PHYSICS 140B : STATISTICAL PHYSICS PRACTICE MIDTERM SOLUTIONS Consider a four-state ferromagnetic Ising model with the Hamiltonian X X X Si Sj − H Si Sj − J 2 Si , Ĥ = −J1 hhijii hiji i where the first sum is over all nearest neighbor pairs and the second sum is over all next nearest neighbor pairs. The spin variables S i take values in the set − 32 , − 21 , + 12 , + 23 . (a) Making the mean field Ansatz Si = m + (Si − m), where m = hSi i is presumed independent of i, derive the mean field Hamiltonian ĤMF . You may denote z1 as the number of nearest neighbors and z2 as the number of next nearest neighbors of any site on the lattice. [15 points] Solution : As usual, we neglect fluctuations and obtain X ˆ m+H Si , ĤMF = 21 N Jˆ(0) m2 − J(0) i where ˆ = J(0) X J(R) = z1 J1 + z2 J2 . R (b) Find the mean field free energy F (m, T, H). [15 points] Solution : The free energy is obtained from the partition function, N ˆ m+H)S ˆ m2 −βF − 12 N β J(0) β(J(0) Z=e =e Tr e S =e ˆ m2 − 12 N β J(0) " ˆ ˆ #N J(0) m + H 3(J (0) m + H) 2 cosh + 2 cosh . 2kB T 2kB T Thus, F (m, T, H) = 2 1 ˆ 2 N J(0) m −N kB T " ˆ ˆ # J(0) m + H 3(J (0) m + H) ln 2 cosh . +2 cosh 2kB T 2kB T ˆ (c) Adimensionalize, writing θ = kB T /Jˆ(0) and h = H/J(0). Find the dimensionless free ˆ energy per site f = F/N J(0). [15 points] Solution : We have " # m + h 3(m + h) f (m, θ, h) = 21 m2 − θ ln 2 cosh + 2 cosh . 2θ 2θ 1 (d) What is the self-consistent mean field equation for m? [15 points] ∂f = 0 we obtain the mean field equation Solution : Setting ∂m m= sinh 2 cosh m+h + 3 sinh 3(m+h) 2θ 2θ m+h + 2 cosh 3(m+h) 2θ 2θ . (e) Find the critical temperature θ c . [15 points] Solution : We set h = 0 and expand the RHS of the above equation to lowest order in m. This yields m + 3 sinh 3m sinh 2θ 2θ m= m 2 cosh 2θ + 2 cosh 3m 2θ 5m = + O(m3 ) . 4θ The critical temperature occurs when the slope of the RHS matches the slope of the LHS, which occurs at θc = 54 . (f) For θ > θc , find m(h, θ) assuming |h| 1. [15 points] Solution : For θ > θc , if |h| 1 then |m| 1 and we can again expand, obtaining Thus, 5(m + h) 5h m' =⇒ m(h) = . 4θ 4θ − 5 (g) What is the mean field result for |Si | ? Interpret your result in the θ → ∞ and θ → 0 limits. Hint : We don’t neglect fluctuations from the same site. [10 points] Solution : We have · e3(m+h)2/θ + 12 · e−(m+h)2/θ + 12 · e(m+h)2/θ 2 cosh m+h + 2 cosh 3(m+h) 2θ 2θ + 3 cosh 3(m+h) cosh m+h 2θ 2θ = . 2 cosh m+h + 2 cosh 3(m+h) 2θ 2θ Note that as θ → ∞ we have |S| → 1, since all four states are equally probable and two of them have |S| = 12 and the other two have |S| = 32 . As θ → 0 the ground state configurations are selected. These are two completely polarized states, one with Si = + 32 ∀ i and the other with Si = − 32 ∀ i. Thus |S| → 23 in this limit. |S| = 3 2 · e−3(m+h)2/θ + 3 2 2