GAF
Safety Data Sheet
SDS # 2210
SDS Date: December 2015
_________________________________________________________________________
SECTION 1: PRODUCT AND COMPANY INFORMATION
PRODUCT NAME:
GAF 2 Part Adhesive (G2PRA) Part A
TRADE NAME:
N/A
CHEMICAL NAME /
SYNONYM:
N/A
CHEMICAL FAMILY:
N/A
MANUFACTURER:
GAF
1 Campus Drive, Parsippany, NJ 07054
ADDRESS:
24 HOUR EMERGENCY
PHONE: (CHEMTREC)
INFORMATION ONLY:
PREPARED BY:
APPROVED BY:
800–424–9300
800–766–3411
Corporate EHS
Corporate EHS
GHS LABEL ELEMENTS:
NFPA and HMIS RATINGS:
NFPA Hazard
Rating
HMIS Hazard
Rating
2
1
0
Health
2
Flammable
Reactive
Flammable
Reactive
1
0
Special Hazards
-
Personal Protection
X
Health
GHS LABEL ELEMENTS:
GHS CLASSIFICATION:
Acute Toxicity - Category 1
Target Organ (SE) - Category 1
Target Organ (RE) - Category 1
Aspiration Toxicity - Category 1
Skin Irritant - Category 2
Skin Sensitizer
Hazardous to the Aquatic Environment (chronic) - Category 2
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GAF
SDS# 2210
GHS PICTOGRAMS:
SIGNAL WORD:
Danger
HAZARD
STATEMENTS:
Causes skin irritation
Causes serious eye irritation
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Harmful if inhaled.
May cause respiratory irritation.
May cause damage to organs: cardiovascular system
Causes damage to organs through prolonged or repeated exposure:
respiratory system
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
OCCUPATIONAL EXPOSURE LIMITS
CHEMICAL NAME
Polymethylene
Polyphenylene Isocyante
Fire Retardent
1,1,1,2,-Tetrafluroethane
Nitrogen
p,p’-methylenebis(phenyl
isocyanate)
CAS #
% (BY WT)
OSHA
ACGIH
OTHER
9016-87-9
40 -50
NE
NE
NE
Trade
Secret
10-15
811-97-2
5 -10
NE
NE
AIHA 4240
3
mg/m
NE
NE
NE
NE
NE
NE
7727-37-9
101-68-8
0.1- 5
0- 1
NE = Not Established
SECTION 3: HAZARDS IDENTIFICATION
PRIMARY ROUTE OF EXPOSURE:
Skin Contact, Eye Contact, Inhalation, Ingestion
SIGNS & SYMPTONS OF EXPOSURE
EYES:
May cause severe eye irritation. Signs and symptoms may include
significant redness, swelling, pain, tearing, cloudy appearance of
the cornea, and impaired vision.
SKIN:
May cause allergic skin reaction or irritation. Signs and symptoms
may include redness, swelling, cracking, dryness, blistering, itching
and pain.
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GAF
SDS# 2210
INGESTION:
May cause gastrointestinal irritation. Signs and symptoms may
include abdominal pain, stomach upset, nausea, vomiting and
diarrhea.
INHALATION:
May cause an allergic respiratory reaction. Signs and symptoms
may include difficulty breathing, wheezing, cough and tightness of
chest. May cause a respiratory tract irritation. Signs and symptoms
may include cough, sneezing, nasal discharge, headache,
hoarseness and nose and throat pain. Signs and symptoms of
prolonged or repeated exposure may include cough, shortness of
breath, chest tightness, wheezing, increased heart rate, bluish
colored skin, sputum production, changes in lung function tests
and/or respiratory failure.
ACUTE HEALTH HAZARDS:
A single exposure above recommended guidelines may cause
cardiac sensitization. Signs and symptoms may include irregular
heartbeat, faintness, chest pain, and may be fatal. Intentional
concentration and inhalation may be harmful or fatal.
CHRONIC HEALTH HAZARDS:
Prolonged and repeated overexposure may cause kidney, bladder
effects. Signs and symptoms may include changes in urine
production, abdominal or lower back pain, increased protein in
urine, increased blood urea nitrogen, blood in urine and painful
urination. Persons previously sensitized to isocyanates may
develop a cross sensitization reaction to other isocyanates.
CARCINOGENICITY:
None
SECTION 4: FIRST AID MEASRURES
FIRST AID PROCEDURES
EYES:
Flush eyes immediately with large quantities of water for 15 minutes.
Seek immediate medical attention.
SKIN:
Remove contaminated clothing and shoes. Immediately flush skin with
large amounts of water. If irritation persists, get medical attention.
Discard contaminated clothing/shoes or wash thoroughly with detergent
before reuse.
INHALATION:
Remove to fresh air. Administer oxygen if necessary. Seek immediate
medical attention.
INGESTION:
Do not induce vomiting unless instructed to do so by a licensed medical
professional. Drink 1 or 2 glasses of water to dilute. Never give anything
by mouth to an unconscious person. Seek immediate medical attention.
NOTES TO PHYSICIANS OR
FIRST AID PROVIDERS:
Exposure may increase myocardial irritability. Do not administer
sympathomimetic drugs unless absolutely necessary.
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GAF
SDS# 2210
SECTION 5: FIRE FIGHTING PROCEDURES
SUITABLE EXTINGUISHING MEDIA:
CO2, Dry Chemical.
HAZARDOUS COMBUSTION PRODUCTS:
Carbon dioxide, carbon monoxide, hydrogen cyanide, oxides
of nitrogen
RECOMMENDED FIRE FIGHTING
PROCEDURES:
Water may be ineffective in extinguishing a fire. Water may be
used to blanket the fire and keep the fire-exposed containers
and surfaced cool to prevent explosive rupture. Use selfcontained breathing apparatus and full fire protective
equipment (Bunker Gear).
UNUSUAL FIRE & EXPLOSION
HAZARDS:
Closed containers exposed to heat from fire and may build
pressure and explode.
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES:
Personal precautions, protective equipment and emergency
procedures: Evacuate unprotected and untrained personnel form
hazard area. The spill should be cleaned up by qualified
personnel. Ventilate the area with fresh air. For large spill, or spill
in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene
practice. Warning! A motor could be an ignition source and could
cause flammable gases or vapors in the spill area to burn or
explode.
Environmental precautions: Place in a container approved for
transportation by appropriate authorities, but do not seal the
container for 48 hours to avoid pressure build-up. For larger spills,
cover drains and build dikes to prevent entry into sewer systems or
bodies of water. Collect the resulting residue containing the
solution. Dispose of collected material as soon as possible.
Clean-up methods: Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory
protection, ventilation, and PPE. Contain the spill. Working from
around the edges of the spill inward. Cover with bentonite,
vermiculite, or commercially available inorganic absorbent
material. Mix in sufficient absorbent until it appears dry. Collect as
much of the spilled material as possible. Note: In the event of a
release of this material, the user should determine if the release
qualifies as reportable according to local, state and federal
regulations.
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE:
Do not eat, drink, or smoke when using this product. Wash
exposed areas thoroughly with soap and water. Contents may be
under pressure, open carefully. Avoid breathing of vapors, mists
or spray. Avoid skin contact. Avoid eye contact with vapors, mists,
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GAF
SDS# 2210
or spray. For industrial or professional use only. Avoid contact
with oxidizing agents. Store the product away from heat and out of
direct sunlight. Keep container in well-ventilated area. Store away
from oxidizing agents.
None
OTHER PRECAUTIONS:
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS /
VENTILATION:
Local exhaust preferable. If venting, discharge exhaust away from
ignition sources. If in confined areas, use mechanical ventilation to
keep vapor concentration under permissible TLV and LEL and/or
control mist, vapor, or spray. If ventilation is not adequate, use
respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray. Select one of the
following NIOSH approved respirators based on airborne
concentration of contaminants and in accordance with OSHA
regulations: Half face piece or full-face air-purifying respirator with
organic vapor cartridges. Select and use respiratory protection to
prevent an inhalation exposure based on the results of an exposure
assessment. Consult with your respirator manufacturer for the
selection of appropriate type of respirators.
EYE PROTECTION:
Avoid eye contact with vapors, mists, or spray. Use indirect vented
goggles.
SKIN PROTECTION:
Avoid skin contact. Select and use gloves and protective clothing to
prevent skin contact based on the results of an exposure
assessment. Consult with your glove and/or protective clothing
manufacturer for selection of appropriate compatible materials.
Gloves made from either Butyl Rubber or Nitrile Rubber is
recommended for handling of this product.
OTHER PROTECTIVE EQUIPMENT:
Clothing adequate to protect skin. Remove and wash before reuse.
Eye wash, safety shower.
WORK HYGIENIC PRACTICES:
Normal industrial hygienic practices should be followed. Do not eat,
drink, or smoke when using this product. Wash hands before
eating, smoking or using the washroom and use soap and water to
clean exposed areas.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE & ODOR:
Light brown color, liquid, slight musty odor
>=200 °F
LOWER EXPLOSIVE LIMIT:
N/A
METHOD USED:
N/A
UPPER EXPLOSIVE LIMIT:
N/A
EVAPORATION RATE:
N/A
BOILING POINT:
FLASH POINT:
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o
<=0 F
GAF
SDS# 2210
pH (undiluted product):
N/A
SOLUBILITY IN WATER:
Insoluble
3.6
VAPOR DENSITY:
85.7 psi
VAPOR PRESSURE:
0.46
VOC WITH WATER (LBS/GAL):
MELTING POINT:
N/A
SPECIFIC GRAVITY:
1.23
PERCENT VOLATILE:
N/A
MOLECULAR WEIGHT:
N/A
WITHOUT WATER (LBS/GAL):
0.46
SECTION 10: STABILITY AND REACTIVITY
THERMAL STABILITY:
STABLE X
UNSTABLE
CONDITIONS TO AVOID (STABILITY):
Heat, and open flames.
INCOMPATIBILITY (MATERIAL TO
AVOID):
Strong oxidizing agents
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
Carbon dioxide, carbon monoxide, hydrogen cyanide, oxides of
nitrogen
HAZARDOUS POLYMERIZATION:
Will not occur.
__________________________________________________________________________________________
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:
There are no S.A.R.A. Section 313 ingredients in this material in
excess of de minimis amounts.
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:
No information available.
__________________________________________________________________________________________
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD:
Incinerate in a permitted hazardous waste incinerator in the presence of a
combustible material. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
RCRA HAZARD CLASS:
D003 (Reactive). Since regulations may vary, consult applicable
regulations or authorities before disposal.
SECTION 14: TRANSPORTATION INFORMATION
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GAF
SDS# 2210
U.S. DOT TRANSPORTATION
PROPER SHIPPING NAME:
N/A
HAZARD CLASS:
N/A
ID NUMBER:
N/A
PACKING GROUP:
N/A
LABEL STATEMENT:
N/A
OTHER:
N/A
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA:
N/A
CERCLA:
None
SARA
311/312 HAZARD CATEGORIES:
Pressure, Immediate and delayed hazard.
313 REPORTABLE INGREDIENTS:
Polymethylene Polyphenylene Isocyanate
CALIFORNIA PROPOSITION 65:
N/A
SECTION 16: OTHER INFORMATION
ADDITIONAL COMMENTS:
None.
DATE OF PREVIOUS SDS:
December 2015
CHANGES SINCE PREVIOUS SDS:
Revisions per manufacturer.
This information relates to the specific material designated and may not be valid for such material used
on combination with any other materials or in any process. Such information is to the best of our
knowledge and belief accurate and reliable as of the date compiled. However, no representation,
warranty or guarantee, expressed or implied, is made as to its accuracy, reliability, or completeness. It
is the user’s responsibility to satisfy himself as to the suitability and completeness of such information
for his particular use. We do not accept liability for any loss or damage that may occur from the use of
this information. Nothing herein shall be construed as a recommendation for uses which infringe valid
patents or as extending a license of valid patents.
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