1
Known Examples of Interpenetration
Current To 31/10/05
Dr. Stuart Batten, School of Chemistry,
Monash University 3800
Australia
Ph: +61 3 9905 4606
Fax: +61 3 9905 4597
E-mail: stuart.batten@sci.monash.edu.au
• In Review: "Interpenetrating Nets: Ordered, Periodic Entanglement", Stuart R. Batten and Richard Robson, Angew. Chem. Int. Ed., 1998, 37, 1460-1494;
Angew. Chem., 1998, 110, 1558-1595. (Or "Catenane and Rotaxane Motifs in Interpenetrating and Self-Penetrating Coordination Polymers", Stuart R. Batten
and Richard Robson, in Molecular Catenanes, Rotaxanes and Knots, A Journey Through the World of Molecular Topology, eds. J.-P. Sauvage and C.
Dietrich-Buchecker, Wiley-VCH, Weinheim, 1999, 77-105.)
If you find this table useful, please cite "Topology of Interpenetration", CrystEngComm, 2001, 3, 67-73. http://xlink.rsc.org/?DOI=10.1039/B102400k
** A number of entries have been added or corrected thanks to the extensive CSD and ICSD database searches contained in the following papers: V.A.
Blatov, L. Carlucci and D.M. Proserpio, CrystEngComm, 2004, 6, 377-395; I.A. Baburin, V.A. Blatov, L. Carlucci, G. Ciani and D.M. Proserpio, J. Solid
State Chem., 2005, 178, 2471-2493.
*** Every effort has been made to ensure this table is both comprehensive and correct, but if you know of any possible omissions or errors (and it is highly
likely there will be examples of each), I would greatly appreciate the feedback. Compliments are also accepted! ***
Compound
Notes
# Reference
1D!1D parallel
(C5Me5)Rh(NC5H4CONH2)3(OTf)2
1D chains of alternating rings and 2
rods, held together by H-bonding.
Chains entangle in pairs. Further
H-bonding may connect all
together - each chain further
connected to four adjacent
strands in this way.
C.J. Kuehl, F.M. Tabellion, A.M. Arif and P.J. Stang, Organomet.,
2001, 20, 1956-1959.
2
{(HO2CC6H4CH2)(Bu2bipy)Me2Pt}3
{tpt}(PF 6)3, tpt = tripyridyltriazine
1D chains of alternating rings and
rods, held together by H-bonding.
Chains entangle in pairs.
[AdeH](I3)(I2)5/2(H2O), Ade = adenine Iodine chains with alternating
rings and rods.
[Zn2(bib)2(OAc)4].2H2O, bib = 1Chains of alternating rings and
rods, the later defined by Br...Br
bromo-3,5-bis(imidazol-1contacts.
ylmethyl)benzene
(NH4)1.5 [1,3,5H-bonded nets. 2 ladders
interpenetrating with inclined
C6H3(CH2COOH)1.5 (CH2COO)1.5 ]
mean planes but a coincident
direction of propagation; NH4+
counterions may bridge ladders.
4,4'-sulfonyldiphenol / 4,4'H-bonded nets.
trimethylenedipyridine (1/1)
1,7-phenanthroline
1D chains of alternating loops
and rods, defined by C-H...N
interactions.
2
C.S.A. Fraser, M.C. Jennings and R.J. Puddephatt, Chem. Commun.,
2001, 1310-1.
2
Z. Wang, Y. Cheng, C. Liao and C. Yan, CrystEngComm, 2001, 50,
1-6.
J. Fan, W.-Y. Sun, T. Okamura, Y.-Q. Zheng, B. Sui, W.-X. Tang
and N. Ueyama, Cryst. Growth Des., 2004, 4, 579-584.
2
2
H.-F. Zhu, J. Fan, T. Okamura, W.-Y. Sun and N. Ueyama, Chem.
Lett., 2002, 898-899.
2
G. Ferguson, C. Glidewell, R.M. Gregson and E.S. Lavender, Acta
Crystallogr., Sect. B, 1999, 55, 573-590.
K.K. Arora and V.R. Pedireddi, Cryst. Growth Des., 2005, 5, 13091312.
2
1D!2D parallel
[Cu2(MeCN)2L3](X)2.solv, L = 1,4bis(4-pyridyl)butadiyne, X = PF6, BF4
4,4'-sulfonyldiphenol / pyrazine (2/1)
Undulating 1D ladders which lie 5
parallel; each ladder is penetrated
by four others. 2D sheets formed.
Ladders held together by O3
...
...
H O=S and O-H N H-bonding.
Each ladder is penetrated by two
others (parallel), giving an
overall 2D sheet. Linked by CH...O H-bonds into 3D net.
Zn2(bix)3(SO4)2, bix = 1,41D nets contains alternating rings 2
and rods. Each chain entangles
bis(imidazol-1-ylmethyl)benzene
with two others (one either side),
with each ring containing one rod
from another net. Only rotaxanelike interactions.
Ni2(oba)2(bpy)2(H2O)2.bpy, oba = 4,4'- 1D tubular nets, each
3
oxybis(benzoate), bpy = 4,4'-bipyridine interpenetrating with 2
neighbours.
A.J. Blake, N.R. Champness, A. Khlobystov, D.A. Lemenovskii, W.S. Li and M. Schroder, Chem. Commun., 1997, 2027-2028; M.
Maekawa, H. Konaka, Y. Suenaga, T. Kuroda-Sowa and M.
Munakata, J. Chem. Soc., Dalton Trans., 2000, 4160-4166.
G. Ferguson, C. Glidewell, R.M. Gregson and E.S. Lavender, Acta
Crystallogr., Sect. B, 1999, 55, 573-590.
L. Carlucci, G. Ciani and D.M. Proserpio, Cryst. Growth Des., 2005,
5, 37-39.
X.-L. Wang, C. Qin, E.-B. Wang, Y.-G. Li, Z.-M. Su, L. Xu and L.
Carlucci, Angew. Chem. Int. Ed., 2005, 44, 5824-5827.
3
1D!2D inclined
Ag2(bix)3(NO3)2, bix = 1,4bis(imidazol-1-ylmethyl)benzene
1D chains interpenetrating to
give a 2D square sheet. Only
rotaxane-like interactions formed,
with each ring of each net
containing a rod of another net.
Similar to Ag2(bix)3(NO3)2
structure, except nets crosslinked
by SO4 bridges to give a single,
self-penetrating net.
1D chains interpenetrating to
give 2D layers. Only rotaxanelike interactions formed, with
each ring of each net containing a
nodes of another net.
Catenane interactions formed.
2?• B.F. Hoskins, R. Robson and D.A. Slizys, J. Am. Chem. Soc., 1997,
119, 2952-3.
[Cd(L)1.5 ](NO3)2, L = NC5H4-CH2C6H4-CH2-C5H4N
M2(bpethy)3(NO3)4, M = Zn or Co,
bpethy = 1,2-bis(4-pyridyl)ethyne (and
Co2(bpethe)3(NO3)4, bpethe = 1,2-(4pyridyl)ethene)
Cd2(bix)3(SO4)2, bix = 1,4bis(imidazol-1-ylmethyl)benzene
Ca{5,10,15,20-tetra-(4carboxylate)phenylporphyrin}
M(IIMB)2(H2O)(SO4).xH2O and
Cu(IIMB)2(SO4).8.5H2O, M = Co, Cd,
Mn, IIMB = 1-(1-imidazolyl)-4(imidazol-1-ylmethyl)benzene
2?
L. Carlucci, G. Ciani and D.M. Proserpio, Cryst. Growth Des., 2005,
5, 37-39.
2
M.E. Kosal, J.H. Chou and K.S. Suslick, J. Porph. Phthal., 2002, 6,
377.
2
H.-F. Zhu, W. Zhao, T. Okamura, J. Fan, W.-Y. Sun and N. Ueyama,
New J. Chem., 2004, 28, 1010-1018; H.F. Zhu, J. Fan, T. Okamura,
W.-Y. Sun and N. Ueyama, Cryst. Growth Des., 2005, 5, 289-294.
Interpenetrating 1D polymers molecular ladders. 3D struct.
5•
Ladders where the
interpenetrating ladders are
inclined, and each square
penetrated by two other ladders.
bpethe structure not fully
reported - poor data.
Ladders - claim are
interpenetrating ladders, but no
diags (or detailed description) of
intptn!!! Cell, however, is
isomorphous with M = Zn, Co
described above.
Ladders.
3
M. Fujita, Y.J. Kwon, O. Sasaki, K. Yamaguchi and K. Ogura, J. Am.
Chem. Soc., 1995, 117, 7287; M. Fujita, O. Sasaki, K.-Y. Watanabe,
K. Ogura, K. Yamaguchi, New J. Chem., 1998, 22, 189-191.
L. Carlucci, G. Ciani and D.M. Proserpio, J. Chem. Soc., Dalton
Trans., 1999, 1799-1804; Y.-B. Dong, R.C. Layland, N.G. Pschirer,
M.D. Smith, U.H.F. Bunz and H.-C. zur Loye, Chem. Mater., 1999,
11, 1413-1415 (M = Co).
3
Y.-B. Dong, R.C. Layland, M.D. Smith, N. G. Pschirer, U.H.F. Bunz
and H.-C. zur Loye, Inorg. Chem., 1999, 38, 3056-3060.
3
J. Tao, X. Yin, R. Huang and L. Zheng, Inorg. Chem. Commun.,
2002, 5, 1000-1002.
1D!3D inclined
[Cd(NO3)2L1.5 ], L = 1,2-bis(4pyridyl)ethyne
Cu2(ip)(bipy).3.5H 2O, ip =
isophthalate, bipy = 4,4'-bipyridine
4
Cd2(nbpy4)3(NO3)4, nbpy4 = N, N'-bis- Ladders.
(4-pyridinylmethylene)-1,5naphthalenediamine
CoL1.5 (NO3)2, L = 1,4-bis[(4Ladders.
pyridyl)ethynyl]benzene
5
C.-Y. Su, A.M. Goforth, M.D. Smith and H.-C. zur Loye, Chem.
Commun., 2004, 2158-2159.
3
M.B. Zaman, K. Udachin, J.A. Ripmeester, M.D. Smith and H.-C. zur
Loye, Inorg. Chem., 2005, 44, 5047-5059.
2•
J. Konnert and D. Britton, Inorg. Chem., 1966, 5, 1193; S.R. Batten,
B.F. Hoskins and R. Robson, New J. Chem., 1998, 22, 173-175; B.F.
Abrahams, S.R. Batten, B.F. Hoskins and R. Robson, Inorg. Chem.,
2003, 42, 2654-2664.
P.I. Coupar, G. Ferguson, C. Glidewell and P.R. Meehan, Acta
Crystallogr., Sect C, 1997, 53, 1978-1980.
2D!2D parallel (6, 3)
Ag(tcm) and Ag(tcm)(MeCN)
(1,1,1-tris(4-hydroxyphenyl)ethane).
(hexamethylenetetramine)
Sr13Mg2Si20
H-bonded; analogous to Agtcm,
except nets are cross-linked
through C-H...O bonds.
Contains interpenetrating Si2030sheets with Agtcm-like
interpenetration.
"-(BEDT-TTF)2Cu2(CN)[N(CN)2]2
2•
2
A. Currao and R. Nesper, Angew. Chem. Int. Ed., 1998, 37, 841-843;
Angew. Chem., 1998, 110, 843-845.
2•
G. Saito, H. Yamochi, T. Nakamura, T. Komatsu, N. Matsukawa, T.
Inoue, H. Ito, T. Ishiguro, M. Kusunoki, K. Sakaguchi and T. Mori,
Synth. Met., 1993, 55-57, 2883; T. Komatsu, H. Sato, N. Matsukawa,
T. Nakamura, H. Yamochi, G. Saito, M. Kusunoki, K. Sakaguchi and
S. Kagoshima, Synth. Met., 1995, 70, 779-80; T. Komatsu, H. Sato, T.
Nakamura, N. Matsukawa, H. Yamochi, G. Saito, M. Kusunoki, K.
Sakaguchi and S. Kagoshima, Bull. Chem. Soc. Jpn., 1995, 68, 2233.
L. Carlucci, G. Ciani, D.M. Proserpio and A. Sironi, Angew. Chem.
Int. Ed. Engl., 1995, 35, 1088.
C.V.K. Sharma and M.J. Zaworotko, Chem. Commun., 1996, 2655.
A. Zafar, J. Yang, S.J. Geib and A.D. Hamilton, Tetrahedron Lett.,
1996, 37, 2327.
M. Fujita, Y.J. Kwon, O. Sasaki, K. Yamaguchi and K. Ogura, J. Am.
Chem. Soc., 1995, 117, 7287.
Y. Aoyama, K. Endo, T. Anzai, Y. Yamaguchi, T. Sawaki, K.
Kobayashi, N. Kanehisa, H. Hashimoto, Y. Kai and H. Masuda, J.
Am. Chem. Soc., 1996, 118, 5562.
D. Venkataraman, S. Lee, J.S. Moore, P. Zhang, K.A. Hirsch, G.B.
Gardner, A.C. Covey and C.L. Prentice, Chem. Mater., 1996, 8,
2030-2040.
B.F. Hoskins, R. Robson, and D.A. Slizys, Angew. Chem., 1997, 109,
2430-2432; Angew. Chem. Int. Ed. Engl., 1997, 36, 2336-2338.
Ag(CH3COCH2C(CN)2C(CN)2)
Very similar to Agtcm.
2•
TMA.3/2bipy, TMA = trimesic acid
C6H4(OC6H3(COOH)2)2
H-bonded.
3•
3•
[Cd(L)1.5 ](NO3)2, L = NC5H4-CH2C6F4-CH2-C5H4N
((HO)2C6H3-C14H8-C6H3(OH)2)
.2(1,4-benzoquinone)
3•
H-bonded net.
3•
Ag(TEB)(CF3SO3), TEB = 1,3,5-tris(4- A polymorph of another
structure.
ethynylbenzonitrile)benzene
6•
Zn(bix)2(NO3)2.4.5H2O, bix =
bis(imidazole)xylene
2•
2D polyrotaxane-like
interpenetration.
5
2,2'-diamino-5,5'-{[4-(tertbutyl)cyclohexylidene]methylene}
dipyrimidine
RPI4, R = i-Pr, Me, Ph
(CuCN)2(butda), butda = 1,4butanediamine
M2(bpethy)3(NO3)4.S, M = Cd (S =
CH2Cl2), Co (S = MeOH),
Cd2(azpy)3(NO3)4, bpethy = 1,2-bis(4pyridyl)ethyne, azpy = trans-4,4'azobis(pyridine)
M2(apy)3(NO3)4.CH2Cl2.xH2O, M =
Co (x=0), Cd (x=2), apy = trans-4,4'azobis(pyridine)
1,1,1-tris(4-hydroxyphenyl)ethane /
1,10-phen / methanol (1/1/1)
Cd2(NO3)4(Py2C5H10)3(H2O),
Py2C5H10 = 1,5-bis(4-pyridyl)pentane
Cd2(azpy)3(NO3)4•2Me2CO, azpy =
4,4'-azopyridine
Cu(1,2-ethanediamine)2(I3)2
Cd4L6(NO3)8, L = 1,3-bis(4pyridyl)propane
(H2bipy)2[Ni(NCS)4(H2O)2](NO3)2
[{(2,2'-bipy)Cu(bpethe)}2Cl]
(BF4)3.2.5H2O.CH2Cl2, bpethe = 1,2bis(4-pyridyl)ethene
H-bonded nets. (6,3) - where one
of in three links is covalent - else
could be (4,4).
Nets held together by I...I
contacts between RPI3+ and Inodes.
Agtcm-like interpenetration.
Short Cu2(CN)2 interactions
between layers.
Tiled-pattern (6,3), with Tshaped nodes.
2
M.J. Krische, J.-M. Lehn, N. Kyritsakas and J. Fischer, Helv. Chim.
Acta, 1998, 81, 1909-1920.
2
W.-W. du Mont, V. Stenzel, J. Jeske, P.G. Jones, A. Sebald, S. Pohl,
W. Saak and M. Batcher, Inorg. Chem., 1994, 33, 1502-1505; W.-W.
du Mont and F. Ruthe, Coord. Chem. Rev., 1999, 189, 101-133.
3
F.B. Stocker, T.P. Staeva, C.M. Rienstra and D. Britton, Inorg.
Chem., 1999, 38, 984-991.
3
L. Carlucci, G. Ciani and D.M. Proserpio, J. Chem. Soc., Dalton
Trans., 1999, 1799-1804; Y.-B. Dong, R.C. Layland, N.G. Pschirer,
M.D. Smith, U.H.F. Bunz and H.-C. zur Loye, Chem. Mater., 1999,
11, 1413-1415 (M = Co).
Herringbone grids.
3
Pendant phen. H-bonded.
2
M.A. Withersby, A.J. Blake, N.R. Champness, P.A. Cooke, P.
Hubberstey and M. Schroder, New J. Chem., 1999, 23, 573-575; M.A.
Withersby, A.J. Blake, N.R. Champness, P.A. Cooke, P. Hubberstey,
A.L. Realf, S.J. Teat and M. Schroder, J. Chem. Soc., Dalton Trans.,
2000, 3261-3268.
G. Ferguson, C. Glidewell and E.S. Lavender Acta Crystallogr., Sect.
B, 1999, 55, 591-600.
M.J. Plater, M.R.St.J. Foreman, T. Gelbrich, S.J. Coles and M.B.
Hursthouse, J. Chem. Soc., Dalton Trans., 2000, 3065-3073.
M. Kondo, M. Shimamura, S. Noro, S. Minakoshi, A. Asami, K. Seki
and S. Kitagawa, Chem. Mater., 2000, 12, 1288-1299.
C. Wieczorrek, Acta Crystallogr., Sect. C, 2000, 56, 1085-1087.
3
3
Nets partially defined by I... I
contacts.
4
H-bonded nets with NO3- nodes.
3
2
C.V.K. Sharma, R.J. Diaz, A.J. Hessheimer and A. Clearfield, Cryst.
Eng., 2000, 3, 201-208.
H-J. Chen, M-L. Tong and X-M. Chen, Inorg. Chem. Commun.,
2001, 4, 76-78.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, Chem.
Commun., 2001, 1198-1199.
6
Cu(tmeda)[Au(CN)2]1.5 (ClO4)0.5
[Ag3L4](NO3)3.H2O, L = bis(4pyridyl)dimethylsilane
TbL(NO3)3, L = 4,4'-bipyridine-N,N'dioxide
Interpenetration of the
3
'Borromean' type (L. Carlucci, G.
Ciani and D.M. Proserpio,
CrystEngComm, 2003, 5, 269;
Coord. Chem. Rev., 2003, 246,
247). Nets crosslinked by
Au...Au interactions.
2- and 3-coordinate Ag.
2
One of the links is defined by
(+ N-O-)(-O-N+ ) electrostatic
interactions.
3
Cu2{(iPr2SiOCH2py)2O}3Br4
2
LnL1.5 (NO3)3.H2O, Ln = Er, Yb, L =
1,2-bis(4-pyridyl)ethane-N,N'-dioxide
CTA.bipy.H2O, CTA = 1,3,5H-bonded nets.
cyclohexanetricarboxylic acid, bipy =
4,4'-bipyridine
[Ni(C10H24N4)]3[C33H15O6]2.6C5H5N. Interpenetration of the
'Borromean' type (L. Carlucci, G.
4H2O
Ciani and D.M. Proserpio,
CrystEngComm, 2003, 5, 269;
Coord. Chem. Rev., 2003, 246,
247).
Cu(en)Cu(CN)2Ag(CN)2, en =
Weak Cu(I)...Ag(I) interactions
crosslink sheets.
ethylenediamine
[K(K.2.2.2)]I(I(CF2)8I)1.5 , K.2.2.2 =
I- nodes; nets defined by I-...I
4,7,13,16,21,24-hexaoxa-1,10interactions. Unusual mode of
diazabicyclo[8,8,8]-hexacosane
interpenetration whereby any two
sheets in a layer are not
interpenetrating, and it is only the
addition of the third which causes
the entanglement of all three.
Interpenetration of the
'Borromean' type (L. Carlucci, G.
Ciani and D.M. Proserpio,
CrystEngComm, 2003, 5, 269;
Coord. Chem. Rev., 2003, 246,
247).
3
3
D.B. Leznoff, B.-Y. Xue, R.J. Batchelor, F.W.B. Einstein and B.O.
Patrick, Inorg. Chem., 2001, 40, 6026-6034.
O.-S. Jung, Y.J. Kim, K.M. Kim and Y.-A Lee, J. Am. Chem. Soc.,
2002, 124, 7906-7.
D.-L. Long, A.J. Blake, N.R. Champness, C. Wilson and M.
Schroder, Chem. Eur. J., 2002, 8, 2026-2033.
D.M.L. Goodgame, P.D. Lickiss, S.J. Rooke, A.J.P. White and D.J.
Williams, Inorg. Chim. Acta, 2001, 324, 218-231.
W.-J. Lu, L.-P. Zhang, H.-B. Song, Q.-M. Wang and T.C.W. Mak,
New J. Chem., 2002, 26, 775-781.
B.R. Bhogala, P. Vishweshwar and A. Nangia, Cryst. Growth Des.,
2002, 2, 325-328.
3
M.P. Suh, H.J. Choi, S.M. So and B.M. Kim, Inorg. Chem., 2003, 42,
676-678.
2
C.J. Shorrock, B.-Y. Xue, P.B. Kim, R.J. Batchelor, B.O. Patrick and
D.B. Leznoff, Inorg. Chem., 2002, 41, 6743-6753.
R. Liantonio, P. Metrangolo, T. Pilati and G. Resnati, Cryst. Growth
Des., 2003, 3, 355-361.
3
7
H3CTA.(bpe-eta)1.5 ,
H-bonded nets.
H3CTA.bipy.0.5bipy-eta. H3CTA.bipyete.0.5bipy-eta, H3CTA = cis, cis-1,3,5cyclohexanetricarboxylic acid, bpe-eta
= 1,2-bis(4-pyridyl)ethane, bpe-ete =
1,2-bis(4-pyridyl)ethane, bipy = 4,4'bipyridine
Ag4(Me4bpz)5(NO3)4.2H2O, Me4bpz = Unusual interpenetration
topology.
3,3',5,5'-tetramethyl-4,4'-bipyrazole
3
B.R. Bhogala and A. Nangia, Cryst. Growth Des., 2003, 3, 547-554;
B.R. Bhogala, S. Basavoju and A. Nangia, Cryst. Growth Des., 2005,
5, 1683-1686.
4
1,4-di[bis(4'hydroxyphenyl)methyl]benzene
.dioxane
Zn2(bdc)2(bipy)(EtOH)(H2O)2.EtOH.0.
5H2O, H2bdc = 1,3benzenedicarboxylic acid, bipy = 4,4'bipyridine
[M2(OH)6(Bpybc)3](OH)4.15H2O, M =
Mn, Ni, Co, H2BpybcCl2 = 1,1'-bis(4carboxybenzyl)-4,4'-bipyridinium
dichloride
Ag2L3(BF4)2, L = 1,4-bis(2methylimidazol-1-ylmethyl)benzene
Cs6[Ag11(CN)16][Ag(CN)2].2MeCN
2
K.V. Domasevitch, I. Boldog, E.B. Rusanov, J. Hunger, S. Blaurock,
M. Schroder and J. Sieler, Z. Anorg. Allg. Chem., 2005, 631, 10951100.
S. Aitipamula and A. Nangia, Supramol. Chem., 2005, 17, 17-25.
H-bonded nets.
2
L. Xu, G.-C. Guo, B. Liu, M.-S. Wang and J.-S. Huang, Inorg. Chem.
Commun., 2004, 7, 1145-1149.
Although paper says they're not
interpenetrating, it's actually
Borromean interpenetration.
3
Y.-Q. Sun, J. Zhang, Z.-F. Ju and G.-Y. Yang, Cryst. Growth Des.,
2005, 5, 1939-1943.
Borromean interpenetration.
3
Layers held together by some of
the Cs ions.
3
L. Dobrzanska, H.G. Raubenheimer and L.J. Barbour, Chem.
Commun., 2005, 5050-5052.
V. Urban, T. Pretsch and H. Hartl, Angew. Chem. Int. Ed., 2005, 44,
2794-2797.
H-bonding between tetrahedral
clusters.
2•
2D!2D parallel (4, 4)
[Re(CO)3(µ3-OH)]4.2bipy.2MeOH
[trans-Cd(4-Mepy)2{Ag(CN)2}2].(4Mepy) (Mepy = 4-picoline)
SO2(4-C6H4OH)2
Cu(tcm)(bipy)
2•
H-bonded.
2•
2•
S.B. Copp, S. Subramanian and M.J. Zaworotko, Angew. Chem. Int.
Ed. Engl., 1993, 32, 706.
T. Soma and T. Iwamoto, Chem. Lett., 1994, 821.
C. Glidewell and G. Ferguson, Acta Crystallogr., Sect. C, 1996, 52,
2528-2530; C. Davies, R.F. Langler, C.V.K. Sharma and M.J.
Zaworotko, Chem. Commun., 1997, 567.
S.R. Batten, B.F. Hoskins and R. Robson, Chem. Eur. J., 2000, 6,
156-161.
8
[Mn(p-XBP4)3](ClO4)2, p-XBP4 =
N,N'-p-phenylenedimethylenebis
(pyridin-4-one)
Ag(3,3'-DCPA)2XF6, X = P, As, Sb,
3,3'-DCPA = 3,3'dicyanodiphenylacetylene
Co(4,4'-dipyridyl sulfide)2Cl2
Every second link is a double
2•
bridge, through which the second
sheet interpenetrates in rotoxanelike interactions. Thus the
interpenetration occurs through
links, and thus in explaining the
interpenetration the net is
probably better described in
terms of a 2D 6-connected net.
2D (4,4) parallel interpenetration. 2•
2•
CdL2, HL = 3-[2-(4pyridyl)ethenyl]benzoate
MnL2(EtOH)2Br2, L = 2,3,5,6tetrafluoro-1,4-bis(4pyridylsulfenyl)benzene
[Hbipy][Ln(NO3)4(H2O)2(bipy)], Ln =
La, Ce, Pr, Nd
#-Cu(dca)(bpe)
2
2
Z. Ni and J.J. Vittal, Cryst. Growth Design, 2001, 1, 195-7.
2
Y-B. Dong, M.D. Smith and H-C. zur Loye, J. Solid State Chem.,
2000, 155, 143-153.
Nodes linked by L which coords 3
at one end and H-bonds to EtOH
at other. Of 'over 2-under 2' type.
H-bonded sheets. In La example 2
(and probably the others), there is
further H-bonding b/w sheets to
give (presumably) two #-Po like
nets.
2
Dabco / 5-hydroxyisophthalic acid (1/1) H-bonded nets.
3
Cd2(NO3)4(Py2C3H6)4(H2O),
Py2C3H6 = 1,3-bis(4-pyridyl)propane
K2Co(C4H4O4)2
2
Ag(dps)2X, dps = 4,4'-dipyridylsulfide,
X = PF6, CF3SO3
CoL2(NCS)2.1/3H2O, L = 1,3-bis(4pyridyl)propane
K.A. Hirsch, S.R. Wilson and J.S. Moore, Inorg. Chem., 1997, 36,
2960-2968.
O.-S. Jung, S.H. Park, D.C. Kim and K.M. Kim, Inorg. Chem., 1998,
37, 610-611.
W. Lin, O.R. Evans, R.-G. Xiong and Z. Wang, J. Am. Chem. Soc.,
1998, 120, 13272-3; O.R. Evans and W. Lin, Chem. Mater., 2001, 13,
3009-17.
D.M.L. Goodgame, D.A. Grachvogel, S. Holland, N.J. Long, A.J.P.
White and D.J. Williams, J. Chem. Soc., Dalton Trans., 1999, 34733482.
M. Bukowska-Strzyzewska and A. Tosik, Roczniki Chem., 1977, 51,
193-5; M. Bukowska-Strzyzewska and A. Tosik, Inorg. Chim. Acta,
1978, 30, 189-96; K. Al-Rasoul and T.J.R. Weakley, Inorg. Chim.
Acta, 1982, 60, 191-6; C.V.K. Sharma and R.D. Rogers, Chem.
Commun., 1999, 83-4.
S.R. Batten, A.R. Harris, P. Jensen, K.S. Murray and A. Ziebell, J.
Chem. Soc., Dalton Trans., 2000, 3829-3836.
C.J. Burchell, G. Ferguson, A.J. Lough and C. Glidewell, Acta
Crystallogr., Sect. C, 2000, 56, 1126-1128.
M.J. Plater, M.R.St.J. Foreman, T. Gelbrich, S.J. Coles and M.B.
Hursthouse, J. Chem. Soc., Dalton Trans., 2000, 3065-3073.
C. Livage, C. Egger and G. Ferey, Chem. Mater., 2001, 13, 410-414.
3
Two (4,4) nets formed by Co
bridged by succinate ligands. K
cations, however, cross-link the
two nets into one via oxygens.
D.M.L. Goodgame, S. Menzer, A.M. Smith and D.J. Williams,
Angew. Chem. Int. Ed. Engl., 1995, 34, 574.
9
MnL2(NCS)2, L = 1,3-bis(4pyridyl)propane
ML2(N3)2 (M = Mn, Fe) and
MnL2(NCS)2.0.25H2O, L = 1,3-bis(4pyridyl)propane
M(bipy)(azpy)2(NCS)2.H2O, M = Mn,
Co, azpy = 4,4'-azobispyridine
Zn4{3-[2-(4-pyridyl)ethenyl]
benzoato}8.{3-[2-(4-pyridyl)ethenyl]
benzoic acid}.H2O
Zn{5-[2-(3-pyridyl)ethenyl]thiophene2-carboxylate}2
[Zn2.5 L4OH].5H2O, L = 3-{[4-(4pyridylethenyl)phenyl]ethenyl}
benzoate
Ag(bpp)2(NO3), bpp = 1,3-bis(4pyridyl)propane
Ag(bpp)2(XF6), bpp = 1,3-bis(4pyridyl)propane, X = P, As
Camphoric acid /
hexamethylenetetramine (2/1)
1,1'-biphenyl-2,2',5,5'-tetracarboxylic
acid / 2,7-diazapyrene (1/2)
Ag(NC-(CH2)5-CN)2X, X = SbF6,
CF3SO3
CoL2(NCS)2, L = 2,5-bis(4pyridylethynyl)thiophene
[CuL2(ClO4)]ClO4, L = 1,2-bis(4pyridinecarboxamido)ethane
ZnL2(terephthalate).0.5H 2O, L =
SC(NHMe)2
Imidazolium hydrogen malonate
2
2
M.J. Plater, M.R.St.J. Foreman, R.A. Howie and J.M.S. Skakle,
Inorg. Chim. Acta, 2000, 318, 175-180.
H. Hou, Y. Wei, Y. Song, Y. Zhu, L. Li and Y. Fan, J. Mater. Chem.,
2002, 12, 838-843; S. Konar, E. Zangrando, M.G.B. Drew, T. Mallah,
J. Ribas and N.R. Chaudhuri, Inorg. Chem., 2003, 42, 5966-5973.
B. Li, G. Yin, H. Cao, Y. Liu and Z. Xu, Inorg. Chem. Commun.,
2001, 4, 451-3; B. Li, H. Liu, Y. Xu, J. Chen and Z. Xu, Chem. Lett.,
2001, 902-3.
O.R. Evans and W. Lin, Chem. Mater., 2001, 13, 3009-13.
2
O.R. Evans and W. Lin, Chem. Mater., 2001, 13, 3009-13.
2
P. Ayyappan, O.R. Evans and W. Lin, Inorg. Chem., 2002, 41, 33283330.
2
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4(22), 121-129.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4(22), 121-129.
2
Very unusual mode of
interpenetration involving triple
helicies. H-bonded nets.
Unusual structure in which there
are three layers of sheets - two
are single sheets, but the third
contains two parallel
interpenetrating (4,4) sheets.
3
Stacking alternated between
single (4,4) sheets and 2-fold
interpenetrated (4,4) sheets!!
H-bonded nets.
2
H-bonded nets; unusual
interpenetration mode.
3
2
3
5
3
Chains crosslinked by H-bonds to 2
give (4,4) sheets.
H-bonded sheets including
2
disordered water cluster.
C.M. Zakaria, G. Ferguson, A.J. Lough and C. Glidewell, Acta
Crystallogr., Sect. B, 2003, 59, 118-131.
P. Holy, P. Sehnal, M. Tichy, J. Zavada and I. Cisarova, Tetrahedron:
Asymmetry, 2003, 14, 245-253.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4, 413-425.
S.U. Son, B.Y. Kim, C.H. Choi, S.W. Lee, Y.S. Kim and Y.K.
Chung, Chem. Commun., 2003, 2528-2529.
C.-H. Ge, X.-D. Zhang, P. Zhang, W. Guan, F. Guo and Q.-T. Liu,
Polyhedron, 2003, 22, 3493-3497.
N.J. Burke, A.D. Burrows, A.S. Donovan, R.W. Harrington, M.F.
Mahon and C.E. Price, Dalton Trans., 2003, 3840-3849.
D.R. Trivedi, A. Ballabh and P. Dastidar, CrystEngComm, 2003, 5,
358-367.
10
CoL2Cl2.CHCl3.3H2O, L = (C6H4C6H4)C(C6H4OC(O)C5NH4)2
Mn(dca)2(biim), dca = dicyanamide,
1D coordination polymer chains
crosslinked by H-bonds.
biim = 2,2'-biimidazole
ZnL2.1.5H2O, L = trans-2,3-dihydro-2(4''-cyanophenyl)-benzo[e]indole
Cu4I4L2, L = (3Cu4I4 nodes.
py)CONHCH2CH2NHCO(3-py)
CuL2SO4.8H2O, L = 1,1'-(1,4butanediyl)bis(imidazole)
Co(SCN)2(dpp)2, dpp = 1,3-di-4pyridylpropane
[Ag(C25H20N2O2)2]SbF6
2
Bis(4-Nitrophenyl)diphenylmethane
2
2-amino-5-nitrothiazole.EtOH
Cd(tp)(bpp), tp = terephthalate, bpp =
1,3-bis(4-pyridyl)propane
BNA.2HCl, BNA = 4,4'-bipyridine2,2'-dicarboxylic acid
Tetrakis(nicotinoxymethyl)methane
Zn2(OH)(4-ptz)3, 4-ptz = 5-(4pyridyl)tetrazolate
Piracetam / gentisic acid (1/1)
Nets defined by C-H...O
interactions; but similar
interactions connect the nets in
3D.
H-bonded nets with dimeric
nodes.
2
2
2
2
2
2
3
2
H-bonded nets.
2
H-bonded nets. New
interpenetration topology?
3
2
H-bonded nets.
2
Piracetam / p-hydroxybenzoic acid (1/1) H-bonded nets.
3
P. Grosshans, A. Jouaiti, N. Kardouh, M.W. Hosseini and N.
Kyritsakas, New J. Chem., 2003, 27, 1806-1810.
D. Ghoshal, A.K. Ghosh, J. Ribas, E. Zangrando, G. Mostafa, T.K.
Maji and N.R. Chaudhuri, Cryst. Growth Des., 2005, 5, 941-947.
Q. Ye, Y.-H. Li, Y.-M. Song, X.-F. Huang, R.-G. Xiong and Z. Xue,
Inorg. Chem., 2005, 44, 3618-3625.
M. Sarkar and K. Biradha, Chem. Commun., 2005, 2229-2231.
J.-F. Ma, J. Yang, G.-L. Zheng, L. Li, Y.-M. Zhang, F.-F. Li and J.-F.
Liu, Polyhedron, 2004, 23, 553-559.
C. Merz, M. Desciak, C. O'Brien, R.L. LaDuca, R.C. Finn, R.S. Rarig
and J.A. Zubieta, Inorg. Chim. Acta, 2004, 357, 3331-3335.
Y.-B. Dong, P. Wang, R.-Q. Huang and M.D. Smith, Inorg. Chem.,
2004, 43, 4727-4739.
S. Basavoju, S. Aitipamula and G.R. Desiraju, CrystEngComm, 2004,
6, 120-125.
C. Glidewell, J.N. Low, J.M.S. Skakle and J.L. Wardell, Acta
Crystallogr., Sect. C, 2004, 60, o15-o18.
J.C. Dai, X.-T. Wu, S.-M. Hu, Z.-Y. Fu, J.-J. Zhang, W.-X. Du, H.-H.
Zhang and R.-Q. Sun, Eur. J. Inorg. Chem., 2004, 2096-2106.
R. Custelcean and M.G. Gorbunova, CrystEngComm, 2005, 7, 297301.
K.I. Nattinen, P.E.N. de Bairos, P.J. Seppala and K.T. Rissanen, Eur.
J. Inorg. Chem., 2005, 2819-2825.
C. Jiang, Z. Yu, S. Wang, C. Jiao, J. Li, Z. Wang and Y. Cui, Eur. J.
Inorg. Chem., 2004, 3662-3667.
P. Vishweshwar, J.A. McMahon, M.L. Peterson, M.B. Mickey, T.R.
Shattock and M.J. Zaworotko, Chem. Commun., 2005, 4601-4603.
P. Vishweshwar, J.A. McMahon, M.L. Peterson, M.B. Mickey, T.R.
Shattock and M.J. Zaworotko, Chem. Commun., 2005, 4601-4603.
2D!2D parallel (other)
Hittorf's phosphorus
(8,3) sheets.
2•
V.H. Thurn and H. Krebs, Acta Crystallogr., Sect. B, 1969, 25, 125.
11
[Pr(ntb)2](ClO4)3.2bipy.1.5H2O, ntb =
tris(2-benzimidazolylmethyl)amine
Cd2(NO3)4(dpt)2(MeCN), dpt = 2,4bis(4-pyridyl)-1,3,5-triazine
Zn(bdc)(bpeta).xA, bdc = 1,3benzenedicarboxylate, bpeta = 1,2bis(4-pyridyl)ethane, A = benzene,
nitrobenzene, toluene, benzaldehyde,
dioxane
Pd(Him)2(im)2, Him = imidazole
[(ZnL).3X].13S, ZnL = [5,10,15,20tetrakis(4hydroxyphenyl)porphyrinato]zinc, X =
N,N'-bis(4pyridylmethylidyne)hydrazine, S =
nitrobenzene
[Pb(timpt)(NO3)2].(Et2O)0.417
.(H2O)0.167 , timpt = 2,4,6-tris[4(chloromethyl)phenyl]-1,3,5-triazine
AgLClO4, L = 1,3-bis(1-imidazolyl)-5(imidazol-1-ylmethyl)benzene
Cu3Fe(CN)5(bipy)2, bipy = 2,2'bipyridine
Pb(pyta)2, pyta = 4-pyridylthioacetate
Complicated 4-conn. nets (with
3D character) generated by Hbonding between [Pr(ntb)2]3+
and bipy's.
Three-connected 4.8 2 nets;
bridging dpt and NO3- ligands.
(4,4) coordination net
interpenetrated by two (6,3) noncovalent nets of guest molecules.
2
C.-Y. Su, B.-S. Kang, H.-Q. Liu, Q.-G. Wang and T.C.W. Mak,
Chem. Commun., 1998, 1551-2.
2
S.A. Barnett, A.J. Blake, N.R. Champness, J.E.B. Nicolson and C.
Wilson, J. Chem. Soc., Dalton Trans., 2001, 567-573.
3
S.A. Bourne, J. Lu, B. Moulton and M.J. Zaworotko, Chem.
Commun., 2001, 861-2.
H-bonded nets.
4
N. Masciocchi, G.A. Ardizzoia, G. LaMonica, A. Maspero, S. Galli
and A. Sironi, Inorg. Chem., 2001, 40, 6983-6989.
Y. Diskin-Posner, G.K. Patra and I. Goldberg, Chem. Commun.,
2002, 1420-1421; Y. Diskin-Posner, G.K. Patra and I. Goldberg,
CrystEngComm, 2002, 4, 296-301.
Both H-bonding and coordinative 2
bonding; unusual topology of
both nets and interpenetration.
4.82 nets.
3
S.-Y. Wan, J. Fan, T. Okamura, H.-F. Zhu, X.-M. Ouyang, W.-Y.
Sun and N. Ueyama, Chem. Commun., 2002, 2520-2521.
4.82 nets.
2
4.82 nets.
2
J. Fan, W.-Y. Sun, T. Okamura, W.-X. Tang and N. Ueyama, Inorg.
Chem., 2003, 42, 3168-3175.
X. He, C.-Z. Lu, D.-Q. Yuan, S.-M. Chen and J.-T. Chen, Eur. J.
Inorg. Chem., 2005, 2181-2188.
M. Du, X.-J. Zhao and Y. Wang, Dalton Trans., 2004, 2065-2072.
1D coordination polymer chains 2
crosslinked by S...S contacts, to
give (4,4) sheets if nodes are M
and L2 moieties. Could define the
topology differently.
12
[Mn(p-XBP4)3](ClO4)2, p-XBP4 =
N,N'-p-phenylenedimethylenebis
(pyridin-4-one)
Cu3(ip)(ipH)(bipy)1.5 , H2ip =
isophthalic acid, bipy = 4,4'-bipyridine
Every second link is a double
2•
bridge, through which the second
sheet interpenetrates in rotoxanelike interactions. Thus the
interpenetration occurs through
links, and thus in explaining the
interpenetration the net is
probably better described in
terms of a 2D 6-connected net.
2D!2D parallel interpenetration 2
of 3,4-connected nets.
Cu2(O2CR)4 dimers are 4connecting nodes.
D.M.L. Goodgame, S. Menzer, A.M. Smith and D.J. Williams,
Angew. Chem. Int. Ed. Engl., 1995, 34, 574.
Parallel 2D sheets - each sheet is
penetrated by 4 others - noncoincident planes give 3D struct.
Parallel 2D sheets - each sheet is
penetrated by 4 others - noncoincident planes give 3D struct.
Similar to above structure.
Layer structure in which sheets
have some thickness; each layer
interpenetrated by two others;
sheets are parallel but not
coincident - an overall 3D
structure. Sheets themselves are
self-penetrating (see L. Carlucci,
G. Ciani and D.M. Proserpio,
CrystEngComm, 2003, 5, 269;
Coord. Chem. Rev., 2003, 246,
247).
5•
F.-Q. Liu and T.D. Tilley, Inorg. Chem., 1997, 36, 5090-5096.
5
S.R. Batten, A.R. Harris, P. Jensen, K.S. Murray and A. Ziebell, J.
Chem. Soc., Dalton Trans., 2000, 3829-3836.
3
L. Carlucci, G. Ciani, P. Macchi, D.M. Proserpio, and S. Rizzato,
Chem. Eur. J., 1999, 5, 237-243.
Y.-H. Wen, J.-K. Cheng, Y.-L. Feng, J. Zhang, Z.-J. Li and Y.-G.
Yao, Inorg. Chim. Acta, 2005, 358, 3347-3354; Y.-H. Wen, J.-K.
Cheng, Y.-L. Feng, J. Zhang, Z.-J. Li and Y.-G. Yao, Inorg. Chim.
Acta, 2005, 358, 3347-3354.
2D!3D parallel
{Ag3[Si(p-C6H4CN)4]2}[PF6]3
.1.6THF.0.5C6H6.2CH2Cl2
Cu4(dca)4(bipy)3(MeCN)2
[Ag(sebn)2]X, sebn = sebaconitrile
(1,10-decanedinitrile), X = SbF6,
CF3SO3
13
[Ag2(H2L)3]X2, H2L = N,N'bis(salicylidene)-1,4-diaminobutane, X
= NO3, ClO4
If Ag...Ag interactions ignored,
(6,3) sheets with two other nets
intptg each; non-coincident
planes give 3D struct.
Interpenetration of the
'Borromean' type (L. Carlucci, G.
Ciani and D.M. Proserpio,
CrystEngComm, 2003, 5, 269;
Coord. Chem. Rev., 2003, 246,
247). Else, a single, selfpenetrating net.
[Co5(bpe)9(H2O)8(SO4)4](SO4).14H2O Layers which are five levels
deep; each layer penetrated by
, bpe = 1,2-bis(4-pyridyl)ethane
four others.
Cu6(CN)5(trz), trz = triazolate
Undulating layer which is
interpenetrated by two others and
interdigitated with two others.
Authors claim inclined
interpenetration, but looks to be
2D!3D parallel intptn to me.
Cu4(1,4-C6H4(CO2)2)3(bipy)2
Thick layers, each penetrated by
2 others.
1,1,1-tris(4-hydroxyphenol)ethane.4,4'- (6,3) H-bonded nets. Layers of 5bipy (2/3)
fold 2D!2D parallel intptg
sheets intpte other such off-set
layers in a 2D!3D fashion. My
rough look implied 10 other nets
intpte each net (i.e. 11-fold
intptn), paper says 10.
Zn2(tp)(bipy)V2O6, tp = terephthalate
2D layers composed of pairs of
cross-linked (4,4) sheets; each
'thick' layer penetrated by 2
others.
3,5-dinitroaniline
H-bonded nets.
3
M.L. Tong, X.-M. Chen, B.-H. Ye and L.-N. Ji, Angew. Chem. Int.
Ed., 1999, 38, 2237-2240; Angew. Chem., 1999, 111, 2376-2379.
5
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, Chem.
Commun., 2000, 1319-1320.
3
D.J. Chesnut, A. Kusnetzow, R. Birge and J. Zubieta, Inorg. Chem.,
1999, 38, 5484-5494.
3
S.M.-F. Lo, S.S.-Y. Chui, L.-Y. Shek, Z. Lin, X.X. Zhang, G. Wen
and I.D. Williams, J. Am. Chem. Soc., 2000, 122, 6293-6294.
A.C. Benyei, P.I. Coupar, G. Ferguson, C. Glidewell, A.J. Longh and
P.R. Meehan, Acta Crystallogr., Sect. C, 1998, 54, 1515-1519.
Cu3(bpen)(IN)6(H2O)2, bpen = 1,2bis(4-pyridyl)ethylene, IN =
isonicotinato
3
Triple-level layers.
10
3
J. Tao, X.-M. Zhang, M.-L. Tong and X.-M. Chen, J. Chem. Soc.,
Dalton Trans., 2001, 770-771.
3
C. Glidewell, D. Cannon, A. Quesada, J.N. Low, S.A. McWilliam,
J.M.S. Skakle and J.L. Wardell, Acta Crystallogr., Sect. C, 2001, 57,
455-8.
J.Y. Lu and A.M. Babb, Inorg. Chem., 2001, 40, 3261-2.
14
Cd(isonicotinate)2(1,2-bis(4pyridyl)ethane)1/2(H2O)
1,2-bis(4-pyridyl)ethane - 1,1,1-tris(4hydroxyphenyl)ethane (1/2)
2,2'-bipyridine - 1,1,1-tris(4hydroxyphenyl)ethane (1/2)
[Cu(bpe)1.5 (PPh3)]PF6.1.5CH2Cl2, bpe
= 1,2-bis(4-pyridyl)ethylene
Cd(dca)2(bpp), dca = dicyanamide, bpp
= 1,3-bis(4-pyridyl)propane
Cu3(bipy)2(pydc)2.4H2O, bipy = 4,4'bipyridine, pydc = pyridine-2,4dicarboxylate
Ag(bpe)L0.5 .H2O, bpe = 1,2-bis(4pyridyl)ethane, L = 4,4'biphenylcarboxylate
3
H-bonded nets.
3
H-bonded nets.
3
Highly undulating (6,3) sheets.
3
One isomorph has each parallel
3
sheet interpenetrated by two
others, one above and one below.
While parallel, each adjacent
interpenetrating layer is
orientated ca. 90° within the
plane to its neighbour, so
interpenetration is due to a
mixture of undulation and
thickness of the sheets.
If long Cu...O interactions (2.689 5
Å) are ignored, then highly
undulating sheets; each sheet
interlocked with 4 others.
Otherwise, 2 interpenetrating 3,4connected nets with
(102.12)2(4.102)2(42.102.122)
topology.
T-shaped nodes (Ag). Each 'thick' 3
layer actually interpenetrates
directly which two others, and
only interdigitates with a further
two. However, the
interpenetrating layers 'tie' the
interdigitating layers to the initial
one. See L. Carlucci, G. Ciani
and D.M. Proserpio,
CrystEngComm, 2003, 5, 269;
Coord. Chem. Rev., 2003, 246,
247 for excellent discussions of
this structure.
Z.-Y. Fu, X.-T. Wu, J.-C. Dai, L.-M. Wu, C.-P. Cui and S.-M. Hu,
Chem. Commun., 2001, 1856-7.
C.M. Zakaria, G. Ferguson, A.J. Lough and C. Glidewell, Acta
Crystallogr., Sect. C, 2002, 58, o1-o5.
C.M. Zakaria, G. Ferguson, A.J. Lough and C. Glidewell, Acta
Crystallogr., Sect. C, 2002, 58, o204-o208.
J.M. Knaust, S. Lopez and S.W. Keller, Inorg. Chim. Acta, 2001, 324,
81-89.
E.-Q. Gao, Z.-M. Wang, C.-S. Liao and C.-H. Yan, New J. Chem.,
2002, 26, 1096-1098; E.-Q. Gao, S.-Q. Bai, Z.-M. Wang and C.-H.
Yan, Dalton Trans., 2003, 1759-1764.
X.-M. Zhang and X.-M. Chen, Eur. J. Inorg. Chem., 2003, 413-417.
Z.-Y. Fu, X.-T. Wu, J.-C. Dai, S.-M. Hu and W.-X. Du, New J.
Chem., 2002, 26, 978-980.
15
[Ag2L3OH][ClO4].2.5H2O, L = N, N'- Highly undulating (6,3) sheets.
bis(3-pyridinecarboxamide)-1,6-hexane Each net is interpenetrates with
not other net directly. However,
each interdigitates with four
others in such a way that each
interdigitating layer 'ties' another
layer to the first, such that all
three are inseparable without
breaking links. Interpenetration
of the 'Borromean' type (L.
Carlucci, G. Ciani and D.M.
Proserpio, CrystEngComm, 2003,
5, 269; Coord. Chem. Rev., 2003,
246, 247).
Trimesic acid (# form)
$nd polyhalide clathrates; Hbonding. Highly undulating (6,3)
sheets. Each window of each
sheet has three other networks
passing through it, however it
would be more accurate to
describe it as 10-fold
interpenetration as each sheet
interpenetrates with 9 others.
Zn2(nip)2(bipy)3.H2O, H2nip = 5Thick layers.
nitroisophthalic acid
ZnL2(NCS)2.2H2O, L = 1,2-bis(3Highly undulating (4,4) sheets.
pyridylmethyleneamino)ethane
Cd(bpe)1.5 (NO2-BDC).0.25H2O, bpe = Thick layers.
1,2-bis(4-pyridyl)ethane, NO2-BDCH2
= 5-nitro-1,3-benzenetricarboxylic acid
AgL(CF3SO3).0.5H2O, L = 1,3,5-tris(4- Highly undulated (6,3) sheets.
Layers of doubly interpenetrating
cyanophenoxymethyl)-2,4,6sheets are further interpenetrated
trimethylbenzene
with adjacent layers. Each sheet
interpenetrates with 3 others one in the same plane, one above
and one below.
[H3bta]2[H2-4,4'-bipy], H4bta =
H-bonded nets. Each thick layer
penetrated by two others.
benzene-1,2,4,5-tetracarboxylic acid
0
S. Muthu, J.H.K. Yip and J.J. Vittal, J. Chem. Soc., Dalton Trans.,
2002, 4561-4568.
4
D.J. Duchamp and R.E. Marsh, Acta Crystallogr., Sect. B, 1969, 25,
5; F.H. Herbstein, M. Kapon and G.M. Reisner, Acta Crystallogr.,
Sect. B, 1985, 41, 348; F.H. Herbstein, Isr. J. Chem., 1968, 6, IVp;
J.E. Davies, P. Finocchiaro and F.H. Herbstein in Inclusion
Compounds, eds. J.L. Atwood, J.E.D. Davies and D.D. MacNicol,
Academic Press, London, 1984, vol 2, Ch. 11; F.H. Herbstein, Top.
Curr. Chem., 1987, 140, 107.
3
J. Tao, X. Yin, Y.-B. Jiang, L.-F. Yang, R.-B. Huang and L.-S.
Zheng, Eur. J. Inorg. Chem., 2003, 2678-2682.
Y. Wang, X.-M. Ouyang, Y.-Z. Li and W.-Y. Sun, Bull. Chem. Soc.
Jpn., 2003, 76, 1403-1404.
J. Luo, M. Hong, R. Wang, R. Cao, L. Han and Z. Lin, Eur. J. Inorg.
Chem., 2003, 2705-2710.
3
3
4
S. Banfi, L. Carlucci, E. Caruso, G. Ciani and D.M. Proserpio, Cryst.
Growth Des., 2004, 4, 29-32.
3
C. Ruiz-Perez, P.A. Lorenzo-Luis, M. Hernandez-Molina, M.M. Laz,
P. Gili and M. Julve, Cryst. Growth Des., 2004, 4, 57-61.
16
[(ZnL).bipy].nS, ZnL = [5,10,15,20tetrakis(4hydroxyphenyl)porphyrinato]zinc, S =
nitrobenzene
Zn(bpndc)(bipy)1.5 .0.5bipy.0.5H2O,
bpndc = benzophenone-4,4'dicarboxylate, bipy = 4,4'-bipyridine
CoL2(NO3)2.2Et2O.Me2SO.H2O, L =
N, N'-bis(4-pyridylcarbonyl)-4,4'diaminodiphenyl ether
Ag2NbTi3P6S25, M = Na, Ag
Both H-bonding and coordinative
bonding. Complex layers
interpenetrate in a 2D!3D
parallel fashion (3-fold) (see L.
Carlucci, G. Ciani and D.M.
Proserpio, Coord. Chem. Rev.,
2003, 246, 247 for analysis), but
further H-bonds connect nets
together into a single selfpenetrating(?) 3D net.
Thick layers. Each layer
3
penetrated by 2 others.
Y. Diskin-Posner, G.K. Patra and I. Goldberg, Chem. Commun.,
2002, 1420-1421; Y. Diskin-Posner, G.K. Patra and I. Goldberg,
CrystEngComm, 2002, 4, 296-301.
Highly undulated (4,4) sheets.
3
Y.W. Shin, T.H. Kim, K.Y. Lee, K.-M. Park, S.S. Lee and J. Kim,
Inorg. Chem. Commun., 2004, 7, 374-377.
Thick sheets; each penetrated by
two others.
3
J. Angenault, X. Cieren, G. Wallez and M. Quarton, J. Solid State
Chem., 2000, 153, 55-65.
2•
L.R. MacGillivray, S. Subramanian and M.J. Zaworotko, J. Chem.
Soc., Chem. Commun., 1994, 1325.
H.O. Stumpf, L. Ouahab, Y. Pei, D. Grandjean and O. Kahn, Science,
1993, 261, 447; H.O. Stumpf, L. Ouahab, Y. Pei, P. Bergerat and O.
Kahn, J. Am. Chem. Soc., 1994, 116, 3866; M.G.F. Vaz, L.M.M.
Pinheiro, H.O. Stumpf, A.F.C. Alcantara, S. Golhen, L. Ouahab, O.
Cador, C. Mathoniere and O. Kahn, Chem. Eur. J., 1999, 5, 14861495; M.G.F. Vaz, H.O. Stumpf, N.L. Speziali, C. Mathoniere and O.
Cador, Polyhedron, 2001, 20, 1761-1769; M.A. Novak, M.G.F. Vaz,
N.L. Speziali, W.V. Costa and H.O. Stumpf, Polyhedron, 2003, 22,
2391-2394.
D. Whang and K. Kim, J. Am. Chem. Soc., 1997, 119, 451-2; K.-M.
Park, D. Whang, E. Lee, J. Heo and K. Kim, Chem. Eur. J., 2002, 8,
498-508.
F.H. Herbstein, M. Kapon and G.M. Reisner, Acta Crystallogr., Sect.
B, 1985, 41, 348; F.H. Herbstein, M. Kapon and G.M. Reisner, Proc.
R. Soc. Lond. A, 1981, 376, 301; J.E. Davies, P. Finocchiaro and F.H.
Herbstein in Inclusion Compounds, eds. J.L. Atwood, J.E.D. Davies
and D.D. MacNicol, Academic Press, London, 1984, vol 2, Ch. 11;
F.H. Herbstein, Top. Curr. Chem., 1987, 140, 107.
C. Sun and L. Jin, J. Mol. Struct., 2005, 733, 63-68.
2D inclined (6, 3)
Cu2(pyz)3(SiF6)
(R-rad+)2M2[Cu(opba)]3(DMSO)2
.2H2O, R-rad+ = 2-(4-Nalkylpyridinium)-4,4,5,5tetramethylimidazoline-1-oxyl-3-oxide
(aka 2-(1-alkylpyridinium-4-yl)-4,4,5,5tetramethylimidazolin-1-oxyl-3-oxide);
opba = o-phenylene-bis(oxamato); R =
Me, Et, Pr, Bu, M = Mn, Co, Ni
[Ag2(C16H24N4)3•(C36H36N24O12)3]
(NO3)8.40H2O
R-rad+ actually links the two
interpenetrating sheets.
Trimesic acid (% form)
$nd polyhalide clathrates; Hbonding.
2•
Each rod of the sheets is a
3•
rotaxane with Cucurbituril beads.
4•
17
Cu(bipy)X, X = Cl, Br, I, S
Bipys bridge Cu2X2 clusters.
4•
O.M. Yaghi and G. Li, Angew. Chem. Int. Ed. Engl., 1995, 34, 207 (X
= Cl); S.R. Batten, J.C. Jeffery and M.D. Ward, Inorg. Chim. Acta,
1999, 292, 231-237 (X = Br, I); J.Y. Lu, B.R. Cabrera, R.-J. Wang
and J. Li, Inorg. Chem., 1999, 38, 4608-4611 (X = Br); A.J. Blake,
N.R. Brooks, N.R. Champness, P.A. Cooke, M. Crew, A.M. Deveson,
L.R. Hanton, P. Hubberstey, D. Fenske and M. Schroder, Cryst. Eng.,
1999, 2, 181-195 (X = I); X. Gu, Z. Shi, J. Peng, Y. Chen, E. Wang
and N. Hu, J. Mol. Struct., 2004, 694, 219-222.
Fe(C5H4COC6H4OH)2
H-bonded.
2?• A.C. Benyei, C. Glidewell, P. Lightfoot, B.J.L. Royles and D.M.
Smith, J. Organomet. Chem., 1997, 539, 177-186.
[Et4N][{Ni(Hbim)3}2(H2bim)].MeOH. H-bonded; interesting topology
3
M. Tadokoro, K. Isobe, H. Uekusa, Y. Ohashi, J. Toyoda, K. Tashiro
of interpenetration.
and K. Nakasuji, Angew. Chem. Int. Ed., 1999, 38, 95-98; Angew.
H2O, H2bim = 2,2'-biimidazole
Chem., 1999, 111, 102-6; M. Tadokoro, K. Isobe, H. Uekusa, Y.
MeEt3N derivative also.
Ohashi and K. Nakasuji, Mol. Cryst. Liq. Cryst., 1996, 278, 221-224;
K. Nakasuji, M. Tadokoro, J. Toyoda, M. Mitsumi, T. Itoh and K.
Iijima, Mol. Cryst. Liq. Cryst., 1996, 285, 241-248; M. Tadokoro and
K. Nakasuji, Coord. Chem. Rev., 2000, 198, 205-18.
Cs[Ni(Hbim)3], [Ru(Hbim)3], H2bim = H-bonded nets; Cs just
3
M. Tadokoro, T. Shiomi, K. Isobe and K. Nakasuji, Inorg. Chem.,
counterion.
2001, 40, 5476-8; M. Tadokoro, H. Kanno, T. Kitajima, H. Shimada2,2'-biimidazole
Umemoto, N. Nakanishi, K. Isobe and K. Nakasuji, Proc. Natl. Acad.
Sci., 2002, 99, 4950-4955.
[Mn(bpe)(H2O)4](ClO4)2.4(bpe).2H2O Mn-bpe chains reinforced by two 2
F.D. Rochon, M. Andruh and R. Melanson, Can. J. Chem., 1998, 76,
H-bonding H2O-bpe-H2O links,
1564-1570.
with other connections also H2Obpe-H2O links.
ZnL1.5 (H2O)(SO4).6H2O, L = 1,1'-(1,43
J.-F. Ma, J.-F. Liu, Y. Xing, H.-Q. Jia and Y.-H. Lin, J. Chem. Soc.,
Dalton Trans., 2000, 2403-2407.
butanediyl)bis(imidazole)
Cd(NO3)2L1.5 •1/2L, L = 1,4-bis(33
Y.-B. Dong, M.D. Smith and H.-C. zur Loye, Inorg. Chem., 2000, 39,
4927-4935.
pyridyl)-2,3-diaza-1,3-butadiene
[Ag2(1,4-dithiane)3](NO3)2
2
N.R. Brooks, A.J. Blake, N.R. Champness, J.W. Cunningham, P.
Hubberstey, S.J. Teat, C. Wilson and M. Schroder, J. Chem. Soc.,
Dalton Trans., 2001, 2530-2538.
Ag(TITMB)N3.H2O, TITMB = 1,3,52
J. Fan, H.-F. Zhu, T. Okamura, W.-Y. Sun, W.-X. Tang and N.
Ueyama, Inorg. Chem., 2003, 42, 158-162.
tris(imidazol-1-ylmethyl)-2,4,6trimethylbenzene
CTA.H2O, CTA = 1,3,5H-bonded nets.
4
B.R. Bhogala, P. Vishweshwar and A. Nangia, Cryst. Growth Des.,
2002, 2, 325-328.
cyclohexanetricarboxylic acid
CTA.MeCN, CTA = 1,3,5H-bonded nets.
5
N. Shan, A.D. Bond and W. Jones, New J. Chem., 2003, 27, 365-371.
cyclohexanetricarboxylic acid
18
In(BDC)1.5 (bipy), BDC = 1,4benzenedicarboxylate, bipy = 2,2'bipyridine
1,4-di[bis(4'hydroxyphenyl)methyl]benzene.2solv,
solv = MeOH, EtOH
Tetra(4cyanophenyl)methane.0.5MeCN
3
B. Gomez-Lor, E. Gutierrez-Puebla, M. Iglesias, M.A. Monge, C.
Ruiz-Valero and N. Snejko, Chem. Mater., 2005, 17, 2568-2573.
H-bonded nets. Nets crosslinked
by EtOH in EtOH structure.
3
S. Aitipamula and A. Nangia, Supramol. Chem., 2005, 17, 17-25.
Nets defined by C-H...N
interactions; but similar
interactions connect the nets.
3
S. Basavoju, S. Aitipamula and G.R. Desiraju, CrystEngComm, 2004,
6, 120-125.
2•
2•
T. Soma and T. Iwamoto, Chem. Lett., 1995, 271.
R.W. Gable, B.F. Hoskins and R. Robson, J. Chem. Soc., Chem.
Commun., 1990, 1677; R. Robson, B.F. Abrahams, S.R. Batten, R.W.
Gable, B.F. Hoskins and J. Liu, Supramolecular Architecture, ACS
Symposium Series 499, ed. T. Bein, Am. Chem. Soc., Washington
DC, 1992, 256.
2
S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka
and M. Yamashita, J. Am. Chem. Soc., 2002, 124, 2568-2583.
B.F. Hoskins, R. Robson and E.E. Sutherland, unpublished results.
2D inclined (4, 4)
Cd(NH3)2{Ag(CN)2}2
[M(bipy)2(H2O)2]SiF6,
M = Zn, Cu, Cd;
[Cd(bipy)2(H2O)(OH)]PF6.
[Cu(bipy)2(H2O)2]XF6,
X = Si, Ge
M2(OH)(bpb)4(BF4)3.H2O.C2H5OH,
M = Cd, Cu
[M(bpe)2(NCS)2].CH3OH, bpe = 1,2bis(4-pyridyl)-ethene, M = Fe, Co
Co(NCS)2(Py2L)2, Py2L = trans-1,2bis(4-pyridyl)ethylene
{[Cd(4-ampy) 2{µ-Ag(CN)2}2]
.[Cd(mea)(4-ampy){Ag(CN)2}{µAg(CN)2}]2}n, 4-ampy = 4aminopyridine, mea = 2-aminoethanol
Cd(C5H5N)2{Ag(CN)2}2.C6H6
Cd(C5H5N)2{Ag(CN)2}2.C4H5N
If H2O...SiF6...H2O hydrogen
bonds taken into account, Zn
(and presumably the others) can
be described as a single selfpenetrating 3D net (L. Carlucci,
G. Ciani and D.M. Proserpio,
Coord. Chem. Rev., 2003, 246,
247).
Pairs of bridged square sheets.
2•
Bridging bpes and terminal NCS
ligands.
2•
Diagonal/diagonal mode.
2
Two sets of intpting sheets
different - one coordn (3-fold
intpted), other H-bonding b/w
coordn chains (2-fold intpted).
3
an
d
2•
3•
3•
J.A. Real, E. Andres, M.C. Munoz, M. Julve, T. Granier, A.
Bousseksou and F. Varret, Science, 1995, 268, 265; G. De Munno, F.
Cipriani, D. Armentano, M. Julve and J.A. Real, New J. Chem., 2001,
25, 1031-1036.
S.H. Park, K.M. Kim, S. Lee and O.-S. Jung, Bull. Korean Chem.
Soc., 1998, 19, 79-82.
T. Soma and T. Iwamoto, Acta Crystallogr., Sect. C, 1996, 52, 1200.
T. Soma and T. Iwamoto, Mol. Cryst. Liq. Cryst., 1996, 276, 19-24;
T. Soma and T. Iwamoto, J. Inclusion Phenom. Mol. Recognit.
Chem., 1996, 26, 161-173.
T. Soma and T. Iwamoto, J. Inclusion Phenom. Mol. Recognit.
Chem., 1996, 26, 161-173.
19
[Cu(bpe)2][Cu(bpe)(H2O)2(SO4)2]
.2H2O
2
D. Hagrman, R.P. Hammond, R. Haushalter and J. Zubieta, Chem.
Mater., 1998, 10, 2091-2100.
Co(dca)2(bipy).0.5H2O.0.5MeOH
2
Cu(dca)2(bipy).H2O
A long Cu-N(amide) bond (ca.
2.8-2.9 Å) links interpenetrating
sheets, giving a self-penetrating
net.
M(NCS)2L2, M = Co, Zn, Cd, L = 2,2'- They use phrase "2 x 2
interpenetration".
bi-1,6-naphthyridine
[M(azpy)2(H2O)2]SiF6.H2O, azpy =
trans-4,4'-azobis(pyridine), M = Zn,
Cu; [Cu(azpy)2(H2O)2](NO3)2(H2O)2
2
P. Jensen, S.R. Batten, B. Moubaraki, and K.S. Murray, J. Chem.
Soc., Dalton Trans., 2002, 3712-3722.
P. Jensen, S.R. Batten, B. Moubaraki, and K.S. Murray, J. Chem.
Soc., Dalton Trans., 2002, 3712-3722.
Ni(bipy)2(NO3)2.2pyrene
2
M(bipy)2(NO3)2.2p-nitroaniline, M =
Co, Ni, Zn
Cu(bpe)2 sheets, with
Cu/bpe/SO4 chains between
sheets; weak axial coord. of SO4
in chains by Cu in sheets x-links
nets, presumably generating a
self-penetrating network.
(4,4) Ni(bipy)2 sheets
interpenetrated by (4,4) pyrene
sheets - pyrene molecules held
together by edge-to-face &
interactions - could also be
described as (6,3) sheets.
Similar interpenetration of (4,4)
coordination polymer and guest
molecule nets as described in
pyrene structure above.
3
2
2
Cd(NO3)2(Py2C6H12)2, Py2C6H12 =
1,6-bis(4-pyridyl)hexane
Co2(azpy)2(NCS)2•0.5EtOH, azpy =
4,4'-azopyridine
4
[NiL2(H2O)2](NO3)2, L = 9,10-bis(4pyridyl)anthracene
2
2
H.-P. Wu, C. Janiak, L. Uehlin, P. Klufers, and P. Mayer, Chem.
Commun., 1998, 2637-2638.
L. Carlucci, G. Ciani and D.M. Proserpio, New. J. Chem., 1998, 22,
1319-1321 (Zn); M.A. Withersby, A.J. Blake, N.R. Champness, P.A.
Cooke, P. Hubberstey, A.L. Realf, S.J. Teat and M. Schroder, J.
Chem. Soc., Dalton Trans., 2000, 3261-3268 (Cu); C. He, B.-G.
Zhang, C. Duan, J. Li and Q.-J. Meng, Eur. J. Inorg. Chem., 2000,
2549-2554 (NO3).
K. Biradha, K.V. Domasevitch, B. Moulton, C. Seward and M.J.
Zaworotko, Chem. Commun., 1999, 1327. See also K. Biradha, A.
Mondal, B. Moulton and M.J. Zaworotko, J. Chem. Soc., Dalton
Trans., 2000, 3837-3844 for related arene structures. See also F.H.
Herbstein, Acta Crystallogr., Sect. B, 2001, 57, 517-9 for further
discussion.
B. Moulton, E.B. Rather and M.J. Zaworotko, Cryst. Eng., 2001, 4,
309-317.
M.J. Plater, M.R.St.J. Foreman, T. Gelbrich, S.J. Coles and M.B.
Hursthouse, J. Chem. Soc., Dalton Trans., 2000, 3065-3073.
M. Kondo, M. Shimamura, S. Noro, S. Minakoshi, A. Asami, K. Seki
and S. Kitagawa, Chem. Mater., 2000, 12, 1288-1299; see also B.-L.
Li, Y. Xu, Y.-J. Liu and Z. Xu, Chem. Res. Chin. Univ., 2001, 17,
237-242.
K. Biradha and M. Fujita, J. Chem. Soc., Dalton Trans., 2000, 38053810.
20
Zn(tetra(4-carboxyphenyl)porphyrin)
.solv
H-bonded nets.
3
meso-tetra[4-(3,5diaminotriazino)phenyl]porphyrin
H-bonded nets. The
interpenetrating sheets are crosslinked within each of the two
separate stacks by further Hbonding.
3
NiL2(NO3)2(THF)5/3(H2O)1/3, L = 1,4bis(4-pyridyl)-2,3-diaza-1,3-butadiene
ML2(H2O)2, L = trans-4pyridylacrylate, M = Ni, Cu
Cu(fum)(ppz)(H2O)2, fum = fumarate
dianion, ppz = piperazine
2
ML2(NO3)2.CH2Cl2, M = Cu, Co, L =
1,4-bis(4-pyridyl)butadiyne
Ln2(ad)3(H2O)4.xH2O, Ln = Nd, Sm,
Gd, Er, Yb, H2ad = adipic acid
2
[Cu(bpp)2Cl]Cl.1.5H2O, bpp = 1,3bis(4-pyridyl)propane
NiL2(NO3)2.x(mesitylene), L = 4,4'bis(4-pyridyl)biphenyl
M(C4O4)(bipy)(H2O)2.3H2O, C4O4 = H-bonding crosslinks
squarate dianion, bipy = 4,4'-bipyridine, interpenetrating sheets.
M = Mn, Fe, Co, Ni, Cd
3
2
2
2
4
2
Cu(bpb)2(NO3)2.azo, bpb = 1,4-bis(42
pyridyl)butadiyne, azo = azobenzene
[Cd(bpz)(H2O)3(SO4)].H2O, bpz = 4,4'- 1D coordination polymer chains 2
linked by H-bonding into (4,4)
bipyrazolyl
sheets which then show inclined
interpenetration. However,
further extensive H-bonding may
crosslink sheets.
I. Goldberg, Mol. Cryst. Liq. Cryst., 1996, 278, 57-64; P. Dastidar, Z.
Stein, I. Goldberg and C.E. Strouse, Supramol. Chem., 1996, 7, 257270; M.E. Kosal and K.S. Suslick, J. Solid State Chem., 2000, 152,
87-98.
S. Dahal and I. Goldberg, J. Phys. Org. Chem., 2000, 13, 382-387.
D.M. Ciurtin, Y-B. Dong, M.D. Smith, T. Barclay and H-C. zur
Loye, Inorg. Chem., 2001, 40, 2825-2834.
Y-H. Liu, C-S. Lin, S-Y. Chen, H-L. Tsai, C-H. Ueng and K-L. Lu, J.
Solid State Chem., 2001, 157, 166-172.
P.S. Mukherjee, S. Dalai, G. Mostafa, E. Zangrando, T.-H. Lu, G.
Rogez, T. Mallah and N.R. Chaudhuri, Chem. Commun., 2001, 13461347.
M.B. Zaman, M.D. Smith and H.-C. zur Loye, Chem. Mater., 2001,
13, 3534-41.
A. Dimos, D. Tsaousis, A. Michaelides, S. Skoulika, S. Golhen, L.
Ouahab, C. Didierjean and A. Aubry, Chem. Mater., 2002, 14, 26162622.
L. Carlucci, G. Ciani, M. Moret, D.M. Proserpio and S. Rizzato,
Chem. Mater., 2002, 14, 12-16.
Mentioned in K. Biradha, Y. Hongo and M. Fujita, Angew. Chem. Int.
Ed., 2002, 41, 3395-3398; Angew. Chem., 2002, 114, 3545-3548.
C. Nather, J. Greve and I. Jeb, Chem. Mater., 2002, 14, 4536-4542;
C.-C. Wang, C.-H. Yang, S.-H. Yang, S.-M. Tseng, G.-H. Lee, H.-S.
Sheu and K.W. Phyu, Inorg. Chim. Acta, 2004, 357, 3759-3764; S.
Konar, M. Corbella, E. Zangrando, J. Ribas and N.R. Chaudhuri,
Chem. Commun., 2003, 1424-1425; J. Greve, I. Jeb and C. Nather, J.
Solid State Chem., 2003, 175, 328-340.
M.B. Zaman, K. Udachin, M. Akhtaruzzaman, Y. Yamashita and J.A.
Ripmeester, Chem. Commun., 2002, 2322-2323.
I. Boldog, J. Sieler, A.N. Chernega and K.V. Domasevitch, Inorg.
Chim. Acta, 2002, 338, 69-77.
21
Cd(bpz)2(NO3)2, bpz = 4,4'-bipyrazolyl
Ag(NC-(CH2)7-CN)2X, X = ClO4, PF6,
AsF6, SbF6
Co(mppe)2(NCS)2, mppe = 1-methyl1'-(4-pyridyl)-2-4-pyrimidyl)ethylene
CoL2(NCS)2, L = 1-(3-pyridyl)-2-(4pyridyl)ethene
Co(mpe)2(NCS)2, mpe = 1-methyl-1',2bis(4-pyridyl)ethene
4,4-bis(3-methyl-4hydroxyphenyl)cyclohexanone
Tris(4-hydroxyphenyl)methane
Fe(azpy)2(NCS)2.guest, azpy = trans4,4'-azopyridine
Cd(bpp)2(SCN)2.2H2O, bpp = 2,2'bis(4-pyridylmethyleneoxy)-1,1'biphenylene
Cd4(bpe)3(H2O)2(3,3'-bpda)4, bpe =
1,2-bis(4-pyridyl)ethane, 3,3'-bpda =
1,1'-biphenyl-3,3'-dicarboxylate
Co4(pico)4(bipy)3(H2O)2.2H2O, pico =
3-hydroxypicolinate, bipy = 4,4'bipyridine
[Cu2(mea)2(bpe)2](ClO4)2, Hmea =
monoethanolamine, bpe = bis(4pyridyl)ethylene
AgL2(BF4).MeOH, L = 2,2'-bis(4pyridyl)-9,9'-spirobifluorene
2
Diagonal/diagonal mode.
2
Diagonal/diagonal mode.
2
2
One form.
2
Two types of H-bonded (4,4) nets 2
(square and 'parquet floor'
geometries) - one has one of
other type penetrating each
window, while the other has two
nets penetrating every second
window, while the other types of
windows are not penetrated at all.
H-bonded nets which could also 2
be described as (6,3).
Diagonal/diagonal mode.
2
2
I. Boldog, J. Sieler, A.N. Chernega and K.V. Domasevitch, Inorg.
Chim. Acta, 2002, 338, 69-77.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4, 413-425.
D.M. Shin, I.S. Lee, Y.K. Chung and M.S. Lah, Chem. Commun.,
2003, 1036-1037.
D.M. Shin, I.S. Lee, Y.K. Chung and M.S. Lah, Inorg. Chem., 2003,
42, 5459-5461.
D.M. Shin, I.S. Lee, D. Cho and Y.K. Chung, Inorg. Chem., 2003, 42,
7722-7724.
S. Aitipamula, G.R. Desiraju, M. Jaskolski, A. Nangia and R.
Thaimattam, CrystEngComm, 2003, 5, 447-450.
S. Aitipamula, A. Nangia, R. Thaimattam and M. Jaskolski, Acta
Crystallogr., Sect. C, 2003, 59, o481-o484.
G.J. Halder, C.J. Kepert, B. Moubaraki, K.S. Murray and J.D.
Cashion, Science, 2002, 298, 1762-1765.
R. Wang, L. Han, L. Xu, Y. Gong, Y. Zhou, M. Hong and A.S.C.
Chan, Eur. J. Inorg. Chem., 2004, 3751-3763.
Cd4(3,3'-bpda)4(H2O)2 nodes
2
Inclined sheets are different; in
one every window penetrated by
1 sheet, in other only every
second window penetrated by
one sheet.
Cu2(mea)2 nodes.
0.5 M.-H. Zeng, W.-X. Zhang, X.-Z. Sun and X.-M. Chen, Angew. Chem.
/2 Int. Ed., 2005, 44, 3079-3082.
Net composed of 1D
coordination polymers
crosslinked by pi-pi stacking.
2
3
R. Wang, L. Han, F. Jiang, Y. Zhou, D. Yuan and M. Hong, Cryst.
Growth Des., 2005, 5, 129-135.
G. Marin, V. Tudor, V.C. Kravtsov, M. Schmidtmann, Y.A.
Simonov, A. Muller and M. Andruh, Cryst. Growth Des., 2005, 5,
279-282.
K.-T. Wong, Y.-L. Liao, Y.-C. Peng, C.-C. Wang, S.-Y. Lin, C.-H.
Yang, S.-M. Tseng, G.-H. Lee and S.-M. Peng, Cryst. Growth Des.,
2005, 5, 667-671.
22
Cu2Cl2(chtpy), chtpy = a,a-1,4dihydroxy-e,e,e,e-1,2,4,5-tetra(4pyridyl)cyclohexane
Diagonal/diagonal mode.
2
M.-L. Tong, S. Hu, B. Wang and S.R. Batten, Angew. Chem. Int. Ed.,
2005, 44, 5471-5475.
2D inclined with > 2 stacks
Pt(HL)2L2.2H2O, HL = 4-pyCO2H
H-bonded (4,4) sheets
interpenetrating in 3
perpendicular planes. "each
square cavity of one of the
unique nets is interwoven by 3
other nets, while those of the
other unique net are interwoven
by 5 nets."
Fe(bpb)2(NCS)2•0.5MeOH, bpb = 1,4- Three perpendicular stacks of
sheets.
bis(4-pyridyl)butadiyne
Co2(azpy)3(NO3)4•Me2CO•3H 2O, azpy Remarkable structure with 4
different stacks of (6,3) sheets!!
= 4,4'-azopyridine
Each window has 3 other nets
going through it. Unusual intptn
topology not commented on by
authors!
[Ni6(bpe)10(H2O)16](SO4)6.xH2O, bpe Three sets of (4,4) sheets (of two
different geometries)
= bis(4-pyridyl)ethane
interpenetrating in a
parallel/parallel/parallel fashion;
authors define a 'density of
catenation' of 2/4/4.
4/6 C.B. Aakeroy, A.M. Beatty and D.S. Leinen, Angew. Chem. Int. Ed.,
/6 1999, 38, 1815-1819; Angew. Chem., 1999, 111, 1932-1936.
4/6
/6
4/4
/4/
4
N. Moliner, C. Munoz, S. Letard, X. Solans, N. Menendez, A.
Goujon, F. Varret and J.A. Real, Inorg. Chem., 2000, 39, 5390-5393.
M. Kondo, M. Shimamura, S. Noro, S. Minakoshi, A. Asami, K. Seki
and S. Kitagawa, Chem. Mater., 2000, 12, 1288-1299.
3/5 L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
/5 CrystEngComm, 2003, 5, 190-199.
2D inclined (other)
[Ni(azpy)2(NO3)2]2[Ni2(azpy)3(NO3)4] Two sorts of nets - (6,3) nets and
(4,4) nets showing inclined
.4CH2Cl2, azpy = trans-4,4'interpenetration. (6,3) nets show
azobis(pyridine)
3-fold intptn, while (4,4) nets
show 2-fold.
2/3 L. Carlucci, G. Ciani and D.M. Proserpio, New J. Chem., 1998, 22,
1319-1321.
23
[M(bipy)2(NO3)2].3naphthalene, M =
Co, Ni
(4,4) M/bipy sheets interptd by
2/2 K. Biradha, K.V. Domasevitch, C. Hogg, B. Moulton, K.N. Power
(6,3) naphthalene sheets (edge to
and M.J. Zaworotko, Cryst. Eng., 1999, 2, 37-45. (cf. K. Biradha,
face stacking), where the trigonal
K.V. Domasevitch, B. Moulton, C. Seward and M.J. Zaworotko,
node is take as the centre of
Chem. Commun., 1999, 1327 (above); K. Biradha, A. Mondal, B.
gravity of three neighbouring
Moulton and M.J. Zaworotko, J. Chem. Soc., Dalton Trans., 2000,
molecules (otherwise each
3837-3844, for related arene adducts). See also K. Biradha and M.
naphthalene has four
Fujita, Chem. Commun., 2001, 15-16 for related structures.
neighbours). Each type of sheet is
2-fold intptd.
2D inclined and parallel
[AgL2]SbF6, L = 3-cyanophenyl 4cyanobenzoate
Layers of 2-fold parallel
interpenetrating (4,4) sheets,
which show 2-fold(?) inclined
interpenetration.
2/2 K.A. Hirsch, S.R. Wilson and J.S. Moore, Chem. Commun., 1998, 13=4• 14.
(8, 3) 3D net.
2•
X. Cieren, J. Angenault, J.-C. Courtier, S. Jaulmes, M. Quarton and
F. Robert, J. Solid State Chem., 1996, 121, 230-235; J. Angenault, X.
Cieren, G. Wallez and M. Quarton, J. Solid State Chem., 2000, 153,
55-65.
Two 82.10 3D nets.
2
J.-C. Dai, X.-T. Wu, Z.-Y. Fu, S.-M. Hu, W.-X. Du, C.-P. Cui, L.-M.
Wu, H.-H. Zhang and R.-Q. Sun, Chem. Commun., 2002, 12-3.
Various soft matter (surfactant-water
systems, block copolymers, liquid
crystals).
Ag2(2,3-Me2pyz)3(SbF6)2
See also ‘Misc related’ section.
2
Racemic pair.
2•
[Ag(hex)](PF6).H2O
Two interpenetrating (10, 3)-a
2•
nets, one composed of the
Ag(hex) net, the other formed by
hydrogen-bonding between the
PF6 ions and the H2O molecules;
racemic pair.
X. Zeng, G. Ungar and M. Imperor-Clerc, Nature Materials, 2005, 4,
562-567 and references therein; S.T. Hyde, Curr. Opin. Solid State
Mater., 1996, 1, 653-662, and references therein.
L. Carlucci, G. Ciani, D.M. Proserpio and A. Sironi, Chem.
Commun., 1996, 1393.
L. Carlucci, G. Ciani, D.M. Proserpio and A. Sironi, J. Am. Chem.
Soc., 1995, 117, 12861.
3D (8, 3)
MTi2(PS4)3, M = Na, Ag
3D 82.10-a (or LiGe)
[Ph3PCH2Ph][Cd(tp)Cl].2H2O, tp =
terephthalate
3D (10, 3)-a (or SrSi 2, srs)
24
Cyanamide, NH2CN
RhBi4
Eglestonite, [(Hg2)3O2H]Cl3
Zn(tpt)2/3(SiF6)(H2O)2(MeOH)
Ni3(btc)2(py)6(eg)6.~3eg.~4H2O, btc =
1,3,5-benzenetricarboxylate (TMA), py
= pyridine, eg = ethylene glycol, and
related species with 4-picoline, and with
Co
Ni3(btc)2XmYn.guest, btc = 1,3,5benzenetricarboxylate (TMA), X =
pyridine, 3-picoline or 4-picoline, Y =
ethylene glycol, 1,2-propanediol, 2,3butandediol, 1,2,-hexanetriol or
glycerol, m = 6, n = usually 3 or 6
Ni3(btc)2(py)6(1,4-bd)4(µ-1,4bd).2(1,4-bd), btc = 1,3,5benzenetricarboxylate (TMA), py =
pyridine, 1,4-bd = 1,4-butanediol
H-bonded; racemic pair. If N
atoms nodes, then two (10,3)-a
nets; if whole molecule node, the
diamond nets.
Two enatiomorphic 4-connected
32.104 (lcv) nets which can be
related to (10,3)-a.
If ignore H-bonds between nets,
then four (10,3)-a nets.
Otherwise, two 4-connected nets
with %-Si (gsi) topology.
Four of each enantiomer.
2•
Four nets of same hand. Ni acts
as 2-connector.
4•
Two nets of same hand. Ni acts
as 2-connector.
2
C.J. Kepert, T.J. Prior and M.J. Rosseinsky, J. Am. Chem. Soc., 2000,
122, 5158-5168; T.J. Prior and M.J. Rosseinsky, Inorg. Chem., 2003,
42, 1564-1575; D. Bradshaw, T.J. Prior, E.J. Cussen, J.B. Claridge
and M.J. Rosseinsky, J. Am. Chem. Soc., 2004, 126, 6106-6114.
4
T.J. Prior and M.J. Rosseinsky, Inorg. Chem., 2003, 42, 1564-1575.
2
V.M. Russell, D.C. Craig, M.L. Scudder and I.G. Dance,
CrystEngComm, 2000, 3.
2
X.-H. Bu, K. Biradha, T. Yamaguchi, M. Nishimura, T. Ito, K.
Tanaka and M. Shionoya, Chem. Commun., 2000, 1953-4.
M. Tadokoro, T. Shiomi, K. Isobe and K. Nakasuji, Inorg. Chem.,
2001, 40, 5476-8.
Four nets of same hand. Ni acts
as 2-connector. However, 1,4butanediol actually cross-links
nets into two 3-connected
(62.10)(6.122) nets.
(Ph3MeP)2[NaCr(ox)3]
One net is coord. net, other is net
of cations held together by
phenyl embraces. Opposite
hands.
Ag3L2(NO3)3.solv, L =
A net of either hand - i.e.
racemic. Ligand related to HAT.
diquinoxalino[2,3-a:2',3'-c]phenazine
Cs[Ni(Hbim)3]2(nPr4N).MeOH, H2bim A net of either hand; H-bonded
nets.
= 2,2'-biimidazole
2•
4•
8•
2
M.A. Brook, R. Faggiani, C.J.L. Lock and D. Seebach, Acta
Crystallogr., Sect. C, 1988, 44, 1979-81; B.H. Torrie, R. von Dreele
and A.C. Larson, Molec. Phys., 1992, 76, 405-410; C.L. Christ, Acta
Crystallogr., 1951, 4, 77.
Y. Grin, U. Wedig and H.G. von Schnering, Angew. Chem. Int. Ed.
Engl., 1995, 34, 1204, and references therein; G.S. Zhdanov, Trudy
Inst. Krist., Akad. Nauk SSSR, 1954, 10, 99-116.
Structural Inorganic Chemistry, 5th edn., A.F. Wells, Oxford
University Press, 1983, 1158; K. Mereiter, J. Zemann and A.W.
Hewat, Am. Mineral., 1992, 77, 839-842; K. Mereiter and J. Zemann,
Tschermaks Mineral. Petrogr. Mitt., 1976, 23, 105-115.
B.F. Abrahams, S.R. Batten, H. Hamit, B.F. Hoskins and R. Robson,
Chem. Commun., 1996, 1313.
C.J. Kepert and M.J. Rosseinsky, Chem. Commun., 1998, 31-2; C.J.
Kepert, T.J. Prior and M.J. Rosseinsky, J. Am. Chem. Soc., 2000, 122,
5158-5168; T.J. Prior and M.J. Rosseinsky, Inorg. Chem., 2003, 42,
1564-1575.
25
Cs[MnCp3], Cp = cyclopentadienyl
One net of each hand.
2
Me4bpz.CHCl3, Me4bpz = 3,3',5,5'tetramethyl-4,4'-bipyrazole
%-Me4bpz and 3Me4bpz.MeOH,
Me4bpz = 3,3',5,5'-tetramethyl-4,4'bipyrazole
La2(BTA)6(4,4'-bpdo)1.5 .1.5H2O, BTA
= benzoyltrifluoroacetone, 4,4'-bpdo =
4,4'-bipyridinedioxide
H-bonded nets; two pairs of
opposite chirality.
H-bonded nets; three pairs of
opposite chirality.
4
6
Nodes are La2 dimers. Topology 2
not recognised in paper, and
paper claims four interpenetrating
nets and not two.
M2(tpt)2(NCS)4(BzOH)2.4BzOH.H2O,
2
M = Fe, Co, tpt = 2,4,6-tris(4-pyridyl)1,3,5-triazine, BzOH = benzyl alcohol
Ag3L2(PF6)3, L = tris(2Highly disordered nets.
4
pyridylmethyl)cyclotriguaiacylene
Cu(H3TMT)X, H3TMT = 2,4,6Racemic interpenetration.
2
trimercaptotriazine, X = Cl, Br, I
AgLBF4, L = 5-(4Racemic pair.
2
ethynylpyridine)pyrimidine
(ZnI2)3(tpt)2(G).solvents, tpt = 2,4,6Templated by presence of G;
2
otherwise (10,3)-b nets formed
tris(4-pyridyl)-1,3,5-triazine, G =
(see below).
triphenylene or perylene
t-BuPI4
2
Nets held together by I...I
contacts between RPI3+ and Inodes.
M(dtc)3.3CuI, M = Co, Rh, dtc =
2
dithiocarbamato
NaYbCp3, Cp = C5H5
Yb, Na nodes linked by Cp pi
bridges.
2
Cu2(NCS)4(bpm), bpm = bipyrimidine
2
Cu2(form)2L2(Cu2X2), form = formato, Cu2X2 nodes.
L = ammonioallyl, X = Cl, Br
2
S. Kheradmandan, H.W. Schmalle, H. Jacobsen, O. Blacque, T. Fox,
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26
CuCl(rub)1.5 (H2O)0.45 , rub = rubeanic
acid
TaPS6, Ta4P4S29 and TaPS6Se
Fe(CO)4(HgSCN)2
#-Ag 3BO3
MTe3O8, M = Hf, Sn, Ti
(Winstanleyite), Zr
K(GaTe6O14)
2
P atoms disordered over two sites 2
in TaPS6Se, but same nets
generated if only take major (or
minor) positions. If Ta-Ta
dinuclear units in TaPS6 taken as
nodes, then diamond topology.
Hg2Fe(CO)4 clusters as nodes
2
gives diamond nets; Hg as nodes
gives (10,3)-a.
With B, O nodes, topology is 3- 2
connected (10,3)-a net; if BO3
units nodes, the #-Po.
2
2
(H3O)(SbF6)
If nodes are 3-connecting O and
3-connecting Te3O6 triangles,
then topology is (10,3)-a. If Te
atoms nodes, then bimodal 3connected net with (153)(3.152)3
topology.
H-bonded nets.
[C(NH2)3]Cl
H-bonded nets.
2
Links between nets.
2•
3D (10, 3)-b (or ThSi 2, ths)
Neptunite, LiNa2KFe2Ti2(Si4O12)2
Zn3(tpt)2Cl6, tpt = 2,4,6-tri(4-pyridyl)1,3,5-triazine
Zn3(tpt)2I6.solv, tpt = 2,4,6-tri(4pyridyl)-1,3,5-triazine
2
2•
2
A. Mosset, M. Abboudi and J. Galy, Z. Kristallogr., 1983, 164, 171180.
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27
[Ag2(pyz)3](BF4)2
CrP3S9+x (x'0.25)
Ag(4,4'-bipyridine)(NO3)
3•
Bridging, chelating S2PS2PS2
links, octahedral Cr.
T-shaped silvers - the 'stem' of
the T is a Ag-Ag bond.
3•
3•
Ag(TEB)(CF3SO3), TEB = 1,3,5-tris(4- Polymorph of another structure.
ethynylbenzonitrile)benzene
6•
Cu(bipy)3/2.X, X = NO3.(H2O)5/4 or
(ClO4).H2O
6•
Ag(isonicotinamide)3(X), X = BF4,
ClO4
Ag2HgO2
[AgL(CF3SO3)].2C6H6, L = tris(4cyanophenyl)methanol
{[Rh2(DAniF)2]2(O2CCH2CO2)2}3
[tpt]4.4.1CH2Cl2.Et2O.H2O, DAnif =
N,N'-di-p-anisylformamidinate
(-[Cr(Hbiim)(H2biim)2]SO4.H2O and
[Fe(H2biim)3]CO3.MeOH, H2biim =
biimidazole
[Co(bipy)1.5 ].1.5 benzene
Zn(Hbtc)(bpy)(H2O).3H2O, H3btc =
1,3,5-benzenetricarboxylic acid, bpy =
4,4'-bipyridine
2-aminoethane-1,1,2-tricarbonitrile
Ag4L2(NO3)4.MeCN.2H2O, L = N'N'bis[1-(pyrazine-2-yl)ethylidene]benzil
dihydrazone
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AgL3 complexes linked by Hbonding.
Ag-Ag and Ag-Hg contacts
between nets.
Topology noted but not the
existance of 4 intptg nets.
Two interpenetrating (10,3)b nets
(topology not recognised as
(10,3)b) in which tpt pairs, acting
as the trigonal nodes, bridge Rh4
dimers of dimers.
H-bonded nets.
2
3
K. Larsson and L. Ohrstrom, CrystEngComm, 2003, 5, 222-225.
Other supramolecular isomers of
this with different topology.
3
H. Gudbjartson, K. Biradha, K.M. Poirier and M.J. Zaworotko, J. Am.
Chem. Soc., 1999, 121, 2599-2600.
Y.-F. Zhou, B.-Y. Lou, D.-Q. Yuan, Y.-Q. Xu, F.-L. Jiang and M.-C.
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3
4
2
2
H-bonded nets.
2
Racemic pair.
2
V.A. Tafeenko, K.A. Paseshnichenko, O.V. Ershov, A.V. Eremkin
and L.A. Aslanov, Acta Crystallogr., Sect. C, 2005, 61, o434-o437.
Y. Bai, C. Duan, P. Cai, D. Dang and Q. Meng, Dalton Trans., 2005,
2678-2680.
28
{Mn(N3)2}2L, L = 4,5-diazafluoren-9one azine
3
Cu2(oxpn)(Cu(CN)2)2, H2oxpn = N, N'bis(3-aminopropyl)oxamide)
Ga2Cl4(dioxane)2
3
Cs[AgZn(SCN)4]
2
H2Te2O3F4
{Cu[(NH2)2CS]3}X, X = Cl, Br
2
H-bonded nets; (10,3)-b if Te
nodes, diamond if dimeric
molecules nodes.
1D chains linked by H-bonds.
3
C.-M. Liu, S. Gao, D.-Q. Zhang, Y.-H. Huang, R.-G. Xiong, Z.-L.
Liu, F.-C. Jiang and D.-B. Zhu, Angew. Chem. Int. Ed., 2004, 43,
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329-340.
2
P. Bombicz, I. Mutikainen, M. Krunks, T. Leskela, J. Madarasz and
L. Niinisto, Inorg. Chim. Acta, 2004, 357, 513-525; Y. Okaya and
C.B. Knobler, Acta Crystallogr., 1964, 17, 928-930.
4
L. Ohrstrom, K. Larsson, S. Borg and S.T. Norberg, Chem. Eur. J.,
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4927-4935.
S.R. Halper and S.M. Cohen, Inorg. Chem., 2005, 44, 486-488.
Other 3D (10, 3)
Co(H2biim)3.0.8DMF.0.5H2O, H2biim Four H-bonded nets. Original
paper says (10,3)-b, but actually
= biimidazole
(10,3)-d (see later paper).
Co(NO3)2L1.5 •H2O, L = 1,4-bis(3(10,3)-d.
pyridyl)-2,3-diaza-1,3-butadiene
Co(4-pyrdpm)3Ag(CF3SO3).solv, Fe(4- (10,3)-d.
pyrdpm)3AgBF4.solv, 4-pyrdpm = 5-(4pyridyl)-4,6-dipyrrinato
Cs[Cu3(CN)3X], X = Cl, Br
Binodal nets. Nets chiral but
racemic interpenetration.
)-Ag 3BO3
With B, O nodes, topology is 3connected binodal (10,3) net; if
BO3 units nodes, the #-Po.
3D (12, 3)
4
2
2
2
A.M. Chippindale, S.J. Hibble and A.R. Cowley, Inorg. Chem., 2004,
43, 8040-8048.
M. Jansen and G. Brachtel, Z. Anorg. Allg. Chem., 1982, 489, 42-46.
29
Co(2,2'-bipy-4,4'(CO2)2)(H2O)2
Self-penetrating (12,3) net if both 2
metal and ligands are taken as
nodes. If CoL2 taken as node,
then quartz topology; two
interpenetrating nets missed by
authors (see L. Carlucci, G. Ciani
and D.M. Proserpio, Coord.
Chem. Rev., 2003, 246, 247).
T. Schareina, C. Schick, B.F. Abrahams and R. Kempe, Z. Anorg.
Allg. Chem., 2001, 627, 1711-3.
ZnCl(4-ptz), 4-ptz = 5-(4pyridyl)tetrazolate
Binodal, (6.102 )(62 .10).
2
CuL, L = 2-ethylimidazolate
Binodal, (4.8.12)2(8.12.14)
3
Cu(mtz), Hmtz = 3,5-dimethyl-1,2,4triazole
[Co(Hbiim)2(H2biim)]2(pO2CC6H4CO2H)2.H2O, H2biim = 2,2biimidazole
4.8.16 topology.
2
R.-G. Xiong, X. Xue, H. Zhao, X.-Z. You, B.F. Abrahams and Z.
Xue, Angew. Chem. Int. Ed., 2002, 41, 3800-3803; Angew. Chem.,
2002, 114, 3954-3957.
X.-C. Huang, J.-P. Zhang, Y.-Y. Lin and X.-M. Chen, Chem.
Commun., 2005, 2232-2234.
J.-P. Zhang, S.-L. Zheng, X.-C. Huang and X.-M. Chen, Angew.
Chem. Int. Ed., 2004, 43, 206-209.
K. Larsson and L. Ohstrom, CrystEngComm, 2004, 6, 354-359.
3D 3-connected other
Co3(IDC)2(4,4'bipyridine)(H2O)4.2H2O, H3IDC =
imidazole 4,5-dicarboxylic acid
Mn6(ashz)6(DMF)2(bpea)2, ashz = Nacetylsalicylhydrazidate, bpea = 1,2bis(4-pyridyl)ethane
[BiCl3]2C6Me6
Cu2Br2L2, L = 2,2'-dipyridyldiselenide
Sb(NH4)(D-tatrate)
5 interpenetrating 3-connected H- 5
bonded nets with
(4.122)(4.122)(123) topology
crosslinked into self-penetrating
net via a water bridge.
Not sure of topology, but nodes
2
are IDC ligand and one of the
two types of Co atom.
(4.8.10) or lvt-a topology.
3
Bi nodes linked by Bi-Cl-Bi and
Bi-C6Me6-Bi bridges. Topology
is (4.142)-a or dia-f topology. If
Bi4Cl4 moieties treated as nodes,
then probably becomes diamond
topology.
Topology is (4.142)-a or dia-f
topology.
Topology is (4.142)-b or dia-g.
Y.-L. Wang, D.-Q. Yuan, W.-H. Bi, X. Li, X.-J. Li, F. Li and R. Cao,
Cryst. Growth Des., 2005, 5, 1849-1855.
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2
A. Schier, J.M. Wallis, G. Muller and H. Schmidbaur, Angew. Chem.
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2
C.O. Kienitz, C. Thone and P.G. Jones, Z. Naturforsch., Teil B, 2000,
55, 587-596.
G.A. Kiosse, N.I. Golovastikov, A.V. Ablov and N.V. Belov, Dokl.
Akad. Nauk SSSR, 1967, 177, 329-332.
2
30
Ni3(btc)2(py)6(1,4-bd)4(µ-1,4bd).2(1,4-bd), btc = 1,3,5benzenetricarboxylate (TMA), py =
pyridine, 1,4-bd = 1,4-butanediol
Ta2P2S11
[Ag6Cl(atz)4]OH.6H2O, Hatz = 3amino-1,2,4-triazole
[Ag6Cl(atz)4]OH.xH2O, Hatz = 3amino-1,2,4-triazole, x ! 2
Glyoxal 4-nitrophenylhydrazone
Ag(CNO)
K(GaTe6O14)
3D 4-connected diamond
2
Four nets of same hand. Ni acts
as 2-connector. However, 1,4butanediol actually cross-links
nets into two 3-connected
(62.10)(6.122) nets.
Pentanodal nets with
(6.8.12)4(62.10) topology.
4.142 (dia-f) topology. Upon
partial desolvation, a new phase
with 6 (!) nets is formed (see
below)!
4.142 (dia-f) topology. Formed
from the partial desolvation of a
5-fold interpenetrating structure
(see above)!
Nets defined by N-H...O and CH...O interactions. Molecules are
nodes; not sure of topology.
With Ag and C nodes, it’s 3connected (4.122) nbo-a
topology; with Ag2(CNO)2
nodes, it’s 4-connected NbO.
If nodes are 3-connecting O and
3-connecting Te3O6 triangles,
then topology is (10,3)-a. If Te
atoms nodes, then bimodal 3connected net with (153)(3.152)3
topology.
2
T.J. Prior and M.J. Rosseinsky, Inorg. Chem., 2003, 42, 1564-1575.
2
M. Evain, S. Lee, M. Queignec and R. Brec, J. Solid State Chem.,
1987, 71, 139-153.
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5
6
J.-P. Zhang, Y.-Y. Lin, W.-X. Zhang and X.-M. Chen, J. Am. Chem.
Soc., 2005, 127, 14162-14163.
3
C. Glidewell, J.N. Low, J.M.S. Skakle and J.L. Wardell, Acta
Crystallogr., Sect. C, 2005, 61, o493-o495.
2
D. Britton, Acta Crystallogr., Sect. C, 1991, 47, 2646-2647; D.
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2
K.M. Ok and P.S. Halasyamani, Chem. Mater., 2001, 13, 4278-4284.
31
Various organic polymers.
Diamond (proposed). See also
‘Misc related’ section.
2
or
3•
Two lipid-water phases
M2O, (M = Cu, Ag, Pd, Zr, Pt), Au2S,
Ag2-xAuxS
See also ‘Misc related’ section.
2•
Note that although the structure
2•
of Pb2O was assigned as being
isomorphous with Cuprite
(Cu2O), based on powder X-ray
data, in a 1926 paper, later papers
conclude that Pb2O does not
exist.
CaWO4 (scheelite) and related
structures; ZrSiO4 (zircon) and related
structures.
Diamond nets can be constructed 2•
if only consider 4 shorest
contacts. Approx. 340 codes in
ICSD.
D.B. Alward, D.J. Kinning, E.L. Thomas and L.J. Fetters,
Macromolecules, 1986, 19, 215; H. Hasegawa, H. Tanaka, K.
Yamasaki and T. Hashimoto, Macromolecules, 1987, 20, 1651; D.M.
Anderson and E.L. Thomas, Macromolecules, 1988, 21, 3221; E.L.
Thomas, D.B. Alward, D.J. Kinning, D.C. Martin, D.L. Handlin, Jr.
and L.J. Fetters, Macromolecules, 1986, 19, 2197; E.L. Thomas,
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1964, 9, 413-415; T. Yamaguti, Proc. Phys.: Math. Soc. Jpn., 1938,
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ICSD entry 28838. For "non-existence" of Pb2O, see: M. Le Blanc
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Sect. B, 1978, 34, 259; D. de Waal and K.-J. Range, Z. Naturforsch.,
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32
NH4XO4, X = I, Re
H-bonded nets.
2
MO.2B2O3, M = Li2, Mg, Zn, Cd, Mn,
Fe, Co, Ni, Hg
M links 2 nets in Li ??? Others??
2•
#-Na 2O.3B2O3
M2O.4B2O3 M = Ag, Na, Ba1/2
Na links 2 nets ???
Ag links 2 nets ???
2•
2•
)-M 2O.4B2O3 M = Ag, Na
M links nets??
2
W. Levason and M. Webster, Acta Crystallogr., Sect. C, 1999, 55,
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33
M2O.5B2O3, M = K (#- and )- forms),
Rb (#- and )- forms), Cs ()- and %forms), Tl
2•
LiAlB2O5
2
Li2(AlB5O10)
2
K2[PdSe10]
Cs2PdSe8
Some high pressure forms of ice (Ice
VII and VIII)
2,6-dimethylideneadamantane-1,3,5,7tetracarboxylic acid
Each net has different
composition.
Diamond topology not
recognised. Each net has same
composition. Commented upon
in later paper by MGK.
Diamond nets - Ice VII is
orientationally disordered, while
Ice VIII is not.
2•
H-bonded; four structures with
different guests, one of which
interpenetrates asymmetrically.
2•
2
2•
J. Krogh-Moe, Acta Crystallogr., 1965, 18, 1088-1089; J. KroghMoe, Acta Crystallogr., Sect. B, 1972, 28, 168-172; J. Krogh-Moe,
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34
Ln2(C6H2O4)3.24H2O, Ln = Ce, La,
Gd, Y, Yb, Lu
Diamond net with one link being
a H-bonded water cluster. Hbonding between nets.
K2M[NC5H3(CO2)2-2,3]2, M = Mn, Zn
[Sn5S9O2][HN(CH3)3]2
2•
S linked tetrahedral Sn10S20O4
clusters.
Si(NCN)2
CBr4.Hexamethylenetetramine
2•
2•
2•
Net linked by N-Br interactions.
2•
Tetrakis(4-nitrophenyl)methane.G, G = Net held together by weak CTHF, dioxane, nitrobenzene, 4H...O and &...& interactions.
bromoanisole, anisole, phenetole, pxylene, shlorobenzene
Si(C5H4NO)4.G, G = 4CH3CO2H,
H-bonded nets
4CH3CH2CO2H, CH3(CH2)3CO2H,
0.5CH3(CH2)3CO2H.CH3CO2H
2
[M(CO)3(µ3-OH)]4 + L, M = Mn or Re, L H-bonds between tetrahedral
clusters.
L = H-bonded bridging ligand
2,
3,
or
4•
SCd8(SCH(CH3)C2H5)12(CN)2
2•
Cd17S4(SCH2CH2OH)26
Clusters forming nodes.
2•
2•
B.F. Abrahams, J. Coleiro, B.F. Hoskins and R. Robson, Chem.
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35
M(CN)2, M = Zn, Cd, Be, Mg
2•
MGa(CN)4, M = Li, Cu
2•
M[B(CN)4], M = Ag, Cu, Na, Li, NH4,
Rb, Cs, Tl, K
For Rb, Cs, Tl, K, this only
applies if only shortest M-N
interactions taken into account,
and next shortest (ca. 0.1-0.2 Å
longer) ignored. Otherwise, a
single 4,8-connected net.
2
Li[Al(CN) 4 ]
Li[Co(CO)4]
Isomorphous with Zn(CN)2.
2
2•
Mn(CN)2
Proposed on basis of XRPD, etc.
2
Cu(4-cyanopyridine)2(ClO4)
Cd(en)Cd(CN)4
2•
Four-connected net which can be 2•
related to a diamond net where
the nodes are Cd(CN)4 squares.
With Cd nodes, topology is
(43.62.8) or gismondine (gis).
Nodes are B/S clusters. See
2•
below also.
Li5B7S13
H.S. Zhdanov, C. R. Acad. Sci. URSS (or Dokl. Akad. Nauk?), 1941,
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Kristallogr., 1983, 162, 138.
J.L. Manson, W.E. Buschmann and J.S. Miller, Angew. Chem. Int.
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B.F. Hoskins, J. Liu and R. Robson, unpublished results.
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74, 825).
F. Hiltmann, P. zum Hebel, A. Hammerschmidt and B. Krebs, Z.
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36
Na6B10S18, Li6+2x [B10S18]Sx,
Li5B7S13, Ag6B10S18, Li5.88 B10S18
Nodes are B/S clusters. See
above also.
2
Cu(3,3'-bipy)2X, X = BF4, PF6
2•
[Me2NH2]6In10S18
[Et2NH2]6In10S18
In10S2010- act as tet. centres.
In10S2010- act as tet. centres.
Isomorph. with above structure.
[pyrollidine]6In10S18
In10S2010- act as tet. centres.
Isomorph.? with above structure.
(Ph3P)2(Cl)(CO)Os{Si(OH)2O(OH)2Si CSD refcode LADDEZ; Net
defined by 6PE interactions.
}Os(CO)(Cl)(PPh3)2
[Cd(py-CO2)2(EtOH)][EtOH]
2•
2
CuCN(pyz)
2
CuCN(Mepyz)
[Cd(isonicotinate)2(EtOH)][EtOH],
[Cd(isonicotinate)2(H2O)][pyrazine]
[Cd(isonicotinate)2(H2O)][DMF]
Interpenetration and diamond
topology missed by authors.
Interpenetration missed by
authors.
2
2
2
2
2
2
O. Conrad, C. Jansen and B. Krebs, Angew. Chem. Int. Ed., 1998, 37,
3208-18; Angew. Chem., 1998, 110, 3396-3407; C. Puttmann, P. zum
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1587-1594.
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37
ZnI2, *-GeS 2, BeCl2, BeI2, ZnBr2, HgI2 Two nets with M4X6
(one orange phase)
adamantane-like clusters as
tetrahedral centres.
2
M(NH2)2, M = Be, Mg, Mn, Zn
Two nets with ZnI2 structure. Hbonds between nets.
2
Li(dioxane)2.5 TaCl4S.1/2dioxane
Diamond nets if take into account 2
S...S interaction of 3.561 Å.
2
[AgL]BF4.1.5C6H6, L = cyanotris(4cyanophenyl)methane
)-Ca3Ga2N4
Na2[SnAs2]
[Cu(en)2]Cu7Cl11
Cu4I4(µ-Me612Se3)2, Me612Se3 =
3,3,7,7,11,11-hexamethyl-1,5,9triselanacyclohexadecane
Cd4In16S33.(H2O)20(C10H28N4)2.5
Ignoring Ca... N interactions, two
interpenetrating nets with
adamantane-like Ga4N6 clusters
linked by four further bridging N
atoms.
Ignoring Na cations, two
interpenetrating netws with
adamantane-like Sn4As6 clusters
as the tetrahedral nodes.
Two interpenetrating diamondoid
Cu/Cl nets. Long (2.7 - 2.8 Å)
Cu... Cl interactions to Cu(en)22+
cations cross-link nets.
Two interpenetrating diamondoid
nets, not mentioned in original
paper.
2
Tetrahedral nodes are
Cd4In16S352- clusters sharing S
atoms.
2
P.H. Fourcroy, D. Carre and J. Rivet, Acta Crystallogr., Sect. B,
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2
M. Asbrand and B. Eisenmann, Z. Naturforsch., 1993, 48B, 452-456.
2
J.R.D. DeBord, Y. Lu, C.J. Warren, R.C. Haushalter and J. Zubieta,
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2001, 123, 11506-7 for analogous structures with different cations
and Zn, Mn or Co in place of Cd.
2
38
Various cation-templated
Zn/Ga/In/Cu/Sn/Ge chalcogenides
Tetrahedral nodes are clusters.
2
M(LMn(CO)3)2, L = benzoquinone, M
= Mn, Co, Zn
2
[Mn(hfac)2]2(tetranitroxide), hfac =
hexafluoroacetylacetonate,
tetranitroxide = tetrakis-[4-(N-tertbutyl-N-oxyamino)phenyl]methane
Zn(ADC)2.(HTEA)2, ADC =
acetylenedicarboxylate, TEA =
triethylamine
Zn2(ATB)(H2O).(H 2O)3(DMF)3, ATB
= adamantanetetrabenzoate
Ag(bpp)2(X), bpp = 1,3-bis(4pyridyl)propane, X = BF4, ClO4
[CuL2(H2O)2]X, X =
(ClO4)(OH)(H2O)2.5 or
(PF6)2(H2O)1.25 , L = 2,5-bis(4pyridyl)-1,3,4-oxadiazole
NH4(bpedo)2PF6.3H2O, bpedo = trans- H-bonded nets.
bis(4-pyridyl)ethylene dioxide
M(im)2, M = Hg, Cd, Him = imidazole Solved by PXRD initially, then
single crystal for Cd. Normal
mode.
2
Cd(bpp)(NO2-BDC)(H2O).0.25H2O,
bpp = 1,3-bis(4-pyridyl)propane, NO2BDCH2 = 5-nitro-1,3benzenetricarboxylic acid
[Zn(DPT)2(H2O)2]
[Zn(DPT)2(MeCN)2](ClO4)4.2MeCN,
DPT = 2,4-di-(4-pyridyl)-1,3,5-triazine
2
N. Zheng, X. Bu, B. Wang and P. Feng, Science, 2002, 298, 23662369; C. Wang, X. Bu, N. Zheng and P. Feng, J. Am. Chem. Soc.,
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2
J. Kim, B. Chen, T.M. Reineke, H. Li, M. Eddaoudi, D.B. Moler, M.
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2
J. Kim, B. Chen, T.M. Reineke, H. Li, M. Eddaoudi, D.B. Moler, M.
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2
2
2
2
2
N. Masciocchi, G.A. Ardizzoia, S. Brenna, F. Castelli, S. Galli, A.
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39
KH2PO4 (KDP)
[Ag(C25H20N2O2)2]SbF6
Two interpenetrating nets if only 2
count shortest K-O interactions
(e.g. 2.834 Å) and ignore second
shortest (e.g. 2.900 Å). Probably
better described as a single
diamond net of H-bonded H2PO4
anions (e.g. O...O = 2.498 Å)
with K counterions!
2
Cd(HBTC)(TMD)(H2O).4.5H2O,
H3BTC = 1,3,5-benzenetricarboxylic
acid, TMD = 4,4'trimethylenedipyridine
Ag(malononitrile)2BF4
2
Asymmetric interpenetration.
2
Ca1.5 Li11(In22Li4S42).44H2O
Large cluster as node.
2
[{Cu(acac)(phen)}2(bpp)](ClO4)2.6H2
O, phen = 1,10-phenanthroline, bpp =
1,3-bis(4-pyridyl)propane
Nodes are pairs of dimeric
complexes twisted around each
other and held together by
lipophilic interactions. Nodes
then connected by pi-pi
interactions.
2
Ag2(pcp)2(HO2CC4F8CO2)2.toluene,
pcp = [2.2]paracyclophane
M[Ru(acac)2(CN)2]2, M = Mn, Co
LiM2(NCN)X3, M = Sr, Eu, X = Br, I
2
2
One net has adamantine-like
Li4X6 cages connecting through
shared Li atoms, the other
contains cube-like M4N4 cages
connected by bridging NCN
ligands. Although the two nets
have different SBU clusters, the
overall topology of both is
diamond with the clusters as
nodes.
2
S. Endo, T. Chino, S. Tsuboi and K. Koto, Nature, 1989, 340, 452455.
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40
Ag(tpb)(NO3)(MeOH), tpb = 3,3',5,5'tetrakis(4-pyridyl)bimesityl
(MeLi)4(tmeda)2, tmeda = N, N, N',N'tetramethylethylendiamine
[Tl(t-BuO)3Sn]2Mo(CO)4
If ligand considered as
2
tetrahedral node, then topology is
diamond. If ligand considered as
two linked 3-connecting nodes,
then becomes a 3,4-connected net
with Wells' (8,3/4)-b (or
(83)2(86)) topology.
If Li atoms nodes, then topology 2
is (33.123) dia-a topology. If
Li4Me4 clusters nodes, then
diamond.
2
Mo2(OAc)4.0.5hmt.0.5CH2Cl2, hmt = Abstract says topology PtS, but
actually diamond.
hexamethylenetetraamine
[Et4N]6[Na14Mo24P17O97(OH)31].xH2 Mo24 cluster nodes.
O
Cd2.75 L(H2O)7.1.5NO3.7H2O.MeOH,
H4L = N, N'-bis(phosphonomethyl)1,10-diaza-18-crown-6
SbCl3L, L = p-diacetylbenzene
2
Fe(CO)4(HgSCN)2
2
Hg2Fe(CO)4 clusters as nodes
gives diamond nets; Hg as nodes
gives (10,3)-a.
2
2
2
Cd(nic)2(H2O), Hnic = nicotinic acid
2
(SnMe3)3CrO4(OH)
2
Zn(HCN4)2
2
TaPS6
[Ir4(CO)8F2](Sb2F11)2
(NH4)3Cu4Ho2Br13 and
Rb3Cu4Tm2Br13
(10,3)-a topology, but if Ta-Ta
dinuclear units taken as nodes,
then diamond topology.
Ir cluster as node.
2
2
2
R. Natarajan, G. Savitha, P. Dominiak, K. Wozniak and J.N.
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41
(NH4)5Ce[Ni(NO2)6]2
2
NH4Br I and NH4I III
H-bonded nets.
2
(D2O)2(DF)3
H-bonded nets.
2
NH4[F(HF)3]
Cyanamide, NH2CN
H-bonded nets.
2
H-bonded; racemic pair. If N
2•
atoms nodes, then two (10,3)-a
nets; if whole molecule node, the
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M(AlCl4)2, M = Ca, Yb, Sr
2
CsHSO4
2
Tetrasodium 1,3,5,7Adamantanetetracarboxylate
Tetrahydrate
2,6-Dioxoadamantane-1,3,5,7tetracarboxylic acid (hydrate)
3,3-Bis(carboxymethyl) glutaric acid
("methanetetraacetic acid")
all-trans-cyclobutane-1,2,3,4tetracarboxylic acid
4,4',4'',4'''tetraphenylmethanecarboxylic acid
Cu(CN)(4-cyanopyridine)
H-bonded.
3•
O. Ermer and L. Lindenberg, Chem. Ber., 1990, 123, 1111.
H-bonded; contains acetic acid
guests.
H-bonded.
3•
O. Ermer and L. Lindenberg, Helv. Chim. Acta, 1988, 71, 1084.
3•
O. Ermer and A. Eling, Angew. Chem. Int. Ed. Engl., 1988, 27, 829.
H-bonded.
3•
H-bonded.
3•
O. Ermer and M. Schank, unpublished results (as referenced in O.
Ermer and L. Lindenberg, Helv. Chim. Acta, 1991, 74, 825).
B.F. Hoskins, A. Liang and R. Robson, unpublished results.
Ag2(OOC-(CH2)2-COO)
Ag4 cluster bridged by chelating
bridges.
3
3•
3•
D.T. Cromer and A.C. Larson, Acta Crystallogr., Sect. B, 1972, 28,
1052.
A. Michaelides, V. Kiritsis, S. Skoulika and A. Aubry, Angew. Chem.
Int. Ed. Engl., 1993, 32, 1495.
42
[Cd(mea)(dahxn){Ni(CN)4}].H2O, mea
= 2-Aminoethanol, dahxn = 1,6Diaminohexane
[Cu(DMTPN)2]X(DMTPN)(thf), X =
BF4, ClO4, DMTPN = 2,3dimethylterephthalonitrile
3•
H. Yuge, S. Nishikiori and T. Iwamoto, Acta Crystallogr., Sect. C,
1996, 52, 575.
3•
T. Kuroda-Sowa, M. Yamamoto, M. Munakata, M. Seto and M.
Maekawa, Chem. Lett., 1996, 349; T. Kuroda-Sowa, T. Horino, M.
Yamamoto, Y. Ohno, M. Maekawa and M. Munakata, Inorg. Chem.,
1997, 36, 6382-6389.
A.J. Blake, N.R. Champness, A.N. Khlobystov, D.A. Lemenovskii,
W.-S. Li and M. Schroder, Chem. Commun., 1997, 1339-1340. See
also L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, Chem. Eur.
J., 2002, 8, 1520-1526.
D.S. Reddy, D.C. Craig and G.R. Desiraju, J. Am. Chem. Soc., 1996,
118, 4090-4093; R. Thaimattam, D.S. Reddy, F. Xue, T.C.W. Mak,
A. Nangia and G.R. Desiraju, New. J. Chem., 1998, 22, 143-148.
D.S. Reddy, D.C. Craig and G.R. Desiraju, J. Am. Chem. Soc., 1996,
118, 4090-4093; A. Anthony, G.R. Desiraju, R.K.R. Jetti, S.S.
Kuduva, N.N.L. Madhavi, A. Nangia, R. Thaimattam and V.R.
Thalladi, Cryst. Eng., 1998, 1, 1-18.
Cu(L)2PF6, L = 2,7-diazapyrene
Unusual ('abnormal') mode of
3
interpenetration noted by Ciani et
al.
C(p-C6H4X)4, X = Br, I
Isomorphous structures of
3
alternating C and X4 'synthons' as
the tetrahedral nodes.
Alternating methane and CBr4
3?
tetrahedral centres, connected by
Br...Ph interactions; isomorphous
with the above structure.
However, in Cryst. Eng. paper
Desiraju says that there is no
interpenetration in this isomorphous may just mean has
diamond net.
Acentric nets.
3
Tetraphenylmethane.CBr4
Zn(py-CO2)2
Tetrakis(4-ethynylphenyl)methane
4-bromo and 4- ethynyl substituted
tetraphenylmethanes
[CuCN.Me3SnCN.pyz]
4-connecting nodes are
alternating methane and (C+CH)4 clusters held together by
C+C-H ...C+C interactions.
Isomorphous with above
structure held together by weak
intermolecular interactions.
Distorted because of different
length bridges.
3
O.R. Evans, R.-G. Ziong, Z. Wang, G.K. Wong and W. Lin, Angew
Chem. Int. Ed., 1999, 38, 536-8; Angew. Chem., 1999, 111, 557-9.
E. Galoppini and R. Gilardi, Chem. Commun., 1999, 173-4.
3
W. Guo, E. Galoppini, R. Gilardi, G.I. Rydja and Y-H. Chen, Cryst.
Growth Design, 2001, 1, 231-7.
3
E. Siebel, A.M.A. Ibrahim and R.D. Fischer, Inorg. Chem., 1999, 38,
2530-2532.
43
[CdL2.G2](NO3)2, L = pyCH2-C6F4CH2py, G = phenyl acetate, Nmethylaniline, toluene, #methylestyrene, m-xylene, omethoxyaniline, benzyl methyl ether,
biphenyl
UP4S12
Diamond nets; full structure
reported on phenyl acetate.
3
K. Kasai, M. Aoyagi and M. Fujita, J. Am. Chem. Soc., 2000, 122,
2140-2141.
U4+ bridged by P2S62- ligands.
3
C. Gieck, F. Rocker, V. Ksenofontov, P. Gutlich and W. Tremel,
Angew. Chem. Int. Ed., 2001, 40, 908-911.
Z.-M. Wang, B.-W. Sun, J. Luo, S. Gao, C.-S. Liao, C.-H. Yan and
Y. Li, Inorg. Chim. Acta, 2002, 332, 127-134.
T.-B. Lu and R.L. Luck, Acta Crystallogr., Sect. C, 2002, 58, m1524.
R.G. Kostyanovsky, K.A. Lyssenko, D.A. Lenev and I.A. Bronzova,
Tetrahedron: Asymmetry, 2002, 13, 2697-2701.
[Cu(pn)2][Mn(dca)4], pn = 1,3diaminopropane, dca = dicyanamide
NiL2, L = isonicotinate
3,7-Diazabicyclo[3.3.1]nonane-2,6dione-1,5-dicarboxamide
(NIPA)2.HEL, NIPA = 5nitroisophthalic acid, HEL =
hexahelicene
Zn(dimb)2(ClO4)2, dimb = 1,3di(imidazole-1-yl-methyl)-5-methylbenzene
Tetrakis(3,5-dihydroxyphenyl)silane.G,
G = 2.0 ethyl acrylate, 2.7 ethyl acetate,
3.3 THF, or 3.3 dioxolane
Cu(BCDC)2PF6, BCDC = N,N'-bis(4cyanophenyl)-(1R,2R)diaminocyclohexane
CuL(L1).2H2O, L = 1,1'-(1,4butanediyl)bis(imidazole), H2L1 =
fumaric acid
CuL2(H2O)(ClO4)2.solvate, L = 2,5bis(4-pyridyl)-1,3,4-oxadiazole
Cat.H2CTA, Cat = NH4+ , NH2NH3+ ,
OHNH3+, H3CTA = 1,3-cis,5-ciscyclohexanetricarboxylic acid
3
3
H-bonded nets. Normal
interpenetration, but two nets of
one chirality, one of the other.
Nets defined by O-H...O
hydrogen bonds in conjunction
with either C-H...O or &...&
interactions (both alternatives
give the same topology).
H-bonded nets. Weaker Hbonding interactions between
nets.
Normal mode.
3
3
O. Ermer and J. Neudorfl, Helv. Chim. Acta, 2001, 84, 1268-1313.
3
Y. Ma, W. Huang, J. Yao, B. Li, S. Gou and H.-K. Fun, J. Mol.
Struct., 2003, 658, 51-58.
3
O. Saied, T. Maris, X. Wang, M. Simard and J.D. Wuest, J. Am.
Chem. Soc., 2005, 127, 10008-10009.
3
S.P. Anthony and T.P. Radhakrishnan, Cryst. Growth Des., 2004, 4,
1223-1227.
3
J. Yang, J.-F. Ma, Y.-Y. Liu, S.-L. Li and G.-L. Zheng, Eur. J. Inorg.
Chem., 2005, 2174-2180.
3
J.-P. Ma, Y.-B. Dong, R.-Q. Huang, M.D. Smith and C.-Y. Su, Inorg.
Chem., 2005, 44, 6143-6145.
B.R. Bhogala, P. Vishweshwar and A. Nangia, Cryst. Growth Des.,
2005, 5, 1271-1281.
H-bonded nets defined by anions, 3
however cations also H-bond and
crosslink nets.
44
PI4[Al(OC(CF3)3)4]
Nets defined by I...F interactions. 3
Zn(beta-alaninato)2
3
Ag(MeCN)(N(NO2)2)
3
Cu3(CN)3(pyz)2
Paper says 2 nets, but actually 3.
3
[CN3H6]2[Cd(C4H4O4)2]
Paper says 2 nets, but actually 3.
3
CsCo(CO)4
Tetrakis[(4nitrophenoxy)methyl]methane
Pentaerythrityl tetrakis(4-bromobenzyl
ether)
Tetrakis[(4aminophenoxy)methyl]methane
Ag3CuS2 (Jalpaite)
H2Te2O3F4
3
Nets defined by C-H...O
interactions; phenyl embraces
between nets.
Nets defined by Br...pi
interactions.
Each molecule connected to 8
others via N-H...N interactions,
however can be regarded as a
diamond nets if the nodes
alternate between the central C
atoms and H-bonded square ring
motifs.
Abnormal interpenetration?
3
H-bonded nets; (10,3)-b if Te
nodes, diamond if dimeric
molecules nodes.
3
3
3
3
M. Gonsior, I. Krossing, L. Muller, I. Raabe, M. Jansen and L. van
Wullen, Chem. Eur. J., 2002, 8, 4475-4492.
C.-H. Ng, Z.-Y. Zhou, H.-K. Fun, S.-B. Teo, S.-G. Teoh, P. Naumov
and S.W. Ng, Main Group Metal Chem., 2001, 24, 747-748.
H.-G. Ang, W. Fraenk, K. Karaghiosoff, T.M. Klapotke, P. Mayer, H.
Noth, J. Sprott and M. Warchhold, Z. Anorg. Allg. Chem., 2002, 628,
2894-2900.
D.J. Chesnut, D. Plewak and J. Zubieta, J. Chem. Soc., Dalton Trans.,
2001, 2567-80.
R. Vaidhyanathan, S. Natarajan and C.N.R. Rao, Inorg. Chem., 2002,
41, 5226-5234.
P. Klufers, Z. Kristallogr., 1983, 165, 217-226; P. Klufers, Z.
Kristallogr., 1983, 162, 138.
D. Laliberte, T. Maris and J.D. Wuest, CrystEngComm, 2005, 7, 158160.
D. Laliberte, N. Raymond, T. Maris and J.D. Wuest, Acta
Crystallogr., Sect. E, 2005, 61, o601-o603.
D. Laliberte, T. Maris, E. Demers, F. Helzy, M. Arseneault and J.D.
Wuest, Cryst. Growth Des., 2005, 5, 1451-1456.
C.L. Baker, F.J. Lincoln and A.W.S. Johnson, Aust. J. Chem., 1992,
45, 1441-1449.
J.C. Jumas, M. Maurin and E. Philippot, J. Fluor. Chem., 1976, 8,
329-340.
4
Disodium and Dipotassium Dihydrogen H-bonded.
1,3,5,7-Adamantanetetracarboxylate
[Cu(Hcmp)4]X, Hcmp = 3-cyano-6Nets constructed by H-bonding
between CuL4 molecules.
methyl-2(1H)-pyridinone, X = PF6,
CF3SO3
4•
O. Ermer and L. Lindenberg, Chem. Ber., 1990, 123, 1111.
4•
M. Munakata, L.P. Wu, M. Yamamoto, T. kuroda-Sowa and M.
Maekawa, J. Am. Chem. Soc., 1996, 118, 3117.
45
Cu(bipy)2(PF6)
4•
M(bipy)2(CF3SO3), M = Ag, Cu and
Ag(4-cyanopyridine)2(BF4)
Ag2L.solv, L = tetrapyridinocyclophane Tetrahedral L linked by linear Ag
ions.
ZnL2.G, L = trans-3-(4pyridyl)acrylate, G = trans-2-butene
[Cu(bpp)2Cl2].2.75H2O, bpp = 1,3Normal mode.
bis(4-pyridyl)propane
TbL(MeOH)(NO3)3, L = 4,4'Normal mode; both H-bonding
and coordinative links.
bipyridine-N,N'-dioxide
[Ag(ddn)2]ClO4, ddn = 1,12The BF4 structure is apparently
dodecanedinitrile
isomorphous but gave poor
crystals.
Cd(imidazole-4-acrylate)2.1.7H2O
Unusual mode of
interpenetration, directed by
inter-net H-bonding.
Ag(NC-(CH2)4-CN)2X, X = PF6, AsF6, Normal mode.
SbF6, CF3SO3
Ag(NC-(CH2)2-CN)2CF3SO3
Normal mode.
4•
CuCN.Me3SnCN.cpy, cpy = 4cyanopyridine
[WS4Cu4(bipy)4][WS4Cu4I4(bipy)2].4
H2O, bipy = 4,4'-bipyridine
Cu4(mea)4(Au(CN)2)4.H2O, Hmea =
monoethanolamine
Zn(dpe)(OH-BDC).0.5dpe and
Zn(bpp)(OH-BDC).H2O, dpe = 1,2di(4-pyridyl)ethylene, OH-H 2BDC = 5hydroxyisophthalic acid, bpp = 1,3bi(4-pyridyl)propane
4
Two cationic nets and two
anionic nets.
Aurophilic interactions between
nets. Cu4O4 nodes.
4
4
4
4
4
L.R. MacGillivray, S. Subramanian and M.J. Zaworotko, J. Chem.
Soc., Chem. Commun., 1994, 1325; O.M. Yaghi, D.A. Richardson, G.
Li, C.E. Davis and T.L. Groy, Mater. Res. Soc. Symp. Proc. (Adv. in
Porous Materials), 1993, 371, 15.
L. Carlucci, G. Ciani, D.M. Proserpio and A. Sironi, J. Chem. Soc.,
Chem. Commun., 1994, 2755.
C. Klein, E. Graf, M.W. Hosseini and A. De Cian, New J. Chem.,
2001, 25, 207-209.
J. Zhang, W. Lin, Z-F. Chen, R-G. Xiong, B.F. Abrahams and H-K.
Fun, J. Chem. Soc., Dalton Trans., 2001, 1806-1808.
L. Carlucci, G. Ciani, M. Moret, D.M. Proserpio and S. Rizzato,
Chem. Mater., 2002, 14, 12-16.
D.-L. Long, A.J. Blake, N.R. Champness, C. Wilson and M.
Schroder, Chem. Eur. J., 2002, 8, 2026-2033.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, Chem. Eur. J.,
2002, 8, 1520-1526.
4
Y.-H. Liu, H.-C. Wu, H.-M. Lin, W.-H. Hou and K.-L. Lu, Chem.
Commun., 2003, 60-61.
4
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4, 413-425.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4, 413-425.
H. Hanika-Heidl, S.E.H. Etaiw, M.S. Ibrahim, A.S.B. El-din and R.D.
Fischer, J. Organomet. Chem., 2003, 684, 329-337.
K. Liang, H. Zheng, Y. Song, M.F. Lappert, Y. Li, X. Xin, Z. Huang,
J. Chen and S. Lu, Angew. Chem. Int. Ed., 2004, 43, 5776-5779.
C. Paraschiv, M. Audruh, S. Ferlay, M.W. Hosseini, N. Kyritsakas,
J.-M. Planeix and N. Stanica, Dalton Trans., 2005, 1195-1202.
X. Li, R. Cao, D. Sun, W. Bi, Y. Wang, X. Li and M. Hong, Cryst.
Growth Des., 2004, 4, 775-780.
4
4
4
4
46
Cu3(CN)(IN)2, IN = isonicotinate
Four interpenetrating diamond
4
nets if Cu...Cu interactions (2.698
Å) are ignored. If not, then two
alpha-Po nets with Cu2 moieties
as nodes.
[Ni(dpa)2(SO4)(H2O)].2H2O, dpa = di- Distorted nets; monodentate SO4 4
4-pyridylamine
and waters H-bond b/w nets.
Paper says 2 nets, but actually 4.
Tetrakis[(4Each molecule connected to 8
4
nitrobiphenoxy)methyl]methane.2DMS others via C-H...O interactions,
O
however can be regarded as a
diamond nets if the nodes
alternate between the central C
atoms and H-bonded square ring
motifs.
Y. Kang, Y.-G. Yao, Y.-Y. Qin, J. Zhang, Y.-B. Chen, Z.-J. Li, Y.-H.
Wen, J.-K. Cheng and R.-F. Hu, Chem. Commun., 2004, 1046-1047.
M.C. Laskoski, R.L. LaDuca Jr., R.S. Rarig Jr. and J. Zubieta, J.
Chem. Soc., Dalton Trans., 1999, 3467-3472.
D. Laliberte, T. Maris and J.D. Wuest, CrystEngComm, 2005, 7, 158160.
5
Adamantane-1,3,5,7-tetracarboxylic
acid
4,4-bis(2-carboxyethyl)pimelic acid
('Methanetetrapropionic Acid')
Ni(fum)(bpe), fum = fumarate, bpe =
1,2-bis(4-pyridyl)ethane
1,3,5,7-Tetraiodoadamantane
Cu(1,4-dicyanobenzene)2(BF4)
H-bonded. Different mode of
interpenetration.
H-bonded nets; same mode of
interpenetration as above
structure.
Unusual mode of
interpenetration; seems to be the
same as Ermer's (above).
Tetrahedral molecules connected
by I-I contacts; I-I contacts of
almost the same length cross-link
the nets.
Normal mode of interpenetration.
5•
O. Ermer, J. Am. Chem. Soc., 1988, 110, 3747.
5
O. Ermer, A. Kusch and C. Robke, Helv. Chim. Acta, 2003, 86, 922929.
5
S. Konar, E. Zangrando, M.G.B. Drew, J. Ribas and N.R. Chaudhuri,
Dalton Trans., 2004, 260-266.
5
V.R. Pedireddi, D.S. Reddy, B.S. Goud, D.C. Craig, A.D. Rae and
G.R. Desiraju, J. Chem. Soc., Perkin Trans. 2, 1994, 2353-2360.
5•
R. Robson, B.F. Abrahams, S.R. Batten, R.W. Gable, B.F. Hoskins
and J. Liu, Supramolecular Architecture, ACS Symposium Series
499, ed. T. Bein, Am. Chem. Soc., Washington DC, 1992, 256.
A.J. Blake, N.R. Champness, S.S.M. Chung, W.-S. Li and M.
Schroder, Chem. Commun., 1997, 1005-1006 (solv = CH2Cl2); S.R.
Batten, J.C. Jeffery and M.D. Ward, Inorg. Chim. Acta, 1999, 292,
231-237 (solv = MeCN).
A.N. Parvulescu, G. Marin, K. Suwinska, V.C. Kravtsov, M. Andruh,
V. Parvulescu and V.I. Parvulescu, J. Mater. Chem., 2005, 15, 42344240.
Cu(1,2-trans-(4-pyridyl)ethene) 2BF4
.solv
Normal mode of interpenetration. 5•
Cu(1,2-trans-(4-pyridyl)ethene) 2NO3
Normal mode of interpenetration. 5
47
Cu(4,4'-azpy)2X, 4,4'-azpy = trans-4,4'- Normal mode of interpenetration. 5
azobis(pyridine), X = BF4, ClO4
5
M(py-CHCHCO2)2(H2O)n, M = Cd (n
= 1), Zn (n = 0)
Different mode of
interpenetration.
Acentric nets. Abnormal
interpenetration?
CoL2, L = trans-4-pyridylacrylate
Abnormal interpenetration?
5
(2-amino-4,6-dimethylpyridinium)+
(MeSO2)2NCo(L1)(L2), L1 = 1,2-bis(4pyridyl)ethane, L2 = 2aminoterephthalate
X(4-C6H4B(OH)2)4, X = C, Si
H-bonded nets.
5
Abnormal interpenetration?
5
)-Cu(dca)(bpe)
5
Normal mode of interpenetration. 5
H-bonded nets.
Ag(NC-(CH2)2-CN)2X, X = BF4, ClO4, Normal mode.
5
PF6, AsF6, SbF6
Zn(4,4'-bipy)(4,4'Paper claims normal mode - I
5
biphenyldicarboxylate).3H2O
think it is an unusual mode of
interpenetration.
Tetrakis(3,5-dihydroxyphenyl)silane
H-boned nets. May be weaker H- 5
bonding interactions between
nets.
Zn(bpe)(OH-BDC), bpe = 1,2-bi(45
pyridyl)ethane, OH-H2BDC = 5hydroxyisophthalic acid
ZnL2(ClO4)2, L = N,N'-bis(4Normal mode.
5
pyridyl)urea
CuL(NO3), L = fumaronitrile
5
M.A. Withersby, A.J. Blake, N.R. Champness, P.A. Cooke, P.
Hubberstey, A.L. Realf, S.J. Teat and M. Schroder, J. Chem. Soc.,
Dalton Trans., 2000, 3261-3268 (BF4); C. He, B.-G. Zhang, C. Duan,
J. Li and Q.-J. Meng, Eur. J. Inorg. Chem., 2000, 2549-2554 (ClO4).
S.R. Batten, A.R. Harris, P. Jensen, K.S. Murray and A. Ziebell, J.
Chem. Soc., Dalton Trans., 2000, 3829-3836.
O.R. Evans, R.-G. Ziong, Z. Wang, G.K. Wong and W. Lin, Angew
Chem. Int. Ed., 1999, 38, 536-8; Angew. Chem., 1999, 111, 557-9;
O.R. Evans and W. Lin, Chem. Mater., 2001, 13, 2705-12.
Y-H. Liu, C-S. Lin, S-Y. Chen, H-L. Tsai, C-H. Ueng and K-L. Lu, J.
Solid State Chem., 2001, 157, 166-172.
O. Moers, K. Wijaya, I. Lange, A. Blaschette and P.G. Jones, Z.
Naturforsch., Teil B, 2000, 55, 738-752.
Z.-Y. Fu, X.-T. Wu, J.-C. Dai, S.-M. Hu, W.-X. Du, H.-H. Zhang and
R.-Q. Sun, Eur. J. Inorg. Chem., 2002, 2730-2735.
J.-H. Fournier, T. Maris, J.D. Wuest, W. Guo and E. Galoppini, J.
Am. Chem. Soc., 2003, 125, 1002-1006.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4, 413-425.
K.O. Kongshaug and H. Fjellvag, J. Solid State Chem., 2003, 175,
182-187.
O. Saied, T. Maris, X. Wang, M. Simard and J.D. Wuest, J. Am.
Chem. Soc., 2005, 127, 10008-10009.
X. Li, R. Cao, D. Sun, W. Bi, Y. Wang, X. Li and M. Hong, Cryst.
Growth Des., 2004, 4, 775-780.
D.K. Kumar, D.A. Jose, A. Das and P. Dastidar, Inorg. Chem., 2005,
44, 6933-6935.
P. Kamau and R.B. Jordan, Inorg. Chem., 2002, 41, 884-891.
6
Zn(L)2(ClO4)2, L = O2CCH2CH2N+(CH2CH2)3N+CH2CH2CO2-
Diamond - Mak said 2 nets, I say 6•
it's 6.
P.-R. Wei, B.-M. Wu, W.-P. Leung and T.C.W. Mak, Polyhedron,
1996, 15, 4041; R.E. Marsh, M. Kapon, S. Hu and F.H. Herbstein,
Acta Crystallogr., Sect. B, 2002, 58, 62-77.
48
Cu(NC-(CH2)4-CN)(NO3)
6•
Cu(bpb)2(X), bpb = 1,4-bis-(4-pyridyl)butadiyne, X = ClO4, BF4
(NH4)(Me2NH2)(CdL2), L = 3,3'Unusual mode of
interpenetration.
azodibenzoate
Ag(NC-(CH2)4-CN)2BF4
Normal mode.
6•
Cu(pybz)2, pybz = 4-(4pyridyl)benzoate
NiL2Cl2, L = 1,3-bis(4pyridylthio)propan-2-one
Si(4-C6H4NHCO2Et)4.2dioxane
6
6
6
6
H-bonded net in which dioxane
molecules bridge between
molecules via N-H...O hydrogen
bonds.
6
Y. Kinoshita, I. Matsubara, T. Higuchi and Y. Saito, Bull. Chem. Soc.
Jpn., 1959, 32, 1221.
B.F. Hoskins, R. Robson and E.E. Sutherland, unpublished results.
Z.-F. Chen, R.-G. Xiong, B.F. Abrahams, X.-Z. You and C.-M. Che,
J. Chem. Soc., Dalton Trans., 2001, 2453-5.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4, 413-425.
T.-B. Lu and R.L. Luck, Inorg. Chim. Acta, 2003, 351, 345-355.
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J. Inorg. Chem., 2005, 1303-1311.
D. Laliberte, T. Maris and J.D. Wuest, Can. J. Chem., 2004, 82, 386398.
7
Cu(R1,R3-DCNQI)2 and deuterated
derivs., DCNQI = N,N'dicyanoquinodiimine, R1,R3 = CH3,
CH3O, Cl, Br, I. M = Li or Ag
isomorphous, M = Na, K, NH4, Rb or
Tl very closely related (but no longer
separate interpenetrating frameworks).
7•
O. Ermer, Adv. Mater., 1991, 3, 608; K. Sinzger, S. Hunig, M. Jopp,
D. Bauer, W. Bietsch, J.U. von Schutz, H.C. Wulf, R.K. Kremer, T.
Metzenthin, R. Bau, S.I. Khan, A. Lindbaum, C.L. Lengauer and E.
Tillmanns, J. Am. Chem. Soc., 1993, 115, 7696; A. Aumuller, P. Erk,
G. Klebe, S. Hunig, J.U. von Schutz and H.-P. Werner, Angew.
Chem. Int. Ed. Engl., 1986, 25, 740; R. Kato, H. Kobayashi, A.
Kobayashi, T. Mori and H. Inokuchi, Chem. Lett., 1987, 1579; R.
Kato, H. Kobayashi and A. Kobayashi, J. Am. Chem. Soc., 1989, 111,
5224; A. Kobayashi, R. Kato, H. Kobayashi, T. Mori and H.
Inokuchi, Solid State Commun., 1987, 64, 45; S. Hunig, A. Aumuller,
P. Erk, H. Meixner, J.U. von Schutz, H.-J. Gross, U. Langohr, H.-P.
Werner, H.C. Wolf, C. Burschka, G. Klebe, K. Peters and H.G. v.
Schnering, Synth. Met., 1988, 27, B181; R. Kato, H. Kobayashi, A.
Kobayashi, T. Mori and H. Inokuchi, Synth. Met., 1988, 27, B263; A.
Kobayashi, T. Mori, H. Inokuchi, R. Kato and H. Kobayashi, Synth.
Met., 1988, 27, B275; A. Aumuller, P. Erk, S. Hunig, J.-U. von
Schutz, H.P. Werner, H.C. Wolf and G. Klebe, Mol. Cryst. Liq.
Cryst., 1988, 156, 215; see also S. Hunig, J. Mater. Chem., 1995, 5,
1469; S. Hunig and P. Erk, Adv. Mater., 1991, 3, 225; S. Unig, Pure
Appl. Chem., 1990, 62, 395.
49
C(C6H5CCC5H4NO)4.G, G = butyric
acid, butyric acid, valeric acid,
isovaleric acid
Cd[4-(4-pyridyl)benzoate]2.H2O
H-bonded.
7•
7
M. Simard, D. Su and J.D. Wuest, J. Am. Chem. Soc., 1991, 113,
4696-4698; D. Su, X. Wang, P. Deschatelets, L. Vaillancourt, M.
Simard and J.D. Wuest, Polymer Prepr., 1995, 36, 554-555.
O.R. Evans and W. Lin, Chem. Mater., 2001, 13, 2705-12.
8
Si(C6H5CCC5H4NO)4.2G, G = valeric
acid
H-bonded.
[Ag(sebn)2]X, sebn = sebaconitrile
(1,10-decanedinitrile), X = BF4, ClO4
Ag(3,3'-DCPA)2ClO4.H2O, 3,3'-DCPA Diamond nets. Unusual
('abnormal') mode of
= 3,3'-dicyanodiphenylacetylene
interpenetration noted by Ciani et
al., who describe it as '4+4'.
[Ag(ddn)2]X, ddn = 1,12Unusual ('abnormal') mode of
interpenetration, described as
dodecanedinitrile, X = PF6, AsF6
'4+4'; topology the same as the
above structure.
Zn(PEBA)2, PEBA = 4-[2-(4Abnormal interpenetration?
pyridyl)ethenyl]benzoate
ML2, L = 4-[2-(4-pyridyl)ethenyl]
Abnormal interpenetration?
benzoato, M = Zn, Cd
Cu3(4-pya)2(H2O)(BF4), 4-pya = 4CuI4(CO2)4 clusters as nodes.
pyridylacrylic acid
(C(CH2O)4C2)(CH2C6H4C3N3(NH2)2) H-bonded nets.
8•
8
8•
8
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, Chem. Eur. J.,
2002, 8, 1520-1526.
8
R.-G. Xiong, J.-L. Zuo, X.-Z. You, B.F. Abrahams, Z.-P. Bai, C.-M.
Che and H.-K. Fun, Chem. Commun., 2000, 2061-2.
W. Lin, L. Ma and O.R. Evans, Chem. Commun., 2000, 2263-2264.
8
8
8
4
HC(C6H4OH)2(C6H3(OH)2)
H-bonded nets.
HC(2-C6H4OH)2(3,5-C6H3(OH)2).4,4'- H-bonded nets.
bipyridine
[Ni(cyclam)]2[TCM].2DMF.10H2O,
[4+4] interpenetration.
TCM = tetrakis[4(carboxyphenyl)oxamethyl]methane
D. Su, X. Wang, M. Simard and J.D. Wuest, Supramol. Chem., 1995,
6, 171-178; D. Su, X. Wang, P. Deschatelets, L. Vaillancourt, M.
Simard and J.D. Wuest, Polymer Prepr., 1995, 36, 554-555.
L. Carlucci, G. Ciani, P. Macchi, D.M. Proserpio, and S. Rizzato,
Chem. Eur. J., 1999, 5, 237-243.
K.A. Hirsch, S.R. Wilson and J.S. Moore, Inorg. Chem., 1997, 36,
2960-2968. See also L. Carlucci, G. Ciani, D.M. Proserpio and S.
Rizzato, Chem. Eur. J., 2002, 8, 1520-1526.
8
8
8
X.-S. Wang, H. Zhao, Z.-R. Qu, Q. Ye, J. Zhang, R.-G. Xiong, X.-Z.
You and H.-K. Fun, Inorg. Chem., 2003, 42, 5786-5788.
H. Sauriat-Dorizon, T. Maris, J.D. Wuest and G.D. Enright, J. Org.
Chem., 2003, 68, 240-246.
A. Jayaraman, V. Balasubramaniam and S. Valiyaveettil, Cryst.
Growth Des., 2005, 5, 1575-1583.
A. Jayaraman, V. Balasubramaniam and S. Valiyaveettil, Cryst.
Growth Des., 2005, 5, 1575-1583.
H. Kim and M.P. Suh, Inorg. Chem., 2005, 44, 810-812.
9
Ag(NC-C6H4-C6H4-CN)(XF6), X = P,
As, Sb
9•
K.A. Hirsch, D. Venkataraman, S.R. Wilson, J.S. Moore and S. Lee,
J. Chem. Soc., Chem. Commun., 1995, 2199-2200; K.A. Hirsch, S.C.
Wilson and J.S. Moore, Chem. Eur. J., 1997, 3, 765-771.
50
10
[Ag(ddn)2]NO3, ddn = 1,12dodecanedinitrile
10
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, Chem. Eur. J.,
2002, 8, 1520-1526.
H-bonded nets.
11
D.S. Reddy, T. Dewa, K. Endo and Y. Aoyama, Angew. Chem. Int.
Ed., 2000, 39, 4266-4286.
6•
B.F. Hoskins, R. Robson and N.V.Y. Scarlett, Angew. Chem. Int. Ed.
Engl., 1995, 34, 1203; S.C. Abrahams, L.E. Zyontz and J.L.
Bernstein, J. Chem. Phys., 1982, 76, 5458-5461.
2
J. Sun, L. Weng, Y. Zhou, J. Chen, Z. Chen, Z. Liu and D. Zhao,
Angew. Chem. Int. Ed., 2002, 41, 4471-4473.
2
J. Sun, L. Weng, Y. Zhou, J. Chen, Z. Chen, Z. Liu and D. Zhao,
Angew. Chem. Int. Ed., 2002, 41, 4471-4473.
2•
B.F. Abrahams, B.F. Hoskins, D.M. Michail and R. Robson, Nature,
1994, 369, 727.
2
Y. Diskin-Posner, S. Dahal and I. Goldberg, Chem. Commun., 2000,
585-586.
2•
L. Shields, J. Chem. Soc., Faraday Trans., 1985, 81, 1; B.F. Hoskins,
N.V.Y. Scarlett and R. Robson, unpublished results.
R.A. Heintz, H. Zhao, X. Ouyang, G. Grandinetti, J. Cowen and K.R.
Dunbar, Inorg. Chem., 1999, 38, 144-156.
Cu(tcnq) Phase II
Quartz net (chiral). However, if
short Au-Au contacts taken into
account, then becomes two 3,4connected nets with
(92.10)2(94.102) topology.
Quartz net. Chiral space group,
so presumably both nets are of
the same hand.
Quartz net. Chiral space group,
so presumably both nets are of
the same hand.
PtS net; asymmetric
interpenetration due to porphyrin
-porphyrin interaction.
Two H-bonded PtS nets;
described as 'diamondoid' in
paper!!
PtS net; interpenetration not
recognised in original paper.
4-connected net - connectivity
but not topology the same as
Phase II.
PtS net.
Ag(TCNQF4)
Likely PtS net.
2
11
tetrakis[4-(3-hydroxyphenyl)phenyl]
methane:benzoquinone (1:2)
3D 4-connected other
Zn[Au(CN)2]2 and Co[Au(CN)2]2
Zn(ISN)2.2H2O, ISN = isonicotinate
InH(BDC)2, BDC = terephthalate
Cu(tcp)CuBF4.17C6H5NO2, Cu(tcp) =
5,10,15,20-tetrakis(4-cyanophenyl)21H,23H-porphine copper(II)
Zn(TCPP)Zn.ethylene glycol, TCPP =
meso-tetra(4-carboxyphenyl)porphyrin
Ag(tcnq)
Cu(tcnq) Phase I
2
2
R.A. Heintz, H. Zhao, X. Ouyang, G. Grandinetti, J. Cowen and K.R.
Dunbar, Inorg. Chem., 1999, 38, 144-156.
S.A. O'Kane, R. Clerac, H. Zhao, X. Ouyang, J.R. Galan-Mascaros,
R. Heintz and K.R. Dunbar, J. Solid State Chem., 2000, 152, 159-173.
51
(2,7-Dimethyltricyclo[4.3.1.13,8 ]
H-bonded. New net.
2•
undecane-syn-7-diol)4.solv, solv =
C6H6, cyclohexane
Cu(bipy)2(CF3SO3)2
Same net topology as H-bonded
net above - 42.84.
Co(NCacac)2, NCacac = 3-cyano-2,4- 42.84 topology; neither
pentanedionato
interpenetration nor topology
commented on in original paper.
Topology looks the same as the
above two structures.
Cu(Pyac)2.solv, PyacH = 3-(4Two interpenetrating NbO nets.
Topology not recognised in
pyridyl)pentane-2,4-dione, solv =
(EtOH)0.5 (H2O)3 or (THF)0.1 (H2O)2.25 earlier paper.
Cyanuric Acid - Biuret (1:1)
H-bonded. Described incorrectly
in Batten, Robson 1998 Angew.
Chem. review as NbO nets, but
actually CdSO4 topology.
Cu(bis(4-pyridyl)ethane)2(NO3)2
NbO net claimed by MZ; LC
claims it's CdSO4 - related (658).
2
[{Cu(bpethy) 2(H2O)2}{Cu(bpethy)2
759 net (sq. planar nodes). Nets
(NO3)(H2O)}2][NO3]4.bpethy.1.33H2O have 2 different compositions.
bpethy = 1,2-bis(4-pyridyl)ethyne
The 2 NO3 nets are x-linked by
H-bonding via the intercalated
species, giving a 5-conn. net
(intptd by a 4-conn. one).
[Ag(pytz)](NO 3), pytz = 3,6-di(4Described as 1D chain (MS), but
if weak Ag-O-NO2 interactions
pyridyl)-1,2,4,5-tetrazine
taken into account, can be desc.
(LC) as 3-fold 759 nets (see
above).
[Cu(bpe)(H2O)(SO4)]
CdSO4 net - bpe and SO4 links.
2
2
2
2•
2
S.C. Hawkins, R. Bishop, I.G. Dance, T. Lipari, D.C. Craig and M.L.
Scudder, J. Chem. Soc., Perkin Trans. 2, 1993, 1729; R. Bishop, I.G.
Dance and S.C. Hawkins, J. Chem. Soc., Chem. Commun., 1983, 889
(Interpreted in O. Ermer and L. Lindenberg, Helv. Chim. Acta, 1991,
74, 825 as two diamond nets); S.F. Alshahateet, R. Bishop, D.C.
Craig, M.L. Scudder and A.T. Ung, Struct. Chem., 2001, 12, 251;
S.F. Alshaheteet, R. Bishop, D.C. Craig and M.L. Scudder,
CrystEngComm, 2002, 8, 1-4.
L. Carlucci, N. Cozzi, G. Ciani, M. Moret, D.M. Proserpio and S.
Rizzato, Chem. Commun., 2002, 1354-5.
O. Angelova, J. Macicek, M. Atanasov and G. Petrov, Inorg. Chem.,
1991, 30, 1943-1949.
B. Chen, F.R. Fronczek and A.W. Maverick, Chem. Commun., 2003,
2166-2167; S.S. Turner, D. Collison, F.E. Mabbs and M. Halliwell, J.
Chem. Soc., Dalton Trans., 1997, 1117.
N.M. Stainton, K.D.M. Harris and R.A. Howie, J. Chem. Soc., Chem.
Commun., 1991, 1781-4.
K.N. Power, T.L. Hennigar and M.J. Zaworotko, Chem. Commun.,
1998, 595-6; cf. L. Carlucci, G. Ciani, P. Macchi and D.M. Proserpio,
Chem. Commun., 1998, 1837-8.
L. Carlucci, G. Ciani, P. Macchi and D.M. Proserpio, Chem.
Commun., 1998, 1837-8.
3
M.A. Withersby, A.J. Blake, N.R. Champness, P. Hubberstey, W.-S.
Li and M. Schroder, Angew. Chem. Int. Ed. Engl., 1997, 36, 2327; cf.
L. Carlucci, G. Ciani, P. Macchi and D.M. Proserpio, Chem.
Commun., 1998, 1837-8.
2
D. Hagrman, R.P. Hammond, R. Haushalter and J. Zubieta, Chem.
Mater., 1998, 10, 2091-2100.
52
[Ag(sebn)2]X, X = PF6, AsF6, sebn =
4-connected, SrAl2 - like.
sebaconitrile (1,10-decanedinitrile)
[Cu2(TCNB)3](PF6)2, TCNB = 1,2,4,5- Moganite topology, with
tetrahedral and square-planar
tetracyanobenzene
nodes.
4-(carboxamindo)-1-cubanecarboxylic Two nets defined by H-bonding
acid
interactions. Claimed to be NbO,
but looks like CdSO4. Networks
linked thru a C-H...O H-bond.
Cu(SCN)(bpa), bpa = 1,2-bis(4Two 42.63.8 4-connected
pyridyl)ethane
networks.
5-hydroxyisophthalic acid / 1,3-di(4H-bonded CdSO4 (?) networks.
pyridyl)propane (1:1)
SmL2(NO3)3.0.5H2O, L = 4,4'CdSO4-like nets.
bipyridine-N,N'-dioxide
Ag(1,4-dithiane)BF4
CdSO4-like nets.
4
Ag(C(CN) 2NO)
2•
[Cu(S-py2)]4Mo8O26.2H2O
[NiYb(pypyd)4(NCS)2(NO3)2](NO3),
pypyd = 1-(4'-pyridyl)pyridin-4-one
Similar to Ag(tcm), with two
cyanides and the nitroso O
coordinating within the sheets.
The nitroso N bonds to a Ag in
the next layer of double sheets,
making a 3D structure.
4-connected net with Cu4L4
squares and Mo8O26 species as
the 'square-planar' 4-connectors.
Interpenetration such that the
Mo8O26 nodes of one net lie in
the centre of the Cu4L4 nodes of
the other net. Could also be
described as a 3,4-connected net,
which Cu as the 3-connector.
Two CdSO4 nets.
2
L. Carlucci, G. Ciani, P. Macchi, D.M. Proserpio, and S. Rizzato,
Chem. Eur. J., 1999, 5, 237-243.
M. Munakata, G.L. Ning, T. Kuroda-Sowa, M. Maekawa, Y.
Suenaga, and T. Horino, Inorg. Chem., 1998, 37, 5651-5656.
2
S.S. Kuduva, D.C. Craig, A. Nangia and G.R. Desiraju, J. Am. Chem.
Soc., 1999, 121, 1936-1944.
2
Q.-M. Wang, G.-C. Guo and T.C.W. Mak, Chem. Commun., 1999,
1849-1850.
P.S. Wheatley, A.J. Lough, G. Ferguson and C. Glidewell, Acta
Crystallogr., Sect. C, 1999, 55, 1486-1489.
D.-L. Long, A.J. Blake, N.R. Champness and M. Schroder, Chem.
Commun., 2000, 1369-1370.
A.J. Blake, N.R. Brooks, N.R. Champness, J.W. Cunningham, P.
Hubberstey and M. Schroder, CrystEngComm, 2000, 6; N.R. Brooks,
A.J. Blake, N.R. Champness, J.W. Cunningham, P. Hubberstey, S.J.
Teat, C. Wilson and M. Schroder, J. Chem. Soc., Dalton Trans.,
2001, 2530-2538.
Y.M. Chow and D. Britton, Acta Crystallogr., Sect. B, 1974, 30,
1117.
4
2
2
2
D. Hagrman and J. Zubieta, C.R. Acad. Sci. Paris, Serie IIc, Chimie,
2000, 3, 231-240.
2
D.M.L. Goodgame, D.A. Grachvogel, A.J.P. White and D.J.
Williams, Inorg. Chem., 2001, 40, 6180-6185.
53
[Cu2(Py2C6H12)4(H2O)2](NO3)4(Py2C
6H 12)(EtOH)(H 2O) 2, Py 2C6H 12 = 1,6bis(4-pyridyl)hexane
CMCR.1.5bipy.1.5EtOH.0.85ferrocene,
CMCR = Cmethylcalix[4]resorcinarene, bipy =
4,4'-bipyridine
CoLCl2.CHCl3.3.5H2O, L =
C(CH2OC(O)-4-C5H4N)4
Fe(pmd)(H2O)(M(CN)2)2.H2O, pmd =
pyrimidine, M = Ag, Au
Si(C6H4OH)4.H2O
CdSO4 nets.
4
M.J. Plater, M.R.St.J. Foreman, T. Gelbrich and M.B. Hursthouse,
Cryst. Eng., 2001, 4, 319-328.
H-bonded nets. Unsure of
topology. CMCR molecules as
nodes.
2
T. Friscic and L.R. MacGillivray, J. Organomet. Chem., 2003, 666,
43-48.
PtS nets.
2
CdSO4 nets; cross-linked by Hbonding between H2O and pmd
ligands.
H-bonded nets; NbO topology.
3
P. Grosshans, A. Jouaiti, M.W. Hosseini and N. Kyritsakas, New J.
Chem., 2003, 27, 793-797.
V. Niel, A.L. Thompson, M.C. Munoz, A. Galet, A.E. Goeta and J.A.
Real, Angew. Chem. Int. Ed., 2003, 42, 3760-3763.
2
[Cu(TINM)(NO3)2](H2O)4.5 (MeOH)2.5 PtS nets.
, [Cu(TINM)(H2O)2](NO3)2(H2O)10,
[Ni(TINM)Cl2](TINM)0.5 (H2O)4,
[Co(TINM)Cl2](TINM)0.5 , TINM =
tetrakis(isonicotinoxymethyl)methane
Fe(3CNpy)2[M(CN)2]2.2/3H2O,
NbO nets.
3CNpy = 3-cyanopyridine, M = Ag, Au
2
[bipyH2][Zn(mnt)2], mnt =
maleonitriledithiolate
Ag2CsB15O24
2
Co(2,2'-bipy-4,4'(CO2)2)(H2O)2
Cu2(µ-OMe) 2L2.0.69H2O, HL = 9acridinecarboxylic acid
H-bonded nets; not sure of
topology.
Two interpenetrating borate nets
in which B5O10 clusters act as
nodes; quartz topology. Ag
cations crosslink nets.
Self-penetrating (12,3) net if both
metal and ligands are taken as
nodes. If CoL2 taken as node,
then quartz topology; two
interpenetrating nets missed by
authors (see L. Carlucci, G. Ciani
and D.M. Proserpio, Coord.
Chem. Rev., 2003, 246, 247).
NbO nets; nodes are Cu2(µOMe)2 dimers.
3
2
J.-H. Fournier, T. Maris, M. Simard and J.D. Wuest, Cryst. Growth
Des., 2003, 3, 535-540.
K.I. Nattinen and K. Rissanen, Inorg. Chem., 2003, 42, 5126-5134.
A. Galet, V. Niel, M.C. Munoz and J.A. Real, J. Am. Chem. Soc.,
2003, 125, 14224-14225; A. Galet, M.C. Munoz, V. Martinez and
J.A. Real, Chem. Commun., 2004, 2268-2269.
X. Ren, J. Xie, Y. Chen and R.K. Kremer, J. Mol. Struct., 2003, 660,
139-146.
A. Wiesch and K. Bluhm, Z. Naturforsch., Teil B, 1998, 53, 157-160.
2
T. Schareina, C. Schick, B.F. Abrahams and R. Kempe, Z. Anorg.
Allg. Chem., 2001, 627, 1711-3.
2
X.-H. Bu, M.-L. Tong, H.-C. Chang, S. Kitagawa and S.R. Batten,
Angew. Chem., Int. Ed., 2004, 43, 192-195.
54
Fe(NCS)2(tmbpz)2, tmbpz = 3,3',5,5'tetramethyl-4,4'-bipyrazolyl
[M(TBG)(H2O)3].2H2O, M = Cu, Co,
H2TBG = terephthaloylbisglycine
[Ag(C5H4NCONH2)2][BF4]
CoL2(SCN)2.2DMF, L = 1,3-bis(4pyridylthio)propan-2-one
[Cu(bipy)2(H2O)2][Cu(bipy)2(H2O)(N
O3)](NO3)3.12H2O, bipy = 4,4'bipyridine
Ag(phen)(CN).phen, phen = 1,10phenanthroline
NbO nets.
2
P.V. Ganesan and C.J. Kepert, Chem. Commun., 2004, 2168-2169.
Coordination nets with cds
topology. Nets crosslinked by Hbonding to an intercalated water
molecule.
Cds nets defined by N-H...O and
N-H...F hydrogen bonds.
Cds nets.
2
G.E. Kostakis, L. Casella, N. Hadjiliadis, E. Monzani, N.
Kourkoumelis and J.C. Plakatouras, Chem. Commun., 2005, 38593861.
5
42.84 topology.
2
B.R. Bhogala, P.K. Thallapally and A. Nangia, Cryst. Growth Des.,
2004, 4, 215-218.
B. Wu, D. Yuan, F. Jiang, L. Han, B. Lou, C. Liu and M. Hong, Eur.
J. Inorg. Chem., 2005, 1303-1311.
J.Y. Lu, W.A. Fernandez, Z. Ge and K.A. Abboud, New J. Chem.,
2005, 29, 434-438.
Nets defined by C-H...N
hydrogen bonds and pi-pi
stacking give (55.6)(54.82)
topology. Nets linked by C-H...pi
interactions.
1,3,5-tris[4-pyridyl(ethenyl)]benzene
H-bonded nets defined by CH...N interactions. SrAl2
topology.
Cu4I4(bpp)2, bpp = 1,3-bis(4Quartz nets with Cu4I4 clusters as
pyridyl)propane
nodes.
CdL2(H2O)2(ClO4)2.2DMF.3EtOH.5/3 Unusual topology.
H2O, L = (R)-6,6'-dichloro-2,2'diethoxy-1,1'-binaphthyl-4,4'-bipyridine
Mn(tpb)Cl2(MeOH)(H2O), tpb =
If ligand considered as
tetrahedral node, then topology is
3,3',5,5'-tetrakis(4-pyridyl)bimesityl
PtS. If ligand considered as two
linked 3-connecting nodes, then
becomes a 3,4-connected net with
(4.122)2(42.124) topology.
Cu1.5 (3-pyd)3(H2O).1.5H 2O, 3-Hpyd = Unusual topology.
3-(3-pyridyl)acrylic acid
Ni3(H2O)6(4,4'Unusual topology.
bipyridine)4(SIPA)2.8H2O, H3SIPA =
5-sulfonisophthalic acid
3
3
X.-C. Huang, S.-L. Zheng, J.-P. Zhang and X.-M. Chen, Eur. J.
Inorg. Chem., 2004, 1024-1029.
3
L.S. Reddy, B.R. Bhogala and A. Nangia, CrystEngComm, 2005, 7,
206-209.
3
S. Hu and M.-L. Tong, Dalton Trans., 2005, 1165-1167.
3
C.-D. Wu and W. Lin, Chem. Commun., 2005, 3673-3675.
2
R. Natarajan, G. Savitha, P. Dominiak, K. Wozniak and J.N.
Moorthy, Angew. Chem. Int. Ed., 2005, 44, 2115-2119.
2
X. Li, R. Cao, Y. Sun, W. Bi, X. Li and Y. Wang, Eur. J. Inorg.
Chem., 2005, 321-329.
D. Sun, W. Bi, X. Li and R. Cao, Inorg. Chem. Commun., 2004, 7,
683-686.
2
55
Me3X, X = Ga, In, Tl
Connected via X-CH3...X
interactions. Topology is that of
gismondine (gis), (4.4.4.82.8.8).
Ag2L2(SbF6)2.4MeOH.CHCl3, L =
4,4',4''-tricyanotriphenylmethanol
Zn2(µ-OH)(4-pyridylbenzoate) 3.EtOH
(MeLi)4(tmeda)2, tmeda = N, N, N',N'tetramethylethylendiamine
(42.63.8) or SrAl2 (sra) topology. 2
Ag(4,4'-bipyridine)BF4
Cd(en)Cd(CN)4
Zn(bdc)(bpeta).solv, bdc = 1,3benzenedicarboxylate, bpeta = 1,2bis(4-pyridyl)ethane, solv = MeOH,
MeOH/naphthalene, CH2Cl2
Ag(NCC(C(CN)2)2)
Ag(pybut)BF4.MeCN, pybut = 1,4bis(4-pyridyl)butadiyne
NaCo(CO)4
[Cu2(chtpy)3](NO3)2, chtpy = a,a-1,4dihydroxy-e,e,e,e-1,2,4,5-tetra(4pyridyl)cyclohexane
2
(42.63.8) or SrAl2 (sra) topology. 5
If Li atoms nodes, then topology 2
is (33.123) dia-a topology. If
Li4Me4 clusters nodes, then
diamond.
CdSO4 (cds) topology.
3
Four-connected net which can be 2•
related to a diamond net where
the nodes are Cd(CN)4 squares.
With Cd nodes, topology is
(45.62.8) or gismondine (gis).
3
(65.8) topology.
Tetranodal net with
(43.63)2(42.82.102)(43.63)2(42.63.
8) topology.
CdSO4 (cds) nets if long Ag...F
interactions (2.948 Å) taken into
account.
Na and Co 4-connecting nodes,
SrAl2 (sra) topology.
Moganite topology. H-bonded
NO3 anions crosslink nets.
J. Lewinski, J. Zachara, K.B. Starowieyski, I. Justyniak, J.
Lipkowski, W. Bury, P. Kruk and R. Wozniak, Organomet., 2005,
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59, 140-147; R. Boese, A.J. Downs, T.M. Greene, A.W. Hall, C.A.
Morrison and S. Parsons, Organomet., 2003, 22, 2450-2457; G.M.
Sheldrick and W.S. Sheldrick, J. Chem. Soc. A, 1970, 28-30; A.J.
Blake and S. Cradock, J. Chem. Soc., Dalton Trans., 1990, 23932396; N.W. Mitzel, C. Lustig, R.J.F. Berger and N. Runeberg,
Angew. Chem. Int. Ed., 2002, 41, 2519-2522; E.L. Amma and R.E.
Rundle, J. Am. Chem. Soc., 1958, 80, 4141-4145.
S. Ferlay, S. Koenig, M.W. Hosseini, J. Pansanel, A. De Cian and N.
Kyritsakas, Chem. Commun., 2002, 218-219.
O.R. Evans and W. Lin, Chem. Mater., 2001, 13, 2705-12.
H. Koster, D. Thoennes and E. Weiss, J. Organomet. Chem., 1978,
160, 1-5.
L. Carlucci, G. Ciani and D.M. Proserpio, Private Communication,
2002 (CSD Refcode PUYJUO).
S. Nishikiori, T. Iwamoto and Y. Yoshino, Chem. Lett., 1979, 1509;
S. Nishikiori and T. Iwamoto, J. Incl. Phenom., 1985, 3, 283 (as
interpreted in O. Ermer and L. Lindenberg, Helv. Chim. Acta, 1991,
74, 825).
S.A. Bourne, J. Lu, B. Moulton and M.J. Zaworotko, Chem.
Commun., 2001, 861-2.
2
L. Jager, C. Wagner and W. Hanke, J. Mol. Struct., 2000, 525, 107111.
4
A.J. Blake, G. Baum, N.R. Champness, S.S.M. Chung, P.A. Cooke,
D. Fenske, A.N. Khlobystov, D.A. Lemenovskii, W.-S. Li and M.
Schroder, J. Chem. Soc., Dalton Trans., 2000, 4285-4291.
P. Klufers, Z. Kristallogr., 1984, 167, 275-286; P. Klufers, Z.
Kristallogr., 1983, 162, 138.
M.-L. Tong, S. Hu, B. Wang and S.R. Batten, Angew. Chem. Int. Ed.,
2005, 44, 5471-5475.
2
3
56
Eglestonite, [(Hg2)3O2H]Cl3
If ignore H-bonds between nets,
then four (10,3)-a nets.
Otherwise, two 4-connected nets
with %-Si (gsi) topology.
With Ag and C nodes, it’s 3connected (4.122) nbo-a
topology; with Ag2(CNO)2
nodes, it’s 4-connected NbO.
With A, M and S as 4-connecting
nodes, then topology is that of
Sulvanite (Cu3VS4), trinodal
(42.84)3(43.63)4(44) (jsa). With
A3BX4 cages as nodes, then #Po.
PtS nets.
2
2•
Ce(IO3)4
Two enatiomorphic 4-connected
32.104 (lcv) nets which can be
related to (10,3)-a.
(43.62.8) or gis topology.
KC(NO2)3
(42.84) or lvt topology.
2
BaNb3O6
NbO topology.
2
PBr5
SrAl2 or sra topology.
2
(Se6I)(SbF6)
CdSO4 or cds topology.
2
M[B(PO4)(OH)2](H2O)2, M = Mg or
Ni0.5 Mg0.5
Binodal (32.102.112)(32.6.72.8)2
or pcu-h-e topology.
2
Ag(CNO)
Tl3VS4, Tl3TaS4, Tl3TaSe4, K3SbS4,
Na3SbS4, Na3SbSe4, K2BaSnTe4,
PbPbF6, KMF6 (M = Bi, Nb, Sb),
AgTaF6
RhBi4
2
Structural Inorganic Chemistry, 5th edn., A.F. Wells, Oxford
University Press, 1983, 1158; K. Mereiter, J. Zemann and A.W.
Hewat, Am. Mineral., 1992, 77, 839-842; K. Mereiter and J. Zemann,
Tschermaks Mineral. Petrogr. Mitt., 1976, 23, 105-115.
D. Britton, Acta Crystallogr., Sect. C, 1991, 47, 2646-2647; D.
Britton and J.D. Dunitz, Acta Crystallogr., 1965, 19, 662-668.
2
M. Vlasse and L. Fournes, C. R. Acad. Sci. Ser. C, 1978, 287, 47-49;
C. Crevecoeur, Acta Crystallogr., 1964, 17, 757; H. Graf and H.
Schaefer, Z. Anorg. Allg. Chem., 1976, 425, 67-80; B. Eisenmann and
R. Zagler, Z. Naturforsch., Teil B, 1989, 44, 249-256; J. Li, H.-Y.
Guo, D.M. Proserpio and A. Sironi, J. Solid State Chem., 1995, 117,
247-255.
2
P. Charpin, H. Marquet-Ellis, N.G.H.I. Nguyen and P. Plurien, C.R.
Hebd. Seances Acad. Sci. Ser. C, 1972, 275, 1503-1506; C. Hebecker,
Z. Anorg. Allg. Chem., 1971, 384, 12-18; H. Bode and H. von
Boehren, Acta Crystallogr., 1958, 11, 80-82; G.J. Kruger, C.W.F.T.
Pistorius and A.M. Heyns, Acta Crystallogr., Sect. B, 1976, 3, 29162918; K. Matsumoto, R. Hagiwara, Y. Ito and O. Tamada, J. Fluor.
Chem., 2001, 110, 117-122.
Y. Grin, U. Wedig and H.G. von Schnering, Angew. Chem. Int. Ed.
Engl., 1995, 34, 1204, and references therein; G.S. Zhdanov, Trudy
Inst. Krist., Akad. Nauk SSSR, 1954, 10, 99-116.
L.A. Azarova, E.E. Vinogradova, E.M. Mohajlova and V.I.
Pakhomov, Dokl. Akad. Nauk SSSR, 1972, 206, 613-615; D.T.
Cromer and A.C. Larson, Acta Crystallorg., 1956, 9, 1015-1018.
N.I. Golovina and L.O. Atovmyan, Zh. Strukt. Khim., 1967, 8, 307311.
S. Moehr and H. Mueller-Buschbaum, Z. Naturforsch., Teil B, 1994,
49, 915-918.
W. Gabes and K. Olie, Acta Crystallogr., Sect. B, 1970, 26, 443-444;
M. van Driel, C.H. MacGillavray, Recl. Trav. Chim. Pays-Bas Belg.,
1943, 62, 167-171.
W.A.S. Nandana, J. Passmore, P.S. White and C.M. Wong, Inorg.
Chem., 1989, 28, 3320-3328.
H.-Z. Shi, Y.-K. Shan, M.-Y. He and Y.-Y. Liu, Z. Kristallogr. New
Cryst. Struct., 2003, 218, 21-22; I. Boy, G. Schaefer and R. Kniep, Z.
Anorg. Allg. Chem., 2001, 627, 139-143.
2
57
Ice VI
Related to #-Po - actually a 4connected net. Same as
Edingtonite (edi) net.
(42.84)(43.83)4.
H-bonded nets.
2•
B. Kamb, Science, 1965, 150, 205-209; W.F. Kuhs, J.L. Finney, C.
Vettier and D.V. Bliss, J. Chem. Phys., 1984, 81, 3612-3623.
2
(NH4)(N(CN)2) and (NH4)(N(NO2)2)
H-bonded nets. SrAl2 or sra
topology.
2
HX(H2O)2, X = Cl, Br
2
CdCl2[(NH2)2CS]4
H-bonded nets. SrAl2 or sra
topology.
H-bonded (42.84) or lvt nets.
H2S IV h.p.
(42.84) or lvt nets.
2
Rb(H2C6H9)(H2O)0.5
H-bonded CdSO4 nets.
2
T.R.R. McDonald, Acta Crystallogr., 1960, 13, 113-124; M.T.
Rogers and L. Helmholz, J. Am. Chem. Soc., 1940, 62, 1533-1536;
H.-W. Lerner, M. Bolte and N. Wiberg, J. Organomet. Chem., 2002,
649, 246-251; E. Prince and C.S. Choi, Acta Crystallogr., Sect. B,
1978, 34, 2606-2608; Z.V. Zvonkova and G.S. Zhdanov, Zh. Fiz.
Khim., 1949, 23, 1495-1501; C.S. Choi and H.J. Prask, Acta
Crystallogr., Sect. B, 1983, 39, 414-420; M. Ahtee, K.L. Smolander,
B.W. Lucas and A.W. Hewat, Acta Crystallogr., Sect. C, 1983, 39,
651-655; M. Ahtee, K.J. Smolander, B.W. Lucas and A.W. Hewat,
Acta Crystallogr., Sect. B, 1983, 39, 685-687.
B.V. Lotsch, J. Senker, W. Kockelmann and W. Schnick, J. Solid
State Chem., 2003, 176, 180-191; B.V. Lotsch, J. Senker and W.
Schnick, Inorg. Chem., 2004, 43, 895-904; R. Gilardi, J. FlippenAnderson, C. George and R.J. Butcher, J. Am. Chem. Soc., 1997, 119,
9411-9416.
J.O. Lundgren and I. Olovsson, Acta Crystallogr., 1967, 23, 966-971;
R. Attig and J.M. Williams, Angew. Chem., 1976, 88, 507-508.
X.N. Jiang, W.T. Yu, D.R. Yuan, D. Xu, M.K. Lu, X.Q. Wang, S.Y.
Guo and M.H. Jiang, Z. Kristallogr. New Cryst. Struct., 2000, 215,
499-500.
H. Fujihisa, H. Yamawaki, M. Sakashita, K. Aoki, S. Sasaki and H.
Shimizu, Phys. Rev. B, 1998, 57, 2651-2654.
B. Juergens, H.A. Hoeppe and W. Schnick, Z. Anorg. Allg. Chem.,
2004, 630, 35-40.
5-connecting Cu. Network
topology 4664.
2
NH4X, X = HF2, N3, NO3
2
3D 5-connected
Cu(bipy)1.5 Cr2O7.H2O
Cu2(2,5-Me2pyz)(dca)4, 2,5-Me2pyz =
2,5-dimethylpyrazine, dca =
dicyanamide
CMCR.2bpmh.Ph2CO, CMCR = Cmethylcalix[4]resorcinarene, bpmh =
bis(4-pyridylmethylidyne)hydrazine
2
H-bonded nets with CMCR
molecules as nodes.
3
L. Pan, N. Ching, X. Huang and J. Li, Chem. Commun., 2001, 10641065.
W.-F. Yeung, S. Gao, W.-T. Wong and T.-C. Lau, New J. Chem.,
2002, 26, 523-525; J.L. Manson, J.A. Schlueter, H.-J. Koo and M.-H.
Whangbo, Inorg. Chem., 2004, 43, 4007-4011.
B.-Q. Ma and P. Coppens, Chem. Commun., 2003, 412-413.
58
Zn2(OH)(btc)(pipe), btc = 1,3,5benzenetricarboxylate, pipe =
piperazine
CuL1.5 (L2).3H2O, L = 1,1'-(1,4butanediyl)bis(imidazole), H2L2 = 1,1'ferrocenedicarboxylic acid
Cd4(bpa)4(bipy)6.0.5bipy.7H2O, bpa =
4,4'-biphenyldicarboxylate, bipy = 4,4'bipyridine
[Cd(PDCO)(bix)1.5 ].1.5H2O, DPCO =
pyridine-2,6-dicarbosylic acid N-oxide,
bix = 1,4-bis(imidazol-1ylmethyl)benzene
Mn(tcm)2(bpeado), tcm =
tricyanomethanide, bpeado = 1,2-bis(4pyridyl)ethane-N,N'-dioxide
Yb2(OH)(atpt)2.5 (phen)2.1.75H2O,
H2atpt = 2-aminoterephthalic acid, phen
= 1,10-phenanthroline
Nodes are Zn2(OH)(O2CR)
clusters.
2
Z. Shi, G. Li, L. Wang, L. Gao, X. Chen, J. Hua and S. Feng, Cryst.
Growth Des., 2004, 4, 25-27.
46.64 nets.
2
J. Yang, J.-F. Ma, Y.-Y. Liu, S.-L. Li and G.-L. Zheng, Eur. J. Inorg.
Chem., 2005, 2174-2180.
Borazone (46.64) topology.
4
J.C. Dai, X.-T. Wu, S.-M. Hu, Z.-Y. Fu, J.-J. Zhang, W.-X. Du, H.-H.
Zhang and R.-Q. Sun, Eur. J. Inorg. Chem., 2004, 2096-2106.
Unusual network, which I
calculate has 42.63.8 topology.
2
L.-L. Wen, D.-B. Dang, C.-Y. Duan, Y.-Z. Li, Z.-F. Tian, and Q.-J.
Meng, Inorg. Chem., 2005, 44, 7161-7170.
46.64 nets.
2
H.-L. Sun, B.-Q. Ma, S. Gao and S.R. Batten, Cryst. Growth Des.,
2005, 5, 1331-1333.
Yb2(OH) dimers as nodes.
5
C.-B. Liu, C.-Y. Sun, L.-P. Jin and S.-Z. Lu, New J. Chem., 2004, 28,
1019-1026.
Various soft matter (surfactant-water
systems, block copolymers, liquid
crystals).
Nb6F15
See also 'Misc related' section.
,ctahedral centre is a cluster.
2
or
3
2•
Li2Zr6Cl15Mn, LiZr6Cl15Fe,
Zr6Cl15Co, Zr6Cl15Ni
Nb6F15 structure (above).
2•
X. Zeng, G. Ungar and M. Imperor-Clerc, Nature Materials, 2005, 4,
562-567 and references therein; S.T. Hyde, Curr. Opin. Solid State
Mater., 1996, 1, 653-662, and references therein.
H. Schafer, H.-G. Schnering, K.-J. Niehues and H.G. NiederVahrenholz, J. Less-Common Met., 1965, 9, 95-104.
J. Zhang and J.D. Corbett, Inorg. Chem., 1991, 30, 431-435.
Th6Br15M, M = Mn, Fe, Co, Ni, NaFe;
Th6Br15H7
Nb6F15 structure (above).
2•
M(dcbpyH)3, dcbpy2- = 2,2'-bipyridyl5,5'dicarboxylate, M = Co, Rh.6H 2O
H-bonds connect metal
complexes.
2•
3D 6-connected #-Po
F. Böttcher, A. Simon, R.K. Kremer, H. Buchkremer-Hermanns and
J.K. Cockcroft, Z. Anorg. Allg. Chem., 1991, 589-599, 25-44; A.
Simon, F. Böttcher and J.K. Cockcroft, Angew. Chem. Int. Ed. Engl.,
1991, 30, 101.
P.G. Desmartin, A.F. Williams and G. Bernardinelli, New J. Chem.,
1995, 19, 1109; C.J. Matthews, M.R.J. Elsegood, G. Bernardinelli,
W. Clegg and A.F. Williams, Dalton Trans., 2004, 492-497.
59
Cd(mea)(daptn){Ni(CN)4}, mea = 2Aminoethanol, daptn = 1,5Diaminopentane
Mn(N,N'-butylenebisimidazole)3(X)2,
X = BF4, ClO4, ClO4/PF6,ClO4/AsF6
[Zn(H2O)4(bipy)][NO3]2.bipy
)-Mn[Fe(CN)6]
M(bipy) chains connected by MH2O-bipy-H2O-M links and MH2O-(NO3)2-H2O-M links.
Based on powder XRD and
density measurements.
2•
H. Yuge, S. Nishikiori and T. Iwamoto, Acta Crystallogr., Sect. C,
1996, 52, 575.
2•
P.C.M. Duncan, D.M.L. Goodgame, S. Menzer and D.J. Williams,
Chem. Commun., 1996, 2127; L. Ballester, I. Baxter, P.C.M. Duncan,
D.M.L. Goodgame, D.A. Grachvogel and D.J. Williams, Polyhedron,
1998, 17, 3613-3623.
L. Carlucci, G. Ciani, D.M. Proserpio and A. Sironi, J. Chem. Soc.,
Dalton Trans., 1997, 1801-3.
2•
2
M3Co(CN)6, M = Ag, H, H3Fe(CN)6
3•
Ag3CrxCo1-x(CN)6, x = 0.0001 - 1.0
Rb[Cd{Ag(CN)2}3],
K[Co{Au(CN)2}3],K[Cd{Au(CN)2}3],
K[Cd{Ag(CN)2}3]
3•
3•
K[Mn{Ag(CN)2}3]
3
K[Fe{Au(CN)2}3]
3
K2[Na{Ag(CN)2}3]
3
Cd(pyz)(Ag2(CN)3)(Ag(CN)2)
3•
Cu3(tpt)4(ClO4)3
Zn3(tpt)2(CN)3(NO3)3.G, G = guest
molecules
A (3,4)-connected net, or #-Po
arrangement of Cu6(tpt)46+
clusters.
A (3,4)-connected net, or #-Po
arrangement of clusters.
2•
2•
W.E. Buschmann and J.S. Miller, Inorg. Chem. Commun., 1998, 1,
174-176.
L. Pauling and P. Pauling, Proc. Natl. Acad. Sci. USA, 1968, 60, 362367; A. Ludi and H.U. Gudel, Helv. Chim. Acta, 1968, 51, 17621765; H.U. Gudel, A. Ludi and P. Fischer, J. Chem. Phys., 1972, 56,
674-675; H.U. Gudel, A. Ludi, P. Fischer and W. Halg, J. Chem.
Phys., 1970, 53, 1917-1923; H.U. Gudel, A. Ludi and H. Burki, Helv.
Chim. Acta, 1968, 51, 1383-1389; A. Ludi, H.U. Gudel and V.
Dvorak, Helv. Chim. Acta, 1967, 50, 2035; R. Haser, C.E. de Broin
and M. Pierrot, Acta Crystallogr., Sect. B, 1972, 28, 2530-2537.
A.D. Kirk, H.L. Schlafer and A. Ludi, Can. J. Chem., 1970, 48, 1065.
B.F. Hoskins, R. Robson and N.V.Y. Scarlett, J. Chem. Soc., Chem.
Commun., 1994, 2025-2026; S.C. Abrahams, J.L. Bernstein and R.
Liminga, J. Chem. Phys., 1980, 73, 4585-4590; B.F. Hoskins, R.
Robson and N.V.Y. Scarlett, unpublished results.
U. Geiser and J.A. Schlueter, Acta Crystallogr., Sect. C, 2003, 59,
i21-i23.
W. Dong, L.-N. Zhu, Y.-Q. Sun, M. Liang, Z.-Q. Liu, D.-Z. Liao, Z.H. Jiang, S.-P. Yan and P. Cheng, Chem. Commun., 2003, 2544-2545.
M. Zabel, S. Kuhnel and K.-J. Range, Acta Crystallogr., Sect. C,
1989, 45, 1619-1621.
T. Soma, H. Yuge and T. Iwamoto, Angew. Chem. Int. Ed. Engl.,
1994, 33, 1665.
B.F. Abrahams, S.R. Batten, H. Hamit, B. F. Hoskins and R. Robson,
Angew. Chem. Int. Ed. Engl., 1996, 35, 1690-2; Angew. Chem., 1996,
108, 1794-6.
S.R. Batten, B.F. Hoskins and R. Robson, J. Am. Chem. Soc., 1995,
117, 5385; S.R. Batten, B.F. Hoskins, R. Robson and D. Slizys,
unpublished results.
60
)-Hydroquinone
Clathrates also; H-bonding. Can
be related to #-Po.
2•
Ice VI
Related to #-Po - actually a 4connected net. Same as
Edingtonite (edi) net.
(42.84)(43.83)4.
Oct. Rh bridged by
Me3Sn(SCN)2 bridges.
2•
(Me3Sn)3Rh(SCN)6
Zn(bib)3(BF4)2 and Co(bib)3(NO3)2,
bib = bis(imidazole)butyne
Cd(bix)3(An)3, An = ClO4, NO3 bix =
1,4-bis(imidazol-1-ylmethyl)butyne
Ag(tcm)(bpe)
M5H(CN2)3, M = Na, K
[Ln(ntb)2](ClO4)3.3bipy.nH2O, Ln =
Eu (n = 2), Tb (n = 1), Nd (n = 2),
[Nd(ntb)2](ClO4)3.3bpe.H2O, ntb =
tris(2-benzimidazolylmethyl)amine
[CuCN.Me3SnCN.0.5bipy]
D.E. Palin and H.M. Powell, J. Chem. Soc., 1947, 208; H.M. Powell
in Non-Stoichiometric Compounds, ed. L. Mandelcorn, Academic
Press, New York, 1964, Ch. 7, 438; D.D. MacNicol in Inclusion
Compounds, eds. J.L. Atwood, J.E.D. Davies and D.D. MacNicol,
Academic Press, London, 1984, vol. 2, Ch. 1, and references therein;
T.C.W. Mak, J.S. Tse, C.-S. Tse, K.-S. Lee and Y.-H. Chong, J.
Chem. Soc., Perkin Trans. 2, 1976, 1169; J.C.A. Boeyens and J.A.
Pretorius, Acta Crystallogr., Sect. B, 1977, 33, 2120; T.C. Mak and
K.-A. Lee, Acta Crystallogr., Sect. B, 1978, 34, 3631; H.M. Powell,
J. Chem. Soc., 1950, 300.
B. Kamb, Science, 1965, 150, 205-209; W.F. Kuhs, J.L. Finney, C.
Vettier and D.V. Bliss, J. Chem. Phys., 1984, 81, 3612-3623.
2•
E. Siebel and R.D. Fischer, Chem. Eur. J., 1997, 3, 1987-1991.
3
B.F. Abrahams, B.F. Hoskins, R. Robson and D.A. Slizys,
CrystEngComm, 2002, 4, 478-482.
B.F. Abrahams, B.F. Hoskins, R. Robson and D.A. Slizys,
CrystEngComm, 2002, 4, 478-482.
B.F. Abrahams, S.R. Batten, B.F. Hoskins and R. Robson, Inorg.
Chem., 2003, 42, 2654-2664.
3
Weak interactions within the
frameworks. Related to #-Po,
with Ag2 dimers as nodes.
M = K, Na isomorphous.
2
-ets generated by H-bonding
between [Ln(ntb) 2]3+ and bipy's
or bpe's.
2
Also deposited with CSD 'new
compounds of relevence to (this
compound)':
Et3SnCN.CuCN.bipy (No. 407
643), Me3SnCN.CuCN.pyz (No.
407 644), and Me3SnCN.CuCN.
pym (No. 407 656).
2
2
M. Becker and M. Jansen, J. Chem. Research (S), 1998, 86-87; M.
Becker, M. Jansen, A. Lieb, W. Milius and W. Schnick, Z. Anorg.
Allg. Chem., 1998, 624, 113-118.
C.-Y. Su, B.-S. Kang, H.-Q. Liu, Q.-G. Wang and T.C.W. Mak,
Chem. Commun., 1998, 1551-2; C.-Y. Su, B.-S. Kang, Q.-C. Yang
and T.C.W. Mak, J. Chem. Soc., Dalton Trans., 2000, 1857-1862.
A.M.A. Ibrahim, E. Siebel and R.D. Fischer, Inorg. Chem., 1998, 37,
3521-3525.
61
#-M(dca)2(pyz),
Cu, Zn
MII
2
= Mn, Fe, Co, Ni,
M(dca)2(bipy), M = Fe, Co, Ni
2
Cu(dca)2(bpe)2, bpe = 1,2-bis(4pyridyl)ethane, dca = dicyanamide
M(dca)2(bipy)(H2O).0.5MeOH, M =
Mn, Fe, Co
One briding dca and one
2
uncoordinated dca.
1D tubes - H-bonding links tubes 2
into 2 separate #-Po like nets.
Fe(dca)2(bipy)(H2O)2.bipy
H-bonded nets.
Cu(pyz)[Au(CN)2]2
Two #-Po networks if long Cu-N 2
interactions (2.4 Å) taken into
account (not by authors)!
Only Cu structure done.
2
M(pyz)[Au(CN)2]2, M = Co, Ni, Cu
Fe(pyz)[Ag(CN)2]2.pyz, pyz = pyrazine
2
2
P. Jensen, S.R. Batten, G.D. Fallon, D.C.R. Hockless, B. Moubaraki,
K.S. Murray and R. Robson, J. Solid State Chem., 1999, 145, 387393; P. Jensen, S.R. Batten, B. Moubaraki, and K.S. Murray, J. Solid
State Chem., 2001, 159, 352-361; J.L. Manson, C.D. Incarvito, A.L.
Rheingold and J.S. Miller, J. Chem. Soc., Dalton Trans., 1998, 37053706; J.L. Manson, Q. Huang, J.W. Lynn, H-J. Koo, M-H. Whangbo,
R. Bateman, T. Otsuka, N. Wada, D.N. Argyriou and J.S. Miller, J.
Am. Chem. Soc., 2001, 123, 162-172; C.M. Brown and J.L. Manson,
J. Am. Chem. Soc., 2002, 124, 12600-12605.
P. Jensen, S.R. Batten, B. Moubaraki, and K.S. Murray, J. Chem.
Soc., Dalton Trans., 2002, 3712-3722; B.-W. Sun, S. Gao, B.-Q. Ma
and Z.-M. Wang, New. J. Chem., 2000, 24, 953-954; S. Martin, M.G.
Barandika, J.M. Ezpeleta, R. Cortes, J.I.R. de Larramendi, L. Lezama
and T. Rojo, J. Chem. Soc., Dalton Trans., 2002, 4275-4280.
S. Dalai, P.S. Mukherjee, J. Ribas, C. Diaz, E. Zangrando and N.R.
Chaudhuri, Ind. J. Chem., 2003, 42A, 2250-2255.
P. Jensen, S.R. Batten, B. Moubaraki and K.S. Murray, J. Chem. Soc.,
Dalton Trans., 2002, 3712-3722; see also J.L. Manson, C.D.
Incarvito, A.M. Arif, A.L. Rheingold, and J.S. Miller, Mol. Cryst.
Liq. Cryst., 1999, 334, 605-613; J.L. Manson, A.M. Arif, C.D.
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State Chem., 1999, 145, 369-378; S. Martin, M.G. Barandika, J.M.
Ezpeleta, R. Cortes, J.I.R. de Larramendi, L. Lezama and T. Rojo, J.
Chem. Soc., Dalton Trans., 2002, 4275-4280.
P. Jensen, S.R. Batten, B. Moubaraki and K.S. Murray, J. Chem. Soc.,
Dalton Trans., 2002, 3712-3722.
W.-F. Yeung, W.-T. Wong, J.-L. Zuo and T.-C. Lau, J. Chem. Soc.,
Dalton Trans., 2000, 629-631.
D.B. Leznoff, B-Y. Xue, C.L. Stevens, A. Storr, R.C. Thompson and
B.O. Patrick, Polyhedron, 2001, 20, 1247-1254.
V. Niel, M.C. Munoz, A.B. Gaspar, A. Galet, G. Levchenko and J.A.
Real, Chem. Eur. J., 2002, 8, 2446-2453.
62
[H6Mn3V18O42(H2O)12(VO4)].30H2O,
Li6[Fe3V18O42(H2O)12(VO4)].24H2O,
Li6[M3V18O42(H2O)12(XO4)].24H2O
(M = Cd, Mn),
(N2H5)2[M3V18O42(H2O)12(XO4)].24
H2O (M = Mg, Ca),
[M3V18O42(H2O)12(XO4)].24H2O (M
= Fe, Co), X = V/S,
Li6[Ni3V18O42(H2O)12(SO4)].24H2O
Tb2(ADB)3(Me2SO)4.16Me2SO, ADB
= 4,4'-azodibenzoate, C 12H8N2(CO2)2
Zn4O(L)3, L = various bridging linear
dicarboxylates
[Mn(bpe)(H2O)4](ClO4)2(bpe)4, bpe =
1,2-bis(4-pyridyl)ethane
V18O42(XO4) clusters bridged by 2
M(H2O)4 units.
M.I. Khan, E. Yohannes and R.J. Doedens, Angew. Chem. Int. Ed.,
1999, 38, 1292-1294; Angew. Chem., 1999, 111, 1374-1376; M.I.
Khan, J. Solid State Chem., 2000, 152, 105-112; M.I. Khan, E.
Yohannes and D. Powell, Inorg. Chem., 1999, 38, 212-213; M.I.
Khan, E. Yohannes, R.J. Doedens, S. Tabussum, S. Cevik, L. Manno
and D. Powell, Cryst. Eng., 1999, 2, 171-179; R.J. Doedens, E.
Yohannes and M.I. Khan, Chem. Commun., 2002, 62-63.
,ctahedral nodes are Tb 2C6O12
dimers.
Both single networks and doubly
interpenetrating #-Po nets found.
Nets involvine both coord.
bonding and H-bonding b/w bpe
and H2O - one link is a 'triple'
link. The mode of intptn is
unprecedented.
Zn4(µ3-OH)2 nodes.
2
T.M. Reineke, M. Eddaoudi, D. Moler, M. O'Keeffe and O.M. Yaghi,
J. Am. Chem. Soc., 2000, 122, 4843-4844.
M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O'Keeffe
and O.M. Yaghi, Science, 2002, 295, 469-472.
C.S. Hong, S.-K. Son, Y.S. Lee, M.-J. Jun and Y. Do, Inorg. Chem.,
1999, 38, 5602-5610.
Binuclear nodes with slightly
different bonding within nodes in
each structure.
Cd(tp)(bipy), tp = terephthalate, bipy = M3(O2CR)4 nodes (different to
4,4'-bipyridine
above structure).
Cu2(tp)4(bipy), tp = terephthalate
Cu2(OAc)4 - like nodes; structure
proposed based on models which
apparently fit the PXRD well.
Proposed structure different to
those above.
[NiL2(H2O)2](NO3)2•C6H6•5MeOH, L Nets constructed from (4,4) sheet
cross-linked by M= 1,4-bis(4-pyridyl)benzene
OH2(NO3)2(MeOH)2H2O-M Hbonded rings.
2
Zn4(OH)2(fa)3(4,4'-bipy)2, fa =
fumarate
M(tp)(bipy), M = Co, Cd, Zn, tp =
terephthalate
2
2
2
2
J. Tao, M.-L. Tong, J.-X. Shi, X.-M. Chen and S. Weng Ng, Chem.
Commun., 2000, 2043-2044.
J. Tao, M-L. Tong and X.-M. Chen, J. Chem. Soc., Dalton Trans.,
2000, 3669-3674.
2
J.C. Dai, X.-T. Wu, S.-M. Hu, Z.-Y. Fu, J.-J. Zhang, W.-X. Du, H.-H.
Zhang and R.-Q. Sun, Eur. J. Inorg. Chem., 2004, 2096-2106.
K. Seki, Phys. Chem. Chem. Phys., 2002, 4, 1968-1972; R. Kitaura,
K. Seki, G. Akiyama and S. Kitagawa, Angew. Chem. Int. Ed., 2003,
42, 428-431.
2
K. Biradha and M. Fujita, J. Chem. Soc., Dalton Trans., 2000, 38053810.
63
M(tpyp).solv (M = Zn, solv =
MeOH.H2O or H2O; M = Co, solv =
2CH3CO2H.2H2O; M = Mn, solv =
10H2O; M = Mn, solv = 2EtOH.4H 2O),
tpyp = tetrapyridylporphyrin
AgTe3
Some of the nodes are 6membered H2O H-bonded rings
which are H-bonded to free
pyridyl rings.
2
Two #-Po nets, but only if use
2
Ag-Te connections (3.02, 3.08
Å), and ignore Te-Te connections
(3.05 vs. 3.02 Å in Te metal).
Tl3VS4, Tl3TaS4, Tl3TaSe4, K3SbS4,
With A, M and S as 4-connecting 2
nodes, then topology is that of
Na3SbS4, Na3SbSe4, K2BaSnTe4
Sulvanite (Cu3VS4), trinodal
(42.84)3(43.63)4(44) (jsa). With
A3BX4 cages as nodes, then #Po.
M(btzb)3(An)2, M = Fe, Ni, Cu, btzb = First paper tentatively says 2
3
nets,
based
on
poorly
resolved
1,4-bis(tetrazol-1-yl)butane, An = ClO4,
solution; later corrected to 3.
PF
6
W(OPhOH)6.2(1,2-di-4-pyridylethane)
H-bonded nets; looks like #-Po.
2
W(OPhOH)6.3(1,2-di-4pyridylethane).THF
M(NO3)2(H2O)4.2L, M = Co, Ni, L =
4,4'-bipyridine-N,N'-dioxide
H-bonded nets; looks like #-Po.
3
Co(bipy)2Cr2O7
(ZnTCPP){1,2-bis(4,4'-bipyridinio)
ethane-dibenzo-24-crown-8}.4H2O,
TCPP =
tetrakis(carbosyphenyl)porphyrin
[Fe(bte)2(BF4)2], bte = 1,2-bis-(1,2,4triazol-1-yl)-ethane
H-bonded nets; octahedral 'nodes' 2
consist of a {M(H2O)2}2L4
cluster with the same topology as
that seen in Cu3tpt4 (see above).
2
#-Po nets, with H-bonding.
2
2
H. Krupitsky, Z. Stein, I. Goldberg and C.E. Strouse, J. Incl.
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J.A. Kolnaar, Ph.D. thesis, Leiden University, Leiden, 1998,
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64
NavHw[Mo12O46(C6H4As-4COOH)4].xH2O
[Cu2L2(bipy)].0.5H2O, L = fumarate
LnL3(ClO4)3.H2O, Ln = Er, Yb, L =
1,2-bis(4-pyridyl)ethane-N,N'-dioxide
Zn8(XO4)(L)6, X = Si, Ge, L =
terephthalate dianion
M(adipate)(L), M = Co, Mn, L = 1,2bis(4-pyridyl)ethane, 1,2-bis(4pyridyl)ethene
M(adipate)(bipy), M = Mn, Zn, bipy =
4,4'-bipyridine
H-bonding gives two parallel
2
interpenetrating (4,4) nets of
clusters; clusters then linked by
O-Na-O bridges to adjoining
layers to give two intptng 3D nets
with 6-connected clusters. If #Po, then a new mode of intptn.
Cu2 nodes.
2
H-bonding between nets.
2
Zn8(XO4) nodes linked by
double terephthalate bridges into
#-Po nets.
Nodes are M2 dimers.
2
2
Normal mode of interpenetration, 2
with M2(O2CR)2 nodes.
Cd(succinate)(bipy).1/4H2O, bipy =
4,4'-bipyridine
Co(L1)(L2), L1 = 1,2-bis(4pyridyl)ethane, L2 = terephthalate
Cd2(C4H4O4)2(C4N2H8)(H2O)3
Normal mode of interpenetration, 2
with M2(O2CR)2 nodes.
Normal mode of interpenetration, 2
with Co2(O2CR)2 nodes.
2
Na3Cd5(C4H4O4)6X, X = Cl, Br
Clusters as nodes.
[M(H2O)4]3[W6S8(CN)6].ca.23H2O, M Clusters as nodes.
= Mn, Fe, Co
[Ru2(O2CMe)4]3[M(CN)6], M = Cr, Fe, M nodes and Ru2 links, proposed
Co
on the basis of powder diffraction
indexing only.
Cu2(4-pya)3, 4-pya = 4Cu2 dimers as nodes.
pyridinecarboxylate
Cd(bpe)2(ClO4)2, bpe = 1,2-bis(4pyridyl)ethane
2
2
B.J.S. Johnson, R.C. Schroden, C. Zhu and A. Stein, Inorg. Chem.,
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S. Dalai, P.S. Mukherjee, E. Zangrando, F. Lloret and N.R.
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2003, 3, 47-51.
S. Jin and F.J. DiSalvo, Chem. Mater., 2002, 14, 3448-3457.
2
Y. Liao, W.W. Shum and J.S. Miller, J. Am. Chem. Soc., 2002, 124,
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2
M.-L. Tong, L.-J. Li, K. Mochizuki, H.-C. Chang, X.-M. Chen, Y. Li
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3
65
(Me3Sn)4Fe(CN)6.2H2O.C4H8O2
C(C6H4OH)4
[Zn(p-CO2)P2Mes2P]3Zn4O, (pCO2)P2Mes2P = 5,15-di(pcarboxyphenyl)-10,20-di(2',4',6'trimethylphenyl)porphyrinate(-2)
M3(2,6-NDC)2(bipy)1.5 , M = Ni, Co,
2,6-NDC = 2,6naphthalenedicarboxylate
[Co(H2O)2(bipy)2](NO3)2.2bipy.2H2O
M2(bpda)2(dpe), bpda = 1,1'-biphenyl3,3'-dicarboxylate, bpe = 1,2-di(4pyridyl)ethylene, M = Cd, Co.solv
Nets defined by both
coordination and hydrogen
bonding.
H-bonded nets.
2
M. Adam, A.K. Brimah, R.D. Fischer and L. Xing-Fu, Inorg. Chem.,
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2
Zn4O clusters as nodes.
2
J.-H. Fournier, T. Maris, M. Simard and J.D. Wuest, Cryst. Growth
Des., 2003, 3, 535-540.
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42, 7719-7721.
Nets defined by combination of
coordinate, hydrogen-bonding
and &-& stacking interactions.
M2(O2CR)4 dimers as nodes.
[ML3(H2O)(OTf)][Cl][OTf]7, M = Sm, Ligands are [2]pseudorotaxanes
with dipyridinium N-oxide axles
Eu, Gd, Tb
and dibenzo-[24]crown ether
wheels.
[Zn4O(L1)3(dmf)2].4DMF.3MeOH.2H2 Nodes are Zn4(µ-O) clusters.
O and [Zn4O(L2)3].5DMF.5EtOH.H2O,
H2L1 = 6,6'-dichloro-2,2'-diethoxy-1,1'binaphthyl-4,4'-dibenzoic acid, H2L2 =
6,6'-dichloro-2,2'-dibenzyloxy-1,1'binaphthyl-4,4'-dibenzoic acid
Pb(bpno)(NO3)2.H2O, bpno = 4,4'4,4 sheets crosslinked by weak
Pb-O interactions.
bipyridine N,N'-dioxide
Cd2(bipy)(3,3'-bpda)2, bipy = 4,4'Cd2(O2CR)4 nodes.
bipyridine, 3,3'-bpda = 1,1'-biphenyl3,3'-dicarboxylate
Mn(phth)(bipy), phth = p-phthalate,
M2(O2CR)2 nodes.
bipy = 4,4'-bipyridine
Cu(bbtz)3(ClO4)2.2EtOH, bbtz = 1,4di(1,2,3,4-tetrazol-2-yl)butane
3
S.W. Lee, H.J. Kim, Y.K. Lee, K. Park, J.-H. Son and Y.-U. Kwon,
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2
M. Felloni, A.J. Blake, N.R. Champness, P. Hubberstey, C. Wilson
and M. Schroder, J. Supramol. Chem., 2002, 2, 163-174.
3
R. Wang, M. Hong, D. Yuan, Y. Sun, L. Xu, J. Luo, R. Cao and
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2
4
B. Kesanli, Y. Cui, M.R. Smith, E.W. Bittner, B.C. Bockrath and W.
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2
Y. Xu, D. Yuan, L. Han, E. Ma, M. Wu, Z. Lin and M. Hong, Eur. J.
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3
2
2
C. Ma, C. Chen, Q. Liu, D. Liao, L. Li and L. Sun, New J. Chem.,
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Zn2(1,4-bdc)2(bipy), 1,4-bdc = 1,4benzenedicarboxylate, bipy = 4,4'bipyridine
Zn2(2,6-ndc)2(bipy), 2,6-ndc = 2,6naphthalenedicarboxylate, bipy = 4,4'bipyridine
Cd(bte)3(NO3)2, bte = 1,2-bis(1,2,4triazol-1-yl)ethane
Cu(dpe)(dpa), dpe = 1,2-di(4pyridyl)ethylene, H2dpa = diphenic acid
Co(adipate)(bipy), bipy = 4,4'bipyridine
Cu(imidazole)2(HL)2, H2L = adipic
acid
ScL3(An)3, L = 4,4'-bipyridine-N,N'dioxide, An = ClO4, NO3
Cd2(isonic)4(bpe)(H2O)2, isonic =
isonicotinate, bpe = 1,2-bis(4pyridyl)ethene
Zn2L2L'.solvent, H2L = fumaric acid,
1,4-benzenedicarboxylic acid, 2,6naphthalenedicarboxylic acid, 1,4biphenyldicarboxylic acid, L' = 4,4'bipyridine, N, N'-di(4-pyridyl)-1,4,5,8naphthalenetetracarboxdiimide
2,2',6,6'-tetramethyl-4,4'-terphenyldiol
Cu(hfipbb)(H2hfipbb)0.5 , H2hfibpp =
4,4'-(hexafluoroisopropylidene)bis(benzoic acid)
Zn(bim)3(NO3)2.4H2O, bim = 1,2bis(imidazol-1-yl)ethane
M(Cr2O7)(4,4'-bipyridine)2, M = Ni,
Cu
M2(O2CR)4 nodes.
2
H. Chun, D.N. Dybstev, H. Kim and K. Kim, Chem. Eur. J., 2005,
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M2(O2CR)4 nodes.
3
H. Chun, D.N. Dybstev, H. Kim and K. Kim, Chem. Eur. J., 2005,
11, 3521-3529.
2
B. Li, X. Zhu, J. Zhou, Y. Peng and Y. Zhang, Polyhedron, 2004, 23,
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2
M2(O2CR)2 nodes.
2
H-bonded nets.
2
2
3
H-bonded nets.
2
B.-Q. Ma, K.L. Mulfort and J.T. Hupp, Inorg. Chem., 2005, 44, 49124914.
4
2
S. Aitipamula and A. Nangia, Chem. Commun., 2005, 3159-3161.
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2
2
67
Ni3(oba)2(bpy)2(Hoba)2(H2O)2.bpy.2H Heavily interdigitated (4,4)
2O, oba = 4,4'-oxybis(benzoate), bpy = sheets with arms projecting
above and below. Each sheet
4,4'-bipyridine
penetrated by arms from four
others, however if hydrogen
bonds between dangling arms
and coordinated water ligands are
taken into account, then three
interpenetrating alpha-Po nets are
formed.
1,4-bis(dibromomethylidene)
Nets defined by Br...Br and
cyclohexane
Br...pi interactions.
Cd(bimb)2Cl2, bimb = 4,4'(4,4) coordination polymers
sheets linked by C-H...Cl
bis(imidazol-1-ylmethyl)biphenyl
interactions.
Ln(INO)(H2O)SO4, Ln = Nd, Sm. Eu, Ln2O2 nodes.
Gd, Tb, HINO = isonicotinic acid,
Cu3(CN)(IN)2, IN = isonicotinate
Zn4(OH)2(bdc)3(dmso)4.2H2O, bdc =
1,4-benzenedicarboxylate
K[CdL3], L = 1,3-bis(4nitrophenyl)triazenido
Ti2L3(i-propoxy)2(i-propanol)2, H2L =
4,4'-dihydroxybiphenyl
Cu(dca)2(cypy)2, dca = dicyanamide,
cypy = 3- or 4-cyanopyridine
3
X.-L. Wang, C. Qin, E.-B. Wang, Y.-G. Li, Z.-M. Su, L. Xu and L.
Carlucci, Angew. Chem. Int. Ed., 2005, 44, 5824-5827.
2
P.G. Jones, J. Kampen, P. Bubenitschek and H. Hopf, Acta
Crystallogr., Sect. E, 2005, 61, o2179-o2180.
W. Zhao, H.-F. Zhu, T.-A. Okamura, W.-Y. Sun and N. Ueyama,
Supramol. Chem., 2003, 15, 345-352.
2
2
Four interpenetrating diamond
2
nets if Cu...Cu interactions (2.698
Å) are ignored. If not, then two
alpha-Po nets with Cu2 moieties
as nodes.
Nodes are Zn4O2 clusters.
2
Cd and K nodes.
2
Ti2 dimer nodes.
2
1D chains crosslinked by weak
2
C-H...N interactions. If
Cu(cypy)2 moieties treated as
nodes, then alpha-Po. If Cu and
cypy considered separate nodes,
then 3,6-connected nets. In the 3cypy structure nets are
crosslinked by weaker C-H...N
interactions.
Z. He, E.-Q. Gao, Z.-M. Wang, C.-H. Yan and M. Kurmoo, Inorg.
Chem., 2005, 44, 862-874; Z. he, Z.-M. Wang and C.-H. Yan,
CrystEngComm, 2005, 7, 143-150.
Y. Kang, Y.-G. Yao, Y.-Y. Qin, J. Zhang, Y.-B. Chen, Z.-J. Li, Y.-H.
Wen, J.-K. Cheng and R.-F. Hu, Chem. Commun., 2004, 1046-1047.
R. Wang, M. Hong, Y. Liang and R. Cao, Acta Crystallogr., Sect. E,
2001, 57, m277-m279.
M. Horner, V.S. Carratu, R. Herbst-Irmer, C.M. Mossmer and J.
Strahle, Z. Anorg. Allg. Chem., 2003, 629, 219-222.
J.M. Tanski, E.B. Lobkovsky and P. Wolczanski, J. Solid State
Chem., 2000, 152, 130-140.
M. Du, X.-J. Zhao, S.R. Batten and J. Ribas, Cryst. Growth Des.,
2005, 5, 901-909.
68
#-Ag 3BO3
)-Ag 3BO3
Li9B19S33
[M(H2O)4]3(W6S8(CN)6)(H2O)x, M =
Co, Fe, Mn, x = 23.13, 24.62, 23.4
Ln2O3, Ln = La, Nd
Fe(OH)Te2O5 (Mackayite)
With B, O nodes, topology is 3connected (10,3)-a net; if BO3
units nodes, the #-Po.
With B, O nodes, topology is 3connected binodal (10,3) net; if
BO3 units nodes, the #-Po.
Nodes are B/S clusters.
2
M. Jansen and W. Scheld, Z. Anorg. Allg. Chem., 1981, 477, 85-89.
2
M. Jansen and G. Brachtel, Z. Anorg. Allg. Chem., 1982, 489, 42-46.
2
W6S8 clusters as nodes.
2
F. Hiltmann, P. zum Hebel, A. Hammerschmidt and B. Krebs, Z.
Anorg. Allg. Chem., 1993, 619, 293-302.
S. Jin and F.J. Disalvo, J. Biochem., 2002, 14, 3448-3457
Fe2Te4O4 nodes.
2
2
Hg3CdCl2(SCN)6
2
(NH4)6(MMo9O32)(H2O)6, M = Mn, Ni Clusters as nodes; H-bonded nets. 2
LiNa2H[Al(PO4)2(OH)] (tancoite)
H-bonded nets.
2
P. Aldebert and J.P. Traversse, Mater. Res. Bull., 1979, 14, 303-323.
F. Pertlik and A. Gieren, Neues Jahrb. Mineral. Monatsch., 1977,
145-154; F. Pertlik, Anz. Oesterr. Akad. Wiss. Math.: Naturwiss. K1,
1968, 105, 332-333; F. Pertlik, Tschermaks Mineral. Petrogr. Mitt.,
1969, 13, 219-232.
A. Mosset, M. Bagieu-Beucher, A. Lecchi, R. Masse and J. Zaccaro,
Solid State Sci., 2002, 4, 827-834.
H. Stratemeier, M.A. Hitchman, D.L. Kepert, B.W. Skelton, K.E.
Sugars and A.H. White, J. Chem. Soc., Dalton Trans., 1992, 30353039; T.J. Weakley, Acta Crystallogr., 1987, 43, 2221-2222.
F.C. Hawthorne, Tschermaks Mineral. Petrogr. Mitt., 1983, 31, 121135.
3D 6-connected other
Eu[Ag(CN)2]3.3H2O and
6-connected 3D net. Each
3•
identical
net
has
hexagonal
La[M(CN)2]3.3H2O, M = Ag, AgxAuy,
channels, whose sides are
Au
composed of zigzaging Eu-CNAg-CN-Eu links. The water
molecules are trans to two CN's
on the Eu, and point between two
links of another net. Close
contacts between the Ag's.
Interpenetrating nets not
remarked upon by authors.
Topology is (49.66) acs.
Cd(BPhDC)(BPE)(H2O), H2BPhDC = H-bonding crosslinks nets. Has
3
8
4
3
biphenyl-4,4'-dicarboxylic acid, BPE = (4 .5 .6 ) or )-Sn topology.
1,2-bis(4-pyridyl)ethane
Z. Assefa, R.J. Staples and J.P. Fackler Jr., Acta Crystallogr., Sect. C,
1995, 51, 2527-2529; J.C.F. Colis, C. Larochelle, R. Staples, R.
Herbst-Irmer and H. Patterson, Dalton Trans., 2005, 675-679.
F.A.A. Paz, Y.Z. Khimyak, A.D. Bond, J. Rocha and J. Klinowski,
Eur. J. Inorg. Chem., 2002, 2823-2828.
69
[YbL3(OTf)][Cl][OTf]7
Complicated and novel topology. 2
Ligands are [2]pseudorotazanes
with dipyridinium N-oxide axles
and dibenzo-[24]crown ether
wheels.
H-bonded nets. Topology is
2
(49.66) acs.
D.J. Hoffart and S.J. Loeb, Angew. Chem. Int. Ed., 2005, 44, 901904.
8-Connecting nodes are
M3(CO2)6 clusters bridged by 6
bpdc into a (3,6) sheet; these
sheets are then connected
together by bipy ligands.
2
Tetrakis[(4Each molecule connected to 8
nitrobiphenoxy)methyl]methane.2DMS others via C-H...O interactions,
O
however can be regarded as a
diamond nets if the nodes
alternate between the central C
atoms and H-bonded square ring
motifs.
Tetrakis[(4Each molecule connected to 8
aminophenoxy)methyl]methane
others via N-H...N interactions,
however can be regarded as a
diamond nets if the nodes
alternate between the central C
atoms and H-bonded square ring
motifs.
4
L. Pan, H. Liu, X. Lei, X. Huang, D.H. Olson, N.J. Turro and J. Li,
Angew. Chem. Int. Ed., 2003, 42, 542-546; Q. Fang, X. Shi, G. Wu,
G. Tian, G. Zhu, R. Wang and S. Qiu, J. Solid State Chem., 2003,
176, 1-4; Q.-R. Fang, X. Shi, G. Wu, G. Tian, G.-S. Zhu, Y.-F. Li, L.F. Wang, C.-L. Wang, Y. Chen, Z.-D. Zhang, Z. Guo, T.-C. Shang,
X.-H. Cai and S.-L. Qiu, Huaxue Xuebao, 2002, 60, 2087-2091.
D. Laliberte, T. Maris and J.D. Wuest, CrystEngComm, 2005, 7, 158160.
C[CH2O-C6H4-C4N3(NH2)2]4
D. Laliberte, T. Maris and J.D. Wuest, J. Org. Chem., 2004, 69,
1776-1787.
3D 8-connected
[M3(bpdc)3(bipy)].solv, M = Co, Zn,
bpdc = biphenyldicarboxylate
3
D. Laliberte, T. Maris, E. Demers, F. Helzy, M. Arseneault and J.D.
Wuest, Cryst. Growth Des., 2005, 5, 1451-1456.
2•
S. Nishikiori, J. Coord. Chem., 1996, 37, 23-38.
2•
R. Gilardi, J. Flippen-Anderson, C. George and R.J. Butcher, J. Am.
Chem. Soc., 1997, 119, 9411-9416.
Nodes with different
connectivity
(3,4)-Connected Nets
K2[Cd(H2O)Cu4(CN)8]1.5H2O
(NH4)[N(NO2)2]
Two enantiomeric 3D 3,4connected nets.
NH4 = 4-C, N3O4- = 2 by 3-C;
H-bonding links.
70
[Ag2Si(p-C6H4CN)4][OTf]2.2C6H6
Ag2(µ4-tta)(µ3-tta), Htta = tetrazole
Ag2L2, L = 1,3bis(dicyanomethylidene)indan
[H2N(CH2)2NH2]1/2ZnHPO3
Cu3(BTB)2(H2O)3.(DMF)9(H2O)2,
H3BTB = 4,4',4''-benzene-1,3,5-triyltribenzoic acid
Ag(tcm)(phz)1/2
Cu(NH3)(py)Ag3-xCux(CN)5.py, py =
pyridine
Cu3(tpt)4(ClO4)3
Zn3(tpt)2(CN)3(NO3)3.G, G = guest
molecules
[Cu(S-py2)]4Mo8O26.2H2O
Related to Ag(tcm)(phz)1/2;
cross-linked into a single, selfpenetrating net thru close Ag-Ag
contacts.
Complicated net with 3- and 4connecting Ag and 3- and 4connecting tta. Topology is
(4.102)Ag(4.8.10)tta(42.83.10)Ag
(42.6.8.102)tta
Very complicated(8 3)2(85.10)
net.
4•
F.-Q. Liu and T.D. Tilley, Inorg. Chem., 1997, 36, 5090-5096.
2
L. Carlucci, G. Ciani and D.M. Proserpio, Angew. Chem. Int. Ed.,
1999, 38, 3488-3492; Angew. Chem., 1999, 111, 3700-3704.
5
I. Ino, J.C. Zhong, M. Munakata, T. Kuroda-Sowa, M. Maekawa, Y.
Suenaga and Y. Kitamori, Inorg. Chem., 2000, 39, 4273-4279.
J.A. Rodgers and W.T.A. Harrison, Chem. Commun., 2000, 23852386.
B. Chen, M. Eddaoudi, S.T. Hyde, M. O'Keeffe and O.M. Yaghi,
Science, 2001, 291, 1021-1023.
2
Two interpenetrating Pt3O4 nets.
2
Bridged puckered hexagonal
Ag(tcm) sheets; tetrahedral Ag.
Ag(tcm) - like, but connections
b/w sheets give a structure
analogous to Ag(tcm)(phz)1/2. If
Ag dimers taken as nodes, then
topology becomes that of rutile.
A (3,4)-connected net, or #-Po
arrangement of Cu6(tpt)46+
clusters.
A (3,4)-connected net, or #-Po
arrangement of clusters.
2•
4-connected net with Cu4L4
squares and Mo8O26 species as
the 'square-planar' 4-connectors.
Interpenetration such that the
Mo8O26 nodes of one net lie in
the centre of the Cu4L4 nodes of
the other net. Could also be
described as a 3,4-connected net,
which Cu as the 3-connector.
2
2•
2•
2•
S.R. Batten, B.F. Hoskins and R. Robson, New J. Chem., 1998, 22,
173-175.
M. Schwarten, J. Chomic, J. Cernak and D. Babel, Z. Anorg. Allg.
Chem., 1996, 622, 1449.
B.F. Abrahams, S.R. Batten, H. Hamit, B. F. Hoskins and R. Robson,
Angew. Chem. Int. Ed. Engl., 1996, 35, 1690-2; Angew. Chem., 1996,
108, 1794-6.
S.R. Batten, B.F. Hoskins and R. Robson, J. Am. Chem. Soc., 1995,
117, 5385; S.R. Batten, B.F. Hoskins, R. Robson and D. Slizys,
unpublished results.
D. Hagrman and J. Zubieta, C.R. Acad. Sci. Paris, Serie IIc, Chimie,
2000, 3, 231-240.
71
Cu2(CN)2(bpe), bpe = 1,2-bis(4pyridyl)ethylene
Cu2(CN)2(2,3-dmp), 2,3-dmp = 2,3dimethylpyrazine
Cd1.5 (BTC)(BPE)(H2O)2.H2O, H3BTC
= trimesic acid, BPE = 1,2-bis(4pyridyl)ethane
K6Yb3(PS4)5
3D net.
[Cu3(tpt)4](BF4)3.2/3tpt.5H2O, tpt =
2,4,6-tris(4-pyridyl)-1,3,5-triazine
[Cu(4,4'-bipyridine)]4V4O12.2H2O
Net has (83)(86) topology, the
same as C3N4 or Cu15Si4.
V4O12 cluster acts as 4connecting node. (83)(86) net.
If ligand considered as
tetrahedral node, then topology is
diamond. If ligand considered as
two linked 3-connecting nodes,
then becomes a 3,4-connected net
with Wells' (8,3/4)-b (or
(83)2(86)) topology.
If ligand considered as
tetrahedral node, then topology is
PtS. If ligand considered as two
linked 3-connecting nodes, then
becomes a 3,4-connected net with
(4.122)2(42.124) topology.
2D!2D parallel interpenetration
of 3,4-connected nets.
Cu2(O2CR)4 dimers are 4connecting nodes.
3D nets.
Ag(tpb)(NO3)(MeOH), tpb = 3,3',5,5'tetrakis(4-pyridyl)bimesityl
Mn(tpb)Cl2(MeOH)(H2O), tpb =
3,3',5,5'-tetrakis(4-pyridyl)bimesityl
Cu3(ip)(ipH)(bipy)1.5 , H2ip =
isophthalic acid, bipy = 4,4'-bipyridine
Cd3(isonicotinate)4(NO3)2(4,4'bipyridine)2(H2O)2
K3[Cu6(CN)6I3]
Ca(H2O)2Ni(S2C2O2)2.4H2O
2
3D net. Table/text contradictary 2
about interptn, but is interptg.
Shortest circuits are 9-membered. 2
2
2
2
2
J.A. Aitken and M.G. Kanatzidis, J. Am. Chem. Soc., 2004, 126,
11780-11781.
D.N. Dybstev, H. Chun and K. Kim, Chem. Commun., 2004, 15941595.
C.-D. Zhang, S.-X. Liu, L.-H. Xie, B. Gao, C.-Y. Sun and D.-H. Li, J.
Mol. Struct., 2005, 753, 40-44.
R. Natarajan, G. Savitha, P. Dominiak, K. Wozniak and J.N.
Moorthy, Angew. Chem. Int. Ed., 2005, 44, 2115-2119.
2
R. Natarajan, G. Savitha, P. Dominiak, K. Wozniak and J.N.
Moorthy, Angew. Chem. Int. Ed., 2005, 44, 2115-2119.
2
Y.-H. Wen, J.-K. Cheng, Y.-L. Feng, J. Zhang, Z.-J. Li and Y.-G.
Yao, Inorg. Chim. Acta, 2005, 358, 3347-3354; Y.-H. Wen, J.-K.
Cheng, Y.-L. Feng, J. Zhang, Z.-J. Li and Y.-G. Yao, Inorg. Chim.
Acta, 2005, 358, 3347-3354.
J.-H. Liao, C.-Y. Lai, C.-D. Ho and C.-T. Su, Inorg. Chem. Commun.,
2004, 7, 402-404.
A.M. Chippindale, S.J. Hibble and A.R. Cowley, Inorg. Chem., 2004,
43, 8040-8048.
A. Gleizes, F. Maury and J. Galy, Nouv. J. Chim., 1984, 8, 521-529.
2
2
(83)2(85.10) topology.
D.J. Chesnut, D. Plewak and J. Zubieta, J. Chem. Soc., Dalton Trans.,
2001, 2567-80.
D.J. Chesnut, D. Plewak and J. Zubieta, J. Chem. Soc., Dalton Trans.,
2001, 2567-80.
F.A.A. Paz and J. Klinowski, Inorg. Chem., 2004, 43, 3948-3954.
2
72
[CuL2]KX, L = 2-amino-2hydroxymethyl-1,3-propanediolato, X =
F.3H2O or Br.2H2O
Cu3(EDTA)(4,4'bipyridine)3.5 (H2O)(OH)2.2H2O
Cu3(bipy)2(pydc)2.4H2O, bipy = 4,4'bipyridine, pydc = pyridine-2,4dicarboxylate
AgC(CN)2NO2
K6Yb3(PS4)5
[Cu2Cl(chtpy)](NO3), chtpy = a,a-1,4dihydroxy-e,e,e,e-1,2,4,5-tetra(4pyridyl)cyclohexane
[Cu2L(bipy)(H2O)2][Cu(bipy)(H2O)4],
L = mellitate, bipy = 4,4'-bipyridine
Cs2O.9B2O3
(4.102)2(42.104)
topology.
(5.82)(4.52.6.7.8)2 topology.
2
S. Kotila and J. Valkonen, Acta Chem. Scand., 1994, 48, 312-318.
2
Z. Shi, S. Feng, Y. Sun and J. Hua, Inorg. Chem., 2001, 40, 53125313.
X.-M. Zhang and X.-M. Chen, Eur. J. Inorg. Chem., 2003, 413-417.
If long Cu...O interactions (2.689 2
Å) are ignored, then highly
undulating sheets; each sheet
interlocked with 4 others.
Otherwise, 2 interpenetrating 3,4connected nets with
(102.12)2(4.102)2(42.102.122)
topology.
Two interpenetrating 3,42
connected, self-penetrating nets
with
(6.8.10)(6.8.10)(6.8.10)(82.10)(83
.103) topology.
3D nets.
2
(62.82.102)(62.8)2 topology.
2
Two 3,4-connected 3D nets (and 2
not PtS as implied in the paper),
with 1D chains running down the
channels. Mellitate anions form
planar 4-connecting nodes, Cu
atoms are 3-connecting nodes.
Nodes are 3-connecting and 42
connecting B2O3 units.
Y.M. Chow and D. Britton, Acta Crystallogr., Sect. B, 1974, 30, 147151.
J.A. Aitken and M.G. Kanatzidis, J. Am. Chem. Soc., 2004, 126,
11780-11781.
M.-L. Tong, S. Hu, B. Wang and S.R. Batten, Angew. Chem. Int. Ed.,
2005, 44, 5471-5475.
E. Yang, J. Zhang, Z.-J. Li, S. Gao, Y. Kang, Y.-B. Chen, Y.-H. Wen
and Y.-G. Yao, Inorg. Chem., 2004, 43, 6525-6527.
J. Krogh-Moe and M. Ihara, Acta Crystallogr., 1967, 23, 427-430; J.
Krogh-Moe, Ark. Kemi, 1959, 14, 451; A.C. Wright, R.N. Sinclair,
C.E. Stone, K.S. Knight, I.G. Polyakova, N.M. Vedishcheva and B.A.
Shakhmatkin, Phys. Chem. Glasses, 2003, 44, 197-202; N. Penin, M.
Touboul and G. Nowogrocki, J. Solid State Chem., 2003, 175, 348352.
73
Zn[Au(CN)2]2 and Co[Au(CN)2]2
Ag2HgS2 (Imiterite)
Hg2[B(CN)4]2
Hg3OCl (Poyarkovite)
Quartz net (chiral). However, if
short Au-Au contacts taken into
account, then becomes two 3,4connected nets with
(92.10)2(94.102) topology.
(4.82)(4.85) or dmc topology.
2
B.F. Hoskins, R. Robson and N.V.Y. Scarlett, Angew. Chem. Int. Ed.
Engl., 1995, 34, 1203; S.C. Abrahams, L.E. Zyontz and J.L.
Bernstein, J. Chem. Phys., 1982, 76, 5458-5461.
2
J.-J. Guillou, J. Monthel, P. Picot, F. Pillard, J. Protas and J.-C.
Samama, Bull. Mineral., 1985, 108, 457-464.
M. Berkei, E. Bernhardt, M. Schuermann, M. Mehring and H.
Willner, Z. Anorg. Allg. Chem., 2002, 628, 1734-1740.
Tetranodal
2
2
3
2
3
5
(4 .6)(6 )(4 .6 .8)(6 .8)
topology.
Pentanodal (4.82)(4.85) topology. 2
N.V. Pervukhina, G.V. Romanenko, S.A. Magarill, V.I. Vasiliev and
S.V. Borisov, J. Struct. Chem., 1999, 40, 155-158; V.I. Vasiliev, N.V.
Pervukhina, G.V. Romanenko, S.A. Magarill and S.V. Borisov, Can.
Mineral., 1999, 37, 119-126.
(3,5)-Connected Nets
Ag(tcm)(L), L = pyz, dabco, bipy
Bridged hexagonal sheets; 5coord Ag.
Ag(NC-(CH2)4-CN)CF3SO3
Structures have same topology as 2
AgtcmL above.
Nets have the same topology as
2
AgtcmL.
Ag(tpba)N3, tpba = N,N',N''-tris(pyrid3-yl-methyl)-1,3,5benzenetricarboxamide
KH3(C2O4)2.2H2O
2•
S.R. Batten, B.F. Hoskins and R. Robson, New J. Chem., 1998, 22,
173-175; B.F. Abrahams, S.R. Batten, B.F. Hoskins and R. Robson,
Inorg. Chem., 2003, 42, 2654-2664.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2002, 4, 413-425.
J. Fan, H.-F. Zhu, T. Okamura, W.-Y. Sun, W.-X. Tang and N.
Ueyama, Chem. Eur. J., 2003, 9, 4724-4731.
(42.6)(42.65.83) topology.
2
C.J. Gilmore and J.C. Speakman, Acta Crystallogr., Sect. B, 1982, 38,
2809-2813.
Rutile nets.
2•
S.R. Batten, B.F. Hoskins and R. Robson, J. Chem. Soc., Chem.
Commun., 1991, 445; R. Robson, B.F. Abrahams, S.R. Batten, R.W.
Gable, B.F. Hoskins and J. Liu, Supramolecular Architecture, ACS
Symposium Series 499, ed. T. Bein, Am. Chem. Soc., Washington
DC, 1992, 256; S.R. Batten, B.F. Hoskins, B. Moubaraki, K.S.
Murray and R. Robson, J. Chem. Soc., Dalton Trans., 1999, 29772986; J.L. Manson, C. Campana and J.S. Miller, Chem. Commun.,
1998, 251-2 (Mn); H. Hoshino, K. Iida, T. Kawamoto and T. Mori,
Inorg. Chem., 1999, 38, 4229-4232 (Cu, Mn); J.L. Manson, E.
Ressouche and J.S. Miller, Inorg. Chem., 2000, 39, 1135-1141.
(3,6)-Connected Nets
M(tcm)2, M = Cr, Mn, Fe, Co, Ni, Cu,
Zn, Cd, Hg
74
Cd(bipy)2(Ag(CN)2)2
Rutile nets.
2•
Mn(bipy)2(Ag(CN)2)2
Rutile nets.
2
Cd(1,3-bppn)2(Ag(CN)2)2, 1,3-bppn =
1,3-di(4-pyridyl)propane
FeL2[Ag(CN)2]2, L = 4,4'-bipy, 1,2bis(4-pyridyl)ethylene
[Zn(H2O)]2[Re6S8(CN)6].7H2O
Rutile nets.
2•
Rutile nets.
2
6-connecting clusters and 3connecting tetrahedral Zn
centres. Topology is that of %MnO2 (Ramsdellite) or
(4.62)(43)(44.68.83).
Zn3O(HBTB)2(H2O).(DMF)0.5 (H2O)3, 6-Connecting node is a
Zn3O(H2O) cluster. Doesn't look
BTB = benzenetribenzoate
like rutile.
Zn4O(TCA)2.3DMF.G, TCA = 4,4',4''- Pyrite (FeS2) topology (with S-S
tricarboxtriphenylamine, G = 3H2O,
bond ignored). Zn4O(CO2)6 as 6EtOH
connecting nodes.
Mn(N(CN)2)2(imidazole)2
1D chains which are crosslinked
by H-bonding beween the
imidazole and N(CN)2- ligands,
such that the 3-connecting nodes
are N(CN)2-...imidazole moieties.
Zn(HBTC)(bipy), H3BTC = 1,2,4Highly interdigitated layers
benzenetricarboxylic acid, bipy = 4,4'- which become two rutile nets
when H-bonding interactions
bipyridine
taken into account.
Cu2(CN)2(bipy)
3D rutile nets with Cu and Cu2
dimer nodes; interpenetration not
mentioned in later reference.
AgL(ClO4), L = tris(4Rutile nets, with Ag2(ClO4)2
iodophenyl)amine
clusters as nodes. However, this
requires a long (3.236 Å) Ag-O
interaction.
2
T. Soma, H. Yuge and T. Iwamoto, Angew. Chem. Int. Ed. Engl.,
1994, 33, 1665.
W. Dong, Q.-L. Wang, S.-F. Si, D.-Z. Liao, Z.-H. Jiang, S.-P. Yan
and P. Cheng, Inorg. Chem. Commun., 2003, 6, 873-876.
T. Soma and T. Iwamoto, Acta Crystallogr. Sect. C, 1997, 53, 18191821.
V. Niel, M.C. Munoz, A.B. Gaspar, A. Galet, G. Levchenko and J.A.
Real, Chem. Eur. J., 2002, 8, 2446-2453.
L.G. Beauvais, M.P. Shores and J.R. Long, Chem. Mater., 1998, 10,
3783-3786.
2
J. Kim, B. Chen, T.M. Reineke, H. Li, M. Eddaoudi, D.B. Moler, M.
O'Keeffe and O.M. Yaghi, J. Am. Chem. Soc., 2001, 123, 8239-8247.
2
H.K. Chae, J. Kim, O.D. Friedrichs, M. O'Keeffe and O.M. Yaghi,
Angew. Chem., Int. Ed., 2003, 42, 3907-3909; E.Y. Lee, S.Y. Jang
and M.P. Suh, J. Am. Chem. Soc., 2005, 127, 6374-6381.
S. Konar, S. Dalai, J. Ribas, M.G.B. Drew, E. Zangrando and N.R.
Chaudhuri, Inorg. Chim. Acta, 2004, 357, 4208-4214.
2
2
C. Qin, X. Wang, L. Carlucci, M. Tong, E. Wang, C. Hu and L. Xu,
Chem. Commun., 2004, 1876-1877.
2
D.J. Chesnut, D. Plewak and J. Zubieta, J. Chem. Soc., Dalton Trans.,
2001, 2567-80; O. Teichert and W.S. Sheldrick, Z. Anorg. Allg.
Chem., 2000, 626, 1509.
I. Ino, L.P. Wu, M. Munakata, M. Maekawa, Y. Suenaga, T. KurodaSowa and Y. Kitamori, Inorg. Chem., 2000, 39, 2146-2151.
2
75
Cu(NH3)(py)Ag3-xCux(CN)5.py, py =
pyridine
Cu(dca)2(cypy)2, dca = dicyanamide,
cypy = 3- or 4-cyanopyridine
Cu2(M6X14), M = Mo, W, X = Cl, Br
Ag(tcm) - like, but connections
2•
b/w sheets give a structure
analogous to Ag(tcm)(phz)1/2. If
Ag dimers taken as nodes, then
topology becomes that of rutile.
1D chains crosslinked by weak
2
C-H...N interactions. If
Cu(cypy)2 moieties treated as
nodes, then alpha-Po. If Cu and
cypy considered separate nodes,
then 3,6-connected nets. In the 3cypy structure nets are
crosslinked by weaker C-H...N
interactions.
Cu 3-connecting, M6X14 cluster 2
6-connecting. Net has
(43)2(46.129) (PrI2 or spn)
topology.
M. Schwarten, J. Chomic, J. Cernak and D. Babel, Z. Anorg. Allg.
Chem., 1996, 622, 1449.
5-connected node is a cluster; 4connected node is a H-bonded
synthon.
2
C.M. Oertel, R.D. Sweeder, S. Patel, C.M. Downie and F.J. DiSalvo,
Inorg. Chem., 2005, 44, 2287-2296.
Two complicated (4,6) nets.
2
M.J. Plater, M.R.St.J. Foreman, T. Gelbrich, S.J. Coles and M.B.
Hursthouse, J. Chem. Soc., Dalton Trans., 2000, 3065-3073.
H-bonded nets have
(44.62)(44.69.82) topology.
3
J.A. Cowan, J.A.K. Howard and M.A. Leech, Acta Crystallogr., Sect.
C, 2001, 57, 1196-8.
A.M. Kutasi, A.R. Harris, S.R. Batten, B. Moubaraki and K.S.
Murray, Cryst. Growth Des., 2004, 4, 605-610.
M. Du, X.-J. Zhao, S.R. Batten and J. Ribas, Cryst. Growth Des.,
2005, 5, 901-909.
A. Peppenhorst and H.-L. Keller, Z. Anorg. Allg. Chem., 1996, 622,
663-669; Y.-Q. Zheng, J. Nuss and H.G. von Schnering, Z.
Kristallogr. New Cryst. Struct., 1998, 213, 680; S. Ihmaine, C. Perrin,
M. Sergent, Eur. J. Solid State Inorg. Chem., 1997, 34, 169-178; Y.Q. Zheng, Y. Grin, K. Peters and H.G.V. Schnering, Z. Anorg. Allg.
Chem., 1998, 624, 959-964.
(4,5)-Connected Nets
W6S8(4-pyridineacetamide) 6.DMF.4pyridineacetamide
(4,6)-Connected Nets
Cd2(SO4)2(Py2C3H6)3(H2O)2.7 •4.5H2
O, Py2C3H6 = 1,3-bis(4pyridyl)propane
4,4'-bipyridine / 2,3,5,6-tetrahydroxy1,4-benzoquinone (3/2)
Mn2(dca)3(NO3)(Mepyz)2, dca =
dicyanamide, N(CN)2-, Mepyz = 2methylpyrazine
Ce2(C2O4)(H3C2O3)4
2
2
J.C. Trombe, J. Jaud and J. Galy, J. Solid State Chem., 2005, 178,
1094-1103.
76
(4,12)-Connected Nets
Pd16S7 (Vasilite) and Pd13Cu3S7
Cu3Au (ftw) or (436.630)(44.62)3
topology. Pd-Pd interactions
neglected.
2
P. Matkovic, M. El Boragy and K. Schubert, J. Less-Comm. Met.,
1976, 50, 165-176; C. Romming and E. Roest, Acta Crystallogr.,
Sect. A, 1976, 30, 425-428.
(3,5,6)-Connected Nets
Cs3[Mo3O4(C2O4)3(H2O)3]CF3SO3.3H Triflate 3-connecting, Mo cluster 2
4-connecting, Cs 6-connecting.
2O
Topology is
(43)(34.74.82)3(33.43.76.83).
E. Benory, A. Bino, D. Gibson, F.A. Cotton and Z. Dori, Inorg.
Chim. Acta, 1985, 99, 137-142.
Nets of different topology or
chemical composition
Hg2Nb2O7 (pyrochlore)
Bi3GaSb2O11, Bi3AlSb2O11,
La3Ru3O11, La3Ir3O11, Bi3Ru3O11,
NaBi2Sb3O11,
[Ln2(Pb4O4)](Al6O12), Ln = Ho, Lu,
Eu, Gd, Nd, Sm
[H31O14][CdCu2(CN)7]
K2[PdSe10]
Diamond nets of different
2•
composition. ICSD has ca. 600
entries for related species.
Nets of different composition 3•
two diamondoid, one NbO-like.
Using example of La3Ru3O11,
nodes of diamond nets are La 4O4
cubane-like moieties, while
nodes of NbO net are Ru 2O6
moieties.
Two diamond nets and one
3
sodalite. Pb4O4 cubane-like
clusters and Ln atoms are nodes
of diamond nets; Al atoms are
nodes of sod net.
Pyrite-like M-CN net with
2•
another (rutile-like) 3D net of Hbonded waters interpenetrating it.
Each diamond net has different
2•
composition.
A.W. Sleight, Inorg. Chem., 1968, 7, 1704; Structural Inorganic
Chemistry, 5th edn., A.F. Wells, Oxford University Press, 1983, 258.
A.W. Sleight and R.J. Bouchard, Inorg. Chem., 1973, 12, 2314-2316;
Ismunandar, B.J. Kennedy and B.A. Hunter, J. Solid State Chem.,
1996, 127, 178-185; Ismunandar, B.J. Kennedy and B.A. Hunter,
Solid State Commun., 1998, 108, 649-654; F. Abraham, J. Trehoux
and D. Thomas, Mater. Res. Bull., 1978, 13, 805-810; F. Abraham, J.
Trehoux and D. Thomas, J. Less-Comm. Met., 1979, 63, 57-63; F.
Abraham, D. Thomas and G. Novogorocki, Bull. Soc. Fr. Mineral.
Crystallogr., 1975, 98, 25-29; G.R. Facer, M.M. Elcombe and B.J.
Kennedy, Aust. J. Chem., 1993, 46, 1897-1907; J.-C. ChamparnaudMesjard, B. Frit, A. Aftati and M. El Farissi, Eur. J. Solid State Inorg.
Chem., 1995, 32, 495-504.
M. Scheikowski and H. Mueller-Buschbaum, Z. Anorg. Allg. Chem.,
1993, 619, 1755-1758; H.K. Mueller-Buschbaum and J.-P. Werner, Z.
Naturforsch., Teil B, 1996, 51, 883-887; H.K. Mueller-Buschbaum
and J.-P. Werner, Z. Naturforsch., Teil B, 1997, 52, 449-452.
S. Nishikiori and T. Iwamoto, J. Chem. Soc., Chem. Commun., 1993,
1555.
K.W. Kim and M.G. Kanatzidis, J. Am. Chem. Soc., 1992, 114, 4878.
77
[Ag(hex)](PF6).H2O
{[Cd(4-ampy) 2{µ-Ag(CN)2}2]
.[Cd(mea)(4-ampy){Ag(CN)2}{µAg(CN)2}]2}n, 4-ampy = 4aminopyridine, mea = 2-aminoethanol
Rb2Au6Sb4S10
Li2M3B, M = Pd, Pt
Two interpenetrating (10, 3)-a
nets, one composed of the
Ag(hex) net, the other formed by
hydrogen-bonding between the
PF6 ions and the H2O molecules;
racemic pair.
Two sets of intpting sheets
different - one coordn (3-fold
intpted), other H-bonding b/w
coordn chains (2-fold intpted).
Layers of 2D parallel sheets of
different topology and
composition: [Au3Sb4S8]- and
[Au3S2]-. Latter has (6,3)
topology, former doesn't.
M3B forms 6-connected
(33.59.63) or lcy net (B nodes),
while Li atoms form a (10,3)-a
net. In the case of Pt, there are
Li-Pt distances between the nets
very slightly shorter than the LiLi distances that define the 'net'.
2•
L. Carlucci, G. Ciani, D.M. Proserpio and A. Sironi, J. Am. Chem.
Soc., 1995, 117, 12861.
3
&
2•
T. Soma and T. Iwamoto, Acta Crystallogr., Sect. C, 1996, 52, 1200.
2
J.A. Hanko and M.G. Kanatzidis, Chem. Commun., 1998, 725-726.
2
U. Eiberstein and W. Jung, J. Solid State Chem., 1997, 133, 21-24.
1D/2D!2D
[Co(bipy)2.5 (NO3)2].2C14H10
1D/2D!3D
1D railroad coordination
2/2 K.V. Domasevitch, G.D. Enright, B. Moulton and M.J. Zaworotko, J.
polymers interpenetrating with
Solid State Chem., 2000, 152, 280-285.
(4,4) phenanthrene nets (held
together by edge-to-face
interactions). However, there are
also edge-to-face and face-to-face
interactions between the
phenanthrenes and the bipys
which connect the two types of
nets.
78
[Cu5(bpp)8(SO4)4(EtOH)(H2O)5](SO4) (4,4) sheets and inclined 1D
chains. Each sheet window has 1
.EtOH.25.5H2O, bpp = 1,3-bis(4chain through it, and each chain
pyridyl)propane
window has 2 sheets through it.
[Fe(btb)2(NCS)2], btb = 1,2-bis-(1,2,4- (4,4) sheets with 1D chains
interpenetrating at an inclined
triazol-1-yl)-butane
angle such that the rods of the
sheet penetrate the loops of the
chains.
Cd3(bbtz)6(H2O)6(BF4)6.1.75H2O, bbtz (4,4) sheets with 1D chains
interpenetrating at an inclined
= 1,4-bis(1,2,4-triazol-1angle. Each sheet window has 4
ylmethyl)benzene
chain rods through it, and each
chain window has 1 sheet rod
through it.
3/2 L. Carlucci, G. Ciani, M. Moret, D.M. Proserpio and S. Rizzato,
Angew. Chem. Int. Ed., 2000, 39, 1506-1510.
2/3 J.A. Kolnaar, Ph.D. thesis, Leiden University, Leiden, 1998,
mentioned in J.G. Haasnoot, Coord. Chem. Rev., 2000, 200-202, 131185.
2/5 B. Li, Y. Peng, B. Li and Y. Zhang, Chem. Commun., 2005, 23332335.
1D/3D
[Co(bix)2(H2O)2](SO4).7H2O, bix =
1,4-bis(imidazol-1-ylmethyl)benzene
1D chains interpenetrating with a
3D CdSO4 net.
L. Carlucci, G. Ciani and D.M. Proserpio, Chem. Commun., 2004,
380-381.
#-Po coordination net with two
2•
different (6,3) H-bonded sheets
interpenetrating it (but not each
other).
H-bonded nets; Faraday paper
2
describes it as interpenetration of
a 3D net with 2D nets. However,
if add connection between O2 of
molecule B and H1 of molecule
A (N...O = 3.275 Å), then
becomes a self-penetrating net.
3D CdSO4-like nets
interpenetrating 2D (4,4) nets.
3D CdSO4-like nets
interpenetrating 2D (4,4) nets.
B.F. Hoskins, R. Robson, and D.A. Slizys, Angew. Chem. Int. Ed.
Eng., 1997, 36, 2752-2755.
2D/3D
M(L)F2.14H2O, M = Cd, Zn, L =
hexakis(imidazol-1-ylmethyl)benzene
Sulfathiazole, Phase I
[Cu2L4.3H2O][Cu2L4.2H2O].3H2O, L
= isonicotinate
Ni(bipy)2(H2PO4)2.C4H9OH.H2O
G.J. Kruger and G. Gafner, Acta Crystallogr., Sect B, 1972, 28, 272283; N. Blagden, R.J. Davey, H.F. Lieberman, L. Williams, R. Payne,
R. Roberts, R. Rowe and R. Docherty, J. Chem. Soc., Faraday
Trans., 1998, 94, 1035-1044.
J.Y. Lu and A.M. Babb, Chem. Commun., 2001, 821-822.
Y.-C. Jiang, Y.-C. Lai, S.-L. Wang and K.-H. Lii, Inorg. Chem.,
2001, 40, 5320-5321.
79
[Co(mppe)2(NCS)2].2[Co(mppe)2(NCS Two separate CdSO4 3D nets
)2].5MeOH, mppe = 1-methyl-1'-(4interpenetrating with 2D (4,4)
sheets. Each window of each
pyridyl)-2-4-pyrimidyl)ethylene
sheet penetrated by the two
CdSO4 nets.
Co(mpe)2(NCS)2, mpe = 1-methyl-1',2- One form has two separate
CdSO4 3D nets interpenetrating
bis(4-pyridyl)ethene
with 2D (4,4) sheets. Same as the
above structure.
1,3,5-tris(4-methylbenzoyl)benzene
Nodes are dimeric Piedfort units,
which link via C-H...O hydrogen
bonds. These form alpha-Po nets
and 2D (6,3) sheets.
D.M. Shin, I.S. Lee, Y.K. Chung and M.S. Lah, Chem. Commun.,
2003, 1036-1037.
D.M. Shin, I.S. Lee, D. Cho and Y.K. Chung, Inorg. Chem., 2003, 42,
7722-7724.
V.S.S. Kumar, F.C. Pigge and N.P. Rath, New J. Chem., 2004, 28,
1192-1194.
Misc Other Nets
[Pd2Cl2([18]ane-N2S4)]1.5 I5(I3)2
Two 3D nets composed of
weakly interacting polyiodide
species with intercalated
palladium macrocycles.
2
1,1,1-tris(4-hydroxyphenyl)ethane 1,4,8,11-tetraazacyclotetradecane methanol (2/1/1)
M2(bipy)3(NO3)4, M = Co, Ni
Complicated 3D H-bonded net.
2
Two 64(6,10)1 3D nets, where H- 2
bonding b/w NO3 and bipy C-H's
provides one of the connections;
else its just interdigitated, noninterpenetrating 2D sheets.
[NiL4(H2O)2]Br2.2L, L = 4-pyCHNOH (4,4) H-bonded nets cross-linked
by H2O...Br interactions into 3D
nets. Guest molecules of L also
H-bonded to Br anions - link 2
nets?
2
A.J. Blake, R.O. Gould, W.-S. Li, V. Lippolis, S. Parsons, C. Radek
and M. Schroder, Angew. Chem. Int. Ed. Eng., 1998, 37, 293-296;
Angew. Chem., 1998, 110, 305-308; see also A.J. Blake, F.A.
Devillanova, R.O. Gould, W.-S. Li, V. Lippolis, S. Parsons, C. Radek
and M. Schroder, Chem. Soc. Rev., 1998, 27, 195-205.
G. Ferguson, C. Glidewell, R.M. Gregson and P.R. Meehan, Acta
Crystallogr., Sect. B, 1998, 54, 139-50.
C.J. Kepert and M.J. Rosseinsky, Chem. Commun., 1999, 375-6; E.J.
Cussen, J.B. Claridge, M.J. Rosseinsky and C.J. Kepert, J. Am. Chem.
Soc., 2002, 124, 9574-9581; G.J. Halder and C.J. Kepert, J. Am.
Chem. Soc., 2005, 127, 7891-7900. (cf. M. Kondo, T. Yoshitomi, K.
Seki, H. Matsuzaka and S. Kitagawa, Angew. Chem. Int. Ed. Engl.,
1997, 36, 1725; K.N. Power, T.L. Hennigar and M.J. Zaworotko,
New J. Chem., 1998, 22, 177; H. Gudbjartson, K. Biradha, K.M.
Poirier and M.J. Zaworotko, J. Am. Chem. Soc., 1999, 121, 25992600; J.T. Sampanthar and J.J. Vittal, Cryst. Eng., 1999, 2, 251-264)
C.B. Aakeroy, A.M. Beatty and D.S. Leinen, Angew. Chem. Int. Ed.,
1999, 38, 1815-1819; Angew. Chem., 1999, 111, 1932-1936.
80
t-BuPI4
meso-5,5,7,12,12,14-Hexamethyl1,4,8,11-tetraazacyclotetradecane-4,4'biphenol (1/3)
1,2-bis(4-pyridyl)ethene - 1,1,1-tris(4hydroxyphenyl)ethane - methanol
(1/1/1)
2,2'-bipyridine / fumaric acid (1/1)
bta.H2O, bta = benzene-1,3,5-triacetic
acid
Zn(SC(NH2)(NHMe))2(terephthlate)
N1 , N4 -bis(pyridin-4ylmethyl)terephthalamide.H2O
A 3D 3-connected net - I think
it's a (10,3) net but I'm not sure
which. Held together by I...I
contacts b/w 3-conn. t-BuPI3+
and 3-conn. I-.
Three 3D H-bonded nets; unsure
of topology.
2
W.-W. du Mont and F. Ruthe, Coord. Chem. Rev., 1999, 189, 101133.
3
R.M. Gregson, C. Glidewell, G. Ferguson and A.J. Lough, Acta
Crystallogr., Sect. B, 2000, 56, 39-57.
Three complicated 3D H-bonded
nets; unsure of topology.
3
C.M. Zakaria, G. Ferguson, A.J. Lough and C. Glidewell, Acta
Crystallogr., Sect. C, 2002, 58, o1-o5.
3D H-bonded nets; unsure of
topology.
3D H-bonded nets; unsure of
topology.
3D H-bonded nets; unsure of
topology.
Complicated 3D H-bonded nets.
2
K.F. Bowes, G. Ferguson, A.J. Lough and C. Glidewell, Acta
Crystallogr., Sect. B, 2003, 59, 100-117.
H.-F. Zhu, J. Fan, T. Okamura, W.-Y. Sun and N. Ueyama, Chem.
Lett., 2002, 898-899.
N.J. Burke, A.D. Burrows, A.S. Donovan, R.W. Harrington, M.F.
Mahon and C.E. Price, Dalton Trans., 2003, 3840-3849.
H.-T. Zhang and X.-Z. You, Acta Crystallogr., Sect. E, 2005, 61,
o2055-o2057.
2
2
2
Misc Related
BeF2 / MO2, M = Si, Ge
Hypothetical C3N4 nets
Various mesophases, lipids and fluidic
media
Self-penetrating
Proposed interpenetration as a
way of generating superhard
materials. Two interpenetrating
diamondoid nets, one BeF2, the
other either SiO2 or GeO2.
Talks about possible hypothetical C/N nets, including
interpenetrating (10,3)-b and
diamondoid nets.
One cubic phase is 2 x #-Po,
another is 2 x (10,3)-a (both
proposed). Also diamondoid. Cf.
(10,3)-a, diamond and #-Po
sections above.
D.M. Proserpio, R. Hoffmann and P. Preuss, J. Am. Chem. Soc.,
1994, 116, 9634-9637.
P. Kroll and R. Hoffmann, J. Am. Chem. Soc., 1999, 121, 4696-4703.
S. Kutsumizu, T. Ichikawa, S. Nojima and S. Yano, Chem. Commun.,
1999, 1181-2, and references therein; J. Charvolin and J.F. Sadoc, J.
Physique, 1987, 48, 1559-1569, and references therein; V. Luzzati
and P.A. Spegt, Nature, 1967, 215, 701-704.
81
[Ag2(H2L)3]X2, H2L = N,N'bis(salicylidene)-1,4-diaminobutane, X
= NO3, ClO4
Ni(tpt)(NO3)2
Co(2,2'-bipy-4,4'(CO2)2)(H2O)2
Mn(dca)2.H2O, M(dca)(tcm), M = Co,
Ni, Cu, dca = dicyanamide, N(CN)2-,
tcm = tricyanomethanide, C(CN)3Ice IV
(Me3S)3I26
[Zn3(OH)3L3][NO3]3.8.67H2O, L =
1,3-bis(4-pyridyl)propane
Cd2(4,4'-pytz)3(µ-NO3)(NO3)3
(MeOH), 4,4'-pytz = 3,6-bis(pyridin-4yl)-1,2,4,5-tetrazine
Cd(CN)2(4,4'-bipy)0.5
3
If Ag...Ag interactions ignored,
(6,3) sheets with two other nets
intptg each; non-coincident
planes give 3D struct.
Interpenetration of the
'Borromean' type (L. Carlucci, G.
Ciani and D.M. Proserpio,
CrystEngComm, 2003, 5, 269;
Coord. Chem. Rev., 2003, 246,
247). Else, a single, selfpenetrating net.
Self-penetrating (12,3) net.
Self-penetrating (12,3) net if both 2
metal and ligands are taken as
nodes. If CoL2 taken as node,
then quartz topology; two
interpenetrating nets missed by
authors (see L. Carlucci, G. Ciani
and D.M. Proserpio, Coord.
Chem. Rev., 2003, 246, 247).
Rutile-related self-penetrating
nets.
Not strictly self-penetrating as
shortest circuits not penetrated.
I-net appears self-penetrating in
diagram.
Self-penetrating sheet structure.
M.L. Tong, X.-M. Chen, B.-H. Ye and L.-N. Ji, Angew. Chem. Int.
Ed., 1999, 38, 2237-2240; Angew. Chem., 1999, 111, 2376-2379.
B.F. Abrahams, S.R. Batten, M.J. Grannas, H. Hamit, B.F. Hoskins
and R. Robson, Angew. Chem. Int. Ed., 1999, 38, 1475-1477; Angew.
Chem., 1999, 111, 1538-1540.
T. Schareina, C. Schick, B.F. Abrahams and R. Kempe, Z. Anorg.
Allg. Chem., 2001, 627, 1711-3.
P. Jensen, D.J. Price, S.R. Batten, B. Moubaraki and K.S. Murray,
Chem. Eur. J., 2000, 6, 3186-3195.
H. Engelhardt and B. Kamb, J. Chem. Phys., 1981, 75, 5887.
P.H. Svensson, G. Raud and L. Kloo, Eur. J. Inorg. Chem., 2000,
1275-1282.
M.J. Plater, M.R.St.J. Foreman, T. Gelbrich and M.B. Hursthouse, J.
Chem. Soc., Dalton Trans., 2000, 1995-2000.
M.A. Withersby, A.J. Blake, N.R. Champness, P.A. Cooke, P.
Hubberstey and M. Schroder, J. Am. Chem. Soc., 2000, 122, 40444046.
Ladders interpenetrate in an
inclined fashion such that each
ladder window has two others
passing through it; ladders crosslinked by µ-NO3- anions to give
a single, self-penetrating net.
•
M.J. Hardie, Ph.D. Thesis, University of Melbourne, 1995; J. Kim
and K. Kim, Cryst. Eng., 2000, 3, 1-10.
82
Cd(CN)2(pyrazine)
•
Cd(CN)2L, L = 1,4-bis(4pyridyl)butadiyne
Cu5Cu(CN)6(DMF)4
•
M(dca)2(bpeado), M = Mn, Fe, Co, Ni,
Cu, dca = dicyanamide, N(CN)2-,
bpeado = 1,2-bis(4-pyridyl)ethane-N,
N'-dioxide
Cu(HCO2)2(pyrazine)
[Ag(2-ethpyz)2][SbF6], 2-ethpyz = 2ethylpyrazine
Coesite (SiO2)
[Cu(bpe)2(SO4)].5H2O, bpe = 1,4bis(4-pyridyl)ethane
1,2,4,5-(Et3SnN4C)4C6H2.2H2O
[Cu(bpe)2][Cu(bpe)(H2O)2(SO4)2]
.2H2O
Cu2 dimers as nodes; same
topology as Cd(CN) 2(pyrazine)
(above).
44.610.8 topology.
Complex 4-connected selfpenetrating network of
(42.63.8)(42.6.82.9) topology
(same as coesite - see below).
Complex 4-connected selfpenetrating network of
(42.63.8)(42.6.82.9) topology
(same as above structure).
Complex 3D self-penetrating
network with (64.82)(6.85)
topology.
Self-penetrating, not intptng.
Cu(bpe)2 sheets, with
Cu/bpe/SO4 chains between
sheets; weak axial coord. of SO4
in chains by Cu in sheets crosslinks nets, presumably generating
a self-penetrating network.
B.F. Abrahams, M.J. Hardie, B.F. Hoskins, R. Robson and E.E.
Sutherland, J. Chem. Soc., Chem. Commun., 1994, 1049-1050.
B.F. Abrahams, M.J. Hardie, B.F. Hoskins, R. Robson and E.E.
Sutherland, J. Chem. Soc., Chem. Commun., 1994, 1049-1050.
S.-M. Peng and D.-S. Liaw, Inorg. Chim. Acta, 1986, 113, L11-L12;
X.-J. Zhao, S.R. Batten and M. Du, Acta Crystallogr., Sect. E, 2004,
60, m1237-m1239.
H.-L. Sun, S. Gao, B.-Q. Ma and S.R. Batten, CrystEngComm, 2004,
6, 579-583.
J.L. Manson, J.G. Lecher, J. Gu, U. Geiser, J.A. Schlueter, R.
Henning, X. Wang, A.J. Schultz, H.-J. Koo and M.-H. Whangbo,
Dalton Trans., 2003, 2905-2911.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, J. Chem. Soc.,
Dalton Trans., 2000, 3821-3827.
M. O'Keeffe and B.G. Hyde, Crystal Structures I. Patterns and
Symmetry, Mineralogical Society of America, Washington, DC, 1996;
M. O'Keeffe, M. Eddaoudi, H. Li, T. Reineke and O.M. Yaghi, J.
Solid State Chem., 2000, 152, 3. (referenced in L. Carlucci, G. Ciani,
D.M. Proserpio and S. Rizzato, J. Chem. Soc., Dalton Trans., 2000,
3821-3827.).
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, J. Chem. Soc.,
Dalton Trans., 2000, 3821-3827.
S. Bhandari, M.F. Mahon and K.C. Molloy, J. Chem. Soc., Dalton
Trans., 1999, 1951-1956.
D. Hagrman, R.P. Hammond, R. Haushalter and J. Zubieta, Chem.
Mater., 1998, 10, 2091-2100.
83
4,4'-diiodo-4'',4'''dinitrotetraphenylmethane
CuBr(3,3'-dipyridylethyne)
Mn(SO4)(bipy)(H2O)2
A self-penetrating network, held
together by I... O interactions, that
can be deconstructed into 5-fold
intptg diamondoid nets and 3fold parallel intptg (4,4) sheets.
H-bonded nets; Faraday paper
2
describes it as interpenetration of
a 3D net with 2D nets. However,
if add connection between O2 of
molecule B and H1 of molecule
A (N...O = 3.275 Å), then
becomes a self-penetrating net.
A long Cu-N(amide) bond (ca.
2
2.8-2.9 Å) links inclined
interpenetrating sheets, giving a
self-penetrating net.
Self-penetrating??
Self-penetrating??
3(4,4'-Me4bpz).H2O.solv, 4,4'-Me4bpz
= tetramethyl-4,4'-bipyrazolyl
H-bonded net; looks to me to be
self-penetrating.
[Co3(bpypr)4(H2O)4V6O18].2H2O,
bpypr = 1,3-di-4-pyridylpropane
Chains and (4,4) sheets entangled
in a parallel fashion; cross-linked
into a self-penetrating net (?).
Both H-bonding and coordinative
bonding. Complex layers
interpenetrate in a 2D!3D
parallel fashion (3-fold) (see L.
Carlucci, G. Ciani and D.M.
Proserpio, Coord. Chem. Rev.,
2003, 246, 247 for analysis), but
further H-bonds connect nets
together into a single selfpenetrating(?) 3D net.
H-bonded nets containing a 2fold parallel interpenetration of
(4,4) sheets which are then linked
into a single net.
Sulfathiazole, Phase I
Cu(dca)2(bipy).H2O
[(ZnL).bipy].nS, ZnL = [5,10,15,20tetrakis(4hydroxyphenyl)porphyrinato]zinc, S =
nitrobenzene
Bis-(4-aminobenzoato)-1,4,8,11tetraazacyclotetradecanenickel(II)
R. Thaimattam, C.V.K. Sharma, A. Clearfield and G.R. Desiraju,
Cryst. Growth Design, 2001, 1, 103-106.
G.J. Kruger and G. Gafner, Acta Crystallogr., Sect B, 1972, 28, 272283; N. Blagden, R.J. Davey, H.F. Lieberman, L. Williams, R. Payne,
R. Roberts, R. Rowe and R. Docherty, J. Chem. Soc., Faraday
Trans., 1998, 94, 1035-1044.
P. Jensen, S.R. Batten, B. Moubaraki, and K.S. Murray, J. Chem.
Soc., Dalton Trans., 2002, 3712-3722.
E. Bosch and C.L. Barnes, New J. Chem., 2001, 25, 1376-8.
H. Hou, Y. Wei, Y. Fan, C. Du, Y. Zhu, Y. Song, Y. Niu and X. Xin,
Inorg. Chim. Acta, 2001, 319, 212-8.
I. Boldog, E.B. Rusanov, A.N. Chernega, J. Sieler and K.V.
Domasevitch, Angew. Chem. Int. Ed., 2001, 40, 3435-3438; Angew.
Chem., 2001, 113, 3543-3546; K.V. Domasevitch, personal
communication.
R.L. La Duca Jr., R. Ratkoski, R.S. Rarig Jr. and J. Zubieta, Inorg.
Chem. Comm., 2001, 4, 621-625.
Y. Diskin-Posner, G.K. Patra and I. Goldberg, Chem. Commun.,
2002, 1420-1421; Y. Diskin-Posner, G.K. Patra and I. Goldberg,
CrystEngComm, 2002, 4, 296-301.
C.M. Zakaria, G. Ferguson, A.J. Lough and C. Glidewell, Acta
Crystallogr., Sect. B, 2002, 58, 78-93.
84
[Ag8(Zntpyp)7(H2O)2](NO3)8.xsolv,
H2tpyp = 5,10,15,20-tetra(4pyridyl)porphyrin
Two sets of 2D sheets showing
inclined interpenetration crosslinked by further Zntpyp
molecules.
(Me3Sn)3Co(CN)6.3H2O.3/2bipy, bipy Net defined by both coordination
and hydrogen bonds.
= 4,4'-bipyridine
(Me3Sn)4Ru(CN)6.2H2O.3/2cpy, cpy = Net defined by both coordination
and hydrogen bonds. If
4-cyanopyridine
disordered cpy ignored, then
contains 2 interpenetrating 3D
3,5-connected nets.
Co(bpdc)(bipy).0.5DMF, bpdc =
Fascinating new 6-connected net,
biphenyldicarboxylate, bipy = 4,4'with Co2 dimers as nodes. Layers
bipyridine
of doubly interpenetrating
parallel (4,4) sheets are
crosslinked by bipy bridges such
that a self-penetrating net is
formed, rather than two
interpenetrating #-Po nets.
Zn(Him)2(tpa).H2O, Him = imidazole, Two interpenetrating 3D nets
defined by both coordination and
tpa = terephthalate
H bonding, linked by further Hbonding.
Cu3(N(CN)2)6(pyrimidine)2.0.75H2O
Fe(pmd)(M(CN)2)2, pmd = pyrimidine, Dehydration of hydrated nets
converts crosslinking of three
M = Ag, Au
interpenetrating CdSO4 nets from
a H-bonding interaction
(pmd...H2O) to a coordination
bond.
Mn(4-PMK)(N3)2, 4-PMK = 4pyridylmethylketazine
Tris(4-hydroxyphenyl)methane - 4,4'May be a self-penetrating net bipyridine (1:1)
not sure; definitely a single 3D
net.
L. Carlucci, G. Ciani, D.M. Proserpio and F. Porta, Angew. Chem.,
Int. Ed., 2003, 42, 317-322.
R. Eckhardt, H. Hanika-Heidl and R.D. Fischer, Chem. Eur. J., 2003,
9, 1795-1804.
R. Eckhardt, H. Hanika-Heidl and R.D. Fischer, Chem. Eur. J., 2003,
9, 1795-1804.
L. Pan, H. Liu, S.P. Kelly, X. Huang, D.H. Olson and J. Li, Chem.
Commun., 2003, 854-855.
J.-H. Yang, S.-L. Zheng, . Tao, G.-F. Liu and X.-M. Chen, Aust. J.
Chem., 2002, 55, 741-744.
J.L. Manson, J. Gu, J.A. Schlueter and H.-H. Wang, Inorg. Chem.,
2003, 42, 3950-3955.
V. Niel, A.L. Thompson, M.C. Munoz, A. Galet, A.E. Goeta and J.A.
Real, Angew. Chem. Int. Ed., 2003, 42, 3760-3763.
E.-Q. Gao, Z.-M. Wang and C.-H. Yan, Chem. Commun., 2003,
1748-1749.
S. Aitipamula, A. Nangia, R. Thaimattam and M. Jaskolski, Acta
Crystallogr., Sect. C, 2003, 59, o481-o484.
85
[Ag(sebn)2]X, sebn = sebaconitrile
(1,10-decanedinitrile), X = SbF6,
CF3SO3
[M(bipy)2(H2O)2]SiF6,
M = Zn, Cu, Cd;
[Cd(bipy)2(H2O)(OH)]PF6.
#-M(pyara)2(H2O)2, M = Ni, Co,
pyaraH = 3-(3-pyridyl)-acrylic acid
Layer structure in which sheets
have some thickness; each layer
interpenetrated by two others;
sheets are parallel but not
coincident - an overall 3D
structure. Sheets themselves are
self-penetrating (see L. Carlucci,
G. Ciani and D.M. Proserpio,
CrystEngComm, 2003, 5, 269;
Coord. Chem. Rev., 2003, 246,
247).
If H2O...SiF6...H2O hydrogen
bonds taken into account, Zn
(and presumably the others) can
be described as a single selfpenetrating 3D net (L. Carlucci,
G. Ciani and D.M. Proserpio,
Coord. Chem. Rev., 2003, 246,
247).
(8,4) or 86 net.
[Cu(L1)(L2)(H2O)].5H2O, L1 = 1,1'(8,4) or 86 net.
(1,4-butanediyl)bis(imidazole), L2 = mphthalate
Cd3(sipa)2(bipy)4(H2O)2.3H2O, H3sipa
= 5-sulfoisophthalic acid
Cu(bix)2(SO4).7H2O, bix = 1,4bis(imidazol-1-ylmethyl)benzene
Inclined interpenetration of 2D
sheets, but sheets cross-linked by
SO4 bridges into a single, selfpenetrating 6-connected net.
Zn(OAc)2(bpe)].2H2O, bpe = 1,2-bis(4- Coordination and hydrogen
bonding define net.
pyridyl)ethane
Cd2(bix)3(SO4)2, bix = 1,4Similar to Ag2(bix)3(NO3)2
bis(imidazol-1-ylmethyl)benzene
structure (1D!2D inclined
interpenetration), except nets
crosslinked by SO4 bridges to
give a single, self-penetrating net.
3
L. Carlucci, G. Ciani, P. Macchi, D.M. Proserpio, and S. Rizzato,
Chem. Eur. J., 1999, 5, 237-243.
2•
R.W. Gable, B.F. Hoskins and R. Robson, J. Chem. Soc., Chem.
Commun., 1990, 1677; R. Robson, B.F. Abrahams, S.R. Batten, R.W.
Gable, B.F. Hoskins and J. Liu, Supramolecular Architecture, ACS
Symposium Series 499, ed. T. Bein, Am. Chem. Soc., Washington
DC, 1992, 256.
M.-L. Tong, X.-M. Chen, and S.R. Batten, J. Am. Chem. Soc., 2003,
125, 16170-16171; M. Kurmoo, C. Estournes, Y. Oka, H. Kumagai
and K. Inoue, Inorg. Chem., 2005, 44, 217-224.
J.-F. Ma, J. Yang, G.-L. Zheng, L. Li and J.-F. Liu, Inorg. Chem.,
2003, 42, 7531-7534.
X. Li, R. Cao, D. Sun, W. Bi and D. Yuan, Eur. J. Inorg. Chem.,
2004, 2228-2231; X. Li, R. Cao, W. Bi, D. Yuan and D. Sun, Eur. J.
Inorg. Chem., 2005, 3156-3166.
L. Carlucci, G. Ciani, D.M. Proserpio and L. Spadacini,
CrystEngComm, 2004, 6, 96-101.
M.T. Ng, T.C. Deivaraj, W.T. Klooster, G.J. McIntyre and J.J. Vittal,
Chem. Eur. J., 2004, 10, 5853-5859.
L. Carlucci, G. Ciani and D.M. Proserpio, Cryst. Growth Des., 2005,
5, 37-39.
86
[Ni(timpt)2](ClO4)2, timpt = 2,4,6A 3,6-connected net with
tris[4-(imidazol-1-ylmethyl)phenyl](42.6)(63)(42.64.89) topology.
1,3,5-triazine
{Fe(pmd)[Ag(CN) 2][Ag2(CN)3]}, pmd (6,6) topology.
= pyrimidine
[ScL4(H2O)2](ClO4)3, L = 4,4'bipyridine-N,N'-dioxide
[ScL3](CF3SO3)3(MeOH)2.7 (H2O)3, L
= 4,4'-bipyridine-N,N'-dioxide
Mn(4-PMK)(N3)2, 4-PMK = 4pyridylmethylketazine
Five interpenetrating diamond
nets crosslinked by water bridges
to give a single net with 4867
topology.
48668 topology.
6-connected net in which (4,4)
sheets are linked by crisscrossing
links.
[Co(Hbiim)2(H2biim)]2(p5 interpenetrating 3-connected HO2CC6H4CO2H)2.H2O, H2biim = 2,2- bonded nets with
(4.122)(4.122)(123) topology
biimidazole
crosslinked into self-penetrating
net via a water bridge.
H2N(CO)NH-(CH2)n-NH(CO)NH2, n = H-bonded nets. Layers of
2D!2D parallel interpenetrating
4, 5
(6,3) sheets crosslinked into a
single 3D net.
Ni(oba)(bpy).2H2O, oba = 4,4'Can be described as either a 3,5- 3
oxybis(benzoate), bpy = 4,4'-bipyridine connected net with
(4.82)(4.64.84.10) topology, or a
6-connected net with (4 4.611)
topology.
AgC(CN)2NO2
Two interpenetrating 3,42
connected, self-penetrating nets
with
(6.8.10)(6.8.10)(6.8.10)(82.10)(83
.103) topology.
Zn5(OH)2(bdc)4(phen)2, H2bdc = 1,4- Zn5 clusters as nodes. 8benzenedicarboxylic acid, phen = 1,10- connected 3D net with 424.5.63
phenanthroline
topology.
S.-Y. Wan, Y.-T. Huang, Y.-Z. Li and W.-Y. Sun, Micropor.
Mesopor. Mater., 2004, 73, 101-108.
V. Niel, A.L. Thompson, A.E. Goeta, C. Enachescu, A. Hauser, A.
Galet, M.C. Munoz and J.A. Real, Chem. Eur. J., 2005, 11, 20472060.
D.-L. Long, R.J. Hill, A.J. Blake, N.R. Champness, P. Hubberstey, C.
Wilson and M. Schroder, Chem. Eur. J., 2005, 11, 1384-1391.
D.-L. Long, R.J. Hill, A.J. Blake, N.R. Champness, P. Hubberstey, C.
Wilson and M. Schroder, Chem. Eur. J., 2005, 11, 1384-1391.
E.-Q. Gao, Z.-M. Wang and C.-H. Yan, Chem. Commun., 2003,
1748-1749.
K. Larsson and L. Ohstrom, CrystEngComm, 2004, 6, 354-359.
K. Eda, T. Okazaki, K. Yamamura and M. Hashimoto, J. Mol. Struct.,
2005, 752, 93-97.
X.-L. Wang, C. Qin, E.-B. Wang, Y.-G. Li, Z.-M. Su, L. Xu and L.
Carlucci, Angew. Chem. Int. Ed., 2005, 44, 5824-5827.
Y.M. Chow and D. Britton, Acta Crystallogr., Sect. B, 1974, 30, 147151.
X.-L. Wang, C. Qin, E.-B. Wang, Z.-M. Su, L. Xu and S.R. Batten,
Chem. Commun., 2005, 4789-4791.
87
Cd(succinate)L(H2O), L = N,N'bispyridin-4-ylmethylsuccinamide
Self-penetrating 2D sheets.
G.O. Lloyd, J.L. Atwood and L.J. Barbour, Chem. Commun., 2005,
1845-1847.
1D polymers entangled like true
chickenwire.
Entangled chains.
E.A. Axtell III, J.-H. Liao, and M.G. Kanatzidis, Inorg. Chem., 1998,
37, 5583-5587.
K.O. Klepp and G. Brunnbauer, J. Alloys Compd., 1992, 183, 252262.
L. Carlucci, G. Ciani, P. Macchi, D.M. Proserpio, and S. Rizzato,
Chem. Eur. J., 1999, 5, 237-243.
P.M. Van Calcar, M.M. Olmstead, and A.L. Balch, J. Chem. Soc.
Chem. Commun. 1995, 1773-1774; P.M. Van Calcar, M.M.
Olmstead, and A.L. Balch, Inorg. Chem., 1998, 36, 5231-5238.
P.M. Van Calcar, M.M. Olmstead, and A.L. Balch, Inorg. Chem.,
1998, 36, 5231-5238.
Entangled but not
interpenetrating
NaAuS
Na7Au5S6
[Ag(sebn)]AsF6, sebn = sebaconitrile
(1,10-decanedinitrile)
[I-Au-P(C6H5)2-(CH2)6-P(C6H5)2-AuI]n
1D chains which criss-cross in
three directions.
Layers woven like woof and weft •
threads in cloth. Au..Au
interactions.
Criss-cross patterns of layers of
chains.
[Cl-Au-P(C6H5)2-(CH2)7-P(C6H5)2Au-Cl]n.CH3OH
[I-Au-P(C6H5)2-(CH2)8-P(C6H5)2-AuI]n.CH2Cl2
[Cl-Au-P(C6H5)2-(CH2)8-P(C6H5)2Au-Cl]n.CH2Cl2
[Cu(2,2'-bipy)(azpy)(H2O)](NO3)2
Woven woof and weft threads.
•H2O, azpy = trans-4,4'azobis(pyridine)
[AgL(µ-PO2F2)1/2](PF6)1/2, L = 1Woven woof and weft threads
which are then cross-linked to
(isocyanidomethyl)-1H-benzotriazole
give (82.10) net.
1,1,1-Tris(4-hydroxyphenyl)ethane /
H-bonded three-fold helix; some
hmt (1:2)
weak interactions b/w helices
(but not within).
[bpeH][La(NO3)4(H2O)(bpe)]
Corrugated (4,4) sheets which
have ...Hbpe...Hbpe... chains
running through corrugations
(like 'Chinese blinds').
[Ag2(bpethy)5}(BF4)2, bpethy = 1,2Railroad-like ladders where the
terminal rods of on each side
bis(4-pyridyl)ethyne
penetrate two other ladders each;
each square of each ladder
penetrated by four rods from four
adjacent ladders.
L. Carlucci, G. Ciani, A. Gramaccioli, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2000, 29.
I. Ino, J.C. Zhong, M. Munakata, T. Kuroda-Sowa, M. Maekawa, Y.
Suenaga and Y. Kitamori, Inorg. Chem., 2000, 39, 4273-4279.
P.I. Coupar, C. Glidewell and G. Ferguson, Acta Crystallogr., Sect B,
1997, 53, 521-33.
C.V.K. Sharma and R.D. Rogers, Chem. Commun., 1999, 83-4.
L. Carlucci, G. Ciani and D.M. Proserpio, Chem. Commun., 1999,
449-450.
88
[M2(bipy)3(H2O)(phba)2](NO3)2.4H2O
, M = Cu, Co, phba = 4hydroxybenzoate
[Cu(C16H24N4)(H2O)3•C36H36N24O12]
(NO3)4.14H2O
[Ag(C16H24N4)C36H36N24O12]
(C7H7O3S)3.11H2O
[Ag(py-CH2NH2(CH2)5NH2CH2-py)
•C36H36N24O12](NO3)3.12H2O
Ag{py-C(O)O(CH2CH2OCH2CH2)5
OC(O)-py}ClO4
Ladders with dangling arms
which interdigitate into the
square rings of adjacent ladders.
Polymeric 1D chain rotaxane
-•
with Cucurbituril beads.
Polymeric 1D chain rotaxane
-•
with Cucurbituril beads.
Helical, polymeric 1D chain
rotaxane with Cucurbituril beads.
Two 1D chains entangled in
pairs; weak Ag-O interactions
connect the two.
[Fe(bte)2(NCS)2].
1D linear chains and 1D chains
[Fe(bte)(NCS)2(H2O)2], bte = 1,2-bis- composed of loops - the linear
chains penetrate through the
(1,2,4-triazol-1-yl)-ethane
loops of the other chains but are
not penetrated themselves. Hbonds crosslink the linear chains.
[Cu2(bpa)2(phen)2(H2O)]2.2H2O, bpa = Beautiful structure - extensively
interdigitated squares.
biphenyl-4,4'-dicarboxylate, phen =
1,10-phenanthroline
[CdL2(NO3)2][Cd4L4(NO3)6(MeOH)6] Entanglement of (4,4) sheets, 1D
ladders, and 1D chains. H[CdL(NO3)3]NO3.2G.3MeOH, L =
bonding links the 1D ladders and
4,4'-bis(4-pyridyl)biphenyl, G =
chains, which would give
mesitylene, m-xylene, o-xylene
interpenetrating networks.
[Ag(bpp)][Ag2(bpp)2(ox)]NO3, bpp =
1D chains penetrating in an
1,3-bis(4-pyridyl)propane, ox = oxalate inclined fashion through (6,3) 2D
sheets.
[Mn(dca)2(H2O)2].H2O, dca =
1D chains penetrating in an
inclined fashion through (4,4) 2D
dicyanamide
sheets. H-bonding crosslinks
nets.
[Cu(Py2C6H12)3(NO3)2].2[Cu(Py2C6H Linear 1D polymers penetrate
through the windows of other
12)2(H 2O)(NO3)](NO3)2(EtOH),
chain-like 1D polymers.
Py2C6H12 = 1,6-bis(4-pyridyl)hexane
M.-L. Tong, H.-J. Chen and X.-M. Chen, Inorg. Chem., 2000, 39,
2235-2238.
D. Whang, Y.-M. Jeon, J. Heo and K. Kim, J. Am. Chem. Soc., 1996,
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D. Whang and K. Kim, J. Am. Chem. Soc., 1997, 119, 451-2.
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B. Schmaltz, A. Jouaiti, M.W. Hosseini and A. De Cian, Chem.
Commun., 2001, 1242-3.
J.A. Kolnaar, Ph.D. thesis, Leiden University, Leiden, 1998,
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G.-F. Liu, B.-H. Ye, Y.-H. Ling and X.-M. Chen, Chem. Commun.,
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K. Biradha and M. Fujita, Chem. Commun., 2002, 1866-1867.
M.-L. Tong, Y.-M. Wu, J. Ru, X.-M. Chen, H.-C. Chang and S.
Kitagawa, Inorg. Chem., 2002, 41, 4846-4848.
K.S. Murray, S.R. Batten, B. Moubaraki, D.J. Price and R. Robson,
Mol. Cryst. Liq. Cryst., 1999, 335, 313-322; S.R. Batten, P. Jensen,
C.J. Kepert, M. Kurmoo, B. Moubaraki, K.S. Murray and D.J. Price,
J. Chem. Soc., Dalton Trans., 1999, 2987-2997.
M.J. Plater, M.R.St.J. Foreman, T. Gelbrich and M.B. Hursthouse,
Cryst. Eng., 2001, 4, 319-328.
89
[CuL(solv)(NO3)2][CuL1.5 (NO3)2]
.2solv, L = 1,4-bis[(4'-pyridylethynyl)
benzene, solv = MeOH or EtOH
"Interpenetration of 1D rods
through 1D ladders" - but rods
not penetrated - only the ladders
are!
[Co2(bpe)3(SO4)2(MeOH)2].xSolv, bpe Structure contains a single 3D net
with catenated 6-membered
= bis(4-pyridyl)ethane
rings, but not self-penetrating
because shortest circuits are 4and 5-membered rings.
Cu(HCO2)2(bipy)
Structure contains a single 3D net
with catenated 6-membered
rings, but not self-penetrating
because shortest circuits are 5membered rings. Like the selfpenetrating Cd(CN)2(bipy)
structure, it is composed of a
diamond net with a 'cross-bar',
however the topology is different.
Ni(acac)2L.xMeCN.yH2O, L = C2Structure contains 'tubes' of 5fold helicies; each tube is
symmetric 1,1-binaphthyl-6,6'entangled with four others.
bipyridine derivatives
HgI2L, L = 2,6-bis(4-pyridinylmethyl)- Layers composed of 1D chains
running in two inclined directions
benzo[1,2-c:4,5-c']dipyrroleand showing a 'two-over/two1,3,5,7(2H,6H)-tetrone
under' arrangement.
Cd(bpea)(phen)2, H2bpea =
Entanglement of nine tubular 1D
biphenylethene-4,4'-dicarboxylic acid, helicies.
phen = 1,10-phenanthroline
[Cu(L1)(bipy)(H2O)]NO3 and
Tubular helicies; each
[Cu(L2)(bipy)(H2O)](NO3)2.3H2O, L1 interdigitates with four others.
= L-threoninato, L2 = L-alaninato, bipy
= 4,4'-bipyridine
[Cd2(bpea)(pt)(phen)2][Cd(pt)(phen)].2 Alternating layers of 1D chains
H2O, H2bpea = biphenylenethene-4,4'- and (4,4) 2D nets; the chains
dicarboxylic acid, pt = phthalate, phen interdigitate into the 2D sheets.
= 1,10-phenanthroline
[AgL2][Co(C2B9H11)2].9MeCN, L =
Parallel 1D chains that
interweave to give 2D sheets.
tris(isonicotinoyl)cyclotriguaiacylene
M.B. Zaman, M.D. Smith and H.-C. zur Loye, Chem. Commun.,
2001, 2256-2257; M.B. Zaman, K. Udachin, J.A. Ripmeester, M.D.
Smith and H.-C. zur Loye, Inorg. Chem., 2005, 44, 5047-5059.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2003, 5, 190-199.
J.L. Manson, J.G. Lecher, J. Gu, U. Geiser, J.A. Schlueter, R.
Henning, X. Wang, A.J. Schultz, H.-J. Koo and M.-H. Whangbo,
Dalton Trans., 2003, 2905-2911.
Y. Cui, S.J. Lee and W. Lin, J. Am. Chem. Soc., 2003, 125, 60146015.
Y.-H. Li, C.-Y. Su, A.M. Goforth, K.D. Shimizu, K.D. Gray, M.D.
Smith and H.-C. zur Loye, Chem. Commun., 2003, 1630-1631.
X.-L. Wang, C. Qin, E.-B. Wang, L. Xu, Z.-M. Su and C.-W. Hu,
Angew. Chem. Int. Ed., 2004, 43, 5036-5040.
B.-Y. Lou, R.-H. Wang, D.-Q. yuan, B.-L. Wu, F.-L. Jiang and M.-C.
Hong, Inorg. Chem. Commun., 2005, 8, 971-974.
X.-L. Wang, C. Qin, E.-B. Wang, L. Xu, Z.-M. Su and C.-W. Hu,
Angew. Chem. Int. Ed., 2004, 43, 5036-5040.
M.J. Hardie and C.J. Sumby, Inorg. Chem., 2004, 43, 6872-6874.
90
[Cu2(bipy)3(H2O)2(4aba)2](NO3)2(H2O)4, bipy = 4,4'bipyridine, 4-aba = 4-aminobenzoate
Cu4(bpp)4(maa)8(H2O)2.2H2O, bpp =
1,3-bis(4-pyridyl)propane, Hmaa = 2methylacrylic acid
Zn3(OABDC)2(phen)3.2H2O,
H3OABDC = 5-oxoacetate isophthalic
acid, phen = 1,10-phenanthroline
1D ladders with side-chains
interdigitated into 3D
arrangement.
Three strands entangled like a
hair plait or braid.
R. Wang, F. Jiang, Y. Zhou, L. Han and M. Hong, Inorg. Chim. Acta,
2005, 358, 545-554.
Interdigitated tubes.
X.-Y. Cao, J. Zhang, J.-K. Cheng, Y. Kang and Y.-G. Yao,
CrystEngComm, 2004, 6, 315-317.
X.-J. Luan, Y.-Y. Wang, D.-S. Li, P. Liu, H.-M. Hu, Q.-Z. Shi and
S.-M. Peng, Angew. Chem. Int. Ed., 2005, 44, 3864-3867.
Not interpenetrating
1,1,1-tris(4-hydroxyphenyl)ethane /
dabco / water (1:1:1)
H-bonded 2D parallel (6,3) 2-fold
G. Ferguson, W. Bell, P.I. Coupar and C. Glidewell, Acta
nets which are further H-bonded
Crystallogr., Sect B, 1997, 53, 534-43.
into a single 3D net.
1,1,1-tris(4-hydroxyphenyl)ethane /
Two interpenetrating 3D HG. Ferguson, W. Bell, P.I. Coupar and C. Glidewell, Acta
piperazine (4:3)
bonded net IF piperazine split in
Crystallogr., Sect B, 1997, 53, 534-43.
half.
1,1,1-tris(4-hydroxyphenyl)ethane / 1,2- Two parallel intptg (6,3) nets of (2) G. Ferguson, C. Glidewell, R.D. Gregson and P.R. Meehan, Acta
diaminoethane (2:1)
the trihydroxy, cross-linked by
Crystallogr., Sect B, 1998, 54, 330-338.
weak H-bonds to diamine. CH..O bonds then give a 3D net.
Paper comes up with a notation
for interwoven sheets: {p,q,r},
where p = no. of nets to give
entire contents of unit cell; q =
no. of such nets which are
interwoven; r = no. of strands of
other nets passing through the
reticulations (assumed identical)
of any given net.
tetraoxa-[4]-peristylane
Claims a 'novel, interpenetrating
G. Mehta, R. Vidya and K. Venkatesan, Tetrahedron Letters, 1999,
..
40, 2417-2420.
architecture' generated by C-H O
bonds, but I think it's not
interpenetrating.
1,2,4,5-(Et3SnN4C)4C6H2.2H2O
Self-penetrating, not intptng.
S. Bhandari, M.F. Mahon and K.C. Molloy, J. Chem. Soc., Dalton
Trans., 1999, 1951-1956.
Co(bipy)(O2CCH3)2(H2O)2
H-bonding between two sets of
Y.-S. Zhang, G.D. Enright, S.R. Breeze and S. Wang, New J. Chem.,
H-bonded 2D inclined (4,4)
1999, 23, 625-628.
sheets - i.e. not intptg.
91
[Cd(NO3)2(L)1.5 ], L = 1,2-bis(4pyridyl)ethane
KH2PO4 (KDP)
[CuL(solv)(NO3)2][CuL1.5 (NO3)2]
.2solv, L = 1,4-bis[(4'-pyridylethynyl)
benzene, solv = MeOH or EtOH
Various 1D coordination polymer
chains containing 1,4-bis[(3pyridyl)ethynyl]benzene
[Cu3L2Cl](ClO4)2(H3O)2Cl, H2L =
bis(3-propionyloxy)-1,5diazacyclooctane
6,13-dihydro-6,13-ethano-5,12diazapentacene and 6#,13#-dibromo2,9-dichloro-5b#,6,12b#,13tetrahydropentaleno[1,2-b:4,5b']diquinoline
(Hbipy)2{[(H2O)3Ni(bipy)0.5 Ni(bipy)(
H2O)4]2[Mo5P2O23][Ni(bipy)(H2O)2][
Mo5P2O23]}.8H2O
Ethylenediammonium
phenylphosphonate hydrate, and
hexamethylenediammonium
phenylphosphonate hydrate
Claims in one line that it forms
an interpenetrating lattice (but
shows no diags or cell
parameters), then says it's the
same as Fujita's version, which is
definitely not intptg!!!
Two interpenetrating nets if only 2
count shortest K-O interactions
(e.g. 2.834 Å) and ignore second
shortest (e.g. 2.900 Å). Probably
better described as a single
diamond net of H-boned H2PO4
anions (e.g. O...O = 2.498 Å)
with K counterions!
"Interpenetration of 1D rods
through 1D ladders" - but rods
not penetrated - only the ladders
are!
Just a crisscross motif.
Y.-B. Dong, R.C. Layland, M.D. Smith, N. G. Pschirer, U.H.F. Bunz
and H.-C. zur Loye, Inorg. Chem., 1999, 38, 3056-3060. cf. M. Fujita,
Y.J. Kwon, M. Miyazawa and K. Ogura, J. Chem. Soc., Chem.
Commun., 1994, 1977-1978; M. Fujita, M. Aoyagi and K. Ogura,
Bull. Chem. Soc. Jpn., 1998, 71, 1799-1804.
Title mentions an 'interpenetrated
double-chain architecture', but
chains linked into a single 1D
polymer.
Interlocked not interpenetrating
nets.
M. Du, X.-H. Bu, Y.-M. Guo, J. Ribas and C. Diaz, Chem. Commun.,
2002, 2550-2551.
S. Endo, T. Chino, S. Tsuboi and K. Koto, Nature, 1989, 340, 452455.
M.B. Zaman, M.D. Smith and H.-C. zur Loye, Chem. Commun.,
2001, 2256-2257; M.B. Zaman, K. Udachin, J.A. Ripmeester, M.D.
Smith and H.-C. zur Loye, Inorg. Chem., 2005, 44, 5047-5059.
M.B. Zaman, K. Udachin, J.A. Ripmeester, M.D. Smith and H.-C. zur
Loye, Inorg. Chem., 2005, 44, 5047-5059.
S.F. Alshahateet, A.N.M.M. Rahman, R. Bishop, D.C. Craig and
M.L. Scudder, CrystEngComm, 2002, 4, 585-590.
J. Chen, S. Lu, R. Yu, Z. Chen, Z. Huang and C. Lu, Chem.
Commun., 2002, 2640-2641.
Likely that the word
'interpenetration' is meant to
mean 'crosslinked' or similar;
neither structure interpenetrating.
A.H. Mahmoudkhani and V. Langer, J. Mol. Struct., 2002, 609, 97108.
92
M4X4, M = Na, Rb, Cs, X = Pb, Sn
X4 tetrahedra linked by M to give
two interpenetrating diamond
nets; however further X-M
interactions link the nets together.
AgL(acetone) x(An), L = 1,3,5-tris(4cyanobenzoyl)benzene, x = 1.67 (An =
BF4), x = 2 (An = PF 6)
Cd(Htma)(bipy)(H2O).0.5H2tp.2H2O,
H3tma = trimesic acid, H2tp =
terephthalic acid
Interdigitating but not
interpenetrating.
(4,4) coordination polymer nets
and inclined (4,4) H-bonded nets;
but H-bonded nets contain parts
of coordination polymer nets.
Co3(btec)(C2O4)(H2O)2, btec = 1,2,4,5benzenetetracarboxylate
(Co(4-pya))3PO4, 4-pya = 4pyridinecarboxylate
2,3-lutidine pamoate
Pr2(PDA)3(H2O)3.H2O, H2PDA =
pyridine-2,6-dicarboxylic acid
M(porph).Zn(H2O)2.solv, M = Zn, Pd,
Pt, H2porph = tetra(4carboxyphenyl)porphyrin
Er2(bpndc)3(phen), bpndc =
benzophenone-4,4'-dicarboxylate
2(1,7-phenanthroline).2H 2O.HCl
Papers of special interest
Pairs of parallel interpenetrating
(4,4) sheets defined in paper, but
really describing a motif rather
than a net - i.e. no significant
interactions connecting some
components of the nets.
A single net overall.
Interdigitated chains (Zn) or
sheets (Pd, Pt), but not
interpenetrating.
Interpenetrating sub-structures,
but overall a single net (not selfpenetrating either).
"Interpenetrating" nets share
nodes, so a single net.
M. Baitinger, K. Peters, M. Somer, W. Carrillo-Cabrera, Y. Grin, R.
Kniep and H.G. von Schnering, Z. Kristallogr. New Cryst. Struct.,
1999, 214, 455-456; M. Baitinger, Y. Grin, R. Kniep and H.G. von
Schnering, Z. Kristallogr. New Cryst. Struct., 1999, 214, 457-458;
R.E. Marsh and D.P. Shoemaker, Acta Crystallogr., 1953, 6, 197-205.
F.C. Pigge, M.D. Burgard and N.P. Rath, Cryst. Growth Des., 2003,
3, 331-337.
J.-C. Dai, S.-M. Hu, X.-T. Wu, Z.-Y. Fu, W.-X. Du, H.-H. Zhang and
R.-Q. Sun, New J. Chem., 2003, 27, 914-918.
Y.-G. Li, N. Hao, E.-B. Wang, Y. Lu, C.-W. Hu and L. Xu, Eur. J.
Inorg. Chem., 2003, 2567-2571.
X.-G. Zhou, Z.-G. Han, J. Peng, J.-S. Chen, E.-B. Wang, C.-G. Tian,
L.-Y. Duan and N.-H. Hu, Inorg. Chem. Commun., 2003, 6, 14291432.
D.A. Haynes, W. Jones and W.D.S. Motherwell, CrystEngComm,
2005, 7, 538-543.
B. Zhao, L. Yi, Y. Dai, X.-Y. Chen, P. Cheng, D.-Z. Liao, S.-P. Yan
and Z.-H. Jiang, Inorg. Chem., 2005, 44, 911-920.
M. Shmilovits, M. Vinodu and I. Goldberg, Cryst. Growth Des.,
2004, 4, 633-638.
Y. Wang, Z. Wang, C. Yan and L. Jin, J. Mol. Struct., 2004, 692,
177-186.
K.K. Arora and V.R. Pedireddi, Cryst. Growth Des., 2005, 5, 13091312.
93
Various reviews on
interpenetration.
Searches of the CSD and ICSD
for interpenetrating structures.
Authors define a 'density of
catenation' for 'polycatenated'
systems - i.e. those in which
lower dimensional nets
interpenetrate to give a higher
dimension entanglement.
Review focussing on 'Borromean'
interpenetration.
Excellent review on
interpenetration and
entanglement; reviewing, in
particular 'polycatenanes', and
describing 'degree of catenation
(Doc)', and 'index of separation
(Is)'.
Interpenetrating sphere packings.
S.R. Batten and R.Robson, Angew. Chem. Int. Ed., 1998, 37, 14601494; Angew. Chem., 1998, 110, 1558-1595; S.R. Batten and R.
Robson, in Molecular Catenanes, Rotaxanes and Knots, A Journey
Through the World of Molecular Topology, eds. J.-P. Sauvage and C.
Dietrich-Buchecker, Wiley-VCH, Weinheim, 1999, 77-105; S.R.
Batten, CrystEngComm, 2001, 3, 67-73; "Interpenetration", S.R.
Batten, Encyclopedia of Supramolecular Chemistry, Eds. J.L.
Atwood and J.W. Steed, Marcel Dekker, New York, USA, 2004, 735741.
V.A. Blatov, L. Carlucci and D.M. Proserpio, CrystEngComm, 2004,
6, 377-395; I.A. Baburin, V.A. Blatov, L. Carlucci, G. Ciani and
D.M. Proserpio, J. Solid State Chem., 2005, 178, 2471-2493.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato,
CrystEngComm, 2003, 5, 190-199.
L. Carlucci, G. Ciani and D.M. Proserpio, CrystEngComm, 2003, 5,
269-279.
L. Carlucci, G. Ciani and D.M. Proserpio, Coord. Chem. Rev., 2003,
246, 247-289.
W. Fischer and E. Koch, Acta Crystallogr., Sect. A, 1976, 32, 225232; E. Koch and W. Fischer, Z. Kristallogr., 1978, 148, 107-152; E.
Koch, Z. Kristallogr., 1984, 166, 23-52; W. Fischer and E. Koch,
Acta Crystallogr., Sect. A, 1990, 46, C449-C450; H. Sowa and E.
Koch, Z. Kristallogr., 1999, 214, 316-323; H. Sowa and E. Koch,
Acta Crystallogr., Sect. A, 2004, 60, 158-166; H. Sowa and E. Koch,
Acta Crystallogr., Sect. A, 2005, 61, 331-342.
94
Paper comes up with a notation
for interwoven sheets: {p,q,r},
where p = no. of nets to give
entire contents of unit cell; q =
no. of such nets which are
interwoven; r = no. of strands of
other nets passing through the
reticulations (assumed identical)
of any given net.
Introduces parallel/parallel,
diagonal/diagonal,
parallel/diagonal notation for 2D
inclined interpenetrating sheets.
Discusses interpenetrating
diamond nets in detail.
Describes some interpenetrating
systems with useful properties.
Both papers have interesting
discussions on interpenetration.
Li15Al3Si6
A good discussion on 'abnormal'
interpenetration of diamondoid
nets.
Paper proposes use of
interpenetrating nets as a system
capable of 'flexing' to
accommodate different guests.
Structure described as
interpenetration of a diamondlike lithium lattice and graphitelike Li3Al3Si6 layers. Obviously
lithium lattice is not a 'net', but
shows an interesting possible
interpenetration topology.
Papers describe interpenetrating
'dual' nets.
G. Ferguson, C. Glidewell, R.D. Gregson and P.R. Meehan, Acta
Crystallogr., Sect B, 1998, 54, 330-338.
M.J. Zaworotko, Chem. Commun., 2001, 1-9.
K.A. Hirsch, S.C. Wilson and J.S. Moore, Chem. Eur. J., 1997, 3,
765-771.
J.S. Miller, Adv. Mater., 2001, 13, 525-527.
T.M. Reineke, M. Eddaoudi, D. Moler, M. O'Keeffe and O.M. Yaghi,
J. Am. Chem. Soc., 2000, 122, 4843-4844; B. Chen, M. Eddaoudi,
S.T. Hyde, M. O'Keeffe and O.M. Yaghi, Science, 2001, 291, 10211023.
L. Carlucci, G. Ciani, D.M. Proserpio and S. Rizzato, Chem. Eur. J.,
2002, 8, 1520-1526.
R. Kitaura, K. Seki, G. Akiyama, S. Kitagawa, Angew. Chem. Int.
Ed., 2003, 42, 428-431.
L. Spina, M. Tillard and C. Belin, Acta Crystallogr., Sect. C, 2003,
59, i9-i10.
O.D. Friedrichs, M. O'Keefe and O.M. Yaghi, Solid State Sci., 2003,
5, 73-78; O.D. Friedrichs, M. O'Keeffe and O.M. Yaghi, Acta
Crystallogr., Sect. A, 2003, 59, 22-27; O.D. Friedrichs, M. O'Keeffe
and O.M. Yaghi, Acta Crystallogr., Sect. A, 2003, 59, 515-525.
95
Mathematical aspects of
interpenetrating nets.
Interesting review that looks at
coordination polymers in which
the bridging ligands are the axles
of rotaxanes.
Computerised generation of 4connected nets which produced
some interpenetrating nets.
Describes the structures of some
(non-interpenetrating)
compounds, such as helvite and
tennantite, in terms of
interpenetrating nets.
© Dr. Stuart Batten, 2005.
S.T. Hyde, A.-K. Larsson, T. Di Matteo, S. Ramsden and V. Robins,
Aust. J. Chem., 2003, 56, 981-1000.
S.J. Loeb, Chem. Commun., 2005, 1511-1518.
M.M.J. Treacy, K.H. Randall, S. Rao, J.A. Perry and D.J. Chadi, Z.
Kristallogr., 1997, 212, 768-791.
M. Schindler, F.C. Hawthorne and W.H. Baur, Acta Crystallogr.,
Sect. B, 1999, 55, 811-829.