J K K K K M N N N-J contant O O O O O O O O (clay rich) O (coarse sand) O (coarse) R R S S U U U U- V contact V V Geologic Units 0.25 0.47 0.09 0.064 0.054 0.35 GHNJRM0029 GHNKMD0018 GHNKMD0063 GHNKMD0096 GHNJRM0028 GHNKMD0014 0.1 0.16 GHNKMD0065 0.11 GHNKMD0079 0.26 2.85 GHNKMD0078 GHNKMD0056 0.19 GHNKMD0074 GHNKMD0071 0.425 GHNKMD0015 GHNKMD0016 0.17 GHNVTM0450 0.049 0.55 GHNKMD0073 0.056 0.079 GHNVTM0453 GHNKMD0080 0.07 GHNKMD0072 GHNKMD0081 0.16 0.0395 GHNLFG0088 0.06 0.1 GHNKMD0019 0.115 0.15 GHNJRM0031 GHNKMD0057 0.08 GHNJRM0030 GHNKMD0051 0.03 0.14 GHNKMD0053 GHNKMD0027 GHNKMD0028 0.075 0.075 GHNKMD0026 0.04 0.055 GHNKMD0055 0.067 0.013 GHNKMD0017 GHNLFG0085 0.05 GHNKMD0052 0.054 2.6 3.3 2.8 2.8 27 2.75 7.2 1.65 0.97 3 4.9 2.35 0.83 0.99 2.9 2.55 1.4 2.4 2.5 2 2.6 0.23 2.45 2.55 2.1 1.15 4.7 1.6 1.6 1.4 3.3 3.5 1.8 0.22 0.73 1.05 (mm) (mm) GHNLFG0037 D30 D10 GHNKMD0095 Field_id 20 17 14.8 19.5 320 15 47 13 6.7 11.6 10.7 12 5.1 7.9 15 11.6 8 10.2 10 8 19 2.9 10.3 19.2 12.5 7 10.7 6 6 9 10.3 10.2 10.3 4.0 6.3 5.1 (mm) D60 125 65 148 177 112 79 111 232 137 68 20 152 73 200 94 101 133 102 67 100 136 97 137 256 187 175 31 111 94 100 22 41 187 308 125 94 Cu 2.1 2.5 5.3 3.7 0.8 2.7 2.6 3.7 2.9 4.6 4.1 5.8 1.9 3.1 3.5 4.9 4.1 5.6 4.2 6.3 2.5 0.6 7.8 4.5 5.3 4.7 5.9 7.9 6.7 2.4 2.3 4.8 5.7 0.9 1.7 4.0 Cc 58.75 65.12 60.45 61.03 87.39 60.06 74.83 54.98 45.9 63.12 70.45 58.39 41.56 48.51 62.53 59.56 49.81 53.25 56.94 51.48 58.77 51.53 57.57 61.18 56.95 47.97 69.62 45.06 50.13 49.84 61.71 63.4 55.69 37.21 45.98 41.83 (%) Gravel 33.31 28.11 30.65 30.31 9.66 32.33 19.59 33.68 41.12 29.07 24.21 31.97 47.93 38.85 29.42 31.69 39.48 37.82 35 38.1 33.34 38.95 32.8 28.83 32.32 39.49 24.97 44.2 39.17 41.01 33.59 29.36 32.32 43.66 40.3 46.95 (%) Sand 7.94 6.77 8.9 8.66 2.95 7.61 5.58 11.34 12.98 7.82 5.34 9.64 10.51 12.64 8.05 8.75 10.71 8.93 8.06 10.42 7.89 9.53 9.36 9.99 10.74 12.54 5.41 10.74 10.7 9.15 4.7 7.24 11.99 19.13 13.72 11.22 (%) Fines 5.03 4.57 5.31 5.05 1.7 4.57 4.7 7.04 8.78 6.05 3.23 6.09 8.2 7.75 5.92 5.31 6.54 5.82 5.84 7.88 5.06 8.07 8.18 5.58 6.73 6.83 3.12 7.97 6.74 8.34 4.42 6.67 10.87 14.57 10.37 5.51 (%) Silt 2.91 2.2 3.58 3.61 1.25 3.04 0.88 4.31 4.2 1.77 2.1 3.55 2.3 4.89 2.13 3.44 4.17 3.11 2.22 2.54 2.83 1.46 1.45 4.41 4 5.71 2.28 2.77 3.97 0.82 0.28 0.57 1.12 4.56 3.34 5.71 (%) Clay CL ML ML CL CL n.d. CL n.d. CL n.d. n.d. n.d. CL CL CL CL CL ML n.d. n.d. CL n.d. ML CL CL CL CL n.d. CL CL n.d. CL ML ML n.d. CL GW-GC GW-GM GP-GM GP-GC GP n.d. GW-GC n.d. SC n.d. n.d. n.d. SW-SC SP-SC GP-GC GP-GC SP-SC GP-GM n.d. n.d. GW-GC n.d. GW-GM GP-GC GP-GC SC GP-GC n.d. GP-GC SW-SC GW GP-GC GP-GM SM n.d. SP-SC Classification USCS from plasticity Classification chart Well graded Well graded Poorly graded Poorly graded Well graded Well graded Well graded Poorly graded Well graded Poorly graded Poorly graded Poorly graded Well graded Poorly graded Poorly graded Poorly graded Poorly graded Poorly graded Poorly graded Poorly graded Well graded Well graded Poorly graded Poorly graded Poorly graded Poorly graded Poorly graded Poorly graded Poorly graded Well graded Well graded Poorly graded Poorly graded Well graded Well graded Poorly graded Comments 90 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution- GHN-JRM-0037 SILT 0.0100 HYDROMETER CLAY 0.0010 91 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution- GHN-KMD-0014 SILT 0.0100 HYDROMETER CLAY 0.0010 92 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0015 SILT 0.0100 HYDROMETER CLAY 0.0010 93 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution- GHN-KMD-0016 SILT 0.0100 HYDROMETER CLAY 0.0010 94 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0017 SILT 0.0100 HYDROMETER CLAY 0.0010 95 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0018 SILT 0.0100 HYDROMETER CLAY 0.0010 96 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0019 SILT 0.0100 HYDROMETER CLAY 0.0010 97 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0026 SILT 0.0100 HYDROMETER CLAY 0.0010 98 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0027 SILT 0.0100 HYDROMETER CLAY 0.0010 99 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0051 SILT 0.0100 HYDROMETER CLAY 0.0010 100 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0053 SILT 0.0100 HYDROMETER CLAY 0.0010 101 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0055 SILT 0.0100 HYDROMETER CLAY 0.0010 102 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0056 SILT 0.0100 HYDROMETER CLAY 0.0010 103 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0057 SILT 0.0100 HYDROMETER CLAY 0.0010 104 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0063 SILT 0.0100 CLAY HYDROMETER 0.0010 105 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0065 SILT 0.0100 HYDROMETER CLAY 0.0010 106 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0071 SILT 0.0100 HYDROMETER CLAY 0.0010 107 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0072 SILT 0.0100 HYDROMETER CLAY 0.0010 108 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0073 SILT 0.0100 HYDROMETER CLAY 0.0010 109 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0074 SILT 0.0100 HYDROMETER CLAY 0.0010 110 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0078 SILT 0.0100 HYDROMETER CLAY 0.0010 111 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0079 SILT 0.0100 HYDROMETER CLAY 0.0010 112 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-KMD-0081 SILT 0.0100 HYDROMETER CLAY 0.0010 113 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-LFG-0037 SILT 0.0100 HYDROMETER CLAY 0.0010 114 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-LFG-0085 SILT 0.0100 HYDROMETER CLAY 0.0010 115 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-LFG-0088 SILT 0.0100 HYDROMETER CLAY 0.0010 116 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-VTM-0450 SILT 0.0100 HYDROMETER CLAY 0.0010 117 PER CENT FINER BY WEIGHT BOULDERS 0 1000.0000 10 20 30 40 50 60 70 80 90 100 COBBLES 100.0000 3 2 Fine 10.0000 3/8 GRAVEL 1 3/4 Coarse 1-1/2 U.S. STANDARD SIEVE NUMBERS 4 1.0000 16 30 40 50 Coarse Medium SAND GRAIN SIZE MILLIMETERS 10 200 Fine 0.1000 60 100 Particle Size Distribution - GHN-VTM-0453 SILT 0.0100 HYDROMETER CLAY 0.0010 APPENDIX C – DIRECT SHEAR STRESS DIAGRAMS 118 Shear strain (H) Shear strain is obtained considering the following equation: H = (Horizontal deformation/ Sample length)*100 Horizontal deformation (in. 10-3) Sample length, Lo (in) Direct Shear Test Data Sheet Name Date Project Molycorp Specimen No. Visual Description notes 12/9/2005 GHN-EHP-0002 _1d_2_152 sample sieved with No. 6 2 Loads no. 25.81 Frame+Hanger Sample Length, Lo (in) 2 Sample area, Ao (cm ) Strain rate,L/Lo (100)/min (%/min) Deformation rate, L/min (in/min) (Lo x strain rate) 1 0.02 LC-8 dial gage divisions per min. 20 116.27 2.54 dry 1.77 Mass of sample(g) Sample height (cm) Moisture content (%) Dry density (Mg/m3) 3 Moist/saturated density (Mg/m ) Normal load (kg) Normal stress, n (kPa) Shear stress at failure,(kPa) Shear stain at failure, H (%) Horizontal deformation (sec) LC-8 (in.10 ) 0 15 30 45 60 75 90 105 120 135 150 165 180 195 210 225 240 -3 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 6 7 8 9 10 11 41.96 159.46 159.15 Residual shear strength (kPa) 132.79 5.00 primary none -1.01 secondary Vertical stain at failure, V (%) Elapsed Time 2 3 4 5 Mass(Kg) check mark 9.96 1 8.46 0 8.12 0 8.13 0 8.14 0 8.15 0 16 1 1 16 16 0 0 16 14.33 0 Vertical deformation Load Dial Gage (in.) LC-2 (in.10 ) 0.2932 0.2953 0.297 0.2983 0.2994 0.3001 0.3009 0.3025 0.3041 0.305 0.3058 0.306 0.306 0.306 0.306 0.306 0.3057 Shear Strain H Vertical Strain V Shear Load P Shear Stress P(98.07)/Ao (kg) (kPa) -4 0 117 145 171 195 215 231 244 258 268 274 280 286 288 290 293 295 0 0.250 0.500 0.750 1.000 1.250 1.500 1.750 2.000 2.250 2.500 2.750 3.000 3.250 3.500 3.750 4.000 119 0 -0.2100 -0.3800 -0.5100 -0.6200 -0.6900 -0.7700 -0.9300 -1.0900 -1.1800 -1.2600 -1.2800 -1.2800 -1.2800 -1.2800 -1.2800 -1.2500 0 16.33 20.24 23.87 27.22 30.01 32.25 34.06 36.02 37.41 38.25 39.09 39.93 40.20 40.48 40.90 41.18 0 62.07 76.92 90.72 103.45 114.06 122.55 129.44 136.87 142.18 145.36 148.54 151.73 152.79 153.85 155.44 156.50 GHN-KMD-0013 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0013 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 2 Vertical strain (%) Shear stress (kPa) 600 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 120 14 16 18 20 GHN-KMD-0014 800 700 600 Shear stress (kPa) Normal stress = 637kPa Normal stress = 457kPa 500 Normal stress = 303kPa Normal stress = 159kPa 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0014 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 121 14 16 18 20 GHN-KMD-0015 800 700 Normal stress = 754kPa Normal stress = 562kPa Normal stress = 356kPa 600 Shear stress (kPa) Normal stress = 159kPa 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0015 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 754kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 122 14 16 18 20 GHN-KMD-0016 800 Normal stress = 453kPa Normal stress = 368kPa 700 Normal stress = 243kPa Normal stress = 152kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0016 4 Normal stress = 152kPa Normal stress = 243kPa Normal stress = 368kPa Normal stress = 453kPa 3 Vertical srain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 123 14 16 18 20 GHN-KMD-0017 800 Normal stress = 460kPa Normal stress = 368kPa 700 Normal stress = 243kPa Normal stress = 122kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0017 4 Normal stress = 122kPa Normal stress = 243kPa Normal stress = 368kPa Normal stress = 460kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 124 14 16 18 20 GHN-KMD-0018 800 Normal stress = 453kPa Normal stress = 368kPa Normal stree = 243kPa Normal stress = 152kPa 700 Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0018 4 Normal stress = 152kPa Normal stree = 243kPa Normal stress = 368kPa Normal stress = 453kPa 3 Vertical strain(%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 125 14 16 18 20 GHN-KMD-0019 800 700 Shear stress (kPa) 600 500 Normal stress = 754kPa 400 Normal stress = 562kPa Normal stress = 356kPa 300 Normal stress = 159kPa 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0019 4 3 Vertical strain (%) 2 1 0 -1 -2 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 754kPa -3 -4 0 2 4 6 8 10 12 Shear strain (%) 126 14 16 18 20 GHN-KMD-0026 800 Normal stress = 427kPa Normal stress = 368kPa 700 Normal stress = 243kPa Normal stress = 152kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0026 4 Normal stress = 152kPa Normal stress = 243kPa Normal stress = 368kPa 3 Normal stress = 427kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 127 14 16 18 20 GHN-KMD-0027 800 Normal stress = 453kPa Normal stress = 368kPa Normal stress = 243kPa 700 Normal stress = 122kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0027 4 Normal stress = 122kPa Normal stress = 243kPa 3 Normal stress = 368kPa Normal stress = 453kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 128 14 16 18 20 GHN-KMD-0051 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0051 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 129 14 16 18 20 GHN-KMD-0052 900 Normal stress = 637kPa Normal stress = 457kPa 800 Normal stress = 303kPa Normal stress = 159kPa 700 Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0052 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical Strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 130 14 16 18 20 GHN-KMD-0053 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0053 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 131 14 16 18 20 GHN-KMD-0053_DUPLICATE 800 Normal stress = 637kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0053- DUPLICATE 4 Normal stress = 159kPa Normal stress = 303kPa 3 Normal stress = 637kPa Shear stress (kPa) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 132 14 16 18 20 GHN-KMD-0055 800 700 600 Normal stress = 754kPa Shear stress (kPa) Normal stress = 562kPa 500 Normal stress = 356kPa Normal stress = 159kPa 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0055 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 754kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 133 14 16 18 20 GHN-KMD-0056 800 Normal stress = 504kPa Normal stress = 368kPa Normal stress = 274kPa 700 Normal stress = 152kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0056 4 3 Vertical strain (%) 2 1 0 -1 Normal stress = 152kPa -2 Normal stress = 274kPa Normal stress = 368kPa -3 Normal stress = 504kPa -4 0 2 4 6 8 10 12 Shear strain (%) 134 14 16 18 20 GHN-KMD-0057 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0057 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 135 14 16 18 20 GHN-KMD-0057-DUPLICATE 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0057-DUPLICATE 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical Strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 136 14 16 18 20 GHN-KMD-0062 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0062 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 137 14 16 18 20 GHN-KMD-0063 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0063 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 138 14 16 18 20 GHN-KMD-0071 Normal stress = 754kPa 800 Normal stress = 562kPa Normal stress = 356kPa Normal stress = 159kPa 700 Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0071 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 754kPa 3 Vertical stress (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 139 14 16 18 20 GHN-KMD-0072 800 Normal stress = 754kPa Normal stress = 562kPa 700 Normal stress = 356kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0072 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 754kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 140 14 16 18 20 GHN-KMD-0073 Normal stress = 754kPa Normal stress = 562kPa 800 Normal stress = 356kPa Normal stress = 159kPa 700 Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0073 4 Normal stress = 159kPa Normal stress = 303kPa 3 Normal stress = 457kPa Normal stress = 754kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 141 14 16 18 20 GHN-KMD-0074 800 700 Shear stress (kPa) 600 500 Normal stress = 754kPa Normal stress = 562kPa 400 Normal stress = 356kPa Normal stress = 159kPa 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0074 4 Normal stress = 159kPa Normal stress = 303kPa 3 Normal stress = 457kPa Normal stress = 754kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 142 14 16 18 20 GHN-KMD-0078 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0078 4 Normal stress = 159kPa Normal stress = 303kPa 3 Normal stress = 457kPa Normal stress = 637kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 143 14 16 18 20 GHN-KMD-0079 800 Normal stress = 754kPa Normal stress = 562kPa 700 Normal stress = 356kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0079 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa 3 Normal stress = 754kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 144 14 16 18 20 GHN-KMD-0079-DUPLICATE 800 Normal stress = 754kPa Normal stress = 562kPa Normal stress = 356kPa 700 Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 22 24 26 Shear strain (%) GHN-KMD-0079-DUPLICATE 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 754kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 14 Shear strain (%) 145 16 18 20 22 24 26 GHN-KMD-0081 800 Normal stress = 430kPa Normal stress = 368kPa 700 Normal stress = 274kPa Normal stress = 152kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0081 4 Normal stress = 152kPa Normal stress = 274kPa 3 Normal stress = 368kPa Normal stress = 430kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 146 14 16 18 20 GHN-KMD-0081-DUPLICATE 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 22 24 16 18 20 22 24 Shear strain (%) GHN-KMD-0081-DUPLICATE 4 3 Vertical strain (%) 2 1 0 -1 -2 Normal stress = 159kPa Normal stress = 303kPa -3 Normal stress = 457kPa Normal stress = 637kPa -4 0 2 4 6 8 10 12 14 Shear strain (%) 147 GHN-KMD-0088 900 Normal stress = 637kPa Normal stress = 457kPa 800 Normal stress = 303kPa Normal stress = 159kPa 700 Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-KMD-0088 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 148 14 16 18 20 GHN-LFG-0037 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 22 24 Shear strain (%) GHN-LFG-0037 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 14 Shear strain (%) 149 16 18 20 22 24 GHN-LFG-0085 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-LFG-0085 4 Normal stress = 159kPa Normal stress = 303kPa 3 Normal stress = 457kPa Normal stress = 637kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 150 14 16 18 20 GHN-LFG-0088 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-LFG-0088 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 151 14 16 18 20 GHN-LFG-0090 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-LFG-0090 4 Normal stress = 159kPa Normal stress = 303kPa 3 Normal stress = 457kPa Normal stress = 637kPa Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 152 14 16 18 20 GHN-VTM-0450 800 700 Shear stress (kPa) 600 500 Normal stress = 754kPa Normal stress = 562kPa 400 Normal stress = 356kPa Normal stress = 159kPa 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-VTM-0450 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 754kPa 3 Shear stress (kPa) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 153 14 16 18 20 GHN-VTM-0453 800 Normal stress = 754kPa Normal stress = 562kPa Normal stress = 356kPa 700 Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-VTM-0453 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 754kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 154 14 16 18 20 GHN-VTM-0454 800 Normal stress = 637kPa Normal stress = 457kPa 700 Normal stress = 303kPa Normal stress = 159kPa Shear stress (kPa) 600 500 400 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 Shear strain (%) GHN-VTM-0454 4 Normal stress = 159kPa Normal stress = 303kPa Normal stress = 457kPa Normal stress = 637kPa 3 Vertical strain (%) 2 1 0 -1 -2 -3 -4 0 2 4 6 8 10 12 Shear strain (%) 155 14 16 18 20 APPENDIX D – MOHR COULOMB DIAGRAMS 156 Maximum Particle Size Sample ID Dry Density Minimum GHN-KMD-0056 GHN-LFG-0003 GHN-KMD-0071 3 (mm) (g/cm ) (g/cm ) No. 6 sieve (3.36mm) 1.42 1.85 1.38 1.76 1.43 1.84 1.41 1.82 No. 6 sieve (3.36mm) No. 6 sieve (3.36mm) Average Geologic Units Maximum 3 Sample ID Peak Friction Residual Angle Friction Angle (degrees) (degrees) 41 38 42 38 43 38 Test(1) Density (g/cm3) 1.75 1.72 1.78 Relative Density (%) 96 95 98 H I I GHN-LFG-0037 GHN-KMD-0017 GHN-KMD-0055 J J contact between Unit N-J N N GHN-KMD-0018 GHN-KMD-0063 GHN-KMD-0053 GHN-KMD-0027 GHN-KMD-0062 44 45 43 44 44 39 39 38 37 39 1.48 1.61 1.59 1.62 1.76 81 88 87 89 97 O O O O O O O O O O O O O GHN-KMD-0013 GHN-KMD-0019 GHN-KMD-0051 GHN-KMD-0057 GHN-KMD-0082 GHN-KMD-0088 GHN-LFG-0088 GHN-VTM-0454 GHN-VTM-0453 GHN-VTM-0450 GHN-KMD-0073 GHN-KMD-0092 GHN-KMD-0072 43 45 43 43 44 45 42 43 44 44 43 44 43 38 39 38 40 37 38 39 35 38 41 39 39 38 1.62 1.77 1.63 1.61 1.75 1.74 1.78 1.77 1.79 1.71 1.8 1.77 1.78 89 97 90 88 96 96 98 97 98 94 99 97 98 K K K GHN-KMD-0014 GHN-KMD-0052 GHN-LFG-0085 47 43 42 39 37 39 1.73 1.73 1.74 95 95 96 M P S GHN-KMD-0026 GHN-LFG-0090 GHN-KMD-0016 44 46 45 41 37 39 1.64 1.68 1.68 90 92 92 R R U U U Unit U, V contact V V GHN-KMD-0015 GHN-KMD-0081 GHN-KMD-0074 GHN-KMD-0078 GHN-KMD-0079 GHN-KMD-0071 GHN-KMD-0056 GHN-KMD-0065 45 43 44 46 43 43 47 44 40 39 39 38 38 37 40 39 1.76 1.79 1.79 1.78 1.75 1.79 1.82 1.77 97 98 98 98 96 98 100 97 Average 44 38 1.72 95 Maximum 47 41 1.82 100 Minimum 41 35 1.48 81 (1) Test density for one sample is an average of the achieved density from 4 specimens. 157 GHN-KMD-0013 Peak internal friction angle Residuall friciton angle 800 700 2 R = 0.99 o peak =42.6 500 400 2 R = 0.99 o residual =38 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0014 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) Shear stress (kPa) 600 R2 = 1.00 o peak =47.3 600 500 400 R2 = 0.92 residual =40.1 300 o 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 158 600 700 800 GHN-KMD-0015 Peak internal friction angle Residual friciton angle 800 700 2 R = 0.99 o peak =45.3 Shear stress (kPa) 600 500 400 2 R = 0.99 o residual =39.8 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0016 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 1.00 o peak =44.9 500 400 300 2 200 R = 0.99 residual =39.1 o 100 0 0 100 200 300 400 500 Normal stress (kPa) 159 600 700 800 GHN-KMD-0017 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 500 400 2 R = 0.96 o peak =42.1 300 200 2 R = 0.97 residual =37.9 o 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0018 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 500 400 2 R = 0.99 o peak =44.4 300 2 200 R = 0.98 residual =38.7 o 100 0 0 100 200 300 400 500 Normal stress (kPa) 160 600 700 800 GHN-KMD-0019 Peak internal friction angle Residual friciton angle 800 700 2 R = 0.95 o peak =45.2 Shear stress (kPa) 600 500 400 2 R = 0.81 o residual =38 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0026 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 500 400 2 R = 0.99 o peak =44 300 2 R = 0.97 o residual =40.7 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 161 600 700 800 GHN-KMD-0027 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 500 2 R = 0.97 400 peak =44.4 o 300 200 2 R = 0.99 100 residual =37.2 o 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0051 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.98 o peak =42.7 500 400 2 R = 0.99 o residual =37.9 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 162 600 700 800 GHN-KMD-0052 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.99 500 peak =42.3 o 400 2 R = 0.99 300 residual =36.9 o 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0053 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.99 o peak =43.3 500 400 2 R = 0.99 o residual =38 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 163 600 700 800 GHN-KMD-0053-DUPLICATE Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.99 o peak =42.8 500 400 2 R = 0.99 o residual =37.7 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0055 Peak internal friction angle Residual friciton angle 800 700 2 R = 0.99 Shear stress (kPa) 600 peak =43.2 o 500 400 300 2 R = 0.99 o residual =37.7 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 164 600 700 800 GHN-KMD-0056 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 500 2 R = 1.00 o peak = 47 400 300 2 R = 0.99 o residual = 40 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0057 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 1.00 o peak =43.1 500 400 2 R = 0.98 o residual =38.5 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 165 600 700 800 GHN-KMD-0057-DUPLICATE Peak internal friction angle 800 700 Shear stress (kPa) 600 2 R = 1.00 o peak =43.7 500 400 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0062 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.99 o peak =43.9 500 400 2 R = 0.97 o residual =38.9 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 166 600 700 800 GHN-KMD-0063 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 1.00 o peak =44.9 500 400 2 R = 0.99 o residual =38.9 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0071 Peak internal friction angle Residual friciton angle 800 700 2 R = 1.00 Shear stress (kPa) 600 peak =43.2 o 500 400 2 300 R = 0.99 o residual =36.9 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 167 600 700 800 GHN-KMD-0072 Peak internal friction angle Residual friciton angle 800 700 2 R = 0.99 Shear stress (kPa) 600 peak =42.5 o 500 400 2 R = 1.00 o residual =37.6 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0073 Peak internal friction angle Residual friciton angle 800 700 2 R = 1.00 Shear stress (kPa) 600 peak =43 o 500 400 2 R = 0.98 o residual =39 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 168 600 700 800 GHN-KMD-0074 Peak internal friction angle Residual friciton angle 800 700 2 R = 0.98 Shear stress (kPa) 600 peak =43.6 o 500 400 300 2 R = 0.96 o residual =38.8 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0078 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.99 o peak =46 500 400 2 R = 0.99 o residual =37.9 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 169 600 700 800 GHN-KMD-0079 Peak internal friction angle Residual friciton angle 800 700 2 R = 1.00 Shear stress (kPa) 600 peak =42.7 o 500 400 2 R = 0.99 o residual =37.6 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0079-DUPLICATE Peak internal friction angle Residual friciton angle 800 700 2 R = 1.00 Shear stress (kPa) 600 peak =42.8 o 500 400 2 R = 1.00 o residual =39.8 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 170 600 700 800 GHN-KMD-0081 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 500 2 R = 0.99 400 peak =44.1 o 300 200 2 R = 0.97 100 residual =39.2 o 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-KMD-0081-DUPLICATE Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.99 o peak =41.7 500 400 2 R = 0.99 o residual =37.1 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 171 600 700 800 GHN-KMD-0088 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 500 R = 0.99 peak =42.1 o 400 300 2 200 R = 0.95 residual =38.7 o 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-LFG-0037 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 500 2 R = 0.98 o peak =40.8 400 2 R = 0.99 o residual =37.9 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 172 600 700 800 GHN-LFG-0085 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.99 o peak =42.4 500 400 2 R = 0.99 o residual =39 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-LFG-0088 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 500 R = 0.99 o peak =42.1 400 300 2 200 R = 0.95 residual =38.7 o 100 0 0 100 200 300 400 500 Normal stress (kPa) 173 600 700 800 GHN-LFG-0090 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.98 peak = 45.7 500 o 400 300 200 2 R = 1.00 100 residual =37 o 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-VTM-0450 Peak internal friction angle Residual friciton angle 800 700 2 R = 1.00 peak = 44 Shear stress (kPa) 600 o 500 400 2 R = 0.99 o residual =40.6 300 200 100 0 0 100 200 300 400 500 Normal stress (kPa) 174 600 700 800 GHN-VTM-0453 Peak internal friction angle Residual friciton angle 800 700 2 R = 1.00 peak =44.1 Shear stress (kPa) 600 o 500 400 2 R = 1.00 o residual =38.3 300 200 100 0 0 100 200 300 400 500 600 700 800 Normal stress (kPa) GHN-VTM-0454 Peak internal friction angle Residual friciton angle 800 700 Shear stress (kPa) 600 2 R = 0.99 500 peak = 43 o 400 300 200 2 R = 0.99 100 residual =35.2 o 0 0 100 200 300 400 500 Normal stress (kPa) 175 600 700 800 APPENDIX E – DESCRIPTION OF GEOLOGIC UNITS, SUMMARY OF GEOLOGICAL AND GEOTECHNICAL DATA USED FOR CORRELATIONS 176 Descriptions of geologic units at GHN. No relative age relationships can be determined between surface units A-H. (McLemore et al. 2005) Geologic Unit in this report A Description Structure Lithology Light brown unit with approximately 60% covered by cobbles or larger sized rocks with vegetation growing upon the surface. Massive, light brown to gray to yellow brown unit containing crusts of soluble acid salts. Approximately 65% is covered by cobbles or larger sized rocks. Consists of clayey sand with gravel and cobbles and is locally cohesive. Grayish brown to yellowish gray unit consisting of fine-grained materials (sand with cobbles and gravel) and approximately 15% boulders. Locally is cohesive and well cemented by clays and soluble minerals. Yellow-brown gravely sand unit that differs from Unit C by a marked increase in cobbles and boulders (approximately 30-40%). Orange brown unit with patches of gray sandy clay with approximately 15% cobbles and boulders. Layered in some of the rills near the base. mixed rocks volcanic Southern-most surface unit of the stable part Shallow rills (0.2-1 m deep) of finer grained material are cut into the surface. quartz-sericitepyrite (QSP) altered Amalia Tuff (70%) and andesite (30%). Surface unit of stable portion of the GHN rock pile Massive alternating zones, up to 10 ft thick. Amalia Tuff (70%) and andesite (30%) Surface unit of stable portion of the GHN rock pile Massive Amalia Tuff (80%) and andesite (20%). Surface unit of unstable portion of the GHN rock pile Massive Surface unit of unstable portion of the GHN rock pile F Similar to Unit A, consists of dark brown, silty sand with some gravel. Massive 70 % moderate to strong QSP altered Amalia Tuff and 30% weakly altered Amalia Tuff andesite G Orange brown to yellow brown sandy gravel with some cobbles, includes colluvium material. Dark gray to red-brown V-shaped unit with oxidized orange zones and consists of poorly sorted, well graded, weakly cemented, gravel sand with some fine sand to fine sand with clay, approximately 80% cobbles or boulders. Light-gray, poorly sorted, well graded clayey to sandy gravel, medium hard with weak cementation, and no plasticity. The matrix is locally sandy clay with medium to high plasticity. The unit is less cemented and finer grained than the overlying unit C. Massive andesite Massive andesite Overlain by Unit C, up to 10 ft thick Andesite Amalia Tuff B C D E H I 177 Location and Surface unit of unstable portion of the GHN rock pile Surface unit of unstable portion of the GHN rock pile Surface unit at the top of stable portion of the GHN rock pile Subsurface oxidized unit of stable portion of the GHN rock pile Geologic Unit in this report J Description Structure Lithology Location Dark orange-brown, poorly sorted, well graded, coarse gravel with clay matrix and weak cementation. The top of the unit locally is a bright orange oxidized layer, 2-4 inches thick. Overlain by unit I, 3-12 ft thick Primarily andesite Subsurface oxidized unit of stable portion of the GHN rock pile N Light to dark brown moderately sorted, uniformly graded, moderately hard sandy clay with cobbles, with moderate to high plasticity and well cemented by clay, zones of bright orange to punky yellow oxidized sandy clay. Distinctive purplish-brown gravelly sand with cobbles and is weakly cemented and very coarse, almost no clay. Cobble layer is locally overlain and underlain by finer gravelly sand layers and contacts are gradational. Brown gray, poorly sorted, well graded gravelly sand with cobbles. Heterogeneous with numerous coarse and fine layers, 5-10 ft thick andesite and Amalia Tuff Subsurface intermediate unit of stable portion of the GHN rock pile grades into Unit O, 0-4 ft thick Primarily andesite Subsurface unoxidized unit of stable portion of the GHN rock pile Grades into Unit O andesite Brown, poorly sorted, sandy gravel matrix in coarse gravel and cobbles. Numerous coarse and fine layers at varying dips and thicknesses appear in the mass of the unit. The unit has cobbles and clay layers. Heterogeneous, deformed layer with numerous S-shaped clay lenses and coarse layers. Orange brown to brown, poorly sorted, well graded sandy gravel with boulders (up to 1 m diameter). Sandy gravel forms a matrix between boulders and cobbles. The fines are generally gritty. dark brown, poorly sorted, well graded, sandy gravel with medium hardness and no to weak cementation Variable dip of individual beds Primarily andesite Subsurface unoxidized unit stable portion of GHN rock pile Subsurface unoxidized unit stable portion of GHN rock pile Unit locally flattens with 20 degree dip andesite and Amalia Tuff Subsurface unoxidized unit of stable portion of the GHN rock pile Pinches out, 0-3 ft thick andesite Dark brown, poorly sorted, well graded, sandy gravel with cobbles with medium hardness and no to low cementation. Orange gray, poorly sorted, well graded sandy gravel to gravel with cobbles with medium to weak cementation by clay. Steeply dipping andesite Subsurface unoxidized unit stable portion of GHN rock pile Subsurface unoxidized unit stable portion of GHN rock pile Subsurface unoxidized unit stable portion of GHN rock pile K L O M P Q R Pinches out, 0-3 ft thick 178 Primarily andesite of the of the of the of the of the Geologic Unit in this report S Description Structure Lithology Location Dark gray, poorly sorted, well graded sandy silt with no cementation or plasticity. Pinches out, 0-4 ft thick Primarily andesite Subsurface unoxidized unit of stable portion of the GHN rock pile T Dark gray, poorly sorted, well graded sandy gravel. andesite Subsurface unoxidized unit stable portion of GHN rock pile Subsurface unoxidized unit stable portion of GHN rock pile Subsurface unoxidized unit stable portion of GHN rock pile Subsurface unoxidized unit stable portion of GHN rock pile U V W Brown, poorly sorted well graded, sandy gravel with cobbles. Pinches out, 0-2 ft thick andesite Gray to brown gray poorly sorted, sandy gravel. Pinches out, 010 ft thick andesite Olive gray clay zone, similar and possibly correlated to Unit S. andesite 179 of the of the of the of the Sample GHN-KMD-0013 GHN-KMD-0014 GHN-KMD-0015 GHN-KMD-0016 GHN-KMD-0017 GHN-KMD-0018 GHN-KMD-0019 GHN-KMD-0026 GHN-KMD-0027 GHN-KMD-0051 GHN-KMD-0052 GHN-KMD-0053 GHN-KMD-0055 GHN-KMD-0056 GHN-KMD-0057 GHN-KMD-0062 GHN-KMD-0063 GHN-KMD-0065 GHN-KMD-0071 GHN-KMD-0072 GHN-KMD-0073 GHN-KMD-0074 GHN-KMD-0078 GHN-KMD-0079 GHN-KMD-0081 GHN-KMD-0082 GHN-KMD-0088 GHN-KMD-0092 GHN-LFG-0085 GHN-LFG-0088 GHN-LFG-0090 GHN-VTM-0450 GHN-VTM-0453 GHN-VTM-0454 Units O K R S I J O M N O K contact between Unit I V O N J V Unit U, V contact coarse zone in Unit O O (coarse sand) U U U R O O O1 K O P O (coarse layer) O (clay rich) O FrictAngle ResidFrictAngle 43 38 47 39 45 40 45 39 42 38 44 39 45 39 44 41 44 37 43 38 43 37 43 38 43 38 47 40 43 40 44 39 45 39 44 39 43 37 43 38 43 39 44 39 46 38 43 38 43 39 44 37 45 38 44 39 42 39 42 39 46 37 44 41 44 38 43 35 n.d. = not determined, LL= Liquid limit, PI= Plastic index 180 LL 37.81 26.51 n.d 28.11 35.28 28.73 29.55 30.03 33.88 31.67 n.d 35.2 29.95 29.54 32.75 35.58 38.44 35.34 34.52 32.99 n.d n.d n.d 32.71 35.51 n.d n.d n.d 34.68 36.06 n.d n.d 31.63 n.d PI 14.31 8.47 n.d 7.17 17.91 9.26 6.69 11.01 14.29 14.29 n.d 17.24 5.28 3.9 14.69 15.14 16.36 16.98 8.07 16.44 n.d n.d n.d 14.38 18.76 n.d n.d n.d 15.13 17.82 n.d n.d 9.15 n.d NAGpH pastepH 6.06 2.49 8.55 3.19 6.78 4.92 8.36 5.74 2.43 2.19 3.88 3.5 n.d 5.84 n.d 3.8 n.d 2.49 8.51 7.19 n.d 5.08 6.26 4.32 n.d 4.27 7.05 4.85 n.d 7.96 n.d 4.43 n.d 3.95 n.d 5.77 2.53 4.35 n.d 7.15 8.62 6.55 6.59 3.36 n.d 3.26 6.4 3.07 3.15 3.29 n.d 3.3 n.d 2.63 n.d 3.72 4.2 2.98 8.99 5.43 8.43 6.71 7.18 6.7 8.49 4.55 3.33 3.56 Sample GHN-KMD-0013 GHN-KMD-0014 GHN-KMD-0015 GHN-KMD-0016 GHN-KMD-0017 GHN-KMD-0018 GHN-KMD-0019 GHN-KMD-0026 GHN-KMD-0027 GHN-KMD-0051 GHN-KMD-0052 GHN-KMD-0053 GHN-KMD-0055 GHN-KMD-0056 GHN-KMD-0057 GHN-KMD-0062 GHN-KMD-0063 GHN-KMD-0065 GHN-KMD-0071 GHN-KMD-0072 GHN-KMD-0073 GHN-KMD-0074 GHN-KMD-0078 GHN-KMD-0079 GHN-KMD-0081 GHN-KMD-0082 GHN-KMD-0088 GHN-KMD-0092 GHN-LFG-0085 GHN-LFG-0088 GHN-LFG-0090 GHN-VTM-0450 GHN-VTM-0453 GHN-VTM-0454 WPI 4.18 12.01 6.65 9.34 1.37 4.13 9.2 4.82 3.53 8.36 6.47 4.31 0.65 6.93 n.d n.d n.d 6.45 6.36 7.82 8.95 7.33 n.d 6.4 6.29 7.98 4.56 n.d 6.11 6.83 7.89 7.97 6.34 4.81 MI 0.39 0.7 0.49 0.58 0.31 0.37 0.54 0.41 0.37 0.55 0.46 0.39 0.26 0.48 n.d n.d n.d 0.5 0.43 0.52 0.57 0.52 n.d 0.46 0.44 0.51 0.37 n.d 0.45 0.45 0.53 0.55 0.46 0.37 SWI 3 2 2 2 4 3 2 2 3 2 2 3 4 2 2 3 3 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 181 GravMoist Amalia 13.67 25 8.34 10 9.91 0 9.18 0 14.97 80 7.27 35 10.05 0 12.7 60 17.25 50 7.86 60 9.81 n.d. 9.35 50 10.72 n.d. 8.59 70 7.89 n.d. 13.54 n.d. 10.3 n.d. 9.49 60 9.6 40 7.35 n.d. 11.39 10 20 n.d. 20 50 11.05 95 11.76 n.d. 9.75 n.d. 90 0 0 10 0 35 Andesite 75 90 100 100 20 65 100 40 50 40 n.d. 50 n.d. 30 n.d. n.d. n.d. 40 30 n.d. 90 80 n.d. 80 50 5 n.d. n.d. 10 100 100 80 75 60 Intrusive 0 0 0 0 0 0 0 0 0 0 n.d. 0 n.d. 0 n.d. n.d. n.d. 0 30 n.d. 0 0 n.d. 0 0 0 n.d. n.d. 0 0 0 10 25 5 Sample_id Sphericity Roundness GHNKMD0013 GHNKMD0014 GHNKMD0015 GHNKMD0016 GHNKMD0017 GHNKMD0018 GHNKMD0019 GHNKMD0026 GHNKMD0027 GHNKMD0051 GHNKMD0053 GHNKMD0056 GHNKMD0071 GHNKMD0073 GHNKMD0074 GHNKMD0079 GHNKMD0081 GHNVTM0450 GHNVTM0453 subprismoidal subprismoidal subdiscoidal subprismoidal spherical spherical subprismoidal spherical subdiscoidal subprismoidal subdiscoidal spherical spherical subdiscoidal subdiscoidal subdiscoidal subdiscoidal subprismoidal subprismoidal subangular very angular angular subangular subangular subangular subangular angular subangular subrounded angular subangular angular subangular subangular subrounded subangular subangular subangular Field_id Specific_Gravity (g/cm3) GHNKMD0014 2.68 GHNKMD0015 2.66 GHNKMD0017 2.65 GHNKMD0018 2.65 GHNKMD0019 2.75 GHNKMD0026 2.67 GHNKMD0027 2.66 GHNKMD0071 2.62 182 Percent of Hydrothermal Alteration. QSP = quartz-sericite-pyrite Sample GHN-KMD-0017 GHN-KMD-0013 GHN-KMD-0014 GHN-KMD-0015 GHN-KMD-0016 GHN-KMD-0018 GHN-KMD-0019 GHN-KMD-0026 GHN-KMD-0027 GHN-KMD-0051 GHN-KMD-0052 GHN-KMD-0053 GHN-KMD-0055 GHN-KMD-0056 GHN-KMD-0057 GHN-KMD-0062 GHN-KMD-0063 GHN-KMD-0065 GHN-KMD-0071 GHN-KMD-0072 GHN-KMD-0073 GHN-KMD-0074 GHN-KMD-0078 GHN-KMD-0079 GHN-KMD-0081 GHN-KMD-0082 GHN-KMD-0088 GHN-KMD-0092 GHN-LFG-0085 GHN-LFG-0088 GHN-LFG-0090 GHN-VTM-0450 GHN-VTM-0453 GHN-VTM-0454 QSP Propylitic 50 30 25 25 25 20 10 40 30 25 n.d 30 n.d 30 n.d n.d n.d 20 25 n.d 25 35 n.d 50 55 30 n.d n.d 25 25 25 15 55 40 2 5 20 12 20 8 25 1 7 15 n.d 5 n.d 7 n.d n.d n.d 5 10 n.d 12 10 n.d 7 10 15 n.d n.d 2 12 8 8 15 6 183 Argilic 20 3 0 3 0 0 0 0 0 3 n.d 0 n.d 2 n.d n.d n.d 0 0 n.d 2 0 n.d 3 3 0 n.d n.d 4 3 3 5 4 3 184 Sample GHN-KMD-0013 GHN-KMD-0014 GHN-KMD-0015 GHN-KMD-0016 GHN-KMD-0017 GHN-KMD-0018 GHN-KMD-0019 GHN-KMD-0026 GHN-KMD-0027 GHN-KMD-0051 GHN-KMD-0052 GHN-KMD-0053 GHN-KMD-0055 GHN-KMD-0056 GHN-KMD-0057 GHN-KMD-0062 GHN-KMD-0063 GHN-KMD-0065 GHN-KMD-0071 GHN-KMD-0072 GHN-KMD-0073 GHN-KMD-0074 GHN-KMD-0078 GHN-KMD-0079 GHN-KMD-0081 GHN-KMD-0082 GHN-KMD-0088 GHN-KMD-0092 GHN-LFG-0085 GHN-LFG-0088 GHN-LFG-0090 GHN-VTM-0450 GHN-VTM-0453 GHN-VTM-0454 SiO2 TiO2 63.68 0.6 61.05 0.82 63.83 0.7 61.88 0.79 61.34 0.61 70.45 0.36 61.78 0.81 69.83 0.32 68.03 0.43 67.83 0.59 61.82 0.6 70.62 0.33 71.86 0.27 68.34 0.59 n.d n.d n.d n.d n.d n.d 66.82 0.66 67.81 0.49 63.63 0.65 62.63 0.72 65.16 0.71 n.d n.d 67.58 0.55 66.8 0.43 60.3 0.74 64.35 0.49 n.d n.d 62.66 0.69 61.25 0.77 60.36 0.77 63.45 0.77 59.8 0.71 64.87 0.48 Al2O3 Fe2O3T FeOT FeO Fe2O3 MnO MgO CaO Na2O K2O P2O5 S 14.59 6.23 n.d 3.48 2.4 0.07 1.46 1.17 2.42 3.68 0.23 0.24 14.79 5.1 n.d 2.72 2.11 0.22 2.74 3.12 3.31 4.65 0.29 0.08 14.36 5.72 n.d 3.15 2.25 0.37 2.05 1.38 2.49 4.07 0.25 0.18 14.44 5.51 n.d 3 2.21 0.31 2.83 2.97 3.36 3.12 0.29 0.13 14.37 6.03 n.d 3.35 2.35 0.08 1.51 1.15 2.5 3.49 0.23 3.06 12.95 3.48 n.d 1.73 1.58 0.22 1.23 0.81 1.29 4.81 0.08 0.8 14.94 5.35 n.d 2.88 2.18 0.32 3.14 3.59 3.48 2.92 0.26 0 12.81 3.86 3.52 1.98 1.68 0.15 0.76 0.5 2.59 4.26 0.13 0.17 12.93 4.57 4.15 2.45 1.88 0.21 1.05 0.56 2.03 4.15 0.19 0 14.44 4.32 n.d 2.22 1.88 0.29 1.8 1.94 3.22 3.96 0.16 0 14.16 5.34 4.85 2.9 2.15 0.37 2.23 2.32 2.48 3.44 0.27 0 12.82 3.73 n.d 1.9 1.64 0.3 0.91 0.53 1.78 4.54 0.06 0 12.19 3.49 3.17 1.77 1.54 0.06 0.63 0.76 0.38 3.88 0.1 0 14.53 4.31 n.d 2.2 1.89 0.22 1.64 1.21 3.21 3.8 0.16 0 n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d 14.69 6.12 n.d 3.4 2.38 0.52 2.15 1.29 2.76 3.73 0.2 0.11 14.77 3.85 n.d 1.89 1.77 0.13 1.35 1.28 3.1 3.75 0.13 0.29 14.26 5.25 4.77 2.84 2.13 0.4 2.25 2.1 3.09 3.57 0.29 0 14.38 5.14 n.d 2.76 2.1 0.34 2.65 2.28 3.33 3.37 0.26 0.04 14.68 5.7 n.d 3.12 2.27 0.33 2.26 1.66 2.86 3.53 0.22 0.16 n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d 14.22 4.56 n.d 2.38 1.94 0.23 1.49 1.26 2.8 3.82 0.16 0.12 14.17 3.82 3.47 1.9 1.73 0.13 1.32 1.11 2.79 3.87 0.19 0.13 14.32 5.31 4.83 2.88 2.14 0.64 2.74 2.74 3.46 3.05 0.34 0 14.19 4.19 3.81 2.14 1.84 0.16 1.51 1.13 2.92 3.8 0.21 0 n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d n.d 14.68 6.13 n.d 3.41 2.38 0.28 2.48 2.08 2.62 3.56 0.24 0.37 14.44 5.04 n.d 2.69 2.08 0.3 2.77 2.96 3.31 3.41 0.27 0.14 14.7 6.52 n.d 3.66 2.49 0.46 2.55 2.3 3.32 3.37 0.29 0.55 14.62 6.38 n.d 3.57 2.45 0.36 2.6 1.68 3.27 3.3 0.25 0.19 14.49 6.18 5.47 3.45 2.38 0.46 2.57 2.26 2.61 3.53 0.29 1.46 15.32 4.11 n.d 2.04 1.87 0.19 1.61 1.46 2.68 3.68 0.13 0.96 F CO2 0.0112 0 0.0081 0 0.0138 0 0.0099 0 0.0151 0 0.0122 0 0.0103 0 0.0075 0 0 0 0.0071 0 0 0 0.0096 0 0 0 0.0088 0 n.d n.d n.d n.d n.d n.d 0.0121 0 0.0127 0 0 0 0.0093 0 0.0091 0 n.d n.d 0.0113 0 0.0087 0 0 0 0 0 n.d n.d 0.0109 0 0.0084 0 0.0103 0 0.0091 0 0.0134 0 0.0953 0 LOI 4.81 2.34 3.7 3.42 7.4 4.2 4.3 3.53 4.48 2.72 4.49 3.65 5.04 3.09 n.d n.d n.d 3.59 3.35 3.6 3.17 3.23 n.d 3.21 3.16 4.6 5.14 n.d 4.94 6.03 4.13 3.19 5.13 4.9 185 Sample GHN-KMD-0013 GHN-KMD-0014 GHN-KMD-0015 GHN-KMD-0016 GHN-KMD-0017 GHN-KMD-0018 GHN-KMD-0019 GHN-KMD-0026 GHN-KMD-0027 GHN-KMD-0051 GHN-KMD-0052 GHN-KMD-0053 GHN-KMD-0055 GHN-KMD-0056 GHN-KMD-0057 GHN-KMD-0062 GHN-KMD-0063 GHN-KMD-0065 GHN-KMD-0071 GHN-KMD-0072 GHN-KMD-0073 GHN-KMD-0074 GHN-KMD-0078 GHN-KMD-0079 GHN-KMD-0081 GHN-KMD-0082 GHN-KMD-0088 GHN-KMD-0092 GHN-LFG-0085 GHN-LFG-0088 GHN-LFG-0090 GHN-VTM-0450 GHN-VTM-0453 GHN-VTM-0454 18 17 16 34 15 14 13 14 13 6 18 14 13 20 16 15 12 13 8 13 41 47 43 40 26 39 37 33 45 43 33 36 34 49 50 35 32 33 47 40 11 6 10 11 13 11 11 0 12 0 11 0 11 10 5 14 12 11 13 10 12 11 13 11 8 8 2 9 14 1 12 11 6 10 9 10 12 4 16 9 5 5 7 0 0 0 1 1 1 0.001 0 3 1 4 2 2 0 0 2 2 0.001 1 0 0.65 0.001 0 0 0.001 0.91 0.001 0.95 0.001 0.001 2 0 0.001 0 0.67 0 0 0 0 0.25 6 3 5 2 6 4 2 3 4 3 1 5 3 7 8 3 5 3 4 4 0.16 0 0 0.04 0 0 0 0 0 0 0 0.17 0.12 0.06 0 0 0.35 0 0.75 0 0 0 0 0 0.3 0.08 8 5 8 0 6 10 2 6 8 3 8 5 8 8 4 12 6 2 3 3 0.9 3.78 2 2 1.95 1 1 2 1.95 3 1 0.2 2.04 1.29 2 2 0.001 0.9 1 1 2.1 2.22 2 2 1.05 1 1 2 1.05 1 1 0.8 0.96 1.71 3 1 3 2.1 1 1 14 18 11 14 13 6 14 14 15 19 12 13 11 13 11 13 Quartz k-feldspar Plagioclase epidote calcite pyrite FeMnOxide goethite hematite chlorite AuthGyp DetritGypTotalClay 46 7 40 0 0 2.87 0 0.01 0.04 0 0.001 8 32 0 APPENDIX F – STANDARD OPERATING PROCEDURES FOR PETROGRAPHIC ANALYSES 186 STANDARD OPERATING PROCEDURE NO. 24 PETROGRAPHIC ANALYSES REVISION LOG 1.0 Revision Number Description Date 24.0 Original SOP 24.1 Revisions by PJP 1/14/04 24.2 Revisions by PJP 5/19/2004 PURPOSE AND SCOPE This Standard Operating Procedure describes the method for petrographic analyses involving optical examinations and mineral identification, which are the basis for all geologic models and characterization, specifically in differentiating various rock units, determining rank and intensity of alteration, determining chemistry of alternating fluids, describing cementation, and determination of paragenesis of mineralization, alteration, and cementation. Mineralogical data is required in selecting samples for weathering cells (Lapakko), and for developing geotechnical models (Wilson), weathering models (Trujillo), and geologic (mineralogy, stratigraphy, internal structure) models of the rock piles. Alteration rank is based upon the mineral assemblages, which infers temperature, pressure, and permeability conditions at the time of formation. Forms are in Appendix 1. Digital photographs will be taken (SOP 4). 2.0 RESPONSIBILITIES AND QUALIFICATIONS The Team Leader and Characterization Team will have the overall responsibility for implementing this SOP. They will be responsible for assigning appropriate staff to implement this SOP and for ensuring that the procedures are followed. All personnel performing these procedures are required to have the appropriate health and safety training. In addition, all personnel are required to have a complete understanding 187 of the procedures described within this SOP, and receive specific training regarding these procedures, if necessary. All environmental staff and assay laboratory staff are responsible for reporting deviations from this SOP to the Team Leader. 3.0 DATA QUALITY OBJECTIVES This SOP address objectives 2-7 and 9 in the data quality objectives outline by Virginia McLemore for the "Geological and Hydrological Characterization at the Molycorp Questa Mine, Taos County, New Mexico”. Determine how mineralogy, stratigraphy, and internal structure of the rock piles contribute to weathering and stability. Determine if the sequence of host rock hypogene and supergene alteration and weathering provides a basis to predict the effects weathering can have on mine rock material. Determine how weathering of the rock pile affects the geotechnical properties of the rock pile material. Determine if cementation forms in the rock piles and the effect of such cementation on the stability of the rock piles. Determine the concentrations of pyrite and carbonate minerals so that a representative sample goes into the weathering cells. Determine how the concentration and location of pyrite and its weathering products in the waste rock piles affect the weathering process. Determine if the geotechnical and geochemical characteristics of the bedrock (foundation) underlying the rock piles influences the rock pile stability. 4.0 RELATED STANDARD OPERATING PROCEDURES The procedures set forth in this SOP are intended for use with the following SOPs: SOP 1 Data management (including verification and validation) SOP 2 Sample management (chain of custody) SOP 4 Taking photographs SOP 5 Sampling outcrops, rock piles, and drill core (solid) SOP 6 Drilling, logging, and sampling of subsurface materials (solid) SOP 8 Sample preparation (solids) SOP 9 Test pit excavation, logging, and sampling (solid) 5.0 EQUIPMENT LIST The following materials are required for petrographic analyses: Petrographic microscope Camera Forms 188 6.0 PROCEDURES Petrography will be performed using standard petrographic and reflected ore microscopy techniques. Mineral concentrations will be estimated using standard charts and data are summarized. Estimates of both primary and alteration minerals will be determined, cementation described, diagenesis described, porosity estimated, and the alteration intensity will be determined from the concentration of alteration minerals. Any special features will be noted on the forms (Appendix 1). Photographs will be taken and the thin section photograph subform will be filled out. Description of alteration Alteration is a general term describing the mineralogic, textural, and chemical changes of a rock as a result of a change in the physical, thermal, and chemical environment in the presence of water, steam, or gas (Bates and Jackson, 1980; Henley and Ellis, 1983). The nature of the alteration depends upon (a) temperature and pressure at the alteration site, (b) composition of the parent rock, (c) composition of the alteration (invading) fluids, (d) permeability of the parent rock, and (e) duration of the alteration process. Recognition and genesis of alteration are important in mineral exploration and understanding the formation of ore deposits, because specific alteration types are associated with specific ore deposits. Furthermore, alteration halos surrounding ore deposits are typically more widespread and easier to recognize than some of the orebodies themselves (Guilbert and Park, 1986). Intensity of alteration is a measure of how much alteration has occurred and can be estimated by determining the percentage of newly formed secondary minerals by visual estimation (P. R. L. Browne, unpubl. report, Spring 1992). For example, a parent rock that has not been affected by any alteration would have zero intensity of alteration, whereas a parent rock in which all primary minerals have been replaced by secondary minerals would have an alteration intensity of 100%. Alteration rank is based upon the identification of new secondary minerals and their significance in terms of alteration conditions such as temperature, pressure, and permeability. The intensity of alteration is independent of rank of alteration (Browne, 1978; Simmons et al., 1992). It is possible to have rocks with a high rank but low intensity (hot, impermeable zones) or other rocks of low rank, but high intensity (cooler, permeable zones; P. R. L. Browne, unpubl. report, Spring 1992). Alteration of parent rock occurs by several processes: (1) direct deposition, (2) replacement, (3) leaching, and (4) ejecta (Browne, 1978). All four processes are found in the Questa district. Direct deposition occurs by precipitation of new minerals in open spaces, such as vugs or fractures. Replacement occurs when one mineral is converted to a new mineral by fluids entering the rock. These two processes are common and depend upon permeability and duration of the process. Complete fluid/mineral equilibrium is rarely achieved because of these factors. Leaching and supergene enrichment occurs locally where steam condensate reacts to form acidic solutions by the oxidation of H2S or CO2 which then attacks the parent rock and dissolves primary or secondary minerals. 189 Silica residue is a common result of leaching and is a spongy or vuggy altered rock consisting of predominantly quartz, iron and titanium oxides. Direct deposition or replacement may occur after leaching, thereby producing overlapping alteration types. Ejecta, hydrothermal brecciation, and hydrofracturing are another form of alteration, where hot water and/or steam physically breaks the parent or even altered rock apart. If this forceful ejection of fluids occurs at or near the surface, hydrothermal eruptions of water, steam, and rock can occur. Silicification following the brecciation is common. The term mineral assemblage implies mutual equilibrium growth of mineral phases, whereas mineral association implies that the mineral phases are only in physical contact. A number of terms are applied to various alteration assemblages. Deuteric alteration refers to the interaction between volcanic or magmatic rocks and magmatichydrothermal fluids during the cooling of the igneous rocks. A variety of alteration minerals may be produced. Propylitic alteration is the mineral assemblage consisting of epidote, chlorite, pyrite, quartz and carbonate minerals. Sericitic alteration is defined by the dominance of illite, sericite, and/or muscovite. The major difference between these three K-micas is size: illite is a clay-size K-mica, whereas muscovite is larger. Sericite is of intermediate size. Some minor compositional differences also occur between the three minerals. Argillic alteration consists of kaolinite, smectite (montmorillonite clays), chlorite, and sericite. Advanced argillic alteration consists of kaolinite, quartz, alunite, pyrophyllite, and other aluminosilicate minerals. Silicic alteration is produced by the addition of silica, predominantly as quartz. Then the rock and minerals are subjected to supergene alteration and finally weathering, which continues today. It may be difficult to distinguish between supergene alteration and modern weathering. Description of pyrite and carbonate minerals Pyrite and carbonate minerals are described in detail because of their importance in generating or preventing acid drainage. The abundance, texture, grain size, contact relationships, shape, integrity, paragenesis, composition, surface area, and occurrence or association are described in detail in the petrographic form. Specific carbonate minerals are identified. 7.0 COLLECTION OF SAMPLES Samples are collected according to the sample plan and SOP 5, 6, and 9 and prepared according to SOP 8. Thin sections are preferred, but grain mounts can be used for unconsolidated material. 8.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES AND SAMPLES 9.0 SAMPLE HANDLING Thin sections, grain mounts and other samples are archived after petrographic description. 190 APPENDIX F – TERMINOLOGY 191 Terminology Liquid Limit Definition The liquid limit is the dividing line between the liquid and plastic states. The liquid limit is reported in terms of the water content at which a soil changes from the liquid to the plastic state (Liu and Evett, 2003). NAG pH(Net Acid Generation) The NAG pH measures the net acid remaining, if any, after complete oxidation of the material with hydrogen peroxide and allowing complete reaction of the acid formed with the neutralizing components of the materials (Lewis et al., 1997). After neutralization is complete, the remaining H2SO4, if any, is titrated with NaOH. The amount of NaOH needed is expressed as kg of CaCO3 equivalents per ton of material and is equal to the NAG of the material. Paste pH Paste pH is the pH measured on a mixture of soil and deionized water which forms a slurry or paste. Plasticity Index The plasticity index is the difference between the liquid and the plastic limits (Liu and Evett, 2003). Plastic Limit Plastic limit is the dividing line between the plastic and semisolid states. It is quantified for a given soil as a water content at which the will begin to crumble when rolled into small threads (Liu and Evett, 2003). Specific gravity The term specific gravity is defined as the ratio of the mass of a given volume of material to the mass of an equal volume of water. Equation: Gs = (Ms/Vs)/w, where Ms is the mass of solids, Vs is the volume of solids, and w is the density of water (Liu and Evett, 2003). 1 2