NUMERICAL MODELING OF BUOYANT PLUMES IN A TURBULENT, STRATIFIED ATMOSPHERE by Ralph Ge Bennett and Michael W. Golay Energy Laboratory Report MIT-EL 79-002 January, 1979 I NUMERICAL MODELING OF BUOYANT PLUMES IN A TURBULENT, STRATIFIED ATMOSPHERE by Ralph G. Bennett and Michael W. Golay Energy Laboratory and Department of Nuclear Engineering MassachuSetts Institute of Technology Cambridge, Massachusetts 02139 MIT-EL 79-002 January, 1979 Sponsored by The Consolidated Edison Company of New York, Inc. Northeast Utilities Service Corporation MIT-EL 79-002 ERRATA ,tt Page Line 64 5 speed 78 9 atmospheres 84 3 library 116 17 122 8 0.50 OF 126 3 analysis 11 19 uncertainty The name of Pasquill is in common usage today for plume modeling. The bivariate Gaussian plume description was originated by O. G. Sutton Soco A. 135, (Proc. Roy. pp. 143-165). NUMERICAL MODELING OF BUOYANT PLUMES IN A TURBULENT, STRATIFIED ATMOSPHERE by Ralph G. Bennett and Michael W. Golay ABSTRACT A widely applicable computational model of buoyant, bent-over plumes in realistic atmospheres is constructed. To do this, the two-dimensional, time-dependent fluid mechanics equations are numerically integrated, while a number of important physical approximations serve to keep the approach at a tractable level. A three-dimensional picture of a steady state plume is constructed from a sequence of time-dependent, two-dimensional plume cross sections--each cross section of the sequence is spaced progressively further downwind as it is advected for a progressively longer time by the prevailing wind. The dynamics of the plume simulations are quite general. The buoyancy sources in the plume include the sensible heat in the plume, the latent heat absorbed or released in plume moisture processes, and the heating of the plume by a radioactive pollutant in the plume. The atmospheric state in the simulations is also quite general. Atmospheric variables are allowed to be functions of height, and the ambient atmospheric turbulence (also a function of height) is included in the simulations. A demonstration of the ability of the model to reproduce the solutions to problems that are known is undertaken. Comparisons to buoyant line-thermal laboratory experiments show that the model calculates the dynamics of the fluid motions to an acceptable accuracy. Comparisons to atmospheric plume rise and dispersion experiments show that the model can simulate individual plumes more accurately than existing correlations because it calculates the effect of the atmospheric turbulence and stratification from first-principles. The comparisons also show that improvements to the model are likely to be made by more accurately describing the anisotropic nature of atmospheric turbulence, and the production of turbulence by the sources of buoyancy. TABLE OF CONTENTS 1. 2. ACKNOWLEDGEMENTS 6 Problem Description and Solution 8 1.1 Introduction 8 1.2 Background and Problem Description 9 2.2 9 1.2.1 Historical Background 1.2.2 Characteristics of Bent-Over Buoyant Plumes 10 1.2.3 Overview of Plume Models 11 1.2.4 Scope of Work 14 16 Literature Review 2.1 3. page Numerical Plume Models 16 2.1.1 Three-Dimensional Models 17 2.1.2 Two-Dimensional Models 19 2.1.3 Experimental Studies 20 Numerical Planetary Boundary Layer Modeling Hydrodynamic Model Development 21 23 3.1 Introduction 23 3.2 Model Equation Sets 23 3.2.1 3.2.2 Dry Equations 23 3.2.1.1 Reference State Decomposition 24 3.2.1.2 Reynolds Decomposition and Closure 30 3.2.1.3 Pollutant Transport Equation 37 3.2.1.4 Radioactive Decay Heating 38 Moist Equations 39 3.2.2.1 Reference State Decomposition 40 3.2.2.2 Reynolds Decomposition and Closure 46 -4- page 3.2.2.3 3.2.2.4 3.3 4. 5. Equilibrium Cloud Microphysics Model 49 Latent Heat Source Term 50 Model Solution Methodology 53 3.3.1 The VARR-II Fluid Mechanics Algorithm 53 3.3.3.2 Orientation of the Computer Mesh 54 3.3.3 Downwind Advection of the Mesh 58 3.3.4 Property Data 60 3.3.5 Input Profiles and Boundary Conditions 64 3.3.5.1 Input Profiles 64 3.3.5.2 Boundary Conditions 64 3.3.5.3 Mesh Initialization 67 3.3.6 Mesh Coarsening Capability 69 3.3.3.7 Statistics Package 72 Description of Atmospheric Turbulence 74 4.1 Introduction 74 4.2 Atmospheric Profiles of Wind, Temperature, and Humidity 74 4.3 Turbulence in the Planetary Boundary Layer 77 4.3.1 Introduction 77 4.3.2 Layers in the PBL and Important Processes 78 4.3.3 Prescription of Eddy Viscosity 81 4.3.4 Prescription of Turbulence Kinetic Energy 86 Results 90 5.1 90 Introduction -5- page 5.2 5.3 5.4 6. Comparisons to Analytical Models 93 5.2.1 General Nature of the Solutions 93 5.2.2 Turbulent, Buoyant Line-Vortex Results 108 5.2.3 Brunt-Vaisala Period of a Turbulent, Buoyant Parcel 112 Comparisons to Field Studies 115 5.3.1 Pasquill Dispersion and Briggs Plume Rise in Neutral Atmospheres 115 5.3.2 LAPPES S0 2 Dispersion Studies 120 Results of Model Extension 133 5.4.1 Fumigation Episode 133 5.4.2 Plumes with Change of Phase 134 Conc lusions and Recommendations 137 6.1 Model Validation 137 6.2 Recommendations 139 6.2.1 Calculational Scheme to Include Wind Shear 139 6.2.2 Calculational Scheme for Time-Dependent Releases 142 6.2.3 Cloud Microphysics Model 143 NOMENCLATURE 146 LIST OF FIGURES AND TABLES 151 REFERENCES 154 APPENDIX -- Computer Code Listing 160 -6ACKNOWLEDGEMENTS This research was conducted under the sponsorship of Consolidated Edison and Northeast Utilities Service Corp. The authors gratefully acknowledge their support. -7- Blank Page d -8- 1. PROBLEM DESCRIPTION AND SOLUTION 1.1 Introduction With the rapidly increasing burden of air pollution over recent decades, the engineer's ability to analyze the behavior of an ever-widening assortment of effluents has not kept up with the importance of the consequences of the releases. The reason for this is that the "predictive" models of plume behavior that are currently available universally suffer from a lack of extendability. That is, they need to observe the behavior of an ensemble of the releases that they wish to model before they can form an accurate picture of the release. The models are useful only to the extent that an appropriate ensemble of plumes can be created for study, either as full-scale atmospheric releases, or as scaled-down laboratory experiments. Inasmuch as the important turbulent and thermal characteristics of the atmosphere cannot be simulated in the laboratory, and since an ensemble of plumes with catastrophic consequences (e.g., radioactive plumes from nuclear reactor accidents) may be impractical to produce, plume modeling has needed to take a more universal approach. The purpose of this work is to construct a widely applicable model of plume behavior in realistic atmospheres. To do this, a "first principles" approach is adopted. A -9- numerical integration of the fluid mechanics equation is undertaken, while a number of important physical approximations to the problem serve to keep the approach at a tractable level. The advantage of the model presented here is the ability to tackle problems outside of the scope of existing models without greatly increasing the resources spent on the analysis. 1.2 1.2.1 Background and Problem Description Historical Background Man has produced and observed bent-over buoyant plumes since the discovery of fire. However, the bent-over plume did not have any great impact on society until the advent of large industrial sources near population centers during the industrial revolution. The number of large industrial sources has increased steadily with the industrialization of many countries. In the recent past, the variety of releases from large industrial sources has increased greatly, and now includes the potentially more harmful effluents from chemical refining and combustion processes, nuclear power plants, and large cooling towers. Also, the steady growth of population centers almost always dictates that these new sources will be located in at least moderately populated areas. Historically, the ability to analyze the effects of large releases and hence to develop technologies for their -10- mitigation has not kept pace with the consequences of the releases. To date, the advances have been quite modest: early observations during the industrial revolution suggested the use of tall stacks for lessening the effects of large releases. The strong influence of the synoptic-scale weather on releases (first investigated in order to increase the effectiveness of chemical warfare agents) has largely motivated the Pasquilltype correlations of plume behavior. The hope of simply re- ducing the consequences by reducing the amount of effluents has stimulated an abundance of filtering, scrubbing, and effluent control technologies. However, increasingly important releases are certain to occur. A brief review here of the existing approaches to plume modeling can indicate the most promising avenue for study. 1.2.2 Characteristics of Bent-Over Buoyant Plumes The character of the bent-over buoyant plume is central to all of the available plume models. When an effluent stream with a given upward momentum and initial buoyancy is released from a stack into a windy atmosphere, the plume is deflected downwind. This occurs partly because of pressure forces that develop around the plume, and partly because the plume entrains the ambient air, which mixes a lot of downwind momentum into the plume. The deflection quickly causes the plume to bend over (usually within about one stack height) and then to be -11- carried downstream. The buoyancy of the plume is converted into kinetic energy, and the plume rises under this action for a considerable distance downwind. About 20 years ago it was notedl that the motion of the plume in cross section during this rise was essentially that of a two-dimensional turbulent vortex pair. Initially the vortex pair rises and grows with- out being too dependent upon atmospheric turbulence (although atmospheric stratification is always important). After the kinetic energy of the cross-sectional motions has essentially died out, the plume continues to disperse solely by atmospheric motions. It will be found in the review of plume models that only the detailed numerical plume models provide a method that can easily bridge between the regimes where plume turbulence dominates and where atmospheric turbulence dominates. 1.2.3 Overview of Plume Models With regard to the detailed three-dimensional nature of plume motions, existing models of plume behavior are found to possess a wide variety of sophistication. The Pasquill- type models, the entrainment models, and the numerical models are considered here. The Pasquill-type models develop a highly idealized picture of the fluid motions in and around the plume. Pollu- tants in the plume cross section are assumed to fit Gaussian -12- distributions of height and width. In essence, the model parameters (standard deviations of the Gaussian distributions) are simply an ad-hoc replica of the experimental results; as such, the models are unable to predict in cases for which experiments have not been performed. The wealth of non- passive effluents and the rich variations in the meteorological state of the atmosphere serve to guarantee that cases outside of the Pasquill-type models will always exist. The entrainment models develop a much less idealized, and much more physical picture of the fluid motions in the plume. In general, the models make use of the very elegant non-dimensional formulations and similarity relationships that are central to the theory of homogeneous isotropic turbulence. Typically the models are successful at analyz- ing the initial plume behavior, where the self-generated plume turbulence dominates over the atmospheric turbulence. The entrainment models are generally able to analyze plumes only in fairly simple atmospheres when analytical solutions are sought. But this is not the primary limitation of entrainment models, since in some cases their solutions are found on computers. The limitations of the entrainment models are the condition that the plume self-generated turbulence is dominant over the atmospheric turbulence, (which eventually breaks down for all plumes, commonly at downwind distances for which the solution is still needed) and the basic entrainment velocity assumption, which cannot be obtained from fundamental constants and scales in a straightforward way. Numerical plume models are capable of developing the most detailed picture of the fluid motions in the plume. In general, the models seek to integrate a closed set of Reynoldsaveraged fluid mechanics equations, either in two or three dimensions. Turbulence leads to a fundamental closure problem in writing this set of equations, so that each model will have a collection of closure assumptions that together form a turbulence model, aside from other assumptions that are made concerning the plume behavior. Numerical plume models are becoming capable of analyzing the most detailed cases, yet they are often limited by the large computing costs. Aside from the computer costs, the tasks of initial- izing and validating the problem with fully two- or threedimensional data can also quickly become intractable. Until computer costs are reduced greatly, the most useful numerical plume models will likely have to be two-dimensional. The greatest benefit that comes from such models is the wider range of application of the models, and the ease of extending them to new cases. -14- 1.2.4 Scope of the Work This work constructs a three-dimensional solution of a steady state plume from a sequence of time-dependent twodimensional plume cross sections; each plume cross section of the sequence being spaced progressively further downwind as it is advected for a progressively longer time by the prevailing wind. The two-dimensional cross sections are simulated with a time-dependent turbulent fluid mechanics code which integrates the time-averaged equations of continuity, momentum, energy, moisture, and pollutant. The behavior of an individual plume is modeled in this way until the height or radius of the plume reaches several hundred meters, which roughly corresponds to the plume cross section being tens of kilometers downwind of the source. The dynamics of the plume simulations are quite general. The buoyancy sources in the plume encompass the sensible heat in the plume, the latent heat absorbed or released in plume moisture processes, and the radioactive decay heating of the plume by a radioactive pollutant species in the plume. Buoyancy from chemical reactions could be easily included. The atmospheric state in the simulations accepts atmospheric wind, temperature, water vapor, liquid water, background pollutant, turbulent eddy viscosity, and turbulent kinetic energy as functions of height. The turbulence is treated -15- with the sophisticated second-order closure model of Stuhmiller 2 , which allows the turbulent recirculation and entrainment of the plume cross section to be treated in a very natural way. The model is validated against the Pasquill model 3 and the entrainment model of Richards4 for idealized cases in which these models apply, and for several cases from the LAPPES 5 field data for actual large power plant stacks. Simulations are obtained for cases outside of the Pasquill and entrainment models, and while no specific field data for these cases exists, the behavior of the simulation agrees with the physical changes imposed on the problems. -16- 2. LITERATURE REVIEW The literature review in this work undertakes a broad survey of plume modeling. In the first section, existing numerical plume models are discussed, along with the experimental data base that is available for the validation of these detailed plume models. The first section also includes the research that has been done on computational and experimental modeling of two-dimensional line vortex pairs. It is important to include them since the results of such work are very easily interpreted in the context of air pollution problems. In the second section, existing numerical models of the planetary boundary layer are discussed. Again, these models are very easily extended to air pollution problems (with the inclusion of a pollutant transport equation and pollutant source), so it is important to include them in the review. 2.1 Numerical Plume Models A large number of plume models have been developed that are available as computer programs. Several recent reviews 6-8 have reported dozens of such models, and it is important to make a distinction regarding them. A majority of the models employ the Gaussian plume assumption; as such, the computer -17- is simply being used to look up and present the standard handbook calculations, with minor modifications in some cases. These are not"numerical plume models" in the sense that the primitive equations are not being integrated to show the plume development, although computers are being used. Such models are not considered further here. The remaining models in the reviews are truly numerical plume models, and they will be considered next, along with several models that were reported elsewhere. 2.1.1 Three-Dimensional Models The most sophisticated numerical plume models to date have not yet attempted a second-order turbulence closure to the fully three-dimensional flow field for non-passive pollutants. Some of these features are found in each of the models discussed here, but not all of them. The notes of Rao 9 and Nappo1 0 discuss the desirable features of three-dimensional numerical plume models, and provide a good introduction to future work that may be undertaken. Donaldson's modelingl has concentrated on a second-order turbulence closure for a three-dimensional planetary boundary layer simulation with a passive pollutant. Because the pol- lutant is passive, and hence does not affect the flow field or its turbulence, the turbulence closure only addresses PBL -18- turbulence, and is independent of the behavior of buoyant plumes. This is in contrast to the method in this work, where the second-order closure is "tuned" to the development of turbulent buoyant plumes, and is largely independent of PBL turbulence development. Lewellen's modeling begins with a second-order closure to the passive pollutant transport equation, and then adopts the PBL flow field and turbulence from Donaldson's model.ll Only integrations of the pollutant transport equation are needed in Lewellen's model because of the adoption of a complete PBL solution. model 1 Patankar's of a deflected turbulent jet in three-dimensions also uses a second-order closure model, but does not allow for buoyancy and stratification, although it does allow for nonisotropic turbulent transports in the vertical and horizontal directions. A fundamentally different approach to three- dimensional modeling is found in the Atmospheric Release Advisory Capability (ARAC) system. 1522 A mass-consistent threedimensional wind field is interpolated from a small set of local tower wind measurements and used to predict the advection of a passive pollutant. Turbulent diffusion is modeled with a zero equation model, although many other important features such as rainout, wet and dry deposition, and surface terrain have been added. -19- 2.1.2 Two-Dimensional Models Two two-dimensional numerical plume models have been Henninger's model23 solves contin- found in the literature. uity, momentum, energy, and moisture with a less-sophisticated zero-equation turbulence closure, and with a more sophisticated treatment of moisture. For plumes in a wind, the model chooses the mesh alignment shown in Fig. 3.3.2.1b of Sec. 3.3.2, which is felt to be a less satisfactory choice than that of the present work. to the model in this work Taft's model24 is much closer , since it adopts the same mesh alignment (see Fig. 3.3.2.1c in Sec. 3.3.2). The principal differences are that Taft's model employs a one-equation turbulence model, uses a more complex moisture model, and does not make any attempt to describe ambient atmospheric turbulence. A number of two-dimensional numerical buoyant thermal models have evolved in the literature of meteorology, usually in support of efforts to parameterize the growth of rain clouds. The models have not been applied to air pollution directly, but could be easily converted. Lilly's model2 5 seeks a self-preserving solution for the (dry) buoyant line thermal, and as such, would only be applicable for the early plume behavior when plume self-turbulence is dominating. Johnson's model 2 6 is used to study fog clearing on runways -20- with helicopter downwash; while the moisture equations are more complex than that in this work, the eddy viscosity is assumed to be constant. Ogura's model27 of rain cloud dev- elopment also assumes a constant eddy viscosity, while Arnason's model2 8 ignores eddy transports altogether. Liu's model 2 9 employs a stratification of atmospheric turbulence While the treatment into two constant eddy viscosity layers. of turbulence in these models is verysimple, it should be emphasized that these models are focussed on precipitation modeling, and they are likely to be helpful in the improvement of the moisture model in this work. A recent review of pre- cipitation modeling is found in Cotton. 3 0 2.1.3 Experimental Studies The field study that the model in this rork is validated against is the Large Power Plant Effluent Study (LAPPES). Complete field data for stack plumes from three mine-mouth coal-fired plants are found in the four volumes of the study: wind, temperature, and humidity profiles, plant operating characteristics, and plume SO 2 concentration cross sections are of the most interest in this work. The Chalk Point Cooling Tower Project (CPCTP)3 1 is also of interest to this work since it provides cooling tower plume cross sections, but plant operating data 3 2 was not available during this work. -21- The experimental laboratory studies that this work is validated against are the papers of Tsang33 and Richards. 4 The experiments study the behavior of two-dimensional line thermals released in a water tank. The ambient receiving fluid in the tank is both laminar and unstratified, and the thermals are fully turbulent. 2.2 Numerical Planetary Boundary Layer Modeling A three-dimensional numerical model of the planetary boundary layer has been reported by Deardorff3 4 36 that could easily be adapted to local air pollution studies, although the expense is likely to be prohibitive. The model solves the complete set of primitive equations (with an eighteen-equation model of turbulence) in a box that ranges 5 km on a side and 2 km deep. The numerical experiments to date have compared very favorably with several well-documented Planetarv boundary laver field studies. To alv the model to a single source of pollutant, a sinale mesh cell could be initialized with sources of momentum., heat, moisture, pollutant, and turbulence. To accommodate this, a pollutant transport equation would have to be added, and an additional three-equation model of turbulent pollutant fluxes would need to be developed. Time-dependent or steady- state releases could be modeled in great detail in this way. -22- However, the model currently requires 15 seconds of CPU on a CDC-7600 to simulate 1 second of flow in the atmosphere. Also, the specification of boundary conditions on a threedimensional mesh with accurate time-dependent micrometeorological data would require a very elaborate reporting network. Nonetheless, the model represents a more sophisticated and potentially more accurate approach than the model in this work. -23- 3. HYDRODYNAMIC MODEL DEVELOPMENT 3.1 Introduction In order to model buoyant plumes in the atmosphere, the equation set contained in the VARR-II computer code is reinterpreted and expanded. A reinterpretation of the hydrody- namic variables is necessary in order to satisfactorily account for the compressible nature of an atmosphere that is at rest. The euations are expanded in Sec. 3.2.1 to include the transport of a pollutant and radioactive decay heating by the pollutant, and in Sec. 3.2.2, where the transport of water vapor, cloud liquid water, and the energy released or absorbed during the phase changes of water substance considered. are Since so many fundamental changes are made here in reinterpreting the VARR-II equation set, this discussion of the model development undertakes a derivation of the equations; for completeness it reiterates the important assumptions ontained in the VARR-II code which were developed out- side of this work. 3.2 3.2.1 Hydrodynamic Model Equation Sets Equations for Dry Atmospheres The equations for a dry atmosphere are derived in this -24- section. When the potential temperature is simply reinter- preted as the virtual potential temperature, these equations are applicable to moist plumes in moist atmospheres if none of the moisture undergoes a change of phase, and if the turbulent diffusion coefficients of heat and moisture are equal. A further discussion of virtual potential temperature is found in Sec. 3.2.2.1. 3.2.1.1 Reference State Decomposition As a starting point for the model development, consider the three-dimensional compressible fluid mechanics equations, where the six primitive variables , , T, and i. are physically measurable values of the fluctuating pressure, density, temperature, and velocity, respectively: Continuity Eq: at+ = (3.1) Momentum Eq: at 3a i. u) ax. aa ij X - 0gi ax.x1 + (3.2) (3.2) 11-i Energy Eq: at gt+ax axT)+ (-j+T) ~~ j = ~ a +9 Cx. xj] T 1 j cp t (3 3) -25- Equation of State: p = pRT These equations have property values depend upon temperature in general. (3.4) , cp, and k, which may The energy equation has neglected the kinetic energy in the fluid motions, and the equation of state is that for an ideal dry gas. The variations of temperature, pressure, and density in a static atmosphere are usually "subtracted out" of these equations in meteorological analyses by a reference state decomposition. That is, equations of motion for perturba- tions about an adiabatic atmosphere are sought by decomposing the primitive variables as the value of a primitive variabl its value in an adiabatic - atmosphere (function of height only + a departure from the state at est (3.5) or, in terms of the notation in this work P _. P + p (3.6) P + P (3.7) T - T + T (3.8) - 0 + Ui (3.9) .i The state of the dry, adiabatic atmosphere is found by -26- making the substitutions Eq. 3.6-Eq. 3.9 into Eq. 3.1-Eq. 3.4, and setting the time derivatives and the perturbations p, p, T, and u i to zero. The continuity and energy equations be- come trivial under this substitution. The momentum equation becomes the hydrostatic equation: dPo dz Pg = (3.10) The equation of state is simply po = P Ro (3.11) The First Law of Thermodynamics for an adiabatic process is dQ = = cpdTo - dPo /p (3.12) Dividing by a displacement dz gives dp dz dT =o Pocp dz° (3.13) and substitution of Eq. 3.13 into Eq. 3.10 gives rd, the lapse rate of the dry adiabatic atmosphere: dT T 5 rd d 9.76 _C/km dz (3.14) cp To this point the solution of the adiabatic atmosphere has been presented. Substituting the reference state decom- position, Eq. 3.6-Eq. 3.9 into the equations of motion, -27- Eq. 3.1-Eq. 3.4, and using the results of the adiabatic atmosphere, Eq. 3.10 and Eq. 3.14, gives the equations of motion for the perturbations: Continuity Equation au. + o axc a2T- Ed_ k 0~ = - . + Co P- a POaX = (3.15) au2 aX (3.16) Momentum Equation: au. P Uj o at +. + pou x. = -a x.i Pgi + / Energy Equation: 2 P aT + - oUj aT aXjI3 Rd T (3.17) 7 Equation of State: P = P0 T + P To p0 + pT (3.18)' P T The fluid perturbations will generally be assumed to be incompressible in the Boussinesq sense. That is, changes in fluid density are assumed to be produced only by temperature changes, and not by pressure fluctuations. Neglecting the pressure fluctations in the equation of state, and noting that generally pT<<poTo, the equation of state becomes P/p0 - -T/T (3.19) -28- which is the familiar Boussinesq equation of state. This equation allows the buoyancy term (-pgi/o) in the momentum equation (Eq. 3.16) to be similarly approximated. The con- tinuity equation (Eq. 3.15) becomes that of an incompressible fluid, assuming that the fluid motions do not rapidly mix 37 deep layers of the fluid, e.g., comparing length scales of velocity and density: a (fi 11 a. < «X. (3.20) andll that the heat conduction term in Eq. 3.1 is a small contribution to the divergence. Making these approximations, the equations for the perturbations may be written as Continuity Eq.: a u. 3= 0 (3.21) ax. Momentum Eq: 2 au. 1 + u au. a + U ao ap 1 jar xPo x. p - 11 o g. 9(3.22) + I au. 1 ;x Energy Eq: T+u " - ~' j~x] =+ P -aT o ~~O ~~x: (3.23) -29- Define the potential temperature, , as T 10p (3.24) Differentiating with respect to height finds that the adiabatic atmosphere has a lapse rate of potential temperature of zero, de 0 dzdz (3.25) or that the potential temperature is a constant in an adiabatic atmosphere. Errors introduced by evaluating density with 8 instead of T are assumed to be small (this is investigated in Sec. 3.3.4). Neglecting the perturbation p with respect to p 0 in Eq. 3.24, and approximating p as p(0o ) in Eq. 3.22, the use of 8 instead of T in the primitive equations (Eq. 3.21-Eq. 3.23) gives Continuity Eq: au. 3 (3.26) Momentum Eq: 9u. t u. + 1 1 9p P(6 o) x. ' z 1 j D. p(6)-p() P() p) gi 9 2u. + v (3.27) 3 Energy Eq: a6+ at u a X. vPr x. (3.28) -30- The utility of the potential temperature formulation is that strong variations of pressure and density with height in the hydrostatic approximation of Eq. 3.10 are no longer present in the primitive equations. Initialization errors to the hydrostatic state, if included in the primitive equations, 38 The transients are lead to strong transient fluid motions. neatly avoided by this formulation. To this point the fully three-dimensional fluid mechanics equations have been decomposed into an adiabatic reference state, and a flow field of perturbations about this state. A number of approximations have simplified the equa- tions for the perturbations to those of a Boussinesq incompressible flow. The equations need to be ensemble-averaged and a turbulence closure formulated, and then the set must be finite-differenced for computer solution. 3.2.1.2 Reynolds Decomposition and Closure To model the effects of turbulence on the mean flow, each primitive variable in the equation set is decomposed into its time-averaged and fluctuating parts as the value of the perturbation of a primitive variable its ensembleaveraged value + any fluctuations about its ensembleaverage value '(3.29) -31- which is represented here by the decompositions P -P + P' (3.30) e + 8' (3.31) P + P' (3.32) -8 P U.iu.+ U. 1 ) J (3.33) Under this transformation, by selectively ensemble-averaging and subtracting the equations, and by making use of the continuity equation, the primitive equations become Continuity Equations a j/ x. = 0 (3.34) x 0 (3.35) au' j Momentum Equations: aui a 1u - at + j 1 Xe p ax. J3 P(e)-P(6 ) p(0 0o) + a 2u. a 1 3x (u] u'.) j au' at -1 p(6O) + a u! 1 jaX ap' ax 1i ,au. 3i X au! ax ax. 3 P(e')-p(e 0 ) P(e) o (3.36:) 1 9i + .2u ---i a x2 I ( J ) = (3. 37) -32- Energy Equations: e U ae j aX ae'I at e -1a2 VPr ax j axj ja~~~ ~x. aza j J t+ `at - -- = a i U J ~U i i . Jx ) j ael U a -. - . 3 a a xIj (3.38) J -1 a 2 e, (u!G'J = VPr Iax ax.; (3.39) The set of ensemble-averaged equations (i.e., Eq. 3.34, Eq. 3.36 and Eq. 3.38) suffer from the well-known closure problem due to the generation of the uU and u!e terms by the non-linear advection terms in Eq. 3.27 and Eq. 3.28. Equations 3.37 and 3.39 may be manipulated to produce transport equations for these two new variables: au. a u. D uu XXkJ = U-1lu Dti;j a xk uj3U -a I 3Xk (ulu 3u) -l PF 1 P0 a ax (p'u3) aU! pI 1 a Po aXj P 1+__ ' J 0 au i ax.1/ 3 production terms turbulent transport term pressure diffusion terms tendency toward isotropy term -33- + buoyant production terms + g iu-) 1 u-3 + (gi (i 2 a (uuT) + V molecular diffusion terms 1. a xk -2va 1 dissipation term 3 axk Xk (3.40) D D Dt (e,) 1 ' = -uu'., a ax. j j J a (! ax. a u a e = U 1 3 , ') (p oTO (P FO ) ~ ae'' p xi Po -- gi 8e8' 1 a xD U. ax. J production terms turbulent transport term pressure diffusion term tendency toward isotropy term buoyant production term molecular diffusion term -34- a e' -au! - dissipation term 1 2v j j (3.41) A discussion of the individual terms noted in Eq. 3.40 and Eq. 3.41 can be found elsewhere.ll These equations were closed by Stuhmiller2 and the results are listed here for completeness. In Eq. 3.40, the tendency toward isotropy term is neglected, because the turbulence is assumed to be homogeneous, and the molecular diffusion term is neglected because the flow is expected to be highly turbulent. The buoyant pro- duction term is also neglected, mainly in order to see how well the turbulence model can do without it, since it was neglected in Stuhmiller's turbulence model. It is found that the incorporation of this term would probably aid the model in reproducing the buoyant line-thermal results (see Sec. 5.2.2). By further making the assumption that the average flow is twodimensional in the y-z axes of Fig. 3.1, the following closure is made for the trace of Eq. 3.40, which is the turbulence kinetic energy, q, q Dt = 2 Dt+ v ay + = TT, (aw )aw ) 2 2 (()av +y z) (z + yaz ay a z) cay atz -4q2 a z(3.42) (43q ) -35- Figure 3.1 Flow Field Orientation The flow field of Eqs. 3.42-3.47 is time-dependent and two-dimensional in the y-z axes. The relationship of the timedependence to the (downwind) x-axis is discussed in Sec. 3.3.3. VERTICAL Xj z =Z3W I -M.~ w CROSSWIND Xz y to v ZZ DOWNWIND x, x -36- The off-diagonal terms of the Reynolds stress tensor are related to a scalar eddy viscosity, a, and aW 3-a xj + u /, xi/ has the following transport equation: 2 Da where u!u! = _ Dt = +r 3/av 2 q \ta- "a + ay3 a aw2 13v z +a + + aw z) 2 a z(g,) (3.43) Finally, the turbulent fluxes of heat in Eq. 3.41 are related to the turbulent momentum fluxes through a reciprocal turbulent Prandtl number, T'T which is specified along with the three other turbulence constants a, r, and r1l. With this turbulence closure, the continuity, momentum, and energy equations become, in a two-dimensional flow 3 at + Tt + +w 3y (v ) + (VW) P(0) (vw)+ 32 (w2)= a3zt -e3w P(e 0 = ) (3.44) + y 3y +3y a z = aa zw a w-z + a ( ) (3.45 gz -(0) ay g) ) +az (aU--) ( P( (o) ) (3.46) -37- at +a; v)+ a zz (ew)= ''d~ay + az (Ta-z ) (3.47) With an internal energy variable, I, defined as Ic tions 3.42-3.47 are solved by the VARR-II code. , equaP Additional pollutant and moisture transport equations are discussed in the next two sections, and possible modifications to these equations are discussed in section 6.2. 3.2.1.2 Pollutant Species Transport Equation A transport equation for a pollutant species density, x The pollutant is is added to the set of Eqs. 3.42-3.47. assumed to be a neutrally buoyant, passive species, although The it may be contained in a buoyant stream of effluent. assumption that the species is neutrally buoyant could be relaxed, but the model is felt to be useful in modeling most The turbulent diffu- dilute pollutants in its present form. sion of the pollutant is related to the eddy viscosity of momentum by a reciprocal turbulent Schmidt number, 7X. The transport equation may be written down as substantial derivativej of X [turbulent transport 1 =of X Vrate of I - destruction .of (3.48) X -38- which is represented here as a x +3 a + a (i) X x) i=l in the notation of Fig. 3.1. The destruction of X is assumed to be by radioactive decay into any of N decay channels, so that the rate of destruction of X is the product of X and the sum of its radio(i) active decay constants Ax , in Eq. 3.49. This formulation makes no account of sources of the pollutant species through decay of radioactive precursors. It also ignores chemical reactions which could alter the pollutant concentration. How- ever, the extension of the model to include these effects is straightforward. 3.2.1.4 Radioactive Decay Heating The thermal energy released by radioactive decay of the pollutant is added to the specific internal energy of the fluid. Pollutants may decay by any one of N different decay channels with decay constant >(i) x and energy Ei). A fraction F(i) x of the energy is deposited within the plume, yielding an energy release rate of -39- BTU-atoms - radioactive = 4.151x1010 ,4 xx PWmolX MeV-ibm -mole N /X ¢' ) x i (3.50) where WmolX is the molecular weight of X in bm/lbm-mole. Daughter radiations have been ignored in this formulation, but could be included with their own transport equation. Similarly, alterations of the energy balance caused by chemical reactions has not been treated in this work, but would be easy to address in extensions of this work. Moist Equations 3.2.2 The inclusion of moisture is considered in this section with the purpose of pointing out the assumptions that allow the equations to be formulated with the concept of virtual potential temperature, in addition to two other moisture variables. The assumptions that are made in this section are important--the moisture model is not meant to be perfectly general; it is expected to do poorly when these assumptions are not valid. -40- 3.2.2.1 Reference State Decomposition Atmospheric moisture is assumed to be in either the liquid or vapor phases. The amount of vapor is described by the vapor density moisture variable, -vap,and the amount of cloud liquid water is described by the liquid density moisture variable, Pliq' Transport equations for these two variables are written that take note of the turbulent transports of vapor and liquid, and the processes of evaporation and condensation that cause the interchange of vapor and liquid. First, however, the effect of moisture on the buoyancy of a parcel of air is developed and applied to the description of a hydrostatic reference state. The density of a parcel of moist air is the sum of the dry air, vapor, and liquid densities: = dry + vap + (3.51) liq In this work the contribution to the density of the typically small amount of cloud liquid water is ignored, (there is usually no liquid water present in the simulations, and when it is present, it is typically less than 1% of the mass of the fluid), so that the concept of virtual potential temperature can be explored. perfect gas law to Dropping the Pliq term and applying the dry and Pvap yields: P RdT d RvT v va (Pdry vap) RdT v dv (3.52) RT dv -41- where p is the total pressure, mvap and mdry are molecular weights and the virtual temperature, T v , is I+ T v drYPvap/mP vap.dry T Pvap/ 1+ (3.53) dry It is very important to note in Eq. 3.52 that the virtual temperature is a fictitious temperature that is used in the dry gas equation of state to give the density of moist air. Gen- erally the virtual temperature is no more than a few degrees higher than the thermodynamic temperature for typical atmospheric conditions. Following the development in Sec. 3.2.1.1, the variations of virtual temperature, pressure, and density of a static atmosphere are "subtracted out" by making a reference state decomposition: the value of a primitive variable its value in a uniformly moist adiabatic atmosphere (function of height only) = a departure from the state at rest (3.54) Or, in the notation of this work: P PO + p (3.55) P PO + p (3.56) Tv - T vo + Tv (357) u. 1 (3.58) + u 1 -42- the only difference here to the reference state decomposition of Eqs. 3.6-3.9 is in the use of the (fictitious) virtual temperature in order to allow the use of an equation of state that is analogous to Eq. 3.4: (3.59) /RdTv Substituting Eqs. 3.55-3.58 into the primitive equation set (Eqs. 3.1-3.3 and Eq. 3.59), and setting the time derivatives and perturbations to zero yields the state of the moist adiabatic atmosphere. The continuity and energy equations are trivial (as before), and the momentum equation becomes the moist hydrostatic equation: ii-0 _Pog (3.60) The equation of state is simply (3.61) PO = poRdTvo The first Law of Thermodynamics for an unsaturated adiabatic process in this atmosphere is dQ = 0 = cpmoist dT dp/p (3.62) ° as that Approximating the heat capacity for a moist gas, c pm oist, of a dry gas, cp, dividing by dz and substituting Eq. 3.62 into 3.60 yields an approximate lapse rate for a moist, unsaturated atmosphere which is the same as that for a dry adiabatic atmosphere: -43- -dT vo = = 9.76 0 C/km dz CP (3.63) To this point the resting state of a moist adiabatic atmosphere has been presented. The neglect of the effect of the liquid water on the total density has allowed the treatment of moisture to duplicate the dry atmosphere equations after the transformation of temperature to virtual temperature. The equations for the perturbations are identical to those of the dry atmosphere developed in Sec. 3.2.1.1, except that temperature is replaced by virtual temperature, and a latent heat release term is included: Continuity Eq. a u. a3 x0 axj (3.64) Momentum Eq. at +u u au = x. P Po E ++ T vo gi i + Po a 9 (3.65) phase (3.66) x Energy Eq. -laT a2T aT at+Uj a = vPr 1 P Dp- ( Dt The latent heat release term is considered in Sec. 3.2.2.4. Define the virtual potential temperature, ev, as -44- 8vv - Tvv Rd/Cmoist p 1000 0 p (3.67) Again assume that cmoist is essentially equal to c P . Differ- P entiating with respect to height finds that the moist unsaturated adiabatic atmosphere has a lapse of virtual potential temperature that vanishes: de (3.68) = O vo dz The result here is that the virtual potential temperature is a constant in the reference state. Neglecting the perturbation pressure, p, with respect to p in Eq. 3.56, the use of equations ev instead of Tv in the primitive (Eq. 3.64-Eq. 366) gives Continuity Eq: a u. = (3.69) 0 Momentum Eq: 3 ui at + + Uj 3 i -1 3 -- F ax -x p p(evo) vo ax i P(ev))-p( )0 - P(eOvo o g+v 9 ui ax2 (3.70) Energy Eq: ev +u +Uj t -1 x Jx vPr 2 v 2 xj L pc p yDPvap phase Dt (371) -45- The result here is the same as in Sec. 3.2.1.1: the strong variation of pressure with height is no longer present in the primitive equations. This formulation is common (al- though in slightly different forms) among papers in meteorology. Transport equations may be written down for the water vapor and liquid water densities according to the conservation scheme: Eulerian time rate of change of vapor or liquid Diffusion of vapor or liquid Gain or loss of vapor or liquid due to phase changes + (3.72) or, in the notation of this work: vap at Pli j 3 + u. ap ax lila a p 1 vSc 1 a2 P xa 2 liq .a. (DP Dt/ q - phase (3.73) D D where the gain or loss of vapor due to phase changes, (Dvap/Dt)phase' identically shows up as a loss or gain of liquid, and Schmidt numbers that describe the molecular diffusion of vapor and liquid are introduced, respectively. The terminal fall velocities of the liquid water droplets are ignored. The! vap, term is discussed in Sec. 3.2.2.3. Dt /phase -46- Note that any constant background (ambient atmospheric) value of Pvap and Pliq trivially satisfied these equations, so that no new information would be brought into the specification of the reference state by decomposing the variables in these transport equations. That is, Pvap and Pliq do not have a reference state "subtracted away" from them, unlike the other primitive variables , 3.2.2.2 ~v' and p. Reynolds Decomposition and Closure A Reynolds decomposition of the primitive equations is made as in Sec. 3.2.1.2. Each primitive variable in the equ- ation set is decomposed into its ensemble-averaged and fluctuating parts: p 8 p + p' (3.75) 8 + 8' v (3.76) - p+ p+ Uj 4o Pvap Pliq ' p' (3.77) + u (3.78) vap + Pvap (3.79) Pliq + Piiq (3.80) By selectively ensemble-averaging and subtracting the equations, and by making use of the continuity equation, the primitive equations yield the following relationships: Continuity Eq: au. ax. ] = 0 (3.81) -47- Momentum Eq: au Uj X. at ~t~~~~~ 3 u. -1 P' vo P e )-p(e ap a xi 3 2 ui gi1. + va- X2 ) Vo - (U! U ) (3.82) 3x. i 1 Energy Eq: D v t e 1_W = vPr + j3 a 3x - 2 x 3. (u!e )- 3 jv L Dt p(Ov ) c VP ) phase (3.83) and the transport equations for moisture, Eq. 3.73 and Eq. 3.74 yield Vapor Eq: 3a at -1 va vap 1 = 'vap + vScvap + Uj =X. 3rvap ( a 27vap 2 ax - + D vap x(p' o u ) DDt ) phase x.va (3.84) aX ( (3.84) Liquid Eq: !E iq at 1 iq +uj P'liq 3Cx X 1 = ( lisL -3vap) (Piiquj)a x phase Dt (3.85) Rather than providing the full equations for the correlated fluctuations uu, u!, i; u · u J vap' and u' 7, jPliq' the turbulence closure is simply extended from that developed in Sec. 3.2.1.2. The closed set of equations in two-dimensions is, in the -48- notation of Fig. 3.1 Continuity Eq: av + ay aw = az (3.86) 0 Momentum Eqs: av a. -1 + a (. 3y p (vo) ay Dv Dt -1' Dw Dt peO Fvo Pcevo p'vo"' + y 3az gz+vo) a (f (a ) D (3.87) w)+ .+ a-f a aw Energy Eq: a (c e a Dt (p 6V) -5- (YTa a y (Ce v) )+ a z aY (YT c L z) Dt P (V) phase (3.88) Vapor Eq: D Dt ay vap a a PvaP) a - (TvCya + a (vC _vap I P yapz) +( Dt phase (3.89) Liquid Eq: D - a ( y ayiiq) Dt Pliq = a(YLa + a (Y z L(Io Pliq) z ( Eddy Viscosity Eq: Da 2 D5t q / 2 a y/ +1( +W) 2 + (aw)) q Dt phase (3.9 0) -49- + r(( a a() aas))- rl( a aa)+(ak a a(a) (3.91) Turbulence Kinetic Energy Eq: Dq = 2a )+ + 1 av + (I w)+ as a + aZ a O ay az 4qa sa z(3.92) Pollutant Eq: DXI a Dt ay o -2Y )( ++ Y) +Xa ( z ) - X (3.93) i=l where reciprocal turbulent Prandtl and Schmidt numbers have been introduced, and are assumed to be constants. 3.2.2.3 Equilibrium Cloud Microphysics Model The cloud microphysics model simply assumes that water vapor and liquid are always in equilibrium. Further, the surface tension of the liquid droplets is ignored. That is, phase equilibrium over a flat surface of water is assumed to exist. A phase diagram that illustrates this equilibrium is -50- sketched in Fig. 3.2.2.3.1. The liquid-vapor equilibrium curve above 2730K is the locus of points that the saturation vapor pressure, esat(T), may take. The vapor density, Pvap' in the presence of liquid water would be e sat (T)/RvapT. If there is no liquid available to evaporate, then the vapor density may be less than this saturation value. Below 273°K the subcooled liquid-vapor equilibrium (dashed line) is obeyed. ice formation is allowed. No The entire liquid-vapor equilibrium curve is given by Magnus' formula: 3 9 log0e The ( = 2937.4 1~~~~ T 4.9283 log1OT + 23.5518 0 sat 10(3.94) ) phase term of Eq. 3.89 and Eq. 3.90 is simply adjusted to make the liquid and vapor coexist. of the moisture model is illustrated in Fig. 3.2.2.3.2. The logic Liquid and vapor are advected and diffused in an initial calculation for each computer cell. This generally results in a non-equi- librium moisture state in the cell, so the cell is allowed to evaporate or condense water in order to restore the equilibrium. The amount of evaporation or condensation in each cell is noted in order to provide the latent heat release term in the energy equation. 3.2.2.4 Latent Heat Source Term The latent heat source term is calculated in each cell -51- II M w .9'-4 vapor en by nula .ncluding line 9-1 .1-4 5 subcoole, vap, 6.11 liquid- a p nr it Mc M5 VAPOR __ M 273 TEMPERATURE, Fig 3.2.3.1 T (°K) Phase Diagram for Hater Substance -52transport vapor and liquid using updated velocities liquid evaporates completely Di vap \Dt aps e Dt Phase vapor condenses Dt Dt/= Phase Rsat - pvap fsat - Pvap Dt Fig. 3.2.2.3.2 Dt eDt Logic Diagram for the Equilibrium Moisture Calculation in a Single Cell during a Single Timestep -53- at every step depending on whether evaporation or condensation takes place. The latent heat release term is calculated as Latent Heat Release lb BTU] = - P( L DPvap Dt phase (3.95) where the latent heat of vaporization, L, is assumed to be a constant, 1075 BTU/lb m . The vaphase is found in the logic diagram of Fig. 3.2.2.3.2. 3.3 3.3.1 Model Solution Methodology The VARR-II Fluid Mechanics Algorithm The VARR-II computer code40 is the starting point for the model development methodology in this work. In its ori- ginal form, the VARR-II code solves the two-dimensional timedependent turbulent fluid mechanics equations of continuity, momentum, and energy for a Boussinesq fluid. (The Boussinesq approximation to the momentum equation is considered in Sec. 3.2.1.1.) Two closure variables, the eddy viscosity, a, and the turbulence kinetic energy, q, are also calculated from their own transport equations. The original VARR-II computer code is quite flexible in the choice of boundary conditions, allowing no-slip, free-slip, continuative inflow/outflow, or prescribed inflow/outflow boundaries. I - - -54- The VARR-II fluid mechanics algorithm is the Simplified Marker and Cell (SMAC) method. The computer mesh for this method is Eulerian in either Cartesian or cylindrical geometry, and the primitive variables are solved directly, with no transformation to vorticity-stream function variables. The algorithm divides naturally into two sections during each time step: In the first section the velocity field is updated using the previous velocity and pressure fields with mixed central and donorcell differencing42 of the equations. These velocities gener- ally do not satisfy the continuity equation, so in a second section a pressure iteration adjusts these velocities until they satisfy continuity. Once the divergence-free updated velocity field is knownthe energy and turbulence transport equations are updated, completing the calculational cycle of the time step. The basic SMAC fluid mechanics algorithm has not been modified in this work. Pollutant and moisture transport equ- ations have been added to the equation set, and they are updated in the same manner as the energy and turbulence variables, using the divergence-free updated velocity field. The stability of the method for problems of an atmospheric scale is considered in Sec. 5.2.1. 3.3.2 Orientation of the Computer Mesh The optimal orientation of the two-dimensional computer -55- solution mesh is discussed here. Consider the representative three-dimensional plume in Fig. 3.3.2.1a. The plume has bent over in the imposed (one-dimensional) wind field, and the plume boundaries monotonically expand as the plume proceeds downwind. The most natural possibilities of orienting a two- dimensional solution mesh on this flow are: (1) to align the mesh parallel to the wind and through the center of the plume, as in Fig. 3.3.2.1b, or (2) to align the mesh perpendicular to the flow, as in Fig. 3.3.2.1c. The advantages of the "crosswind" alignment of Fig. 3.3.2.1c over the "downwind" alignment of Fig. 3.3.2.1b are immediately apparent. In the crosswind alignment a three- dimensional simulation results since in the downwind Lagrangian translation of the computational mesh the time variable becomes a surrogate for the downwind position x, where t x = / (z(t)dt. The downwind alignment is appropriate only for cases of line-source plumes--in which internal recirculation and entrainment will be of secondary importance to buoyant plume rise and atmospheric turbulent entrainment. Further, the crosswind alignment can take advantage of the centerline symmetry of the turbulent vortex pair to reduce the total mesh area by a factor of two, while the downwind -56- z X y Fig. 3.3.2.1a Bent-Over Buoyant Plume with Ambient Thermal Stratification. -57- Fig. 3.3.2.1b Mesh Alignment Appropriate for a Line Source Release 1 km z 5 km X Fig. 3.3.2.1c Mesh Alignment Appropriate for a Point Source Release 7 I1 b symmetry line 1 km --Omy -58- alignment scheme needs an extraordinarily long x-axis to model the same plume. Overall, the crosswind alignment scheme is about five times smaller than the downwind scheme. The vel- ocity field in the crosswind alignment is that of a two-dimensional turbulent vortex, which typically exhibits strong shearing and entrainment of fluid. The velocity field in the downwind alignment is that of a two-dimensional turbulent deflected jet, which over most of the flow field exhibits a much smaller amount of shearing and entrainment. Clearly, the crosswind alignment scheme is expected to simulate the more important features of the flow. The singular disadvantage of the crosswind alignment scheme is that it cannot explicitly calculate the shearproduced turbulence of the mean wind field, since the mean wind has no component in the y-z plane. The resolution of this problem is discussed in Sec. 4.3.3. 3.3.3 Downwind Advection of the Mesh From the discussion in Sec. 3.3.2, the computer solution mesh is aligned perpendicular to the wind. The time evolution of the flow field of the plume cross section is drawn in Fig. 3.3.3.1. The choice of an appropriate downwind advection velocity of the computer mesh is needed in order to reconstruct -59- t 3 >t 2 >tl z wind t=t7 = (tY -1 9 Fig. 3.3.3.1 Reconstruction of the Three-dimensional Plume. Wind vectors as a function of height are shown. -60- the full steady state plume, i.e., the time of the computer simulation must be related to a downwind distance. The choice is difficult because the wind profile dictates that fluid elements at different heights will advect downwind at different rates. A simple approximation is that the advection velocity should be equal to the "pollutant averaged" wind speed: x = at u(z) bu g ffX X(y,z)dydz (3.96) (y, z)dydz The finite difference form of Eq. 3.96 is written in Fig. 3.3.3.1. The calculation of this quantity is performed in the "statistics package" of Sec. 3.3.7. A further refinement of the solution scheme is discussed in Sec. 6.2.1. In practice, for plumes that are released from tall stacks, the amount of wind shear that the plume encounters is ordinarily moderate and does not greatly alter the plume behavior. 3.3.4 Property Data The original VARR-II computer code allows for quadratic fitting of air property data versus temperature. In view of the fact that potential temperature is substituted for -61- temperature in moist simulations, the scheme of fitting property data to temperature must be examined. The air property data to be fitted includes density, specific internal energy, dynamic viscosity, thermal conductivity, and heat capacity at constant pressure. The coefficients of the quadratic fits for dry air data43 are listed in Table 3.3.4.1, along with the quadratic form that they are used in. erty value of the substitution of The effect on the propfor T is considered or next. The use of T or T v in the perfect gas law yields, by definition, the correct density of a dry or moist parcel of air, respectively. A quadratic fit of the perfect gas law over a small temperature range of interest would yield essentially exact results for the density as well. of densities with e or The calculation y substituted into the formula for also appropriate because or v is vary from T by very little compared to the absolute temperature. Recall that or is used in the problem formulation to eliminate the compressible nature of the hydrostatic atmosphere. The relevant density variations in the momentum equation are the relative density variations, and the criteria for the use of, say v for T is that p(T)-p(T o ) p(To) 0 I_ P(8e)-(e P(Evo) vo o (3.97) · -62- 0' ao CO 00 .J r. Ln o o m CO o U) 4J '14 m r"l 0 O o o N H o 0 Ln I rl a kD I I *H O .1i r. U) l X X X H rH LO 0 ,4 ,4 I 0 C) .1 v r 44 U, ! I >1 o I X .- a) 0 o o X o x o m o I0x O I E-1 X CS (' -I .0 04 O U rH U) U) 4-i 4) , Un , -W 44 44 L H N" . Eq m z: 0 O o E -i NE .I E P-~ _ SQ r E-4 c, .rl >1 11 I *r-I ., 0) k -I I 1 4 .r4 0 0 ·rl Q. H N 4., I k4 t1 a) - >1 r > o 4O 4. > >1 *dq - g )u n O O 4 O U0 U)'~O (1 . M ~ U3 4 u Lr ~04 ) 0 4 04 , -63- with a similar condition for in dry simulations. This rela- tion holds with about four percent accuracy for the most extreme cases encountered in this work. The specific internal energy is originally fitted versus T. Again, the fact that e or ev is close to T compared to the absolute temperature allows them to be interchanged without significant error. The specific internal energy is accurate to about 4 percent under this substitution. The values of dynamic viscosity and thermal conductivity are important only if the flow becomes laminar. None of the simulations in this work are expected to encounter regions of laminar flow, so the fitted values of molecular viscosity and thermal conductivity are unimportant. The specific heat varies slowly with temperature, and the substitution of or ev for T results in only a 0.02 percent error for typical cases. The necessary property data for equilibrium conditions of water vapor and cloud liquid water are included in Secs. 3.2.2.3 and 3.2.2.4. The inclusion of water in the simulations is assumed to have a negligible effect on the property data of the air-water mixture, except for the density, which is corrected through the use of the virtual temperature. -64- Me;sh Initialization and Boundary Conditions 3.3.5 3.3.5.1 Input Profiles Seven vertical profiles are required for a simulation. Five of the profiles serve to specify the boundary conditions on the computer mesh, one profile (the mean wind wpeed) is needed by the statistics package, and one profile (the hydro- static pressure) is needed by the equilibrium moisture thermodynamics model. 3.3.5.1. The required profiles are listed in Table Each vertical profile consists of a set of values that are representative of th.e cell-centered temperature, wind speed, etc. The number of values is obviously equal to the number of fluid cells in the z-direction. The extension of the model to time-dependent vertical profiles is considered in Sec. 6.2.2. 3.3.5.2 Boundary Conditions Boundary conditions must be specified for each of eight variables on the four walls of the computer mesh. of the computer mesh are numbered in Fig. 3.3.5.1. The walls Wall #1 is in the plume centerline with the real computer simulation to its left. wall. For this purpose, wall #1 is a free-slip solid Wall #4 always represents the earth, and is specified to be a no-slip wall. The earth is assumed to be a perfect -65- Table 3.3.5.1 Required Input Profiles Atmospheric Profile virtual potential temperature Units OF water vapor density lbm/ft3 cloud liquid water density lbm /ft 3 eddy viscosity turbulence kinetic energy ft2 /sec ft2/sec2 mean wind speedA ft/sec hydrostatic pressureB millibars A. The mean wind speed is required by the statistics package of Sec. 3.3.7. B. The hydrostatic pressure is required by the equilibrium moisture thermodynamics model of Sec. 3.2.2.3. -66- Z (Vertical) symmetry line I (crosswind) EARTH Fig. 3.3.5.1 all Numbering Scheme -67- reflector of pollutant and humidity in this work. This assumption could be easily modified to account for deposition of pollutant, sources of humidity, etc., for any case of specific interest. Walls #2 and #3 are chosen to be sufficient- ly far away from the plume so that negligible error is introduced in making them solid and free-slip. In practice, the plumes rise toward wall #3 and begin to deflect when their 10% boundary intersects the wall. This serves as a rough criterion on when to stop the computer simulation. A summary of the boundary conditions is found in Table 3.5.5.2. The solid-wall, no-slip and free-slip conditions are found in the specification of the two velocity components, v and w. The reflective conditions are due to the "perfect ref- lecting walls" assumption; they are foregone at wall #2 for the five variables that are known as functions of height. 3.3.5.3 Mesh Initialization The entire computer mesh in Fig. 3.3.5.2 is first initialized with the known atmospheric profiles of virtual potential temperature, eddy viscosity, turbulence kinetic energy, water vapor density, and cloud liquid water content. The entire mesh is initialized with a single background value of pollutant, and the velocity field is initialized to be at rest. The plume cells in the figure are then initialized by volume-averaging -- ----i--il I -68- HZ H Z P: P; m H H- r - m U- P P ; I I ', 0 ,-4 CN 4K1 H H r-q (a C) U] C/ r% P p) H 40 r-I U r-i r(0 O 0 M4 Et 11 4w O II 0 -- U > -H > .l .) 1 'H U * o r r -I O H U > 0 H H > o a) m ,i 0 0 _ O H) 44 U 0 O > O 4k ) - ,) H m a) 'H >1 tD 54 4* 3 En 54 D I w (1) 00U 0 .H .>1 -I s 'H 40 -H *1 U) C a 14I 0 -I H - > 0) >1 4 V a U) z I (1 O 4 0U '~ U >4J U) 4J U0 5-4 o 4J) k 04 J 4 *H 4 03 'H C U H 0 I I ci) I I Z I I I I 9P'K I I -69- the plume sources of energy, pollutant, and moisture over those cells, using mean wind speed at that height to define the depth of the cells swept out in one second. The initial eddy visco- sity and turbulence kinetic energy in the plume cells are set to about 100 times that of the surrounding atmosphere--in practice, the plume turbulence values very quickly relax into values that are consistent with the flow field. No initial volume- averaged momentum is given to the plume cells. Instead of this, an effective stack height increment due to momentum is added to the actual stack height in specifying the location of the center of the plume cells. 3.3.6 Mesh Coarsening Capability Model programming has been undertaken to allow the mesh spacing to be doubled periodically during the simulations, while keeping the same number of fluid cells on the whole computer mesh. The motivation for this is the desire to keep the growing plume cross section away from the unphysical (solid wall) top and right mesh boundaries. When the simulation is "coarsened," the mesh spacing doubles, which reduces the plume cross section by a factor of four. The 'calculation is restarted, and the simulation proceeds on a mesh that has four times the area of the old mesh, but the same number of fluid cells. The coarsening procedure is outlined in Fig. 3.3.6.1. -lil II I--i-I ---------1-- 1111-_ _ _ In - -70- __I F - DZ D ~E I I I~~ I ~~~~~~~ (a) Step One - Four Cell Averaging I new cell initialization area 2xDZ old cells transformed in Step One (b) i I Step Two - Initialization of New Cells Figure 3.3.6.1 Mesh Coarsening Procedure Steps -71- a first step (a) the entire mesh is swept over, four cells at a time. Note that the number of cells vertically or hor- izontally must be even in order to do this. The fluid vari- ables in these four cells are averaged in the following way: the cell specific internal energy, momenta, and turbulence kinetic energy are mass-averaged over the four cells, since these variables are defined on a per unit mass of air basis. The cell pollutant, eddy viscosity, and moisture variables are simply averaged over the four cells, since these variables are not defined on a per unit mass of air basis. The cell pressure is set to zero, which conforms with the usual starting guess procedures in running VARR-II. The average cell made up from these four cells is now stored in its proper place on the larger mesh, which is half of the distance to the origin vertically and horizontally. When the entire mesh has been swept, four cells at a time, the old mesh has now been relocated in the lower left corner, and is one-fourth of its old size. In a second step b) the remaining three-quarters of the mesh needs to be initialized. row in ascending order, This "new" area is swept row-by- The velocity field is assumed to be initially at rest, and th.e pressure field is initially set to zero. The remaining atmospheric state variables are all spec- ified from a master library of profiles. When the "new" area has been initialized, the calculation is restarted with the ---------------- -72- vertical and horizontal mesh spacings doubled. The computer mesh may be coarsened up to five times during a simulation--this would result in a final mesh that is 5 2 5 x 2 = 1024 times as large as the original mesh. The five times are user specified, and need not take place at regular intervals. 3.3.7 Plume Statistics Package At regular intervals specified by the user, the program calls on a statistics package to calculate a number of important plume statistics without printing out the data of the entire computer mesh. The quantities that are reported by the statistics package are listed in Table 3.3.7.1. The average plume advection velocity is the feature discussed in Sec. 3.3.3, and is defined in Eq. 3.96. -73- Table 3.3.7.1 Data Reported by the Plume Statistics Package Units Quantity jl I_ Time of Simulation sec Total Number of Problem Iterations (none) Current Number of Pressure Iterations (none) Current Time Step Size sec Center Height of Pollutant Field ft Total Specific Internal Energy on Mesh BTU Average Downwind Advection Velocity ft/sec Plume Downwind Distance ft I· 1 ^II 111 IIJLIIPI___LII___1·1111111-·---·1-^ -74- 4. DESCRIPTION OF ATMOSPHERIC TURBULENCE 4.1 Introduction This chapter describes in detail how atmospheric turbu- lence is represented in the model. The description begins with the knowledge (e.g., from a set of measurements) of the common atmospheric variables as functions of height: the set includes the wind speed and direction, virtual potential temperature, water vapor density, and cloud liquid water density. The important processes that are responsible for the characteristic shapes of these profiles are outlined, and the concept of layers in the atmosphere arises naturally in the explanation of the interdependencies of the profiles. With a working know- ledge of the dominant phenomena in the atmospheric layers, the problem of prescribing the atmospheric turbulence is undertaken. For the model in this work, the atmospheric turbulence is specified with profiles of eddy viscosity and turbulence kinetic energy. The relation of these two variables to the other profiles, and their inclusion into the model occupies most of this chapter. 4.2 Atmospheric Profiles of Wind, Temperature, and Humidity The vertical atmospheric profiles considered in this work -75- are assumed to have been measured with some appropriate meteorological instruments over a flat terrain. For instance, a tower with a series of instruments at various heights would produce essentially pointwise values of the variables, which could then be linearly interpolated between the measurement heights to produce the full profiles. It is assumed that the measurements were time-averaged for at least 20 minutes so that there is very little time-dependence in the profiles. Alterna- tively, a radiosonde (balloon) ascent is commonly used for measuring vertical profiles, although the measurement averaging times are not long enough to completely average over the larger atmospheric eddies. The measured atmospheric wind profiles have several common features. First, the atmospheric wind vanishes at the ground. This is in accord with the no-slip velocity boundary condition of real fluids. Second, the time-averaged (i.e., averaged over about 20 minutes) vertical velocity is very small at any height. This is because the very low frequency (of the order of 1 per day) vertical velocities are due to the synoptic scale subsiding or lifting motions associated with fronts; these velocities are usually only about 10 cm/sec. Because the average vertical velocities are small, the wind at any height is assumed to be parallel to the ground. Generally, the wind speed increases with height and commonly exhibits some turning with height-- -76- especially in the first several hundred feet of elevation, where pressure gradient, Coriolis, and frictional forces are all important. The fact that the wind vector may very roughly approxi44 45 or a thermal an Ekman spiral, mate a logarithmic profile, wind relation,46 is only of minor interest here since the actual wind profile determines the behavior of an individual plume. In this work, the turning of the wind with height is not represented in the hydrodynamic simulations, although the prospect of including it is considered among the extensions of the model outlined in Sec. 6.2. Also, the difficulty of defining an average wind direction when there are only light, variable winds at a station dictates that the computer simulations are not expected to be accurate for winds of less than about 5 knots. The temperature and humidity profiles directly provide the information about the local stability of vertical atmospheric and plume motions. No approximations to the temperature or humidity profiles are needed to incorporate them into the simulations. The temperature and humidity profiles are used to evaluate the virtual potential temperature profile: Note that in defining equations for virtual potential temperature (Eq. 3.53 and Eq. 3.67) the temperature, humidity, and pressure are required at any height. To this end the pressure profile could have been measured by itself, or calculated with any of -77- a number of approximations (dry hydrostatic, moist hydro- static, various interpolations between points, etc.) Whatever assumptions are made, the pressure profile consistent with these assumptions must be input to the simulation where it is used to recalculate the correct temperature from the virtual potential temperature and humidity for the equilibrium moisture thermodynamics model. 4.3 4.3.1 Turbulence in the Planetary Boundary Layer Introduction The planetary boundary layer CPBLL is a boundary layer in a rotating, stratified, multi-component fluid whose moisture component can undergo changes of phase. Further, the boundary conditions on fluxes of momentum, sensible and latent heats, and radiant energy can vary greatly over large and small distances (i.e., distances that are large or small in comparison to the depth of the boundary layer), and are typically strongly coupled to the flow. Although. a number of excellent reviews have been written 4 7 - 5 7 at many levels of detail, the basic notions of turbulence in the planetary boundary layer are developed here with the aim of pointing out the limitations of the description of the PBL turbulence embodied in the computer simulations. -78- 4.3.2 Layers in the PBL and Important Processes Without much loss in generality, it is assumed in this work that all of the energy in turbulent atmospheric motions ultimately comes from the sun. Although it is possible to conceive of special situations where this is not quite true (for example, the turbulence near a busy expressway, much of which is caused by mechanical stirring and buoyant exhausts), the atmopsheres which are encountered in this work are free of man-made turbulence, except for the buoyant plumes themselves! For the purposes of illustration, the solar energy which produces atmospheric turublence may be divided into two streams: (1) that part of the solar energy that produces the large synoptic-scale pressure patterns on the earth, which in turn drives the wind and produces turbulence in regions of the atmosphere of sufficiently large wind shear, and (2) that part of the solar energy that produces the local thermal stratification of the atmopshere, which in turn produces turbulence in regions of sufficiently unstable stratification. The turbul- ence that is produced by the first stream is called "mechanically produced turbulence," and that produced by the second stream is ca-lled "buoyancy produced turbulence." The thermal stratification that is produced by the second stream is usually formulated in terms of virtual potential temperature, so that -79moisture and latent heat effects are naturally included in the "buoyancy produced turbulence." There are two mechanisms that destroy atmospheric turbulence: (1) viscous dissipation, which is always at work in a turbulent flow, and (2) buoyant destruction, which is present in regions of stable thermal stratification. From the preceding discussion it is expected that in a region in steady state the mechanisms of turbulence production and destruction will be balanced, and that the turbulence kinetic energy will maintain a value that is commensurate with the destruction rate. Very commonly in micrometeorological studies, the regions that these processes are studied in are simplified to layers, so that the description of atmospheric turbulence becomes one-dimensional--the single dimension is then height. The situation is illustrated in Fig. 4.3.2.1. In the uppermost layer of laminar flow, the'strong geostrophic winds usually have very small wind shears with height, and are usually associated with stably stratified air, so that there is little or no turbulence. The next layer down usually is a region of buoyancy produced turbulence with only small wind shear--the buoyancy is typically from solar heating at the ground and latent heat release in cloud formation (clouds ob- viously affect the amount of solar heating at the ground, so that these effects are strongly coupled). _ __ __ ____ The layer nearest I___ -80V g laminar (geostrophic) flow (very small turbulence kinetic energy) clouds buoyancy - dissipation (small turbulence kinetic energy) shear + buoyancy - dissipation (large turbulence kinetic energy) EART Fig. 4.3.2.1 The Concept of Layers in the Planetary Boundary Layer. Atmospheric turbulence is assumed to be variable in one-dimension only in this figure. The turbulence is steady-state. -81- to the ground typically exhibits a lot of wind shear due to the no-slip condition at the ground, so that mechanically produced turbulence is present in addition to buoyant production, and turbulence kinetic energy is usually a maximum somewhere in this layer. The particular illustration of atmospheric layers in Fig. 4.3.2.1 is certainly not unique. Many investigators have coined names for layers to illustrate different refinements on the processes in the PBL. Such terms as the surface layer, Ekman layer, subcloud layer, cloud layer, inner layer, outer layer, tower layer, convection layer, inversion layer, superadiabatic layer, and viscous sublayer are common, but they do not represent anything more sophisticated than treating the atmosphere as one-dimensional. The prospect of treating the atmospheric state as two-dimensional--now including its downwind development as well as its profile with height--is considered in Sec. 5.4.1 in conjunction with the modeling of a fumigation episode. 4.3.3 Prescription of the Eddy Viscosity The prescription of the eddy viscosity in the two-dimen- sional mesh of the crosswind alignment scheme of Fig. 3.3.2.1c is considered in this section. --- I It was mentioned in Sec. 3.3.2 I - -- -82- that the absence of any mean wind component (by definition) in the crosswind direction means that, away from the plume, and as far as the computer simulation is concerned, there is no explicit mechanical production of turbulence in the atmosphere. In fact, what takes place in the atmosphere is that the turbulence kinetic energy component, u' , and the Reynolds stress, u'w', of the downwind x-z plane are feeding into the crosswind y-z plane turbulence kinetic energy component, v' , and Reynolds stress, v'w', through the return to isotropy term in Eq. 3.40. For this work, the assumption is made that the return to isotropy term is very strong, so that the turbulence is isotropic. Experiments on atmospheric return to isotropy indicate that this assumption is reasonably good. 58 It is seen in the discussion of the results in Chapter Five that this is probably the most limiting assumption in the work with regard to being able to model real atmospheres. The eddy viscosity as a function of height in the downwind x-z plane is estimated from a number of prescriptions for eddy viscosity that are correlated from mean wind and temperature profiles, then the eddy viscosity in the crosswind y-z plane is assumed to be the same as in the x-z plane under the assumption of isotropy. The incorporation of an ambient eddy viscosity profile on the simulation mesh finds two problems. First, any -83- arbitrary eddy viscosity imposed on the mesh cells at the start of the simulation will, in the absence of sufficient mechanical and buoyant production, rapidly decay down to the molecular kinematic viscosity. Second, the turbulence field inside the plume must be allowed to develop on its own. The method of incorporating the ambient eddy viscosity profile in light of these problems is as follows: to start the simulation, the cells outside of the initial plume cells are initialized with the eddy viscosity profile, depending on their height in the mesh. After each time step, each cell on the mesh is tested to see if it has fallen below the prescribed eddy viscosity profile at its height. If it has, its eddy viscosity is simply reset to the ambient value. If it has not fallen below the ambient value, presumably because either the plume-induced turbulence or the turbulently diffused turbulence from neighboring cells is dominating, then the cell eddy viscosity value is left alone. In this way, the far field always maintains the ambient atmospheric turbulence values, and the plume turbulence, if greater than the ambient turbulence, is left to develop on its own. Overall, this method has the effect of adding a non-uniform source term to the eddy viscosity equation--the term always adjusts itself to yield the original eddy viscosity in the far field, and to "turn itself off" if the plume turbulence is dominating. Mathematically, the -84- inequality a(y,z,t)l alibrary(Z) (4.1) has been added to the equation set, where libary(z) is the prescribed eddy viscosity profile as a function of height. Before discussing the available prescriptions of eddy viscosity, it should be noted that the potentially most accurate method of prescribing the eddy viscosity for an individual release would be to actually measure it in the field--perhaps simply by estimating it from bivane wind fluctuation data. The effort in this work to arrive at workable prescriptions from the micrometeorological literature is motivated by the total absence of these measurements in existing plume field data. The particular prescriptions that are recommended here are used only because they offer a simple way to estimate the eddy viscosity profile. A number of prescriptions for the eddy viscosity in the outer boundary layer of the atmosphere as a function of height have been reviewed. 5 9 64 A summary of the various prescriptions is presented in Table 4.3.3.1, where they are separated into two major groups--those that require wind speed and direction profiles, and those that do not. Those which do not require wind profiles as input are easier to use because the wind profiles need not be measured (e.g., with instrumented towers or -85- a) 0 U) a U) a Uw a · z >1 >1 >1 :>.,c O O a) a) U) a) U) a) tn a O tn En a) a ao la-Q rC (a 43 ¢ r. a) U) .4 C 0 U4 0 a) I ..i - H r--t Cd m c .4-i tn .r-i r-- U a C a 0 C' U a) >1 ..Q H 4 CI1 .ri C a 0 4 4 O U) : 0 .r o U) 0 0 lz Q-4 a ,4 ,l O a) 3 N tO a Ss P4 cn a) 04 E! u z O 3 a) .,fl 01 a) 4, .4 to .a -,.4 t.t: H m "C S o- C rd U to ·U 3 0-. 43 0 O EH 43 O N~ d C O o a . Z~~~~a c O 0 0 m -86- balloons). However, they are not expected to be as accurate, since the wind profile has taken an ideal shape. All of the models in Table 4.3.3.1 are searched for applicability to neutral, stable, and unstable atmospheres. It is recommended that if the wind speed and direction profiles have been measured, the prescriptions of Blackadar, 5 9 ' 6 0 and Yamamoto and Shimanuki 6 1 should be used. If the wind speed and direction profiles have not been measured, the prescriptions of Bornstein63 or O'Brien 2 should be used. The pres- cription of Nieuwstadt 6 4 requires a substantial numerical analysis of the profiles and has not been tested. Any of these prescriptions must be used with caution since all of them are only capable of providing an estimate to the eddy viscosity. The greatest difficulty in using these pre- scriptions is that they typically require values for quantities that were not measured, such as the heat flux at the ground, the roughness height, geostrophic velocity, etc. 4.3.4 Prescription of the Turbulence Kinetic Energy The prescription of the turbulence kinetic energy (TKE) in the two-dimensional mesh of the crosswind alignment scheme of Fig. 3.3.2.1c is considered in this section. The turbulence kinetic energy suffers from exactly the same problem as the eddy viscosity in Sec. 4.3.3.: in the absence of explicit -87- buoyant and mechanical production of turbulence on the twodimensional mesh, the turbulence kinetic energy would gradually decay away entirely. To satisfactorily avoid this problem, the concept of the turbulent "return to isotropy" is again invoked to allow the turbulent kinetic energy produced by the mean flow shearing and buoyancy to be fed into the crosswind motions. A turbulence kinetic energy profile is needed, so that it may maintain the turbulence for mesh cells that lack the sufficient turbulence production in exactly the same way that an eddy viscosity profile maintains the eddy viscosity for the mesh. Ideally, the TKE profile should be measured or deduced from other profiles for an actual atmosphere. In fact, how- ever, prescriptions for the turbulence kinetic energy from mean wind and temperature profiles are not generally available in the literature. The actual prescription of the turbulence kinetic energy profile in this work has had to come from the following, very approximate analysis of the transport equations. Consider the TKE transport equation in a region away from the plume. The vertical and horizontal velocities, v and w, are zero, and the eddy viscosity, , and TKE, q, are functions of height, z, only; with the resulting expression being -88- s at 4q2 + r az c- aa) z (4.21 For a properly time-independent TKE, there must be a balance of dissipation and diffusion in Eq. 4.2; or g = ra (v ) (4.31 Performing a scale analysis of the terms, noting that r/4, 10 and that the depth of the planetary boundary layer is taken equal to Ldy , one obtains the result (4.4) q 10 eddy For typical values in the atmosphere, c-100 ft2/sec and L eddy 'w103ft,giving the value q 10 -3 sec - (4.5) Note that for a highly idealized picture of turbulence,65 with eddies of a single size, Leddy and velocity, Ueddy q~ueddy ' q-u~2 ~(4.6) (4.71 Ueddy eddy and therefore Ueddy a Leddy 1 ] -sec- (4.8) -89- This states that q/a is simply the inverse of the eddy turnover time. The scale analysis (Eq. 4.5) of the q transport equation shows that the choice q-10-3secallow q to have a constant value. a should roughly The fact that this choice of q agrees with the eddy turnover time of roughly the most diffusive atmospheric eddies 6 6 (103 seconds, or about 15 minutes) lends support to the idea that a and q have been chosen consistently in this scheme. The crude specification of qlibrary(z) has been found to be satisfactory in this work primarily because the turbulence kinetic energy only indirectly influences the eddy viscosity, so that errors in estimating TKE are tolerated much more than the errors in estimating the eddy viscosity. The preceding analysis, since it is a scale analysis, only provides a very approximate estimate of the turbulence kinetic energy profile. Mathematically, the inequality q(yz,t)> qibrary() = 10-3sec -1 library(z) (4.9) has been added to the equation set, where qlibrary (z) is the prescribed turbulence kinetic energy profile as a function of height. -90- 5. RESULTS 5.1 Introduction The discussion of the results of the computer plume sim- ulations is very naturally divided into two sections corresponding to the two regimes of plume behavior outlined in Sec. 1.2.2. To illustrate the two regimes, typical values of effluent temperature, velocity, and pollutant are shown in Fig. 5.1.1 for several stations downwind of a large combustion source. At the stack exit, the plume rushes upward at 20m/sec, is about 100 0 C above the ambient air temperature, and has an SO 2 concentration of about 100 000 pphm (parts per hundred million). At the second station the plume has become diluted about 200 times. Without a detailed picture of its cross section, it may be stated generally that its average temperature excess is now only about 0.5°C and its turbulent velocity fluctuations (disregarding those induced by its buoyancy) are about 10 cm/sec--and these are just about on the level of observed atmospheric fluctuations. However, the plume SO2 concentration is still many times higher than the background SO 2 level, so that the plume is recognizable by its SO 2 concentration field, but not by its temperature or velocity fields. Throughout this first regime the plume -91x 0 0 En 4 c ..4 .C "4 C) H C E 0 -C 0 Ua 4 C Oan 0 rd .9-4 U in .r4 H 0 f O 0 0oo In 0 m 0- 4:J H 0 0 Oz C) E-4 4 O H W O 0 H ..4 U) C :> g C · 0 0 P4 Ln E4 C) 0W w rM ri U 0- 0 o ° CU 2 r . ,- I _ _ 0 0 C)U O l) U U 0 x H E- 4 4J 4-,o C) 4U-4 C 4 V ,' 0C *a 0 n o ¢> ~ -N o 00 _C_) z: C Cm -92- velocity and temperature fluctuations have been stronger than the atmospheric fluctuations, so that in a large part the plume motions have been dominated by the plume properties. Throughout the second regime the atmospheric motions are responsible for the plume dilution to the point where the pollutant becomes indistinguishable from the background level, and the plume disappears. The selection of these regimes is very natural in the discussion of the results. The results that are applicable in the plume dominated stage will address the question of how adequately the dynamics of a buoyant, deflected plume are simulated. Such results are found in Sec. 5.2. The results that are applicable in the atmospheric dominated stage will address the question of how adequately the atmospheric turbulence is being simulated. Such results are found in Sec. 5.3. The results in Sec. 5.4 are essentially model extensions that are applicable in the atmospheric dominated regime for Sec. 5.4.1, and the plume dominated regime for Sec. 5.4.2, but which do not have a body of experimental results to be compared with. The plume simulations that are presented in this chapter have been included for several different reasons. The general simulation in Sec. 5.2.1 is included to acquaint the reader with the general features of the buoyant line-vortex. The -93- detailed comparison of simulations like the one in Sec. 5.2.1 with experimental results is made in Sec. 5.2.2. The effect of thermal stratification on the buoyant line vortex is then developed in the simulation of Sec. 5.2.3. The simulations for comparison with actual field studies again considers the neutral atmosphere case in Sec. 5.3.1. The effect of thermal stratification is then developed in the simulation of Sec. 5.3.2, where a large stack plume in a low-level inversion is studied. Simulations that demonstrate the model extensions are found in Sec. 5.4. 5.2 5.2.1 Comparisons to Analytical Models General Nature of the Solutions The general nature of all the computer solutions in this work is discussed in this section. All of the simulations are performed on a 20 cell by 20 cell mesh, although the cell height and width vary between different simulations. The time step size is selected by the program at each time step, and is usually from one-tenth of a second to several seconds. The selection of a time step size is performed by the code,6 7 where it always chooses the smallest step size from a choice of -94- a diffusion condition, TSTEP .. T DT = max ( ;Dy7t 1 5 .1) Dz 2) a Courant condition, DT = DT TSTEP min(Dx,Dz ) max v,w) 5.2) C5.2) or a simple rate of change condition, DT .2 max (v,w) (max(v,w) - max(vold,wold) + 10 where TSTEP usually has a value of 0.01. (5.3) As a practical matter, it is found that the time steps have to be reduced beyond these conditions by about a factor of 25 for the mesh cell sizes encountered in this work. This allows the codeto conserve energy in the computer mesh cells within an acceptable tolerance. The non-conservation of energy arises from the first order accuracy of the differencing scheme for the advection terms. Full donor cell differencing of the advec- tion terms is found to give the best answers in the simulations--less than full donor cell differencing produces noticeable nonlinear instabilities in the flow. A simple plume development is found in Figures 5.2.1.1 to 5.2.1.6. Figure 5.2.1.1 interprets the mesh cell quant- ities found in the following figures. In Fig. 5.2.1.2, the -95- ordered-pair notation for locating cells e.g., 3rd cell from left, 2nd from bottom w velocity, ft/sec f^ cell temperature, OF 0. 0 XXXXX XXXXX ( 3, 2) " 49.999 F ZLL x X X Y X X DZ X 0.1 TNU= 1.000E+00 X X CHI= 1.OOOE-05 X X VAP= 1.OOOE-07 X X LIQ= 1.OOOE-07 X X 1 X TKE 1.0OOOE-03 X v velocity, ft/sec _-xxxxxxxxxxxxxxxxxxx k- DY-| eddy viscosity in ft2/sec turbulence kinetic energy in ft2/sec2 CHI is pollutant concentration in lbm/ft 3 VAP is water vapor density in lbm II2 0/ft 3 LIQ is liquid water density in lbm H20/ft3 TNU is TKE is Fig. 5.2.1.1 Key to Cellwise Quantities for Figs. 5.2.1.2, 5.2.1.3, 5.2.1.4, 5.2.1.6, and 5.3.2.1. -96XKKK 0.0 XKXXXxxK 0.0 KKXXKKXx X' A X K 4 2, 9) 49.999 F 0.0 X X ( 3, 81 49.999 F X X 0.0 ( 4 8 49.q99 F 0.0 XXKXXXXK X X X XKXXXXXXx X XXXXX X I 5 8) 49.9)9 F X X X X X X X I 6, -"49.99 X X X 8) F -. 1 O.0. 0.0 I 0.0 I 0.0 0 I 1.COOE0a X TNU= t.COOE+OO X r TNU X TNU, 1.000E+0 X TNUs 1.OOOE00 X TNU' l.OOOE.o00 s X tKE I.OOOE-03 X TKE 1.O000E-03 X TKE- I.COOE-03 X TKE= l.00OE-03 X. TKE= I.0OOE-03. X 1.00E-05 X X CHIs 1.000E-05 X CHIs 1.000E-05 X CHI" 1.013OE-05 X CHIs 1.OOE-05 X CH-I 1, COOE-7O X X VAP, l.03OE-07 X VYAP- I.COOE-07 X VAP- 1.00E-07 X VAP-4.OO0-07 X VYAP X L1Q, l.OOCE-37 X LEO 1.0006-07 K LXG. 1.00OE-07 X LIO0 1.COOE-07 X LIQ- 1.OO00-07 X 0.0 XXXxx. XXXXX 0.0 XXXXXXX 0.0 XXXXXXXXX 0.0 XXtX..XXXX 0.0 XXXXXXXXX X X X X X X X 1 2, 7) X 1 3, 7) X I 4, 7) X I 5, 7) X I 6, 7) X' X X 49.999 F X 49.999 F X 49.991 F X 49.999 F X 49,.999 F X X X X x X 0 I 0.0 1 0.0 1 0.0 1 0.0 I O.C = X TUO 1.OOE+00 X TNUu 1.00CE+00 X TNU 1.000E*00 x ThNU 1.0000 X ThU- 1.COOEOC X X TKEw 1.000C-03 X TKE a 1.00E-03 X TKE .OO000E-03 X TKE 1.000OE-03 X TKE- I1.nOE-03 X X CHI, 1.000E-05 X CHI 1.0OOE-05 X CH- I.COOE-05 X CHI 1.000E-05 X CHII l.COOE-O5 X X VAP- .000EX VAP .COEX AP07 X YAP AP X.COOE-07 .COOEVYAP.COOE-C X XX I LQ10 t.OOOE-07 0 X L 1OCOE-07 LIQ= 1.006E-0 EX LIC 1.000E-0 X E X LIQ X .OOEX XXXX 0.0 XXXXXXXXX 0.0 XXXXXXXXX 0.0 xXXXXXXXX 0.0 XXXXX0XXXX 0.0 XX X X X X X X I S 6) X I 6, 6 X 1 2 6 X 1 3, 6) X I 4* 6) X X .X 49.999 F X 49.999 F X 49.999 F X 4q.999 F X 49.999 F X X X X X X X 0 1 0.0 1 0.0 1 0.0 I 0.0 1 O.C X TNUJ 1.000E+OO0 X TNUs 1.000E+00 X TNU- 1[.E00 X THU= L.CCOE+00 X TNA U l.00OE00 X X TKEx 1.00E-03 X TKES 1.0005-03 X TKE 1000OOE-03 X TKE 1i.GOOE-03 X TKE- 1.000E-03 X CHII 1.COCE-35 X CHi 1.C00E-05 X CHII 1.030E-05 X CHI' 1.000E-05 X Cl! 1.OOCF-C5 X X YAP.OOOE-07 X VYAPs 1.COOE-07 X VPw 1.00OE-07 X VAP 1.0006E-07 X YAP .00OOOE-C? X X LIQ t.COCE-07 X LIO- 1.COOE-07 X LIQ 1.OOO-07 X LIQ L.000E-07 X LIQ0 1.000E-C1 X XXXXX 0.0 XXXrXXXXX C.C XXXXXXX 0.0 XXXxxXXxx 0.0 XXXXAXXXX 0.0 XXA;X X X X X X X X ( 5, S5 X ! 6, 51 X .(.'5)X S X ( 3, 51 X (2, X 49.999 F X 49.999 F X 49.999 F X 49.999 F X . 49.999 F X X X X X X ' X a 1 0.0 I 0.0 1 0.0 1 C.O 1 0.0 X TNU- 1.OOCE+00 X TNU- 1.CGOE00 X TUs I.000E+00 X TNU. 1.000E+OC X TNUM l.OOCE*CC X X TKE- I.COCE-03 X tKE" 1COGE-03 X TKE.0OOOE-03 X TKE 1.000E-03 X TKCs 1t000E-03 X X ;H I 1.000EC05 X CHI- 1.000E-05 X CHI- [.00OE-05 X CHIt 1.000E-05 X CHI l.0OOE-CS 'X X VAP- 1.000E-07 X YAP- 1.00-07 X VYAP- 1.000E-07 X VAP- L.OOOE-07 X VAPs 1.00OE-C7 X X LIQ- L.OOCE-07 X L1- [.CCOE-07 X LO= 1.000E-07 x LIC= 1.OOOE-07 X LICs 1.000E-07 X XXXXX 0.0 XXXXXXXXX 0.0 XXXXXXXXX 0.0 XXXXXXXXX 0.0 iXXXXXXx 0.0 -XXXXX: X X X X X X X X I 4i 41 X ( 5, 4) X 6, 41 X ( 2 41 X t 3, 4 X 61.088 F X 49.999 F X 49.999 F X 49.999 F X 49.999 F X X . X X X X o 1 0.0 1 0.0 01 0 1 C.O .C 1 X TNUw 1.OOOE02 X TNU- I.COOE+00 X TNUI l.000E+00 X TNU. l000E'00 X TNU. I.OGOECC X X TKE- I.OCCE+02 X TKE- I.COOE-03X TKE- 1.000E-03 X TKE s 1.000E-03 X TKE l.O00CE-C3 X X CHI- 1.00E00 X CHIs 1.CCOc-35 X CHI 1.0O0EE-05 X CHI' 1.COOE-05 X CHI- I.COOE-05 X X VAP- 1.OOQE-07 X VAP- 1.000E-07 X vAP. I.OOOE-07 X VAP.00OOE-07 X VAP- 1.000E-07 X X LIQ- 1.OOE-07 X LIQ- L.000E-OT X LO- 1.QOOE-07 X LQ = 1.COOE-07 X LOQ 1.000E-07 X XXXXX 0.0 XKXXXK 0.) X. 'KXXXXXXXX 0.0 XXXXXXXX 0.0 XXXXXXXXX 0.0 XXXXX X X X X X X X X I 4, 3) X { 5 3 X I 6w 31 X ( 2 3 X ( 3, 31 X 49.999 F X 49.999 F X 49.999 F X 49.999 F X 49.S99 F X X X X X X X 0 1 0.0 1 0.0 0.0 1 0.0 1 0.0 X TNU- l.00E*00 X TNU 1o000f00 . X TNU- 1.0O0E+00 X TNU= 1.C00E+00 X TNU= 1.OOE+00 X X TKE= 1.00GE-03 X TKEs l.C00E-03 . TKE- I.COO0-03 X rKEw l.COOE-o3 X TKE= I.CCE-C3 X CHI 100E-05 O X CHI= 1.000E-05 X CHI I 1.OOCC-05 X CHI= 1.C30E-05 X CHI= 1.0OOE-G X X VAPw 1.000E-07 X VAP- 1.00OE-07 X VAP t.COOOE-07 x VAP = 1.COOE-07 X VAP= I.COOE-07 X I.OCOE-07 X LIC= 1.COOE-07 X X LIO L.000E-07 X LIQO 1.000E-0? X LI0' 1.003E-Q7 XKL1Q XXXXX 0.0 XXxXXXXXX O.0 XXXXXXXXX C.0 XXXXX 0.0 XXXXXXXX 0.0 XXXXXXX X X ( 2, 2) 49.999 F X X X X X ( 3 2 49.999 F I 0 X X X X 1 0.0 TNUs l.000E00 X TKE- l.OnOC-03 X CHI- 1.00CE-5 X .OOrF.-7 X V.AP- 5.2.1.2 X I 4, 2) 49.999 F 0.0 TNU. TKECHI* VAP. IOIxEXXXXXX X I 5, 2) 4',.999 F X X X 1 0.0 Trlu. 1.00OEO00 X TKE. l-OOC-7'3 XK CHII L.000-aS X VAPs l.oonnr-o7 x X LQ= tl.0'-)7 X L IQ= I.0CE-o X .XXXXE 0.0 XrKxxxXXX Fig. X X x ( 6, Z) 49.999 F X X X X 1 0.0 l.OOaF+t0 X I.COOE-03 X 1 0.0 TP!j= 1.3iCSO tKE= 1.CZOt:-O3 x X X X 1 0.0 CIr= 1.03r-O X [.Onfr-nO7 X VAP= I.CXO'E-O X 1.OGOE+CO0 X Tn rX TrK.= 1.C0C-03 X CHI = I.C00-C5 X V.M= 0.0 O:!-A7 1.; X .I 1.OCOF-0 0.0 X X XXXXXXXXX .:).:E- O.n XOXXXXXXt 1. COCt -C x 0.0 xxxxx Initialized Plume Cross Section at 0 sec. DY = 100 ft, DZ = 200 ft. Disregard moisture values. -97- entire 400 mesh cells are initialized at rest and at 50°F, except for one warm cell(2,4)centered 500 ft/high (and on the left boundary) which is at rest and at 68 F. is 200 ft high and 100 ft wide. Each mesh cell The ambient turbulence is set uniformly to 1 ft /sec in eddy viscosity and 10 ft2/sec 2 in turbulence kinetic energy, which are essentially laminar values compared to the values that develop inside the plume cell. After 20 seconds of development (see Fig. 5.2.1.3) a vortex circulation has formed in the vicinity of the warm fluid, and mixing has brought the warmest fluid cell (,4) from 68 F to 61.24°F. The strongest updraft (6.57 ft/sec) occurs in the warmest cell, and the downdrafts tend to be weaker, since they are spread over a larger area. After 80 seconds of development (.see Fig. 5.2.1.4) the plume has risen 379 ft. Considerable mixing has reduced the warmest cell temperature to 52.9°F from 680 F, and the updraft has now increased to 10.8 ft/sec. Again, the vortex circula- tion is very easy to identify and it occupies a progressively larger area as the plume cross section grows. The turbulence kinetic energy field at this point in time is illustrated in Fig. 5.2.1.5, where the maximum TKE occurs in the updraft region and is about 1600 times that of the ambient field. After 200 seconds of development (see Fig. 5.2.1.6), the -98XXXXX0.215 YXXXXNXXC.107 xxxXxxx 0.142 XXXXXXXXX 0.073 xxxxxxxxx 0.041 XXXX) X X X X I e6, ) X X { 2 8) X ( 3, 8) X 4 8) X 5S, 8) X 49.922 F X X 50.137 F X X 49.942 F X 50, .019 F 49.922 F X X X X 0 1 0.073 1 0.120 1 0.148 1 C.121 0. 126 X TNU 1 .005E+00 X TNU- 1.C07E+30 X ThU- 1.005E+00 X TNU- 1.033E+OC X TNU- 1.00E+CC X X TKE- 1.039E-03 X TKE= 1.014E-03 X TKE- 1.009E-03 X TKE= 1.006E-03 X TKE- 1.OGIE-03 X X CHI5 1.084E-05 X CHI- 1.00£E-O5 X CHI 1.030OE-05 X CHI- 9.S99E-06 X CHl- 9.99E-06 X X VAP= 2.000E-07 X VAP- 2.000E-37 X VAP= 2.031E-07 X VAP-.2.COOE-07 X VAP- 2. CJE-07 X X LQ10 0.0 X LIO= 0.C X Lt0= 0.0 X X LIQ- 0.0 x L10- 0.0 XXXXX 0.348 XXXXXXXXX 0.232 XXXXXXXXX 0.209 XXXXXXXX 0.005 XXXXXXX 0.029 XrxX X X X X X X X 1 2, 7) X I 3, 7) I 5 7 X I 6, 71 X t 4, 7) X F X X 49.957 F X 49.777 F X 50.t09 F X 49. .964 F X 50 .089 X X X X X X O 1 0.209 1 0.294 1 0.277 1 C.254 1 0.218 = X TNU 1.000E00 X TNU= I.C39E+00 X TNU- 1.024E+00 X TNU= 1.010E+CC X TNU= 1.004t+CC X X TKE= 7.111r-03 X TKE- 1.239E-03 X. TKE= 1.050QE-03 X TKE= 1.019E-C3 X TKE= 1.0)37-C3 X X CHI- 2.144E-04 X CHI= 1.398E-05 X CHIt 1.004E-05 X CHI- 9.996E-06 X CH= 1.000E-05 X m= 2.030E-C7 X VAP= 2.000E-07 X VAP- 2.000E-07 X VAP= 2.030E-07 X VAPX 1.999E-07 X VA X LO1 0.0 X LIC- 0.0 X L IQ 0.0 X X LIQ1 0.0 X LIQa C.O 0.380 XXXXXXXXX 0.150 XXXXXXXXX -0.045 XXXXXXXXX -0.028 XXXXX XXXXX 3.791 XXXXXXXX X X X X X 4 6 X 1 5, 6) X X I 2, 6) X 6 6) X 3, 6) X 50.172 F X 49. .985 F X 50.012 F X 5C.040 F X 50.068 F X X X X X X 1 0.756 1 0.543 1 C.430 1 0.276 1 0.8375 = X TNU 2.255E+00 X TNU= 1.018OlE+00 X TNU 1.047E+00 X TNU- 1.028E+CC X TNUt 1.027E+CC X X TKEw= 3.841E-0 X TKE= 1.945E-02 X TKE- 1.626E-03 X TKE- 1.061E-03 X fKE- 1.052E-03 X X CHI 1.611E-02 X CHI 5.960E-04 X CHI- 2.124E-05 X CHI- 1.012E-05 X CHI- L.C00E-05 X VAP- 2.O00E-07 X VAP- 2.COOE-07 X VAP= 2.COOE-07 X VAP- 2.COE-07 X 'IAP= 2.000E-07 X LIQ= 0.0 X LI0.0 X LIQ= 0.0 x LIQ- 0.0 X LIQ- 0.0 X .XXXXX 2.530 XXXXAAXX 0.153 XXXXXXX -. 260 XXXXXXXXX -0.266 XXXXXXXXX -0.345 XXXXX X X X X X X X 1 2, 5) X 1 3, 5) X I 4, 5) X 1 5, 5) X 6 5 X X 54.088 F X 50.324 F X 50.061 F X 50.234 F X 49.888 F X X X X X x 0 1 2.009 1 1.302 1 0.711 I C.392 1 0.180 X TMUu 1.840E+01 X TNU- 3.753_+00 X TNU= 1.141E+00 X TNU= 1.084E+CC x TNI- 1.0TeE+CC X X TKE* 4.772E+00 x TKE- 7.725E-IL X TKEw 5.368E-02 X TKE= 2.?22E-C3 x TKE- 1.176E-C3 X X CHI- 2.405E-01 X CHI= 3.218E-02 X CHI= 1.717E-03 X CHIII 4.576.-05 X CHI- 1.032E-05 X X VAPw 2.000E-07 X VAP- 1.999E-07 X VAP- 2.00CE-07 X VAP- 2.COIE-07 X VAP- 2.COGE-07 X X LIQ- 0.0 X LQ= 0.0 X LI0- 0.0 X Ll0= 0.0 X LIQ- C.0 X :XXXXX 6.566XXXXXXXXXX -1.302 xxxXXXXX -1,462 XXXXXXXXX -Q.889 XXxxxxxxx -. 738 xxxX X X X-' K X- - - - X- X ( 2 4 X , 4) 4 X 4) X S 4 X ( 6, 4) X X 61.240 F X 50.768 F X 49.888 F X 49.908 F X 49.770 F X X X X X X X 0 1 -0.536 1 -0.461 1 -0.319 1 -0.260 1 -0.157 X TNU* 4.347E+01 X TNUm 2.428E+01 X TNU- 4.466E00 X TNU- 1.035E+00 X TNU- 1.071E+00 X X TKE- 1.122E+01 X TKE- 3.101E+00 X TKE- 9.614E-02 X TKE= 1.592E-03 X TKE- 1.146E-03 X X CHIt 6.256E-01 X CHI- 6.555E-32 X CHI- 1.012E-03 X CHI- 1.180E-05 X CHI- 9.999E-G6 X X VAP- 2.COCE-07 X VAP= 1.S99E-07 x VAP= 2.000E-07 X VAP- 2.OOO2-07 X VAP= 1.999E-C7 X X LTI- 0.0 X LO= 0.0 0.0 X L X LTO= 0.0 X LTC= 0.0 X -0.582 rNrXX -1.117 XXXXXXXXX -0.775 XXXXXXXXX -1.077 XX'XXXXXX XXXXX 5.434 XXXXXXXXX X X X X X I X I 2, 3) X ( 3, 3) X ( 4, 3 X 5, 3) X 1 6, 31 X X 49.735 F X 50.207 F X 49.860 F X 49.943 F X 50.116 F X X X X X X x 0 1 -2.248 1 -1.472 1 -0.924 1 -0.626 1 -0.426 X T 3. 3E+U 3.36E00 TNU 3.074E+30 X TNU- 1.050E+OO X TNU- t.151E+CC X TNU- 1.073E+CC X X TYrE 8.033E-01 X tKE- 2.349E-31 X TKE- 5.556E-33 X TKE- 1.33E-C X TKE- 1.14eE-C3 X X CHI- 1.297E-02 x CHI- 3.665E-03 X CHI- 4.321E-n05 CH[= 1.C04E-05 X CHI= 1.000E-05 X X VAP- 1.99)E-07 X VAP- 2.001E-07 X VYAP 1.999E-07 X VAP= 2.CCOE-37 X VAP- 2.000-07 X X LIQ- 0.0 x LIQ- 0.0 X LIQ0 0.0 X L1it 0.0 X LIQ 0.0 X XXXXX 1.012 XXXXXXXXX 0.435 XXXXXXXXX -0.102 XXXXXXXXX -0.217 xxxxxxxxx -0.154 XXXXX X X X X ! 2, 2) 49.659 F X X X X ( 3 2 40.999 F X X X X I 4, 2) 49.957 F X -0.492 1 -0.710 TI{Jr 1.0CRF+00 X TlU- 1.CCOE*0 X TNIJTKE- 4.085£-) X TKE- 1.iSlFE-)3 X TKE X CHI CH{I 1. 10-O5 X s 2 4S.915 F X 1 0 X X 2.746f-05 x X X Cl1= X X X ( 6, 2) 49.964 F X X X X 1 -0.618 I -C.583 I -0.50 1.147f+00 X T :U= l.06PE+CC X TNL-= 1.03E+CC X t.323F-Ol X TKE .t31. -3 X TrKF; 1.OSC-C3 I.0(,':-)5 X CMl= q9.96E-06 X CFl= .99E:-C6 X X YaPr I .99E-0 X VAP- 2.COOC-07 X V6Pz ?.000-01 X VAP= 2.OOOE-C7 X VAP= 2.C00O-C7 x x L1Q 0.0 x LIO= C. x LI)= 0.,) x LIO 0J.O X LI, 0o.0 x xxxxxxxx 0.3 xxxxxxxxx 0.0 XXIX: xxxxx 0.0 xxxvxgxxx C.C xxxxxxxxx 0.0 Fig. 5.2.1.3 Plume Cross Section at 20 sec. DY = 100 ft, DZ = 200 ft. Disregard moisture values. -99-0.170 IX.IXx 0.168 XXXXXXX xxxXXxxXX I.C4C XXXXXXX 0.609 xxxxXXXXX X X X X X x X 6., 83 I 5, 8) X 2 8) X 3 8 X ( 4, 8 X X 49.936 F X 5C. 137 F X X X 49.999 F 50.809 F 50.082 F X X X X X X X 1 0.843 1.585 1 1.118 I 1 1.592 1 1.860 0 X - TNi I- 5.087E*00 X TNU. 2.169E.00 X TNJU 1.658C+00 X TNUs 2.01ZE+CC x TNUI 1.370E+CC X :4.702E-01 X TKE. 1.135E-01 x IKI E2.026E-02 X TKE6.234E-C3 X TKE2.041E-C3 X TKI s 1.078E-02 X CHI. 1.448f-03 X CHI- 1.383E-C4 x CHIs 1.682E-CS X X CHI !- 4.895E-02 X CHI '2.00CE-07 X VAP2.000E-07 X VAIP 2.000E-07 x VAP- 2.000E-07 X VAP: 2.000E-C7 X X YV X L[I '.0.0 X LIQ- 0.0 X LIQO 0.0 X X LIQU 0.0 XI LIC1- 0.0 -0.752 XXXXIXXXX -0.7114 XXXX XXXXX 5.963 XXXXXXXKX 1.573 XXXXXxXXX 0.074 XXXXXXXX X X X X X X X X ! 6 7 I S 7) X 1 2 7 X t 3 7 X 1 41 7) X X X 49.999 F 50.165 F X 49.888- F X 50.927 F X X 52.397 F X X... X X X 1 1.345 1 0. 966 1 2.327 1 1.898 0 1 1.790 .560E+CC X TNU 1. 364E01 X TNU- 6.0942E00 X TNU- 2.564E*00 X TNUs 1.746E4CC X TNUX TKE, 1.42CE*00 X TKE- 5.864E-01 X .TKE- 1.550E-01 X TKE- 3.042E-02 X TKE- 5.69E-C3 : CHI- 2.2u9E-C4 X X CHIS 1.422E-01 X CHI& 5.942E-02 X CHI 1.527E-02 X CHI- 2.390E-03 X VAP- 2.000E-07 X VAP- 2.COOE-07 X VAPz 2.000E-07 X VAP- 1.991E-07 X VAP- 2.000E-C? X X X LIQa 0.0 X X LIQz Q 0.0 X L QO 0.0 X LtQ 00 0.0 X LIQ 0.0 -. 471 XXXXX -0.778 XXXXXXXXX -1.852 XXXXXXXXX 9.S35 XXXXXXXXX 2.644 XXXXXXXX XXXXX X X X X X X X 1 6, 6) X ( 5, 6) X 1 4, 6) 3 6) 2 61 X X 50.006 F X 5C.137 F g X X 5C.733 F X 51.870 F X 52.903 F X X X X X X 0.313 C.562 1 0.740 1 1.127 1 1 0 1 0.651 X TNU. 1. 802E+01 X TNU 1.130E+01 X TNU= 4.335E+00 X TNU 1..775+CC X tNU- 1.98CE4OC X X TEN 1.815E+00 X TXE- 1.200E+00 X TKEs 3.780E-01 X TKE- 7.838E-02 X TKE- 1.715E-C2 X X CHI. 1.763E-01 X CHI- 1.146E-01 X CHI= 4.295E-02 X CHIs 8.16TE-03 X CHI- 9.445E-04 X X VAPO 1.999E-07 X VAP. 2.000-07 X V.Ps 2.C00E-07 X VAP- 2.000E-07 X VAP- 2.COOE-07 X X X LIO- 0.0 X LIO- 0.0 X LWQ- 0.0 X LIQz 0.0 X LIQ 0.0 XXIXXX -1.998 XXXXX 10.633 XXXXXXXXX 3.637 XXXXXXXXX -1.545 XXXXXXXXX -2.236 XXXXXXXXX ' X X X X X X ( e, 5) X X ! 5, 5) 4 5) X 1 3, 5) X 2 5 X X 49.943 F X X 5C.096 F 50.324 .F X X 51.607 F X 52.119 F X X X X X 1 -0.833 1 -C.988 1 -1.372 1 -1.622 1 -1.157 0 TNU t.922E+CC X X TNU- 1.397E+0C TNU 283298E+00 X X TNU- 1.677E+01 X TNU. 1.1982.01 TKE- 8.061E-03 X X TKE. 1.643E*00 X TKE 1.242E+00 X TKEz 2.058E-01 X TKE- 3.337E-02 1.046E--01 X CHI- 2.520E-02 X CHI- 2.410E-03 X CHI- 1.479E-C4 X X CHIN 1.300E-01 X CHI VAP- 2.00OE-C7 X VAP- 2.000E-07 X VAP- 2.00CE-07 X VAP. 1.999E-07 X VAPs 2.000E-07 X _: . x x. J-..0[s-.O '.. ... X I:t .... X..LZG- .0.0 X. LIQ-O.O IxXxxxxx - ---r. 665 -XXXI. .- 'tr..O6l XXXxxxXX --*t. 48 XXXXX -' 8';533-XXXkXXC---*.-676 xxXXXXx' X X X X X X X ( 6 4 X I 5, 4) X 1 4, 4) X X ( 3, 4) ( 2, 41 X X X 49.811 F 49.902 F X X 50.061 F X 50.394 F 50.858 F X :XXXXX X X 2.792 X .. . X X X 1 -1.2 69 1 -1.733 1 -2.173 1 -2.552 1 -1.958 O TNUs 1.141E+O0 X NhUs 4.348E00 X TNU- 2.004E+00 X TNU, 2.577E+CC X X TNU. 1.359E+*01 X TKE8.188E-03 X TKE1.617E-02 X TKE 1.2b7E+00 X TK E- 8.776E-01 X TKE= 1.592E-01 X X CHlm 5.792E-02 X CH I 3.061E-02 X CHI- 8.101E-03 X CHI- 5.101E-04 X CHI- 2.975E-CS X YAP- 2.0002-07 X VAP- 1.999E-07 X X V AP 2.000E-07 X VAPAP 2.CCCE-07 X YAP. 2.000E-07 X X LIQ' 0.0 X LIQ. 0.0 X LIOJ 0.0 . X L1 0. 0.0 X LIQ- 0. 4.668 XXXXXXXXX 1.477 XXXXXXXXX -0.350 XXXXXXXXX -0.614 XXXXXXXXX -0.739 XXXXX 'XXXXX X X X X X X X X I6 3 1 5, 3) X X I 4, 3) X 1 39 3) X I 2, 31 X X 50.103 F 49.936 F X X 49.714 F 49.735 F F X X 49 .978 X X x X X X -1.166 -1.SO0 1 1 1 -1.970 I -1.76S 0 1 -1.689 3.1925+00 X ThUs 2.453E+00 X TNUw 2.1t50E0C X TNU' 2.20CE+CC X X TNU- 5.732E+00 X Th 1.307E-01 X TIE- 4.032E-02 X TXE- 7.152E-03 X TKE- 5.154E-C3 X X TXE 4.311E-01 X TI 2.758E-03 X CHI- 9.150E-04 X CHI= 5.188LE-5 X CHI- t.13E-05 X X CHI- 6.642E-03 X C YAP' 2.000E-07 X VAP- 2.COCE-C7 X 1.599E-07 X VAP. 1.qq9E-07 X YAP. 2.000E-07 X VA X X LIQ- 0.0 X LICs 0.0 0.0 X LIQ= 0.0 X LIQ. 0.0 X LI XXXXX 1.202 XIXXXXXXX 0.886 XXXXXXXXX 0.151 XXXXXXXXX -0.036 XXXXX. 0.01 XXXXXXXXX X X X X 1 2, 2) X 3, 2) x I 4 21 X ( 5 2) X I 6, 2) X X 49.583 F X .061 F X 50 .089 F X 49.995 F X 49.874 F X X X x X X 0 1 -0.619 L -1.082 1 -1.137 l -1. 113 1 -1.078 X TNU- 2.11SE,00 X TNU s 2.726E+00 x TNU. 3.23CE+00 X TNU-U 2.270ECC ( TrNL 1.936E2G X X TKE 2.4?2E-02 X TKE 1.;24E-02 x TKE% 1.210E-02 X TXF= 5.171E-C3 X TKE- 3.723E-C3 x X CHI. 7.8dlE-05 X CHI- 2.39LE-05 X CHI- 1.320C-05 X CHI= 1.031E-05 X C1iI 1.001E-05 X X VAPt 1t.98E-07 X VAP9 2.COOE-Q0 X YAP- 2.000o-07 x VAP- 2. 00E-C X VAP- 1.99'9E-C7 X X L Ir3 0.0 'X L:U' 0.0 X Llq= 0.0 x LIQ= 0.0 x LIC= 0.0 X XXXX 0.0 xxxxxxIxx 0.0 IxxxxtxEX 0.0o XXXXXXx 0.0 JlXXXX'XXX 0.0 xIxxxX Fig. 5.2.1.4 Plume Cross Section at 80 sec. DY = 100 ft, DZ = 200 ft. Disregard moisture values. -100- z 0.005 0.1 1.0 1.5 Y Fig. 5.2.1.5 Turbulence Kinetic Energy Profile at 80 sec. Contours of TKE in ft 2 /sec 2 . The maximum TKE is 1.82 ft2 /sec2 , and the minimum TE is 0.001 ft 2 /sec2 (throughout the far field). -101XXXX 4. 66h XXXZXtZZ X X { 2,12) X 50.588 X f X X 0 X X 1.270 1 TaU= 8.396.3-00 X -3,*%-%%TWIK.XX 0.917 XXXXXXXA.X 9.397 XXXXXXXX 0.014 XXXX Y X X X ( 3,12) T. 4,1'2) X ( 5,12) x ( 6,12) X 5..047 r 50.255 % 49.950 7 'X . 49.929 ? F X K 1 2.036 T'US 6.390+03J X X TE=r X CHI= I VAP. X LIQ= XXXXX X X 1 2.231 1 2. 37 T'1 3-SJ '.089E40 X T~IN1 2 .9q4'03 X TNU 'E 1.147E-01 X rKE= 3.51JE-02 X TXE Tl Es; 1 1.739 2.371E+00 X 1.140O-02 5.049E-01 X TKEs 3.143E-01 3.858E-02 X CHL- 1.840E-02 CHI Et= 6.147E-03 X X CHIs CHI- 1.435r-03 1.435-03 T X CHI* CHIs 2.628R-04 2.628X-04 X 3.857E-02 X VAP = 1.834E-02 X VAT?a VAP- 1.425E-03 X YAP= 2.52SE-0 ,a 6.137E-03 T x TAP· 1.425E-03 YAP' 2.528E-04 T S 7.714E-02 X LIQ 3.678_-02 X LI'av 2? 1.223E-32 X LIQ 2.850_-;)3 X LI;) 5.056Z-04 X 7.1b5 XXXXXXXX 3.oo1 XXIIXAIIXX . 11.249 29 XXXXXXXXX -- '.O.,'CF,7 XXXXx. -. 0Fi7 XXxxvxxrr XXXXXXX -0.%Rfi -0.586 xxxxv XXXX % X i S X ( 2,11) X ( 3,11) X ( 4,11) X ( 5,1) F 6,11) S x 50.990 X 50.699 F X 50.352 x 50. 14;F : 50.012 F I x X X X X x 0 1 1.191 1 2.153 1 2.442 1 2.207 1 1.781 · TiUS 1.321E+O01 TNUl 1.106101 X T1U0 6.546.+00 X TNU 4.055E00 X T'u 2.917E+00 I TKs 8.242E-01 X 'KE: 7.557E-01 X 'rr 3.537E-01 X 'KE 1.313-Cl X TKIE 4.229E-02 X CHIl 6.5191-02 X CHl- 4.620E-02 X CRII 2.2921-02 X CH= 8.101_-03 X CHI 2.071E-03 S I VAP 6.518E-02 X TIP= 4.6202-02 X VTAr 2.291E-02 X AP- 8.091E-03 X VAP: 2.0C61-03 X I LUQ- 1.304E-01 X LIZQ 9.239-02 S LXIQ 4.582E-02 X LIQ= 1.6183-02 % LQ= 4.123E-03 X XxxIX 9.549 XXXIXXXXX 5.520 XXXXXXX 1.d25 XXXXYXXXX -. 401 XXXXXXXS -1.429 XXYXX. X X X I 0 S (2,10) 51.031 F K X X ( 3,13) 50.962 X F x x X ( 4,10) 50.560 F X X ( 5,10) 5s.186 r x x I r % ( 6,10) 49.999 TF . K 1 0.616 1 1.358 1 1.676 1 1.520 1 1.199 1 TUw 1.373.+01 11NU 1.4495+01 X TNU= 9.508E+00 X TNU 5.302E+00 TIU- 3.155+,00 I TIE. 8.007E-01 X IKE- 1.077 '+3) X TKE- 6.129E-01 X TE 2.499E-01 X TIEE 8.170E-02 X I CUl 6.9821-02 X CrIZ 6.276E-32 X CE1I 3.956tE-02 X CHI= 1.769E-02 X CHII 5.453M-03 X s X TAPs 6.982Z-02 X VA, 6.2752-02 X YAP: 3.9555-02 I VAP' 1.768E-02 r VAP 5.443E-03 X I KLXQ: 1.3963-01 X LIQw 1.255E-01 X L1;= 7.91CE-02 X L'2 3.536E-02 I LIXQ 1.089E-02 X XXXII 10.783 XXXXXXXX 7.0039 XXXXXXX 2.458 XXXXXXXX -0.720 XIXXXXXIX -2.077 XXXXX I X X X t X K ( 2, 9) I (3, ) .. X 44( 9) X 5, ) I { 6, 9) X K 50.837 Ft 50.934 r x 50.657 -F X 50.269 Fr 50.006 r x K X X X K1 0 -0,308 1 0.230 1 0.396 1 0.339 1 0.298 TUO- 1.2433+01 TINU 1. 430E*01 TN= 1.331E+01 TNU= 5.267E+00 X TIJ 2.875E*CO X I TlK6.9412-01 X TK1.077E03 X TKE- 6.959E-01 X T2.578E-01 TE= 7.728E-02 r S CI1I 6.017E-02 K CHII 6.223E-02 X CIT= 4.516E-02 X CII= 2.060E-02 X CHRI 6.351E-a3 X I APs 6.016£-02 X VAPw 6.222E-02 X YA#P 4.515E-02 X AP- 2.059E-32 X VAP= 6.341E-03 X S-tIQ: 1.-203-01 X LIQ 1.245-51-1 K LOIQ 9.:30E-02.X .Lt. a .117;-02 LQ. 1.ti2f8E-Q2 X xftf -"fb;.76' XXXIXXJX'i ' 7.474.--XXXXftt 2i795 ZtKStXzX -'.R23 .%XXtItXXt1 -2, 149 1tXXX X ; X X X I ( 2, 8) X ( 3, 8) x ( 4, 8) X t 5, 8) ; ( 6, 8) X K 50.636 F X 50.754 F X 50.539 F X 50.179 P X 50.026 F X S ''S X O 1 -0.501 1 -0.384 1 -0.849 1 -0.39 1 -0.602 IrTUII= 1.112*.01 TI 1.2+01 154+01 X TNIw 8.778100 X TNHU= 4.489E+00 k TINO 2.716E+00 TKE: 1.973l-01 I TXI 6.111B-02 X TiE 6.3041-01 X TIKE 8.2111-01 X TEE'' 5.6741-01 C 4.694E-02 X CUIs 5.021E-02 X CHI= 4.157E-02 X CHI 1.996E-02 X CHI- 6.007'-03 X X AP- 4.6932-02 X TAPw 5.0201-02 X VAP=t .156E-02 X VAP- 1.995-02 TAP: 5.997E-03 X V K LIQ 9.3d63-02 X LIQ- 1.004-C X LI2: 8.310E-02 X L3:= 3.991.-02 X LIQw 1.199E-02 X XXSIX 5.763 XXXXXXXXX 6.718 XXXXXXXXX 2.861 %.089E*00 XXXXXXX -0.613 XXXXXXXXX -1.882 XXXX. x X X x X x K ( 2 7) 7) (4, 7) X (5 7 ( 6, 7) K __( 3, X 50. 08 X 50.498 F X 50.442 F X 50. 165 F . 49.971 F X x X X X 4 I .865 I -1.592 1 -1.882 I -1.710 1 -1.444 1. I TUJ 9. 805E+00 X tV1 8.357E+03 X T'YU 53.846&*00 X T:llJU 3.547£'3o X Tiqil' 2.6R5E+OC S.612E-01 X T$;E 5.3230-31 X Trt.: 3.141E-01 X TE: 1.2211-01 X ?KSl 4.248E-32 X X- CUts 3. 38 1E-02 X ClIt 3.36iE-C2 I CHIs 2.736E-02 1.'410E-02 x Cit. 3.847E-03 X 1.223E-32 X CiP. TAP: 3. 31-02 I X VAP' 3.367!-C2 X YAPa 2.735E-02 YAP. 1.'09tE-02 X YAP: 3.8171-03 I LIQ. 6.7bOE-02 X LIQ' 6.7322-02 X ,I=Q 5.1471-02 X LIn- 2.814-02 X LIQ= 7.6751-03 8. 017 IXXx YXXXXX .XXX 5.265 XX XTX'.:-KK O.2_51 JTX -1.341 XXXXX X X X X X X x ( 3, 6) S 4. ) x ( 2, 6) ( 5, ) X ( 6, 6) K .2.9 r X 50.151 r x 50.433 F X 49.'564 F K 49.9'0 ? X 0 X 1 -0. t X -1.128 CTNII8. 57.Etn10 X 4.8043J1-01 X 2. 207K-0 X · .',,I.JoX X IL;L/ XW ;XE-- Fig. 2 A A = 1 X -1.917 T2NU . 132F*C1 tE 1.23lE--1 CllIs 1.78h!.-02 VAP 1--t.7:r*':; tI.-'-. L 1 X TJI1 %. .K= CX lil -2.37.1 n%,.0n 4. 1. 41heE-O1 . 15% .-. 2 ( I VA"=· :. .- e ! ?. i .; 5.2.1.6 t -2. 183 I -1. 4 T;l= 3.tR1EfnO X TNI= 3.128v*13 K TK I?- 6f.r.6-O' J TKF= 3.1.11I2 X !. :( .l' t . t ' XX iA. X s!C ,711 F--ll X Cll= 1.h3-:-31 v .7' -e r. X Va hn'1 X If L -. .'"-~' !.1x&_'.X '~. 1 X/$!' XX -) .. :"' ;X(X Plume Cross Section at 200 sec. DY = 100 ft, DZ = 200 ft. Disregard moisture values. 147E-012. X 231 LIQX T' (IrK E- 2.R50%-,13 23. 1.9Q!6!:&00 15I 3 E-02X 2.1137 XX LI;)x TNEI-x 5.056Z-04 TXEx 2.371!+03 1 1.140'3-02 1.739 1 X -102- plume has risen 1003 feet. The warmest cell in the plume is barely 1°F warmer than the surroundings, and the updraft velocity has remained constant. The plume cross section has grown considerably, and the maximum TKE has dropped by a factor of two from its value at 80 seconds. The effect of adding an initial internal circulation to the plume cross section is developed in Figures 5.2.1.7 and 5.2.1.8. In Fig. 5.2.1.7, the initial circulation is shown. The mesh cells are not 50 ft by 50 ft, although the same size plume is initialized as in the earlier discussion. The uniform 3 ft/sec circulation pattern is simply a rough guess at the actual circulation. Simulations to 40 seconds with and without the circulation are found in Fig. 5.2.1.8. The presence of an initial circulation makes only a small difference between the runs, as seen in the selected velocity and temperature values. The initialization of all of the subse- quent simulations with no initial circulation is presumed to introduce little error into the results, i.e., the dynamics are strongly affected by the buoyancy, and not by the initial circulation. The effect of ambient atmospheric turbulence is developed in Figures 5.2.1.9 and 5.2.1.10. The initialization is the same as in Fig. 5.2.1.7 without the initial circulation, but with 50 ft square cells. In Figure 5.2.1.9, the ambient -103- symmetry line +4 + + + + + + + + + ++ + ++ + ++ ++ Plum ie: 4 -i + i I + ia_ + + 4. + + + + + + + + -- 4 + + Ambient Field: at rest 50 0F everywhere + + + + + 300 ft ft 300 + ++ + + + +T+ ++ + 200 ft on a side, total 18 0 F above ambient internal circulation as shown (all arrows are 3 ft/sec) + + I - + 50 ft x 50 ft cells 400 cells total + + + + I Fig. 5.2.1.7 Initialized Plume Cross Section with Internal Circulation. + -104- No initial circulation 3.67 ft/sec 3 ft/sec initial circulation 4.14 ft/sec 57. c ft/sec Fig. 5.2.1.8 4.81 ft/sec Plurme comparison at 40 sec of simulation showing the small effect of an initial circulation on the plume development. -105- computer mesh boundary 2/sec] I ! ! .- 6.0 armbient % 475 ft 1 Fig. 5.2.1.9 Plumne development in a moderately turbulent atmosphere. Mean flow field velocity vectors are shown. 15 15 15 15 15 15 15 -106- .-o1 L A _n -1 l "/secl I at 40 sec I 10 2 10-2 I f I / 1 le warmest cell is 475 f 1.94 F above *_~ ambient 0. jI r 15 Fig. 5.2.1.10 Plume developmlent in a very turbulent atmosphere. Mean flow field velocity vectors are shown. II I -107- eddy viscosity is maintained at a uniform 15 ft 2 /sec. The resultant plume cross section at 40 seconds has developed the usual circulation, and its warmest cell is found to be 6.05°F above ambient. In strong contrast to this is the plume cross section of Fig. 5.2.1.10 which has a much stronger ambient turbulence field below 850 ft, and a much weaker turbulence field above 850 ft. The fictitious eddy viscosity profile quoted in Fig. 5.2.1.10 reflects a very turbulent boundary layer whose depth is about 850 ft. The resultant plume cross section at 40 sec is markedly different. The strong atmospheric dispersion has resulted in a much more diffuse plume whose maximum cell temperature is about onethird that of the previous run, although the plume rise is quite similar. This agrees with the notion that plume rise is dominated by the thermal stratification of the atmosphere (which is neutral in both cases here), and to a much lesser extent by other factors. Plume dispersion, which is very different in the two cases here, is affected strongly by the turbulent state of the atmosphere (which in turn is strongly affected by the thermal stratification of the atmosphere, among other factors). The effects of using continuative outflow versus free-slip solid walls for the top and right boundaries was studied. The alternative assumptions produce little difference -108- between runs. The solid free-slip walls give more satisfac- tory results, although they are somewhat unrealistic physically, as are the continuative walls. Further refinement of the boundary conditions is expected to have little influence on the solutions. 5.2.2 Turbulent, Buoyant Line-Vortex Results The results of the plume simulations in the plume domi- nated regime (see Fig. 5.1.1) are discussed here. To obtain these results, the ambient turbulence level should be less than one-tenth of the plume turbulence, so that the ambient turbulence will have only a small effect on the results. Plume simulations are compared to the experimental results of Richards and Tsang. Tsang's results are generally more accurate since his experimental technique is more sophisticated, but Richards was first to set down the basic similarity arguments. Similarity and dimensional analyses by Richards and Tsang have revealed the formula for the plume top height, Z, versus the plume radius, R, and the formula for Z versus time, T. The concept of a virtual origin of Z and T simplifies the results in their analyses. (T,,Z) Briefly, the virtual origin is the limit where the plume radius vanishes, much as if the plume had emanated from a single point at time T. -109- This is shown in Fig. 5.2.2.1, where the two formulas are quoted. Two universal constants, N and C, are found in the formulas. Tsang found that N = 3.0 and C = 1.9 provided a very good fit to dense salt water line thermals released in a tank of still, fresh water. The flow inside the line ther- mals is turbulent. Tsang's results are simulated with the computer and presented in Fig. 5.2.2.2. Essentially, the virtual origin (T*, Z,) is free to be chosen to provide the best agreement between experimental and calculational results. center height (not top height) The plume is to be compared--the formula quoted in the figure is readily derived from the formulas in Fig. 5.2.2.1. The calculated values are represented by the points, and the experimental results (with an optimal T and Z) are represented by the solid line. Since ambient atmospheric turbulence is not important, the comparison serves to test the turbulence model by making sure that it can reproduce the self-similar plume development. The results are acceptably accurate through several hundred seconds of development. The calculated plume is found to rise a little too fast, so that a more "diffusive" turbulence model would be more accurate. a, The VARR turbulence constants, , and Fl, were varied in an effort to accomplish this. The dissipation constant, a, was decreased tenfold to allow -110- Z-Z.= NR , c[ Ao AP 9 "/2(T-T) (Z- Z~) 't)7,3 / 2 P1 circle of equivalent area R oundary Z (T-T*) Z *) )wn) Fig. 5.2.2.1 Geometry for plume analyses. -111 - o o m~~~ 4J 4t 9Q: 3x H a 4)i o 0E o o aw N t r-4 o 0 H u a E> 04 E-4 8 r, rz- or M 0- 0 o s o ~ ~ ~ oa~~ U20 * CO~ 'U U U O tnt o a HX 0) C4 P3 *H X 0~~ o o o o o o U (4 o o o ) Z o o U ' HDIH HaN3D alnqd o N -112- the turbulence to persist with less dissipation. lent transport constants, r and r,1 to enhance turbulent diffusion. The turbu- were increased tenfold Alone or in any combination these variations produced little more than a 20 ft decrease of plume rise at 200 sec. Thus, these line-thermal results are largely independent of the model constants. The only term not associated with these constants (see Eq. 3.43) is the production term. It is suggested here that the production term is probably too small because it neglects buoyant production in favor of mechanical production alone. This hypo- thesis was not tested further in this work, however. 5.2.3 Brunt-Vaisala Period of a Turbulent, Buoyant Parcel As a test of the hydrodynamic model, the Brunt-Vaisala period of a buoyant parcel in a stably stratified atmosphere is calculated. Briefly, the Brunt-Vaisala period is the per- iod of the oscillation of a parcel of fluid that is perturbed from its equilibrium level in a stably stratified fluid. A consideration of the restoring force on the parcel yields the formula6 9 Brunt-Vaisala period = 2[r if az sec] s (5.4) ( -113- For typical atmospheric values of T and d/dz, the period is hundreds of seconds. Computer simulation to hundreds of seconds is too costly, so the stratification, d/dz, is increased to 0.1 F/ft--about a twentyfold increase over typical atmospheric values--which decreases the predicted period to 81 sec and allows much more inexpensive simulations. The entire computer mesh, 103 ft by 103 ft, was initialized to this stable stratification, and a warm parcel was placed at an elevation of 300 ft. The results of two differ- ent runs are shown in Fig. 5.2.3.1. In a first run, the par- cel had a small buoyancy parameter: F U- gQh -4.6 = s CpTsU -=cTU x 10 3 3 2 ft3/sec which resulted in the lower curve. The curve exhibits a Brunt- Vaisala period of 92 seconds, and a fair amount of "jitteriness"--which is not surprising since the total parcel motion is much less than one cell spacing, so that the motion is not very well resolved on the mesh. In a second run, the parcel had a larger buoyancy parameter: = 4 .6 x 104 ft3/sec which resulted in the upper curve. The curve exhibits a Brunt-Vaisala period of 102 seconds, and a much smoother motion since several mesh cells have been traversed, and thus -114I I I I 440 __ ,,- parcel rising in a neutral I41g*O a txnosphere I I 420 I .****4 0 4 0a I. 0 I. 400 - e 0a S 00 .00· O 00 .... e.0 . 0 eOOO0** 0 380 I. t I 360 .0 0 I I 102 sec period I 44 E4 j I 340 - / H 92 sec period I 320 - .06 0*00.0@ .00 . 6.6 10 O. 4 OO*.OOO~t80 *........ O . . I',0. "@** 60-9*0 o6a .600 0I 5 _ 300 0 L,* 0 _ __ __ I L 50 I 100 200 TIME (seconds) Fig. 5.2.3.1 Demonstration of the 13runt-Vaisala period. Parameters for these runs are discussed in the text. -115- the motion is better resolved on the mesh in this run. Overall the agreement between calculated and observed values is good, considering that the classic Brunt-Vaisala problem allows no turbulent mixing, while the simulations in this work allow it. Generally, the action of turbulent mixing is to rapidly diffuse the temperature field and to slow the period of oscillation. For comparison to these results, the parcel motion in a neutral atmosphere for the stronger (F/U = 4.6 x 104 ft3 /sec 2 ) run has been included in Fig. 5.2.3.1. The stratification thus has a very strong effect on the motion. 5.3 5.3.1 Comparisons to Field Studies Pasquill Dispersion and Briggs Plume Rise in Neutral Atmospheres A comparison of plume simulation and experiments both in the plume and atmospheric dominated regimes (see Fig. 5.1.1) are discussed here for neutral atmospheres. To obtain these results, the ambient atmospheric turbulence is estimated from the discussion in Chapter Four. The plume simulations are started in the plume dominated regime and the simulations are run out to times where the plume excess temperature is very small, and the plumes are followed with the pollutant species concentration. The atmospheres in this section all have dry -116- adiabatic lapse rates of temperature. A comparison to Briggs' 70 plume rise for neutral atmospheres is made in Fig. 5.3.1.1. Briggs' work found that the plume rise and downwind distance, when nondimensionalized with a length L, L - F = gQh ft 4/ T 3 cpP U 3 ps 3 (5.5) s yields a 2/3 power law relation between the plotted values for a wealth of field data. To interpret the data from the sim- ulations, the plume rise is taken as the plume center height minus the virtual origin height (i.e., the rise from the virtual origin), and the downwind distance is then the product of the downwind velocity and the elapsed time from the virtual origin (see Fig. 5.2.2.1). For the run in Fig. 5.3.1.1, the distance, L, for a 100OMWt release in a 30 mph wind is 11.3 ft when calculated with Eq. 5.5. The agreement is generally good between calculation and experiment; the errors of estimation of Z, and T, and the undertainty in the ambient turbulence level all contribute to the discrepancy. Also, the data point at X/L = 78 is taken from the initialized plume cross section at time t = 0 which is not a physically accurate picture of the plume. The good agreement between calculation and experiment at this point is felt to be simply a cancellation of opposing errors. -117- 004 me 0S mo -40o 4 .a 4.) Z4 ,-4%4 ,-4 .4 X 44 XE- Ono 0o 0 ·04 o O0rC0 d4)c C I -4 U CoQ .Z4U N *O UZ m 0 O E o * ^ -118- A comparison to Pasquill's plume dispersion in neutral atmospheres (exactly the Pasquill D class) is made in Fig. 5.3.1.2. The Pasquill dispersion curves are taken from Turner's workbook 1, whose values are corrected from older The calculated plume dispersion sources of dispersion data. is taken from plume cross section printouts at four different times during the simulations. The calculated plume dispersion follows the Class D dispersion fairly well, but with a trend toward overpredicting the dispersion at points closer than the point 1/2 km downwind. This overprediction is again related to the finite plume size at time t = 0 in the initialization scheme. This error affects the earlier solution greatly, but has a decreasing effect on the solution at longer times. The error bars in the figure represent the error associated with increasing or decreasing the plume cross sectional area by one mesh cell. This gives a rough notion of the errors expected when the mesh cells are interpreted as Note being either entirely inside or outside of the plume. that these one-cell error bars decrease as the total number of cells in the plume increases with downwind distance. The trend to underpredict the dispersion at large distances reflects probable errors in the estimation of the ambient turbulence. Also note that since the turbulence is assumed to be isotropic, the calculated horizontal and vertical -119- 10 M W rn 4) 43 4) 0 I b 1 z H r4 C12 M H in E-1 z 0o N H 0: o 100 10 000 1000 DISTANCE DOWNWIND (meters) Turner's7 lHorizontal Dispersion versus Fig. 5.3.1.2 Distance Downwind Compared to a Computer Simulation of a 1000 MWt Release in a 30 mph Wind. -120- dispersion will not differ greatly; therefore, Pasquill dispersion cases that have significantly different a 's, and y ai's (e.g., extreme stability) will be difficult for this z model to duplicate. LAPPES SO 2 Dispersion Studies 5.3.2 A number of comparisons to a well-studied plume from the LAPPES field experiments are made in this section. The plume emanating from stack No. 1 of the Keystone coal-fired generating station at about 8 a.m. on October 20, 1967 is modeled with a computer simulation. Information about the ambient weather and plant operating characteristics are provided in the LAPPES study. Experimental helicopter SO2 plume cross sections and S02 bubbler data are available for comparison. The computer simulation is initialized in Fig. 5.3.2.1 The stack is releasing heat at in the following way: 6 28.6 x 10 cal/sec. Half of this is to be arbitrarily put into three mesh cells that are 164 ft (50 m) high and 492 ft (150 m) wide. The other half of the heat resides in the mirror image of these cells. Using a Briggs plume rise cor- relation for the rise induced by the initial momentum of the effluent (20 m/sec exit velocity) yields a rise of about 100 ft. The three cells are then to be centered at the 121.. XXXXA X XXXXXXXX O.0 s X ( ?,Et . 4q.C2 X F X ll) 44. 02 I x F x X x X I CO Z.t4l1-n2 2.7410,IC X 5.21E-C3 x X 3.C T 'NuIrF. CCPI, vtAPLIC- 0.0 iX 0.0 X X ( 2, 1) 49.212 F 4q.q0Z F ( 3, g9 49.202 F X tIU' xxxxxxxxx X X x X C. XiXKKK I N ! S I? X 4q.qO2 F 0.0 I X 2.?'41,f. X ?.74t*) X L.O I 4, 49.232 C. I TKU-l 2.74;:OCZ X1 2.74.1CC TkS.' J-C3 X C3l X VAP. C.C X LIC' XxxxxvW K C.C.0 F x ) f bJl')I 4'1.90) F 41. 2,2 x F x X I X I C.C I Tlt. ?.7'It- C. x +1(CI T11#F.;.41! 5Z9 I't-C1 I C x VAP. C.C . X L IC i. 0.0 xxII)]xxw C.C C.G X q) X ))p) oC X x I 0.0 TNU* 2.7.1r')2 X TUe TKE- 2.?4t..,, X .T CX !.21it-X CaiI. CHI 5.2q 3-J1 X VPS VP C.C X LIQ" 0.Z C.C KIxxxxxxx X X X 4) x X X 0 x X XXXXIXXXI x ..J XXIXXXXXXK X C.C ( e, 3) 4,.202 F X D))A x ) I C.C C.C I C.C t 1 ;1.0 1 0.0 3.134E*32 X ThU- 3.134EeI X ThUs 3.1 34F+? T ThU. 3.134+CZ x TNLa 3.. 14ECZ I X TK X TEI 3.114*CC X TXE- 3.-04S20 X TIE- 3 .1 3 4 +00 x TKE- 3. 34C+CC x TKEa 3.114ECC X CHti 5. 2q3'-03 :H1 - 5.Z93E-C3 x tC:1 5.29JE-C3 x Ix Cili 5.293-33 X CHI- S.2qE-3 3 1 X VAP' C.,; X VAon C.C X VAPv C.0 X VIPu 0.0 X VAPO C.C X LI Cr O . X LtCs C0.0 X LIC 5. X L QO 0.0 X LO- C.C 0.0 . xxx C.O xXXXXXXXX C.C xxxxxxxxx xxxxxxxxx XXXXx 0.0 XXXXXXXXX C.C K X X ]1 X X . X X t 6, e! I s R) X 3, 8) X I 4, 681 X I 2, ) F K X 4e.55s X X 4F.599 F X 48 .5s9 r .59q r F X 49. .09 X X 0." 1 I C.C I C.C 0.a0 t. O X TNU* L.0CCE+02 X TNU 1.61654CC Tl!. 1.616E *+CC X TNtJ 1.eL6E.CC X TNI. I.ttECc A X TIKE .CCCE+02 X TKEa 1.6CC-2 X TKEa 1.60C -02 X TKE= t.6OE-C X TKE- I.;CC-C2 X C!1-- !. 213:-C X CtI- 2.3OCE--1 X CHI 5.293E-33 X CH-I 5. 293C:-J3 x CHlI 5..23C-C3 X VAP, F.AC X VAP. X YAP' C.0 X VPC O.C X VAPw C.C x_ L IQ" C.O X LIG' C.C X LIC= 0.0 KX X LICl C.C XX LICX 0.0 X XXXXXIIXX C.C0 xlXxXXxx C., C.C )xxxxxxX xxx ,xxxx 0.0 XXXXX X . _ X X X X I e, 7) I 5,) X I 4, 7) 3 7) ' X 2, T! X J F 47. f0 F 47.631 X X 47.601 F 47.601 F 48.1C0 _F.... X X. X X X X X X t.C I C.C t 1 0.2 I . 0.0 1 0.0 r1TU 2.45CE+C x TahU 2.45CE+0C X ThU- 2.45CE+CC x TNIt; 2.4CE*CC I TkU. I.CCCE+02 ._ TIE 1.CCCE+02 X TKEs 2.5C0-2 X TKC Z.5CC_-32 X TKE- Z.SCCE-C2 x TKcE- 2.5CC-C2 X PI= 5.293E-03 X CHI- 5.293E-C3 X CI. !I. 5.293C-C3 X 5.293E-33 X K Clia 2.3CCE-01 X CHI X VA X VAP- G.C X VAP- C.C X VAP- C.0 X VYAP 0.0 K x LI C. 0.0 X L .C X LICQ I.0 X LIQ= C.C X L IC 0.0 i C.0 -KK) C.0 xxxxxxxxx Jxx)>): a. XXXXXXXXX C.C 0.Q_ XXxxxXiXX ,xxX__. ZIX. X X X X X X ) X { 6, 1 5, 6) X 1 4 6 X ( 3 6 x I. 2, 6) X. X 41.596 f - X 41.598 F X 41.598 F X X 41.599 F F 42.098 X X · X ,x X 1 C.C C.0 I 0.0 1 C.0 1 0. 0 t 0 X. TNUsl 1 CCCE+02 x TU. l.elcE-al x TNUw- .8ICE-01 X tNU- I.etOE-01 x TU- I.eICE-CI x X TiEs 1.CCtE+32 X TKE- 2.CCCE-93 X TKE- 2.C3CC-03 x TKEC 2.CCCE-C3 x TKEs 2.CCCE-C3 x X Cti 2.3CCE-01. x CHI, 5.293C-33 X CMll, 5.293E-03 X CHIs 5.243E-C3 x Clif 5.Z93E-C. x X VYAP C .0 X VAP- C.C X VAPS .q0 C.C X APIQ0.0 X VyAP .... x LIG_'03- ..X- L1Q--=O.C X LtsC-0. _. X L lx O. . X .tIQo GOC ' X) 0. 5 CC -_-lr')xxxxxx .- xx.xxlK.)xx. CC .XK CC Kxlxx wwXltX 0,0'" XYXt 9XXxI-x. 1 _ X X X X X X I 6, 51 X X ( 5. 5) ( 4, S5 X ( 3. 5) x X I 2 5) KX 4C.496 F X F 4.496 F 40.4 40.46 4C.496 F X__ 4096__F _. x X X X X X X C.C IC.C I 0.0 I 0.0 1 x 2.C5!EsCC TINtL 2.C684CC TIUI X 2.Q06E+G0 x Thlj. X ThUi Z.0668+00 x TKNIs 2.C68E+130 tKE- 2. ICC--92 X TKE- 2. 10CE-n2 X TKE= 2.1 CC-C2 X TIKE, 2.1CCE-C2 x X TE 2.1CCE-02 5.293E-C3 X CIi- 5.29T.-C] x CHl= 5.293E-.3 X CPI 5.293E8-03 X Cll5.293E-03 X C X X VAP" C.C X VAP- C.C X VAP" 0.0 VAP% C.0 X L AP O.0 X LiC 0.0 X I TQ10C.O LItC C.O L1TQ C.C .0O ))ix xxxxxxxxI xx>)xxxxx 0.0o xxxxxxXxX C.C XXXI Ixx AXX C.C O.0 xxxxx X x X X x K W ( (, 4) X 1 4, 4) I 5, 4) x X 3, 4) ,,X I 2, 41 x X X 39.595 F X 3.535S F 39..,95 3. 595 F X F X 39.595 F x X X X X _ _ XI_ _ I C.C 1 0.0 t C.C 0 I C.C TNI , 6. 71C: CC x TINL e.7LCC+CC X X rhU= ..11CE0+0 X TNU- 6.7t1C+OC X ThU TKPr E.7;.c-C2 x X IKE. 6.7C::-32 X TKE. 6.7CQ]-12 X TICE .7Cr-OJZ X TKE: 5.293C-C3 x C I !.21IE-C3 X CHI X CPli. 5.293E-03 X CHlI 5.293:--0 X CH I 5. 203C-03 X X Ldi C.0 X VIP- 0.0 X VIPw O.O X VIPO C.A X VAP. C.C 0.0 X x LIC C.C I LIC X L.I0u C, X L C- O.0 C.: xxxxxxxx. CC -" 0o. XXXI(XXXX C.C 0.0 XXXX: xxx-X XXXXX Fig. 5.3.2.1 Initialized Plume Cross Section for the Keystone No. 1 Stack on 20 October 1967. DY = 150 m, DZ = 50 m. -122- stack height (800 ft) plus the momentum rise height (100 ft), or 900 ft. If the cells are all 164 ft high, then the center of cell (2,7) is at 902 ft--thus cells (2,6), (2,7), and (2,8), are to be initialized with half of the heat release. Checking the prevailing winds for cells (2,6), 2,7), and (2,8) finds that they sweep out 7.3 million cubic feet in one second. Releasing 14.3 x 106 cal into 7.3 x 106 ft3 gives a temperature rise of 0.47°F, and this is added to the ambient air temperature in these cells in Fig. 5.3.2.1, which shows the computer initialization in the vicinity of the plume cells. This whole initialization process is admittedly crude, particularly in the treatment of momentum, but it gives very satisfactory answers. The experimental results for this plume are found in Figs. 5.3.2.2 and 5.3.2.3. The former figure shows the pre- vailing wind speed, direction and potential temperature. The weather was clear on that morning, and a sizeable low-level inversion had formed during the night to about 250 m depth. The flow above 250 m was essentially neutrally stratified and flowed from the west. The turning of the wind with height is ignored in the computer simulation, but the wind speed and potential temperature values are input directly onto the computer mesh. The ambient humidity was fairly low due to a wide subsidence inversion over most of the computer mesh, -123- i i I i I t 0 to r-4 4 3 0 C) W 0 *0 U] w a 4J) o z N H a) El >1 0 q4 4W 44 0 o 0 W LA ; LA M a) 4J U 00 00 00 0* P4 0 C N Ln W E-4 H 0 o a E-4 z Ln 0 44 E-e O P4 0 a) · · *00 z0 :r ° .. 0 .000 CD H E-4 Ca N ao N U N Q LA H In zH @*- I __ _ o H( _ I 0 0 0 O O O O N 0 O CO 0 %O 0 w C CN -4 0 -4 ( sa 4u9) l4T4iTDH o t; .rq rz4 -124- .,4 Q 0. 14 0U) 0 .,l e4 U S. o3 0to 3 w uE.4 4.-4= :3 :3 zH i-i 3: 0 4) U Un So i-4 0 ,-I 40 02 Fo 0 C) 0a) o-i 0 44 rn u3 I 0 0 0 0 Hl ,lHi oli .,-I -125- so humidity is neglected in this simulation. Turbulence values are calculated for a neutral atmosphere from Blackadar, S9 and the turbulence in the inversion layer is supp- ressed by a factor of 100 in the absence of any better information about the turbulence in the stably stratified region. The eddy viscosity is of the order of 100 ft2/sec in the neutral region, and about 1 ft2/sec in the stable region. The helicopter plume cross section at 4.8 km downwind is drawn in Fig. 5.3.2.3 as the jagged outline. The outline con- nects the measured SO2 horizontal traverses, and represents essentially a 1 percent boundary of SO 2. A mass balance of SO 2 in the plume cross section finds only 55 percent of the SO 2 that was emitted at the stack. It is suggested that much of the remaining 45 percent of the SO 2 could be found below 200 m, since the helicopters flew no lower than this safety) yet were still finding SO 2 at this level. (for The comp- uter simulation at 600 sec is superposed on the experimental plume outline. Again, the computer trace represents about a 1 percent boundary of SO 2. of SO 2, Except for the two large "wings" the agreement is fairly good. The "wings" are likely produced by low frequency horizontal turbulent eddies generated in the region of the turning of the wind--but since the turbulence on the computer is assumed to be isotropic, this can- not be corrected in these runs in any simple way. -126- To put the computer and experimental results into perspective, a handbook calculation of the plume S taken here. 2 is under- The trouble with the anlaysis of the plume of October 20 is to decide whether the stable or neutral conditions have the greatest effect on the behavior, since only one stratification can be used in handbook estimates. The plume rise and dispersion in an F class (stable inversion) is presented in Fig. 5.3.2.4. Note that the plume rise fits the data well, but the dispersion is too small sion is the 3a, or 1 percent level value). and dispersion in a D class Fig. 5.3.2.5. (the disper- The plume rise (neutral layer) is presented in Note that the plume rise is too large, while the dispersion is fairly close to the actual, but is also not able to reproduce the "wings" of S 2. It is seen that either single choice of stability does not agree as well as the computer simulation (which was able to follow the plume through both regions of stability). This generality in the computer simulations appears to be a major source of improvement over the handbook estimates. The comparison of experimental and computational plume cross sections is continued in Fig. 5.3.2.6 for the plume at 10.0 km. The helicopter results have the jagged outline in Fig. 5.3.2.6. A mass balance of SO 2 yields only 29 percent of the emitted S2, which brings the experimental -12 7- 4J ,-4 0 0 0) w 'U ,-4 U) 0 rz (D 0 4J 0> U EA rO 0 zH U *14 .1-I 'U U r-4 0 U rn O~ 44 0 0 0 9U (d 19 C4 ., .- 0 0 0 Ho ITID I *r -i. -128- 4. ri H U) r4 :3 m (D 0 a ,-4 U, w .4J r4 U4 -H .4 ra 9 'U w U U u EN4 cn H 0 -,-4 4J ,(U ,-4 u lz 9 H Z 0 0 (n to 0 :1 U H 'U .r4 04 (d 44 U to r.( 0 (d 10 0 .r $4 It 'U z: 9 0. ¢ ¢ ¢0 N L4 .94 PI Pk r4 U) -129- >1 .01.4 'b 4) J ,l Lo 0a w :U q -H 43 ,4 44 (a r-I 410 'a E2 0 m 43 04 r q E 9u D 0 ., 0 OC cn U) 0 0c tn h o.4 r4 t)u 4 I o 0 0 H-4 0 0~ *0 -130- results into question. The computer simulation is super- posed, but not much emphasis should be placed on the comparison since the helicopter results appear to be inaccurate on the basis of the low mass balance. Two other tests of the model with the October 20 plume are found in Figs. 5.3.2.7 and 5.3.2.8. Four S02 bubblers were placed on a small hill at 65 m elevation above the stack base, at 6.5 km downwind. The bubbler 1/2 hour averages were all averaged together to yield a 12 pphm ground-level SO2 concentration. The central region of the simulated plume cross section is copied in Fig. 5.3.2.7. Each S02 concentration represents the value in a single computer mesh cell. The dashed line is drawn through the plume at the 65 m elevation, where the 12 pphm experimental value compares very well with the predicted values inside the plume The entire simulation was carried to 12 km downwind. The maximum ground level SO 2 concentration is plotted at 2 km intervals in Fig. 5.3.2.8. yet reached a maximum. Even at 12 km the S02 has not However, the maximum S02 in the plume (calculated at 12 km) is 33 pphm, while the ground level is already 17 pphm--so the maximum calculated value will have to be between 17 and 33 pphm. A handbook estimate of the maxi- mum ground level concentration (taken from Eq. 3.146 of Slade) 2 yields 47 pphm at 17 km downwind in neutral D class -131- -F c plume centerline II I I I 75 48 84 48 16 88 45 14 60 36 13 22 22 9 m 65 m 11 m 8 m 15 m _m 9 _ _ _ 9 _ 7 _ _ 7 m m 7 7 --- EARTH Fig. 5.3.2.7 Comparison of the computer simulation of the 20 Oct 67 Keystone #1 plume cross section with the half-hour average SO2 concentration at 65 m. The values in the boxes are the mesh cell [SO 2 ] in pphm predicted by the code at 6.5 km downwind. An average [SO 2] of 12 pphm was recorded in four SO2 bubblers at 65 m elevation and 6.5 km downwind. The dashed line at 65 m represents the bubbler elevation on the computer mesh. -132- 4.I .J u O 4 0 gu 1, H 0 .4k 0 4 O W 4J r4 U U 'UN~~U C 40 0 0 O e4 0 0 O 5 0X H 0 q £ 0 .rq Ez 0 Q (% 4.u . Ua 0 E) 10 E f.... 'U :r 0d *e *e 0 ,_ h u 044- c to UZ ~ -133- stability (which is roughly an upper bound for this value) and 22 pphm at 90 km downwind in stable E-class stability (which is roughly a lower bound for this value). The calculated value must therefore fall somewhere between these handbook estimates which lends credence to the results, even though the actual maximum ground level S0 2 value was not calculated. 5.4 5.4.1 Results of Model Extension Fumigation Episode A computer simulation that approximates a fumigation episode is presented in this section. No particular episode is intended to be represented by this run, but several of the general features of a fumigation episode near a shoreline site in the Great Lakes area are included. 73 These episodes are commonly characterized by a wind off of a large cool lake on a sunny spring day. The air that has traveled over the lake has developed a deep stable layer because of sensible heat exchange with the cool lake water. As this deep stable layer streams inland, the strong solar heating at the gound causes a deepening unstable thermal boundary layer to develop. This layer is characterized by strong mixing as vigorous turbulent thermal convection sets in. Plumes re- leased in the stable air exhibit small plume rise and dispersion until they encounter the growing boundary layer -134- from below. Quite rapidly they have their pollutants spread to the ground, in a sense "fumigating" a relatively small area with high pollutant concentration. A rough calculation was performed to demonstrate this. The plume in a stable inversion from Sec. 5.3.2 was released over a deepening turbulent layer coming up from the ground. The situation is shown in Fig. 5.4.1.1. At 0, 20, 50, 100, and 200 seconds the turbulent layer (eddy viscosity = 1000 ft2/sec) is deepened by an increment of 100 meters--this is represented by the staircase in Fig. 5.4.1. The plume that is released at 0 km is about half engulfed in the turbulent layer at 1 km, and almost entirely engulfed at 2 km. The strong turbulent mixing has produced ground level concentrations a factor of 4 and 8 times higher at these stations than the results of Sec. 5.3.2. This agrees qualita- tively with actual fumigation episode results, and serves to demonstrate the ability of the model to extend into these important cases. A more refined calculation of the boundary layer, and actual weather and plume data from a shoreline site would be needed to more carefully test this type of simulation. 5.4.2 Plumes with Change of Phase Model validation has not been carried out for plumes -135- 0 4.J x o I II ! I 0 a .O k .,4 .,4 4J U) ,U 0 0 4- . I I 0 O ,n CU . ) UO) La oO r, .q o0 .,4 aC3 Ln w U -136- with change of phase. The available Chalk Point data were incomplete during this work and could not be used. The bal- loon data from several mechanical draft towers at the Commanche plant74 suffers from a lot of scatter from a variety of sources, and data were only obtained very close to the towers, which casts doubt on the ability of the simulations to handle this case. From preliminary work with saturated parcels of air on the computer mesh, the model is found to suffer from oscillations that are due to the explicit nature of the moisture equilibrium calculation. The oscillations can be brought under control by reducing the timestep size, but a more fundamental solution to this problem is recommended in Sec. 6.2.3. -137- 6. CONCLUSIONS AND RECOMMENDATIONS 6.1 Model Validation A widely applicable calculational model of buoyant bent over plumes has been developed. The advantage of the model is its ability to treat problems outside the scope of existing plume models without greatly increasing the resources required for the analyses. The acceptance of the model, however, must begin with a demonstration of its ability to reproduce the solutions to problems that are known to be solvable. This demonstration has proceeded along two lines in this work--problems in which the plume properties dominate the flow, and problems in which the atmospheric turbulent mixing dominates the flow. Some overlap between these simple regimes occurs, but overall this organization serves to highlight the causes of the particular successes and discrepancies in the model validation work. The results of Sec. 5.2 deal mainly with the plume dominated motions. Generally it is found that very good agree- ment with laboratory experiments is obtained. In particular, the buoyant line-vortex motions and the Brunt-Vaisala period of a buoyant cylinder of fluid are studied, and they compare very favorably with the predictions. However, the -138- unsuccessful attempts to "tune" the turbulence model coefficients point out the rather limiting assumptions contained in the present turbulence model, particularly with regard to buoyant production of TKE. been noted 75 To the model's credit, it has that wall-free turbulent flows are the most difficult to "tune," and that the model does a credible job in its current form. The results of Sec. 5.3 deal mainly with the atmospheric dominated motions. There is a large amount of overlap into the plume-dominated motions in the Briggs plume rise and Pasquill dispersion results, but these cases both represent experiments that were actually performed in the atmosphere, and they exhibit a fair amount of scatter in their data because of this. Again, the agreement between calculation and experiment is good. The results of the LAPPES individual plume study provides the best indication of where the calculational model is expected to benefit the modelers of plumes. In the limited number of calculations contained in that section, it is found that the calculational model agrees with the experimental results more closely than the current handbook estimates simply because it has made a more fundamental calculation, taking into account the actual micrometeorological profiles. Furthermore, the model provides a relatively accurate starting point for the detailed description of other -139- important processes in a plume: chemical reactions, visi- bility, radiation dose rates, etc. 6.2 6.2.1 Recommendations Calculational Scheme to Include Wind Shear Effects A brief overview of a plausible calculational scheme that would address one of the important effects of wind shear on the plume dynamics is discussed here. The effect is that of the dilution of the plume properties as the plume rises into progressively stronger winds. The process is sketched in Fig. 6.2.1.1, and is well-known to plume modelers. A constant release of pollutant (illustrated in Fig. 6.2.1.1), momentum, sensible heat, moisture, etc., diluted into air that moves with a velocity u(Z o ) will have a density proportional to the inverse of the velocity. A plume property that is released into a stronger wind, u(Z), will be correspondingly more dilute. This effect is important in buoyant plumes when the plume updrafts and downdrafts in the presence of a wind shear cause parcels of the plume to change their downwind advection rate. Clearly, the problem is fully three-dimensional (though it can be in steady state), but a very restrictive assumption may afford a useful recasting of the two-dimensional problem. next. This assumption is discussed -140- -L R bm/sec - X(z) - R/u(z) 1 ft2/ u (z) I r - R lbm/sec -- mm 1 ft 2 u (z o) z z X(z) > X(Z) for EARTH Fig. 6.2.1.1 Dilution of a Steady Re leas e of Pollutant. -141- Consider the advection and turbulent diffusion of a pollutant in three dimensions (the results extend directly to momentum, sensible heat, etc.): ax + u ax + v at ay + aXz = Y CPX 7 (6.1) X Assuming that the system is in steady state, we have u a ax + v ay + w a Z = Xa x (6.2) In the presence of a steady uniform wind field, u, the first term is commonly interpreted as the time-rate-of-change for an observer moving with the wind, and is written as t ' 0 where uot o = x. This contains the important assumption that the plume always has the downwind velocity u--implying infinite accelerations at the stack exit, to be sure. In a strong wind field the downwind diffusion is commonly neglected with respect to the downwind advection, so the gradient operator has only y and z derivatives. If the wind field is allowed to have shears, then the first term may be represented as u(z) where u ax-_X u(z) u(z ) (uU(z) o ax u(z0 ) x at 0 has been arbitrarily chosen to be u(zo . (6.3) This interpretation allows the equation to be formulated as -142- a- + u (z u(z o ) ay + u (.Zol (z 2 x ) (6.4) This equation holds the assumption that any parcel of air in the plume, when advected into a region of stronger wind, immediately takes on the local wind velocity and is corresNote that it also causes parcels that pondingly diluted. are decelerated to concentrate their properties, which is physically unrealistic, but hopefully is not too serious an error since plume rise and updrafts are almost always stronger than downdrafts. The important feature that this scheme hopes to address is the dilution Cusually by about 10 to 50 percent) of plume buoyancy, momentum, and moisture, which affect the plume dynamics. The procedure could be extended to every transport equation in the equation set--only the effect on the divergence condition in the fluid mechanics algorithm has not been studied. Its satisfaction would still be re- quired as a constraint on the solution. 6.2.2 Calculational Scheme for Time-Dependent Release or Weather The simulation of "mildly" made with the model. time-dependent plumes can be Essentially, the governing assumption here is that the prevailing weather or effluent properties -143- will advect downwind, and never affect the flow that precedes or follows it. The situation is developed in Fig. 6.2.2.1, where a stack is assumed to have a set of exit properties, , that are piecewise-constant in time over periods of 100 sec. To reconstruct the behavior, an initial simulation with the properties at time to, (to) is made to 300 sec. properties changed at time t The plume to 100 sec, so a second simula- tion is made with properties QCto + 100) to 200 sec. the plume properties changed at time t Again + 200 sec, so a third simulation is made with properties Q(to + 200) to 100 sec. The actual plume is then "cut and pasted" from the pertinent data in the simulations as shown at the bottom of the figure. The calculation is somewhat wasteful, since 600 sec of simulation produces only 300 sec of results--but the scheme surely saves time and storage over a fully three-dimensional calculation. Eventually, for sufficiently "strong" time-dependence the scheme becomes too laborious with respect to a threedimensional calculation. 6.2.3 Cloud Microphysics Model The limited success of the equilibrium moisture thermo- dynamics model is due to its explicit differencing. In short, the model is ignorant of the latent heat released in a current timestep, and it adjusts the equilibrium conditions without -144- I simulation with plume properties at time t I I simulation with plume properties at time t+100 I I __ I I I II simulation with plunae properties at time to+ 2 0 0 I 8I mill - III II a I 100 200 Time Fig. 6.2.2.1 I I I 00 I I _ 300 (sec) Simulation of a Time-Dependent Plume in Steady-State Weather. Scheme is discussed in the text. -145- this knowledge. The resultant oscillations in the equilib- rium conditions are not surprising, nor is the ability to control them with very small timesteps. If the calculation was made implicit--essentially iterating on the coupled latent heat release equation and Magnus' formula for liquid-vapor equilibrium--the timesteps could be relaxed back to their original size. The prospect of incorporating a non-equilibrium moisture model is not investigated in this work. The limitations of the equilibrium model have not been sufficiently explored to justify the change at this point. -146- NOMENCLATURE A 0 2 initial line-vortex area (ft ) C experimental constant, 1.9 Cp heat capacity at constant pressure (BTU/lbm °R) c m oist P heat capacity of moist air at constant pressure (BTU/lb °R) m DT timestep size (sec) DY cell width (ft) DZ cell height (ft) esat (T) saturation vapor pressure of water (mb) E(i) X energy of the i t h decay channel from pollutant species X (MeV) F (i) X fractional energy deposition for i t h radioactive decay channel from pollutant species X) g acceleration due to gravity (ft/sec 2 ) gi vector acceleration due to gravity (ft/sec2) I specific internal energy (BTU/lbm) k thermal conductivity (BTU/ft-sec-°R) L buoyancy parameter (ft) Leddy eddy length scale (ft) Lva p latent heat of vaporization of water (BTU/lbm ) N experimental constant, 3.0 p physically measurable pressure (millibars) P pressure perturbation about an adiabatic reference state (mb) pO pressure in a quiet adiabatic atmosphere (mb) -147time average pressure perturbation p (mb) P p fluctuating pressure perturbation (mb) Pr Prandtl number q,q(y,z,t) turbulence kinetic energy per unit lb qlibrary (Z) prescribed turbulence kinetic energy profile (ft2 /sec 2 ) Q heat (BTU) QH heat emitted at stack exit (BTU/sec) R(T) plume radius as a function of time (ft) Rdry Rd Rvap Rv gas constant for dry air (ft3 mb/lbm°R) gas constant for water vapor (ft3mb/lb °R) Sliq Schmidt number for liquid water Sc Schmidt number for water vapor vap t,T time (seconds) t x/u O o ) 2 (ft2/sec (sec) T* time coordinate of virtual origin (sec) T physically measurable temperature (R) T temperature perturbation about an adiabatic reference state (R) T temperature in a quiet adiabatic atmosphere T temperature of stack effluent (R) s virtual temperature Tv T virtual temperature in a quiet adiabatic atmosphere (OR) vo u U (R) downwind velocity (ft/sec) windspeed, constant with height (ft/sec) U Ueddy turbulent velocity scale in an eddy (ft/sec) ui,u j velocity (ft/sec) Ui,u j velocity (ft/sec) (R) -148ui.Uj time average velocity (ft/sec) ui',uj' fluctuating velocity (ft/sec) Reynolds stress tensor (ft2/sec2 ) correlation of fluctuating velocity and temperature Ui ,' 'uk, triple correlation of fluctuating velocity (ft3/sec3 ) v crosswind velocity (ft/sec) Vg geostrophic wind (ft/sec) w vertical velocity (ft/sec) W ol molecular weight of the pollutant species (lbm/lbm-mole) X downwind distance (ft) X i jX j cartesian coordinate (ft) y crosswind distance (ft) z height (ft) *, height coordinate of virtual origin (ft) -149- a, a1 turbulence constants YL reciprocal turbulent Schmidt number for liquid water YT reciprocal turbulent Prandtl number for heat YV reciprocal turbulent Schmidt number for water vapor YX reciprocal turbulent Schmidt number for pollutant r turbulence constant r1 turbulence constant rd dry adiabatic lapse rate (R/ft) Eh eddy diffusivity of heat Em eddy diffusivity of momentum (ft2 /sec) (ft2/sec) eddy diffusivity of pollutant e potential temperature (ft2/sec) (R) potential temperature perturbation about an adiabatic reference state (R) 8e potential temperature in a quiet adiabatic atmosphere (R) time average potential temperature (R) (R) 8' fluctuating potential temperature 8v virtual potential temperature 8vo virtual potential temperature in a quiet adiabatic atmosphere (R) 8v time average virtual potential temperature ev fluctuating virtual potential temperature (i) X x decay constant for i t h radioactive decay channel from pollutant species X (sec -1 ) (R) (OR) (R) -150- 1j dynamic viscosity (lbm/sec. ft) V kinematic viscosity (ft2/sec) Pdry Pliq density of dry air (lbm/ft 3) liquid water density (lbm/ft 3) Pliq time average liquid water density (bm/ft P liq fluctuating PS density of stack effluent (lbm/ft3) Psat saturation water vapor density (lbm/ft 3) Pvap Pvap yap a, a (y,z,t) library(z) X 3) liquid water density (lbm/ft3) water vapor density (lbm/ft3) time average water vapor density (lbm/ft 3) fluctuating water vapor density (lbm/ft 3) eddy viscosity (same as m) (ft2/sec) prescribed eddy viscosity profile pollutant density (lbm/ft 3) (ft2 /sec) -151LIST OF FIGURES AND TABLES page Figure 3.1 Flow Field Orientation 35 Figure 3.2.2.3.1 Phase Diagram for Water Substance 51 Figure 3.2.2.3.2 Logic Diagram for the Equilibrium Moisture Calculation in a Single Cell during a Single Timestep 52 Figure 3.3.2.la Bent-Over Buoyant Plume with Ambient Thermal Stratification 56 Figure 3.3.2.lb Mesh Alignment Appropriate for a Line Source Release 57 Figure 3.3.2.1c Mesh Alignment Appropriate for a Point Source Release 57 Figure 33.3.3.1 Reconstruction of the Three-dimensional Plume. Wind vectors as a function of height are shown. 59 Table 3.3.4.1 Property Values of Air 62 Table 3.3.5.1 Required Input Profiles 65 Figure 3.3.5.1 Wall Numbering Scheme 66 Table 3.3.5.2 Boundary Conditions 68 Figure 3.3.6.1 Mesh Coarsening Procedure Steps 70 Table 3.3.7.1 Data Reported by the Plume Statistics Package 73 Figure 4.3.2.1 The Concept of Layers in the 80 Table 4.3.3.1 Planetary Boundary Layer. Comparison of Eddy Viscosity Prescriptions 85 Figure 5..11 Figure 5.2.1.1 Plume Regimes Key to Cellwise Quantities for Figs. 5.2.1.2, 5.2.1.3, 5.2.1.4, 5.2.1.6, 91 95 and 5.3.2.1. Figure 5.2.1.2 Initialized Plume Cross Section at 0 sec. 96 Figure 5.2.1.3 Plume Cross Section at 20 Sec. 98 -152page 99 Figure 5.2.1.4 Plume Cross Section at 80 sec. Figure 5.2.1.5 Turbulence Kinetic Energy Profile at 80 sec. 100 Figure 5.2.1.6 Plume Cross Section at 200 sec. 101 Figure 5.2.1.7 Initialized Plume Cross Section with Internal Circulation 103 Figure 5.2.1.8 Plume Comparison at 40 sec of simulation showing the small effect of an initial circulation on the plume development. 104 Figure 5.2.1.9 Plume development in a moderately turbulent atmosphere 105 Figure 5.2.1.10 Plume development in a very turbulent atmosphere 106 Figure 5.2.2.1 Geometry for plume analyses 110 Figure 5.2.2.2 Comparison of Computational and Experimental Results for Plume Rise versus Elapsed Time for Buoyant Line-Thermals 111 Figure 5.2.3.1 Demonstration of the BruntVaisala period 114 Figure 5.3.1.1 Briggs' 70 Comparison of Plume Rise in Neutral Atmospheres Compared with a Computer Simulation of a 1000 MWt Release in a 30 mph Wind. 117 Figure 5.3.1.2 Turner's 7 1 Horizontal Dispersion versus Distance Downwind Compared to a Computer Simulation of a 1000 MWt Release in a 30 mph Wind. 119 Figure 5.3.2.1 Initialized Plume Cross Section for the Keystone No. 1 Stack on 20 October 1967. 121 Figure 5.3.2.2 Weather for 20 October 1967 at the Keystone Plant 123 -153page * _ 1_1_1 Figure 5.3.2.3 Comparison of Computational and Helicopter Results at 4.8 km Downwind 124 Figure 5.3.2.4 Comparison of Handbook Calculations and Helicopter Results at 4.8 km Downwind 127 Figure 5.3.2.5 Comparison of Handbook Calculations and Helicopter Results at 4.8 km Downwind. 128 Figure 5.3.2.6 Comparison of computational and experimental results at 10.0 km downwind for the 20 October '67 Keystone #1 plume. 129 Figure 5.3.2.7 Comparison of the computer simulation of the 20 Oct 67 Keystone #1 plume cross section with the half-hour average SO 2 concentration at 65 m. 131 Figure 5.3.2.8 Maximum ground-level SO concentrations predicted in te computer simulation of the 20 Oct 67 Keystone #1 plume 132 Figure 5.4.1.1 Fumigation Episode at a Shoreline Site 135 Figure 6.2.1.1 Dilution of a Steady Release of Pollutant 140 Figure 6.2.2.1 Simulation of a Time-Dependent Plume in Steady-State Weather 144 ____)__1 _I_ II_ _ __ -154- REFERENCES 1. R. Scorer, Natural Aerodynamics, New York, Pergamon Press, 1958, p. 194. 2. J. Stuhmiller, "Development and Validation of a TwoVariable Turbulence Model," SAI-74-509-LJ, 1974. 3. F. Pasquill, Atmospheric Diffusion, Second Ed., England, Ellis Horwood Ltd., 1974. 4. J. Richards, "Experiments on the Motions of Isolated Cylindrical Thermals Through Unstratified Surroundings," Int. Jour. Air Water Poll., 7, pp 17-34, 1963. 5. F. Schiermeier, Large Power Plant Effluent Study, Vol. 1-4, Research Triangle Park, NC,EPA, Office of Air Programs, 1971. 6. R. Sklarew, and J. Wilson, "Air Quality Models Required Data Characterization," Palo Alto, CA, EPRI EC-137, May, 1976. 7. F. Hoffman, et. al., "Computer Codes for the Assessment of Radionuclides Released to the Environment," Nuclear Safety, Vol. 18, No. 3, pp 343-354, MayJune, 1977. 8. M. Winton, "Computer Codes for Analyzing Nuclear Accidents," Nuclear Safety, Vol. 15, No. 5, pp 535552, Sept.-Oct., 1973. 9. K. Rao, "Numerical Simulation of Turbulent Flows-A Review," ARATDL internal note, April, 1976. 10. C. Nappo, "The Detailed Numerical Simulation of Vorticity Concentration Downwind of Large Heat Sources," (unpublished notes). 11. C. DuP. Donaldson, "Construction of a Dynamic Model of the Production of Atmospheric Turbulence and the Dispersal of Atmospheric Pollutants," in D. Haugen, ed., Workshop on Micrometeoroloq, Ephrata, PA, Science Press, AMS, 1973, pp 313-392. 12. W. Lewellen, and M. Teske, "Second-Order Closure Modeling of Diffusion in the Atmospheric Boundary Layer," Boun. Lay. Met., 10, pp 69-90, March 1976. -155- 13. S. Patankar, et. al., "Prediction of the Three-Dimensional Velocity Field of a Deflected Turbulent Jet," Trans. ASME, J. Flu. Enq., pp 758-762, Dec. 1977. 14. K. Rao, et. al,, "Mass Diffusion from a Point Source in a Neutral Turbulent Shear Layer," Jour. Heat Transfer 299, pp 433-438, Aug. 1977. 15. M. Dickerson, and R. Orphan, "Atmospheric Release Advisory Capability," Nuc. Safety, Vol. 17, No. 3, May-June, pp 281-289. 16. R. Lange, "ADPIC: A 3-D Computer Code for the Study of Pollutant Dispersal and Deposition Under Complex Conditions," UCRL-51462, Oct. 1973. 17. M. Dickerson t et. al., "Concept for an Atmospheric Release Advisory Capability," UCRL-51656, Oct. 1974. 18. J. Knox, "Numerical Modeling of the Transport, Diffusion, and Deposition of Pollutants for Regions and Extended Scales," UCRL-74666, Mar. 1973. 19. J. Knox, "Atmospheric Release Advisory Capability: Research and Progress," UCRL-75644 (Rev. 2), May 1974. 20. R. Lange, and J. Knox, "Adaptation of a 3-D Atmospheric Transport Diffusion Model to Rainout Assessments, UCRL-75731, Sep. 1974. 21. R. Lange "ADPIC: A 3-D Transport-Diffusion Model for the Dispersal of Atmospheric Pollutants and its Validation Against Regional Tracer Studies," UCRL-76170, May 1975. 22. C. Sherman, "Mass-Consistent Model for Wind Fields Over Complex Terrain," UCRL-76171 May 1975. 23. R. Henninger, "A Two-Dimensional Dynamic Model for Cooling Tower Plumes," Trans. ANS, Vol. 17, 1973, pp 65-66. 24. J. Taft, "Numerical Model for the Investigation of Moist Buoyant Cooling-Tower Plumes," in S. Hanna and J. Pell, coords., Coolinq Tower Environment-1974 ERDA Symposium Series No. 35, Oak Ridge, Tenn., USERDA, Conf-740302, April, 1975. 25. D. Lilly, "Numerical Solutions for the Shape-Preserving Two-Dimensional Thermal Convection Element," Jour. of the Atmos. Sci., 21, pp 83-98, Jan. 1964. ___ I -156- 26. D. Johnson, et. al., "A Numerical Study of Fog Clearing by Helicopter Downwash," Jour. AppD. Met., 14, pp 1284-1292, 1975. 27. Y. Ogura, "The Evolution of a Moist Convective Element in a Shallow, Conditionally Unstable Atmosphere: A Numerical Calculation," Jour. Atmos. Sci., 20, pp 407-424, Sept. 1963. 28. G. Arnason, et. al., "A Numerical Experiment in Dry and Moist Convection Including the Rain Stage," Jour. Atmos. Sci., 25, pp 404-415, May 1968. 29. J. Liu, and H. Orville, "Numerical Modeling of Precipitation and Cloud Shadow Effects on Mountain-Induced Cumuli," Jour. Atmos. Sci., 26, pp 1283-1298, Nov. 1969. 30. W. Cotton, "Theoretical Cumulus Dynamics," Rev. Geophs. and Space Phys., Vol. 13, No. 2, pp 419-448, May 1975 31. Chalk Point Cooling Tower Project, Vol. 1-3, PPSP-CPCTP-16, Applied Physics Lab., Johns Hopkins Univ., Laurel, MD, August, 1977. 32. Chalk Point Cooling Tower Project, PPSP-CPCTP-ll and PPSPCPCTP-12, Applied Physics Lab., Johns Hopkins Univ., Laurel, MD, 1978. 33. G. Tsang, "LaboratDry Study of Line Thermals," Atmos. Environ., 5, pp 445-471, 1971. 34. J. Deardorff, "Numerical Investigation of Neutral and Unstable Planetary Boundary Layers," Jour. Atmos. Sci., 29, pp 91-115, 1972. 35. J. Deardorff, "Three-Dimensional Numerical Modeling of the Planetary Boundary Layer," in D. Haugen, ed., Workshop on Micrometeorolov, Ephrata, PA, Science Press, AMS, 1973. 36. J. Deardorff, "Three-Dimensional Numerical Study of the Height and Mean Structure of a Heated Planetary Boundary Layer," Boun. Lay. Met., 7, pp 81-106, 1974. 37. E. Spiegel, and G. Veronis, "On the Boussinesq Approximation for a Compressible Fluid," Astrophys. Jour., 131, pp 442-447, 1960. 38. L. Cloutman, C. Hirt, and N. Romero, "SOLA-ICE: A Numerical Algorithm for Transient Compressible Fluid Flows," UC-34, July, 1976. -15739. J. Iribarne, and W. Godson, Atmospheric Thermodynamics, Holland, Reidel Publ. Co., 1973. 40. VARR-II--A Computer Program for Calculatina Time- Dependent Turbulent Fluid Flows with Sliaht Density Variation, Vols 1,2,3, Madison, PA, Westinghouse Adv. React. Div., May 1975. ---- 41. A. Amsden, and F. Harlow, "The SMAC Method: A Numerical Technique for Calculating Incompressible Fluid Flows," LA-4370, May 1970. 42. R Gentry, et. al., "An Eulerian Differencing Method for Unsteady Compressible Flow Problems," Jour. of Comp. Phys., Vol. 1, 1966, pp 87-118. 43. E. Eckert, and R. Drake, Heat and Mass Transfer, New York, McGraw-Hill Book Co., 1959. 44. S. Hess, Introduction to Theoretical Meteorology, New York, Holt, Rinehart, and Winston, 1959, Chap 18.6. 45. Ibid., Chapter 18.7. 46. Ibid., Chapter 12. 47. H. Tennekes, "The Atmospheric Boundary Layer," Physics Today, Jan. 1974, pp 52-63. 48. C. Priestly, Turbulent Transfer in the Lower Atmosphere, Chicago, U. of Chicago Press, 1959. 49. R. Scorer, Natural Aerodynamics, New York, Pergamon Press, 1958. 50. A. Monin, "The Atmospheric Boundary Layer," in M. Van Dyke, ed., Ann. Rev. of Fluid Mechanics, Vol. 2, pp 225-250, 1970. .- 51. J. Businger, "The Atmospheric Boundary Layer," V. Derr, ed., Remote Sensing of the Troposphere, Washington, D.C., U.S.Dept. of Commerce, NOAA, Govt. Printing Office, Aug. 1972. 52. H. Panofsky, "The Boundary Layer Above 30 M," Bound. Lay. Met., 4, pp 251-264, 1973. 53. H. Panofsky, "The Atmospheric Boundary Layer Below 150 M," in Annual Review of Fluid Mechanics, pp 147-177, 1974. --------c- II -158- 54. G. Csanady, Turbulent Diffusion in the Environment, Boston, MA, Reidel Publ., 1973. 55. J. Lumley, and H. Panofsky, The Structure of Atmospheric Turbulence, New York, John Wiley & Sons, 1964. 56. A. Monin, and A. Yaglom, Statistical Fluid Mechanics, Vol. 1, Cambridge, MA, MIT Press, 1971. 57. A. Monin, and A. Yaglom, Statistical Fluid Mechanics, Vol. 2, Cambridge, MA, MIT Press, 1975. 58. Ibid., Vol. 1, p 280. 59. A. Blackadar, "The Vertical Distribution of Wind and Turbulent Exchange in a Neutral Atmosphere," Jour. Geophys. Res., 67, pp 3095-31029 1962. 60. A. Blackadar, and J. Ching, "Wind Distribution in a Steady State Planetary Boundary Layer of the Atmosphere with Upward Heat Flux," AF(604)-6641, Dept. of Meteor., Penn. State Univ., pp 23-48, 1965. 61. G. Yamamoto, and A. Shimanuki, "Turbulent Transfer in Diabatic Conditions," J. Meteor. Soc. Japan, Ser. 2, 44, pp 301-307, 1966. 62. J. 63. R. Bornstein, "The Two-Dimensional URBMET Urban Boundary Layer Model," J. Appl. Met., 14, pp 14591477, Dec. 1975. 64. F. Nieuwstadt, "The Computation of the Friction Velocity, u,, and the Temperature Scale, T,, from Temperature and Wind Velocity Profiles by LeastSquare Methods," Bound. Lay. Met., 14, pp 235-246, 1978. 65. H. Tennekes, and J. Lumley, A First Course in Turbulence, Cambridge, MA, MIT Press, 1972. 66. A. Monin, Weather Forecasting as a Problem in Physics, Cambridge, MA, MIT Press, 1972. 67. VARR-II Users' Guide, Op. Cit., p. 88. 68. Ibid., p. 37. O'Brien, "A Note on the Vertical Structure of the Eddy Exchange Coefficient in the Planetary Boundary Layer," J. Atmos. Sci., 27, pp 1213-1215, Nov. 1970. -159- 69. J. Holton, An Introduction to Dynamic Meteorology, New York, Academic Press, 1978, pp 167-169. 70. G. Briggs, "A Plume Rise Model Compared with Observations," Jour. Air Poll. Con. Assoc., Vol. 15, No. 9, pp 433-438, Sep. 1965. 71. D. Turner, Workbook of Atmospheric Dispersion Estimates, Cincinnati, Ohio, Us. Dept. HEW, 1969. 72. D. Slade, ed., Meteoroloqgy and Atomic Enerqv--1968, Oak Ridge, Tenn., USAEC, TID-24190, July, 1968. 73. R. Meroney and J. Cermak, "Modeling of Atmospheric Transport and Fumigation at Shoreline Sites," Bound. Lay. Met., 9, pp 69-90, 1975. 74. R. West, "Field Investigation of Cooling Tower and Cooling Pond Plumes," EPA-600/7-78-059 t Corvallis, Oregon, April, 1978. 75. J. Lumley, and B. Khajeh-nouri, "Computational Modeling of Turbulent Transport," in Advances in Geophysics, 18A, New York, Academic Press, 1974, pp 169-192. __~-----PI^-· l··ill *___Cl~qU_P__ s~l1~~·._ I CI~--l~-·-·lll ~ ~ L·~--· I 11·- ---- __ --·-- -- ---- 1------ 1^1_1 -160- APPENDI X Computer Code Listing t - . 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