AN ABSTRACT OF THE THESIS OF Heeyong Park for the degree of Doctor of Philosophy in Mechanical Engineering presented on December 12. 1991. Title: A Study of Laser Generated Rayleigh and Lamb Waves in Graphite/Epoxy Composites. Abstract Approved : Redacted for Privacy Clarence A. Calder The application of laser generated ultrasonics was first demonstrated in the mid-seventies and has shown good potential when applied to isotropic materials. However, its use with composite materials is still in the early stages of development. This study explores the potential for application of laser generated Rayleigh and Lamb waves in graphite/epoxy composites. Numerical results are obtained by the solution of the wave equations using assumed solutions, and enforcing the boundary conditions. Experimentally, Rayleigh and Lamb waves were generated by a Q- switched ruby laser in the ablation regime and detected by piezo- electric pinducers which permitted accurate phase velocity measurements. The Rayleigh wave velocity was measured at various directions relative to the fiber direction and results were found to agree closely with numerical predictions. The increase of surface wave velocity using thin plates could be useful for the application of delamination detection in thick composites and an increase of Rayleigh wave attenuation could indicate damages caused by impact. waves can reflect from small surface cracks. Also, surface Therefore, laser generated surface waves, particularly along the fiber direction, have high potential for application in non-destructive testing. Lamb wave experiments were conducted in aluminum plates and gave distinctive signals, but there were some difficulties in detecting the precise arrival of each Lamb wave mode for the graphite/epoxy composite plates. A Study of Laser Generated Rayleigh and Lamb Waves in Graphite/Epoxy Composites. by Heeyong Park A THESIS submitted to Oregon State University in partial fulfillment of the requirement for the degree of Doctor of Philosophy Completed December 12, 1991 Commencement June 1992 APPROVED: Redacted for Privacy Associate Professor of Mechanical Engineering in charge of major Redacted for Privacy Head of Department of Mechanical Engineering Redacted for Privacy c Dean of Graduate 6 hool q Date thesis is presented December 12, 1991 Typed by researcher for Heeyong Park ACKNOWLEDGMENTS I would like to express my deepest gratitude to Professor C. A. Calder, for his academic guidance and financial support as my advisor and his encouragement like my father in Korea. I appreciate my thesis committee members, T. C. Kennedy, M. N. L. Narasimhan, E. Wolff, and Graduate Committe Representative, R. H. Cuenca, for their support and Wyle Labs in Edwards Air Force Base for graphite/epoxy specimens. Patience, support, and love of my wife ( Young-mee Park ) and my father ( Hae-chul Park ) are beyond description. like to share my Ph.D with my mother in heaven. Finally, I would TABLE OF CONTENTS 1. INTRODUCTION 1.1. General 1.2. Literature Review 1.2.1. Rayleigh Wave 1.2.2. Lamb Wave 1.3. Purpose of Study 2. BACKGROUND 2.1. The Potential of Laser-generated Ultrasound 2.2. Generation of Ultrasonic Waves by Laser Deposition 2.2.1. Absorption of Laser Energy 2.2.2. Thermoelastic Effects of the Surface 2.2.3. Ablation of the Surface 2.3. Michelson Interferometer 3. NUMERICAL SOLUTIONS FOR RAYLEIGH AND LAMB WAVES 3.1. Formulation of Equations for Rayleigh Waves 3.1.1. Wave Equation 3.1.2. Assumed Solutions for Rayleigh Waves 3.1.3. Secular Equation for Rayleigh Waves 3.1.4. Boundary-condition Determinant 3.2. Numerical Solutions of Rayleigh Waves 3.2.1. Numerical Procedure 3.2.2. Material Constants 3.2.3. Numerical Results 3.3. Formulation of Equations for Lamb Waves 3.3.1. Assumed Solutions for Lamb Waves 3.3.2. Secular Equation of Lamb Waves 3.3.3. Boundary-condition Determinant 3.4. Numerical Solutions of Lamb Waves 3.4.1. Numerical Procedure 3.4.2. Numerical Results 1 1 3 3 6 10 11 11 13 13 15 17 18 23 23 23 24 26 27 29 29 32 32 43 43 44 45 48 48 50 4. EXPERIMENTS 4.1. Experimental Arrangement 4.2. Preparation of Specimen 4.3. Experimental Procedure 4.4. Experimental Results and Discussion 4.4.1. Rayleigh Waves 4.4.2. Lamb Waves 5. CONCLUSIONS AND RECOMMENDATIONS 55 55 61 61 64 64 75 82 BIBLIOGRAPHY 84 APPENDIX A : PROGRAM FOR RAYLEIGH WAVES 93 APPENDIX B : PROGRAM FOR LAMB WAVES 101 111 APPENDIX C : COMPONENTS OF [Aii] APPENDIX D : EXPERIMENTAL WAVEFORMS AND FFT ANALYSIS OF RAYLEIGH WAVES 112 APPENDIX E : EXPERIMENTAL WAVEFORMS AND FFT ANALYSIS OF LAMB WAVES 117 LIST OF FIGURES Figure Page Thermoelastic effects of the surface at low laser power density. 17 2.2.2. Ablation of the surface at high laser power density. 18 2.3.1. Basic Michelson interferometer. 19 2.3.2. Sensitivity comparison of Michelson interferometer. 22 3.1.1. Coordinate system for the Rayleigh wave propagation. 25 3.2.1. Finding three roots of L3 from an eigen value plot. 30 3.2.2. Flow chart for numerical search procedure of 2.2.1. 3.2.3.A 3.2.3.B 3.2.4.A 3.2.4.B 3.2.4.0 3.2.4.D Rayleigh wave velocity. 31 Polar plot of Rayleigh and body wave phase velocities in the unidirectional graphite/epoxy composite. 34 Rayleigh and body wave phase velocities in the unidirectional graphite/epoxy composite as a function of the wave propagation direction. 34 Normalized X,Y, and Z displacements vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite (0 = 0° ). 36 Normalized X,Y, and Z displacements vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite ( 0 = 10° ). 36 Normalized X,Y, and Z displacements vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite (0 = 30° ). 37 Normalized X,Y, and Z displacements vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite (0 = 90° ). 37 3.2.5. 3.2.6. 3.2.7.A 3.2.7.B 3.2.7.0 3.2.7.D 3.3.1. 3.4.1. Angular deviation at the surface between Rayleigh wave propagation directions and horizontal displacement vectors given every 10°. 39 Change of horizontal displacement vector at every 0.02 wave length depth relative to the Rayleigh wave propagation direction. 40 Normalized X,Y, and Z stresses vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite ( 0 = 0° ). 41 Normalized X,Y, and Z stresses vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite ( 0 = 30° ). 41 Normalized X,Y, and Z stresses vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite ( 0 = 60° ). 42 Normalized X,Y, and Z stresses vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite ( 0 = 90° ). 42 Coordinate system for the Lamb wave propagation 43 Combined eigen value plot of [Aid] according to the L3 value. 49 Lamb waves propagation in the unidirectional graphite/epoxy composite plates ( 0 = 0° ). 51 Lamb waves propagation in the unidirectional graphite/epoxy composite plates ( 0 = 45° ). 51 Lamb waves propagation in the unidirectional graphite/epoxy composite plates ( 0 = 90° ). 53 3.4.3. Lamb waves propagation in the aluminum plate. 53 3.4.4. The Ao mode velocities by the change of wave propagation directions in the unidirectional graphite/epoxy composite plates. 54 3.4.2.A 3.4.2.B 3.4.2.0 3.4.5. 4.1.1. 4.1.2. 4.1.3. 4.3.1. 4.4.1. The So mode velocities by the change of wave propagation directions in the unidirectional graphite/epoxy composite plates. 54 Schematic diagram of experimental setup for the single pinducer technique. 56 Schematic diagram of experimental setup for dual pinducer technique. 57 Measurements of Rayleigh wave propagation time by the single and the dual pinducer techniques. 60 Layout of laser deposition tests for Rayleigh and Lamb waves generation. 62 Rayleigh waves in the unidirectional graphite/ epoxy composite as a pinducer moves from a line source (0 = 0° ). 4.4.2. 4.4.3. 4.4.4. 66 Rayleigh waves in the unidirectional graphite/ epoxy composite as a pinducer moves from a line source ( 0 = 90° ). 66 Relation between the laser energy and the pinducer output. 67 Attenuation of Rayleigh wave amplitudes in the graphite/epoxy composite 4.4.5. 4.4.6. 4.4.7.A when 0 = 0° & 90° ( laser energy = 205 mJ ). 70 Calculations and experiments of Rayleigh wave phase velocities in the unidirectional graphite/ epoxy composite and comparison with Rose's results [see reference 57]. 72 Comparison between the single and the dual pinducer techniques in Rayleigh wave velocity measurements. 74 Laser generated ultrasonic waves in an aluminum plate of 0.8 mm thickness. 76 4.4.7.B Frequency analysis of Fig. 4.4.7.A. 76 4.4.8.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness perpendicular to the fiber direction. 78 4.4.8.B Frequency analysis of Fig. 4.4.8.A. 4.4.9. Digital filtering analysis for Lamb wave signal of 78 Fig. 4.4.8.A i) Low pass filtering with a cut-off frequency of 0.7 MHz, ii) Band pass filtering between 0.7 and 1.7 MHz, iii) High pass filtering with a cut-off frequency of 1.7 MHz. 4.4.10. 79 Polar plot of surface wave phase velocities on the graphite/epoxy composite plates of thickness 0.87 & 16.25 mm. 80 LIST OF TABLES Table 3.2.1. Page Material constants of graphite/epoxy specimen with 60 % fiber volume fraction ( T300/5208 ). 32 4.2.1. Dimensions of graphite/epoxy plates ( T300/5208 ). 61 4.4.1. Attenuation calculation of a graphite/epoxy composite. 69 LIST OF APPENDIX FIGURES Figure D.1.A Page Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 0° ). 112 D.1.B Frequency analysis of Fig. D.1.A. 112 D.2.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 20° ). 113 D.2.B Frequency analysis of Fig. D.2.A. 113 D.3.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 50° ). 114 D.3.B Frequency analysis of Fig. D.3.A. 114 D.4.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 70° ). 115 D.4.B Frequency analysis of Fig. D.4.A. 115 D.5.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 90° ). 116 D.5.B Frequency analysis of Fig. D.S.A. 116 E.1.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 0° ). 117 E.1.13 Frequency analysis of Fig. E.1.A. 117 E.2.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 20° ). 118 E.2.B Frequency analysis of Fig. E.2.A. E.3.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite 118 plate of 0.87 mm thickness ( 0 = 40° ). 119 E.3.B Frequency analysis of Fig. E.3.A. 119 E.4.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 50° ). 120 E.4.B Frequency analysis of Fig. E.4.A. 120 E.5.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 60° ). 121 E.5.B Frequency analysis of Fig. E.S.A. 121 E.6.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 80° ). 122 E.6.B Frequency analysis of Fig. E.6.A. 122 E.7.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite E.7.B plate of 0.87 mm thickness ( 0 = 90° ). 123 Frequency analysis of Fig. E.7.A. 123 A STUDY OF LASER GENERATED RAYLEIGH AND LAMB WAVES IN GRAPHITE/EPDXY COMPOSITES CHAPTER 1 INTRODUCTION 1.1. General When the equations of motion for an infinite isotropic solid are solved, it is found that there are two types of elastic body waves that can propagate independently: 1) the longitudinal wave in which the particle motion is parallel to the direction of propagation and 2) the transverse wave in which the motion is perpendicular to the direction of propagation. If the medium occupies a half-space and has one free surface, then the solutions must satisfy the boundary condition that the surface stresses are zero. This condition can be used to find the reflection coefficients for body waves, but a solution exists that describes a wave confined to the near-surface. Waves of this type are referred to as Rayleigh waves. They propagate along the free surface and decay exponentially in the direction normal to the surface. In a plate, there are two surfaces at which traction-free boundary conditions must be satisfied. When the boundary conditions are imposed, the Rayleigh-Lamb equations relating the wave number, K ( = 27c/X, ), and the angular frequency co are obtained. 2 It is found that, for a given value of K, there is an infinite number of frequencies which satisfy the Rayleigh-Lamb equations. These correspond to different modes of Lamb waves. Ultrasonic waves including Rayleigh and Lamb waves have been one of the most powerful tools of NDE ( Non-Destructive Evaluation ) for isotropic materials. However, the attention of the NDE community has shifted toward composites because their very large strength-to-weight and stiffness-to-weight ratios are attractive for a wide range of applications, especially in the aerospace industry. Many of the NDE tools available for testing of isotropic materials have been applied to composites. Quite naturally, ultrasonic testing has been used for the NDE of composites with varying degrees of success. The major difficulty in case of composites arises from the fact that the theoretical analysis of wave propagation is considerably more difficult. For example, in an isotropic material, the wave propagation and energy propagation directions are the same: In an anisotropic material, however, they are quite different in general. The most popular tool of ultrasonic NDE has been the conventional piezoelectric transducer and the various, associated techniques have been developed. There are, however, limitations of piezoelectric transducers such as required physical contact, temperature limits, flat surface for coupling, etc. Therefore, NDE of composites by laser generated stress waves with detection using various interferometry techniques along with fiber optics is currently under active development. 3 1.2. Literature Review 1.2.1. Rayleigh Wave Lord Rayleigh established the basic properties of acoustic surface wave propagation along the surface of an elastic isotropic solid. He showed that the wave is non-dispersive, propagates at a velocity slightly less than the shear wave velocity, and that most of its energy is contained within a wave length of the surface [54]. It was realized during the 1950's that Rayleigh waves could be useful for nondestructive testing. Much of the early work in this field was carried out in Russia and Germany. Major contributions on the application of Rayleigh waves to NDT ( non-destructive testing were made by Victorov [73]. ) He pointed out that Rayleigh waves in the ultrasonic range could be used to detect the presence of flaws such as cracks and holes, near the surface of a sample. Also, he pointed out that the change in attenuation and velocity of Rayleigh waves could be used as an indication of the material state near the surface of a solid. An important problem of great interest in structural mechanics Surface cracks weaken is the determination of the size of a crack. a material and lead to its eventual fracture. If it is assumed that the Rayleigh wavelength is large compared to the size of the crack, then it is possible to develop quasi-static theories for Rayleigh wave scattering from a crack based on fracture mechanics theories. The basic Typically, surface cracks have a half-penny shape. quantitative theory to determine these effects for Rayleigh waves was 4 developed by Kino [40]. An NDT technique for larger cracks, which has been highly successful, was carried out by Silk [63]. He made use of the fact that a surface wave incident on a crack propagates along the surface of substrate, then along the surface of the crack, and radiates as a body wave from the tip of the crack. Detection of this body wave can be obtained on the top or bottom surfaces of the substrate, away from the crack. In either case, a good estimation of the crack depth can be made by measuring the extra time delays due to propagation of the wave along the length of the crack. In 1963 White demonstrated laser generation of acoustic waves in a solid [75]. The first models describing the phenomenon were one-dimensional [76,55,12,74], and assumed that the laser impact occupied the entire surface of the material. Since the laser generated ultrasound was received by means of narrow passband piezoelectric transducers, harmonic directivity patterns were initially used for describing the ultrasonic waves generated by a point laser impact [35,36]. Subsequently the use of broadband receivers such as capacitive sensors [21,62], thick piezoelectric discs [22], or laser interferometers [69,38,8] have made wideband modelling of laser generated acoustic displacements necessary. Laser generated ultrasound is now widely accepted as a versatile NDT technique in the laboratory, and is starting to find industrial applications [61,56,6,39,59,60,2]. Cooper, Dewhurst, and Palmer studied interaction of laser generated Rayleigh pulses with surface breaking slots in metal using a capacitance probe [20]. Surface 5 echoes reflected from the defect had two major components. The first arose from direct reflection of a Rayleigh pulse from the top of the defect, whereas the second arose from a shear pulse originating at the bottom of the defect which mode-converted to a Rayleigh pulse on reaching the metal's surface at the critical angle [23]. On the other hand, fiber optic sensor systems for ultrasonic NDT have been developed by many authors [24,25,9,17]. Fiber optic sensors have some advantages over conventional transducers and laser interferometers. For example, a flexible fiber can reach rather inaccessible surfaces and can be readily incorporated into a scanning system. Duffer, Burger, and Piper machined a slot on a steel specimen and used a dual channel fiber tip interfero- meter to detect the Rayleigh wave as it passed underneath each sensor [26]. Comparison of the frequency spectrum of the incident Rayleigh wave with that of the transmitted Rayleigh waves contained information about the depth of surface cracks. Recently, Huang and Achenbach employed a dual-probe interferometer to obtain accurate measurements of the surface wave forms on an aluminum plate with increasing degrees of surface roughness [33]. McKie et al designed and developed a dual-beam interferometer for the accurate measurement of surface wave velocity on an aluminum block [49] . A system of polarizing optical components was used in order to efficiently derive two beams from a single input laser beam. By accurate Rayleigh wave measurement, the degree of anisotropy of the test specimen could be obtained. 6 Development of laser-based ultrasonics for composites is now in the early stages. Addison, Jr., Ryden, and McKie made measurements of the angular diffraction pattern for longitudinal elastic waves from a laser generated thermoelastic source in both aluminum and a graphite/epoxy composite [1]. Tittman, Linebarger, and Addison, Jr. demonstrated a laser based transmission C-scan of a simulated ( 10 mm by 10 mm ) delamination in a graphite/epoxy composite [70]. 1.2.2. Lamb Wave The governing equations for Lamb waves were first derived by Professor Horace Lamb in 1917 in his famous work [44]. He formulated the problem using potentials and arrived at the wellknown Rayleigh-Lamb equation for wave propagation in isotropic plates. These equations were quite complicated and a solution could be obtained only in the short and long wavelength limits. The first comprehensive solution of Lamb waves was obtained by Mindlin [50] in 1950. Later, Viktorov dealt with the solution of Lamb waves in great detail [73]. He provided the dispersion curves for aluminum with a Poisson's ratio of 0.34. Solie and Auld investigated waves in anisotropic plates theoretically and compared the results to the uncoupled shear vertical and longitudinal modes [64]. Habeger, Mann, and Baum conducted a theoretical and experimental study of ultrasonic Lamb waves in machine-made 7 papers [30]. The papers were modeled as homogeneous orthotropic plates. The dispersion equation for Lamb wave propagation in the principal directions was developed analytically and verified experimentally. Moon used a variational method to obtain an approximate solution for Lamb wave propagation in laminated composite plates [51]. Sun and Tan derived an approximate solution based on Mind lin's plate theory [68]. Stiffler and Henneke obtained a low-frequency Lamb wave solution using elementary plate theory [67]. Mal developed a general theory, based on a matrix formulation, to solve the wave propagation problem in multi-layered composite laminates [46], and the results have been corroborated with experimental data by Mal and BarCohen [47,5]. There are many methods to generate and detect Lamb waves in composite materials. wave method. The most popular method is the leaky Lamb In this particular method, two transducers and a composite plate are immersed in a water tank. By varying the sending and receiving angles of the transducers, relative maxima corresponding to Lamb modes are detected when the Lamb wave energy leaks from the surfaces of the plate. By knowing the angles and the excitation frequencies, dispersion curves can be obtained experimentally. Worlton was the first one to confirm the theory of Lamb waves and determined the dispersion curves for aluminum and zirconium experimentally using this method [77]. Chimenti and Nayfeh verified their approximate solution for unidirectional 8 composite plates in the fiber direction by the detection of null zones that indicated the presence of leaky Lamb waves [19]. Bar-Cohen and Chimenti studied the application of leaky Lamb waves for NDT of composite laminates [4]. They observed a correlation between the character of the excited Lamb wave modes and the presence of certain defects such as porosity and delaminations. Martin and Chimenti refined this method by signal processing [48]. The results of the leaky Lamb wave method look promising, but the technique may not be particularly well suited for field inspection of composite laminates because the method requires the plates to be immersed in water. A simple method similar to the acousto-ultrasonic technique [72,32] has been studied by Stiff ler and Henneke to generate and detect Lamb waves in composite laminates [67,27,66]. The experi- mental data obtained by this simple method generally belong to the lowest symmetric and anti-symmetric Lamb modes. In this method, two piezoelectric transducers acoustically coupled to the plate by water-soluble couplant are directly in contact with the composite plate to create and receive Lamb waves. The Lamb wave speed can be determined by measuring the change in arrival time of a phase point on the receiving signal while moving the receiver a certain distance. Chapman used the same idea in the detection of debonding in fiberglass-reinforced plastic lap joints [18]. In a similar approach, Rose, Rokhlin, and Adler measured Lamb wave speeds with energy flux deviation in composite laminates [58]. 9 Liu generated Lamb modes and SH modes in a unidirectional graphite/aluminum composite plate by a shear wave transducer and used an electro-magnetic acoustic transducer ( EMAT ), which was not sensitive enough to detect the signals [45]. Wormley and Thompson, who used two EMATs as receivers, determined the wave speed by cross-correlation between the two receiving signals and thus evaluated the texture of rolled-metal plates [78]. Recently, laser-generated Lamb waves were studied by Hutchins and Lundgren [37]. The Lamb wave was propagated within thin materials ( aluminum and metallic glass samples ) and detected by Michelson interferometer. The thickness of the samples and their elastic constants were estimated with good accuracy. Burger et al generated Lamb waves in a thin aluminum plate by Nd:YAG laser and detected signals by a fiber optic system [10]. They demonstrated good agreement between experiment and finite element models. Aussel and Monchalin measured the dispersion of Rayleigh waves on thick and thin metallic substrates using laser-ultrasonics. In order to enhance the precision of the measurements, the signalto-noise ratio was increased by focusing the Rayleigh wave with an annular generating source [3]. Hutchins et al presented the ultrasonic inspection of composite panels, fabricated by attaching a thin layer of aluminum to a rigid foam substrate using an epoxy resin, and of aluminum composites consisting of aluminum sheets bonded together with an epoxy adhesive layer [34]. A ruby laser 10 beam was focused to a line source and the receiver was an EMAT for the detection of vertical displacements. They demonstrated that the presence of high frequencies serves as a test for disbond. 1.3. Purpose of Study To date, laser ultrasonics have been developed mainly for isotropic materials as given in the literature review. Recently, it has been used for applications in composite materials, which are highly anisotropic. The characteristics of laser generated stress waves including Rayleigh waves, Lamb waves, and body waves need to be fully explored and understood so that NDE of composite materials by laser systems will soon be possible. In this study the characteristics of laser generated Rayleigh waves and Lamb waves was studied for unidirectional graphite/epoxy composite plates. Graphite fibers with an epoxy matrix constitute one of the most popular composites. The velocity changes of Rayleigh and Lamb waves according to wave propagation direction was studied numerically and verified experimentally as far as possible. Also, the attenuation of Rayleigh waves and their dependence on wave propagation direction and on the distance between laser source and detection point was studied for future NDE applications using graphite/epoxy and similar composites. 11 CHAPTER 2 BACKGROUND 2.1. The Potential of Laser-generated Ultrasound By far the most commonly used method of generating and detecting ultrasound has been by piezoelectric transducer. Historically, piezoelectric crystals such as quartz were predominantly used as transducer materials. Many of the problems with piezoelectric generation and reception lie not in the transducer, but in the coupling which is necessary between transducer and specimen. The choice of couplant ( often an oil or grease ) and its method of application often tend to be an art rather than a science. Variability of couplant thickness and partial transmission and partial reflection of the ultrasonic energy in the couplant layer result in loss of sensitivity, change of waveform, unwanted resonances and time-of-flight measurement errors. The entire test structures are often immersed in a tank of water or coupling fluid. Although the couplant allows acoustical energy to propagate into the test material, it causes several problems in addition to potential harm to the material, particularly porous ceramics or polymer-based materials. There are additional problems and limitations of using piezoelectric transducers [60,61]. The laser generation of ultrasound can eliminate the need for any coupling between source and sample and overcomes all of these problems. 12 Calder and Wilcox showed the potential of laser-generated ultrasound through the following developments: 1) demonstration of the detection of an artificial flaw, a 1.5 mm diameter hole located midway across a 25 mm aluminum plate [13]; 2) the measurement of dilatational and mode-converted pulse arrivals in rods along with calculation of the elastic constants of many isotropic materials [14,15]; 3) the use of laser energy deposition and wave detection by Michelson interferometer to provide a unique method for the measurement of acoustic velocity in liquid metals [16]. They pointed out some distinct advantages of laser ultrasonics over the conventional transducers: 1) The laser loading produces a large stress pulse amplitude of short duration so that tests of highly attenuating or very thin materials are possible. 2) The short measurement time of a few microseconds or less can be made at a precise instant in time. 3) The noncontact feature is especially useful for testing in severe environments and with toxic materials. 4) There are few restrictions on specimen size and configuration. ( Laser beams can be focused to a point or a line by optical methods. ) 5) The specimen can be far removed from the instrumentation hardware. 13 The following sections will give the background of how ultrasonic waves are generated by laser deposition and detected by Michelson interferometer. 2.2. Generation of Ultrasonic Waves by Laser Deposition 2.2.1. Absorption of Laser Energy A pulsed laser emits bursts of coherent electro-magnetic radiation. When low intensity radiation ( 106 W/cm2) is incident on a metal surface, the combination of electric and magnetic fields generates currents in the conduction band near the surface of the material. Some of the incident energy is absorbed by resistive losses and converted into heat, while the remainder is re-radiated as a reflected pulse. Most of the absorption and reflection takes place very close to the surface, within what is called "skin depth" 8. At longer wavelengths in the infrared, the following classical expression for 5 can be used [7] S2 1 Eafligo (2.2.1) where a = conductivity of material g = relative permeability of material f = frequency of the incident radiation P.O = 4n x 10-7 H/m = permeability of free space. 14 For a Nd:YAG laser of wavelength 1.0611m in the near infrared, the skin depth is - 5 nm in aluminium. Again,using classical electromagnetic theory [7) the reflectivity of the material R can be calculated as the ratio of the reflected energy Er to the incident energy Ei i.e., R= Er 2-2t+t2 = (2.2.2) 2+2t+t2 where t = 1.10005 c = velocity of light. For a metal, t »1 for all frequencies up to visible light, so that reflectivity can be approximated as 4 R=1-T (2.2.3) . Therefore, the absorbed energy Ea is given by Ea = (1 R) = (2.2.4) For example, theoretical absorption ratio is 6% for aluminium. Thus in a low power regime where other effects can be neglected, the pulsed laser acts as a transient heat energy source at the surface. If the absorption of energy is assumed to occur so rapidly that thermal conductivity into the bulk of the material can be neglected, the deposition of energy Ea in a surface layer of area A and depth 8 causes a temperature rise sr given by AT = Ea spAS (2.2.5) 15 where s = specific thermal capacity of material P = density of material. Substituting Ea from eq (2.2.4) gives 4 AT = ilocpase (AJ (2.2.6) Therefore the temperature rise is proportional to the mean incident energy density. Over the timescales of typical laser pulses ( 10 ns to 100 ns ), there is, in fact, appreciable thermal conductivity into the bulk of most materials [55,76]. The main effects as regards the generation of ultrasound are that the volume of heated material increases as a function of time. 2.2.2. Thermoelastic Effects of the Surface The sudden rise in temperature of the surface layer by the absorption of thermal energy should be accompanied by thermal expansion. If the volume expands from v.M to V + AV, then AV = 3aVAT (2.2.7) where a = coefficient of linear expansion. Substituting for AT from eq (2.2.5) and for Ea from eq (2.2.4) gives AV = 3a sp E = a 3a sp (1-R) Ei (2.2.8) 16 Therefore, the absorption of laser energy causes thermoelastic strains equivalent to the sudden insertion of a volume AV of material immediately below the surface that is proportional to the incident energy Ei. Note that the magnitude of the increased volume is independent of both the beam area A and the thickness 8 at constant reflectivity R. If the source is situated deep in the material, it will appear to be a pure expansion and will generate only compressional waves in all direction. However, the close proximity of the actual source to the surface introduces some conversion of the compressional waves to shear waves [11]. As shown in Fig. 2.2.1.A, compressive dipolar stresses parallel to the surface are unchanged, and the boundary conditions require zero net stresses normal to the surface. However, since the heating occurs to the skin depth, the source is actually just below the surface so that a small normal stress can be produced. This thermoelastic source of ultrasound is different from a piezo-electric compressional transducer which principally generates a stress normal to the surface. For many applications it is adequate to treat the thermo- elastic source of ultrasound as a point or line source, provided sufficient beam focusing is employed. When the surface is constrained by oil layer, glass, plastic cover, etc. as shown in Fig. 2.2.1.B, the stress normal to the surface becomes dominant and is the cause of dramatic increase in the generation efficiency of longitudinal waves. 17 Incident Incident Laser Pulse Laser Pulse Skin Depth Constraining 5 - - el. Layer 40- -- -P. ik. Dipolar Surface Stress (A) Free Surface Normal stress due to Thermal Expansion (B) Constrained Surface Fig. 2.2.1 Thermoelastic effects of the surface at low laser power density. 2.2.3. Ablation of the Surface From eq (2.2.6.), the surface temperature increases linearly with incident energy or power density. As the optical power density is increased, whether by increasing the energy per pulse or by focusing a constant energy onto a small surface area using a converging lens, the temperature must rise until the melting point of the surface material is reached and ablation takes place from the surface. Once ablation occurs, some of the incident energy is dissipated as kinetic energy of the material vapor. During transient heat pulses of short duration, thermal equilibrium is not reached, so that the surface can become superheated for a short time above the 18 boiling point of the material. The detailed interactions among the laser pulse, plasma, and surface are beyond the scope of the present discussion [431. When the laser intensity is sufficient to cause ablation, the impulse force given to the surface by the vaporization of coating material or ablation of the surface itself produces a strong impulsive recoil force, by the transfer of momentum, as with a constrained surface in the thermoelastic region ( refer to Fig. 2.2.2 ). M Laser Pulse Momentum due to Surface Vaporization iii -> Dipolar Surface Stress due to Thermal Expansion Normal Stress due to Momentum Transfer Fig. 2.2.2 Ablation of the surface at high laser power density. 2.3. Michelson Interferometer As described in sec. 2.1, laser-generated ultrasound has great potential in NDE. Many types of interferometric techniques [28,651 19 can be useful for noncontact, remote sensing, optical detection. The Michelson interferometer shown in Fig. 2.3.1 is the basic one which has been widely used. The basic principle of fiber optic detection is also the same as that of the Michelson interferometer. Therefore, the following discussion on the principles of Michelson interferometry will also be useful for understanding other laser based interferometric methods. Fig. 2.3.1 shows a schematic for this interferometer. from a laser is divided by a beam splitter into two parts. Light One part goes through the beam splitter and strikes a movable reflecting surface at a distance Xi from the beam splitter. The other part of beam is reflected by the beam splitter to a fixed reference mirror located at a distance X2 from the beam splitter and is reflected back. Reference Mirror Specimen Beam Splitter Out of plane motion Detector (Photomultiplier Tube) Fig. 2.3.1 Basic Michelson interferometer. 20 The two beams are recombined at the beam splitter and travel Because these beams originate from the together to the detector. same coherent source, sharp interference fringes are produced at the detector which represent a measure of the difference in the Note that the optical path optical paths of the two beams [531. length changes twice as much as the out of plane motion of the For large displacements, it is necessary to count fringes since each fringe indicates an optical path difference of only specimen. X/2. For changes less than X/2 , a measure of the variation in the fringe intensity gives the change in position, since the fringe intensity varies sinusoidally as a function of optical path difference. For very small displacements, the interferometer can be stabilized on the most sensitive position of the sine wave resulting in an output that is nearly linear with displacement. The light intensity Lt measured at the detector of an interferometer is Lt = [ IC, Re exp { i (KX coot + 2KX1(t ) + 01(t ))} ± 4172 Re exp { i (KX coot + 2KX2(t ) + 02(t )) }]2 (2.3.1) where co. = 27cf. (fo = optical frquency ) = intensity of the object beam (i=1) or reference beam (i=2) K = 2rc / X = wave number cOi(t ) = noise fluctuations in object beam (i=1) or ref. beam (i=2). Since all the contributions to the signal from extraneous thermal or mechanical fluctuations are contained in 41(t) and (02(t ), X2 can be 21 considered constant and the variation of X1(t) from its equilibrium value ( X1(0)) is the variable of interest, e.g. AX, (t ) = X1(t) X1(0). Then, eq (2.3.1) can be written 2 1. 1 = L1 +L2 F O r T 2 cos ( 2KAX,(t ) + A4)(t ) +43 ) where octo = K [ Xi (0) (2.3.2) X2(0) l, 04) .-. 4)1(t ) _ 4)2(t ) = noise displacement. Obviously, 4) is a system parameter and can be adjusted to any convenient value, i.e. it / 2. Therefore, after removing electronically the constant term from eq (2.3.2), the signal is given by Ls = II7I72 sin ( 2KAXs(t )+ A4)(t )) (2.3.3) Fig. 2.3.2 shows the sensitivity change of interferometer. The sine function is most sensitive to changes in As when the argument is small ( or - nn ,where n = integer ). is directly proportional to AXs. Then, the measured intensity However, if 2ICAX2(t )+ A4)(t ) - it / 2 ( or (n + 1) 7E / 2 ), the interferometer is operating at its least sensitive position and relatively large changes in AXs cause little change in the observed intensity. Because, typically, 2KAXs(t ) « 1 and dA4)(t ) / dt « dAXs(t)/dt, the noise A4)(t) causes the signal to drift in and out of the most sensitive region. This noise results in low frequency shift of the output signal, which changes signal sensitivity and makes the system unstable. It is important to compensate for this noise to maintain the interferometer at its most sensitive position [6]. 22 Most Sensitive Case Least Sensitive Case 2 kAXs 2 IcAXs Optical Phase Fig. 2.3.2. Sensitivity comparison of Michelson interferometer. 23 CHAPTER 3 NUMERICAL SOLUTIONS FOR RAYLEIGH AND LAMB WAVES 3.1. Formulation of Equations for Rayleigh Waves 3.1.1. Wave Equation In a perfectly elastic, homogeneous, anisotropic medium without body forces and piezoelectric effects, the wave equation can be written by using the usual summation convention, a2 Ui P Tat a2 Uk corm axiax, (3.1.1) where Ui = displacement component along the Cartesian axes Xi to which the stiffness tensor Ciikm is referred P = density of the medium j, k, m = 1, 2, 3. Here, the epoxy matrix of the graphite/epoxy composite is assumed to be elastically isotropic and the fibers are assumed to be transversely isotropic. If fibers are distributed randomly in the matrix, then the graphite/epoxy can have hexagonal symmetry. Of course, this is not homogeneous in a microscopic point of view. However, if the wave length of the Rayleigh wave is large with respect to the diameter of fibers ( the diameter of the graphite fibers is about 5 lim), then the scattering by the individual fibers can be ignored and the graphite/epoxy composite can be treated as homogeneous and transversely isotropic. 24 If the medium is infinite in all directions, the simplest solutions of eq (3.1.1) are given by the real part of U = A exp[iK(LiXi with A = ii (xi vt)] (3.1.2) = 1, 2, 3), where ii is a unit vector along the Xi axis and K is a wave number. The phase velocity v of the wave is measured along the propagation vector K, whose direction cosines are given by the Li (K= ii). These homogeneous plane waves are called bulk waves. In general, there will be three distinct velocities of body wave propagation [421. The values of these velocities will depend on the 21 elastic constants of the material, and on the direction of propagation. 3.1.2. Assumed Solutions for Rayleigh Waves The coordinate system for the Rayleigh wave problem will use X3 as the outward normal to the traction-free surface of the medium as shown in Fig. 3.1.1. The axis X1 is chosen in the convenient direction, e.g. along the fiber direction. Solutions for Rayleigh waves are assumed to decay with depth below the surface and to be homogeneous plane waves whose displacements are independent of the distance perpendicular to the wave propagation direction. Therefore, the solutions are assumed to be linear combinations of terms in the form Ui = ai exp[iK(LiXi - vt )] = ai exp[iKL3X3] exp[iK(Li XI + L2X2 (3.1.3) vt )] 25 which satisfy the wave equation (3.1.1) and the traction-free surface condition. Conceptually, the term oci exp[iICL3X3] is regarded as the "amplitude" of the solution which varies in the X3 direction over the planes of constant phase. The planes of constant phase are taken to be perpendicular to the surface and to the propagation vector. The next term is taken as the wavelike properties. Thus, the propagation vector is always assumed to be parallel to the surface so that L1 and L2 are assumed to be real and can be initially defined. (outward normal to the surface) X3 (Z) Surface of material Fiber direction A .......... L1= COS° L2 = sine Plane of Constant Phase K Propagation Ve ctor Fig. 3.1.1. Coordinate system for the Rayleigh wave propagation. 26 The quantity 1,3 should be such that the amplitude of all the displacement components vanish as X3 ---> -00. In other words, L3 with a negative imaginary part can only satisfy the boundary condition of zero displacement at infinite depth. 3.1.3. Secular Equation for Rayleigh Waves The assumed solutions of the Rayleigh waves should satisfy the wave equation (3.1.1). Substituting eq (3.1.3) into eq (3.1.1), the following homogeneous set of equations are obtained: Ajk 8jk PV2 aj = 0 where Ajk = LiLinCijkm (i, j, k, m = 1, 2, 3). (3.1.4) Details are given in appendix C. In order to have nontrivial solutions, it is necessary that the determinant of the coefficients be zero, Ajk 8jk PV2 =0. (3.1.5) This secular equation can be regarded as a cubic equation in v2 with L3 as a parameter and the phase velocity v can be calculated from the eigenvalue of tensor A. Or the equation can be considered as a sextic equation in L3 with v as a parameter. For any specified value of v, any root L3 of eq (3.1.5) gives a solution of eq (3.1.3). In a general anisotropic material, there are three pairs of complex 27 conjugate roots in this equation for each value of v. If the wave is propagating on the plane of material symmetry, eq (3.1.5) becomes bicubic due to material symmetry. However, the roots L3 with negative imaginary part are taken to satisfy the boundary condition as discussed in the previous section 3.1.2. In case of isotropic materials, all roots lie on the imaginary axis of the complex plane. Therefore, three roots of I.z3 should be combined together for the assumed solution to eq (3.1.3) because they satisfy eq (3.1.5) and each term has the same phase velocity v. The assumed solution is 3 = ± Wn ap) exp[ iK(Li XI + L2X2 +L(3n)X3 vt)] (3.1.6) n=1 a.(n)= thee components of the eigenvector of eq (3.1.4) according to the root Ij3n) Wn = weighting factor. These three weighting factors Wn should be determined by the satisfaction of traction-free surface boundary conditions. 3.1.4. Boundary-condition Determinant The boundary conditions at the surface are given as follows. T3j = C3jkm auk axm = at X3 = 0 (j=1,2,3) (3.1.7) 28 Substituting eq (3.1.6) into the boundary conditions eq (3.1.7) and setting X = 0 and t = 0 in order to omit the constant term, 3 T3i C3 jkm Wn a(kn) i K 1(n11) (3.1.8) n =1 3 Ir ,c3Jkm 4,1) Om° Wni K =0 n=1 where L(in) = L1 and L2) = L2 for notation convenience. Therefore, three linear homogeneous equations from the surface traction-free boundary condition are given as follows. B. W. = 0 1.1 (i, j = 1, 2, 3) (3.1.9) where Bij = C3ikm ak In order to get a nontrivial solution, the determinant of the coefficient should be zero. IBij I =0 (3.1.10) It should be noted that the eigenvectors a(k) can be complex here. The latter determinant " Boundary-condition Determinant " is complex in general [291. 29 3.2. Numerical Solutions of Rayleigh Waves 3.2.1. Numerical Procedure As discussed in section 3.1.3., there are three pairs of complexconjugate roots to eq (3.1.5) for each assumed value of phase velocity in a general anisotropic material. These roots L3 should satisfy eq (3.1.4). In other words, one of the eigenvalues of [ , v (i, j = 1, 2, 3) should be equal to pv2 for any assumed value of v and propagation direction. But the correct eigenvalue can be found only when wave propagation direction is parallel or perpendicular to the fiber direction. Otherwise, the coupling of equations leads to calculation errors during L3 root finding resulting in incorrect eigenvalues. In order to get the correct eigenvalues and eigenvectors, a root search method other than direct root finding will be used. In Fig.3.2.1, only half of eigenvalue plot is given and [ Ai) has three eigenvalues for each negative imaginary value of L3. In the case of an isotropic material, two of three eigenvalues are equal, i.e., degenerated. Here, "limit eigenvalue" EL can be defined as the smallest eigenvalue at L3 = 0 and "limit velocity" VL can be given by EL. This means that the Rayleigh wave velocity VR is limited by 0 < V R < VL VL, (3.2.1) where VL = 4/TTP . Also, the limit velocity of an isotropic material is the shear velocity. For an assumed phase velocity v, there are three intersections between three eigenvalue plots and the "assumed eigenvalue" pv2 30 which is less than EL . Therefore, the root L3 can be found by a suitable search algorithm for each eigenvalue. Root Root Root Fig. 3.2.1. Finding three roots of L3 from an eigenvalue plot. The Rayleigh wave velocity can be found when the boundary condition determinant (BCD) is equal to zero as follows ( refer to Fig. 3.2.2.): 1) The search interval of the phase velocity should be carefully selected from a rough plot of BCD. Wide interval selection can result in an wrong value of phase velocity because of the abrupt change in the BCD value. 2) The interval is reduced until the specified tolerance is met. The tolerance should be small enough to make both the real and imaginary part value of the BCD close enough to zero. If the tolerance is not met, return to step 1 and select the other interval. 31 start ) .LIM111 Plot rough BCD value Reduce search interval by root finding algorithm BCD value is close enough to zero ? Yes Plot displacements Decay of displacements with depth? Yes Try Another? End Fig. 3.2.2. Flow chart for numerical search procedure of Rayleigh wave velocity. 32 3) After the velocity calculation, the displacement plot should be checked to make sure that displacements decay with depth. Otherwise, an incorrect velocity can be obtained. 3.2.2. Material constants Typical material constants of graphite/epoxy are given in Table 3.2.1 [52,41]. Only 5 material constants are needed for a transversely isotropic material and Tsai's index convention is used [71]. Table 3.2.1. Material constants for graphite/epoxy specimen with 60 % fiber volume fraction ( T300/5208 ). Density p 1.52 g / cm3 Poisson's ratio v 21 0.31 v23 0.54 E1 138.5 GPa E2 11.0 GPa G12 6.3 Young's modulus Shear modulus GPa 3.2.3. Numerical results For given material constants, the phase velocity of the Rayleigh wave can be calculated by the numerical procedure given in 33 section 3.2.1. Also, there are three body waves in anisotropic materials as discussed in section 3.1.1: one quasi-longitudinal wave ( QL ) and two quasi-transverse waves ( QT ), which can be calculated from eq (3.1.4). Note that these body waves generally do not have particle displacements which are purely parallel or perpendicular to the wave propagation direction. Therefore, the body waves of anisotropic materials are generally neither longitudinal nor transverse as those of isotropic materials [31]. If three velocities are different, eq (3.1.4) implies that the vibration directions corresponding to the three velocities are mutually perpendicular. In Fig. 3.2.3.A and B, the QL wave always shows the highest wave velocity. The QL wave is about four times faster than the QT wave when wave propagation is parallel to the fiber direction. This results from the high Young's modulus along the fiber direction. For wave propagation perpendicular to the fiber, the QL wave velocity approaches the value of the two QT wave velocities. As expected, Rayleigh wave velocity is below the limit velocity corresponding to the slowest body wave. Rayleigh wave velocity has its maximum 2.02 ( km/sec ) at 0 = 0°, and is continuously decreased to its minimum 1.44 ( km/sec ) at 0 = 90°. Displacements are given by the real part of the complex solution of eq (3.1.6). Note that the X axis is parallel to the fiber direction and the Z axis is outward normal to the surface in Fig. 3.1.1. The X and Y displacement solutions have only real parts and the Z displacement solution has only an imaginary part. This means that 34 10 Body wave QL, QT Rayleigh wave VELOCITY (KM/SEC), PARALLEL TO FIBER Fig. 3.2.3.A Polar plot of Rayleigh and body wave phase velocities in the unidirectional graphite/epoxy composite. 10 __ Body wave Rayleigh wave ------- ------------------------------------- _ .............r-a-na,-.., ---------------------------------------------- 10 20 30 40 50 60 70 80 90 ANGLE RELATIVE TO THE FIBER DIRCTION (DEGREE) Fig. 3.2.3.B Rayleigh and body wave phase velocities in the unidirectional graphite/epoxy composite as a function of the wave propagation direction. 35 the Z displacement is ic/2 phase shifted relative to the X and displacements. Y Therefore, for comparison with the X and Y displacements, the Z displacement is plotted with an imaginary part. From Fig. 3.2.4.A to 3.2.4.D, the right end of abscissa is the surface of material and the left end is the inside of the material. Note that the absolute value of the calculation has no importance, and X, Y, and Z displacements are normalized relative to the surface Z displacement. There is no Y displacement when 0 = 0° and no X displacement when 0 = 90°, because of material property symmetry. High stiffness of the fiber makes X displacement relatively small and almost zero at a depth lower than 0.1 wave length. The Y displacement direction changes between the surface and a depth of about 0.2 wave length. The Z displacement shows a maximum value essentially at the surface and disappears at a depth of about 5 wave lengths. From 0 = 30° to overall displacement patterns are similar and show only minor changes of amplitude. When 0 = 90°, the displacement pattern of a 90° , unidirectional graphite/epoxy is exactly the same as that of isotropic materials because the plane of wave propagation is transversely isotropic. Isotropic materials have no horizontal transverse displacement component of the Rayleigh wave. However, the unidirectional graphite/epoxy has a horizontal transverse displacement component and there is an angular deviation between the wave propagation direction and the horizontal displacement vector. When 0 = 30°, angular deviation at the surface is about 25.7° as shown in Fig. 3.2.5. 36 1.2 X disp. 00000 Y disp. Z disp. 0.8 0.6 0.4 0.2 0.2 5 4.5 4 3 3.5 2.5 2 1.5 1 0.5 0 DEPTH (Z) / WAVE LENGTH A) 0 = 0° 1.2 X disp. 00000 1 Y disp. Z disp. 0.8 0.6 0.4 0.2 0.2 5 4.5 4 3.5 3 2.5 2 1.5 1 0.5 0 DEPTH (Z) / WAVE LENGTH B ) 0 = 10° Fig. 3.2.4. Normalized X,Y, and Z displacements vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite 37 1.2 X disp. 00000 1 Y disp. Z disp. 0.8 0.8 0.4 0.2 0 0.2 5 4.5 4 3.5 3 2.5 1.5 2 1 0.5 0 DEPTH (Z) / WAVE LENGTH C ) 0 = 30° 1.2 1 0.8 0.6 0.4 0.2 0 0.2 5 4.5 4 3.5 3 2.5 2 1.5 1 0.5 0 DEPTH (Z) / WAVE LENGTH D) = 90° Fig. 3.2.4. Normalized X,Y, and Z displacements vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite 38 At increasing value of depth Z, this deviation becomes larger toward the Y axis and the X displacement approaches zero as shown in Fig. The high Young's modulus along the X axis minimizes the X 3.2.6. displacement inside the material resulting in the X displacement rapidly reducing to near zero at about 0.1 wave length depth. Stresses can be easily calculated using generalized Hooke's law given as T1 = Cijk, aDUk (i, j = 1, 2, 3) (3.2.2) The three normal stresses disappear at a depth of about three wave lengths. T11 ( ax ) is dominant when 0 = 0°, but T22 (6y ) is dominant when 0 = 90°. The stress plots shown in Fig. 3.2.7.A to 3.2.7.D were normalized relative to the surface T22 for comparison and T11 can be regarded as the average value assuming homogeneity of the graphite/ epoxy composite because the axial normal stress T11 of the fiber is much higher than that of the matrix at the same elongation. 39 2 Wave Propagation direction Displacement Unit Vector 1.8 1.6 E- 1.4 1.2 1 w a. 0.8 4.1 0.6 0.4 rn 0.2 0 0 0.5 1 1.5 2 0 DEGREE (FIBER DIRECTION) Fig. 3.2.5. Angular deviation at the surface between Rayleigh wave propagation directions and horizontal displacement vectors given every 10°. 40 L6 c:4 1.4 Displacement Unit Vector Wave Length 1.2 E1 0.8 a., 1:1- 0.6 44 0.4 A rn 0.2 0 0 0.5 1 15 0 DEGREE (FIBER DIRECTION) Fig. 3.2.6. Change of horizontal displacement vector at every 0.02 wave length depth relative to the Rayleigh wave propagation direction. 41 60 50 0 0 0 0 40 6Z 30 20 10 .; 0 -10 -5 -4.5 -4 -3.5 -3 31,, -2 -2.5 -1.5 711,111 -1 -0.5 0 DEPTH (Z) / WAVE LENGTH A ) 0 = 0° 16 14 12 0000 10 8 6 4 2 0 2 -5 -4.5 -4 -3.5 -3 -2.5 -2 -1.5 -0.5 0 DEPTH (Z) / WAVE LENGTH B ) 0 = 30° Fig. 3.2.7. Normalized X,Y, and Z stresses vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite 42 ax 3.5 a 0 0 0 0 aZ 2.5 1.5 0.5 ---------- -0.5 -5 -4 -4.5 -3.5 -3 -2 -2.5 -1.5 -1 -0.5 DEPTH (Z) / WAVE LENGTH C) 0 = 60° 1 ax 0.8 0 0 0 0 a aZ 0.6 0.4 0.2 0 -0.2 -5 -4.5 -4 -3.5 -3 -2.5 -2 -1.5 -1 -0.5 0 DEPTH (Z) / WAVE LENGTH D) 0 = 90° Fig. 3.2.7. Normalized X,Y, and Z stresses vs. depth plot for Rayleigh wave propagation in the unidirectional graphite/epoxy composite 43 3.3. Formulation of Equations for Lamb Waves 3.3.1. Assumed Solutions for Lamb Waves Lamb waves occur in relatively thin plates. The coordinate system for the Lamb wave problem here will be similar to that of the Rayleigh wave problem with X3 (Z) as the outward normal to the traction-free surface of the medium as shown in Fig. 3.3.1. X3 (Z) (outward normal to the surface) Fiber direction Ll = COS° L2 = sine N----11°' Plane of Constant Phase K Propagation Vector X Fig. 3.3.1 Coordinate system for the Lamb wave propagation. 44 The axis X1 (X) is chosen along the fiber direction and X2 (Y) perpendicular to the fiber direction. As before, the propagation vector H lies at 0 degrees from the X1 (X) axis. As with the Rayleigh wave solution, the solution for the Lamb wave is assumed to be linear combinations of the terms of the form U = A exp[iK(LiXi vt )] (3.3.1) which satisfy the wave equation (3.1.1) and the traction-free surface boundary conditions. The propagation vector is always assumed to be parallel to the surface ( L1 and L2 are assumed to be real and can be initially defined ). Displacements do not necessarily vanish at the bottom surface similar to Rayleigh waves in the semi-infinite domain and can have any amplitude as long as eq (3.1.1), eq (3.3.1), and the traction-free surface boundary conditions are satisfied. Therefore, the quantity L3 can have either a positive or negative imaginary part. 3.3.2. Secular Equation for Lamb Waves The assumed solutions of the Lamb wave should satisfy the wave equation (3.1.1). Substituting eq (3.3.1) into eq (3.1.1), the following equation is obtained as found previously ( eq.3.1.4 ), ( Ajk 8jk pv2 ) aj = 0 (3.3.2) 45 where Ajk =LiLmCiikm (i, j, k, m = 1, 2, 3). In order to have a nontrivial solution, it is necessary that the determinant of the coefficients be zero, I Aik 8jk pv2 I = 0 (3.3.3) . This secular equation is also the same as that of the Rayleigh wave. Therefore, six roots of L3 should be combined together for the assumed solution eq (3.3.1) because they satisfy eq (3.3.3) and each term has the same phase velocity v. The assumed solution is I 6 tii = wn 41) exp[ iK(Li Xi + 11X2 +II3n)X3 vt)] (3.3.4) n =1 where a.( `)= the components of the eigen vector of eq (3.3.2) according to the root L(3n) Wi, = weighting factor. These three weighting factors Wn should be determined by the satisfaction of traction-free surface boundary conditions. 3.3.3. Boundary-condition Determinant With the enforcement of boundary conditions, the solution procedure is similar to that for the Rayleigh wave. The boundary conditions at the top and bottom surfaces are given as follows. 46 auk ° (j = 1, 2, 3 ) (3.3.5) T3i = C3jkm axm = ° (j= 1,2,3) (3.3.6) T3j = C3jkm axm at X3 =0 auk at X3 = -h Substituting eq (3.3.4) into the boundary conditions eq (3.3.5) and setting X = 0 and t = 0 in order to omit the constant term, 6 E C3ikmwvvn ak T3i 1K (n) (3.3.7) n=1 6 E [C3jkm = Lm61) Wni K = 0 at X=0 &t=0 n =1 where Li = L1 and L2(n) = L2 for notation convenience . Again, substituting eq (3.3.4) into the boundary conditions eq (3.3.6) and setting X1 = 0 = X2 & t = 0 in order to omit the constant term, 6 E T3i = (n) (n) C3jkm %lc ak i KLm exp(-iKL3() h) (3.3.8) n =1 6 E [C3jkm okn) = exp(-iKLV h)] Wni K = 0 n=1 at X = (0,0,-h) & t= Therefore, six linear homogeneous equations from eq (3.3.7) and eq (3.3.8) result from the surface traction-free boundary conditions and are given as 47 Dij Wi = 0 ( j = 1, ..., 6) where Dm" = C3mki C1") 11") (3.3.9) for m = 1, 2, 3 Dnin = C3 6,1_3 )ki a(11,1) L(in) exp(-iK041) h) for m = 4, 5, 6 k, j = 1, 2, 3. In order to get a nontrivial solution, the determinant of the coefficients should be zero. I Dmn l =0 (3.3.10) The latter determinant is the "Boundary-condition Determinant" for Lamb wave propagation. 48 3.4. Numerical Solutions of Lamb Waves 3.4.1. Numerical procedure The search method for Lamb wave solutions is similar to that of the Rayleigh wave except for minor differences. Rayleigh wave velocity has an upper limit, i.e., limit velocity VL, and L3 can have negative imaginary values only. The Lamb wave velocity is not restricted by VI, and L3 can have a real or pure imaginary value depending on the assumed velocity. Therefore, a modified search method is used for evaluation of Lamb wave velocities. L3 is real for solid lines and is pure imaginary for dotted lines in Fig. 3.4.1. There are three intersections E1, E2, E3 of solid and dotted lines at L3 = 0. Four different search regions of L3 are divided as follows. Region I : 0 < pv2 < Ei Region II : El < pv2 < E2 , 4 imaginary roots & 2 real roots Region III : E2 < pv2 < E3 , 2 imaginary roots & 4 real roots Region IV : E3 < pv2 6 imaginary roots 6 real roots The numerical search procedure given in Fig. 3.2.2 can also be used for the Lamb wave velocity calculation, but the boundary value determinant of the Lamb wave is different from that of the Rayleigh wave and a modified search method of L3 should be used. Instead of checking decay of displacement with depth, the displacement pattern should be a symmetric or anti-symmetric mode as given in the next section. 49 X10-5 E3 E2 El Eigenvalues with imaginary L3 Eigenvalues with real L3 -1.5 1 0.5 0 0.5 1 15 L3 or L3/i Fig. 3.4.1. Combined eigen value plot of [Aid] according to the L3 value. 50 3.4.2. Numerical Results The Lamb wave has a different phase velocity depending on the propagation direction as with the Rayleigh wave but is dispersive unlike the Rayleigh wave. The phase velocity v of the Lamb wave is related to wave number K, wave length X, period T, and frequency co as follows: v= co K = 27r - X- = X, T 27c (3.4.1) T For a dispersive wave, the relationship between phase velocity and wave length X is nonlinear. There are an infinite number of solutions satisfying eq and eq (3.3.10) for the given values of plate thickness h and wave length X. They can be divided into two (3.3.3) groups as for Lamb waves in isotropic materials. When the vertical Z displacement is symmetric about the central plane of the plate, it is called the " symmetric mode". If the Z displacement is antisymmetrical about the central plane of the plate, it is called the "anti-symmetric mode" corresponding to flexural vibrations of the plate. First two symmetric modes So, S1 and anti-symmetric modes Ao, Al are given for the cases of 0 = 0°, 45°, 90°. When 0 = 0°, the Ao mode velocity is continuously increasing and approaches the Rayleigh wave velocity as ha increases as shown in Fig. 3.4.2.A. The So mode velocity approaches the QL wave velocity when the plate is very thin (11/A 0) and approaches the Rayleigh wave velocity as the plate becomes thicker. When 0 = 45° in Fig. 3.4.2.B, the So 51 10 - 9 SYMMETRIC MODE ANTISYM. MODE 8 7 6 2 5 4 O 3 2 1 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 1.8 2 PLATE THICKNESS ( h ) / WAVE LENGTH A) 0 = 0° 7 SYMMETRIC MODE 6 ANTISYM. MODE 5 4 3 2 1 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 PLATE THICKNESS ( h ) / WAVE LENGTH B) 0 = 45° Fig.3.4.2. Lamb waves propagation in the unidirectional graphite/epoxy composite plates 52 mode velocity has reduced significantly compared with Fig. 3.4.2.A The Al mode velocity of a very thin ( hA - 0) plate approaches the QL wave instead of the So mode velocity. . When 9 = 90°, Ao and So modes in Fig. 3.4.2.0 show the same dispersion pattern as those for an isotropic material as given in Fig. 3.4.3. This reflects that the wave propagation plane is transversely isotropic as expected. As the thickness of the plate increases, the velocities of Ao and So modes of every plot converge to the Rayleigh wave velocity. As hA increases, Al and S1 mode velocities approach the QT wave velocity. When the plate is thick enough, the Rayleigh wave on one surface can be regarded as a linear combination of Ao and So modes, and vise versa in isotropic plates [73]. The same interpretation can be applied to the composite plate. The Ao mode velocities are continuously increasing and reach 90% of the Rayleigh wave velocity at h/2t, 0.5 regardless of the wave propagation direction as shown in Fig. 3.4.4. The So mode velocities for a very thin plate ( hA < 0.4 ) are close, but show a large rise very close to the fiber direction ( 0° 5 9 < 10 °) in Fig. 3.4.5. 53 3 SYMMETRIC MODE ------- ANTISYM. MODE 2.5 SI 2 So 1.5 1 0.5 0 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 PLATE THICKNESS ( h ) / WAVE LENGTH C) 0 = 900 Fig.3.4.2. Lamb waves propagation in the unidirectional graphite/epoxy composite plates PLATE THICKNESS ( h ) / WAVE LENGTH Fig. 3.4.3. Lamb waves propagation in the aluminum plate. 54 PLATE THICKNESS ( h ) / WAVE LENGTH Fig. 3.4.4. The Ao mode velocities by the change of wave propagation directions in the unidirectional graphite/epoxy composite plates. 10 0=0° 0000 8 =45° 8 =90° 3 2 ---------- ------------ ------------------------------------------ 1 oo 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 PLATE THICKNESS (h)/ WAVE LENGTH Fig. 3.4.5. The S0 mode velocities by the change of wave propagation directions in the unidirectional graphite/epoxy composite plates. 55 CHAPTER 4 EXPERIMENTS 4.1. Experimental Arrangement Schematic diagrams of the experimental setup for single and dual sensors are shown in Fig. 4.1.1 and Fig. 4.1.2, respectively. Velocity measurements using these two methods will be compared in section 4.4. The experiments were conducted using a laser ultrasonic wave generation system, wave detection sensors ( piezoelectric pin transducers ), and a high-speed digital data acquisition system. The ultrasonic wave generation system consists of a ruby laser with its remote control unit. The ruby laser produces a light pulse with a wave length of 0.694 gm, a pulse duration of about 30 nsec, a maximum energy of 1.2 J, and a beam diameter of about 11 mm. It is operated in a Q-switched mode in order to generate a strong single impulse onto the specimen. The remote control unit, which can provide a trigger signal to the digital oscilloscope, is used to set the laser power level and control the pockel cell operation. The digital oscilloscope can be triggered accurately by a PMT ( Photomultiplier tube ) as shown in Fig. 4.1.1. This optical triggering method can eliminate most significant triggering time errors except for PMT risetime and the light flight time by the optical path difference from the ruby laser to the PMT and a specimen surface. For example, an optical path of 0.5 m produces only a 1.5 nsec time 56 ENERGY METER \ SPECIMEN FOCUSING CYLINDRICAL LENS BEAM SPLITTER Q - SWITCHED RUBY LASER 7 REMOTE CONTROL PMT UNIT J L ULTRASONIC WAVE GENERATION SYSTEM WAVE DETECTION SENSOR ( PIN TRANSDUCER ) TRIGGER SIGNAL CH.1 1 PRINTER PLOTTER IBM PC TEK 2342A GURU SOFTWARE DIGITAL FFT PROGRAM OSCILLOSCOPE L HIGH SPEED DIGITAL DATA ACQUISITION SYSTEM Fig.4.1.1. Schematic diagram of experimental setup for the single pinducer technique. 57 ENERGY METER FOCUSING CYLINDRICAL LENS / Q-SWITCHED RUBY LASER SPECIMEN BEAM SPLITTER r 1 REMOTE CONTROL UNIT ULTRASONIC WAVE GENERATION SYSTEM WAVE DETECTION SENSORS (DUAL PIN TRANSDUCERS) TRIGGER SIGNAL CH.1 CH.2 r PRINTER PLOTTER IBM PC TEK 2342A GURU SOFTWARE DIGITAL FFT PROGRAM OSCILLOSCOPE HIGH SPEED DIGITAL DATA ACQUISITION SYSTEM Fig. 4.1.2. Schematic diagram of experimental setup for dual pinducer technique. 58 difference) [13]. On the other hand, the triggering time delay is not important in Fig. 4.1.2 because only the time delay between dual pinducers is measured. Wave detection is provided by pinducers ( piezo-electric pin transducers ) which have broad band response. The outer diameter of a pinducer is about 2.4 mm and the inner-core of the piezoelectric material is 1.4 mm diameter. Note that the pinducers are used instead of a Michelson interferometer or a fiber optic detection system which usually require a good reflective surface for high signal-to-noise response. Metal surfaces are often quite reflective and can be polished easily. On the other hand, graphite/epoxy composites are poorly reflective and highly diffusive. A thin mirror may be attached to the surface of the composite to provide a reflective surface. Preliminary studies show that when a thin, small mirror is attached on a large mirror, the shape of a Rayleigh wave on the thin mirror is the same as that on a large mirror with a small additional time delay due to the attached mirror thickness. However, if a mirror is glued on a graphite/epoxy composite, the transmitted Rayleigh wave shape on the attached mirror is somewhat different from that on the composite surface. Because of this, the piezoelectric pinducers have been chosen over laser interferometry for use with graphite/epoxy composites. The pinducer does require couplant as with conventional piezoelectric transducers. However, the small diameter of the pinducer minimizes the possible variability of couplant thickness 59 and problems associated with surface roughness as long as the pinducer is positioned perpendicular to the surface. Tests show that good signals can be obtained just by touching contact to the surface. Even an intentionally slight gap ( 0.1-0.3 mm ) between the pinducer and the surface results in only a small attenuation of wave signals where couplant is used. With the single pinducer approach, wave propagation time can be measured from the PMT trigger signal in channel 2 to the slight initial rise of the Rayleigh wave as shown in Fig. 4.1.3. When the dual pinducer technique is used, direct measurements of pinducer distance and time interval between peak to peak signals are straightforward with each signal stored in channel 1 and 2. The time interval can be directly measured by using a curser on the digital oscilloscope. It is possible that the Rayleigh wave can be affected by the presence of the pinducer and couplant. This contact problem can be minimized by using a laser induced line source and just the touching contact to the surface without further pressure. A train of Rayleigh waves induced by a line source produces a stronger signal than a point source and should minimize possible perturbations produced by the front pinducer. A graphite/ epoxy composite is very attenuative and attenuation from the same source is expected to be measured accurately by the dual pinducer technique. The high speed digital data acquisition system consists of a digital oscilloscope ( Tektronix 2342A ) which can store 1024 digital 60 Wave propagation time Channel 1 Channel 2 (PMT trigger) A) EXPERIMENT WITH A PIN TRANSDUCER Channel 1 (PIN #1) Channel 2 ---,le-A-1 (PIN #2) Wave propagation time B) EXPERIMENT WITH DUAL PIN TRANSDUCERS Fig. 4.1.3. Measurements of Rayleigh wave propagation time by the single and the dual pinducer techniques. 61 data points, and an IBM computer with digital interface software ( GURU ) and an FFT ( Fast Fourier Transform ) spectrum analysis program. 4.2. Preparation of Specimen Four unidirectional graphite/epoxy composite plates with 60% fiber volume fraction were cured and fabricated by Wyle Labs at Edwards Air Force Base as given in the following table: Table 4.2.1. Dimensions of graphite/epoxy plates ( T300/5208 ). Plate No. Length (inch) Width (inch) 1 6 6 0.034 (0.87 mm) 2 6 6 0.067 (1.7 mm) 3 6 6 0.128 (3.25 mm) 4 6 6 0.6395 (16.25 mm) Thickness (inch) 4.3. Experimental Procedure The experimental setups were essentially the same for Rayleigh wave and Lamb wave measurements. Plate no. 4 was very thick compared to the others and was regarded as approaching a semi-infinite specimen relative to the induced surface wave length. Therefore, the velocity and attenuation measurements of Rayleigh 62 waves were conducted on plate no. 4. The other three plates were thin enough to use for Lamb wave measurements. One edge of each plate was held tight by a table vise and other edges were free of constraints. Surfaces of plates were free of stress. Any low frequency, flexural plate vibrations initiated by the laser deposition would have much slower velocities than the induced ultrasonic waves. Each measurement was completed before the arrival of any flexural vibration of the plate. Therefore, the one-edge-fixture seems to be convenient and sufficient for this experiment. As shown in Fig. 4.3.1, the plate was rotated with 10 degree increments for each laser deposition test. Line sources by focusing laser beam Pinducer distance = 20 60 mm Spacing = 10 - 20 mm 76 mm / 0 50° 10 increments 47 mm 60 mm Fiber direction Fig. 4.3.1. Layout of laser deposition tests for Rayleigh and Lamb waves generation ( 150 mm by 150 mm ). 63 Test Procedure (refer to Fig. 4.1.1. and Fig. 4.1.2.) 1) The ruby laser was set to generate maximum energy resulting in maximum wave amplitude. Because the S/N ratio ( Signal-to-Noise ratio ) was very low in the thermoelastic regime, every experiment was conducted in the ablation regime. 2) An energy meter, set perpendicular to the laser beam path, received about 17 % of the laser energy as reflected by a plane glass plate placed 45° at to the laser beam path. Most experiments were monitored by an energy meter to compare data at same energy level. 3) The laser beam was focused to a line of about 0.5 mm width and 15 mm length using a cylindrical lens. The focusing width controls the power density of the laser beam and the corresponding induced wave amplitude, but does not influence the measurement accuracy of the wave propagation time. 4) The pinducers were positioned perpendicular to and just touching the specimen surface without further pressure. Each pinducer was held in position by a bracket attached to a strong magnetic base. The distance from the line source to a pinducer center or the spacing distance of the dual pinducers was measured accurately using a micrometer. 64 5) At least 3 minutes of shot interval time was used between laser firing to maintain stability of output. 6) The digital oscilloscope was triggered by a signal from the remote control unit of the laser power supply or from the PMT output. The first arrival of the wave was recorded on channel 1 and the second arrival or the PMT signal on channel 2 of the digital oscilloscope. Wave propagation time was measured accurately on the oscilloscope screen by using the vertical time cursers and wave amplitudes by using the horizontal voltage cursers. The corresponding wave propagation velocity and attenuation coefficient were then calculated. 7) The digital signal was transferred from the oscilloscope to an IBM PC computer using GURU software. FFT spectrum analysis and digital filtering were then performed. Hard copies of the wave signals were made on a laser printer. 4.4. Experimental Results and Discussion 4.4.1. Rayleigh Waves As discussed in section 4.1, dual pinducers were expected to be accurate for wave velocity and attenuation measurements because many measurements could be made at each single experiment with the same source. Before conducting the main experiments, the characteristics of pinducers were studied. 65 A pinducer was located at 20 mm distance from a line source and a wave signal was obtained. Then, the pinducer was moved 10 mm farther from the line source and another wave signal was recorded and so on. This test was performed at the same energy level for wave propagation parallel and perpendicular to the fiber directions as shown in Fig. 4.4.1 and Fig. 4.4.2, respectively. For comparison purposes, time scale and voltage output scale are the same for every waveform. Each trace shows a disturbance at time zero caused by electrical noise from the ruby laser at the time of firing. The largest sharp signal of each trace is a Rayleigh wave. Each Rayleigh wave arrival time is found to be proportional to the corresponding distance from the line source. Thus, the Rayleigh wave velocity is independent of wave propagation distance. The wave is also non-dispersive maintaining approximately the same wave length and shape. Wave amplitude is found to decrease with propagation distance due to the high attenuation of the The wave amplitude of the first large graphite/epoxy composite. negative signal was used for attenuation measurements. The relation between the laser energy and the pinducer output was found to be linear as shown in Fig. 4.4.3. A pinducer was fixed at 20 mm distance from a line source and the pinducer output voltage of the first large negative peak was measured as the laser energy was changed. Both correlation coefficients for 9 = 0° and 0 = 90° show high linearity. The wave amplitude may be attenuated somewhat by contact with the pinducer, but the output 66 70 60 50 40 30 20 10 5 0 10 15 20 25 30 35 TIME (micro second) Fig. 4.4.1. Rayleigh waves in the unidirectional graphite/ epoxy composite as a pinducer moves from a line source ( 0 = 0° ). 60 --- ------77-1 50 ..-"" 40 30 20 10 10 5 0 5 10 15 20 25 30 35 TIME (micro second) Fig. 4.4.2. Rayleigh waves in the unidirectional graphite/ epoxy composite as a pinducer moves from a line source ( 0 = 90° ). 40 67 40 Linear regression ( 90 degree ) 35 Y = 0.43606 + 0.11995 X Correlation coeff. = 0.99535 30 25 20 15 10 Linear regression ( 0 degree ) Y = 0.38097 + 0.05918 X Correlation coeff. = 0.99533 5 Oo 50 100 150 200 250 300 350 LASER ENERGY (mJ) Fig. 4.4.3. Relation between the laser energy and the pinducer output. 400 68 voltages of piezo-electric crystals should be linear with small amplitudes if the attenuation of wave amplitude by a pinducer is negligible. Also, if there was any high nonlinearity among the laser energy, the wave amplitude, and the pinducer output, these high correlation coefficients would not be obtained. Therefore, Rayleigh wave amplitudes and laser energies show good linearity at lower laser energy levels. At higher energy levels, this may not be true. Tests using the dual pinducer technique resulted in many problems. First, the outputs of each pinducer were different from one another at the same laser energy even though each one had a high output linearity and showed repetitive signals. The wave amplitude after passing a pinducer was attenuated about 10% more compared to that without contact. This attenuation amount seemed to be a function of many factors, i.e., the characteristics of each pinducer, wave propagation directions, distances from a line source, etc. Also, minor dispersion occurs so that the measurement of wave propagation time was different when wave shape was changing. The attenuation coefficient Y is defined as follows [33]: 20 logi 0 I V2 , I Ax where V1 = wave amplitude at a reference point x1 V2 = attenuated wave amplitude at point x2 (4.4.1) 69 Ax = x2 - x1 = distance between the two point of measurements. The measurements of wave amplitudes at the first major negative going signal for 0 = 0° and 0 = 90° were plotted with each 10 mm interval as shown in Fig. 4.4.4. Constant attenuation curves were calculated using the first and the last pinducer output. Table 4.4.1. Attenuation calculation of a graphite/epoxy composite angle (0) interval attenuation average (mm) (dB/cm) attenuation 20 - 30 0° 0 90° 30 40 40 50 50 60 -1.859 -2.948 -2.923 -3.757 20 30 30 40 40 50 -6.508 -4.358 -1.987 -2.872 dB/cm -4.284 dB/cm Along the fiber direction, experimental data were close to the calculation and the attenuation coefficient was approximately constant. However, at 0 = 90°, the Rayleigh wave was attenuated rapidly near the line source and more slowly far from the line source. Wave attenuation appears to change with the distance from the line source. If composites are damaged by impact, then wave propagation velocity is expected to decrease and attenuation to 70 35 0000 30 Experiment ( 0 degree ) Experiment ( 90 degree ) Constant Attenuation ( 0 degree ) Constant Attenuation ( 90 degree ) XXXX 25 --- 20 15 10 5 Oo 10 20 30 40 50 60 70 DISTANCE FROM A LINE SOURCE (mm) Fig. 4.4.4. Attenuation of Rayleigh wave amplitudes in the graphite/epoxy composite when 0 = 0° & 90° ( laser energy = 205 ml ). 80 71 increase. Therefore, attenuation measurements along the fiber direction would appear to be more useful for NDT of composite damage by impact. Some plots of experimental Rayleigh wave forms and FFT analysis are given in Appendix D. Each plot shows a similar wave form with Rayleigh wave having a frequency of about 0.8 ± 0.05 MHz. The calculated wave length of the Rayleigh wave is about 2.5 mm when 0 = 0° and 1.8 mm when 0 = 90°. Therefore, plate no. 4 is about 6.5 - 9.0 wave lengths thick and the simulation of a semi- infinite composite as discussed in section 4.3. should be valid. The calculations and experimental results for Rayleigh wave phase velocities are plotted as shown in Fig. 4.4.5. Experimental data were obtained by the single pinducer technique and show a very good agreement with calculated values. Rose and Pilarsky formulated the same equations as given in section 3.1. to calculate the Rayleigh wave velocity of unidirectional graphite/epoxy composites ( 60% fiber volume fraction ) [57]. Their results appears to be in error due to incorrect eigen value and eigen vector calculations caused by the direct solution of bicubic equations as discussed in section 3.2.1. They used conventional transducers with frequencies of 1 MHz and 2 MHz, and generated Rayleigh waves along one surface line and received at two others separated 10 mm. Such a small separation was chosen not only due to large attenuation, but mainly to avoid any difficulties with the interpretation of 72 2.5 experiment calculation experiment by Rose calculation by Rose 2 1.5 1 0.5 0 0 0.5 1 1.5 2 25 VELOCITY (KM/SEC), PARALLEL TO FIBER Fig. 4.4.5. Calculations and experiments of Rayleigh wave phase velocities in the unidirectional graphite/ epoxy composite and comparison with Rose's results [see reference 57]. 73 the received signals, due to finite thickness of the composite layer and possible reflected waves from the far side. As shown in Fig. 4.4.5, the velocity calculations by Rose et al [57] were very close to calculations of this work along the fiber direction (0 = 0 °) because an eigen value and an eigen vector could be found correctly without the coupling difficulty. difference is probably due to material constants used. The small Rose's calculations show increasing deviations compared to present results with increasing values of 0, and even show a sharp change between 0 = 85° and 90° where material properties are nearly the same. Rose's experimental results can not be compared directly with their calculations because material constants of the unidirectional graphite/epoxy composite were unknown. However, their experimental results also showed significant change near 0 = 90° similar to their calculations. Such a rapid change does not appear reasonable without significant changes of material constants which do not occur when approaching 0 = 90° . The same experiments were repeated using dual pinducers and showed poor agreement with calculations, Fig. 4.4.6. As pointed out in section 4.4.1, dual pinducers caused additional attenuation and dispersion. Also, the short spacing of dual pinducers was necessary because of the high attenuation, and even small changes of spacing could produce the rather large errors. 74 2.5 oooo xxxx experiment with a pinducer experiment with dual pinducers 2 Rayleigh wave calculation 1.5 x x x 1 x 0.5 0 0 0.5 1 1.5 2 25 VELOCITY (KM/SEC), PARALLEL TO FIBER Fig. 4.4.6. Comparison between the single and the dual pinducer techniques in Rayleigh wave velocity measurements. 75 4.4.2. Lamb Waves Before considering Lamb waves in graphite/epoxy composites, Lamb waves in aluminum were briefly considered for a case study. The laser beam was focused to a line source on an aluminum plate of 0.8 mm thickness and waves were detected at 35 mm distance from the line source. As shown in Fig. 4.4.7.A, the So wave of 2.2 MHz arrives at 6.3 gsec followed by a surface wave with sharp large amplitudes and a frequency of 1.95 MHz. Then, the Ao wave of lower frequency ( 0.8 MHz) arrives at about 10 ilsec with the S1 wave of higher frequency ( 4.4 MHz ). As shown in Fig. 4.4.7.B, the peak frequency of each wave mode can be clearly found in aluminum. The waveforms and corresponding FFT analysis for the thinnest plate, no. 1, are given in Appendix E. Note the presence of a surface wave in the plate wave propagation. If the laser energy is low enough, the surface wave will not appear, but the signal-to-noise ratio will be very low. The surface wave has a frequency of about 0.77 ± 0.04 MHz which is nearly the same as that of the Rayleigh wave, and its wave length is about 2.7 mm when 0 = 0° and 2.0 mm when 0 = 90°. The wave length of the plate surface wave is two or three times larger than the thickness 0.87 mm of plate no. 1. Therefore, the "plate surface wave" should not be called a "Rayleigh wave" which is a surface wave in a semi-infinite medium. As an example of thin plate wave analysis, Lamb wave propaga- tion in plate no. 1 when 0 = 90° is considered. A pinducer was 76 100 50 0 0 E-4 o -50 -100 a. -150 -10 -5 0 5 10 20 15 25 30 35 40 TIME ( micro second ) Fig. 4.4.7.A Laser generated ultrasonic waves in an aluminum plate of 0.8 mm thickness. x106 3 Surface wave 2.5 2 AO 1.5 SO 1 0.5 2 3 4 5 6 FREQUENCY ( MHz ) Fig. 4.4.7.B Frequency analysis of Fig. 4.4.7.A. 7 77 located 20 mm from a line source. As shown in Fig. 4.4.8.A and B, the So wave arrives at 7 lisec followed by a surface wave with a sharp large amplitude and a frequency of 1.74 MHz. Then, the Ao wave of lower frequency ( 0.25 MHz ) arrives with the S1 wave of higher frequency ( 2.0 MHz) superposed . To find an accurate arrival of each mode, digital filtering was performed as shown in Fig. 4.4.9. In spite of the low pass digital filtering ( cut-off frequency 0.7 MHz a.--. ), the true Ao wave is difficult to find because of the "ringing" sideeffect of the filtered signal. The band pass digital filtering between 0.7 and 1.7 MHz shows the surface wave. The high pass digital filtering ( cut-off frequency E- 1.7 MHz) shows the arrival of S1 wave at about 7 ilsec before the surface wave arrival. is, however, difficult to find by filtering. The So wave In general, the exact arrivals of the laser generated Lamb waves are difficult to find, and frequently the Ao, So, S1 Lamb waves, and the surface wave are superposed on each other. On the other hand, the "leaky Lamb wave technique" by conventional transducers can generate Lamb waves without the surface wave and can find each Lamb wave mode more easily. Therefore, this experiment was not continued further for plates no. 2 and 3. The evaluation of Lamb wave velocities using laser generated Lamb waves is not recommended. In Fig. 4.4.10, the surface wave phase velocities of plate no. 1 are plotted against Rayleigh wave phase velocities of plate no. 4. The plate surface waves when 9 E 0° are about 7 % faster than Rayleigh waves, but difference is much less when 0 -E- 90°. This 78 80 surface wave 60 40 e-a 20 a. 0 0 z -20 Si So 40 5 0 5 15 10 20 25 35 30 40 TIME ( micro second ) Fig. 4.4.8.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness perpendicular to the fiber direction. x105 14 Surface wave 12 S1 10 AO 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. 4.4.813 Frequency analysis of Fig. 4.4.8.A. 7 79 100 50 0 ers 50 a) 100 a) 4. -150 0 200 :2' 250 A 300 350 15 10 5 0 5 10 15 20 25 30 TIME ( micro second ) Fig. 4.4.9. Digital filtering analysis for Lamb wave signal of Fig. 4.4.8.A i) Low pass filtering with a cut-off frequency of 0.7 MHz, fi) Band pass filtering between 0.7 and 1.7 MHz, iii) High pass filtering with a cut-off frequency of 1.7 MHz. 80 experiment ( h = 16.25 mm ) experiment ( h = 0.87 mm ) Rayleigh wave calculation 0 0.5 1 1.5 2 25 VELOCITY (KM/SEC), PARALLEL TO FIBER Fig. 4.4.10. Polar plot of surface wave phase velocities on the graphite/epoxy composite plates of thickness 0.87 & 16.25 mm. 81 increase of the plate surface velocity when 9 a 0°, rather than when 9 a 90°, may be useful for the detection of delamination in thick composites because the delaminated part of the composite can be represented as a thin plate with traction-free surfaces. 82 CHAPTER. 5 CONCLUSIONS AND RECOMMENDATIONS The results of the laser generated Rayleigh and Lamb waves in graphite/epoxy composites can be summarized as followings: 1) The Rayleigh wave phase velocities can be calculated accurately by a new eigenvalue search method. 2) The relation between the laser energy and the pinducer output was found to be linear. Therefore, the relation of the Rayleigh wave amplitude and laser energy should be approximately linear at least in lower laser energy levels. 3) Attenuation along the fiber direction shows an approximate constant value and could provide means for NDT of composite damage by impact. 4) The dual pinducers technique suffered from the additional attenuation and dispersion by the front pinducer. This approach is believed to be less accurate than the single pinducer technique for velocity and attenuation measurement. 5) Laser generated Rayleigh waves with detection by a pinducer shows better accuracy agreement with theory than the conventional transducer technique for Rayleigh wave velocity measurement. 83 6) Laser generated Lamb waves with detection by a pinducer lead to difficulties in finding precise arrivals of each Lamb wave mode. 7) The increase of the plate surface velocity when 0 a 0°, rather than 0 -2 :- 90°, may be useful for the detection of delamination because the delaminated part of the composite can be simulated as a thin plate with traction-free surfaces. 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APPENDICES 93 APPENDIX A PROGRAM FOR RAYLEIGH WAVES % ************************************************************* % CSW.M for Rayleigh wave velocity calculation. % % This program finds the accurate Rayleigh wave velocity which can satisfy the zero value of BCD(boundary condition determinant) within tolerance. % The proper search interval can be found by PD.M. % If there is no solution, search interval will move out of the % initial interval by the modified golden section method. % VV = monitoring velocity according to E(1) = smaller velocity in search interval v2 = larger velocity in search interval E(i) = eigen value according to the assumed velocity F(i) = BCD corresponding to E(i) = stiffness matrix of plate % AA = all or part of A matrix components % THETA = wave propagation direction relative to fiber direction (degree) % RHO = density of plate % TOL = tolerance for iteration termination % ARM = arm for search interval change % Ll = X direction cosine of wave propagation vector % L2 = Y direction cosine of wave propagation vector % X (L3) = 3 roots of L3 according to the assumed velocity % A(:,i) = eigen vector components corresponding to X(i) % ************************************************************* clear format short e i = sqrt(-1) getdata % % % % vl %C vl =input(' vl initial =') v2 =input(' v2 final =') E(1) = RHO*vl*v1 E(4) = RHO*v2*v2 F(1) = Eval(E(1),C13,C23,C33,C44,C55,AA,THETA) ; F(4) = Eval(E(4),C13,C23,C33,C44,C55,AA,THETA) ; index = 1 TOL = le-5 count = 0 while ((E(4)-E(1))/E(4)) > TOL ARM = (E(4) - E(1))*0.618 E(2) = E(4) ARM E(3) = E(1) + ARM if (index=3), F(2) = Eval(E(2),C13,C23,C33,C44,C55,AA,THETA);, end if (index=2), F(3) = Eval(E(3),C13,C23,C33,C44,C55,AA,THETA);, end [MIN,index] = min(F) 94 if(index==1) E(4) = E(2) ; F(4) = F(2) ; E(1) = E(1) - ARM; F(1) = Eval(E(1),C13,C23,C33,C44,C55,AA,THETA) ; elseif(index==2) E(4) = E(3) E(3) = E(2) elseif(index==3) E(1) = E(2) E(2) = E(3) else ; F(4) = F(3) F(3) = F(2) ; F(1) = F(2) F(2) = F(3) ; E(4) = E(4) + ARM; F(4) = Eval( E( 4 ),C13,C23,C33,C44,C55,AA,THETA) ; E(1) = E(3) ; F(1) = F(3) , end VV = sqrt(E(1)/RHO) count = count +1 ; [count real(VV) E(1) E(4) F(1) F(4) ] end % end while A(3,3) = 0 ; [X(1) A(:,1)] = eigen(1,E(1),C33,C44,C55,AA) [X(2) A(:,2)] = eigen(2,E(1),C33,C44,C55,AA) [X(3) A(:,3)] = eigen(3,E(1),C33,C44,C55,AA) if THETA ==O temp = X(3) X(3) = X(2) X(2) = temp tempi = A(:,3) A(:,3) = A(:,2) A(:,2) = temp 1 end S = MatrixB(C13,C23,C33,C44,C55,A,L1,L2,X) ; VV = sqrt(E(1)/RHO) % save csw VV S A X Ll L2 C11 C12 C13 C22 C23 C33 95 % ************************************************************* % Getdata.m % % This M-file is to get the material constants of plate and calculates components of stiffness matrix. % % RHO = Density % P21, P23 = Poisson's ratio % El, E2 % G12 = Young's modulus = Shear modulus (following Tsai's convention) % pi = 3.141592 % ************************************************************* THETA = input('Enter angle = ') ANGLE = THETA*pi/180 RHO = 1.52e-6 P21 =0.31 P23 = 0.54 El = 138.5e-6 E2 = 11.e-6 G12 = 6.3e-6 P12 = P21*E2/E1 D = 1/(1+P23)/(1-P23-2*P21*P12) C11 = (1-P23*P23)*D*E1 C22 = (1-P21*P12)*D*E2 C33 = C22 C12 = P21*(1.+P23)*D*E2 C13 =C12 C23 = (P23+P21*P12)*D*E2 C44 = (1.-P23-2*P21*P12)*D*E2/2 C55 = G12 C66 = G12 Ll = cos(ANGLE) L2 = sin(ANGLE) AA(i) = C11 *Ll*L1 +C66*L2*L2 AA(2) = C66*Ll*L1 +C22*L2*L2 AA(3) = C55*L1 *L1 +C44*L2*L2 AA(4) = (C12+C66)*Ll*L2 AA(5) = (C13+C55)*L1 AA(6) = (C23+C44)*L2 ; % Kg/mm/mm/mm , , ; % Kg/mm/microsec/microsec ; % These units make a velocity ; % units in mm/microsec. 96 % ************************************************************* % Eval.m for csw.m % This M-file calculates the value of boundary condition determinant % and returns absolute value of it. % ************************************************************* function y = Eval(E,C13,C23, C33, C44,C55,AA,THETA) Ll = cos(THETA*pi/180) L2 = sin(THETA*pi/180) A(3,3) = 0 [X(1) A(:,1)] = eigen(1,E,C33,C44,C55,AA) [X(2) A(:,2)] = eigen(2,E,C33,C44,C55,AA) [X(3) A(:,3)] = eigen(3,E,C33,C44,C55,AA) if THETA ==O temp = X(3) X(3) = X(2) X(2) = temp ; temp 1 = A(:,3) A(:,3) = A(:,2) A(:,2) = temp 1 end S = MatrixB (C13, C23, C33, C44,C55,A,L1 ,L2,X) y = abs(det(S)) % ************************************************************* % Eigen.m % This M-file is to find imaginary root of L3 and calculate % corresponding eigen value and eigen vector. % ************************************************************* function [Y,A] = eigen(K,E,C33,C44,C55,AA) i = sqrt(-1) LOW = FL = Avalue(LOW,K,E,C33,C44,C55,AA) while FL > 0 LOW = LOW - i FL = Avalue(LOW,K,E,C33,C44,C55,AA) end HIGH = 0 FH = Avalue(HIGH,K,E,C33,C44,C55,AA) index = 1 TOL = le-10 while abs(HIGH-LOW) > TOL MID = (LOW+HIGH)/2 97 FM = Avalue(MID,K,E,C33,C44,C55,AA) if FM > 0 HIGH = MID = FM else LOW = MID FL = FM end end T = MatrixA(LOW,C33,C44,C55,AA) [VECTOR VALUE] = eig(T) Y = LOW A = VECTOR(:,K) % ************************************************************* % Avalue.m % This M-file returns difference between the assumed eigen value and % the eigen value corresponding to X. % When this difference approaches to zero, root of L3 is found. % ************************************************************* function y = Avalue(X,K,E,C33,C44,C55,AA) Z = MatrixA(X,C33,C44,C55,AA) EIGVALUE = eig(Z) y = EIGVALUE(K)-E % ************************************************************* % MatrixA.m % This M-file is for component calculation of A matrix. % ************************************************************* function y=MatrixA(X,C33,C44,C55,AA) A(1,1) = AA(1) +C55*X*X A(2,2) = AA(2) +C44*X*X A(3,3) = AA(3) +C33*X*X A(1,2) = AA(4) A(2,1) = A(1,2) A(1,3) = AA(5)*X A(3,1) = A(1,3) A(2,3) = AA(6)*X A(3,2) = A(2,3) y=A 98 % ************************************************************* % MatrixB.m % This M-file is to calculate components of boundary condition matrix (B matrix). % ************************************************************* function y= MatrixB(C13,C23,C33,C44,C55,A,L1,L2,X) B(1,1) = C55*(A(1,1)*X(1) +A(3,1)*L1) B(1,2) = C55*(A(1,2)*X(2) +A(3,2)*L1) B(1,3) = C55*(A(1,3)*X(3) +A(3,3)*L1) B(2,1) = C44*(A(2,1)*X(1) +A(3,1)*L2) B(2,2) = C44*(A(2,2)*X(2) +A(3,2)*L2) B(2,3) = C44 *(A(2,3) *X(3) +A(3,3)*L2) B(3,1) = C13*A(1,1)*L1 +C23*A(2,1)*L2 +C33*A(3,1)*X(1) ; B(3,2) = C13*A(1,2)*L1 +C23*A(2,2)*L2 +C33*A(3,2)*X(2) ; B(3,3) = C13*A(1,3)*L1 +C23*A(2,3)*L2 +C33*A(373)*X(3) ; y=B % ************************************************************* % CD.M % This M-file is to calculate the value of BCD( boundary condition determinant) % within an interval selected and show the pattern of BCD. % After finding a small interval including root, % run csw.m to find accurate root value. % ************************************************************* clear format short e i = sqrt(-1) getdata A(373) = 0 V1 = input(' Initial = ') V2 = input(' Increment = ') V3 = input(' Final = ') index = 1 for V = V1 :V2:V3 E = RHO*V*V [X(1) A(:,1)] = eigen(1,E,C33,C447C55,AA) [X(2) A(:,2)] = eigen(2,E,C33,C44,C55,AA) [X(3) A(:,3)] = eigen(3,E,C33,C44,C55,AA) if THETA ==O temp = X(3) X(3) = X(2) X(2) = temp tempi = A(:,3) A(:,3) = A(:,2) 99 A(:,2) = tempi end S = MatrixB(C13,C23,C33,C44,C55,A,L1,L2,X) V = sqrt(E/RHO) detl(index) = real(det(S)) det2(index) = imag(det(S)) [V detl(index) det2(index) ] index = index +1 end V = (V1:V2:V3)' out=[V detl' det2' ] plot(V, detl',':',V,det2',' -') title(' DETERMINANT VALUE OF S MATRIX ') text(0.5,0.85,' Real value of det(S) ','sc') text(0.5,0.8,' Imag. value of det(S) ','sc') xlabel(' VELOCITY ( MM / MICRO SEC) ') ylabel(' DETERMINANT VALUE') % ************************************************************* % CSWD.M % This M-file is to calculate and plot displacements of Rayleigh wave. % ************************************************************* clear load csw45 CC(1) = 1 CC(2) = (S(2,1)*S(1,3)-S(1,1)*S(2,3)) /(S(1,2)*S(2,3)-S(1,3)*S(2,2)) CC(3) = -(S(3,1)+S(3,2)*CC(2))/S(3,3) i = sqrt(-1) ; XX = 0 YY = 0 WL = 1 ; K = 2*pi/WL TT = 0 N=1 ; fl = 50 f2 = 5 for ZZ = 0:-WL/f1:42*WL DX(N) = 0 ; DY(N) = 0 ; DZ(N) = 0 ; for J = 1:3 DX(N) = DX(N) +CC(J)*A(1,J)*exp(i*K*(L1*XX +L2*YY +X(J)*ZZ -VV*TT)); DY(N) = DY(N) +CC(J)*A(2,J)*exp(i*K*(Ll*XX +L2*YY +X(J)*ZZ -VV*TT)); DZ(N) = DZ(N) +CC(J)*A(3,J)*exp(i*K*(L1*XX +L2*YY +X(J)*ZZ -VV*TT)); end N=N+1 end [DX(1) DY(1) ] ZZ = (0:-WL/f1:42*WL)' disp = [DX',DY',conj(DZ')] 100 DZ = DZ*(-i) DX = DX/DZ(1) DY = DY/DZ(1) DZ = DZ/DZ(1) , ; % Phase change % Normalization ; , plot(ZZ, DX',':',ZZ,DY','--',ZZ,DZ','-') title(' X,Y,Z DISPLACEMENT PLOT : THETA = ? ') text(0.2,0.85,' X disp. ','sc') text(0.2,0.8, '- Y disp. ','sc') text(0.2,0.75; Z disp.','sc') xlabel(' Z / WAVE LENGTH') ylabel(' NORMALIZED DISPLACEMENT') 101 APPENDIX B PROGRAM FOR LAMB WAVES % ************************************************************* % PP.M for plate problem % % % % % This program finds the accurate Lamb wave velocity which can satisfy the zero value of BCD(boundary condition determinant) within tolerance. The proper search interval can be found by PD.M. If there is no solution, search interval will move out of the initial interval by the modified golden section method. %V % V1 % V2 % % E(i) F(i) %C = monitoring velocity according to E(1) = smaller velocity in search interval = larger velocity in search interval = eigen value according to the assumed velocity = BCD corresponding to E(i) = stiffness matrix of plate = all or part of A matrix components = wave number K * plate thickness H % AA % KH % THETA = wave propagation direction relative to fiber direction (degree) % RHO = density of plate % TOL = tolerance for iteration termination % ARM = arm for search interval change = X direction cosine of wave propagation vector L2 = Y direction cosine of wave propagation vector % X (L3) = 6 roots of L3 according to the assumed velocity % A(:,i) = eigen vector components corresponding to X(i) % ************************************************************* % % Ll % --- Initialize and get material constants. clear ; format short e ; i = sqrt(-1) getconst ; % Call Getconst.m V1 = input(' Beginning of interval = ') ; V2 = input(' End of interval = ') E(1) = RHO*V1*V1 ; E(4) = RHO*V2*V2 F(1) = DETvalue(E(1),C,AA,KH,THETA) ; F(4) = DETvalue(E(4),C,AA,KH,THETA) ; index = 1 ; TOL = le-5 ; count = 0 ; %---- Start search until tolerance is met. % This is the modified golden section method. while ((E(4)- E(i))/E(4)) > TO ARM = (E(4) E(1))*0.618 ; E(2) = E(4) - ARM ; E(3) = E(1) + ARM ; if (index=3), F(2) = DETvalue(E(2),C,AA,KH,THETA);, end if (index ' =2), F(3) = DETvalue(E(3),C,AA,KH,THETA);, end [MIN,index] = min(F) 102 %---- Future search interval depends on minimum of F. % (Modified golden section method) if(index==1) Minimum is toward the left of interval, so move interval to the left. E(4) = E(2) ; E(1) = E(1) - ARM F(4) = F(2) ; F(1) = DETvalue(E(1),C,AA,KH,THETA) ; elseif(index==2) Minimum is close to E(2), shrink interval to E(2). E(4) = E(3) ; E(3) = E(2) ; F(4) = F(3) ; F(3) = F(2) ; elseif(index==3) Minimum is close to E(3), shrink interval to E(3). E(1) = E(2) ; E(2) = E(3) ; F(1) = F(2) ; F(2) = F(3) ; else Minimum is toward the right of interval, so move interval to the right. E(4) = E(4) + ARM ; E(1) = E(3) ; F(4) = DETvalue(E(4),C,AA,KH,THETA) ; F(1) = F(3) ; end % end if V = sqrt(E(1)/RHO) ; count = count +1 [count real(V) E(1) E(4) F(1) F(4) ] end % end while %---- Final result calculation by E(1). A(3,6) = 0 ; E = E(1) ; e = sort(eig(Amatrix(0,C,AA))) ; if(E <= e(1)) [X(1) A(:,1)] = ieigen(1,1,E,C,AA) ; [X(3) A(:,3)] = ieigen(2,1,E,C,AA) ; [X(5) A(:,5)] = ieigen(3,1,E,C,AA) ; X(2) = -X(1) ; A(:,2) = conj(A(:,1)) ; X(4) = -X(3) ; A(:,4) = conj(A(:,3)) ; X(6) = -X(5) ; A(:,6) = conj(A(:,5)) ; elseif(e(1)<E & E<(2)) [X(1) A(:,1)] = reigen(1,1,E,C,AA) ; [X(3) A(:,3)] = ieigen(2,1,E,C,AA) ; X(4) = -X(3) ; A(:,4) = conj(A(:,3)) ; elseif(e(2)<E & E<(3)) [X(1) A(:,1)] [X(3) A(:,3)] [X(5) A(:,5)] else [X(1) A(:,1)] [X(3) A(:,3)] [X(5) A(:,5)] end [X(2) A(:,2)] = reigen(1,0,E,C,AA) ; [X(5) A(:,5)] = ieigen(3,l,E,C,AA) ; X(6) = -X(5) ; A(:,6) = conj(A(:,5)) ; = reigen(1,1,E,C,AA) ; = reigen(2,1,E,C,AA) ; = ieigen(3,1,E,C,AA) ; [X(2) A(:,2)] = reigen(1,0,E,C,AA) ; [X(4) A(:,4)] = reigen(2,0,E,C,AA) ; X(6) = -X(5) ; A(:,6) = conj(A(:,5)) ; = reigen(1,1,E,C,AA) ; = reigen(2,1,E,C,AA) ; = reigen(3,1,E,C,AA) ; [X(2) A(:,2)] = reigen(1,0,E,C,AA) ; [X(4) A(:,4)] = reigen(2,0,E,C,AA) ; [X(6) A(:,6)] = reigen(3,0,E,C,AA) ; DMAT = Dmatrix(C,KH,A,L1,L2,X); X V = sqrt(E/RHO) save PP DMAT A VXH Ll L2 clear 103 % ************************************************************* % GETCONST.M for pp.m % % This M-file is to get the material constants of plate % and calculates components of stiffness matrix. % % RHO = Density % El, E2 % G12 = Young's modulus = Shear modulus % P21, P23 = Poisson's ratio (following Tsai's convention) % pi = 3.141592 % ************************************************************* %--- Get material constants. RHO = 1.52e -6 P21 = 0.31 P23 = 0.54 ; % Kg/mm/mm/mm El = 138.5e-6 E2 = 11.e-6 G12 = 6.3e-6 ; % Kg/mm/microsec/microsec ; % These units make a velocity ; % units in mm/microsec. %--- Calculate components of stiffness matrix. P12 = P21 *E2/El C(1,1) = (1-P23*P23)*D*E1 C(3,3) = C(2,2) C(2,1) = C(1,2) C(3,1) = C(1,3) C(3,2) = C(2,3) C(5,5) = G12 D = 1/(1+P23)/(1-P23-2*P21*P12) C(2,2) = (1-P21*P12)*D*E2 C(1,2) = P21*(1.+P23)*D*E2 C(1,3) = C(1,2) C(2,3) = (P23+P21*P12)*D*E2 C(4,4) = (1.-P23-2*P21*P12)*D*E2/2 C(6,6) = G12 THETA = input(' ANGLE OF WAVE PROPAGATION: THETA =') ANGLE = THETA*pi/180 ; Li = cos(ANGLE) ; L2 = sin(ANGLE) 9 9 ; ; %--- Calculate A matrix components. AA(1) = C(1,1)*Ll*L1 +C(6,6)*L2*L2 ;AA(2) = C(6,6)*L1 *L1 +C(2,2)*L2*L2; AA(3) = C(5,5)*Ll*L1 +C(4,4)*L2*L2 ;AA(4) = (C(1,2)+C(6,6))*L1 *L2 ; AA(5) = (C(1,3)+C(5,5))*L1 ;AA(6) = (C(2,3)+C(4,4))*L2 , K . 2*pi ; KH = K*H , H = input(' PLATE THICKNESS H =') ; 104 % ************************************************************* % DETVALUE.M for pp.m % This M-file calculates the value of boundary condition determinant % and returns absolute value of it. % ************************************************************* function y = DETvalue(E,C,AA,KH,THETA) Ll = cos(THETA*pi/180) L2 = sin(THETA*pi/180) A(3,6) = 0 e = sort(eig(Amatrix(0,C,AA))) if(E <= e(1)) [X(1) A(:,1)] = ieigen(1,1,E,C,AA) [X(5) A(:,5)] = ieigen(3,1,E,C,AA) X(4) = -X(3) ; A(:,4) = conj(A(:,3)) ; elseif(e(1)<E & E<(2)) [X(1) A(:,1)] = reigen(1,1,E,C,AA) ; [X(3) A(:,3)] = ieigen(2,1,E,C,AA) ; X(4) = -X(3) ; A(:,4) = conj(A(:,3)) ; elseif(e(2)<E & E<(3)) [X(1) A(:,1)] = reigen(1,1,E,C,AA) ; [X(3) A(:,3)] = reigen(2,1,E,C,AA) ; [X(5) A(:,5)] = ieigen(3,1,E,C,AA) ; else [X(1) A(:,1)] = reigen(1,1,E,C,AA) ; [X(3) A(:,3)] = reigen(2,1,E,C,AA) ; [X(5) A(:,5)] = reigen(3,1,E,C,AA) ; end D = Dmatrix(C,ICH,A,L1,L2,X) y = abs(det(D)); [X(3) A(:,3)] = ieigen(2,1,E,C,AA) ; X(2) = -X(1) ; A(:,2) = conj(A(:,1)) ; X(6) = -X(5) ; A(:,6) = conj(A(:,5)) ; [X(2) A(:,2)] = reigen(1,0,E,C,AA) ; [X(5) A(:,5)] = ieigen(3,1,E,C,AA) ; X(6) = -X(5) ; A(:,6) = conj(A(:,5)) ; [X(2) A(:,2)] = reigen(1,0,E,C,AA) ; [X(4) A(:,4)] = reigen(2,0,E,C,AA) ; X(6) = -X(5) ; A(:,6) = conj(A(:,5)) ; [X(2) A(:,2)] = reigen(1,0,E,C,AA) ; [X(4) A(:,4)] = reigen(2,0,E,C,AA) ; [X(6) A(:,6)] = reigen(3,0,E,C,AA) ; ; % ************************************************************* % REIGEN.M for pp.m & pd.m % This M-file is to find real root of L3 and calculate % corresponding eigen value and eigen vector. % ************************************************************* function [Y,A] = reigen(K,SIGN,E,C,AA) LOW = 0 FLOW = value(LOW,K,E,C,AA) if (SIGN == 1) HIGH = 5 else HIGH = -5 end ; % To find positive real root of L3. ; % To find negative real root of L3. 105 FHIGH = value(HIGH,K,E,C,AA) ; %---- Find root of L3 by half interval search. index = 1 TOL = le-10 while abs(HIGH-LOW) > TOL MID = (LOW+HIGH)/2 FMID = value(MID,K,E,C,AA) ifFMID >0 HIGH = MID FHIGH = FMID else LOW = MID FLOW = FMID end end %---- Calculate eigen value and eigen vector. T = Amatrix(LOW,C,AA) [VECTOR VALUE] = eig(T) Y = LOW [VEC,j] = sort(diag(VALUE)) A = VECTOR(:,j(K)) % ************************************************************* % IEIGEN.M for pp.m & pd.m % This M-file is to find the imaginary root of L3 and calculate % corresponding eigen value and eigen vector. % ************************************************************* function [Y,A] = ieigen(K,SIGN,E,C,AA) %--- Find the negative imaginary root of L3. i = sqrt(-1) LOW = -5*i ; % SIGN has no meaning here FLOW = value(LOW,K,E,C,AA) HIGH = 0 FHIGH = value(HIGH,K,E,C,AA) %---- Find root of L3 by half interval search. index = 1 TOL = le-10 106 while abs(HIGH-LOW) > TOL MID = (LOW+HIGH)/2 FMID = value(MID,K,E,C,AA) ifFMID >0 HIGH = MID FHIGH = FMID else LOW = MID FLOW = FMID end end %---- Calculate eigen value and eigen vector. T = Amatrix(LOW,C,AA) [VECTOR VALUE] = eig(T) Y = LOW [VEC,j] = sort(diag(VALUE)) A = VECTOR(:,j(K)) % ************************************************************* % VALUE.M % This M-file returns difference between the assumed eigen value and % the eigen value corresponding to X. % When this difference approaches to zero, root of L3 is found. % ************************************************************* function y = value(X,K,E,C,AA) Z = Amatrix(X,C,AA) EIGVALUE = sort(eig(Z)) y = EIGVALUE(K)-E % ************************************************************* % AMATRIX.M % This M-file is for component calculation of A matrix. % ************************************************************* function y=Amatrix(X,C,AA) A(1,1) = AA(1) +C(5,5)*X*X A(2,2) = AA(2) +C(4,4)*X*X A(3,3) = AA(3) +C(3,3)*X*X 107 A(1,2) = AA(4) A(2,1) = A(1,2) A(1,3) = AA(5)*X A(3,1) = A(1,3) A(2,3) = AA(6)*X A(3,2) = A(2,3) y=A % ************************************************************* % DMATRIX.M for pp.m % This M-file is to calculate components of boundary condition matrix. % ************************************************************* function y= Dmat(C,KH,A,L1,L2,X) D(6,6) = 0 D(1,1) D(1,2) D(1,3) D(1,4) D(1,5) D(1,6) = C(5,5)*(A(1,1)*X(1) +A(3,1)*L1) = C(5,5)*(A(1,2)*X(2) +A(3,2)*L1) = C(5,5)*(A(1,3)*X(3) +A(3,3)*L1) = C(5,5)*(A(1,4)*X(4) +A(3,4) *Ll) = C(5,5)*(A(1,5)*X(5) +A(3,5)*L1) = C(5,5)*(A(1,6)*X(6) +A(3,6)*L1) D(2,1) = C(4,4)*(A(2,1)*X(1) +A(3,1)*L2) D(2,2) = C(4,4)*(A(2,2)*X(2) +A(3,2)*L2) D(2,3) = C(4,4)*(A(2,3)*X(3) +A(3,3)*L2) D(2,4) = C(4,4)*(A(2,4)*X(4) +A(3,4)*L2) D(2,5) = C(4,4)*(A(2,5)*X(5) +A(3,5)*L2) D(2,6) = C(4,4)*(A(2,6)*X(6) +A(3,6)*L2) D(3,1) = C(1,3)*A(1,1)*L1 +C(2,3)*A(2,1)*L2 D(3,2) = C(1,3)*A(1,2)*L1 +C(2,3)*A(2,2)*L2 D(3,3) = C(1,3)*A(1,3)*L1 +C(2,3)*A(2,3)*L2 D(3,4) = C(1,3)*A(1,4)*L1 +C(2,3)*A(2,4)*L2 D(3,5) = C(1,3)*A(1,5)*L1 +C(2,3)*A(2,5)*L2 D(3,6) = C(1,3)*A(1,6)*L1 +C(2,3)*A(2,6)*L2 for j = 1:6 D(4,j) = D(1,j)*exp(-i*KH*X(j)) D(5,j) = D(2,j)*exp(-i*KH*X(j)) D(6,j) = D(3,j)*exp(-i*KH*X(j)) end y=D +C(3,3)*A(3,1)*X(1) +C(3,3)*A(3,2)*X(2) +C(3,3)*A(3,3)*X(3) +C(3,3)*A(3,4)*X(4) +C(3,3)*A(3,5)*X(5) +C(3,3)*A(3,6)*X(6) 108 % ************************************************************* % PD.M for pp.m % This M-file is to calculate the value of BCD( boundary condition determinant) % within an interval selected and show the pattern of BCD. % After fmding a small interval including root, % run pp.m to fmd accurate root value. % ************************************************************* clear format short e i = sqrt(-1) getconst %-- Get search interval. A(3,6) = 0 = ') V1 = input(' V1 (initial) V2 = input(' V2 (increment) = ') = ') V3 = input(' V3 (final) index =1 %--- Calculate BCD value for each velocity within interval. for V = V1:V2:V3 E = RHO*V*V e = sort(eig(Amatrix(0,C,AA))) if(E <= e(1)) [X(1) A(:,1)] = ieigen(1,1,E,C,AA) ; [X(5) A(:,5)] = ieigen(3,1,E,C,AA) ; X(4) = -X(3) ; A(:,4) = conj(A(:,3)) ; elseif(e(1)<E & E<=e(2)) [X(1) A(:,1)] = reigen(1,1,E,C,AA) ; [X(3) A(:,3)] = ieigen(2,1,E,C,AA) ; X(4) = -X(3) ; A(:,4) = conj(A(:,3)) ; [X(3) A(:,3)] = ieigen(2,1,E,C,AA) X(2) = -X(1) ; A(:,2) = conj(A(:,1)) X(6) = -X(5) ; A(:,6) = conj(A(:,5)) [X(2) A(:,2)] = reigen(1,0,E,C,AA) [X(5) A(:,5)] = ieigen(3,1,E,C,AA) X(6) = -X(5) ; A(:,6) = conj(A(:,5)) elseif(e(2)<E & E<(3)) [X(1) A(:,1)] [X(3) A(:,3)] [X(5) A(:,5)] else [X(1) A(:,1)] [X(3) A(:,3)] [X(5) A(:,5)] end = reigen(1,1,E,C,AA) ; = reigen(2,1,E,C,AA) ; = ieigen(3,1,E,C,AA) ; [X(2) A(:,2)] = reigen(1,0,E,C,AA) [X(4) A(:,4)] = reigen(2,0,E,C,AA) X(6) = -X(5) ; A(:,6) = conj(A(:,5)) = reigen(1,1,E,C,AA) ; = reigen(2,1,E,C,AA) ; = reigen(3,1,E,C,AA) ; [X(2) A(:,2)] = reigen(1,0,E,C,AA) [X(4) A(:,4)] = reigen(2,0,E,C,AA) [X(6) A(:,6)] = reigen(3,0,E,C,AA) D = Dmatrix(C,ICH,A,L1,L2,X) V = sqrt(E/RHO) detl(index) = real(det(D)) det2(index) = imag(det(D)) det3(index) = abs(det(D)) [V detl(index) det2(index) det3(index)] index = index +1 109 end V = (V1:V2:V3) , %--- Plot value of BCD within interval. out =[V' detl' det2' I % plot(V, det1,':',V,det2,'-',V,det3) % plot(V,detl,V,det2,V,det3) plot(V,detl,V,det2) title(' DETERMINANT VALUE OFD MATRIX : THETA = ? : PHI = ? : H = ?') text(0.5,0.85,' Real value of det(D) ','sc') text(0.5,0.8,' Imag. value of det(D) ','sc') xlabel(' VELOCITY ( MM / MICRO SEC) ') ylabel(' DETERMINANT VALUE ') % ************************************************************* % PU.M for pp.m % % This M-file is to calculate and plot displacements of Lamb wave. % ************************************************************* clear load PP %--- Solve for weighting factor W. for J = 1:5 R(J) = -DMAT(J+1,1) for K = 1:5 P(J,K) = DMAT(J+1,K+1) end end Q = 'AR' for J = 1:5 W(J+1) = Q(J) end ; W(1)=1 ; % Solve PQ = R. ; % W = Weighting factor. %--- Initialize constants and calculate displacements. i = sqrt(-1) XX = 0 ; N= 1 ; fl =30 ; YY = 0 ; WL = 1 f2 = 5 ; , T=0 , K = 2*pi/WL ; for ZZ = 0:-WL/f1:-H DX(N) = 0 ; DY(N) = 0 ; for J = 1:6 DZ(N) = 0 ; 110 DX(N) = DX(N) +W(J)*A(1,J)*exp(i*K*(L1*XX +L2*YY +X(J)*ZZ -V*T)); DY(N) = DY(N) +W(J)*A(2,J)*exp(i*K*(L1*XX +L2*YY +X(J)*ZZ -V*T)); DZ(N) = DZ(N) +W(J)*A(3,J)*exp(i*K*(Ll*XX +L2*YY +X(J)*ZZ -V*1)); end N = N+1; end %--- Plot displacements. ZZ = (0:- WL/fl: -H)' ; disp = [DX',DY',conj(DZ')] % DZ = DZ*(-i) ; % Change of phase DX = DX*(-i) , DY = DY*(-i) ; % DX = DX/DZ(1) ; % Normalization % DY = DY/DZ(1) , % DZ = DZ/DZ(1) , plot(ZZ, DX',':',ZZ,DY','--',ZZ,DZ','-') title(' X,Y,Z DISPLACEMENT PLOT : H = ?') text(0.2,0.85,' X disp. ','sc') text(0.2,0.8, '- - - - Y disp. ','sc') text(0.2,0.75,' Z disp.','sc') xlabel(' Z / WAVE LENGTH') ylabel(' DISPLACEMENT ') 111 APPENDIX C COMPONENTS OF [Ali] Material stiffness component contracted form is used. > 2 22 4 23, 32 > has four indices, but usually a Indices are changed as follows: *1 11 Ciiki 33 13, 31 > 5 -4 3 12, 21 > 6 Then, components of [Ali] can be written as following for ortho- tropic materials. An = A22 2C56L2L3 2C15L3L1 C221-32 + C441-13 4- 2C261.11,2 2C24L2L3 2C46L3L1 N4412 + 2C341-21/3 2C35L3L1 2 + 2C161,1 C11L + C66122+ C551-3 = C661-11 + A33 7r + 2A-45111-2 2 C45L3 Al2 = A21 = C161.1 + C26L2 (C12 +C66) L11-1 (c-25 + C46) III-3 + (C14 + C56) L3L1 r .....46L2 T A13 = A31 = + (C36 r, 1,-351/3 ki,-.14 T 1-,11,2 + C45) 1,2L3 + (Ci3 + C55) L31.1 T 2 Al2 = A21 = 7 2 + T 2 + -34-1-13 to + `-'25 + C46) L111 + (C23 + C44)11113 + (C36 + C45) L3L1 For transversly isotropic materials, these can be simplified. A11 =Ci + C661-1 T A22 = `-'661-1 r, C55I-3 T r, T + A33 = + C44122 + C33123 = A 21 = (C12 +C66) L11-2 Al2 A13 = A31 = (C13 + C55) L3Li Al2 = A 21 = (C23 + C44) 1-21-13 112 APPENDIX D EXPERIMENTAL WAVEFORMS AND FFT ANALYSIS OF RAYLEIGH WAVES 40 30 E 20 10 0 .",-^-'`"^-) 10 30 40 50 60 5 5 0 15 10 20 35 30 25 40 TIME ( micro second ) Fig. D.1A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness (0=00). x105 5 1 3 4 5 6 FREQUENCY ( MHz ) Fig. D.1.8 Frequency analysis of Fig. D.1.A. 7 113 20 10 10 20 30 40 50 5 0 5 10 15 TIME ( 20 25 30 35 40 micro second ) Fig. D.2.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 20° ). x105 6 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. D.2.B Frequency analysis of Fig. D.2.A. 7 114 30 20 10 0 L'irVA 10 20 30 40 50 5 0 5 10 15 20 30 25 35 40 TIME ( micro second ) Fig. D.3.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 50° ). x105 16 14 12 - 10- 86- 420 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. D.3.B Frequency analysis of Fig. D.3.A. 7 115 30 20 10 cy\ - 10 - 20 - 30 - 40 - 50 60 -10 -5 0 5 10 15 20 25 30 35 40 TIME ( micro second ) Fig. D.4.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 70° ). x105 12 10 1 oo 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. D.4.B Frequency analysis of Fig. D.4.A. 7 116 40 20 ?:*. 0 4i -tt a c -20 E-. EM. E-' o -40 Ix c.i 0 00 -60 -4 -80 z -100 -10 -5 0 5 10 20 15 25 30 35 40 TIME ( micro second ) Fig. D.5.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 16.25 mm thickness ( 0 = 90° ). x106 6 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. D.5.B Frequency analysis of Fig. D.5.A. 7 117 APPENDIX E EXPERIMENTAL WAVEFORMS AND FFT ANALYSIS OF LAMB WAVES 150 100 E 50 - 50 100 - 150 5 0 10 5 15 35 30 25 20 40 TIME ( micro second ) Fig. E.1.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 0° ). x1013 12 10 8 6 4 2 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. E.1.B Frequency analysis of Fig. E.1 A 7 118 60 40 20 Ar -20 40 60 - 80 100 5 0 5 10 15 TIME ( 20 25 30 35 40 micro second ) Fig. E.2.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 20° ). x105 FREQUENCY ( MHz ) Fig. E.2.8 Frequency analysis of Fig. E.2.A. 119 80 60 40 20 T-NN/0-nn,- 20 40 5 0 5 10 15 20 25 30 35 40 TIME ( micro second ) Fig. E.3.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness (0=40°). x100 2.5 2 1.5 1 0.5 0 0 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. E.3.B Frequency analysis of Fig. E.3.A. 7 120 50 40 30 44 20 10 ,-.1.(11J-111.4 0 -10 20 Z 30 40 50 5 0 5 10 15 20 25 30 35 40 TIME ( micro second ) Fig. E.4.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 9 = 50° ). x105 16 14 12 10 8 6 4J 2 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. E.4.B Frequency analysis of Fig. E.4.A. 7 121 60 40 E 20 0 7,*.nrvrn.on f, i 20 i 40 - 60 5 0 10 5 15 20 30 25 35 40 TIME ( micro second ) Fig. E.5.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 60° ). x106 1.8 1.6 1.4 - 0.8 0.6 t' 0.4 0.2 Oo 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. E.5.B Frequency analysis of Fig. E.5.A. 7 122 80 ...-. 60 40 20 -20 -40 1 -60 -80 -5 0 5 10 15 20 25 30 35 40 TIME ( micro second ) Fig. E.6.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 80° ). 4 x106 3.5 2.5 1.5 0.5 = 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. E.6.B Frequency analysis of Fig. E.6.A. 7 123 80 60 - 40 20 1 20 40 5 0 5 15 10 20 30 25 35 40 TIME ( micro second ) Fig. E.7.A Laser generated ultrasonic waves in the unidirectional graphite/epoxy composite plate of 0.87 mm thickness ( 0 = 90° ). X105 14 12 10 1 2 3 4 5 6 FREQUENCY ( MHz ) Fig. E.7.B Frequency analysis of Fig. E.7.A. 7