New Mexico Bureau of Mines & Mineral Resources Socorro. N M 87801 Information: 505/835-5420 NEWMEXICO A DIVISION OF INSTITUTE OF MINING & TECHNOLOGY Publications: 505/835-5410 OPEN-FILE REPORT 301 GEOCHEMICAL ANALYSES OF HYDROCARBONS, CUTTINGS, AND CUTTINGS HEADSPACE GAS, MAR OIL AND GAS NO. 1 ESTES WELL, TORRANCE COUNTY, NEW MEXICO By Brown & Ruth Laboratories, Inc., Geochem Laboratories, Inc. and Precision Service, Inc. June 18, 1987 NEW M W C O TECH IS AN EQUAL OPPORTUNlMlAFFIRMATlVE ACTION 1.~:,'1" ' STATE OF NEW MEXICO ENERGY AND MINERALS DEPARTMENT P E T OFFICE BOX 2088 STATE LAND OFFEE BcllLCllvG SANTL FE.I*EWMEXICO 07501 [5051827-5800 WAIVER OF CONFIDENTIALITY ” _ RE: MAR OIL AND GAS Estes Well No. 1 See. 35. T-5-N. R-8-E. Torrance County, New Mexico A P I #30-057-20022 I ~~ The enclosed reports GeoChem Laboratories Inc., Jobs Numbers 3181 and 3230 andBrown and Ruth Laboratories the New Inc. Job Number 1939 should be placed into Mexico Bureau o f Mines Open-File System and be made available to the general public. \ I JACEK GAWRON Agent f o r Gila Explo ation, Inc. .. November 27,1985 Gila Exploration, Inc Peralta 839 Paseode Suite J Santa Fe, NewMexico Attention: . 87501 Robert G. McKinney Gentlemen: Four canned samples containing water and hydrocarbons recovered during analysis. In addition. a drilling f r o m the Estes Project were submitted for hydrocarbon sample of rig diesel was also analyzed. It was requestedthatthe fluids betopped,deasphalted. and subjected to liquid and gas chrorratography in an effortto determine whether the hydrocarbon fluids were relatsd to the diesel. Topping showed the fluids f r o m zone B and one of the cans marked"zone C" to contain 30%-45% volatile hydrocarbons.The nonvolatile fraction of both samples consists of 60%-73% hydrocarbons, with saturates and aromatics Fresent in nearly equal concentrations. Only very small quantities of asphaltenes are present (3%-6%). Gas chromatography proves that the fluids f r o m zone B and the above-mentionedsample (1939-003) from zone C are identical with the rig diesel. The material in theother can from zone C (sample 1939-005) is different, however. Liquid chromatography yielded only small amounts of hydrocarbons after removal of about 90% asphaltenes. G a s chromatography of thesaturated hydrocarbons shows that this sample is not identical with therig diesel. The distributions of n-alkanes having fewer than about 23 carbon atoms arevery similar to the diesel sample, but sample 1939-005 also contains a small amountof sample heavier material (unlike the diesel sample), It is thusapparentthat 1939-005 represents a mixture of rig diesel with other organic matter. Theorganic matter indigenous to sample 1939-005 is ratherrich in asphaltic componentsandpoor inhydrocarbons.Theseresultstentativelysurgestthat it is either immaturematerial or a tar or solidified bitumen ofsome scrt. It is -" .7 1 t Gila Exploratfon, Inc. November 27, 1985 Page 2 : ! i unlikely that this material represents a crude oil, although' heavy, asphaltic oils are common in some areas.Further analyses on uncontaminated sampleFmight be helpful in establishing the nature of the indigenous organic matter. We appreciate the opportunity to be of service to Gila Exploration. anyquestions regardingthesedata,then please contact us. I f you have I Very truly yours, BROWN & RUTH LABORATORIES, INC. Stephen W. Brown SWBIcahIC14 Enclosures TABLE I-A Results of C15+ Liquid Chromatography .........Hydrocarbons.. ....... Client Sample Number % I .D . % ............Nonhydrocarbons ........... Non-Eluted Asphaltene Saturates Aromatics Total Volitiles ($1 (%)(%) 1939-002A Zone B 30.7 41.2 31.8 1939-003A Zone C 43.0 30.2 65.8 35.6 1939-005A Zone C 6.1 SatlArom 73.0 *Partial Chromatography (%) NSO's NSO'S (%) Total ($1 (%I 1.29 3.6 2.9 20.5 27.0 0.85 5.6 5.1 23.5 34.2 -" 67.9 "_ *Amount of hydrocarbon insufficient for completeliquidchromatography.Partialseparation carriedout i n ordertoobtainsaturatefractionfor Q.C. analysis. _" _" '.., . L .. TABLE I-B Summary Table for C15+ Extract Analyeis I.D. Sample Extract Client Number ~~ ~~ CPI -mir Pristane Pristane PA%; Phytana n;Cr7- 1.13 0.73 0.70 1.13 0.78 0.72 1.40 ,ll.46 0.35 ~ 1939-002A Zone B 1939-003A Zone C 1939-005A Zone C """- ""1.05 . i ! TABLE I-C C16+ Saturate Hydrocarbon Analysis Normal Paraffin Distribution 1839-002A Zone B 16.8 15.8 12.8 1930-003A Zone C 7.6 16.7 1930-006A Zone C 8.6 12.4 9.4 12.0 8.3 13.9 10.9 13.4 11.1 8.6 13.9 6.3 12.9 4.6 10.0 7.0 4.3 4.6 8.1 11.0 8.1 5.5 0 0. 4. 2 --- --- --- -- --- -- --- ----- --- --- --- --- --- --- --- -- -- 1 .19. 8 1.1 1.1 0.7 0.7 0.4 2.1 0.9 0.4 2.6 1.0 3.6 2.4 0.2 --- 0.9 0.8 0.5 0.5 0.1 .. 0 3 m V f a 7 ...U... .,,. . .<.-_. . I . 8 I ” u N QEOCHEM1cAL SOURCE ROCK EVALUATION CRUDE OIL CHARACTEWATION OEOCnEMICAL CRUDE OIL-SOURCE ROCK CORRELATION August 12, 1985 G I L A EXPLORATION COMPANY 839 Paseo de Peralta Suite J Santa Fe, New Mexico 87501 Attention: Mr. Jack J. RE: GeoChem Job No. 3181 MAR OIL & GAS #1 ESTES * Gawron Dear Jack: The r e s u l t s o f , t h e Cl-C7 analyses performed on the three (3) canmd samples are enclosed. The r e s u l t s were also given t o Bob over the phone on July 23, e also discussed the condition of t h e samples and t h e s o i l typas found 1985. W i n t h e cans. The invoice is also included. Please c a l l i f we can assist you further. Sincerely, - TechnicalServices Manager G E O C W LABORATORIES, INC. If Enclosvres /2 TABLE I-A AIRSPACE DATA I i I i PAOE 1 TABLE II-A PAQE 1 AIASPACE DATA I GEOCHM ID DEPTHS =:======== =E==== C1-a ===== "_ C244 . C2/C2= WC3= IC4/NC4 Cl/(C2+C3) sszz== ==z=== ======E =x========= SUERlESS ====s=== 197-200 193.06 54.98 2.29 1.152.84 0.21 28* 47 3181-002 220-225 14.74 3.72 1.97 1.28 3.25 0.22 25.24 3181-003 310-311 304.68 39.38 0.34 0.18 7.11 0.54 12.92 3181-001 ' TAELS 1-8 COTPINOS DATA PAGE 1 3181-001 197-200 1356.90 1.35 1.32 0.87 0.76 0.18 0.35 '1.43 3181-002 220-225 1140.92 3.49 2.21 1.56 1.40 0.18 0.49 6.78 3181-003 310-311 1412.03 3.39 3.99 1.51 1.24 0.35 0.58 7.6 PAGE 1 G E - ID SEE======= C1-a "_ 197-200 1.02 2.17 1359.67 3181-002 220-i25 5.74 1146.66 3181-003 310-311 1417.88 3181-001 ! DEPTH3 ====== ' "_ C 2 4 . C2/C2= =====x 1.57 5.84 287.800.840.59 ICWNC4 C3/C3= =~=iil= ""_ Cl/(C2+C3) 1.14 0.510.20 606.82 1.11 0.37 1.21 ZWhTNLW ""'='f ns====== ." 225.40 0.50 0.41 , TABLE I-C :. I PAOE 1 CONBINED DATA QEOCBM ID DEFT89 HLTEANE ETEANE ETHYLENE PEDPANE PEOPyLELlE ISOBUTANE P BGTANE LIE===.==== E===== " " " " " " ===E*= L==.=.== ==a=*== =====x== 197-200 1494.98 3181-002 220-225 1151.94 3181403 310-311 3181401 . - ' 1677.34 40.22 1.30 18.29 9.19 5.91 0.24 35.55 2.14 3.44 1.1097.5629.31 =====E"= ========= "_ c5-CT 10.60 5.61 23.05 2.53 0. TI 7.60 6.61 29.71 1.95 TABLE II-C COHBINED DATA GEOCBM ID ====x%===== DEPT89 c1-c4 " " " " " " x==== "_ C2/C2= c2-c4 C3/C3= . ===sa= PAGE 1 " " " " " " Cl/(C2+C3) "ICWNC4 "_ " " " " " " " " " " ZUETHESS " " " " " " " " 197-200 1552.73 57-15 2.19 1.15 0.23 29.41 3.71 3181-002 220-2i5 1161.41 9.46 1 .71 1.17 0.31 136.42 0.81 3181-003 310-311 1722.57 45.22 0.36 0.22 0.56 39.77 2.62 3181-001 . _. . ! TABLE 11-A AIRSPACE DATd (IEOCBM ID DEPTES ====== ========a5 c1-c4 "_ c2-c4 ___== "_ PAaE 1 c2/c2= c3/c3= Ic4/Nc4 Cl/(C2+0) SUEl?lEss =sa=== " " " " " " ,==._=I== ====x=== ========== 323001 66 0 65.69 9.96 2.w 1.00 0.65 6.34 15.17 3230-OW 700 11.84 3.12 1.00 4.77 0.47 2.96 26.38 3230-003 820 56.97 13.38 1.55 2.05 0.25 3.59 23.49 3230-0011 900 n.4 26.63 1.66 4.75 0.35 2.03 34.55 1000 184.41 50.96 1.83 2.50 0.25 2.88 27.63 3230-006 1100 53.03 13.72 1.42 1.96 0.26 3.20 25.87 3230-007 1200 36.55 9.50 1.47 1.go 0.25 3.17 25.99 3230-008 1300 30.28 6.66 2.81 7.53 0.43 4.19 21.99 3230-009 1400 166.24 58.28 8.28 15.01 0.79 4.29 35. 05 3230-01 0 1500 30.49 7.79 2.54 3.76 0.54 4.01 25.57 3230-011 1600 31 -95 12.35 3.46 4.49 0.35 1.66 38.61 3230-012 Iio0 52.54 15.30 5.35 10.24 0.51 2.16 29.12 3230413 1800 57.75 17.33 7.16 25.69 0.60 3.01 30.00 323-014 1900 61.08 37.55 2.00 23.17 a35 0.82 55.98 3230-015 2000 122.60 35.13 2.55 10.03 0.40 3.41 28.65 32W-016 21COA 190.99 141.12 0.27 1.10 0.24 0.42 73.89 3230-017 210oB 132.39 36.52 4.92 20.79 0.81 3. a 27.58 3230-018 2255 2173.39 183.65 63.20 10.23 0.62 10.91 8.45 3230-019 2300 460.34 47.74 16.37 6.59 0.58 9.10 10.37 3230-020 2400 1642.12 71.93 54.35 11.63 0.7 1 22.42 4.38 3230-021 2500 322.85 31 .I4 22.13 32.35 1.74 11.36 9.83 3230-022 2600 183.44 60.14 12.38 18.58 a77 2.12 32.78 3230-023 2700 147.50 69.43 14.36 20.19 0.79 1.17 47.07 3230-005 ' TdBLE II-A AIBSPACE DATA I .. PAW 2 TABLE I-B CUTTINGS DATA GECCBM I D "_ i. . ! ; -- " DEPW mm " " " " " " " " " "E= = E m "_ r "_*== PAGE E m E "_r -N - - -- 1 1J BUTANE x======= " " "_ c547 3230-001 660 1796.38 9.96 0.58 4.13 0.10 1.W 1.14 10.44 3230-002 100 307.75 1.51 0.62 0.34 0.13 0.10 0.11 0.35 3230-003 820 1713.95 2.67 0.88 0.72 0.19 0.22 0.25 0.88 3230-004 900 1182.08 1.72 -483 0.82 0.14 0.24 0.24 3.21 3230-005 1000 1897.98 1.21 0.81 0.58 0.19 0.14 0.18 4.10 3230-005 1100 1608.11 1.68 0.97 0.86 0.18 0.21 0.35 4.19 3230-007 1200 1486.27 0.74 0.92 0.29 0.17 0.01 0.11 3.44 3230-008 1300 1136.17 3.29 0.75 1.30 0.4 0.48 0.57 4.41 3230-009 1400 1882.42 30.55 1.56 12.11 0.12 8.42 13.77 w7.m 3230-010 1500 1462.42 3.86 0.76 1.85 0.18 0.67 0.97 9.96 3230-011 1600 1416.91 1.10 0.85 0.18 0.14 0.16 0.27 5.62 230-012 1700 1615.46 4.71 0.11 2.91 0.07 1.oo 1.51 9.25 3230-013 1800 1308.84 1.13 0.13 1.24 0.12 0.32 0.75 10.28 3230-014 1900 844.05 0.10 0.56 0.56 0.13 0.12 0.40 5.14 3230-015 2000 1298.59 2.92 0.63 1.39 0.13 0.68 1.36 4.31 3230-016 21WA 1855.57 6.63 15.51 2.64 0.59 2.30 3.29 33.54 3230-017 21 OOB 2108.69 5.92 0.65 3.13 0.16 4.80 5.3 46.34 3230-018 2255 1927.16 9 0.28 1.31 4.44 0.14 0.40 0.65 4.88 3230-019 2300 1118.51 11.60 0.46 5.61 0. 4.59 4.30 4.03 3230-020 2400 1324.46 18.21 0.09 3.72 0.09 1.18 1.42 8.97 3230-021 2500 875.49 18.01 0.94 6.47 0. a7 4.96 3.40 11.43 3230-022 2600 1321.I2 1.13 0.38 2.91 0.10 1.30 1.21 11.79 3230-023 2700 1172.39 6.59 0.32 2.02 0.09 0.39 0.47 1.13 . lBgLE 1-6 CGlTINQS DATA PAGE 2 TABU 11-8 PAQE 1 CLIlTINGS DATA QEEOCEM ID ==========, . DEPTBS Cl-c4 " " " " " " " " ""5 c2-c4 ==*== c2/c2. O/C3= " " " " " " =a==== m E s s =x=="== 3230401 660 1812.65 16.26 17.11 38.64 0.89 127.45 0.89 3230-002 700 309.83 2.01 2.41 2.57 0.68 165.58 0.66 3230403 820 1717.83 3.88 3.01 3.82 0.87 503.76 0.22 900 1785.11 3.03 .2.06 5.73 0.99 696.96 0.17 3230405 1000 1900.10 2.12 1.48 3. CB 0.75 1057.19 0.11 3230-006 1100 1611.96 3.18 1.73 4.69 0.78 629.65 0.19 3230407 1200 1487.50 1.22 0.80 1.67 0.63 1432.21 0.a 3230-008 1300 1741.82 5.64 4.35 18.48 0.83 377.92 0.32 3230409 1400 1947.94 65.52 19.51 98.87 0.61 43.44 3.36 329-010 1500 1469.80 7.37 5.05 9.99 0.69 255.70 0.50 3230-01 1 1600 1479.29 2.32 1.29 5.37 0.59 780.63 0.15 3230-012 1700 1625.73 10.26 6.58 38.28 0.64 210.16 0.63 3230413 1800 1312.31 3.46 1.53 10.04 0.43 548.82 0.26 329-014 1900 845.85 1.80 1.25 4.25 0.30 662.66 0.21 3230-015 2000 1304.97 6.38 4.60 10.41 0.50 300. m 0.48 3230-016 21mA 1870.46 14.88 0.42 9-47 0.69 199.99 0.79 3230417 2100B 2128.45 19.76 9.04 23.34 0.90 218.16 0.92 3230-004 ' I I 329-018 2255 2022.95 95.79 65.75 29.88 0.62 20.34 4.13 3230-019 2300 1804.75 26.17 25.01 96. 1.05 102.94 1.45 3230-020 2400 1349.01 24.54 20.38 39.51 0.83 60.37 1.81 3230421 2500 908.38 32.88 19.13 81.34 1.46 35. 70 3.62 3230-022 2600 1334.89 13.16 20.10 27.52 1.01 124.08 0.98 3230423 2700 1181.87 9.48 20.25 20.59 0.84 136.12 0.80 (u 2 39Vd TABLE I-C PAGE 1 COHBINED DATA GEOCBM - I ! .- DEPTE.3 ID " " " . . =irLI=== HETBMlE ====DD= "_ W BLil'ANE ======== c5-m "_ 3230-001 660 1852.11 15.35 3.21 1.53 3.41 1.48 1.85 89.13 323-002 IO0 316.41 2.25 1.31 2.53 0.59 0.16 0.24 11.05 3230403 820 1151.54 9.30 5.16 6.23 2.86 0.48 1.24 24.59 323-004 900 1832.51 10.09 5.85 11.22 3.59 0.13 1.61 48.96 3230405 1000 2031.42 24.52 13.49 23.60 9 -31 1.07 3.88 20.24 323-006 1100 1648.08 8.24 5.58 6.59 3.10 0.51 1.49 11.84 3230401 1200 1513.32 5.11 3.92 4.31 2.32 0.27 0.90 4.50 323-w8 1300 1159.80 5.61 1.58 4.54 0.50 0.79 1.29 a .16 3230409 1400 1990.31 43.34 3.10 25.09 0.94 23.15 32.22 362.13 323-010 1500 1485.12 6.87 1.94 4.49 0.88 1.43 2.31 25.85 ' 3230-0 1 1 1600 1496.51 9.48. 3.26 4.15 0.89 0.32 0.12 8.16 . 323-012 1700 1652.11 13.56 2.36 1.59 0.52 1.62 2.11 15.59 3230413 1800 1349.21 6.10 1.51 9.09 0.42 1-79 3.19 51.15 323-014 1900 813.51 6.61 3.51 30.64 1.43 0.52 1.56 16.25 3230415 2000 1386.6 10.62 3.64 19.28 1.91 3.42 8.18 12.96 323-016 2lrnA 1905.44 109.56 367.15 18.17 14.66 6.14 21.52 138.89 3230411 21 008 2204.56 15.19 2.53 26.32 1.24 6.98 1.78 66.13 323-018 2255 3916.90 266.63 4.i6 10.38 0.12 0.93 1.50 14-09 3230419 2304 2191.11 48.23 2.10 14.34 1.31 5.50 5.84 17.89 323-020 2400 2894.65 18.50 2.00 13.44 0.92 1.98 2.54 19.32 3230421 2500 1166.60 31.33 1.54 18.80 0.46 8.86 5.63 18.14 323-022 2600 1445.02 45.43 3.112 23.12 1.19 2.28 2.41 22.28 3230423 2100 1250.45 49.43 3.30 25.46 1.26 1 B .o 2.22 11.83 x ' . .. .". LS' 9Z'EZ Z6'0 LO'LZ 08'0 69'91 LL'OZ LlO-OEZE EOOLZ eto-cm 5Szz 6lO-OEZE OOEZ OZO-&ZE OOhZ El'L66Z LZG GEZE GGE EZ'LEZL E9.119 ZZO-&ZE 009z hE'81SL LE'EL SZ'EL OOLZ BE'6ZEL Z6'8L h6.111 LS'lh 16'2 9I'OL Sh'l9oZ 10'95L 8Z'O EZ' L LE'O h8'09ZZ ez-94 ZL'LZ 68.0 .OL'ES SE'961h hh'6LZ 60'99 EZ'hL Z9'0 El'hL 60 'S9ZZ Z6'EL ge*Lt hb'OL h6'0 LO 'SE 811.96 OZ'6E 9h'hl 8L'O Bh'LE OE'OZ woh LE'6L L 66'5 EZO-OEZE E6'EL Zb'9Z ES'E 90'5 09'0 0091 5Z'LL5L 89'hl 06'2 E9'B hh'0 BL'60L ZLO-&ZE OOLL ezwa 95'SZ EL'S SE'hl 85'0 01'8L ELC-OEZE 0081 LO'OLEL 6L'OZ Zh'h 95-0 LE'S8 hlO-&ZE 0061 E6'ZL6 SE'6E Ef '0 hh'EZ SLWEZf oooz 8S'LZtrl Lh'O hE'9h 16'hl Zh'LZ 61'12 88'1 m-z3 =z3/z3 'EWE3 " = = . = " a "I= =====)I ""_Z Zz'9Z LL'tl "_ ======e " " " " " " " " " " 91.2 08.0 116.08 61.5 h9' L 8Z'h L9'0 00 '99 LI '2 8E'O LO'ELL 5tl.O 5Jo'L9 15.1 LZ'O OZ'Zh Lh' L ZL'Z 8E'O 9o'LLL EL'OL LE'L 88- L OE'O 9h.851 L L 'ZLLL OE'ZL 8S'E L0'6 19'0 EL'ZLL CB'EZL LL'O W '61 09'OEL ( E 3 * Z 3 ) / L 3h 3 W h 3 I 6L'h YWLZ 9LQ-lEZE 1 LO-OEZE 800-OEZE OOEL 60HEZE OOhl 8L'hllZ OOSL OE'OOSL LL'SL 010-QZE L8'hLLl LZ'LL 6L'Z98L L9.62 ZL; L LS'hBOZ W 'E5 L8'L 900-0EZE OOLt 66'h991 .06'9L LOO-OEZE OOZL 9lO'hZSL W'L . L9'LZE hE.8181 , 000 L 006 , . OZ8 ' ' SOO-OEZE WO-&ZE EOO-OEZE OOL mO-OEZE 099 LOO-OEZE ' ====DE =ma "13 ="x=====* (11 ma3030 I . TABLE I11 CARBON DIOXIDE ANALYSIS RESULTS .............................. GEO CHEM NUMBER . 3230-001 3230-002 3230-003 3230-004 3230-005 3230-006 3230-007 3230-008 3230-009 3230-010 3230-011 3230-012 3230-013 3230-014 3230-015 3230-016 3230-017 3230-018 3230-019 3230-020 3230-021 3230-022 3230-023 3230-024 WELL DEPTH CARBON DIOXIDE,MOL. 600 700 820 900 1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 . " " 2000 2100A 2100B 2255 2300 2400 2500 2600 2700 2800 I 0'. 168 2.946 4.786 3.665 3.237 4.621 4.998 4.317 3.405 11.442 10.197 6.969 11.567 7.616 7.117 5.794 3.721 4.528 4.886 5.581 3.441 3.894 2.765 5.665. . - .. Mol. Y 75.075 . . . . BTU Dry . mu Wmt . ,' 0 . 4 1 8 1 . 1 2 1 :. . . 1.FIAA .. , 717 066 0.248 . 9 1 6 0.059 2 5 . 3 5 w.8pclflo aRvkv I3 S t d . Press.. . BTU Dry BTU Wet . , 2 5 . 8 0 . 1 . 3 h 9 14.696 25.74 25.29 .: . , .. ... .vPsnlans ..... IC6 . . . . . "'.. . . or.Psntanm NCS - ?*anel CB . ' . . 2 Factor .. . : . .. ' ' .9972 9; ' ,planes P l u ~ C7+ {OPANE t ' 0.016 : GPM . . . . ...... . . . ,. .. . . .. .. .. . . .. . Runby .. .. . .: ,.,L&, ....... . . . .I. . . . . . . I I Jeffrey!.A. P r o p p .. ' .., ..,,. c ..,.. . .:. . . . . . -. . . . . .e . - '. . . I . .., ..r: . . ...... . . . . , . " I ... ,, . ~iribulion: ,. .. . _..,. . . . .*'+. , . . . .. .':. . . . . .. ... . ', : '. . ,.. . . . . .. , . . ., . . . . . . . . . . . . . . . . . . . >.,+. .>,?.'. . . . . ,,:.." , . . . . .I ... . ,>... . . . . . . . . . . . . . . . .... .'......... . ..... . . . . . . .... .... .. (.. . . . _ . ' I . . ' I .I I .i __ .. - -. - " ..... ... .... .. .-...-I ........ -. .. " " __..... . . . . ..-. . _.- ... .......... .. ._ - ..... - -. - " . . "-_ .. -?> - PRECISION SERVICE I N 6 Flow h u r a m s n t Enpinean Anrlyrir Reulu Summary Run No. Date Run 1028 1 DatsSarnpled 10/24/85 CJrper, WY 82801 Mol. % Llq. % lO/B/85 GPM P a MCF A BTU Dry BTU Wst Calc. Spsciik Gravity 0 I b T A Std. Press. 14.696 . BTU Dry BTU Wet 348 342 Calc. Vap. Prerr. */Sq.ln. Reid Vap. P m t . WSq.ln. .003. .001 .001 "LJZiL 2 . 8 4 7 . Z Factor .9949 Jaffrev A . P r o m Run by Jeffrey A , P r o m WICUIO~~BV 'mtane + Q.P.M. 2.8_49 Propane + G.P.M. Ethane 2;891 + C.P.H. 2.920 lirtributlon: '. " " " " -. - - I 53 " " " " " " " " " . " " ..-- . ". . .. PRECISION SERVICE INC. rnalyru For: .Mu: .ocstlon C o C T I A FXPl m 41 F s t a s lnnr : Y 1 1- N-1 urwn dmpiing Temp. Producar n DareRun MU T IOlUmeldaV ‘ m u r e on Bomb PSIG Run No. N n v Ln - lfl7A 7 1 n/7R/a.; Date Sampled ln13h/A r; Flow Mesruramant Enginaarr Andyria R w i t r Summary Carper, WY 82601 Preuure Line Sampled By ‘Atmos Temp. Formation PSIG: n j r L. ~ m n sat. I OF1 n- 7- Press. Bass 14.73 Mol. % Liq. % GPM Per MCF L BTU Dry BTU Wet Gals. Specific Grawitv C;nR e Std. Press. 14.696 BTU Dry BTU n e t ” 4 .004 h n u n e IC6 .001 -” Hexanas+- -” 5.113 4or.?onuM NC6 100 .ooo ‘Olsl + Calc. Vap. Preu. WSq.ln. Raid Vep. P r w . */Sq.in. .9970 Z Factor 5,174 5.116 5 :160 ’antane t G.P.M. Propane 617 607 G.P.’M. Ethane + G.P.M. 5.165 Xstribution: ” ” ” ” . -. . . . . . ..” _ - . . ” ” ” ” -.” . .- . - . . July 24, 1985 Mr. Leon A. Romero MAR Oil & Gas Corp.,Inc. P.O. Box 5155 Santa Fe, NM 87502 RE: MAR 0 & G #1 Estes Torrance County,New Mexico Dear Leon: At your request we sent three canned samplesthe from referenced well to Geochem, Inc. in Houston for headspace and cuttings'gas analysis for hydrocarbons. You will receive a written report from Geochem in two weeks, but we thought you might want a summary of their findings as to given me over the telephone yesterdayby Don Davis. A summary o f their analyses is attached. The data show that hydrocarbon shows you have encountered while drilling are: 1. Live shows, 2. Oil shows in samples 1 and 3, and gas shows in sample2, and 3. There is good evidence to support the contention that these hydrocarbons did not originatein the formations in which they now reside. Therefore, your objectiveof an o i l reservoir at depth seems reinforce? by these shows. Sample 3 has a (C,X lOOO)/C, ratio of 87, which compares favorably with surface geochemical anomalies we mapped on this prospect which ledto the drillingof the well. Recall that any ratio greater than80 indicates an oil prone source. The driller has reported hole deviation problems in association with these shows which ,suggests that the hydrocarbons are coming from fractures associated with faulting, and that the sourcethe ofoil noted onthe pits at 310' is a reservoir at.depth. The dissimilarity between headspace and cuttings gas for sample 3 tends to confirm this. From other studies we have made in the Estancia Bas'in the most likely oil is a gray shale'to siltstone interprone source associated with this structure val just abovethe Sandia sandstone. All other intervals are either inmature, lacking. in source material, or are gas prone. This analysis should helo you find a partner for the completion of this well. Yours truly, . Analysis of Canned Samples: MAR 0 & ( #1 Estes Geochem, Inc., Houston 1 Sample number 197 Depth - 200' 2 220 3 - 225' 310 - 3 11' Headspace Gas ( P P d methane 138 11 265 39 2 32 ethylene 17 1 94 propane 10 1 5 propylene 8 1 28 iso-butane 1 -35 normal butane 1 .27 pentane 5 ethane ' ' ' .35 1 23 1 Cuttings Gas ( PPm) methane 1,356 1,148 1,412 ethane 1 4 3 ethylene 1 2 4 propane 1 2 2 propylene 1 1 .5 iso-butane 1 1 .35 normalpentane butane .35 7 .5 0 1 7 i TABLE I CARBON DIOXIDE ANALYSIS GEOCHEM SAMPLE NUMBER 3230-001 3230-002 3230-003 3230-004 3230-005 3230-006 3230-007 3230-008 3230-009 3230-010 3230-011 3230-012 3230-013 3230-014 3230-015 3230-016 3230-017 3230-018 3230-019 3230-020 3230-021 3230-022 3230-023 3230-024 DEPTE INTERVAL (feet) CARBON DIOXIDE 660 700 820 900 1000 1100 1200 1300 1400 1500 1600 1700 ,1800 1900 2000 2100B 2255 2300 2400 2500 2600 2700 2800 . " 99.83 97.05 95.21 96.33 96.76 95.38 95 .OO 95.68 96.60 88.56 89.80 93.03 88.43 92.38 92.89 94.21 96.28 95.47 95.11 94.42 96.56 96.11 97.24 94.34 0.17 2.95 4.79 3.67 3.24 4.62 5.00 4.32 3.40 11.44 10.20 6.97 11.57 7.62 7.11 5.79 3.72 4.53 4.89 5.58 3.44 3.89 2.76 5.66 2100A " NITROGEN OXYGEP' ARGON . ... "