NMBMMR Open-File Report 344 THE HYDROCARBON POTENTIAL, OF THE TUCUMCARI BASIN, NEW MEXICO Appendix A Geochemical Data Robertson Research (U.S.), Inc. 1988 APPENDIXA GEOCHEMICAL DATA APPENDIX A TABLE OF CONTENTS NEW MEXICO BURaU OF MI#@ A N D MINFRAL RESOURCES SOCORRO. NEW MEXICO PAGENO. TABLEOFCONTENTS L I S T OF FIGURES L I S TO FT A B L E S A-i A-ii A-fi FIGURES AMOCO, #1 G.C.BAKER AMOCO. #1 BLACKBURN FARMS SUNRAY, #1 BRISCOE PURETEX, #1 CHAPPELRANCH STANOLIND. #1 FULLER A-1 A-3 A-9 A-15 A-25 A-31 GREENESTATE. #1 FRANKLIN,ASTON,ANDFAIR HUSKY, #1 HANCHETTSTATE TRANSPECOS, #1 LATIGORANCH A GENERALCRUDE, #1 SIMPSON #1 T-4CATTLECO. YATESPETROLEUMCORP., TABLES A-37 A-43 A-53 A-59 A-65 A-71 AMOCO. #1 G.C.BAKER AMOCO, #1 BLACKBURNFARMS SUNRAY, #1 BRISCOE PURETEX. #1 CHAPPELRANCH STANOLIND. #1 FULLER GREENESTATE, #1 FRANKLIN,ASTON,ANDFAIR A-73 A-87 A-103 A-145 A-167 A-195 HUSKY, #1 HANCHETTSTATE TRANSPECOS, #1 LATIGORANCH #1 SIMPSON GENERALCRUDE, #1 T-4CATTLECO. YATESPETROLEUMCORP.. A-209 A-241 A-257 A-273 OILS A-287 A-i APPENDIX A LIST OFFIGURES PAGE NO. AMOCO. til G.C. FIGURE A.l BAKER Summary plots showing kerogentypes, richness. source and maturity A-5 FIGURE A.2 Summary plots of Rock-Eva1 pyrolysis data. FIGUREA.3 Kerogen type determination fromRock-Eva1 data. pyrolysis FIGURE A.4 data. A-6 A-7 Maturation profilebased on vitrinite reflectance A-8 AMOCO, #l BLACKBURN FARMS FIGURE A.5 Summary plots showing kerogentypes, maturityandsourcerichness. A-11 FIGURE A.6 Summary plots of Rock-Eval pyrolysis data. A-12 FIGURE A.7 Kerogen type determination fromRock-Eval pyrolysisdata. FIGURE A.8 A-13 Maturation profilebased on vitrinite reflectance data. A-14 A-ii APPENDIX A LIST OF FIGURES (continued) PAGE NO. SUNRAY 81 BRISCOE FIGURE A.9 Summary plots showing kerogentypes, maturityandsourcerichness. A-17 FIGURE A.10 Summary plots showing kerogen types, maturity and source richness. (NON RR(US) A-18 DATA) FIGURE A . l l Summary plots Rock-Eva1 of pyrolysis data. FIGURE A.12 Summary plots of Rock-Eval pyrolysis data. DATA)(NON RR(US) A-19 A-20 FIGURE A.13 Kerogen type determination fromRock-Eval data. - pyrolysis A-21 FIGURE A.14 Kerogen type determination fromRock-Eva1 pyrolysisdata. (NON RR(US) DATA) A-22 FIGURE A.15 Maturation profile based on vitrinite reflectance data. A-23 FIGURE A.16 Maturation profilebased reflectancedata. on vitrinite (NON RRCUS) DATA) A-iii A-24 APPENDIX A LIST OFFIGURES (continued) PAGE NO. PURETEX, #l CHAPPEL RANCH FIGURE A.17 Summary plots showing kerogen types, maturity and source richness. (NON RRCUS) A-27 DATA) FIGURE A.18 Summary plots of Rock-Eva1 pyrolysis data. (NON RR(US) DATA) A-28 FIGURE A.19 Kerogen type determination fromRock-Eval pyrolysis data. FIGURE A.20 (NON RR(US) DATA) Maturation profilebased reflectance data. A-29 on vitrinite (NON RR(US) DATA) A-30 STANOLIND, #l FULLER FIGURE A.21 Summary plots showing kerogen types, maturity and source richness. (NON RR(US) ' DATA) FIGURE A.22 A-33 Summary plots of Rock-Eva1 pyrolysis data. (NON A-34 RRCUS) DATA) FIGUREA.23 Kerogen type determination fromRock-Eval pyrolysis data. (NON RR(US) DATA) A-35 FIGURE A.24 Maturation profile based on vitrinite reflectancedata. (NON RR(US) DATA) A-iv A-36 APPENDIX A LIST OFFIGURES (continued) PAGE NO. GREEN ESTATE, # l FRANKLIN,ASTON, AND FAIR FIGURE A.25 Summary plots showing kerogen types, . richness source maturity and A-39 FIGURE A.26 Summary plots of Rock-Eva1 pyrolysis data. A-40 FIGURE A.27 Kerogen type determination from Rock-Eval data. pyrolysis A-41 FIGURE A.28 Maturation profilebased data. on vitrinite reflectance A-42 HUSKY, 81 HANCHETTSTATE FIGURE A.29 Summary plots showing kerogen types, A-45 maturity and source richness. FIGURE A.30 Summary plots showing kerogen types, maturity and source richness. (NON RRCUS) A-46 DATA) FIGURE A.31 Summary plots of Rock-Eva1 pyrolysis data. FIGURE A.32 Summary plots of Rock-Eval pyrolysis data. (NON A-48 RR(US) DATA) A-V A-47 APPENDIX A LIST OF FIGURES (continued) PAGENO. FIGURE A.33 Kerogen type determination fromRock-Eva1 pyrolysis data. FIGURE A.34 Maturation profilebased A-49 on vitrinite reflectance data. A-50 FIGURE A.35 Maturation profilebased reflectancedata. on vitrinite DATA) (NON RRCUS) TRANSPECOS, A-51 # l LATIGORANCH FIGURE A.36 Summary plots showing kerogen types, maturity and source richness. (NONRR(US) A-55 DATA) - FIGURE A.37 Summary of organicanalyses. (NONRR(US) DATA) A-56 FIGURE A.38 Summary of organic analyses hydrocarbon. - C1-C7 DATA) (NON RR(US) FIGURE A.39 Summary of carbondata. QENERALCRUDE, A-57 A-58 #1 SIMPSON FIGURE A.40 Summary plots showing kerogen types, maturity and source richness. A-vi A-61 APPENDIX A LIST OF FIGURES (continued) PAGR NO. FIGURE A.41 Summary plots of Rock-Eval pyrolysis data. A-62 FIGURE A.42 Kerogen type determination fromRock-Eval data. pyrolysis A-63 FIGURE A.43 Maturation profile based on vitrinite data. reflectance A-64 YATESPETROLEUMCORP.. #l T-4CATTLE CO. FIGURE A.44 Summary plots showing kerogen types, richness. source and maturity A-67 FIGURE A.45 Summary plots of Rock-Eva1 pyrolysis data. A-68 FIGURE A.46 Kerogen type determination fromRock-Eval pyrolysis data. data. A-69 FIGURE A.47 Maturation profilebased reflectance on vitrinite A-vii A-70 APPENDIX A L I S T OF TABLES PAGE NO. AMOCO, 81 G.C. gic A.l BAKER TABLE A.2TABLE TABLE A.3 A-75 Total D aCtOa r bg oa n i c A-76 Rock-Eval Pyrolysis DataRaw A-77 T A B L E . A . 4H y d r o g e n and O x y g e n Indices fromRock-Eval P y r o lDy as it as and T O C TABLE A.5 - V i s uKael r o gAe n a l y s i s R e f l e c tLeidg h t of Source E R xo tcrka c t Composition TABLE A.6 TABLE A.7 A-77 A-83 S u m m a r y Table Showing Selected P a r a m e t e r s of A-83 Oil S a m p l e s TABLE A.8 A-78 H e a v yH y d r o c a r b o n sN o r m a l i z e d to 100% A-84 AMOCO, NO. 1 BLACKBURNFARMS TABLE A.9 A-89 L i t h o l o g i cD e s c r i p t i o n TABLE A.10 Total O r g a n i c C a r b o n D a t a TABLEA.llRock-Eva1 Pyrolysis RawData A-viii A-90 A-91 APPENDIX A LIST OF TABLES (continued) PAGE NO. TABLE A.12 Hydrogenand Oxygen Indices fromRock-Eval Pyrolysis and TOC Data A-91 TABLE A.13 Visual Kerogen Analysis-Reflected Light A-92 TABLE A.14 Composition of Source Rock Extract A-98 TABLE A.15 Summary Table Showing SelectedParameters of Oil Samples A-98 TABLE A.16 Heavy Hydrocarbons Normalized to 100% A-99 SUNRAY, 111 BRISCOE * TABLE A.17 Lithologic Description A-105 TABLE A.18 Total Organic Carbon Data A-106 TABLE A.19 TotalOrganicCarbon A-107 Data (NON RR(US) DATA) TABLE A.20 Rock-Eva1 Pyrolysis Raw Data TABLE A.21 Hydrogenand and Pyrolysis A-108 Oxygen Indices from Rock-Eval TOC Data TABLE A.22 Rock-Eval Pyrolysis Raw Data (NON RR(US) DATA) A-iX A-108 A-109 APPENDIX A LIST OF TABLES (continued) PAGENO. and O x y g e nI n d i c e sf r o mR o c k - E v a 1 Pyrolysis and TOCData(NONRR(US)DATA) TABLEA.23Hydrogen TABLE A.24 V i s u a l K e r o g e n A n a l y s i s - ReflectedLight TABLE A.25 V i s u a l K e r o g e n A n a l y s i s - ReflectedLight (NONRR(US)DATA) A-110 A-111 A-116 TABLE A.26 V i t r i n i t e R e f l e c t a n c e D a t a S u m m a r y ( N O N RRCUS)DATA) A-117 TABLE A.27 V i s u a l K e r o g e n D a t a S u m m a r y ( N O N R R ( U S ) DATA) A-127 TABLE A.28 Compostion of Source R o c k E x t r a c t A-135 TABLE A.29 S u m m a r y Table Showing Selected P a r a m e t e r s o f A-135 Oil S a m p l e s TABLE A.30 H e a v y H y d r o c a r b o n s N o r m a l i z e d to 100% A-136 PURETEX, 81 CHAPPELRANCH TABLE A.31 Total OrganicCarbonData(NONRR(US)DATA) A-147 TABLE A.32 Rock-Eva1 Pyrolysis RawData(NONRRCUS) DATA) A-148 A-X APPENDIX A L I S T OF TABLES (continued) rAun NU. and O x y g e nI n d i c e sf r o mR o c k - E v a 1 Pyrolyis and TOCData(NONRR(US)DATA) TABLEA.33Hydrogen TABLEA.34VisualKerogenAnalysis - A-148 R e f l e c t e dL i g h t (NONRR(US)DATA) A-149 TABLE A.35 V i t r i n i t e R e f l e c t a n c e D a t a h m m a r y ( N O N RR(US)DATA) A-150 TABLE A.36 V i s u a l K e r o g e n D a t a S u m m a r y ( N O N R R ( U S ) DATA) A-158 STANOLIND. # l FULLER TABLEA.37 Total OrganicCarbonData(NONRR(US)DATA) TABLE A.38 Rock-Eval Pyrolysis RawData(NONRR(US) DATA) A-169 A-170 TABLE A.39 H y d r o g e n and O x y g e n Indices fromRock-Eva1 Pyrolysis and TOCData(NONRR(US)DATA) TABLE A.40 V i s u a l K e r o g e n A n a l y s i s - (NONRR(US)DATA) A-170 ReflectedLight A-171 A-172 A-Xi APPENDIX A LIST OF TABLES (continued) PAGE NO. TABLE A.42 Visual Kerogen DataSummary ( N O N RRCUS) DATA) A-180 GREEN ESTATE, #l FRANKLIN,ASTON, A.43 TABLE AND FAIR Lithologic Description TABLE A.44 Carbon Organic Total A-197 Data A-198 TABLE A.45 Rock-Eva1 Pyrolysis Data TABLEA.46 A-199 Hydrogen and Oxygen Indices from Rock-Eva1 Pyrolysis and TOC Data TABLE A.47 Visual Kerogen Analysis A-199 - Reflected Light A-200 I TABLE A.48 Composition of Source Rock Extract A-204 TABLE A.49 Summary Table Showing Selected Parameters of Oil Samples A-204 TABLE A.50 Heavy Hydrocarbons Normalized to 100% A-205 HUSKY, 81 HANCHETTSTATE TABLE A.51 Lithologic Description TABLE A.52 TotalOrganicCarbon A-211 Data A-xii A-213 APPENDIX A LIST OF TABLES (continued) PAGENO. T'ABLEA. 53 Total O r g a n i c C a r b o n D a t a ( N O N R R ( U 'SI DATA TABLE A.54 Rock-Eval Pyrolysis Raw Data A-214 A-215 TABLE A.55 H y d r o g e n and O x y g e n Indices fromRock-Eva1 Pyrolysis and T O C D a t a A-215 TABLE A.56 Rock-Eva1 Pyrolysis RawData(NONRR(US) DATA) A-216 TABLE A.57 V i s u a l K e r o g e n A n a l y s i s - Reflected Light TABLE A.58 V i s u a l K e r o g e n A n a l y s i s - R e f l e c t e dL i g h t A-217 A-223 (NONRR(US)DATA) TABLE A.59 VitriniteReflectanceDataSummary(NON RR(US)DATA) A-224 TABLE A.60 V i s u a l K e r o g e n D a t a S u m m a r y ( N O N R R ( U S ) A-229 DATA) T R A N S PECOS. It1 LATIGO RANCH TABLE A.61 LithologicDescription(NONRR(US)DATA) A-243 TABLE A.62 Total O r g a n i c Carbon Data(NONRR(US)DATA) A-247 TABLE A.63 V i s u a l K e r o g e n A s s e s s m e n t Worksheet (NON A-248 RR(US)DATA) A-xiii APPENDIXA LIST OF TABLES (continued) PAGE NO. TABLE A.64 Summary of C15+ Soxhlet E x t r a c t i o n , D e a s p h a l t e n i n g and L i q u i d C h r o m a t o g r a p h y DATA) (NON RR(US) TABLE A.65C1-C7 TABLEA.66 of Air Space HydrocarbonAnalyses and C u t t iGnagss (NON RR(US) DATA) Saturate H y d r o c a r b o n A n a l y s e s A-255 for C r u d e OS TABLE A.67 DetailedCompositionalData (NON RR(US)DATA) GENERALCRUDE, A-256 # 1 SIMPSON TABLE D A.68 e s c r iLpittihoonl o g i c A-259 Total DC aOtaarrgbaonni c A-260 TABLE A.70 D aPtRya rooclky-sEi sv a l T A B L EA . 7 1H y d r o g e n A-261 and O x y g e n I n d i c e s from Rock-Eva1 P y r o lDy as it as and T O C TABLE A.72 V i s u a l Kerogen A n a l y s i s TABLE Composition A.73 A-252 (NON RRCUS) DATA) A.69 TABLE A-250 A-261 - R e f l e c tLe idg h t of Source RE ox ct rka c t A-262 A-267 APPENDIX A LIST OF TABLES (continued) PAGE NO. TABLE A.74 Summary Table Showing Selected Parameters of Oil Samples A-267 TABLE A.75 Heavy Hydrocarbons Normalized to 100% YATESPETROLEUM C0RP.s C1 T-4CATTLE A-268 CO. TABLE A.76 Lithologic Description TABLE A.77 Carbon Organic Total A-275 Data A-276 TABLE A.78 Rock-Eva1 Pyrolysis Raw Data A-277 TABLE A.79 Hydrogen and Oxygen Indices fromRock-Eval Pyrolysis and TOC Data - TABLE A.80 Visual Kerogen Analysis TABLE A.81 A-277 - Reflected Light A-278 Composition of Source Rock Extract A-282 TABLE A.82 Summary Table Showing SelectedParameters of Oil Samples TABLE A.83 A-282 Heavy Hydrocarbons Normalized to 100% A-XV ' A-283 APPENDIX A LIST OF TABLES (continued) PAGE NO. OILS TABLE A.84 Oil Composition and API Gravities A-289 TABLE A.85 Summary Table Showing SelectedParameters of Oil Samples A-289 TABLE A.86 Heavy Hydrocarbons Normalized to 100% TABLE A.87 List of Abbreviations used A-290 in Gasoline Range Hydrocarbons Data Table TABLEA.88 Individual Component Concentrationsin A-295 Gaso- lineRangeHydrocarbons A-296 TABLE A.89 Gasoline Hydrocarbons A-299 TABLE A.90 Classification of Oil on the Basis of Light Hydrocarbon Composition A-300 FIGURES A- 1 0 0 0 c c P c c A-2 AMOCO, #l G.C. BAKER A-3 A- 4 i"' E AHOCO # I G.C. BAKER L O 0 A- 5 MOCO # I G.C. BAKER 0 UR c FIGURE A.2 Summary plots of Rock-Eval pyrolysis data. A- 6 A- 7 I, \ \ \ \ \ \ \ \ \ \ \ \ ' \ \ \ \ \ i FIGURE A.4 LL Maturation profile based on vitrinite reflectance data. A- 8 c AMOCO, It 1 BLACKBURN FARMS A-9 I) I) a A-10 AnOCO BLACKBURN FAWS I" - E- m' AND 'RIA! - P E R N I A N P E N N - '7 P R E C A H B R I A N FIGURE A.5 Summary plots showing kerogen types. maturit;~ and source richness. A-1 1 e AMOCO BLACKBURN FARMS BENERATION (S2) ZONES I (T-sox) I L O y e I DRY 816 'RIAS e e I' P R E C A M B R I I' A N FIGURE A.6 Summary plots of Rock-Eval pyrolysis data. A-12 AMOCO BLACKBURN FARMS 1000 H Y 800 D R G 600 E N ' N D E 400 X 200 0 - 0 25 150 125 100 7550 200 1 75 OXYGEN FIGURE A.7 INDEX Kerogen type determination f r o m Rock-Eval pyrolysis data. AIIOCO BLACKBURN FAWS ~ A T U R A T X O NP R O F I L E 0 GENERATION ZONES 1.2. -mft I B.6. O" 2. 1.2 I 4€m ft m.4 I n 1.B. MM ft DRV L a m ft as RANDOM REFLECTANCE #.E 1.) I r 1.4- ct I , 916 I , I I 1.c )aae ft 3.2.IW f t , , . , , , , , , 1 ,,,, 8 4 \ \ 0 \ \ \ \ \ \ \ a \ \ \ 1. \ \ a \ \ \ \ \ FIGURE A.8 Maturation profile based on ritrInite reflectance data. A-14 SUNRAY, #l BRISCOE a I’ A-16 SUNRAY tl IRA J. BRISCOE m I I SOURCE RICYNESS FIGURE A.9 Summary plots showing kerogen types, maturity and sourcerichness. A-17 I 0 BRISCOE tl (SUN) A L I T ( X ORGANIC CARBON) 0 0 ” E L O 0 Y 0 0 c c NON RRI DATA FIGURE A.10 Summary plots showing kerogen types. mstuAty and source richness. A-I8 SUNRAY # I IRA J. BRISCOE P R E C A M B R I A N L J FIGURE A.11 Summary plots of Rock-Eval pyrolysis data. A-1 9 0 1-1 la I: 1 BRISCOE tt (SUN) POTENTIAL ” TI e I‘ R E C A M B R I A N NON RR(US) DAT,A I‘ SUNRAY C H I I R A J . BRISCOE 600 E N I N 400 X 200 0 200 175 150 125 100075 50 25 WYGE?! FIGURE A.13 I!YDEY Kerogen type determination from Rock-Eva1 pyrolysis data. \ A-22 1 a oc I C a Ia n v) A 3 Y a a B 2 SUNRAY # I IRA J. BRISCOE ~ A T U R A T X O NP R O F I L E OIL GENERATION ZONES m.8. I l e f t KT 88.4wafL I1.4.11m X ft RANDOH I.8 m.4 REFLECTANCE rn.8 I P R E C A H B R I A N i L FIGURE A.15 Maturation profile based on vitrinite reflectanoe data. A-2 3 DRI us Ie:crMm ft BAS 1 c 74eaft I 3 : * m f a Ct i 0 BRISCOE (SUN) I' M B R I A N \ I' PURETEX, I1 CAAPPELRANCH A-25 I' c A-26 PURETEXCHAPPELRANCH (SUN) SOURCE R I C ' I N E S S CENCE EENERATIO ( X ORGANICCARBON) 8.6 1.0 4 I! i ! !I I 1 I I i i I II ~ I i i I NON RR(U FIGURE A.17 Summary plots showing kerogen types, maturity and mume richness. A-2 7 0 PURETEX CHAPPEL RANCH (SUN) I PRmCTIVIM (T-max 1 INDEX (S'/CS1+S21) YET EA6 DRY 9A6 -r T T 0 P P FIGURE A.18 Summary plots of Rock-Eval pyrolysis data. A-28 c z I) - m 0 A-29 0 0 0 a m N m N - PURETEX CHAPPELRANCH (SUN) P R O F I L E M A T U R A T I O N GENERATION ZONES m-- m \ \ \ \ 1- \ - \ \ 2- \ 3-1 \ -. -h + +'i 4- \r =\* '\. +r - 5- \ -. \ \ \ 6- \ \ .-2 \ 7- \ \ \ 8- \ - \ \ \ e- \ "3 10- 1 FIGURE A.20 \ L 1 1 1 1 1 1 A Maturation profile based on vitrinite reflectance data. A-30 STANOLIND, #I FULLER A-3 1 0 0 0 I’ c A-32 FULLER # I ll (SUN) MATURITY X EXiNITE 1% AMORPHOUS ORGANIC CARBON) D R Y YET BAS BAS T V E h l 'IL T I I I FIGURE A.21 Summary plots showing kerogen types, matu-ity and source riohness. A-33 FULLER tl (SUN) G 0 k U R M EOOD 0 0 8) DATA A-3 5 0 0 0 0 0 FULLER # I (SUN) P R O F I L E M A T U R A T I O N OENERATION ZONES I n J I , I I , I , I , , , , , , , \ I,,,. I, \ \ \ a .' \ \. \ 0 P I' A rA FIGURE A.24 Maturation profile based on vitrinite reflectance data. A-36 GREEN ESTATE,#lFRANKLIN, A-37 ,P ASTON, AND FA1 a A-38 GREEN ESTATE #I, FRANKLIN,ASTON 8 FAIR CENCE BENERATION T P R E C A tl B R I A N FIGVRE A.25 Summary plots showing kerogen types, maturfty and source richness. A-39 GREEN ESTATE'II, FRANKLIN,ASTON8 FAIR A e E T I P R E C A M B R I A N FISIIRE A.26 Summary plots of Rook-Eval pyrolysis data. A-40 I GREEN ESTATE # I , lBBO H 800 Y FRANKLIN,ASTON & FAIR 1 *OlL 1f D R 0 600 G E N P E . I N 4 00 D E X 200 I 0 0 0 t . 25 75 50 I00 125 1 50 1 75 OXYGEN IIVDEX FIGURE A.27 Kerogen type determination from Rock-Evd pyrolysis data. 200 CF GREEN ESTATE# I , FRANKLIN,ASTON 8 FAIR # m CUK 1 fi I A 6 6 1 C .”, P E R M I A N P E N N -” P R E C A M B R I A N j \ : \ : \ : \ \ I FIGURE A.28 Maturation profile based on vitrinite reflectance data. A-42 HUSKY, #l HANCHETT STATE A-43 I) a c c HUSKY tl HANCHETT STATE SOURCE RICFNESS 12 OREANIC CARBON) 1.6 -Ai:; IJ 0 2.0 o E D FIGURE A.29 Summary plots showing kerogen types, maturit: and source richness. A-45 ,v r a v 0 HANCHETT STATE (SUN) SOURCE RICHNESS 0 -r 0 ! 0 0 I ! I i I’ I FIGURE A.30 Summary Plots showing kerogen types, matufity and BOurce richness. A-46 HUSKY I POTENTIAL SOURCE I tl HANCHETT STATE I H-INDEX I 0 I TI I 2 ". 3 4 - " FIGURE A.31 Summary plots of Rock-Eval pyrolysis data. A-47 HANCHETT STATE (SUN) INDEX 0 0 j 0 5 ' 1 l I e I m10N RR(US) DATA FIGURE A.32 Summary plots of Rock-Eval pyrolysis data. A-48 w I- U m II- t P c A-49 1 0 HUSKY tl HANCHETT STATE ~ 0 X tl F 1 0 \ 0 0 : \ : i : \ \ \ \ \ \ \ \ \ \ I' FIGURE A.34 Maturation profile based on vitrinite reflectance data. A-50 E HANCHETTSTATE (SUN ) P R O F I L E M A T U R A T I O N BENERATION ZONES KF 0.2. Pt OIL m.8. m [ 1.4. ct KI Ea Pt B)is 08- 48118 Pt DRY {*:e l24m Ct Io. RANDOM REFLECTANCE #.e Le I 2 2 1 \ \ 3 i i \ i \ i \i \i ;\ : \ \ \ \ \ \ \ \ + +++ +\ \ : \ ; \ : \ i \ \ \ \ \ .\ \ \ I * I , I . , . : , . . , . I, , . . - R(US1 DATA FIGURE A.35 Maturation profile based on vitrinite reflectancedata. A-5 1 EKw P i 3:2. 1 8 2 8 8 B)is ft 4 e .e e e e c A-5 2 TRANS PECOS,#l LATIGO RANCH A-53 0 I' I' A-54 LATIGO RANCH W A-55 l- LATIGO RANCH SUMMARY OF ORGANIC ANALYSES 0 SOURCE CHARACTER 0 0 c 3 I' I' I' NON RR(US) DATA FIGURE A 3 Summary of organic analyses. A-56 LATIGO RANCH SUMMARY OF ORGANIC ANALYSES . .. . " CrC7 HYDROCARBON -5- .. . " . FIGURE A.B Summary of organic analyses carbon. A-5 - C1-C7 hydro- v LATIGO RANCH i I I I I I I I I I I 0 II I I I I I I i I I I I I I II I' I I II I I I II I I 0 A-58 'IW GENERAL CRUDE,#l SIMPSON A-59 e I' I' A-60 GENERAL FIGURE A.40 CRUDE # I SItlPSON Summary plots showing kerogen types, maturity and source richness. A-6 1 GENERALCRUDE tl SIMPSON BENERATION 1 ZONES H-INDEX I' FIGURE A.41 Summary plots of Rock-Eval pyrolysis data. A-62 0 A-63 0 0 i \ i \ \ \ \ \ \ \ 0 c I' \ \ - i \ \ 1. A.43 Maturation profile based on vitrMte reflectance data. 1. A-64 YATES PETROLIJEM CORP.. A 1 T-4CATTLE A-65 CO. I’ c c A-66 YATES # I T.V. CATTLE CO. HATURITY BENERATIOh CENCE INTENSITY S O U R C ER I C ' 4 N E S S ( 2 O R G A N I C CARBON) 1.00.5 ! I FIGURE A.44 Summary plots showing kerogen types. maturity and sourcerichness. A-67 YATES # l T.9. CATTLE CO. JUR AND RIA6 P E R H I A N 0 - P E N N ."$ P R E C A M B R I A N FIGURE A.45 Summary plots of Rock-Eval pyrolysis data. A-68 A-69 0 0 0 0 v \ \ \ \ \ \ \ \ \ +\ \ \ \+ t \ \ \ \ \ P \ R E C A K 6 R I A N LL FIGURE A.47 Maturation profile based on vitrinite reflectance data. A-70 TABLES A-7 1 0 0 0 0 c c I' A-72 AMOCO. #1 G.C. BAKER A-73 I' A-74 TABLE A.l LITHOLOGICDESCRIPTION AMOCO PRODUCTION #1 G.C. BAKER 210- 660' 700790' 790-1,900' Mudstone. reddish brown Sandstone.fine-grained.lightbrown Mudstone, reddish brown. some lightgreenishgray mudstone. trace of lime mudstone and gypsum below 1.390 1,900-2,420' 2.420-2,790' 2,7904,910' 2,940-2,980' 3.000-3,340' 3,370-3.380' 3.400-3.440' 3.460-3.470' 3.490-3.540' 3,560-3,600' 3,620-3.840' 3.860-4.390' 4.410-6,280 6.280-6.970' Gypsum and dolomudstone. light gray Limestone, dolomudstone and gypsum, med. to da-k gray Mudstone. light gray, some limestone and gypsum Halite, V. light gray to pink Mudstone, lightreddish brown Halite, light pink Mudstone, lightreddish brown Halite, pinkish Mudstone, reddishbrown Trace of halite Halite pinkish Mudstone, reddishbrown Mudtsone. light reddish brown Trace of gypsum Trace of dark gray mudstone Mudstone, reddish brown Trace of gypsum Somemedium gray mudstone Trace quartz sand Mudstone, medium to dark gray, some light browrish red Some cgarsequartzgrains Trace of pink feldspar granite wash Granite wash Trace of dark gray mudstone Mudstone, medium darkgray, some light brownisk red Some granite wash Mudstone. darkgrayandreddish brown Sandstone, medium Mudstone, darkgray,reddish brown Trace of granite - 6,970-7.060' 7,080-7.700' 7.700-8.180' 8,200-8.330' A-75 TABLE A.2 TOTAL ORGANIC CARBON DATA AMOCO * 1 C . C . BAKER 1 P r o j e c t NO. : R R U B I ~ ~ S I ~ I ~ O ~ I ~ SAMPLEIDENTIFICATION : DATA DEPTH : TOC% RRUS 1001 : 230 520 : 1004 1530 1005 1860 : : : 1006 1007 1008 1009 : 1010 2455 2650 2855 3040 3420 1011 1012 1013 1014 1015 3820 4120 4280 4720 5240 1002 1003 1020 (Feet) : 0.05 : 0 . 0 8 I 1017 1018 : 0.07 1019 : 0.03 1020 : 0.09 5720 6335 6470 6770 7100 1021 1022 1023 1024 1025 7220 7370 7510 7705 7810 1026 1027 7915 8050 8150 8310 : : 2490 2670 2890 3080 3940 : : : : : : : : : : 38004100426047005220- 3840 4140 4300 4740 5260 : 0.05 : : DATA : TOCYl 3 2 1 0 -2 5 0 500540 1000- 1040 1 5 1 0 - 1550 1840- 1880 24202630282030003400- : I SAMPLEIDENTIFICATION RRUS DEPTH (Feet) 0.25 0.20 0.08 0.16 0.10 : 0.24 : 0.16 : 0.04 1016 1028 1029 : : : : : 57005740 6300- 6 3 7 0 6 4 5 0 - 6490 6750- 6790 7080- 7120 : : : : 7170- 7270 7340- 7400 7490- 7530 7670-7740 7790-7830 : : : : 7880803081208290- : :-0.06 : 0.20 : 0.23 : : 0.23 0.31 1 0.27 : 0.36 : 0.29 : 0.31 : 0.37 7950 : 0.42 8070 : 1 . 2 1 8180 :-0-.8P 8330 : 0 . 4 4 : 0.C5 I' A-76 TABLE A.3 ROCK-EVAL PYROLYSIS RAW DATA BAKER AMOCO Ul G . C . Project N o . : R R U S 1 8 4 5 I M 1 8 0 7 l 4 I : DATA ( S l , S 2 , 8 3 mglgm of r o c k , Tmax SAMPLE IDENTIFICATION RRUS DEPTH (Feet) I I 82 51 c) deg Sl/(Sl+S2) Tmax S 25l3S 3 ! 1 0 0264 5 5 1 0 1421 2 0 1018 6470 7100 1020 1022 7370 1024 1025 1026 1027 1028 1029 7705 7810 7915 8050 8150 8310 : : : : : : : : : : : 2 4 9 0 ’ 0.040 4 1 0 04-1 4 0 0.070 6450- 6490 I 0 . 2 2 0 7080- 7120 I 0.060 7340- 7 4 0 0 I 0.020 0.200 0 . 3 0 0 0 . 4 ~ 0 0.680 0.470 0.150 0.240 0.340 0.110 0.290 7670- 7 7 4 0 i 0 . 0 5 0 7790- 7830 I 0 . 0 5 0 7880- 7950 ’ 0.060 8 0 3 0 -8 0 7 0 i 0.200 8120- 8180 I 0.080 0.250 0.150 0.190 0.940 0.330 0.250 0.350 0.280 0.330 0.250 1,000 0.429 01679 2.848 1.320 0.200 0.340 0.588 2420- i 0 . 6 607. 1 6473 7 0.662 0.135 3.133 0.319 0.706 0.200 0.379 0.154 ! 0.167 cI.250 I 0.070 8 2 9 0 -8 3 3 0 c.259 ----- 408 --- .. . 0.240 c . 41 57 15 0.195 I --409 ”- 462 --- NOTE: A DASH INDICATES AN INDETERMINABLE VALUE. TABLE A.4 HYDROGEN AND OXYGENINDICES FROM ROCK-EVAL PYROLYSIS AND TOC DATA AMOCO I1 G.C. BAKER Project N o . : R R U S l 8 4 5 I M I 8 0 7 l 4 SAMPLE IDENTIFICATION I I RRUS DEPTH (Feet) I 1006 1012 1018 1020 1022 1024 iOZS 1026 1027 1028 18032190 2420- 4120 6470 7100 7370 7705 : : : 7 677704-0 I 7790- i e i o i 7880- 7950 : 8030- 8070 I 8120- 8180 I : 8 289303-0 7eio 7915 8050 8150 4100645070807340- 2490 4140 6490 7120 7400 I I I I : 80 188 204 77 31 I I : OXYGEN INDEX TOC (mg CO2lgm TOC) (%) I : : : : : 2455 HYDROGENINDEX (mg HClgmTOC) E1 41 45 7 8 37 I 45 A-77 0.44 120 283 65 110 81 0.25 81 95 67 27 28 0.31 0.37 77 0.24 0.23 0.31 0.36 , 0.42 1.21 0.88 e' TABLE A.5 VISUAL KEROGEN ANALYSIS- REFLECTED LIGHT AMOCO tl C . C . BAKER P r o j e o t No. SAMPLE IDENTSFICATXDN RRUS DEPTH (Feet) I I I I REFLECT. RD % KEROGEN Am% I : : : : : 2420- 2490 : 4100- 4 1 4 0 ' 6450- 6490 i 7 3 4 0 7- 4 0 0 I 7 7 9 07 -8 3 0 I 0.37 1.09 1.14 1.14 35 tr 45 0 0 0 0 50 0 1 0 28 70 5 0 1 0 28 1 5 0 1029 8310 : 8 0 3 08 -0 7 0 8 1 2 08 -1 8 0 8 2 9 08 -3 3 0 : 1.18 1.19 30 tr 0 : CHARACTERIfTICS Ex% VitS I n e r t % F l u o r 1006 2455 1012 4120 1018 6470 1 0 2723 7 0 1025 7810 : 0 : RRUS/845/M/B07/4 I I I ---- ---- A-7 8 55 so 0 0 30 15 tr 0 3350 30 2 03 0 25 50 20 23 00 0 0 LOW None None None None LOW None None TOC K 0.25 0.24 0.23 0.36 0.37 @ 1.21 0.88 0.44 I) AMOCO Wl G.C. BAKER RRUS N o . ID 1’106 tTt5. I DEPTH I 9 I 2545 0 Ft 775.7 n t = Ro RATURITY P l5 * 8 VALUES MEAN STD 0.37 0.03 I DEV flEDIAN MODE 0.38 : 0.35 HISTOGRAR: Range: 0- 4 % Increment: 0.10% ORDERED REFLECTANCE VALUES, V0.32 V0.33 t0.36 10.37 V0.38 VE.38 V0.40 10.40 0.51 KEROGEN DESCRIPTION 55 X Amorphous : Exinite : 0 % Vitrinite : 30 X Inertinite , 15 f Back Fluor Bitumen Cohe AROCO s1 : Low I Snail : Nom G.C. B M E R RRUS ID I No . 1012 CTtS. DEPTH BARREN MEAN I 3770.0 F: I 1148.1 : li N.D. gL e0.0 I .0 2.0 3 e VITRINITE REFLECTANCE (RANDOM X I ORDERED REFLECTANCE VALUES: 4.0 HISTOCRAV: lncpement 0- RDnge 4% E,l0% KEROGEN DESCR1P:ION lr 2 Amorpnous : 0 X Exinlte Vitrinite I tr X 0 % Inertinyte Bsch Fluor B i tumen Cohe A-7 9 ; None None : Nore I W RRUS ID > NO. : I018 CltS. DEPTH I I 6620.0 F t 2017.8 M f = Ro MATURITY I VALUES 8 I 43 : E . I0 WEAN 1.09 STD DEV MEDIAN UODE I .0Q I .E5 I ii1STOCRAn Range: 0- 4% lncremenl: e . 1 0 ~ I VlfRINITE REFLEClANCE [RANDOM X1 VALUES. ?I .I4 ?I .I4 tl . I 5 tl .I6 *I .I8 KEROGEN DESCRIPTION Amorp-ous : 35 x I Ex;nite 0 % Vitrlnlte . 35 t lnerlinite : 30 X SI .22 f . l. ." .23 f1 .24 ? I .24 tl .25 fl.18 1.27 tl.IE 1.58 t0.85 ? I .06 f1.12 fl.20 f0.07 11.07 f1.13 fl.21 f0.88 t1.07 tl.14 f1.21 Back Fluor B i lumen : : : Coke 1.28 1.29 1.33 Nore None ~r 8 DEPTH : 1 f 7435.0 F t 2266.2 K = Ro nATUR1TY VALUES MEAN STD DEV 37 1 .I4 E.09 I 1.15 .0 VITRINITE REFLECTANCE IRANDOn ORDfRED REFLECTANCE VALdES: 0.78 f l 0: t1.12 f 1 . 2 1 t1.26 0.80 0.81 0.85 0.87 0.87 t0.82 f0.85 f0.86 F1.81 t1 .04 ? I 08 tl.09 ?I.I0 tI.10 ? I I2 71.12 q1.13 tl 15 t1.15 t1.15 71.21 ? I .27 31.21 t1.27 X1.22 1.28 11.23 I 30 31.24 1.30 *l.II tl.25 1.32 81.11 11.17 1 1 . 2 5 1.32 fl.11 tl.17 t1.26 1 32 fI.11 tl.18 t 1 . 2 6 1.38 A-80 X1 KiROGEh' DESCRIPTION Amorpnous 45 % A % Er,ni,* . Vlrrlnire a 30 2 Inerr inlte 25 x . " Each Fluor Bi lumen Cohe I None i IF , rr P RRUS No. ID : 1925 I CTGS. DEPTH 7310.0 Ft 2'90.5 n t I t = Ro f l A l U R l T Y VALUES D 34 I nEAN STD DEV PEDIAN RODE 1.14 0.BQ 1.16 1.15 I t I VITRINITE REFLECTANCE fRANDOn x 1 ORDERED REFLECTANCE VALUES 0.82 11.04 t1.16 fl.24 0.85 :I .04 t1.17 TI .24 0.87 T1.07 51.17 V I .25 . . . . . . ? I .27 71.02 tl.10 t1,IE ? I .27 t1.02 tI.10 1 1 . 1 8 TI .27 t1.02 tl.11 tl.18 ? I .28 t1.02 TI .I2 7n - t.1. .." I .32 t1.03 * I .I4 t1.22 I .32 11.04 tl.15 t1.24 1.34 Q SEROGEN DESCR'PTION 50 Amorphous I Exinite : 0 Virrlnire 30 lnerr lnite : 20 1.36 I .36 1.38 I .38 1.38 1.40 I 41 1 .41 1 48 I .52 Beck Fluor 8 i tumen Coke RRUS No. li ID I . . : t I 10?7 80- e F t 2453.6 I! = Ro nATURl.*V 1 0 ' 2.0 ' 4.0 3.0 VlTRlNlTE REFLECTANCE IRANDOP ORDERED REFLECTANCE VALUES. .06 51 .I6 51.06, * L I E 51 .86 TI.18 51 .0E tl.19 51 tI.10 t L I Q rl.12 51120 :I20 TI .I3 tl 22 * I .I4 ? I .23 tl.14 t1.23 T I.13 TI 23 TI .24 :I .25 11.27 11.27 X I .27 XI .27 TI .28 T I .30 tl .30 .33 .33 .34 .34 .34 35 .36 38 .38 48 A-81 %I 32 MEAN : STD DEV 1.18 I 0.ee nEDIAN nODE ., .. ! x None None None VALUES . 0 1 , , ," 0.0 X CTtS. DEPTH l5 8.84 0.87 0.84 0.88 0.99 0.88 1.0a 1.02 * I .04 t1.05 I : ; x % : 1.:8 I .25 hlSTOGRAfl: Rsnge. 0- 4 % Increment 0.le% KEROGEN DESCRIPTION 30 2 Amorphous : . tr x Exinire 50 % Vitrlnite : lnerr inite : 20 % Beck Fluor . 8 i tumen Coke Lor lr- Nom RRUS No. ID : I028 I CTCS. MEAN 1.18 STD DEV 0.07 1 19 I .25 : MEDIAN nODE I HISTOGRAM: Range, 0 - 4 % Increment: 0.10% ORDERED REFLECTANCE VALUES: 0.86 1.06 31.13 tI.18 tl.25 0.86 tl.08 t1.14 t1.20 11.26 0.87 tl.08 ~ 1 . 1 4r1.20 tl.26 0.87 ? I .08 :I .15 tl.20 il :25 0.89 tl.08 31 17 81.21t1.27 0.89 tl.10 Vl.17 tl.22 f 1 . 2 8 0.88 tl.10 31.17 t1.23 tl.28 1.00 t1.12 tl.18 t1.23 't1.28 1.02 tl.12 tI.18 t1.24 t1.30 1.06 '11.12 71.18 t1.25 t1.31 35 KEROGEN DESCRIPTION Amorptlouo I 5E x R Z Exinite I Back Fluor : toke z RRUS s ID 8 No. : hone None None I B i tumen l0lQ CTGS. P INSUFFICIENT SAMPLE MATERIAL e MEAN I N D P 0 - , , , , , . , , , , , , , ~ , , , .,~, ,,, ,, , , ,, , 0.0 1 .a 2.0 3.0 4.0 VITRIhITE REFLECTANCE IRANDOM XI ORDERED REFLECTANCE VALUES, HISTOGRAM: Range. 0- 4 % Increment: 0.10% KEROGEN DESCRIPTION 0 x Amorphous : Erinite : 0 X Vitrinite , 0 X lnertinite I 0 X Boch Fluor B i tunen Coke A-82 : I : None None None COMPOSITION OF SOURCE ROCK EXTRACT AMOCO # 1 G.C. BAKER Project N o . -I SAMPLE IDENTIFICATION D E P T HR R U S 1027 1028 : : AROH SI A TE X T R A C T (Feet) 8050 8150 : RRUB18451M1807/4 P Pm 8 0 3 0 -8 0 7 0 percentage 548 8 1 2 0 -8 1 8 0 POLARS 46.0 44.0 243 1 6 .7 13.3 37.3 42.7 TABLE A.7 SUMMARY TABLE SHOWING SELECTED PARAMETERS OF O I L S A M P L E S AMOCO b 1 G.C. BAKER Project N o . : R R U S l 8 4 5 1 M 1 8 0 7 1 4 SIADMEPNLTEI F I C A T I O N RRUS (D FE eP eT tH I I ) I -IEPC-Xh:T-T1O-R87C-A -C-T SATS W Prl RCAPTII O S PPhrl I I 1027 1028 8050 8150 : : 8030 8070 I 8120- 8 1 8 0 I 0 . 0 4456 .00. 4 7 0.028 44.0 A-83 0.44 0.59 0 . 5 9 0.53 0.83 ------- TABLE A.8 H E A V Y H Y D R O C A R B O N S N O R M A L I Z E D TO 100% AMOCO # 1 Projeot No. : R R U S ( F e eDtE)P T H a050 8150 : : 8030- 8070 8120- 8 1 8 0 I RRUS 1027 1028 8050 8150 C-19 C-20 C-21 5 . 6 0 1 1 . 8 0 1 5 . 8 0 1 6 . 4 0 1 5 . 8 0 11.70 8.40 15.80 1 5 . 9 0 1 2 . 8 0 9.70 7 . 1 0 i. C-22 C-23 C-24 C-25 C-26 C-27 C-28 : : 8030- 8070 1 8120- E180 (DFEePeTtH 8050 8150 1.40 1.50 - NORMALIZED n-ALKANES C-15 C-16 C-17 C-18 RRUS ( F e eDtE)P T H 1027 1028 : RRUSl845lMI807l4 -i SAMPLE IDENTIFICATION 1027 1028 G . C . BAKER : 8030- 8 0 7 0 8120- 8180 : RRUS ( F e eDtE)P T H 3.90 6.10 C-29 C-30 C-31 ) : 9.60, 5.60 8.10 7.70 :. 0.00 0.30 0.00 0.20 0.00 0.00 1.40 3.30 0.70 C-32 C-33 C-34 C-35 0.00 0.00 0.00 0.00 1.80 0.30 0.90 0.00 0.00 0.00 0.40 0.00 0.00 PPRH C-36 C-37 C-38 C-39 C-40 : 1027 1028 8050 8150 : : 8 0 3 0 -8 0 7 0 8120-E180 0.00 0.00 0 . 00 . 0 0 A-84 0.00 0.00 0.00 0.00 0.00 5 . 59 0. 4 0 0.00 7.00 8.40 AHOCO # I G.C. BAKER 1=188xPristans/Totol 2=I00xPhytondlotol %Pridme/n-C-17 4=Phytons/n-C-l8 5PPristaneRhyt& b b m Praf.Index NORMALIZED DISTRIBUTION OF n-AWES A-85 G. C. BAKER I SAMPLE: RRUS NO. 1027 8050 feet SAMPLE: RRUS8150 NO. 1028 feet GASCHROMATOGRAMS OF C l 6 + SATURATEHYDROCARBONS A-86 AMOCO. It 1 BLACKBURN FARMS A-07 a c A-88 TABLE A.9 LITHOLOGICDESCRIPTION AMOCO #1 BLACKBURN FARMS 1,500-1,860' 1,890-1.900' 1,920-1.980' 1,980-2.230' 2,250-2.260' 2,280-2,320' 2,340-2,410' 2,430-2.500' 2,520-2,560' 2,580-2.710' 2,730-3.960' 3,980-4,530' 4.550-4,680' 4.700-4.740' 4,760-4,920' 4,940-4,950' 5,000-6,390' 6,410-7,370' 7.400-8,200' 8,200-8,290' 8.310-8.580' Mudstone? Halite, It. pink Claystone,reddish brown Halite, It. pink Some claystone Some anhydrite Claystone, It. grayandpink;anhydrite Claystone,reddish brown Claystone,green-gray (some reddishbrown) Some anhydrite Halite,It.pink Claystone, reddish brown and green-gray anhydrite Halite, It. pink Claystone,reddish brown (some green) Halite, It.pink Some claystone,reddish brown Some anhydrite Claystone,reddish brown Halite, It. pink Some claystone,reddish brown Claystone. reddish brown Lst., gray Shale Trace of qtz., feldspar Anhydrite Claystone.reddishbrown Claystone, brown Anhydrite Shales,dark Traces of granite wash Claystone. reddish brown Shale. dark Anhydrite Claystone.reddishbrownandgray Shale, dark Anhydrite Lst., gray Anhydrite A-a9 TABLE A.10 TOTAL ORGANIC CkRBON DATA AMOCO BLACKBURN FARMS Project No. : R R V S 1 8 4 5 I M 1 8 0 7 l 4 SAMPLEIDENTIFICATlON RRUS DEPTH (Feet) 1201 1202 1203 1204 1205 1580 2120 2540 2985 3505 : 1206 1207 1208 1209 1210 4015 4510 4825 4945 5495 : 1211 1212 1213 1214 6005 6460 6650 6770 : : : : DATA : TOCK : SAMPLEIDENTXFlCATION RRUS 1560- 1600 : 0 . 0 5 2 1 0 02 -1 4 0 : 0.04 2520 2 -5 6 0 : 0.26 2 9 8 02 -9 9 0 : 0.19 3500 3 -5 1 0 : 0.38 I I DEPTH 1215 1216 1217 12 71 48 35 1 27 17 95 0 6990 7200 7335 : : : 40104490482049405490- 4020 4530 4830 4950 5500 0.12 0.14 0.14 0.45 0.17 1220 1221 1222 1223 1224 7765 7955 8045 8165 8255 : : : : 6000- 6010 6440- 6480 6 6 0 60 7- 0 0 6 7 5607- 9 0 0.19 0.20 0.350.28 1225 1226 1227 8330 8390 8505 : (P-ct) : DATA : TOCW : 6970- 7010 7180- 7220 7300- 7370 7 473404- 0 7 578902- 0 : : : : : 0.27 0.19 1.90 0.26 0.35 : : 7 7 3 07 -8 0 0 7920 7 -9 9 0 : : 8010- 8080 : 0.40 : 0.75 : 1.20 : 0.80 : 0.54 : 831083708490- 8350 e410 8520 : : : : : : : 8130- 8 2 0 0 8228 02 - 90 1 0.50 : 0.82 : 3 . 8 7 I' A-90 TABLE A . l l ROCK-EVAL PYROLYSIS RAW DATA AMOCO BLACKBURN FARMS Project No. : R R U S 1 8 4 5 1 M 1 8 0 7 1 4 SAMPLE IDENTIFICATION RRUB DEPTH (Feet) 1 2 0235 4 0 1205 1209 1213 1214 : : 3505 4945 6650 6770 : : : 2 5 2 02-5 6 0 3500- 3510 4940- 4950 6600- 6700 6750- 6790 1 2 1659 9 0 1 2 1773 3 5 1219 7750 1220 7765 1221 7955 : : : : : 6 9 7 07-0 1 0 7 3 0 07-3 7 0 7580- 7920 7730- 7 8 0 0 7920- 7990 I I -~ DATA ( S l , S 2 , 5 3 mglgm o f r o e k , T m a x I 51 I SlI(Sl+S2) Tmax 5 2S/35532 i 0 . 0 100. 1 300. 3 000. 4 303. 0 7411 7 0,410 0.700 1,030 0.680 0.360 0.890 I 0 , 0 1 0 0.120 0.380 I 0,020 I 0.390 I 0,010 i 0.010 I --- I 0.010 0.100 0.210 “ - I 0.020 0.260 I 0.040 5.830 : : : 8 4 9 08-5 2 0 ; : 1227 8505 1;;: fO l01308 2 2 08-2 9 0 8 3 1 08-3 5 0 8 3 7 08-4 1 0 0.586 1,515 0.404 0.316 0.350 0.286 0 . 7 900. 2 606. 0 4 5 ”- 0.870 0.650 I 12 82 02 45 1223 8165 1 2 2842 5 5 1225 8330 1 2 2863 9 0 c) deg --_ _-_ --_ ”- --- 0.091 -” ”- “- 0.299 8.969 0.071 0.007 ::z!i: 0 . 1 3454 4 01..100700 00 .506805 0 . 1 000. 6 4 0 0:520 0.020 0 . 4 100. 2 610. 5 707. 0 4 7 I 0 . 0 300. 2 600. 4 400, 5 901. 1 0 3 I 0.060 0 . 3 900. 4 700. 8 300. 1 3434 8 I I 0.060 0 . 3 600. 3 700. 9 703. 1 4434 8 iI 0.047 0.275 0.027 0.077 -” 411 431 446 453 444 NOTE: A DASH INDICATES AN INDETERMINABLE VALUE TABLE A.12 HYDROGEN AND OXYGEN INUICEZ FROM ROCK-EVAL P Y R O L Y S I S AS3 TOC DATA AMOCO BLACKEURN FARMS Project No. I I SAMPLE IDENTIFICATION RRUS DEPTH (Feet) 1 2 0 32 5 4 0 1205 3505 1209 4945 1213 6650 1214 6770 ; 2520- : 3500494066006750- 1 2 1 56 9 9 0 1217335 1219 7750 1220 7765 1221 7955 : 1222 : : 1223 1224 1225 1226 8045 8165 8255 8330 8390 : : : : : : : : : ; I 2560 3510 4950 6700 6790 6 9 7 0 -7 0 1 0 73007370 75807920 77307 -800 7 9 72 90 9- 0 8010- 8080 8130- 8 2 0 0 8 2 2 0 - 8290 8310- 8 3 5 0 8370- 8 4 1 0 I I I I I ; i I I : I I 1 ; RRUS1845IM1807l4 HYDROGENINDEXOXYGEN INQE’ (mg HClgm TOC) tmg C02Igm TOC) so (%) 0.26 0.38 0.45 0.35 43 115 184 151 254 136 37 11 1920 65 777 130 42 891 217 87 0.27 108 229 103 I I 89 80 76 I 52 I TOC 48 0.40 0.75 1.20 0.82 47 65 48 88 57 0.28 1.90 0.35 0.80 0.54 0.50 ! 1 2 28 75 0 5 : 8 4 9 08 -5 2 0 I I 41 A-9 1 43 0.87 TABLE A.13 ~~ - VISUAL KEROGEN ANALYSIS REFLECTED LIGHT AMOCO BLACKBURN FARMS P r o j e c t No. : R R U S / 8 4 5 / M / 8 0 7 / 4 ~~ SAMPLEIDENTIFICATION RRUS DEPTH (Feet) : REFLECT.KEROGEN CHARACTERlS7ICS I : Ro % Am% Ex% V l t + Inert% Fluor i 1205 3505 1 2 04 99 4 5 1213 6650 1217335 1219 7750 : : : : : 35003 -510 49404 -950 66006 -700 7 3 0 07 -3 7 0 75807 -920 1220 7765 1221 7955 1 2 28 20 4 5 1 2 2863 9 0 1227 8505 : : : : : 7 7 3 07-8 0 0 : 7 9 2 07-9 9 0 : 8010- 8080 : 8370- 8410 : 8 4 9 08 -5 2 0 I I : I I ---0.65 0 55 0.80 0.31 0.93 45 35 1.00 ---- 45 0 45 tr 50 tr tr 40 0 0 tr 30 t r 2 53 5 t r 15 40 tr 50 0 None 1S LOW LOW 15 None LOW - TOC $4 0.38 a .45 0.35 1.90 0.35 1 1.12 1.20 1.23 20 0 5 2 03 5 0 3s High 0 40 15 10 60 20 None fled Med LOW 0.40 0.75 1.20 0.e2 0.87 I' I' A-9 2 AnOCO BLACKBURNFARnS RRUS No. N ID > DEPTH REAN 1.0 3.0 2.0 4.0 VITRINITE REFLECTANCE IRANDOfl X ) ORDERED REFLEETANCE VALUES: I 3505.0 Ft 1068.3 n 7 h.D I INSUFFICIENT SAnPLE nATERIAL 0 0.0 1205 I CTGS. HISTOGRAn: Ronge: 0- 4 % Increment: e.102 KEROGEN DESCRIPTION 0 2. Arnorp3ous I Erinite I 0 % Vitrinite I 0 X lnertinite 8 0 X Bock Fluor I B i lumen Cohe > None None None AnOCO BLACKBURN FARnS RRUS No. : 1209 ID : CTGS DEPTH . : 4 4845.0 F i 1507.2 fl t = Ro flATURITY VALUES REAN SlD DEV HEDIAN nODE VITRINITE REFLECTANCE fRANDOn XI ORDERED REFLECTANCE VALUES. 0.42 t0.50 ta.52 20.53 L0.54 .*0.55 L0.56 t0.56 f0 50 t0.60 t0.60 t0.68 t0.61' t0.72 te.64 10.73 t0.64 t0.75 70.65 r0.78 t0.65 t0.02 t0.65 L0.83 70.66 r0.85 L0.67 0.89 t0.68 0.89 27 : 0.65 0.IB 0.65 0.65 : . : HISTOGRAn. Ronge. 0- 4% Increment: 0.10% KEROGEN DEfCRlPTIOh 55 X Amorpnous : Exinrte I tr % Vltrinlte : 30 X Inert inite: 15 X 0.80 0.85 0.05 0.87 Bock Fluor Bitumen Cohe A-93 I ! Low ned '1 2s , AnOCO BLACKBURN f ARHS No. RRUS ID : I213 CTGS. 2 DEPTH I 6635.0 Ft : 2011.5 n Ro HATURITY f D * VALUES 20 I HEAN STD DEV HEDIAN noDE 0.78 0.10 0.79 8.85 I : I : HISTOGRAn: Range, 0- 4% Incremenr: 0.10% ORDERED REFLECTAGE VALUES: 0.48 0.50 0.55 0.58 0.58 f0.63 t0.64 10.65 f8.66 f0.67 ~ 070. f0.73 f0.73 fO.74 t0.78 0.60 0.60 0.60 0.60 0.61 f0 79 KEROGEh DEStRIPTIOh 40 x horpnous : Exinire I lr X Vltrinire : 35 X Inert inile 25 X 0.86 .. f O 82 0 88 f0.86 0.00 f0.86 1 .OO 70.87 . I .03 f0.8E 1. 17 ._ f0 .88 1 .I2 f0,80 1 . I 8 t0.02 1.25 f0.03 ~ Fluor Bltumen : z Low Cohe 8 lr Each ?5 . RRUS ID : No. I ned I' 1217 CTCS. DEPTH I I 8335.0 FI 2845.3 R 8 = Ro nA7UR:TY * VALUES EAN STD DEV nEDIAN H3DE 21 : 0.01 0.07 0,92 0.85 ! : I : HISTOGRAR: Range. 0. 4% lncremenr. 0.10% - ORDERED REFLECTANCE VAI.LIES, 0.56 0.59 0.63 0.68 0 71 0.73 0.74 10.78 f0.78 10.80 t0.83 f0.83 t0.85 t0.84 t0.85 70.85 f0 86 f0.88 f0.88 f0.89 fO.OO tl.01 I0 81 fI.01 ?0.82 r1.02 70.83 1.04 10.83 1.04 I .05 1.17 1 I .21 1 I .26 1 I.lI I .I2 I .I2 1.14 1.14 1.16 I .26 I .26 1 .26 : .28 1 .28 KERXEN DESCRIPTION 49 % Amorphous . Erinire I lr X 40 X Vilrlnire I Inert infile: 15 X Back Fluor . 8i 1 m e n Coke : : None a, Sml; 5mo.i 1 30 1.30 c A-94 ABOCO BLACKBURN FARMS 25 _I RRUS No. ID t t f G S . Ill8 DEPTH I 7E00.0 Ft I 2316.5 X Ro 11ATURITY D VALUES nEAN STD DEV MEDIAN BODE VIfRINITE REFLECTANCE IRANDDW XI ORDERED REFLECTAKE VALUES 0.66 ?e 85 20.86 I .07 1 .22 0.71 re.86 10.97 I .08 I 23 0.72 t O 88 t0.87 I .0Q I .28 0.74 t0 88 t0.88 1.09 ! .28 0.75 t0.8e X0.98 1 . 1 8 1 .30 0.77 ra.81 r 0 . w 1.14 1 ,32 ae.78 t0.83 tI.02 1.16 I .34 t 0 . 8 1 t0.94 r1.02 1.17 1 .35 X0 82 t0.95 t1.03 1.18 1 .44 V0.83 f0.85 tl.03 1.21 1 .46 n 24 r 0.83 0.07 0 85 8.85 I 8 : I HISTOGRAW: Range. 0- 4 3 Incremeqt: E.l0% KEROGEN DESCRIPiIOY 35 X Amorp?ous Exinire : lr X Vitrtnire I 50 X I5 X Inert inire , Beck Fluor Bitumen Coke : I : Lor Sma:! lr rnoco BLACKBURF; FARWS s 25 1 RRLlS ID I No. : I220 CTGS. ? = a VALUES Ro MATURITY MEAN STD DEV nEDl AN 31 : 1.00 0 e7 1 01 1 :05 : : n5DE VIlRINiTE REFLECTANCE [RANDOW ORDERED REFLECTAWE VALUES: 0.78 V0.86 t0.87 V0 88 t0.81 t0 82 t0.82 t0.84 V0.84 r0.W t0.QE t0.Qa fl.OO tl.01 t1.01 03 tl.10 11.E3 Vl.10 ? I 04 1 .I3 ? I 04 1.14 t1.06 1.14 TI .07 1 .I6 t1.01 ? I ,013 1.18 rl.02 tl.08 1.18 ?1.02 t1.08 1 . I8 V 0 . 9 4 t l .02 * I .OQ I .20 ?I 1 22 1.22 1 .23 1 .26 1.27 I .28 .a2 1 I .32 1.32 1.37 A-95 X1 HISTOGRAna Range. 0- 4% Increnenr e.l0% KEROGEN DEStRIDTICh Anorpnous : 45 2 Exinire , li f - .. Vitrinire ; 35 i 20 X lnertlnire I Beck Fluor 81 tumen toke , : : High Sma:l rr ' AROCO BLACKBURN FARflS RRUS No. , 1221 ID : CTGS. 25 7 I 7955.0 Ft 2424.7 fl I N.D. DEPTH I INSUFFICIENT SAflPLE RATERIAL MEAN 0 0 0 0.0 ,...,.... ,.,. ,,,,, 2:0 3t0 ’ VJTRINITE REFLECTANCE IRANDDR X1 1 .a HISTOGRAP(, Range: 0- 4% Increment2 0.10% 4.0 ORDERED REFLECTANCE VALUES, KEROGEN DESCRIPTION 0 X Amorphous I Exlnite I 0 x Vltrinite 8 0 X Inerllnite I 0 X Erin Fluor B I rumen Cohe I I I None None None a P I’ AROCO BLACKBURN FARflS RRUS No. I 1222 ID I CTCS. DEPTH I I 8045.0 F1 2452.I M % = Ro MATURITY SI VALUES nEAN STD DEV PEDIAN RODE ’ 42 I I 1.12 I 0.07 t 1.13 1.15 HISlOGRAP(~ VITRINITE REFLECTANCE IRANDOR X I ORDERED REFLECTANCE VALUES, 0.84 t1.04 ?1.10 t1.16 t1.20 0.87 21.05 tI.11 t1.16 51.20 0.8Q tI.06 tl.11 t1.16 tl.21 0.00 tl.06 $1.12 t1.16 t1.22 80.06 ?1.07 t1.13 t1.17 t1.23 t0.90 tl.08 t1.13 t1.18 t1.25 t0.90 t1.09 ti.15 tl.18 1.27 tl.OO $1.09 t 1 . 1 5 xI.19 1.27 t1.01 ?l.BQ ?1.15 ?1.10 1.28 t1.03 tl.10 t1.16 ?1.19 1.32 A-96 Renget e- 4% Increment, F.10X KEROGEN DESCRIFTION 45 X Amorphous t Exlnite I 5 X Vlrrlnlte 8 35 X 15 X Inertlnlre Exin Fluor Bitumen Core , I : ned lr None AnOCO BLACKBURN FARMS 25 T RRUS NO. t 1226 ID 8 CTGS. DEPTH 8378.0 Ft 2657.3 n I f t = Ro nATURITY VALUES nEAN STD DEV nEDIAN MODE 4:0 VITRINITE REFLECTANCEiRANDOtl X ) ORDERED REFLECTANCE VALUES, 1.20 0.11 I .21 1.25 2 t I 8 HIS TO CRAM^ Range) 0- 4X Increment, 0.10X KEROGEN DESCRITION Amorphous I 50 X Exlnlre I tr X Vltrlnlre t 40 X Inertlnlte I 10 x 0.88 tl.10 t1.20 t1.28 t1.37 0.84 t1.14 t1.21 r1.28 ~ 1 . 3 8 t1.08 51.14 t1.21 11.28 1.40 51.01 t 1 . 1 551.21 *1.2e 1.42 21.02 51.17 t1.22 t1.32 1.43 f1.03 t1.18 t1.22 t1.33 1.43 51.06 t1.18 51.22 t1.33 1.43 t1.06 fl.18 ~ 1 . 2 3 ~ 1 . 3 4 1.44 51.07 tl.20 t1.23 tl.36 1.47 51.08 tl.20 t1.25 tl.36 1.49 AMOCO 40 I Exln Fluor t Co he I 2 81 tumen BLACKBURN FARMS tr .~ RRUS NO. I 1227 ID I CTGS. DEPTH I I ._ ned None 85P5.0 = Ro MATURITY .-. .. VALUES I 15 REAN t 1.23 STD DEV I 0.04 nEDIAN v-. I .22nODE 1.25 HISTOCRAMa.. Range, P - 4X Increment, F.I0X t ~ , t VITRINITE REFLECTANCE (RANDOMXI ORDERED REFLECTANCE VALUES, 1.12 tl .25 1.44 t1.16 t1.26 1.47 tl.19 51.28 1.55 t1.20 fl.28 *I .20 *I .28 1.60 tl .20 fl.28 51.21 1.35 31.22 1.41 11.22 1.43 t1.24 1 . 4 3 A-97 Ft T5F2.3 ' M KEROGEN DESCRIFTION Amorphous I 20 X Exlnlre t tr X 60 X Vltrlnlre I t 20 X Inert lnlte Exln FluorI Lor 81 turnen : None to he : None 750 0 TABLE A.14 COMFOSITIDN OF S.UURCE ROCK EXTRACT AMOCO BLACKBURN FARMS Project NO. : EXTRACT SIADMEPNLTEI F I C A T I O N I RRUS ( F e e t D) E P T H I 0 : RRUSlB45lt3l.90714 SAT ARDH POLARC pcrotntage ppm ! 1219 1221 8 0 41 52 2 2 7920 7955 : : : 75807 9 2709- 9 0 8 0 1 0 - PO80 I 475 399 220 ' i 41.8 48.5 36.1 43.6 36.9 47.1 14.6 14.6 16.8 0 TABLE A.15 0 SUMMARY TABLE SHOVING SELECTED PARAMETERS OF OIL B A M F L E S AMOCO BLACKBURN FARMS P r o j e c t No. SAMPLE IDENTIFICATION RRUS 1219 1221 18 20 24 25 0E P T H 7750 7955 (Feet) : : : 7 57 89 02 -0 7 97 29 09 -0 8010- BOB0 : RRUS1845/M/B0714 i: E- X- T- R- -A -C -T I TOC iI 0.136 0.053 I 0.018 A-98 SATS 9b Pr I IPh / CI C : 1: 1 78 41.8 48.5 36.1 0 RCAPTII O S Phl Prl 0.40 0.40 001. .4.44927 0 1. 3. 14 1 0 1. 3. 49 1 1.25 1.12 ---- I. TABLE A.16 HEAVY HYDROCARBONS N O R M A L I Z E DTO 100% AMOCO BLACKBURN FARMS Project No. : RRUS1845lM180714 I RRUS S A M P LIED E N T I F I C A T I O N I D E P(TFHe e t ) : 1217 9750 1221 7955 8045 1222 : : : 75807 -920 : 7920- 7990 I 8 0 1 0 - 8080 I NORMALIZED n-ALKANES C-15 C-16 C-17 C-18 C-19 C-20 C-21 0 . 6 03 . 8 01 0 . 1 01 0 . 5 0 8.40 2.60 1 0 . 5 0 16.10 11.90 8 . 4 0 3 . 2 0 11.60 1 5 . 4 0 12.20 10.40 5 . 7 07 . 5 0 6 . 3 0 7.20 7.60 8.10 I RRUS 1219 1221 1222 RRUS D E P(TFHe e t ) 7750 7955 8045 : : : I I C-22 C-23 C-24 C-25 C-26 C-27 C-28 7 5 8 0 -7 9 2 01 2 . 4 01 1 . 8 07 . 6 05 . 7 03 . 0 02 . 9 02 . 1 0 7 9 2 0 -7 9 9 0 i 9 . 9 07 . 5 04 . 3 03 . 4 02 . 4 02 . 2 01 . 6 0 8 0 1 0 - 8 0 8 0 . .: 9 . 670. 640. 620. 810. 810. 610. 0 0 D E P(TFHe e t ) I I C-29 C-30 C-31 C-32 C-33 C-34 C-35 i 7750 1219 1221 7955 1 2 2820 4 5 : : : 75807920 I 7 9 2 0 -7 9 9 0 I 8010- 8 0 8 0 I 2 . 0 01 . 6 01 . 8 00 . 9 00 . 7 00 . 4 0 1 . 4 01 . 2 01 . 2 0 . 7 0 0 . 90 . 60 . 50 . 20 . 1 0 . 0.50 0.40 0.00 0.00 0.30 0.00 - RRUS D E P(TFHe e t ) 1 2 1797 5 0 1221 7955 1222 8045 : : : : I 7 5 8 07-9 2 0 : 7920- 7 9 9 0 : 8010- 8 0 8 0 I C-36 C-37 C-38 C-39 C-40 0.00 0.00 0.00 A-99 0.00 0.00 0.00 0:OO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 PR PH 4.00 6.50 7.50 3.60 4.60 5.10 0 0 4 0 0 AMOCO BLACKBURN FARMS I=I0W'rirtom/Totul 2400xPhytan/Total 3=Prittm~/wC-17 &Phytom/wC-18 &Prlctam/Phyt&Corbon Pr.f.Indu NORMALIZED DISTRIBUTION OF n-ALKANES A-100 BLACKBURN FARMS I SAMPLE: RRUS NO. 1219 7750 feet r SAMPLE: RRUS NO. 1221 GASCHROMATOGRAMS OF C16 -t SATURATE HYDROCARBONS A-101 0 0 0 BLACKBURN FARMS 0 ! SAMPLE: RRUS NO. 1222 0 P 8045 feet GAS CHROMATOGRAMS OF C16+ SATURATE HYDROCARBONS A-102 SUNRAY, I1 BRISCOE A-I03 0 6' 0 A-104 TABLE A.17 LITHOLOGIC DESCRIPTION SUNRAYMIDCONTINENT #1 BRISCOE 0- 730' 750- 880' 900-1.060' 1.080-1.180' 1,200-1,300' 1,320-1,390' 1,410-1,670' 1.690-1.785' 1,810-2,225' 2.250-2.315' 2,340-2,550' 2.580-2,615' 2.640-4.940' 4.970-5.035' 5,060-5.275' 5,300-5,395' 5,420-5.515' 5,540-5.575' 5,600-6.085' 6,110-7.585' 7,610-9.045' Claystone,reddish brown (some green) Lst. clasts abundant in part Sst..greenish. calc.cement,poorly sorted Claystone,reddish brown Slst.,It.brown Claystone. reddish brown Claystone,reddish brown. green Claystone.reddish brown (some purple) Claystone,reddish brown Anhydrite(increasing) Claystone,reddish brown (some purple) (some green) Anhydrite Claystone,green,purple Claystone,reddishbrown,anhydrite Claystone,green Claystone,reddish brown (some green) Anhydrite Mudstone, dark reddish brown Increasing anhydrite Mudstone. dark reddish brown Granite wash Mudstone, dark reddish brown (some green) Mudstone, dark reddish brown Granite wash abundant Mudstone, darkreddish brown (some green) Mudstone, dark reddish brown (some green) in part Granitewash,abundant Mudstone, dark reddish brown (some green) Granite wash Dark shale Dark shale increasing Some granite wash Some dark reddish brown mudstone Anhydrite - A-105 TABLE A.18 TOTAL ORGANIC CARBON DATA 0 SUNRAY 01 I R A J . BRISCOE P r o j e c t NO. : ~ R U 5 f 8 4 5 f M 1 8 0 7 1 4 SAMPLEIDENTIFICATION RRUS DEPTH (Feet) 1101 110 1419052 1103 860 11041490 11052005 : 1106 1107 1108 1109 1110 : : : : : 90-130 470-520 840- 8 8 0 1470-1510 1 9 9 0 -2 0 2 0 2268 2598 3018 3518 3923 : : 2250- 2285 2580- 2615 3000- 3035 3500- 3535 3920-3925 1111 4323 1 1 1 24 8 5 3 1113 5393 1114 5873 1115 6147 : : : : : 4 3 1 0 -4 3 3 5 4 8 5 0 -4 8 5 5 5390- 5395 5870- 5 8 7 5 6140- 6154 : : : DATA TOC# I 0.08 : : : : : : : : : : RRUS I 0.09 I 0.31 I 0.07 I 0.04 : I 0.23 I 0.35 0.06 0.20 I 0.12 I 0.05 : 0.06 : 0.09' DEPTH 1 116 1 117 1 118 1 119 1 120 6698 6983 7173 7313 1 121 122 123 1 124 1 125 7418 7473 7638 7838 8108 i; : 0.09 : 0.10 ; S A M P L E IDENTIFICATIO?~ 6508 1 1 2 68 2 7 3 1127 8498 1128 8663 1129 8903 1 1 3 09 0 1 0 A-106 : : : : : : : : ; ; : : : : : (Feet) DATA : TOCW : 6505- 6510 6680- 6715 6950- 7015 7120- 7225 7280-7345 0.12 0.36 0.25 0.27 0.28 7 4 0 0 -7 4 3 5 7420- 7 5 2 5 7605- 7 6 7 0 7820- 7 8 5 5 8090- 8 1 2 5 0.44 0.39 8240-8305 8480- 8515 8630- 8 6 9 5 8870- 8935 8 9 9 0 -9 0 3 0 0 0 0.48 0.41 1.66 : 0.70 : s.93 : 1.39 : 1.09 : 1.68 0 TABLE A.19 TOTAL ORGANIC CARBON DATA BRISCOE a1 ( B U N ) Project N o . : R R U S 1 8 4 5 1 M 1 8 0 7 1 4 , T ~ SAMPLEIDENTIFICATION RRUS DEPTH (Feet) : DATA I SAMPLEIDENTIFICATION : TDCY RRUS DEPTH (Feet) 3321 3322 3301 3302 3303 6145 6680 7160 7425 7560 : 0.16 : 0.28 : 0.34 : 0.50 : 0.36 : 331 1 8500 : 3312 3313 3314 3315 8550 : 1.0% 3323 3304 3305 3306 3307 7900 8100 8200 8250 8300 : 0.36 : 0.65 3316 3317 3324 3325 3318 8850 3308 3309 3310 8350 8370 3319 3320 . I. : 0.73 : 0.50 I : 1.27 : 0.59 : 0.36 : 0.79 I .I , NON RR(US) DATA A-107 DATA : TUCK : 1.11 8600 8650 8700 : 2.30 8750 8800 8900 8950 : : : : : 9000 9050 : 1.25 : 0.73 : 0.52 : 0.91 3.22 0.70 0.95 1 .01 0.80 TABLE A.XI ROCK-EVAL PYROLYSIS RAW DATA SUNRAY P i I R A J . BRISCOE Projeot No. : R R U S 1 8 4 5 1 M l 8 0 7 l 4 SAMPLE IDENTIFICATION RRUS DEPTH (Feet) I I I I 0 DATA t S l , S 2 , 9 3 m g l p m o f roc&. T m a x s1 s2 Tmax 8 2B8/l38l3( S l + S Z ) I I 1103 1107 1117 1121 1123 860 2598 6698 7418 7638 : : 7838 : : : 1124 1125 1126 1128 1129 8273 8663 8903 : : : : : 1130 9010 : 8108 8402580668074007605- deg C ) 0.660 0.380 0.190 0.250 0.300 0.490 0.340 0.250 0.180 0.200 1.347 1.118 0.760 1.389 1.500 0.130 2.190 0.340 0.480 0.550 0.100 0.180 0.120 1.300 12.167 2.833 0.160 3.438 0.172 0.179 418 446 458 447 459 8990- 9030 I 0.090 0.670 0.160 4.188 0.118 453 i I 0.420 1 . 1 ~ 3 0.083 --- I 0.060 2 6 1 5 I 0.020 6 7 1 5 I 0.040 7435 I 0.030 7 6 7 0 I 0.050 I 7820- 7855 I 0 . 0 1 0 8 0 9 0 - 8 1 2 5 I 0.160 8 2 4 0 - 8305 I 0 . 0 5 0 8630- 8695 0.100 8870- 8935 I 0.120 880 0.050 0.174 0.107 0.143 0.071 0.068 0.128 0 435 ----435 0 0 NOTE: A DASH INDICATES AN INDETERMINABLE VALVE. TABLE A.21 HYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL PYROLYSIS AND TOC DATA SUNRAY # l .. I R A J . BRISCOE Project No. : R R U S 1 8 4 5 l M 1 8 0 7 l 4 I SAMPLE IDENTIFICATION I I RRUS DEPTH (Feet) I I 1103 860 1107 2598 1117 6698 1121 7418 1 1 2 37 6 3 8 : : : : : 2615 6680- 6715 7 4 0 07 -4 3 5 7 6 0 5 -7 6 7 0 1124 7838 1125 8108 18122763 1 1 28 6 6 3 1129 8903 : 7 8 2 0 -7 8 5 5 : : 8090- : 8 284300-5 86308695 88708935 9 0 1 01 1 3 0 : 840- 880 I 2580- :9 0 3809 9 0 - 8125 I I I I I I 1 I ' i HYDROGEN INDEX (mg HClpm TOC) OXYGEN INDE' (mp C02lpm TOC) TOC (%) P 213 109 53 57 62 32 132 49 35 50 iI 40 24 11 17 30 15 1.39 1.68 0.41 1.66 0.70 P 1.09 10 1* A-I08 TABLE A.22 R O C K - E V A L PYROLYSIS R A W DATA BRISCOE # l (SUN) Projeot N o . : R R U S 1 8 4 5 1 M 1 8 0 7 / 4 SAMPLE IDENTIFICATION D E(PFTeHe t ) RRUB , I DATA 6600 7160 7425 7560 7900 3322 3301 3302 3303 3323 (51.52.63 mglgrn o f rook:, TTax d e g C ) I I S1 I 0.120 0.140 ~I I 52 0.200 I 0.190 : 0.060 I 8100 8200 3304 3305 3306 3307 3308 8250 3309 3310 "" 3311 3312 3313 i 1.100 1.100 0.282 0.400 1.090 1.310 1.170 0.275 0.360 0.080 0.180 0 . 3 110. 1 4 0 0 . 1 000, 3 500. 0 500. 4 1 2 0 . 1 3 0 0 . 2 7 0 0 .09.8207 6 I I 8370 8450 8500 I 0.060 I 0.250 8550 I I I 0.140 0.140 0.300 0 . 009.0709.01 1 4 00 .. 75 23 00 0.290 0.310 0.670 1.500 0.950 0.640 I 0650 8700 8750 3325 3318 3319 3320 --- I 0.080 821.53 S l t ( S l + S 2 ) T m a x 0.310 0.260 I 0 .00.061.094.044.403242460 ' 0.120 0 . 3 1l0. 1 0 0 8300 8350 8600 53 0.068 0.279 0.350 0.333 0.345 0.429 439 --------- 0.282 0.272 0.27 49 39 0.367 --- 0.236 0.367 0.222 0.325 0.736 0.193 0.326 1.047 ' 448 443 0 . 440406 0.321 0.326 0.311 0.309 449 439 440 444 0 . 1 300. 9 400. 1 308. 3 8416 0 I 0 . 1 100. 2 310. 0 000. 2 300. 3 2444 1 8800 1 I 8850 I 8900 8950 9000 9050 I 0 .03.9809 0 1.150 0.774 0.305 I 0. 01.131.0070.001.40740303 I 0.210 0 . 4 0 0 1.040 0 . 3 805. 3 4444 1 I 0 . 2 0 0 0 . 4 310. 0 900, 3 904. 3 1 74.4 1 0 . 6 010. 3 700. 9 1 0 0 .01.193.030.053.0 41344635 0 . 1 9 0 0.460 REPRESENT5 AN INDETERMINABLE VALUE NON RR(US) DATA A-109 1.505 0 . 3 0454 0 1 . 0 40 0. 4 40 2. 2 9 2 448 442 TABLE A.23 HYDROGEN AND OXYGEN INDICES F R O M ROCK-EVAL PYROLYSIS AND TOC DATA BRISCOE # I (SUN) 0 Pro9cot No. : R R U S 1 8 4 5 I U 1 8 0 7 l 4 SAMPLE IDENTIFICATION RRUS 3322 3301 3302 3303 3323 I : DEPTH (Feet) I 6680 7160 7425 7560 7900 8100 I I I I : e200 8250 8300 8350 3309 3310 331 1 3312 3313 ~~~ 3314 8370 8450 8500 8550 8600 OXYGENSNDEX TOC I I I I : tmg HClgm T O C ) tmg C 0 2 I g m I O C ) t%) ~~ Ill 76 80 IO0 22 0.28 0.34 0.50 0.36 0.36 -2 9 42 62 28 46 68 151 228 67 146 0 .65 0.73 0.50 1.27 0.59 25 67 26 30 29 219 91 135 91 28 0.36 0.79 1.11 1.04 181 0.52 0.91 3.22 2.30 3316 3317 3324 3325 3318 3319 3320 8900 8950 9000 9050 I I I I I I 25 25 43 47 48 88 21 32 59 NON RR(US) DATA A-110 110 0.70 28 150 109 114 12s 83 149 ~ 0 393 324 218 364 325 I 8650 8700 8750 8800 8850 33is HYDROGEN INDEX I 0 .95 1.01 0.80 1.25 0.73 0 0 TABLE A.24 VISUAL KEROGEN ANALYSIS- REFLECTED LIGHT IRA J . BRISCOE SUNRAY U l Projeet SAMPLEIDENTIFICATION No. I I REFLECT,KEROGENCHARACTERISTICS I : RRUS DEPTH (Feet) : RRU5t845IMI807l4 Ro Am% E%% VitS IntrtK F l u o r 03.05 7 0.73 I I ---0.99 40 tr tr % I 1103 860 1107 2598 1117 6698 1123 7638 8108 1125 : : 840880 2580- 2 6 1 5 6680- 6715 76057670 8 0 9 08 -1 2 5 I 1.00 95 35 10 1 1 2862 7 3 1120 8663 1 1 3900 1 0 : : : 8 2 4 08-3 0 5 I 8630- 0 6 9 5 : 8 9 9 09 -0 3 0 I 1.06 1.14 1.14 SO 35 50 : : : TOC I : I A-Ill 0 65 3525 tr 0 2 54 0 5 35 50 0 20 30 t r 3 53 0 tr 23 00 5 5 None None fled 'k 0 . 31 0.35 0 . 36 None 0.48 Pled 1.66 fled 0.70 1.39 1.68 Low Low SUNRAY St IRA .I. * ERISCOE 25 1 RRUS No. ID 1103 I CTGS. I DEPTH L = L VALUES RO Fr 800.0 243.8 I I n ~ATURITY 3 I VEIN : nEDIAN nDDE : STD DEV 0 0.57 0.00 0.57 0.55 8 0 HISTDGRAII: Range: 0- 4 % Increment, 0 . 1 0 ~ ORDERED REFLECTANCE VALUES. 20.56 f0.57 f0.57 0.83 I .OO 1.08 1 .0E 1.I0 1.1: 1.14 KEROGElv DESCRIP710N 30 X Amorphous : Exinire 3 0 X Vitrinite ; 65 X Inerrinite : 5 X I .20 1.23 1.28 1.31 Back Fluor, I Bitumen COhe SUNRAY SI ID ':1 7 : CTGS. DEPTrl nEAN STD DEV nEDIAN nDDi : : 1107 2432.5 741.4 0 96 8.87 0.07 0 97 0 Q8 0.Qi I .Ea 1.81 1.16 1.01 LE5 1.18 1.18 1 P7 0.73 0.07 0,74 0.75 I I I I KEROGEN DESCRlFTlON 40 % Amorphous I Exinire : lr X Vllrinlte I 25 X Inert inlte I 35 x Fluor Birumen : Cole : Back 1 II 1 .I2 1 .I3 A-I12 Ft n 19 I HISTOGRAlI: Range: 0- 4 X Increment: 0 . 1 0 % 0 81 a = Ro nATURITY VALUES ORDERED REFLECTANCE VALUES: ~ z POSSIBLY REUDRKED OR OXIDIZED? 0 0.0 f 0 . 5780 . 7 4 f 0 .7 60 2.0 7 .48 3 f 0 .L 60 4 .07.68 4 1 0 . 6L70 . 7 7 L0.68 70.7R . . 2 0 . 6 8 70.81 v 0 . 7 2 70 83 f 0 . 7 3 7a 85 L 0 . 7 3 70.85 L0.74 0.W 1 None tr Small IRA J . BRISCOE RRUS N O . i! I 0 I None lr rr P SUNRAY SI I R A J . BRISCOE RRUS No. ID I 1117 : CTCS. DEPTH 6847.5 Ft 2087.I n I I 0j ... !ln,n,n, ,.,, 0.0 1.0 ' ,,, ' 2.0 ale ' I HISTOGRAfl: Ranae; 0- 4% VITRINITE REFLECTANCE I R ~ N ~ O f% lI ORDERED REFLECTANCE VALUES: KEROGEN DESCRIPTION 85 X Amorpnous Exinite r lr X Vltrinlte : tr % Inertlnlte I 5 X 0.41 0.47 0.61 8.83 1.26 Back Fluor : : Bitumen Coke SUNRAY -1 I fled lr None IRA 1. BRISCOE RRUS No. , 1123 ID I CTGS. DEPTH 8 t f 7730.0 Ft 2356.I n = Ro flATURITY VALUES : 31 flEAN STD DEV nEDIAN n0DE - I 0.88 0.07 3 0.Q 8 .. : 0.85 ! HISTOGRAfl: VITRINITE REFLECTANCE IRANDOn ORDERED REFLECTANCE VALUES. 0.74 *0 QZ 1100 - - X. I. . ta . - 1. 0.76 f0 82 VI .E2 VI I01.18 ~ " 0.78 f0.85 V1.03 f l . 1 1 f0.88 f0 85 * I E3 :I . I 1 f0.89 I0 06 fl.03 1 14 X0 88 r E . 0 6 f1.06 1.15 fO Q0 w0.97 f : E6 1 .I6 f0 81 X0 87 f l 07 I 16 V0.81 f0.88 81.08 1 . 1 6 I 16 f0.01 ~ 1 . 0 r! e 10 . 17 . 1.18 I 21 1.23 1.24 I .26 1.27 I.I7 I 32 A-113 XI KEROGEN DESCRIPTION Amorphous : 35 X A Ektnile -~.... . - Vlrrlnlle Inertinlte Back Fluor 8 ;tmen Cohe I " I I t ! r 40 X 25 X None tr tr 25 - RRUS NO. ID I125 3 ClGS. I DEPTH 8107.5 F T 2471.2 tl I I = Ro HATURTTY I VALUES I 35 nEAN STD DEV I 0.11 REDIAN nODE I 0.Q8 I 0.Q5 I .OO 0 HISTOGRAt?t Range: 0- 4 x Increment, 0 . 1 8 ~ ORDERfLD REFLECTANCE VALES 0.67 0.82 T0.61 * I .a2 fl I4 0.70 ~ 0 . ~t0.61 4 ?I .03 T I ,15 0.72 ~ 0 . ~ t 05. w SI .04 tl . I5 0.74 T0.85 f0 03 f l .05 TI. 16 0.75 t0 86 t0.94 tl .06 fl .17 0.77 t0.87 W0.85 t ;,07 T 1 . I8 0.80 r 0 . e ~m . 8 6 t ! .0Q I .20 0.80 ~ 0 . 8a0~67 t ’ .0Q 1.20 0.82 t0.GD ~ 2 . 9 8*’ I0 ! .23 0.82 r0.0: :I eB t: . l e 1 .23 KEROGEN DESCRIPTION 10 x Amorphous I Exlnile I 5 x 50 X Vllrinite : fnertinile : 35 X . SUNRAY a1 I R A 25 1 Back Fluor I B~rumen Coke I : ned ned Sma!l J . BRISCOE RRUS ID 8 No. : 1126 CTGS. DEPTH I : t P 8272.5 F T 2~21.5 n = Ro nATURITY a VALUES : nEAN STD DEV MEDIAN RODE : 29 I‘ 1.06 0.10 I .04 0.95 a : : HISTOCRAPI: Range: 0- 4 X Increment: 0.10% ORDERED REFLECTANCE VALUES: f0.92 f1.01 71.13 1.26 1 .33 t 0 . m t1.01 11.14 1.27 1 .35 T0.95 t1.02 t1.15 I . 2 Q 1 .36 T0.07 f1.02 f1.17 1.29 1 .37 t0.87 t1.04 TI 17 1.30 I .38 t 0 . w ~ 1 . 0 4f1.22 1.32 1 .38 T0.88 t1.06 T t . 2 2 1.32 1 38 t0.08 :\.eo f : 23 1.32 ! .38 f0.OQ f1.09 t1.24 1 33 I .38 10.99 t1.13 1.26 1.33 1 41 A-114 0 KEROGEN DESCRlPTlON 50 X Amorpnous : I 8 X Exinite 30 X Vilrinile I lnerr inite I 28 X Back Fluor B i 1m e n tone I : : Red Small None P SUNRAY 81 I R A J . BRISCOE DEPTH I I 8562.5 Fr 2'40.3 = Ro nATURlTY 50 VALUES 8 nEAN 1.14 STD DEV 0.09 BEDlAN r 1.16 nODE I 1.15 t I ORDERED REFLECTANCE VALUES: t0.81 f0.84 t0.84 t0.08 t1.02 t1.02 tl.02 r1.02 X1.04 31.04 KERXEh DESCR'PTION AmOrphDus 4 35 X Exlnlte I tr X Vltrlnlte : 30 x Iner?lnlre , 35 X Bock Fluor , Lor Bitumen : Smsl I I : .06 t1.12 tl.IB tl.23 tI.08 t1.13 tl.18 $1.24 tl.0B X1.14 t1.18 ryl.24 tl.0Q t1.15 tl.18 tl.24 tI.10 11.16 tl.1B t1.25 : ] . l a ry1.16 t 1 . 1 911.26 tI.10 11.17 f1.20 tl.27 tl.10 *1.17 rl.20 11.27 tI.11 f61.18 ::.20 11.28 tI.11 ?:.18 tl.22 tl.31 SUNRAY 1. Coke lr I IRA J . BRISCOE t = Ro tlATUR1-V VALUES nEAN STD DEV (IEDIAN nODE 50 : I .I4 0.10 1 .I5 1.15 8 1 : HISTDCRAtl~ VITRINITE REFLECTANCE (RANDOM ORDERED REFLECTANCE VALUES: tE.81 t084 t0.06 t0.97 t0.97 SI .OO tl.O1 t1.05 tl.06 tl.08 tl.11 tl.13 t1.13 tl.13 tl.15 tI.II '11.15 t1.12 t1.15 t1.12 11.17 t 1 . E t1.12 t1.18 tl.02 I : .I2 tI.lB t1.04 tl.12 t l . I B fl.18 tl.lB tl.18 r1.20 t1.20 fl.21 t'.21 tL23 tl.23 ?!.24 tI.24 tl.25 tl.26 fl.27 t1.27 tl.27 :I 28 11.28 71.29 f1.30 A-115 XI 4 Range, 0- : lncremenr : 0.10% KEROGEN DESCRIPTION 50 X Amorphous I I tr X Exinite Vlrrinlre I 30 X t 20 X Inert lnlre Bach Fluor I Low B i turnen Cohe , I tr ~r TABLE A.25 LIGHT VISUAL KEROGEN ANALYSIS-.REFLECTED BRISCOE 4tl ( S U N ) P r o j e c t No. : R R U S 1 8 4 5 l M 1 8 0 7 i 4 ~~ S A M P L E IDENTIFICATION URUS DEPTH (Feet) 3301 3302 3303 3304 3305 7160 7425 7560 8100 8200 3306 3307 3300 3309 3310 8250 8370 8450 3311 3312 3313 3314 3315 8500 8550 8600 8650 8700 3316 3317 3310 3319 3320 8750 8000 9000 i I I REFLECT. Ro % KEROGEN CHARACTERISTICS Am% Ex% 0 0 0 0 0 0 0 0 I I I I I I 1 .Ol 0.96 0.97 0.98 1.02 0 0 0 0 1.01 0 I 1.06 1.04 1.06 1.06 0 0 0 I I I I I I I I I I I 0 V i t Y Inert# F l u o r 0 0 0.34 0.50 0.36 0.65 0.73 None None None None None 0.50 1.27 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.08 0 1.14 1.11 0 0 0 0 0 0 1.11 1.11 1.07 1.10 1.11 0 0 0 0 0 0 0 0 0 0 % None None None None None 0 1.06 1.06 TOC 0 0 0 0 0 0 0 0 0 ~~ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 None None None None None None None None None None 0.59 0.36 0.79 1.ll 1 .0 4 2.30 0.52 0.91 3.22 0.70 0.8 0 1.25 0.73 NON RR(US) DATA I' A-116 VlTRlNlTE REFLECTANCE DATA SUMMARY NO.l BRISCOE 2 2 L -c W SAMPLE a @ Y - POINTS READ ._ COWtlTS 7160 90 7425 97 7560 81 8100 93 Organic material scattered with mixed populations. Some material may be cave. Mineral matter abundant. 0200 94 Shift of Ro range due tointroduction of less mature material, which may be cave. Mineral matter still present. a250 114 No significant change. a300 101 Rp profile 0350 90 0 P * J. L. Martinez Tucumcari Dasin -I broken- in abundant material Organic up small pieces. matter, present. Some mineral Slight shift in range may be attributed to influx of less mature organic material, which may be cave. c U similar tot h a t cstahllshed at 7560. R, Profile similar to that of sample R250. VlTRlNlTE REFLECTANCE DATA SUMMARY z- NO.l BRfSCOE - Tucumcari Basin J. L. Martinez 0 m n @ 4 D ? c. c. SAMPLE COYENTS POINTS READ 8370 94 Mean R, and standard deviationindiis cate that the material present similar to that recorded at 7425. 8450 77 Ro Profile reverts back to that of sample 8 3 0 0 . esoo 95 Sample appears to have less mixed assemblage than previous samples. Material shows one distinct peak. esso 92 mean slightly higher due 9 f ux of more mature material. other significant change. 8660 102 RO range wide, scattered material with mixed populations. Some material may becave. e650 100 Ro profile similar to that of sample 8370. e700 103 Ro range is wide due to mixed VOVUlatlons in sample. R750 102 m c 0 to inNo VtTRtNtTE REFLECTANCE DATA SUMMARY z NO.l BRISCOE - Tucumcari Basin 0 a n c 100 @ SIIMPLE z J . L. Martinez POINTS R€AO COUWWTS Ro profile reverts to that of 8800 sample 8500. Y U 14 P 2 8950 Ro material less than previous samples. 9000 84 Sample ha5 less mixed assemblage of material. 9050 87 Slight shift in Ro mean due to influx of less mature material. No other significant change. BRISCDE - 1 ' [SUN1 No. RRUS ID : DEPTH I 3 E 3-81 CTCS. I 7"60.0 Ft 2'82.4 n Ro nAlURI7Y VALUES 30 I nEAN STD DEV IlEDlAN X nODE : I .01 0.07 I .OO 0.Q5 HISTOGRAti~ VITRINITE REFLECTANCE [RANDO? Range. 0- 4 % Increment: 0 . 1 0 % x1 NON RR(US) DATA BRISCOE # I RRUS No. ID I I 3332 CTGS. DEPTH 8 7415.0 Ft I 22'3. I n * = Ro MATURITY VALUES a nEAN STD DEV MECIAN nODE .0 VITRIKITE REFLECTANCE [RAkDOn % I 31 : : , L 0.Q6 0.08 0.95 1.05 HISTOGRAM: Range: 0- 4 % Increment: 0 . 1 0 % BRISCOE a I RRUS ID I NO. 8 3303 ClGS. DEPTH : , 7560.0 Ft 23~4.3n * = Ro I l A l U R I T Y a VALUES nEAN STD DEV nEDIAN nODE VITRINITE REFLECTANCE fRAhDD!' X 1 A-120 e I I : 8 32 0.97 0.09 0.W I .05 HISlDGRAn: Range, 0- 4 % Incremenl: 0.10% BRISCOE L 1 DEPTH I t ? = Ro MATUR'Tr L VALUES VITRINITE REFLECTANCE IRAhDOtl x1 29 : nEAN STD DEV MEDIAN RODE .0 8'00.0 F I 2,168 9 n I : 1 : 0 98 0.09 0.97 0.95 HISTOGRAM: Range: 0- 4 % Increment: 0.10% BRISCOE . I 25 RRUS No. . 3305 ID : CTGS. N IJ DEPTH : : 8203.0 F I 2400.4 tl := Ro nATURITY n VALUES REAF; STD DEV MEDIAN MOEE VITRINITE REFLECTANCE I R A N D X X 1 21 I : : 8 I .02 0.11 0.89 0.Q5 HISTOCRAI1: Range: 0- 4% Increment: 0.10% BRISCOE r l RRUS No. . 3306 ID : CTGS. DEPTH 8250 0 : n T = RO nATuRnY VALUES MEAN STD DEV nED1AN nODE VITRINITE REFLECTANCE IRANDO!? A-121 %I 2514.6 : : ; I Increme: 31 I .01 0 . I0 I .OO 0.95 FI tl 0 BRISCOE - 1 RRUS No. ID I a 3307 ClCS. t DEPlH 3 t 850E.0 F I 2f29.8 n Ro IlATURITY L E L VALUES REAN 1 STD DEV : IlED1A.N RODE : 0 33 : 1.06 0.11 I .06 I .05 HISTOGRAR: Range: 0- 4 % Increment, 0 . 1 0 ~ VIlRINiTE REFLECTAhCE IRANDOR X 1 25 - BRISCOE LI DEPTH P l5 0 I 8330.0 I 2515.1 Ft R n VALUES v 26 : REAN DEV REDIAN RODE 570 : : 1.04 0.09 1.05 1 .05 HlSTOGRAIl: Range: 0- 4% Incremenl: e . ~ e % BRISCOE L I RRUS N o . ID I I DEPlH : t L 3309 CTGS. VALUES : RE AN STD DEV REDIAN RODE 8370 0 F T 2551.2 R 39 I .E6 8 I 0.11 I .04 1.05 HISlDGRAIl: Range. E- 4% Increment, e . 1 0 ~ c ERISCOE * 1 RRUS No. : 3310 ID 4 CTCS. B P DEPTH I 3 l5 I = * VALUES 8.550.0 F I 2575.6 n Ro MATUR’TY 24 : nEAk STD DEV REDIAN MODE : 8 I .E6 8.12 1.08 I .05 HISTOGRAM: Range: 0- 4 % Increment. 0.10% 25 - BRISCOE *1 RRUS No. . 3311 ID I CTGS. DEPTrl : : 8E00.0 2E00.8 Ft n t = Ro VATURITY VALUES MEA& STD DEV nEDlAN M03E 44 : I : : I .06 0 I I 1.05 0.95 HISTOGRAM: Range: 0- 4 % lncrernenl, 8 . 1 0 ~ E VITRlNlTE REFLEZTANCE IRAKDO? X1 RRUS No. . 3312 ID : CTGS DEPTH : : 8550.0 2696.0 ? = Ro MATURITY * VALUES I REAN SlD DEV REDIAN MODE I I 44 I ..06 0.11 I .E6 I .05 HISTOGRAn: VITRlNlTE REFLECTANCE IRAtiDOD A-123 X1 Range: 0- 4 X lncremenl: 0.102: FI fl 0 BRI SCOE I1 0 RRUS No. : 3313 ID I CTCS. DEPTH I E8;00.0 I 2li2l 8 = Ro MATUR'TY I VALUES 0 28 t PIE AN S?D DEV nEDlAN nODE FI .a n 2 I .08 0.14 : 1.08 I .25 HISTOtRAn: VITRINITE REFLECTANCE IRANDDn 25 P - BRISCOE Range: 0- 42 Increment, 8 . l ~ ~ XI c 11 2Ei 0 RRUS No ID : : 3314 ctgs. c l5 I VALUES 44 8 REAN STD DEV rE2IAN RODE 1 . 14 : : 0.13 1.15 1.15 HISlOGRAI1: Ranget 0- 4 % Increment, 0.18% VITRINI?E REFLEZTANCE IRANDOP X 1 BR1 SCDE rn 1 RRUS No. : 3315. ID : CTGS DEPTH : I V 8710.0 2651.8 = Ro nATURITY VALUES MEAN STD DEV MEDIAN X 8 : RODE 43 1.11 0.13 I .08 I .05 HISTDCRAI1; VITRINITE REFLECTANCE IRANDO:! % I A-I24 Range: 0- 4 % lncremenl: 0 . 1 0 % FI 25 - RRUS NO. I ID 2 CTGS. 3316 DEPTH 8750.0 F t 2K67.0 n 8 9 n I = Ro # VALUES nATUR'TY 42 : 1.11 PEAN SlD DEV I flEDlAN MODE : : 0.14 1.11 0.95 HISTOGRAn: Ronge: 0- 4 x lncremenl: 8 . 1 0 % 25 RRUS No ID : CTGS 3317 DEPTH I I n 1 f = Ro a ~ a 0 . 0 F~ 2~82.2 n MATURITY 47 VALUES : HISTOGRAPI: V I T R I N I - ER E F L E E T A K E lRAhDOI1 % I Range: 0- 4 2 Incremenl, 8 . 1 0 % e 25 RRUS ID : N U N O . I 3318 CTGS. DEPTH : I f !1 = Ro PATURITY VALUES t REAhr 510 DEV nEDIAN noni 8950.0 F I 2728.0 n : : 24 I .07 0.12 I .02 1 .05 HISTOGRAII: 0 0.0 .0 V I T R I N I T ER E F L E t T A N t EI R A N D O 3 N O N RR(US) DATA A-I25 XI Ronge. 0- 4% Increment: 0.10% 0 0 0 BRISCOE * I ISUNI 25 RRUS No. N ID 2 I DEPTH : I T 3319 CTGS. 0000.0 2743.2 F1 n = Ro IlATURITY ' VALUES : 34 MEAN 513 DEV PIE31AN M03E : 1.10 0.13 I .87 I .85 I HISTOGRAM, Range, 0- 4 % Incremenr: 8 . 1 0 % BRISCOE * 1 ISUNI RRUS No. I 3?20 ID I CTGS. DEPTH . : I 9850.0 2758 4 T = Ro MATURITY * VALUES : MEAN STD DEV MEDIAN : PlODE : 24 1.11 0.12 I 1.11 1.85 HISTOCRAPI: V I T R I N I T E REFLECTANCE IRANDOPI N O N RR(US) DATA A-126 XI Range, 0- 4 % Increment, 8 . 1 0 % FI M 0 - Tucumcari Basin BRISCOE NO.1 z v , FV ='", sz *VI a c in W3 g1 0 : 3 n h o a w n n m sw b 6145 6680 7160 7425 7560 7900 8100 8200 8250 8300 8350 - n a a m P.C n S n o n x a mly n n m *R s *m T 1 T B P P P s S+ SS+ P T " " T ." S+ " " T T T "2n ,. Type of Organic Platter ' " P. BurbrtdRe TIIEWAL ALTERATION INDEX (TAI) F e r m a Undal l Maturation Increases- TAI w- c. c2.0 2.0 2.3 2.5 3.0 3.5 3.2 3.7 4.0 5.0 -3 -2 1 W 1 T T z ,j, o w h-cm * P D 1 0 0 -I y" VISUAL KEROGEN DATA SUKMRT m 64 Structured Nnnstructured structured Nonstructured Stmrtured Nonstructured Structured Nonstrurtured Structured Nonstructured 36 47 53 60 40 37 63 51 49 Structured Nonstructured 61 39 structurd Nonstructured 64 36 structured Nonstructured 49 51 67 Structured Nonstructured 33 Structured Yonstructurej Structured Nonstructured * M ~ , r l o e R-Rrarktsh t - T e r r e n t r l a l 70 30 61 I9 --- ------ I O i l and Cas Generation -- --- --- -- - -- -- - -- --- --- 1 - 3 0 1 D r y Cas O n l y 6 11 13 - - 9 -- -- 3918 14 -4 -- 245 1121 -4 -- 241 1 -- -- 122 2816 -- - 9 8 - 15 8 - 1 5 - 4 14 18 -- 73 1 6- 22 81 10 31 7 -- -- '13 I4 4 14 17 - -- - 13-5 1-1 28- 3.2 3.2-3.7 3.2+5.0 3.2 3.95.0 3.2 3 5 6 I - 3.2-3.5 5 9 7 21 - 3.5M.0 3.5 15 19 4.0-5.0 8 3.2-3.5 5 26 5 11 II 5 .95.0 - IS- . 3312-3.5 15 15 6 9 12 17 1 1 0 1 5 - 9 6 2 4 - 14 3 2 4 5 3 4 11 1 10 14 5 7 4 5 - 7 **A=Ahundant P - P r r w n t Pl-Moclrrate S m S u f f l r t e n t T - 33 1 2 - - 19 13 - 3.2-3.7 3.2+5.0 3.2-3.5 3.5 3.2-3.5 3.95.0 3.5 3.2-3.5+5.0 3.2-3.5 T R-Rnrren ~ ~ ~ ~ s r rn N U - Tucumcari Bnstn FF ; $5 Z O * B W L s Em 0 I= < V I-01 -0 OII J" 6 mo J J n m v) D W Y W :Eig m n 0 z J"" n t m: z nImm ALTERATION 1 * Type of Organic Platter n n F e r +- :: T H S 8430 T P n 8500 T 8550 T 8600 T 8650 8700 8750 P P T T T 8800 f 8850 T 8900 n T P n " " s a nodal l Uaturation Increanes- TAI 2.0 -2.0 2.3 2.5 3.0 3.5 3.2 3.7 5.0 4.0 -I Y 1 W m Structured Nonstrurtured Structured Nonstructured . Structured Non6tructured Structured Nonntrurtured Structured Nonstructured Structured 46 Nonstructured structured tlonstructured Structured Nonstructured Structured Nonstructured 50 50 87 13 44 56 67 33 49 51 54 66 54 27 73 26 74 Structured 66 Nonstructured 34 Structured Nonstructured 90 lo * K t b r l n r R-Rrarkish T-Trrrestrlal c m H - v.i 8 r* r 8370 INDEX (TAI) C 011 and Gas Generation P 4 P. Burbrldge VISUAL KEROGEN DATA SUU?URY NO.1 BRISCOE ---- - -- - ----- ------ -- --- --- --- - - - - - -- -- -2 5 27 - -- -1 -- --- --- --- --- --- - - - - - 1 2 5 5 5 22 21 29 19 7 912 I8 1 - 6 13 3 22 12 8 7 11 3 12 3 11 18 6 13 11 15 6 13 18 6 I4 7 13 11 7 18 4 27 7 4 37 9 6 19 7 38 3 -3 35 35 - 18 17 I D r y Cas Only 14 7 5 19 3 3 R . 27 - 3.H5.0 3.5 3.0-3.5 3.5 3.5+5.0 3.2-3.5 3.2+5.0 3.2-3.7 14 6 3.2+5.0 3.5-3.7 13 4 3 3.2-3.5 3.5-4.0 7 13 3 3.H5.O 3.2-4.0 8 13 3 9 3.95.0 - - 3.5 2 0 3.545.0 3.5 3 1 9 ' 3.5+5.0 4 - .3.?-3.5 6 **A=hhundan,t P=Prr.sent H-Hrrclrrate S-SufCtclent T I1 6 16 4 - 7 17 3 19 2 12 - - 12 21 - - T 3.2+5.0 3.5 O-narren ~ ~ ~ ~ NO.l BRISCOE zul 0 Z w : Z 3 m I- c u) - Tucumcari R a s h VISUAL KEROGEN DATA SUIOVIRY ul TIIERFVIL ALTERATION INDEX (TAIL *C rl *VI O Y 3 BI.I m o 2; rl J J n a- 0 % 2 n " . Type of Organlc Matter 0 c-' -mal (2.0 d 0 -b4 9050 9100 T T P P P H M H Maturation Increases- 2.0 1 n W T bdal TAI n - cn -Hm* 2.3 2.5 3.0 3.5 3.2 3.7 5.0 4.0 L1 L 9000 P. Burbridge Structured Nonstructured 40 60 Structured Nonstructured 72 28 71 29 Structured Nonstructured ---- O i l and Cas Generation ---- --- --- -- -1 - 12 31 32 - 1 3 2 22 31 11 1 Dry Cas Only 8 25 I7 7 15 I -4 -5 3.2+5.0 15 3 6 2 3 6 14 9 - 2 4 3.2-3.5 3.2+5.0 3.2 3.2-3.5 3.2-3.5 0 0 A-I30 TU urn A-131 0 0 "1 0 (2. 1.0 2.3 2.8 3.0 3.2 S.b 3.7 4.0 8.0 (2. 2.0 2.3 2 .8 3.0 3 2 3.b 3.7 4.0 6.0 * TU MM so 24 1B P 12 e P <2. 2.0 2.3 2.8 3.0 3.2 3.8 3.7 4.0 8.0 "1 n (2. 2.0 2.3 2.8 3.0 3.2 3.8 3.7 4.0 b.0 NON RR(U.S.) DATA A-132 NO. 1 BRISCOE OStn~cturmdK o m p n Doto D Non-Structumd Koropm Doto 4.0 6.0 '<2. 2.0 2.3 2.6 3.0 3.2 3.6 3.7 4.0 8.0' ' ~ 2 2.0 . 2.3 la 3.0 3.2 sd 3.7 4.0 6.0' NON RR(U.S.) DATA A-133 0 -1 0 TU NON RR(U.S.) DATA c A-I34 TABLE A.28 C O M P O S I T I O N OF S O U R C E SUNRAY # I ROCK EXTRACT IRA J . B R I S C O E Projeot N o . : R R U S 1 8 4 5 t M I 8 0 7 I 4 I I EXTRACT S A M P L EI D E N T I F I C A T I O N I I ppm 8125 8990- 9 0 3 0 I 220 (D FERePReTUtHS) 1 1 2851 0 8 9010 1130 : : 8090- 5AT AROM POLARS ptroentage 456 22.8 4 0 .s 29.2 48.0 45. 6 13.3 TABLE A.29 SUMMARY TABLE SHOWING SELECTED PARAMETERS OF O I L S A M P L E S S U N R A Y X 1 IRA J . B R I S C O E Project No. S A M PILDEE N T I F I C A T I O N : RRVS1845tM1807I4 I E X T R ABCARTTAST 1 OS CP I D E PRTRHU S 1 1 2851 0 8 1 193001 0 : : 8 0 9 08 -1 20 5. 0 2 7 8 9 9900-3 0 : 0.013 , 2 2 .08. 5 1 A- 135 40.5 0.41 0.41 1.29 0.90 0.38 1.17 ---- TABLE A.30 0 H E A V Y H Y D R O C A R B O N S N O R M A L I Z E D TO 100% SUNRAY # l IRA J . B R I S C O E Projeot N o . : R R U S t 8 4 5 I n t 8 0 7 t 4 S A M P LIED E N T I F I C A T I O N RRUS D E P(TFHe e t ) I : 0 NORMALIZED n-ALKANES : C-15 C-16 C-17 C-18 C-19 c-20 c-21 I 0 . 3 03 . 3 07 . 8 07 . 6 07 . 1 09 . 3 01 1 . 3 0 1 . 04 0. 21 01 . 5 0 10.50 7 . 9 0 I 1125 1130 RRUS 1125 1130 8108 9010 : : 8 0 9 0 -8 1 2 5 8 9 9 09 -0 3 0 : : (Feet) I C-22 C-23 C-24 C-25 C-26 C-27 C-28 I I 8 0 9 0 -8 1 2 5 I 1 3 . 6 01 0 . 1 09 . 9 04 . 3 03 . 3 02 . 5 02 . 6 0 8 9 9 0 -9 0 3 0 : 1 0 . 5 0 1 0 . 0 0 8 . 3 05 . 2 0 4.00 DEPTH 8108 9010 I : 8.00 9.40 2 . 5 02 . 1 0 I I R RDVESP(TFHe e t ) 0 * C-29 C-30 C-31 C-32 C-33 C-34 C-35 ! l 1125 1130 8108 9010 : : 8090- 8125 : 89909030 : 2 . 2 01 . 9 01 . 4 0 . 9 0 . 5 0 . 3 0 1.80 1.30 1.00 0.80 0.00 0.00 0.00 0.00 PR PH 4.00 3.10 4.70 4.00 I R RDUESP(TFHe e t ) 1125 1130 8108 9010 : : 8090- 8125 8990- 9 0 3 0 r i C -c 3-c63-c73-c83- 94 0 i 0.00 : 0.00 0.00 0.00 A-I36 0.00 0.00 O.DO 0.00 0.00 0.00 R 1 .A-137 SAMPLE: MUS 8180 NO. 1125 SAMPLE: feet 9010 feet RRUS NO. 1130 GAS CHROMATOGRAMS OF C1S + SATURATE HYDROCARBONS A-138 NON RR(U.S.) DATA A-139 NON RR(U.S.)DATA A-I40 a== " NON RR(U.S.)DATA A-I41 10.1 BRlSCDE P7S-SUN 8 7 5 Z THERMAL Rt~5.9 NON RR(U.S.)DATA A-142 tc NON RR(U.S.)DATA A-I43 NON RR(U.S.)DATA A-144 PURETEX, I1 CHAPPELRANCH A-145 A-146 3500 TMLE A.31 T O T A L O R G A N I C C A R B O N DATA PURETEX CHAPPEL RANCH (SUN) Project No. : R ~ u S 1 e 4 5 l M 1 . 9 0 7 1 4 S A M P L EI D E N T I F I C A T Z O N FiR’JS D E(PFTeHe t ) 3015 3001 3016 3002 3017 3400 3003 3004 3005 3006 3600 3700 4000 4100 4200 : DATA S A M PI LD E N T I F I C A T I O M : TOC% RRUS : 0.12 3oc7 3008 3009 30!0 : 0.15 : 0.13 : 0.13 : 0.06 : 0.07 : 0.02 : 0.20 : 0.6? D E(PFTeHe t ) P>.Th : : 301 1 4300 4900 4500 4600 9700 3012 3013 3O! 4 4eoo 4900 4930 : : NON RR(US) DATA A-147 T9C.h 1 23 : 0 49 : 0.40 : 0.61 : 0.58 . 0 . 1 7 0.28 0.26 TABLE 4.32 R O C K - E V AP: Y R O L Y S I S RAW D A T A P U R E T EC X H A P P ERL A N C H Project Yo - ' (SUN) RRVSlaq5/MI807/4 ! ! , 3500 3700 3001 3002 3005 3006 3007 *. 0.170 0.820 0.590 1.2t0 0.468 0 090 0.220 0 . 1 7 0 0.570 0.221 0.260 0.120 0.100 0.490 0.770 0.740 0.800 0.260 I 1.050 4100 3008 3009 30: 0 3011 3013 4200 4300 ! 4500 46@C I ! ! 4700 ! 4500 301 4 49CO : 4930 I 00..134100 NON RR(US) DATA 0.350 0.210 0.612 0.346 0.278 0.347 0 .06.055.032 85 5 0.550 0.382 0.323 3;8 437 354 0 , 7 5 0 0.311 354 0,770 0.413 440 252 TABLE A.33 ~ H Y D R O C E IA4 N D @XYCEN I N U I C EFS R O M R O C K - E V A LP Y R O L Y S I SA N DT O CD A T A P U R E T EC X H k P P ERL A N C H (SUN) P r o j e c t N ? . : RRUS1845I!t180714 S A M P L IED E X T I F I C A T I O G RRUS 3001 3002 (Feet: E,EPTH . I HYDR3CEN INDEX tmo H C l p T O C ) ! 35131) _ ~ . . 393 3ccs 3700 4:OC 631 145 3006 3007 4200 4300 41 3008 3009 3010 44oc 3011 35 142 BO 4700 3013 4900 1301 19 4 4930 68 4500 4600 60 75 , I NON RR(US) DATA A-148 O X Y G E N INIjEX TOC tmp CO2Jgm T O C ) ( 'Is ) 840 808 425 102 71 0 . 1 5 0.13 0.2c 0.63 1 23 157 0 40 0.40 i e$ 131 112 196 0.58 288 . 0.2t 0.61 o.ze TABLE A.31 VXBUAL KEROGEN ANALYSIS - REFLECTED LIGHT PURETEX CHAPPEL RANCH (SUN) Project N o . : R R V S 1 8 4 5 1 M t 8 0 7 l 4 S A M P LIED E N T I F I C A T I O N RRUS (Feet) DEPTH I REFLECT. i Ro % KERDGEN CHARACTERISTICS Am% EVRiUItnUe r t % TOC Fl.ucr PI; 1 3001 3002 3003 3004 3005 I 3700 I 4000 I I I 0.69 0.65 0.83 0.73 0.63 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N5r.e None None Ncne Ncne Plzr,e YGne 0 0 0 G 15 0.13 0 07 0.02 0.2C 1 3006 3007 3008 3009 3010 4200 4300 4400 4500 4600 0.70 0.71 0.76 0.74 0.77 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 I 0.72 0.76 0.75 0 I 0.80 0 0 0 0 0 0 I : I I I ?‘?ne f:one Fone 1 3011 3012 3013 3014 4700 4800 4900 4930 I : NON RR(US) DATA A-149 0 63 1.23 G 45 0 91 0 61 h’one :inr.e 0 5P. Vcne 0 17 0 . 2 8 h’one 0.26 VITRINITE REFLECTANCE DATA SUMMARY No.? CIV\PPEL RANCIl 20 z - e Basin J. L. Martinez POINTS COMMZUTL RE A 0 c v) 3400 ” W 3500 14 3600 ” 3700 13 3800 ” 3900 20 Organic material very marginal. Mixed populations. Ro mean may not bevalid due to amount. 4000 52 5 range narrow due to amount and maturity of material. Organic debris and large gritty sand grains present. 4100 e3 It, range is wide w i t h mired populatigns. Some of the more mature organic material maybe cave, and appears to be thermally. altered. Mineral matter is abundant. P 4 P 8 SAMPLE - Tucumcari 3 Barren. Insufficient data for valid Ro mean. Barren. Insufficient data forvalid Ro mean. Barren. 3 e VlTRlNlTE REFLECTANCE DATA SUMMARY z NO.l CHAPPEL RANCII - TucumcariBasin J. L. Martinez 0 51 W A SAMPLE POINTS REA0 COMMENTS - c 4200 86 4300 07 4400 74 cc W D -1 D - Ro p r o f i l e is mimilar t o t h a t e s t a b l i s h e d a t 4000 w i t h an i n f l u x of more m a t u r e m a t e r i a l , appear making Ro range wider. Ro p r o f i l e shows no s i g n i f i c a n t changeotherthan a v e r y s l i g h t i n f l u x o f more mature organic material. profile r e v e r t s t o t h a t est a b l i s h e d a t 4000. Mineral matter s t i l l p r e s e n t . 4500 70 No s i g n i f i c a n t c h a n g e . 4600 94 No s i g n i f i c a n t chanse. 4700 63 S l i g h t c h a n g e i n lb may be a t m t r i b u t e d t o m a t e r i a-l which -.-,r v becave. V e t y s l i g h ti n f l u x of o x i d i z e d m a t e r i a l . 4999 ?2 Mean Ro and s t a n d a r d d e v i a t i o n i n d i c a t e t h a t t h e m a t e r i a l pres e n t is s i m i l a r t o t h a t recorded at 4500. VlfRlNlfE REFLECTANCE DATA SUMMARY ” 2 N 0 . 1 CHAPPEL RANCH - Tucumcari J . 1. Martinez Basin 0 - s SAMPLE POINTS COMMENTS at A 0 Mean Ro is higher due to slight influx of mote mature organic material. Organic debris is present. B c c 4930 3 eo No significant change in Ro profile. 3 J PURETEX CHAPPEL RANCH ISUNl 25 RRUS No. 3001 ID I CTGS. I N DEPTH 9 8 VALUES L 3500 0 Ft 1066.8 V 3 : I STD DEV nEDlAN I I 1 0.68 0.07 0.71 0.75 HISTOCRAn: 3.0 2.0 Range: 0- 4% Increment. 0.10% 4 0 VITRINITE REFLEClANCE IRANDO? % I PURETEX CHAPPEL RANCH ISUNI RRUS No. . 3102 ID C T G S . I nEAN DEV VEDIAN nODE S7C : : : : 0.65 0.07 0.68 0.65 HISTOGRAH; Range, 0- 4 X Increment: 0.102 4.0 VIlRINITE REFLECTAWE IRANDOV 25 - %I PURETEX CMAPPEL RAlvCH ISUlvl RRUS No. ID I : DEPTH ; 2 P I5j i 30e3 CltS. 3FB0.0 Ft 1188.7 v = Ro HATURITY s VALUES > 9 nEAN I 0.83 STD DEV I 0.09 nEDIAN 0.87 nODE I 0.85 HISTOGRAV: I 5L ;kn 0 0.0 1:0 8 . " ' , ' ' ' . , . ' 2.0 3.0 3.0 VITRINITE REFLECTANCE IRANDO IRANDO? NON RR(US) DATA A-153 I 4.0 XI Range: 0- 4 % Increment: 8.101. 0 PURETEX CHAPPEL RANCH lSUNl RRUS NO. ID : 0 3104 CTCS. I DEPTH t I 4700.0 F t 1218.2 1 = Ro tlATURlTY * VALUES 35 : nEAN I STD DEV I MEDIAN MODE rl 0 0.73 0.10 0.72 0.75 I I HISTOGRAfl: Range: 0- 4 % Incremenr: 0.10% VITRINITE REFLECTANCE'IRANDOrl X I c PURETEX CHAPPEL RANCH (SUN1 RRUS No. ID : : 3M05 CTGS. DEPTH I I 4100.0 Ft 1248.7 M t = Ro llATUR:TY * VALUES MEAN STD DEV MEDIAN n0DE 13 I I 0.63 0.13 I 8.66 : 0.75 I P HISTOGRArl, Ronge: 0- 4% Increment: 0.10% 0 VITRINITE REFLECTANCE IRANDOI1 X1 PURETEX CHAPPEL RANCH (SUN1 RRUS No. ID : 3P06 CTGS. DEPTH 4280.0 Ft I I : 1z~0.z n Ro HATURITY t D S VALUES : 47 0.70 0.13 0.71 0 85 HISTOGRAM: 0 VITRINITE REFLECTANCE IRANDON % I NON RR(US) DATA A-154 Range. 0- 4% Increment 0.10% PURETEX CHAPPEL RANCH ISUNI RRUS ND. : 3007 ID 2 CTCS. DEPTH I 9 P = RD MATURITY f l5 4300.0 F 1 1310.6 n m VALUES 47 I nEAN STD DEV MEDIAN MODE I : 0.71 0.I4 0.72 0.85 HJSTOGRAn; Range : 0- 4% Incremenr: 0.10% 0 VJTRJNJTE REFLECTANCE IRANDOnX 1 PURETEX CHAPPEL RANCH ISUNI 25 _1 RRUS ND. I 30w ID I CTGS. DEPTH : I = Ro nATURITY f VALUES VITRINITE REFLECTANCE IRAhD3n X 1 48 8 nEAN STD DEV MECIAN nODE 0 4430.0 F 1 1361.1 n : t 0.76 0.13 0.70 0.E5 HISTOGRAnt Ronge . 0- 4% Incremenr: 0.10% PURETEX CHAPPEL RANCH ISUNI RRUS ID I ND. : 3009 crts. DEPTt4 I : f = 1 VALUES RD nEAN STD DEV nEDIAN nODE 0 0.0 1.0 2.0 3.E VITRINIlE REFLECTANCE IRAhDOn X I NON RRWS) DATA A-155 4 E 4500.0 F I 1371.6 n MATURITY I f I I r 42 0.74 0.13 0.76 0.85 HISTOGRAn: Range: 0- 4% Incremenrz 0.10% 0 PURETEX CHAPPEL RANCHISUkl 25 7 NO. RRUS ID I 0 31310 CTCS. I 0 nEAN STD DEV nEDIAN nODE 1 : I I 0.77 0.14 0.79 0.85 HISTOCRAn: Rsnge, 0- 4% Incremenr. 0 . 1 0 % 0 PURETEX CHAPPEL RANCH (SUN1 25 7 RRUS N O . : 30: I ID I C T C S DEPTH : I f = Ro HATURITY a VALUES : DEV nEDIAN nODE STD ? 5 0 0.0 2.0 3.0 VITRINITE REFLEClANCE fRAND3N % I 4 0 3 : : c 31 I nEAN N 5 C 4700.0 F 1 1432.6 n 0.72 0.14 0.71 0.55 H15TOtRAf'l: Rsnge: 0- 4% Incremenr: 0.10% P PURETEX CHAPPEL RANCH ISUNI 25 _I RRUS No. ID I . DEPTH : : T = 30'2 CTGS. 48m0.0 F i 1463.8 n Ro tlA7URITY s VALUES IlEAN S7D DEV MEDIAN nODE I : : 43 0.76 0.13 4 0.76 : 0.85 HISTDGRAfl: VITRIhIT E REFLECTANCE IRANDOR X 1 NON R R ( U S ) DATA A-156 Range 0- 4% Incremenr: 0.10% P 25 - PURETEX CHAPPEL RANCH lSUNl RRUS ID : No. : 3313 CTGS. DEPTH : n VALUES 4800.0 Fr 1403.5 n 44 : MEAN STD DEV NEDIAN nODE I : I I 0.79 0.13 0.80 0.85 HISTOGRAM: VI'RINITE REFLECTANTE (RAND3fl XI Range: 0- 4 % .0 lncremenr: 0.10% PURETEX CHAPPEL RANCH lSuNl 25 RRUS No. : 3914 ID t CTGS. h' U DEPTH : : * 4530.0 Fr 1502.7 = Ro nATURlTY VALUES nEAN STD DEV PlEDIAN nODE 1. I , 49 0.88 0.12 I 0.81 I 0.75 HISTOGRAn: Range: 0- 4% VITR!NITE REFLECTANCE (RANDOn 1 1 NON RR(US) DATA A-157 fl Increment: 0 . 1 0 % CHAPPn RANCH L v1 Z a I- 3 a c m 35! 5: rtm O F ;$5 c c r n n m I n gg 0 %E @. * P Y * 0 VISUAL KEROGEN DATA SU"&RY s s arno - 3 o n3: % m** m%n m 2 ** ?!rl Type of Organic Matter 0 A C h." I- Structured Nonstructured 89 11 4200 T p s Structured Nonstructured 62 47 53 64 4300 T p s Structured Nonstructured 4400 T P s Structured Nonstructured T 4700 T 4800 4900 4930 T P P S S T T P *MMarineB-Brackish S r 2.0 I a m s 4600 c2.0 w rl s e m 2.3 a Modal l Maturation Increases2.5 3.0 3.2 3.5 TAI 3.47.0 5.0 r-1 P P B n T T THERMAL ALTERATION INDEX (TAI) 5 4100 4500 B u r b r i dPgaet Structured Nonstructured Structured Nonstructured Structured Nonstructured Structured Nonstructured Structured Nonstructured Structured Nonstructured TITerrestrial - 38 36 61 39 62 . 38 69 31 62 38 53 47 81 l7 , O i l and Gas Generation - -- - - - - -- -- - - - - - - -- - --- -- -4 1915 - - - 7 - - 8 - - 6 - - 10 4 - 16 - .. 7 - - 13 - - 4 -- -- 1 148 4 - 9 - - 4 - - 6 4 - 4 4 -- - 10 5 ?? 1 0 I Dry Gas Only - I 11 40 3.95.0 4 4 3 3.5-4.0 4 17 4.0-5.0 5 29 3.7 - 1 9 1 1 13 8 9 11 3.5t5.0 2 22 19 3.7-4.0 4 13 4 23 3.2+5.0 13 11 5 3.5-3.7 11 4 6 27 3.2+5.0 4 5 13 13 4.0-5.0 13 11 24 3.2-3.95.0 5 5 8 2 3.2 9 6 23 4.0-5.0 18 1 1 3 7 6 3.5 24 7 3 22 3.95.0 10 10 5 5 3.5-3.7 9 2 5 27 3.2-3.5+5.0 9 17 10 2 3.5-3.7 - - t- a i# - 17 **A=Abundant +Present+ModerateS-Sufficient 7 -3 - ??- . 19 3.2+5.3 3.2 T-TraceB-Barren ~ c oa, <2. 2.0 2 3 2 6 3.0 3.2 SA S.7 4.0 A0 4- <2. 2.0 A-I59 2.S 2.4 3.0 3 2 3.6 3.7 4.0 6.0 . FI CHAPPELRANCH No.1 BSlrvctumd Kerogen &to 0 Non-ftrvcfumd Kerogen Doto 47m . TU 4em c c P NON RR(U.S.) DATA c A-I60 N0.1 W P L i . W'O PB2-PCR 95C2 THERMAL GC RG1558 NON RR(U.S.) DATA A-I61 I' NON RR(U.S.) DATA A-162 NON RR(U.S.) DATA A-163 7 NON RR(U.S.) DATA A-I64 NO.1 CHAPPEL X S C E P B a ~ m ' TE TOTAL E X T R A C T R A I B26 NON RRWS.) DATA A-165 # NO. 1 CHAPPEL RANCH I) ....... ... SLIPLE RAir EILF, pa24600' R41626 TE Ir AREA '& K-PAMFFIN HYDf;3CARaONS 19.43 2.63 41.64~ 36.29 ISOi?GENOID HYDROCAR3ONS OT3CH RESOLVED C 5 C35 HYDROCARZClNS UI9RESCLVED CS - - C 3 5 HYDEOCAREONS m yE 4REA 3 KAW. AR?A '3 NC14 IP16 iJC15 NC16 IP18 iJC17 IP19 LC18 IP20 -NC19 I,?c 2 0 NC21 NC2 2 .10 NC 2 3 NC24 NC 25 NC26 NC 27 NC28 KC 29 NC30 NC31 K32 IJC33 1iC 3 4 5.85 5.00 14.18 3.57 3.42 2.51 2.15 1.41 1.17 .51 .90 .47 .30 1.30 3.42 2.44 5.55 4.38 6.90 4.13 7.26 7.62 7.17 6.47 NON RR(US) DATA A-166 ' I' STANOLIND. %1 FULLER A-I67 0 0 0 c c A-168 TABLE A.37 TOTAL ORGANIC CARBON DATA F U L L E R (I1 ( 6 U N ) P r o j e c t No. : RRUS1845In1807l4 SAMPLE IDENT!€!CATION RRUS DEPTH (Feet) 3101 3102 3103 5 9 5301 0 4 3105 5800 3114 31 1 5 3106 6 2 0301 1 6 6 2 5301 0 7 6050 6100 6000 : DATA : TOCSC : : : : : I I I I 1 SAMPLE SDENTIFICATIO~~ : DATA RRUS 0.13 I 6 33 100 8 0.09 I 3117 0 . 1 3 ' 3118 0.12 i 3109 0 . 1 2 I 3110 0.10 : 0.13 : 0.14 : 0.10 : 0.12 , i 3119 I 3111 I 3112 I 3113 1 3120 I I NON RR(US1 DATA A-169 DEPTH (Faat) : TOCY : 0.15 6350 6400 6450 6500 : 0.12 : 0.19 : 0.18 6550 6600 6650 6700 6750 : 0.13 : 0.18 : 0.21 : 0.13 : 0.21 : 0 17 TABLE A.38 R O C K - E V A L P Y R O L Y S I S RAW DATA FULLER t l (SUN) Project No. SAMPLE IDENTIFICATION I c) I DATA ( 5 1 , 5 2 , 8 3 m g l g m o f r o o k , m a x d e g I I I D( EF Pe Te Ht) RRUS : RRUS1845IM180714 51 5 2 / 5 3 91/(51+52) T m a a 53 52 I) 1 3101 3103 3105 3115 3116 5800 5900 6000 6100 3108 3118 3109 6550 3119 6400 6450 3112 6650 I 0 . 0 .7007 0 0.420 0.167 0.070 0.07 .7 001 . 009 9 0.240 0.480 0 .06.087,003 63 3 0 . 01 .5109 0 0.580 0.0 3 .2484 1 I 0.040 0.02 .7 00 1 . 00 2 . 68 6 7 I I 0 . 0 .9010.3905 0 0.137 I 010 .. 5162 66 900 I 0.760 0.450 02 .. 18 54 80 I 0 . 02 .5103 0 0 . 8 1 0 0 . 03 .4320 9 0.1 0 .9I0 16.50 10.1009 0 I * 0.500 0.500 0.450 __ __ __ --___ --_- ____ 0.391. --- i 0.409 0.283 0.628 I : 3120 I NON RR(US) 350 358 DATA 0.286 0.0 1 .80 20.8908 0 * 366 Ir TABLE A.39 H Y D R O G E N A N D O X Y G E N I N D I C E S FROM R O C K - E V A L P Y R O L Y S I S AND T O C D A T A FULLER # l (SUN) P r o f e e t N o . : RRUS/8451M1807l4 S A M P LIED E N T I F I C A T I O N RRUS I I H Y D R O G EINN D E X I DEPTH (Feet) I I OXYGEN (mg H C l g mT O C )( m gC O Z l g mT O C ) INDEX T UC I. (%I ! 3101 3103 3105 3115 31 16 3108 3118 3109 3119 3112 I 5800 S900 I I 6200 I I I 6450 6650 54 54 400 146 20 0.13 87 347 250 192 52 0.15 ! 3120 "_ 0.17 576 I I 165 R E P R E S E N T S AN I N D E T E R M I N A B L E V A L U E N O N RR(US) DATA A-170 0.10 0.13 323 546 567 446 710 0.13 0.12 0.13 633 611 1578 623 548 0.19 0.18 0.21 r r TABLE A.40 ~ ~ VISUAL KEROGEN ANALYSIS FULLER W l - P r o j e cN t o. SAMPLE IDENTIFICATION RRUC DEPTH (Feet : n RO (SUN) KEROGEN C H A R A C T ~ R I S T I C S Am% Ex% V i t ’ L I n a r tFs l u o r TOC % 0 0 0 0 0 0 0 0 0 0 None None None None None 0 . 1 3 U0.09 0 1 3 I? 0.12 b 0 . 12ke” 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 .05 1.05 1.05 1.07 0 0 0 None None None None 0. 1 4 r > , y 0.12&.”0 . 155+-0.18 1.05 1.05 1.04 0 0 0 0 0 0 0 0 0 0 0 0 None None 0.21 0.99 0.99 I .05 1.07 3106 3107 3108 3109 3110 6150 6250 6300 6450 6500 3111 3112 3113 6650 6700 1.04 1 . :- R E F L E C T E D LIGHT 0 0 0 0 0 5800 5850 5900 5950 6000 I ~~~ 0 0 0 0 0 3101 3102 3103 3104 3105 6600 ~~~ : RRUS1845lM180714 I REFLECT. > - ~~ .os NON RR(US1 DATA A-171 0 0.215?=.”- VlTRlNlTE REFLECTANCE DATA SUMMARY 2- - 87 NO.l FULLER - Tucumcari Baasin - J. L. Martinez Organicmaterialsmall,scattered pieces. 5800 0 D Largesandgrainspresent. 2 S l i g h t s h i f t i n 5 p r o f i l e may of less m a t u r e o r g a n i c m a t e r i a l . Amount of o r g a n i c m a t e r i a l h a s decreasedslightly. 5850 53 5900 38 Amount of o r g a n i c m a t e r i a l is moderate. Mean Ro andstandard d e v i a t i o n do n o t d i f f e r s i g n i f i c a n t l y from previoussamples. 5950 55 Ro r a n g e narrow. be a t t r i b u t e d to a n i n f l u x ? F U N test may be c a v e or second CycleO . r g a n i cd e b r i s present. 6000 6050 82 5 P r o f i l e is similar to that e s t a b l i s h e d a t SROO. w i t h a v e w s l i g h t i n f l u x of less mature organic material. No smwle residue l e f t a f t e r acid mgacrration. 1 VlTRlNlTE REFLECTANCE OATA SUMMARY ~ 0 . 1FULLER 20 a - Tucumcari Basin POIUTS RE AD SAMPLE J. L. Martinez COMMENTS m CI C in " 6150 67 6200 " 6250 53 Shift in 5 profile may be attributed to an inElux of less mature organic material. 6300 93 Ro profile reverts to that established at 6150 with mixed populations. " No sample residue left after acid maceration. 0 D -1 B No sample residue left after acid maceration. 6100 Y 6350 , 5499 - 6450 100 Ro profile indicates an influx of less mature orqanic material, with some mixed populations. Organic material excluded by No sample residue left after acid maceration. No sample residue left after acid maceration. Ro Profile similar to that cf s.lmf-lr 6300. Minrr.11 matter is VlTRlNlTE REFLECTANCE DATA SUMMARY NO.l 2' 0 W SAMPL€ - - Tucumcnri Basin FULLER ?lltNTS VAll v, 6500 82 0 6550 " F;P 96 COMMENTS No significant change. No sample residue left after acid maceration. Ro profile similar to that 6600 6650 96 L. Martinez - m CI I; J. of sample 6500. 100 No significant change. 6700 No significant change. 6750 No sample residue left after acid maceration. FULLER ISUNI st RRUS ID : . No. 3101 CTCS. nEAN STD DEv nEDlAN MODE : I .04 0.11 : I .05 1.15 HISTDCRAM: Range: 0- 4% Incremenr, 0 . 1 0 % FULLER (SUN1 st No. 3102 CTCS. RRUS ID DEPTh : : VALUES s 5850.0 1783.1 : . : n 31 I nEAN STD DEV VEDIAN MODE Ft 0.99 0.11 I .OO I .05 l4ISTOCRAn: VITRiNITE REFLECTANCE [RANDOM FULLER * I Range: 0- 4 % Incremenr: 0.10% XI (SUN1 RRUS ID I No. : DEPTH : I 1: STD DEV MEDIAN nODE VITRINITE REFLECTAKCE IRANDOM % I NON RR(US1 DATA A-I75 59130.0 Fr 1708.3 n = Ro nATURITY nEAh 0 3103 CTGS. 3 : 0 99 0.12 0.96 1.15 141 STOCRAtl Range; 0- 4% Incremenr: 8 . 1 0 % FULLER r l 1SUN1 25 RRUS No. N ID VALUES FULLER 36 1 PIEAN STD DEV MEDIAN nODE VITRihlTE REFLECTANCE (RANDOn X 1 3104 I tTtS. I 1.05 x 8.12 I 1.06 1.15 : HISTOGRAII: Range: 0- 4% IncremenlI 0.10% 0 r l ISUNI RWS No. ID = Ro f : tlATURlTY VALUES STD DEV MEDIAN I : nODE FULLER .I I' 43 r nEAN 0 3'05 CTGS. I 1.10 0.10 I .08 I .05 HISTOGRAM: Range: 0- 4 % Increment: 0.18% ISUNI RRUS No. . 3136 ID : CTGS DEPTH : : f = Ro tlATURITY VALUES niAN SlD DEV MEDIAN nODE 6150.0 F I 1874.5 n : : : : 32 I .05 0.12 1.05 0.95 H!STOGRAM: Range: 0- 4% Increment: 0.10% NON RR(US) D A T A A-I76 P FULLER . I ISUNI RRUS No. 3107 ID I CTGS. DEPTH r I 6250.0 Ft lW5.0 n * = Ro nATUR1TY VALUES 25 : REAN STD DEV REDIAN nODE 1 .05 0.12 1 .O1 1.15 : HISTOGRAn: Rsnge: 0- 4% Incremenr: 8.10% FULLER r l ISUNI RRUS NO. 3108 ID C T G S . ; L = Ro RATURITY VALUES 46 : nEAh SYD DEV : : REDIAN nox 1.05 0.11 I .06 I .05 HISTOGRAn: VITRINITE REFLECTANCE lRAI\DO?l X 1 FULLER . I Rsnge: 0- 4% Increment. 0.10% ISUNI RRUS No. . 3109 ID I CTCS. t = Ro RATURITY VALUES MEAN STD DEV PEDIAN nODE VITRINITE REFLECTANCE IRAhDOg %I NON RR(US) DATA A-177 : > > 37 1 .05 0.09 1.04 I .05 HIST3GRAR: Rsnge: 0- 4% Increment. 8.18% FULLER . I fSUNl 25 N U I VALUES 35 : IlEAFl SlD DEV nEDIAN nODE I .a7 0 0.09 1.08 > : 1.15 HISlOCRAn: Range: 0- 4% Increment. 0.18% VITRINITE REFLECTANCE fRANDOn % I FULLER . I 0 ISUNI RRUS No. 3111 ID z ClGS. DEPTH I 8 f E 6600.0 F I 2011.7 n Ro IiAlURI’IY VALUES nEAh SlD DEV I IlEDlAN : MODE P 47 I 1.05 0.11 I .04 1.05 I. HISTOGRAn: Range, 0- 4 % Increment, 0.10% a VI’IRINiTE REFLECTANCE 1RANDOn FULLER # I XI ISUNI RRUS No. 3112 ID I C T G S . I DEPlH : , I 6650.0 F I 2076.0 n f = Ro nA7URITY L VALUES 1 nEAN SlD DEV UEDIAN nODE I : 42 1.05 0.I0 I .04 1 .05 HISlOCSAll: .0 VIlRIN!TE REFLECTANCE lRAND3n N O N RR(US) DATA A-178 XI Range: 0- 4% Incremenl: 8.10% FULLER .I ISUNI RRUS N o . : 3’I3 ID I C T G S . DEPTH I 6700.0 F I 2042.2 M t = RoMAlURlTY P l5 s VALUES.: MEAN STD EEV MEDIAN MODE . 35 I .04 0 10 1 .03 0.95 HISTOSRAE: 1.0 3.0 2.0 V1TRIN:TEREFLECTANCE NON RR(US) DATA A-179 4 0 IRANDOM X 1 Range : 0- 4% Incremenl: 0.10% I 1 I I I 1 I I I t I I I 1 I 1 I 1 I- 0 f. U I" VI N u u 0 I" U N U N 0 N 0 A N S s l I' 2a 7 'C2. 2.0 2.3 2.6 3.0 3.2 3.5 3.7 4.0 6.0' .C2. 2.0 2.3 2.5 3.0 3.2 3.6 3.7 4.0 6.0' TU 24 10 . . . . (2. 2.0 2.3 2 3 3.0 3 9 3.6 3.7 4.0 S.0 .o#) 'C2. 2.0 2.5 2.6 3.0 3.2 3.6 3.7 4.0 8.0' NON RR(U.S.) DATA 03 oo um (2. e254 2.0 2.3 2.6 3.0 5.23.5 3.7 4.0 5.0 UQO 401 an 27 14 a 7 '<2. 2.0 2.3 2.55.05.2 3.5 3.7 4.0 5.0' .<2. 2.0 2.3 2.5 3.0 3.2 3.8 3.7 4.0 8.0' UDO "1 t 2 . 2.0 2.3 a.8 3.0 3.2 3.5 3.7 4.0 8.0 NON RR(U.S.) DATA A-183 21 v4 7 .7w c2. 2.0 2.3 2.5 S.0 3.2 3.8 3.7 4.0 b.0' NON RR(U.S.) DATA A-I84 li ai l 8e a. 2.0 2.3 2.8 3.0 3.2 3.5 3.7 4.0 8.0' TU NON RR(U.S.1 DATA A-185 e NO. 1 FULLER SAMPLE ...... .... RP 3A3l6G42570 ’ 0 TE RAW F I L E AREA % N-PAFAFFIN I I Y C ~ C P . R i 3 ~ d S ISOPKENJGID HYDROCAlnBOiiS GTAER KESOLVED C5 C 3 5 HYDXOCARBONS UNRESOLVL3 CS C35 BYDkSCAREOiG - NAME 15.50 1.32 38.41 - AREA % IPlG NC15 -14 .30 44-17 NAME AREA % dC23 NC 2: NC 25 5.29 3.43 22.09 2.17 l.C.5 3.45 1.86 1.51 2-35 1.12 1-01 .65 NC16 IP18 NC17 IP19 1.33 5.31 N” 2.65 NC26 1P20 NC19 2-76 7-29 NC20 NCZ1 5.77 1iC 3 2 6.96 5.34 KC33 x 3 4 Ncla NC22 NON RR(US) DATA 1.40 -/ . G 2 UC 27 -r 45 NC29 NC3C NC31 1’ k* NCl6 NClD ................................ NCa4 NO. 1 FULLER P83 B 4 5 E ’ TE TOTAL E X T R A C T RAl@’;?7 NON RR(U.S.)DATA A-187 0 " NON RR(U.S.)DATA A-188 ND.1 FULLEQ P83-SF 6102 THERMAL Ct R H 1 552 NON RR(U.S.)DAfA A-189 YD.1 FULLER P83-SF 6401: TUERHAL G C RU1553 NON RR(U.S.)DATA A-I90 HD.1 FULLER P83-SF 6 4 5 E THERMAL t f RG1553 NON RR(U.S.)DATA A-191 P YO.) FULLER PB3-SF C 5 5 C THERMAL GC RH1554 NON RR(U.S.)DATA A-192 wD.1 FULLER PEP-SF C 7 5 C THERMAL GC Rt1554 NON RR(U.S.)DATA A-193 a A-I94 GREEN ESTATE,#l FRANKLIN. ASTON, AND FAIR n n b 0 A-196 TABLE A.43 LITBOLOQICDESCRIPTION FRANKLINASTON & FAIR #1 ClREEN ESTATE 400520- 500' 650' 670-2.600' 2,620-2.750' 2.700-2.930' 2.960-3,030' 3.050-3.300' 3,320-3.360' 3,380-3.390' 3,410-3.840' 3.860-3.960' 3.980-4,050' 4,070-4.170' 4.190-4.260' 4,280-4.320' 4,340-4,530' 4.550-4.660' 4,680-4.720' 4,740-4.810' 4,830-5,410' 5,440-6.200' 6,220-8,160' Mudstone, reddish brown Mudstone, reddish brown Mudstone, greenish-gray(abundantin places) Mudstone, reddish brown (some green) Lst. clasts (abundant in places) Anhydrite Mudstone, It. green (some reddishbrown) Some dolomite Siltstone,It. (Sandsized) mudstone, reddishbrown-gray Mudstone, reddish brown ?(Sandsized)mudstone,reddishbrown-gray Mudstone, reddish brown (greenish gray) Anhydrite ?(Sandsizedparticles) mudstone, reddishbrown-gray Halite, lt. pink ?(Sandsizedparticles) mudstone, reddishbrown-gray Mudstone, green-gray Mudstone, reddish brown Halite, It. pink Mudstone, reddish brown Mudstone, green Halite. It.pink Mudstone. reddish brown Mudstone. green Anhydrite Halite, It. pink Mudstone, reddish brown Mudstone, green Anhydrite Mudstone. reddish brown Mudstone (some green, some purple) Anhydrite Mudstone, dark brown Lst.. dark Black shale, abundant in places Some anhydrite Traces of feldspar (granite wash) A-197 TABLE A.44 TOTAL ORGANIC CARBON DATA GREEN ESTATE a i , FRANKLIN,ASTON 6 PAIR n Projeot No. : R R U S / 0 4 5 I M I 8 0 7 / 4 I SAMPLEIDENTIFICATION RRUS DEPTH (Feet) 1501 405 525 1502 1005 1503 1395 1504 1725 1505 : : : : : 1506 1507 1508 1509 1510 . 2145 2700 2965 3250 3430 : : 1511 1512 1513 1514 3655 4000 4090 4615 : : : : : : : : DATA : DEPTH (Feet) I I 0.11 : 0.14 : 0.06 : 0.05 : 0.03 2 1 4 0 -2 1 5 0 2680- 2 7 2 0 2960- 2 9 7 0 3230- 3270 3410- 3450 I: 3690 4020 4110 4620 SAMPLEIDENTIFICATIOV I TOG% I RRUS 400410 5 2 0 -5 3 0 1000-1010 1390- 1400 1720- 1730 3620398040704610- I 0.02 0.26 : 0.08 : 0.27 : 0.17 i 1515390 6015 1516 I 1 5 1 76 5 3 0 6980 I 1518 I 1519 7090 I I 1 5 2 07 3 0 0 I 1521 7405 7615 I 1522 7705 : 1523 1 1524 7795 I ' : 0 . 1 3 I 1526 0.15 I 1527 0.06 I 1520 I 7975 8065 8145 i: 53705 -410 6010- 6 0 2 0 6 5 1 0 -6 5 5 0 6960- 7000 7070- 7110 :-0-.06 : 0.03 : 0.10 : : : 7 2 9 07-3 200. 0 4 7370- 7 4 4 0 7500- 7 6 5 0 7670- 7740 7760- 7830 : 0.04 : 0.42 : 0.25 : : : : 7 8 5 0 -7 9 2 0 7940- PO10 8 0 3 0 -8 1 0 0 8120- 8170 : : : : : : f a . 14 i 15257885 DATA : TOCK : n 0.08 0.06 n :-'0.05 I: 0.45 0.33 : 0.57 : 0.38 I' I' I' A-198 TABLE A.45 ROCK-EVAL PYROLYSIS RAWDATA GREEN ESTATE e l , FRANKLIN,ASTON S FAIR Project No. : R R V S / 8 4 5 / M / 8 0 7 / 4 SAMPLE IDENTIFICATION I DATA ( S 1 , 9 2 , 8 3 m Q l g m o f r o o k , T m a n d e g C) I RRUS DEPTH (Feet) I 51 82 53 5 2 / 8 3 S l / ( S l + S Z ) Tmax I 2700 3250 7705 7885 8065 1507 1509 1523 1525 1527 A : : : 1 5 2881 4 5 NOTE: : : : 2680323076707'8508030- 2720 i 0.130 3270 I 0.240 7 7 4 0 I 0.010 7920 I 0.010 8 1 0 0 I 0.020 81208170 I I 0.030 0.880 1.640 0.170 0.240 1.160 1.050 0.250 0.290 0.290 0.160 0.510 0.160 ' 0.123 0.128 0.056 0.059 0.077 0.759 1.562 0.680 0.552 0.828 --- 425 443 468 453 0 . 3 104. 1 5485 8 DASH INDICATES AN INDETERMINABLE VALVE TABLE. A.46 HYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL PYROLYSIS AND TOC DATA GREEN ESTATE # l , FRANKLIN,ASTON S FAIR Project No. : R R U S 1 8 4 5 / M 1 8 0 7 / 4 ~~ SAMPLE IDENTIFICATION RRVS DEPTH (Feet) 1507 1509 1523 1525 1527 8 114552 8 2700 3250 7705 7885 8065 : : : : 26803230767078508030- : 88117200 - : 2720 3270 7740 7920 8100 I i I I I I HYDROGEN INDEX (mg HClpm TOC) 338 607 40 36 42 I 42 A-199 ~~ OXYGEN INDEX tmg C02Igm TOC) 446 0.45 (%h) 0.26 0.27 0.42 389 60 64 51 134 TOC 0.57 ' 0 .38 , fl TABLE A.47 VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT GREEN ESTATE a i , FRANKLIN,ASTON 6 FAIR P r o j e c t Nn S A M P LIED E N T I F I C A T I O N RRUS D E( PF Te He t ) : RRU51845lMI807l4 n I I R E F L E C TK.E R O G ECNH A R A C T E R I S T I CTSO C I I Ro % Am% Ea% V i t w Inert% Fluor I % I 1 5 02 77 0 0 1509 3250 1 5 2 75 8 8 5 1 5 2870 6 5 1 5 28 1 4 5 : : : : : 2 6 8 0 2- 7 2 0 3 2 3 0 3- 2 7 0 78507 -920 8030- 8100 8 1 2 08 -1 7 0 I I I I I I 0.69 ---1.05 1.09 1.12 20 95 10 20 35 0 0 0 0 tr 10 70 Ned Ned 0.26 0.27 50 50 40 40 None None None 0.57 5 tr 30 25 n 0.45 0.38 n A-200 GREEN ESTATE * I , FRANKLIN, A. 6 F . 25 No. IC17 ID I CTGS. DEPTH t 2700.0 Ft RRUS 128 6?3.0 n 8 8 P l5 t Ro. MATURITY VALUES i5 E I0 15 I MEAN STD DEV, MEDIAN MODE 0.68 0.07 0.68 E.65 t I I > HISTOGRAM: 0 0.0 2.0 3.0 VITRINITE REFLECTANCE (RANDOn Range: 0- 4 % Increment: 0.10% 4.0 %I ORDERED REFLECTANCE VAL2ES. t0.58 t0.74 I0 58 t0.75 t0.60 t0.77 t0.64 t 0 77 80.64 80.84 80.67 t0.68 t0.68 t ~68 . t 0 . 7E KEROGEN DESCRIPTION Ex ini te : : 20 X 0 % Vitrinire Inertinire I 70 X Amorphous , Bach Fluor Birumen to he t , I 10 X lied rr tr GREEN ESTATE * I . FRANKLIN, A . b F ?5 7 RRUS No. ID I DEPTH MEAN 1.0 0 1 ........................................ 0.0 2.0 30 4.0 VITRINITE REFLECTANCE (RANDOU %I ORDERED REFLECTANCE VALUES: 1538 CTGS. : : 3233.0 f I 07B.6 t l 8 N.D. HISTOGRAM: RDnge. 0- 4 2 Increment, 0.10% KEROGEN DESCRIaTION hOrphOu6 Exinire Virrlnlre Inerr inire Bscr Fluor B i turnen Cohe A-201 I 95 X 0 X 5 % I tr X : I I ned , Pione , None e GREEN ESTATE . I . FRANKLIN, A . 8 F . RRUS No. : 1525 ID I CTGS. lu .DEPTH I > B Ro 7885.0 Fr 2403.3 R MATURITY ? I 8 VALUES IO I l0-l flEAN STD DEV' MEDIAh' I .05 0.08 I .06 I .I5 I I : MODE HISTOCRARI Range- 0- 4% Incrcmenr: 0.10% VITRINITE REFLECTANCE IRANDOR X 1 ORDERED REFLECTANCE VALUES:' 0.64 0.70 0.75 0.82 ?0.D2 20.82 t0.85 t0.07 I(ER0GEK DESCRIPTION Amorphous 10 % Exinite I 0 % Vitrinlre : 50 % lnerrinite I 40 x 00 rl.12 ti.03 3 1 . 1 5 tl.03 t1.17 V1.06 ?i ?I .07 Back Fluor 8 i 1 umen to he *I.I0 tI.II ti 0 .I2 I I I None No-e NO-,? e 0 GREEN ESTATE 81, FRANKLIN, A, & F. RRUS No. , 1527 ID : CTGS. DEPTH : I 8065.0 F1 2458.2 R t = Ro MATURITY n VALUES MEAN STD DEV REDlAFj MODE . VITRlNITE REFLECTANCE (RANDOR % I ORDERED REFLECTANCE VALUES. V0.83 10.84 r0.96 ? I .OO SI .O1 * I .03 tl.03 tl .I0 :I. I I :I. 1 I * I . I8 *I .I8 *I .I8 tl.20 *I. I0 tl . 10 A-202 1.09 0.1e 1.10 1 .I5 I : t : HISTOGRAR: Ronge; 0- 4 % Increment, 0.10% KEROGEN DESCRIPTION 20 % Amorphous 8 Exinire 0 : V;lrinire I 50 % Inerrinire I 30 X Bsch Fluor B4rumen toke ? I .88 ? I .28 18 I : : None Smal: lr I' I' GREEN ESTATE . I . FRANKLIN, A , 6 F RRUS ID I No. I DEPTH I f t = Ro MEAN STD DEV MEDIAN nODE ORDERED REFLECTAkCE VALUES: f0.92 fl.OO fl.ll t1.23 11.30 tl.OO xI.11 tl.23 f1.34 f0.05 .. ~. f0.95 tl.EZ t1.13 tl.23 t0.06 f1.02 t1.13 L1.24 m . n s t 1 . e 4 t 1 . 1 571.24 f0.07 fl.06 tI.18 f1.26 f0.07 fl.07 tl.18 11.27 f0.97 :1.07 x l . 1 8 f1.27 f0.99 fl.09 f1.20 f1.28 q1.00 tl.10 11.21 f1.30 ~~ A-203 8145.0 F1 2482.6 n tlATURITY VALUES VITRINITE REFLECTANCE IRANDOn X 1 1528 CTGS. 42 I t 1.12 0.12 I 1.11 s 1.25 1 HISTOCRAn: Range, 0- 4% Incremenr: C.l0X KEROGEN DESCRIPTION Amorpnous t , Exinire Vitrinile Inertinite a : B a t h Fluor t B i lumen Cole t , 35 X lr X 48 X 25 X None lr IlO!-,r TABLE A.48 COMPOSITION OF SOURCE ROCK EXTRACT GREEN ESTATE 0 1 , FRANKLIN,ASTON 6 FAIR Project No. : RRUS1845lMI80714 ~~ S A M PILDEE N T I F I C A T I O N RRUS : EXTRACT I D( EF Pe Te Ht ) AROM SAT ppm I POLAR5 ptro*?tage ~ : 3 23 72 03 0 - 3 2 15 50 0 9 : si . 9 1449 I 18.6 29.5 ~~ 0 TABLE A.49 SUMMARY TABLE SHOWINC SELECTED PARAMETERS OF O I L S A M P L E S a GREEN ESTATE # t , FRANKLIN.ASTON 6 FAIR Project No. SAMPLE IDENTIFICATION (RRUS Feet) 13520590 DEPTH IPh : 3 23 32 07 -0 ; RRUS1845lMl807l4 i; EXTRACT - - ----: I I SATS TOC ‘rc RATIOS Phl Pr IC:17 IC: 1 8 Prl CPI I 0 ~ 0 . 5 0310.7.04.95.384 5 -”- 0 P c c c A-204 H E A V Y H Y D R O C A R B O N S N O R M A L I Z E D T O1 0 0 % GREEN ESTATE Y 1 , FRANKLINoASTON 6 FAIR Project N O . ~~ S A N P L EI D E N T I F I C A T I O N RRUS : RRUS I 1 NORMALIZED n-ALKANES I CC- C 2-IC 21- C 10- C 19- C 18- 17- 16 5 D E P(TFHe e t ) 1 53 02 95 0 ~ ~ u s t a 4 5 1 ~ 1 a 0 7 ~ 4 I 3 233207- 0 I 0 .12.906. 01 0 8.50 5.40 8.50 9.50 I D E P(TFHe e t ) CC-C I2-C2-8C2-7C2-6C2-52-4232 ~~ ~ ~~ I 1 5.0392 5 0 : 3 2 33 02 -7 0 I 1 1 . 98 .07 0 7.60 6.60 2.8 30 .30 .60 I RRUS 1509 RRUS 1509 I DEPTH 3250 (Feet) I : 3 233207- 0 D E P(TFHe e t ) 3250 : 3 2 3 02 -7 0 c-35 CC - 2C - 93C - 03C - 13C - 23- 33 4 ~ I I 2 . 29 .0 24 .04 0 I I CC -I4C - 03C - 93C - 83- 73 6 I I I 0.00 0.00 A-205 0.00 0.00 0.00 ~~~ 1 .22. 00 0 0.00 ~ 0.80 PR PH 3.90 4.60 P P NO. 1 GREEN SAMPLE: RRUS NO. 1509 3250 feet GAS CHROMATOGRAMS OF C15+ SANRATE HYDROCARBONS A-207 a P c P A-208 HUSKY, I1 HANCHETT STATE A-209 a a A-210 TABLE A.51 LITHOLOGICDESCRIPTION HUSKY OIL # 1 HANCHETTSTATE (Sample every 10 feet) 0- 200' 200- 440' 440- 500' 500- 560' 560-680' 680- 780' 780- 970' 990-1.090' 1,090-1,360' 1,360-1.400' 1.400-1,450' 1,450-1,600' 1.600-1,790' 1.790-2.180' 2.180-2.280' 2,470-3.270' 3.270-3,500' 3.500-3.970' 3,970-4.100' 4,100-5.050' Very red, calcareoussandstone Red sandstone. contains clasts of calcareousmudstone in part. Red sandstone, contains large clasts of calcareous mudstone Red sandstone, clasts of limestone decrease in volume a s well as size Sandstone, fairly clean, cuttings are large indicating possibly well consolidated lithology Sandstone (may be shale), shale (dark), calcarw~s clasts. Limestone andsandstone white tobuff. Approximate equal percentage of all lithologies Same as above but sandstone percentage increasirg Veryred.calcareoussandstone Red sandstone, calcareous percentage increased and clasts become larger towards base of unit Shale,sandstone.andcalcareousclasts,(possibly gypsum) Shale dark gray (possibly mudstone) Sandstone.shaleandcalcareousclasts.Percentage of red material greatly depreciates, shale increases Shale limestone and sandstone, some red clasts possibly some gypsum. Sandstone. limestone, shale (mudstone)possiblygypsum, very red (1.960-1.990) percentages of lithologies variable, however on a whole approximatelyequal. Sandstone, limestone,shale (mudstone), becomingmore redtowardsbase.Sandstone or gypsum at 2,320-2.340' Red to very red sandstone with limestone clasts. Mudstone (shale) percentage is very low, except large increase in shale 2.860-2.900' Sandy limestone slight shale increase towards bas?, also becomesmore red towards base Very red to red sandstone with clasts of limeston? and shale(mudstone) Red sandstone, no larecalcareousclasts. howeveappears to have very fine pieces of shale (mudstone) Sandstone and dark green to dark gray shale (mudstone), no visible white or buff limestones LITHOLOGICDESCRIPTION HUSKY OIL # 1 HANCHETT STATE (continued) 5.050-7.000' 7,000-7,320' Shale.green to gray with variable amounts of white to buff limestone or gypsum, no visible red sandstone Shale. dark green togray. not fissil. granite and calcareous fragments. Granite greatlyincreases towards base 0 I' c TNLE A.52 TOTAL ORGANIC CARBON DATA HUSKY # l HANCHETT STAT€ . . Projeot No. : R R V S l B 4 5 l U l B 0 7 I 4 . SAMPLE IDENTIFICATION RRUS DEPTH 1401 500 1 4 0 21 4 3 0 14031935 14042495 14053335 1406 14.07 1408 1409 1410 4085 4650 5335 5490 5825 : : : : : : : : : : ~~~~~ I : DATA I I I ~~ ~ ~~~~ ~~~ SAMPLE IDENTIFIC~TIOM (Feet) : TOCS 4 5 0 -5 5 0 1410-1450 1910-1960 2 4 7 0 -2 5 2 0 3 3 1 0 -3 3 6 0 I 0 . 1 0 I 1 4 1 16 0 3 0 0 . 6 8 I 1 4 1 26 3 3 5 0 . 5 2 : 1413 6475 0 . 3 7 ' 1 4 1 46 5 9 5 0 . 4 2 i 1 4 1 s6 7 1 0 I 0 . 2 9 : 1416 6805 6940 0.22-1 1 4 1 7 7035 0 . 2 9 I 1418 0 . 5 3 I 1419 7075 7105 0.48 I 1 4 2 0 40504600531054705800- 4120 4700 5360 5510 5850 : : : : : : : : : RRUS DEPTH (Feet) DATA : TOCK I I A-213 : : : : : 6000- 6 0 6 0 6 3 1 0 -6 3 6 0 6 4 5 0 -6 5 0 0 6 5 8 0 -6 6 1 0 6680- 6740 1.66 1 .oo 0.75 0.25 0.29 : : : : : 67706920701070607090- 1.95 0.91 0.79 0.93 0.84 6840 6960 7060 7090 7120 0 TABLE A.53 TOTAL ORGANIC CARBON DATA . HANCHETT STATE (SUN) Project SAMPLE IDENTIFICATION RRVS 3203 3204 3201 3202 DEPTH (Feet) 6100 6260 6400 6550 NO. RRUS/845/M1807/4 ; : DATA I I 1 ,; TOCk : 0.22 : 0.23 : 0.59 0 SAMPLEIDENTIFICATIOY RRU5 I 3206 I 3207 I 3208 DEPTH (Feet) 6640 6750 6040 7000 : QATA : TOCk : 0.45 : 0.37 : 0.39 : 0.53 e i ~ N O N RR(US) DATA 0 0 A-214 TABLE A.54 ROCK-EVAL HUSKY PYROLYSIS RAW DATA U l HANCHETT STATE . . . Projeet No. : R R U S 1 8 4 5 I M 1 8 0 7 l 4 SAMPLE IDENTIFICATION DEPTH RRUS (Feet) c) I DATA ( S l , S 2 , 5 3 m g t g m o f r o o k , Tmax d e g i I SI 52 ' Tmax S 2513S 3 z 8 1 1 ( S 1 + S 2 ) I 1402 1403 1405 1409 1410 1411 1412 1413 1416 1417 1430 1935 3335 5490 5825 : : 6030 6335 6475 6805 6940 : 1 4 1780 3 5 7075 1419 7105 1420 : : : : : : : : : : 14101910331054705800- i i 1450 0.120 1960 ' 0.080 3360 0.010 5510 I 0 . 0 2 0 5850 I 0.040 6000- 6 0 6 0 6310- 6360 6450- 6500 6 7 7 06-8 4 0 6920- 6960 1.440 0.530 0.050 0.140 0.160 2.250 0.640 1.082 0.152 0.519 0.533 0.310 0.290 0.280 1.968 0.047 0.828 0.143 0.857 0.143 3 . 7 2r0. 1 2435 2 0.862 0.138 I I 0 . 0 3 0 0.610 I 0.040 0 . 2 4 0 0.240 I 0.040 I 0 . 1 300. 9 3 0 I 0.040 0.250 I I 0.050 7 0 1 07-0 6 0 7060- 7 0 9 0 I 0.050 7090- 7120 I 0 . 0 4 0 0.240 0.310 0.220 0 . 0 7473 1 0.131 0.167 0.125 0.200 0.490 0.330 0.270 0.300 0.250 0.290 0 . 3 300, 7 2P7. 1 7426 3 1.107 C.139 0.280 0.290 0.759 c.154 430 ------460 452 467 460 456 454 I NOTE: A DASH INDICATES AN INDETERMINABLE VALUE. HYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL PYROLYSIS AND TOC DATA HUSKY 1 1 HANCHETT STATE Project N o . : R R U S t 8 4 5 1 M I B 0 7 1 4 SAMPLE IDENTIFICATION iI R R U S (Feet) DEPTH 1 4 0 21 4 3 0 1935 1403 1405 3335 5490 1409 1410 5825 : : : 1411 6030 633s 1 4 1 36 4 7 5 6805 1416 1417 6940 : : : : 7035 7075 7105 : 1412 1418 1419 1420 : : : : : : 1450 i 1960 I 3360 : 5510 ' SBOO- 5850 i I 6000- 6 0 6 0 * 63106360 6450- 6500 I 6770- 6840 I 6920- 6960 I 1410191033105470- HYDROGENINDEX (mp HClgm TOC) 212 102 12 26 33 OXYGEN INDEX (mg C O Z I TOC) ~ ~ 94 94 79 51 62 TOC (YI) 0.68 0.52 0.42 0.53 0.48 37 24 32 48 a7 i I 7010- 7060 i 7060- 7 0 9 0 ' 7090- 7 1 2 0 30 33 26 i A-215 42 30 35 0.79 0.93 0.84 TABLE A.56, PYROLYSIS RAW DATA ROCK-EVAL WANCHETT STATE (SUN ) Projrct No. 5ANPLE IDENTIPICATION DEPTHRRUS DATA ( S 1 , 5 2 . 5 3 o g l p m o f ?,Oak. Tana (Feet) 3203 3204 3201 3202 3205 6100 6240 6400 6550 6640 3206 3207 3208 6750 6840 7000 --- T 0 0 0 0 ! : RRUS1845/M1807/4 51 52 .110 .050 ,040 .070 0.030 ”- ”- 0.040 0,130 0 ,080 0.040 0 050 0.090 0,040 0.050 0.110 REPRESENTS AN UNDETERNINED VALUE 53 de$ C ) 6 2 / 8 3 611(51+S21 T m a s -” ” _ ” _ ”- - ” _ ” -” -” ” _ ” _ ”- ”- ” _ ”- -” ” _ 0.786 --- -” ” _ ”- ” _ 0.350 0.331 467 0.500 0.500 440 490 448 0.450 0 --0 NON RR(US) DATA 0 0 c c c c A-2 16 TABLE A.57 ~~ ~ ~~~~ ~~~ ~~~ - VISUAL KEROGEN ANALYSIS REFLECTED LIGHT HUSKY U l HANCHETT STATE Proleot No. : R R U S 1 0 4 5 1 N t 6 0 7 l 4 SAMPLE IDENTIFICATION RRUS DEPTH (Feet) I I I I : I 1 4 0124 3 0 1 4 0139 3 5 1 4 05 94 9 0 1410 5825 1411 6030 : : : : : 1 4 1 01-4 5 0 1 9 1 01-9 6 0 5 4 7 05 -5 1 0 5800- 5850 6000- 6 0 6 0 ---0.54 I I ; 1.04 1.04 ! 1412 6335 1416 6805 1 4 1 67 9 4 0 1 4 17 90 7 5 1420 7105 : : : : : RO W i I 6 3 1 06 -3 6 0 I 67706 -840 I 6 9 2 0 6- 9 6 0 I 7 0 6 07-0 9 0 ' 7090- 7120 TOC REFLECT.KEROGENCHARACTERISTICS Am% 0 Ex% V f t w Inart% F l u o r 0 0 1400 0 20 30 5 50 so tr tr ---- 80 0 0 0 1.01 1.00 1.04 1.03 30 0 30 20 tr tr tr 50 iI ---- A-217 15 30 0 0 15 0 55 40 0 None None LOW None 0 None 40 30 30 30 0 None High LOW Ned None K 0. 0.S 2 d G 0.53g0.40". 1.66- 1.ODLr1.9&" o . 9150.33c-c 0.84~"~- 0 HUSKY * I HANCHETT STATE 1 25 7 RRUSNo. 1402 ID I CTGS. 20/ DEPTH 1430.0 Fr 435.8 n I INSUFFICIENT SANPLE MATERIAL I nEAN I 0 N.D. 0 01 0.0 ..,, ,,., 1.0 2.0 41.0 3!0 VITRINITE REFLECTANCE fRANDOn XI ORDERED REFLECTANCE VALUES: HISTOGRAn~ Range: 0- 4% Incremenr: 0.10% REROCEN DESCR'PTION 0 x Amorphous I Exinire , 0X Virrinlre 0 X Inert inireI 0 x Each Fluor : None 2 None , None Bi rumen tome 0 0 0 HUSKY v1 HANCrlETT STATE RRUS No. 1403 ID : CTGS. I DEPTH I 1635.0 Fr 5E8.8 I t = Ro nATURITY * VALUES nEAN STD DEV nEDIAN nODE 0.0 1 .a 2.0 3.0 VITRINITE REFLECTANCE IRANDOPI X I ORDERED REFLECTANCE VALUES 0.36 t0.44 50.45 t0.48 t0.48 t0.48 t0.51 t0.51 50.51 t0.52 t0.52 v0.52 t0.55 f0.64 20.55 t0.65 t0.56 t0.66 t0.57 0 71 f0.5E 0.77 v0.6a 4 0 N 32 I 0.54 0.06 0.54 0.55 I t I I HISTOGRAIl>* Range, 0- 4% lncremenr: 0.I0X KEROGEN DESCRlPTlON AmOrphOu6 - Erlnlin -. . . . .. . .i I 50 X lt- 2 a i X Vitrinire 10 X lnerrlnire Each Fluor None : Small Eirumep : None tohe I 0.84 A-218 c .. HUSKY rl HANCHETT STATE 25 7 No. RRUS ID 14013 I CTGS. t DEPTH 5480.0 Ft 1373.4 n t I = Ro HATUR'TY VALUES I 27 nEAN 2 I .04 STD DEV , 0.11 PlEDlAN I 1.04 HODE 1.15 HISTOGRAH: Range: 0- 4% Increments 0 . 1 0 ~ f ORDERED REFLECTANCE VALUES: 0.45 0.47 0.50 0.51 0.51 0.53 0.56 0.W 0.61 0.64 1 0.65 0.71 t0.80 t0.84 t0.84 t0.86 ?0.93 *0 E4 10 E9 r0.w tl.0e fl.O1 tl.03 S1.03 t1.03 f1.04 :1.07 tl.08 t1.09 t1.10 t1.11 t1.13 t1.15 tl .16 t1.17 t1.17 t1.17 t1.17 1: .:@ 1.22 KEROGEN DESCR'PTION 50 X Amorphous t Exinite rr X Vitrinire t 20 X Inertinite : 30 X BSCK Fluor : Low I tr Birumen tohe None 1 1 1 1 1 1 1 1 I 1 1 HUSKY I 1 HANCHETT 25 STATE RRUS ID 20! I No. I DEPTH X t P 15! n 5825.0 Ft 1775.5 n Ro HATURITY VALUES nEAN STD DEV nEDIAN nODE N 5 1410 CTGS. 7 8 1.04 0.12 1.80 1.15 I I HISTOGRAn: Range: 0- 4% VITRINITE REFLECTANCE IRANDOnX1 ORDERED REFLECTANCE VALUES: t0.RE Incremenr; 0.10X KEROGEN DESCRITJON 80 % Amorphous Exinite I 0 X Vilrinire 8 15 X lnerr inite I 5 X I tl .OO * I . 13 . fl. 16 fl .23 Each Fluor Birumen toke A-219 None : tr I None 0 HUSKY D l HANCHETT STATE 25 7 RRUS No. : ID I CTGS. 1411 DEPTH I 6030.0 F1 1837.8 M I N.D t INSUFFICIENT SAMPLE MATERIAL nEAN !:I 0 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0 0 0.0 1.0 2.0 3.0 4.e VITRIbiIlE REFLECTANCE IRANDOM % I ORDERED REFLECTANCE VALUES: HISTOGRAM, Rsnge: 0- 4% Incremenr: 0.18% KEROGEN DESCR IPT1 ON 0 x Amorpnous , Erinite I 0 % Vltrlnire 0 X lnerrinire I 0 X Bock Fluor 81 turnen Core , None , None I None 0 HUSRY .1 HANCHETT STATE 25 RRUS No. : 1412 ID 3 CTCS. N DEPTH : I ?.= F 4 D Ro MATURITY VALUES MEAN STD DEV nEDl AN noDE 0 - VITRINITE REFLECTANCE IRANDOtl X I ORDERED REFLECTANCE VALUES. 0.55 0.70 fE.06 51 0r 1 1B 0.64 .0.71 0.72 0.73 0.73 0 78 0.70 ~ 0 . 0 6T I 08 t0.01 Z8 01 10.04 r0.05 T0.05 1 1n ZI.OO t 1 . 1 2 1 25 Tl 01 fl e2 12 1. ."7 5 1 1 16 1 17 ;.28 1 28 03 TI.E3 TI *I 1z 1.30 A-220 6335.0 F I 103E.O tl : f a 23 1.01 0.87 1.80 0.05 HISTOGRAfl Range: 0- 4% Incremenr: 0.10% KEROGEN DESCR'PTION 30 X Amorphous , Exlnire 0 % Vltrinlle : 30 X Inert inire 40 X Bock Fluor : None 8 ; turnen . ~r : rr Cohe P HUSKY * I HANCHETT STATE RRUS No. ID t DEPTH I t t 1416 I CTGS. 6805.0 F1 2074 .z n RO nATURlTY 36 VALUES I I MEAN I STD DEV , HEDIAN I MODE VITRINITE REFLECTANCE IRANDOMX I ORDERED REFLEETAYCE VALUES. 0.51 0.67 0.71 0.73 0.73 0.75 t0.77 t0.81 w.04 :~.m I 1.22 1.28 Bnch Fluor High 1.28 1.31 1.33 1.34 1.36 XI.:^ tl.14 t0.81 r a . 8 5 * I 0r t0 83 r0.07 * I 05 VI .I7 HUSKY -1 HISTOGRAM, Rnnge: 0- 4% Increment: 0.IBx KEROGEN DESCRIPTION Amorphous 20 X Exinite : tr X Vlrrinire : 50 X lnertlnlte : 30 X m . 8 4 re.88 :I 06 t 1 . 1 7 t0.85 tE.08 *I 07 71.18 t0.80 tl.01 fl.11 1.20 :0 80 tl.01 11.11 re.63 t1.01 :I .II T 0 84 TI.01 7 1 . 1 4 :@.E4 tl.03 7 1 . 1 4 1 .OO 0.11 I .01 1.15 B i tumen : . tohe tr None HANCHETT STATE RRUS No. ; ID I CTGS. 1417 DEPTH 6f40.0 Ft 2115.3 n : I Ro MATURITY t D * VALUES nEAN STD DEV nEDlAN MODE 32 3 1.04 0.11 1.06 I I : I .15 HISTOGRAM^ Range: 0- 4% VITRINITE REFLECTANCE IRA1UDOII ORDERED REFLECTANCE VALUES. 0.62 V0.87 tI.E2 f l 14 0.71 t8.88 t1.03 qI.16 0.72 r0.00 r1.04 :I . I 7 1 .24 1.24 ~~ 1 ~ 7 4 XI Increment. 0.I0X KEROGEN DESCRIPTION 15 X Amorphous I Exinite t tr X Virrinlte , 55 X Inert inite I 30 X Back Fluor 8 ;tonen Cohe A-221 , Lor : : Small None 0 HUSKY * I HANCHETT S A T E RRUS No : 1410 ID i CTGS. DEPTH 7075.0 2156.5 I I Ft n t = R a MAlURITY VALUES REFLECTAKCE 0.05 KEROGEN DESCRIPTION 30 X Amorphous I Exinite : tr X Vltrinite I 40 I: Inertlnite : 30 x 00 . 7. 8 4 0 . 7 8 t0.87 0 . 7 0t 0 . 8 0 0 . 8 0 r0.8e 0.88 :B.BO 0 81 r 0 . w 0.82 t0.03 8.83 ~ 0 . 0 4 VI.lt? 0 . 8 3 V0.04 0.83 t 0 . 0 5 , Back Fluor 8 I lumen 0 0 ned Smsl! I . tohe 1.31 None 0 HUSKY * I HANCHETT STATE RRUS NO. 8 1420 ID I CltS. N j: I .02 I : HlSTOtRAn: Range: 0- 42 Incremenr, 0.10% VITRINITE REFLECTANCE IRANDOIl X I - 0.12 I nED1AN nODE 25 1.03 t STD D E W 0.70 0.71 0.72 0.74 0.76 0.77 0.77 0.77 0.78 23 I nEAN 0 DEPTH INSUFFICIENT SAMPLE IlATERIAL nEAN 0 1 ........................ 0.0 2 . 01 . 0 ' ,,,, ,.,, 3'.0 ,. VlTRINITE REFLEClANCE (RANDOM X I ORDERED REFLECTANCE VALUES, 4.0 2 7105.0 2165.6 I N.D I HISTDGRAfl I Range: 0- 4 % Increment> 0 . 1 0 % KEROGEN DESCRIPllON 0 X Amorphous Exinlre 0 2 Vltrinlre 0 x Inertinite 0 x I Fluor Bitumen Cohe BDch A-222 : None None : None 3 0 FI li 6640 TABLE A.58 V I S U A L K E R O G E N A N A L Y S I S- R E F L E C T E D L I G H T . H A N C H E T T 5 T A T E (SUN) Projcot No. : R R U S 1 8 4 5 l M l 8 0 7 l 4 S A M P L EI D E N T I F I C A T I O N RRU6 3203 3204 3201 3202 3205 D E P (T FH e e t ) 6 1 DO 6260 6400 6550 I I I I I I I I I CHARACTERISTICS R E F L E C T .K E R O G E N Ro % ”” 1.os 0.97 0.92 0.96 Am% 0 0 0 0 0 Ea% Vit% Xnorts F l u o r 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 None None None None None TOC 4! 0.19 0.22 0.23 0.59 0.45 I 3206 3207 3208 6750 6840 7000 ; I I 0.96 0.99 0.98 NON RR(US1 DATA A-223 0 0 0 0 0 0 0 0 0 0 0 0 None None None 0.37 0.39 0.59 WTRINITE REFLECTANCE DATA SUMMARY ‘ 2”- Hanchett State- . _. J . L. Martinez . D m n ?i ’ SAMPLE POINTS COMMENTS UEAV 61 00 15 6260 64 Insufficient amount of identifiable organic material for a valid Ro mean. 0 to appears material organic be weathered. Very small amounts of oxidized matter. , 6400 60 Material appears to be unconsolidated with mixed populations. 6550 83 Light-brom gritty matter (may be sand). Organic debris is present. Organic material appears to be weathered. 6640 11 t o s s of some less-mature organic material that wasin previous sample has raised Ro mean slightly. 6750 93 Sliqht shift in & , mean due to loss 05 more-mature organic material. 6 ~ 4 0 R9 Continued shift t o lessmaturr n r q a n i cm a t e r i a l . or- VIfRlNlTE REFLECTANCEDATA SUMMARY llanchett State = z J . L. Martinez 0 - SAMPLE m POINTS READ COMMENTS 31 5 ID Y U x- * -4 . 7000 56 Possible change in d e p o s i t i o n and/or environment. Majority of m a t e r i a l i s less-maturethan This i np r e v i o u s a m p l e s . m a t e r i a l may be cave or contamination. 0 1 1 HANCHETT STATE ISUNI 0 RRUS NO. 3201 ID I CTCS. I DEPTH I 8 6400.0 F t 1950.7 ll Ro hATUR:TY 'I I 1 VALUES nEAN STD DEV nEDIAN nODE 0 26 : 0.87 0.09 0.99 0.95 I I 8 a HISTOGRAn: Ronge. 0- 4 % Increment: 0.10% e V I T R I N I T E REFLECTANCE CRANDDPI X 1 1 1 HANCHETT STATE (SUN1 25 0 . RRUS N o . ID DEPTH > I !i f = Ro 1 VALUES [ 5 0 0.0 I I 8 0 36 : 0.82 0.10 0.84 I .05 0 HISTOGRAV: 1.0 Range: 0- 4 % Incremenr: 0.10% 2.0 4.0 3.0 V I T R I N I T E REFLECTAWE IRANDOV X I 25 6550.0 F I 1686.4 n nATURITY MEAN DEV S'D nEDIAN nODE j0 3202 CTCS. : - * I HANCHETT STATE ISUNI RRUS No'. ID I : 3213 CTCS. DEPTH : 6120.0 nEAN I N.D , HISTOGRAV: Ronge: 0- 4 % Incrementt 0.10% NON RR(US) DATA A-226 FI 1859.3 n 25 - .I HANCHETT STATE (SUN1 RRUS No. I 3104 ID CTGS. I I 6761 . 0 1708.4 m VALUES : 35 DEPTH ! REAN STD DEV nEDlAN nODE : : Ft n I .05 0.12 I .85 I .05 HISTOGRAn: VITRINITERECLEtTANtE Range: 0- 4% Incrementi 0.18% IRANDOn X 1 * I HANCHETT STATE ISUNI RRUS No. . 3205 ID I CTGS. N 1e DEPTH : 20 . ! G 6640.0 F t 2823.8 n I = Ro tlATUR,~TY l5 ‘0 N : S 0 0.0 nEAN STD DEV PlEDlAN nO3E c, 5 Ib.7.. ,.r! ..,..,..,. I .0 VALUES 3’.2.0 0 V I T R I N I T E REFLECTANCE IRANDOC X 1 .1 4!0 40 : : : I 0.96 0.12 0.87 I .05 HISTOGRAPI: Range; 0- 4 % Increment. E.lE% HbNCHETT STATE (SUN1 25 RRUS N o . I 3206 ID I CTGS. DEPTH , : nEAN STD DEV nEDIAN noDE I z I I 6750.0 Ft 2857.4 n 8.86 0.12 0.95 0.95 HISTDGRAn: V I T R I N I T E REFLECTANCE IRAhDOP XI NON RR(US) DATA A-227 Range. 0- 4 % Increment. 0.10% 0 0 0 r l HANCHETT STATE !SUN1 25 RRUS N O . t 3207 I D I CTGS. 120 DEPTH I 1 0 t = Ro nATURITY P l5 5 52 I REAN STD DEV I I 0.89 0.13 nEDIAN nODE I : 01.02 .85 0 HISTOGRAtl: 0 0.0 VALUES S E 10 1 68,'@.0 F I 2084.8 n I .0 2.0 3.0 V I T R I N I T E REFLECTANCE IRAFIDOP! X I Range: 0- 4 1 Incremenr: 0 . 1 0 2 4.e 0 r l HANtHETT STATE ISUNI RRUS No. ID z 3208 c CTGS. DEPTH . s V = * VALUES 70'0.0 Fr 2136.6 n Ro nATURITY HEAN DEV STD HEDIAN nODE : I s > : 16 0.88 0.14 0.86 0.85 HISTOCRAn: Rsnge: 0- 4 2 Incremenr: 0.10X I' NON RR(US) DATA c c A-228 VlSllAL KERW!?N DATA SIIMMARY v) P. Ilrlrbr1dp.e TIIERTIAI. AI.1T.RATION INDEX (TAl) n -I c n rrc h . ,m h r m 7 hdal TA I l Uaturnt Inn fncreanen- 1 c. c2.0 2.0 2.3 2.5 3.0 3.5 3.2 3.7 5.0 4.0 cl c Y V m 1 011 and Cas C m w r a t I m 1 Dry Cas Only 1 0 0 n 0 I e.2 0 21 2.0 S.0 S 2 sb 3.7 4.0 A O ' '(2 2.0 2.3 sd S.0 5 1 sb 5.7 4.0 b.0' 0 TI1 D4m 0 0 NON RR(U.S.)DATA k A-230 c No.1 HANCHETT STATE nhtruc(und K o q o n Ootn ~ N o n - S t r v c l u M K o m p n Ooto . . . sd 3.7 4.0 8.0' NON RR(U.S.)DAfA A-231 0 0 NO. 1 HANCHETTSTATE P 00076260 THERMAL tc RH1735 NON RR(U.S.)DATA A-232 kC 7 7OL'ILUl Y YES Y I L I U i *: "UC IS I1 , NO. 1 HANCHETT STATE 00876759 TUERHAL t f RH1737 NON RR(U.S.)DATA A-233 :- . -I 0 NO. 1 HANCHETT ~ ~ ~ STATE 7 6 THERMAL G f RG1736 NON RR(U.S.)DATA A-234 4 0 ~ I' u: I? NO. I HANCHETTSTATE 00078 100 THERMAL Gt Rtl735 NON RR(U.S.)DATA A-235 c NO. 1 HANCHETTSTATE NON RR(U.S.:DATA A-236 NO. 1 HANCHETT STATE DBR76SSP TUERHALCC RU1736 NON RR(U.S.)DATA A-237 "I.. 0 0 0 I' NO. 1 HANCHETT STATE DDC7684E TIiERMALCf RC 1738 NON RR(U.S.)DATA A-238 NO. 1 HANCHETTSTATE NON RR(U.S.)DATA A-239 I' I' A-240 TRANS PECOS,#l LATIGORANCH A-241 0 0 0 0 0 P TABLE A.61 LATIGO RANCH SCREEN ANALYSIS SVIMARY Sacple !,s.bcr Ye1 1 Interval (Feet) Tot81 Orgacic Brief Lithologlcal Dercriptfon Cartar. (i of RG:~) 2260-025 3100 Sandstone. slightly dolwnitlc. pale yellowish brwn. 0.06 2260-031 3400 Composfte: 60% Sandstone. sllghtly dolomltic, pale yellowfsh brown. 402 Shale. pale red. 0.02 2260-033 3500 Composlte: 65% Sandstone, slightly dolmftic, pale yellowish brown. 35% Shale, pale red. 0.03 2260-035 3600 Conposfte: 702 Sandstone, slightly dolomitfc, pale yellowfsh brown. 30: Shale. pale red. 0.0210.02 5260-037 3700 Composlte: 60% Shale, pale red. 40% Sandstone, slightly dolomitic. pale yellowfsh brown. 0.02 2260439 3000 Composite: 70% Shale, pale red. 30% Sandstone, slightly dolomltic. pale yellowish brown. 0.02 2260-041 3900 Shale, pale red. 0.01 2260-043 4000 Composlte: 60% Shale, pale red. 40% Sandstone, slightly dolomitic. pale yellowfsh brown. 0.01 2260-045 4100 Composfte: 80% Shale. pale red. 20% Sandstone. slightly dolomitfc. pale yellowfsh brown. 0.03 2260-047 4200 Composfte: 60%: Shale, pale red. 40% Sandstone, slightly dolomitic, pale yellowish brown. 0.01 ?260-049 4300 Shale. pale red. 0.03 2263-051 4400 Shale, pale red. 0.0410.05 2260-053 4500 Conposlte: 60% Shale, pale red. 40% Sandstone, pale reddish brwn. 0.03 2260-055 4600 Conposlte: 60% Shale, pale red. 40% Sandstone. pale reddish brown. 0.03 NON RR(US) DATA A-243 0 .LATIGO RANCH StRLEN ANALYSIS SUWMY 0 Total Drjisr,ic Uell Sa-ple $fiber Interval Brief LithologicalC akrct rmi p t i o n (%Of Rock) e 5260-057 2260-059 4700 4800 Composite: 80% paleShale. Composite: 70% Shale,pale gray. 30% Sandstone, pale 2260-061 grayish4900 2260-063 * 5000 2260-065 5100 2260-D67 5200 9260-069 2260-071 2260-073 red. 0.02 205 Sandstone. pale reddish brown. Shale. red rnd medium dark 0.10 reddish brown. red. Composite: 70% Shale. grayish red and medium 0 0.09 0.12 darkgray. 30% Sandstone. l i g h t gray. Composite: 85% Shale, graylsh red and medium e 0.13 dark gray. 15% Sandstone, l i g h t gray. Composite: 90% Shale, grayish red rnd medium dark gray.. 10% Sandstone, l i g h t gray. O.l0/0.09 5300 Composite: 905 Shale, grayish red and medlum darkgray. 10% Sandstone. l i g h t gray. 0.11 54 00 Composite: 85% Shale, grayish red and medium 0.09 5500 Composite: 70% Shale, grading t o siltstone. medium l i g h t 'gray t o medium grcu. 30% Dolomite. brownish gray. 0.20 0 I, darkgray. 15% Sandstone, l i g h t gray. P 2260-075 5600 Composite: 70% Dolomite, brownish gray. 30% Shale, medium gray. 0.23 2260-077 5700 Composite: 70% Dolomite, brownish gray. 30% Shale. medim gray. 0.10 2260-079 5800 Composite: 70% Shale, grayish red and medium darkgray. 30% Quartz fragments. 0.17 2260-081 5900 Composite: BDX Shale, grayish red and medium dark gray. 20% Sandstone, l i g h t gray. 0.20 P c. NON RR(US) DATA A-244 c LATIGO RANCH SCREEN ANALYSISSUWVJIRY Sanple finber Ye1 1 Interval (Feet) 2260-OB3 6000 Composfte: 2260-085 6100 Composite: 85% Quartz fragments, white. 15% Shale. graylshred and medim dark pray. 0.07 2260-0~a 6200 Composlte: 70% Shale. grayishred and medium 0.19 2260-090 6300 Composite: 2260-093 6400 Shale, grayish red and medlum dnrk gray. 2260-095 6500 Conposlte: 80% Shale, grayishred andmedlum dark gray. 20% Sandsione, l t g h t gray. 0.22 2260-098 6600 Composlte: 70"; Shale, grayishred and medium dark gray. 30:: Sandstone, l i g h t gray. 0.16 2260-101 6700 Composlte: 80% Shale. grayish red andmedium dark gray. 20% Limestone and sandstone, l i g h t 0.21 Tots1 Orga~,ic BriefDescriptlon Lithotopical 75% Shale, graylshred and medim dark gray. 252 Sandstone. l i g h t pray. dark gray.. 30% Quartz fragments. 85% Shale, graylshred andmedium dark gray. 15% Quartz fragments. Csrbm (iof Rc:t) o.1wo.m 0.16 0.16 * 2260-104 6750 Composlte: 60%Dolomite,brownlsh gray. 40% Shale, graylsh red and nedium dark gray. 0.49i0.47 2260-106 6900 Composlte: 60% Shale, grayishred andmedium dark gray. 30% Dolomite,brownish gray. 10% Sandstone. l i g h t gray. 0.31 2260-110 7000 Composite: 802 Sandstone, d o l o m i t l c ,l i g h tb r o m i s h gray. 20: Shale, graylsh red and medium dark gray. 0.26 NON RR(US) DATA A-245 0 LATIGO RANCH SCREEN ANALYSIS SUWARY 0 Samp 1e UrAer 7100 2260-113 2260-115 Uel 1 L f ItBnhrtoieDleroefvpsaiclcrai pl t i o n t o t s 1 Or5ar.i~ tt r h n (Feet) 0.03 7190 (2 Df RXk) 0 white. Quartz fragments. 8DX Shale, grayish red and medim 20% S i l t s t o n e , s i l i c i f i e d , dark pray. moderateorangepink. 0.13 0 0 0 4 P t. NON RR(US) DATA c A-246 ~ TABLE A.62 TOTAL ORCANIC CARBON DATA LATICO RANCH (SUN) P r o j e c t NO. : R R V S I ~ ~ S I M I ~ O ~ I ~ SAMPLE IDENTIFICATION RRU5 DEPTH (Feet) : DATA I I TOCII, SAMPLE IDENTIFI6ATIOY RRUS DEPTH ( F e e t > : DATA : TOCk 1 31 3501 3502 3503 3504 3505 .02 3800 3506 390 30 507 3508 4 1 0305 0 9 4 2 0 03 5 1 0 0.06 00 3700 4000 351 1 3512 4 5 0305 1 3 3514 47003515 4300 3516 3S17 5 0 03 05 1 8 3519 5 2 0 03 5 2 0 4800 4900 : 0.02 0.03 0.02 0.02 i 3521 3522 I 3523 I 3524 I 3525 5300 i 5800 5900 6000 6100 0.17 0.20 0.18 0.07 : 0.19 6300 : 0.16 I 3526 : 0.01 I 3527 : 0.01 I 3 5 2 8 : 0.03 I 3529 : 0 . 0 16 2 I0 03 5 3 0 I : 0 . 0 3 I 3531 : 0 . 0 4 I 3532 : 0 . 0 3 I 3533 : 0.03 I 3534 : 0 . 06 27 0I 0 3 5 3 5 I : 0.01 I 3 5 3 6 : 0 . 0 9 1 3537 : 0.12 I 3 5 3 8 : 0 . 1 3 I 3539 : 0.10 I 354.0 I 'NON RRWS) DATA A-247 5400 5500 5600 5700 * : 0.11 : 0.09 : 0.20 : 0.23 : 0.10 : : : : 6500 6600 : : : : 6750 : 0.48 6400 6900 7000 7100 7190 0.16 0.22 0.16 0.21 0.31 0.26 : 0.03 : 0.13 : : LATIGO RANCH c m NON RR(US) DATA c c 3 0 0 0 0 0 0 A-249 v) h 3 Y a a e t t t 0 0 i i 4 H3NVtl 0011Vl LATIGO RANCH aim OAB CURDMATOORAMD i 1 I i I ! NON RR(US) DATA A-251 LATIGO RANCH 27b0-075 22bo-oz% 22h0-071 22W-078 27b0-079 2-0-OW 22b0-031 2760-032 27bO-031 27W-OF Z7bO-035 ??bo-036 27h0-031 ??bo-030 22W-039 27643-0W 22bO-OQl 2260-002 ? N n l N 3100 3150 3200 3250 3>00 3350 3bWO 3b50 35w 3S50 3hm 3hSO 3700 3750 3.900 m o 10.1 8b.5 12.1 9.1 9 .l 1.1 235.0 0.2 90.1 32.1 11.9 30.2 1b.5 26.6 32.0 51.0 bU7ll b4>0 b5W b550 b6W 4b50 btm, blVJ 41100 5850 69m bQ50 nm, 77hIl-Oh) 7i'hO-O'tb SflW 5100 77bO-Ob5 21.1 11.0 21.8 l?.2 0.12 0.29 0.1 1.1 11.0 1.3 5.1 0.6 0.6 11.1 0.1 10.1 1.9 2.1 29.1 lW.3 111.9 167.0 231.6 158. I 5162 939.9 150.1 36.5 30.b 50.3 53.1 0.31 0.13 0.32 1.1 3.0 2- 3 2.8 2.9 3.5 1.1 1.2 9.5 15.2 3.0 ?b .6 1.1 0.2 0.2 0.2 0.3 0.2 I .6 9.b b.2 b.1 2.6 0.3 7.b 1.2 0.0 1.0 0.1 0.5 2.1 1.1 12.5 20.1 0.3 1.0 10.0 2.1 0 .e 111.1 l.b l51.0 bb.1 I 1 .G 3.1 0.1 6.2 1.1 3119.3 27.1 10.2 0.2 1 .o 6.1 1.5 51.6 0 .9 1.6 1.1 19.2 50.2 51 .O 1.3 1.2 0.1 O.? 5.1 19.1 779.b 1712.3 5R5.2 75v .o I21 .b 3.1 110.2 150.1 90.5 102.1 116.9 100.9 117.0 93.2 01 .o 35 .O 50.0 102.9 111.1 3.0 30.1 LO50 1100 b I 50 b 700 b250 5 n .2 3.2 n .o 0.3 b o 0 27W-Ob1 77b0-015 22643-Obb b .5 11.2 1.9 91.1 1.O 52.2 132.1 R2.b 27b0-0Q3 2.1 1.9 0.6 1.b bb.9 0.0 15.3 1.2 10.5 b3W 1 .v 2.1 ?.9 5 .2 3.3 0.9 2.1 1.2 0.9 0.0 1 .9 1n.e uno 11.6 1.9 1.9 3.1 2.1 2.0 4.5 3.9 3.9 17.3 3950 22bO-Ob0 27b0-019 I2hO-OW 27bO-051 2260-052 2260-053 27bO-051 ZZW-055 2260456 2260-051 2260-050 2W+9 27W-OhO 27bO-Ob1 27bO-Oh2 1.o 1.2 7.b 0.9 1.1 JPW 2760-011 6.1 0.7 0.b 0. I 0.0 0.v 0.2 b .7 1.o 2.2 1.6 2.5 0 .l 19.1 3.6 3.1 2.1 2.1 1.0 0.0 1.6 0.9 1.b 1.0 1.3 0.9 1.2 13.0 b.1 1.3 5.1 2.1 1.l 3.9 0.9 1.1 1.1 0.b 0.1 1.1 0.1 b .6 8.1 v.0 7. I 3.5 31.3 315.0 110.1 127.8 201 -9 121.I 118.1 253.8 211.6 137.q 205.9 291.0 165.9 923.3 w3.9 0 I6 .O 710.0 552.8 Ob9.0 551.0 535.5 612.0 300.7 377.0 195.5 b21.0 671.1 5Q7.5 ~n5.0 301. I 313.1 20.I ( 9 .5 15.8 811.6 11.3 lbb.l 8b.5 62.2 39.5 59 -2 3b.5 36.0 bJ.1 51.0 15.6 39.2 50.2 59.1 13P.l 170.2 110.1 111.3 (15.2 111.5 171.1 lR6.3 9 .e 0.1 119.6 6 .O 9.1 1.1 8.1 b.8 1.o 31 -6 31.3 10.2 9.1 11.1 19.2 26.5 16.* 12.9 21.3 321. 3 10.3 11.2 1O.b 11.0 1l.b 5.1 31 .O 51.1 31.1 712.0 17110.9 Wl. J tlQ.0 21.2 22 .9 23.b 21.1 2l.l 11.1 (5.3 12.6 9.9 I .O 9 -1 5.5 5.1 793.0 15.3 1111.7 18l.b 105.1 97. I 12.1 41.8 13.b 12.1 11.2 19.1 5.3 39.5 12.1 5.1 8.1 b2.0 8.6 50.0 111.2 13.1 I.l 21.0 11.5 5.b 1.o 0.21 0.19 0.55 0.52 0.W 0.11 0.10 0.51 0.38 0.7b 0 .bO 0.20 0.:0 0.21 0.21 0.32 0.25 0.20 0.19 0.21 0.20 0.21 0.29 0.51 0.31 0.51 0.11 0. Jb 0.22 5.3 0.03 1b.b b2.0 $1.5 13.1 13.8 5 .Q Q.b t.s.3 70.1 0.20 ISV 0.00 0.7Q 0.10 0.7: 1J.Z NON RR(US) DATA c c 3 0 0 0 0 0 0 LATIGO RANCH 51 W 1m.1 5200 5250 399.9 550.0 9111.5 tm2.0 615.1 550.3 602.5 75 1A 0a.o 1331.7 1092.0 1203.1 1657.3 m5.3 2517 .5 1115.1 5300 51W 5kW WW 5500 S550 5600 5650 5700 5750 9 1 0 0 m u 5900 5950 11.5 7.3 652 62.9 9.1 7.b 15.5 68.9 1.1 0.0 10.0 3.1 25.b 15.9 2.9 2.9 0.0 0.2 87 .Z 9.7 16.5 30.1 4.5 3.9 1.3 1.7 63.2 6.0 w.3 13.9 68.7 19.1 w1.0 Tl.7 tam 2576.6 280.1 bOW 6100 61 50 bI 70 6200 6250 637.9 lm3.2 137.1 106.0 63W 6350 63bO W00 tA50 6900 6S20 6550 6hW 6662 6670 b7WO 6720 6740 6750 nnw 6900 6Wh 6950 bq70 7nnn 701 6 7n50 7100 1 DATA ObO.0 ll79.0 2011.9 1098.1 68b.l 507 .? ??82 198.1 27% .I OV9.3 2197.5 116.7 352.5 351.0 1990.0 156.2 2.6O.b 1913.9 355.2 166.9 301.6 7766.3 '2a7.1 lWV.8 0179.1 1051.9 19~53.0 155.7 2018.0 2rnl.O 591.3 961.0 2738.0 n15.1 118161.6 1713.5 mn.1 353.0 135.1 bb -9 170.1 601.2 110.9 8778 .6 ant.7.t. 1675.1 znt~8.5 ll56.0 '133.5 1819.0 91m.7 30- .6 1215.1 1102.O li'63.9 ?91.1 2.0 0.b 1.7 1.1 0.2 0.0 0.0 0.1 0.0 3-0 2.6 5 -6 3.0 8.3 7.0 23.9 31 S 21. 1 "3 w1.3 -. ' 1.b 0.3 1.1 1.I 0.5 0.9 1M.b 18.2 71.926.5 87 -5 25.5 1??.6 20.1 5.1 55.1 150.5 2.5 2.1 01.3 06.9 75.3 66.5 lOl.7 91.3 177.9 631.5 (031.2 1160- 1 0 .o 1.0 0.0 0.3 1.1 1.2 17.7 1.6 1.3 lO3.0 1 .5 3.0 2.3 1.O 163.9 19.9 27 -0 0.9 21.o 1.1 53.2 13.0 0 .e 20.0 3.3 3.3 13.5 25.9 W1.b 2.2 2.9 2.5 n .t 91.0 70 .o 3118.6 99.1 553.b 115.7I5.b 638.1 171.8 11u .9 1110.1 23.5 10.5 17.1 21.) 83 .9 17.1 a7.5 13.3 M.l 11.1 m.9 13.8 123.7 56.5 I 3 .2 15.3 21.1 .. 3.9 0.00 3.1 0.5 195.7 378.1 2990.0 397.5 ll1.3 110.5 181.5 1601.7 1735.7 1330.9 2TlT.T 0.00 0.01 1531.0 0807.1 017.7 08 .o T8.1 53.6 (10. I 06.5 310.1 cn.7 161.6 220.3 1126.1 318.0 527 .O ?V8.0 m.7 339.5 1.0 6.3 - r.05 5.7 0.05 l0.D 0.31 22 .o 16.1 11.7 20.b 21.1 32.b 0.63 025 0.22 0.90 OCV 1.20 b77. 1 1o.u 0.w m6.9 10?.9 lb.9 0.19 133.5 151.1 163.a 117.9 ((5.7 m.0 11.1 162.5 20.1 19.5 92.5 121.3 110.7 .* 201.2 98 932.8 l7rn.l 113.1 67.9 " .. 555.2 2ew .7 am.5 05.2 202.3 )opA S-1 31.1 060.0 591.2 115.9 2B15.9 n.a l.@b r.99 0.80 o.*o 0.78 1.22 1.11 W.2 S.7 2098.T 2b.2 555.7 9b9.7 V3.D 30.5 23 .o 21.7 l.?b 1.b1 . a.05 0.02 1.09 1. ln 1112.1 28ttO.b m.l 16.1 5.W 1191.5 26.1 1.13 03.0 03.0 3W.6 3J.2 2b.T b4 Wb5.0 l165.? a.7 32.6 1.11 2.11 56.1 ?7.0 51.7 66.0 mu.1 5.1 P5.l 21.5 -71.7 .. 91.2 1?.5 97.b 563.1 171.0 38.9 15.2 15.0 11.3 11.5 75.7 36 .O 91.b 18.0 111.1 1nn.O 311.5 3.2 30.2 0.96 1.08 0.10 0.15 n5.2 m9.0 1.00.) 1136.5 3.0 6.b 23.6 51.0 71.2 V1.3 1zio.j 1.1 - 0.m 053 wS.0 0.1 1.) 7.5 0.11 0.n 0.01 3.1 707.3 135.9 10.1 16.3 11.0 11.D 3.0 b.1 5.1 vo.1 216.7 200.1 28 3 .O 0.0 9.1 29.1 77 .9 71.1 4.6 OT.3 20.5 19.5 >I 0.7 10.1 90.0 77.0 Y.) 2.?0 1.15 1. J5 2260-111 21bOo-115 2zM)-116 71 50 7190 7190 3090.2 105.6165.6 1lPO.l53.3 780.2 391.2 1315.6 1111 .lam. "d 13.9 1.8 10.0 a. V o l u . el 11.1 0.6 10.6 10.3 e. p 0 u .Illla, 131.0 90.0 m.2 - HW.1 15W.B 1000.8 Tam. of O m tW 0 9 TW.2 350.1 16.2 n.r 22.1 8.9 0.99 0.91 0.91 TABLE A.66 A-255 8 C z L- L z E LY LY h Y cn 3 a a 0 TABLE A.67 LATIGO RANCH W S S OIL COWDSITJOti (2) Less t h r n Frrctfon Cl5+ Frrctton 42.0 58.0 DETAILED C 4 4 7 COY?3SlTlON (N3RY.2) Isohttrne n-B;rtrne lsopentrne n-fenzrne 2.2-Dimcthylbutrne Cy:lopentrne 2,3-Dimtthylbutrne 2-Y,rthylpentrne 3-Ntthylpentrne n-Hexane t!Ethy~Cyt~opcn:rne 2.2-Dimthylpenttne Bmene 2,L-Dinethylpent#ne 2,2,1-'lrl~~thylbutrne tyc~oherrne 3,3-Dimethylpcntrne 1,l-Dic~thylcyctopentrne 2-tk thy1 hcrrne 2,3-Di1wthylper,trne ~.~1~-3-Din~thylc~clopentane 3-Ktthylhexane l,trtn~-3-Din~thy~cyctopentrne 1bt~tnr-t-DimethyWtcyclopentrne 3-fthylpentrne n-h'e;trne lbC~~-2-Dimethyttyc~~pent~ne +!tthytcyttohcrrne Toluene 0.6 1.5 4.5 3.6 0.4 0.4 1.4 5.6 4.0 8.6 7.0 0.5 2.4 1.2 0.5 7.3 0.3 0.9 6.0 0.0 1.4 4.3 1.5 2.2 0.3 7.8 0.3 16.4 8.0 7.56 0.23 1.05 1.08 0 4.6 7.9 e 8.5 2.1 8.2 1.5 8.0 7.5 7.3 6.7 6.2 5.5 5.3 4.3 4.0 3.2 T' P 2.8 2.2 1.42 1.23 I .05 0.42 1.7 1.2 0.7 0.4 0.2 c NON RR(US) DATA c QENERAL CRUDEI#l SIMPSON A-257 0 0 c c TABLE A.68 LITHOLOGICDESCRIPTION GENERAL CRUDE #I SIMPSON 4.490-4.790' 5,010-8.110' Mudstone. reddish brown Some anhydrite Mudstone, reddish brown (some purple) Mudstone, greenish-gray Dark shale. abundant in places Some anhydrite Traces of feldspar A-259 TABLE A.69 TOTAL ORGANXC CARBON DATA GENERAL CRUDE e1 SIMPSON Project SAMPLEIDENTIFICATION RRUS DEPTH (Feet) 4510 901 914 915 902 5 892053 ' 5090 5345 5615 904 6015 905 6125 6 295006 907 6430 6 596106 9 1 76 7 6 5 . : 44905070531055805790- 4530 5110 5380 5650 5860 : 59606070 60906160 6210- 6290 6400- 6 4 6 0 6540- 6580 : 67306600 : : : - No. : R R U S 1 8 4 5 / M 1 8 0 7 / 4 : DATA TOC# SAMPLEIDENTIFICATIO~ RRUS DEPTH ( F e e t ) : : : : : 0.29 0.12 0.18 0.43 0.47 9 0 86 8 8 5 918 919 909 920 : 0.61 : 0.49 910 921 7765 911 922 912 7840 7965 BO40 : 0.31 913 8100 : : 0.72 : 0.68 : 0.99 DATA : TOC# : I 6975 7095 7275 7380 : : : : : 68506920 6940-7010 7060-7130 7240-7310 7360-7400 7580 : : : : 7540-7620 77307800 7820- 7 8 6 0 7930- B O O 0 8020- 8 0 6 0 : 8080- 8 1 200. 5 6 : 0.33 : 0.31 : 0.26 : 0.36 : 0.44 1 : : : : 0.52 0.43 0.61 0.45 0.58 I' TABLE A.70 ROCK-EVAL PYROLYSIS RAW DATA GENERAL CRUDE W l SIMPSON Profcat No. : R R U S 1 8 4 5 l M 1 8 0 7 1 4 ~~ SAMPLE IDENTIFICATION RRUS DEPTH (Feet) 901 902 903 904 9 0651 2 5 6 295006 907 6 898058 7275 909 7 59 81 00 91 1 912 8 190103 DATA ( 5 1 , 5 2 , 8 3 m g l p o f r o o k , % a x d e p C ) 51 s2 53 5 2 / 8 3 Sl/(Sl+SZ) Tmas 4510 5615 5825 6015 : : : : : 4490- 4 5 3 0 5580- 5650 5790- 5 8 6 0 5960- 6 0 7 0 6 0 9 06-1 6 0 0.170 0.070 0.080 0.150 1.280 0.110 0.420 0.330 0.930 ; 6430 : : 62106400685072407540- 6290 6460 6920 7310 7620 0.610 1.780 0.050 0.200 0.670 1.620 4.230 0.280 0.510 1.650 0.640 7820- 7 8 6 0 I 0 . 0 7 0 8020- 8060 I 0 . 0 6 0 8080- 8 1 2 0 I 0 . 1 1 0 0.530 0.610 0.490 0.570 0.510 0.430 : : 7840 8040 : : : ~~~ 0.020 .I. 0.880 1.455 0.330 0.390 0.340 0.610 0.333 1.077 0.971 1.525 0.117 0.154 0.143 0,195 0.139 0.780 1.000 2.077 4.230 0.438 0.911 1.964 0.274 0,296 0.152 0.282 1.082 1.070 1.186 0.090 0.560 0.840 0.289 0.117 0.177 ----------- --402 ------- ------- NOTE: A DASH INDICATES AN INDETERMINABLE VALVE TABLE A.71 HYDROGEN AND OXYGEN INDICES FROM ROCK-EVAL PYROLYSIS AND TOC DATA GENERAL CRUDE # l 5IMPSON Project No. : R R U S 1 8 4 5 I M l 8 0 7 I 4 SAMPLE IDENTIFICATION I I DEPTH RRVS (Feet) I 90 1 902 5 89 20 53 6 091054 6 192055 4510 5615 : : : : : 906 907 90E 909 910 6250 6430 6885 7275 7580 91 1 912 913 7840 8040 8100 : : : : : 44905580579059606090- 4530 5650 5860 6070 6160 HYDROGEN INDEX OXYGEN INDEX TOC ( m g HClgm T O C ) tmg C O Z l g m TOC) I I I I I 441 26 89 54 129 0.43 0.47 0.61 0.72 303 77 83 56 85 238 427 85 142 317 0.68 0.99 0.33 0.36 0.52 115 101 194 156 162 (%) 0.29 I 6210-6290 ' 6850-6920 7240-7310 7540- 7620 I I 6400- 6460 i I I : : : E? 7820-7860 I 8020- 8060 'I 8 0 8 0 - 8120 I 105 91 A-261 80 98 77 0.61 0.58 0.56 TABLE A.72 VISUAL KEROGEN ANALYSIS- REFLECTED LIGHT G E N E R A L C R U D E I1 S I M P S O N 0 P r o j e c t No. : RRU518451M1807I4 I S A M P L EI D E N T I F I C A T I O N RRUS D E P( TF He e t ) 4 95 01 0 : 6015 : 905 6125 9 0662 5 0 911 7840 : : 904 912 913 8040 8100 : : : I R E F L E C T .K E R O G E NC H A R A C T E R I S T I C S I Ro Y Am% Ez% Vlt% I n e r t % F l u o r 4 44 95 03 -0 : 5 9 6 0 -6 0 7 0 I 6090- 6 l b O I 6 2 1 06-2 9 0 : 7820- 7 8 6 0 I 8020- 8 0 6 0 8 0 8 0 - 8120 i 1.01 1.11 1.24 1.25 ---- ---1.35 35 35 30 40 0 0 30 30 LOW Low Low 0 None 0 0 None 40 30 LOW 0 50 0 35 30 0 40 tr 2535 0 0 0 0 15 LOW TOC Ya 0.29 0.61 0.72 0.68 0.61 0.58 0.56 0 0 0 0 I' c c Ad262 GENERAL C R U X # I SItlPSON RRUS No. 001 I D I CTGS. DEPTH 4035.0 Ft 1504.2 n 8 t t t L VALUES Ro tlATURlTY MEAN 31 r : 1.01 0.08 1.01 ; 1.05 I STD DEV t IIEDIAN MODE HISTOGRAnl Ronge: 0- 4% Increment: 0.10% ORDEREDREFLECTANCEVALUES: t0.80 t0.08 t1.04 V l . 1 8 t0.82 t0.98 t1.041.31 1.38 f0.80 tO.OO51.84 *0.90 %0.88 f1.06 tO.OO tl.01 t1.07 50.05 tI.01 tl.10 t0.85 21.02 tl.10 t0.06 t1.02 tI.11 *0.06 t1.02 t1.15 $0.07 tl.03 21.15 KEROGENDESCRIPTJON Amorphous : 35 X Erinirc , ilirinite i lnerrlnlre : Back Fluor GENERALCRUDE x i 15 X Lor I Bltmen Coke E 5i 3 lr z None *I SIWSON RRUS NO. ID I DEPTH . 2 I 004 6915.0 Fr 1933.4 fl Ro nATUR‘TY t 1 I CTGS. VALUES 26 t MEAN STD DEV REDIAIU MODE 1 .. 1. 1. 8 0.08 1.10 8 1.05 : HISTOGRAPIa V I T R I N I T ER E F L E C T A N C E IRANDOPI X 1 ORDEREDREFLECTANtE VALUES: t0.07 Vl.08 t1.17 I .32 f0.87 11.08 ~1.18 1.32 * I .01 * I .08.* I . a I .33 *1.02 fl.10 tl.22 I . 3 3 tl.03 *l.12 11.24 I .33 * I .05 tl .I2 * I .25 1.34 .t1.05 t1.13 1.28 I .34 t1.06 t1.15 1.29 I .35 Vl.07 t1.15 1.28 t1.07 t1.17 1.31 Range; 0- 4% Increment. 0.103: KEROGENDE5CR:PTION 35 Amorphous 2 Exinite I 0 30 Vlqrinlle t Inert inite I 35 B8Ch I Lor COhe I rr Fluor Bitumen A-263 X X t , None X GENERAL CRUDE . I SIRPSON DEPTH I L t I nEAN STD DEV MEDIAN nODE 0 26 z 1.24 I 8.08 1.26 I .35 t : ? I 1 1 tl .21 :ti33 tl.ll tl.22 t1.35 tl.22 31.35 t1.26 tl.35 t1.27 t1.36 t1.27 31.38 ? I . 18 tl.28 : I . 18 tl.30 V I . 19 tl .30 f1.13 t1.14 :I .I6 t1.16 0 HISTOGRAPI~ Range, 0- 4X Increment, 0.10X KEROGEN DESCR'PTION Amorphous I 30 I 0 Exinite Vitrlnlre I 40 30 Inercini1e 8 ORDERED REFLECTANCE VALUES: 0.88 _ " tl.20 *1.33 PI 1866.8 Rd l l A T U R ' T Y VALUES VITRINITE REFLECTANCE IRANDOPI X1 6'25.0 F t BaCh Fluor Bitumen tohe I 0 X LOW I 7 X X X tr done 0 0 GENERAL CRUDE . I SInPSON RRUS No. ID , 8% P CTGS. I DEPTH I I 6335.0 f r 1330.8 n Ro HATUR'TY t E S VALUES nEAN STD DEV flED1A.N n0DE 34 I 1.25 0.08 1,23 1.35 I I r * HISTOGRAH~ Range: 0- 4% Increment: 0.10% ORDERED REFLECTANCE VALUES: 0.85 ? I .17 0.87 ? I .18 1.01 tt.1a 1.01 t1.18 1.03 tl . I 8 tl.10 t1.20 11.23 t1.23 t1.23 t1.24 t1.26 11.26 .32 ? I .33 tl .34 ? I .34 T1 KEROGEN DESCR'PTION 1.38 1.41 1.43 tl .35 tl.36 ? I . l I ? I .21 11.28 . ." ? I .36 t1.12 t1.31 ? I .36 t 1 . 1 3 tl.22 t1.32 t1 .36 ?I121 ~ t1.16 t1.22 t1.32 c Amorphous t Exinite Vltrinlte Inert inite : Back Fluor Bitumen : t o he : I , : 40 % tr % 35 % 25 X LOW tr c None I .30 c A-264 GENERAL CRUDE D'I 51nPSON RRUS N o . I 0'1 ID CTGS. I DEPTH INSUFFICIENT SAHPLE flATERlAL BEAN P k 8 71348.0 Ft I ~ 7 ~ 9 .n6 I N D. HISTOGRAII~ Range, 0- 4 % Increment: 0.10% VITRINITE REFLECTANCE IRANDDn X 1 ORDERED REFLECTANCE VALUES: KEROGEN DESCR'PTIOti Amorphous I 0 X Exinite I 0 % Vitrinite t 0 X lnertlnite I 0 X Back Fluor Bi tunen Coke GENERAL CRUDE . I : I None Nope None SIflPSON INSUFFICIENT SAHPLE nATERlAL " 00 . 0 1.0 2.0 3 0 VITRINITE REFLECTANCE IRANDDH X 1 ORDERED REFLECTANCE VALUES: 4 0 HISTOGRA~~~I0- 4% Rsnge, Incremenr: E.107, KEROGEN DESCRIPTiON 0 2 Amorphous 8 Exinite 0 X Vlrrlnlte I 0 X Incrtinite t 0 % Each Fluor B i lumen Cohe A-265 , : None None Nore GENERAL CRUDE ~1 . s U SInPSDN z5j RRUS No. ID . I DEPTH 1 nEAN STD DEV nED1AN nODE l0 8'3 I 8'80.0 FI I 2.16B.6 , tl 0 Ro nATURlTY VALUES !g 5 0 0.0 = I C7tS. 46 1.35 0.09 1.35 1.35 : t I 2 0 HlS7OGRAfl: 3.e VITRIKITE REFLECTANCE IRAN30fl X 1 1 .E 2.0 4 0 Ronge E- 4% Increme-1 E.1E.Z ORDERED RiFLECTANfE VALUES. P E.86 Xl.24 t!.32 11.36 11.45 l.E6 11.24 11.32 1: 38 11.45 1.06 71.27 11 .34 11 .38 11 .45 qI.16 11.27 11 .34 11 .41 11 .46 11.18 11.26 1 1 .35 tl .42 11 .47 tl.20 11.29 Tl.35 tl.42 1 1 . 4 8 t1.21 1 1 .30 t1.35 1 1 .42 11 .46 71.21 tl .30 t1.35 11.43 tl . 4 6 t1.23 t1.31 t1.37 11.44 11.55 31.24 % I .31 t1.36 71.44 Bock Fluor Bltumen Core , Lor : lr : ~r c c c A-266 TABLE A.73 COMPOSITION OF S O U R C E R O C K E X T R A C T GENERAL CRUDE ll S I M P S O N Project No. : R R U S / 8 4 5 / M / 8 0 7 / 4 S A M P L EI D E N T I F I C A T I O N ~ I I EXTRACT ~~ ~~ AROM SAT POLARS I pasoentape I ppm e e tD)E P T H R R U S 906 907 7 5 8 09 1 0 6250 6430 I : : : 6210- 6 2 9 0 I 6400- 6 4 6 0 7540- 7 6 2 0 i 4444 5906 2877 49.6 45 .6 55.727.7 8.1 42.3 46.4 8.0 16.6 TABLE A.74 SUMMARY TABLE SHOWINC SELECTED PARAMETERS OF O I L S A M P L E S GENERAL CRUDE X 1 SIMPSON Project No. : R R U S l 8 4 5 l U l 8 0 7 1 4 6 A M PILDEE N T I F I C A T I O N RRUS 9 0662 5 0 907 910 ( DF Ee Pe Tt H) 6430 7580 : : : : EXTRACT I I - -TOC - - -- - SATS YI RAT1 OS Phl Pr I IC:17 IC:18 IPh Prl I 6 2 1 06-2 9 0 I 6400- 6 4 6 0 I 7540- 7 6 2 0 : 0 . 6 5449 .06. 108. 027. 4 3 0.597 45.6 0.25 0.553 55.7 0.27 A-261 0.29 0.34 1.00 0.71 CPI _--_ --_ ---- 0 TABLE A.75 HEAVY HYDROCARBONS NORMALIZED TO 0 1 0 0'U G E N E R A L C R U D E a 1 SIMPSON Project No. S A M P L IE D E N T I F I C A T I O N : RRUSI845IMI807I4 I NORMALIZED n-ALKANES I 0 ! RRUS 906 907 910 D E P(TFHe e t ) 6250 6430 7580 : : : : I 6 2 1 0 -6 2 9 0 I 6400- 6460 I 7540- 7620 I I I R RDUESP(TFHe e t ) C-15 C-16 C-17 C-18 C-19 C-20 C-21 7 . 0 08 . 3 09 . 4 09 . 7 09 . 9 09 . 7 0 1.30 1.30 2 . . 4 0 2.10 2.30 4.30 5 . 6 0 6.10 2 . 9 0 4 . 7 0 6.40 7.60 10.90 1 0 . 6 0 9.20 ~ C-22 C-23 C-24 C-25 C-26 C-27 C-28 I ! 9 0662 5 0 907 910 : 6430 7580 : : 6210- 6 2 9 0 : 8.50 7 . 460. 1 0 4.80 3.50 6400- 6 4 6 0 I 10.60 12.00 11.30 11.80 10.70 7540- 7 6 2 0 ; 1 2 . 7 0 11.80 9 . 7 0 7 . 5 0 4 . 7 0 2.40 8.20 1.70 1.40 6.30 1.10 0 I RRUS 906 907 910 D E P(TFHe e t ) 6250 6430 7580 : : : 6 2 1 0 -6 2 9 0 I 6400- 6 4 6 0 I 75407620 I i R RDUESP(TFHe e t ) 906 907 910 6250 6430 7580 I : : : 6 2 1 06-2 9 0 6 4 0 0 -6 4 6 0 7540-7620 i I I C-29 C-30 C-31 C-32 C-33 C-34 C-35 0 . 7 50 . 5 0 . 3 0 . 1 0 . 4 0 3.50 2 . 1 0 1.50 0.60 1 . 3 01 . 1 0 0.00 0 . 0 0 0.00 0.20 0 . 0 0 0.00 .00 C-36 C-37 C-38 C-39 C-40 PR 0.00 0.00 0.00 PH 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 - 1 . 700. 7 0 0 . 6 0 0.60 1.50 2.10 I' A-268 RRUS L I 2 *I 2 DEPTH 806 : 62% : RRUS (Feet) i DEPTH a. : a10 : 7688 (F-1) : II A L A I :k I II 0 246 KEY RRUS DEPTH A L : 607 : 6430 ( F d ) R GENERAL CRUDE # I SIMPSON I=I08xPristone/TotoI 2=100xPhvtane/Totol 3.Pristone/n-C-17 4=Phytone/n-C-I8 &Prfstone/Phytmne GPCmbon Prsf.Index NORMALIZED DISTRIBUTION OF n-ALKANES A-269 NO. 1 SIMPSON I 0 SAMPLE: RRUS NO. 906 6250 feet P I SAMPLE: =US 6430 feet NO. 907 QASCHROMATOGRAMS OF C15 + SATURATE HYDROCARBON? A-270 NO. 1 SIMPSON 1 SAMPLE: RRUS NO. 910 7580 feet GAS CHROMATOGRAMS OF C16+ SATURATE HYDROCARBONS A-271 0 0 0 0 YATES PETROLUEM CORP.. I1 T-4 CATTLE CO. A-273 0 0 0 I' A-274 TABLE A.76 LITHOLOGICDESCRIPTION YATES T-4CATTLECOMPANY 400- 560' 560950' 950-6.570' 6,570-'7,220' Pink siltstone with abundant calcareous percentage, shale percentage very small. Red sandstone with varyingpercentages of shale (mudstone)andcalcareous pieces. Calcareous pieces are the least abundant, possibly some angular to subangular gypsum. Sandstone, red to pink, clean large pieces of quartz, angular to subangular pieces of light to dark gray. shale, much of the sandstone stuck together with white and green to ochre clays, novisible gypsum, horsver some large calcareous(mudstone) clasts Sandstone-calcareous mudstone, red to pink, shale various colors red, It. to dk. gray. Some rhyoli'r? and quartz pieces. Quartz is sharp and clean. I t is very difficult to determine the percentages of lithologies due to the dirt in the samples, however, the shale is definitely not as abundant as the sandstone. A-275 0 TABLE A.77 TOTAL ORGANIC CARBON DATA YATES # l T.Y. CATTLE C O . P 1 0 5 e e t No. : R R U 5 / 8 4 5 / M l 8 0 7 1 4 SAMPLE IDENTIFICATION RRUS DEPTH (Feet) 435 1301 13021035 1303 1635 13042025 13052520 : : : : : 4 0 04 -7 0 1000-1070 16001670 2000-2050 2500-2540 : I DATA I SAMPLE IDENTIFICATION I ' : TOCW I RRUS I I : : : : 0 0 . 01 53 15 15 3 5 0 . 0 6 I 1 3 1 26 0 3 5 0.06 1313 6320 0 . 2 1 i 1 3 1 46 4 5 5 0 . 3 8 I 13156595 DEPTH : : : : (Feet) DATA .. TOC% i: : 55005 -570 6 0 0 0 -6 0 7 0 63006340 6 4 2 0 -6 4 9 0 6 5 8 0 -6 6 1 0 0.30 0.14 : 0.35 : : : : 6 7 3 0 -6 7 7 0 1 0.20 6 8 6 0 - 4 9 0 0 : 0.16 6 9 5 0 -6 9 6 0 : 0.16 7 1 7 0 -7 2 3 0 : 0.23 : 0.25 : 0.38 I 1 3 0361 2 0 3535 1307 1308 4025 1309 4535 1310 5035 : : : : : 3 0 7 03-1 7 0 3490- 3 5 8 0 3990- 4060 4500- 4 5 7 0 5000- 5070 0 . 0 7 i 1 3 1 66 7 5 0 0 . 0 9 I 1 3 1 76 8 8 0 0 . 0 4 I 13186955 0 . 0 g I 1 3 1 97 2 0 0 0.08 0 0 I I 0 0 A-276 TABLE A.78 ROCK-EVAL PYROLYSIS RAW DATA YATES # l T.H. CATTLE C O . Project No. : R R U S 1 8 4 5 l M 1 8 0 7 1 4 I SAMPLE 1DENTIFICA.TION I DATA ( S 1 , 9 2 , 5 3 mglgm of r o c k , Tmax d e g C) I RRVS DEPTH (Fast) I 51 52 83 8 2 / 5 3 8 1 1 ( 5 1 + 5 2 ) Tmax I I 1304 1305 1311 1313 1315 2025 2520 5535 6320 6595 131 66 750 1319 7200 : : : : 20002500550063006580- : : 6 7 3 06-7 7 0 71707230 : 2050 2540 i I 5570 I 6340 I 6610 I I 0.050 0.030 0.060 0.070 0.360 0.160 0.140 0.080 0.160 0.340 0.020 0.060 0.080 0.170 0.130 0.111 0.600 0.314 0.318 0.460 0.630 0.600 0.510 0.440 0.520 0.455 0.222 0.193 0.333 0.176 0.32 07 .320 0 . 7 506. 3 2 0 0.450 --------------- fi NOTE: A DASH INDICATES AN INDETERMINABLE VALUE. TABLE A.79 HYDROGEN AND OXYGEN INDICES F R O M ROCK-EVAL PYROLY6IS AND TOC DATA YATES # I T , V . CATTLE CO. Project No. : R R U S 1 8 4 5 I M 1 8 0 7 1 4 ~~~ SAMPLEIDENTIFICATION I I RRVS DEPTH (Feet) I I HYDROGEN INDEX (mg HClgmTOC) OXYGEN INDEX (mg COZlgm TOC) TOC (H) 8 1304 1305 1311 1313 1315 2025 2520 5535 6320 6595 : : : 2000- 2 0 5 0 2500- 2540 5500- 5 5 7 0 6300- 6340 6 5 8 0 -6 6 1 0 : : 67306770 7 1 7702-3 0 : : I I I I I 29 18 120 46 37 219 166 200 146 116 0.21 0.38 0.30 0.35 0.38 260 196 0.23 I 1316 750 1319 7200 I : I 85 0.20 148 A-277 e TABLE A.80 VISUAL KEROGEN ANALYSIS - REFLECTED LIGHT Y A T E S # 1 T.q. CATTLE C O . 0 Projeot No. : R R U S / 0 4 5 / M l 0 0 7 / 4 SAMPLE IDENTIFICATION RRUS R E F L E C T .K E R O G E NC H A R A C T E R I S T I C ST O (Feet) DEPTH RO U Am% C Ex# V i t Y InortU Fluor % - 1305 1311 1313 2520 5535 6320 1315 6595 : : 1316 6750 : : : 1319 7200 : 2500- 2 5 4 0 5500- 5570 6300- 6340 6 5 0 0 - 6610 6730- 6770 71707230 ”” 25 0.73 ”” 0.96 0.95 I I .I . ”” tr tr 0 tr 0 0 tr 40 0 455 5 0 20 35 2205 0 0 0 0 35 0 None None None None 0.38 0.30 0.35 0.38 0.20 None 0.23 ne6 0 a a 0 I’ A-270 YATES 1.4. CATTLE CO. SI 25 RRUS NO. ti ID I 1305 I CTCS. DEPTH I 2070.0 630.0 I N.D. I BARREN nEAN Ft I I E S 0 ,...,,....I..,. O.e ,,,, .,,, 2 . 0I . 0 ' , I , , ,,,, 3.0 I HISTOGRAII: Range: 0- 4 % Increment, 0 . l E X 4.0 VITRINITE REFLECTANtE IRANDOn X 1 ORDERED REFLECTAHCE VALUES: KEROGEN DESCRlDTlOh tr x Amorpnous t Expnite I 0 x Virrinire I tr X Inerrinite I 0 X 0.0e Back Fluor B i lumen Coke YATES S I 1.V. I I 9 None None None CATTLE CO. RRUS No. ID : 1311 CTCS I DEPTH I I E035.0 1534.7 Ro IIATUfilTY I E n VALUES IIEAN STD DEV MiDlAN MODE I 6 3 0.73 : 0.11 0.70 0.E5 I 8 5 0 VITRINITE REFLECTANCE IRANDOII XI ORDERED REFLECTANLE VALUES: X0.50 HISTOGRAII~ Range. 0- 4 % Increment E.10X KEROGEN DESCRIPTION 25 X Amorphous 8 I tr X Exinire 40 X Vitrinite I lnerr inire I 35 X Boch Fluor Eit m e n Coke A-279 : None I tr . tr Ft n YATES 25 20 T.Y. SI CATTLE CO 1 _I RRUS ID : No. , 1313 CTCS. DEPTH 15 t 6170.0 F I 1880.6 n I N.D. 8 INSUFFICIENT SAnPLE nATERIAt MEAN HlSTOGRAM: Range> 0- 4 % Increment. 0.10% ORDERED REFLECTANCE VALUES. KEROGEN DESCRIPTIO& tr X Amorphous I Exinlte : 0 x Virrinite : 0 f Inertlnlre , 0 x Back Fluor B i lumen Cohe I None Nore 1 Nono : 0 0 0 YATES SI T.Y. CATTLE CO. RRUS No. I 1315 ID I CTGS. DEPTH . : : := * RO nATmITy VALUES V iAN SlD DEV MEDIAN MODE .0 VITRINlTE REFLECTANCE (RANDOM XI ORDERED R E F L E C T A K E VALUES. 20 80 tl.02 t0.83 tl .03. $0.84 :I .06 f0.85 tl .07 20.86 :I .08 tE.89 * I .15 f0.QI :I 15 t0.82 f0.82 6515.0 Ft lF85.8 fl I 17 a 0.86 0.11 e.82 0.85 : I : HISTOGRAM; Range. 0- 4 2 Increment. @.I01 V' KEROGEY DESCRIPTlOk Amorphous I 45 X Exinite : 0 % 35 f Vlrrinlre I lnertinite I 20 X Back Fluor ned Elrumen Cohe f0.98 A-280 : I tr tione YATES 81 T . M . CAllLE CO. RRUS No. ID I , 1316 ClGS. DEPTH 6815.0 Ft 2877.2 n t t . S i 5] J& ,.,,, 0 0.0 = Ro nATURITY VALUES MEAN t SfD DEV r nED!AN I noDE ............................ 1.0 3.0 2.0 VJTRJNITE REFLEClANCE IRANDOn X 1 4.8 . ORDERED REFLECTANCE VALUES: S0.83 X 1 .06 S0.85 :1.07 S0.86 1 1 .I0 13 t 0.85 0.08 0.80 0.85 > HJSTOGRAH: Rnnge: 0- 4 2 Incremenr, E.102 KEROGEN DESCRIPTION 55 X ~morDnous I Exinire : 0 X Vitrlnlte I 25 X lnertinite : 20 x ~0.87 BDCh Fluor None Bitumen : None Co he , tiope SI .08 $1.03 YAlES . I - 0 0.0 1.H. CATTLE CO. 2 0 4.0 3.0 VJTRJNITE REFLEClANCE IRANDOn XI 18 ORDERED REFLEClANCE VALUES: HJSTOGRAn: Rnnge: 0- 4% Jncremenr: 0.10% KEROGEN DESCR'DTION 0 Amorphous I Exinlte : E Vltrlnlte I 0 lnertlnite 0 Bsch Fluor 8 i rumen Cohe A-281 8 None None : honP I t X X X TABLE A.81 COMPOSITION OF SOURCE R O C K E X T R A C T YATEE a 1 T.N. CATTLE Project No. R R U S( F e e t )D E P T H : 71230109 71707230 I a : RRUSl8451HlB~714 I I EXTRACT 1 I ppm I S A M P L EI D E N T I F I C A T I O N co. BAT POLARS percentage 6114.4 3 TABLE AROH a 1270..79 4 A.82 SUMMARY TABLE SHOWING SELECTED PARAMETERS OF OIL SAMPLES Y A T E S t l T.Y. CATTLE CO. P r o f e o t No. : R R U S l B 4 5 l M 1 0 0 7 1 4 SAMPLE IDENTIFICATION I I RRUS ( F e eDtE)P T H -E -X -T -R -A-C-T . SAT5 n TOC PI1 IC:17 RATIOS Phl Pr I CFI IC:18 IPh 0 ~~ 1319 7200 : 71707230 : 0.627 61.4 0 . 07 .1 7 2 0.71 --__ 0 c I' A-282 TABLE A.83 H E A V Y H Y D R O C A R B O N 3 N O R M A L I Z E D T O100% YATES # l T.Y. CATTLE CO. Project N o . : R R U S 1 8 4 5 1 M J B 0 7 J 4 S A M P LIED E N T I F I C A T I O N I I DEP( TF Heet) I I C-15 C-16 C-17 C-18 C-19 C-20 C-21 : 0.60 RRUS : 13197200 RRUS : 1319 7200 I I 71707230 : i I D E P T H( F e e t ) 1319 7200 RRUS I D E P T H( F e e t ) 1 3 17 92 0 0 RRUS 7170-7230 7 1 7 07 -2 3 0 : 3.30 8 . 5 0 1 1 . 8 03 . 2 02 1 . 4 01 5 . 7 0 C-22,C-23C-24C-25C-26C-27C-28 12.77 0.30 6.20 3.30 2.10 1.30 C-29 C-30 C-31 C-32 C-33 C-34 C-35 i 0.60 I . NORMALIZED n-ALKANES I (Feet) I DEPTH . 0.50 0 . 30 . 3 0 0.00 C-36 C-37 C-38 C-39 C-40 0.80 0.00 0.00 PR PH 6.00 8.50 1 I 71707230 I I 0.00 0.00 A-283 0.00 0.00 0.00 KEl NORHALIED DISTRIBUTION OF n-ALKANES i A-284 T-4 CATTLE CO. I SAMPLE: 7200 feet RRUS NO. 1319 GAS CHROMATOORAMS OF C l S + SATURATE HYDROCARBONS A-285 0 0 0 0 0 0 c c c OILS A-207 0 0 0 c TABLE A.84 OIL COMPOSITION AND API GRAVITIES . OILS Project Nc. : RRUSl845lM180714 I I S A M P LIED E N T I F I C A T I O N RRUS (ID) SAMPLE API SAT I P U L A RASR O M I GRAVITY I percentage I 3401 3402 3403 3404 3405 B.T. E A S23.7 TB I L L Y 72.8 I B . T . # l NETTLES I I B . T . B I L L Y DSTl 1A L A T I G OR A N C H B.T.BILLY 39.6 40.3 46.7 62.6 I 47.2I 46.0 94 . B 31.7 26.7 3.2 21.8 I I 32.6 51.6 36.4 M AMYA3FR4I.0E6L D 66.6 42.5 3.5 5.7 6.7 2.0 31.0 12.0 TABLE A.85 SUMMARY TABLE SHOWING SELECTED PARAMETERS OF OIL SAMPLES OILS Projact No. : RRUS18451M180714 SAMPLE IDENTIFICATION RRUS SAMPLE (ID) 7I I 1 MAR. MAYFIELD -””” TOC ---------- 3401 B.T. EAST BILLY 3402 B.T. a 1 NETTLES DSTl 3 4B0.3T . B I L L Y 3404 LATIGO RANCH 1 A B . T3.4B0I5L L Y 3406 E XRTBARATAT1CST ---- ”” I I I. ---- % OS Prl Phl Pr I C :I1C7:IlP8h CP I I 72.8 0.84 0.96 0.95 0.93 62.6 66.6 94.8 47.2 1.04 0.86 0.10 0.82 1.25 0.83 0.11 0.95 0.88 1.ll 1.00 1 .O4 ---- 5 11..67 5 1 .17.80 3 0.93 1.14 ”” 1.08 TABLE A.86 0 H E A V Y H Y D R O C A R B O N S N O R M A L I Z E D T O100% OILS P r o j e o t No. : RRVS1845/M1807/4 I S A M P L IE D E N T I F I C A T I O N NORMALIZED n-ALKANES I I RRVS SAMPLE (ID) I I C-15 C-16 C-17 C-18 C-19 3 4B0.1T . EAST BILLY 11.00 12.10 11.30 10.40 I 10.50 11.40 11.00 10.30 B . T .0 1N E T T L E S 3402 I 10.70 11.70 11.70 10.90 DST1 3 4B0.3T . B I L L Y 0 . 8 90 . 1 0 3 4 0L4A T I GROA N C H 1A I 10.40 1 0 . 2 9 9.90 9.90 9.70 8.50 C-20 C-21 8.80 9.30 9.10 6.90 7.20 6.90 8.00 7.50 9.00 6.70 7.40 I B . T3.4B0I5L L Y 3406 I 14.30 12.80 11.40 10.50 1 0 . 0 0 M AMRA.Y F I E L D I 9.50 9.60 9.20 8.80 8.90 9.20 2.60 2.00 1.60 I 3405 3406 B.T.BILLY M A RM.A Y F I E L D I I 6 . 2 0 4.80 3.50 7 . 460. 140. 930. 630. 020. 4 0 1.20 1.90 I RRVS SAMPLE (ID) B . T3.4B0I5L L Y 3.406 RRUS M AM RA .Y F I E L D S A M( PI LD E) 3401 B . T . EAST BILLY B . T . 01 N E T T L E S 3402 3 4B0.3T . B I LDLSYT l 1A 3 4 0L4A T I GROA N C H B . T3.4B0I5L L Y 3 4 0M6A RM.A Y F I E L D I I C-29 C-30 C-31 C-32 C-33 C-34 c-35 I 1.20 2.10 : I I I 0.90 1.60 0.60 1.40 0.40 0.80 0.20 0.70 0.00 0.40 0.00 0.40 PH C-36 C-37 C-38 C-39 C-40 PR 4 I I I : : : 0.00 0.20 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 0 0 9.50 1 0 . 0 0 0 . 0 0 11.4012.90 0 . 0 0 1 0 . 1 09 . 1 0 0 . 0 0 1.00 1.00 0.00 0.30 0 . 0 00 . 0 0 0.00 0 . 0 0 0.00 0.00 0.00 9.30 10.00 0 . 0 0 16.10 15.70 A-290 OILS SAMPLE: RRUS NO. 3401 #1 EAST BILLY'S CREEK 1 SAMPLE: RRUS NO. 3402 # I NETTLES ~ GAS CHROMATOGRAMS OF C15 A-291 ~~ ~~ ~ + SATURATE HYDROCARBON:? OILS 0 0 1 0 SAMPLE: RRUS NO. 3403 #1 BILLY'S CREEK, CST.1 0 I,I !1 b A-292 OILS SAMPLE: RRUS NO. 3406 MAR. .MAYFIELD GAS CHROMATOWtAMS OF C 1 6 + SATURATE HYDROCARBONS A-293 0 A L 0 I I 11 ? L R C E * I 0 T KEV N CU AM RB I EORN RRUS : SWLE g a. P . M I A L 3482 I KEY YC UA MR II LOPN I B.T. # I NETTLES ( I D ) ' h R ! ":k 0 A 1 e CAIIOON NUIIOLR 0 a4Ed KEY 0 c OILS I-IWdxPrIstdotoI PI0ExFhytone/Totol Wrimtmn./n-C-I7 &Prirtm/Phytm. 4EPhytmln-C-18 &Corbw, Prd.1nd.x NORMALIZED DISTRiBUTION OF rrAU(AMS A-294 I' TABLE A.07 tXST OF ABBREVIATIONS USED IN GASOLINE RANCE HYDROCARBONSDATA TABLE COMPONENT DEFINITION METHANE ETHANE 3 . PROPANE 4. I-BUTANE 5. n-BUTANE 6. I-PENTANE 7. n-PENTANE a . 2.2 DMB 9 . CP 10.2,3 DMB 11. 2 UP 1 2 . 3 MP 13. HEXANE 1 4 . ncp IS. 2.2 DMP 16. a , 4 DMP 17. BENZENE l a . CH 19.3.3 DMP 20. 2 MH METHANE ETHANE PROPANE 160-BUTANE norml-BUTANE I.0-PENTANE normal-PENTANE 2 , 2 DX-METHYL-BUTANE CYCLO-PENTANE 2.3 DX-METHYL-BUTANE 2 METHYL-PENTANE 3 METHYL-PENTANE HEXANE METHYL-CYCLO-PENTANE 2,2 DI-METHYL-PENTANE 2 , 4 DX-METHYL-PENTANE BENZENE CYCLO-HEXANE 3.3 DX-HETHYL-PENTANE 2 METHYL-HEXANE 1. 2. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 2.3 DMP 1 , l DMCP 3 MU 1-0-3 DMCP 1-t-3 DMCP 2,3 DI-METHYL-PENTANE 1 . 1 DI-METHYL-CYCLO-PENTANF 3 METHYL-HEXANE 1-Cis-3 DX-METHYL-CYCLO-PEhTANE 1-trans-3 DI-METHYL-CYCLO-FENTANE 1-t-2 DMCP 3 EP 1-trans-2 DX-METHYL-CYCLO-FENTANE 3 ETHYL-PENTANE HEPTANE MCU ECP TOLUENE HEPTANE METHYL-CYCLO-HEXANE+(l-0-2 DMCP) ETHYL-CYCLO-PENTANE a TOLUENE tr : na : * : TRACE AMOUNT DETECTED((0.1%) COMPONENT RATIO NOT AVAILABLE CO-ELUTINC COMPONENTS A-295 0 TABLE A.88 ~~ ~~ INDIVIDUAL COMPONENT CONCENTRATIONS IN GASOLINE RANCE HYDROCARBONS OIL5 P r o j e c t No. : R R U S 1 8 4 5 l H 1 8 0 7 1 4 RRUS : 3 4 0 1 ID : B.T. EAST BILLY ””” COMPONENT COMPONENT Y ””_”” 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. COHPONE?IT % “”””_ METHANE ETHANE PROPANE 1-BUTANE n-BUTANE I-PENTANE n-PENTANE 2 , 2 DMB CP 2,3 DMB 2 UP 3 MP HEXANE 1 4 . MCP 1 3 .2 , 2 DMP 1 6 .2 , 4 DMP 1 7 . BENZENE 1 8 . CH 1 9 . 3 , 3 DMP 2 0 . 2 MH 2 1 .a , 3 DMP 2 2 .l , l DMCP 0.0 0.0 12. 13. 0.0 0.2 0.1 3.0 0.2 0 .4 0.3 1.4 3.5 Y ”-””” 3.4 0.9 2.6 2.6 0.0 0.1 7.8 0.3 5.6 0.0 6.0 23. 3 MH 1-0-3 DMCP 24. 1 - t - 3 DMCP 26. 1 - t - 2 DPICP 2 7 . 3 EP25. 2.9. HEPTANE 2 9 . MCH 3 0 . ECP 3 1 . TOLUENE 5.5 3.8 3.6 4.7 4. . 7 ~ . 2.5 32.2 0.6 2.1 RAT I OS ”” ” ~~” 1 . 1-BUTANE I n-BUTANE 2 . i-PENTANE I n-PENTANE 3 . CP I 2.3 DMB 4 . 2 MP I 3 MP 5 . HEX I (MCP + 2 , 2 DMP) 6. 2 - nn ”” -2 ..4- I 1.9 10.9 - DMP -. . 7 . 3 MH I ( 1 , l DMCP + l - o - , 3 DMCP) 0 . 1 - t - 3 DMCP I 1 - t - 2 DMCP 9 . CH I ( 1 , l : + 1 - 0 - 3 : + 1 - t - 2 : + 1 - t - 3 : DMCP ) 1 0 . (HEX + HEP) I 3 M H 1 1 . (CH + 1 - 0 - 2 DMCP + MCH) I 3 MH 1 2 . CH I (MCH + 1 - 0 - 2 DMCP) 1 3 . (MCP + 2 . 2 DMP) I (MCH + 1 - 0 - 2 DMCP ) RRVS : 3 4 0 2 0 0.2 1.0 0.1 7.0 0.5 0.7 0.4 0.6 7.1 0.2 0.1 0 ID : B.T. e 1 NETTLES ””” w COMPONENT “””“- 1 . METHANE -2. 3. 4. 5. 6. 7. 8. ETHANE PROPANE I-BUTANE n-BUTANE I-PENTANE n-PENTANE 2 , 2 DMB 9 . CP 1 0 ; 2;3 DMB 1 1 . 2 MP COMPONENT COMPONEYT Y 0.0 0.0 0.0 0.2 0.1 3.7 0.5 0.3 0.3 1.8 3.3 1 2 . 3 MP 1 3 . HEXANE 1 4 . MCP 1 5 .2 , 2 DMP 1 6 .2 , 4 DMP 1 7 . . BENZENE 1 8 . CH 1 9 .3 , 3 DMP 2 0 . 2 MH 2 1 . a , 3 DMP 2 2 .1 , 1 DMCP u ”^””” ””””_ 3.4 0 . 9 3 . 1 3.1 0.9 0.6 0.9 0.3 4.6 0.0 5.1 23. 24. 25. 26. 27. 28. 29. 30. 31. 3 MH 1-0-3 1-t-3 I-t-2 3 EP DYCP DYCP DYCP 5. 4. 4 . 5. 5. 2. 26. 0 . 5. HEPTANE HCH ECP TOLUENE v‘ P RATIOS ””” 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. I-BUTANE I n-BUTANE I-PENTANE I n-PENTANE CP I 2 , 3 DMB 2 MP I 3 PIP HEX I (MCP + 2 , 2 DMP) 2 M H I 2 , 4 DMP 3 HH I ( 1 . 1 DMCP + 1 - 0 - 3 DMCP) 1 - t - 3 DMCP I 1 - t - 2 DMCP CH I ( 1 , l : + 1 - 0 - 3 : + 1 - t - 2 : + I-t-3:DMCP) (HEX + HEP) I 3 M U (CH + 1 - 0 - 2 DMCP + MCH) I 3 MH CH I (MCH + 1 - 0 - a DMCP) (MCP + 2 , 2 DMP) I (MCH + 1 - 0 - 2 DMCP) A-296 ’ 1.6 7.5 0.2 0.9 0.1 5.0 v’ 0.5 0 0 0 7 0 0 . 7 .4 .6 .0 . 3 .2 c . INDIVIDUAL COMPONENT CONCENTRATIONS IN GASOLINE RANGE HYDROCARBONS OILS P r o j e c t No. RRUS : : RRUSI045lM1007/4 ID : B.T.BILLY DSTI 3403 ””” COMPONENT COMPONENT # ””-”” I . METHANE ETHANE PROPANE I-BUTANE n-BUTANE 6 . I-PENTANE 7 . n-PENTANE 8 .2 , Z DMB 9 . CP 1 0 . 2 , 3 DMB 1 1 . 2 MP 2. 3. 4. 5. !h ”-””” ~~ 0.0 0.0 0.0 0.2 0.7 2.4 1.9 0.5 0.3 0.9 2.6 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 3 MP HEXANE MCP 2 , 2 DMP 2 , 4 DMP BENZENE CH 3 . 3 DMP 2 MH 2 , 3 DMP 1 , l DMCP 2.5 3.0 2.2 2.2 0.6 2.4 7.3 0.2 4.7 0.0 3.4 COMPONE‘tT 23. 3 MH 2 4 . 1 - C - 3 DXCP 2 5 . 1 - t - 3 DXCP 2 6 . 1 - t - 2 DNCP 2 7 . 3 EP 2 0 . HEPTANE 2 9 . MCH 3 0 . ECP. 3 1 . TOLUENE w 4 2 2 3 3 . . . . . 5 6 4 9 9 6.6 23.5 0.7 13.6 RAT1 OS ””” 1. I-BUTANE I n-BUTANE I-PENTANE I n-PENTANE CP I 2 . 3 DMB 2 UP I 2 MU iiEX‘l.tkP’+ 2 . 2 DMP) 6 . 2 MH I 2 , 4 DMP 7 . 3 MH I ( l , l DMCP + 1 - C - 3 DMCP) 8 . I - t - 3 DMCP I I-t-2 DMCP 9 . CH I ( 1 , l : + 1 - 0 - 3 : + 1- t - 2 : + l - t 1 0 . (HEX + HEP) I 3 MU 1 1 . (CH ~+ l - c L i DMCP”; MCH) I 3 MH 1 2 . CH I (MCH + 1 - C - 2 DMCP) 1 3 . (MCP + 2 , 2 DMP) I (MCH + 1 - c - 2 DMCP RRUS : 3 4 0 4 ID : LATICORANCH 1A COMPONENT # COMPONENT !h 2 3 4 5 0.3 . . . . 1.2 0.4 : DMCP ) ~ 1.0 0.6 7.4 0.7 0.6 0.5 2.1 6.0 0.3 0.2 ”“” -”””” 0.0 0.0 0.0 2.3 4.7 10.6 9.5 0.4 0.4 1.4 5.5 12. 13. 14. 15. 16. 17. 10. 19. 20. 21. 22. 3 MP HEXANE MCP 2 , 2 DMP 2 , 4 DMP BENZENE CH 3 , 3 DMP 2 MH 2 . 3 DMP l , l DMCP 3.5 10.3 2.4 2.4 0.6 1.6 4 . 1 0.1 4.5 0.0 tr 23. 24. 25. 26. 27. 20. 29. 30. 31. 3 MH 1-0-3 DYCP 1-t-3 DP’CP 1 - t - 2 DFCP 3 EP HEPTANE MCH ECP TOLUENE I-BUTANE I n-BUTANE I-PENTANE I n-PENTANE CP I 2 , 3 DMB 2 MP I 3 MP HEX I (MCP + 2 . 2 DMP) 6 . 2 MH I 2 . 4 DMP 7 . 3 MH I ( 1 , l DMCP + 1 - c - 3 DMCP) 8 . 1 - t - 3 DMCP I 1 - t - 2 DMCP 9 . CH I ( 1 , l : + 1 - 0 - 3 : + 1-t-2: + I-t-3:DMCP) 1 0 . (HEX + HEP) I 3 MH 1 1 . (CH + 1 - 0 - 2 DMCP + MCH) I 3 HH 1 2 . CH I (MCH + 1 - c - 2 DMCP) 1 3 . (MCP + 2 , 2 DMP) I (MCH + 1 - c - 2 DMCP) 1. 2. 3. 4. 5. A-297 C.5 1.1 c.3 1.5 2.1 1 . 4 na 1.1 1.7 6.6 4 . 3 0.3 0 . 4 3.4 0.8 0.0 0.7 0.7 12.2 10.7 0.4 5.7 0 INDIVIDUAL COMPONENT CONCENTRATIONS IN GASOLINE RANGE HYDROCARBONS OILS P r c j e c t No. : RRUS1845lM180714 RRUS : 3405 -””- COMPONENT ID : B.T.BILLY w COMPONENT w COMPONE\‘T -”””” 1. 2. 3. 4. 5. 6. 0.0 0.0 0.0 2.2 10.9 9.6 14.2 0.1 1.2 0.5 5.2 7. 8. 9. 10. 2,3 DME 11. 2 MP 3 MP HEXANE MCP 2 , 2 DMP 2 . 4 DMP BENZENE CH i-,~3DMP 2 0 . 2 MH 2 1 . 2.3 DMP 2 2 . ‘1,l DMCP 12. 13. 14. 15. 16. 17. 18. 19. . w ””””_ 3.2 7.7 0.2 0.2 0.3 0.4 4.6 tr 3.3 0.0 0.9 2 3 . 3 EIH 1-0-3 DYCP 2 5 . 1 - t - 3 DYCP 24. 26. 27. 28. 29. 1-t-2 3 EP DYCP HEPTANE MCH 3 0 . ECP 31. TOLUENE RATIOS 1 . I-BUTANE I n-BUTANE 2 . I-PENTANE I n-PENTANE 3 . CP I 2 , 3 DMB 4 . 2 MP I 3 MP 5. HEX I (MCP + 2 , 2 DMP) 6. 2 nu I 2 , 4 DMP 7 . 3 MH I ( l , l DMCP + 1-0-3 DMCP) 8 . 1-t-3 DMCP I 1-t-2 DMCP 9 . CH I ( 1 , l : + 1-0-3: + 1-t-2: + 1-t-3:DMCP) 10. (HEX + HEP) I 3 MH 11. (CH + 1 - 0 - 2 DMCP + MCH) I 3 MH 1 2 . CH I (MCH + 1 - c - 2 DMCP) . 13. (MCP + 2 , 2 DMP) I (MCH + 1-0-2 DMCP ) RRUS : 3406 ID : MAR. MAYFIELD “&”” COMPONENT w COMPONENT w 3.4 2.1 0.2 0.1 0.1 6.3 9.8 0.4 1.8 0 ””” “”””_ 3. 4. 5. 6. 7. 8. 0 .. 10. 11. 0.2 0.6 2.3 1.6 17.6 10.6 1 .o 1.2 1.3 4.1 4.2 0 0.4 na % ”””_” 1. METHANE 2. 0 0.0 1 2 . 3 MP 3.8 2 3 . 3 MH ETHANE 0.0 13. HEXANE 4.0 2 4 . 1-e-3 DMCP PROPANE 0.0 14. MCP 2 5 . 1-t-3 DMCP 0.5 1-BUTANE 0.2 I S . 2 , 2 DMP 0.5 2 6 . 1-t-2 DMCP &BUTANE 0.5 1 6 . 2 . 4 DMP 0.3 2 7 . 3 EP I-PENTANE 3.0 1 7 . BENZENE 0.4 2 8 . HEPTANE n-PENTANE 2.9 1 8 . CH 3.0 2 9 . MCH 2 , 2 DMB 0.1 1 9 . 3 , 3 DMP 0.1 3 0 . ECP r.P 2 0 . 2 MH 4.5 0.9 3 1 . TOLUENE 2,3 DME 0.3 2 1 . 2 , 3 DMP 0.0 2 MP 4.0 2 2 . 1 , l DMCP 1.8 RATIOS 1 . I-BUTANE I n-BUTANE 0.4 2 . i-PENTANE I n-PENTANE 1.o 3 . CP I 2 , 3 DMB 2.9 4 . 2 MP I 3 MP 1.0 5 . HEX I (MCP + 2 , 2 DMP) 4.0 6 . 2 MH I 2 , 4 DMP 13.9 7. 3 MH I ( 1 , l DMCP + 1-c-3 DMCP) 0.6 8 . 1 - t - 3 DMCP I 1-t-2 DMCP 0.9 9 . CH I ( 1 , l : + 1 - 0 - 3 : + 1-1-2: + 1-t-3:DMCP) 0.1 1 0 . (HEX + HEP) I 3 MH 1.9 11. (CH + 1-0-2 DMCP + MCH) I 3 MH 2 . 8 12. CH I (MCH + 1-c-2 DMCP) 0.2 13. (MCP + 2 , 2 DMP) I (MCH + 1-0-2 DMCP) na ” ””” 5.8 7.4 7.0 7.4 7.4 7.0 13.1 1.7 2.1 c c c t A-298 TABLE A.89 G A S O L I N EH Y D R O C A R B O N S T h o m p s Io n d l o e s I I I P r o j e c t : RRUS1845lM180714 T i t l e : OILS ~ RRUS SAMPLE 3401 3402 3403 3404 3405 (ID) B.T. EAST BILLY B.T. 0 1 NETTLES B.T.BILLY DSTI LATICO RANCH 1 A B.T.BILLY M A 3Y4F0I6E L D M A R . I I I S O - H E HVP EAT PLA TUN AE N E VALUE I I I I : 0.922 0.698 1.023 3.342 2.694 3.312 3.248 10.565 32.206 20.339 I 0.475 10,854 I A-299 0 .TABLE A.90 Classification of oil on the basis of light hydrocarbon composition. I I Limits Petroleum Class Class Isoheptane Heptane Value Normal, Paraffinic 18 - 22 (41%) Mature 22 - 30 (26%) Value 0.8 - 1.2 I (42%) I 1.2 - 2.0 I I 0 Limits Petroleum Class Class Isoheptane Heptane Value Supermature Biodegraded (28%) 30 - 60 Value 2.0 - 4.0 (13%) 0 18 - (10%) 0 - 0.8 (20%) ( 20%)"- . 0 I, Thompson, K. F. M., 1983, C l a s s i f i c a t i o n and t h e r m a lh i s t o r y of petroleum based on l i g h t h y d r o c a r b o n s : Geochim. e t Cosmochim. Acta, Vol. 47. p. 303-316. c c A-300