New Mexico Bureau of Mines and Open-File RECHARGEAT Mineral Report 338 THE V E G U I T AL A N D F I L LS I T E , SOCORRO COUNTY, NEW MEXICO William J. Stone Senior Hydrogeologist June 1988 REVISED AUGUST 1990 SEE ADDENDUM Resources CONTENTS Page Introduction 1 Regional Setting 1 Methods sampling Analysis 3 5 5 Results 6 Conclusions 8 Acknowledgments 11 ADDENDUM (see for important corrections) 11 References 15 Appendix - Description of Cores 17 Figures Location map Lithologic logs 3. Chloride vs depth profile A-1. Moisture and chloridevs depth profiles and geology, Veguita Hole BH-1 1. 2. 2 4 9 14 Tables 1. 2. A-1. 7 Results of chloride analyses 11 Analysis of basal clay, Hole V-2 Results of chloride analysis, Veguita Hole BH-1 13 INTRODUCTION When Veguita the Store northern neared Counties acquired to serve asa new Socorro County landfill capacity 1985, in Socorro 75 acres approximately facility for the of opposite and Valencia land adjacent the. south of portions Veguita of the two counties. The site lies in the Casa Colorada Grant. If the land grid is projected into the site, it occupies the northern parts of Sections16 and 17, Township 3 North, Range2 East (Figure1). In response of the toa suit adjacent land brought against owners, a site the counties characterization by study some was called for by Socorro County. The work was performed under contract by John W. Shomaker, Inc. of Albuquerque. Asa supplement to that recharge was evaluation, evaluated by pre-development the New ground-water Mexico Bureau of Mines an3 Mineral Resources. The purpose of the recharge study was to determine downward This the at average the report gives long-term site, under the results rate the at which influence of the of Bureau's water has mov?-d precipitation alone. recharge investigation. REGIONAL The Veguita structural site Basin is within SETTING situated the in Mexican the Albuquerque-Belen Highlands Section of th,? Basin and Range physiographic province. More specifically, it lies upland at the surface western edge extending of the Llano from the Manzano Rio Grande Valley (Machette, 1978). valley froma position averaging river. 1 de Manzano, Uplift the westward The site overlooks the approximately 140 ft above the broad to the 0 Figure 1. 50011. Location of Veguita study area and auger holes. A veneer (lag) of coarse gravel lies at the surface or the higher divide areas of the property. Beneath this are unconsolidated Figure 2 and sediments the of Appendix the show Santa Fe Formation that (Tertiary). the 99 upper ft of thip unit consists of clay, silty clay, silty sand, sand, and gravelly sand. These materials represent deposition in stream channels, floodplains, temporary lakes,as well as dune fields. Thickness of the Santa Fe in this vicinity is 2,000 ft, based approximately 1977, Figure 20, crosson an oil well north of the site (Kelley, . section D-Dl) Data lies presented at by Spiegel (1955) suggest depths 70-125 of ft below the the property water and table that ground- water flow is southwesterly toward the river. A hydraulic gradient of 5-15 ft/mi is indicated. Although Spiegel (1955) gave no chemical that water from analyses two for water wellsa sulfate had in this township, he re-orted taste. METHODS Recharge was determined by the chloride mass-balance In this relatively simple and inexpensive procedure, it is assumed that P'Clp =where R'Clsw P = average I annual precipitation (in/yr), Clp = annual chlo-ide R = recharge rate (in/yr)l Clsw = input via precipitation (mg/L), average soil-water Rewritten for chloride recharge R P and Clp are either this = content below the root(mg,/L). zone becomes (P'Clp)/Clsw. obtained 3 from the literature or by m?-thod. E l no recovery Figure 2. Lithologic logs for Veguita auger holes. measurements made on site. Clswis determined from samples of the unsaturated zone (above Preliminary tests the suggest water the are valid (McGurk and Stone, 1985). table). general lab procedures used The method has been widely used in arid settings (Allison and Hughes, 1978; Allison and others, 1985; Stone, 1986). SAMPLING Samples of the unsaturated zone were taken at two sites by means of coring with a hollow-stem auger rig. More specifically, a CME-55 continuous sampling system with a 5-ft split barrel was hired for the work. Each 5-ft core at Hole V-1 was subsampled at 1-ft intervals for the recharge study. Samples were taken 1- in oz screw-top, plastic jars.To prevent moisture loss, thes? were also sealed with plastic electrical plastic bags, and stored out of sun. the taken in report) acrylic liners for tape, placed in zip-top Cores at Hole V-2 were permeability tests (see Shomaker’s . In the consistency case of incomplete that the partial recovery,it was core was assumed obtained, for then the barrel became plugged. Thus, the core obtained was routinely assigned to the upper part of the interval drilled. For example, if only 3 ft were assigned recovered in the interval 10-15 ft, the core was toa depth of 10-13 ft. ANALYSIS Various First, steps moisture are content necessary of each in order to determine sample is determined is weighed as it gravimetrically. In other words, each sample 5 clsw. comes from the field, dried remove tomoisture, oven then weighed again. The weight loss is attributedto moisture content. Next, samples are shaken gently with a known volume of deionized water to remobilize the salt (chloride). The resulting solution is decanted off and its chloride measureda pH withmeter content and chloride electrode. The chloride content of the original soil water (Cl) in each sample is calculated using - C1 = (Cle-W/Sd)/(Sw-Sd/Sd-J) Cle = chloride of water and Db Once contentof the extract (mg/L),W = weight added (g), Sw = wet = dry extraction Sd (g), in weight is the C1 where, Db of bulk values the sample density of the are weight of the (g), J = weight of the sample calculated sample jar(9) (approximately 1.5). for each sample, they are plotted versus depth. A typical plot is characterized aby chloride peak near the surface corresponding to the root 2078. Plants take up water but leave salts behind. This accumulates of over time to produce the chloride peak. For every volume water that comes in, through precipitation/infiltration, an equivalent volume of water moves downward by piston flow. In most storms there is rarely enough precipitation to displac? any water out of the root zone. However, intense storms do res’llt in deep percolation/displacement. This shows up as lower ch1o-ri.de values below the peak. Only these are used to determine Clsw. RESULTS In spite of partial recovery due to plugging of the co-e barrel, enough samples were obtained. Chloride content of the soil water varies from less 1than to just 6 over 115 mg/L (Table 1). - - .- . - .". " Table 1. ~ ~~ . .. . -. " Results of chloride analyses, Veguita HoleV-1. Sample Sample Moist. Dry D Ceop Sntothei n t No. (ft) (gm) (cu.m/cu.m) (gm) Wt. 1 W t . Wtr. Fldded C1 i n E x t r aS co t il ( PPm) C1 i n Wtr. (mg/l) .................................. 1 2 3 4 5 6 7 8 7 10 11 12 13 14 15 16 17 18 19 20 21 22 2:s 24 25 26 27 28 29 30 32 T... a: .>. 34 35 36 37 38 .39 4(3 41 42 43 44 4s 46 47 48 49 50 1.52 0.61 4.24 3.76 4.22 3.68 5.1 0 2.52 1.64 43 2 09 0.59 2 8() 1.33 2.94 6.29 5.46 6.62 6 0 I:) 6.52 7 50 6.7.3 1.68 C) . . . . . .3u 2.35 2 3.09 .3.62 1 .82 0.64 3.72 13.65 0 36 90 0.87 . I 3.55 7.70 3.57 1 .54 1.97 2.2.3 2.04 1 .7.3 1.48 1.59 1 0 .69 1 0 92 IC1 90 11.92 9.42 .. . 54.69 81 03 59.48 7s.2s 36.82 81.79 32.67 80 57 80.58 40.18 42.90 R1.21 80.28 44.19 80. 89 44.09 49.73 80.69 81.63 54 05 48. 04 8(3 86 80. 72 47.66 rJ9.88 8()81 8O..38 48.70 49.82 81.62 36.31 81.13 34.69 8 0 . 29 35.62 81.48 3.3.42 81.71 34.51:) 82.26 32.2:; 80 73 33.94 80 81 45.48 81.63 40.13 80.07 48.37 79.75 45.12 81 .02 42.93 79.80 80. .32 5.3.46 48.35 81.41 44.40 81.31 53.61 79.49 49.69 RC). 48 57.3.3 80.62 SO. 62 80.42 37.51 8 0 . 42 28.88 81.76 46 02 79.74 51.49 81"48 3:) 1):( 79.49 41.81 79.71 44.93 79.81 52. 36 81.09 49 YO 80 1R 45.59 80.45 32.49 79 80 28 "74 R1 ( 3 0 25.89 81 04 28.85 80.52 40* 18 80. 95 . . . . . . . . . . ... . 3 80 10.78 115.26 91.83 9c'. 29 92"59 t35.49 65.52 27. 70 35.48 4E1 .32 11.48 4.. 92 4." 22 6.34 2.49 . 3 .1a:( :3 05 2.76 3.29 3..37 2 9C1 4. 70 3.56 .. 3.,& 3 1 :,2 ~.26 . -l 2.89 F.68 1 .87 7.12 30.59 h .85 4 .3s 2.9u 1.69 2.14 4.58 5.15 3.lh 5.57 5.131 4.78 4.22 . . 1.21 1.08 1 1:1.3 1. 0.3 0.71 Moisture content is generally less than 5 cu. m/cu. m, except between 30 and 4 0 ft The bulge and below 95 ft. chloride profile representing the is typical, obtained root zone and (Figure 3). A secondary ft. of nearly5 mg/L is obtained. A Clsw Published lower values below that peak of30 mg/L occurs ata depth of56 for P and values witha shallow Clp were used in the recharge calculation. The value of8.18 in/yr used forP comes from Sabinal, approximately 3 mi Socorro, of the site (Gabin and The value of 0.37 mg/L used for Clp comes Lesperance, 1977). from west approximately 30 mi to the south (Phillips and others, 1984). The mass-balance equation gives a recharge rate of approximately 0.7 in/yr. This is slightly higher than valu?s 1986). reported previously for New Mexico (Stone, expected in view of the sandy texture of This is to be most of the material this site (Santa Fe Formation). It is a reasonable baselin? value for deep be noted should percolation that the driven by recharge precipitation rate alone. It above is a lony-term given average. It may include input from wetter conditions in th? geologic past. CONCLUSIONS Deep percolation rate after the landfill is in operation should not be appreciably higher. The aridity and presumed lack of liquid waste should essentially preclude the development a of leachate at the Veguita site. As an additional precaution, trenches should be covered with 8 relatively impermeable mate-ial at v) N m when filledto hinder infiltration/leachate formation. Additionally runoff (including arroyo flow) should be diverted from reaching the If a leachate controlled Unsaturated by fill and should the flow somehow texture behaves (Winograd, 1974). trenches. of develop, the just its materials the opposite migration below of would the be trench. saturated flow Under saturated conditions, coarse intervals (sand and gravel) are high-flow pathways. By contrast, SUC? materials are barriers to unsaturated flow. Under unsaturated conditions flow is greatest through fine intervals (clay an3 silt). Conceptually, a leachate encountered stop, eithera sufficiently ora sufficiently migrate wouldthus move laterally fine until it coarse downward horizon, horizon, along ran of out where which fluid until it or it it would would the horizon ended/changed. The interbeds of silty sand, silty clay, and clay beneath the site (Figure 2, Table 3 , and Appendix) shouldmuse any leachate that might develop to move more laterally than vertically. The thickness of the silty clay at the bottom of Hole V-2 (Table 3 ) is not known as drilling stopped within it, but other beds on the order6-7offt were penetrated. Such material that would might In landfill slow the downward progress of any leachate and the present plume develop. viewof the results regulations, the of this Veguita study site is deemed suitable for solid waste disposal. With proper management it should provide no threat to local ground-water 10 quality. Table 3. Analysis of basal clay, Hole V-2. Under mineralcgy S = smectite, I = illite, K = kaolinite, I/S = mixed layer illite/smectite. Texture ( % )* Sand silt Clay 42 56 2 Mineralogy (parts in S I K 3 2 2 10) I/S 3 *sand = greater than0.062 mm silt = 0.016-0.062 mm clay = less than0.016 mm ACKNOWLEDGMENTS This work was done without charge a public as serviceto Socorro County. Lab and computer work was performed by Lori Leser (undergraduate student, New Mexico Tech). Clay analyzis was done under the supervision of George Austin (New Mexico Bureau of Mines and Mineral Resources). Drilling costs wer? born by Socorro County. ADDENDUM TO OPEN-FILE REPORT 338 Due to soil-water an error chloride in calculating values and thus soil-moisture recharge content, rate the originally reported for the Veguita landfill site are incorrect. Howe-rer, the original useful report information is and retained is of in the asfiles it contains historical interest in other terms of court case. The error arose when the lab assistant mistakenly calculated should moistureas simply have been the calculated dry wt minus averagejar wt. wet w t minus usingw t wet minus the dry wt; it drywt, divided by To make matters worse, raw data 11 the were never entered recalculation was in the lab book and could not be so located, impossible. Fortunately, however, samples from another hole at the site (BH-l), cored in April 1990 by Cathy Aimone-Martin (New Mexico Tech Department of Mining, Environmental and Geological Engineering), provided an opportunity to re-evaluate recharye at the site. In addition to samples, she provided moisture coytent (as % by weight), sample depths and a lithologic log for th2 hole. The moisture values were converted to grams of moist-Ire per gram of soil: moisture w t = %xdrywt ---------- . 100 Chloride content was analyzed as described in the original contents for this report. Correct moisture and chloride hole are given in Table A-1. Moisture and chloride profiles, as well aas lithologic log, are presented in Figure A-1. The chloride profile shows chloride Using that bulge) the the but lowest hole the got chloride chloride value below the content root had occurring zone not below (main leveled of? the bulge (120.82 mg/L at 60 ft) and the same values Pfor (8.18 in/yr) and Clp (0.37 mg/L) as in the original report, a minimum 0.025 in/yr is obtained. This value is more in line with values recharge rate of 1986). from similar settings elsewhere in the state (Stone, The recalculation shows that recharge is even slower originally reported. Thus, the original conclusion that deep percolation should not be appreciable appropriate. 12 at the site more is even than yet. Table A - 1 . Sample 3 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Results of chlorideanalysis,VeguitaHole Sample Moist DryUet Ut Depth (ft) (B) 54.26 5 60.30 7 60.60 9 58.4959.99 0.03 17 60.98 20 59.86 26 58.13 32 63.77 36 59.04 42 62.6363.54 47 59.94 52 39.37 57 55.97 57.35 62 54.88 ut Content (9) (gig) SpL Ut Utr Ut Added 0.03 116.08 53.01 0.02 98.67 59.31 0.02 59.51 58.49 59.71 0.02 59.71 58.68 0.02 101.65 58.68 57.14 0.0298.39 57.14 62.80 0.02 62.80 0.02 58.13 58.13 0.02 4.3 103.5562.63 59.18 59.18 0.01 38.85 38.85 0.02 0.03 55.97 0.03 99.7753.67 53.67 53.01 59.31 59.51 13 BH-1. (8) 100.02 97.95 97.01 103.04 99.18 108.17 118.55 118.07 CL in e x tsr oa icl t (PW) 2.8 6.8 10.0 1,281.10 15.3 11.2 10.3 7.5 5.6 4.5 4.9 2.4 1.9 1.3 Cl in water (mg/L) 306.57 848.44 1,260.54 1.364.73 1,338.18 968.58 6F9.11 57'5.83 533.20 1,343.27 549.27 200.40 120.82 I 0 r I :: 1 m 0 I 0 -k I g I m 0 I 0 b REFERENCES Allison, G. B., and Hughes, M. W., 1978, The use of environmental chloride and unconfined tritium to estimate aquifer: total Australian recharge to an Journal of Soil v. Research, 16, p. 181-195. Allison, G. B., Stone, W. J., and Hughes, M.W., 1985, Recharge through karst and dune elements a semiarid of landscape as indicated by natural isotopes and chloride: Journal of Hydrology, v. 76, p. 1-25. Fleischhauer, H. L., Jr., and Stone,W. J., 1982, Quaternary geology Mexico of Lake Bureau Animas, of Mines Hidalgo and County, Mineral New Mexico: Resources, Nev Circular 174, 25 p. Gabin, V. L., and Lesperance,L. E., 1977, New Mexico climatological data, precipitation, temperature, evaporation, and wind--monthly and annual means: W. K. Summers and Associates, Socorro, New Mexico, 436 p. Kelley, V. C., 1977, Geology of the Albuquerque Basin, New Mexico: New Mexico Bureau of Mines and Mineral Resourc~?s, Memoir 33, 60 p. Machette, M. N., 1978, Dating Quaternary faults in the southwestern United States by using buried calcic paleosols: U.S. Geological Suxvey, Journal of Research, v. 6, no. 3, p. 369-381. McGurk, B. E., and Stone, W. J., 1985, Evaluation of laboratory procedures for Bureau Mines of determining and soil-water chloride: New Mexico Mineral R ~ S O U ~ C ~Open-file S, Repor".215, 34 p. 15 Phillips, F. M., Trotman, K. N., Bentley, H. W., and Davis, S. N., 1984, The bomb-36 C1 pulseas a tracer movement near Socorro, New Mexico: New for soil-water Mexico Bureau cf Mines and Mineral Resources, Hydrologic Report 7, p. 271280. Spiegel, Zane,1955, Geology and ground-water resources of northeastern of Mines Socorro and County, Mineral New Mexico: Resources, New Ground-Water Mexico Bureau 7, 99 p. Report Stone, W. J., 1986, Natural recharge in Southwestern landscaping --examples Association from New Focus Mexico: Proceedings, Conference on National Southwestern Water Well Ground-Water Issues, p. 595-602. Stone, W. J., 1987, Paleorecharge, climatohydrologic variability, and water-resource management: Proceedings, IAHS Symposium on the Influence of Hydrologic Climate Regime Change and and Water Climatic Resources, Variability Vancouver, IAHS Publication no. 168, p. 143-152. Van Devender, T. R., and Spaulding, W. G.,1979, Developmen’ of vegetation and climate in the southwestern United States: Science, v. 204, p. 701-710. Winograd, I. J., 1974, Radioactive waste storage in the arid zone: EOS, Transactions of the v. 55, no. 10, p. 884-894. 16 American Geophysical Union, on APPENDIX Brief F i e l d Description 17 of Cores Hole V-1 (chloride samples)--Just north of middle of property near boundary. existing trenches in .................................. Sample NO. Lithology General (ft)Depth "_"_"""""""~ 1 2 3 0-1 Sandy gravel, light gray 1-4 No recovery 4-5 Sandy 5-9 No recovery 9-10 Gravelly gravel as sand above and clay 10-14 No recovery 4-9 14-20 Silty clay, red 10 20-21 Gravelly sand, loose 11 21-22 Clayey sand, reddish tan 22-24 No recovery 24-26 Gravelly sand, pink 26-29 No recovery 14,15 29-31 Silty sand, pink/red 16,17 3 1-3 3 Clay 33-34 No recovery 18-22 34-39.5 Clay 23-30 39-5-41 Sand, very fine to fine, and gravel in places, reddish brown 47-49 No recovery 49-50 Sand 50-54 No recovery 54-56 Sand asabove but gravelly at base 56-59 No recovery 59-60 Sand 60-64 No recovery 12,13 31 32,33 34 18 and as as and silty above above clay, with but gravel, reddish rusty less mottles gravel coarser, pinkish brown gray ................................. Sample NO. Lithology General (ft)Depth "_""""" 35 64-65 65-69 36 69-70 73-74 74-75 75-79 green rusty Clay, No recovery above as Gravelly sand No recovery Sand, very medium, fine to gray 41,42 79-81 81-84 No recovery above Sand with as some granules 84-85 43 85-89 89-91 91-94 No recovery above Sand as No recovery gravel above Sand and as 46-50 94-99 "_""""""" No recovery Gravelly yellowish sand, gray 70-73 37-39 40 above gravel as and Sand TOTAL DEPTH= 99 ft 19 Hole V-2 (permeameter samples)--Due west of V-1 Holeat middle (in E-W sense) of narrow divide which is last sizeable finger of high ground on west end of property. """""~""_"""""""""""""""~""""~""""Sleeve General Lithology NO. (ft) Depth """"""""""""""""""""""""""""""""1 0-1.5 Gravelly 1.5-4 No recovery Gravelly above sand finer as but 4-5.25 2 3 9 sand 5.25-5.75 Clayey silt 5.75-9 No recovery 9-11 Clayey above silt as 11-11.5 Sand, very fine-fine 11.5-14 No recovery 14-15.5 Sandasabove,butuptomedium 15.5-19 No recovery 19-20.75 Sand as above, finer in botton half 20.75-24 No recovery 24-24.5 Pebbly, clayey sand 24.5-25.75 Sand as above but no pebbles 25.75-26.50 Alternating sand and silty clay 26.50-29 NO recovery 29-32.75 and Interbedded silty clay, clay silt: clay chocolate colored,waxy 32.75-34 No recovery 34-35.75 Pebbly, silty sand 35.75-37.75 Silt and sand, powdery material at surface 37.75-39 No recovery 39-39.5 Sand 39.5-40.25 Clay, 20 as above silty (?) white """"""""""""""""""""""""""""""""Sleeve No. Lithology General (ft)Depth . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 11 12 13 14 15 16 17 40.25-41.25 Sand 41.25-43.25 silty clay and 43.25-44 Sand, very fine to fine 44-44.75 silty clay 44.75-46.5 Sand, very fine to fine 46.5-49 No recovery 49-49.5 silty 49.5-51 Sand, very fine to fine 51-51.5 silty 51.5-54 No recovery 54-55.5 Sand, very fine at base, to fine medium at top 55.5-56.25 Alternating silty clay, silt, and very fine sand 56.25-59 No recovery 59-60.5 Sand, 60.5-64 NO recovery 64-66 Sand 66-69 NO recovery 69-70.5 sand as 70.5-71.5 clay and 71.5-74 No recovery 74-77 Clayey sand, some pebbles 77-79 No recovery 79-81.25 Sand, 81.25-84 NO recovery 21 as above clay clay clay as very as above fine to medium above above clayey fine to sand medium, some granules Sleeve NO. 18 19 20 Depth (ft) General Lithology 84-86.5above as Sand 86.5-89 No recovery 89-91.5 Sand half 91.5-94 No recovery 94-96.25 Sand as above 96.25-99 Clay, chocolate texture, light brown as above, but clayey TOTAL DEPTH = 99 ft ................................. 22 in lower