New Mexico Bureau of Mines and Mineral Open-File Report No. OF-268 Resources GEOCHEMICAL ANALYSIS OF THE BRINKERHOFF DRILLING CO. NO. 1 CABEZON-GOVERNMENT (SANDOVAL COUNTY), GREAT WESTERN DRILLING CO.NO. 1 HOSPAH-SANTA FE (MCKINLEY COUNTY), MAGNOLIA PETROLEUM CORF'. 1NO. HUTCHINSON-FEDERAL (SANDOVAL COUNTY), UNION OIL CO. SUN OIL CO. OF CALIFORNIANO. 1 "13 USA (SANDOVAL COUNTY), NO. 1 NAVAJO LANDS (SAN JUAN COUNTY), APACHECOW. NO. 1 FOSHAY (SAN JUAN COUNTY), SHELL OIL CO. 113-17 NO. CARSON UNIT (SAN JUAN COUNTY), SKELLY OIL CO. 1 NAVAJO NO. 0 (SAN JUAN COUNTY), TEXACO, INC. NO. 1 NAVAJO AL (SAN JUANCOUNTY), AMERADA PETROLEUM CORP. NO.1 NAVAJO TRACT20 (SAN JUAN COUNTY), AND DELHI OIL CORP. 4 NO. UTE (SAN JUAN COUNTY) WELLS, NEW MEXICO By James E. Kea1 Robertson Research,Inc. Houston. Texas August 5, 1982 ROiiERTSONRESEARCH (U.S.) INC. REPOXT NO. S2S1.13 GEOCHEMICALANILYSIS OF ELEVEN WELLS FROM SAN JUAN BASIN, NEW MEXICO B r i n k e r h o f f #1 Cabezon 7-17N-3W Sandoval Great Western 81 Hospah 1-17N-9W McKinley Magnolia 8 1 Hutchinson-Fed. 14-19N-3W Sandoval Union or' C a l . #1 X-13 USA 13-21N-5W Sandoval Sun #1Navajo Lands 25-22N-9W San Juan 9-23N-13W Juan San Apache 81 Foshay S a r i Juan S h e l l #113-17 Carson Unit 17-25N-llW S k e l l y #1Navajo 0 34-26N-14W San Juan Texaco #1 Navajo 28-26N-18VJ San Juan Amerada #1Navajo T r . 20 31-29N-17W saa Juan 10-32N-14WJuan San D e l h i # 4 Ute ~~ bY James E. Kea1 PROJECT NO. RRUS/8231T143/2 Preparzcl by: Robertson Reser-ch (U.S.) Ina. 1073C Hedgecroft, Suite 305 HvOSiOn, Texas 77060-3697 Prepared for: Champlir. P e t r o 4 z n Compacy 5500 S. Quebec EngkWOcjd, ColorRdo 80111 ROBEqTSON RESEARCH [US.] INC. TABLE OF CONTENTS m PAGE NO. I. SUMMARY 11. INTRODUCTION 111. DISCUSSION Organic Matter Richness Kerogen Type KerogenMaturity IV. REFERENCES 17. FIGURES 1. Organic Carbon and Visual Kerogen n L. Rock-Eval Pyrolysis Plots 3. Kerogen Type from Pyrolysis Data 4. Kerogen Maturation Profile VI. .A-PPENDICES I. Organic Carbon Data 11. Rock-Eval Pyrolysis Dats 111. Vitrinite Reflectznce Bate 1 6 Plots 7 8 9 10 45 57 66 ROBEqTSON RESEZRCH [US.] INC. m Geochemical evaluation of samples from eleven wells in San Juan aasin, NewMexico indicate that Loxer Cretaceous samples range fro= rarginal tovery good in source rockquality.Organiccarbonvaluesfor Dennsylvanian age samples are much lower ranging from non-source to marginalexcept in tkle Delhi, #4 Ute well wheresuurce rock quality is good in some samples. The kerogen in all samples antllyzad is p~imarily terrestrial and dry gas-generating. Wet gas-generatingkerogen m e w s to some extentinnorthwesterly wells. Cretaceous age samples have retxhedtheoil-generatingmaturation zone only in the lower most part of the sectionin two of the three wells analyzedcontainingZre;aceous szmples. These samples are not mature enough for gas-generatior Most . Pennsylvanian age samples have matured beyona the oil-generatio-? zone, although in two wells the section is immature. Erosionhas removed 1,300 TO 7 , 6 0 0 feetsince maximum buriel took placs :n these wells =nd hydrocarbon generation may no longer be active in some areas. E :onomis evaluation of t h e areashouldincludeconsideration af source b’?d distribution and timing of hydrocarbongeneration in relation to s t x c t w al events. I1 INTRODUCTION Cretaceous and Pennsylvanian age samples from eleven weils ir? San Juan Bssin, New Mexico were snalyzed accordir,g to a program outlined by the client.Gecause sf very 1017 organiccontent,Rock-malpyrolysis could not be run on three of these wells. -1- ROBEqTSON RESEARCH [US.] INC. Analytical dataaretabulated in Appendices 1-111 andselectedparameters are plotted on Figures i through 38. Age designations shown on the figures were taken from sample logs supglied by the client. 111 DISCUSSION OrganicRichness rjrgenic richness refers to the weight percentorganiccarbon tha? samples contain. Cretaceous ssmples from three wells were se1ect.d for totalorganiccarbon ( T O C ) analyses.TheShell, #113-17 car so"^ Unit &ad the Apache, #1 Foshay contain the highest carbon content of Cretaceoussamples. Lower Cretaceous samples from these two wells range frcm marginal i0.5-1.0%) io very good (>2.0%) (Figures 7 and 1 5 ) ',? source quality. The Great Western, #1 YOSpah-S8nta Fe Cretacsous sannplesrange from marginalto good (:.0-3.0%) with the excegtion of tha Garople at 405 feet which is very good (Figure 1). Most Pennsylvanian samples range from non-source ( < 0 . 5 % ) to narsinal (Figares 1, 5 , 7 , 1 11, 51, 9 , 21, 2 5 , 29,31, and 35) in source quality. HighestorgsniccarbcnvaluesinPennsylvaniansgesampl?sare foundin wells tothenorthwest,particularlythe Delhi, # 4 Ute (Figure 35). In this well sourcequalityranges from maranal to good. Tile Amerada, $1 Navajo Tract-20 contains one sample e t 6,768 feet rated es very good by TOC content(Figure 11). Other samples nearthisdepth fir2 verylean.Thehigh TOC valuefor this sample is probably due tc large amounts of migrated bitumen present as verified by v i s u a l kerogen examinztion (Appendix 111;. The majority of samples ana1,ysad of Fennsylvanianageareorgmicleanandare not considered to he source rocks. The volume of any possible source quality Pennsylvenian section which which may be present and the amount of petroleum generated would -2- be limited from this part of thebasin. may be piwent in other areas More favorablesourcefacies of the basin. Kerogen Type its capability to generate oil or gas. was determinsd by Rock-Eval pyrolysis a r d byvisualexminntion with reflectedlight microscopy. Both techniqueshdicate apredominance of gas-gecerating,terrestrialorganicmatterin all of the sampl~.sanalysed. Poor source potential (data from pyrolysis S2 peak, Figures 2 , 8, 12, 16, 2 2 , 26, 32, and 36), low hydrogenindexvalues(Figures 3 , 9, 1 3 , 1 7 , 2 3 , 27, 33, and 3 7 ) , and low visusl percentages of oilgeneratingamorphous and exiniteorganicmatter (Figures 1, 5, 7, 11, 1 5 ,1 9 , 21, 2 5 ,2 9 ,3 1 , and 3 5 ) , all arecharacteristic of low hydrogen gas-generatingkerogen. Somewhatmore favorable convertabilit:r to ail de*-ed bypyrolysis S2/S3 ratios(Figures 2, 8, 12, 16 tlnd 36) is believedtobe'dueto solidbitumen in the samples(Appendix I I I ) and tounusually !ow cxygenindexvalues(Figures 3, 9 , 13, 17, scd 37). Thisratio,therefme, is probably nota good ksrogentypeindicatcr for samples from these wells. The type of kerogen present, and Pennsylvanian organic carbon values were too low for kerogen typing by pyrolysis in the Teuco, #I Navajo AL, Great Western, #1 Hospah-Smlta Fe, Magnolia, 81 Hutchinson-Federaland the Sun, #1Navejo Lands, nut appear to contain terrestkal kerogen from visual analysis. Of the wells analysed, those in thenorthwesterlyareaappeartohava thebestpotentiaiforkerogenconvertability to liquidhydrocarbons from visual kerogen examination (Figures 5 ,7 , 11, 25, and 35). -3- ROBEqTSON RESEARCH [U.S.] INC. Kerogen Maturity Kerogen maturity was determined byvitrinite.reflectance (Ro) and Rock-Eva1 pyrolysis (T-max). Zones of petroleum generation nnd destrgcrionarecorrekted with T-max andvitrinitereflectancevahes (Figure, P-ppendix 111). Fyrolysis T-max valuesareoften low due to ca-rings. Significant amounts of cavedmaterial affectedT-malvelues inthese wells. Theapparentlack of maturityincrease with depthin the Skelly, #1 Navajo-0, Brinkerhoff, $1 Cabezon G w ' t , Apache, #1 Foshay, Shell, #113-17 Carson U n i t , and Union, #l-M-13 U.S.A. is prohablyduetothepresence of cavings from shallower organicrichflee ticns(Figures 9 , 16, 22, 26, and 32). Thepresence of anomalously low-rank vitriniteindeeperPennsylvanian samples inthese :veils was confirmed b y visrlal kerogen analysis of samples(Appendix 111). Indigenous vitrinite is presentinnearly .all wells examined except the Skelly, $1 Wavajo-0. ThePennsylvaniansecticnanalyzedinthis contains p r i m d 1 caved vitrinite. Maturation profiles are well more reliable when samples forvitriritereflectancearechosenevery few hundredfeetthroughouta well. Two wells, Skelly, #l Navejo-O end Texaco, #1 Navajo A L , containonlyonedepth with leasonablereflectancevalues.Forthese wells we haveprojecteda maturationprofile similar to that of nearby wells with more reliable data. The most likelyindigenousvitrinitepopulationsare usad inconstructingmatwationprofiles(Figures 4 , 6 , 10, 14, 18, 20, 24, 28, 30, 34, and 38). I n spite of contaminationproblems and somewhat poor queliiydztain many samples, we believe thematurityprofilesareresonable. Lower Cretaceouscuttingsreachtheoil-generation zone (0.6-1.4 Ro) in the Shell, #113-17 Carson U n i t (Figura 18) and in the Apacke, $1 Foshay(Figure 10). CretaceollsagecuttingsintheGreatWestern, $1 Hospah-Senh Fe well do not attain oil-generating maturity (Figurl? 4 ) . ileflectance valnes in Pencsylvanian Apache, #1 Foshay, Skelly, @gc sections indicate that the #: Navajo-0, -4- Magnolia, #1 Hutchbson- Federal, Sun, #1 Navajo Lands, Union, #1-"13 m U.S.A., and Sher, #113- 17 Carson U n i t havematuredbeyond the oil-generation zone a r d have reached the wet gas (0.8-2.0 Ro) and dry gas-generation zone (1.0-3.2 Ro) (Figures 1 0 , 18, 20, 24, 28, and 30). Pennsylvanianagesections in the Great Western, #1 Hospah-Santa Fe, Texaco, #1 Nav6jo AL, kmerada, #1 Navajo Tract-20,andBrinkerhoff, #1 Cabezon Gov't have not maturedbeyond the oil-generation zone (Figures 6. 4, 14, and 34). Projection of thematurityprofileto 0.2 Ro inthese wells irdicates that 1,300 to 7,600 feet of overburdenhasbeenlosttoercsio?since maximum burial took plape.Cooling associated with this loss of section may havecausedhydrocarbongenerationto become suspenc'ed and sourcebedsclassifiedasbeing in acertainhydrocarbon-gererating zone (i.e. oil, wet, o r drygas)byvitrinitereflectance may not be .activelygenerating oil o r gas at the present time. Hydrocarbonexpul- sion, migration and accumulation are likelytohavecccurredduring maximum burial.Structures formed later may notcontainhydrocarbons unlessremigrationhasoccurred. Maturation trends from these wells suggest that the geothermd gradiefit increases basinward. Meissner (1081) found that Upper Cretaceous coals are low in rank on the south flar'k of the basin while they crop out on thenorthandnortheastflankata much higherrank.Thissuggests equivalent maturation levels differential erosion and variable sives . inthebasinare not horizontaldueto geothermal gradientsduetointru- ROBERTSON RESEARC'1 [US.] INC. m m V m REFERENCES Bryant, A. C., 1980, Entradafields Mexico: of southern Sari Juan Bar.in, New Bull., AAPG, vo1.64, p.682 (abstract). Clementz, D. M., 1979, Effect of oil andbitumensaturation as source rockpyrolysis: Bull., AAPG, vol. 63, pp. 2227-2232. Dow, W. G., 1977, Kerogen studies and geological interpretations: Jour. of Geochem. Expl., vol. 7, pp, 79-99 , 1982, Geochemical evalutaion of the James P. Dunigan No. i S m t a Fe, McKinley County, New Mexico: (U.S.) Inc.Report I" RobertsonR?search No. 580, pp. 1-27. oil find: McClasin, J. C., 1382, San Juanbasingasareayields and Gas Journal, May 17, pp. 123-124. , 1952, Small New Mexico basins draw interest: oil Oil and Gas Journal, pp. 341-342. Meissner, F. F., 1981, Case studies of hydrocarbon generation and migration: AAPG Geochemistry for Geologists CourseNotes, pp. 10-52. Ross, L. M., 1980, Geochemical correltation of San Juan Basin oils study: - a Oil and Gas Journal, Nov. 3 , pp. 102-110. Silver, C., 1968, Principles of gas occurrence, Sen Juan Basin: in Netural Gases of North America: ABPGMemoir 9. pp. 946-960. -6- ROBERTSON RESEARC'1 [US.] INC. GREAT UESTERN, 31 HOPAH-SANTA-FE S O U R C E RICt'NESS % MINITE OENERATION ( X O R B A N I C CA28ON) f 1 TI I I ! ] FIGURE I : SUMMP.RY PLOTS SHOU!NG KEROGEN TYPES, HANRITY, AND SCIJRCE RICHNESS (SEE APPENDICES I M!D 111) -7- ROBEqTSON RESEARCH [US.] INC. GREAT kESTERN, 81 HOSPAH-SANTA-FE I . I 2.5 5.8 FUR'EVRG DOOD t I I I I I I I @ I I I I I I i I I I J I I GREAT WESTERN, I I' r r Y I II H3SPAH-SANTA-FE P I t 0 ' a 25 50 75 100 GXYCEN 125 158 175 zm INGEX FIGLiRE 3 : KE2OGEN TYPEOETERtlINATION FROPl ROCK-EVAL. PYRSLYSJS DATA IAPPENOIX 1 1 ) . -9- ROBE7TSON RESEARCH [U.S.] INC. ." -y, I GGEAT XESTERN, # I HOSPAH-SANTA-FE H A T U R A T i O N P R O F I L E GENERATIONZONES E O a I Y \ FIGURE 4: V!+TURATION PROFILE, BASED ON YITRINITE REFLECTANCE DATA (APPENDIX II 11 -10- TEXACO, + I NAVAJO AL I X MINITE I HATURITY F L " a R C E - GENERATION CENCE INTENSITY 'ONES LOU H E D iilffl OIL SOURCE RICHNESS 1 ( X ORGANIC CAQ80N) I 818 r 7 FIGURE 5: SUENARY PLOTS SdCUING KEROGEN TYPES, MTURITY, A N E SOURCE RICHNESS(SEEAPPENDICES FY~~~~RTS -11- kEsEaRCH~ [US.] INC. TEXACO, # I NAVAJO 4L :RET JUR RIAS \ PERH \ FiGURE 6: rt4TURATIGNPROFILE, BASED CIN V i T R i N I T E REFLECTANCE DATA (APPENDIX i I1 1 -12- m m .. 7 E APACHE, + I FOSHAY SOURCE RICENESS ( X ORGANIC CARBON1 O S Y I I I .6 3. I l l FIGURE 7: SUMFARY FLOTS SHOVING KEGGiN TYPES, MATURITY, -13Y RESEZRCH~ [U.S.] INC. APACHE, # I FOSHAY S O u R CE POTENTIAL I I P E TTRYOPLEE U H !I ENERATION PRODUCTIVITY~ Z O N E S I I IN3EX I cI 1 I I I I 1 0 j i ' 1 'i' I i 4 2 .) I I I I I I 3 4 3 FIGURE 8: SUMMARY PLOTS OF ROCK-EVAL -14- PYROLYSIS DATA !APPENDIX 11) 3I I ... m m APACHE, FOSHAY E l 0 ' 0 J 25 50 75 100 OXYGEN FIGURE Q t 125 150 175 20F INDEX KERGCEN TYPE OETERNINATION FROn ROCK-EVAL. PYROLYSIS DATA [APPENOIX 1 1 1 . -15- ROBERTSON RESEARC'i [US.] INC. APACHE, % I FOSHAY T E H A T U R A T I O N GENERATION P R O F I L E ZONES O L8Y FiGURE IB: MATLRATIONPPGFILE, BASED ON VITRiNITE REFLECTANCE DhTA(APPENDIX 111) -16- m m m fl AMERADA, # I NAVAJO TRACT-20 I SOURCE RICHNESS I 1- Y B SUMMARY PLOTS SHOUING KEROGENTYPES, MATURITY, AND SGURCE RICHNESS (SEE APPENDICES FIGURE i I : -17- MYBERTSON RESEARCH [US.] INC. AMERADA, # I NAVAJO TRACT-20 SOURCE POTENTIAL I (S2/S3) 2.5 5.8 E O e Y OIL L FIGUiiE 12: S U M R Y PLOTS OF ROCK-NALPYROLYSIS -18- DATA (APPENDIX 11) ." m r r ANERAOA, e l NAVAJO TRACT-20 1009 t ' N i 400 D E x 200 0 0 f 1 25 50 75 125 INOEX 100 OXYGEN 150 175 201 FIGURE 13r KEROGEN TYPE DETERNINATION ?RON ROCK-E"AL. PYROLYSIS DATA (APPENDIX 1 1 1 . c Y -19- ROBERTSON RESEARCH [U.S.] INC. d 1 I - 1 1 1 I I \ \ \ FIGURE 14: NATURATIONPFIOFILE, SASED ON VITRINITE RERECTANCE CATA (AP?ENDIX 1I I ) -20- SHELL, #113-17 CARSON UNIT 1 T Y P E X EXINITE S O U R C RE I C t N E S 8 I AMO~HOUS -.I ,. ,. ,. ,. ,. ,. D R Y 6 A S .. .. .. .. .. .. .. .. .. .. .. .. .. I. FIGURE 15: SUMMARY ?LOTS SHOVING KEROGEN TYPES, MATURITY, AND SOURCE RICHNESS (SEE APPENDICESP)DEERTSON -21- RESEARC'i [US.] INC. I SHELL, #113-17 CARSON I p E ? - PETROLEUH TYPE POTEtlTIAL I (S2) UNIT 0ENERATION .ZONES I I PRODUCTIVITY INDEX 4 I t I I I I I 1 I I I I 1 I J FIGURE 16: SUMMARY PLOTS OF ROCK-NALPYROLYSISJATA(APPENDIX -22- 11) I I m m .” SHELL, S 1 1 3 - 1 7 CARSON UNIT I000 ~ rI 800 1 Y c R t 600 i N NI 400 0 E X 1’ 2a0 I CCPY a 0 200 25 175150 50 125100 75 OXYGEN INOEX FIGURE 17: KEROGEN TYPE DETERRINATION FROR ROCK-SV.4L. PYROLYSIS DATA (APPENDIX 111. 1’ Y -23- ROBERTSON RESEARCH [US.] INC. Y SHELL, # I 13-17 CARSCN UNIT M A T U R A T I O N 4 P R O F I L E SENERATIOaZONES OIL 2 I a.4 I K: a n - m r t mrt yn Mart CAS [ 2 : B . l l E € J r k 8.6 I Ms L 2 4 m r t REFLECTANCE RANDOM E.$ I I ~ . n - m t t D ~ I I I I I 2 I I I I , c * a t l a 3 t ! c t w ] u 4 r u u u l u I I I I I I \ '\ \ '/\ FIGCHE 16: flATU4AT!Ob! ?R3FILE,aASE3 ON YITRINITE REFLECTANCE DATA (APPENDIX I 11) -24- SUN, #I NAVAJOLANDS I l l 1 .0 .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. D R Y 6 A S .. .. .. .... .... .. .. .... 1. .. .. .. .. .. .. .. .. .. I . I Y Y FIGlJRE 19: SUMMARY PLOTS SHOWINGKEROGENTYPES, flATURIT'r, ANDSOURCE RICHNESS (SEE APPENDICES I AND 1111 -25- SUN, i t 1 NAVAJO LANDS \ I A FIGURE 28: MATURATION PROFILE, BASED ON 'JITRINITE REFLECTANCE DP.TA (APPENDIX I I i ) -26- UNION, P1-"13 A e 1 11 1 T IYI NPi iEE / \ X AHOP$HOUS USA H A T U R I T Y 1 1 S O U R C E RICHNESS ( X ORGANIC C A Q R O N ) c E N c E GENERATION 'ONES INTENSITY 0.5 I 1.B T .0 ... I' ,.. ... , . I ... ... ... ... ... ... ... ... ... I.. I . . I . . I . . ... . . I D R Y G A S .. .. ... ... ... ... ... Y Y FIGURE 21: SUMMARY PLOTS SHOWING KEROGEN TYPES, MATURITY, -27- RESEARCH [U.S.] INC. UNION, 81-”13 USA 1 PSO TO EUNRTCITAEYLPI EI PETROLEUM 1 1 GENERATION I PRWWTIVITY I ZONES I INDEX .~ 2.5 5.0 - 1 2.5 5.8 m / wt l/ OOD TERT CRET JUR ‘RIAS PE2M PEtlN nrss7 q PC FIGURE 22: SUMMARY PLOTS OF ROCK-NAL PYROLYSIS DATA -28- (APPENDIX I i ) UNION, El-R-I3 USA I000 H 800 Y 0 R OC 6 x 1 E f I ,OIL N I N 400 0 E X 200 0 0 25 50 75 100 OXYGEN 125 150 175 2013 INOEX FIGURE 23, KEROGEN TYPE OETERRINATION FROR ROCK-EVAL. PYROLYSIS DATA (A?PENOIX 111. -29- ROBERTSON RESEARCH [US.] INC. UNION, tl-"13 USA \ \ \ \ \ \ \\ \ \ FIGURE 24: MATURATION PROFILE, EASED ON VITRINITE REFLECTANCE DATA (APPENDIX 111 1 -30- SKELLY, # I NAVAJO-0 S O U R C ER I C H Y E S S AMOR~HOUS GENERATION INTENSITY Za’4ES cENcE ( X ORGANIC CARSON) FIGURE 25: SUMMARY PLOTS SHOUiNG KEROGENTYPES, MATURITY. AND SOURCE RICHNESS (SEE APPENDICES -31- H~YBERTSON RESEARC’i [U.S.] INC. I D E P T SKRLY, # I NAVAJO-0 :li E O 3 I I I I I I I I I I I I I J FIFJRE 26: SUMMARY PLOTS OF RCCK-EVAL PYROLYSIS DATA (APPENDIX I i ) -32- I I r SKELLY. # I NAVAJO-0 1000 H 80(3 Y O R G 630 E N N 400 0 E X 200 0 e 25 50 100 75 125 150 175 281 OXYG I NEONE X FIGURE 27: KEROGEN TYPE OETERflINATION FROn R O W - € V A L . PYROLYSIS DATA (APPENOIX 111. Y -33- ROBERTSON RESEARCH [U.S.] INC. Y \ \ \ \ \ \ \ \ FIGURE 23: MATURATION PROFILE, BASED @N ViTRINITE REFLECTANCE .DATA (APPENCIX I I I ) -34- I I MAGNOLIA, iel HUTCHINSON-FEDERAL SOURCE RICHNESS GENERATION L 0 8 Y ( X ORGANIC CARBON) INTENSITY - FIGURE 29: SUMMARY PLOTS SHOUING KEROGEN TYPES, MATURITY, AND SOURCE RIMNESS (SEE APPENDICES I m B E R T S O N RESEARCH [U.S.] INC. -35- MAGNOLIA, # 1 HUTCHINSON-FEDERAL \ \ \ \ \ FiGURE 30: MATURATiW PEOFILE, B A S D ON ViTRINITE REFLECTANCE DATA (APPENDIX I 1 1 1 - 36- BRINKERHOFF, # I CABEZON-GOV'T ( X O R B A N I CC A R S O N ) I 0.5 I.# " .8 ... ... ... 1.. ... ... ... ... ... ... ... ... ... ... ... ... ... . . I D R Y _ ... I: ... ... FIGURE 31: XMMARY PLOTS SHOWING KEROGENTYPES, MATURITY, AND SOURCE RICHNESS (SEE APPENDICES WWERTSON -37- RESEARC'i [US.] INC. BRINKERHOFF, 41 CABRON GOV'T FIGURE 22: SC?WRY PLCTS OF ROCK-E\IAL PYRO?YS!S DATA (APPENDIX 11) - 38- m m BRINKERHOFF, 0 R E l CABEZON G O V ' T IIlOIL b LA5 - G c N 600[ 400 0 E X 200 - ;i //" + i 0 0 25 t 50 75 125 100 OXYGEN 150 111,Ws 175 200 INDEX FIGURE 33: KEROGEN TYPE OETERflINATION FROn ROCK-€VAL. PYROLYSIS DATA IAPPENOIX 1 1 ) . Y -39- ROBERTSON RESEARC'i (US.) INC. BRINKERHOFF, #I CABRON-GOV'T \ \ \ \ \ \ \ \ \\ \ \ \ FIGURE 34: MATURATICN PROFILE, BASED ON 'IITRINITE REFLECTANCE DATA ( A P F E i i I X I 1 1 1 ~ 40- \ m ." 1 DELHI, +4 UTE D n A TuR ITY II SOURCE,.RICHNESS m T H Y Y FIGURE 35: SUMMARY ?LOTS SHOUING KERCGEN TYPES, MATURITY, AND SOURCE RICHNESS (SEE APPENDICES I AND 111) -41- Y I DELHI, a4 UTE lid RXRtW G O O D 2.5 5.0 d I I 1 I 1 I I I 1 I 1 1 I I 3I I m ... m DELHI, "4 UTE I000 H " 800 0 R N N 0 400 E X 200 > 25 58 75 100 125 OXYGEN INDEX 150 175 200 FIGURE 37, KEROGEN TYPE OETERflINATION FROn ROCK-EVAL. PYROLYSIS DATA [APPENOIX 1 1 1 . -43- - .. . FIGURE 38: MATURATION PRCFILE, SASED ON VITRINITE REKECT.4NCE DATA (APPENDIX I11j ”. ... PSPENDIX I TOTALORGANICCARBONDATA I’ Total organiccarbon is determined by pulverizing the sample, treating a carefully weighed portion with warm hydrochloric acid to remove carbonateminerals, andanalysing the residueforcarboncontent with a Leco carbonanalyser. I t is generallyacceptedthat samples with less than about 0.5 percent TOC cannot yield sufficient petroleum to form commercial deposits and are thereforeconsiderednonsources; samples with between 0.5 and 1.0 TOC are rated as marginal in source quality; and samples with more than 1.0 TOC are considered to be good in murce quality. Y Y -45- ROBERTSON RESEARC’1 [US.] INC. Y T O T A L 0RCP.NIC CARBON DATA G R E A T W E S T E R N , (11 H O S P A H - S A N T X - F Z DEPTH (Feet ) TCC (%> DEPTH TOC (Feet j (%) 405 e55 1365 1S95 1985 3.15 6.64 0.50 0.86 0 . 87 7135 7345 7475 7555 7565 2235 1.90 0.77 0.67 0.05 0.11 7655 7725 7785 7815 7825 3615 2665 6735 7035 0.12 -46- 0.OP 0 .05 0.10 0.07 0.11 0.11 (1.13 0.17 0.14 m m TOTAL ORGANIC CARBON DATA T E X A C O , fll N A V A J O A L T ODCE P T H (Faet) 6268 < %) o .a7 0. l o 0 . 0 35 6 0 5 5685 0.04 5815 5885 0.os 6288 6313 0.04 6318 0.11 0 . 06 6005 0.08 6393 0 6185 6263 0.06 0.06 6398 0.06 -47- .os ROBERTSON RESEARC‘1 [US.] INC. Y TOTAL ORCAKiC CARBON DATA APACHE, # l EOSHkY T ODCE P T H (Feet) T ODCE P T H (Feet 2065 6.00 2615 3048 3475 3975 4485 4745 8835 ) (K) 5.38 5.08 0.65 6.25 3 . 6 7 4.66 0.20 -43- ( %) RP25 31.25 9te5 0 .13 0 . 14 9345 9335 0.48 0.14 9975 9675 0.05 0.12 0.16 ". T O T A L O R G A N I C CAFLBON D A T A I AMERADA, #1 NAVAJO TRACT-20 T ODCE P T H (Feet) 0.12 ( 6743 6748 6763 6768 6823 0.19 0. 1 7 6828 6913 6918 6933 6938 0.23 7013 7010 D E P TTHO (Feet) ?4 ) 7043 7048 7083 7098 7113 0.12 3.18 a . 40 0.15 0.06 7118 7173 7178 7273 7278 0. 1 8 7363 7368 0.06 0.05 0 . 04 C (%) 5.28 0 . 32 a. a. 13 a9 0 . 1 3 0.16 0 . 17 a.ta a. 12 a. 23 0.14 Y Y -49- ROBERTSON RESEARCH [US.] INC. Y J TOTAL ORGANIC CARBON DATA SHELL, # 1 1 3 - 1 7 DEPTH (Feet) 205 625 1025 :515 2105 2615 3055 3.02 3615 D E P TTHO (Feet) TOC (%J 0.18 0 0 0 0 . . . . 0 3 3 4 8 4 4 4 C (%I 10033 10038 10263 10268 10493 0.88 0 . 3 7 11003 a 0.90 a, 77 0.18 0.85 3 . (18 4565 5.23 1. l a 5025 5505 3.81 1.50 400s CARSON UNIT 11008 .24 0.23 I 1 I I 1 I I I I I 1 I I -50- m m m TOTAL ORGANIC ARBON DATA SUN, TOC DEPTH (Feet) 0.11 9225 9485 9. 9. .7 5 9645 9845 ~ 9975 #l N A V A J LOA N D S D ETPOT H < 0% 0 0 0 0 . . . . ) C (Feet ) (%h) 10035 0.10 10 11 12 10 10185 10305 10415 10535 0 0 0 0 0.19 10595 0.25 .07 .12 .10 .10 " Y -51- ROBERTSON RESEARC'I [U.S.] INC. TOTAL O R G A N I C C A R B O N DATA UNION, #1-M-l3 USA DEPTH (Feet) 10445 0 . 3l1a 6 6 5 10835 la845 10895 1 . 1l4o a 7 5 11035 1112s 0.21 0.35 245 345 0.15 0.54 SSS 0.19 -52- ( % > 51: 0 . 18 0.19 0 . 14 525 0.15 625 a . la 725 0.12 0.17 TOC 0.11 ... m m TOTAL ORGANIC CAREON DATA SKELLY, # i NAVAJO-0 D E P TTHO (Feet) C (%h) DEPTH (Feet > TOC 10845 0.35 1 1. 0 0" s ~ . 0.~ .51 11025 11096 0.45 (%) ~~ 0 . 2 9 I' . -53- ROBERTSON RESEARC"I [U.S.] INC. TOTAL ORGANIC CARBON DATA MAGNOLIA, # I HUTCHINSON-FEDERAL DEiTH (Feet) TOC DEPTH (Feet) (%) -54- TOC ( %) 3I I .. .. TOTAL ORGANIC CARBON DATA BRINKERHOFF, *l DEPTH (Feet) 6983 6788 7223 7228 7323 7328 7453 7458 Y CABEZON-COV'T T ODCE P T H (Feet) TOC (oh) 0.12 (45) 7583 0 . 14 7758 7873 7878 0.10 0.31 0.36 a.11 0.31 0.38 0.10 0.31 0.11 a. 16 -55- ROBERTSON RESEARCH [US.] INC. TOTAL ORGANIC CARBON DATA DELHI, # 4 UTE T ODCE P T H (Feet) DEPTH (Feet ) (oh) 7843 0.61 7 8 . 8 .9.. 0. . . 4.~ 4 a143 0.43 8148 0.56 8223 0.86 a228 0.42 0.34 3763 8768 a773 8776 a933 TOC (%) 0.94 1.13 0.71 0.66 0 . 4 7 a4sa 0.32 1. l a 0.89 8938 9123 91za 9473 9478 0.39 I . 34 1.40 0.56 0.84 8633 3638 0.55 0.56 9603 9608 I . 01 0 . 8 6 a353 8358 8453 -56- I I . APPENDIX I1 ROCK-EVAL PYROLYSIS DATA Rock-Eval dataareexpressedasmg/g of rockandincludefourbasic parameters: 1) SI representsthequantity of freehydrocarbonspresent in the rockand is roughly analogous tothe solventextractable portion of theorganicmatter; 2)S2 representsthequantity of hydrocarbonsreleasedbythekerogen in the sampledui-ing pyrolysi,3; 3) S3 is relatedtothe amount of oxygenpresent in thekerogen; ard 4) T-max, in OC, is the temperature at which the maximum rate of generation (of the S 2 peak)occursand can be used as en estimate of thermal maturity. In addition, the ratio S2/S3 provides a general indication of kerogenquality (type) and reveals ahether oil or gas are likelyto be generated. 'The ratio S,/(S1+S2), or the productivity index, is an indication of the relative, amount of free hydrocarbons (in pia"-e or migrated) present in the sample. Hydrogen and oxygen index values are in mg of hydrocarbons ( S 2 peak) or carbon dioxide (S3 peak)per O E 8. van gram of organiccarbon. When plottedagainsteachother Krevelen-type diagram, information on kerogen type and maturity o m be obtained. Data are interpreted in the following manner: Sowce Potential Petroleum Type - values of S2 - value of S2/S3 <2.5 2.5-5.0 >5.0 : poor : marginal (2.5 2.5-5.0 : d r y gas : wet gas : oil >5.0 Generation Zones - values T-max of Productivity Icaex hydrocarbons. - highvalues (435 435-470 450 + : good : immature : oil : gas of Sl/(Sl+S2) indicate migrated Y -57- ROBERTSON RESEARCH [US.) INC. ROCK-EVAL PYROLYSIS RAW DATA G R E A T W E S T E R N , # 1 HOSPAH-SANTA-FE DEPTH (FEET) SI 405 1.265 0.326 a . 120 0.335 0.214 0s: !365 1595 2235 2615 2685 0,5 4. 24 729 0.230 a . 170 53 SZ IS3 3.7a6 a . 546 0.669 1.473 0.533 0,866 5.670 0 . 806 2.516 1 . a24 0.772 a . 757 0.698 1.126 0.620 a . 942 5.766 903 I . a77 a . 978 a . 972 a. 0.872 9 . 053 SlI(SlCS2) a. 255 0.374 0 .1 6 O a . 333 a . 234 T-MAX 426 427 427 424 429 425 431 432 I I I HYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL P Y R O L Y S I S D A T A , WTTH TOC DATA G R E A T W E S T E R N , # 1 HOSPAH-SANTX-FE DEPTH (FEET) HYDROGEN INDEX tmg H C / g T O C ) 3.15 0.64 78 80 103 0.84 129 0.87 274 126 127 48 117 13a a . 77 118 1369 1595 134 2235 2615 2685 (Oh) 47 a3 173 40s 8-59 1985 OXYGENINDEXTOC (mg C 0 2 / 9 TOC) 9s -58- 0.50 1.98 0.67 I I I 1 I 1 ... ROCK-EVAL U PYROLYSIS APACHE, # 1 DEPTH (FEET) 2065 2615 3048 340: 0 .379499s 4485 474s 9345 51 52 13.491 0 . 5 8142 . 6 9 7 0.063 0.451 0.608 7 . 292 4034.22.80.27 ,149719710 0.467 0.536 0,050 6.902 6.607 0 .526 DATA FOSHAY 53 0.504 RAW S2/S3 SlI(SlcS2) T-MAX 430 429 431 427 433 1 . 202 1.059 1 .Q0.7432 1 1.981 11.222 11.948 4.691 0.036 0.044 0 . 133 0.061 1.668 4.137 9.357 0 .?27 427 0.064 0.075 0.087 0.706 I .5 6 7 436 HYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL P Y R O L Y S I S D A T A , WITH T O C D A T A I” I I I APACHE, # 1 FOSHAP DEPTH (ZEET) HVDROGZN IXDEX tmg H C / g T O C ) OXYGEN INDEX TOC tmg C O Z / g T O C ) 2 0 6~. 5 -~ 251 ’2615 208 67 149 22 17 65 32 149 35 198 142 110 45 3048 3495 399s 4485 474s 9345 15 118 (Oh) 5.38 6.08 0.65 6 . 2 5 6 . 00 3.67 4.66 0.49 Y Y -59- ROBEqTSON RESEARCH [US.] INC. Y ROCK-EVAL PYROLYSIS RAW DATA AMERADX, d l NAVAJO TRACT-2Q 52 (D SFE tEPETTH) 2 60..526167676 8 4 3 86 8 2 3 (7100..42181924 0.104 0.732 s3 S2/S3 S l / ( STl-+MSA2X) 2.316 0.517 a .437 11.448 1.416 a04..4541242 a . a10 0.124 429 I I I H Y D R O G E N AND O X Y G E N I N D I C E S F R O M R O C K - E V A L PYROLYSIS DATA, WITH TOC DATA AMERADA, d l NAVAJO TRACT-20 DEP HT YH DROG IE NN DEX (mg H C / gT O C ) (FEET) 5768 6823 7048 OXYGEI NNDET XOC (mg C O 2 / g T O C ) 73 129 137 8.~ 34 183 61 (Oh) 3.18 0 . 4a 0.32 I . I I 1 I J -60- I n ROCK-EVAL PYROLYSIS RAW DATA S H E L L , 8 1 1 3 - 1 7 CARSON UNIT DEPTH ( F E E T 1 s 2 /SI s3 53 52 0.113 0,073 0.170 1.228 0.489 0.547 0,898 4.663 4.206 8.923 10..142837 0.~ . 7 4~. s 1.192 0.781 4565 5025 5505 10033 10038 0.265 0 .67.1370 4 0.327 0,043 0.105 1.409 0 . 4 1 9 0 . 135.93 6 4 0.814 7.748 60..150051 0.404 1.734 0 , 2 604. 8 2 6 10263 10268 10723 10728 0.051 2105 2645 3055 361: 4005 0.069 0.174 0.046 1.118 3.057 0.701 0.218 0.457 0.764 0.222 a . 277 0.411 0.307 0.358 0.390 1.205 4.049 5.389 0 .7 0. 59 28 1 1.112 0 . 027.34 9 2 0 . 403.96 1 9 0 .01.4721 1 s i / ( S i r s 2) T-MAX 0.171 0.075 0.035 0,051 434 434 433 433 432 0.102 0.097 429 431 434 436 437 0.058 0.324 434 434 430 433 0.100 HYDROGEN AND OXYGEN INDICES F R O M ROCK-EVAL PYROLYSIS DATA, WITH TOC DATA SHELL, 8113-17 CARSON UNIT DEPTH HYDROGEN INDEX (mg HC/g TOC) (FEET) OXYGENINDEXTOC tmg C 0 2 / g T O C ) 111 88 37 26 21 (Oh) 0.44 2105 2645 3055 3615 4005 134 106 151 139 171 4565 5025 5505 10033 10038 119 35 165 2 1 ~. 204 80 33 46 59 71 0 .as 0.37 10263 10266 10723 10728 51 99 63 73 46 40 102 103 0 . 90 0.77 0.35 0.38 0.85 -61- 3.08 3.02 9. 23 1.18 3.81 1.50 ROBE7TSON RESEARCH [U.S.] INC. I J R O C K - E V A LP Y R O L Y S I S SKELLY, (FEE D TE )P T H s1 RAW D A T A #1 N A V A J O - 0 52 s3 SZlS3 S l / ( S l + S Z ) T-MAX a ,258 a. 332 a .082 434 434 437 a.263 436 0 .z s a HYDROGEN AND OXYGEN I N D I C E FS R O M ROCK-EVAL . P Y R O L Y S I SD A T AW , I T HT O CD A T A SKELLY, SDYE D P TRI N H ODCEEX N (FEET) 1(1 N A V A J O - O 439 I I I I I I I O X Y IGNET DNO EC X (mg C O Z l g T O C ) ( m g H CTl gO C ) (Oh) I I I I I I -62- . . ROCK-EVAL PYROLYSIS RAW DATA U N I O N , til-"13 U S A s1 52 0.122 0,113 0.097 0.083 0.394 0.212 0.594 0.2 2 0 0.343 0 . 6 4 0 466 0.147 0.511 0.287 45s 0.340 0.397 ( DF EE PE TT H) 10665 10845 11245 93 SZlS3 Sl/(Sl+SZ) T-MAX 463 HYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL PYROLYSIS DATA, WITH TOC DATA UNION, #1-M-13 DEH PY TD HROI GN ED NEX (mg H C l g T O C ) (FEET) I” Y 10665 27 10845 41 11245 42 USA OXYGEI NNDET XOC ( m g C O 2 I gT O C ) 127 64 146 -63- (YO) 0.31 9.54 0.35 ROBERTSON RESEARCH [US.] INC. Y ROCK-€VAL PYROLYSIS RAW DATA BRINKERHOFF, d l CABEZON GOV'T ( DF EE PE TT H) s1 7223 7228 0 .01.30739917 3 7878 0 . 11 2257 0. 52 s3 0.36: 0.261 0.288 0 . 3 1 5 0.256 0,0. 70 276 00..332000 S5l2I/(5S3Tl-cMSA2X) 0.723 433 0.327 0.715 0.303 0.517 0 .408 0.489 XYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL PYROLYSIS DATA, WITH TOC DATA BRINKERHOFF, # l CABEZON GOV'T D EH PY TD HR OI GN ED NE X (FEET) ( m g H C l gT O C ) 7223 7228 7873 7878 84 0.36 O X Y G EI NN D ET XO C tmg C O Z l g T O C ) (Yo) 116 0 .31 83 83 0.38 83 0 .31 430 431 43: I I I I I I I 1 I 1 I I I I . ROCK-EVAL PYROLYSIS RAW DATA DELHI, # 4 UTE 91 DEPTH (FEET) 7843 7848 8148 8223 84S3 0,193 0.127 0 .1 0 8 0 .2 0 0 0. 5 3 8 8458 8633 8638 8763 8768 0.3 4 9 0.0 66 58 7 0 0. 3, 20 05 2 0.163 0 .2 9 7 8773 8778 8933 9123 9128 00 .. 17 55 41 0 0. 07 .3 .117678 4 0.429 0.9 429 6 9473 9478 9603 7608 I” n nsi ~ I S 352 52 T-MAX s3 0.926 0.622 0 .8 2 9 105. .6.32820948 1.967 0.980 0.728 0.624 1.407 0.621 0.645 0.570 0.603 0 . 17 .3948 4 0.215 433 436 430 433 429 2.265 1.018 0.516 2 ,703 0 .1 9 9 0.094 0 .3 9 8 0.091 0.169 43 1 433 430 432 436 0 .7 9 5 1.a01 0.528 2 225. 0.118 0 . 170 0.315 0.278 0.315 437 433 43: 432 433 0 .2 0 6 0. 1 8 3 0 . 151 0. 1 2 2 433 432 434 43 1 0 .9 5 6 0.854 1.329 0 . 537. 74 0 8 1.629 1.457 0 . b0 o .57 6 1 0.750 0.501 0 . 51 9. 59 5 1 I . 115 0- . ( 11 2.04 9.096.877 43 7 0:667 0.194 710. 4 7 6 0 . 2 8 24 . 009. 8 0. 1 3 8 0 .09 .9184.4128 1 ~ ” 1. 055 0.821 0.171 0.170 0.115 0.106 HYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL PYROLYSIS DATA, WITH TOC DATA DELHI, # 4 UTE DZPTH (FEET) Y HYDROGEN INDEX (mg HClg TOC) O X Y G EI NN D ET XO C (mg C 0 2 l g TOC) (%) 7843 7848 8148 8223 8453 54 41 48 96 67 1.18 161 165 0.61 0.44 111 0 . 5 6 0 86 5458 8633 8638 8763 8768 58 19 54 73 32 117 105 64 67 38 49 7 0 ~. 8773 8779 8933 9123 9128 8.~ 5 0.71 114 80 0.47 83 1.34 66 107 114 152 37 43 74i3 9478 9603 9608 89 103 146 116 121 98 70 98 0.84 0.86 -65- . 0.87 0.55 0 . 5 6 0,94 1.10 0. 66 1.40 0.56 1. 0 1 ROBERTSON . . U APPENDIX 111 REFLECTEDLIGHTMICROSCOPYDAT-4 A sample of ground rock is treated successively with hydrochloricand hydrofluoric acids to concentrlte the kerogen, freeze-dried, mounted in an epoxy plug, and polished.Kerogen type is identified with the aid of blue light fluorescence. The visual kerogenanalysisdatasheetcontainsvisualpercentageestitype, notes on vitrinitedescription, mates of each principlekerogen andkerogenfluorescence data. Thehistograms show measured reflectancevalues of all vitrinitepresent and on all naterial with the visual appearance of vitrinite. Shadedvaluesarethoseusedtocalculatetheinterpwtedvitrinite reflectancenaturities.Unshadedvalues are interpreted tobe oxic‘ized vitrinite, recycled vilrinits, o r possibIy misidentified material such as solid bitumen, pseudo-vitrinite, o r senifusinite. Sometimes the samples analysed contain no vitrinite o r haveaninsufficientnumber of readings to allow a reliable naturitydetermination to be nade. Alternatematuritycalculations are possible on a few samples.The histograms are identified by a sequence number and depth o r notation. -66- ROBERTSON RESEARC’1 [US.] INC. = - - = I N r m * D n I I ~ c : I w l c m m o - SPORE COLORATION INDEX (SCI) m I I VlTRINlTE - , - -I- "." r. I I W .. . . VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT G R E A T W E S T E R N # l HOSPAH-SANTA-FE I I I I I Project No. : RRUS1823/T143/02 SAMPLE IDENTIFICATION REFLECT. KEROGEN CHARACTERISTICS TOC RRUS 60 1 602 603 504 605 606. 507-608 610 614-61s 616 DEPTH (Feet) 4 0 53 0 855 1365 1595 1985 2235 2650 7035 7570 7785 Ro H 45 10 0.40 0.41 0.47 0.45 0.55 0.54 0.55 0.93 0.34 1.06 Am% BxSb V 1 t % In&rt% Fluor Med 15 25 40 40 35 5 5 15 15 25 10 5 5 30 5 30 5 tr tr 40 25 10 tr 10 65 35 'Io 35 35 30 40 tr t r 45 45 so tr Xed h ' 3.15 0.64 L0 O. W5 0 High High 0.86 Mad Ned 1.98 ---- 0.87 LOW 0.11 LOW LOW "" 0.17 V ' 3 -68- ROBERTSON RESEARCH [U.S.] INC. 25 GREAT WESTERN x 1 HOSPAH-SANTA-FE - RRUS No. DEPTH I 6Bi 405.0 Ft 123.4 il : I Ro PIATURITY 2 E VALUES 45 : MFAN VITRINITE REFLECTANCE IRANDOM XI KEROGEN DESCRIPTION Amornnntra 1. R_ X .. -. .. Exlnite > 15 x 45 X Vltrinite Inertinite I 30 X ORDERED REFLECTANCE VALUES: -- m . 3 2 30.38 10.40 70.40 ~ 0 . 4 3 ~ 0 . 3 3~ 0 . 3 8r0.4a x 0 , 4 1 ~ 0 . 4 4 *8.36 X0.36 78.40 X0.41 X0.45 m.36 ~0.38 ~0.40 sa.41 ~0.47 1 0 . 3 6 XO. 38 X0.40 X0.41 X0.47 .. 70.36 X0.38 X0.40 X0.41 30.36 X0.39 a0.40 0.52 30.36 X0.39 X0.40 r0.42 8.60 r0.37r0.39 ~ 0 . 4 0a0.42 0.64 r0.37 10.39 X0.A0 X0.43 0.64 X0.38 X0.39 X0.40 70.43 0.88 I I B o C h Fluor I B I rumen : ~ Coke fled Hign None I GREAT WESTERN * I HOSPAH-SANTA-FE 1 RRUS N o . DEPTH 29 : 682 655.0 Ft 260.6 tl I I R X = Ro flATURITY q dbF. E VALUES i P' S 0 0.0 , , , PlEAN ST0 JEV nEOIAN nOoE , , , , , ( , , , 4% 3.0 ,,,,,,,, I .9 2'. E VITRINITE REFLECCTANCE IRANCOM OROERED REFLECTANCE VALUES: ~0.32 X8.36 20 39 X0.40 20.43 X0.43 x0.45 10.48 0.52 0.53 0.54 0.55 0.58 0.60 0.6a 0.60 a.63 0.67 a.7a 0.70 0.71 0 71 0.72 0.73 0.76 0.77 0.80 0.85 0.94 0.97 4 0 0.41 a.05 a. 43 0.~5 t : HISTOGRAM: Ronge: 0Increment. 0.101 51 KEROGEN DESCRIPTION ].a1 1 8 : .I0 Pmorphous I Exlnite Vitrinlte Inert inlre : E a c h Fluor 8 I rumen Coke -59- : 5 5 65 25 I fled fled I Nane I % % X X 1 1 1 I I 1 I I I 1 ” ... GREAT VESTERN 11 HOSPAH-SANTA-FE RRUS 25 7 No. DEPTH I 1 F I I , , , , n , , , , , , , , , , , , , , , , I , , , , ~ 3 ..00 0 2.0 I.0 VITRINITE REFLECTANCE IRANOOPI = Ro IIATURITY n VALUES 6 8 IIEAN 0.47 p;:kV 0.m 0.47 0.45 71. KEROGEN OESCRIPTIOII 15 x Amorphous I I 10 x Erlnlie Vlirlnife t 35 X 40 X Inertinile I OROEREO REFLECTANCE VALUES: I I X HISTOGRAM: Range: 0- 4% Increcenl I 0.10:: 0 4.0 Fi PI 1365.0 416.1 I L 0 15 603 70.58 0.61 0.62 0.63 0.30 0 . 6 6 70.35 0.6a X1 0. 0 43 2 70 1. 4 63 6 z0.47 0.26 0.28 0.30 0.30 Bock Fluor B I lumen Co h e LOW 8 , Nons Non? I ? E . 56 I” GREAT WESTERN * l HOSPAH-SANTA-FE RRUS NO. DEPTH X0.35 7 0 . 4 0 70.36 70.41 X0.36 7 8 . 4 1 X0.37 J 0 . 4 1 X0.38 X0.41 t 0 . 3 ~m . 4 1 *0.39 1 0 . 4 1 ~ 039. X 8 . 4 5 t 0 . 3 9 10.42 7 0 . 4J30 . 6 3 X0.43 1 0 . 6 5 z0.44 7 0 . 6 6 1 0 . 4 4 X0.68 70.44 X0.48 486.2 = Ro MATURITY I) VALUES n 34 I nEAN ST0 OEV s 0.I0 IIEDIAN : 0.41 0.45 R 45 i7onge: 0- 42 Incremenrj 0 . 1 0 % Fluor B I lumen Co he Bock ~0.53 x0.57 Xn.56 Z0.62 1565.0 Ft KEROGEN DESCRIPTION Amorphous I 15 X Erinlte 5 % Vltrlnlte : 40 X lnerilnlte 4 40 % OROEREO REFLECTANCE VALUES> 70.32 ‘10.40 4.0 a a 604 7 nooE :.a 2.0 3.0 VI?RINITE REFLECTANCE IilANDOP: XI 3 -70- 8 I , Hlgh ned None ROBERTSON RESEARC‘I [US.] INC. GREAT WESTERN 8 1 HOSPAH-SANTA-FE RRUS NO. t OEPTH : 606 I T = Ro nATUR!TY e VALUES nEAN ST0 OEV nEDIAN nCOE N 5 G S 0 1985.0 F t 605.0 n 22 I 0.55 0.I0 0.57 0.65 I I HISTOCRAn. Ronge, 0- 4% Increment, 0.10% VITRINITE REFLECTANCE IRANOOn Xi OROERED FtEFLECTANCE VALUES I x0.34 r0.56 ~ 0 . 6 9 30.42 T0.57 T0.69 ~ 0 . 4 3 ~ 0 . 5 7 a.72 0.73 r0.45 T0.SI -0.46 T0.62 0.75 r0.48 r0.62 0.79 30.48 t0.62 0.79 70.50 X2.64 2.79 ~ 0 . 5 4 r0.67 0.80 ~ 0 . 5 5 13.67 2.82 0.82 0.82 0.83 0.86 0.86 0.90 .92 .93 0 .97 0 .97 I .04 .05 0.90 .I1 0.90 0.91 0.92 .28 .30 .36 ~.. - vitrinite t Inert inifeI Bock Fluor 81 fumen Coke GREAT WESTERN . I Hign I Mad None 9 I HOSPAH-SANTA-FE RRUS NO. OEPTH T'= S R F 20/ 0 l5 3 I , 606 2235.3 Fl 681 .z n Ro MATURITY VALUES 25 : WEAN ;a OEV PEOIAN nODE ST0 8 i5 0 a a 35 X 35 X I .a 3.0 2.0 4.0 : . HISTOGiiAn: Range: Increment: VITXINITE REFLECTANCE IRANOOn X i OROEREJ REFLECTANCE VALUES, 0.27 T0.42 T0.56 V 0 . 6 6 0.28 r0.45 T0.57 t0.67 0.33 7 0 . 4 6 T0.57 0.71 0.33 T0.47 r0.58 0.73 T0.60 0.73 0.34T0.58 0.75 0.34 TJ.50 T 0 . 6 0 3.75 0.35 T 0 . 5 1 T 0 . 6 2 78.40 70.53 10.S3 0.75 8.76 r0.J0 T0.53 10.63 ~ 0 . 4 0x 0 54 a0 64 0 77 KEROGEN OESCRIPTiON 30 X Amorpnous I 5 % Exinite Vitrinite I 35 X Inertinire 30 X 0.7'3 Back Fluor 81 lumen Coke I .E0 .05 I .E5 1 -/I- a : 8 Pled Pled Smoll . I I I I 1 I 1 I GREAT WESTERN # 1 HOSPAH-SANTA-FE RRUS NO. 8 DEPTH t 607-688 * = RO IIATURITY 8 VALUES ST0 DEV nED1AN nOoE n : 19 : 0.55 0.07 0.55 MEAN m Fr 2650.0 807.7 I 1 a. 55 HISTOGRAnt Ronget 0- 4 % Increment: 0.10X CI I I KEROGEN DESCRIPTIOI’ Amorpnous I 25 X 5 % Exini ? e 30 X Vitrinile I lnertlni te I 40 X ORDERED REFLECTANCE VALUES I x 0 . 4 1 1 0 .05. 9 72 * 0 .7 40 5.0 5 .67 5 78.45 t 8 . 5 9 X0.46 x 0 . 5 8 x0.50 30.61 t 0 . 5 1 70.63 1 01. 5 001 .06 .7 .4972 t0.53 t0.66 x 0 . 5 5 X0.68 10.55 a.71 0.86 .~ I .01 ~~~~ ~ ~ 8.76 0.76 0.77 a.77 0.89 0.89 0.80 0.92 0.g2 I .03 1.04 I .I2 1 .I3 1.18 I .21 0.84 0.84 0.85 0.84 0.84 0.98 1.22 1.33 B o c k Fluor B i rumen Coke tled t ned None I I 1.44 GREAT WESTERN # I HOSPAH-SANTA-FE RRUS No. DEPTH , I I RECYCLED .., ,.w , . . ? I 0 ...,.,.., 2’. 0 . . I . 1 ., 3.0 4.0 Ft 7035.0 2144.3 X = Ro MATURITY 8 VALUES MEAN ST0 OEV nEDIAN nODE 0 , , 8.0 610 n 2 I a.93 0.01 0.9‘ 0.95 : : HISTGGRAn: RonSa: 0- 42 Increment, 0 . i 8 : VITRINITE REFLECTANCE IRANOOPl X 1 KEROGEN DESCRIPTION Amorpnous 8 10 X 0 % Exini re Vltrinite t 40 X Inerrlnlte I 50 X ORDERED REFLECTANCE VALUES: x 02..9030 ?E. 94 I .58 I .59 1 .71 1 .76 Bock Fluor B I lumen Co h e I .78 1.86 I LOW t r j Small I 1 .Q4 1198 -72- ROBERTSON RESEARCH [US.) INC. GREAT WESTERN SI HOSPAH-SANTA-FE 25 7 RRUS NO. I 614-615 DEPTH , 757a.a I RECYCLED T = RO nATURITY F VALUES I PIEDIAN 8 nooE 0 . 04 . 0 13 . 0. 0 M I : .M E A .N. S T 0 DEV F: 2307.3 0.94 0.00 0.94 0.95 HISTOGRAPII Range: 0- 4 % Incrementl 0 . 1 0 % 2.0 VITRINITE REFLECTANCE [RANDOPI 2 ) ORDEaEO REFLECTANCE VALUES: 70.94 I .58 I .59 I .71 1 .76 I .78 I .86 I .94 I .98 2.00 2.1a -. . . . . . - Vitrlnire lnertlnlte 8ach Fluor 8 I rumen Co he lr X lr X x t I : , Low None None GREAT WESTERN * I HOSPAH-SANTA-FE RRUS No. : DEPTH , > 618 7785.0 2372.9 X = Ro MATURITY # VALUES 24 : .nEAN .. ST0 OEV PIEDIAN 3 I. ." .06 0.09 I .05 I .05 : I PIODE f i 5 :a 0.3 I 0 2.0 3.0 4.0 HISTOGRAPI: Range, 0- 4 % Increnent, 0 . 1 0 % VITRIkITE REFLECTANCE lRAN130tl % I ORDERED REFLECTANCE VALUES: a.66 X I .a3 T I . I 5 T I . 0 3 xI.15 0.78 r 0 . 8~51 . a141 . 117. 7 2 1 0 . 9 2 T I 05 X I. I 8 T 0 . 9 7 1 1 . 0 5 x1 . 2 0 T0.97 T I . 0 6 1 1 . 2 7 1 ,36 X0.98 T I . 0 6 X1.00 T I .E8 1 .39 x1 . O 1 T1.12 1.45 r1.02 T I . 1 5 1.54 6EROCElr DESCRIPTION 10 X Amorphous I x tr X Exini :e 45 Z . Vltrlnire I 45 X lnerrinite I I .56 I .61 Back Fluor B I tuman Coke -73- I I a Loa Smoll None FI PI VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT TEXACO dl NAVAJO AL I I Project No. : RRUS1823IT143lO2 S A M P L E I D E N T I F I C A T IROENF L E CKTE.R O GCEHNA R A C T E R I S T ITCOSC RXUS DEP (T FH ezt) R o 4b saas 0.74 6288 " " Am% Ex% tr tr sa? tr V i t % Inert% tr 41 t r 10 FIuor ph LOW a.g4 None IJ a. P ." -74- ROBERTSON RESEARC'i [US.] INC. TEXACO .=I NAVAJO A I RRUS N o . I DEPTH a I RECYCLED , , , , , , f f l , , , , , m , ~,,,,,,.,,,,,,..,....i 4.0 0.0 3.02.0I .0 5885.0 F t 1793.7 n T = R O MATURITY rn VALUES PIEAN S T 0 DEV MEDIAN nODE a 804 2 : 0.74 0.03 0.77 0.75 : : HISTOGRAPI: Range, 0- 4% I n c r e m e n t I 0.10% V I T R I l v I T E REFLECTANCE IRANDOPI X1 KEROGEN DESCRIPTION ORDERED REFLECTANCEVALUES: T0.71 70.77 Amorphous Exinire Vitrlnire Inerrinite I.45 I .59 I .aa B o c k Fluor B I lumen Co h e lr tr t I : I t I X Z lr X lr X Low Smoll Small TEXACO SI NAVAJO AL RRUS No. I DEPTH I t 809 6288.0 F t 1816.6 n RECYCLED f VALUES 16 : I .71 0.19 I .75 1.79 nEAN A 0 Ni G s ST0 DEV PIEDIAN RODE ' : 52 HISTOGRAPI: 1i Range: 0- 4 % . . . , .m a& I .0 0.0 2'.0 . , . . 5,. ......:..._I 4.0 0 V I T R I N I T E REFLECTANCE IRANOOil I.6Q I ncr em ent : 0.10% X1 KEROGEN DESCRIPTION I 7 50 X .Amorphous ORDERED REFLECTANCEVALUES, 1.29 1.31 1.56 1.57 1.67 : : 1.76 1.78 1 .90 1.84 1.96 1.96 Exinitz Vitrin!te Inertinlre Soch Fluor 81 lumen Coke I .71 I .72 I .75 1 .76 -75- : : 8 i I I tr X 40 X I0 X None High None I I ... I - VKIEASRNUOAAGLLEYNS I S APACHE # 1 Project No. 1 S A M P L E IDENTIFICATION URUS D E P(TFHe e t ) 101 102 103 104 10s 2065 2615 3048 106 107 108-109 112 115 4485 474s 8910 9345 9675 3995 R E F LLEICGTHETD FOSHAY RRUS1823/T143/02 : R E F L E CKTE.R O GCEHNA R A C T E R I S T ITCOSC RO 0 0 0 0 . . . . 4 4 5 4 n Am% En% 4 4 1 9 251 201 20 10 5 10 " " a. 58 Y -76- 15 5 10 5 Vi tY I n e r t % F I u o r 50 45 45 55 65 20 25 60 4c 5.38 6 .08 15 Med Low High Med Med 15 Hioh 3.67 30 15 0.65 6 . 2 5 6.00 ROBERTSON RESEARCH [US.] INC. APACHE It I FOSHAY NO. RRUS DEPTH 101 > 2065.0 F1 629.4 n I I f = Ro I VALUES IIATURITY nEAN ST0 DEV IIEOIAN 35 I 0.44 0.05 0.43 0.45 I : nDOE HiSTOGRAM: Range: 0- 4% Incremenr: 0.10% CRDE3EO KEROGEN REFLECTANCEVALUES: OESCRIPTIDN : 25 % Amorphous 70.35 70.42 70.43 70.49 *a zR xa.42 .- 70.43 -~ 70.49 ~ 0 . 3 870.42 70.44 70.52 70.38 ra.42 r0.44 t0.57 70.39 78.42 70.46 f0.59 T0.39 70.42 '10.46 I0.39 78.43 70.47 70.40 70.43 10.48 X0.40 70.43 70.48 70.41 70 43 70.48 I 5 % Erlnire Virrinire I 50 % I 20 % Inert inite Each Fluor 8 ned I Small 81 rumen I None Cohe ~ APACHE a t FDSHAI 25 7 5 RRUS ! NO. DEPTH ! I , I f 20 15 E I02 45 0.44 0.05 a.44 0.45 MEAN S T 0 DEV : P)EDIAN : nooE 5 n Ro RATURITY D VALUES : I0 Fr 2615.0 797. 1 HISTOGRAP): Range; la- 4% Incremenri 0.10% a V I T R I N I T E REFLECTANCE IRANDOil 6ERDGEN DESCRIPTIOb' ORDERED REFLECTANCE VALUES 10.33 T0.40 70.44 rO. 47 T0.34 T0.40 f0.44 10.47 70.34 70.40 T0.44 70.47 x0.35 ?0.41 70.44 70.47 XB.37 70.42 30.44 T0.47 78.37 10.42 70.45 LE. 4 8 re. S 8 78.43 70.45 r0.49 7e.40 70.43 70.45 10.50 70.40 1B. 44 '10.46 T0.50 ~ 0 . 4 070.44 ~ 0 . 4 6 f9.50 X1 ?0,E0 10.51 r0.51 70.54 r g . 56 : 20 I0 45 25 8och F l u o r 6 I rumen r LOV Cohe I None Amorphous Exlnite Vitrlnlte Inertinire - 77- : I I , X x X X Small APACHE El FOSHAY RRUS NO. t DEPTH > 103 3048.0 929.0 I Ft n r = RO PIATURITY n n R I0 50 1 VALUES PEAN ST0 OEV nEOIAN nOCE 5 I 26 8 0.51 0.07 L 0.52 0.45 HISTOGRAPI, Range, 0- 4% Increment2 0.10% 0 0.0 VITRINITE REFLECTANCE IRANOOPI % I KEROGEN OESCRIPTION Amorphous I 20 % 8 5 % Exinite Vltrinite I 45 X Inertlnite t 30 X OROERED 4EFLECTANCE VALUES: I I I' 7 0 .r400.T409.05.9 07.38 3 7 0 .r400.X 40 9.05.0 97.48 3 X0.42 7 0 . 5 0 T 0 . 59 7 0 . 4 3 7 0 . 52 * E . 6 0 T0.44 T 0 . 5 3 70. 62 X0.45 * E .53 r 0 . 6 5 0.70 70.45 r 0 . 5 5 0.71 7 0 . 47 x 0 . 5 5 0.71 x0.47 7 0 . 5 7 0.72 T 0 . 48 70 .5a 0.75 0.75 0.76 0.77 0.79 0.81 0.81 0.81 0.86 0.88 0.89 0.96 0.99 I .OO I .06 1 .E7 I APACHE SI Back Fluor E i lumen Coke j R R U S NO. I 104 DEPTH t I I .E 3 . 0 I " " ~ " " I " " I ' " ~ I 2.a 1.0 34Q5.F 1065.3 7 = RO PIATURITY a VALUES PIEAN S T 0 OEV EEOIAN PIODE 0.0 I High Small None FOSHAY n 0 I Ft PI 37 I 0.49 0.03 0.49 0.45 > 4 HISTOGRAPIS Range: 0- 4% Increment, 0.1'2% VITRINITE REFLECTANCE (RANOOP1 % I r Y Y KEROGEN OESCRIPTION Amorphous I 18 % Exinlre I I0 X Vitrlnire I 65 X Inerrinlte t 15 X OROEREO REFLECTANCE VALUES: 0 . 3720 . 4740 . 4770 . 5 0 0.37 ~ 0 . 4 4 r0.47 8 . 3 7 x0.44 ~ 0 . 4 8 0 . 3 8 70.45 7 0 . 4 9 0.39 r 0 . 4 5 10.49 0 . 4 0 70.46 r 0 . 4 0 0.41 r 0 . 4 6 r 0 . 4 9 0 . 4 1 X0.47 X0.48 X0.43 7 0 . 4 7 T 0 . 5 0 70.43 70.47 x0.50 30.52 70.50 ~ 0 . 5 2 ~ 0 . 5 0 r0.52 10.50 T0.52 r0.51 r 0 . 5 3 70.51 x0.51 each Fluor 81 lumen Co he T0.51 X0.51 70 51 -78- I I I ned None None ROBERTSON RESEARC'1 [US.] INC. APACHE El FOSHAY RRUS N o . 25 7 OEPTH I05 3985.B Ft 1217.7n I I CAVED 35 II VALUES : nEAN ST0 OEV PIEOIAN 0.44 0.04 0.44 0.45 I t nOOE HISTOGRAn, Ronge: 0- 4% Increment: 0.10% ORDERED VALUES : 0.34 0.36 0.36 0.38 0.3g 0.39 0.40 0.42 0.42 0.42 0.48 0.49 0.50 0.51 a.52 0.43 0.43 3.43 0.43 0.43 0.44 0.44 0.44 0.45 0.45 0.46 0.46 0.46 0.46 0.46 0.47 0.49 0.48 KEROGEN DESCRIPTION Amorphous Exinite : Vlrrlnite I Inerrinlte I Bock Fluor 9 1 lumen Coke z , 15 5 65 15 X % X X Med None None I 8 APACHE a 1 FOSHAY RRUS NO. 'I = 8 VALUES 8 106 R o flATURITY nEAN ST0 OEV tlEDIAN a : 0.58 0.0e 0.54 0.55 : : nODE HISTOGRAM: Range, 0- 4% Increment: 0.10% V I T R I N I T E REFLECTANCE (RANDOti X1 VALUES : 0.33 0.41 0.36 0.37 0.38 0.38 0.38 0.38 0.38' 8.39 -0.39 . .. 0.41 0.39 0.40 0.40 0.40 0.40 0.40 0.41 0.41 0.41 0.41 0.41 0.42 0.42 0.42 0.43 0.44 0.44 0.44 0.45 0.4 0.45 0.46 0.A7 0.47 0.48 10.50 r0.50 r0.52 X0.53 70.54 '?0.64 r0.69 *0.i2 1.13 -.. . . . . . Vitrinite Inert i n i r e Bock F l u o r 8 I rumen Coke -79- ; I I I I 60 x 15 X Hlgr None None m APACHE * I FOSHAY RRUS NO. DEPTH I 107 I 4745.0 : 1446.3 Ft n X = Ro MATURITY E n MEAN ST0 DEV nEOIAN nOOE . I I I 1 I II" I I I VITRINITE REFLECTANCE LRANOON I AEROGEN DESCRIPTIC:' Amorpnous I I0 X OROEREO REFLECTANCE VALUES: 0.42 0.48 70.53 0.84 0.42 0.51 X0.64 m - . . . -4 ~ 0.51 ~ 0 . 6 4 0.44 0.52 X0.65 0.45 0.52 x0.66 0.47 0.53 x0.73 0.47 *E.55 X0.74 0.47 X0.57 X0.75 0.47 x 0 . sa X0.76 0.48 X B . S ~ 0.83 ~~ 1.05 0.86 Frinite __ ~.. - 1.07 1.09 0.87 ! virrlnire Inertinire 1.10 1.11 0.90 0.93 0.93 0.93 0.97 0.99 I .00 Bock Fluor B I rumen Coke 1.18 1 .27 1 .31 1 .31 : la 35 % X 45 X I x I ned ned Nons-. 1.51 - APACHE 81 FOSHAY HRUS NO. DEPTH I 108-109 I 8910.8 I k 2715.8 x = R o MATU9ITY 0 l5 E F VALUES MEAN STD DEV MEDIAN MODE S 0 ,....,. 0.0 F ,. . . ," , . . . . , I .a I 2.0 ~~ . I / . . , 3'.0"" YITRIN!TE REFLECTANCE IRANOOn .A, 0.66 0,07 0.64 0.65 : %I G P 13 : HISTOGRAM: Range. 0- 4% Increment, 0.10; 0 1 0.0 25 VALUES " ' 4 I .0 1 1 I .40 0.00 I .40 : : 1.45 HISTOGRA2: Ronge: 0- 4X Increment: 3.10% X1 KEROGEN DESCRIPTION Amorpnous I 35 % Exlnite : 5 % Vlfrinite I 25 X Inertinlle I 35 X ORDERED REFLECTANCE VALUES, 0.70 0.m X 1 .40 Bock Fluor B i tumen -9 Coke -80- 8 Lor j None I None Ff n APACHE a1 FOSHAY RRUS NO. I DEPTH I 112 CAVED ? T = Ro IIATURITY I VALUES nEAN ST0 OEV MEDIAN nOOE .......................... 4.0 3 .00. 0 2 . 0 1 0.50 0.50 0.50 0.51 0.52 0.53 I .40 0.00 I .40 I .45 I I HISTOGRAD: Ronge: 0- 4 % Increment. 0 . 1 0 % XI KEROGEEI OESCRIPTION Amorpnous I 20 X : I0 x Exinite Vitrinite v 50 X Inertinite I 20 X OROEaED REFLECTANCE VALUES, 0.55 0.54 0.55 a .05. 5 81 0.58 0.61 0.66 0.67 0.68 I I I .0 VIT2INITE REFLECTANCE IRANDOn 0001...3 .5707314 0.38 0.46 0.45 Ft n 9345.0 2848.4 : 0.73 0.78 0.78 1.05 1.11 I .I5 ~1.40 Bock Fluor 0.82 0.89 0.92 0.93 1.02 B I lumen Coke X ned Pled I tr APACHE * I FOSHAY RRUS NO. DEPTH CAVE0 7 G = Ro E I 115 : 5675.D I 2948.9 VALUES 2 8 1 .75 0.03 I .73 1.75 t : nOOE 1 n RATURITY nEAN ST0 OEV XEDIAN O.a Ft HISTOGRAP1, Rnnge: 0- 4 1 Increment: 0.IBX .a VITRINITE REFLECTANCE IRANDCPI XI CESCRIPTION 10 X Amorphous I 40 X Exini re Vltrinlte I 35 X !5 % Inertlnite LOW Bock Fluor I I None 8 1 tumen , tr Coke KEROGEN OROE3ED REFLECTANCE VALUES: 0.52 ' 0.53 0.63 0.70 B.97 ri .72 T I .79 I .90 I -81- 1 I 1 I 1 I ~1 1 I I I I I m " VISUAL KEROGEN ANALYSIS AMERADA # 1 P r o j e c t No. I : - REFLECTED LIGHT NAVAJO TRACT-20 RRUS1823ITI43I02 C S A M P LIED E N T I F I C A T I ORNE F L E C TK,E R O G ECNH A R A C T E R I S T ? CTSO RRUS D Z P(TFHe e t ) Ro % Am% E x % Vi t% 1.06 5 0 75 0 0 20 1.12 60 60 5 40 t K 70 40 i Io9 " " 1.24 -82- tr 20 I n e rFtl%u o r 20 20 20 25 20 ~~ ~ % Xed 3.19 High 0.40 High LOW LOW ~ ~~ ____ ---"" ROBEqTSON RESEARCH (US.] INC. AMERAOA 111 NAVAJO TRACT-20 25 7 RRUS No. DEPTH 0 F b5 2.0 4 I 6768.0 I 2062.9 V = 8 VALUES : V I T R I N I T ER E F L E C T A M E 1 .06 8.08 I .08 8 3 I . 15 IRANOOM X I ORDERED ZEFLECTANCEVALUES, 0.34 E.71 7 0 . 9 1 71 .I8 00.X.57 182 .01 1.65 KEROGEN DESCRIPTION Amorpnous t 5 X E x i n l !e : 0 % Vltrinite : 75 X Inertinite I 28 % Back F l u o r 0.65 0.67 0.69 I2 HISTOGRAM, Rongea 0-4% Increment: 0 . 1 0 % 0 0.0 8.63 Ft M Ro MATURITY MEAN S T 0 OEV MEDIAN MOOE 0 8 0 79 0.80 0.81 Z0.89 Z1.10 X1.10 71.11 XI : B I lumen 8 Co : he fled Hign None .I3 AMERAOA 1 1 NAVAJO TRACT-20 RRUS No. DEPTH I 3 4 5 6823.0 F t 2079.7 M X = RO MATURITY L VALUES MEAN ST0 OEV MEDIAN MOO€ 8 I I .09 0.09 I .!2 I .I5 : : HISTOGRAMt R o c g e : a- 4% I n c r e m e n r : 0.18% V I T R I N I T E REFLECTANCE (RANDOM X 1 ORDERED REFLECTANCEVALUES: 10. .2871 0.83 1 .30 r(ER0CEN DESCRIPTION : 60 X Amorphous I 0 % Exinire : 20 X Vltrinite I n e r r i n i t e : 28 X Sack F l u o r 8 I lumen Co he I , b Hlgn Hign None JI I I I I I I I m .. AVERADA E l NAVAJO TRACT-20 RRUS NO. DEPTH 13-14 I , I 7045.0 2147.3 Ft n T = RO nATURITY VALUES I .0 2.0 1.0 nEAN S T 0 OEV PlEOIAN nooE &! 5 0 0.0 , , , , , , , , , , ) , , , , , , , , , / , , , , I 10 8 1.12 0 . 14 I .IS I . 15 : I HISTOGRAn, Rongea 0- 4 Z Increment I 0,10:: VITRINITE ZEFLECTANCE [RANOOn 21 KEROGEN OESCR IPT 101 I 60 % Amorphous : a % Exinl re I 20 % Vltrinlte I n e r t i n i t e : 20 f ORDERED REFLECTANCE VALUES: 0.67 T1.27 a . 7 7 X I .33 q0.65 10.96 .05 * I .05 XI Back Fluor B I lumen Cohe X I . 17 X I , 18 X I . 19 I : I Higll Hlgll Nonp X I . 18 AVERADA S I NAVAJO TRACT-20 RRUS No. I DEPTH , I 19-20 7175.0 2186.9 Fr V RECYCLED rn I;Ilh ;5 00 . 0 V ! T R I NII T. 0 E ORDERED I 30 I .40 I .46 ." 1.51 1.51 I .iK 1.53 I .53 1.54 I .57 REFLECTANCE 2.0 IRANOOM 3.0 XI REFLECTANCE VALUES: I .58 1.68 I .82 1.72 1 .82 1.7 60 1.74 I .61 1 .70 1.76 I .64 I .85 1.62 1.70 1.76 1.62 1.77 1.70 I 85 1.78 1 ,85 I .63 1.70 1.71 i .sa 1 . 8 5 1.64 1.71 I .80 1.65 I .86 I .87 1.71 I .81 I .66 1 .82 I.S8 1.72 1 .87 1.87 1 .90 I .Q0 1 .90 I .Ql I .98 2.00 2.01 2.84 2.06 E VALUES I nEAN S T 0 DEV REDIAN : 64 I .75 0.13 I .76 : I .a5 PlODE HISTOGRAV: Range, 0- 4L Increment: 0 . l W 4.0 2.07 2.16 2.20 2.20 KEROGEN DESCRIPTION Amorphous : 5 I I 0I: Exinlte Vlrrlnlre : 70 f Inwtlnlre Back Fluor 81 rumen Co he : I 25 f Low I ned a None ROBERTSON RESEARC'i [US.] INC. -84- AnERAOA E l NAVAJO TRACT-20 RRUS No. OEPTH RECYCLED T = 8 VALUES I 23-24 I 7365.0 1 2244.9 Rn RATURITY IIEAN S T 0 DEY IIEOIAN 12 I 1 .26 0 . I3 , I .23 I .25 : RODE I 0.0 HISTOtRAn: Ronge, 0- 4 % Incremenr I 0.13% .a4.0 3.0 2.0 V I T R I N I T E REFLECTANCE IRANOOII ORDEREJ REFLECTANCE VALUES I Xl.05 71.47 71 .I2 vI.47 TI.14 1.50 TI.17 1.50 r1.21 1.51 Xl.23 1.52 1.55 I .57 I 59 1.59 tl .23 r1.2a Xl.33 Xl.38 1.59 1.60 1 .61 L62 1.63 1.63 Each F l u o r B I lumen Co h e I .a5 I .a7 I .90 1.72 1.73 i .95 X1 KEROGEN OESCRIPTION a 40 % Amorpnous Exinite I 0 % I 40 % Vitrinire Inert i n 1 r e I 20 % 1.80 I .a2 1.83 I .83 I .84 1.66 1.66 FI n I I > Lou High None I .9a -85- I 1 ". m m I I VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT SHELL R l 1 3 - 1 7 C A R S O N U N I T Project N o . : RRUS1323IT143/02 SAMPLE IDENTIFICATION REFLECT. KEROGEN CHARACTERIETICS TOC I RRUS I I I 20 P I DEPTH (Feet) Ro % 65 0.37 0.41 0.38 300. 4 3 0.44 203 204 205 1515 206 207 2645 3055 208 209 3615 4005 2 1 0. ~. 4~. 5 6.5. 0.49 0.54 0.56 21 1 212 SO25 0.56 5505 0.67 213 1 . 612501256-52 1 6 2 17-2 1 8 . 219-220 10825 21-222 223-224 10 10725 11005 Ex% Vit% Inert% Fiuor 10 10 1s 10 5 10 15 1.66 1.63 1.75 1.91 -86- la 15 Xed 4s 60 40 20 LOW Med Med S 15 60 5 15 5 10 55 60 30 5 10 3 0 5 5 10 5 0 1 0 20 io 50 15 15 % 35 20 20 5 1 . 6 51 0 0 3 3 10495 Am% 0.34 0.34 0.44 0.85 LOW 3.08 25 Med 20 Med Me d Med High 3.02 5.23 I . 18 3.81 1.50 LOW 0.88 20 3s 10 50 3 10 0 10 5 5 40 60 3: 45 20 . 4s 3s Low Pled Low 5 40 40 Low None ---------- ------- ROBERTSON RESEARCH [US.] INC. SHELL E113-17 CARSON UNIT -. 25 RRUS No. t OEPTH I 203 1025.0 F t I n 312.4 T = Ro nATURITY E VALUES 13 I 0.37 0.06 0.36 0.35 0.0 1 .0 VITRINITE REFLECTANCE IRANOOPl % I AEROGEN DESCRIPTION Amorphous ; I0 X Exinire I 10 x Vitriniie : 65 % lnertlnite : 15 X ORDERED REFLECTANCE VALUES: 30.31 70.31 70.33 78 .33 x0.34 HISTOtRAnl Range: 0- 4% Increment: 0.10% 70 42 T0.42 70.52 Back Fluor 8 i tumen Coke ned None None : : , SHELL S113-17 CARSON UNIT RRUS No. 201 OEPTH 0 F l5 I 204 I I 1515.8 461 . B T = Ro PIATURITY It VALUES nEAN S T 0 DEV FI Pl 5 8 0.41 a . 10 0.37 0.55 I HISTOGRAPI: E'ange: a- 4% Increment 8 0 . ! 0 % VITRIN!?E REFLECTANCE [RANGOM X 1 KEROGEN OESCRIPTION AmorpncUS I 5 % Exinite ' : 15 Z vitrinile I 35 Z Inerrinite I 45 X OROEFZED REFLECTANCE VALUES: * E . 29 X0.34 T0.37 X0.51 T0. 53 0.64 -87- B o c h Fluor B i lumen I I LOW None Coke I None 1 1 I I I I I 1 I I I I I I I SHELL n-113-17CARSON UNIT RRUS NO. I 205 DEPTH I 2185.8 1 * = Ro IIATURITY a VALUES , MEAN ST0 OEV MEDIAN MODE Ft 641.6 fl I 31 0.38 0.04 : , 0.38 E . 35 HISTOGRAfl: Range, E- 4% Increment, 0.10% ORDERED REFLECTANCE VALUES I 8.27 rE.35 0.29 30.35 T O . 32 X E . 3 5 10.32 70.36 XE.32 r0.37 T0.32 XE.37 TE.33 XE.37 T0.33 XE.38 28.33 X0.38 XE.34 XE.38 ~ ~~ KEROGEN DESCRIPTION Amorphous : IE X Erinite I IE X V. .I. . ~. .P. . .I ~ I,. ~ Ra D z Inertlnite 28 X TE.39 XE .44 XE.. 3. 9 X0.45 T 0 . 5 9 VE. 47 - ~ r0.41 78.42 xE.42 70.43 XE.43 XE.44 rE.44 0.63 0.87 -- - Bock Fluor 8 I tumen to he I I I flea None None SHELL *113-17 CARSON UNIT 9 I RRUS NO. : OEPTH I I W = RO MATURITY E VALUES nocE 1 0 2.0 3.0 VITRINITE REFLECTANCE IRANOOM 78 .42 70.42 XE. 43 T O . 43 t0.43 78.43 X'd. 44 '16.45 3 E . 45 JE .45 T0.45 * E . 46 T0.48 V E . 48 X0.48 VE.51 * E . 55 T0.55 7E.62 *E. 66 58 ; 8.43 0.06 0.41 : : 9.45 AISTOGRARI Range, a- 4% Incremenl: a,lE% X1 KEROGEN DESCRIPTION Amorphous I 38 X I IE X Exinite Vltrlnire I 48 X Inerrinite 1 28 X ORCERED REFLECTANCE VALUES I '16.35 r0.39 38.41 70.36 10.46 38.41 ~ 8 . 3 6~ 0 . 4 0ra.41 XE.36 FE.AE 78.41 X E . 3 8 38.48 X0.41 X E . 3 9 10.40 JE.41 ~ 0 . 3 9 ~ 0 . 4 8r8.41 X 0 . 3 9 38.48 T0.42 70.38 T E . 4 1 38.42 78.39 XE.41 18.42 4.0 2645.8 F t 806.2 tl 1: flEAN ST0 OEV MEDIAN E 0.0 206 Bock I ned 8I Fluor lumen t tled I None Coke -88- ROBERTSON RESEARCH [US.] INC. SHELL 0113-17 CARSON UNIT RRUS No. I DEPTH 9 t 207 3855.8 F T 031.2 M 7 = Ro PIATURITY If VALUES nEAN Sib b E V PIEOIAN nom 34 1 -0.44 . . . 0.06 0.43 0.45 ; : .HISTOGRAM: Ronge: 0- 4% Incremanr: 0 . i 0 X I(ER0GEN OESCRIPTION I 5 X Arnoronous .~ ." Exlni le I I5 Vilrinife , 60 X Inerrlnite I 28 X ORDERED REFLECTANCE VALUES: 30.34 '40.41 70.44 T8.52 T0.35 T0.41 x0.44 70.54 70.36 70.41 70.45 x0.55 78.36 78.42 70.45 70.64 70.38 30.42 X0.45 70.48 10.42 ? E 47 78.40 70.42 70.47 10.40 X 0 43 10.48 70.48 78.43 70.58 78.41 70.44 r0.58 r r~ ~ B a c k Fluor 8 I lumen : Coke I Low None None SHELL 9113-17 CARSON UNIT 25 A RRUS _I No. DEPTH I I : 208 3615.8 ll01.9 T = RO MATURITY 8 VALUES nEAN ST0 DEV PEDIAN nODE 50 , 6.49 0.87 8.48 8.45 : : HISTOGRAPI: Ronge, 0- 47. . a4.8 4.8 3.0 3.02.a Incrnrnenfs 8.18% ORDERED REFLECTANCE VALUES: KEROGEN DESCRIPTION 5 X Amorphous I 8 15 % Exinile Vltrinile 8 55 % inertinlte I 25 % a.a 1 VITRINITE REFLECTANCE 12ANDOM % I 10.31 ?E,40 V0.40 78.41 70.41 70.42 70.43 70.43 *0.43 7 8 , 44 70.45 70.46 T0.50 T0.53 30.45 70.47 70.58 70.53 8 0 . 4 5 T0.47 T0.50 10.55 r 8 . 45 x0.47 ?0.50 10.45 7 8 , 48 70.50 70.45 78.48 78.51 70.46 70.48 70.51 TO.46 70.49 70.52 T0.46 70.49 70.52 70.69 10.46 70.49 70.53 7 8 . 78 B o c k Fluor 8 I lumen Coha -89- I ned a Med , None Ft n 4 l I I I I I I SHELL 8113-17 CARSON UNIT RRUS No. I DEPTH : E 209 4005.0 1220.7 X = Ro flATURITY 8 VALUES flEAN ST0 OEV MEDIAN noDE Ft n 50 s 0.54 0.07 0.52 0.55 I : HISTOGRAfl; Range, 0- 4% Increment. 0.10% OROERED REFLECTANCE VALUES, X0.40 X0.90 70.52 70.53 70.58 7 0 . 4120 . 5100 . 5 2 ~- 7 0 . 5 4 X0.43 3 0 . 5 1 7 0 . 5 2 3 0 . 5 5 X0.44 X0.51 1 0 . 5 2 3 0 . 5 6 X0.46 Xp1.51 X0.52 X0.56 7 8 . 4~68 . 5~10 . 5720 . 5760 . 6 4 q 0 . 4178 . 5710 . 5 2 X0.57 7 0 . 4 7 70.51 X0.53 7 0 . 5 7 X0.48 X0.51 70.53 7 0 . 5 7 3 0 . 4 9 X0.51 X0.53 70.57 ~ ~~ ~ KEROGEN OESCRIPTION 5 X Amorphous : : I0 X Exinlte Viiriniie I 60 % Inertlnite : 20 X X0.58 Z0.60 X0.61 70.63 Bock Fluor B I lumen 70.68 70.70 X0.70 X0.70 SHELL a113-17 CARSON I 1 Red None None Coke : RRUS No. 210 UNIT DEPTH I I 4565.0 1391.4 7 = Ro nATURITY a VALUES MEAN ST0 OEV flEDIAN flO0E Ft n 48 : 0.56 0.07 0.56 0.55 : I AISTOGRAn, Range, 0- 4% Increments 0.10% OROEREO REFLECTANCE VALUES X0.45 X0.50 X0.54 7 0 . 4 5 ‘70.50 X0.45 ‘70.50 X0.45 70.50 7 0 . 4 6 X0.51 7 0 . 4 6 X0.52 7 0 . 4 6 X0.53 7 0 . 4 6 70.53 X O . 47 7 0 . 5 4 X0.50 7 0 . 5 4 70.59 7 0 . 5 5 70.60 7 0 . 5 5 70.60 7 0 . 5 6 70.61 1 0 . 5 6 X0.61 X0.56 Z0.62 X8.57 7 0 . 6 2 70.57 30.62 X0.58 7 0 . € 2 X 0 . 5 8 7 0 . 63 X0.64 70.65 X0.66 70.67 70.67 70.67 70.70 T0.70 0.94 1.08 KEROGEN OESCRIPTlON Amorphous : 5 X Exinire I I0 x ViTrlnire : 55 X Inertinite I 30 X Each Fluor Bi tumen Co h e .go- I fled I fled I None ROBERTSON RESEARC’i [US.] INC. SHELL El13-17 CARSON UNIT 25 -, RRUS No. : DEPTH I 211 5625.0 Ft 1531 .6 M j T = Ro MATURITY If VALUES MEAN ST0 DEV MEDIAN MODE 31 > 0.56 0.11 0.52 : : 0.55 HISTOGRAM: Range: 0- 4% Incremenr: 0.10% I I I I VITRINITE REFLECTANCE [RANDOM% ) REROCEN DESCRIPTION Amorpnous I0 X Exlnile I I0 X Vitrlnlte I 50 % Inertinite 30 X ORDERED REFLECTANCE VALUES: 0.36 70.51 x0.53 70.85 70.45 ~ 0 . 5 1 70.54 30.90 30.47 r0.52 X0.55 30.48 X0.52 r0.55 10.49 ~ 0 . 5 27 0 . 5 6 30.51 50.52 T0.56 70.91 r0.52 70.62 r E . 5 1 T0.53 70.67 70.31 T0.53 r0.73 70.51 70.53 r0.76 d I Back Fluor E I turnen Coke Med None None I I t I I I 9 S H U L u113-17 CARSON UNIT RRUS NO. I OEPTH : i 212 5505.0 Ft 1677.6 rn := Ro tlAlURITY E VALUES MEAN ST0 OEV MEDIAN RODE 36 : E. 67 0.14 0.66 0.55 : : HISTOGRAM, Range: 0- 4 % Increment 2 0.10% VIiR!NiTE ?EFLECTANCE IRANOOM X I ORDERED REFLECTANCE VALUES: 50.43 x0.54 X0.71 r0.85 t0.47 70.55 10.72 :E. 85 ~ n49. '~0.5678.73 X0.88 70.50 r0.56 X0.74 T0.89 30.51 ~ 0 . 6 010.75 50.91 70.51 ~ 0 . 6 0 70.77 I0.82 70.52 X0.61 70.78 8.96 70.53 X0.62 t0.79 0.99 1 .a0 70.53 70.6s 70.81 r0.54 X0.63 t0.82 I .E0 .at .02 .03 .06 ,07 .07 .09 11 KEROGEN DESCRIPTION Amcrpncus : 20 % Exinlre : 10 % Vitrinlfe 50 X lnertinite L 20 % eock Fluor ~i tumen I Coke I I Hign Small None I I I I I I . I SHELL 8113-17 CARSON UNIT ". f 10 RRUS N o . , DEPTH ~10033.0 Fr I 3058. I t l t = Ro RATURITY 8 VALUES 0 6 t REAN ST0 DEV flEDIAN nODE A 213 1.65 0.BE 1 .71 1.7E I I HISTOGRAfl, 0.0 4.0 3.0 Ronge: 0- 4:: , ' , ' , , " ' , , ' . . . , . , . . I Increment: 0.I0x 2.0 VITRINITE REFLECTANCE lRANDOfl X 1 r r P I' ORDERED REFLECTANCE VALUES, 0.50 0.86 r1.71 0.53 0.91 1 1 .72 0.590.95 11.74 0.60 1.00 1 . 8 6 0.62 I.II 1.86 0.63 1.23 1.90 0.67 1.25 1 .."P 3 0.69 r1.57 1.97 0.70 ti.61 1.97 0.80 TI.62 2 . 0 2 I(ER0GEN OESCRIPTIOK 5 X Amorphous I Exlnite 2 10 x Virrlnlte I 50 X Inertinire t 35 X 2.07 2.15 B o c k Fluor rumen Coke 8I : I I Low None Smoll SHELL U 1 1 3 - 1 7 CARSON UNIT RRUS NO. DEPTH 4.0 1 0 3.0 2.0 1 ' ' ' I " I . . I 118265.0 Ft 1 3128.8 n = Ro tlAlURITY 8 VALUES RODE . , , . , m i " 215-216 T nEAN ST0 DEV REDIAN 0 , , 0.0 I 9 1 1 .65 0.15 I .71 I .75 I , HISTOGRAfla Ronge: 0- 4 % Incremenr: 0.10% VITRINITE RFFLECTANCE IRANDOEx1 OROERED REFLECTANCE VALUES: Yl) Y 0.42 0.51 0.52 0.54 0.68 0.83 0.96 1.12 X1.37 t1.40 KEROGEN DESCRIPTION Amorphous I 20 Z Exlnite L I0 x Vitrinlte I 40 X Inertinire I 30 % .61 tl.65 *I .71 X I .73 X I .75 71.76 tt.85 XI B o c k Fluor tumen Coke 8I 1.90 1.96 2.04 -92- I I I None None None 25 SHELL EI13-17 CARSON UNIT - RRUS No, DEPTH 110495.0 Ft : 3198.9 n T = RO MATURITY a VALUES 2: 0 0. 13 1 .67 1 .65 I I HISTOGRAM: Ronge. 0- 4% Increment: 0.10% 3'.0 X1 6EROGEN DESCRIPTION ORDERED HEFLECTANCE VALUES: 0.51 x 1 . 5 1 rl.84 0.62 x1 .54 X I .85 0.75 XI .58 1.90 I .92 0.90 71.61 1.92 0.95 71.63 1.95 1.01 71.67 1 . 1 1 5 31.68 1.95 1.24 71.73 1.96 2.01 1.25 Xl.75 2.02 X1.40 T 1 . 8 1 13 8 1 .66 MEAN ST0 OEV PIEDIAN nOOE VITRINITE REFLECTANCE IRANDOPI 217-218 8 Amorphous 2.02 2.16 Exinlre Virrlnlre Inertinire Back Fluor B I turnen Co he : I0 X 8 s 10 % 60 X 20 X I Low I Small , None f I SHELL g113-17 CARSON UNIT RRUS NO. : 219-220 I x = Ro MATURITY VALUES 8 I VtTRINITE REFLECTANCE [RANDOM X I KEROGEN DESCRIPTION ORDERED REFLECTAWE VALUES, Amorphous 0.56 TI .41 0.58 71.43 0.65 71.46 0.85 Exinite Vltrlnlre Inertinite TI .61 0.91 X1.71 1 . 0 1 31.71 1.06 XI.74 1.10 x1.97 I .I2 1 .I2 Bock Fluor E I lumen Coke -93- : I I 8 I a 15 X 5 % 35 X 45 X ned Small None I 1 I I 3I I SHELL n113-17 CARSON U N I T 25 7 . - 0 0.0 3.02.01 .0 4.0 RRUS No. z DEPTH ,18825.0 F t 8 3299.5 n % = Ro 11 VALUES 221-222 PIATURITY PIEAN STD OEV PIEOIAN PIODE 5 : 1.75 0. I3 1.75 : : I .65 HISTOGRAPI: Ronge: 0- 4 1 Increment : 0.10:'. V I T R I N I T E REFLECTANCE IRANDOPI X I KEROGEN OESCRIPTI31' ORDERED REFLECTANCEVALUES) Arnacnnous --- 0.65 rl.85 0.76 T l . 9 4 0.97 2.08 1.00 2.15 1.09 2.25 B o c k Flugr B I turnen Coke is 1.29 .60 TI .SI V I .75 71 . I Exin1 t e Vltrlnlre Inerrinite I 9 I I I I I5 X .~ 5 % 45 X 35 X Low horn Nom? SHELL 8113-17 CARSON U N I T DEPTH I I 11005.0 F I n 3354.3 7 x Ro nATURITY E VALUES PEAN ST0 OEV KEDIAN PIODE ti 5 1 01 . . . , l ~ . + , r . 0.0 1.0 I ' ' ' ~ , ~ ~ ' ' I ' ' " 1 2.0 3.0 4.0 5 I 1.91 0.0.3 I ,93 1 .93 : : HISTOGRAPI~ R o n g e : 0- 4 7 I n c r e m e n r < 8.10: V I T R I N I T E REFLECTANCE IRANOOM X 1 r Y ORDERED REFLECTANCE VALUES) 0.53 X 1 . 8 4 .. . vitrinlte Inerrinite 0.56 TI.90 0.88 * I .95 0.90 72.06 " 1.01 B o cF kluor 81 l u m e n Coke 1.14 1.21 I .23 1.51 X I .80 -94- ; I 2 I , 46 X 40 X Low Smoll None ROBERTSON RESEARC'i [US.] INC. VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT SUN # 1 N A V A J O L A N D S Project N o . : R R U S / 8 2 3 / T / 4 3 / 0 2 TOC S A M P LIED E N T I F I C A T I ORNE F L E C TK,E R O G ECNH A R A C T E R I S T I C S RRUS 301 Ro % Am% €x% 15 t c 65 10 20 15 6a 25 10309 10595 1.73 10 tr tr tr 75 9975 1.62 1 . A2 1.62 1.84 15 5 50 DEPTH (Feet) 9225 9645 -95- 15 Vi t% so Inert% 40 30 Fluor Law Law Med Low Med % 0. 1 1 0.12 0.1? 0.12 0.25 1 1 1 1 .. , SUN S1 NAVAJO LANOS 9 NO. RRUS 1 = E VALUES RO MATURITY MEAN ST0 DEV MEDIAN PIODE l0 RS 5 Id s 1.62 0.16 I .67 I .65 : I HISTOGRAM: Ronge) Incrementa 0 X1 KEROGEN OESCRIPTIOI' 15 X Amorphous : L lr X Exini le 65 X Vltrlnlte I Inert In1 I te 20 X ORDERED REFLECTANCE VALUESI 71.68 '11.70 ... -1.74 V I .75 TI .E3 1.14 . l. -a T I .35 x1 . 3 6 XI . 4 2 T I .45 '11.60 . T1.64 T1 .65 TI . 6 7 t LOW 8I rumen Fluor I High Co h e t Small Bock T I .88 2.03 2.39 ~~ 0- 4 % 0.10% .0 . VITRINITE REFLECTANCE IRANOOM 1, X 301 I SUN -1 NAVAJO LANOS RRUS 25 7 No. OEPTH 304 I t T = 8 VALUES 2Q3Q.E Ft fl MATURITY Ro flEAN STD DEV flEOIAN MODE 1 "1 9645.0 10 I 1 . Si? : 0. I0 : I .65 I .55 HISTOCRAMz 0 . , . . , . , , , , . . . . , . , , . , . . , . ( . . / , , . . , . , . . . 4. /. 0 I .0 0.0 3.0 2.0 VITRINITE REFLECTANCE IRANDOM Range) 0- 4': Incremenrt 0.10: XI 3 KEROGEN OESCRIPT 10'1 : 10 X Amorphous t tr X Exlnite 75 % Vitrlnire t 15 X Inert lnite8 ORDERED REFLECTANCE VALUES, Y "9 Y 1.29 7 1 . 6 8 1 . 3 9 X1.76 1.40 11.77 XI .45 ? I .52 TI . 5 5 * 1 .58 81.59 X 1 .65 X i .67 Bock Fluor B i lumen Coke -96- t Low None : Small I ROBERTSON RESEARC'i [US.] INC. SUN 9 1 NAVAJO LANDS :i U ! S 1.0 , DEPTH j T = RO flATURITY 8 VALUES 18 : nEAN ST0 OEV : MEDIAN I nom 5 306 9Q75.0 FT 3040.4 n A F l5 0 R 1 RRUS No. I .62 0.11 I .63 I .65 HISTOGRAM, Ronge: 0- 4% 0 0.0 2.0 Increment, 0.10% 4.0 3.0 VITRINITE REFLECTANCE :RA\NOOn X1 AEROGEN DESCRIPTION 15 X Amorphous I I lr X Exinite I 60 X Vitrinite Inertinlle I 25 X ORDERED REFLECTANCE VALUES, .44 rl.68 T I .51 T1.68 1 . 1 0 Tl.53 71.71 1.23 t l . 5 4 LI.73 1.25 tl.55 Zl.75 1.26 T I . 5 9 Ll.75 0.92 0.99 TI Bock Fluor B i lumen Co kc SUN a1 : fled ned I lr I NAVAJO LANOS 25 Y N RRUS NO. I DEPTH 110305.8 Ft I 0 15 F 389 3141.8 T = Ro tlATURITY a VALUES MEAN STD OEV MEDIAN IlODE 21 I I .73 0. 16 I .68 I .65 I I HlSTOGRAfll Ronge, 0- 4% Incremenr: 0.10Z VliRlNlTE SEFLECTANCE ( R A N O O M ORDERED REFLECTANCE VALUES, X1 6EROGEN DESCRIPTION 10 X Amrphous 8 , tr x Exinlte 50 X Vitrinite I 40 X Inertinlte I fl.45 Tl.68 72.07 T I .56 T I .71 3ock Fluor B I lumen Coke -97- I : I Low None None M m m m 25 - SUN s1 NAVAJO LANOS RRUS No. = Ro MATURITY # VALUES nooE I I ' I .0 2.0 3.0 VITiiINITE REFLECTANCE liiAN00M X 1 4.0 312 T PlEAN ST0 OEV REDIAN a:0 I 7 : I .84 0. I 0 8 I .82 I .85 > HISTOGRAn: Ranget 0- 4% Incremenrn 0.10:: REROGEN DESCRIPlIOh ORDERED REFLECTANCE VALUES! 0.66 a.76 0.79 0.83 1.07 0.68 0.76 0.80 0.84 1.08 I .20 0.69 0.76 0.80 TI .6Q 0.70 0.76 0.80 x1 .78 0.73 a.77 0.81 71.78 0.73 0.77 a.81 T1 .82 0.73 0.78 0.81 TI .82 0.74 0.78 0.81 tl .94 0.79 0.81 0.74 ~ 2a2 . 0.75 0.79 8.83 Amorphous Exinl re Virrinlle lnerrinite ~~ Back Fluor 8 I rumen Coke -98- 1 15 X I 5 % 50 X 30 X I I t : Pled None Nonr ROBERTSON RESEARC'i [U.S.] INC. VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT UNION #1-M-13 USA Project No. : RRUS/923/T143/02 S A M PILDEE N T I F I C A T IROENF L E CKTE.R O GCEHNA R A C T E R I S T ITCOSC RRUS a0 D E P( TF He e t ) 46 50 1 502 10445 1 .63 10665 1.82 504 507 10845 11035 509 11245 511 5 114. 7 0 11455 11625 1.84 1.75 1.73 1.76 -99- Am% 20 15 5 5 5 Ex% V i t # 5 35 5 5 7: 85 5 80 5 ao 5 5 80 5 5 45 Inert% 40 5 5 10 Fluor O.h - 0M.e2d1 LOW 0.31 0.54 10 Med Low Low 10 45 None N0 o. n1 e8 0.12 0.35 0 19 i 1 I 1 m m UNION 81-n-13USA 25 3 RRUS NO. DEPTH .m 3 I 501 110445.P Ft , 3 1 8 3 . ~n = RO nATURITY VALUES 19 I MEAN 570 OEV MEDIAN nom l- I HISTOGRAMt Range, 0- 4% Increment, 0.IPX c I I .E3 0.13 1 .El 1 .E5 : VITRINITE REFLECTANCE IRANOOM Z1 ORDERED REFLECTANCE VALUES I 0.62 1 . 1 5 Tl.52 71 .73 0.781.20 31.56 XI ,76 0.88 1.20 71.56 T I .78 0.80 1.31 ~ 1 . 5 X6I .a0 0.83 1 .32 Tl.57 Z I .a5 1.33 z1.59 Z I .90 0.84 I .33 71.61 0.86 I .E4 Tl . 4 1 T 1 . 6 1 1 .09 X1 .47 T 1 . 6 1 I .I5 TI .50 T I .66 Bock Fluor B i lumen Coke ne6 nee Smell I I t UNION SI-n-13USA 25, RRUS NO. DEPTH I 582 ,10665.8 F T 3250.7 n , Z = Ro MATURITY II VALUES 20 : MEAN ST0 DEV MEDIPN MODE I .a2 0.1I I .a6 I .95 t I HISTOGRAn: Range: 8- 4% Incremenr: Q . 1 0 X ORDERED REFLECTANCE VALUES) KEROGEN DESCRIPTION Amorphous I 15 % 5 % Exlnl le Vitrlnire I 75 X Inertlnite I 5 % 1 . 1 7 ~ 1 . a 1~ 1 . 9 6 1.26 1 1 .83 71 .99 31.60 *I .86 2.21 t l . 6 6 TI.87 2.28 Z I.sa T I .aa Bock Fluor 81 lumen Coke .68 $1.90 T I .72 TI . g 0 T1.74 T I .90 T I .57 TI .g2 71 .60 T l .94 X1 -100- : , I Lon Med None UNION *I-PI-13 USA RRUS NO. I DEPTH t 10845.8 Ft 3305.6 Pl I CAVE0 ' 1 = RO PlATURITY 8 VALUES nEAN ST0 OEV PIEOIAN PIOOE VITRINITE REFLECTANCE IRANDOPI I .a1 1.01 I .01 1.02 1.03 I .03 1.03 I .a4 1.05 1.84 0.00 I .84 1 : I .85 X1 KEROGEN OESCRIPTION 5 % Amorpnous t 5 % Exini le Vilrinlfe I 85 X Inerrinire t 5 % OROEREO REFLECTANCE VALUES, 1.01 1 : HISTOGRAPI, Range, 0- 4% Incremenl I 0.10% 0 u 4.03.0 0:0 ' 2.0I .0 0.82 0.96 0.83 0.97 0.88 0.98 0.90 0.98 0.99 0.91 0.92. 0.99 0.94 0.99 0.94 1.00 0.95 1.00 0.95 I . O O 504 1.05 1 .I2 I .05 1 .I3 1.05 1.14 I .06 1.17 I .06 1.18 1.08 I . 2 2 I .I0 I .31 1.10 1.31 I.II I .51 1 . 1 2 X1.84 Back Fluor B I lumen Cc he UNION SI-PI-13 ned None None I a I USA RRUS No. DEPTH I 507 t11039.0 FT : 3363.5 PI T = Ra nATURITY a VALUES PIEAN ST0 OEV IEOIAN nooE 37 : I .75 0.12 I .74 1.75 : 7 HISTOGRAtl: Range: 0- 4% Increments 0.10% KEROGEN OESCRIPTION 5 % Amorphous I 5 % Exlnl le ViTrinlre I 80 X Inerr in1 l e z I0 X OROEREO REFLECTANCE VALUES: I .4i 0.85 I ,47 0.98 1.00 TI.55 1 . a 5 TI.57 1.08 rl.58 - K . .I. A X. 1 6 -0 . .. 1.13 t 1 . 6 1 I , 14 11 .62 I .25 TI .63 1.35 31.64 T1.67 11 .74 1 1 .67 TI .74 11.68 Tl.75 Tl.68 11.76 71.69 1 1 . 7 7 11.71 Tl.77 31.71 T 1 . 7 8 ~ 1 . 7 2TI .78 11.72 J1.79 T 1 . 7 2 31.79 fl.80 ?1.80 TI.89 71.89 ! 11.91 Back Fluor B I lumen Co he 11.97 t2.50 3. T2.01 J 72.01 2.17 -101- I , a Lon Small None J 1 i 1 1 1 1 1 m m UNION SI-n-Iz USA RRUS No. I 509 m CAVED T = Ro nATURITY a VALUES nEAN STD DEV nEDIAN nODE 30 : I .73 0 .14 I .74 I .75 : I HISTOCRAns Ronge: 0- 4:: I ncremen r 1 0.IO:? VITRINITE REFLECTANCE lRANDOn % I SEROGEN 0ESCRIPTIO:I OROERED REFLECTANCE VALUES: 1.19 t1.54 Tl.70 71.83 L Z 3 Tl.54 T1.70 T1.84 1.25 T l . 5 5 T l . 7 2 11.85 1.33 ~ 1 . 5 6~ 1 . 7 2~ 1 . 8 6 1.34 ’rl.58 T1.74 il.92 1.36 Xl.58 X1.74 Tl.93 1.37 T l . 6 2 tl.76 11.94 1.12 I .I2 I .39 71 .63 i1.76 32.02 1.48 71.64 TI.76 T2.02 1.15 1 . 1 7 11.53 ~ 1 . 6 6~ 1 . 8 1 2.27 0.80 0.95 0.95 1.02 1.02 1.06 Amorphous : Exini te Vitrinite 8 lnerrinlre : Bock Fluor 8 1 rumen Co he : RRUS 511 5 5 80 I0 % % % X % Lou Nons I Small UNION SI-n-13USA =! DEPTH 20 53F NO. 15 I :11455.0 F T I 3491.5 n T = Ro nATURITY It VALUES VEAN ST0 OEV nEJIAN nODE 30 8 1.78 0 . 16 : I .77 I .85 I HISTOGRAnn Ronge, 0- 4X Increments 0.10% 1 Y KEROGEN OESCRIPTION ORDERED REFLECTANCE VALUES: 0.88 T I .62 T1.79 L2.06 1.32 tl.62 Tl.E0 tZ.09 1.36 T1.67 L1.80 T2.13 TI.54 T 1 . 6 8 t1.80 T 1 . 5 6 Tl.70 Tl.82 T1.57 T l . 1 1 *1.83 T 1 . 5 8 rl.72 tl.83 Tl.61 Tl.72 tl.89 T I .61 31.77 T I .91 t1.61 ?I.77 X2.01 Amorphous I 5 % Exinite Vitrlnite I 80 X Inertinlre I le Z Bock Fluor 8 I lumen Co he -102- E X 1 I I Nore Nore Nore 3 I I UNION SI-M-13 USA I DEPTH ,11625.8 F i I T R la 5D 514 RRUS No. 3543.3 = RO MATURITY e VALUES I MEAN S T 0 OEV MEOIAN : 21 I .78 0. 14 I .80 : HISTOCRAP1: Range: 0- 4% a Increment: 0.10% V I T R I N I T E REFLECTANCE IRANOOF1 %I KEROGEN DESCRIPTION I 5 % Amorphous 5 % Exini te 8 45 % Vitrlnite I n e r t l n ti e I 45 % ORDERED REFLECTANCE VALUES, ti.81 8.63 1.20 1 . 4T61 . 5 9 I .49 T1.61 X1.81 1.00 I . z i 1.03 I .23 I .51 T 1 . 6 1 T I . 8 5 I . 5 1 T I . 6 5 T I .85 1.24 1.a4 1.10 I .26 1 .53 71.67 x1.86 1.30 1 .53 T l . 6 8 T l . 8 7 1.13 1.30 I . 5 5 Tl.73 T I . 8 9 1.15 I .33 I .57 TI.75 Tl.94 1.15 1.36 I . 5 7 :1.77 r2.05 1.17 1.18 1.37 T I . 5 9 :I 80 T2.06 Bock Fluor 81 tumen Co he -103- I I I .85 MOOE 1:5 G S II 1 i : I , None None None I m m m VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT SKELLY # I NAVAJO-0 Projeot No. I ; RRUS1823IT143lOZ TO C S A M P LIED E N T I F I C A T I ORNE F L E C TK.E R O G ECNH A R A C T E R I S T I C S RRUS 701 702 705 707 DEPTH (Feet) 10575 10675 Ro % "" " " ioao5 1.84 11005 "" -104- Inert% F l u o r Vit% Ex% Am% 3~. a IO ~. 5~. 0 l.~ a 35 30 30 15 10 40 45 45 10 10 15 15 @la Xed 0 .. .62 High High High 0.54 ~ " 0.48 0.51 ROBERTSON RESEARC'i [U.S.] INC. 25 - SKELLY r l NAVAJO-0 RRUS No. s 701 VALUES MEAN ST0 DEV PIEOIAN MODE . 48 : 0.56 0.14 L 0.51 0.45 HISTOGRAM, Range: 0- 4% Incremenr: 0.10% VITRINITE REFLECTANCE (RANDOPI X1 E R O G E N OESCSJPTION OROERED REFLECTANCE VALUES: 0.40 0.46 a - .. 4 - 0 0.47 0.48 0.48 0.48 0.48 0.49 0.4Q a , 40 0.41 0.43 0.43 0.43 0.44 0.44 0.45 0.45 0.49 25 0.49 0.49 0.50 0.51 0.51 0.51 0.52 0.55 0.55 0.55 0.56 0.56 0,56 0.57 0.58 0.58 0.58 0.60 0.61 0.63 a.71 - 0.72 0.77 0.80 0.94 0.97 0.99 I Bock Fluor B I rumen Co he " 8 fled Smoll I None 8 SKELLY * I NAVAJO-0 - RRUS No. n 1 l'j,,ihb i2Q/ DEPTH I 702 Ft PI :10675.0 3253.7 : CAVED VALUES F 0 I5 MEAN ST0 DEV MEDIAN MODE , , , , , , / , , , , , , , , , ( , , , , , , , , , , , a I .0 0.0 2.0 3.0 VITRINJTE REFLECTANCE IRANOOM 0.36 0.38 0.40 0.40 0.48 0.41 ~~ 0.42 0.42 0.42 0.43 0.44 0.15 0.49 0.58 8.45 a.si 0.49 0.64 0.45 0.45 0.46 0.47 0.48 0.48 0.49 0.51 0.53 0.54 0.69 0.69 a.75 0.75 0.54 0.55 0.56 0.58 " 0.78 0.79 0.80 0.87 47 : 0.60 0.21 0.51 : 0.45 HISTOGRAM: Range, lncremenrz 0- 4 1 0.10% 4.0 KEROGEN OESCRIPTION Amorphous I 35 X 0.88 0 -.S0 0.31 0.98 ~ : XI ORCERED REFLECTANCE VALUES: ~ 30 X I0 X 50 i 10 X Amorphous a I Exinite v, .i .v. ~ . . .t. n. i t ~. 1nerl;nire 8 0.71 " Exinifo I Vltrlnire a Inerrlnite 1.01 1.08 I .I7 Back Fluor B i rumen Co he -i05- I : 15 x 40 X I0 X Hlgh I Small I None SKELLY S1 NAVAJO-0 RRUS No. DEPTH I 810805.0 F t : CAVED 705 3293.4 * = RoMATURITY E VALUES MEAN ST0 OEV tlEDIAN I : I .8.i 0.00 I .84 : : I .85 MODE 0 4 . 0 30 .. 00 OROE3ED a.33 0.42 a.47 0.50 0.51 0.52 0.55 0.55 0.57 00.0.5 0.77 .80 936 " HISTOGRAPI: Ronge, 0- 4X I n c r a m e n 1 2 0.10; 2.0 I .0 V I T R I N I T E REFLECTANCE [RANDOM X I REFLECTANCE VALUES, 0.57 0.71 0.85 0.58 a.72 0.85 0.60 0.73 0.86 0.60 0.75 0.86 0 0.75 0.91 .. 6 .3 . 0.66 0178 0.92 0.66 0.80 0.92 0.68 0.80 0.93 0.64 0.81 0.94 .02 .a2 1.21 I .25 .04 .05 1 .25 I .38 KEROGEN DESCRIPTIOI' : 30 X Amorphous Exinire : 10 X 45 X Vitrinile I 15 X Inert i n i t e I .13 '11.84 .I5 Back F l u o r 81 tumen Coke .15 16 16 1 .21 . . SKELLY SI M I 8 8 Hlgn High None NAVAJO-0 RRUS No. I DEPTH I I 707 11005.0 3394.3 Ft n CAVED I) VALUES MEAN ST0 DEV MEDIAN ; 34 : : 0 6.3 0.23 0.63 0.6.5 . nODE 0 0.0 HISTOGRAM: R a n g e , 0- 4? I n c r e m e n t , 0.10X 1.0 2.a 3 0 V I T R I N I T E REFLECTANCE IRANOOM X 1 - ORDERED REFLECTANCE V'ALUES : 00.0.3.53 720 1 .03 000 ..3.57 458 I .07 0.39 I .I0 0.44 i .I3 0.48 48 0.49 a . 48 0.51 0.52 d.0 KEROGEN DESCRIPTIO'I I 30 X Amorphous : I0 X Exinl le Vitrlnlte I 45 X 15 X Inertinite I a. Back Fluor 81 tumen Coke -106- I I L Hlg? Smol I Non? ROBERTSON RESEARC'i [U.S.] INC. VISUAL KEROGEN ANALYSIS MAGNOLIA - I 1 REFLECTED LIGHT # l HUTCHINSON-FEDERAL Project No. : RRUSl823/T/43/02 C S A M P LIED E N T I F I C A T I ORNE F L E C TK.E R O G ECNH A R A C T E R I S T I CTSO RRUS ‘ D E P(TFHe e t ) 901 9 0.. 3 906 910 ~ 896s 9125 9514 Ro K Am% 1.5 1.5 I. 5 1 .6 30 30 25 0 3 9 2 ZO Ex% Vi t % 5 5 45 5 tr 50 50 65 I n e rFtl%u o r 20 1s 20 15 I % LOW a. !4 Low LOW 0.12 3 -107- MAGNOLIA * I HUTCHINSON-FEDERAL 25 7 " RRUS NO. I DEPTH : I I I I I I c 801 8565.0 F T 2610.6 R '# = Ro MATURITY II VALUES flEAN S T 0 OEV ilE0IAN . 8 1.5P 0.IC I i .52 I I .6E ROO€ HISTOGRAMt Range, 0- 4% Incrementa 0.10% S 0 0.0 n 1 I .0 2.0 4.0 3.0 VI7RINITE REFLECTANCE IRANOOPl X 1 KEROGEN OESCRIPTION 30 % Amorphous I 5 % ExiniTe 45 % Vitrinite t Inerr in I ire 20 % ORDERED REFLECTANCE VALUES, 0.67 1.90 ~ 1 . 1 8 2.21 71 .za T I .4a X I .4a X I .52 .63 .67 TI .78 TI TI Bock Fluor B I lumen Coke a Small I tr RRUS NO. I 903 DEPTH I Lor I .85 PtAGNOLIA 1 1 HUTCHINSON-FEDERAL I t = F E VALUES $ MEAN ST0 OEV REDIAN nODE R 0 t 5 S 0 0.0 m d . -3 I .0 2.0 3.a VITRINITE REFLECTANCE IRANOOM X 1 Ro PlATURITY 22 I I .53 0.13 : : 1 .5.1 1 .65 HISTOGRARt Range: 0- 4 X Increment: 0.10? KEROGEN DESCRIPTIO[I Amorphous z 30 X Exinlte 5 % V, . . .I . . . ~ ~ xI . . ~ : I 50 15 X lnertlni te ORDERED REFLECTANCE VALUES: T1.32 tl.52 X1.73 1 1 . 3 2 ~ 1 . 5 4~ 1 . a ~ TI .33 TI .54 T I .4l XI .60 T I .42 T1 . 4 3 4.0 8965.0 F1 2732.5 M .63 ' # I .63 X I Bock Fluor El I Tumen Coke TI .46 T I .64 TI .48 TI .64 T I .48 T I .66 T I .51 X 1 . 8 6 -108- 1 LOX t Smoll 2 tr ~ ~ PIAGNOLIA n l HUTCHINSON-FEDERAL RRUS NO. I DEPTH I I = Ro b WAN S T 0 DEV PIEDIAN PIOCE 5 9125.0 F t 2781.3 n MATURITY VALUES 0 906 25 t : I I HISTOGRAPIt 0 Ranger 0- 4% I n c r e m e n t , 0.10% .E V I T R I N I T E REFLECTANCE (RANOOPl X 1 KEROGEN OESCRIPTION : 25 % Amorphous 5 % Exinire 1 50 X Vitrlnite Inerrlnite I 20 X OROERED REFLECTANCE VALUES, 0.91 I .17XI.45 X1.65 1.86 1.001.27 rl.56 1.03 1.27Xl.52 Tl.55 1.071.28 I .i0 I .29 T I .56 .1 .. .l-U x. 1. . 3-~ 1 I , 1 0T I. a I , 1 3 V I .40 1.14 J1.43 I ,14 T I .43 11.65 Xl.66 1.91 2.13 TI.67 X I .69 x 1 . 5 8 x1.72 XI. S i T I .76 T I .62 Tl.77 Tl.62 rl.80 XI .64 * I .83 PIAGNOLIA .1 Back F l u o r 81 rumen Coke I ~r j HUTCHINSON-FEDERAL No. DEPTH I 8 I 910 9515.0 F t zg~m.2 n Ro nATURITY R 15 0 VALUES l nEAN ST0 DEV PIEOIAN 14 > 1 .62 0 .14 1 .65 : : I .65 nOOE ' I .0 2.0 3l.0, ' ' ' ' V I T R I N I T E REFLECTANCE IRANOOPl X 1 1.06 4". 0 : Amorphous I Exinire : Vltrinlte Inerrinlle 8 .68 31.69 XI .72 Tl .78 T I .81 TI .36 T I .42 fl.43 * I .54 T1 . 8 5 31.56 1.97 ~ 1 . 5 a 2.04 TI ' HISTOGRAPI: Range, a- 4% I n c r e m e n t ) 0.10% KEROGEN OESCRIPTIOF ORCERED REFLECTANCE VALUES: 0.90 Low Pled I I I RRUS F I I 1 I .59 0.13 1 .62 1.65 I . I T I .61 X I .66 -109- Back F l u o r : B i fumen I Co he I 20 tr 65 15 Low ned tr X X X X ... ... .1 VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT BRINKERHOFF # I CABEZON-GOV'T Project No. .r SIADMEPNLTEI F I CRAETFIKLOEENCRCHOTAG.REANC T E R ITSOTCI C S RRUS .1 : RRUS/823/T/43/02 403-404 409-410 415-416 D Z P(TFHe e t ) 7226 7583 7876 Ro % Am% E x % V I t % I n e rFtl%u o r 1.17 35 35 30 10 10 10 " " 1.20 40 45 50 % 1s LOW 10 LOW 10 LOW ---0.14 ---- I -110- ROBERTSON RESEARCH [US.] INC. BRINKERHOFF # I CABEZON-GOV'T RRUS No. I OEPTH : I CAVEO + CANTAn.7 403-404 7226.0 2202.5 'Z = RoIIATURITY 8 VALUES flEAN ST0 OEV MEOIAN . . ORDERED 0.33 0.34 0.35 0.37 0.37 0.38 0.40 a.41 0.41 0.43 00. .4657 00. 4 . 657 0.45 0.48 0a. .4795 0.54 0.57 0.59 0.62 0.67 0.70 . n 2 I 1.17 0.07 1 .24 1 .25 8 I MODE V I T R I N I T E REFLECTANCE IRANOOfl Ft HISTOGRAI1: Range: 0- 4% I n c r e m e n t , 0.10% XI VALUES : 0.88 a.89 0.92 0.92 a.98 0.98 KEROGEN OESCRIPTION I 35 X Amorphous 1 I0 x Exinire Virrinire I 40 X I n e r t in1 t e I 15 X Back F l u o r 8 i rumen Co he 0.76 0.82 0.83 0.88 t I I Lou Small None BRINKERHOFF SI CABEZON-GOV'T RRUS No. I DEPTH I : CAVEO * 409-410 7583.0 2311 . 3 FI I1 RECYCLED ? II VALUES nEAN ST0 OEV IlEOIAN 16 I 0.99 0.49 0.82 a.55 > I nODE HISTOGRAfl: Range, 0-4% I n c r e m e n l t 0.10% 0.24.0 : . 3a . 0 2.a V I i R I N I T E REFLECTAkCE IRANOOn X i KEROGEN OESCRIPTION OROEREO REFLECTANCE VALUES: 0.50 0.98 .43 Amorphous Erini t e Viirinite Inerlinire ,GI .63 .72 .93 B o cFk l u o r B i lumen Coke -1111 , I I t I I I 35 Z 10 x 45 X 10 X Low None None ERINKERHOFF . I I CABEZON-GOV'T RRUS No. I DEPTH I : 415-415 7876.0 2400.6 FI n V = Ro MATURITY PN 5 , ,,, a.0 , , , , , , ,, ,,,,,, ,, 2.8 4.0 3.0 I .a VITRINITE REFLECTANCE (RANSOn X 1 - : MEAN ST0 OEV nEDIAN nOOE : : 12 1.28 0.12 I .32 I . 15 HISTOGRAM: Ronge, a- 42 Incremenll 5.10% KEROGEN OESCRIPTICN 30 X AmorDhous I I ~e x Exinire 5E X Vltrtnl1e I IO X Inerr inlteI ORDERED REFLECTANCE V .UES : .66 1.93 0.30 0.91 Xl.20 .67 5.38 0.97 x1.32 .67 0.97 Xl.32 0.41 .69 0.48 1.00 *1.38 .70 0.57 1.07 X I .40 .70 0.58 X I .I3 TI .44 .72 0.58 * I .is r~ .47 .74 0.60 71.17 1.55 .80 0.67 X1 .I9 1 . 5 6 .93 0.90 T1 .20 1.64 EOch Y -112Y s VALUES Fluor I 81 lumen I to he I LOU Smcll Nore VISUAL KEROGEN ANALYSIS - 1 REFLECTED LIGHT DELHI # 4 UTE Project No. : RRUS1823IT143102 S A M P IL DE E N T I F I C A T I RO EN F L E C KT E. R O G CE HN A R A C T E R I S T I C S RRUS I O O I - ~ ~ 8145 8765 1003-04 1009 1013-14 D E P(TFHe e t ) 7845 8453 Ro % E2% Am% 0.90 0.91 0 . 9 4 40 1.00 1. 9125 9475 1019-20 1az1-22 1023-24 9605 aa 1.11 1.14 3 51 . 1 0 40 50 35 35 40 30 V i t % Inert% Fluor 5 5 5 5 S 5 10 5 2: 2a 20 35 35 30 35 25 25 25 25 30 30 35 25 30 % Med Med High Mad ------1 . 18 ---- Hfgh High Med ---------- I I 1 DELHI ,..'3 a4 UTE RRUSNo. 1001-1?W2 DEPTH I t . I T = Ro 8 VALUES MEDIAN MODE W0?.l, 0 ,,,,, W 0.0 2.0 , , 3.0 ' ' VITRINITE REFLECTANCE IRANOOM ' 4: 0 2391 .2 M nATURITY PIEAN ST0 DEV S Fr 7845.0 7 r 0.90 0.1Q 0.88 I , 0.85 HISTOGRAMt Range: 0- 41. Incrementt 0.10% X1 KEROGEN DESCRIPTION Amorphous : 48 X Exinite E X 25 X Virrinire I Inertlnite I 3E X ORDERED REFLECTANCE VALUES: T0.88 a.4 X10 . 9 8 0 . 4 5 Xl.02 0.55 X1.03 0.41 0.55 Bock Fluor 0.61 B I rumen Coke 0.69 ~4.74 I Mecl : Smell : Nore * E . 82 r0.85 DELHI 84 UTE RRUS NO. DEPTH * ~ , , , , , , , , , , , , , , ( 2.0 3.0 VITRINITE REFLECTANCE IRANDOE 4.0 f'l 9 I EiEF 0.61 0 .I I 0.62 I .F5 1 HISTOGRAP(: Range: 0-4% Increment: 0 . 1 0 % KEROGEN DESCRIPTICN Amorphous I 4r % Exinite 5 % Virrinire I ZF X Inertinire 35 % 0.3J T 0 . 8 5 Y FT X1 ORDERED REFLECTANCE VALUES: -1) 8145.e 2482.E MEAN S 0 . 5r00 . 9 2 0 . 5 0 al.00 0 . 6 2 $1.00 0 . 7 0 TI.02 0.71 J1.07 1.40 0.72 T0.76 t0.77 T0.83 1003-1004 = Ro MATURITY * VALUES ,~ , , , , , . , , , I .0 I : IIlL, 0 0.0 I Bock Fluor 8 I rumen Coke -114- I t : Mecl Smoll Nore DELHI a4 UTE 25 RRUS N o . DEPTH R 0 F 7 = E VALUES 15 , IEEg : : 8453.8 Fr 2576.5 PI RotlATURlTY 17 L V I T R I N I T E REFLECTAhCE 1RANOCM % I KEROGEEI DESCRIPTION : 58 X Amorphous Exinlre 5 % OROEREO REFLECTANCEVALUES: 0.51 0.77 0.53 0.77 0.57 78.83 E . 6 1 70.84 XE.93 XE.93 30.96 LE. 98 0 . 6 1 X E . 8 4 71 .01 E . 63 78.87 X 1 . E 1 0 . 6 6 7E.87 71 . E 2 0.67 XE.90 XI .E4 E . 68 Y E . 9 2 X I . E 6 ~~ 0.75XE.92 1.41 1.43 1.52 I .63 Vlrrlnlre Inertlnlre Back Fluor 8 I rumen Co he 25 X Hlgn t I , ned None UTE 25 3 RRUS No. > 1813-1814 DEPTH I 8765.8 2671 . 6 8 T 18 8 = Ft n RoMATURITY s VALUES L tlEAN ST0 OEV VEDIAN I I0 I .0E E.09 I .07 8.95 : nOoE Ei5 G HISTOGRAPIS 5 Range: E- 4% E 0.0 1 .E 3.0 2.0 V I T R I N I T E REFLECTANCE 1RANDOn X I OROERED REFLECTANCE VALUES, 8.45 E . 6 6 XE.88 1.12 1.21 1 .I4 I .26 0.47 0.67 XE.91 8.50 a.68 ~ 0 . 9 1 1 . 1 4 I . x 6.50 8 . 6 8 76.93 1.15 1.27 0.52 a.72 r ~ 1 . 9 5 I . 1 5 1 . 2 7 8.55 0.72 X1.07 1.15 1.38 0.55 0.77 11.09 I .2E I .33 0.59 a.77 71.08 I . Z E 1.48 1.21 0.60 8.77 7 1 . 1 8 1.68 0.64 28 X I 1.28 DELHI a4 E 8 '3.83 S1.IE 1.21 4.0 Incremenr: E.IEX KEROGEN DESCRIPTION I 35 X Amorphous Exinire 5 % Vlrrlnlre : 35 X Inerrinire I 25 X Back 2.12 -115- Fluor I 8Irumen : t o he I ned iled None I I I I I I I m DELHI a4 UTE RRUS No. : DEPTH I 1017 8933.0 Ft 2722.8 M I = Ro MATURITY 8 i VALUES MEAN ST0 OEV MEDIAN MODE 5 21 I I .08 0.03 I .09 I : 1.15 HISTOGRA~I Ronge, 0- 4 % 0 Increment, 0.10% VITRINITE REFLECTANCE IRANOOM X1 .- KEROGEN OESCRIPTION Amorphous : 35 % 5 % Exinlte 35 X Vltrinite t Inert inlte I 25 X ORDERED REFLECTANCE VALUES, 0.77 0.80 70.94 X0.96 r0.87 r0.99 71 .06 XI.19 XI .07 7 1 . 2 0 .09 X1.20 .I0 1.22 TI .12 1.22 ~ 1 . 1 3 1.23 T I .I5 1.24 X1.01 1.25 Xl.O1 X 1 . 1 6 ~ 1 . 0 271.17 1.27 XI .03 X I . I 8 I .27 71 TI 1.30 I .34 1 .35 I .47 1 .48 I .50 I .52 I .52 I .58 1 .59 1.62 .66 .71 .83 .83 I83 .85 .92 ,95 OELHI Bock Fluor 8 I lumen to k a s4 t I UTE 25 7 RRUS No. I DEPTH s 1019-1020 I .0 r Y Y 9125.0 2781.3 X = RO MATURITY # VALUES NEAN ST0 OEV MEDIAN MODE VITRINITE REFLECTANCE IRANOOM Med Med Nore : Ft M 15 1.11 I 0.09 : 1.11 1.05 HISTOCRANt Ronge: 0- 4% Increments 0.10% XI KEROGEN DESCRIPTION 4R X Amorphous I 5 % Exinl t e 25 X Vitrinlte I 363 % Inertlnlte I Back Fluor I ti i gh t Ne\$ B I rumen I None Coke ORDERED REFLECTANCE VALUES: 0.47 a.85 X I . 0 8 ~ 1 . 2 9 I .84 0.68 0.86 X I .09 1.32 2.03 0.73 0.88 '11.09 I .32 1.39 ' 0 . 7 3 0.92 XI.11 1.41 0.74 0.93 X I . 1 1 0.75 0.93 71.13 1.57 0.77 10.97 ~ 1 . 1 7 I .SE 1.63 0.78 71.00 X1.17 0 . 8 1 ~ 1 . 0 0~ 1 . 2 0 1 . 7 0 0.84 XI.01 X1.22 1.72 -116- ROBERTSON = RESEARCH [US.] INC. .. .~ Y .~ - -?c , DELHI 84 UTE RRUS No. I DEPTH , 1021-1022 I T = Ro MATURITY 8 VALUES nEAN ST0 OEV MEOIAlv MOOE E.0 2.0 3.0 I .a VITRINITE REFLECTANCE IRANOOM 4.0 Tl.06 0.90 T I .10 1.48 1 .41 1.61 2.81 .63 .63 .66 2.01 ~~ : I .25 HISTOGRAnt Range: 0- 4 % Increment, E.10X Bock Fluor 8 I 1 umen Coke ~ 2.02 2.16 2.17 .67 1.14 E . 14 1.15 I KEROGEN OESCRIPTION 30 4! Amorphous I 1 I0 X Exinlte Vitrlnite I 30 % 30 X Inertlnite I 1.84 .62 13 I X1 OROEREO REFLECTANCE VALUES, 0.45 m.96 1 1 . 2 7 1.50 1.77 0.45 TE.96 71.32 1.54 I . 8 8 8.53 LE.96 T I .33 1 .56 1.89 8.67 78.98 1.37 1.59 l.Ql 0.73 9475.A Fi 2888.0 n 8 I I High Med None . DELHI m4 UTE RRUS NO. I DEPTH I t '# E MEAN ST0 OEV MEDIAN MOOE ,.a. E.O I .0 , .. 3.0 OROERED REFLECTANCE VALUES: 8.62 E . 66 Xl.19 1.82 .50 1.92 0.76 .52 1 .96 0.77 .52 1 .99 E . 79 .54 2.07 .61 8.86 .63 0.93 E.94 .63 X 1 .E5 .66 XI . E6 .68 4.0 2 : 0 " " " " " ' " ' " " ' VITRINITE REFLECTANCE IRANOOM 8685.B F? 2927.6 pi Ro MATURITY VALUES S 1023-1924 3 : 1.1a 0.87 I .05 I .a5 : I HISTOGRAM: Range: 0- 4% Increment: 0.10% XI KEROGEN OESCRIPTION 35 % Amorphous I 5:: Erlnlte Vltrinlle 1 35 2 25 X Inertinlte 3 B o c k Fluor E I tumen Co he I I a ned High None