Experimental Investigation of a New Combustor Model for Gas Turbines by M.J. Melo(1), J.M.M. Sousa(1), M. Costa(1) and Y. Levy(2) (1) Instituto Superior Técnico, Mechanical Engineering Department, Av. Rovisco Pais, 1049 - 001 Lisboa, Portugal E-Mail: mcosta@navier.ist.utl.pt (2) Faculty of Aerospace Engineering, Technion, Israel Institute of Technology, Haifa 32000, Israel E-Mail: levyy@aerodyne.technion.ac.il ABSTRACT The study reported herein aims to provide information on the present performance of a new combustor model for gas turbines both under non-reacting and reacting conditions. The flow characteristics of the combustor model under non-reacting conditions have been investigated using Laser-Doppler Anemometry. Data is reported for mean and turbulent velocities as a function of the air mass flow rate and its preheating temperature. The isothermal flow characterization was followed by combustion measurements at the exit of the combustor model. Measurements of mean gas species concentration (O2, CO2, CO, HC and NOx) are reported as a function of the equivalence ratio and thermal input for two different configurations of the main air inlets. The isothermal data revealed that (i) a common feature to all test conditions is the establishment of a large recirculation zone, as shown in Fig 1; (ii) mean and turbulent velocities increase within the recirculation zone as the air mass flow rate increases and (iii) the effect of the air preheating temperature on the flow field is marginal. Under reacting conditions the data revealed that (i) combustion performance is higher for both lower values of thermal input and equivalence ratio; (ii) NOx emissions are very low regardless of the combustor operating conditions and (iii) the effect of the air inlet configuration on both combustor performance and pollutant emissions is marginal. |V| [m/s] 18.0 Air 16.8 15.6 14.4 13.2 12.0 10.8 9.6 8.4 7.2 6.0 4.8 3.6 2.4 1.2 0.0 V [m/s] Fig. 1. Typical result for the isothermal mean flow structure within the combustor model 1 1. INTRODUCTION The increase, in recent years, in the efficiencies of Gas Turbines (GT) has occurred regardless of a tightening in environmental legislation on the emission of nitrogen oxides (NOx). The hot primary zone within the combustor and the higher turbine inlet temperatures, a prime factor for increased efficiency, tend to increase the formation of NOx. Dry low-NOx combustion systems have therefore been developed, but it appears that there is still a great need for low-cost, safe and reliable NOx reduction methods especially for high efficiency small GT engines. The primary objective of the present study is to develop innovative combustors for small GT, suitable for safe and reliable operation at high temperatures while maintaining low NOx levels (typically less than 20 ppm). As an example, for a GT with conventional efficiencies of the turbine (87%) and compressor (85%), operating at about 15 bars, a Turbine Inlet Temperature (TIT) above 1600 K is required to boost the thermal efficiency over the value of 35%. A similar concept is applicable to larger GT incorporated in Combined Rankin–Brayton Cycle (GTCC) to exceed 60% efficiencies of energy conversion. Hence, relatively high exit combustion temperatures are required for high efficiency GT systems. The low-NOx emission levels from flameless oxidation combustors enable the operation of GT at higher TIT levels (in comparison to conventional dry low-NOx technologies) thus maintaining elevated efficiency values and by that enabling reduction in CO2 emissions. In power systems which incorporates a heat exchanger (the regenerative cycle), the effect of TIT is even more significant. In a GT combustor, there is only a minor link between the maximum flame temperature within the combustor (the major parameter which affects NOx production) and the TIT value. High combustion temperature values (in the primary combustion zone) are typically used to improve flame stability. The maximum TIT values are determined by the ability of the turbine blades to operate reliably while exposed to the high temperature gases and being heavily loaded by the centrifugal stresses. Significant cooling using dilution air is applied to the combustion products of the primary zone in order to reduce their temperature to allowable TIT values. Dry low-NOx techniques, as Lean Premixed Pre-Vaporizer (LPP) or Catalytic Combustion (CC) are typically based on attempts to reduce the flame temperature of the primary zone while maintaining flame stability. The method proposed in the present FLOXCOM program1, presents an innovative alternative that is aimed for clean and efficient GT. It is based on a technologically combustion solution, the flameless oxidation method. This promising technology allows operation of the combustor at high temperature with ultra-low NOx levels. In addition, this combustion mode has further advantages over other advanced NOx reduction technologies such as safety, reliability and the possibility for its incorporation in a heat exchanger cycle using high air temperatures at the combustor inlet. Flameless oxidation requires exhaust gas recycling, whether it is internal or external. It is an effective method to reduce flame temperature and thereby NOx emissions. Unfortunately, the efficiency of this method is affected by the maximal possible amount of recirculated hot exhaust gas. Flame instabilities and eventually blowout may occur if the burner is operated with too low internal recirculation rates of combustion products. Whenever the temperature of the mixture of the recycled exhaust gas with the fresh air exceeds the autoignition temperature of the fuel, the fuel is ignited automatically and continuous combustion is sustained. In contrast to classic diffusion flame, temperature peaks can be avoided even at high air preheat temperatures in this combustion mode. It is characterized by a moderate and distributed temperature rise, small gradient of species or temperatures, low radiation emissions and noise. Therefore, the thermal-NO formation can be largely suppressed. Other advantages are: improved internal combustor aerodynamics for more uniform wall temperature and lower wall cooling requirements; lower thermal stresses, and lower values of the exhaust gas pattern factors for more circumferential uniformity at the combustor exit. Both of these advantages are relevant for increased Mean Time Between Failure (MTBF) and reliability of the GT. The main objective described in the present paper is directed to the development of an innovative combustor for GT. It can also be applied to aero-engines for both helicopters and jet aircrafts. The application of the flameless oxidation combustion concept to GT combustors and the role of the flameless oxidation mode in NOx emission reductions was already confirmed by computer simulations (Levy et al., 2004a). Flameless oxidation is also being currently used in industrial furnaces with regenerative burners in non-adiabatic cycle, indicating extremely low-NOx emission levels (typically less than 5 ppm), much below the environmental requirements. 1 The FLOXCOM program is conducted through the support of the FP5 program of the EC (ENK5-CT-2000-00114, see http://floxcom.ippt.gov.pl) by a consortium of industrial and academia partnership that consists of eight parties from different European Countries and Israel. The partners include departments of universities and engineering firms having expertise in the development of GT engine evaluation, and an R&D center of an industrial group. 2 The technological objectives achieved and described in the present paper are to test a sector of a pilot combustor using the flameless oxidation combustion concept at atmospheric pressure. More specifically, it describes the effort invested to improve the combustion air injection mode and distribution. This is done by numerical (elsewhere) and experimental investigation of the flow field and combustion features. Different combustor models (of the 60-degree sectors) were produced with optical windows, for detailed local measurements of the velocity field, temperatures and species concentrations distributions under non-reactive and reactive conditions. These were used for further adjustments of the different models and for comparisons with the CFD predictions (Levy and Arfi, 2004 and Levy et al., 2004a, 2004b). 2. EXPERIMENTAL METHOD and PROCEDURES Figure 2 shows a schematic of the combustor cross section of the model. In this work, two different configurations for the Air 1 (see Fig. 2) inlets were used, as shown in Figs. 3a) and 3b). Air 1 Fuel Air 2 Exhaust gases Fig. 2. Schematic of the combustor model Prior to the combustion experiments, the isothermal flow in the combustor model was thoroughly characterised by the application of Laser-Doppler Anemometry (LDA), as shown in Fig. 4. A two-component velocimeter from DANTEC, which was operated in the dual-beam backward-scatter mode, was employed to meet this objective, see, e.g., Melo et al. (2002). High data rates, close to 1 kHz, were obtained by seeding the flow with small droplets of a mixture prepared with ethyleneglycol (20%) and water (80%). The droplets were generated by four medical nebulisers INSPIRON 002305-A. The back-scattered light collected by the receiving optics was band-passed filtered and processed by two DANTEC 57N20/57N35 Burst Spectrum Analyzers interfaced with a IBM AT compatible computer. Velocity statistics were evaluated by ensemble averaging, calculated from 10,000 samples, using BURSTware software. Errors incurred in the measurement of velocities by displacement and distortion of the measuring volume due to refraction on the combustor model walls were found to be negligibly small and within the accuracy of the measuring equipment in the case of the LDA. 3 (a) (b) Fig. 3. Schematics of the flow configurations for the Air 1 (see Fig. 1) a) Original Configuration b) Modified Model Configuration Slave BSA Master BSA 2x Oscilloscope Photo multipliers Laser (Ar+-ion) Fiber optics 3-D traverse system Back-scattering probe Seeding Pressurized air Test rig Pressurized air for windows cleaning Air 1 P P Fan T Flowmeter T Preheater Pressurized Air 2 Fuel (CH4) Fig. 4. LDA measurement system Figure 5 shows the measurement system for the combustion tests. The gases for the measurement of the flue-gas data mean O2, CO, CO2, hydrocarbons (HC), and NOx concentrations - were withdrawn using a water-cooled stainless steel probe. The wet sample was drawn through the probe and part of the sampling system by an oil-free diaphragm pump. A condenser removed the main particulate burden and condensate. A filter and a drier removed any residual moisture and 4 particles so that a constant supply of clean dry combustion gases was delivered to each instrument through a manifold to give species concentrations on a dry basis. The analytical instrumentation included a magnetic pressure analyzer for O2 measurements, nondispersive infrared gas analyzers for CO2 and CO measurements, a flame ionization detector for HC measurements, and a chemiluminescent analyzer for NOx measurements. The analog outputs of the analyzers were transmitted via analogic/digital (A/D) boards to a computer where the signals were processed and the mean values computed. Zero and span calibrations with standard mixtures were performed before and after each measurement session. The maximum drift in the calibration was within ± 2% of the full scale. At the combustor exit, where the gas composition was nearly uniform, probe effects were negligible and errors arose mainly from quenching of chemical reactions and sample handling. Samples were quenched near the probe tip to about 150 °C and condensation of water within the probe was avoided by controlling the inlet temperature of the cooling water (typically to around 60 °C). Repeatability of the flue-gas data was, on average, within 5%. 12 bit A/D FID analyser (UHC) Probe 88888 88888 Chemiluminescent analyser (NOX) Paramagnetic analyser (O2) 88888 Infrared analyser (CO, CO2) Exhaust Termocouple type K Cotton wool Condenser Zero Span gas gas Silica gel Water Filter Dryer Water Diaphragm pump Pressurized air for windows cleaning Test rig P Exhaustion T Air 1 Flowmeter P T Pressurized Fuel Air 2 Preheater Fan Thin-plate orifice (CH4) Fig. 5. Combustion measurement system 3. RESULTS AND DISCUSSION Table 1 summarises the operating conditions for the experiments under non-reacting conditions, which allow for an assessment of the effects of the air mass flow rate (Air 1, see Fig. 2) and its preheating temperature on the flow characteristics. Table 1. Operating conditions for the experiments under non-reacting conditions for the original model configuration* Test condition Air 1 flow rate (kg/s) Air 1 temperature (K) 1 0.12 293 2 0.12 330 3 0.095 330 4 0.07 330 * For all conditions: Air 2 flow rate = 0 kg/s; Fuel (air) flow rate = 0.00317 kg/s; Fuel (air) temperature = 293 K. 5 Figure 6 shows the effect of the flow rate of Air 1 on the mean flow structure. The figure reveals that a common feature to all test conditions is the establishment of a large recirculation zone and that the mean velocities increase within the recirculation zone as the Air 1 mass flow rate increases. The figure also reveals that near the combustor outlet the mean velocities are higher for the intermediate Air 1 mass flow rate tested (test condition 3 in Table 1). Figure 7 shows the effect of the flow rate of Air 1 on the turbulence kinetic energy contours. It is seen that they are consistent with the data presented in Fig. 6. Figure 8 shows the effect of the Air 1 inlet preheating temperature on the mean flow structure. As it can be seen, this has only a marginal effect on the flow field. Test condition 2 Air 1: 0.12 kg/s Test condition 3 Air 1: 0.095 kg/s Test condition 4 Air 1: 0.07 kg/s |V| [m/s] |V| [m/s] |V| [m/s] 18.0 18.0 16.8 16.8 15.6 15.6 14.4 14.4 13.2 13.2 12.0 12.0 10.8 10.8 9.6 9.6 8.4 8.4 7.2 7.2 6.0 6.0 4.8 4.8 3.6 3.6 2.4 2.4 1.2 1.2 0.0 0.0 V [m/s] 18.0 16.8 15.6 14.4 13.2 12.0 10.8 9.6 8.4 7.2 6.0 4.8 3.6 2.4 1.2 0.0 V [m/s] V [m/s] Fig. 6. Effect of the Air 1 flow rate on the mean flow structure Test condition 3 Air 1: 0.095 kg/s Test condition 4 Air 1: 0.07 kg/s Test condition 2 Air 1: 0.12 kg/s k [m2 /s2] k [m2/s2] k [m2/s2] 19.0 19.0 19.0 17.8 17.8 16.6 16.6 15.4 15.4 14.2 14.2 13.0 13.0 11.8 11.8 10.6 10.6 9.4 9.4 8.2 8.2 7.0 7.0 5.8 5.8 4.6 4.6 3.4 3.4 2.2 2.2 1.0 1.0 17.8 16.6 15.4 14.2 13.0 11.8 10.6 9.4 8.2 7.0 5.8 4.6 3.4 2.2 1.0 Fig. 7. Effect of the Air 1 flow rate on the turbulence kinetic energy contours Test condition 1 Temperature of Air 1: 293 K Test condition 2 Temperature of Air 1: 330 K |V| [m/s] 18.0 16.8 15.6 18.0 16.8 15.6 14.4 14.4 13.2 13.2 12.0 12.0 10.8 10.8 9.6 9.6 8.4 8.4 7.2 7.2 6.0 6.0 4.8 4.8 3.6 3.6 2.4 2.4 1.2 0.0 V [m/s] Fig. 8. Effect of the Air 1 inlet temperature on the mean flow structure 6 |V| [m/s] 1.2 0.0 V [m/s] Table 2 summarises the operating conditions for the experiments under reacting conditions, which allow for an assessment of the effects of the equivalence ratio and thermal input on pollutant emissions for both configurations studied (see Figs. 3b and 3c). Table 2. Operating conditions for the experiments under reacting conditions for both model configurations Air 1 flow rate Air 1 Equivalence ratio ( φ ) Methane flow rate (kg/s) Model (kg/s) temperature (K) -5 -4 Original (Fig. 2a) 0.012-0.038 361-387 7.8x10 -4.2x10 0.013-0.34 Modified (Fig. 2b) 0.012-0.035 378-417 1.2x10-4-5.1x10-4 0.13-0.49 Figure 9 show the measured flue-gas data for the original model configuration, shown in Fig. 3a, as a function of the equivalence ratio and of the thermal input. The figure reveals that combustion performance is higher for both lower values of thermal input and equivalence ratio. It is interesting to note that NOx emissions are very low regardless of the combustor operating conditions. Total thermal input (kW) 12.0 7.8 12.0 10000 22 9000 20 10000 CO2 18 CO CO NOx 16 HC 7000 14 6000 12 5000 10 4000 8 3000 6 4 2000 2 1000 0.10 0.15 0.20 7.8 12.0 0.25 0.30 0.35 0.40 0.45 0 0.50 HC 14 5000 4000 8 3000 6 4 2000 2 1000 0.10 0.15 0.20 0.25 0.30 0.35 0.40 Total thermal input (kW) 16.3 7.8 12.0 CO2 18 CO NOx 14 10000 22 9000 20 8000 7000 6000 12 5000 10 4000 8 3000 6 4 2000 2 1000 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 16.3 0 0.45 0.50 20.9 10000 O2 20 HC 7000 10 Total thermal input (kW) 16 8000 6000 Equivalence ratio O2 9000 12 Equivalence ratio 22 0 0.00 0.05 NOx 16 0 0.00 0.05 CO2 CO 18 O2, CO 2 (dry volume %) 0 0.00 0.05 O2, CO 2 (dry volume %) 8000 O2, CO 2 (dry volume %) CO2 18 CO, HC, 100 NO x (dry volume ppm) O2 20 CO, HC, 100 NO x (dry volume ppm) O2, CO 2 (dry volume %) O2 CO, HC, 100 NO x (dry volume ppm) 7.8 22 0 0.50 NOx 16 HC 14 8000 7000 6000 12 5000 10 4000 8 3000 6 4 2000 2 1000 0 0.00 0.05 0.10 0.15 0.20 Equivalence ratio 0.25 0.30 0.35 0.40 Equivalence ratio Fig. 9. Flue-gas data for the original model configuration shown in Fig. 3a 7 9000 0 0.45 0.50 CO, HC, 100 NO x (dry volume ppm) 3.9 Total thermal input (kW) In order to try to improve the combustion performance of the combustor, the configuration of the air inlets has been modified, as shown in Fig. 3b). The measured flue-gas data for this new configuration is represented in Fig. 10. As can be seen, the effect of the air inlet configuration on both combustor performance and pollutant emissions is marginal. Total thermal input (kW) 12.0 7.8 O2 20 CO2 18 CO HC 20 CO2 18 CO 8000 6000 12 5000 10 4000 8 3000 6 2000 4 1000 2 0 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 NOx 20.9 HC 14 5000 4000 8 3000 6 2000 1000 2 0 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 7.8 20.9 25.6 30.1 10000 22 9000 20 CO2 18 CO 18 CO 16 HC 14 8000 7000 O2 6000 12 5000 10 4000 8 3000 6 2000 4 1000 2 0.40 0.45 NOx O2, CO 2 (dry volume %) CO2 CO, HC, 100 NO x (dry volume ppm) 20 NOx O2, CO 2 (dry volume %) 0 0.45 0.50 Total thermal input (kW) 25.6 0.25 0.30 0.35 7000 10 O2 0.10 0.15 0.20 8000 Equivalence ratio 22 0 0.00 0.05 9000 6000 4 0 0.50 10000 12 Total thermal input (kW) 16.3 O2 16 Equivalence ratio 12.0 20.9 9000 7000 14 16.3 22 16 HC 14 7000 5000 10 4000 8 3000 6 0 0.00 0.05 2000 1000 0.10 0.15 0.20 0.25 0.30 0.35 0.40 Equivalence ratio Fig. 10. Flue-gas data for the modified model configuration shown in Fig. 3b 8 8000 6000 2 Equivalence ratio 9000 12 4 0 0.50 10000 0 0.45 0.50 CO, HC, 100 NO x (dry volume ppm) O2, CO 2 (dry volume %) NOx 16 12.0 10000 O2, CO 2 (dry volume %) 22 CO, HC, 100 NO x (dry volume ppm) 7.8 CO, HC, 100 NO x (dry volume ppm) Total thermal input (kW) 5.8 4. CONCLUDING REMARKS The flow characteristics of a combustor model under non-reacting conditions have been investigated using LaserDoppler Anemometry. Data is reported for mean and turbulent velocities as a function of the air mass flow rate and its preheating temperature. The main conclusions are as follows: i) a common feature to all test conditions is the establishment of a large recirculation zone; ii) mean and turbulent velocities increase within the recirculation zone as the air mass flow rate increases; iii) near the combustor outlet the mean and turbulent velocities are higher for the intermediate air mass flow rate tested and iv) the effect of the air inlet preheating temperature on the flow field is marginal. The isothermal flow characterization was followed by combustion measurements at the exit of the combustor model. Measurements of mean gas species concentration (O2, CO2, CO, HC and NOx) are reported as a function of the equivalence ratio and thermal input for two different configurations of the air inlets. The main conclusions are as follows: i) combustion performance is higher for both lower values of thermal input and equivalence ratio; ii) NOx emissions are very low regardless of the combustor operating conditions and iii) the effect of the air inlet configuration on both combustor performance and pollutant emissions is marginal. ACKNOWLEDGMENTS Financial support for this work was provided by the European Commission under the contract number ENK5-CT 20000014 and is acknowledged with gratitude. The first author (M. Melo) is pleased to acknowledge the Fundação para a Ciência e Tecnologia for the provision of a scholarship (SFRH/BD/6345/2001). REFERENCES Levy, Y. and Arfi, P. (2004). “Turbulence-Chemistry Interactions Calculations for Improved NOx Predictions”, Cleanair Journal, in press. Levy, Y., Sherbaum V. and Arfi, P. (2004a). “Basic Thermodynamics of FLOXCOM, the Low-NOx Gas Turbines Adiabatic Combustor”, Applied Thermal Engineering, in press. Levy, Y., Banzger (Polyakh), Y. and Sherbaum V. (2004b). “Theoretical Investigation of Single-Point Water Injection In Cross-Flow”, submitted for publication. Melo, M., Sousa, J. and Costa, M. (2002). “PDA Measurements of Single Point Injection in Cross-flow”, 11th International Symposium on the Application of Laser Techniques to Fluid Mechanics, Lisbon, 7-11 July. 9