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SECTION 1: PRODUCT AND COMPANY INFORMATION
PRODUCT NAME:
TRADE NAME:
CHEMICAL NAME /
SYNONYM:
CHEMICAL FAMILY:
MANUFACTURER:
ADDRESS:
24 HOUR EMERGENCY
PHONE: (CHEMTREC)
INFORMATION ONLY:
PREPARED BY:
APPROVED BY:
GHS LABEL ELEMENTS:
GAF 2 Part Adhesive (G2PRA) Part B
N/A
N/A
N/A
GAF
1 Campus Drive, Parsippany, NJ 07054
800–424–9300
800–766–3411
Corporate EHS
Corporate EHS
NFPA and HMIS RATINGS:
Health
Flammable
Reactive
Special Hazards
NFPA Hazard
Rating
2
0
0
-
Health
Flammable
Reactive
Personal Protection
HMIS Hazard
Rating
2
0
0
X
GHS LABEL ELEMENTS:
GHS CLASSIFICATION: Acute Toxicity - Category 1
Target Organ (SE) - Category 1
Target Organ (RE) - Category 1
Aspiration Toxicity - Category 1
Skin Irritant - Category 2
Hazardous to the Aquatic Environment (chronic) - Category 2
Page 1 of 8
GAF
GHS PICTOGRAMS:
SDS# 2210A
SIGNAL WORD: Danger
Harmful if swallowed.
Causes serious eye damage.
Causes skin irritation.
Causes damage to organs.
May cause damage to organs.
Causes damage to organs through prolonged or repeated exposure.
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
OCCUPATIONAL EXPOSURE LIMITS
CHEMICAL NAME
Poly(oxypropylene)diamine
CAS #
9046-10-0
% (BY WT)
1 -10
OSHA
N/A
ACGIH
N/A
OTHER
N/A
1,1,2,-Tetrafluroethane
Nitrogen
811-97-2
7727-37-9
10 -30
0.1- 5
NE
NE
NE
NE
AIHA - 4240 mg/m
3
NE
Diethyltoluenediamine 68479-98-1 1 - 10
NE NE NE
Diethylene Glycol
Aliphatic hydrocarbon
111-46-6
Trade
Secret
1 -10
1 -10
NE NE
AHIA - 10 mg/m
3
NE = Not Established
SECTION 3: HAZARDS IDENTIFICATION
PRIMARY ROUTE OF EXPOSURE:
SIGNS & SYMPTONS OF EXPOSURE
EYES:
Skin Contact, Eye Contact, Inhalation, Ingestion
SKIN:
May cause severe eye irritation. Signs and symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. May be harmful or fatal if absorbed through eyes.
May cause skin irritation. Signs and symptoms may include localized redness, swelling, cracking, dryness, blistering, itching and
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GAF SDS# 2210A
INGESTION:
INHALATION:
ACUTE HEALTH HAZARDS:
CHRONIC HEALTH HAZARDS: pain.
May be harmful if swallowed. Gastrointestinal irritation. Signs and symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target organ effects. May include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. May cause central nervous system depression. Signs and symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness and unconsciousness
May cause a respiratory tract irritation. Signs and symptoms may include cough, sneezing, nasal discharge, headache, hoarseness and nose and throat pain.
A single exposure above recommended guidelines may cause cardiac sensitization. Signs and symptoms may include irregular heartbeat, faintness, chest pain, and may be fatal. Intentional concentration and inhalation may be harmful or fatal.
Signs and symptoms of prolonged or repeated exposure may lead to an endocrine effect. Signs and symptoms may include disruption of gonadal, thyroid, adrenal or pancreatic function: changes in hormone production; alterations in circulating hormone levels; and/or changes in tissue response to hormones. In addition, may lead to kidney or bladder effects. Signs and symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increase blood urea nitrogen, blood in urine, painful urination.
None CARCINOGENICITY:
SECTION 4: FIRST AID MEASRURES
FIRST AID PROCEDURES
EYES:
SKIN:
INHALATION:
INGESTION:
Flush eyes immediately with large quantities of water for 15 minutes.
Seek immediate medical attention.
Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. If irritation persists, get medical attention.
Discard contaminated clothing/shoes or wash thoroughly with detergent before reuse.
Remove to fresh air. Administer oxygen if necessary. Seek immediate medical attention.
Do not induce vomiting unless instructed to do so by a licensed medical professional. Drink 1 or 2 glasses of water to dilute. Never give anything by mouth to an unconscious person. Seek immediate medical attention.
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GAF SDS# 2210A
NOTES TO PHYSICIANS OR
FIRST AID PROVIDERS:
RECOMMENDED FIRE FIGHTING
PROCEDURES:
UNUSUAL FIRE & EXPLOSION
HAZARDS:
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: FIRE FIGHTING PROCEDURES
SUITABLE EXTINGUISHING MEDIA:
HAZARDOUS COMBUSTION PRODUCTS:
CO2, Dry Chemical.
Carbon dioxide, carbon monoxide, hydrogen cyanide, oxides of nitrogen, aldehydes
Water may be ineffective in extinguishing a fire. Water may be used to blanket the fire and keep the fire-exposed containers and surfaced cool to prevent explosive rupture. Use selfcontained breathing apparatus and full fire protective equipment (Bunker Gear).
Closed containers exposed to heat from fire and may build pressure and explode.
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures : Evacuate unprotected and untrained personnel form hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spill in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Close cylinder. If the cylinder can’t be closed, place in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors.
Environmental precautions: For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.
Collect the resulting residue containing the solution. Dispose of collected material as soon as possible.
Clean-up methods: Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and PPE. Contain the spill. Working from around the edges of the spill inward. Cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Note: In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state and federal regulations.
SECTION 7: HANDLING AND STORAGE
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GAF SDS# 2210A
HANDLING AND STORAGE: Handling: Do not eat, drink, or smoke when using this product.
Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents.
Storage: Store the product away from heat and out of direct sunlight. Keep container in well-ventilated area. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents and acids.
None OTHER PRECAUTIONS:
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS /
VENTILATION:
RESPIRATORY PROTECTION:
EYE PROTECTION:
SKIN PROTECTION:
OTHER PROTECTIVE EQUIPMENT:
Use with appropriate local exhaust ventilation. Local exhaust ventilation with a minimum capture velocity of 100 linear feet per minute should be provided for application at or above the boiling temperature. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational
Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection.
Avoid breathing of vapors, mists or spray. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half face piece or full-face airpurifying respirator with organic vapor cartridges. Consult with your respirator manufacturer for the selection of appropriate type of respirators.
Avoid eye contact with vapors, mists, or spray. Use indirect vented goggles.
Avoid skin contact. Select and use gloves and protective clothing to prevent skin contact based on the results of an exposure assessment. Gloves made from either Butyl Rubber or Nitrile
Rubber is recommended for handling of this product. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Clothing adequate to protect skin. Remove and wash before reuse.
Eye wash, safety shower.
WORK HYGIENIC PRACTICES:
Normal industrial hygienic practices should be followed. Do not eat, drink, or smoke when using this product. Wash hands before eating, smoking or using the washroom and use soap and water to clean exposed areas.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
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GAF SDS# 2210A
APPEARANCE & ODOR:
FLASH POINT:
METHOD USED:
EVAPORATION RATE: pH (undiluted product):
SOLUBILITY IN WATER:
VAPOR DENSITY:
VAPOR PRESSURE:
VOC WITH WATER (LBS/GAL):
Amber brown color, liquid, slight sweet odor
>=200 °F
N/A
N/A
N/A
Moderate
3.6
85.7 psi
0.46
LOWER EXPLOSIVE LIMIT:
UPPER EXPLOSIVE LIMIT:
BOILING POINT:
MELTING POINT:
SPECIFIC GRAVITY:
PERCENT VOLATILE:
MOLECULAR WEIGHT:
WITHOUT WATER (LBS/GAL):
N/A
N/A
<=0 o
F
N/A
<=1.11
N/A
N/A
0.46
SECTION 10: STABILITY AND REACTIVITY
THERMAL STABILITY:
CONDITIONS TO AVOID (STABILITY):
INCOMPATIBILITY (MATERIAL TO
AVOID):
HAZARDOUS DECOMPOSITION OR BY-
PRODUCTS:
HAZARDOUS POLYMERIZATION:
STABLE X
None known
Strong oxidizing agents, strong acids
UNSTABLE
Carbon dioxide, carbon monoxide, hydrogen cyanide, oxides of nitrogen, aldehydes
Will not occur.
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SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION: There are no S.A.R.A. Section 313 ingredients in this material in excess of de minimis amounts.
Component-based Toxicology Information – Increased number of tumors in liver, thyroid, and possibly the mammary glands were observed in rates five DETDA (CAS No 68479-98-1) in their diet for two years.
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: No information available.
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GAF SDS# 2210A
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SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD:
RCRA HAZARD CLASS:
Incinerate in an industrial or commercial facility in the presence of a combustible material. The facility should be equipped to handle gaseous waste. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Combustion products will include HF. Facility must be capable of handling halogenated materials.
Not regulated.
SECTION 14: TRANSPORTATION INFORMATION
U.S. DOT TRANSPORTATION
PROPER SHIPPING NAME:
HAZARD CLASS:
ID NUMBER:
PACKING GROUP:
LABEL STATEMENT:
OTHER:
N/A
N/A
N/A
N/A
N/A
N/A
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA:
CERCLA:
SARA
311/312 HAZARD CATEGORIES:
313 REPORTABLE INGREDIENTS:
CALIFORNIA PROPOSITION 65:
Diethyltoluenediamine - CAS No. 68479-98-1
None
Pressure, immediate and delayed hazard.
Polymethylene Polyphenylene Isocyanate
N/A
SECTION 16: OTHER INFORMATION
ADDITIONAL COMMENTS: None.
Page 7 of 8
GAF SDS# 2210A
DATE OF PREVIOUS SDS:
CHANGES SINCE PREVIOUS SDS:
December 2015
Revisions per manufacturer.
This information relates to the specific material designated and may not be valid for such material used on combination with any other materials or in any process. Such information is to the best of our knowledge and belief accurate and reliable as of the date compiled. However, no representation, warranty or guarantee, expressed or implied, is made as to its accuracy, reliability, or completeness. It is the user’s responsibility to satisfy himself as to the suitability and completeness of such information for his particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license of valid patents.
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