STUDY OF CE VISCOELASTIC E'iN T PASTE by SB, JOSEPH NEMC, Massachusetts Institute SM, Massachusetts JR. of Technolcgy (1963) Institute of Technolog, (1964) Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology 1967 Signature of Author. . .. . . . . Department of Civil Engineering , June 24, Certified by . . . . . . . . . .. 1D67 v Thesis Super-visor Accep te(d by . . . . . Chairman, Departmen .. ........ . . . . . . . . . . . al Committee Students tn c- - on o Grdu.ate = t St' ABSTRACT VISCOELASTTC "'DY OF CEMENT PASTE by JOSEPH NEMEC, JR. Submitted to the Department of Civil Engineering on June 24, 1967, in partial fulfillment of the requirements for the degree of Doctor of Philosophy. Creep of concrete presents serious problems to the structural designer. The currently available design techniques are mostly based upon empirical formulae consisting of additional factors of safety. The major portion of the creep of concrete is reported to be due to the creep of cement paste. It is thus the purpose of this thesis to study the applicability of the theories of linear viscoelasticity to the time dependent mechanical response of cement paste. This is expected to be the first step in the development of a time dependent composite model of concrete. Specimens of cement paste of water cement ratio of 1/3 are subjected to creep and relaxation in uniaxial compression tests, to creep in triaxial compression, and to flexural creep tests. The results of this study indicate that cement paste specimens tested under conditions of constant moisture, exhibit a linear viscoelastic response within the range of stresses and strains used in the study. To verify the applicability of the principle of superposition and the interchangibility of the data within the context of the laws of viscoelasticity, the results of creep tests are transformed to the Laplace domain and compared with the values of the results of the stress relaxation tests transformed into the Laplace domain. The characterization is utilized in a simple problem of viscoelastic deflection analysis using a simple beam made -2- The predicted deflections agree with the of cement paste. experimental data using the characterization obtained on beams. The creep behavior of larger size specimens is investigated. The results are similar to that of creep of smaller specimens. A limited number of long range tests are performed in axial creep, relaxation, and flexure creep. The behavior of cement paste under long range creep is found to be similar to that of shorter duration tests. Thesis Supervisor: Title: Fred NMoavenzadeh Associate Professor of Civil Engineering ACKNOWL EDG NT S The author wishes to express his gratitude to Professor Fred Moavenzadeh, his thesis advisor, for his valuable advice and suggestions during the preparation of this thesis. The author wishes to thank Professor F. J. McGarry, Division Head, for his encouragement during the work of this thesis. The author wishes to acknowledge the financial support of the Materials Division of the Department of Civil Engineering, the Ford Foundation, the Province of Quebec, and the Owens Corning Fiberglas Corporation. The author is very thankful to Miss Caroline G. Whitney for the typing of this thesis. -4- CONTENTS . . Title Page Abstract . . . Acknowledgment . . . . . . . . . . . . . . . . . . . .. Table of Contents . Chapter I. & 0 P0_9 Creep of Concrete . . . . . . . .a .0 . .. . . . . . . . . Concrete as a Composite Viscoelasticity . . . . . . . . . . . . . . . 15 16 Objective and Scope Chapter IV. Chapter V. Numerical Methods . . . 0 . 1 . . . Experimental Results . . . . . . . . . ... 36 Flexure Cree ......... . . . . . .. . . . Creep of 4" x 8" Cylinders. . . . . . . . Properties. . . . . . . . . . . . . .......... Discussions of Experimental . Flexure Creep and Its Prediction. . . . . Creep of 4" x 8" Cylinders. . .. ........ Chapter IX. . . . . . . . . . . Recommendations for Future Work. -5- . . . 36 36 38 39 41 42 44 Results Characterization . . . . ............ Interrelation of Functional Representation of Cement Paste . . . . . . . . . . . . . Conclusions. . 25 27 27 28 31 E. F. Elastic . . . . . . . . . . 22 . . . . . . . . . . . . . . . . . . .. Strength and Apparent Stress Relaxation . . Axial Creep Tests . . Triaxial Creep Tests . Chapter VIII. . 25 A. B. C. D. C. D. . . Functional Representation . . . . Linear Viscoelastic Behavior. Laplace Transformation. . . .. ..... Ramp Transformation Correspondence Principle. .. Inverse Laplace Transformation . Chapter VII. 9 20 Materials and Procedures Chapter VI. A. B. 5 0 Review of Literature 0 a 0 0 0 Chapter III. A. B. C. D. E. F. . . . Introduction...... Chapter II. A. B. C. . .. . . 2 45 . 50 50 54 . 55 . 57 CONTENTS (Continued) Page Figures . . . . . Bibliography . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 . . . . . . . . 140 Appendix A. Chemical Analysis of Cement ...... 146 Appendix B. Computer Programs . 147 . . . . . . B-I. Ramp Transformation . . . . . . . B-II. Collocation. . . . . . . . . . . B-III. Laplace Transformation. . ... . B-IV. Inverse Laplace Transformation . Appendix C. 147 151 154 157 . 161 C-I. Creep Tests . . . . . . . . . . . C-II. Relaxation Tests . . . . . . . . C-III. Flexure Tests . . . . . . . . . 161 164 167 Long Range Tests. . . . . . . . . . . -6- CHAPTER I. INTRODUCTION The existence of time dependent deformations of portland cement presents serious problems to the structural engineer. The time dependent deformations due to sustained loads are known as creep. as: The manifestations of creep are common such the sagging of reinforced concrete floor beams and the loss of prestressing force in the steel cables used in prestressed concrete. Since the phenomenon is not well under- stood, the solution to the design of structures for creep is difficult. In general, the methods utilized today make use of a reduced modulus of elasticity to compute deformations due to creep. Other widely used techniques simply multiply the elastic deformations by an arbitrary safety factor. The cur- rently available design techniques must be improved since concrete structures are being designed with increasing geometric and analytic complexity. The advent of ultimate design em- phasized the importance of a more accurate technique of time dependent stress analysis. There exist several theories that attempt to explain the mechanisms of creep of concrete. In general, it may be said that none of the currently available theories are adequate to fully describe the creep behavior of concrete. Therefore, more work is also needed to achieve better understanding of the phenomena. One approach to the problem consists in examining the be- havior of concrete along the lines of a composite. Concrete is a composite made of aggregates, matrix (cement paste) and voids. The properties of the whole are determined by the properties of the components. -7- In general, concrete creep is primarily due to the matrix. In other words, the time de- pendent behavior of the binder (i.e. cement paste) will govern the time dependent properties of the concrete. There- fore, for these reasons, it was decided to limit this to the study of time dependent properties of the matrix. This thesis will study the time dependent properties of cement paste which is a major component of concrete. The study utilizes the theory of viscoelasticity in the characterization and stress analysis of cement paste. -8- CHAPTER II. In this REVIEW OF LITERATURE section a brief review of the pertinent litera- ture is presented. The areas covered will include creep of concrete, considerations of concrete as a composite, and viscoelasticity. A) Creep of Concrete The time dependent behavior of concrete was considered very early in the development of concrete technology (1). The increasing deflections of reinforced concrete structures with time, the loss of prestressing in prestressed structures, and the cracking of plaster on the partitions as the load carrying frame bears on them due to increased deflections caused by creep are a few manifestations of creep. Since creep deflections can reach a magnitude of two or three times greater than the elastic deformations (2, 3), it is clear that the structural engineer must consider creep in his design of structures. The mechanisms of creep of portland cement and the methods to control the creep have received significant attention in concrete literature (4, 5). One of the earliest theories that was proposed is the plastic slip analogy (6), which explains the creep of concrete in a manner analogous to the plastic deformations of metals. The absence of yield stress and the sensitivity of creep of concrete to moisture are among the discrepancies which could not be explained by the plastic slip theory. Freudenthal (7) and others considered hardened cement paste as a viscous fluid surrounding the loose and rigid -9- aggregate components and the creep was considered due to the flow of fluid. viscous this with the absence of a although This view, limiting consistent or yield stress for creep, does not explain the observed creep recovery. The morphology of hydrated cement (8, 9) shows the presThese ence of a crystalline and a non-crystalline component. components, of colloidal size, are saturated by adsorbed moisture. The gel, under load, is thought to behave as a phases of varying elas- composite body consisting of several tic and viscous properties. The externally applied load is As the viscous initially borne by the elastic phase. ponent deforms, the overall body is creeps. com- deformed and the body This is known as delayed elasticity. This theory cannot explain the recovery phase present in concrete creep. Freyssinet (10) suggested that creep is due to the ex- change in the surface tension forces arising in the capillary pores of the hardened cement paste. This theory cannot ex- plain the experimental result which shows that the creep of a concrete with practically empty capillaries is not significantly lower than that for saturated concrete. said about this More will be later. The seepage of gel water theory (11) is based on the as- sumption that hardened cement paste may be considered as a limiting swelling gel. The gel equilibtrium ton and the externally applied load, vapor pressure of the gel water. lates that creep is with its skele- is determined by the The seepage theory postu- caused by the disturbance of this equi- librium due to externally applied loads, and its gradual reestablishment by a moisture exchange with the environment. This theory seems to be supported and also contradicated by -10- the work of Dolsch and Mullen (12). Their work consisted of a creep study of neat cement paste specimens. obtained under humid environmental Their results conditions tend to sup- port the theory of gel water seepage. The tests performed on oven dried specimens (110 0 C), showed no measurable creep. This would tend to contradict the theory of gel seepage and also that of delayed elasticity. Ali and Kesler (13) hypothesized that creep deformations could be explained in terms of the modification, by the externally applied loads, of the shrinkage and swelling due to changes in moisture content and in terms of the viscoelastic deformation of the structural elements of the gel. From this brief review of the theories of concrete creep it becomes apparent that none is really adequate in explaining the entire behavior. dictions are present. In several cases outright contra- It is clear that more work is needed in order to determine the true mechanism. One of the aspects that this additional work may follow would use the general theories of rheology. Rheology is the study of flow of materials. of concrete, the rheological approach was followe/d by Bingham and Reiner (14), (16). In the creep Forshind and Torroja (15), Paez and Mason An up-to-date review of the rheology of concrete is presented by Ali and Kesler (17). The attempts in applying the principles of rheology to the creep of concrete are based on the theory of viscoelasticity. Since viscoelasticity is a study of materials exhibiting both elastic and time dependent behavior, and since it has been used with considerable success with other materials such as polymers (18), it seems to be feasible to attempt its use in the study of the creep -11- of concrete. Such a first attempt took the form of model fit-- ting to empirical time dependent data, (19), Cowan and was made by Flugge (20), Hansen (21), and Glucklich and Ishai (22). The procedure followed by these authors consisted of selecting phenomenological models and determining their parameters so that the model response closely approximates the empirical data. The authors did not attempt to use the empirical formulations to stress analysis. The structural engineer analyzing a concrete structure must design it in such a manner that the finished product will provide adequate service iTmediately after construction and throughout its useful life. For this reason, the engi- neer must know how much the structure will defle-ct and how long it will take to achieve this deflection, therefore, the data required by the structural engineer includes the magnitude of creep deformations and the rate of the deformations. The technique that is used by most engineers is undoubtedly that of the American Concrete Institute (23). tion of the ACI Code specifies that: The 1963 Edi- "reinforced concrete structures subject to bending should be designed to have adequate stiffness to prevent deflections or other deformations which may adversely affect the strength or serviceability of the structure." However as far as the design procedure is concerned, the ACI Code specifies that instantaneous deflections are to be computed by the usual elastic formulae and that the long time deflections are to be obtained by multiplying the instantaneous deflections by 2.0. The Code im- poses certain deflection limits which are expressed in terms of the ratios of the spans. This design for creep is clearly empirical and entirely arbitrary. -12- The method does not consider loading conditions, the history of loading, and the possibility of changing loads. The method seems to be that of an increased safety factor rather than a method of rational design. Among the other available design methods there are the rate of creep method (24), method the reduced or equivalent modulus (25) and various design methods developed by Disching- er (26), Leonhardt (27), and Bieger (28). The rate of creep method uses a creep coefficient derived for a constant load. This coefficient is then introduced into a differential equation of equilibrium as a function of time, and the solution yields a time dependent solution for deformation. solution is often quite tedious and time consuming. major drawback of this technique creep coefficient. lies in The The the selection of the The coefficient is usually computed on the basis of constant load tests and thus does not reflect the influence of changing loads. The method also assumes that the magnitude of the load does not affect the creep coefficient. Finally, the assumption of a constant rate of creep coefficient with time is questionable. The method of reduced or equivalent modulus uses elastic methods, with a reduced modulus of elasticity, to compute creep deformations. It is similar to the ACI method. The design methods of Dischinger et al, use a differential equation relating creep deformations to the applied load. The creep shortening is assumed to be proportional to values of creep obtained for constant loads with modifications due to the ambient humidity. In many ways, it is similar to the rate of creep meth- od with some considerations given to age at loading and environmental conditions. -13- Recently there have been a few attempts at the correlation of theoretical and experimental estimates of the deflection of reinforced concrete structures. were performed by Gorley and Sozen (30), and Washa and Fluch (29), (31, 32). Such studies Bresler and Selna Each of these studies used one type of beam and are thereby of limited application in a general case in which the from the beams tested. structures used are different A more rational approach to creep has been used by Finnie and Heller (33). The authors attempted to describe creep properties mathematically and use these descriptions in a few cases of structural analysis. Another promising approach was followed by Polivka and Best (34) and Tielz and Dorn (35). The authors tried to analyze the creep of concrete along the lines of reaction rate theories and activation energies. This has theoretical promise but is still far from practical applications. The discussion of the currently available design methods shows that a more rational and universal design method is needed. This may take the form of a large scale testing de- signed to cover all major design cases. This approach must be rejected, not only due to the high costs involved, but much rather due to the basic approach to the problem since such a large scale testing program does not examine the problem at its source. Another basic approach could consist in determining the mechanisms of creep and then in estimating the time dependent deformations based upon the creep mechan- isms. Among the disadvantages inherent in this approach are that it is not clear structural analysis could be performed on the basis of microscopic mechanisms and that the creep mechanisms have not been determined. -14- A more rational and practical approach could use the concepts of composite materials. forms. Such a study could take two First, the time dependent behavior could be studied at the microscopic level. This is quite difficult since the morphology of cement is not known accurately (36). Second, the study could follow the phenomenological approach. From the standpoint of the designer such a study is very appealing since it does not concern itself with many details that are unfamiliar to the engineer. As far as the engineer is con- cerned, the topics of interest include mathematical characterization of the material and the application of such a characterization to structural analysis. B. Concrete as a Composite Concrete is a multiphase material consisting of mineral aggregates, stones and sand, bound by hydrated portland cement. The study of concrete as a composite began with La Rue (37) studying the influence of the aggregates on the properties of the composite as a whole. A theoretical study of the subject was performed by Dantu (38). The author examined the time independent properties of concrete, such as the distribution of stresses in the material. tended by Hirsch (39), Similar studies were ex- to include not only the binder but also the influence of the volume content of aggregates on the properties of the concrete. Kaplan (40) used ultrasonic meth- ods to perform a study of the strength of concretes made with different aggregates. This type of study was extended to cover the time dependent properties of concrete. Kordina (41) was among the first authors to examine the influence of the mineralogical properties of the aggregates on the creep -15- of concrete. He concluded that creep decreased with in- creasing stiffness of the aggregate. followed by Counto (42). A similar approach was Counto proposed a mathematical model which he used to describe the elastic and the time dependent properties of concrete. Similar models, used mainly for numerical descriptions of the distribution of internal stresses were proposed by Baker (45), and Hsu (46). (43), Reinius (44), Pickett Pickett and Hsu studied the behavior of concrete as a composite during shrinkage. The models were used by Baker to describe and rationalize the mode of failure of concrete. Reinius' model examined the failure properties of concrete by assuming that the hydrated cement gel consisted mainly of crystals in needle shapes. been supported by electromicrographs This assumption has (47). A very thorough study of multiphase systems was made by Hansen (48). He sum- marized the various models and developed mathematical formulations to describe their behavior. C. Viscoelasticity The concept of viscoelastic materials evolved from the studies of the theory of elasticity during the latter part of the nineteenth century. The theory was based on Maxwell's superposition principle and was first proposed by Butcher (49). Jeffreys Further progress was made during the 1920's when (50) considered creep in solids and attempted to fit mathematical formulae to experimental data. During the 1940's, polymeric materials were first used extensively. (51) Leaderman used the theory of viscoelasticity to describe the time dependent properties of cellular fibers. The theory was fur- ther extended by the work of Alfrey (52), Tobolsky (53), -16- Ferry (54), and Lee (55). The growth of the field became explosive in the 1960's with the development of solid fuel rocket engines (56). The mathematical representation of viscoelastic materials may take many forms. The general theory of viscoelasticity may be developed in terms of simple spring dash pot models or in terms of a series of such models. The early work in viscoelasticity was concentrated on materials that could be represented by these simple models. In general, however, materials commonly used have viscoelastic characteristics of such a nature that simple models are not sufficient to represent their behavior accurately. One way to improve the de- gree of mathematical representation consists in using integral operator laws based on the hereditary theory of Volterra (57). Another such improved representation consists in the complex modulus representation (Bland (58)]. A good presen- tation of the various characterization techniques and mathematical representations have been presented by Gross (59). Each mathematical form has definite advantages and disadvantages as far as the adequacy of representation of a real material is concerned. The ease with which material con- stants or functions may be measured, and the adaptability of such forms .to stress analysis manipulations, are important criteria affecting the selection of any given characterization form. A good discussion of the merits of each form is presented by Lee (60). When the characterization process and the material properties have been determined, the stress analysis of viscoelastic materials becomes possible. -17- The general method of viscoelastic stress analysis consists in solving the differential equations of equilibrium, and the time dependent consti- the compatibility equations, tutive equations. In the case of linearly viscoelastic materials,atechnique known as the principle correspondence, simplifies this general technique. The correspondence principle consists in using an associated elastic solution, that is an elastic solution with the material properties expressed in the Laplace domain. The time dependent solution is obtained by taking the inverse Laplace transform of the p dependent parameters. The requirements of this technique may be summarized as follows. linearly viscoelastic. First, the material must be Second, the boundary conditions and their type may not vary. Third, the associated elastic solu- tion must exist and must be known. Fourth, the inverse La- place transform must exist and must be unique. The limits of linearity are determined during characterization. The re- quirement of the boundary conditions was first advanced by Alfrey (61). The technique is best applied in the case of quasi-static conditions. The existence of the inverse Laplace transform presents some problems. The structure of the mathematical theory of this procedure has been presented in detail by Gurtin and Sternberg (62). and Onat (63). A simplified presentation was made by Breuer The authors have shown that the solution of the linear viscoelastic problem is unique provided that the relaxation modulus is a steadily decreasing function of time and is convex from below and tends towards a non-negative constant asymptotic value. -18- The actual computation of the inverse transform in a closed form is difficult. In order to eliminate this diffi- culty a large number of numerical inversion programs were developed. (64). Another technique was presented by Churchill This method takes the form of a direct numerical in- tegration for the evaluation of the inversion integral in terms of a numerically equivalent elastic solution. method is rather complex. This Schapery (65) presented another approximate inversion method which is simple but which provides for an evaluation of the error introduced and which permits the reduction of the error by the introduction of additional terms. This technique is known as the collocation method and will be discussed in detail in Chapter V. The scope and objective of this thesis, determined on the basis of this brief literature survey, will be expanded in Chapter III. -19- CHAPTER III. OBJECTIVE AND SCOPE This dissertation is a study of the time dependent behavior of cement paste. The study of the available litera- ture showed that while a great number of studies of creep of concrete were performed beginning as early as 1900 (66, 67), the studies reported on special cases and did not attack the problem from a rational point of view. Since concrete is a composite made of aggregates and portland cement, one obvious way of studying the properties of the whole is to study the properties of the components. As it was pointed out in the survey of literature, the binder is responsible for the major portion of the creep in concrete. The aggregates will modify the creep properties but will not cause creep. the Therefore, study of cement paste was performed and represented a first step in a composite time dependent analysis of concrete. This thesis studied the time dependent properties of cement paste for several testing variables. clude the age at loading and the stress study will follow a dual approach. The variables in- (strain) levels. First, the engineering properties of the material must be determined. as characterization. follows: The characterization The This is known will proceed as the creep and relaxation properties of the material will be determined for different stress and strain levels. The limits of linear viscoelastic behavior are determined by graphical methods. These limits are then verified using the relationship between the transformed values of the creep compliance and the transformed value of the relaxation modulus. The creep compliance J(t) is defined as the strain divided by t) and the relaxation the con'stant stress (i.e., J(t) , and the relaxation 0- -20- modulus strain is defined as the stress divided by the constant (i.e., E(t) =-- . After transformation Laplace domain here denoted by [J(p) and E(p)] into the the functions are related in the following manner: E(p) = 1 (Williams) The characterization is then utilized in a simple case of structural analysis, consisting of the creep behavior of a simply supported point load cement beam. The midspan de- flections are measured as a function of time and are compared to the deflections computed on the basis of the characterization. The correspondence principle form the calculations of deflections. (69) was used to perThe mathematical operations have been programmed for the Civil Engineering Systems Laboratory IBM 360-40. The mathematical methods will be presented in detail in Chapter V. In all, a total of [176] specimens were tested. These included 54 specimens used for the strength determination for 2" x 4" cylinders. 16 specimens. The 4" x 8" cylinder series consisted of The beam series consisted of 24 specimens. There were 42 specimens tested in stress relaxation and 40 specimens tested under creep both axial and triaxial. The specimens were tested at various stress, strain levels as it was discussed in the preceding chapters. -21- CHAPTER IV. v.ATEI:ALuS AND PROCEDURES The material used throughout this thesis was Type I ce- ment manufactured to ASTM Specification C-150 (70). The chemical analysis of this cement is presented in Appendix (A). The specimens were prepared in batches of 2800 gm. with a water/cement ratio of 1/3. In general, the preparation of the specimens followed ASTM C-187-58 (71). The creep and re- laxation specimens were cast in brass moulds and the flexure specimens were cast in Plexiglass moulds. After vibration, and smoothing of the surface, the specimens were placed in a moist room for 24 hours and under water after stripping and capping of the cylinders. The creep tests were run in a frame designed for this purpose. a steel The See Figures (1, 2). The triaxial cell consisted of cylinder blocked off at both ends by steel plates. steel plates were clamped together by four one-inch di- ameter threaded rods. Through the top plate, a piston guided by brass bushings applied a load on the specimen. The load was applied using a standard railroad car spring. The stiff- ness of the spring was such that the load remained constant during the creep of the specimen. The hydrostatic pressure was applied using water as a pressurizing medium. sure was generated by a pneumatic-hydraulic system coupled with a manifold that permitted the filling and emptying of the 6 pressure cells and allowed the use of a small gallon) Greer accumulator. compressed Nitrogen. strain gauges. The pres- (one The pressure was generated by The springs were calibrated using 'Thir creep deflections were measured using an -22- Ames dial gauge #0112 with divisions of 0.00005". The tests were carried out in a jacketed condition for about five days and were performed at several stress levels. The values of Young's modulus in compression were determined using the Instron Machine. The internal amplifier and servo-mechanism drive chart of the Instron were used in conjunction with the "U-Bars" to measure the strain due to the load applied. The sensitivity of the U-Bars and ampli- fier system was of the order of .00001". In this fashion a continuous record of deformation-load was obtained graphically. The U-Bars were calibrated using a dial gauge. To maintain the humidity equilibrium of the specimens, the specimens were coated by paint. This effectively prevented the weight losses for the duration of the modulus tests and the relaxation tests. loss is The influence of the paint on the weight illustrated by Figure 3 which shows that the coated specimens showed no weight loss up to 20 hours whereas the uncoated control specimenslost up to 1-5%. A similar tech- nique was used in the case of the relaxation tests. The stress relaxation tests were performed on the Instron Machine. After coating the specimens to prevent moisture losses, the specimens were deformed at a constant rate of strain (X = .05"/M) until the desired value of initial strain was reached. At this point, the cross head was stopped, and the decay of the load was monitored with time. The duration of the test at each strain level was of two hours. Each specimen was tested at four strain levels. The beams were tested in a controlled environment (700 F and 50%oRH). The beams were coated to prevent moisture losses and shrinkage stresses. The load was applied using a -23- mechanical lever with a 2:1 ratio. The mid-space deflections were monitored with time and were recorded for various loads. Strain gauges (A-7) were used to obtain the tensile and compressive extreme fiber strains. These were used to compute values of Young's modulus in flexure for the tensile and compressive cases. The tests were performed for 5 days. NUMLERICAL METHODS CHAPTER V. The experimental results of the tests performed in this In order to thesis are presented graphically in Chapter VI. achieve a form of viscoelastic representation, certain mathematical functions must be fitted to the data. As it was mentioned in Chapter II, a large number of different mathematical functions is available. A. Functional Representation One of the most The methods vary greatly in complexity. convenient techniques consists in a finite exponential series, As an illustra- (68). known as the Dirichlet or Prony series tion, the time dependent modulus E(t) could be represented as E,+ E D follows: where Ea is the initial value of the modulus, E. are the constants attached to each expoential term, 6; are the coefficients of the exponential, and t is time. This method has several attractive features. First, the curve fitting is easy; second, the accuracy of the fit increases with the addition of more terms in the series and is therefore not limited to any arbitrary value. this method is Third, particularly well suited to the computation of the Laplace transformation and the inverse transformations. used thrloughout this For these reasons this representation is thesis. The Dirichlet series collocation may be presented as follows: a series of discrete ordinates Do, Dl, ...Dn is available over a domain D consists at the Y) of collocating data points. (i.e., the series n+l points). D(t) = For the creep test -25- Et The technique -+ E; -V the formulation is modified slightly such that J~t) C -t L i--1 - where J(t) is the creep compliance, Je is the instantaneous value of the ccmpliance,T . * are constants, and t is time. The collocation will be exact in that the fitted series will agree exactly with the data at each abscissa. For conven- ience the constants are selected such that they lie mid span of each of the time decade. by Brisbane (72) at the This step was proposed since it effectively triangulizes the coef- ficient matrix and thereby simplifies the matrix inversion. The problem consists in finding the column matrix of the coefficients in the Dirichlet series. This column matrix is obtained by pre-multiplying the column matrix formed with the experimental results, by the inverse of the matrix formed by the exponential coefficients. matrix is This exponential coefficient formed from the exponential of the product of the by the various times corresponding to the experimental results. This system of equations may be shown as follows: E Se D,-E The procedure will yield the coefficients of the Dirichlet series and since the exponential coefficients have been preassigned the problem is thus fully described. The matrix multiplications and inversions programs are shown in dix B. -26-1) JI_ Appen- ) B. Linear Viscoelastic Behavior Linear viscoelastic behavior is defined by Tobolsky (53) as being the domain within which the strain, in a creep test, is directly proportional to stress, and in the stress relaxation test, the stress is directly proportional to strain. Therefore, one way to represent linear viscoelastic behavior consists in showing graphs of stress and strain at constant time. Within the linear viscoelastic region, the points at one given time will lie on a straight line. Deviations from the straight line provide an indication of the nonlinearity of the system. Another analogous technique consists in plotting the creep compliance T . E~4/ versus time for various stress levels; within the linear domain the curves should superimpose. Similarly, for a stress relaxation, the re- laxation modulus zL) .,,/Fs E should be plotted versus time for several strain levels and again the curves should superimpose within the linear domain. The viscoelastic functions are interrelated. pointed out by Gross (59), Laplace domain E ) I'/i As it was the following is verified in the where E(J) and J(r) are the La- place transforms of the relaxation modulus and creep compliance respectively. In order to achieve this equality, the functions must be transformed into the Laplace domain. C. LaDlace Transformation The Laplace transform of a function follows: - formed function and 6 where I () )- is defined as is the trans- the Laplace parameter. Extensive q tables of Laplace transforms are available e.g. -27- Hodgman (73), and in the case of exponential expressions, solutions are available in closed form. pressed in a Dirichlet For the stress relaxation ex- series CLt)= E EL e the following expressions are obtained for the Laplace trans- form D )= E-- - Williams (68). Simi- lar results are obtained for the creep compliance whose / A' transform is as follows A computer program has been written to generate values of U( ) and D(y) as a function of This program is pre- sented in Appendix B. D. Ramn Transformation In order to obtain E(t), the data obtained for the stress relaxation must first be transformed from the ramp loading used to the step strain input that is required by the definition of stress relaxation. As it was mentioned in Chapter IV, the stress relaxation tests were performed using the Instron testing machine. The limitations of the machine are such that, for the specimen size used in this thesis, the maximum rate of cross head deformation that could be used without losing accuracy was of the order of .05"/min. At this rate, the average length of time required to deform the specimen was of the order of .01 min. During the load- ing time the specimen relaxed so that when the desired constant deformation had been achieved, the load registered by the Instron was less than it would have been for the step input case. (I) This is best illustrated graphically in Table which shows the strain conditions and their stress re- sponses for the ramp loading used experimentally and the step strain input required theoretically. can be illustrated graphically The transformation (see Table I). of the ramp should be significant The effects £ at time 1 , where , is the duration of the ramp, and should become negligible at times tt) . For polymeric materials Hilton (77) found I L. that the effect of the ramp becomes negligible at times This transformation may take several forms depending on the form of the mathematical representation used. The tech- nique that is best suited to the Dirichlet representation has He assumed that the strain been proposed by Brisbane (72). applied to the specimen had a linear rise to a constant value and could be expressed as follows: E in./min. where R = Strain rate in i (-,) )= g o ' D LI S= Loading time in./min. = The Heaviside step function such that H I t<L, Using the above strain input, the stress response is given by for L b the stress SR+ responses reduces to A (v-2) wlhere fl -v-DLth re e 4; ~0 -29- D Ac,~ D D~ 4 L1 " time Ramp Strain Input time Step Strain Input r) () Cl) time Stress due to Ramp I Stress Corrected for Table. Stress due to Step Strain time aPRamp Loading Strain Inpit for Stress Relaxation. -30- To simplify the formulation, may be rewritten as fol- (V.-2) lows: C where where DL : (V-3) C LLg)L CL e then the relaxation modulus may be written as E (t)= E +2jIL E; e where E and E; e = E, 0 C -, .ii, ;, ) := Therefore, once the stress is known for may be obtained by the series representation. of the relaxation modulus is the modulus The accuracy highly dependent upon the accu- racy of the curve fit in the time domain corresponding to the stress response immediately after hI . Therefore, the curve fitting technique is improved by taking more data points in this region and the rway c I/2~-l decades. .vhere ; is \1 5 are chosen in the following centered in each of the time The transformation for ramp effects has been pro- grammed and is presented in Appendix B. E. Corresoondence Princip -le As it was mentioned in Chapter II analysis may take several forms. Alfrey (52) and extended by Lee -31- the viscoelastic stress The technique proposed by (69) makes use of the corres- pondence principle. formed in In the case of the stress analysis per- this thesis, the associated elastic solution is obtained by taking the elastic solution of the deflections of a simply supported point load beam and replacing value of E (modulus of elasticity) by tE( ], the Mandel (74). The numerical constants required are derived in Table II. The associated solution is of the following form: -2 3 Ey ) (V-4) where the various symbols are defined in Table II. The time dependent solution is obtained by taking the inverse Laplace transform of both sides of (V-4). Therefore, the problem consists in determining the inverse Laplace transformation of F. Inverse Laplace Transformation The inverse Laplace transform is defined as the function such ( that the function SOc) Hildebrand (75). satisfies (- ) The determination of the inverse is quite difficult in a closed form. co i function There are however, several approximate methods that can be used to obtain the Laplace transform in these are by Schapery a numerical form. The best known among (65) and Cost and Becker (76). This technique uses the fact that most general stress or displacement response for viscoelastic problems where the Laplace technique is wchere (t) applicable, is may be represented as follows: a general stress or displac-ment -32- function and T.ABLE II - rZ The elastic deflection y at the mid span of a simply supported point loaded beam is: SA PL / 4 EI where L is the span, P is the load, E the Young Modulus and I the transverse moment of inertia. In the viscoelastic case, the load is considered to be applied in a step fashion so that it can be represented by a Heaviside function which multiplies Po , the magnitude of SI the load. ?%t(C) There for time dependent deformation we have 48 In the Laplace domain we have: 45t3 E(-0 E(1) Ekt) by replacing the following values for the constants, the desired formula is achieved: = i0o . The moment of inertia in the transverse direction is computed as follows: then K= - .73 -,-Y . then the time dependent deflections will be achieved by taking the inverse Laplace transform of Loth sides of the equation: A ') - Ps 1 33-33 - are constants with respect to time and,"i is the transient component. The constants may vanish depending on the type of problem. If - (t) is a stress then since the stress must remain finite as t--~ if'-(t) is a displacement the i vanishes , conversely is zero when the body does not manifest steady flow under constant loads. Schapery (65) -%- Si suggests that a Dirichlet seriesa& where 46%"is the approximation to transient response, can be used as a good approximation to- the solution .1/-(). uses a series in which the The technique ,,are prescribed positive con- stants and the Si are unspecified coefficients to be determined by minimizing the total square error between,7' and ' This total square error is E2 = Applying the minimizing criterion, derivation with respect to Si yields In this way relations are obtained between the Laplace transforms of evaluated at . - This can be represented as follows: (/ By letting p = 1/f . - :., ', ,, -) and multiplying throughout the following result is obtained: ris - . V Explicitly, a more useful expression is achieved The system ( 1k for the given ' ) of equations is . used to calculate the These operations yield the transient -34- ' component of A the constants ). For the complete viscoelastic response, 7!and)'. of tp(i ) and %A(IO9 must be determined from the behavior as p tends to zero. This technique has been programmed and the determination of the coefficients proceeds along steps similar to the series collocation described earlier in this chapter. in Appendix B. -35- The program is presented CHTIP'ER VI. EXPERIEbTNTAL RESULTS This section presents the results on the elastic properties of cement paste, stress relaxation, creep in axial, triaxial, and flexural modes, and creep of larger specimens. There is no attempt to analyse the results. The analysis of the results is presented in Chapter VII. A. Strength and Elastic Properties. The compressive strengths of 2" x 4" cement paste cylin- ders (w/c = 1/3), as function of age, are shown in Figure 4. Each point represents the average of nine individual tests. The stress-strain curves obtained on 2" x 4" cylinders, using the U Bar extensometers are shown in Figure 5. The stress- strain curves are obtained for the four testing ages of 1, 3, 14, and 28 days. The variation of the modulus of elasticity with age at testing is shown in Figure 6. B. Stress Relaxation. The stress relaxation tests are performad on 2" x 4" cyl- inders that are paint coated to prevent the loss of moisture during testing. The tests are performed on an Instron testing machine and the specimens are subjected to several levels of strains to verify the linear viscoelastic behavior of cement paste in stress relaxation. The Instron recorder shows the load and its decay with time. Figure 7 is a typical result obtained from a relaxation test. This figure shows the varia- tion of stress with time for one day old specimens, tested at the two strain levels shown on the graph. could not be applied instantaneously, -36- it Since the strain becomes necessary to correct for the relaxation of the specimen which takes place during the loading time. This correction is performed using techniques discussed in Chapter V. The influence of the ramp loading is shown in Figure 8 which shows the results of a stress relaxation test corrected for the ramp effect. In this figure, the original stress relaxation data is comIt is seen that the pared with the ramp corrected results. stress relaxation results when corrected for the effects of the ramp loading have larger initial maximum values than the original uncorrected data. The corrected stress relaxation results coincide with the original data in about 50tl where tl is the duration of the ramp loading. Similar results are obtained for the other relaxation tests. Figure 9 shows the stress relaxation tests performed at four strain levels for 1 day old specimens. The data presented in this figure are corrected of the influence of the ramp loading. Figure 1 shows the results for stress relaxation tests performed at several levels of strain for the same 1 day old specimens. The results are corrected for the effects of the ramp loading. Figures 11, 12, and 13 show similar results obtained for specimens 3, 14, and 28 days old. average of two separate tests. Each curve is the In order to determine whether the material behaves in a linear viscoelastic manner, the stresses for constant values of imposed strains are plotted at constant time. The values of stress are taken from Figure 10 and are plotted for the 0 minute and for the 120 minutes isoclines. fashion, If the material behaves in a linear viscoelastic the isoclines must be straight lines. Figure 14 shows the stress-strain curves obtained for the 0 and the 120 minutes isoclines. ures 15, 16, This data is for I day old specimens. Fig- and 17 show similar results for specimens 3, -37- 14, and 28 days old. The material is seen to behave linearly. Figure 18 shows a typical relaxation modulus curve for the 28 days old specimens. This figure is obtained by taking the stress versus time curves shown in Figure 14, and dividing it by the corresponding imposed strain. Similar results are obtained for the other three ages at testing. The re- laxation moduli versus time are shown in Figure 19 for the four ages at testing. Data used in Figure 19 are obtained from Figures 10, 11, 12, and 13. A limited number of stress relaxation tests were performed for long time durations. weekend. In general, the tests lasted over a The long range tests are presented in Appendix C. The stress relaxation results are discussed in detail in Chapter VII. C. Axial Creep Tests. The creep tests are performed on 2" x 4" cylinders using the creep frames described in Chapter IV. filled with unpressurized water. The cells are The creep tests are per- formed at several levels of stress to verify whether the viscoelastic behavior is linear or not. cal creep test. Figure 20 shows a typi- In this figure the creep curves are shown for various levels of stresses used for 1 day old specimens. Figure 21 shows creep strains versus time for 1 day old specimens loaded at several levels of stress. and 24 show similar results for specimens 3, old. Figures 22, 23, 14, and 28 days Each curve represents the average of two separate tests. In order to verify the linearity of viscoelastic behavior in creep, similar methods to those in the stress relaxation tests are used. If the material behaves linearly, the -38- isoclines joining creep st:rains plotted for constant values of stress must be straight lines. Figure 25 shows stress and strain curves plotted for the 0 and 120 hours isoclines. The data is obtained from Figure 21. Figures 26, 27, and 28 show similar results for specimens 3, 14, and 28 days old. The figures are obtained from the data presented on Figures 22, 23, and 24. The material is seen to behave linearly un- der axial creep. When creep strains are divided by their imposed stresses, a creep compliance J(t) is obtained i.e., ~0/60)/ EJO() Figure 29 shows the creep compliance versus time for 3 days old specimens. The data presented in the figure is obtained by dividing the creep strains of Figure 22 by their constant imposed values of stress. the other ages at loading. Similar curves are obtained for Figure 30 shows the creep com- pliance versus time for the four ages at loading. A limited number of long range tests are shown in Appendix C. The axial creep results are discussed in detail in Chapter VII. D. Triaxial Creep Tests. The triaxial creep tests are performed on 2" x 4" cement paste cylinders. The rationale for the tests is two fold. First, triaxial creep tests bring out the effects of complex states of stress on the creep behavior of cement paste. Sec- ond, terms similar to Poisson's ratios in elasticity can be evaluated using the results of triaxial and axial creep tests. This evaluation completes the characterization of cement paste under the assumption of isotropic and homogeneous material conditions. The triaxial creep tests are performed using the creep frames described in Chapter IV and are performed in -39- a jacketed condition. The tests are executed at several levels of stress and the ratiol/!30 with( O= ; that is, the ratio of axial to transverse stresses is kept constant at 3. Figure 31 shows the curves of axial creep strains versus time for the several values of stresses and for 1 day old specimens. Figure 32 shows axial creep strains versus time for several values of stresses shown and for 1 day old specimens. Similar curves are obtained for the other ages at loading and are shown in Figures 33, 34, and 35 for specimens 3, 14, and 28 days old. Each curve is the average of two separate tests. The triaxial creep curves are not corrected for the influence of the transverse stress. The isoclines are plotted for the uncorrected data and the influence of Poisson's ratio will be discussed in Chapter VII. To verify whether the viscoelastic behavior of cement paste, under triaxial conditions, is linear or not, the method of time isoclines is used again. The con- dition of linearity requires that the time isoclines joining creep strains at several levels of stress must be straight lines. Figure 36 shows stress and strain for triaxial creep for 1 day old specimens. The data is obtained from Figure 32. Similar results are obtained for the other ages at loading. Figures 37, 38, and 39 show time isoclines for specimens 3, 14, and 28 days old. The data are obtained from Figures 33, 34, and 35. The material is seen to behave linearly. When creep strains are divided by their corresponding imposed stresses, a triaxial complianceS't) is obtained i.e., S')= '6 where formation and and 0- -- CO. is E!A) is the time dependent axial de- the axial stress such that The creep compliances uncorrected uniaxial data. COI /o-i are calculated for the The influence of Poisson's ratio will be discussed in Chapter VII. -40- Figure 40 shows creep compliance versus time for several values of stresses and for 1 day old specimens. This figure is derived from data pre- sented in Figure 32. Similar results are obtained for the three other ages at loading. Figure 41 shows the creep com- pliance versus time for specimens 1, 3, 14, and 28 days old. The figures are obtained from data available in Figures 32, 33, 34, and 35. The triaxial creep results are discussed in de- tail in Chapter VII. E. Flexure Creep. The flexure creep tests are performed on 1" x 1" x 12" cement paste beams. for two reasons. The flexure creep tests are performed First, the data obtained is used to apply and to verify the viscoelastic characterization obtained for the cement paste cylinders. Second, the flexure creep tests illustrate the influence of a stress gradient and the influence of a tensile stress on the creep behavior of beams. The flexure creep tests are performed using painted beams to prevent moisture losses during the tests. The creep flexure tests are performed for three mid span point loads. This will permit to verify whether the viscoelastic response of cement paste beams when tested in flexure, is linear or not. In addition to the mid span deflections, readings of extreme fiber strains are taken both in tension and in compression. Figure 42 shows the mid span deflection creep versus time for the three loads levels and for 1 day old specimens. Similar results are obtained for the three other ages at loading. Figures 44, 45, 45, and 47 show mid span creep deflections for the three loads and for specimens 1, 3, 14, and 28 days old. Each curve is the average of two separate tests. -41- The extreme fiber strains are obtained in tension and compression and are plotted in microinches/inches on a common graph. Figure 43 shows the extreme fiber strains in microinches/inches versus time, for the three load levels, and for 1 day old beams. Similar curves are obtained for the other ages at loading. Figures 48, 49, 50, and 51 show the extreme fiber strains versus time for the three loads used and for specimens 1, 3, 14, and 28 days old. The linear viscoelastic determination makes use of the technique of time isoclines. Figure 52 shows the load versus mid span deflections for the three loads and for the four ages at loading. The material is seen to behave linearly under flexure. When the extreme fiber strains in compression are divided by corresponding stress, a flexure creep compliance achieved i.e., tS')is Figure 53 shows the flexure A creep compliance for 1 day old specimens. Similar results are obtained for the three other ages at loading and are shown in Figure 54. In this figure flexure creep compliance versus time is shown for specimens 1, 3, 14, and 28 days old, and the data is obtained from Figures 44, 45, 46, and 47. A limited number of long time creep flexure tests are presented in Appendix C. The flexure creep tests are discussed in detail in Chapter VII. F. CreeD of 4" x 8" Cylinders. Axial creep tests are performed on 4" x 8" cement paste cylinders to investigate the effects of specimen size on the creep properties of cement paste. The creep tests are per- formed using the creep frames described in Chapter IV and are conducted under fully saturated conditions. -42- The creep tests are performed at several levels of stress to determine whether the viscoelastic behavior of 4" x 8" cement paste cylinders is linear or not. The strength properties of 4" x 8" cylinders are shown in Figure 55 which shows the compressive strength versus age. Each point represents the average of 6 specimens. The creep strains versus time, for 1 day old specimens, are shown in Figure 56. Similar curves are obtained for creep strains versus time for 4" x 8" cylinders loaded at several stress levels and for specimens 3, 14, 28 days old. in Figures 57, 58, and 59. This is shown To verify linear viscoelasticity, the concept of time isoclines is used again. Figure 60 shows the stress and strain, for 1 day old specimens, for the 0 and 120 hours isoclines. Figures 61, 62, and 63 show similar re- sults for specimens 3, 14, and 28 days old. The isoclines are derived from the data presented in Figures 57, 58, 59, and 60. The material is seen to behave linearly under axial creep for 4" x 8" cylinders. The axial creep compliance '"\b] is obtained by dividing the axial creep strain by the imposed constant stresses i.e., /<1 . Figure 64 shows the creep compliance versus time for I day old specimens. Similar results are available for the 3, 14, and 28 days old specimens. Figure 65 shows the creep compliances versus time for the 1, 3, 14 and 28 days old specimens. The axial creep strains for 4" x 8" cylinders are dis cussed in detail in Chapter VII. -43- CHAPTER VII. DISCUSSION OF EXPERIMENTAL RESULTS The review of literature and the preliminary tests performed confirmed that cement paste does not behave in an elastic manner. The manifestations of deviations from the elastic behavior are quite common. These include the creep of specimens, the relaxation of stresses, and the sensitivity of cement paste to rate of loadings. This last point is illustrated by Trost (78) in studies on concrete cylinders subjected to compressive loads applied at different rates of deformation. The deviations of cement paste from elastic behavior, bring about the need for another approach to the problem. The approach proposed by several authors suggests the application of the theories of linear viscoelasticity to the solution of the non-elastic behavior of cement paste. It should be pointed out that the study of cement paste represents the first step in the composite analysis of the time dependent behavior of concrete. The need for a new approach to the solution of the time dependent behavior of concrete is illustrated in the review of literature presented in Chapter II. proach is followed in this thesis. The viscoelastic apIt becomes therefore necessary to verify whether or not the theory of linear viscoelasticity is applicable to the study of cement paste. The verification takes the form of creep and relaxation tests. The tiie dependent tests are performed under the following conditions and for the following variables. The creep and relaxation tests are performed on 2" x 4" cement paste cylinders tested at four different ages: 1, 3, 14, and 28 days. The specimens are tested in the absence of shrinkage since all specimens are tested coated or fully saturated so that the humidity equilibrium is maintained in the specimens. specimens are tested for the water/cement ratio of 1/3. All The casting and curing conditions remain identical throughout the tests. The discussions presented in this chapter are for the tests carried out within the scope of the experimental techniques described above. A. Characterization. The results of the axial creep tests as presented in Figures 20 through 30, indicate that the material behaves in a linearly viscoelastic manner as is illustrated by the use of time isoclines presented in Figures 25 through 28. This linearity is valid within the stress levels used in this thesis. age The magnitude of the creep strains decreases as the (strength) of the specimens increases. to the results of Neville et al This is similar (79) reporting on the re- lationships of creep and the gain in strength of concrete. The decrease is due to the change in the structure of cement paste as the hydration proceeds. At first the morphology of cement paste resembles a loose network of tubes or needles arranged in three dimensional arrays. with water. The pores are filled As the hydration proceeds, the products of hy- dration fill up the voids. water present, both iT the There is still considerable gel and capillary pores, but the density of the structure increases considerably. The result is a stiffer structure that is somewhat less sensitive to deformations since more of the load is carried by the skeleton than was the case for the early cement. stiffness reduces the deformations extent of creep. This increase in and thereby reduces the The decrease in creep magnitudes is further -45- illustrated in Figure 30 which shows the creep compliance versus time for the four ages at loading. decreases with increasing age. to explain this decrease. The compliance Similar arguments are used The functional representations of the compliances shown in Figure 30 are obtained using the collocation program shown in Appendix B-I. A limited number of long range axial creep tests are presented in Appendix C-I. The long range axial creep tests show that creep continues to occur at a decreasing rate. The long range axial creep tests are allowed to creep for approximately 25 days. The long range specimens continue to creep at reduced rates. This is related to the arguments on the hydration processes mentioned earlier. is continuing at reduced rates. The hydration The strength increase rate slows down and the creep decreases. The results of the stress relaxation tests when corrected for the influence of the ramp indicate that cement paste behaves in a linear viscoelastic manner; this is illustrated by the use of time isoclines presented in Figures 14 through 17. The magnitude of the relaxation decreases with increas- ing specimen age. This is again similar to the data presented by Neville et al (79). The argument explaining this behavior is the same as that presented for creep. The reduction in re- laxation is further illustrated by the curves shown in Figure 19. This figure shows the variation of the relaxation modulus versus time for the four ages at loading. The modu- lii increase with age, indicating a reduction in the extent of relaxation as the specimens increase in functional representations, strength. The for the relaxation modulii, shown in Figure 19 are obtained using the ramp transformation program shown in Appendix B-II. range tests are shown in A limited number of long Appendix C-II. The long range re- laxation tests are usually performed over a weekend. The long range tests indicate that stress relaxation continues to occur at decreasing rate. The longest time that the specimens are allowed to relax is of the order of 3500 minutes (approximately 60 hours). The relaxation tests carried out at long times indicate that the behavior of cement paste under relaxation is similar to the observed long time creep behavior. The results of the triaxial creep tests are shown in Figures 31 through 41. formed on jacketed 2" The triaxial creep tests are perx 4" cylinders with $ L , The . ratio of the axial to transverse stresses remains constant throughout the test series. This ratio is selected as being fairly representative of the state of stress found in concrete structures. Before the linearity of the cement paste under triaxial loadings is examined, the values of Poisson's ratios must be determined. The time variation of Poisson's ratio is obtained as follows: Two values of the modulus of elasticity are picked up from Figure 15, which show the axial creep isoclines. The selected values are for the 0 and 120 hours isoclines. Under the assumption of isotropic and homogeneous material, this is represented as follows: -- ~ . U Using the same times, values of axial creep, measured under triaxial conditions, are obtained from Figure 37. points correspond to the following equation: . I~-o -47- The triaxial A e at 0 Hours 120 Hours 0.282 0.272 3.5 0.199 0.192 3.5 14 0.144 0.141 2.1 28 0.128 0.126 1.6 Loading TABLE III. % Difference Poisson's ratio and the variations with age at loading and time of tests. -48- The triaxial conditions used in the experimental tests are as follows: :.~' e- : l . The technique yields values of Poisson's ratios when values of the axial modulus obtained from the axial creep are introduced for triaxial creep for the two times. ratios obtained into the equations The values of Poisson's for the 0 and 120 hours isoclines and for the four ages at testing are shown in Table III. Since the variation of Poisson's ratio does not exceed 4%, it is assumed that for all practical purposes the values of Poisson's ratio remain constant under creep. strains measured on 2" Figure 66 shows the creep x 4" cylinders aged for 3 days, for the axial and triaxial creep conditions. The triaxial creep strains remain consistently smaller than the corresponding axial creep strains. The difference between the strains due to the modes of loading is constant with time. This further illustrates that Poisson's ratio remains constant during creep. The differences increase with increasing stress since the ratio of axial to transverse equal to 3. L'Hermite stress is kept constant and (80)presents similar results on the time variation of Poisson's ratios. The consequence of the constant values of Poisson's ratio during creep is that cement paste behaves elastically in volumetric strains. The stress strain isoclines for the triaxial case are shown in Figures 36 through 39. The influence of the t riaxial stress component consists in reducing the strain by a constant value at each stress level. This reduction does not affect the linearity of the time isoclines since the same constant is subtracted from the two values of strain, the two time isoclines. behave in corresponding Therefore cement paste is seen to a linear viscoelastic manner under triaxial conditions such that: to ~~ = ~til -49- . The creep creep compliance is shown in Figure 41. The reduction in the creep magnitude with increasing age of the specimen is again apparent in this figure. Uniaxial and triaxial creep tests and uniaxial relaxation tests indicate that cement paste behaves in a linearly viscoelastic manner. B. Interrelation of Functional Representation of Cement Paste. The linearity is further investigated by means of the interrelations between the viscoelastic functions. terrelationships are based on the work of Gross The in- (59). Gross presents the mathematical structures of linear viscoelasticity. One such interrelationship is established between the creep compliance and the relaxation modulus. This technique yields an algecbraic relation between the Laplace transforms of the creep compliance and the relaxation modulus. formation into the Laplace domain is The trans- performed using the com- puter program presented in Appendix B-III. Figures 67, 68, 69, and 70 show the curves of E(p) and l/J(p) versus p the Laplace parameter. The curves are shown for 1, 3, 14, and 28 days old specimens respectively. Since the curves of the creep compliance and the relaxation modulus are superimposable the relationship obtained by Gross is verified. This implies that it is possible to transfer creep to relaxation in the Laplace domain and that the accuracy of the numerical techniques is good. C. Flexure Creep and Its Prediction. The flexure creap tests are performed on 1" x 1" x 12" simply supported beams. The beams are testLed at the four -50- ages of loading of 1, 3, 14, and 28 days. The results of the flexure creep tests are shown in Figures 42 to 52. Cement paste is shown to behave in a linear viscoelastic manner under flexure. This is shown by the load-deflection curves plotted for time isoclines presented in Figure 52. The readings of the extreme fiber strains as function of time are shown in Figures 48 through 51. The tensile face ex-- treme fiber strains are consistently larger when compared to the compressive face extreme fiber strains corresponding to the same load. at loading. This increase is present for the four ages Similar results are noticed by Glucklich on experiments with cement paste beams. (22) The explanation proposed by Glucklich attributes this consistent increase in tensile strains to the microcracks induced on the tensile face of the beams. merits further strain gauges This explanation seems rational and comments. In order to permit the mounting of on the cement paste beams, the specimens are removed from the curing tanks and are placed in the constant temperature and humidity room. are maintained at 70 0 The temperature and humidity F and 60% RH. During this time the strain gauges are mounted on the beams and are allowed to set for 24 hours. the Immediately after the gauges are mounted, specimens are coated. It is conceivable that some shrinkage cracking occurs during the short time limited drying of the beams. The shrinkage on the compressive face, but are face. cracks. This probably is Their main in the strain compression. gauges The the process This results show greater reduction -51- are kept closed forced open on the tensile of formation of the influence consists geometry of the beam. and cracks in in altering higher actual readings in the in stress, tension than creep with age is evident in Figure 54 which shows values of creep compliance versus time. Again the magnitude of creep diminishes with in- creasing age of specimens. The values of flexure creep complianceare computed using the measured values of extreme fiber strains and the stresses that are causing them. This is shown in Figure 71 where the creep compliances are plotted for the four ages at loading. Figure 72 shows the comparison between the compliance obtained for cylinders and the compliance computed on the basis of the extreme fiber strains measured on beams. are large. The differences between the compliances This can be explained partly in terms of the tensile stress field present at the bottom of the beam which may have the effect of formation of microcracks as indicated by the larger tensile strains measured on the bottom face of the beam. The cross section under load is reduced and the beams creep more since the load remains the same. This seems to be supported by the observed static fatigue of several trial beams. is reduced. The failures cease when the load level The difference may also be explained in terms of a different behavior of cement paste under axial compression and under a stress gradient. In order to verify the characterization, the deflections of the beam are predicted using the computer program presented in Appendix B-IV. The calculations are performed for each of the load levels used in the flexure creep and for the four ages at loading. The calculations are first performed using the data obtained on cylinders. The results of the calcula- tion are shown in Figures 73, 74, 75, and 76. The results of calculations based on the creep compliances obtained on cylinders are poor. This could be expected due to the large deviations in the compliances as shown in Figure 72. -52- The deflection calculations obtained on beams. are repeated using the creep data The results of the calculations are shown in Figures 77, 78, 79, and 80. In this case the agreement between theoretical values and experimental data is good. The results deviate at most by 8%. The difference in the predicted deflections using the data obtained on cylinders and the results based on data obtained on beams, point out several things. It is apparent that the influence of the tensile stress is larger than first suspected. The calculations of creep in reinforced concrete are based on cylinder creep data. In the case of reinforced concrete the influence of the tensile stresses is not very significant since the steel is assumed to carry all the tensile forces. However in the case of cement paste beams, with no reinforcement, the influence of the tensile stress on the creep behavior of the beam is significant as is shown by the results. One of the consequences of the experimental results is that in order to achieve full characterization, the tensile creep behavior of cement paste should be determined. Some data is crete. Hallaway (81) presents data on the creep properties available on the tensile creep of con- of concrete in tension. Similar experiments could be carried out on cement paste. Another way of explaining the large discrepancies observed between the compressive axial compliance and the flexure creep compliance could be as follows. Since the general shape of the compliance curves is similar but the initial values differ, it is possible that the values used for the strain on the cylinders are not exact, The strain is computed on the basis of the change of overall length divided by the initial. -53- length. The deflections of the beams are taken directly using mechanical gauges. This difference would also ex- plain the variations obtained in the predicted deflections. D. Creep of 4" x 8" Cylinders. The creep tests on 4" x 8" cylinders are performed to investigate the effects of size on the creep of cement paste cylinders. The effects of size are also evident in Figure 55 showing the compressive strength of 4" x 8" cement paste cylinders. The strength of 4" x 8" cylinders is approxi- mately 50%/ of the strength of 2" corresponding ages. x 4" cylinders at the The difference is explained partly on the basis of the strength of brittle materials. The creep behavior of 4" x 8" cylinders is shown in Figures 56 through 65. The stress-strain curves for time isoclines are shown in Figures 60 through 63. in The material is seen to behave a linear viscoelastic manner. the 4" x 8" The creep compliances for cylinders are presented in Figure 65. The comparison between the creep compliances of the 2" x 4" cylinders and the 4" x 8" cylinders is shown in Fig- ure 81. ders This figure shows that the creep of 2" x 4" is greater than the creep of 4" x 8" cylinders. cylinAl- though the trend is not entirely consistent as, evidenced by the behavior of the 3 days old specimens, the difference points to the tentative conclusion that cement paste creep decreases with increased specimen size. reported by Ali (82). -54- Similar trends are CHAPTER VIII. CONCLUSIONS Based on the discussions of the experimental data obtained in this study, the following are the major conclu- sions. 1. Several types of tests show that cement paste does not behave in an elastic manner. The tests include the creep test, under uniaxial dompression, the relaxation under uniaxial compression, and the creep flexure test performed on beams. 2. Under the following conditions and for the following tests, the mechanical response of cement paste is linear viscoelastic. The conditions for which linear viscoelastic behavior holds, are as follows: i. ii. iii. iv. one water/cement ratio equal to 1/3. the specimens are tested in the absence of shrinkage. This is achieved by testing under constant humidity conditions. the specimens are tested for ages 1, 3, 14, and 28 days only. the stresses and the levels used strains are within in this study. The testing modes for which linear viscoelasticity hold are: i. ii. iii. iv. uniaxial compressive creep on 2" cylinders. triaxial x 4" compressive creep such that uniaxial on 2" x creep flexure of 1 x compressive stress relaxation 4" cvlinders. 1 x 12" supported point loaded beams. simply 3. The mechanical linear viscoelastic response of cement paste obtained under the conditions and testing modes stated above can be represented functionally in such a manner that it is possible to achieve the interrelationship between the creep tests and relaxation tests in the Laplace domain. 4. The mechanical linear viscoelastic response of cement paste obtained under the conditions stated above can be used to perform a simple viscoelastic stress analysis of the deflections of a simply supported cement paste beam, loaded in creep. The accuracy of the analysis, when compared to the experimental data, is good. 5. The mechanical response of creep tests performed on larg- er cement paste cylinders, is linearly viscoelastic and is similar to the response obtained on 2" x 4" cylinders. The long range response of axial compressive creep, and axial compressive stress relaxation, and flexural creep is similar to the response obtained for shorter duration tests. -56- CHAPTER iX. RECO ETDATIONS FOR FURTHER WORK This dissertation slhows that cement paste behaves in a linearly visccelastic manner when subjected to different modes of loading. The work included in this thesis could be extended further. There exist several interesting possi- bilities that this extension could take. From a purely materials science point of view, the determination of the frequency domain viscoelastic response is very interesting. Such a determination can help define the creep mechanism of cement paste. The present work could also be extended by a more detailed study of the influence of the various variables involved. These include the water/cement ratio, speci- men size, environmental conditions, curing conditions, types of cements, etc. The influence of the triaxial loadings could be examined more closely. The tensile creep behavior of paste should be investigated. bilities The above mentioned possi- are mostly concerned with the materials character- istics per se. The present work could also be extended in of interest to the structural engineer. the direction This type of work differs from the previously mentioned areas. could take several of the following paths. The extensions The material could be modified by the inclusion of sand. The creep proper- ties could be calculated using the composite models, compared to the experimental data. This is towards the composite study of concrete. and then a step forward This idea could be examined further by studying the influence of aggregate on the creep properties of concrete, proach. using the composite ap- This particuar area shows the greatest promise as far as the ultimate goal of a rational design method for -57- creep. The composite model must then be modified to include the effects of reinforce ment. -58- FIGURE 1. TRIAXIAL CREEP CELL ~i- ssma~ 6 oit-let ta-nifold dra in o 1 lgh- prrassu~c. accjn,!1ator cp al Compre ssed lNitrogen Figj~ 2.Pn~Ttic~i~aIic Pressure System. , t.... ! , 'I . . . . j: t II .I...inted . . .: i :i l-: _,.. -: 1 : : '::' :'I : 1" '''|:I :: F T [I .. .7::' : : :1 lit Lii . :.. . : : :: " .;.:' i ' t "I " l'4 '.:". V : I i , ... . ..2 .. -L..I : - . tti I ' _:j - 1 *i t " 2& •~~I- .... i . .t , ' i : " .. ..... - .....:.. ... 6: " I ' _ ' i- .j; ii • .... r i - ' i :.,: i . ... -i : ... I . 1--i,---- ,-!' I-- t lr .: ; : i l:i ! :, .. ,....... i. ;. ,t ' i i ..... " ... . .... 1-I -. i "" ' i t I. . I : , .- ... . : i 4' ..... I-:, : ', -: -i :.i t i; ..--... - . .........---- ... : l ~ i ~~~i ,;. " - .. : .I ----- i I :-I FA1 " . ,i 1 j ! ''-I '.- . '... 1 j, '.... . '. I .. '.. , : i . .: + ...... .... i--i ! -!-.--f-.... i ... .... i.... .'. . -> ... .i....--- " 'I', I :i aiited saoecixment ! - D:1: | i ,. i - -: L- i-i - it ... - -- -- i ; I::I: ] - : l ' l, I l. :1 :: I_ I ' r ; - : en..s ~" : j.i ,.I. . ! JII . 1 -. 0 . peci ! ' .- j i_ I _ i . . r 1-71 II i... a t . .. i 1 - ' t.:.e , "- ".. .. ; ' .I ' _.i l I t , i i k . ..... i. . .. .. .. Iipoo i I I .. . .. . . : . . . .. .. . .. . i i i .. .. :.. :I j l ,. 'I ...."" : : "" J iI i lo ooo 1000 •(. rn I .: i ,, , i " , i .: ! .I i i " iiiI t :1 i . . , f 0J ... i..::... rTO00 ;: I I . V) -i~ ". 6000 ;L-, .. . ; " i. . . . , . . i.- :I-~- ! . : .... :I .... i ti . .i :; ; ..... . ' ". ! 1 i, . I . ,-- ~- ,: I_- , , ... ! " ".. ..... " . . .! ; . . . i . .. . . . .. ... i .. ii I oo 4 S5000 o t t., 4000 I. . ......... .. ......... ....... 1. .. °-i' . '. . .. . .- . i -t. . ;-t-. ^i( . . 1. . . . . . ...... -. . .. l . , ' I_. i . i _ . '..-I . ._1;. ! _.. " "i ' ' : : ! . . . ... .. .. . .. ... - .. .. . .- -- _ 1 i .. . ,. 2000 1000 0- . -- 1---- -- 20 00 Age, days Figure 4. Compressive Strength of Cement Paste as Fnction of Age i . ... . .. . . - -- 1 -~1~~~-s1---~--slll~-L-L-------~----~ 2 14 3 3400 1 - I ,, ., - .. ar, ) 1800-- ... .l 4-. 1400 -- - . . - 1000 2600 180 Figure 5. 0 .02- .04 .06 _. .08 0, z St rain -63- Stress-Strain Curmes for Cetent Paste, for fo-ir Ages. . .1 .1 20 I i.60 * .. I k K *. -- H ~IL42 * I 11' I j~ ~jt 'I .-II 9, 7~T' I7T777T"~ ii -4--- I ** 2.0 K K I ' -I It- ~I I If i-it I [7r7CL77Iij I::. I -4-.- *1 I. d--4-.4 -I-' LAO- ~***~ 4< LII ~Ii:7j 174 "<1 .iA2; I.,Ij 7 7F7'T 17FHHFF' .LHRIIL t±iiiti+:V+ I I. 'LLJ I 7171 I- KI ,. IliLI~iiK: l~...fK 7 - K 777 KLI III I I. .t'. 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I, I . .. . . 7O[ .. . .j i t i 0 1 '- ; - .r4 i ! , I t i , i f i .. ..... ...!_. - tT---i- ______________________________ 7•771 i 4)4 0C -P '4' 2. i I" 0 i ~-. ~:~ _.___. : i . ..... . -- - - --; i ......- i---... ......... ; .---.........: .... --- - - . - "1.. •- i -- i + i------ ",.....---!. ...---:..... . 4 ..- ..! 7 F , -- - ..r- .... :l' i . i i--- -;" i-.. . :.... + "i..... _... .... .. I ..- --.... ... ' . ..... -::- '" +~ : 20 ... r"- - .. . . .. -- ....--: ........ +- ! ( .. : _ _ , ..---- . ... ...I . ..i .. I--.---rI --- +. 0o 1 : 4 +... -- i--! ....... . -: -- " .J.. i : ... .+ +- -- . ...- Tim, a -71- m 'ate : " -" . t! -- - .... r----i. .. --- .. i_.l. . --.... i- - - 1........ ! ._-.i --....•.~i-- i. . . i ;1- - .. : I0 .. ... ;. .. - ..... ..... -_i-- ~.!..... " -i ! ...I 1--T--T! . F i !- !-I--- :r.- ;-:----- .. Li ! _:. .. .. .. I ........ - ,;, --- 7 +i 100 . '1 ! -- i : I !--- :+.. .. -i._ i -.. -:.. ... ... ' -. :i.. : 'j " ... _ l:--- . r ..... .. . .. . . .... i i i -+---- ,-..... ..... •1- -- : "... . ~ ~ 1 i ' i i i ..... ......... 401 i . • :I ii . .d : 1£0t4, I 1....... . - -- I --- -.- '--E- -- 4-1 c LW]i. I -T- -I-1-- 4 * -:-i -- 900 I . . -.. 4_i - - ---1~-~' --- .--.-- (l-I----- --- I- -- I- I '-I i:_._If --i r ~... C-4- K- -J..:-~ AA YN" 4 - i -- :-- jJ_- i ,..... -- 7 --T -. 4r -1 i TOO i ~~~~i1 I !i :1 i-: : 3-. i 4 --I'--j 1 • -_ .... -- i-I -d .. . -- ----. .. lr4 / 700 ZI W I- h---- (44J CI '.4 I . --.--- 1-.- • '__ --- K 1+/Ix / '-i---~-----'--' T-~7 -Ti ----------1------ -_ 7 I-- ' i-: i..: _ :Ir --: -!I •~~ -l --: - - t :-fi : 2: i-l-; ;;: i- -t; i-i: :-.:!::i: ... : : .( ' iolAt spinenj Ildey ---11 Ii * 400I0 - ,_ IOO 4 •, ] I ._. : - _. : . - ,- -1 :- ,. -- _--I b r - r:i .Jl--- T 300 II o -i --. . .dI . .4_._ . . . i I . .. . i I V ---I--I i ' - - . . . . - --- Hi I f I-. :i~~~ ~~: i i . - ! ... 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Stress-Strain for Time soclines - g -. - . ...... +- . . .01.x i .. ..... tI 100 c St r i /- ... -- . • . 0 --- -------- -- : .......... . .. . -...+. ..... i..02+ '... . . . .03.:. . . :+....... 04.... .. ... .:..... ..... ... .. ..r--. ...:...--. o + "r +~~~S T in +......:.. .. ..........:r...r. . -74- II __ _ _ 100 : ' CTj. : i-:---1" ; -__ :: - ::. " __: I _t A I 90( :::t. - ,I 8OC ___ _ __ ] i_._ l 4_ 7 1 -; . 700 . 12 ," ... . :- 1-. . : . 1-- :. 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L .I_I ^- --:" ;- ----+-- .I ... I- t !7 7 . Ci . .... . I. :.. I.-.. iI ...-: I.'I . . i i .--- . 01..- - - .-. ,.... iT I Z L - jY C-ll -t----l ~-i-'----i ~-.- ~ ..:.1.. ..-.i.~.~l..-.:.~:; ij I 3)'I I i. ulated -a- Fundtiotofi'ljm 0 ... .. i - ,. i * -".l-,-:*..:,--...- P:i :tV i 3-S IS .: ' . I:1- : . .. , - i--I - r - - i: i i , ~--+---": ' i t--,--I~ ,0 ::.r t: I i...-.... ....I--i-i-~t' -+e- " 'I-; - " k :!' : ::: ; I' I /1! ! /7 .---:! .- * :. . . , B aed--8t" .. . .. , 0 : iI:: I -: I--I- i ;I i: i I.I ., -I ii i: i i '' :i;'i i r: 1 n *r4 '' "?- - i " " :, :I'--.-. • - i -:--i---- I tI~I~.-j--,I-.,-i--,.. -----r---- )---~)--.-1 i : II i) I -( - t---i i---) --- 1----i---i-- i...- SII ! . . .. I r' ". -i ... . ... . . ..... ' -.......... .... ... .... .. i.... '..... ... : ... ...I~ . i-- ;- I' i...-... :..~ . .. j... :I • ' , .I~~:~1 ....i.... .... i...... . . . .. . ....: . ... .... . ',.. i I. ! . l • m.. .... i i . .- -- i -; - - ' ] "-l-,, . . -- " - - . . : ---I-- ! -".--. -" . -- ... t .. .. " -T. . .. I ' .. '' deyl old 6teetrens i .,i4 i.i .I 4 I i r ....! t i ' .. ........ -:i-.-:/ -.Ii ../ i t I : i i::I::.: i..:..~. :I:i :--1 :: 1 i 1 I ~ I1 ..._:....i .-. 1 1-I............ ,''' ~ . . 2 U "- h . 0 .. .. . . . . ........ ......... . . -= -4 = . _ . ... . . . t• S go ' EL . __ . - .= 4 - . . . . ... ... - - -.'- .-- .. . - ' . _._.... . . .. ... . . _,. . .. . " " , " i -;_ :... i.. t.i .-, ... IT _.. .-. -. - . --.. . .m. I_ = .a _. -" = " = .5.n~~~~ ..., . .. . " 'd" "on ' Beams '~ ~~~~ . . - : i. -:.... . . : . . - t ; tl -..... . -. .. . .. , :I.. .,.~~~ .... : , I = i.- - .! 7 - • i_: -e • : i , .i - .. , - • . : -i - . - I^ . t~ r l -- ---- -(- (- - s - - ~---'- -~-~~ 777F77, I~: ,-i :--.i-ll .-.- -~--- [1 : -~---- I . 4 4..-.. 1 I-i ~~~~ . f ivi " ' ..... .. .... i.. I iI i .....f i .I . ; :: I: (. : IVI::T SI tl! ~~ i • : 1oo r-4 ' 1. I i . . i : ' ' ! ' . . . . : | ..- . . . ... ." . . .... .... ...I1 i ! f !-. .i . . , . 2 . , . 0 I .1-i r4r ... j" _i21 - "i a 44 60 , ..- t----:l"7, /? I i i 4- ! , , ::-i .. I- 111 I : : o - ---- 1 .......-. I ,......... f~...~ .-.. - t--f---r--j -- i I • CL~-~-3 i .. . .. .. .. ,-- h . . Z.4 .I~...... I i -- " L- -i:l-i ----- --- :& .- -.- i I _.. [ II~- ...- i IJ IS . .]i . . I . .;. . . . ... i - lJ - ' ' -- - - -'I -L -=-b::. T • S ,i- ' ' " -t , -' I -I.- --- - . , * K--'-- -- --- - O 6- " ii ' Meaurld and alculated as P ncti 4,5 Timehourso .T 'L .. i i-- ' T C- . -- i Lss L .... oS .. ! .i "i ~j I -! Dr lac ! . ... .. i.. I s~p r i ~.i.,. n of Time ;Baae 'o -s on Beama o Z C S : : .!:: i i~~.: .o -- -:i ~... ~ !,::., : i ~ - .. . ;, . -, . . ~ ~ ... i'. . I L ..t- 1/ ' I ii: ..... 'j'i ° -- - p....-- .. t -3 .. !r:.. 1~.l. ii . I --- -T..--.... -- i ; ; c-7:~....,.i .. i... ~-... I : j II -~^c--1 ------- ? I I -- i : i I i i ----- : ---------------i 1 ' 1 -,--.. . __ . ' j1 1 : i -" -, .~ . W.d. al--....~-r,: |i ..- ...!-- .. .. Comp :-, --t - ...... -T . .. . . i" ... .... .. .. . .... i -- - j.- : I- i- - - -i - -- Ii ' .. I " ; ""_ i.r4 _ ~I 1 j2x . L m: , .. - ...... .. .. ... .. :,...... :I 35 . I i ... 4 ...... -- ,-.. .- ..... ... . . . - --, ..... --. - : - *- 4.0 I I ...... I '. ..... .... :.:...{ I ' " I tt 7-" 'H .... . .... .. i: i i: 04.5 j3 i -. ~,.-.I-cc,_-. i..- i._ : -I-: :I:: i LI i' t rt-I-c- :''i '' t _ic~rrr~-~1 i: i.... .. 1 . ;..,. I- 0 - ._I =-" i II : . . . . - ..-, I ... " : ..... i . ! .. ... r --.. .r-T -- - tt ... i ' : I '-4 "I nd, 4*8 Cylindes as Funiction 4.5 TifOt .. U~ I 4s Time, hourwo I. . . 75 75 of Ti4 atiFouriAgms ic-s las" i -/ 20 120 ~.__I II I __I__ ~II I ____llllIIIIll BIBLIOGRAPHY 1. Hatt, W.K., "Notes on Effect of Time Element in Load- ing Reinforced Concrete Beams," Proceedings, American Society for Testing Materials, V. 7, 1907. 2. Ferguson, A.M., "Fundamentals of Reinforced Concrete," John Wiley & Sons, New York., 1964. 3. Large, G.E., "Basic Reinforced Concrete Design-Elastic and Creep," Ronald Press, New York, 1960. 4. Neville, A.M., "Theories of Creep of Concrete," Journal, American Concrete Institute, V. 52, 1955. 5. "Symposium on Creep of Concrete," SP-9, American Concrete Institute, 1965. 6. Freudenthal, A.M., "The Inelastic Behavior of Engineering Materials and Structures," John Wiley & Sons, New York, 1950. 7. Freudenthal, A.M. and Roll, F., "Creep and Creep Recovery of Concrete under High Compressive Stress," Journal, American Concrete Institute, V. 54, 1958. 8. Grudemo, A., "The Microstructure of Hardened Cement Paste," Chemistry of Cement, Proceeding of the Fourth International Symposium, Washington, D.C., 1960. 9. Taylor, H.F.W., Editor, "The Chemistry of Cements," Academic Press, New York, 1964. 10. Freyssinet, E., "The Deformation of Concrete," Magazine of Concrete Research, London, V. 3, 1951. 11. Lynam, C.G., "Growth and Movement in Portland Cement Concrete," Oxford University Press, London, 1934. 12. Mullen, W.G. and Dolsch, W.L., "Creep of Portland Cement Paste," Proceedings, American Society for Testing Materials, V. 64, 1964. 13. Ali, I. and Kesler, C.E., "Symposium on Concrete Creep," American Concrete Institute, SP-9, -1965. 14. Bingham, E.C. and Reiner, M., "Rheological Properties of Cement-Mortar-Stone," Physics, No. 4, 1933. 15. Forshind, E. and Torroja, E., "Elasticity and Inelasticity of Building Materials," North Holland, Amsterdam, 1954. -140- __I__ ^_ ~___~________ I~----~IIYU*- IL~-XI~ -~-^~-^-^ ~s~--------------- il BIBLIOGRAPHY (Continued) 16. Paez, A. and Mason, P., "Elasticity and Inelasticity of Building Materials," North Holland, Amsterdam, 1954. 17. Ali, I. and Kesler, C.E., "Rheology of Concrete, Review of Research," University of Illinois, Engineering Experimental Station, Bulletin 476, 1965. 18. Tobolsky, A.V., "Stress Relaxation Studies of Viscoelastic Properties of Polymers," Rheology, M. Reiner, Editor, Academic Press, New York, 1956. 19. Flugge, W., "Mechanical Models in Plasticity and Their Use for Interpretation of Creep in Concrete," Report No. 8, Office of Naval Research, Stanford University, 1950. 20. Cowan, H.J., "Inelastic Deformation of Reinforced Concrete in Relation to Ultimate Strength," Engineering, London, 1952. 21. Hansen, T.C., "Creep and Stress Relaxation in Concrete," Swedish Cement and Concrete Research Institute, Stockholm, Report No. 31, 1960. 22. Gluckich, J. and Ishai, 0., "Further Study of the Rheological Behavior of Hardened Cement Paste," Journal, American Concrete Institute, V. 57, 1961. 23. American Concrete Institute, Building Code 1963. 24. Yu, W.W. and Winter, G., "Instantaneous and Long Time Deflections of Reinforced Concrete Beams under Working Loads," Journal, American Concrete Institute, V. 57, 1960. 25. "Deflections of Prestressed Concrete Members," American Concrete Institute, Report 60-72. 26. Dischinger, F., "Elastische und Plastische Verformung der Eisenbetontrabwerke," Bauingenieur 20, 1939. 27. Leonhardt, F., "Prestressed Concrete," W. Ernst & Sohn, Berline, 1964. 28. Bieger, K.W., "Prestressed Concrete," Indian Concrete Association, Sahu Cement, Bombay, 1963. 29. Corley, W.G. and Sozen, M.A., "Time-Dependent Deflections of Reinforced Concrete Beams," Journal, American Concrete Institute, V. 63, 1966. -141- ~~~---- -- 30. Bresler, B. -- ,I and Selna, L., "Analysis of Time Dependent Behavior of Reinforced Concrete Structures," American Concrete Institute, 1965. SP-9, 31. Washa, G.W. and Fluck, P.G., "Effects of Reinforcement on the Plastic Flow of Reinforced Concrete Beams," Journal, American Concrete Institute, V. 48, 1952. 32. Washa, G.W. and Fluck, P.G., "Plastic Flow of Reinforced Concrete Continuous Beams," Journal, American Concrete Institute, V. 52, 1955. 33. Finnie, I. and Heller, W., "Creep of Engineering Materials," McGraw Hill, New York, 1959. 34. Polivka, M. and Best, C.H., "Investigation of the Problems of Creep in Concrete by Dorn's Method," Department of Civil Engineering, University of California, Berkeley, 1960. 35. Tietz, T.E. and Dorn, J.E., "Creep of Copper at Intermediate Temperatures," Transactions, American Institute of Mechanical Engineers, V. 206, 1956. 36. Powers, T.C., "Physical Properties of Cement Paste," Chemistry of Cement, Proceedings of the Fourth International Symposium, Washington, D.C., 1960. 37. La Rue, H.A., "Modulus of Elasticity of Aggregates and its Effects on Concrete," American Society for Testing Materials, V. 46, 1946. 38. Dantu, P., "Etude des Contraintes dans les Milieux Heterogenes, Applications au beton," Annales de 1'Institut Technique du Batiment et des Travaux Publics, Paris, 1958. 39. Hirsch, T.J., "Modulus of Elasticity of Concrete Affected by Elastic Moduli of Cement Paste Matrix and Aggregate," Journal, American Concrete Institute, V. 59, 1962. 40. Kaplan, M.F., "Ultrasonic Pulse Velocity, Dynamic Modulus of Elasticity, Poisson's Ratio, and the Strength of Concrete Made with Thirteen Different Coarse Aggregates," RILEM, #1, 1959. 41. Kordina, K., "Experiments on the Influence of the Minerological Character of Aggregates in the Creep of Concrete," RILEM, #6, 1960. -142- _~~r~ss~ I _I ~__~_ BIBLIOGRAPHY _1 ___1 I (Continued) 42. Counto, U.J., "The Effects of Elastic Modulus of the Aggregate on the Elastic Modulus, Creep and Creep Recovery of Concrete," Magazine of Concrete Research, London, 1964. 43. Baker, A.L., "An Analysis of Deformation and Failure Characteristics of Concrete," Magazine of Concrete Research, London, 1959. 44. Reinius, E., "A Theory of the Deformation and Failure of Concrete," Betong, No. 1, 1955. 45. Pickett, G., "Effect of Aggregate on Shrinkage of Concrete and a Hypothesis Concerning Shrinkage," Journal, American Concrete Institute, V. 52, 1956. 46. Hsu, T. and Slate, F.O., "Tensile Bond Strength Between Aggregate and Cement Paste or Mortar," Journal, American Concrete Institute, V. 60, 1963. 47. Brunauer, S. and Copeland, L.E., "The Chemistry of Concrete," Scientific American 1964. 48. Hansen, T.C., "Theories of Multiphase Materials Applied to Concrete, Cement Mortar and Cement Paste," Swedish Cement and Concrete Research Institute Reprint 39, Stockholm, 1966. 49. Butcher, J.G., "Introductory Concepts of Combined Elasticity and Viscosity," Proceedings London Mathematical Society, V. 8, 1876. 50. Jeffreys, H., "On Plasticity and Creep in Solids," ceedings Royal Society, 1932. 51. Leaderman, H., "Elastic and Creep Properties of Filamentous Materials and Other High Polymers," Textile Foundation, Washington, D.C., 1943. 52. Alfrey, T., "Mechanical Behavior of High Polymers," terscience Publishers, New York, 1948. 53. Tobolsky, A.V., "Properties and Structure of Polymers," Joyn Wiley & Sons, New York, 1960. 54. Ferry, J.D., "Viscoelastic Properties of Polymers," John Wiley & Sons, New York, 1961. 55. Lee, E.H., "Stress Analysis in Viscoelastic Bodies, Quarterly of Applied Mechanics, V. -143- 13, 1955. Pro- In- I~_- I _~ _ _ III I I _ 56. "Solid Rocket Fuel Abstracts," cal Society. 57. Volterra, E., "On Elastic Continua with Hereditary Characteristics," Journal of Applied Mechanics, V. Published by the Chemi- 73. 58. Bland, D.R., "The Theory of Linear Viscoelasticity," Pergamon Press, New York, 1960. 59. Gross, B., "Mathematical Structure of the Theories of Viscoelasticity, Herman et Companie, Editeurs, Paris, 1953. 60. Lee, E.H., "Some Recent Developments in Linear Viscoelastic Stress Analysis," Eleventh International Congress of Applied Mechanics, Munich, 1964. 61. Alfrey, T., "Non Homogeneous Stresses in Viscoelastic Media," Quarterly of Applied Mechanics, #2, 1944. 62. Gurtin, M.E. and Sternerg, E., "On the Linear Theory of Viscoelasticity," Archives for Rational Meclhanics and Analysis, V. 11, 1962. 63. Breuer, S. and Onat, E.T., "On Uniqueness in Linear Vis- coelasticity," Quarterly of Applied Mechanics, V. 19, #4. 64. Churchill, R.V., "Operational Calculus," McGraw Hill, New York, 1958. 65. Schapery, R.A., "Approximate Methods of Transform Inversion for Viscoelastic Stress Analysis," Graduate Aeronautical Laboratories, California Institute of Technology, GALCIT 119, 1962. 66. Smith, E.B., "The Flow of Concrete Under Sustained Load," Proceedings, American Concrete Institute, V. 12, 1916. 67. Fuller, A.H. and More, C.C., "Time Tests of Concrete," Proceedings, American Concrete Institute, V. 12, 1916. 68. Williams, M.L., "Structural Analysis of Viscoelastic Materials," AIAA, Journal, 1964. 69. Lee, E.H. and Rogers, T.G., "On the Finite Deflection of a Viscoelastic Cantilever," Division of Applied Mechanics, Brown University, 1961. 70. American Society for Testing Materials, Standard C-150. 71. American Society for Testing Materials, Standard C-188458. 72. Brisbane, J.J., "Characterization of Linear Viscoelastic Materials," Rohm and Haas Company, 1963. -144- L~ -. I I -- ----- --- BIBLIOGRAPHY (Continued) 73. Hodgman, M.S., "Mathematical Tables from the Handbook of Chemistry and Physics," Chemical Publishers, Chicago, 1954. 74. Mandel, J., "Les Corps Viscoelastiques Boltzmanniens," Rheologica Acta, Band 1, No. 2-3, 1958. 75. Hildebrand, F.G., "Advanced Calculus for Applications," McGraw Hill, New York, 2nd Edition, 1958. 76. Cost, T.L. and Becker, E.B., "The Multidata Method of Approximate Laplace Transform Inversion," Rohm and Haas Company, Special Report S-51, 1965. 77. Hilton, H.H., "Analytical Determination of Generalized, Linear Viscoelastic Stress-Strain Relations from Uniaxial, Biaxial, and Triaxial Experimental Creep and Stress Relaxation Data," Aero-General Solid Rocket Plant, Sacramento, California, 1961. 78. Trost, H., "Spannungs-Dehnungs-Gesetz eines Viskoelastischen Festkorpers wie Beton und Folgerungen fur Stabtgwerke aus Stahlbeton und Spannbeton," Sonderdruch aus Beton, H. 6, 1966. 79. Neville, A.M. and Staunton, M.M. and Bonn, G.M., "A Study of the Relation between Creep and the Gain of Strength of Concrete," Civil Engineering Report, University of Alberta, Calgary, 1965. 80. L'Hermite, R.G., "Volume Changes of Concrete," Proceedings Fourth International Symposium on the Chemistry of Cement, Washington, 1960. 81. Hallaway, L.C., "The Creep and Elastic Properties of Concrete in Tension," M.S. Thesis, University of London, 82. 1965. Ali, J., "Creep in Concrete With and Without Exchange of Moisture With the Environment," Ph.D. Thesis, University of Illinois, 1964. -145- - ~ I __ APPENDIX A The chemical analysis of the cement used throughout this thesis is presented in Appendix A. The chemical analysis is provided through the courtesy of the Hercules Cement Company of Stockertown, Pennsylvania. A. 1. Chemical Silica (SiO ) . . . . Alumina (Al 0). . . Ferric Oxide(e2 03). Lime (CaO) 3.. . . . . .... . . . . . . . . ........ . . a 5.81% a 2.53% . 62.96% . 3.80% 2.48% . 0.99% a Magnesia (MgO) .... . Sulfur Trioxide (SO3). . Ignition Loss . . . . . . . . . . . . . . .. . . . . . . Potential Compounds Tricalcium Silicate (3CaO-SiO2). . Tricalcium Aluminate (3CaO-A12 03). . Dicalcium Silicate .. . ........ Tetracalcium Alumino Ferrite . . . CaSO 4 . ............... . 4 2. 20.12% . . . 54.00% . . . . 11.20% 16.80% . . 7.60% 4.30% . Physical Fineness, Specific Surface, Wagner Air Permeability, Blaine Soundness, Autoclave Expansion Time of Setting, Gillmore initial (Hr.: Min.) . ...... Final (Hr.:Min.) . . . . . . . . Compressive Strength, psi 1-Day. . . . . . . . . . . . . . 3-Day . . . . . . . . . . . . . 7-Day. .............. Air Entrainment, % by Vol ...... -146- . 1793 3209 0.32% . . . . . . . . a a . . . . . . . . . 3:20 5:30 1633 3158 4158 9. 800/0 _ I I ~L_ APPENDIX B. B-I. COMPUTER PROGRAMS Ramp transformation program for stress relaxation. -147- ~-- _ /JOB /FTC C C C C C C C C C 999 1 100 2 101 3 102 C 4 103 5 98 6 99 104 7 106 ~~ __ NEIEC 14610. TRANFORMATION DF STRESS RELAXATION FROM I<AMP 1C STEP S TRAIN COLLOCATION METHOD CNT=ASY,',PTTIC VALUE OF STRESS N=NUpbbR OF COLLOCATION POINTS SIlGrtiA(I)=STRESS FkiOM INSTRON ALPHA(I)=COEFFICIENTS OF EXPONENTIALS TNUT=LOADING TIME RATE=RATE CF CROSS HEAD DISPLACEMlENT J=IDENTIFICATION CODE IN TERMS OF AGE AT LOADING uIMENSIUN SIGM4A(50O)T(50),ALPHA(50),HCCOF(50),D(50,50) DIENSIGN A(50,50),FRS(50),F(50,50),FR(50) DI;MENSION COEF(50),DC0EF{50) READ(5, )J,N, M,CNTI, TNCT, RATE FORMAT(315,3F10.5) WRITE(6,1O0)J,N, M,CNOT,TNOT,RATE FORMAT (315,3FI0.5) READ(5,2)(SIGMkA(I),I=,N) FORMAT (7F10.5) WRITE(6,101)(SIGMA(I),I=1,N) FORMAT (7F10.5) RFAO (5,3) (T( I ), I=1,N) FORMAT (7F10.5) WvRITE(6,102) (TlI),I=1,N) FORMAT (7F10.5) CO2MPUTE CUEFFICIENTS DO 4 I=1,N ALPHA(I)=-1./(2.:T(I)-TNOT) WRITF(6,103) (ALPiA( I) ,I=1,N) FORMAT'COEFFICIENTS OF EXPONENTS.=',7FlO.4,//) DO 5 I=1,N D(I, 1)=SIGMA(I)-CNOT wRITE (6,98)D( ,1) FOR Al (IF.10.4) DV 6 I=1,M DU) 6 J=1,M A(I,J)=O.0 FRS(I)=-T(I)''ALPHA(J) CONTINUE DO 99 I=1,M wv ITEI(6,104) (A(I,J),JI1,M) FOR.MAT(7F10.5) CALL MATINV(A,M) 0DO 7 I=I,M WRITE(6,106)(A(I,J),J=1,M) FORCAT(4X,7F10.5) CALL NULTP(Ai),F,M ,M, M1,ISSUC,0) WRIT E(6,105) (F(i, 1), I=1,) 105 C 8 FO MAT(4X,'RAiP COEFFICIENTS.=*,iOE10.3,//) COQPUTE MODULUS COEFFICIENrS DC 8 I=1,N HCuEF()=F(I,1) 00 9 I=1,N -148- I INPUT I __ 9 10 107 C 108 /FTC C 1160 1170 10 11 1180 1190 1100 1110 /FTC C C C C C 1 2 COEF(I)=1iCOEF (I)E(XP(ALPHA(I)*TNOT)) DO 10 I=I,N DCOEF(I)=(COEF(! ) ALPHA(I))/(RATE (1.-_XP(ALPH(tI)'TNFT))) RIT E(6, 1E-F iO7) (0v; I I ),I=iN) F ORMkAT(4X, 'MODiULJS COEFFICIENTS.='t 7E. 3,//) CO!PUTE CCNSTANT VALUE OF MOCULUS D NUT=CNUITI/( TNOT''R ATE) FORMAT (4X,'CUN!STANT VALUE OF MODULUS.=', 1E10.3,//) GO TO 999 END MATRIX INVERSION BY PARTITIONING SUBROUTINE MATINV(A, N) DIMjENSION A(20,20),B (30),C(30) NN=N-1 A(I,i1)=1./A(1,1) DO 1110 M=1tNN K=M+I I)0 1160 T=,M 83(I)=0.0 00 1160 J=1,M 8(I)=B (I)+A ( I ,J)A (J ,K) R=0.0 00DO 1170 I=I,M R=R+A(K,I)*8(I) R=-R+A (K,K) IF (R-.O0001) 0, 10,11 R=.000001 CONTINUE A(K,K)=I./R DO 1180 I=1,M A (I,K)=-B(I)*A(K,K) DO 1190 J=1,M C(J)=O.O C(J)=C(J)+A(K,I )*A( I ,J) DO 1100 J=1,M A(K,J)=-C(J)*A(K,K) DO 1110 I=1,M 00 1110 J=1,M A (IJ )=A( I,J)--B(I)*A (K,J) R ETURN END A=MA'NA MATRIX = M BNB MATRIX C=PRODUCT MATRIX ISSUC=TEST FOR CONFORMABILITY IB=TEST FOR HOMOGEI4EOUS SYSTEM SUBROUT INE fMULTP(AB, C,MA,NA,M8B, NB, ISStU , I 8) DIM'ENSIO)N A(20,20) ,B(20,20),C(20,20 ), TEBAP (4030) IF(NA-M3) 1,2,1 ISSUC=2 WRITE (6,40) GO TO 35 ISSUC=1 -149- _ _~ __ _ _ IF( I B-0) 15, 5 15 00 10 I=i, MA DO 10 J=1, NB C( I, J )=0. 0D 10 K=I,NA 10 C(1,J)=C(l,J)+A(I ,K)* (K,J) GO TO 35 DO 30 J=INB DO 20 I=1,'-A TE!P(I )=0.0 DO 20 K=1,NA 20 TEMP(I)=T EP {)I +A(.I, K)* (KJ DO 30 I=1,MA B( I,J)=TEMP( I 30 CONTINUE 40 FORMAT ('MATRIC ES ARE NUT COMFORMABLE 35 RETURN END /ENO OF FILE 5 -150- ' ) ~ ~I I B-II. Collocation program for curve fitting. -151- II__ _~ ~ /JOB /FTC C C 6iC C C C C C 999 L 5 2 6 C 9 3 20 21 60 70 15 /FTC C ____ __________ 1- e610. NEMEC SERIES FITTING BY COLLOCATION ,==;UH ERFF CO iLL_iCA ION PO I N TS -(1 )=TI-iE AT CLLCATION P(.IINTS GA''A(I)=VISCJELASTIC RESPCNSE MAT INV=:MARI X iNVFrSION SUBRLUTINF AULTP=-"ATRIX 4ILTIPLICATIf'.N SUBROUTINE L=l RELAXATION DATA L=2 CREEP DATA IN TH F 1 NTFRVAL kETA(1)=COEFFICIENTS OF EXPONENTS CENTERE) SUN ( 1 ),RSU ( I L ) ,b t TA1 20) DI 1NSION T( 1I ) ,G(10),DELTA(10) OIMENSION FRS( 10),FR(10),GAMMA( 10),A(20,20,20),F(2 ,20) ,t)(20,20) RFAD(5,1)J,L,M, 1N, GAMNOT F]ORAAT(415, IF10. 5) WRITE( 6,5 )J ,L ,M ,N,GAMNOT FOkMAT(4I5,1FIO.5) REAC(5,2)(T(I), 1=1,N) FOi<MAT (7F10.5) R EAD(5,2 ) (GAMA ( I) ,I=1,N) WRITE(6,6)(GAMM4A(I),I=1,N) FORMAT (7F10.5) COMPUTE BETA D-i 9 I=1,N TA( I )=1./(2. T(I)) WR I T (6, ) (,F FA (I) , I=1, N) DO 13 I=1,M ' A ( I) --GAMNOT , 1) =G 3 ( iA FORXATi(LF1O.5) 00 20 J=, A(I,J)-= .O F .S(I) =) BETA(J) A(I,J) A( ,J) r-EXP(FRS I)) OiI INUE DO 21 I= I,M RITE(6,A6)(A(I,J) ,Jl,M) CALL MT.iNV(A,M) DO 60 I=1,M RITE(6 ,7J)(A(i 1,J) J= 1M) FU'MAT ( 7F 10.3 ) CAILL_ '"JITiP 1,D, F M,M M 1 ISSUC 0) (F(I, 1), I=1iiM) t,GAMNOT ,RITE ( ,15) FO[RJ-AT (4X,'CREEP FUNCTION COEFFS.=',1OF10.5,//) GO TO 999 END .IATRIX INVERSION BY PARTITIONING SUROUTINE IATINV(AN) DI-JCENSION A(20,20) ,B(30),C(30) NN=N-1 A(1,I1)= I./ A ( 1 , I) )Dj 1110 M=1,NN K= +1 .- 152- __ _ ~__ 116 1170 1180 1190 1100 1110 I DO B (I DO B( I 1160 I=1,M )=0.0 1160 J=1,M )=3( I )+A( I ,J) J,K) DO 1170 I=1,M R=R+A(K,I )* (I) A(K,K)=l./R O0 1180 I=1,M A(I ,K)=-B( I) *Af K,K) DO 1190 J=1,M C (J)=O.0 C(J)=C(J)+A(K,I )*A(I,J) no 1100 J=i,M A(K,J)=-C(J)*A(K,K) DO 1110 I=1,M DO 1110 J=1,M A( I,J)=A( I,J)(I )*A(K,J) RETURN END / FTC C C C C C A=MA*NA MATRIX B=MB'NB MATRIX C=PRODUCT MATRIX ISSUC=TEST FOR CUNFORMABILITY IB=TEST FOR HOl;i;GENEOUS SYSIEM SUBROUTINE MULT P(A,B,C,MA,NA, MB, NB, I SSUC, [13) DIMENSION A(20,20) , B (20,20) ,C(20,20 ),TEMP (400) IF(NA-R8)1,2,1 1 ISSUC=2 WRITE (6,40) GO TO 35 2 ISSUC=1 -0)15, 5,15 IF( 5 DO 10 I=1,4A DO 10 J=1,N3 CII,J)=O.O 00 10 K=1,NA 10 C(I,J)=C(I,J)+A(I,K)*B(K,J) GU TO 35 15 CONTINUE DO 30 J=1,NB DO 20 I=1,MA TEiP (I )=0.O DO 20 K=1, 1 NA 20 TEMP( I)=TE I) +A I, K)'1 (K,J) DO 30 I=1,MA B(I,J)=TEMP(I) 30 CONTINUE 40 FORcMAT ('MATRICES ARE NOT COMFORMAB LE') 35 RETURN END / END OF FILE -153- _r __ __ B-III. _ _______ _~__ _ Laplace transformation program for relaxation modulus, -154- creep compliance. ________ _ _ _ / JO B / FTC C C C C C C C C C C 999 100 104 101 105 102 106 103 107 7 8 2 108 109 98 3 9 20 11I _~_______ _ __ 14610. LAPLACE TRANSFJORMATIGN OF D.IRICHLET SERIES ANUT=CflNSTANT TE1[r' IN SERIES ALPHA(I)=COEFFICIENTS UF EXPF(NETIALS GAM<A( I)=CCFFICIENTS DIRICHLET ' SERIES P(I)=LAPLACE PARAiETERS NN=NULBER PF P PARAMEIERS CLAPL(I)=LPLACE TRANSFORA OF CREEP '1=1 CREEP M=2 RELAXATION ALAPL(I)=LAPLACE TRANSFORM OF MODULUS oDIMENSION ALPHA( 5,) ,GAMMA(50),P( I00),LAPL( 50),SL APL(50) 0I'bENSI-N PSU4'i (50),SUP(50) DI ENSION CLAPL)(50),ILAPL(50),OLAPL(53),EL APL (50) READ 5,1 C ) i, ,NN,ANOT FORMAT (315,1E10.5) ,RITE(6,104)N,M,NN,ANOT FORMAT (315,1E10.5) READ(5,i01)(ALPHA( ),T=l,N) FORMAT (7F10.5) W;ITE(6,105) (ALPHA(I),I=1,N) FORMAT (7F10.5) R EAo ( 5, 102 )(GA 'IMA ( 1) , =1 ,N) FOPMAT(7E10.5) WRITE (6,106) (GAMMA(I),I=1,N) FOR IMAT(7F10. 5) P(J ),J=INN) R EAD (5 ,103) FOr MiAT ( 7F 10.5) WRITE(6, 107) P( J ,J=1, NN) FOPfMAT (7F10.5) IF(M-2)3,7,7 J=I I=1 SUM(I)=GAMPA(I)/(P(J)+ALPHA(I)) DO 2 I=2,N PSU'k ( I )=GAMAA (I) / P( J )+ALPHA( I)) SJ (i )=SU ,( I-1)+PSUM( I) WRITF(6, I8)M,I, J , SUM(I ) PCtAT(3I5,4X,1-10.5) SIA PL ( J )= ANOT/P (J) MiLAPL( J )=DI APL( J )+SUM(N) Ir ,109) - IJ r LAPLI(J) DLAPL(J) ,(6 X, IE1O.5) FOR.MAT(3I15,4X,IE10.5, J=J+1 IF (J-NN)8,8,98 CONTINUE J=1 I=1 SU(I)=GAMA(I)/IP(J)+ALPHA(I)) 00 20 I=2,N PS I )=G A (I)/ I P( J )+ALPHA( I) ) S Ui (I )=SUM (I- 1) +PSUM( I) WRITE( 6, 1ll), I , J,SUNII) FORMAT(315,4X,1EI0.5) -155- ____ __ __ ___~_~__1~1__ 110 99 /END DLAPL(J)=ANOT/P (J) CLAPLIJ)=1./(,)LAPL(J)-SUM(N)) WKITE(6,11)MI,J,CLAPL(J) 0LAPL(J) E10.5) FORMAT (3I 5,4X,.lEO.5,4X, J =J +-1 IF (J-NN) 9,9,99 C ONT I NUE ENO CF FILE -156- I_ ~~_ B-IV. Inverse Laplace transformation program using Schapery's collocation. -157- _ ~ _ /JOB /FTC C C C C C C C C C C 999 i 99 2 101 100 102 3 109 C C 17 16 110 15 103 C 19 104 C 11 10 _~ _ __ NEMEC 14610. INVERSCELAPLACE TRANSFCRMATICN BY COLLOCATION FERMS IN SERIES iF 4=N=NU, -- -I'U 4R BETA(I)=COEFFICIENIS OF EXPLiNENT.S LLAST=ASSOCIATED ELASTIC SOLUTION SNCT=CONSTANT VALUE OF FIRST TERM GAiMMA (I)=OIRIPCHLET SERIES COEFFICIENTS P(I)=P PARAMETERS R ATIX OF COEFFICIENTS EVALUATED AT P-PA-RA'ET ~S KAPPA( I )=COLUtN F(UI,)=TIMF DEPENDENT STRESS RESPONSE iREAL TIIE EXPONENTS AS INPUT ETA(I)=l./P(J), KAPPA(23),BKAPPA(20) DIMENSION BETA(20),P(1C) ,GAMMA(20), DIMENS ION A(20 ,20) ,f(2C,20),KAPPA( IC ),FRS(50),F (20,20) DIi;ENSIGN PSUi(50), PKAPPA(50),ETA(2J) READ(5,1 )N,, SNOT,ELASTLCAD 5,3F10.5) F ,ORMAT(21 WRITE (6,99) N,M,SNOT, ELAST, LOAD FORMAT(215,3FI0.5) READ(5,2) (BETA(I),=1,N) FlRMAAT(7FIO.5) WRITE(6,101)(BETA(I),I=1,N) FO.YAT(4X,'EXPONENTS OF SERIES.=',7F10.5,//) A( ) ,I=l ,N) READ (5, 100)(GAG FO fr AT (7F 10.5) WRITE(6, 102) (GAMMA(I),I= ,N) FORMAT(4X,'COEFFICIENTS OF SERIES.=',7FIO.5,//) (ETA(I),I=1,N) READ(5,3) FORMAT ( 7E10.5) WRITE(6,109)(ETA(I),I=I,N) EX PNENTS.=',7El0.5,//) F tRAT(i r IE GENERATE P PARAMETERS GETNERATE PGAMMAIP) VECTOR DO 15 J=I,N I=l AKAPPA( I-1)=0.0 PSU; (I )=GAi>MM-A(I)/(ETA(J) +BETA(I)) I)+AKAPPA(I-1) AKAPPA(I)=PSU I=1+1 IF(I-N)17,17,16 ;R I T ( 6,11 ) ,AKAPPA (I) FOR:AT (H 5,4XiE 10.5) KAPPA (J )=(ETA (J)."AKAPPA ( I ))+SNT ) ELAST LOAD WRITE(6,103)I,J,BKAPPA(J) AT ( 15,4X ,I 10.5) FU WR ITE VECTOR IN COLUMN FORM DO 19 I=1,N (1, I)BKAPPA(I ) ;,R ITE{6, 104) (O( 1,1), I=1, N) FORAT ( 'P VECTOR.=' ,IEIO.5,// G. ,NERATE COEFFICIENT MATRIX I=1 DO 10 J=1,N A(I,J)=ETA(I)/tETA(I )+ETAJ)) I=I+L -158- TIMES I _II _I ~._~_.__1.___. _ __._.~___ ____ 12 13 105 C 14 106 C C 107 108 /FTC C 1160 1170 1180 1190 1100 1110 /FTC C C C C C . IF(I-N)11,t11,12 CONT INUE DO 13 I=1,M 00 13 J=l,M WR ITE(6, 105)( A( I, J ) ,J=l1 M) FOR AT(7F10. 5) CU IPUTE IfNVERSE OF COEFFICIENT MATRIX DC 14 I=IM WRITE(6,106)(A(I,J),J=1,M) FORViAT (4X, 7F10.5) COUiPUTE MATRIX PRODUCT CALL tULTP(A,D, F, M,M,M, ISSUC,O ) COniPUTE TIME UEPENDENT SOLUTION WRITE(6,107) (FI I, ),I= ,M) FORPAT(4X, 'REAL TINE COEFFICIENTS.=',I OFI0.3,//) WR IT E (6, 108) SNOT FURMAT(1F10.5) GO TO 999 END MATRIX INVERSION BY PARTITIONING SUBROUTINE iATINV(A ,N) DIMENSION A(20,20), B(30),C(30) NN=N-1 )=1./A(1,) A(,1 DO 1110 M=1,NN K =M + DO 1160 I=1,M B(I )=0.0 DO) 1160 J=I,M A( J,K) B(I)=B(I)+A(I,J) R=0.0 DO 1170 I=l,MA ) 3(I) R=R+AK,I R=-R+A(K,K) A(K,K)=I./R DO 1180 I=1,M A(I,K)=-8( I )A(KK) 0D 1190 J=1,M C(J)=O.0 C(J)=C(J)+A(K,I)-A( I ,J) DO 11CO J=1,M A(K,J)=-C(J)*A(K,K) DO 1110 I=1,M DO 1110 J=1,M A (KJ) A(I,J)=A( I,J)-B3 (I) RETURN END A=MA*NA MATRIX 8=1Bi*NB MATRIX C=PRODUCT MATRIX ISSUC=TEST FOR CONFORMABILITY IB=TEST FOR H&OMCGENEOUS SYSTEM SUBROUTINE MULTP(A,B,C,MA,NA,M3,NB, -159- ISSUC ,3) - ~1~11_ ~~~ _~_^~ I 2 10 15 20 30 40 35 /END DIMtENSION A(20, 20),(2C,20) ,C(20,20), TEMiP('40) IF (NA-MB ) 1,2, 1 ISSUjC=2 WRITE (6,40) GO TO 35 ISSUC=l IF( IB- )15,5,15 DO 10 J=1,NB C ( I,J)=O.0 DO 10 K=I,NA C ( I,J)=C( I ,J)+A( I ,K)*BI(K, J) GO TO 35 C ONT INUE DO 30 J=1,NB DO 20 I=1,MA TEMP(I)=0.0 DO 20 K=1,NA )+A( IK)B (K, J) TEMP( I)=TEPI( DO 30 I=1,MA B ( I, J )=TEMP(I) CONT INUE FORMAT ('MATRICES ARE NOT COMFORMABLE') RETURN END CF FILE -160- _ I~_~ ~ APPENDIX C Long Range Tests C-I. Long range creep tests. -161- ~- -~-----r---rs_~-- _I ~ _ _-_-_r~ ni -;r ~--P9D~ix -s- ----' I- ----~ - --r~-~---T 1 ' : I-dw ,. .. .. .. .. , ... .... : -,.-.-.. I; . + I + .... ,., . ... ... ...... I 1 I" I i-.. .. : ,i -. -1* :'i, I I n5-TT 7.1,*E T.____+ . .. .~...~ .: "4 ' ++ - 4 - . I-__ - __ ____ -- ;r--" ---;.. : .-:... " . :".-t I , + :.. ....! ., ..... .... i-i- L .. . . :I' +-- -+ .'. ."'... - ...... t-.-:' .- . .. .-- t-.. -i ' i; 71:171 . ... "............ ..... ' +-- I . ' -<- --- ...... . ... .. . -" ... . I -- *L-V-,.+-ti ,... -++-+ _. +,__,... .. .... ... ++__ .... :+ _+:+ i+ ~. ~~~~ iii .. ... +.... .. ... ,:,+++... ''+ ., .:.: t -- • " : . . ..+- -'+' -,+t " -:. ::i : , - •- -+ !- I ' i -_i: ! . .. : .. :: . "j " - ': ;I: .. . I£ .-~-i-r 7 "1- .i.~~ i K.. -I-- . -.. .. 1*: * WTI To : motaoung-SIV s I 17V iIp ( Ij r Fl 1 -- ' -- i .... ........ i-- ..._- I 1f77Ji iI _ 1 -t . . 1 i I:: i :-i _ _ t7;:7171:' _ _ _ _ _ _ ___ !:: i ii _ _ _ _ _ i r -T- IrP I .i - II o _ 1 44_rt r , It j-h It......i'fI:I.. _ _ _ l/:11i.. 4 ... .. i _ . ;i-, ------ P ____CII^_~~___I__II___ _~I~ ~~1_1__~__ _ C-II. ___ Long range stress relaxation tests. -164- 2 3 4 5 67891 2 3 4 5 67891 .... 3 4 q 5 4 5.A.. 6 7- 8 9 t-M .-.-- i ., . 1:.-:.471 T f ii :: . t: H i4:44~A .I-- i I T1_: IAi .44. 1? -------c----~---i---e-r-) : I 7 i: i! !i: i• 'il . f:---~-tfi~f:;t . 67 A a I 7" I -I----l-i-i--l-----+--C : 5 q A i -- "~"--" IZIITVV .r -~~rI! Io ~iu.l-r-- -i I:r] :;;--i 171 2 I. too A A 3 ... A l r-i-i I 9 V 7 't' , I ,, " ! ' . i i .. _. i : .. . . . :: I ' C ar4 5 4 T T h 3 2] j , L1L .. II 1 ___TI1~ 1 ,t 41 to 00 - 7- 7--.I _ it _ 9 68 7 5 !S ...... r .:3i.. ' ' - 4 3 ... *. . ,. I . . ljr . . . ... . L :t q''*:O "'' .... K m~" H ' '''' too100. Time, minutes loo. . sv.Qol"ai' 10041 ft 0 _ __~____. II _~ .__ C-III. .... Long range flexure creep tests. -167- - -- Ii 1:1~~~.: I. I ....... 1.... I T.~~t :4 ~~ i:...i.--. 'I 1 ~. 4 I.- irl:i i-.i ~L.jI i J~P61 ii t---l-- ---- ~ :: : i ' ~ i i i. j !.lfl- .1.1,. r ii ' ; i I Ii:i II t 1:1 i: 4... 4 I I LILL' '' '~l I IL +----j j; r' ' )''''~; ii j i I: -1 I ~----------ii .I <-1 ~---- 1 : t : Cln '.1' ~~~ ~~ ( ''W -- I .--.- *1* 4...-..-----.----- 7I .I -- ---4- - It j;:::/ - I: 2 7A- I ; :-+I.-:.I:+ : 1 : ~---f I? A I; tf 7 .! I -- T7 : I I. . . .1 1 11--tii . C 1,6a 1 61.....lixu e rr.4b 4-K II: . III t , 1, tt-On -0 Tim t PUn4 __ 4 -____ __ _ _ __ _ -- ~- l--------- t . . . . ..... ..- . ---- :---;-. I ..... i I'li..l..;. .---. -- - ---- ,.... . . ..... - i- . I .... . .i . . ----...- t , r -I..- • i r , i. .. I _:. , I -T, .. '~ .. j ...... , ...... I ... . , 4----~I~.. - ---- ' i , ;-_',- . ......... I .i . T-: . • . !-~ ;-; - . . I- t . 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